Document Zn7ZE3gY73Naevoz6MmpQdYyJ

Preprintfrom the 1983 BUREAU OF MINES MINERALS YEARBOOK Asbestos UNITED STATES DEPARTMENT OF THE INTERIOR CAPCO JEN 0001697 UNITED STATES DEPARTMENT OF THE INTERIOR * William P. Clark, Secretary BUREAU OF MINES Robert C. Horton, Director This publication is a chapter from the current Bureau of Mines Minerols Yearbook, comprising Volume I, Metoh and Minerals; Volume //, Area Reports: Domestic; Volume III, Area Reports: International. The separate volumes of the Yearbook are sold by the Superintendent of Documents, Washington, D.C. 20402. CAPCO JEN 0001698 Asbestos By R. A. Clifton1 U.S apparent consumption of asbestos continued to decline in 1983 because of its unfavorable public ecological image. U.S. apparent consumption was 88% of that in 1982 and 27% of the alltime high of 1973. Shipments from domestic mines, all chrysotile, increased 10%, and imports decreased 19%. The Manville Corp., formerly JohnsManville Inc., the largest producer of asbes tos in the market economy countries and the largest U.S. manufacturer of asbestos products, ceased all asbestos mining and product manufacturing. Manville's Canadi an mine, the world's largest, was purchased by a Canadian group and production was expected to continue. Domestic Data Coverage.--Domestic pro duction data for asbestos are developed by the Bureau of Mines by means of a volun tary industry survey. Of the three can vassed operations to which a survey collec tion request was made, all responded, repre senting 100% of the total production data shown in table 1. Table I.--Salient asbestos statistics 1979 1980 1981 1982 1963 Ulull'd Si.ilea PrvKluvtimi 'safest ...............nu-lric Ions. _ V.ilue ... . thousands. _ Exerts .md reex|K>rls funmjnuljLturedi metric tons. _ V.ilue - . . . . . thousands. _ Expoi t- dnd reexports of asbestos products lvalue) do. . . . Imports lor consumption (uninanulailured) metric tons. . Value. .......................... _ thousands. _ Kcliused from stockpile (unmanufactured) metric tons. . Consumption . do. . . World Production............... .......... ................................... d i * 93,354 $28,925 411.291 $17,381 $137,890 513,08-1 $135,210 1 .'jiiU,f)O0 r1.758,022 80.U79 $30,599 48.071 $21,007 $141,653 327.200 $91,809 358,700 r4.oyy.3uo 75,618 $30,CSS 04,419 $21,508 $145,130 337,618 $103,893 63.515 $24,917 58.771 $19,713 $127,867 241,737 $64,925 69,906 $27,860 54.634 $19,683 $129,582 196,387 $57,956 348,800 246,500 217,000 4.337,140 P4.0&G,314 *4,157.256 *Estimjted ^Preliminary 1 Revised Legislation and Government Pro grams.--The Occupational Safety and Health Administration tOSHA' published in the Federal Register of November 4 its Emergency Temporary Standard (ETS), which lowers, by a factor of four, the per missible level of workplace, exposure to asbestos. The ETS was challenged in the Fifth Circuit Court of Appeals by the asbes tos industry and, on November 23, was stayed pending judicial review. On July 27, in testimony before the Sen ate Subcommittee on Toxic Substances and Environmental Oversight, the Environmen tal Protection Agency (EPA) testified that within 1 year it would propose a ban on certain asbestos products. The products to be covered by the proposed ban are saturat ed asbestos roofing felt, unsaturated roofing felt, asbestos flooring felt, asbestos sheet flooring, vinyl-asbestos floor tile, and asbestos-cement pipe. It was EPA's inten tion to propose anqther rule in October 1984, which would set production ceilings for remaining asbestos products. These lim its would decline until all products contain ing asbestos would be eventually phased out. 1 CAPCO JEN OOOI699 MINERALS YEAKliOOK, 1983 The Consumer Products Safety Commis sion iCPSC) published its final report of the Chronic Hazard Advisory Panel on Asbes tos. Copies of the report are available from the Office of the Secretary, Consumer Prod ucts Safety Commission, Washington, DC -0307. Copies may also be obtained by calling the Office of the Secretary at 1301) 493-6800. In July, EPA, CPSC, and OSHA set up a formal task force on asbestos. The group was to develop a coordinated Federal ap proach to protect the public from health hazards of asbestos in the workplace, during use of a product, or from disposal practices. The group's goals include assessing avail able data on asbestos health hazards, coor dinating scientific research, identifying con trol measures, and developing a uniform approach to issuingregulations. Environmental Impact.--The mortality rate of Reserve Mining Co.'s employees exposed to asbestos-containing taconite dust was the subject of a medical journal article.* It was found that men employed by Reserve from 1952 to 1976 had a mortality rate significantly lower than that expected for white males in the State of Minnesota and that deaths from malignant diseases were marginally below those expected for the State. Table 2.--Stockpile goals and Government inventories for asbestos as of December 31 (Metric tons) Stockgoafs Total inventories 1881 1982 HlsT Amukite _ .............................................................................. Chrysolite - -___________________________ ______________ -.............. frjciijohte........................................................................................................... Total___________________________ _________________________ _______ 15,422 2.722 18.144 38.587 9.034 f2,l63 r49,784 38,587 9.034 754 48.375 38.591 9.753 754 49.098 DOMESTIC PRODUCTION Mines in the United States shipped about 10% more asbestos than in 1982, and the value increased 12%. Only two States pro duced asbestos; California was the leader, followed by Vermont. Calaveras Asbestos Corp. was California's and the Nation's leading producer, from its Coppcropolis Mine. The other California producer, the Santa Rita Mine on the Joa quin Ridge near Coalinga, in San Benito County, was owned and operated by Union Carbide Corp. This mine was the second largest U.S. producer. The third U.S. pro ducer was the Vermont Asbestos Group's Lowell Mine in Orleans County, VT. Table 3.--Asbestos producers in the United States in 1983 Slate and company California. Cjldserfta Asbestos Corp________ Union Carbide CotP - Vermont Vermont AsmsUm Croup . _ County Mine Tvpe of asbestos Calaveras_________ * San Benito________ Orleans___________ Copperopolia _____ _ Santa Rita_______ Lowell__________ Chrysotile. Do Dc. Employment in U.S. asbestos mines and mills remained at about 400 persons. Miners at the Asbestos Group's mine in Vermont went on strike in October and were still out at yearend. Despite this, the management was optimistic about the fu ture. A foreclosure suit had been dismissed, and there was sufficient inventory at the mine to meet shipments for some time. CAPCO JEN 0001700 ASHESTOS 3 CONSUL 'ION AND USES Total U.S. asbestos consumption decreas ed 12%; of the total, 97% was chrysotile and 3% was crocidolite. Small amounts of amosite were reported used. One percent of the chrysotile used was spinning grades 1, 2, or 3. Grade 7's were the most used, 76%, followed by grades 4 and G, 8% each, and grade 5's, 7%. Table 4.--U.S. asbestos consumption by end use, grade, and type (Thousand metric tone) End use 1982 total. ________ 1983. Asbestos-cement pipe. _ Asbestos cement sheet Cowlings and compuutids _____________ Flooring products_____ Friction products - . . _ Insulation Thermal_______ Electrical________ Packing and gaskets _ . Paper . . _____ Plastic. . . . . _____ Proofing products_____ Other ___ ___ _ Total Grades Grade 1 and 2 J Chrysotile Grade Grade Grade 4 56 Grade 7 23 18 4 150 18.8 1753 4 6 .9 2 .9 7 22 22 ft 44 6 .9 7.3 2 33 9 _ __ _ _ _ .. _ _ 6 4 .5 7 108 .1 _ _ 1 4 0.2 .2 2 28 37 11 1 1 3 1 39 1 1 17.0 13 0 17.4 159 3 Total 229 8 19.9 100 22 8 446 48.3 .6 12.4 1.5 C 6.5 13 41 7 210 2 Crocidolite 160 62 , __ __ _. _. 62 Amosite Total asbes tos 0.7 246 5 26.1 10.0 22 8 44.6 48 3 .1 1 6 124 15 6 6.5 5 42 2 G 2170 PRICES Depressed markets and high producer inventories of the last few years have caus ed final negotiated asbestos prices to be lower than listed prices A realistic set of unit values can be calculated using import data. These averaged data represented most of the domestic market. The unit value of exported asbestos, $360 per metric ton, represented a 7% increase. Table 5.--Customs unit values of imported asbestos (Dollars per metric ton) 1979 19S0 1981 Canada Chrysotile. Cement___ ... Crude __________ Spinning-------- Other___ _____ South Africa, Republic of: Amoaile .....___ Crocidolite___ _____ 238 251 201 158 K63 843 232 296 499 1.611 711 686 272 927 373 728 676 1982 234 380 917 334 771 646 1983 257 195 932 384 84( 621 FOREIGN TRADE There was a 1% increase in the total value of asbestos fibers and asbestos prod ucts exported from the United States; of this, the Tiber portion remained at 13%. Canada remained the largest recipient of U.S. exports, accounting for 51% of th< value, followed by Japan, 8%; Saudi Arabia 7%; and Mexico, 6%. Canada provided 94% of the asbesto fiber imported into the United States, an- CAPCO JEN 0001701 1 MINERALS YEARBOOK, 10H.1 the Republic of South Africa provided 6%. Several countries provided minor amounts. Chrysolite again dominated the imported types with 117% of the total. The value of imported fiber was only 89% of that of 1982. Table 6.--Countries importing U.S. asbestos fibers and products (Thousand dollars) Country Australia__________ ________ _______ - - - ( '.luuJu ... . ---------- < icrin.tn.v, Federal Republic of- .1 i|i.m . ------------------ K>*rea. Republic* of__________ - Kuwait . ---------------------- M. vko _______ _________ Saudi Arabia .. - - ------------- 'I h.uland . .................... Turkr> _. - --------------------- Uiiii.il Kingdom Wne'ueU ...................... Other Unmanu factured fibers 145 24 2 1,144 9K0 3,933 730 17 1.193 178 r5,6l5 19,5-13 IS8J Manu factured products 5.034 387 43,714 2.417 f.,475 2,367 1.114 9.837 15.291 325 334 2.781 5,747 r30,920 120.7 U4 .Toul* 5.179 C09 44.858 3.397 10.408 3.098 1,114 14.739 15,308 1.524 334 2,939 G.GOO *36,735 140.24? Unmanu factured fibers 19 221 1.539 965 3.787 550 4.649 13 2.599 497 204 329 4.005 19-1`W 1U83 Manu factured products 2.107 1.432 73.739 2.367 8.036 781 1,380 3.565 10,339 189 913 2.11() 1.773 19.846 128,584 'U.itu may nul add to totals shown because of independent rounding Total1 2.126 1.653 75.278 3.352 11.823 1.331 1,380 8,214 10,352 2,788 1,410 2,320 2.102 23.851 147,981 Tabic 7.--U.S. exports and reexports of asbestos and asbestos products Products 1981 Quan tity Value (thou sands) 1952 Quan tity Value 'thou sands! 1953 Quan tity Value (thou sands) EXPORTS JnnianufaCturcd Crudes, fibers, stucco . -_______ - - metric tons 50.13! $17,328 13.995 4,021 64.12b 21.319 42.342 16.183 58.525 $14,752 4.791 19.543 40.476 13,760 54.236 $14,679 4,519 19,398 ______ do Caskets............................................. - . - do___ - . _. .do. . _ CluUh facings and linings_____ _ - . _ number. _ Total ................-..................................... REEXPORTS Uimi.mul'.tLturi-d: t 'rudi-s and fillers - -- -- .... . . metric tons. _ Sand and reluse - _ _____ ______ Tula! ----- __________ t'rud ucts Asltestos fibers - .---------- -------------- ----------- do--------- shingles and clapboard__________ _do--------------------- Caskets ______ ____________ _______ ____ do--------- Packing and seals _______ ______ ____ ____ -do--------- Insulation -- ----------------------------------- do-- -- Other articles, nspf-------- ----------------------- do--------- (trake linings' und disk brake pads _ --------do. - - _ Clutch facings and linings- --------------- number. . Other artn. !c of usbealos- metric tons. - Toul NA N1 available XX Not applicable `la-w than 1/2 unit. 3.840 21,771 17,504 451 1,598 NA NA NA NA XX 9.544 3.686 14.292 4.144 16.179 6,185 23,660 50.058 12.7 63 144,531 2.538 4.011 17,639 358 1.311 NA NA NA NA XX 8.119 3.235 13,444 3.020 15.309 6.799 17.047 42.852 16.879 120,704 1.537 3.082 4.953 337 1,015 NA NA NA NA XX 5.193 1.935 5,593 2.196 10,174 3.270 9.477 70,456 128,554 240 150 246 53 9 XX 293 259 246 no 333 XX 65 170 398 6 34 66 34 20 _ _ 17 125 NA 17 NA 120 NA NA 149 NA NA 234 NA 1 16 27 203 3 1 (') 22 l NA 9 NA 539 NA 309 NA 80 59 XX 599 XX 1,163 XX 2i I 14 265 7 117 10 10 166 316 167 203 998 CAPCO JEN 0001702 AHIIICSTOH r Table S,--IJ.S. imports for consumption of asbestos fibers by type, origin, and value T>| JUKI ...........................- . 1082 Chrysotile. Crude . . Spuming fibers All other_____ Crocidolite iblue) . _ Amosite .... . . Total _ . _ i`J83 Chrysoule Crude ............... Spinning fibers All other _ Crocidulite ibluel _ _ Amosile _______ Tuldl - Canada Quantity (metric lOIIS.1 Value (thou sands) 318.367 $!IU,82*< South Africa, Republic of Quantity (metric tons) Value (thou sands! 17.112 $10,846 Otheir Quantity (metric tons) Value (thou sands) 2.139 $2,219 Total Quantity (metric tons) Value (thou sands) 337,618 $103,893 1.32s 227,71.5 229,079 14 1.218 55,482 56.714 1KI4 2.193 7.904 389 11.390 453 1.34] 5,105 300 7.199 8 202 1.058 1,268 1 283 728 1,012 44 2.434 230,906 7,904 389 241.737 15 1.954 57,551 5,105 300 64.925 4 1 313 220 89 138 406 359 1.840 1,711 190 123 nil 225 2,191 2.062 182,459 48,018 4,465 2,398 80 120 187,004 51,136 G.J77 3,887 _ _ 6.177 3,887 . 609 512 609 512 184,30.1 49.733 11.754 7.740 330 483 196,387 57,956 WORLD REVIEW The market economy countries' asbestos industries suffered the same state of over* supply, reduced demand, mine layoffs, and general economic problems that character ised lbSZ. Increased demand m the last quarter did little more than reduce some of the high fiber inventories. Canada.--Manville concluded the sale of the Jeffrey Mine at Asbestos in September. The purchasers included a number of for mer Manville executives headed by the president of their former auditing firm. J. M Asbestos Inc., the new owner, promised to continue production of fine chrysotilc fibers and provide technical services. Preliminary figures were cited that show ed a continued downturn of Quebec's liber production.1 The volume, estimated at 717,000 tons, was 4% below that for 1082, but the value, Can$Jlb million, increased <1%. According to a published report, Asbestos Corp. planned to close its Asbestos Hill Mine for 1 year.4 Inventory shortfalls caus ed by the closing were to be made up by increased production from its Thetford Mine. A closure of Asbestos Hill might cause a temporary shutdown of Asbestos Corp.'s mill in Nordenham, Federal Repub lic of Germany, which currently processes the concentrated ore. Italy.--A mining periodical described the current operation of the Amiantifera Balangero S.p.A. Balangero Mine.1 Asbestos was mined from a face 170 meters high by 700 meters long. The mine's annual capaci ty was rated at 3.1 million tons of ore yielding 150,000 tons of fiber. It was one of the few asbestos mines in the world wdth a salable byproduct. Nearly one-half million tons per year of high-quality crushed stone and sand have been sold from the Balangero Mine. South Africa, Republic of.--A mining periodical detailed workings of a mine and mill that produced roughly one-half of the world's crocidolite in 1982.* The under ground Pomfret Mine of the Griqualand Exploration and Finance Co. Ltd. was con sidered to be the premier crocidolite mine of the world. Ore selection at the face of grades not less than G% was used to main tain an average ore grade of 12% to the mil). Except for a wash cycle to recover fibers, the mill process was dry. Pomfret's 2,400 employees live in the town of Pomfret, which is owned by the company. Zimbabwe.--A weekly mining periodical painted a bleak picture for the country's asbestos industry.* Extrapolation of halfyear production figures showed a 27% pro duction decline from that of 1982, and a 5G% production decline from that of 1976, its record year. 9 CAPCO JEN 0001703 (i MINtiUALS YUAKUOOK, 1JH3 Table 9.--Asbestos: World production, by country1 (Metric tone) Country* Afghanistan. Auilialid Brazil....................................... ............................. Bulgaria.............................................................. Canada (shipments) _______________________ Greece ____________ _______ _______________ Kiwua, Republic of____-_______ _________ Mozambique__ ___ :>ju()i Africa. Republic of_____________ Swaziland (export*!________ _________ ______ Taman.................................................................. Turkey________ _______________________ ~ _ USSR*............. ............................................. United States (sold or used by producers)------ Zimbabwe _________._____________________ Tulal . . _ . ................................................ 19\p 1980 1981 *4^0 ( .. 1.3TV 1.261/ 1,280 79.72l\ 92,41 44.647 138,457 \ 169,173 138,420 600 \ 700 400 1.492,719 \ 1,323,053 1,122,000 '140,000 \. '131.700 106,000 35,472 238 \ 24.535 \ / 316 24.440 325 32.094 143.931 3,502 14,804 789 249.187 34,294 2,95? r60O 2,020,000 92,354 10.041 #9.891 A 31.253 / 157.794 ,/ \ 3,897 / \9.854 / \*800 271734 32*833 683 rL8.l62 2,010,duo 80,0(9 12.106 250,94)? '/.7SS.022 '4,699,30<) 24.515 137,086 3,950 14.084 800 235,943 35,264 2,317 3,860 2.105,000 75,618 13,591 247.600 4,337,140 1982P NA 1.218 ' "20,000 *140,000 600 834.000 110,000 18,952 310 *100.000 26,761 116,410 4.135 15,933 *800 211,860 26.413 2,392 958 2,180,000 63,515 11.657 194,400 4.080.314 1983* NA 1,350 20.000 135,000 600 829.000 110,000 18,000 325 100,000 25,000 120,000 4.000 15.000 800 220,000 *31.275 2,500 4.000 2,250.000 '69,906 10,500 190,000 4,157,256 'Estimated ''Preliminary. 'Revised. NA Not available / 'Table include* data available through Apr 18,1984. *In addition 10 the countries listed. Czechoslovakia, North Korea, and Romania also produced asbestos, but output is i >oi ot i'k- tally reported, and available general information is inadequate for the formulation of reliable estimates of output levels `Reported figure TECHNOLOGY The U.S. Navy tested shipboard trans formers, with and without asbestos, to dem onstrate the superior properties of asbestos electrical insulating papers and boards.1 Among the tests conducted was one to establish failure temperature under various overloads. The transformer containing as bestos surpassed all others by nearly 300* F. Asbestos emission tests demonstrated that little, if any, asbestos fiber was emitted from any of the transformers under actual operating conditions and that the tremen dous overload resistance of the asbestos insulating system permits transformers on board U.S. Navy warships to operate under the most severe combat conditions. A neoprene spray process was developed for coating asbestos fibers to prevent their escape from construction components used in building interiors.1 The process is design ed to both penetrate and surface coat the asbestos and eventually cure the coating to form a tough elastic cocoon. Use of the process was claimed to eliminate or greatly reduce the very high fiber counts generated during the disassembly of buildings. Substitutes.--A glass industry publica tion describes a new alkali-resistant glass fiber.10 The Japanese National Institute for Research in Inorganic Chemicals applied fnr .lananow r.*^ ITS nnlents on its elass fiber produced by England's Pilkington Bros. The process mixture for the glass consists of 25% each of silica and alumina and 50% of an intermediate material used in producing yttrium. Two organic fibers were identified as having comparable properties to asbestos in certain uses. These were an acrylic fiber presented by the Badische Corp." and a polyvinyl alcohol fiber developed by Eter- nits, the Swiss asbestos cement manufactur er, and the Osaka-based Kuraray Co., as an asbestos substitute in cement products.10 `Physical sciential, Division of Industrial Minerals 'Higgins. I T. T.. J H Classman. M S Oh. and R F Cornell "Mortality of Reserve Mining Company Employees m Relation loTacomte Dust Exposure. Am J. Epioemio!, v 118. No. 5, May 1983. pp 710-719 *Remick. J., and M Trottier General Outlook. West. Miner, v. 57, No 2, Feb. 1984, p 31. 'Industrial Minerals (London) Canada. Asbestos Hill Closed. No 195, Dec 1983. p. 9 'Mining Magazine Balangero---Europe's Most Impor tant Asbestos Producer V. 149. No 6, Dec. 1983, p 427. *-------. Pomfret Asbestos Mine. V. 149. No 3, Sept. 1983, pp. 153-159. 'Mining Journal (London). A Mixed Bag for Zimbabwe. V. 301. No 7740. Dec. 23. 1983. p. 4SJ. *Love, D, J. Fitch, and C Y. Lu. Performance of Asbestos Insulation Systems in Dry Type Transformers. Electn-Onict, v. 29, No. 7, July 1983, pp 67-70. Pitilto, J. Neoprene Spray Is Answer to Knotty Asbes tos Problem Chem. Mark. Rep., v. 223. No. 18. May 2,1983, pp 15-16. l0Glass Industry. Japanese Lab Develops AlkaliResistant Glass. V. 65, No. 1, Jan. 1983, p 13. "Chemical Marketing Reporter. Acrylics Aim at Asbes tos V 224. No. 23. June 13,1983, pp. 7,34. CAPCO JEN 0001704