Document RjQzaNGM7YBk3pbp92nRQ7wgV

Matierial Safety D a t -t Pfizer Inc. 235 East 42nd Street New York, NY 10017 Product: COATED LIMESTONE MSDS Nd: MIHERAL / MIN011 Revisions 01 Dates June, 1988 National Paint and Coatings Association Hazardous Material Identification System HEALTH HAZARD FLAfTIABILITY HAZARD REACTIVITY HAZARD PERSONAL PROTECTION 1 - Slight 0 - Minimal 0 - Minimal E - Glasses. Gloves, Dust Resp SECTION I. MATERIAL IDENTIFICATION Trade/Material Name: COATED LIMESTONE Description: Coated Limestone Other Designations: Hi-Pflex 100, Pfinyl 402, Pfinyl 402AX, Super--Fil CAS: 1317-65-3 Chemical Nane: CaCOs Manufacturer: Pfizer Inc. 235 East 42nd Street New York, NY 10017 Phones (413) 743-0591 Mon-Fri 7:30 AM - 4:30 PM (413) 743-0598 Weekends, Holidays and 4:30PM - 7:30 AM SECTION II. INGREDIENTS AND HAZARDS Ingredient Name: CAS Number: Ftrcent: Exposure Limits: Limestone Stearic Acid 1317-65-3 0057-11-4 ACGIH TLV: 10 mg/M3, Total IXist OSm PEL: 5 mg/M3, Respirable ACGIH TLV: 10 mg/M3, Total Dust OSHA PEL: 5 mg/M3, Respirable There are extremely small, but detectable amounts of substances regulated under California's Safe Drinking Water and Toxic Enforcement Act (Proposition 65). Arsenic - less than 2 ppm Cadmium - less than 2 ppm Chromium (VI) - less than 0.1 ppm Lead - less than 4 ppm These levels are "typical" quantities and may change slightly with different lots. The term "less than" indicates that the substance was detected, but the amount was less than the quantifiable limit. Limestone contains crystalline silica at levels above 0.17. but less than 17.. These levels are "typical" and may change slightly with different lots. Page 1 ------ l"H)S MIN011 ctntinues cn page 2 ------ Page 1 0860-^ 00 T At. Material Safety Data Sheet Pfizer Inc. 235 East 42nd Street New York, NY 10017 Prodi^t: COATED LIMESTONE >QE Nto: MINERAL / MIN011 Revision x 01 Date: June, 1908 SECTION III. PHYSICAL DATA Appearance & Odor: White powder, no odor Water solubility (X): Insoluble Specific gravity 2.6-2.8 SECTION IV. FIRE AND EXPLOSION DATA Flash Point (method): Non-flammable Limits: * Fl X: <n X: Extinguishing Media: Non-flammable. As appropriate for surrounding combustibles. Unusual fire or explosion hazards: None Special fire-fighting procedures: None SECTION V. REACTIVITY DATA Material is stable Hazardous polymerization will not occur Chemical incompatibilities: Reacts with acid to liberate carbon dioxide gas. Conditions to avoid: None known Hazardous decomposition Products: None SECTION VI. HEALTH HAZARD INFORMATION This product is not considered a carcinogen bv IARC. NTP. OSHA or ACGIH. Sjmmary of risks: Calcium Carbonate is a "Nuisance Particulate". They "have a long history of little adverse effect on lungs and do not produce significant organic disease or toxic effect when exposures are kept under reasonable control" (ACGIH TLV definition). May cause eye and skin irritation from abrasion. Primary entry route(s): Inhalation and ingestion. Acute effects: Abrassiveness may cause eye and skin irritation. Chronic effect(s): No known chronic health effects. First aid: Eye contact: Flush eyes with plenty of water for at least 15 minutes. If irritation persists, seek medical attention. Skin contact: Wash from skin with mild soap and water. Inhalation: Remove from the exposure area. Ingestim: Ingestion should not cause any significant health problems. If a large amount is ingested and if conscious, give large quantities of water to induce vomiting. Get medical attention. Limestone is not listed as a carcinogen by IARC, NTP, OSHA, or ACGIH. Crystalline silica which may be present in quantities less than IX has been reviewed by IARC. Page 2 ------ HEALTH HAZARD INFER1ATICN continues cn page 3 ------ Page 2 DO 086035 CONFIDENTIAL Material Safety Data Sheet Pfizer Inc. 235 East 42nd Street New York, NY 10017 Products COATED LIMESTONE MSCS No* MINERAL / MINOii Revision: 01 ____ Date* June, 1908 IARC found limited evidence for carcinogenicity of crystalline silica in humans and sufficient evidence in experimental animals. SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES Spill / Leak procedures: Those involved in clean-up of spills should use respiratory protection for airborne dust. Vacuum or scoop up spilled material for recovery or disposal, avoiding dusting conditions and using good ventilation. Wetting the spill with a water spray may help to keep the airborne dust levels down. Waste management / Disposal: Calcium Carbonate is not considered to be a RCRA hazardous waste and may be disposed in a site suitable for industrial wastes. Refer to any local, State or Federal regulations for specific disposal information. For transportation emergencies, call OEMTREC, 24 hour information service, 1-800-4249300. SECTION VIII. SPECIAL PROTECTION INFORMATION Personal protective equipment: Goggles: Safety glasses or dust-tight goggles. Gloves: Leather or rubber gloves. Respirator: If exposure limits are exceeded, a NI0SH approved dust respirator should be used. Workplace ccnsiderations: Ventilation: Provide adequate exhaust ventilation to meet TLV requirements. exhaust filter system may be required to avoid environmental contamination. An Safety stations: An eyewash station should be available to the area of use. SECTION IX. SPECIAL PRECAUTIONS Other precautions: Good industrial hygiene practice requires that employee exposure be maintained below the recommended TLV. This is preferably achieved through the provision of adequate ventilation where necessary. Where dust cannot be controlled in this way, personal respiratory protection should be employed. DOT Class: Not regulated. Prepared/revised by: M. G. Larson June, 1908 The data and recommendations presented herein are based upon a review of Pfizer files, published MSDS's, and standard toxicological reference sources. Pfizer Inc. makes no guarantee or warranty, either express or implied as to the accuracy or completeness of these data and recommendations. Page 3 ------ End of MSDS MINOII ------ Page 3 DO 086036 tdenttal OGNF NOTE: This MSDS win cover all but the following Harwlck clays: 14 Clay. -4-^rLrijv- IJiO. JlftLay , j^rf^i-LKt-cLtxx. JUNE 1986 Form Approved OMO No. 44*11 J3B7 MANUFACTURER'S NAME HARWICK CHEMICAL CORPORATION SECTION 1 EMERGENCY TELEPHONE NO. (216) 798-9300 ADDRESS (Number,SireeuCity, Stale, and ZIP Code) T60 South Seiberlinq Street - Akron, Ohio 44305 CHEMICAL NAME AND SVNONVMS MuHrmic rn 1 trade Wame And svnonyms Aluminum Silicate CAS #'s: 5?Mi,.,V332-58-7 ___Harwick Clavs-Hvdrnm A Anhvdrmj? (Cal CHEMICAL FAMILY .........* FORMULA w Aluminum Silicate________________ Hydrous: Al90i*2Si0o*2Ho0: Anhydrous: cined SECTION It * HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, & SOLVENTS PIGMENTS * TLV (Unitsl ALLOYS AND METALLIC COATINGS BASE METAL CATALYST N/A ALLOYS ty/A VEHICLE SOLVENTS ADDITIVES N/A N/A N/A METALLIC COA'INGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS N../.A. OTHERS HAZARDOUS MIXTURES OF OTHER LIOUIDS, SOLIDS. OR GASES % TLV (Unitsl TLV % (Unitt) N/A SECTION III - PHYSICAL DATA BOILING POINT (F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR-1) N/A N/A N/A SPECIFIC GRAVITY (H^O-l) PERCENT. VOLATILE BY VOLUME {%) EVAPORATION RATE ( -1) SOLUBILITY IN WATER Insoluble appearance and odor White, odorless powder. SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method UKO) Non-Flammable EXTINGUISHING MEDIA N/A SPECIAL FIRE FIGHTING PROCEDURES None ________________ FLAMMABLE LIMITS None____________ L.l 2.5 N/A N/A O.l UNU5UAL FIRE AND EXPLOSION HAZARDS --None------------------------------------------- ,,*N/A = Not Applicable PAGE (w .. . J .. . (Continued on reverse side) DO 086037 ---------------------- CONFTDFNTTAL Form OSHA-20 Rev, M.y It SECTION V HEALTH HAZARD DATA THRESHOLD LIMIT VALUE . . . ... /- , 3 . . , Kaolin is classified as a nuisance dust by ACGIH (5mg/nr respirable dust). crrecTSOF overexposure Primary Route of Exposure: Inhalation. Acute: None expected. Chronic: None ) expected. Prolonged and continuous exposure of any dust may have a pulmona ry effe:t,on some peiple. EMERGENCY AND FIRST AID PROCEDURES None. Call a physician if questions arise. __________________ ___________ STABILITY UNSTABLE SECTION VI . REACTIVITY DATA COj^j^TONS TO AVOID STABLE XX INCOMPAI ABILITY (Materials to avoid) None HAZARDOUS DECOMPOSITION PRODUCTS ____m_________ HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR . ... ... CONDITIONS TO AVOID XX_ ............................. N/A SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Vacuum or sweep for reclamation or disposal. WASTE DISPOSAL METHOD Raw (unused) material may be disposed of in a samtory landfill. Follow all regulations; Federal, State and Local.___________________________________________ SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) N10SH approved dust respirator. VENTILATION LOCAL exhaust _To ma.in.ta.in TLV special None MECHANICAL (Gcner OTHER None PROTECTIVE GLOVES Nnnp OTHER PROTECTIVE EQUIPMENT None ... EVE PROTECTION Recommended - but not required. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Minimize dust generation._________________________________ OTHER PRECAUTIONS None. DOT - Hazard Class-None; STCC Code 32-952-31; Shipping Name - Kaolin Ground. PAGE (?' 0P0 BM.y.o Form OSHA-20 Rv. Miy 72