Document R22YgaxgrjqmN7dnQ556aGd2a
COMPANY CONFIDENTIAL
PLAINTIFF'S EXHIBIT
I.
CORPORATE POLICY AND PROCEDURES FOR
A. POLICY
MATERIAL SAFETY DATA SHEETS
Monsanto has adopted a uniform approach for developing safety and health information on its products for those vho transport, handle, use or consume them. To this end, a Material Safety Data Sheet (MSDS) will be prepared and issued for each Monsanto chemical product. Specific exceptions are fabricated products, such as tex tile fibers, electronics components, instruments, blownware, etc. The MSDS will be kept current by periodic review and adequate records will be kept of its distribution.
B. PURPOSE
The Monsanto MSDS will be used to provide specific information concerning the character and potential hazard, if any, associated with a particular chemical product. In addition to internal uses, it is expected that this information will be used by third parties in developing practices and procedures designed to help protect the health and safety of workers, the public and the environment. The Monsanto MSDS is designed to satisfy the requirements of the U.S. Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200). The Monsanto MSDS will also be used as the basis for compliance with U.S. state requirements and requirements in other parts of the world where Monsanto does business.
* C. SCOPE
An MSDS shall be prepared for each chemical product manufactured or imported by Monsanto and for any other material designated by the Director, Environmental Operations of the Operating Company or the Vice-President, Environmental Policy Staff. An MSDS will also be prepared for isolated intermediates to comply with the OSHA Standard. For purposes of this Guideline, an intermediate includes any chemical substance (1) which is intentionally removed from the equipment in which it is manufactured and (2) which either is consumed in whole or in part in chemical reaction(s) used for the intentional manufacture of other chemical substances(s) or mixture(s).
D. RESPONSIBILITIES
1. Each Operating Company has basic responsibility for the devel opment and distribution of MSDS for its products and materials, for their periodic revision and updating, and for keeping appropriate records.
2. Operating Company and Corporate Staff Departments (Department of Medicine and Environmental Health (DMEH), Corporate (CDD) and Operating Company Distribution Departments, Safety and Property Protection (S & PP), Patent Department, etc.) are responsible for providing appropriate information for incorporation into MSDS.
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D. RESPONSIBILITIES - Continued
Specifically:
The Operating Company has the responsibility for developing the following when an MSDS is initiated: Monsanto Product Name, Product Identification (including component composi tion for formulations or mixtures, residual monomers in polymers and significant impurities or breakdown products)* Fire Protection Information, Physical Data, Reactivity Data, Spill, Leak and Disposal Information, and obtaining a current product label. The Operating Company patent departments will advise on identification of trade secrets.
The Labeling Section of CDD or the Operating Company label group have responsibility for working with the Operating Company DEO group to develop adequate label text.
The Toxicology Projects group of DMEH has responsibility for developing the Health Effects Summary and for coordinating review of an MSDS within DMEH.
The Industrial Hygiene Section of DMEH has responsibility for developing the Occupational Control Procedures in consultation with the Operating Company.
The Information Center of DMEH has the responsibility for entering all final MSDSs (and revisions) into the MEHI-MSDS computer system for permanent storage and ready retrieval.
3. Corporate Staff Departments will review and approve appropriate sec tions of the MSDS. Operating Company Directors of Environmental Operations and Operating Company Law and Patent staff will review and approve each finalized MSDS prior to distribution.
Specifically:
The Product Toxicology Section of DMEH will review and approve the toxicology information included and discussed in the Health Effects Summary.
The Occupational Medicine Section of DMEH will review and approve the Health Effects Summary and Emergency and First Aid information.
The Toxicology Projects Group of DMEH will review the finalized Occupational Controls, Health Effects and Emergency and First Aid sections.
The information is necessary for development of MSDS and may be required for state or federal requirements. The information may be omitted on MSDS in accord with confidentiality and/or trade secret requirements as outlined in Section I.F and Section III.
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S & PP will reyiew and comment on the Fire Protection informa tion and the Precautionary Measures.
CDD and Operating Company Labeling Sections will review and comment on the Warning Statements, Precautionary Measures, and Emergency and First Aid Procedures.
The Regulatory Compliance Section of CDD or the Transporta tion Group of the Operating Company will review DOT procedures.
The Operating Company Patent Department will review identifi cation of trade secrets and the Corporate Patent Department will review trademark usage.
4. The Director, Regulatory Management - Toxic Substances (DRM-TS) will serve as a Corporate focal point on MSDS policy.
5. The DEO Europe/Africa will serve as the focal point for Monsanto Europe/Africa MSDS activity.
Note: With the exception of the policy statement on page 1, other portions of this guideline apply primarily to domestic MSDS activity. A separate guideline for Monsanto E/A is available. Other world areas will be coordinated by the assigned Operating Company DEO and the DRM-TS.
E. FORM
The format of the Monsanto MSDS will be uniform throughout the Cor poration for chemical products and will be prepared using the format (Format G-4048 shown in Figure 2 or ex-US equivalent).
F. CONTENT
Each MSDS will contain information on a product as set forth in Section II. The OSHA Hazards Communication Standard sets forth certain content requirements for Material Safety Data Sheets in paragraph 1910.1200 (g). These requirements are detailed in Section III of this guideline. These requirements apply only to materials determined to be hazardous chemicals under the OSHA Standard. See Section IIC and III for details. The OSHA requirements are integrated into the Monsanto G-4048 format and are referenced in Section II of this guideline. No sections other than Warning Statements (See Section II.B) and/or Additional Comments can be deleted from the G-4048 forma.t. If no information is available for an OSHA requirement, a statement referencing the specific OSHA requirement(s) for that section will be made indicating that; "No applicable information was found."
Confidential or trade secret information, such as the percentage of components in a proprietary mixture, should not be included on the final MSDS. Use trademark or generic terms which do not disclose the confidential subject matter.
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If specific chemical identity of substances or mixture components determined to be a hazardous chemical under OSHA criteria are claimed trade secret, the following statement will be listed for each component so claimed. "The specific chemical identity is withheld because it is trade secret information of Monsanto Company. " If it is necessary for commercial or other reasons to distribute information outside the Company which is considered to be confidential, suitable arrangements (e.g., secrecy agreement) must first be made.
G. REVISIONS AND DISTRIBUTION
1. The MSDS will be modified when the Company becomes newly aware of significant information regarding the hazards of the product or ways to protect against the hazard. The OSHA Standard requires that significant new information will be incorporated into a MSDS for hazardous chemicals within three months.
2. MSDS will be developed for all new products prior to manufacture for commercial purposes. The OSHA Standard requires that R&D samples provided to customers must be accompanied by a MSDS.
3. New or revised MSDS will be distributed to all customers on record for two years prior to the date of the original MSDS or latest revision, to all Monsanto operations that manufacture, process or distribute the chemical, and to carriers, warehouses and terminals arranged by Monsanto for the product involved. The Operating Company may elect tt> send Material Safety Data Sheets to any other person deemed appropriate. These require ments are consistent with the OSHA Standard. The OSHA Standard requires in addition that revised MSDS for covered products either be provided with the first shipment to customers after the revision or sent to the customer on or before the first shipment after revision.
H. PROCEDURE
1. Development of MSDS on the new G-4048 format or revisions of MSDS will be initiated by the Operating Company DEO or designee.
2. The development of the MSDS will follow the flow scheme as shown on Figure 1. The development will be on a subject-by-subject basis and will build on one another, where necessary. A subject section will be completed for each subject unless specifically omitted as outlined under Section F above and Section II.B. Each subject in a given box on Figure 1 must be completed prior to forwarding to the next step.
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3. MSDS will be processed through corporate Staff Departments on a first come, first served basis. The Toxicology Projects Group of DMEH will track the progress of each new or revised MSDS during DMEH review. At periodic intervals, Toxicology Projects of DMEH will issue a report to the DEOs, the DRM-TS and the Director of DMEH showing the status of all MSDS requests. Should a DEO desire a higher priority for his product(s), he may request the DRM-TS to call a meeting of all the Directors of Environmental Operations to review and re assign priorities for products in the current status report.
4. The staff groups of DMEH will add any label text changes they recommend. Any deviation from the label text offered by the Operating Companies and DMEH will be reviewed by CDD or the appropriate Operating Company labeling groups. Any deviations will be resolved by agreement between the Operating Company and the appropriate labeling groups.
5. Any desired wording changes or desired information deletions to the draft MSDS will be made by the OperatingCompany and reviewed by the Staff Section responsible. If differ ences cannot be resolved, the DEO is authorizedto proceed, but, in conjunction with Operating Company legal staff, should document the reasons for the changes or deletions. If the review proves that label changes are required, this will be done prior to MSDS distribution.
6. The final MSDS will be reviewed and approved by the Operating Company Law and Patent Departments. Required changes or deletions will be handled as outlined in 5. above.
7. The final approved MSDS will be distributed in a timely fashion by the Operating Company to the DMEH Information Center (DMEH library), Industrial Hygiene, Occupational Medicine, and Toxicology Projects Group of DMEH, to S & PP, the appropriate Labeling Section, the Emergency Response section of CDD, MERIT coordinators, and the DEO Europe/Africa for the record.
I. RECORDKEEPING
Each Operating Company will assure the following records are kept indefinitely.
1. Copies of each revision of a MSDS.
2. Name and address of ea Ii recipient of a Monsanto MSDS or revision of a MSDS, and the dates of distribution. A computer system is available for this purpose. Consult with the DRM-TS for details.
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Figure 1
MATERIAL SAFETY DATA SHEET DEVELOPMENT FLOW CHART
Operating Company Law Patent Dept.
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II
GUIDELINES FOR PREPARATION OF THE
MONSANTO MATERIAL SAFETY DATA SHEET
A. PURPOSE
The purpose of the Monsanto MSDS guidelines is to establish a uniform format to ensure that data are provided in a consistent, well-organized manner. The guidelines also offer consistent definitions and interpretations.
The format contains 12 major subject areas (headings) which represent the type of information to be contained in a Monsanto MSDS. Specific guidelines and instructions are provided in the following section for preparation of the Monsanto MSDS to ensure consistency and quality of the health and safety information provided. The design of the Monsanto MSDS is formulated to allow maximum flexibility for the wide variety of chemical products manufactured by the several Operating Companies and business units, yet retain a uniform appearance and content. The length of the Monsanto MSDS (Format G-4048) will vary with each specific substance and the quantity of information in each section. In general, the MSDS will vary between three and five pages.
As a matter of general policy, requests for MSDS information on customer-supplied forms should be honored only on an exception basis as determined by the Operating Company Director of Environmental Operations(DEO) or his delegate.
The final OSHA Hazard Communication Standard issued on November 25, 1983. The MSDS guidelines are designed to integrate the requirements of this Standard into the Monsanto MSDS program.
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B. GENERAL
All domestic Monsanto MSDS must be prepared using the recommended form and format. This standard format will ensure consistency in organization, content and identification of a Material Safety Data Sheet from Monsanto Company.
Different formats and contents may be required in ex-U.S. locations.
Page 1 of '.he Monsanto MSDS is designed to provide all necessary product identification and emergency information "up front" at the beginning of the MSDS. These are:
* Product identification * Emergency phone number * Warning statements * Precautionary measures * Emergency and first-aid procedures
(Other sections can be included on the first page if room is available)
Warning statements, precautionary measures and emergency and first-aid procedures should be consistent with information contained elsewhere in the MSDS. The language used should reflect that the primary audience for these sections is the worker. All information on page 1 must be consistent with, and in most cases identical to, product label information. In most cases the principal source of the language used in these sections will be the label text. The sections on Precautionary Measures, Warning Statements and Emergency and First Aid should be eliminated if the Monsanto product label has no warning statement, and based on the information in the MSDS, no label warning statement is needed. These sections should be replaced with a combined Precautionary Measures and First Aid Statements section. Do not leave any other major section heading blank. The following statement should be used in a combined Precautionary Measures and First Aid Section: "Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skir., and clothing."
The product name should appear at the top or side of each page.
For clarity, use of symbols or abbreviations is not generally recommended. (Obvious exceptions include units for physical properties, etc.)
For each subject area (heading) in the Monsanto MSDS form, recommendations and/or examples are provided in the Section IID depicting the type of information to be included if available and appropriate.
Any other health and safety information deemed appropriate to a particular section should be included.
If information for a particular section is available but the operating unit preparing the information elects to omit the information, this exception should be documented in conjunction with the Operating Company law staff and approved by the appropriate DEO or his delegate. Note. "o
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information required by the OSHA Standard may be omitted, except limited information which may be withheld as a trade secret (See Section III.)
The Monsanto Label Guidelines 0 2601/53 (Appendix A of Section IID) should be used to assist in the development of label warnings.
Exceptions will occur when mandated by law (e.g., pesticide labeling, drug labeling, etc.) and when deemed to be necessary and appropriate. These exceptions will be documented, reviewed by operating company law staff, and approved by the appropriate DEO or his delegate unless they are mandated by law.
Exceptions as described above are not to be noted on the Monsanto MSDS form but should be documented separately in the files.
A major objective of reviewing and revising all Monsanto Material Safety Data sheets is to assure correctness and consistency of all published product health and safety information. After review and revision of a product Material Safety Data Sheet, which will include a review of label text and Safety, Health and Toxicity Information, the appropriate business group, in conjunction with the operating company law and patent staffs, should review all product literature for correctness and consistency and revise as necessary.
OSHA COMPLIANCE
The OSHA Hazards Communication Standard requires the development and dissemination of MSDS for certain materials. Some Monsanto products and workplace materials do not fall under the OSHA requirements and criteria for these exemptions are detailed in the Standard. Single component systems and mixtures are handled differently under the OSHA Standard. A decision tree is provided on Figure 3 to facilitate the application of OSHA requirements to Monsanto products. The decision tree should be used in conjunction with Monsanto's Hazard Evaluation Procedure (page 18 of this Section), Monsanto interpretations of the OSHA Standard specified in Section IID, OSHA Hazard Communication Standard - Monsanto Compliance Manual (March 1, 1984, T. F. Evans, author) and the OSHA Standard itself (Section III).
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III. REGULATORY REQUIREMENTS FOR MATERIAL SAFETY DATA SHEETS
A. U.S. Federal OSItA Requirements
Material Safety Data Sheets are required for compliance with the Occupa tional Health and Safety Administration Hazard Communication Standard (29 CFR 1910.1200). The Standard was published on November 25, 1983 and requires chemical manufacturers and importers to determine the hazards of chemicals which they produce or import, and all employers having workplaces in the manufacturing division, Standard Industrial Classification (SIC) codes 20 through 39, to provide information to their employees concerning hazardous chemicals to which they are exposed by means of hazard communication programs including labels, Material Safety Data Sheets, training and access to written records. In addition, distributors of hazardous chemicals are required to ensure that containers they distribute are properly labeled, and that a Material Safety Data Sheet is provided to their customers in the same manufacturing division SIC codes.
By November 25, 1985, manufacturers and importers are required to provide Material Safety Data Sheets to customers and by May 25, 1986, all employees covered by the Standard are required to have access to appropriate Material Safety Data Sheets.
Importers are covered by the standards. In the final standard, importers are required to supply the same information as domestic manufacturers of a hazardous chemical.
The standard applies only to hazardous chemicals which are known to be present in the workplace and to which employees may be exposed under normal conditions of use or in a foreseeable emergency. Employers must determine and communicate the hazards of any such chemicals, but do not have to analyze complex chemical mixtures in the workplace to determine the precise composition and components. According to OSHA, the term "known" means the employer need not analyze intermediate process streams, for example, to determine the presence or quantity of trace contaminants. However, where the employer knows they are such contaminants, and they are hazardous, then they fall under the provisions of the Standard.
Laboratories in the manufacturing facilities are covered by the Standard, but they receive different treatment in terms of hazard communication requirements. Employers are to ensure that labels on incoming containers of hazardous chemicals are not removed or defaced. Any Material Safety Data Sheets received with such chemicals must be main tained and accessible to employees. Employers are also required to ensure that laboratory employees are apprised of the hazards of the chemicals they work with in accordance with the training provision of the Standard. In all other respects, laboratories in the covered SIC Codes are exempt from the provisions of the hazard communication
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standard. For example, employers need not label every container used in the laboratory with an identity and hazard warning as would otherwise be required, according to OSHA.
The standard gives a total exemption for potentially hazardous chemicals intended for personal consumption by employees while in the workplace, such as foods, drugs, cosmetics and tobacco products.
The standard also includes label exemptions for certain chemicals which are regulated by other federal agencies, and total exemptions for substances which are not expected to be hazardous for the purpose of the Standard.
Material Safety Data Sheets: The final Standard requires chemical manufacturers and importers to develop Material Safety Data Sheets for each hazardous chemical they produce or import. Employers are required to obtain or develop a Material Safety Data Sheet for each hazardous chemical used in their workplaces.
Specific requirements are included for the information to be provided on the MSDS. Such information is to be in English, and includes the identity, as well as chemical and common names, for the hazardous chemical. Special provisions apply to the listing of ingredients for hazardous chemicals which are mixtures.
For physical hazards, the employer is to list those ingredients which he or she has determined present a physical hazard. For health hazards, the employer must list each component which comprises 1% or more, and whic is itself, a health hazard.. Any chemical which is determined to be a carcinogen must be listed if it is present in quantities of 0.1% or greater. Employers must also list ingredients present in concentrations of less than one percent if there is evidence that the permissible exposure limit may be exceeded or if it could present a health hazard in those concentrations.
In addition to identity information, the employer must provide, among other things, information specified on the physical and chemical characteristics of the hazardous chemical, known acute and chronic health effects and related health information, as well as information concerning exposure limits, whether the chemical is considered to be a carcinogen by NTP, IARC, or OSHA, primary routes of entry, precautionary measures, emergency and first aid procedures, and identification of the company or party responsible for preparing or distributing the sheet.
Copies of the MSDS's for hazardous chemicals in a given work area are to be readily accessible to employees in that work area. The MSDS must be located close to workers and readily available to them during each workshift.
Trade Secrets: The regulation provides for limited trade secret disclosure to health professionals under prescribed conditions of need and confidentiality.
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The term "specific chemi-cal identity" is used to describe the trade secret information being discussed. This term refers to the chemical name, the Chemical Abstracts Services (CAS) Registry Number, or any other specific information which reveals the precise chemical designa tion. It does not include common names.
The chemical manufacturer, importer or employer is permitted to with hold the specific chemical identity from the Material Safety Data Sheet if certain conditions can be met: (1) The chemical manufacturer, importer or employer can support the claim that the information withheld is a trade secret; (2) information concerning the properties and effects of the hazardous chemical is disclosed as required on the appropriate Material Safety Data Sheet; (3) the chemical manufacturer, importer or employer indicates on the Material Safety Data Sheet that the specific chemical identity is being withheld as a trade secret; and (4) the specific chemical identity is made available to health professionals under certain specified situations. Health professionals are considered to be physicians, industrial hygienists, toxicologists, or any other person providing medical or other occupational health services to exposed employees.
In the case of a medical emergency, the chemical manufacturer, importer or employer must immediately disclose the specific chemical identity of a hazardous chemical to a treating physician or nurse when the information is needed for proper emergency or first aid treatment. As soon as circum stances permit, however, the chemical manufacturer, importer or employer, may obtain a written statement of need and a confidentiality agreement as provided in the regulation.
A copy of the OSHA Hazard Communication Standard (29 CFR 1910.1200) is included in Appendix B. Paragraph (g) details the specific requirements that must be covered by a Material Safety Data Sheet. These requirements are integrated into the Monsanto Material Safety Data Sheet format in Section IID of this Guideline.
U.S. State Requirements
Provisions of the Federal Hazard Coranunications Standard are intended to preempt competing state standards covering employees in the manufacturing sector in those states within the jurisdiction of the federal OSHA.
The 24 states with their own OSHA-approved occupational safety and health plans must adopt a comparable standard within six months of the November 25 publication date. These states are:
Alaska Arizona California Connecticut (state and local government employees only) Hawaii Indiana Iowa Kentucky Maryland
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Michigan Minnesota Nevada New Mexico North Carolina Oregon Puerto Rico Pennsylvania
South Carolina Tennessee Utah Vermont Virginia
Virgin Islands Washington Wyoming
Until such time as a state stanaard is promulgated, federal OSHA will provide interim enforcement assistance.
States other than the 24 listed above have passed and implemented worker right-to-know laws that require the use of Material Safety Data Sheets. Several of these laws and regulations extend beyond the OSHA rule. The current state laws with major impact on Monsanto include Massachusetts, and Illinois. New Jersey's law has recently been held preempted by a federal district court as it applies to employees in SIC codes 20 through 39. Compliance with state requirements is now being handled on a case-by-case basis. Detailed guidance on integration of state requirements into the Monsanto Material Safety Data Sheet system will be developed and issued after federal compliance is established.
International Requirements
Monsanto manufactures and markets products around the world. Material Safety Data Sheets are becoming a universal means of communicating safety and health information to customers, employees and others that handle or use Monsanto products. While there are only a few governments that require Material Safety Data Sheets, it is only a matter of time until these types of laws and regulations spread around the world. Monsanto is preparing for this eventuality. Monsanto Europe-Africa, Monsanto Australia Ltd., and Monsanto Canada all have active programs to develop and distribute Material Safety Data Sheets. The major problem facing Monsanto's international distribution of Material Safety Data Sheets is the monumental task of making the information available in the proper language. Monsanto Europe-Africa have developed a system to facilitate translation. The same Material Safety Data Sheet base is used for both systems, but the Europe-Africa system uses key phrases for the entire Material Safety Data Sheet development. As governments throughout the world institute Material Safety Data Sheets requirements, the translation problem will become more of an issue and the Monsanto Europe-Africa approach to Material Safety Data Sheet development will likely become a necessity in many world areas where Monsanto does business.
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WHAT MAKES A MATERIAL HAZARDOUS?
Listed on one of four "magic" lists
1) OSHA "Z" List - also known as Subpart Z of the the Toxic and Hazardous Substances portion of the Occupational Safety and Health Act
2) TLV List - from the "Chemical Substances and Physical Agents In The Work Environment" published by the American Conference of Governmental Industrial Hygienists (ACGIH)
3) National Toxicology Program (NTP) annual report on carcinogens
4) "Monographs" - a periodic publication of the International Agency for Research on Cancer (IARC)
Manufacturer declares it to be hazardous (examples at Texas City are AC'Y and LN)
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WHAT IS A PHYSICAL HAZARD?
Combustible Flammable Compressed Gas Explosive Organic Peroxide Oxidizer Pyrophoric
Unstable
Water Reactive
- Materials with flashpoint above 100 F - Mobiltherm
Materials with flashpoint below/at 100 F - Acetone
Gas cylinders
TNT, Hydrogen, Ammonia
Hydrogen Peroxide
Potassium Permanganate, Nitric Acid
Spontaneously bursts into flames - Sodium metal, Vanadium Pentoxide
Usually something that polymerizes - uninhibited styrene or AN
Anhydrous HC1
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WHAT IS A HEALTH HAZARD?
Carcinogen
- Cancer causing agent - AN, Benzene, Asbestos, Cigarettes
Toxic
- Toxic to body, usually if eaten. Almost any material at Texas City
Reproductive Toxin
- Harms fetus - stilbene. Butadiene
Irritant
- Does not do permanent damage to skin - organics
Corrosive
- Will permanently damage tissue if not removed acid and bases
Sensitizer
Produces allergic reaction phthalic anhydride
Liver Effects (Hepatotoxin)
Alcohol
Kidney Effects (Nephrotoxins)
Chlorinated Hydrocarbons
Nerve Effects
Benzene, Strychnine
Blood Effects (Hematopoietic)
Benzene, Phenol
Lung Effects
Asbestos, Coal dust
Skin Effects
Dermatitis, rashes
Membrane Effects SC 003526
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CONCEPT OF EXPOSURE LIMITS
PEL - Permissible Exposure Limits; set by OSHA on the Z List, usually an 8 hour time-weighted average
TLV - Threshold Limit Value; same concept as PEL except ACGIH, not OSHA, sets these values
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HOW TO READ A MATERIAL SAFETY DATA SHEET (MSDS)
Composition, synonyms
Physical Properties Flash Point Water Solubility (what does it do when spilled in the North Ditch?) Liquid Density (does it float?) Vapor Density (will it flashback or collect in sewers and low places?)
Fire Hazard Toxic fumes emitted? How to extinguish
Health Hazard Exposure Limits Effects/symptoms of overexposure Long term health effects First Aid Procedures
Reactivity/Incompatibles Does it polymerize? Does it release heat? Does it react violently with any particular chemicals? Does it decompose when heated?
Spill/Leak Procedures Respiratory protection Disposal Precautions
Special Information How to store it Personal protective equipment Miscellaneous recommendations
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How To Read A MSDS (cont.)
Toxcicity Information LD50 - Lethal dose test; 50% of the population died when fed this dose Note: The tests are normally given in mg/Kg, which means the rat was given x mg of the substance per y Kg of rat body weight LC50 - Lethal concentration test; 50% of the population died when fed this dose Note: The concentration is listed in ppm of vapor in air Skin test - for irritation, corrosivity
Carcinogen?
Reproductive Toxin?
Emergency Phone Number, Date
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MATERIAL SAFETY DATA SHEETS
Notice:
Material Safety Data Sheets for all the chemicals listed in the Workplace List of Hazardous Chemicals in Section 2 of this Manual are:
1. In this section of the manual, or
2. The manufacturer has been requested by Monsanto Purchasing Department to supply us with an MSDS, or
3. Monsanto, St. Louis is preparing the MSDS
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LAW1004739
MATERIAL safety data sheet MC-X-01046
MSDS NUMBER
PROOUCT IDENTIFICATION
TRADE NAME
ASBESTOS FIBER (Chrysotile)
MANUFACTURER'S NAME
Johns-Manville Corporation
ADDRESS (STREET)
P. 0. Box 5108
CITY
Denver
STATE
Colorado
ZIP
80217
GENERIC NAME
Asbestos Fiber
CAS NUMBER
1332-21-4
PHONE NUMBER
(303) 978-3120
CHEMICAL STRUCTURE
Mg3(Si705)(OH)4
MATERIAL Chrysotile asbestos fiber
I . PRODUCT INGREDIENTS
CAS NUMBER 1332-21-4
*Vo
100
TtV 2 f/cc
---
II . PHYSICAL DATA
BOILING POINT
N/A
SPECIFIC GRAVITY
2.4 - 2.6
SOLUBILITY IN WATER
Nil
PERCENT VOLATILE
N/A
APPEARANCE AND ODOR
White to gray fibrous material - DO NOT TEST FOR ODOR.
III FIRE AND EXPLOSION DATA
FLASH POINT
,LEL FLAMMABLE LIMITS
Non-flammable--------------------------------------------------------- -----------
EXTINGUISHING MEDIA
r
uza_________________________
SPECIAL FIREFIGHTING PROCEDURES
EZL
UNUSUAL FIRE OR EXPLOSION HAZARDS
N/A
IV . HEALTH HAZARD INFORMATION
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HAZARD BY ROUTES OF EXPOSURE (Indicate chronic or acute)_________________________________________
inhalation _ Excessive exposure to high concentrations of airborne asbestos fibe ccaanrcicnaougseen.chronic rpulmonaryJ disease and cancer. Product is a known human
ginagessttrioon Binatseeds,toinnacl udrriseenatsesstudanieds^tntheerinegeisstinoon eosftatbhlieshqeudanretiltaietsionoshai s,bbeesttwoeser
f i her found in environmental and piirrpnf-.. nrrupahi final
nations
EYE
As with any dust, excessive exposures can cause transient irritation.
skin contact
Fibers can become imbedded in skin and in some cases result in asbestos
SKIN ABSORPTION
corns.
None
ces
RER
SIGNS AND SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV
There are no acute sign or symptoms associated with asbestos. The disease
associated with over exposure are chronic generally taking from 10 to 40
years to become apparent.
HEALTH HAZARD INFORMATION CONTINUED ON BACK
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HAZARD COMMUNICATION DEPARTMENT:
TEXAS CITY PLANT HC-4-1
HAZARD COMMUNICATION LABELING GUIDELINES
The Hazard Communication Standard requires chemical manufac turers to label hazardous chemicals found in the workplace and leaving the workplace. It is the responsibility of each department to be sure containers in that area are properly labeled. Any questions on labeling should be directed to Safety/Industrial Hygiene. Responsibility for labeling containers leaving the plant lies with the Shipping Department. The Corporate labeling group specifies the wording on labels for containers leaving Texas City. The following guidelines outline our labeling compliance at Texas City.
Materials in the Workplace
1. Process Equipment (i.e., vessels, tanks, pumps, exchangers)
Each piece of process equipment has a functional item number stenciled on it. This number can be cross referenced on the container I.D. table to determine the hazardous materials contained within. The table for this unit is found in the section of this manual labeled "Container I.D. Table". The hazardous materials in this table are listed by their Material Safety Data Sheet (MSDS) names. The MSDS's for hazardous materials in this unit are found elsewhere in the manual.
2. Piping
Each pipeline can be traced to the nearest piece of process equipment. This equipment item can be cross referenced on that unit's Container I.D. Table, as described above.
3. Containers in the Workplace (i.e., drums, bags containing chemicals, bottles, aerosol cans)
Each container must have the following information on it:
Identity of the Contained Hazardous Material
The chemical should be stated as it would be found on a MSDS.
Appropriate Hazard Warnings
Acceptable hazard warnings include Corrosive, Explosive, Carcinogen, Compressed Gas, Irritant, Sensitizer, Toxic, Oxidizer, Water Reactive, Pyrophoric, target organ effects.
ORIGINAL ISSUE: 11/15/85 REVISED:
PAGE 1 OF 3
003535 sc
LAM004743
HAZARD COMMUNICATION DEPARTMENT:
TEXAS CITY PLANT HC-4-1
Materials in the Workplace (Cont'd.)
Warnings NOT acceptable include: "Harmful if Swallowed" and "Hazardous Material", because these statements do not adequately describe the hazard of the material.
Existing labels on incoming containers of hazardous chemicals should NOT be removed unless the container is immediately relabeled with the required information.
4. Exceptions:
Portable Containers such as buckets, catch pans and beakers are exempted from labeling requirements if the contents are for the immediate use of the employee who performs the transfer.
Laboratory Chemicals. Labels on incoming containers of hazardous chemicals shall not be removed or defaced. All laboratory storage containers, such as volumetric flasks, must be labeled as to the contents, using the name as stated on a MSDS. In cases where containers are too small to be labeled with the MSDS name, formulas or other abbreviations are acceptable if a placard stating the abbreviation and MSDS name-Ts posted at the work station. This placard will allow a person unfamiliar with the work area to access the appropriate MSDS.
Unit Samples Carriedto Q.A. Laboratory. Routine samples will be carried to the laboratory, labeled by either the chemical name (as found on a MSDS), the ALIS (Automated Laboratory Information System) name, or occasionally the functional item number of the equipment from which it was sampled. Samples labeled by equipment number may be cross referenced using the Container I.D. Table found in the Hazard Communication manual. (The Q.A. laboratory manuals have a Container I.D. Table for every area of the Texas City plant.) Each unit's labeling exceptions and use of portable containers will be documented in the Hazard Communication manual for that area.
Materials Leaving the Workplace
Materials leaving the Texas City plant must be labeled with the following:
SC 003536
ORIGINAL ISSUE: 11/15/85 REVISED:
PAGE 2 OF 3
LAM004744
HAZARD COMMUNICATION DEPARTMENT:
*
TEXAS CITY PLANT .HC-4-1
Materials Leaving the Workplace (Cont' d.)
1. Identity of the Contained Hazardous Material
The chemical name should be stated as it would be found on a MSDS.
2. Appropriate Hazard Warnings
The requirements previously described apply to materials in the workplace and materials leaving the workplace.
3. Name and Address of the chemical manufacturer or other responsible person.
4. Monsanto's telephone number (314/694-1000) and CAS Number
Also, the hazard warning must be approved by the Corporate Distribution Labeling section. NOTE: These two items are required by Monsanto, but not by the Hazard Communication Standard.
The above requirements apply primarily to laboratory samples and special drum samples that are shipped out of Texas City for experimental purposes.
Exceptions:
Materials shipped out by barge, railroad car, or tank truck are not covered by the Hazard Communication Standard, as DOT regu lations cover these forms of transportation.
Hazardous wastes covered under RCRA (Resource Conservation and Recovery Act), Part B, are also exempted.
Products covered under other regulations, such as the Food, Drug and Cosmetic Act; Federal Insecticide, Fungicide and Rodenticide Act; Federal Alcohol Administration Act; Consumer Product Safety Act; are exempted by the Hazard Communication Standard.
SC 003537
ORIGINAL ISSUE: 11/15/85 REVISED:
PAGE 3 OF 3
LAM004745
SC 003538
LAM004746
HAZARD COMMUNICATION DEPARTMENT:
TEXAS CITY PLANT HC-5-1
CONTAINER IDENTIFICATION TABLE
The intent of the Hazard Communication Standard is that employees be informed about the hazards of chemicals found in process equipment and piping. Although each vessel, tank and exchanger need not be labeled with the contents, some method must exist for employees to access Material Safety Data Sheets for contained hazardous chemicals. A Container I.D. table has been prepared for each process unit at Texas City. This will allow personnel to find out what chemicals a vessel contains by cross-referencing its functional item number in the table. Container I.D. tables for all units will be available in the Quality Assurance lab so that lab analysts can cross-reference samples labeled by stream names or equipment numbers.
Process Equipment
Each piece of process equipment has a functional item number stenciled on it. This number can be referenced in the container I.D. table to determine the contained hazardous materials. Hazardous materials in this table are listed by their Material Safety Data Sheet names. The MSDS for hazardous materials are found in another section of this manual.
Piping
Each pipeline can be traced to the nearest piece of process equipment. This equipment item can be cross-referenced on that unit's container I.D. table, as described above.
SC 003539 ORIGINAL ISSUE: 11/15/85 REVISED:
LAM00.47PAGE 1 OF 1
Function Item Number 50B401 50C101 50D201
50D202
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Promoter Exhaust Blower
Vent Control
CO Compressor
Light Ends Column
CO Feed D201 Feed
Drying Column
D201 Reflux D201 Return to S101 D201 Feed to D202 D201 Scrubber Reflux D201 Overhead
D202 Feed
D202 Overhead
Contained Hazardous Materials
Rhodium TriIodide
Iodine Carbon Monoxide
Carbon Monoxide
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Rhodium Tri-
Iodide Hydrogen Carbon Dioxide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid
Methyl Iodide Acetic Acid Methyl Acetate Hydrogen Iodide
Acetic Acid Methyl Iodide Methyl Acetate
Methyl Iodide Methyl Acetate Acetic Acid
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Hydrogen Carbon Dioxide
Acetic Acid Methyl Iodide Methyl Acetate
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide
Jan. 12, 1989
~1_ SC 003540 LAM004748
Function Item Number
50D203
50D205
50D206 50D207
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
D202 Reflux
Product Column
D202 Bottoms MeOH Injection D203 Feed D203 Overhead D203 Reflux D203 Product D203 Bottoms
Alkanes Column
D206 Overhead D205 Feed
CO Purge D205 Overheads
Waste Acid Stripper
T206 Vent Absorber
D205 Bottoms D206 Feed
D206 Overhead D206 Bottoms
T206 Vent
Contained Hazardous Materials
Acetic Acid Methyl Iodide Methyl Acetate
Acetic Acid
Methanol
Acetic Acid
Acetic Acid
Acetic Acid
Acetic Acid
Mixture Acetic Acid-Proponic Acid
Acetic Acid
Methyl Iodide Methyl Acetate Acetic Acid
Carbon Monoxide
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide
Acetic Acid Alkanes
Mixture Acetic Acid-Propionic Acid
Acetic Acid
Mixture Acetic Acid-Propionic Acid
Mixture Acetic Acid-Propionic Acid
Jan. 12, 1989
-2- SC 003541 LAM004749
Function Item Number 50D301'
50D302
50D303
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
High Pressure Absorber
Reactor Off-Gas Stream
D301 Scrubbing Liquid
D301 Overhead
Low Pressure Absorber
D301 Bottoms
Low Pressure Off Gas
D302 Scrubbing Liquid D302 Bottoms
D302 Overhead
Stripper
From D301 and D302 Bottoms
D303 Overhead
D303 Bottoms
Contained Hazardous Materials
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Acetic Acid
Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Acetic Acid Methyl Iodide Methyl Acetate
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Acetic Acid
Acetic Acid Methyl Acetate Methyl Iodide
Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Acetic Acid Methyl Iodide Methyl Acetate Hydrogen Iodide
Methyl Iodide Methyl Acetate Acetic Acid
Acetic Acid Hydrogen Iodide
Jan. 12, 1989
SC -3- 003542
LAM004750
Function Item Number 50D304
50D305
50E101 50E102
50E103
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
High Pressure Methanol
Absorber
From D301 Overhead
Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Methanol Feed
Methanol
D304 Bottoms
Methanol Acetic Acid
D304 Overhead
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
Low Pressure Methanol Absorber
From D302 Overhead
Acetic Acid Carbon Monoxide
Carbon Dioxide Hydrogen
Methanol Feed
Methanol
D305 Overhead
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
D305 Bottoms
Methanol Acetic Acid
Methanol Heater
Reactor Methanol Feed
Methanol
Start-up Heater
Reaction Mixture
Methyl Iodide Acetic Acid Methyl Acetate Rhodium Tri-
Iodide Hydrogen Iodide Soluble Rhodium
Catalyst Complex
Reactor Condenser
SC 003543
Reactor Overhead
Methyl Iodide Acetic Acid
Methyl Acetate Carbon Monoxide Hydrogen Carbon Dioxide
Jan. 12, 1989
-4-
LAM004751
Function Item Number 50E104 50E107
50E108
50E109
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
CO Compressor Aftercooler
Agitator Seal Water Condenser
CO Feed
Steam Feed Cooling Water Condensed Water
Agitator Seal Water Cooler
Reactor Waste Heat Boiler
Seal Water
Reactor Circulating Stream
50E201-1 & 2 50E202
Light Ends Column Reboiler
Light Ends Column Condenser
50E203
Light Ends Condenser
SC 003544
Jan. 12, 1989
Condensate Feed Product Steam E201 Feed to D201 D201 Overhead
S201 Vent
-5-
Contained Hazardous Materials
Carbon Monoxide
None
None
Possible Contam ination with: Acetic Acid Methyl Iodide
Possible Contamination with: Acetic Acid Methyl Iodide
Methyl Iodide Acetic Acid Methyl Acetate Rhodium Tri-
Iodide Hydrogen Iodide Soluble Rhodium
Catalyst Complex
None
Possible Contam ination with: Acetic Acid Methyl Iodide
Acetic Acid Methyl Iodide Methyl Acetate
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
LAM004752
Function Item Number 50E204 50E205
50E206
50E207
50E208 50E209 50E210
50E214
50E215
50E301 50E302 50E304
50E306
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Drying Column Reboiler
Drying Column Condenser
Dilute Acid Cooler
Product Column Reboiler
Product Column Condenser
Product Cooler
Dilute Acid Pump Bypass Cooler
D206 Bottoms Cooler
Waste Acid Stripper Reboiler
Absorbent Cooler
Absorbent Chiller
Stripper Reboiler
D305 Overhead Chiller
D202 Bottoms D202 Overhead
Light Phase to Reactor D203 Bottoms
D203 Overhead Product Light Phase to Reactor D206 Bottoms
D206 Bottoms
D303 Bottoms D302 Scrubbing Liquid D303 Bottoms
D305 Overhead
SC 003545
Jan. 12 1989
-6-
Contained Hazardous Materials
Acetic Acid
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide
Methyl Iodide Methyl Acetate Acetic Acid
Mixture Acetic Acid-Propionic Acid
Acetic Acid
Acetic Acid
Methyl Iodide Methyl Acetate Acetic Acid
Mixture Acetic Acid-Propionic Acid
Mixture Acetic Acid-Propionic Acid
Acetic Acid
Acetic Acid
Acetic Acid Hydrogen Iodide
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
LAM004753
Function Item Number 50E403
50E404 50E501 50E502 50E503-1 & 2 50E504-1 & 2
50E505-1 & 2 50E506
50F102 50F105
50F201
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Promoter Reactor Condenser
V403 Overhead
Promoter Sub Cooler
Atmospheric Steam Condenser
Seal Fluid
Cooler
Generator and Condenser for 50Z502-1 & 2
Absorber and Evaporator for 50Z502-1 & 2
V403 Overhead
Inlet Outlet Inlet and Outlet
Inlet Steam Inlet CTW Inlet CTW Inlet Chilled Water
Heat Interchanger Shell Side for 50Z502-1 & 2
Tube Side
Scavenger Vent Gas Condenser
Process Side
Reactor Agitator Acetic Flush Foot Bearing Seal Flush Filter
Agitator Seal Water Filter
Circulating Seal Water
Hypophosphorous Acid Filter Pot
Hypophosphorous Feed
Contained Hazardous Materials
Methyl Iodide Hydrogen Iodide Iodine Carbon Monoxide
Methyl Iodide
None
None
Possible Contam ination with: Acetic Acid
None
None
None
Water Possible Contam ination with: Acetic Acid Methyl Iodide
Lithium Bromide
Lithium Bromide
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide
Acetic Acid
Possible Contam ination with: Acetic Acid Methyl Iodide
Hypophosphorous Acid
Jan. 12, 1989
SC 003546 -7-
LAM004754
Function Item Number 50F202
50F203
50F204
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Potassium Hydroxide Filter Pot
Steam Condensate Filter for D206
Catalyst Filter
Potassium Hydroxide Feed
D206 Condensate Feed
Rhodium Settling Tank outlet
Filter Outlet
Bottoms
50F402
Ion Residue Filter
R401 Flush
50F403
Backwash Filter
R401 Backwash
50F501-1 & 2
Seal Fluid Filter
50F502
Safety Shower Eyebath Filter
Jan. 12, 1989
SC
003547
Feed Inlet and Outlet
-8-
Contained Hazardous Materials
Potassium Hydroxide
None
Mixture Acetic Acid-Propionic Acid
Mixture Acetic Acid-Propionic Acid
Mixture Acetic Acid-Propionic Acid
Rhodium TriIodide
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Possible Contam ination with: Acetic Acid
None
LAM004755
Function Item Number 50F503 50F504 50F505
50F506 50J501 50K501-1,2,3
50K502-1 & 2
50K503
50K504-1 & 2
50P101-1 & 2
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
Safety Shower Eyebath Filter
Inlet and Outlet
None
Potable Water Filter
Inlet and Outlet
None
Circulating Liquid Filter for K502 & K503
Circulating Liquid Filter for 50K501
Circulating Liquid Acetic Acid Circulating Liquid Acetic Acid
Priming Jet P516 Circulating Liquid Acetic Acid
Vent Scrubbers on T508-1,2,3
Liquid Inlet Drain
Acetic Acid Acetic Acid
Vent Inlet
Acetic Acid
Vent Scrubbers on T502-2 & 3
Liquid Inlet Drain
Acetic Acid Acetic Acid
Vent Inlet
Acetic Acid
Vent Scrubber on T509
Liquid Inlet Drain
Acetic Acid Acetic Acid
Vent Inlet
Acetic Acid
Scavenger Vent Scrubber
Inlet Outlet
Methyl Iodide Acetic Acid Carbon Monoxide
Methyl Iodide Acetic Acid Carbon Monoxide
Methanol Feed Pump
Methanol Feed
Methanol
Jan. 12, 1989
SC 003548 -9-
LAM004756
Function Item Number 50P102-1 & 2
50P103
50P104
50P105 50P201-1 & 2 50P202-1 & 2 50P203-1 & 2
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Reactor Effluent Separator Bottoms Pump
Catalyst Recycle
Sump Pump
Sump Pump Dis charge
Reactor Waste Heat Boiler Feed Pump
Reactor Circulating Stream
Agitator Seal Water Pump
Light Ends Heavy Phase Pump
Light Ends Column Reflux Pump
Drying Column Feed Pump
seal Water Heavy Phase Reflux to D201 Feed to D202
Contained Hazardous Materials
Methyl Iodide Acetic Acid Methyl Acetate Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Possible Contam ination with: Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Methyl Iodide Hydrogen Iodide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Possible Contam ination with: Acetic Acid Methyl Iodide
Methyl Iodide Methyl Acetate Acetic Acid
Methyl Iodide Methyl Acetate Acetic Acid
Acetic Acid Methyl Iodide Methyl Acetate
Jan. 12, 1989
-lo
se
003549
LAM004757
Function Item Number 50P204-1 & 2
50P205-1 & 2 50P206-1 & 2
50P207-1 & 2 50P211
50P212
50P301-1 & 2
50P303-1 & 2 50P304 50P305-1 & 2 50P501-1 & 2 50P502
50P503-1 & 2
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Drying Column Overhead Pump
Reflux to D202
Drying Column Bottoms Pump
Dilute Acid Recycle Pump
D202 Bottoms
Dilute Acid Recycle
Product Column Overhead Pump
Waste Acid Stripper Pump
Reflux to D203 Feed to D206
Waste Acid Transfer Pump
Waste Acid to T206
Low Pressure Absorber Bottoms Pump
Stripper Bottoms Pump
Acid Makeup Pump
D305 Bottoms Pump
Product Pump
Waste Transfer Pump
D302 Bottoms
D303 Bottoms Acid Makeup D305 Bottoms Product Stream Waste From T503 to T206
Chilled Water Pump
Chilled Water
50P504-1 & 2
Condensate Pump
>C 003550
Jan. 12, 1989
Condensate
Contained Hazardous Materials
Acetic Acid Methyl Iodide v Methyl Acetate
Acetic Acid
Methyl Iodide Methyl Acetate Acetic Acid
Acetic Acid
Mixture Acetic Acid-Propionic Acid
Mixture Acetic Acid-Propionic Acid
Acetic Acid Methyl Acetate Methyl Iodide
Acetic Acid Hydrogen Iodide
Acetic Acid
Methanol Acetic Acid
Acetic Acid
Mixture Acetic Acid-Propionic Acid
Possible Contam ination with: Acetic Acid Methyl Iodide
Possibile Contam ination with: Acetic Acid
L/M\A004758
Function Item Number 50P505
50P506
50P507
50P508-1 & 2
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Shore Tank Pump
Rerun Pump
Acetic Acid Car Loading Pump
Seal Fluid Pump
Product
Rerun to Purification Acetic to Loading Rack
Seal Fluid
50P510 50P511-1 & 2 50P512-1 & 2 50P513-1 & 2 50P515 50P516
50P517
50P518-1 & 2
Refrigeration Condensate Pump
Absorber Pump for 50Z502
Evaporator Pump for Z502
High Pressure Condensate Pump
Drain Pump for T517
Circulation Pump for K501-1,2,3
Circulating Pump for K502-1&2 and K503
Analyzer Sample Catch Tank Pump
Condensate
Absorber to Generator Evaporator Circulation High Pressure Condensate Neutralized Acid to Sewer Circulating Fluid
Circulating Fluid
Return to Process
sc 003551
Contained Hazardous Materials Acetic Acid
Acetic Acid Methyl Iodide Acetic Acid
Possible Contamination with: Acetic Acid None
Lithium Bromide
Lithium Bromide
None
Acetic Acid
Acetic Acid
Acetic Acid
Acetic Acid Methyl Iodide Methyl Acetate Hydrogen Iodide Rhodium Tri-
Iodide Soluble Rhodium
Catalyst Complex
Jan. 12, 1989
-12-
LAM004759
Function Item Number 50P521
50P522 50P523-1 & 2 50P526 50P527 50Q501
50R401
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Scavenger Liquid Sump Pump
Return to Process
Scavenger Pit Sump Pump
Methanol Shore Tank Pumps
Methanol Tank Car Pump
Methanol Barge Pump
200 psig Steam Desuperheater
Ion Exchange Resin Bed
To Sewer
Inlet and Outlet
Inlet and Outlet
Inlet and Outlet
Condensate Steam S101 Feed to R401
T402 Feed to R401
Contained Hazardous Materials
Acetic Acid Methyl Iodide Methyl Acetate Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
None
Methanol
Methanol
Methanol
None
None
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen Hydrogen Iodide Rhodium Tri-
Iodide Soluble Rhodium
Catalyst Complex
Hydrogen Iodide Acetic Acid Soluble Rhodium
Catalyst Complex
Jan. 12, 1989
-13-
LAM004760 SC 003552
Function Item Number 50S101
50S102
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Reactor Effluent Separator
S101 Bottoms
S101 Overhead
S101 Feed
Reactor Condenser Separator
Separator Feed
S102 Overhead SC 003553
Contained Hazardous Materials
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen Hydrogen Iodide Rhodium Tri-
Iodide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Carbon Monoxide Hydrogen Hydrogen Iodide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide Carbon Dioxide Hydrogen
Jan. 12, 1989
-14-
LAM004761
Function Item Number
50S103
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
S102 Drain
Inline Separator
S101 Overhead
50S201
Light Ends Decanter
D201 Overhead S201 Vent
50S202
Light Ends Separator
Heavy Phase to P201
Light Phase to P202
S201 to S202
SC 003SS4
Jan. 12, 1989
S202 Bottoms -15-
Contained Hazardous Materials
Acetic Acid Methyl Iodide Methyl Acetate
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen Hydrogen Iodide Rhodium Tri-
Iodide Soluble Rhodium
Catalyst Complex
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Methyl Iodide Methyl Acetate Acetic Acid Alkanes
Methyl Iodide Methyl Acetate Acetic Acid
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Methyl Iodide Methyl Acetate Acetic Acid
LAM004762
Function Item Number
50S203
50S301
50T1011 thru 4
50T102
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
S202 Overhead
P203 Suction Separator
Methanol Separator
Inlet from D201 Bottoms to P203 Overhead to D201 Inlet from D305
Bottoms to D305
Overhead to Fuel Header
Methanol Feed Storage Tank
Catalyst Solution Storage Tank
Inlet Stream Outlet Stream Inlet Stream
SC 003555
Contained Hazardous Materials
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
Acetic Acid Methyl Acetate Methyl Iodide
Acetic Acid Methyl Acetate Methyl Iodide
Acetic Acid Methyl Acetate Methyl Iodide
Carbon Monoxide Carbon Dioxide Hydrogen Methanol
Carbon Monoxide Carbon Dioxide Hydrogen Methanol
Carbon Monoxide Carbon Dioxide Hydrogen Methanol
Methanol
Methanol
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Jan. 12, 1989
-16-
LAM004763
Function Item Number
50T103
50T104 50T106 50T108 50T201
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
Outlet Liquid to S101
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Soluble Rhodium
Catalyst Complex
Overhead Line
Carbon Monoxide
CO Purge
Carbon Monoxide
Sump Tank
Generally Con taminated with: Acetic Acid Methyl Acetate Methyl Iodide Hydrogen Iodide Rhodium Tri-
Iodide Soluble Rhodium
Catalyst Complex
CO Storage Tank
Feed Stream Outlet Stream
Carbon Monoxide Carbon Monoxide
E102 Condensate Flash Drum
Inlet Overhead
None None
Drain
None
Agitator Seal Water Reservoir
Feed Stream
None
Circulating Stream
Possible Contam ination with: Methyl Iodide Methyl Acetate Acetic Acid
Drying Column Overhead Tank
D202 Overhead
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide
Jan. 12, 1989
-17-
sc 003556 LAM004764
Function Item Number
50T202
50T204 50T205 50T206 50T208 50T401 50T402
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
T201 to P204
Acetic Acid Methyl Iodide Methyl Acetate
T201 Vent
Acetic Acid
Methyl Iodide Methyl Acetate Carbon Monoxide
Product Column
Overhead Tank
D203 Overhead T202 Vent D203 Reflux
Acetic Acid Acetic Acid Acetic Acid
Hypophosphorous Acid Storage Tank
Hypophosphorous Feed to D202 Bottoms
Hypophosphorous Acid
Potassium Hydroxide Storage Tank
Potassium Hydroxide Potassium
Feed to D202
Hydroxide
Bottoms
Primary Rhodium Steeling Tank
Waste Acid Stripper Bottoms
Mixture Acetic Acid-Propionic Acid
Waste Heat Boiler Condensate Tank
Condensate from E204
Possible contamination with: Acetic Acid
Promoter Storage Tank
Product Methyl Iodide
Methyl Iodide
HI Storage Tank
Inlet Stream
SC 003557
Hydrogen Iodide Acetic Acid Rhodium Tri-
Iodide Carbon Monoxide
Soluble Rhodium Catalyst Complex
Jan. 12, 1989
-18-
LAM004765
Function Item Number
50T405 50T502-1 & 3 50T503 50T504 50T505
50T506 50T507 50T508-1,2,3
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Outlet Stream
Promoter Exhaust Air Scrubber and Stack
Product Day Tank
Auxiliary Rhodium Settling Tank
Chilled Water Pump Tank
Flare Knockout Drum
Drain Inlet and Outlet Inlet and Outlet Inlet and Outlet Flare Header
25psig Steam Flash Tank
Atmospheric Steam Flash Tank
Shore Tank
Inlet Outlet Liquid Outlet Vapor Inlet Outlet Liquid Outlet Vapor Acid Inlet and Outlet
Contained Hazardous Materials
Hydrogen Iodide Acetic Acid Rhodium Tri-
Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Rhodium TriIodide
Iodine
Acetic Acid
Mixture Acetic Acid-Propionic Acid
Alkanes
Possibile Contamination with: Acetic Acid Methyl Iodide
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide Carbon Dioxide Hydrogen Methanol Natural Gas
None
None
None
None
None
None
Acetic Acid
LAM004766
Jan. 12, 1989
-19-
SC 003558
Function Item Number 50T509 50T510
50T511 50T512 50T513 50T514 50T515 50T517 50T518
50T519 50T520
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Off-Spec Storage Tank
Acid Inlet and Outlet
Flare Sump Tank
Flare Header
Air Receiver Tank
Seal Fluid Tank
Condensate Pump Tank
Collection Pit
Neutralization Pit
Collection Sump
Analyzer Sample Catch Tank
Plant Air Inlet and Outlet Inlet and Outlet Drainings
Drainings Circulating Fluid Analyzer Drains
Neutralization Tank for K502 & K503
Flare Neutralization Pit
Drainings
Flare Tank Drainings
Contained Hazardous Materials
Acetic Acid Methyl Iodide Hydrogen Iodide
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide Carbon Dioxide Hydrogen Methanol Natural Gas
None
Possible Contam ination with: Acetic Acid
None
Acetic Acid Methyl Iodide Methyl Acetate
Acetic Acid
Acetic Acid
Acetic Acid Methyl Iodide Methyl Acetate Hydrogen Iodide Rhodium Tri-
Iodide
Acetic Acid
Acetic Acid Methyl Iodide Methyl Acetate
Jan. 12, 1989
-20-
sc 003559 LAM004767
CONTAINER I .D. TABLE
Acetic Acid Department
Function Item Number
Equipment Name
Process Stream
Contained Hazardous Materials
50T523
Scavenger Tank
Drain to Scaven ger
Acetic Acid Methyl Iodide Methyl Acetate Rhodium Tri-
Iodide Hydrogen Iodide Soluble Rhodium
Catalyst
Complex
50T524
100 psig Steam Flash Tank
Condensate in Steam Out
None None
50T530-1 & 2
Methanol Shore Tank
Inlet and Outlet
Methanol
50T531
Overflow Seal Pot Inlet and Outlet for 50T530-1
Methanol
50V101
Reactor
Methanol Feed
Methanol
CO Feed
Carbon Monoxide
Heavy Phase Return Methyl Iodide Methyl Acetate Acetic Acid
Light Phase Return
Methyl Iodide Methyl Acetate Acetic Acid Hydrogen Iodide
Flashing Liquid
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide
Carbon Dioxide Hydrogen Soluble Rhodium
Catalyst
Complex
SC 003560
VI01 Overhead
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide
Jan. 12, 1989
-21-
LAMC04 7
Function Item Number
50V401
50V402
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
Hydrogen
Catalyst Return
Methyl Iodide Acetic Acid Hydrogen Iodide Rhodium Tri-
Iodide Methyl Acetate Carbon Monoxide Soluble Rhodium
Catalyst Complex
Foot Bearing Flush Methyl Iodide Methyl Acetate Acetic Acid
Waste Heat Boiler Circulating Stream
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst
Complex
Catalyst Dissolver
Vent
Carbon Monoxide Hydrogen Acetic Acid Rhodium Tri-
Iodide
Carbon Monoxide Feed
Carbon Monoxide
V401 to E401
Rhodium TriIodide
Acetic Acid Hydrogen Iodide Soluble Rhodium
Catalyst Complex
Catalyst Residue Concentrator
Feed
Acetic Acid Hydrogen Iodide
Jan. 12, 1989
-22-
SC 003561 LAM004769
Function Item Number
50V403
50Z306
50Z502-1 & 2 Stream 1 Stream 2 Stream 3
Stream 4
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous
Materials
Hydrogen Iodide Rhodium Tri-
Iodide
Promoter Reactor
Vent
Methyl Iodide Hydrogen Iodide Iodine Carbon Monoxide Hydrogen Carbon Dioxide
Drain
Methyl Iodide Hydrogen Iodide Iodine Carbon Monoxide
Soluble Rhodium Catalyst Complex
Off Gas Refrigera tion Unit
D305 Overhead
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
Condensed Methanol Methanol
Return
Acetic Acid
Refrigera tion System
Internal Flows
Lithium Bromide
CO Feed to V101 Carbon Monoxide
MeOH Feed to VI01 Methanol
V101 Off Gas to E103
Methyl Iodide Methyl Acetate Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
003562
V101 Effluent to S101
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide
Carbon Monoxide Carbon Dioxide Hydrogen Soluble Rhodium
Jan. 12, 1989
-23-
LAM004770
Function Item Number Stream 5
Stream 6
Stream 7 Stream 8 Stream 9 Stream 10 Stream 11
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
Catalyst Complex
S101 Overhead Vapor Methyl Iodide
to D201
Methyl Acetate
Acetic Acid
Carbon Monoxide
Carbon Dioxide
Hydrogen
Hydrogen Iodide
Rhodium Tri-
Iodide
Soluble Rhodium
Catalyst
Complex
S101 Bottoms Liquid Methyl Iodide
V101
Methyl Acetate
Acetic Acid
Rhodium Tri-
Iodide
Hydrogen Iodide
Carbon Monoxide
Soluble Rhodium
Catalyst
Complex
D201 Scrubber Bot toms to S101
Methyl Iodide Acetic Acid Methyl Acetate Hydrogen Iodide
SI02 Bottoms Liquid to V101
Acetic Acid Methyl Iodide Methyl Acetate
D202 Overhead Liquid to VI01
Acetic Acid Methyl Iodide Methyl Acetate Carbon Monoxide
Steam Make-up to S101
None
D201 Overhead
Methyl Iodide
Heavy Phase Liquid Methayl Acetate
to V101
Acetic Acid
Jan. 12, 1989
-24-
003563 sc
LAM004771
Function Item Number Stream 13
Stream 14 Stream 15
Stream 16
Stream 17 Stream 18
Stream 19
Stream 21
Stream 22 Stream 24
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
-
Process Stream
Contained Hazardous Materials
S102 Overhead Vapor Acetic Acid
to D301
Methyl Iodide
Methyl Acetate
Carbon Monoxide
Carbon Dioxide
Hydrogen
D303 Bottoms Liquid Acetic Acid
to D301 and D302
Hydrogen Iodide
Combined D301 and Acetic Acid
D302 Overhead Vapor Carbon Monoxide
to Flare
Carbon Dioxide
Hydrogen
S202 Overhead Vapor to D302
Methyl Iodide Methyl Acetate
Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
D201 Overhead Light Methyl Iodide
Phase Liquid
Methyl Acetate
Acetic Acid
D301 Overhead Vapor to Flare
Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
D302 Overhead Vapor to Flare
Acetic Acid Carbon Monoxide Carbon Dioxide Hydrogen
D201 Overhead Vapor Methyl Iodide
to E202
Methyl Acetate
Acetic Acid
Carbon Monoxide
Hydrogen
Carbon Dioxide
Reflux to D201
Methyl Iodide Methyl Acetate Acetic Acid
SC 003564
D201 Bottoms Liquid Acetic Acid
Liquid to D202
Methyl Iodide
Methyl Acetate
Jan. 12!, 1989
-25-
LAM004772
Function Item Number Stream 25
Stream 26 Stream 27
Stream 28 Stream 29
Stream 30 Stream 31 Stream 33
Stream 34 Stream 35 Stream 36 Stream 37
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
S201 Overhead Vapor Methyl Iodide
to E203
Methyl Acetate
Acetic Acid
Carbon Monoxide
Carbon Dioxide
Hydrogen
D201 Overhead Light Methyl Iodide
Phase Liquid to
Methyl Acetate
to V101
Acetic Acid
Combined D201 and D202 Overhead Light Phase Liquid to V101
Methyl Iodide Methyl Acetate Acetic Acid
S202 Bottoms Liquid to S201
Methyl Iodide Methyl Acetate Acetic Acid
D202 Overhead Vapor Acetic Acid
to E205
Methyl Iodide
Methyl Acetate
Carbon Monoxide
D202 Reflux
Acetic Acid Methyl Iodide Methyl Acetate
D202 Bottoms Liquid to D203
Acetic Acid
T201 Overhead Vapor Acetic Acid
to E203
Methyl Iodide
Methyl Acetate
Carbon Monoxide
D203 Vapor Overhead to E208
Acetic Acid
D203 Bottoms Liquid to T503 or D206
Mixture Acetic Acid-Propionic Acid
D203 Reflux
Acetic Acid
D303 Bottoms Liquid to D301
Acetic Acid Hydrogen Iodide
SC 003565
Jan. 121, 1989
-26-
lanioo4773
Function Item Number Stream 38 Stream 39 Stream 40 Stream 41
Stream 42 Stream 43 Stream 44 Stream 45 Stream 46 Stream 51
Stream 52
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
D303 Bottoms Liquid to D302
Acetic Acid Hydrogen Iodide
Make-up Acetic Acid to D303 Sump
Acetic Acid
D303 Bottoms Liquid to E301
Acetic Acid Hydrogen Iodide
Combined D301 and D302 Bottoms Liquid to D303
Acetic Acid Methyl Iodide Methyl Acetate Hydrogen Iodide
D303 Overhead Vapor to E202
Methyl Iodide Methyl Acetate Acetic Acid
D203 Sidedraw Product to T502 or T509
Acetic Acid
D303 Bottoms Blow Acetic Acid
down to S101
Hydrogen Iodide
D302 Bottoms Liquid to D303
Acetic Acid Methyl Acetate Methyl Iodide
D301 Bottoms Liquid to D303
Acetic Acid Methyl Iodide Methyl Acetate
Spent Catalyst from S101 to V401
Methyl Iodide Methyl Acetate Acetic Acid
Rhodium TriIodide
Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
SC 003566
V401 Overhead Vapor to S101
Carbon Monoxide
Hydrogen Acetic Acid Rhodium Tri-
Iodide
Jan. 12, 1989
-27-
LAM004774
Function Item Number Stream 54 Stream 56 Stream 57
Stream 59 Stream 61
Stream 62 Stream 64
Stream 65
Stream 66 Stream 67
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Methanol Feed to V401
CO Feed to V401
Rhodium Feed to V401
Nitrogen Feed to V401 V401 Bottoms Liquid to V402
Methanol Feed to V402 V402 Overhead Vapor to SI01
V402 Bottoms Liquid to Catalyst Residue Drum T402 Overhead Vapor to S101 CO Feed to T402
*
Contained Hazardous Materials
Methanol
Carbon Monoxide
Methyl Iodide Methyl Acetate Acetic Acid Rhodium Tri-
Iodide Hydrogen Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Nitrogen
Rhodium TriIodide
Acetic Acid Hydrogen Iodide Soluble Rhodium
Catalyst Complex
Methanol
Methyl Iodide Carbon Monoxide Carbon Dioxide Hydrogen Acetic Acid Methyl Acetate
Acetic Acid Hydrogen Iodide Rhodium TriIodide
Carbon Monoxide
Carbon Monoxide
SC 003567
Jan. 12, 1989
-28-
LAM004775
Function Item Number Stream 68
Stream 69 Stream 70 Stream 71
Stream 72
Stream 73 Stream 74 Stream 75 Stream 76 Stream 77 Stream 78
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous
Materials
T402 Bottoms Liquid to SI01
Hydrogen Iodide Acetic Acid Rhodium Tri-
Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Condensate Feed to V403
None
CO Feed to V403
Carbon Monoxide
V403 Overhead Vapor Methyl Iodide
to E403
Hydrogen Iodide
Iodine
Carbon Monoxide
Hydrogen
Carbon Dioxide
V403 Overhead Vapor Methyl Iodide
to S101
Hydrogen Iodide
Iodine
Carbon Monoxide
Hydrogen
Carbon Dioxide
Liquid from E403 to V403
Methyl Iodide Hydrogen Iodide Iodine
Iodine Crystals Feed to V403
Iodine
T401 Vapor Overhead Carbon Monoxide
to S101
Methyl Iodide
CO Feed to 50T401 Carbon Monoxide
Liquid from E404 to T401
Methyl Iodide
Liquid from T402 to Hydrogen Iodide
V403
Acetic Acid
Rhodium Tri-
lodide
Carbon Monoxide
SC 003568
Soluble Rhodium Catalyst
Complex
Jan. 12, 1989
-29-
L/XM004776
Function Item Number Stream 79
Stream 80 Stream 81 Stream 82 Stream 83
Stream 84 Stream 85 Stream 86
Stream 87 Stream 88 Stream 89
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Contained Hazardous Materials
Liquid in Catalyst Solution Tank (T402)
Hydrogen Iodide Acetic Acid Rhodium Tri-
Iodide Carbon Monoxide Soluble Rhodium
Catalyst Complex
Liquid in Product Day Tank (T502)
Acetic Acid
Liquid in Off Spec Acetic Acid
Tank (T509)
Methyl Iodide
Hydrogen Iodide
Liquid Rerun from P506 to Area 200
Acetic Acid Methyl Iodide Hydrogen Iodide
Liquid in Waste Tank (T503)
Mixture Acetic Acid-Propionic
Acid Alkanes
Liquid in Shore Tank (T508)
Acetic Acid
Circulating Seal Fluid Liquid
Possible Contain ination with: Acetic Acid
Circulating Chilled Water
Possibile Contam ination with: Acetic Acid Methyl Iodide
Liquid in T405
Rhodium TriIodide
Iodine
Cooling Tower Water to Users
None
Liquid in Collect ion Pit (T514)
Acetic Acid
Methyl Iodide Methyl Acetate
Jan. 12, 1989
-30-
SC 003569 LAM004777
CONTAINER I.D. TABLE
Acetic Acid Department
Function Item
Number
Equipment Name
Process Stream
Contained Hazardous
Materials
Stream 90
Liquid in Neutral Acetic Acid ization Pit (T515)
Stream 91
Liquid in Sump Tank(T103)
Generally Con taminated with: Acetic Acid Methyl Acetate Methyl Iodide Hydrogen Iodide Rhodium Tri-
Iodide Soluble Rhodium
Catalyst Complex
Stream 101
D203 Net Overhead Recycle to D202
Acetic Acid
Stream 102
El09 Condensate Blowdown
Possible Contam ination with: Acetic Acid Methyl Iodide
Stream 103
D201 Tray 8 Liquid Acetic Acid
to Tray 4
Methyl Iodide
Methyl Acetate
Stream 104
D201 Tray 4 Vapor to Tray 8
Acetic Acid Methyl Iodide Methyl Acetate
Stream 105
D206 Bottoms
Mixture Acetic Acid-Propionic
Acid
Stream 106
D304 Ovehead Vapor
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
Stream 107
D305 Overhead Vapor
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
Stream 108
D304 Bottoms Liquid Methanol Acetic Acid
Stream 109 SC
Jan. 12, 1989
003570
D305 Bottoms Liquid Methanol Acetic Acid
-31-
LAM004778
Function Item Number
Stream 110
CONTAINER I.D. TABLE
Acetic Acid Department
Equipment Name
Process Stream
Combined Off-Gas to Fuel Header
Contained Hazardous Materials
Methanol Carbon Monoxide Carbon Dioxide Hydrogen
SC 003571
Jan. 12, 1989
-32-
LAM004779
SC 003572
ri / '.y-
fc LAM004780
HAZARD COMMUNICATION DEPARTMENT:
TEXAS CITY PLANT HC-6-1
WORK PRACTICES
The Hazard Communication Standard requires that employees be trained about appropriate work practices to protect themselves from the physical and health hazards of chemicals in the work area. This section includes references to established plant and area routine work procedures. Manuals containing the referenced procedures are readily identified and available in the work area.
It is the responsibility of each area to keep its procedure list evergreen.
SC 003573 ORIGINAL ISSUE: 11/15/85 REVISED:
PAGE 1 OF 1
LAM004781
DOCUMENTATION OF ROUTINE TASKS
For Ac.e.Ttc,
________ Department
MONSANTO
TEXAS CITY
CODE P-0100 P-0106 P-0107 P-0108 P-0114 P-0115
P-0116
P-0120 P-0121
P-0124
P-0125
P-0126 P-0127 P-0133 P-0134 P-0136 P-0140
P-0142
ISSUE DATE
PROCEDURE TITLE
05/03/82
Plant Safety Program
06/26/84
Contractor Safety Program
03/23/82
Use and Control of Potable Water
05/07/84
Bicycle Safety
11/23/82
Ladder Inspection
10/01/76
Flammable and Combustible Liquids Storage and Dispensing Areas
10/12/82
Area Safety Inspections
01/18/83 (Partial Rev.)
09/01/71
(Addendum A) Electrical Instrument Devices
08/13/82
Use and Control of Hoses
01/18/83 (Partial Rev.)
04/14/82
(Appendix B) Sprinkler System Inspection and Testing
08/29/84
Procurement and Handling of Radioactive Material and X-Ray Producing Equipment
05/03/82
Nitrogen Distribution
09/01/71
Grounding of Plug-Connected Electrical Equipment
09/01/71
Company Furnished Personal and Safety Equipment
06/07/82
Ball Valve Handle Usage
08/25/76
Gas Cylinder Storage
05/04/79
Inspection of Mechanical Equipment Overspeed Protective Devices
06/23/80
Vessel and Heat Exchanger Equipment Reliability Program
SC 003574 LAM004782
ROUTINE TASKS Acetic Acid Department
Instructions for routine tasks may be found in the Acetic Acid Operating Manual. A copy of the manual is located at the Chief Operators desk in the control room. The following topics are covered:
401.00 FUNCTIONS AND CONTROLS
401.100 AREA 100 (REACTION AREA) FUNCTION
401.101 401.102 401.103
Production of Acetic Acid Removal of Heat of Reaction Separation of Acetic Acid from Catalyst
401.200 AREA 100 (REACTION AREA) CONTROLS
401.201 401.202 401.203
401.204
Reactor, V101 Reactor Effluent Separator (Flash Tank)S101 Reactor Waste Heat Boiler, E109, Reactor Startup Heater, E102, and Reactor Waste Heat Boiler Feed Pump. P104 CO Compressor, C101, and CO Storage Tank,T104
401.300 AREA 200 (PURIFICATION AREA) CONTROLS
401.301 401.302 401.303 401.304 401.305 401.306
Light Ends Column, D201 Drying Column, D202 Product Column (Heavy Ends Column), D203 Waste Acid Stripper, D206 Alkane Removal Column, D205 Chemical Addition System, T204/T205
401.400 AREA 200 (PURIFICATION AREA) CONTROLS
401.401 401.402 401.403
401.404 401.405 401.406
Light Ends Column, D201 Drying Column, D202 Product Column (Heavy Ends Column), D203
Waste Acid Stripper, D206 Alkane Removal Column, D2U5 Chemical Addition System, T204/T205
401.500 AREA 300 (LIGHT RECOVERY AREA) FUNCTION
401.501 401.502 401.503 401.504 401.505
High Presure Absorber, D301 Low Pressure Absorber, D302 Stripper, D303 High Pressure Methanol Absorber, D304 Low Presure Methanol Absorber, D305
401.600 AREA 300 (LIGHT ENDS RECOVERY AREA) CONTROLS
401.601 401.602
401.603 401.604
High Pressure Absorber, D301 Low Pressure Absorber, D302
Stripper, D303 High Pressure Methanol Absorber,
D304
April 15, 1986
LAM004783 1- -
sc 003575
ROUTINE TASKS
Acetic Acid Department
401.605 401.606
Low Pressure Methanol Absorber, D305 Light Ends Off Gas to Fuel Header or Flare
401.700 AREA 400 (CATALYST AND PROMOTER MANUF. AREA) FUNCTION
401.701 401.702 401.703 401.704 401.705
401.706 401.707 401.708
401.709
Catalyst Dissolver, V401 Promoter Reactor, V403 Promoter Storage Tank, T401 Ion Exchange Resin Bed, R401 Catalyst Residue Concentrator, V402
HI Storage Tank, T402 Promoter Exhaust System Promoter Reactor Condenser, E403
Promoter Subcooler. E404
401.800 AREA 400 (CATALYST AND PROMOTER MANUF. AREA) CONTROLS
401.801 401.802 401.803 401.804 401.805 401.806
Catalyst Precipitator-Dissolver, V401 Promoter Reactor, V403 Promoter Storage Tank, T401 Ion Exchange Resin Bed, R401 Catalyst Residue Concentrator, V402 HI Storage Tank, T402
401.900 MISCELLANEOUS SUPPORT SYSTEMS FUNCTIONS
401.901 401.902 401.903
401.904 401.905 401.906 401.907
401.908 401.909 401.910 401.911 401.912 401.913
Seal Fluid System Low Pressure CO System Refrigeration System Flare System Waste Treatment System Steam and Condensate System Cooling Tower Water Potable Water System Filtered Water System Nitrogen System Air Systems Electrical System Process Scavenger System
401.1000 MISCELLANEOUS SUPPORT SYSTEMS CONTROLS
April 15, 1986
401.1001 401.1002 401.1003 401.1004 401.1005 401.1006 401.1007 401.1008 401.1009 401.1010 401.1011 401.1012 401.1013
Seal Fluid System Low Pressure CO System Refrigeration system Flare System Waster Treatment System Steam and Condensate System Cooling Tower Water Potable Water System Filtered Water System Nitrogen System Air Systems Electrical Systems Process Scavenger system
LAM004784
2- Sc 03576
ROUTINE TASKS Acetic Acid Department
403.00 NORMAL OPERATIONS
403.100 AREA 100 (REACTION AREA)
403.200 AREA 200 (PURIFICATION AREA)
403.300 AREA 300 (LIGHT ENDS RECOVERY AREA)
403.400 CHANGING PRODUCTION RATES
403.500 AREA 400 (CATALYST AND PROMOTER MANUF. AREA)
403.501 403.502 403.503 403.504
403.505 403.506 403.507
Catalyst Preparation Promoter Preparation Corrosion Metals Removal Catalyst Residue (Corrosion Metals) Concentration Methyl Iodide Addition to Reactor Area Catalyst Addition to Reaction Area Area 400 Sample Calculations and Sample Log Sheets
SC 003577
April 15, 1986
-3-
LAIV1004785
