Document O1Dd0VkvJBbLwxO2mxrGg0k8M

PLAINTIFF'S EXHIBIT Compliance Checklist THE WILDEST DREAMS HAVE A WAY OF COMING TRUE. Just a reminder that planning for tomorrow's possibilities is not only a very important but also a very exciting part of today's work. That's why we are developing unique products for water-borne, hot melts, and other new adhesive and sealant technologies. And why we have an entire department dedicated to serving nearly every segment of your industry. It's why we're maintaining our position as a leading supplier of oxygenated solvents. And at the same time helping our customers reformulate to meet both short- and long-term pollution control standards. Our research and development teams are dedicated to developing a wide variety of products, appli cations and techniques to meet a broader range of customer needs and expectations. And we're expanding our ability to distribute efficiently as well as provide prompt and personal technical service. We already have five full-service regional latex plants. Soon there'll be more. You see, we expect the future to be full of surprises for some people. Andfilied with opportunities for others. PEOPLE PLANNING THE FUTURE. Adhesive and Sealant Intermediates j</h6> 863 Union Carbide Material Safety Data Sheets For The Adhesives Industry The complete Index of MSD Sheets can be obtained from your Union Carbide representative. Material Fomi Number Aceumo Acetophenone Acrylic Acid. Glacial N-Aminoethy!eth;inoluniinc N-Aminoethyl Piperazine ANHYOROL Solvent. PM 1473 IA.T.F.D. Special Industrial Solvent Formula A| ANHYOROL Solvent. PM 1474 [A.T.F.D. Special Industrial Solvent Formula A| ANHYDROL Solvent Special. PM 4080 F-43002 F-43358 F-43949 F-43570 F-44209 F-43059 F-43060 F-45867 ANHYDROL Solvent. PM 4081 IA.T.F.D. Special Industrial Solvent Formula A) F-43I97 ANHYDROL Solvent Special. Anhydrous, PM 4082 F-44079 ANHYDROL Solvent Special. PM 4083 F-45770 ANHYDROL Solvent. PM 4084 (A.T.F.D. Special Industrial Solvent Formula Aj F-43198 ANHYDROL Solvent. PM 4085 F-43943 ANHYDROL Solvent Special 190. PM 4078 (Government Formulation DM) F-44334 ANHYDROL Striven! Special 190. PM 4079 (Government Formulation AM) F-44115 Benzene Bisphcnol A. UCAR 1.5-Butadiene Butanol 2-Butanol Butyl Acetate Butyl Acetate Mixture. PM5131 Butyl Acrylate 8utyl CAR8ITOL 8uty! CARBITOL Acetate Butyl CHLLOSOLVE Butyl CELLOSOLVE Acetate F-43095 F-4357! F-43120 F-43024 F-43572 F-43019 F-43305 F-43073 F-43017 F-43074 F-43003 F-432S2 CARBITOL Acetate CARBITOL Mixture. CARBITOL Solvent CARBITOL Solvent. PM5949 PM 600 F-43026 F-44381 F-43018 F-45S79 Material CARBOWAX Methoxy Polyethylene Glycol 350 CARBOWAX Mcthoxv Polyeihvlene Glycol 550 ' ' CARBOWAX Melhoxy Polyethylene Glycol 750 Form Number F-43443 F-43444 F-43445 CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Glycol Glycol Glycol Glycol Glycol Glycol Glycol Glycoi Glycol Glveol 200 300 400 600 1.000 i .500 1.540 4.000 6.000 20.000 F-43359 F-4343ti F-4.3430 F-43457 F-45438 F-43459 F-43440 F-43441 F-43446 F.45442 KM#? 66 Material Form Number C'F.i.L.OSlZE Hydroxyctnyi Cellulose QP-Gr.ides. General CHt.LOSlZr Hydroxyethy Ceilu.O'c Vv P-Grades. General CEt.LOSOLVE Acetate CEt.LOSOfA E Sol veil: Cyclohexanone' :sss-Deeyl Aeryiate Di.icetonc Alcohol Diethanolamine 2.2-Diclhoxv,ieetophenone Dis-thy 1,inline Dictliy laiiiiitopropylamine Diethy lene Glycol Diethyicnelri amine N.N-Diethylethanolainine Dnsohuiyl Ketone N.N-Dimeihylethnnolumine 1,4-Dioxane Dipropylene Glycol EVA-308 Resin. BAKEUTE Co-MKR F.VA-501 Resin. BAKEUTE Co-MER EVA-505 Resin. BAKEUTE Co-MER EVA-506 Resin. BAKEUTE Co-MER EVA-507 Resin. BAKELITE Co-MER EVA-508 Resin. BAKELITE Co-MER EVA-60? Resin. BAKELITE Co-MER EVA-607 Resin. BAKEUTE Co-MER Epoxy Hardener ERL-2793. BAKEUTE t.iquid Epoxy Hardener ZZ1.-0334. BAKELITE Liquid Epoxy Hardener ZZL-0803. BAKELI TE Liquid Epoxy Hardener ZZ1.4I806. BAKEUTE Liquid Epoxy Hardener ZZL-0804. BAKEUTE Liquid Epoxy Hardener ZZL-08I4. BAKELITE Liquid Epoxy Hardener ZZL-0840. BAKEUTE Liquid Epoxy Hardener ZZl.4)846. BAKELITE Liquid Epoxy Hardener ZZL-0854. BAKELITE Liquid Epoxy Hardener ZZL-0S72. BAKEUTE Liquid Epoxy Hardener ZZLA-033V. BAKELITE Liquid Epoxy Hardener ZZLA-0816. BAKEUTE Liquid Epoxy Hardener ZZLA-0848. BAKEUTE Liquid Epoxy Hardener ZZLB-0822. BAKEUTE Liquid Epoxy Resin ERL-4206. BAKELITE Cycloaliphatic Epoxy Resin ERL-4221. BAKELITE Cycloaliphatic Epo.xv Resin ERL-4234. BAKELITE Cycloaliphatic Epoxy Resin ERL-4289. BAKELITE Cycloaliphatic Epoxy Rexm ERRA-4040. BAKELITE Cycloaliphatic i--4383 7 F-43S36 F-43062 F-43023 F-43075 F-43063 F-43122 F-457! 1 F-4325! F-43923 F-43105 F-45123 F-435SO F-43252 F-43593 F-43585 F-43107 F-4390S F-43647 F-4364S F -44095 F-46056 F-43649 F-44096 F-43650 F-4322S F-43656 F-44163 F-4365S F-43659 F-43661 F-43266 F-43668 F-43669 F-43671 F-44474 F-43662 F-43655 F-43664 F-43674 F-43675 F-43676 F-43677 F-43760 Material Esterumi-20Ethanol -see alto ANHYDROI. and SVN'ASOi, Soi\oms> Ethanol. !'40 proof' Ethanol. 200 proof Ethanol. CD-i9. <90 proof E'.har.ol. CD-14. 200 proof Ethnnoi. SD-29. 140 proof Ethanol. SD--0. 200 proof Etini Acetate. L'ndenatured Ethyl Acetate. S5-K8/V . Denatured Etliyl Acrylate Etltylcnediunttne Ethylene Glycol Ethylene Oxide 2-Ethylhexyl Aeryiate. Inhibited Ethylidcnenorborncnc Form Number F-43 2 80 F-43353 F-43354 F-43412 F-43413 (--43331 F-44749 F-43020 F-4.fi 99 F-4.H26 F-43127 F-43022 F-431 30 F-43386 F-43429 Glutaraidchyde. 250 Aqueous Solution Glyo\al. 40ri Aqueous Solution Hexylene Glycol Isobutanol Isobulyl Acetate. 99 -- ?7 Isohuty! Acetate. 4?,,f Isobutyl Acetate Mixture. PM4413 Isooutyl Aeryiate Isobuivl Heptyl Ketone Isocyanate I'D I and TDI-P.NIAX Isocyanate SF-58. NI.AX Isophoronc Isophoronc 50 and t. PM 5464 Isopropanol. Anhydrous Isoprop.tnol. VI ri Isopropyl Acetate Latex 130. L:CAR Latex 131. UC.AR Latex !53. UC.AR Latex 3SO. UCAR Latex i234. UC.AR F-43549 F-4344? F-43064 F-43203 F-43113 F-43234 F-43301 F-43 SO.'' F-43591 F-43954 F-434S4 F-43U65 F-4414' F-43004 F-4J005 F-43284 F-43753 F-43807 F-45514 F-455S3 F-45940 \t$\& 664 Material Form Number Vk-:!:.i!:;'i Meshy ' Am;: Acetate Moth;; Amyi Acetate Mixture. PM 4433 Methyl Aiml Alcohol a . Vfcthyi -! -But,:n*>! 2-Mei.iyl-l -Butanol. Commercial Methyl n-Butyl Ketone Med'.j! CAKBITOL Methyl CELLOSOLVE Methyl CELLOSOl.vE Acetate S-Methyl Diethanolamine N-Methyl Ethtimtlaniine Methyl Ethyl Ketone 2-Melhyl-5-Elhyl Pyridine Methyl Isoamvl Ketone Methyl Isobutyl Ketone Methyl Isobulyi Ketone Mixture. PM 4914 N-Methyl Morpholine Mom'cthanolum ine Neopemyl Glycol Diacrylato 1.5-PetUanediol 2.4-Pcntancdione Phenolic Bakina Re.siii BKR-2620. BaKELITE Phenolic Bakina Resin BKS-2315. BAKELITE " Phenolic Baking Resin BKS-27IO. BAKELITE Phenolic Resin Solution BLS-2700. BaKELITE Phenolic Resin BRP-8152. BAKELITE Phenolic Resin BRPA-4494. BAKELITE Phenolic Resin CK-1634. BAKELITE Oil-Soluble. Heat-Reactive. 1009c Phenolic Resin CK-0405. BAKELITE Oil - Soluble. Non-Heat- Reactive Phenolic Resin CK-2103. BaKELITE Oil-Soluble. Non-Heat-Reactive Phenolic Resin CK-2432. BaKELITE Oil-Soluble. Non-Heat- Reactive Phenolic Resin CK-5254. BAKELITE Oil-Soluble. Non-Heat- Reactive Phenolic Resin CKM-2400. BAKELITE Oil-Soluble. Non-Heal-Reactivc Phenolic Resin CKS-1282. BAKELITE P.heno!ic Dispersion Resin CKU- 5960. BAKELITE Phenoxy Resin PKHA. PKHC. PKHH. BAKELITE Phenyl Acetate Phenyl Glycol Ether Piperazine. Technical Grade (60*? Water Solution) Plasticizer EP-8. FLEXOL Plasticizer EPO. FLEXOL Plasticizer 3GH. FLEXOL Plasticizer AGO. FLEXOL Plasticizer 4GO. FLEXOl. Plasticizer TOF. FLEXOL Polyethylene Resin DPD-6169. BAKELITE Polyethylene Resin DYDT. BAKELITE Polyethylene Resin DYl.T. BAKELITE Polyethylene Resin DYNT. BAKELITE Polyethylene Resin DYNH-1. BaKELITE Polyol LG-I6S. NIAX Pt'lvoi l.G-Series. General. NIAX F-a.t 11; F-43114 F-4J259 F-43115 F-43590 F-45589 F-44057 F-43025 F-45201 F-43285 F-43804 F-45744 F-43006 F-43547 F-43066 F-43007 F-43302 F-43922 F-43134 F-44743 F-43921 F-43569 F-43328 F-44077 F-43816 F-43957 F-44154 F-45883 F-44436 F-43325 F-43245 F-43326 F-43327 F-43268 F-43267 F-43I6I F-43276 F-4413I F-43919 F-43903 F-43362 F-4336I F-43602 F-43815 F-43603 F-43853 F-43906 F-43938 F-43646 F-45962 F-45890 F-43794 F-43980 Material Form Number Poljoi LHT-67. MAX Polyol I.HT-Series. General. NIAX Polyoi PCP-0200 Scries: NIAX Polyol PCP-0800 Series. NIAX Polyol PPG-425. NIAX Polyoi PPG-1025. MAX Polyoi PPG-1225. NIAX Poiyol PPG-2025. NIAX Polyoi PPG-3025. NIAX POi-YOX Water-Soluble Resin WSR N-750 Primary Amy! Acetate Primary Amyl Alcohol n-Prupunol PROPASOL Solvent B PROPASOL Solvent DM (UCAR2LM) PROPASOL Solvent M (UCAR LM) PROPASOL Solvent P Propylene Glycol Propylene Glycol. Industrial Grade Siianc A-I5I Sdane A-172 Silane A-174 Silane A-186 Silane A-187 Silane A-189 Siianc A-l 100 Sitane A-l 120 Silicone Antifoam. SAG-47 Silicone Amiioam. SAG-470 Silicone Copolymer L-77 Silicone Copolymer L-7001 Silicone Emulsion LEMS Silicone Fluid L-45 Surfactant XD. TERGITOL Nonionic Surfactant XH. TERGITOL Nonionic Surfactant I5-S-9. TERGITOL Nonionic SYNASOL Solvent. Anhydrous. PM 509 SYNASOL Solvent. PM 3224 SYNASOL Solvent 190. PM 41 (Government Formulation 4*1) Tricthyleoctet raminc Vinyl Acetate. Inhibited Vinyl Acetate Resins. General. BAKELITE Vinyl Butyral Resin XYHL. BAKELITE Vinyl Resin VAGD. BAKELITE Vinyl Resin VAGH. BAKELITE Vinyl Resin VERR. BAKELITE Vinyl Resin VMCA. BAKELITE Vinyl Resin VMCC. BAKELITE Vinyl Resin VMCH. BAKELITE Vinyl Resin VYHD. BAKELiTE Vinyl Resin VYHH. 8AKEL1TE Vinyl Resin VYLF. BAKELITE Vinyl Resin VYNC. BAKELITE Vinyl Resin VYNS. BAKELiTE Vinyl Resin VYNW. BAKELITE Vinvl Resin Coaling Solution VYDS. BAKELITE F-43878 F-43999 F-43998 F-43997 F-44003 F-43726 F-4401 1 F-43795 F-44010 F-43743 F-43072 F-432S8 F-43204 F-43544 F-43206 F-43281 F-43545 F-43067 F-43255 F-4493S F-43947 F-43925 F-44057 F-43936 F-4S729 F-43935 F-45727 F-43330 F-43331 F-4392S F-44185 F-43333 F-43332 F-43805 F-43806 F-43530 F-43077 F-43068 F-44205 F-43I4I F-43142 F-439i4 F-43313 F-43312 F-43156 F-43911 F-432'5 F-4315S F-43I.S- F-43:52 F-4315 i F-43153 F-44054 F-43 i 54 F-43155 F-43040 ANHYDROL. BAKELITE, CARBITOL. CARBO- WAX. CELLOSIZE, CELLOSOLVE, FLEXOL. NIAX. POLYOX, PROPASOL. SAG, SYNASOL, TERGITOL and UCAR are registered trademarks of Union Carbide Corp. Vsnu.>684 : Robert W. Wesson Vice-President and General Manager Coatings and Adhesives Materials Dept. Union Carbide Corporation It is a privilege for Union Carbide to cooperate with Ad hesives Age in publishing this OSHA checklist. OSHA has come a long wav in a short time. The OSHA stan dards are now very sophisticated. But in their very sophistica tion lies a serious paradox -- the difficulty of unraveling all the new regulations, and then following them. We at Union Carbide hope the accompanying checklist, sum marizing the OSHA regulations, will be of value to harried adhesives manufacturing people. The checklist provides a way to follow OSHA standards, and that is important because the standards have become extremely comprehensive and we are all obliged to follow them. Of course, regulations alone don't make a safe plant. Effec tive safety programs are needed to ensure that accidents in the workplace are held to a minimum. Employees at every level must be conscious of good safety practice. Union Carbide has long had many committees and groups, at various levels, working in the health and safety area. Recently. Union Carbide estab lished a new corporate department called the Health. Safety and Environmental Affairs Department. The new department will develop an advanced corporate epidemiological program, computerize industrial hygiene and health records, monitor the worldwide environmental impact analysis system, ensure adherence to medical standards, and de velop new corporate systems dealing with product safety. Data generated by this department will be made available to our dis tributors and customers, and to anyone in the adhesives industry who might benefit from it. Union Carbide's emphasis on safety has paid off in the past. For example, the number of our disabling injuries is now less than one-quarter the industrial average. Our Chemicals & Plastics group rating -- which includes the Coatings and Ad hesives Materials Department -- is actually six times better than the average. Sound safety practices and good business go hand in hand. And like other companies, we take many approaches to attack safety problems. I f someone has a better way to protect people -- whether it is OSHA. a competitor or an employee -- we will incorporate the improvement into our operations. We at Union Carbide seek out every opportunity to cooperate with government and industry so that we can all be safer. 1 recently gave a talk entitled "Beyond Safety Regulations." in which I pointed out how we worked closely with OSHA in providing safety information. I thought you might like to read some of the highlights:- they are reproduced on the following pages. 684 Beyond Safety Regulations BY ROBERT W. WESSON I hough many company records, including Union Carbide's, show that employees are safer at work than at home, as long as lives and limbs are being lost in the plant, industry cannot rest on its excellent safety records or regulations. At Union Carbide, improving safety is a goal that everyone is constantly striving to achieve. UNION CARBIDE DISABLING INJURY EXPERIENCE Disabling Injury Frequency Rate 1. -I____i____ i ...... i____ i____ i____i____ i____l___ j____ I__ .' 190 1964 1965 1966.196/ 1963 1969 1970 1971 1972 1973 1974 1975 are rated for their toxicological properties. Much of this work is done at the CarnegieMellon Institute of Research in Pittsburgh. Penna. Union Carbide has long benefited from the services of this toxicology research laboratory, it was nearly 40 years ago that Union Carbide established its Chemical Hygiene Fellowship at the Mellon Institute. This was a full year before the enactment of the Food. Drug and Cosmetic Act. which required testing of food additives and other products that might be harmful. 4,000 Compounds Tested During the ensuing four decades, the Fellowship has grown from a two-man opera tion to a staff of over 35. To date, over 4.000 compounds have been assayed to delineate It is a way of life that begins with upper man agement. In addition to a corporate safety department and its committees, each division or operating unit of the Corporation has a safe ty and health organization devoted to its own particular needs. The Chemicals & Plastics people organized a group known as SHARE, which falls under the direction of a vicepresident. The name is derived from safety, health and affairs related to the environment. SHARE further ensures that Union Carbide's Chemicals & Plastics operations meet ail aspects of the Federal Occupational Safety and Health Act. Union Carbide is extremely cautious with newly developed chemicals and resins. Before manufacture or use in plants, new substances their toxicological properties. Each chemical is examined to answer the following: Under what conditions can the compound be manufactured without injury to plant per sonnel? Can it be shipped without special han- 66-11 jling procedures? It' not. -Aha: procedure must be employed? And. under whin i ii'.atmue. can '< :v list'd safely h\ ;he wbik Safety programs for the industry .at large are. ot course. as vita! as the Corporation's interna! programs. For example, results of the work Jotte at Ccrnegio-Melion by the Chemical Hygiene Fellowship are made available to the scientific community through publication and sharing of information. Product literature rou tinely includes precautionary labeling informa tion. toxicological properties. FDA and EPA status where applicable, and special handling procedures when necessary. Development of MSD Sheets Another advance of which I'nion Carbide is proud is the development of its Material Safety Data (MSD) Program -- perhaps the largest single endeavor undertaken to provide our cus tomers and our customers' customers with per tinent safety data. In ! 970. the Department of Labor mandated that MSD sheets be issued on all hazardous products sold to the ship repairing, ship building and shipbreaking industries (the socalled 3-S industries). These sheets were to be retained at the job site by those using the prod ucts. While safety data have always been published on Union Carbide's products, these new requirements were more detailed and were specific to these three industries. Beyond Government Programs The first Department of Labor MSD regula tion came out on July I. 1970. Union Carbide meanwhile had outdistanced the government program both in time and in scope. By that time, the company had already devised its own modified MSD sheets -- actually more comprehensive than required -- which the Department of Labor approved on June 20. 1970. Union Carbide's first MSD sheet was issued a few months later. Since that time, over 600 sheets have been issued covering an enor mous variety of products going into many dif ferent industries. Eventually, an MSD sheet will be issued on every product produced -- even on those not officially considered hazard ous. This program is much too valuable to limit its use to the legal requirements of the man date. When a request is made for a new1 MSD sheet by customers, distributors or internally, a team o: experts, from chemists to lawyers, col laborates on developing a sheet that is as clear and heipfui as possible. These sheets are so carefully done -- so comprehensive and clear -- that many other companies, and even OSHA. use them as models. To gather the physical data. Union Carbide's labs do extensive testing in areas such as haz ardous ingredients, fire and explosion, health, reactivity, spill or leak procedures. Special pro tection and special precautions. As a result, much more is included in the data sheets than is required by current OSHA regulations. On each data sheet a list of phone numbers is in cluded so that Union Carbide safety experts can provide assistance at any time, day or night. Not only is a major effort made to prepare the sheets, but also to have them widely distrib uted and used. Customers are encouraged, via direct contact, newsletters, seminars, etc., to ask for the sheets. They can be obtained either through Union Carbide's sales force or distrib utors. Special binders are provided for conve nient filing and efficient retrieval of informa tion. A comprehensive index, which lists ail sheets issued to dale, is also provided tor ready refer ence. Holders of MSD binders automatically receive an updated index as soon as it is issued. And. of course, all MSD sheets are systemat ically reviewed for updating and/or revisions. The MSD Program is only one of many recent efforts to make industry safer. Union Carbide is dedicated to the continued up grading of all safety programs. Our lives depend on it. jc<r\/c? 6 G 4 -1 adhesives ane DECEMBER 1976 re L*m:ts ~S..M' 5 15 0.4 1.5 0.1 0.001 10 5 0.2 0.* 0.01 0 05 2 0.5 -50 0.15 13 00 1 6 0.25 20 10 5 0.2 0.1 02 0.05 9 4.170 4.170 35 ' 2 0.075 :->C 0.07 3 S 1.5 0.1 5 2 22 5 Substance Exposure Limits p.p.m." mg./M1' Uranium (soluble compounds) Uranium (insoluDte compounds) C Vanadium: V-Oi dust ... V-Oj fume ........................ * ** Si?*; 5:.*Ar? Vinylcyanide. see Acrylonitrile Vinyl toluene .......................... Warfarin...................................... Xylene (xylol).................... : c -- S\ r Yttrium ........................... Zinc chloride fume . Z ;'C 28 Zirconium compounds (as Zr1 __ -- -- -- -- -- 100 100 5 -- -- 0.05 0.25 0.5 0.1 -- ---' 460 0.1 435 25 1 1 5 5 "Parts of vapor or gas per million parts of contammated air Dy volume at 25 C. and 760 mm. Hg pressure. 'Approximate milligrams of particulate per cubic meter of air. Nc footnote "c" is used to avoid ccnfuston with the `C" that precedes some materials lo indicate ceiling value notations.) "An atmospheric concentration of not more than 0.02 p.p.m.. or personal protection may be necessary to avoid headache. 'As sampled by method that does not collect vapor. Vor control of general room air. biologic monitoring is essential for personnel control. Other Materials Individual standards have been issued for the fol lowing; consult referenced sections for details: MaterialReference Asoesfos. Coal tar silcn vcia'i'es: inlerc-elaho-- of term. 4-Nitrobiphenyl. alpha-Naphihylamine. Methyl chloromethyl ether 3.3'-Oichlorobenzfne (and its salts) bis-Chloromethyl ether. beta-Naphthylamine. Benzidine. 4-Aminodiphenyl. Ethyleneimine. beta-Propiolactone. 2-Acetyiaminofiuorene. 4-0i methylammoazobenzine. N-Niirosodimethylamine. Vinyl chloride. :3'-0.:3Q". gt.j .'002 191o!l003 1910.1004 1910.1006 1910.1007 1910.1008 1910 1009 1910.1010 1910.1011 1910.1012 1910.1013 1910.1014 1910.1015 1910 1015 1910.1017 Substance Mineral Dusts Mppcf" Mg/M': Silica: Crystalline: Quartz (respirable)___ Quartz (total dust) .. .. Cnstobalite: Use Vi the vafue calculated from the count or mass for mulae for quartz. Tridymite: Use vi ihe value calculated from the for mulae for quartz. Amorphous, including nat ural diatomaceous earth 250' %SiC- + 5 -- lOrng/M"'' % SiO- r 2 30mg/M' %S;0. -r2 20 SOmg/M' %SiO. Silicates (less than 1% crys talline silica): Mica ................................. Soapstone ......................... Talc (non-asbestos-form) Talc (fibrous). Use asbes tos limit......................... Tremolite (see lafc, fibrous) Portland cement............... Graphite (natural)................. Coal dust (respirable fraction less than 5% SiOJ ... . For more than 5% SiO* . .. Inert or Nuisance Oust: Respirable fraction......... Total dust ......................... 20 20 20" 50 IS -- ZAmg/M* or --* 10 mg/M" %SiO- + 2 15 5mg/M3 50 iSmg/M* Note: Conversion factors -- mppcfx35.3=million particles per cubic meter =particles per c.c. 'Millions of particles per cubic foot of air. based on impinger samples counted by light-field technics. iYhe percentage of crystalline silica in the formula is the amount determined from air-borne samples, ex cept in those instances in which other methods have been shown to be applicable. "Both concentration and percent quarts for the application of this limit are to be determined from the fraction passing a size-selector with the following characteristics: "Containing <1% quartz; if >1% quartz, use quartz limit. 8 Hour Time Weighted Averages and Acceptable Ceiling Concentrations Acceptable maximum peak above the acceptable ceiling concentra tion for an 8-hour shift. 664^ Exposure Limits p.D.rn.'4 mg./M:`* nde. see t.lne me -- Skin methane .... m .... :poxy-l -propanol) iyt ether, see mol . a Azinphosmethyl Skin ane -- Skin htnalene -- Skin -.1 '. tate Skm .. mde . .. -ifonde . x ude -- Skin x*de (90%) ride . -- 20 -- __ -- 0.1 1.000 5 5 3w so -- -- -- -- 5C0 -- 100 wl< 50 3 5 10 0.05 0.1 ne -- - --- 94 15 1 2.5 0.2 5.600 9 20 20C 150 -- -- 0.5 0.5 2.5CO 10 0.2 : SCO 410 -0 300 1.3 10 7 11 1.4 0.2 2 1 10 v.~ * sc * ~ ~ " e .. ... J. :'*} -S1 3 <m de ... d petroleum :a Skin . . . . Ir see Memyl i*50 V*i:~y ne (propyne) me-propadiene APP) ethoxymethane) . ICC 5 500 50 0.5 -- -- -- 1.000 -- -- C-*3 -- -7 -- -- " 1.000 1.000 * 1.000 :0U 300 10 950 930 12 2.100 2-0 *0.9 0.15 0.5 0.025 l.SOO 3 15 5 - 15 70 1.650 l.SOO 3- 3.100 icohoi. see utyl carbmot I) kelone (2- 10 12 ---- 100 465 Substance Exposure Limits p.p m.*4 mg./M`* Methyl isobetyl sarbinol -- Skin Ver^yJ s.;cuV ketone see Lfexo*"* Methyl isocyanate -- Skin .. C Methyl mercaptan . ...... Methyl "vjtr'acrv-dte Methyl propyl ketone, see 2- Pentanone............................... Cor Methyl styrene C Me^y'ene r-syneny sccyarate -VS:' Molybdenum: Soluble compounds Insoluble compounds ... Monomethyl aniline -- Skin C: *ydfSZ'^e -- Sx.r* Morpno,ne -- Sk*n Naphthalene............................... Nickel carbonyl ........................ Nickel, metal and soluble cmpds. as Ni......................... Nicotine -- Skin....................... Nitric acid................................. Nitric oxide ............................... p-Nitroanilir.e -- Skin.............. Nitrobenzene -- Skin.............. p-Nitrochlorobenzene -- Skin . Nitrogen dioxide....................... Nitrogen tnfluonde Nitroglycerin -- Skin . Nitromethane ............................. s-Nitrpsrooane i-N-t.-corosane Nitrototuene -- Skin . ... Nitrotrichtoromethane. see Chloropicnn ........................... OcUchloronaphmatene -- Skin Ociane Oil mist, mineral ................... Osmium tetroxide Oxalic acid............................. Oxygen difluoride ... Ozone.................... Paraquet -- Skin Parathion -- Skin .............. Pentaborane.............................. Pentachloronaphthatene -- Skin Pentachlorophenol -- Skin en?a*e 2-Pentanone............................. Perchloromethyl mercaptan Perchioryl fluoride..................... etro.e^m nates MS'-V'V 3her.o -- 5k n p-Phenyiene diamine Skin Phenyl ether (vapor) Phenyl ether-biphenyl mixture (vapor)..................... Phenylethylene. see Styrene . Phenyl glyeidy! ether (PGE) Phenylhydrazine -- Skin Phosdrin (Mevinpnos*) -- Skin Phosgene (carbonyl chloride) Phosphine .... .... Phosphoric acid . ... Phosphorus (yellow) .. Phosphorus pentachionde Phosphorus oentasutfide PKfwtrhnm% pmninrirtA 25 -- 0.02 10 :0C -- too J ,`2 -- -- 2 02 20 100 10 0.001 -- 2 25 1 1 -- 100 5 10 0.2 100 '5 rs 5 -- 500 -- -- -- 0.05 0.1 ---- 0.005 -- -- COO 200 0.1 3 SCO 5 -- 1 1 -- 10 5 -- 0.1 0.3 -- -- -- -- 0.5 100 -- 0.05 20 -- 430 02 5 15 9 2 35 ."C 400 so 0.007 1 0.5 5 30 6 s 1 310 9 29 2 250 90 90 30 -- 0.1 2.350 5 0.002 1 0.1 0.2 0.5 0.11 0.01 0.5 0.5 2 553 700 0.6 13.5 > *T, 3 0.1 7 7 -- 60 22 0.1 0.4 0.4 1 0.1 1 1 3 Substance Exoo PP-t Propyne. see Methylacetyiene Pyrathrum.................... _ -- Pyridine .................................... Quinona.................................... 5 0.1 POX -- Skin Rhodium. Metal fume and dusts, as Rh............................ Soluole salts ` Ronnef...................................... Rotenone (commercial) Selenium compounds (as $e) __ -- -- -- Selenium hexafluoride............ Silver, metal and soluble compounds . ..................... 0 0* -- Sodium fluoroacelale (1080) -- Skin .............................. -- Sodium hydroxide ............ -- 0.1 Stocdar-s sotven: Strychnine................ -- Sulfur dioxide ... 5 Sulfur nexafluoride ... Sulfuric acid.............. Sulfur monochloride ... 1.000 -- 1 Sulfur pontafluoride .... o.o: Sulfuryi fluoride...................... Systox. see Demeton* 2.4.5T ... 5 -- -- __ reop -- skm .... Tellurium .. . .......... . -- -- Tellurium hexafluoride ... . TEPP -- Skin...................... C Terphenyis.......................... O.C -- 1.1.1,2-Tetrchloro-2.2-difluoro- ethane.................................. 1.1,2.2-Tetrachloro-1,2-difluoro- 500 ethane .......................... .... 1.1,2.2-Tetraehloroethane -- 500 Skin................................ 5 Tetrachioroethylene. see Per* chloroethylene ............ -- Tatrachloromethane. see Carbon tetrachloride Tetrachloronaphthalene -- Skm Tetraethyl lead (as Pb) -- Skm -- -- -- Tetramethyl feed (as Pb) -- Skm.............................. Tetramethyl sueeinonitnle -- Skin.............. ... ... . Tetranitromethane Tetryl (2.4.6-lrinitrophenyl- methylnitramine) -- Skm Thallium (soluble compounds* -- Skin as T1 .............. Thiram............................ Tin (inorganic cmpds. except oxides)........................ 5*330,3 Cf.DdS; 2 ro:uene-2 z.-r-jocyaraic oToluidine -- Skin ... ,, Toxaphene. see Chlorinated camphene.............. Tributyl phosphate . ... . ;<* -- OS ' -- -- -- -- 5 -- --\ 2 ;.-ce:hir.> :- O oc: -i; < * td- i-o . i-i Trichloromethane, see Chloroform -- DECEMBER 1976 AIR CONTAMINANTS Reference: 1910.1000, OSHA General Industry Standards. Items that apply most directly to the adhesives in dustry appear in red. Exposure Limits Substance p.p.m." mg./M'' ` Acetaldehyde .............. 200 Acecc 3c-d `0 Acetic anhydride .................. 5 Acetone * .occ Acetonitrile.............................. .. 40 Acetylene dichloride. see 1. 2-Dichloroethylene................ -- Acetylene tetrabromide .. .. 1 Acrolein ..................................... 0.1 Acrylamide -- Skin................ -- Acrylonitrile -- Skin................ 20 Aldrin -- Skin......................... -- AJIyJ alcohol -- Skin................ 2 Ally! chloride ............................. 1 C Allyl giycidyl ether (AGE) 10 AKyl propyl disulfide................ 2 2'Aminoetnanoi. see Etharo'amme -- 2-Ammopyndine......................... 05 Ammonia 50 Ammonium surfamate .'Ammatei -- 'Amyl acetate too sec-Amyt acetate ...................... 125 Aniline -- Skin ......................... 5 Amsidine (o. p-isomens) -- Skin -- Ammony and compounds :'as So) . . --* ANTU (alpha naphthyl thiourea) -- Arsenic and compounds (as As) -- Arsine ......................................... 0.05 Azinphoe-methyl -- Skin.......... -- Barium (soluble compounds) .. -- o-Senroquinone. See Quinone -- Benzoyl peroxide ... ---- Benzyl chloride ......................... 1' Biphenyl, see Diphenyl............ Bisphenoi A, see Oigfycidyl ether .... .... -- Boron oxide ............................... -- C Boron trifluoride.................... 1 Bromine....................................... 0.1 8romoform -- Skin..................... 0.5 Butadiene (1.3'txitadiane} Buttnethiof, see 8utyl l.OOG mercaptan ............................... -- 2-Butanone . , . 290 2-Butoxy ethanol (Butyl Ceitosoive) -- Skin . 50 Butyl acetate (n-butyi acetate) :50 seo-Bulyt acetate 200 tert-Butyl acetate 200 8utyl alcohol too sec-Sutyl alconof -.50 tert-Butyl alcohol .. too C Bulylamino -- Skin............... C tert-Butyl chromate (as 5 CtOj) -- Skin ....................... -- :*-3utyt gjyctdyl ethet IBGE'Butyl mercaptan ....................... 50 10 p-tert-Butyltoluene ..................... Calcium arsenate....................... Celcium oxide............................. 10 -- -- Camphor ................................. 2 Carbaryl (Sevin*)..................... 360 25 20 2 -00 70 -- 14 0.25 0.3 45 0.25 5 3 45 12 -- 2 35 '5 535 650 19 0.5 05 0.3 0.5 0.2 0.2 0.5 -- 5 5 -- 15 3 0.7 5 2.200 -- 590 240 71C 950 950 300 450 300 15 0.1 35 60 1 5 -- 5 > S Exposure Limits o.p.m." mg/M1'1 Substance Crotonaldehyde ......................... 2 Cumene -- SKm .................... 50 Cyanide (as CN) -- Skin ... . --- Cycior.exan* 300 Cycichexa-oi 5G Cycionexa"one 50 Cycloflexene ....................... 300 Cyclopentadiene ..................... 75 2. 4-0........................................... DOT -- Skin ................... DDVP, see Dicntorvos ... Oecaborane -- Skin................... 0.05 Demeton' -- Skin................. -- 0=acetcne a ccnoi vt-nyircxy- 4-methy'-2-oenta',or'e) 50 1.2-diamihoethane. see Ethylenediamine..................... Diazomethane ....................... 0.2 Oiborane ..................................... 0.1 Dibutyip/itna-are -- C o-Diehlorobenzene................. 50 p-Oicmorobenzene C'C'iiorodi'iuo.'O'T'ett'ane ?5 ; C00 t.3-Oichloro-5. 5-dimethyl hydantoin ............................. __ 1.1-Dichloroetnane................... 100 1.2-Oichloroethyiene ................. 200 C Dichloroethyl ether -- Skin . 15 Oiehloromethane. see Methylenedtloride ___ ... . Oichloromonofluotomethane . . 1.000 C-l.t-Oiehioro-t-nitroottiane ... 10 t,2-0ichloropropano. see Propylenediehlortde.............. Oichlorotetrafluoroethane ........ 1.000 Oichlorvos (DOVP) -- Skin___ -- Oieldrin -- Skin......................... -- Oiethytamine............................... 25 Qiethylamino ethanol -- Skin .. 10 Oiethylether, see Ethyl ether .. Oitluorodibromomethane.......... 100 C DigiyCidy! e!~er .DSE) 05 Dihydroxybenzene, see Hydroqumone ......................... Diisobutyl ketone....................... 50 Diisopropylamine -- Skin .. .. 5 Oiroethoxymetnane, see Mathyial................................... Dimethyl acetamide -- Skin ... Dimsthylamine ......................... 10 10 Dimethytaminobenzene, see Xylidene................................... Dimethyianiline(N-dimethyl- aniline) -- Skin..................... 5 D'methyibeniere. see Xylene Dimethyl 1,2-dibromo-2,2-di- chloroethyl phosphate. (Oibrom) ................................. D-metnyiforr.amice -- 3<:n 2.6-Dimethylheptanone. see Diisobutyl ketone............. 1.1-Dimethylhydrazine -- Skin . Oimsthylphthalate ..................... 0.5 Dimethylsultate -- Skin............. Dinitrobenzene (all isomers) -- Skin ......................................... Dinitro-o-cresol -- Skin............. Oinitrototuene -- Skin............. C cva.-e .C etnyie-e CiCx'de.. -- Skin Oiohenyf ..................................... ."i.r.p AA/'i^air' ar*.A ii"t-i.*ti 0.2 6 245 5 ' 050 200 290 1.015 200 to t 0.3 O.t 240 0.4 0.1 5 300 450 4 350 0.2 400 790 90 4,200 60 7.000 1 0.25 75 50 860 23 290 20 35 18 25 3 30 0.2 Ethylidine cr Dichloroei N-Ethylmotp Ferbam .. Ferrovanadii Fluoride (?s Fluorine . Fluorotrichlc Formic acid Furfural ~ Furfury 3'Ci Glycidol (2. Glycol mono 2-Ethoxye Guthionv Hafnium .. Heptaehior Heptane Hexachloror Haxachlotor herane 2-Hexanone Hex ;-e v sec-Hexyl 3 Hydrazine Hydrogen b C Hydrogen Hydrogen q Hydrogen pe Hydrogen si Hydroquinoi C Iodine Iron oxide l seamy :.: .saa.-ny- i.c = 500 ,,T/ ic !SCC'tC/ Isopropylair Isopropylati- Keiene .. Lead arsen Lindane -- Lithium hyc L.P.G. (liqui gas Vag-ex . Mafathion - V,l:l `. 3-' C Mangane v.es::.1 Metnanethii mercapta Mathoxych: Methyl acet Methyl acet mixture ( v**.'*. . Methyial (0 y Methylamm ' .rlM^Oyi amy ) * weihyl *s* Methyl (o-n Heptanof 300 7.600 5.100 -- -- 560 :e 9 >y ie f Material 3-hour time weighted average Acceptable ceding concentration Benzene (Z37 4-19691 .... BeiyUium and beryllium comoounds (Z37.29-I970) .. Cadmium fume (Z37 5-1970) Cadmium dust (Z37.5-1970) Carbon disulfide (Z37 3-1968! Q S p m 2 ag..M'; 0.: mg :M` 0 2 mg..'M: 20 p.p m Chromic acid and chromates (Z37.7-1971) Elhylene diOromide (Z37.31-1970) - *. * -j Ffuor.-de as dust (Z37 28-1969) . -- 20 p.p.m s.' - z 2.S mg./M' Hydrogen fluor'de (237.28-1969) Hydrogen sulfide (237.2-1966) ( . do 25 p.p.m 5 ug.-M * 3 mg. M 0 6 mg /M 30 p.p m do 30 b p.m ' . ' 7 " -- 20 p.o.m Concentration Maximum duration 50 p p.m 25 iig.iM'' -- -- >00 p.p.m -- 50 p.p.m 2 r. " -- 50 p.p.m 10 minutes. 30 minutes. Do. z *-*e> ~ 3Tv .J ' J../S 5 minutes. a-. J1- -- A 10 minutes once only if no other measur able exposure occurs. Mercury (237.8-1971) .......................... Methyl chloride (237.18-1969) ... % 1"-/ 23" 3*' 359: Organo (alkyl) mercury (Z37.30-1969) 5 ,.'!*) 22* *5-' 365' Totraailoroethylene (237.22-1967) . . ' I'ti-C/rJ-e ;227 * 3-* 96') -- 100 P.p.m 1 mg.,10M3 200p.pm 0.01 0.CM mg.'M' do do 300 p.p.m 5 minutes >n any 3 hours. ' ay 3"- xrs. PuU p p :oo 5 a iry 3 5 minutes in any 3 hours. *0 5 'TSlCvTiS ** 2,nv 2 "O'-.'S. J E PROTECTION ed Reference re Extinguishers 1910.157 and Hose Systems 1910.158 Sprinkler Systems 1910.159 Chemical shing Systems 1910.160 oxide Extinguishing 1910.161 Alarm Signaling 1910.163 L ENVIRONMENTAL CONTROLS ELECTRICAL REQUIREMENTS Reference: 1910.309 (a) The requirements contained in the follow ing articles and sections of the National Electrical Code, NFPA No. 70-1971; ANSI C11971 (Rev. of C1-1968} shall apply to all electrical installations and utilization equipment: Articles: 500 Hazardous Locations. 501 Class I Installations (Hazardous Locations). 502 Class It Installations (Hazardous Locations). 503 Ctass til Installations (Hazardous Locations). Sections: 250-58 (a)-(b). Equipment on Structural Metal. 250-59 (a), (b), Portable and/or Cord Connected and and (c). Plug Connected Equipment, Grounding Method. 400-3 (aHb). Flexible Cords and Cable. Uses. 400-4 Flexible Cords and Cable Prohibited. 400-5 Flexible Cords and Cables. Splices. 400-9 Overcurrent Protection and Ampacities of Flexible Cords. 410-10 Pull at Joints and Terminals of Flexible Cords and Cables. 422-5 Installation, Appliances w/Ftexible Cords. 422-9 installation, Portable Immersion Heaters. 422-10 Installation, Appliances Adjacent to Com 422-11 bustible Material. k'VytriA C(? / f) Stands for Portable Appliances. DD4>` 422-12 Signals for Heated Appliances. 422-14 Water Heaters. 422-15 (a), (b). Installation of Infrared Lamp and Indus- itono. see 2* OKs -- Skirt owe acetate -- iorr. xane xanoi loxanon -- Skin W4 e -- Ski/* -- 25 25 350 500 too too too 5 *-- 30 120 t .900 2.000 70 460 ... 250 28 picric add -- Skin Rival' '2-P:vatyi-l.3. indandione) Platinum (Soluble Salts) as Pi .... Propargyl aicohoi -- Skin Propane j *!~1 n-Propyl nitrate Propylene dictiionde propylene smine -- Skin Propylene oxide -- -- --- * t.oco 25 75 2 00 ^ o: 0 002 -- 1.30C =:: no iso 5 240 1.2.3-TncMoroprooane 1.i.2*7richloro 1.2.2-trirtuoro eman ... Triettiylamme .................... TrifluoromonoDromomethane 2.4.6-Tnnitfophenol. see Picric 3Cld.......................... 2.4.5-Tnmtrophenylmetttylnitramine. see Tetryl . . . Trinitrotoluene -- Skin . ^ V~ ;** ir, ; Turpentine.............................. so 1.000 25 1.000 -- _ _ 100 HowTo UseThis Checklist j various sections within this chart represent as designated under the Occupational Safety t Health Act as crucial to the safe operation of ir plant. To see how your plant measures up to HA standards, evaluate conditions in each of areas that appear on this checklist. The reences indicate the sections of the Act that >ly. This checklist does not represent the comte scope of the Act. For specific situations not covered here, a thorough study of the compit OSHA Standards is recommended. An ongoi subscription to the OSHA General industry St; dards and Interpretations and ail changes as tig are enacted can be obtained for $21.00 from I Occupational Safety and Health Subscription Sei vice, care of the Superintendent of Documen U.S. Government Printing Office, Washingtc D.C. 20402. JTIVE Reference 1910.133 1910.134 1910.135 on 1910.136 3S 1910.137 ss Reference 1910.36 HAZARDOUS MATERIALS Material Reference 0 Compressed Gas 1910.101 0 Acetylene 1910.102 0 Hydrogen 1910.103 0 Oxygen 1910.104 0 Nitrous Oxide 1910.105 0 Flammable and Combustible Liquids 1910.106 0 Spray Finishing Using Flammable and Combustible Liquids 1910.107 0 Dip Tanks Containing Flammable or Combustible Liquids 1910.108 Q Explosives and Blasting Agents 1910.109 FIH To BeChec 0 Portable? 0 Standpipe 0 Automatic 0 Fixed Dry Extingu 0 CaSrybsotenmDs 0 LoScaysl tFeimre Carbon monoxide .................. Chlordane -- Skin.................... Chlorinated camphane -- Skin , Chlorinated diphenyl oxida ... Chlorine ................................ C Chlorine iritluoride................ C Chloroacetaldehyde.............. ar-Chlofoacetophenone (pnenaeyichtoride).............. 50 *-- -- --- 1 0.1 0.1 C.0S 55 0.5 0.5 0.5 3 0.3 0.4 3 0.3 oer.zenel o-Chlorobenzylidene malononitrile (OC8M) .. Chiorobromomathane .............. 2-Chforo-l .3-butadiene, see Chloroprene .......................... Chlorodiphenyl (42 percent Chlorine) -- Skin................ .. Chlorodiphenyl {54 percent Chlorine) -- Skin.................. I Z i-ecoKfO'caane. see 2-Chloroethanol. see Ethylene chlorohydrin .................... Chtoroethylene. see Vinyl chloride .................................. C Chloroform (trichloromethane) 1-Chloro-1-nitropropane .......... Chloropierin .............................. Chloroprene (2-cnloro-1.3- butadiene) -- Skin................ Chromium, sd. chromic, chromous salts as Cr............ Metal and insol. salts.......... Coal tar pitcn volatiles (benzene soluble traction) anthracene. 3aP. pnenanthrane, acndina. cnrysene, py'ene .. . >. . Cobalt, metal fume and dust ... Copper (ume ............................. Ousts end Mitts.................... Cotton dust (raw)...................... Crag* herbicide........................ Cresol (all isomers) -- Skin ... 0.05 200 **-- -- -- -- -- 50 20 0.1 25 -- -- -- ---- -- 5 '2v 0.4 1,050 -- 1 0.5 -- -- -- 240 100 0.7 90 0.5 1 0.2 O.t 0.1 1 1 15 22 cyd'*a:e VC Dipropylene glycol methyl ether -- Skin................. Oi-sec, octyl phthalate (Oi-2- ethylhexytphthalato) ... _ 100 _--__ Epichlorftydrin -- Skin ... ... EPN -- Skin ........................... 5 -- 1.2-Epoxypropane, see Propyleneoxide .................. -- 2.3-Eooxy-1-propanol, see Glycidol.................................. -- Elhanethiol. see Elhylmercaptan -- 3 2-Sthoxyethanol -- Skin .... 200 2-s-r'c<-/i!.-risce,.a:e .'Cei-o- $c ve aceta-ie- -- 5k.r co E:nvi 400 S:.Hy. ic.*v3:e -- S< n 25 aicbnoi sl-s-ci: i.oco Ethyiemme...................... .. 10 Ethyl sec-amyl ketone (5- methyI-3*heptanone> ............ 25 Ethyl benzene .......................... 100 Ethyl bromide............................ 200 Ethyl butyl ketone (3- Heptanone)............................ 50 Ethyl chloride............................ 1.000 Ethyl ather ... ......................... 400 Ethyl formate ............................ C Ethyl mercaptan.................... 100 10 Ethyl silicate ............................ too Ethylene chlorohydrin -- Skin . 5 Ethylenediamine........................ 10 Ethylene dibromide, see 1.2- Dibromoethane ....................... ` --. Sthyrene dichic.-*oe, sea :.2Dichloroethar-e -- C Ethylene glycol dinitrate and/or Nitroglycerin -- Skin 40.2 Ethylene jiyczi .^e^omethyi einer acetate, sea .Memvi Cetloscive acetate -- Ethylene irmne --* Skin Ethylene oxide 0.5 50 600 s 01 19 0.5 -- -- 6 740 * iM * Jc iOC 18 130 435 390 230 2.600 1,200 300 25 850 16 25 -- -- 1 sC Methyl pyj. Hexanon Methyl Ca Mathyl Ce Sktn Meihyl cm Methylcyc'i Methyfcycii o-M$thylcy t .., . - , Methyl Ion Methyl <odi 7 a a y c t. f 3 F walking--Working surfaces PERSONAL PR OTI EQUIPMEN' To Be Checked Q Eye and Face Protection l~] Respiratory Protection 0 Occupational Head Protection 0 Occupational Foot Protei 0 Electrical Protective Devi ........... ..&P.66 SB5 I MEANS OF EGR General Requirements ;d Reference Carriage Disposal 1910.141 1910.143 Physical Hazards 1910.144 `evention Signs 1910.145 AL SERVICES AND FIRST AID i shall ensure the ready availability net for advice and consultation on taith. of an infirmary, clinic, or hospital in he workplace which is used for the jured employees, a person or perquatefy trained to render first aid. pproved by the consulting physician ailabia. or body of any person may be ous corrosive materials, suitable drenching or flushing oftheeyes and -ovided within the work area for sncy use. 110-17 (a)-(c). Guarding Live Part. 110-18 Arcing Parts. 110-21 Marking. 110-22 Identification. 240-16 (a), (b). Location in Premises {(or Overcurrent (c), and (d). Protection Devices). 240-19 (a) and Guarding of Arcing or Suddenly Moving (b). Parts of Overcurrent Protection Devices 250-3 (a)-(b). D.C. System Grounding. 250-5 (a)-(e). A.C. Circuits & Systems To Be Grounded. 250-7 Circuits Not To Be Grounded. 250-42 (a)-(d). Fixed Equipment Grounding, General. 250-43 (a)-(i). Fixed Equipment Grounding, Specific. 250-44 (a)-e). Nonelectrical Equipment Grounding. 250-45 (a), (b). Equipment Connected by Cord and Plug, (c), and (d). Grounding. 430-142 (a)-(d). Stationary Motor, Grounding. Portable Motors, Grounding. 250-50 (a)-(b). Equipment Grounding Connections. 250-51 Effective Grounding. 250-57 (a)-(b). Fixed Equipment Method of Grounding, 422-16 Appliance Grounding, 422-17 installation of Wall-mounted Ovens and Counter-mounted Cooking Units. (b) Every new electrical installation and all new utilization equipment Installed after March 15, 1972, and every replacement, modification, or repair or rehabilitation, after March 15, 1972, of any part of any electrical installation or utilization equipment in stalled before March 15, 1972, shall be in stalled or made, and maintained, in accor dance with the Provisions of the 1971 National Electrical Code, NFPA No. 70-1971; ANSI C11971 (Rev. of Cl-1968). (c) Notwithstanding the provisions of para graphs (a) and (b) of this section, the effective date of the requirement in section 210-7 of the National Electrical Code, that all 15- and 20-ampere receptacle outlets on singlephase circuits for construction sites shall have approved ground-fault circuit protection for personnel, is postponed pending reconsid eration of the requirement Louisville (Cincinnati, Ohio Sales Office).............................. Metropolitan Area Sales Office: Hackensack. N.J. 07601......... One University Plaza ... . Minneapolis (Chicago, III. Sales Office)....................................... Moorestown. N.J. 08057............308 Harper Drive Mew York (Metropolitan Area Sales Office; Hackensack. N.J.) Philadelphia IMoorestown, N.J. Sales Office)........................... Pittsburgh (Moorestown. N.J. Safes Office) .............................. St. Louis (Chicago. IK. Sales Office) ........................................... San Francisco (Long Beach. Calif. Sales Office)......................... From Arizona. Idaho. Montana. Nevada. Oregon. Utah. Washington, or Wyoming ..................................................... Southfield. Mich. 48037 ............26500 Northwestern Hway. Enterprise-2226 ................. 201-646-1111 ..................800-621-2510 ..................609-235-6200 ................ 212-695-5054 ..................215-923-3200 ..................412-922-5700 ..................314-726-0324 ..................800-352-3789 ..................800-421-3724 ..................313-354-0800 665:? the acceptable ceiling concentra tion (or an 8-hour shift. 1910.37 cits, 1910.37 ... 1910.37 1910.37 1910.37 1910.37 s. ... ess 1910.37 : ; 1910.37 i 1910.37;;; :* .... . `5 ^^i0.37^`'; iSro?^91p.37^ V>,, 'V j I*' ' ,* rHjJO.azJ'l :;;.;i9ib.37r1 {_] Liquid Petroleum Gases Q Anhydrous Ammonia 1910.110 1910.111 OCCUPATIONAL NOISE EXPOSURE Reference: 1910.95 Permissible Noise Exposures' (Table G-16) Duration per day (hours) Sound fevei dBA slow response 8 90 6 92 4 95 3 97 2 ..................................................100 1%..................................................... 102 1 105 % ..................................................110 % or less.......... ............................ 115 ' 'When the daily noise exposure is composed of two or more periods of noise exposure of different levels, their combined effect should be considered, rather than the individual effect of each. If the sum of the following fractions: Cl/71 + C2/T2 . . . Cn/Tn exceeds unity, then, the mixed exposure should be considered to exceed the limit value. Cn indicates the total rime of exposure at a specified noise level, and Tn indicates the total time of exposure permitted at that level. Exposure to impulsive or impact noise should not exceed 140 dB peak sound pressure level. To Be Chec:* Sanitation Q Nonwater C Systems Q Marking of 0 Accident? and Tags MEDIC Reference 1910.1 (a) The employer . of medical persor matters of plant h (b) In the absence near proximity to l v treatment of'all in sons shall be ade - First aid supplies a , shall be reacfily av (c) Where the ey< exposed to injur facilities tor quick body shall be pi immediate emergt U.S. Sales Offices Atlanta. Ga. 30329 ..................... 17 Executive Park Or............................. . 404-633-6161 Baltimore (Moorestown. tM.J. Sales Office) ................................................ .301-944-8211 8oston. Mass. 02194 ...................300 First Ave., Needham Hgts.............. . 617 -444-5400 Charlotte (Atlanta. Ga. Sales Office)............................................................ . 704-364-1400 Chicago, III. 60606 ................... 120 South Riverside Plaza................... . 312-454-2000 Cincinnati. Ohio 45227 ..............West Street & Madisonville Road . 513-272-0206 Cleveland, Ohio 44114.............. 1300 Lakeside Ave.................................. .. 216-621-4200 Dallas, Texas 75207.....................2710 Stemmons freeway .................... . 214-631-0010 Detroit (Southfield, Mich. Sales Office) ....................... .313-354-0800 Houston (Dallas, Texas Sales Office).............................. . 214-631-0010 Indianapolis (Cincinnati, Ohio Sales Office) ................ Enterprise-2226 Kansas City (Chicago, III. Sales Office) .......................... .800-621-8236 Long Beach, Calif. 90802 . . . 100 Oceangate, 11 Fl. .213-435-3721 Ketono 12................................ 100 | Phosphorus pentasulfide.......... -- 465 I OK...h..n ../.kia.i'w* nr 1 I Trichloromathana. see n 1 r-w,-----<----- . MAICKIAL5 nAnuLinu anu STORAGE To B Checked " Handling Materiais-Generai 0 Indoor Generaf Storage r~' Powered Industrial Trucks Reference 1910.176 1910.177 1910.178 MACHINERY AND MACHINE GUARDING Reference General Requirements To Be Checked 0 Types of Guarding 1910.212 1910.212 0 Point of Operation Guarding 1910.212 0 Barrels, Containers, Drums 1910.212 0 Exposure of Blades 1910.212 0 Anchoring of Fixed Machinery 1910.212 10 uevnecKea 0 Exit Components 0 Protective Enclosure of 0 Width and Capacity 0 EgOrecscsuCpaanptaLcoitaydand 0 Arrangement of Exits Access to Exits Q Exterior Ways of Exit A .0 discharge from Exits Headroom ---0 . Changes in; Elevation -0.rMairitenance^.A . U* ' an* d- W 'orkma. .n*". *s:'h*T i*,pr i--0 FUrhishingsjand Decorati A0* , ':.F7T; AutomaticSDrinkldrSvsi > .s. * ` - f `v,3.*\\ - *rn^Aia'nh'and Fire Protects 7 Systems .v ....... 0 Fire Retardant Paints 0 Exit Markings . UNION CARBIDE Adhesives and Sealants Materials 270 Park Avenue New Ycr*. N.Y. 10017 PEOPLE PLANNING THE FUTURE. j C*rbryt (Savin*) . OiononyJ 3.2 Metoyi i<w Heptano Mary C. McMurrer Editor Adhesives Age 1 he Occupational Safety and Health Act has far-reaching implications for ail who engage in the manufacture of gooes or who provide commercial services. In the adhesives industry, which is but a single segment of all U.S. industrial activity, OSHA has received a great deal of attention and has been the subject of many hours of discussion and planning within individ ual companies and by industry organizations. Nevertheless, the very scope of the Act has made Us comprehension a formidable undertaking for harried manage ment in the average adhesives manufacturing company. The ev eryday concerns of business operations, the trany environmental regulations that demand compliance, and a host of hazardous material and consumer safety controls leave little of manage ment's working time for concentration on so broad and all.nclusive a subject as the safety of workers in the manufacturing environment. With these considerations in mtnd, the staff of Adhesives Age has undertaken to provide adhesives management with a working checklist of what is required to achieve compliance with the Occupational Safety and Health Act. In compiling this checklist, we have reviewed the provisions of the Act and have culled out those that most directly apply to such installa tions as may be found in the adhesives industry. The checklist in this fold-out insert is intended to spotlight the most common areas of safety concern for adhesives plants', it is not intended to be a complete digest of the entire Act. We strongly urge company management to obtain complete copies of the OSHA Standards, and to become familiar with them. Perhaps the best way is to secure a subscription to the OSHA Standards service provided by the U.S. Government Prim ing Office. Washington. D.C. '20402. At a one-time cost of S2i.0C. such a subscription furnishes a complete copy of the Act. plus all cnanges as they are enacted from time to time. The Adhesives Age OSHA compliance checklist has been referenced to provide management with a guide to the sections of the Act that apply to the areas covered. With a copy of the Standards in hand, the plant manager can tell at a glance what safety measures must be taken, and where to find the appropriate regulations. Or.e word of caution: It is impossible to anticipate every man ufacturing situation and every plant feature. Where conditions not covered by the checklist exist, a thorough search of the OSHA Standards must be carried out by plant management, in order to accurately determine specific compliance requirements. Safety in the workplace is everyone's business. We trust that this OSHA checklist will assist adhesives management in the performance of this important obligation. We at Adhesives Age welcome the participation of the Coatings and Adhesives Materials Department of Union Carbide Corporation as the sponsor of this special fold-out OSHA com pliance checklist. The long history of devotion to hig.n safety standards at Union Carbide makes it most appropriate for that company to join in this effort toward the achievement of higher safely standards for the entire adhesives industry. 65