Document MGRQmdReN7XLorqBQDNXq742L

( CHLORINATED METHANES PLANT LEAK REPAIR METHODS 1. ENGINEERING DEFINED PROCEDURES ARE FOLLOWED 2. LIST OF ACCEPTED SEALANTS CURRENTLY ON PDP-11 *** PROPOSE USING LACSDC "SAFETY" MENU *** TO AVOID DOUBLE WORK FOR ENGINEERS & CATS Reactive Chemicals November 9,1994 D0 A 037569 conftdfnttai New Superintendent Review 46 \K I TABLE 111. BEACTIVITY OF SEALANT WITH HESS CHEMICAL (SORTED BY PLANT) PUNT PROCESS CHEMICAL SEALANT REF. NO. TEST LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METH ES METHANES METHANES METH>NES METHANES rD> o jZ--n1 o x> oo MzH \1a)) I> 'si O WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CHLORINE (LIQUID) CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CP-1000 OIL SATURATED WITH HCL DIMETHYL ETHER DOWTHERM G FREON 12 HCI (15%) + METHYL CHLORIDE (65%) HO (15%) + METHYL CHLORIDE (65%) Ha, Ml, M2, M3, M4 (T-851) HCI, Ml. M2, M3, M4 (T-851) Ha,M1,M2,M3,M4 (K-350 SUCTION) HYDROGEN CHLORIDE HYDROGEN CHLORIDE HYDROGEN CHLORIDE HYDROGEN CHLORIDE HYDROGEN CHLORIDE SERVICE GROUP INC SG-110 SOLIO 69272 SERVICE GROUP INC SG-113 69272 SERVICE GROUP INC SG-201 89272 SERVICE GROUP INC SG-201HT 69272 SERVICE GROUP INC SG-250 69272 SERVICE GROUP INC SG-302 69272 SERVICE GROUP INC SG-303 89272 SERVICE GROUP INC SG-304 69272 SERVICE GROUP INC SG-306 89272 SERVICE GROUP INC SG-312 69272 SERVICE GROUP INC SGC FIBER 69272 SERVICE GROUP INC SGK FIBER 89272 WHITE BAKERSEAL SEALANT 4792-25A SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 STEAM & PROCESS SP-CM 85133D TEAM LEAK REPAIRS SEALANT DB-2 RCL 82-039 TEAM LEAK REPAIRS SEALANT 16 92288 TEAM LEAK REPAIRS SEALANT DB-2 RCL 62-043 STEAM & PROCESS SP-109 RCL 1458 STEAM & PROCESS SP-2007 RCL 82-037 STEAM & PROCESS SP-1011 RCL 1145 STEAM A PROCESS SP-103 RCL 1147 STEAM & PROCESS SP-2600 RCL 82-014 STEAM A PROCESS SP-CM RCL 1400 STEAM A PROCESS SP-2000 RCL 82-119 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 DSC DSC DSC DSC DSC DSC DSC OSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM OSC ARC HOM OSC HOM DSC HOM DSC DTA DTA DSC DTA DTA DTA DTA DTA OTA DTA DTA HOM DSC HOM DSC HOM Dow Confidential REACTIVITY NO EXO TO 275 C EXOAT 18SC EXO AT 75 C EXO AT 125 C NO EXO TO 325 C NO EXO TO 350 C EXO AT 260 C NO EXO TO 325 C NO EXO TO 290 C NO EXO TO 350 C NO EXO TO 325 C NO EXO TO 325 C EXO AT 360 C NO EXO AT 22 C EXOAT 297 C NO EXO AT 22 C EXO AT 325 C NO EXO AT 22 C EXOAT 185 C EXO AT 8 C NO EXO AT 22 C EXO AT 310 C NO EXO AT 22 C EXO AT 200 C NO EXO AT 22 C EXO AT 224 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 290 C NO EXO TO 100 C NO EXO TO 350 C EXOAT 145 C NO EXO TO 500 C NO EXO TO 300 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 450 C SL. EXO AT 22 C EXO AT 360 C EXO AT 22 C 47 TABLE III. REACTIVITY OF SEALANT WITH PF SS CHEMICAL (SORTED BY PLANT) PLANT PROCESS CHEMICAL meth; -JES METHf !ES METHA JES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES r> o ~7 o3 ~n M 3> mo z -i \> I> si HYDROGEN CHLORIDE HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) Ml. M2. M3, M4, * HCI Ml. M2, M3.M4, + HCI METHANES E-259 VENT (HCI,M1,M2.M3) METHANES R-300 OUTLET (Ml ,M2,M3,M4,HCI) METHANOL METHANOL METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIOE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIOE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE SHELL THERMIA C OIL WITH DISSOLVED HCL SHELL THERMIA OIL C SHELL THERMIA OIL C SODIUM HYDROXIDE (50%) SULFURIC ACID VINYL CHLORIDE WATER/STEAM WATER/STEAM WATER/STEAM SEALANT REF. NO. TEST REACTIVITY SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 STEAM & PROCESS SP-CM 85133F TEAM LEAK REPAIRS SEALANT DB-2 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 RCL 82-042 93093 93093 SILASTIC 732-RTV SILICONE RUBBER STEAM & PROCESS SP-2600 STEAM & PROCESS SP-1015 RCL 83-092 RCL 82-045 85173A TEAM LEAK REPAIRS SEALANT DB-2 RCL 82-041 755 STICK SEALANT 91126 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL GRAFPAK (UCAR CARSON CO GRAFOIL) 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 STEAM A PROCESS SP-1360 RCL 1578 STEAM & PROCESS SP-2007 84E156 STEAM & PROCESS SP-2026 85132A STEAM A PROCESS SP-CM 85133B TEAM LEAK REPAIRS SEAUNT DB-2 RCL 82-040 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL - CHEMOLA TEFLON 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6K8) 94060 SAFE SEAL MULTIPAK (JOHN CRANE 6KB) 94060 STEAM & PROCESS SP-103 RCL 1584 STEAM & PROCESS SP-1300 RCL 1582 STEAM & PROCESS SP-1360 RCL 1577 STEAM & PROCESS SP-2026 85132B STEAM A PROCESS SP-CM 85133C TEAM LEAK REPAIRS SEALANT DB-2 RCL 82-038 ULTRAMETAL LIQUID METAL (CURED) 93028 STEAM A PROCESS SP-1011 90400 STEAM A PROCESS SP-109 90400 STEAM A PROCESS SP-1011 RCL 1146 TEAM LEAK REPAIRS SEALANT DB-2 RCL 82-044 STEAM A PROCESS SP-429 93179 STEAM A PROCESS SP-1011 90037 STEAM A PROCESS SP-2511 TEAM LEAK REPAIRS SEALANT #1 86060A RCL 83-017 DSC DTA DTA DSC HOM DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA DTA DSC DSC DSC DTA DTA DSC DSC DTA DTA NOEXO TO 325 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 200 C NOEXO TO 310 C NO EXO TO 225 C NO EXO TO 175 C NO EXO TO 175 C NO EXO AT 22 C EXO AT 375 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NOEXO TO 140 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 190 C NO EXO AT 22 C EXO AT 228 C NO EXO AT 22 C EXO AT 335 C NO EXO AT 22 C EXO AT 120 C NO EXO TO150C NO EXO TO 150 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 295 C EXO AT 45 C EXOAT 114 C NO EXO TO 300 C NO EXO TO 275 C NO EXO TO 150 C Dow Confidential CHLORINATED METHANES PLANT RAW MATERIAL I.D. MATERIAL MEOH AMYLENE INHIBITOR CYCLOHEXANE SODIUM THIOSULFATE OILS/GREASES FLAKE CAUSTIC LIQUID NITROGEN H2S04 LAB GASES CATALYST MOLE SIEVE I.P. PROCESS G.C G.C G.C IODINE COLOR TEST LABEL LABEL C.OA ON INVOICE DENSITY CYLINDER LABELS COJL LABEL Reactive Chemicals November 9,1994 DO A 03357? CONFTDFNTTAL New Superintendent Review CHLORINATED METHANES PLANT CRITICAL INSTRUMENT PROGRAM 1. THERMALCHLORINATION: REACTION RUNAWAY PREVENTION: MOD V - TRIPLE REDUNDANCY ELIMINATING MANY CRITICAL INSTRUMENT CHECKS 2. HYPROCHLORINATION: DME CARRYOVER QUENCH COLUMN O/H TEMPERATURES SULFURIC COLUMN TEMPERATURES 3. DISTILLATION: PRE-START UP AUDITS NO CRITICAL INSTRUMENTS IDENTIFIED 4. PSA BED TEMPERATURES: PREVENT BED EXOTHERM DUE TO OXYGENATES Reactive Chemicals November 9,1994 oo A 000573 c onf td0NTI Al New Superintendent Review CHLORINATED METHANES PLANT TRAINING PROGRAM * YEARLY TRAINING ON REACTIVE CHEMICALS * IPT SYSTEM IN PLACE * PROCEDURE SYSTEM: ALL PROCEDURES DEFINE SPECIAL CONCERNS * COMPARABILITY CHART IN CONTROL ROOM * TRAINING AND COMMUNICATION ON DIVISION INCIDENTS Reactive Chemicals November 9,1994 DO A 03257a CDNFrDFNTTA! New Superintendent Review