Document M4EQ4KVyDX7Y8kB2VVZkObQny
Form Approved Budget Bureau No. 44-R1387 Approval Expires April 30. 1971
U.S. DEPARTMENT OF LABOR
/rT-3-
ftaAM'
Form No. tS&-OOS*4
Mav 1969
WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standards
Geon Resin
26242001 MATERIAL SAFETY DATA SHEET
SECTION 1
manufacturer's name
The B.F.Goodrich Co., B.F.Goodrich Chemical Co., Div.
EMERGENCY TELEPHONE NO.
216-524-0200
ADDRESS (Number, Street, City, State, and ZIP Code)
6100 Oak Tree Boulevard. Cleveland, Ohio 44131
CHEMICAL NAME ANO SYNONYMS
Polyvinyl Chloride Resin
TRADE NAME AND SYNONYMS
Geon 121
CHEMICAL FAMILY
,,Po,lymer
FORMULA
(CH2CHCl)n
SECTION. II. ..HAZARDOUS INGREDIENTS,
PAINTS. PRESERVATIVES. & SOLVENTS
TLV % (Units)
ALLOYS AND METALLIC COATINGS
pigments
Not Applicable
BASE METAL
Applicable
CATALYST
n ,,
ALLOYS
,,,,
VEHICLE SOLVENTS ADDITIVES
.. ft tl ft ,,,,
METALLIC COATINGS
lt
FILLER METAL
`
PLUS COATING OR CORE FLUX
OTHERS
,, ,,
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES
TLV %
(Units) -
TLV % (Units)
None Knovn
f*Mboiling point
VAPOR PRESSURE (mm Hg. VAPOR DENSITY (AlR=l) SOLUBILITY IN WATER APPEARANCE ANO OOOR
SECTION III PHYSICAL DATA
Not Applicabl
SPECIFIC GRAVITY |H20=1)
1.4
it ll nM
PERCENT VOLATILE
by volume t%> .
EVAPORATION RATE ( =U
,,Not Applicable
,,,,
Slight
Particle Size. 1007. through 200 mesh
TW,,.hite oow,der. .bl-and odor
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT |Method used!
...............................
Not Applicable
FLAMMABLE LIMITS .
Not Applicable
Lei Uel
EXTINGUISHING MEDIA
,,Water
SPECIAL FIRE FIGHTING PROCEDURES
Self contained breathing apparatus for fires in closed areas such as warehouses.
UNUSUALFIRE ANO EXPLOSION HAZARDS
. ..
When forced to burn. PVC will mainly contribute carbon monoxide. carbon dioxide and
hydrogen chloride as gases and smoke# Phosgene and chlorine are not combustion products.
BFG50296
thresholo limit value EFFECTS OF OVEREXPOSURE
SECTION V HEALTH HAZARD DATA
26242002
Not Applicable _In over th. .irty years o_f manur facturing PVC we have no^t ,had,
a serious problem with dermititis or inhalation of PVC powder.
EMERGENCY AND FIRST AIO PROCEDURES
Normal cleanliness.
- - ~
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE
CONDITIONS TO AVOIO
STABLE
X Not Applicable
INCOMPATA0IUTY (Materials to avoid)
None Known
HAZARDOUS DECOMPOSITION PRODUCTS
See Section IV
HAZARDOUS j POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
X
......................-....................... J
-
f ' SECTION VII SPILL OR LEAK PROCEDURES
i- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILlED
1 l
.
Apply normal
clean-up
procedures,
place
in containers,
wash down areas
with water
} ; and ventilate building to remove any large amounts of airborne powder.
i
NOTE: Wet resin is slippery.
t E
waste disposal method gan^Cary landfill or incineration.
If incineration is used.
[ I1
j recognition should be made that carbon monoxide and hydrogen chloride are generated
{
SECTION VIII SPECIAL PROTECTION INFORMATION
^nPrmfliYv^cme-^^opera^on whips up powder use B. of Mines approved dust protector.
VENTILATION
local exhaust At mixing operations and at
hot end of orocessine machine.
MECHANICAL (Gttutml)
SPECIAL OTHER
PROTECTIVE GLOVES
MNorma, -lly none.
EYE PROTECTION
OTHER PROTECTIVE EQUIPMENT
See Section IV
_ ....
Normally None -
,,
Safety Glasses
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
-
Normal cleanliness. Isolation in storage from
large amounts of easily combustibles, heat and ignition sources is desirable.
OTHER PRECAUTIONS
BFG50297
GEON RESIN
2^42003
GEON RESINS MATERIAL SAFETY DATA SHEETS
Refer to attached M.S.D.S. for Geon 121 and make Trade Name Change - Sect. I.
1. Geon Resins 121-124-124F1- 120X241-120X251-126 - 120X127
Completed form as attached.
2. Geon Resins 135-130X10
Completed form as attached plus change
A. Sect. I - "Copolymer of vinyl chloride/vinyl acetate"
B. Sect. IV - '*When forced to burn, these copolymer resins will mainly contribute carbon monoxide, carbon dioxide, hydrogen chloride and minor amounts of acetic acid as gases and smoke. Phosgene and chlorine are not combustion products".
3. Geon 130X17
Completed form as attached plus change
A. Sect. I - "Carboxy-modified vinyl chloride polymer."
4. Geon Resins 128-128Fl-120X270-l00x90
Completed form as attached plus change
A. Sect. Ill - "White powder, practically odorless"
5. Geon Resins 106F2-101F4
Completed form as attached plus change
A. Sect. Ill - "Particle size, 951 through 100 mesh"
'*White powder, practically odorless"
BFG50298
m.no
- 2-
6. Geon Resin 202 Completed form as attached plus change
26242004
A. Sect. I - "Copolymer of vinyl chloride and vinylidene chloride11
B. Sect. Ill - "Particle size, 100% through 40 mesh" " " "White powder, practically odorless"
7. Geon Resins 101-102EP-103EP-104EP-105EP-106-140X4-140X5-140X6-140X30 140X31-80X4-80X5-80X6-80X24-80X25-80X26
Completed form as attached plus change
A. Sect. Ill - "Particle size, 1007. through 40 mesh" " " "White powder, practically odorless"
.8 Geon Resins 92-93-99
Completed form as attached plus change
A. Sect. Ill - "Particle size, 1007. through 30 mesh" " " "White powder, practically odorless"
9. Geon Resins 421-427-428-432-400X47-440X30
Completed form as attached plus change
A. Sect. I -- "Copolymer of vinyl chloride and vinyl acetate"
B. Sect. Ill - "Specific Gravity - (See Data Sheet)" " " "% Volatile by weight - < 3%*" " " "White powder, slight sweet odor" " " "Particle size, 100% through 42 mesh"
C. Sect. IV - '%/hen forced to burn, these copolymer resins will mainly contribute carbon monoxide, carbon dioxide, hydrogen chloride and minor amounts of acetic acid as gases and smoke. Phosgene and chlorine are not combustion products."
,10 Geon Resin 443
Completed form as attached plus change
A. Sect. I - "Carboxyl containing polymer of vinyl chloride and vinyl acetate"
B. Sect. Ill - "Specific Gravity, 1.33"
" " "X Volatile by weight, < 3%*" 11 " "Particle size, 1007. through 42 mesh"
" " "White powder, slight sweet odor"
BFG50299
*B.F.Goodrich Procedure No. 362-E, primarily vinyl acetate and some water.
\
C. Sect. VI - "pH - <7, when slurried in water"
- 3-
26242005
D. Sect. IV - "When forced to burn, this copolymer resin will mainly contribute carbon monoxide, carbon dioxide, hydrogen chloride and minor amounts of acetic acid as gases and smoke. Phosgene and chlorine are not combustion products."
11. Geon 440X24
Completed form as attached plus change
A. Sect. I - "Partially hydrolyzed copolymer of vinyl chloride and vinyl acetate"
B. Sect. Ill - "Specific Gravity, 1.38" II M "% Volatile by weight, < 3%*"
II It "Particle size, 100% through 24 mesh" II II `Vhite to light yellow powder, slight sweet odor"
C. Sect. IV - "When forced to burn, this copolymer resin will mainly contribute carbon monoxide, carbon dioxide, hydrogen chloride and minor amounts of acetic acid as gases arid smoke. Phosgene and chlorine are not combustion products."
12. Geon 222
Completed form as attached plus change
A. Sect. I - "Copolymer of vinyl chloride and vinylidene chloride"
B. Sect. Ill - "Specific Gravity, 1.54" " " "% Volatile by weight, <2.0%**" " " "Particle size, 100% through 20 mesh" " " "White to light yellow powder, practically odorless"
13. Geon Hi-Temp Resins 601X540-603X560-605X560-607X570
Completed form as attached plus change
A, Sect. I - "Chlorinated PVC Resin"
B. Sect. Ill - "Specific Gravity, 1.56" " " "% Volatile by weight, <1.0%" " " "Particle size, 100% through 28 mesh" " " "White powder, practically odorless"
**B.F,Goodrich Procedure No. 362-E, primarily vinylidene chloride and some water.
BFG50300
