Document LJrKQRezBGV7Dnm7R0d0L9Jx7
Report Prepared by: Report Approved by:
NPDES Pretreatment Compliance Sampling Inspection Report
CROWN Cork & Seal - Nichols Site
650 Berry Road Nichols, New York 13812
40 CFR Parts 403 & 465.45 Industrial Wastewater Discharge Permit
Inspection Dates: April 12-13, 2023
THUAN TRAN Digitally signed by THUAN TRAN
_________________D_ate_: _20_23_.0_5._30_1_6:2_5_:14_-_04_'0_0' Thuan Tran, Physical Scientist
Cocuzza, Phil Digitally signed by Cocuzza, Phil
_________________D_ate_: _20_23_.0_5._31_0_6:2_7_:50_-_04_'0_0' Phil Cocuzza, Chief Monitoring Operations Section
CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
1.0 OBJECTIVE
Inspection Dates: April 12-13, 2023
On April 12-13, 2023, the United States Environmental Protection Agency (USEPA) conducted a Pretreatment Compliance Sampling Inspection (CSI) at CROWN Cork & Seal USA, Inc. - Nichols Site. The objective of the Pretreatment CSI was to gather information necessary to determine if the facility is in compliance with the requirements and limitations of the Federal Categorical Standard of 40 CFR Part 465.45 for Coil Coating Point Source Category- Subpart D - Canmaking Subcategory of the Pretreatment Standards for New Sources, the Federal General Pretreatment Regulations for Existing and New Sources of Pollution in 40 CFR Part 403, and the Industrial Wastewater Discharge Permit that was issued by the Town of Nichols, and other related Federal Regulations. The Industrial Wastewater Discharge Permit became effective February 01, 2023 and will expire on January 31, 2024.
2.0 KEY PARTICIPANTS
Listed below are key inspection participants and contact information, grouped by organization.
U.S. Environmental Protection Agency Thuan Tran, Lead Inspector 732-321-4455, email: tran.thuan@epa.gov Robert Morrell, Geologist
CROWN Cork & Seal USA, Inc. - Nichols Site Duy Tran, Environmental Engineer 215-698-5227, email: duy.tran@crowncork.com Chris Wagner, Plant Manager - Nichol's Site James Quinn, EHS Specialist Wastewater Treatment
Marcelo Sanchez, EHS Coordinator
John Horton, Certified Process Operator (CPO) Lead
3.0 FACILITY DESCRIPTION
3.1 General Information:
CROWN Holding, Inc., formerly CROWN Cork & Seal Company, makes metal beverage and food cans, metal aerosol containers, metals closures and specialty packing. CROWN Holding, Inc. has locations world-wide with their headquarter locating in Yardley, Pennsylvania. CROWN Cork & Seal - Nichols Site is located at 650 Berry Road, Nichols, New York (NY). The facility was constructed in 2016 and the 2-Piece Canmaking Manufacturing Operation started in 2017 mainly producing beverage cans. The manufacturing operation consisted of four (4) high-speed manufacturing process lines from fabrication to coating operations with two (2) additional lines added in 2020. The facility encompasses 5,000 square feet (ft2) of workspace; 3,000 ft2 of manufacturing space and 2,000 ft2 of warehouse space. The Nichols Site employs approximately 263 people, operating twenty-four (24) hours per day with 2, 12-hour shifts, producing on average between 12-13 million cans per day. The cans are mainly shipped within Eastern United States and Canada. CROWN Cork & Seal - Nichols Site is categorized under Standard
Page 2 of 9
CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
Inspection Dates: April 12-13, 2023
Industrial Classification (SIC) 3411 - Metal Cans and the North American Industry Classification System (NAICS) 332431 - Metal Can Manufacturing.
3.2 Process Information
CROWN Cork & Seal - Nichols Site uses water from the Town of Nichols for sanitary and manufacturing operation. The drinking water is further treated through a water purification system consisting of carbon filter, water softener, and a deionized (DI) water column before it is used in the 7-Stage Washing Process of the manufacturing operation.
Raw material is received in aluminum coils through trucks and are either stored in the warehouse or moved directly to the manufacturing operation. The aluminum coil is mounted onto a coil unwinder. The coil unwinder feeds the coil through a water-based lubricant to coat the aluminum sheet. Once lubricated, the sheet continues to the cupping press where cups are produced. The cups are conveyed to the wall ironing machine where the cups are extruded and ironed out into cans. The cans are trimmed to level the top. At this point, the cans are covered with water-soluble oil as well as lubricant and cooling oil used by the wall ironing machine. The cans are assembled onto the conveyor belt and proceed to the 7-Stage Washing Process.
The cans are pre-rinsed to remove water-soluble oil, lubricant, and cooling oil. The cans continue to the 1st Stage which is a hot water bath to remove any residual lubricants. After the hot water bath, the cans move to the 2nd Stage for etching with hot solutions of
hydrofluoric (HF) and sulfuric acid (H2SO4), followed by two ambient water rinse cycles in the 3rd Stage. The cans move along to the 4th Stage for a hot water treatment followed by an ambient water rinse bath in the 5th Stage. After the rinse, the cans proceed to the DI rinse water bath in the 6th Stage. In the 7th Stage, a mobility enhancer is added to the cans before
going into the drying oven.
After the drying oven, the cans are conveyed by vacuum to the bottom rim coater. A varnish is deposited on the bottom of the cans and is cured with ultraviolet (UV) lamps. The cans continue to the printer. Ink is applied on the outside surface of the cans as they rotate against the common rotating rubber printing blanket. Once the ink is applied, the cans are coated with a varnish to protect the printed image. After printing and varnish application, the cans are cured in the printer oven. As the cans exit the printer oven, the inside of the cans are coated with a water-based lacquer. The sprayed cans are cured by the inside bake oven to prevent any contact between the beverage and the can's metal. Once the sprayed cans are cured, they are moved to the necker-flanger process. The neck diameter of the can is decreased by forcing it through a series of dies resulting in a smaller opening than the cylinder and curved shoulder. The necker portion of the machine turns the neck back to create a mating surface for the top of the cans. The cans continue to the light tester where a sensor detects any light that may leak through a defective can. Cans with "pin-holes" or dented flanges are rejected. The non-defective cans move to the inspection camera. The camera system inspects the inside and outside of the cans as well as the inside and outside of
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
Inspection Dates: April 12-13, 2023
the neck area. The final product is organized and stacked onto pallets stacked 21 layers for storage and/or distributed to the vendors.
Scrap aluminum sheets and rejected aluminum cans from the manufacturing operation are collected and recycled. The aluminum scraps are melted and reconstituted into rolls of aluminum sheet.
Process waste streams from the pre-rinsed water, rinsed water baths and drag-outs from the 3rd and 5th Stages of the 7-Stage Washer, backwash from the water purification system, and condensates from the boiler blowdowns are directed to the Equalization (EQ) tank. From the EQ tank, the process wastewater is pumped into the oil/water separator. Oil is removed and hauled off for disposal. The wastewater continues to the pH adjustment chamber in the 1st Reaction Tank. Sodium hydroxide (NaOH) is added for pH adjustment before continuing to the flocculation chamber. A polymer is added, and a mixer assists to increase coagulation. After the flocculation chamber, the wastewater is conveyed to the 1st Lamella settling tank for physical separation.
The 1st Lamella settling tank effluent is pumped into the pH adjustment chamber in the 2nd Reaction Tank. The pH is adjusted between 9.5 - 10 Standard Units (SU) with hydrogen peroxide (H2O2). After pH adjustment, the wastewater continues to the flocculation chamber. A polymer is added at the surface and a submerged mixer aids in solid formation. The wastewater continues into the 2nd Lamella settling tank for phase separation.
The 2nd Lamella settling tank effluent flows into the Neutralization Tank. Either sulfuric acid (H2SO4) or sodium hydroxide (NaOH) is added to adjust the pH range between 7.3 - 7.5 SU. In addition, sodium bicarbonate (NaHCO3) is added to boost alkalinity. Once the pH has been adjusted, the wastewater flows into the 3rd Lamella settling tank. The effluent is pumped into the final effluent sampling tank. The pretreated effluent overflows the rectangular weir into the effluent trough. From the trough, the pretreated effluent converges into the discharge pipe. As the pretreated effluent discharges, the flow is recorded by a magmeter before reaching the Town of Nichols sewer collection system.
Sludge removal from the Lamella settling tanks to the sludge holding tank is based on visual inspection. The thickened sludge is pumped into a Plate-n-Frame Press. The sludge cake is disposed of at a landfill. The supernatant from the sludge holding tank is pumped to the oil/water separator. The filtrate from the Plate-n-Frame Press is directed to the EQ tank.
3.3 Facility Self-Monitoring Information
Four (4) individual, 1-gallon, grab samples are collected and stored in the sample refrigerator every hour by the plant operator. The 4 grab samples are composited in a 5-gallon bucket and is considered compliance sample as described in the "CROWN Cork & Seal SOP COP 201 for Monthly Wastewater Sampling". The grab-composite sample is distributed between the provided Microbac Laboratories, Inc. sample containers for BOD5, TSS, COD, TDS,
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
Inspection Dates: April 12-13, 2023
Phosphorus, Ammonia, Fluoride, Total Nitrogen, Metals, O&G, Alkalinity and TTO (VOAs & NVOAs). The samples are transported to Microbac Laboratories, Inc. located on 2369 Elmira Street in Sayre, Pennsylvania. Samples such as pH, Temperature, and Total Residual Chlorine (TRC) are collected and analyzed on-site for process control.
4.0 EPA SAMPLING/INSPECTION ACTIVITIES 4.1 Sampling Activities
An ISCO automatic composite sampler was programmed to take 96 sample aliquots during the 24-hour sampling event from the monitoring location immediately after the final effluent sampling tank. The 24-hour composite sample was collected and analyzed for 5-Day Biochemical Oxygen Demand (BOD5), Total Suspended Solids (TSS), Ammonia (NH3), Total Kjeldahl Nitrogen (TKN), Chemical Oxygen Demand (COD), Phosphorus, Total Dissolved Solids (TDS), Nitrate (NO3), Nitrite (NO2), Fluoride, Alkalinity (CaCO3), Metals (Cr, Cu, Mn & Zn) and Mercury.
Grab-composite sample was collected at various time intervals for Non-Volatile Organic Analytes (NVOAs).
Four (4) sets of grab samples for Volatile Organic Analytes (VOAs) were collected at similar time intervals as the NVOAs sample. The VOAs grab samples were composited in the laboratory. In addition, a grab sample for oil & grease (O&G) was collected.
Furthermore, on-site grab samples were collected and analyzed for pH, Temperature, and Total Residual Chlorine (TRC).
All sample containers, preservation techniques and holding times were in accordance with USEPA requirements specified in 40 CFR Part 136. All samples were transported on ice to the USEPA Laboratory in Edison, New Jersey for analysis.
Flow monitoring data were obtained directly from the facility instrumentation.
Split samples were collected and given to the facility representative.
4.2 Inspection Activities
A Pretreatment Compliance Sampling Inspection (CSI) at CROWN Cork & Seal - Nichols Site was conducted on April 12-13, 2023. The inspectors met with Duy Tran; Environmental Engineer, Chris Wagner; Plant Manager - Nichols Site, James Quinn; Environmental & Health Safety (EHS) Specialist - Wastewater Treatment, Marcelo Sanchez; (EHS) Coordinator, and John Horton; Certified Process Operator (CPO) Lead. Inspector's credential was presented, and business card was provided during the opening conference. The facility representatives were explained that the inspection purpose with supporting onsite activities was to determine if CROWN Cork & Seal - Nichols Site is in compliance with
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
Inspection Dates: April 12-13, 2023
the Federal requirements and conditions of 40 CFR Parts 465.45 & 403, the Industrial Wastewater Discharge Permit and related Federal Regulations.
Supporting on-site activities consist of collecting samples of the pretreated effluent at the monitoring location, observing and evaluating the monitoring location, observing and evaluating CROWN Cork & Seal - Nichols Site Sampling Protocol, observing and evaluating the On-Site Pretreatment System, observing and evaluating where process waste streams are generated during the Canmaking Manufacturing Operation tour, observing and evaluating the flow monitoring equipment, reviewing and evaluating the on-site analytical procedures, reviewing and evaluating the chain-of-custody, contractor's sample containers, and sample preservation, and interviewing the facility's representatives.
The facility's representatives were briefed on the inspection activities throughout the inspection and during the closing conference. On-site sample results and concerns discovered during the inspection were communicated to the facility's representatives so that they understood their responsibilities to comply with the conditions and limitations set forth in the Industrial Wastewater Discharge Permit and related Federal Regulations.
5.0 ANALYTICAL RESULTS
Table 1: 40 CFR Part 465.46 Subpart D - Canmaking Subcategory
Inspection Dates: April 12-13, 2023
Parameter
EPA Result
EPA
Maximum for Maximum for
(mg/l)
Calculated
any 1 day monthly average
Result*
grams (lbs.)/million cans manufactured
Chromium, Total
U
0.191
27.98 (0.0617)
11.45 (0.025)
(RL:0.005)
Copper, Total
0.0186
0.711
120.84 (0.267)
63.60 (0.140)
Zinc, Total
0.054
2.064
92.86 (0.205)
38.80 (0.086)
Manganese, Total
0.351
13.42
3784.20 (8.345) 1679.04 (3.702)
Fluoride
9.29
355
1062.12 (2.342)
434.39 (0.958)
Phosphorus
0.0533
2.038
43.25 (0.095)
18.44 (0.041)
Total Toxic Organics*
U J L
0.191
20.35 (0.045)
9.54 (0.0210)
RL: .005
O & G (alt. monitoring)
8.50 L
325
1272.00 (2.804)
763.20 (1.683)
pH [40CFRP403.5(b)(2)]
7.19 SU
-----
>/= 5.0 SU
-----
Temp. [40CFRP403.5(b)(5)]
22C
-----
</= 40C (104F)
-----
Flow (gallons)
118,073
-----
-----
-----
Production (million cans)
11,669,641
-----
-----
-----
Notes: EPA Calculated Result* (g/million cans) = EPA Result (mg/l) * (1 liter/0.264 gallons) * (daily total flow (gallons)
Production (million cans) * 1000 (mg/g)
Total Toxic Organics*: [40 CFR Part 465.02(j)]: shall mean the sum of the mass of each of the following toxic
organic compounds which are found at a concentration greater than 0.01 mg/l.
U- The analyte was not detected at or above the Reporting Limit (RL).
L- The identification of the analyte is acceptable; the reported value may be biased low.
J- The identification of the analyte is acceptable; the reported value is an estimate.
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
Inspection Dates: April 12-13, 2023
Table 2: Industrial Wastewater Discharge Permit
Inspection Dates: April 12-13, 2023
Parameters
Units IU Permit Limitations
EPA Results
BOD5
mg/l 250
76.9
COD
mg/l 350
231
TSS
mg/l 150
U
TDS
mg/l 10,000
2130
Total Nitrogen*
mg/l 50
10.24
Ammonia
mg/l 20
1.38
TRC
mg/l 2.0
0.00
Mercury
mg/l 0.25
U
Chromium, Total
mg/l 0.21
U
Copper, Total
mg/l 1.19
0.0186
Zinc, Total
mg/l 0.73
0.054
Manganese, Total
mg/l 0.35
0.351
Fluoride
mg/l 15.0
9.29
Phosphorus
mg/l 8.17
0.0533
Total Toxic Organics mg/l 0.10
U J L
: VOAs
------ ------
RL: 5.00 ug/l
: NVOAs
----- -----
RL: 5.21 ug/l
Oil & Grease
mg/l 14.36
8.50 L
pH
SU
7.0 - 8.0
7.19
Alkalinity (CaCO3) mg/l 200 (minimum)
U
Flow
GPD <130,000 (daily); 223,000 (max.)
118,073
Notes: Total Nitrogen*: is the sum of TKN+NO3+NO2. TKN is made up of organic N2 & NH3
U- The analyte was not detected at or above the Reporting Limit.
L- The identification of the analyte is acceptable; the reported value may be biased low.
J- The identification of the analyte is acceptable; the reported value is an estimate.
6.0 FINDINGS
6.1 Sampling Result Findings
The EPA analytical results obtained during this inspection are within the acceptable limits.
6.2 Inspection Findings
In addition to the analytical data, an inspection of the facility operations was conducted as discussed in Section 4.2 above. During the inspection, the following observations were noted which may contravene the requirements of the applicable Federal Regulations and Industrial User Permit:
6.2.1 The On-Site Pretreatment System receives, treats, and discharges pretreated process wastewater to the Town of Nichols sewer collection system continuously throughout the calendar day or 24 hours. The composite sample collected is based on four (4) hours as described in the CROWN Cork & Seal - Nichols Site SOP COP 201 for Monthly Wastewater Sampling. As a result, the composite sample is not
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
Inspection Dates: April 12-13, 2023
indicative or representative of the discharged effluent. According to Part 2(D)(1) Representative Sampling of the Industrial User Permit, it states, "Samples and measurements taken as required herein shall be representative of the volume and nature of the monitored discharge." In addition, 40 CFR Part 403.12(b)(5)(ii), it states, " ......the User shall submit the results of sampling and analysis identifying the nature and concentration (or mass, where required by the Standard or Control Authority) of regulated pollutants in the Discharge from each regulated process. Both daily maximum and average concentration (or mass, where required) shall be reported. The sample shall be representative of the daily operations."
6.2.2 The pretreated effluent is being monitored by the magnetic flow meter. No calibration sticker/tag was observed on the flow meter to indicate the date of last calibration or the next calibration date of the flow meter. According to Part 2(D)(2)Flow Measurement of the Industrial User Permit, it states, "Flow measurement is required by this Permit. The appropriate flow measurement devices and methods consistent with approved scientific practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of monitored discharges. The devices shall be installed, calibrated, and maintained to ensure that the accuracy of the measurement is consistent with the accepted capability of the type of device."
6.2.3 Oil & Grease (O&G) sample is collected as a 4-hour grab-composite sample as discussed in Section 6.2.1. This is incorrect. According to Section 8.3 for Sample Collection, Preservation & Storage of the EPA Method 1664A: N-Hexane Extractable Materials (HEM; Oil and Grease) and Silica Gel Treated N-Hexane Extractable Material (SGTHEM; Non-polar Material) by Extraction and Gravimetry, it states, "The high probability that extractable matter may adhere to sampling equipment and result in measurements that are biased low precludes the collection of composite samples for determination of oil and grease. Therefore, samples must be collected as grab samples. If a composite measurement is required, individual grab samples collected at prescribed time intervals must be analyzed separately and the concentrations averaged. Alternatively, samples can be collected in the field and composited in the laboratory."
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45 & IU Permit
7.0 ATTACHMENTS
Inspection Dates: April 12-13, 2023
Attachment #1. Drinking water from the Town of Nichols is treated through the DI Water Purification System.
Attachment #2. Aluminum coils are used in the Canmaking Manufacturing Operation.
Attachment #3. Process wastewater is generated from the 7-Stage Washer in the Canmaking Manufacturing Operation.
Attachment #4. Besides the 7-Stage Washer, other process waste streams are directed to the EQ tank.
Attachment #5. Process wastewater is treated by the On-Site Physical/Chemical Pretreatment Plant.
Attachment #6. USEPA Chain of Custody for Samples was submitted to the USEPA Lab.
Attachment #7. USEPA Analytical Data Package was received on 05/02/2023.
8.0 PHOTOGRAPHS
Photo #1. An automatic composite sampler was set-up after the effluent tank.
Photo #2. No calibration sticker/tag on the magmeter recording the discharged flow.
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CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45, and IU Permit
Inspection Dates: April 12-13, 2023
7.0 Attachments
Attachment #1. Drinking water from the Town of Nichols is treated through the DI Water Purification System.
Attachment #2. Aluminum coil starts the Canmaking Manufacturing Operation from fabrication to coating.
Can Plant Layout & Equipment Overview
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TRIMMERS
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INSPECTION
INSIDE BAKE OVEN
NECKER I FLANGER I REFORMER
PALLETlZER
Attachment #3. Cans are cleaned and etched through the 7-Stage Washing Process.
Simplified Stages of the Can Washer (7-Stage Washer + Drag Out)
Residual Water from Rinse Tank
Sulfuric Acid to pH 1.6 - 1.8 Temp 140150F
C-IC 62433
Temp 145-155F
City Water Rinse
City Water Rinse
City Water Rinse
City Water Rinse
DI Water Rinse
DI Water Rinse + Mobility
Stage 0 Pre-Rinse
Stage 1 Pre-Rinse Pre-Wash
Stage 2 Cleaner
Drag Out City Water
Rinse
Stage 3 City Water
Rinse
Stage 4 City Water Rinse or Treatment
Stage 5
Stage 5
Stage 7
City Water Recirculating
Mobility
Rinse Deionized Water Enhancer + DI
Water Rinse
6
February 2017
Henkel Washer Operation - Overview
Attachment #4. Generated process waste streams from the Canmaking Manufacturing Operation are directed to the On-Site Pretreatment System.
Attachment #5. Process wastewater is treated by the On-Site Physical/Chemical Pretreatment System. Nichols Current Waste Water Treatment
1-2 m3/h
6 m3/h
FROM PROCESS WATER TREATMENT
7-8 m3/h per washer
WASHER SUMP x3
WASHER x3
DI RINSE x3
LINE #1 #2 #3 COOLANT SUMP
37 m3
37 m3
FE DUMP TANK
WASHER DUMP TANK
OILY WATER TREATMENT (H2SO4/demulsifier)
To EQtank (via sump)
450 m3
From Water Treatment sump
From Wastewater Treatment sump
EQ TANK 7.3 m3/h per washer
OIL SEPARATORS 2 x
To EQtank (via sump)
37 m3
SLUDGE THICKENER TANK
Press filter
Skip of dry sludge 2 T/d
300- 350 m3/d 15 m3/h
OUTFALL (discharge point)
SAMPLE TANK 40m3
1st REACTION TANK
2 x26 m3
1st LAMELLAR SETTLER 2 x 40 m3
2nd REACTION TANK
2 x 26m3
2nd LAMELLAR SETTLER 2 x 40 m3
1st NEUTRALISATION TANK 2 x 10m3
2nd NEUTRALISATION TANK 2 x 10m3
3rd LAMELLAR SETTLER 2 x 40 m3
DOSING 1. BENTONITE 2. LIME 3. COAGULANT
DOSING 1. BENTONITE 2. H202 3. NaOH
DOSING 1. ALKALINITY BOOST 2. SULFURIC ACID DOSING 1. CAUSTIC SODA
TO PROCESS WATER TREATMENT
Wastewater stream Sludge stream Oil stream City water stream Soft water stream RO water stream Blended water stream DI water stream Process waste stream
Attachment #6. Samples were submitted to the USEPA Laboratory on Thursday, April 13, 2023.
Attachment #7. Analytical Data Package was received from the USEPA Laboratory on Tuesday, May 2, 2023.
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
2890 Woodbridge Avenue Edison , New Jersey 08837
732-906-6886 Phone 732-906-6165 Fax
May 02, 2023 Philip Cocuzza Monitoring & Assessment Branch LSASD/MAB Edison, NJ 08837
RE: Crown Cork & Seal - 2304016 Enclosed are the results of analyses for samples received by the laboratory on 04/13/2023. The signature below reflects the laboratory's approval of the reported results. If you have any questions concerning this report, please refer to Project Number 2304016 and contact the laboratory. Sincerely,
John R. Bourbon Chief, LSASD/LB
Project Narrative:
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
The National Environmental Laboratory Accreditation Conference Institute (TNI) is a voluntary environmental laboratory accreditation association of State and Federal agencies. TNI established and promoted a National Environmental Laboratory Accreditation Program (NELAP) that provides a uniform set of standards for the generation of environmental data that are of known and defensible quality. The EPA Region 2 Laboratory is NELAP accredited. The Laboratory tests that are accredited have met all the requirements established under the TNI Standards.
Condition Comments
None
Comment(s):
The "Sample Analysis Date and Time" is included in the results section for any analyte with a prescribed holding time of 72 hours or less.
Results for the laboratory Blank Spike and Blank Spike Duplicate were less than the minimum requirement of 78% and the associated sample analyses were qualified with an "L" to indicate a potential low bias in the reported result.
Data Qualifier(s):
U- The analyte was not detected at or above the Reporting Limit. J- The identification of the analyte is acceptable; the reported value is an estimate. K- The identification of the analyte is acceptable; the reported value may be biased high. L- The identification of the analyte is acceptable; the reported value may be biased low. NJ- There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. The reported value is an estimate.
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 1 of 30
Reporting Limit(s):
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
The Laboratory was able to achieve the standard laboratory reporting limits, where applicable, for each analyte requested except for the following analyte(s):
NVOA GCMS The reporting level of 5.00 ug/L was raised to 30 ug/L for the following analyte(s): 2,4-Dinitrophenol for the following samples: 2304016-09
SUMMARY REPORT FOR SAMPLES
Field ID
Laboratory ID
Outfall #1 - Comp.
2304016-01
TRIP BLANK
2304016-02
Outfall #1 - Grab#1-thru-Grab#4-Lab Comp2o3s0i4te016-07
Outfall #1 - Grab
2304016-08
Outfall #1 - G-C
2304016-09
Matrix Aqueous Aqueous Aqueous Aqueous Aqueous
Date Sampled 04/13/2023 09:40 04/11/2023 09:40 04/13/2023 00:00 04/13/2023 09:43 04/13/2023 09:42
Date Received 04/13/2023 13:35 04/13/2023 13:35 04/13/2023 13:35 04/13/2023 13:35 04/13/2023 13:35
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 2 of 30
Analysis 624.1 VOA EPA-NPDES 625.1 SVOA NPDES Alkalinity Carbonate Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Fluoride Mercury Metals ICP TAL NPDES/DW Nitrate [As N] Nitrite [As N] Nitrogen, Total Kjeldahl Oil & Grease Phosphorus Residue, Filterable Residue, Non-Filterable
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
SUMMARY REPORT FOR METHODS
Method
EPA 624.1 SOP C-89 Rev 3.7 EPA 625.1 SOP C-90 Rev 3.9 SM 2320B SOP C-18 Rev 3.8 EPA 350.1 SOP C-80 Rev 2.8 SM 5210B SOP C-21 Rev 2.8 EPA 410.4 SOP C-53 Rev 2.8 EPA 300.0 SOP C-94 Rev 2.8 EPA 245.1 SOP C-110 Rev 2.8 EPA 200.7 SOP C-109 Rev 3.7 EPA 353.2 SOP C-79 Rev 3.7 EPA 353.2 SOP C-79 Rev 3.7 EPA 351.2 SOP C-40 Rev2.8 EPA 1664A SOP C-126 Rev 1.7 EPA 365.1 SOP C-68 Rev 2.8 SM 2540C SOP C-37 Rev 2.8 SM 2540D SOP C-33 Rev 3.8
Certification NELAP NELAP
NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP
Matrix
Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 3 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
Analyte
Field ID: Outfall #1 - Comp. Metals ICP Chromium Copper Manganese Zinc Mercury CVAA Mercury Sanitary Alkalinity Carbonate Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Fluoride Nitrate [As N] Nitrite [As N] Nitrogen, Total Kjeldahl Phosphorus Total Dissolved Solids Total Suspended Solids
Field ID: TRIP BLANK VOA GCMS Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2304016-01
Date and Time of Analysis*
---
U
5.00
ug/L B304068
18.6
10.0
ug/L B304068
351
5.00
ug/L B304068
54.0
20.0
ug/L B304068
---
U
0.050
ug/L B304079
---
U
1.00
mg/L B304081
1.38
0.100
mg/L B304119
76.9
2.00
mg/L B304063 04/19/2023 06:53
231
40.0
mg/L B304116
9.29
0.500
mg/L B304071
0.277
0.0500
mg/L B304064 04/14/2023 08:18
0.0527
0.0500
mg/L B304064 04/14/2023 08:18
9.91
1.00
mg/L B304095
0.0533
0.0500
mg/L B304067
2130
10.0
mg/L B304072
---
U
10.0
mg/L B304069
Sample ID: 2304016-02
---
U
5.00
ug/L B304075
---
U J
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 4 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
Analyte
Result
Qualifier
Reporting Limit
Units
Batch
Date and Time of Analysis*
Field ID: TRIP BLANK
Sample ID: 2304016-02
VOA GCMS 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
Field ID: Outfall #1 - Grab#1-thru-Grab#4-Lab Composi
Sample ID: 2304016-07
VOA GCMS Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane
---
U
5.00
ug/L B304075
---
U J
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 5 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
Analyte
Field ID: Outfall #1 - Grab#1-thru-Grab#4-Lab Composi VOA GCMS 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
Field ID: Outfall #1 - Grab GC - Sanitary Oil & Grease
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2304016-07
Date and Time of Analysis*
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
---
U
5.00
ug/L B304075
Sample ID: 2304016-08
8.50
L
6.30
mg/L B304139
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 6 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
Analyte
Field ID: Outfall #1 - G-C NVOA GCMS Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2304016-09
Date and Time of Analysis*
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
31.2
ug/L B304084
---
U
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U L
5.21
ug/L B304084
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 7 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
Analyte
Field ID: Outfall #1 - G-C NVOA GCMS 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2304016-09
Date and Time of Analysis*
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
---
U J
5.21
ug/L B304084
---
U
5.21
ug/L B304084
8.67
L
5.21
ug/L B304084
---
U
5.21
ug/L B304084
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 8 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016
VOA GCMS - Quality Control
Analyte
Batch B304075
Blank (B304075-BLK1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
100
ug/L
100.0
101
ug/L
100.0
ND
ug/L
100.0
100
60-140
101
60-140
99.6
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 9 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 VOA GCMS - Quality Control
Analyte
Batch B304075
LCS (B304075-BS1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
56.8
ug/L
50.00
114
19-205
51.1
ug/L
50.00
102
5-195
53.9
ug/L
50.00
108
15-185
54.1
ug/L
50.00
108
40-160
55.5
ug/L
50.00
111
50-150
52.4
ug/L
50.00
105
50-150
53.8
ug/L
50.00
108
60-140
51.6
ug/L
50.00
103
60-140
55.9
ug/L
50.00
112
70-130
54.2
ug/L
50.00
108
70-130
54.6
ug/L
50.00
109
70-135
54.6
ug/L
50.00
109
70-130
52.8
ug/L
50.00
106
70-130
54.0
ug/L
50.00
108
70-130
53.4
ug/L
50.00
107
65-135
52.8
ug/L
50.00
106
65-135
54.5
ug/L
50.00
109
35-165
53.9
ug/L
50.00
108
65-135
54.4
ug/L
50.00
109
25-175
53.4
ug/L
50.00
107
70-130
57.6
ug/L
50.00
115
50-150
52.9
ug/L
50.00
106
70-130
53.6
ug/L
50.00
107
70-130
55.1
ug/L
50.00
110
70-135
53.6
ug/L
50.00
107
65-135
55.6
ug/L
50.00
111
60-140
52.3
ug/L
50.00
105
70-130
50.7
ug/L
50.00
101
60-140
53.9
ug/L
50.00
108
70-130
53.7
ug/L
50.00
107
65-135
53.1
ug/L
50.00
106
65-135
98.7
ug/L
100.0
98.7
60-140
100
ug/L
100.0
100
60-140
99.9
ug/L
100.0
99.9
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 10 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 VOA GCMS - Quality Control
Analyte
Batch B304075
LCS Dup (B304075-BSD1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
48.4
ug/L
50.00
96.7
19-205
16.1
20
39.6
ug/L
50.00
79.2
5-195
25.4
20
45.8
ug/L
50.00
91.6
15-185
16.2
20
45.6
ug/L
50.00
91.1
40-160
17.1
20
45.8
ug/L
50.00
91.6
50-150
19.2
20
44.4
ug/L
50.00
88.9
50-150
16.5
20
46.1
ug/L
50.00
92.3
60-140
15.4
20
45.6
ug/L
50.00
91.2
60-140
12.2
20
47.9
ug/L
50.00
95.9
70-130
15.4
20
47.0
ug/L
50.00
93.9
70-130
14.3
20
46.8
ug/L
50.00
93.5
70-135
15.4
20
45.8
ug/L
50.00
91.5
70-130
17.6
20
44.8
ug/L
50.00
89.6
70-130
16.4
20
47.4
ug/L
50.00
94.8
70-130
13.0
20
45.8
ug/L
50.00
91.6
65-135
15.3
20
46.4
ug/L
50.00
92.8
65-135
12.8
20
47.4
ug/L
50.00
94.8
35-165
14.0
20
47.2
ug/L
50.00
94.4
65-135
13.2
20
47.5
ug/L
50.00
95.0
25-175
13.6
20
46.4
ug/L
50.00
92.8
70-130
14.1
20
50.3
ug/L
50.00
101
50-150
13.5
20
46.1
ug/L
50.00
92.3
70-130
13.6
20
45.4
ug/L
50.00
90.8
70-130
16.6
20
48.3
ug/L
50.00
96.5
70-135
13.3
20
46.5
ug/L
50.00
93.1
65-135
14.2
20
47.8
ug/L
50.00
95.7
60-140
15.1
20
46.6
ug/L
50.00
93.2
70-130
11.6
20
45.2
ug/L
50.00
90.5
60-140
11.4
20
47.0
ug/L
50.00
94.1
70-130
13.6
20
46.8
ug/L
50.00
93.7
65-135
13.6
20
46.8
ug/L
50.00
93.6
65-135
12.6
20
99.8
ug/L
100.0
99.8
60-140
101
ug/L
100.0
101
60-140
100
ug/L
100.0
100
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 11 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 VOA GCMS - Quality Control
Analyte
Batch B304075
Matrix Spike (B304075-MS1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2304016-07
45.4
ug/L
42.6
ug/L
48.4
ug/L
46.0
ug/L
47.6
ug/L
48.0
ug/L
48.5
ug/L
47.5
ug/L
47.5
ug/L
48.5
ug/L
49.4
ug/L
48.2
ug/L
47.6
ug/L
47.7
ug/L
47.6
ug/L
46.8
ug/L
47.8
ug/L
47.2
ug/L
48.8
ug/L
47.4
ug/L
48.6
ug/L
46.4
ug/L
47.5
ug/L
46.7
ug/L
46.9
ug/L
48.3
ug/L
46.0
ug/L
46.8
ug/L
48.3
ug/L
48.5
ug/L
48.3
ug/L
99.7
ug/L
102
ug/L
104
ug/L
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
50.00
0.00
100.0 100.0 100.0
90.8
19-273
85.2
49-251
96.8
21-242
92.0
14-230
95.2
17-181
95.9
52-234
97.0
69-221
95.1
40-160
95.0
54-156
97.1
59-155
98.8
51-138
96.4
52-162
95.2
70-140
95.4
49-155
95.2
37-151
93.7
70-157
95.7
74-210
94.3
35-155
97.5
80-227
94.9
47-150
97.1
17-183
92.7
52-150
95.0
64-148
93.4
53-149
93.7
37-160
96.6
37-162
92.1
45-169
93.7
46-157
96.6
59-156
97.0
18-190
96.6
18-190
99.7
60-140
102
60-140
104
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 12 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 VOA GCMS - Quality Control
Analyte
Batch B304075
Matrix Spike Dup (B304075-MSD1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene
Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2304016-07
50.5
ug/L
50.00
0.00
101
19-273
10.6
28
46.5
ug/L
50.00
0.00
93.0
49-251
8.80
28
54.5
ug/L
50.00
0.00
109
21-242
11.8
28
51.5
ug/L
50.00
0.00
103
14-230
11.2
28
52.0
ug/L
50.00
0.00
104
17-181
8.76
28
52.9
ug/L
50.00
0.00
106
52-234
9.85
28
52.6
ug/L
50.00
0.00
105
69-221
8.04
28
51.7
ug/L
50.00
0.00
103
40-160
8.31
28
52.8
ug/L
50.00
0.00
106
54-156
10.6
28
53.5
ug/L
50.00
0.00
107
59-155
9.80
28
54.1
ug/L
50.00
0.00
108
51-138
9.12
28
52.4
ug/L
50.00
0.00
105
52-162
8.23
28
52.5
ug/L
50.00
0.00
105
70-140
9.83
28
52.5
ug/L
50.00
0.00
105
49-155
9.60
28
53.5
ug/L
50.00
0.00
107
37-151
11.7
28
52.8
ug/L
50.00
0.00
106
70-157
12.0
28
53.5
ug/L
50.00
0.00
107
74-210
11.1
28
53.2
ug/L
50.00
0.00
106
35-155
12.0
28
54.1
ug/L
50.00
0.00
108
80-227
10.3
28
53.4
ug/L
50.00
0.00
107
47-150
11.9
28
54.4
ug/L
50.00
0.00
109
17-183
11.4
28
52.8
ug/L
50.00
0.00
106
52-150
12.9
28
53.4
ug/L
50.00
0.00
107
64-148
11.6
28
53.1
ug/L
50.00
0.00
106
53-149
12.8
28
52.8
ug/L
50.00
0.00
106
37-160
12.0
28
54.6
ug/L
50.00
0.00
109
37-162
12.4
28
53.2
ug/L
50.00
0.00
106
45-169
14.5
28
53.5
ug/L
50.00
0.00
107
46-157
13.3
28
54.2
ug/L
50.00
0.00
108
59-156
11.5
28
54.8
ug/L
50.00
0.00
110
18-190
12.1
28
54.7
ug/L
50.00
0.00
109
18-190
12.4
28
99.8
ug/L
100.0
99.8
60-140
103
ug/L
100.0
103
60-140
105
ug/L
100.0
105
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 13 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Batch B304084
Blank (B304084-BLK1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
RPD Limit
Page 14 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Batch B304084
Blank (B304084-BLK1) Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
LCS (B304084-BS1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
36.1
ug/L
50.00
ND
ug/L
50.00
36.0
ug/L
50.00
35.0
ug/L
50.00
ND
ug/L
50.00
33.9
ug/L
50.00
39.5
ug/L
50.00
40.1
5.00 ug/L
50.00
38.9
5.00 ug/L
50.00
47.2
5.00 ug/L
50.00
48.2
5.00 ug/L
50.00
47.1
5.00 ug/L
50.00
49.0
5.00 ug/L
50.00
59.4
5.00 ug/L
50.00
48.6
5.00 ug/L
50.00
72.1
60-140
35.0
60-140
71.9
60-140
70.0
60-140
57.2
60-140
67.8
60-140
79.0
60-140
80.2
47-145
77.8
33-145
94.4
27-133
96.5
33-143
94.1
17-163
97.9
24-159
119
35-219
97.1
11-162
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 15 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Batch B304084
LCS (B304084-BS1) Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene
47.9
5.00 ug/L
50.00
57.0
5.00 ug/L
50.00
45.4
5.00 ug/L
50.00
46.8
5.00 ug/L
50.00
56.3
5.00 ug/L
50.00
33.9
5.00 ug/L
50.00
47.7
5.00 ug/L
50.00
33.5
5.00 ug/L
50.00
38.4
5.00 ug/L
50.00
39.0
5.00 ug/L
50.00
31.9
5.00 ug/L
50.00
50.9
5.00 ug/L
50.00
44.2
5.00 ug/L
50.00
23.6
5.00 ug/L
50.00
38.0
5.00 ug/L
50.00
40.3
5.00 ug/L
50.00
30.5
5.00 ug/L
50.00
49.1
5.00 ug/L
50.00
53.0
5.00 ug/L
50.00
49.2
5.00 ug/L
50.00
41.0
5.00 ug/L
50.00
47.9
5.00 ug/L
50.00
18.6
5.00 ug/L
50.00
37.5
5.00 ug/L
50.00
38.7
5.00 ug/L
50.00
34.1
5.00 ug/L
50.00
55.5
5.00 ug/L
50.00
43.5
5.00 ug/L
50.00
47.1
5.00 ug/L
50.00
45.6
5.00 ug/L
50.00
32.9
5.00 ug/L
50.00
48.7
5.00 ug/L
50.00
51.0
5.00 ug/L
50.00
47.7
5.00 ug/L
50.00
31.6
5.00 ug/L
50.00
95.7
17-168
114
33-227
90.8
26-137
93.6
59-121
113
39-171
67.8
21-133
95.4
54-120
67.0
44-142
76.9
37-144
78.0
39-135
63.8
32-120
102
39-139
88.4
50-158
47.2
21-191
76.0
60-120
80.6
23-134
61.0
29-182
98.3
38-262
106
17-181
98.5
53-127
82.1
22-147
95.9
25-158
37.1
9-132
75.0
33-184
77.4
12-158
68.2
36-166
111
8-158
87.0
38-152
94.3
60-115
91.2
31-114
65.9
28-120
97.3
1-120
102
4-146
95.4
35-152
63.2
24-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
RPD Limit
Page 16 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Batch B304084
LCS (B304084-BS1) Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
LCS Dup (B304084-BSD1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
33.2
5.00 ug/L
50.00
32.8
5.00 ug/L
50.00
43.7
5.00 ug/L
50.00
38.5
5.00 ug/L
50.00
28.5
5.00 ug/L
50.00
38.2
5.00 ug/L
50.00
54.9
5.00 ug/L
50.00
31.6
5.00 ug/L
50.00
18.6
5.00 ug/L
50.00
44.5
5.00 ug/L
50.00
38.1
ug/L
50.00
18.4
ug/L
50.00
36.9
ug/L
50.00
36.6
ug/L
50.00
41.0
ug/L
50.00
41.5
ug/L
50.00
47.8
ug/L
50.00
40.4
5.00 ug/L
50.00
39.5
5.00 ug/L
50.00
44.2
5.00 ug/L
50.00
40.9
5.00 ug/L
50.00
46.4
5.00 ug/L
50.00
46.5
5.00 ug/L
50.00
54.8
5.00 ug/L
50.00
47.3
5.00 ug/L
50.00
41.2
5.00 ug/L
50.00
52.9
5.00 ug/L
50.00
46.3
5.00 ug/L
50.00
42.8
5.00 ug/L
50.00
54.6
5.00 ug/L
50.00
34.0
5.00 ug/L
50.00
45.0
5.00 ug/L
50.00
33.1
5.00 ug/L
50.00
66.4
15-76
65.7
40-120
87.4
21-196
77.0
35-180
57.0
17-127
76.4
43-230
110
79-139
63.2
14-176
37.2
5-120
89.1
52-120
76.1
60-140
36.8
60-140
73.8
60-140
73.2
60-140
81.9
60-140
83.0
60-140
95.6
60-140
80.9
47-145
0.869
30
79.0
33-145
1.53
30
88.4
27-133
6.52
30
81.8
33-143
16.5
30
92.8
17-163
1.41
30
93.1
24-159
5.05
30
110
35-219
7.99
30
94.6
11-162
2.61
30
82.4
17-168
14.9
30
106
33-227
7.44
30
92.5
26-137
1.92
30
85.6
59-121
8.89
30
109
39-171
3.05
30
68.0
21-133
0.324
30
90.1
54-120
5.74
30
66.3
44-142
1.05
30
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 17 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike Level
Source Result
%REC
%REC Limits
Batch B304084
LCS Dup (B304084-BSD1) 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol
38.3
5.00 ug/L
50.00
39.2
5.00 ug/L
50.00
31.5
5.00 ug/L
50.00
48.3
5.00 ug/L
50.00
46.1
5.00 ug/L
50.00
27.7
5.00 ug/L
50.00
38.0
5.00 ug/L
50.00
38.7
5.00 ug/L
50.00
28.5
5.00 ug/L
50.00
45.2
5.00 ug/L
50.00
53.0
5.00 ug/L
50.00
44.2
5.00 ug/L
50.00
42.0
5.00 ug/L
50.00
42.9
5.00 ug/L
50.00
20.4
5.00 ug/L
50.00
37.4
5.00 ug/L
50.00
37.7
5.00 ug/L
50.00
32.5
5.00 ug/L
50.00
44.9
5.00 ug/L
50.00
47.8
5.00 ug/L
50.00
42.2
5.00 ug/L
50.00
40.6
5.00 ug/L
50.00
32.6
5.00 ug/L
50.00
46.2
5.00 ug/L
50.00
46.5
5.00 ug/L
50.00
44.0
5.00 ug/L
50.00
31.2
5.00 ug/L
50.00
33.0
5.00 ug/L
50.00
31.3
5.00 ug/L
50.00
43.9
5.00 ug/L
50.00
37.9
5.00 ug/L
50.00
27.3
5.00 ug/L
50.00
38.0
5.00 ug/L
50.00
50.5
5.00 ug/L
50.00
30.0
5.00 ug/L
50.00
76.7
37-144
78.3
39-135
62.9
32-120
96.5
39-139
92.2
50-158
55.3
21-191
76.0
60-120
77.4
23-134
56.9
29-182
90.3
38-262
106
17-181
88.4
53-127
83.9
22-147
85.9
25-158
40.7
9-132
74.8
33-184
75.4
12-158
64.9
36-166
89.7
8-158
95.6
38-152
84.5
60-115
81.3
31-114
65.1
28-120
92.3
1-120
93.0
4-146
88.1
35-152
62.4
24-120
65.9
15-76
62.6
40-120
87.9
21-196
75.9
35-180
54.6
17-127
76.1
43-230
101
79-139
60.0
14-176
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
RPD
0.313 0.435 1.42 5.26 4.23 15.9 0.0526 4.03 6.85 8.40 0.0189 10.8 2.24 11.0 9.35 0.374 2.54 4.99 21.2 9.42 10.9 11.5 1.16 5.27 9.17 7.91 1.40 0.786 4.80 0.502 1.54 4.26 0.367 8.35 5.20
RPD Limit
30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30
Page 18 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Batch B304084
LCS Dup (B304084-BSD1) Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
Matrix Spike (B304084-MS1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
18.3
5.00 ug/L
50.00
46.6
5.00 ug/L
50.00
37.6
ug/L
50.00
18.1
ug/L
50.00
36.7
ug/L
50.00
36.4
ug/L
50.00
41.4
ug/L
50.00
39.1
ug/L
50.00
41.0
ug/L
50.00
36.5
5-120
1.74
30
93.3
52-120
4.61
30
75.2
60-140
36.2
60-140
73.5
60-140
72.7
60-140
82.8
60-140
78.1
60-140
82.0
60-140
Source: 2304016-09
39.8
5.05 ug/L
41.2
5.05 ug/L
57.4
5.05 ug/L
46.6
5.05 ug/L
56.6
5.05 ug/L
51.4
5.05 ug/L
66.6
5.05 ug/L
53.0
5.05 ug/L
47.6
5.05 ug/L
68.6
5.05 ug/L
53.2
5.05 ug/L
61.6
5.05 ug/L
70.6
5.05 ug/L
40.3
5.05 ug/L
57.7
5.05 ug/L
40.2
5.05 ug/L
30.8
5.05 ug/L
43.6
5.05 ug/L
38.6
5.05 ug/L
63.7
5.05 ug/L
40.9
5.05 ug/L
32.5
5.05 ug/L
40.8
5.05 ug/L
46.4
5.05 ug/L
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
78.8
47-145
81.6
33-145
114
27-133
92.3
33-143
112
17-163
102
24-159
132
35-219
105
11-162
94.2
17-168
136
33-227
105
26-137
122
59-121
140
39-171
79.7
21-133
114
54-120
79.6
44-142
61.1
37-144
86.3
39-135
76.5
32-120
126
39-139
81.0
50-158
64.3
21-191
80.8
60-120
92.0
23-134
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 19 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Batch B304084
Matrix Spike (B304084-MS1) 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10
Source: 2304016-09
43.2
5.05 ug/L
9.01
5.05 ug/L
64.9
5.05 ug/L
60.8
5.05 ug/L
20.6
5.05 ug/L
62.5
5.05 ug/L
19.5
5.05 ug/L
37.9
5.05 ug/L
42.9
5.05 ug/L
37.6
5.05 ug/L
52.9
5.05 ug/L
55.4
5.05 ug/L
60.0
5.05 ug/L
58.2
5.05 ug/L
38.2
5.05 ug/L
58.5
5.05 ug/L
56.0
5.05 ug/L
59.0
5.05 ug/L
42.9
5.05 ug/L
27.0
5.05 ug/L
41.7
5.05 ug/L
40.1
5.05 ug/L
41.0
5.05 ug/L
24.6
5.05 ug/L
45.8
5.05 ug/L
62.8
5.05 ug/L
51.3
5.05 ug/L
28.4
5.05 ug/L
52.4
5.05 ug/L
43.6
ug/L
21.9
ug/L
43.9
ug/L
44.6
ug/L
27.6
ug/L
52.9
ug/L
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
8.67
50.51
ND
50.51 50.51 50.51 50.51 50.51 50.51
85.6
29-182
17.8
38-262
129
17-181
120
53-127
40.8
22-147
124
25-158
38.6
9-132
75.0
33-184
84.9
12-158
74.5
36-166
105
8-158
110
38-152
119
61-106
115
31-114
75.7
28-120
116
1-120
111
4-146
117
35-152
84.9
24-120
53.5
15-76
82.6
40-120
79.5
21-196
81.2
35-180
48.7
17-127
90.7
43-230
124
79-139
102
14-176
39.0
5-120
104
52-120
86.4
60-140
43.3
60-140
86.9
60-140
88.2
60-140
54.6
60-140
105
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
RPD Limit
Page 20 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Batch B304084
Matrix Spike (B304084-MS1) Surrogate: Chrysene-D12
Matrix Spike Dup (B304084-MSD1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Source: 2304016-09
47.9
ug/L
Source: 2304016-09
38.1
5.00 ug/L
39.2
5.00 ug/L
55.1
5.00 ug/L
46.0
5.00 ug/L
55.5
5.00 ug/L
50.6
5.00 ug/L
65.6
5.00 ug/L
51.6
5.00 ug/L
46.8
5.00 ug/L
67.7
5.00 ug/L
51.1
5.00 ug/L
59.9
5.00 ug/L
67.9
5.00 ug/L
35.1
5.00 ug/L
55.6
5.00 ug/L
34.7
5.00 ug/L
31.5
5.00 ug/L
42.5
5.00 ug/L
37.0
5.00 ug/L
61.4
5.00 ug/L
38.9
5.00 ug/L
29.0
5.00 ug/L
38.2
5.00 ug/L
41.2
5.00 ug/L
37.3
5.00 ug/L
9.66
5.00 ug/L
60.9
5.00 ug/L
58.9
5.00 ug/L
20.2
5.00 ug/L
60.5
5.00 ug/L
17.5
5.00 ug/L
33.7
5.00 ug/L
50.51
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
94.9
60-140
76.2
47-145
4.36
78.5
33-145
4.98
110
27-133
3.99
91.9
33-143
1.40
111
17-163
1.87
101
24-159
1.40
131
35-219
1.52
103
11-162
2.68
93.6
17-168
1.60
135
33-227
1.31
102
26-137
3.88
120
59-121
2.81
136
39-171
3.97
70.3
21-133
13.6
111
54-120
3.70
69.4
44-142
14.7
63.0
37-144
2.06
85.0
39-135
2.45
74.0
32-120
4.27
123
39-139
3.58
77.7
50-158
5.16
57.9
21-191
11.5
76.3
60-120
6.66
82.3
23-134
12.0
74.7
29-182
14.6
19.3
38-262
6.96
122
17-181
6.44
118
53-127
3.22
40.4
22-147
2.14
121
25-158
3.18
35.0
9-132
10.9
67.5
33-184
11.5
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
RPD Limit
24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24
Page 21 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 NVOA GCMS - Quality Control
Analyte
Batch B304084
Matrix Spike Dup (B304084-MSD1) Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2304016-09
35.2
5.00 ug/L
50.00
ND
70.4
12-158
19.7
24
31.2
5.00 ug/L
50.00
ND
62.5
36-166
18.6
24
52.4
5.00 ug/L
50.00
ND
105
8-158
0.986
24
53.5
5.00 ug/L
50.00
ND
107
38-152
3.42
24
57.8
5.00 ug/L
50.00
ND
116
61-106
3.72
24
56.7
5.00 ug/L
50.00
ND
113
31-114
2.63
24
37.0
5.00 ug/L
50.00
ND
74.1
28-120
3.14
24
56.4
5.00 ug/L
50.00
ND
113
1-120
3.67
24
55.1
5.00 ug/L
50.00
ND
110
4-146
1.66
24
56.5
5.00 ug/L
50.00
ND
113
35-152
4.33
24
35.8
5.00 ug/L
50.00
ND
71.7
24-120
17.9
24
22.0
5.00 ug/L
50.00
ND
44.1
15-76
20.4
24
33.3
5.00 ug/L
50.00
ND
66.7
40-120
22.3
24
36.2
5.00 ug/L
50.00
ND
72.4
21-196
10.3
24
35.3
5.00 ug/L
50.00
ND
70.5
35-180
15.0
24
19.0
5.00 ug/L
50.00
ND
38.1
17-127
25.5
24
40.0
5.00 ug/L
50.00
ND
80.0
43-230
13.5
24
60.6
5.00 ug/L
50.00
ND
121
79-139
3.64
24
46.2
5.00 ug/L
50.00
ND
92.5
14-176
10.3
24
25.7
5.00 ug/L
50.00
8.67
34.1
5-120
9.82
24
50.6
5.00 ug/L
50.00
ND
101
52-120
3.62
24
39.8
ug/L
50.00
79.7
60-140
19.4
ug/L
50.00
38.8
60-140
37.9
ug/L
50.00
75.8
60-140
38.2
ug/L
50.00
76.3
60-140
27.2
ug/L
50.00
54.3
60-140
50.6
ug/L
50.00
101
60-140
46.5
ug/L
50.00
93.0
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 22 of 30
Analyte
Batch B304139 Blank (B304139-BLK1)
Oil & Grease
LCS (B304139-BS1) Oil & Grease
LCS Dup (B304139-BSD1) Oil & Grease
Matrix Spike (B304139-MS1) Oil & Grease
Matrix Spike (B304139-MS2) Oil & Grease
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 GC - Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 mg/L
26.8
5.00 mg/L
40.00
67
78-114
29.7
5.00 mg/L
40.00
74
78-114
10
20
Source: 2304016-08
34.9
5.00 mg/L
50.00
8.50
53
78-114
Source: 2304014-01
75.9
5.00 mg/L
81.63
ND
93
78-114
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 23 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Metals ICP - Quality Control
Analyte
Batch B304068 Blank (B304068-BLK1)
Chromium Copper Manganese Zinc
LCS (B304068-BS1) Chromium Copper Manganese Zinc
LCS Dup (B304068-BSD1) Chromium Copper Manganese Zinc
Matrix Spike (B304068-MS1) Chromium Copper Manganese Zinc
Matrix Spike Dup (B304068-MSD1) Chromium Copper Manganese Zinc
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 ug/L
--- U
10.0 ug/L
--- U
5.00 ug/L
--- U
20.0 ug/L
205
5.00 ug/L
200.0
205
10.0 ug/L
200.0
205
5.00 ug/L
200.0
201
20.0 ug/L
200.0
103
85-115
102
85-115
102
85-115
101
85-115
206
5.00 ug/L
200.0
207
10.0 ug/L
200.0
206
5.00 ug/L
200.0
203
20.0 ug/L
200.0
103
85-115
0.316
20
103
85-115
0.875
20
103
85-115
0.341
20
101
85-115
0.703
20
Source: 2304016-01
203
5.00 ug/L
246
10.0 ug/L
550
5.00 ug/L
249
20.0 ug/L
200.0
ND
200.0
18.6
200.0
351
200.0
54.0
102
80-120
114
80-120
99.7
80-120
97.7
80-120
Source: 2304016-01
200
25.0 ug/L
200.0
ND
100
80-120
1.48
10
232
50.0 ug/L
200.0
18.6
107
80-120
5.82
10
548
25.0 ug/L
200.0
351
98.7
80-120
0.366
10
253
100 ug/L
200.0
54.0
99.7
80-120
1.55
10
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 24 of 30
Analyte
Batch B304079 Blank (B304079-BLK1)
Mercury
LCS (B304079-BS1) Mercury
LCS Dup (B304079-BSD1) Mercury
Matrix Spike (B304079-MS1) Mercury
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Mercury CVAA - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
0.050 ug/L
0.974
0.050 ug/L
1.000
97.4
85-115
1.01
0.050 ug/L
1.000
101
85-115
3.63
20
Source: 2304016-01
1.00
0.050 ug/L
1.000
ND
100
80-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 25 of 30
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Sanitary - Quality Control
Analyte
Batch B304063 Blank (B304063-BLK1)
Biochemical Oxygen Demand
LCS (B304063-BS1) Biochemical Oxygen Demand
LCS (B304063-BS2) Biochemical Oxygen Demand
LCS Dup (B304063-BSD1) Biochemical Oxygen Demand
Matrix Spike (B304063-MS1) Biochemical Oxygen Demand
Matrix Spike Dup (B304063-MSD1) Biochemical Oxygen Demand
Batch B304064 LCS (B304064-BS1)
Nitrite [As N] Nitrate [As N]
LCS Dup (B304064-BSD1) Nitrite [As N] Nitrate [As N]
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
2.00 mg/L
196
mg/L
198.0
98.7 84.6-115.4
183
mg/L
198.0
92.4 84.6-115.4
178
mg/L
198.0
89.9 84.6-115.4 9.37
200
Source: 2304016-01
371
2.00 mg/L
264.0
76.9
111
75-125
Source: 2304016-01
297
2.00 mg/L
237.6
76.9
92.6
75-125
22.2
200
0.463 17.0
0.463 16.9
0.0500 0.500
mg/L mg/L
0.4560 16.50
0.0500 0.500
mg/L mg/L
0.4560 16.50
102
90-110
103
90-110
102
90-110
0
20
102
90-110
0.6
20
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 26 of 30
Analyte
Batch B304064 Matrix Spike (B304064-MS1)
Nitrate [As N] Nitrite [As N]
Batch B304067 Blank (B304067-BLK1)
Phosphorus
Blank (B304067-BLK2) Phosphorus
LCS (B304067-BS1) Phosphorus
LCS (B304067-BS2) Phosphorus
LCS Dup (B304067-BSD1) Phosphorus
LCS Dup (B304067-BSD2) Phosphorus
Matrix Spike (B304067-MS1) Phosphorus
Matrix Spike (B304067-MS2) Phosphorus
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2304016-01
0.470
0.0500 mg/L
0.255
0.0500 mg/L
0.2000
0.277
96
90-110
0.2000 0.0527
101
90-110
--- U
0.0500 mg/L
--- U
0.0500 mg/L
8.92
0.250 mg/L
8.450
106
90-110
9.03
0.250 mg/L
8.450
107
90-110
9.30
0.250 mg/L
8.450
110
90-110
4
20
9.17
0.250 mg/L
8.450
109
90-110
2
20
Source: 2304016-01
1.08
0.0500 mg/L
1.000
0.0533
103
90-110
Source: 2304024-05
1.05
0.0500 mg/L
1.000
ND
105
90-110
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 27 of 30
Analyte
Batch B304069 Blank (B304069-BLK1)
Residue, Non-Filterable
Blank (B304069-BLK2) Residue, Non-Filterable
LCS (B304069-BS1) Residue, Non-Filterable
LCS Dup (B304069-BSD1) Residue, Non-Filterable
Duplicate (B304069-DUP1) Residue, Non-Filterable
Batch B304071 LCS (B304071-BS1)
Fluoride
LCS Dup (B304071-BSD1) Fluoride
Matrix Spike (B304071-MS1) Fluoride
Batch B304072 Blank (B304072-BLK1)
Residue, Filterable
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
10.0 mg/L
--- U
10.0 mg/L
55.0
10.0 mg/L
55.10
99.8
85-115
55.0
10.0 mg/L
55.10
99.8
85-115
0.00
20
Source: 2304016-01
9.00
10.0 mg/L
9.00
0.00
20
4.51
0.0500 mg/L
4.860
93
90-110
4.54
0.0500 mg/L
4.860
93
90-110
0.7
20
Source: 2304016-01
11.2
0.500 mg/L
2.000
9.29
95
90-110
--- U
10.0 mg/L
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 28 of 30
Analyte
Batch B304072 Blank (B304072-BLK2)
Residue, Filterable
LCS (B304072-BS1) Residue, Filterable
LCS Dup (B304072-BSD1) Residue, Filterable
Duplicate (B304072-DUP1) Residue, Filterable
Batch B304081 Blank (B304081-BLK1)
Alkalinity Carbonate
Batch B304095 LCS (B304095-BS1)
Nitrogen, Total Kjeldahl
LCS Dup (B304095-BSD1) Nitrogen, Total Kjeldahl
Matrix Spike (B304095-MS1) Nitrogen, Total Kjeldahl
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
10.0 mg/L
444
10.0 mg/L
452.0
98.2
85-115
446
10.0 mg/L
452.0
98.7
85-115
0.449
20
Source: 2304016-01
2120
10.0 mg/L
2130
0.282
20
--- U
1.00 mg/L
13.2
0.200 mg/L
12.40
106
90-110
13.5
0.200 mg/L
12.40
109
90-110
2
20
Source: 2304016-01
17.3
1.00 mg/L
4.000
9.91
185
90-110
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 29 of 30
Analyte
Batch B304116 LCS (B304116-BS1)
Chemical Oxygen Demand
LCS Dup (B304116-BSD1) Chemical Oxygen Demand
Matrix Spike (B304116-MS1) Chemical Oxygen Demand
Batch B304119 Blank (B304119-BLK1)
Ammonia [As N]
Blank (B304119-BLK2) Ammonia [As N]
LCS (B304119-BS1) Ammonia [As N]
LCS Dup (B304119-BSD1) Ammonia [As N]
Matrix Spike (B304119-MS1) Ammonia [As N]
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: Crown Cork & Seal - 2304016
Project Number: 2304016 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
185
40.0 mg/L
194.0
96
90-110
208
40.0 mg/L
194.0
107
90-110
11
20
Source: 2304016-01
318
80.0 mg/L
50.00
231
174
90-110
--- U
0.100 mg/L
--- U
0.100 mg/L
7.67
0.100 mg/L
8.340
92
90-110
7.71
0.100 mg/L
8.340
92
90-110
0.5
20
Source: 2304016-01
6.06
0.100 mg/L
5.000
1.38
94
90-110
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 5/2/2023
Page 30 of 30
CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45, and IU Permit
Inspection Dates: April 12-13, 2023
8.0 Photographs
CROWN Cork & Seal, Nichols, NY 13812 40 CFR Parts 403 & 465.45, and IU Permit
Inspection Dates: April 12-13, 2023
Photo #1. A 24-hr composite sample was collected of the pretreated discharged effluent.
Photo #2. The magmeter monitors the effluent flow before reaching the sewer collection system.
