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CHEMICALS
DIVISION OF KMSER ALUMMUM & CHEMICAL CORPORATION 30100 CHAGRIN BOULEVARD. CLEVELAND OHO 44124
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Kaiser Aluminum & Chemical Corporation Airline Highway Gramercy, LA 70052 Tiaoe NM{Catenae Man*r Stnanpaf Fluorocarbon K-12
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Material or Component
NOTE: Average grade of commerce >99.9%.
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Revised 6/1/85
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(504) 355-1260 or (504) 869-5111
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I. INGREOIENTS
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Ingredient Dichlorodifluoromethane
CAS # 75-71-8
1984-85 ACGIH TLV*
1000 ppm
OSHA 1810.1000 TWA **
1000 ppm
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*TLV Threshold Limit Value
** TWA " Time Weighted Average
Mam) a (M Norma Cenoaanai:
Q Liquid Q Solid Q Git Q Other
pH - N/A
Melting Point Boding Point
II. PHYSICAL DATA
N/A
*F
21.6 - *F
Colorless, liquified compressed pas. Feint, ethereei odor.
Specific Gravity (HfO 1) 1.325 SoMXMyln water by weqM) 0X3
Vasor Rmmn (MBHytfVQ
2980mm 60*F
HI. PERSONAL PROTECTIVE EQUIPMENT
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TM l"lri) r"M`1,1,1 Alrtlno raeolrator or salLcontalned brMthlnf apparatus in concentration* greater titan 10 x TLV. Full face mask with organic vaoor cartridge for concentration uo to 10 x TLV.
C>ee and race
Monogoggles
Rubber gloves
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Sefety shoes if handling cylinders
IV. EMERGENCY MEDICAL PROCEDURES
INHALATION
Remove from contaminated area. Apply artificial respiration and oxygen if breathing stops. Gat medical attention. May cause asphyxiation.
SKIN CONTACT May cause frostbite. Flush with water. Get medical attention if reddening of skin develops.
EYE CONTACT May cause frostbite. Flush with water for 15 minutes. Get medical attention if irritation persists.
INGESTION
Get medical attention.
mcc Msec (uasi front
N/A " Not Applicable
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INHALATION
induce narcoiii in concentrations above 1000 PPM. Persons with cardiac arrhythmia may
be. at increased risk in severe exposures. May cause asphyxiation in high concentrations.
SKIN CONTACT Not readily absorbed through skin, but may causa frostbite if exposed to direct spray.
EYE CONTACT Mild to moderate irritant. May causa frostbite if exposed to direct spray.
INGESTION
Not likely. Low toxicity.
.--_______
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S J Rash Point
N/A f
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N/A
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UnMNtMl On heating to decomposition, may produce products such i
halogen acids and phosgene.
N/A * N/A %
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" ~ , ... N/A N/A
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0 Stable Q Unstable
Slight hydrolysis with water.
Contact with open flame. E
Phosgene or halogen adds in pretence of high temperature or open flame.
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VI. ENVIRONMENTAL.
Jspin or leek procedures
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: We recommend that the purchaser establish a spill prevention, control and countermeasure plan. This plan should include
procedures for proper storage as well as dean-up of spills and leaks. The procedures should conform to safe practices and
provide for proper recovery or disposal. Depending on the quantity spilled, notification of the National Response! Canter
(800/424*8802) may be required in the case of hazardous substances. (See EPA, DOT and various state and local regulations.)* 1 2 3 4 5
Waste Oisposal Method'
Used r unused product should be tested to determine hazard status and disposal requirements under federal, sms and
local laws and regulations.
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`Disposer must comply with federal, state and local disposal or discharge laws.
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1. Use local exhaust to reduce concentration.
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2. Store in well-ventilated, dry area (below 125*F). Contact with flames or high heat should be avoided.
3. K-12 is shipped in steel cylinders as a liquified gas under its own vapor pressure of about 70 PSIG at 70F.
4. High pressure cylinders should not be exposed to high temperatures or pressures because of the increased risk of pressure-
induced cylinder explosions.
5. DOT Proper Shipping name is "Dichlorodifluoromethane (R-12)"; Nonflammable gas.
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