Document GmjN6pz3w0Mp79owXrzYRxOLq

A.**GENERAl INFORMATION TRADE NAME (COMMON NAME) ACUMIST A-12 & A-18 Polyethylene CHEMICAL NAME AND/OR SYNONYM Polyethylene FORMULA CH3(CH2>m(CH2COOH)n ALLIED-SIGNAL INC. A-C Polyethylene P.O, Box 2332R Morristown, N.J. 07960 CONTACT Product Safety ADDRESS (No,, STREET, CITY, STATE AND ZIP CODE) PHONE NUMBER (201)455-3311 gCAS NO ALLIED PRODUCT CODE # 68441 17-8 MOLECULAR WEIGHT Polymeric >2000 LAST ISSUE DATE CURRENT ISSUE DATE January 1, 1988 B. JftFIRSTAID MEASURES Inhalation: Remove to fresh air. Eye contact mechanical irritation' Wash with water 15 minutes. If irritation persists, consult physician. t EMERGENCY PHONE NUMBER (201) 455-2000 (^HAZARDS INFORMATION HEALTH inhalation Treat as nuisance dust. Avoid breathing fumes from molten material. INGESTION No effects known. Acute oral toxicity in rats: LD50 >2500 mg/kg. Tkin ~~ ~ ~ ~ ' " " ----------------------------------------------------------- Negligible primary irritant. EVES DO 085824 ------------------------------------------------- "--------------------------------------------------- rriNcrncMT ------------ J '* r ai awl -------------- Non-eye irritant. Dust may cause mechanical irritation. PERMISSIBLE CONCENTRATION AIR (SEE SECTION J) Recommend using the value established for nuisance dust (10 mg/m3 of total dust). "unusual chronic toxicity ~ `~ "~ ------ ---------- No known hazards in the customary industrial use of these products. BIOLOGICAL None established. CC124.395 (11/84) 1N D = NOT DETERMINED N A - (MOT APPLICABLE C. ^HAZARDS (Cont.) FIRE AND EXPLOSION FLASHPOINT KOpen Cup >293 OC QclOSeocup AUTO IGNITION TEMPERATURE None known or V flammable limits in air ix by vol.) LOWER - NA UPPER - NA UNUSUAL FIRE AND EXPLOSION HAZARDS cFi.re DPoin*t >3I70fC. .M.elts in proximity to fires causing s.l.ippery floors and, stairs. Static charges on the powders or the powders dispersed in liquids may ignite flammable atmospheres. High levels of product dust in the atmosphere may present a dust explosion hazard. Appropriate precautions should be observed. L **fRECAUTIONS/PROCEDURES fire extinguishing agents recommended Carbon Dioxide or Dry Chemical. FIRE EXTINGUISHING AGENTS TO AVOID Water stream on molten burning material may scatter and spread fire. * SPECIAL FIRE FIGHTING PRECAUTIONS Wear self contained breathing apparatus approved by NIOSH. Watch footing on floors and stairs because of possible melting and spreading Use spray to keep containers cool VENTILATION ' If dusty conditions pievail, use local exhaust. In the vicinity of heating processes, use local exhaust. For storage and ordinary handling, general ventilation ,s adequate, NORMAL HANDLING Use local exhaust during heating processes or if dusty conditions prevail when handling. Very slippery on floors, avoid spillage. Use good personal hygiene and housekeeping. STORAGE Avoid excessive heat. SPILL OR LEAK (ALWAYS WEAR PERSONAL PROTECTIVE EQUIPMENT - SECTION E) ' Sweep up with a minimum of dusting, remove ignition sources. Keep away from heat or flame. Collect in container, e.g., fiberboard drum or carton SPECIAL PRECAUTIONS PROCEDURES'LABEL INSTRUCTIONS SIGNAL WORD - NA Avoid conditions that create high levels of product in the air in a closed room as a dust explosion hazard can exist. E. PERSONAL PROTECTIVE EQUIPMENT RESPIRATOR V PROTECTION Use a NIOSH approved dust respirator if dusty conditions prevail. During melting or conveying in molten state use an organic vapor respirator. E VES AND face Chemical goggles around molten material and in dusty conditions. HANDS, ARMS AND BODY Protective garments around molten material. other Clothing and equipment Protective garments around molten material. 2 confTDFNTM( ramn mm MATERIAL IS (AT NORMAL CONDITIONS!: APPEARANCE AND ODOR LIQUID a SOLID . BOILING POINT MELTING POINT SOLUBILITY IN WATER 1% by Weight) Negligible DGAS White waxy powder. Characteristic waxy odor. NA C (Soft. Pt.) 137 C SPECIFIC GRAVITY (H2O 11 pH 0.99 Not applicable VAPOR DENSITY (AIR * 1) Not applicable VAPOR PRESSURE (mm Hgl 20CI (PSIGlD Negligible @ ambient EVAPORATION RATE (Butyl Acetete fc 1) Q (Ether = 1 >Q Not applicable % volatiles by volume IAi 20CI Not applicable G. REACTIVITY OATA STABILITY UNSTABLE STABLE CONDITIONS TO AVOID Excessive heat, although relatively stable as are other polyethylenes. Avoid direct contact with open flame. INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizing agents and amines, although relatively stable as are other polyethylenes. HAZARDOUS DECOMPOSITION PRODUCTS Depends on condition of fire. For polyethylenes m general, CO, CO2 and varjous oxidized and non-oxidized hydrocarbons are present. HA2ARDOUS POLYMERIZATION CONDITIONS TO AVOO MAY OCCUR None El WILL NOT OCCUR H. ^AZARDOUS INGREDIENTS (Mixtures Only) MATERIAL OR COMPONENT/C.A.S. = NA WT. % NA HAZARD DATA (SEE SECT J) NA CC-134-395 (11/84) DO 085826 CONFIDENTIAL '* PROPRIETARY - TRADE SECRET I. ENVIRONMENTAL DEGRADABILITY AQUATIC TOXICITY Not considered biodegradable. Not toxic. OCTANOL/WATER PARTITION COEFFICIENT NA (Insoluble in Water) EPA nP HAKAZuARDOUSA^STUBccSrT-TAN\CE ' Ur"1 YES ES NQ IF SO REPORTABLE QUANTITY # VASTE DISPOSAL METHODS (DISPOSER MUST COMPl> WITH FEDERAL STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS) Discard as harmless organic waste. Keep out of streams. Incinerate in properly engineered facility. 40 CFR 116 117 RCC A S'AT^S . \_SE C MATERIAL IF p,SC AfiQEC Non-hazardous. J. **REFERENCES PERMISSIBLE CONCENTRATION REFERENCES TLV . ACGIH List. 1984 -85, Entry for Nuisance Dusts, Appendix D, HAZARDOUS WASTE NUMBER (IF APPLICABLE! 40 CFR 261 REGULATORY standards DOT CLASSIFICATION Some states legulate the discharge of polyethylene powder to streams. Same as polyethylene, NIOSH registry sequence #TQ33250. FDA: see below. general Not Regulated Fire: N.B.F.U. Research report no. 1 "Fire Hazards of the Plastics Manufacturing Industries." Health; See NIOSH Registry reference above. 49 CFR 173 K.tia>ADOIT!ONALiNFORMATION Fire Allied Technical Data Bulletin1 Cleveland Open Cup Flash & Fire Points. Typical Properties. Allied Technical Data Bulletin. FDA- Allied Technical Data Bulletin. HMIS Code: Health Flammability Reactivity 0 1 0 - Under the criteria established for hazardous chemicals in SARA/TITLE III Section 311/312/313 and the OSHA Hazardous Communication Act, these materials are considered non-hazardous. -- These materials are included in the TSCA Chemical Inventory. DO 085877 CONFTDFNTIAL PSDS FILE NO. -1138 c A. ^GENERAL INFORMATION TRADE NAME (COMMON NAME! ACUMIST B-6, B-12, C-5. C-12, C 18 Polyethylene chemical name and/or synonym Polyethylene FORMULA (C2H4)n ALLIED-SIGNAL INC. A-C Polyethylene P.O. Box 2332R Morristown, N.J. 07960 CONTACT Product Safety ADDRESS (No . STREET, CITY, STATE AND ZIP CODEI PHONE NUMBER (201) 455-3311 0CAS NO ALLIED PRODUCT CODE # 9002-88-4 MOLECULAR WEIGHT Polymeric > 1,000 last issue date CURRENT ISSUE DATE January 1, 1988 B. *$IRSToAID MEASURES Inhalation, Remove to fresh air. Eye contact mechanical irritation: Wash with water 15 minutes If irritation persists, consult physician. emergency phone number (201)455*2000 C. ^HAZARDS INFORMATION HEALTH INHALATION Treat as nuisance dust. Avoid breathing fumes from molten material. INGESTION No effects known Acute oral toxicity in rats. LD50 > 2500 mg/kg. SKIN Mifd dermal irritant. eyes .......... ............................... DO 085828 CONF JDFNTTAl ------------- ---------------------- Non-eye irritant. Dust may cause mechanical irritation. PERMISSIBLE CONCENTRATION AIR (SEE SECTION J) _ . ... Recommend using the value established for nuisance dust. (10 mg/m3 of total dust) BIOLOGICAL None established. unusual chhunic ioxici 1 Y ----------------------------- ------------------------------------------------------------- No known hazards in the customary industrial use of these products. ND = NOT DETERMINED 1 NA = NOT APPLICABLE C. ""HAZARDS (Cant) FIRE AND EXPLOSION FLASHPOINT SOPENCUP >300OC QCLOSEDCUP AUTO IGNITION TEMPERATURfc None known OC FLAMMABLE LIMITS IN AIR [% BY VOL.) LOWER - N.A. UPPER - n.A, unusual fire and explosion hazards pjre p0jnt >3i3c, Melts in proximity to fires causing slippery floors and stairs. Static charges on the powders or the powders dispersed in liquids may ignite flammable atmospheres. High levels of product dust in the atmosphere may present a dust explosion hazard. Appropriate precautions should be observed. i. **>RECAUTIONS/PROCEOURES FIRE EXTINGUISHING AGENTS RECOMMENDED Carbon Dioxide or Dry Chemical. FIRE EXTINGUISHING AGENTS TO AVOID Water stream on molten burning material may scatter and spread fire. SPECIAL FIRE FIGHTING PRECAUTIONS Wear self-contained breathing apparatus approved by NIOSH. Watch footing on floors and stairs, because of possible melting and spreading. Use spray to keep containers cool. VENTILATION Use local exhaust during heatmg processes or if dusty conditions prevail when handling. For storage and ordinary handling, general ventilation is adequate. NORMAL HANDLING Avoid breathing for extended or repeated periods. Avoid breathing fumes from heating operations. Very slippery on floors, avoid spillage. Use good personal hygiene and housekeeping. STORAGE Avoid excessive heat. $pILL OR LEAK (ALWAYS WEAR PERSONAL PROTECTIVE EQUIPMENT - SECTION E) Sweep up with a minimum of dusting. Remove ignition sources. Keep away from heat or flame. Collect in container, e.g., fiberboard drum or carton. special PRECAUTIONS procedures label instructions SIGNAL WORD - N A Avoid conditions that create high levels of product in the air in a closed room as a dust explosion hazard can exist. E. PERSONAU>ROTECTIVE EQUIPMENT "ESP'RA~tr, ppc'ECTiDN Use a NIOSH approved dust respirator when dusty conditions prevail. During melting or conveying in molten state use an organic vapo' respirator E ' E S A \ 0 f - CE .-- -- " '' -- Chemical goggles around molten material and in dusty conditions. HANDS ARMS AND BOOT Protective garments around molten material. OTHER clothing and equipment Protective garments around molten material. DO 085829 CONFIDENTIAL 2 F. '-* PHYSICAL DATA G. REACTIVITY DATA STABILITY UNSTABLE B STABLE CONDITIONS TO AVOID Excessive heat, although relatively stable as are other polyethylenes. Avoid direct contact with open flame. INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizing agents, although relatively stable as are other polyethylenes. HAZARDOUS DECOMPOSITION PRODUCTS Depends on condition of fire. For polyethylenes in general, CO, CO2 and various oxidized and non-oxidized hydrocarbons are present. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID D MAY OCCUR B WILL NOT OCCUR None AZARDOUS INGREDIENTS (Mixtures Only) MATERIAL OR COMPONENT/C.A.S. * WT. % HAZARD DATA (SEE SECT J) N.A. N.A. N.A. CC124-394 (11/84) DO 085830 CONF T DFNT T AL * - PROPRIETARY - TRADE SECRET 3 I. ENVIRONMENTAL DEGRADABILITY/AQUATIC TOXICITY Not considered biodegradable. Not toxic. OCTANOL/WATER PARTITION COEFFICIENT N.A. (Insoluble in Water) EPA HAZARDOUS SUBSTANCE* ,r+, r AA. .A.ATr n a ^-r e-r^-r - <, |l--|1 t tS K1X71J NO _IF SO, RoEcPhOrtRnTTA.BnL,EroQMUA.N.,TTIT,Y^, # WASTE DISPOSAL METHODS (DISPOSER MUST COMPLY WITH FEDERAL STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS) Discard as harmless organic waste. Keep out of streams. Incinerate in properly engineered facility. 40 CFR 116-117 RCRA STATUS OF UNUSED MATERIAL IF DISCARDED Non-hazardous. J. ^DEFERENCES permissible concentration references TLV: ACGIH List, 1984-85, Entry for Nuisance Dusts, Appendix D. HAZARDOUS WASTE NUMBER (IF APPLICABLE) 40 CFR 261 REGULATORV standards DOT classification Some states regulate the discharge of polyethylene powder to streams. Same as polythylene, NIOSH registry sequence AFTQ33250. FDA: see below. Not Regulated general Fire: N.B.F.U. Research report no 1 "Fire Hazards of the Plastics Manufacturing Industries." Health: NIOSH Registry reference above. 49 CFR 173 K. ADDITIONAL INFORMATION Fire: Allied Technical Data Bulletin: Cleveland Open Cup Flash & Fire Points. Typical Properties: Allied Technical Data Bulletin. FDA: Allied Technical Data Bulletin. HMIS Code: Health Flammability Reactivity 0 1 0 - Under the criteria established for hazardous chemicals in SARA/TITLE III Section 311/312/313 and the OSHA Hazardous Communication Act, these materials are considered non-hazardous. -- These materials are included in the TSCA Chemical Inventory. 00 085831 C0NFID8NT7AI PSDS FILE NO. - 1137 \Lt?ltD'CORPORAfib>TPfiOVTDeSNOVARRANfES.-CITHER'XPRES$ dR 1MPLIED,3VND ASSUMES NO RESPONSIBILITY ip rFr O--R-I JTWHEAACCCCUURRAAC_V_iiOR C__O_M__P_L__E_T_E__N_E__S_S__O_ Fijr-H_E.bATACONTAINEP HEREIN. ...... ........................... " ............ 4 ALLIED CORP. A-C POLYETHYLENE O. ACX-0011 Exp. A-C Polyethylene A. ^GENERAL INFORMATION TRADE NAME (COMMON NAME OR SYNONYM) ACX-0011 * CHEMICAL NAME x2 CAS NO. allied PRODUCT CODE ACX-0011 Modified Polyethylene on Calcium Silicate formula MOLECULAR WEIGHT CH3(CH2)nCH3 Modified ADDRESS INo , STREET. CITY, STATE ANDZIPCODEl Allied Corporation, A-C Polyethylene P.0. Box 2332R Morristown, NJ 07960 CONTACT PHONE NUMBER Supervisor - Technical Support (201) 455-2783 Polymeric >1500 |ISSUED DATE | REVISED DATE November, 1983 B.^NFIRST*A1D MEASURES EMERGENCY Phone number Inhalation: Remove to fresh air. v(2C1) 455-2000 Eye contact mechanical irritation: Wash with water 15 minutes. If irritation persists, consult physician. C.^MMAZARDSiNFORMATiON HEALTH INHALATION '----- Treat as a nuisance dust. Avoid breathing fumes from molten material. ingestion No effects known. LD^q ^1000 mg/kg for comparable products. No known hazards in the customary industrial use of these products. Dust may irritate. CA PERMISSIBLE CONCENTRATION AIR ISEE SECTION J> Recommend using the value established for nuisance _____dust (lO.mg/m of total dust) . __________________ L'.I'SLAL LmRONIC TOXICITY " BIOLOGICAL None Established No known hazards in the customary industrial use of these products. CC174 7 PI C. HAZARDS (Cont) FIRE AND EXPLOSION FLASH POINT, >263 C AUTO IGNITION TEMPERATURE C FLAMMABLE LIMITS IN AIR (\ BY VOL > Non-Volatilf Kopencup CLOSED CUP None Known .' LOWER:' Not Applicable UPPER:Solid >1 'SUAL FIRE AND EXPLOSION HAZARDS 'fire point >282C. Static charges on powders or powders dispersed in liquids may Ignite flammable atmospheres and appropriate precautions should be observed. i. hPRECAUTIONS/PROCEDURES FIRE EXTINGUISHING AGENTS RECOMMENDED Carbon Dioxide or Dry Chemical. . FIRE EXTINGUISHING AGENTS TO AVOID Water stream on molten burning material may scatter and spread fire. SPECIAL FIRE FIGHTING PRECAUTIONS Wear self-contained breathing apparatus approved by NIOSH. Watch footing on floors and stairs because of possible melting and spreading. Use water spray to keep containers cool._________________________ VENTILATION If dusty conditions prevail, use local exhaust. In the vicinity of heating processes, use local exhaust, for storage and ordinary handling, general ventilation is adequate. ........... . ' '* ' - - -1 - J * 1- normal HANDLING Avoid breathing for extended or repeated periods. 1 iiV Avoid breathing fumes from Heating operations. Very slippery on floors, avoid spillage. Use normal personal jh^giene.and bnuseVpppjng.----------------------------------------------------------------------------------------------------- Avoid excessive heat. Do not store" near amines. SPILL OR LEAK ' Sweep up with a minimum of dusting, removing ignition sources. heat or flame. Collect in container, eg. fiberboard. """ " Keep away from SPECIAL PRECAUTIONS'PROCEDURES/LABEL INSTRUCTIONS Handle as waxes in general. E^^PERSONAtfROTECTIVE EQUIPMENT ~ RESPIRATORY PROTECTION If dusty conditions prevail, use special (mechanical) respirator. During melting or conveying in molten state use organic vapor respirator. EYES AND FACE Chemical goggles around molten material and in dusty conditions. HANDS. ARMS, AND BODY i Protective garments required around molten material. OThER~CLOTMING and equipment Protective garments required around molten material. 00 085833 C0HFTDFNT1AI. 2 T. rg PHYSICAL DATA MATERIAL IS (AT NORMAL CONDITIONS) LIQUID Pt SOLID GAS _ ... BOILING POINT Non-Applicable c APPEARANCE AND ODOR Modified Polyethylene on Calcium Silicate Characteristic dor, - SPECIFIC GRAVITY (H20- II VAPOR DENSITY (AIR'D MELTING POINT , ,, 86 Active Component SOLUBILITY IN WATER (* by Wi(fit) (Solid) pH Active Component 0.89 Not Applicable VAPOR PRESSURJE (mm Hg at 20 Cl \ (PSIG)D Negligible Not Applicable Negligible Ambient EVAPORATION RATE (Butyl Acetate * 1) (Ether - 11 Not Applicable % VOLATILES BY VOLUME (At 20 Cl Not Applicable G. 'KREACTIVfTY DATA STABILITY UNSTABLE 3L STABLE INCOMPATIBILITY IMATERIALS TO AVOID) CONDITIONS TO AVOID................ Excessive beat, although relatively 6table as other polyethylene. Strong oxidizing agents, although relatively stable as other polyethylenes. HAZARDOUS DECOMPOSITION PRODUCTS Depends on condition of fire* For polyethylenes in general, as reported CO, CO2 and various oxidized and non-oxidized hydrocarbons are present. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID MAY OCCUR x WILL NOT OCCUR Avoid direct contact with open flame. H. ^HAZARDOUS INGREDIENTS (Mixtures Only) - Not Applicable MATERIAL OR COMPONENT/C.AS. WT. % HAZARD DATA (SEE SECT. J) DO 085834 CONFTDFNTTAl. 3 MRDNMENTAL DEGRADABILITy/AOUATIC TOXICITY Not considered biodegradable. 01 OCTANOL/WATER PARTITION COEFFICIENT DNA (Insoluble in Water) EPA HAZARDOUS SUBSTANCE' .D Jfl VE5 NO IF SO. REPORTABLE QUANTITY: * WASTE DISPOSAL METHODS (DISPOSER MUST COMPLY WITH FEDERAL. STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS) Discard as harmless organic waste. Keep out of streams. May dog.. Incinerate in properly engineered facility. 40 CFR iie ii7 RCRA STATUS OF UNUSED MATERIAL Non-Hazardous J. -REFERENCES PERMISSIBLE CONCENTRATION references TLV: ACGIH List, 1983-84, Entry for Nuisance Dusts, Appendix D. 40 CFR 261 REGULATORY STANDARDS D O.T. CLASSIFICATION Not Regulated Some states ..regulate the discharge of polyethylene .powder to streams. Same as polyethylene, NIOSH registry sequence #TQ33250. 49 CFR GFNERAL Fire: N.B.F.V. Research report No. 1 "Fire Hazards of the Plastics Manufacturing Industries." Health: See NIOSH Registry reference above. K/33ADDITI0NAL4NF0RMATI0N 4 Provisional/Experimental TECHNICAL DATA A-C' POLYETHYLENES ------------------------ CONTACT: Product Safety (201) 455-4414 SAFETY INFORMATION ON EXPERIMENTAL POLYMER A-C*X B243 This polymer is an experimental material which is regulated by 15 USC 2604 (Section 5 of the Toxic Substances Control Act). It Is not currently on the Toxic Substances Control Act Inventory of Chemicals in Commerce and may be used only for R&D purposes. Please assure that the work done on this material is supervised by a technically qualified person and that all persons engaged in experimentation, research or analysis on this material are notified of the following risk information to ensure proper handling in conformance with the OSHA Hazard Communication Standard. Product Name: A-C*X B243 CAS Number: 41525-41-1 Description: Ethylene-Acrylic Acid-Methyl acrylate Terpolymer. Health Hazards: None known. Avoid contact with solid, molten material, and fumes from molten material. First Aid: In case of contact with eyes: Flush with water. If swallowed: No effects known. If Inhaled: Treat as nuisance dust. Avoid breathing fumes from molten material as product may contain small amounts of unreacted monomers with TWA values of 10 ppm. Remove to fresh air. TLV: Not available. Physical Hazards: None known. In Case of Fire: Use dry chemical or carbon dioxide. Water may scatter molten burning material. Normal Handling: Personal Protective Equipment: Selected Physical Properties: Hazardous Ingredients: In Case of Spill: Handle as a polymeric wax. Melt material in ventilated area. Chemical goggles and protective garments i.e. gloves around molten material. Use approved dust respirator if dusty conditions prevail. Solid. Melting Point about 80C None Sweep up and avoid dusting. TJO 085836 CONF7DFNTIAI NOTICE: All statements, Information, and data given herein are believed to be accurate and reliable but are presented without guaranty, warranty, or responsibility of any kind, express or Implied. Statements or suggestions concerning possible use of our products are made without representation or warranty that any such use Is free of patent infringement, and are not recommendations to infringe any patent. The user should not assume that all safety measures are indicated, or that other measures may not be required. The Information, and dataIn this brochure relate to a provisional or experimental product. We believe the technical data Is typical, but It may not apply to all products. The data may be changed without notice, and this product may be withdrawn at any time. P/X-,_____ 2/B8 PRINTED IN U.SA 1909 ALLIED-SIGNAL INC. MATERIAL SAFETY DATA SHEET ADVASTAB TM--948 * Heat: Stabilizer Norton Thiokol, Inc. Carstab Division 2000 West Street Cincinnati, Ohio 45215 I. PRODUCT IDENTIFICATION Emergency Phone No. General Information MSDS Reference No. Rev. Date 11/15/85 513-733-2218 513-733-2100 6224 Rev. No. 1 Product name: Chemical name: Chemical family: ADVASTAB1 IM-948 Heat Stabilizer Mixture Alkyltin mercaptoacid ester HAZARDOUS CONSTITUENTS CAS No. Chemical 57583-35-4 Dimethyltin bis(2-ethylhexylthioglycolate) 57583-34-3 Methyltin tris(2-ethylhexylthioglycolate) Proprietary organotin Hazard Data TLV tin-skin, 0.1 mg/mj TLV tin-skin, 0.1 mg/m 3 J.LV tin-skin, 0.1 mg/m 3 PHYSICAL DATA Boiling point: Vapor pressure: HzO solubility: Viscosity: >430F (decom.) <1 mm 3 20C Insoluble 70 cs 0 25C Melting point: Vapor density (air=l): % volatiles by wt.: Specific gravity: Not applicable 4.5 4 0 110C 1.17 0 25C Appear. & odor: Clear colorless to pale yellow liquid with slight mercaptan odor IV. FIRE AND EXPLOSION HAZARD DATA Dq COhjpr 0f5^037 TFNTTAl Flash point (method used) Flammable limits in air : Extinguishing media: Fire fighting procedures: Fire & explosion hazards: 250F (Setaflash - AS1W D3278-78) Unknown Carbon dioxide, water for or foam Self-contained breathing apparatus with full facepiece in positive pressure mode and impervious suit On burning, may produce irritating or toxic vapors including hydrocarbons, organotins and oxides of carbon and sulfur. ADVASTAB B4-948 Beat Stabilizer Pag 2 MSDS Reference No. 6224 11/15/85 Morton Thiokol, Inc. Carstab Division 513-733-2100 V. HEALTH HAZARD INFORMATION Health Hazard Data Baaed on animal studies of a similar product. No human exposure data. TLV: 0.1 mg tin/m3, tin-skin PEL: 0.1 mg tin/mJ, tin-skin LD50: LC50: oral, 1100 mg/kg (rat) dermal, 2150 male and 1000 female mg/kg (rabbit) 240 mg/1 for 1 hour; aerosol (rat) Skin Irritation Index (rabbit): 2.36 (not primary irritant) Eye Irritation Index (rabbit): Not an eye irritant Effects of Overexposure Inhalation: Skin contact: Skin absorption: Eye contact: Ingestion: Chronic: May cause headache, nausea and/or irritation of throat (coughing) or skin (itching). May cause reddening of the skin (erythema), spelling (edema) and irritation (dermatitis). May cause shaking, loss of coordination, ataxia and hypersensitivity. Not an irritant (see above) but good hygiene dictates avoiding any eye contact. May cause depression, excessive salivation, diarrhea, eye and nasal discharge. No known human exposure data. The no-toxic effect level in the diet of rats = 100 ppm in sub-chronic (90 day) toxicity studies. Kidney damage appeared at 300 ppm. Emergency First Aid Procedures Eyes: Skin: Inhalation: Ingestion: Flush with water for 15 minutes. Obtain medical attention. Wash immediately with soap and water. Remove contaminated clothing. Obtain medical attention if contact was prolonged or extensive. Remove to fresh air. Obtain medical attention if any irritation develops. Obtain medical attention immediately. DO 085838 CONFIDENTIAL ADVASTAB TO-348 Heat Stabilizer Page 3 MSDS Reference No. 6224 11/15/85 Norton Xhiokol, Inc. Carstab Division 513-733-2100 VI. REACTIVITY DATA Stability of compound: Chemical incompatibility: Decomposition products: Hazardous polymerization: Stable Compatible with other stable compounds. Hydrocarbons, organotins and oxides of carb n and sulfur may be produced when burned. Will not occur. VII. SPILL OR LEAK PROCEDURES If material is spilled: Spills may be removed with any absorbent: sand, sponge, cloth, paper, etc. Use detergent with water for final cleanup. Wear prescribed protective equipment (see section VIII) to prevent vapor inhalation or skin contact. Waste disposal method: Place absorbed material in an appropriate, closed container for disposal of in accordance with local, state and federal regulations. Reportable quantities: Not applicable VIII. SPECIAL PROTECTION INFORMATION Ventilation requirements: Adequate to prevent vapor accumulation & keep below TIV/PEL. Equipment Respiratory: If vapors are irritating, wear NIOSH-approved cartridge respirator with organic vapor cartridges. Where large vapor concentrations are suspected, wear NIOSH-approved air-supplied breathing equipment. Eye: Safety goggles (and/or safety glasses) and face shield Gloves: Rubberized gloves Other: Impervious suit or rubber apron DO 085839 CONFIDENTIAL ADVASTAB* TM-948 Heat Stabilizer Page 4 MSDS Reference No. 6224 11/15/85 Morton Thiokol, Inc. Carstab Division 513-733-2100 IX. SPECIAL PRECAUTIONS Do not take internally. Store in cool, dry location. For industry use only. Keep away from children. Remove contaminated clothing immediately and launder before reuse. Contaminated shoes and gloves should be destroyed. For MSDS information contact John L. Hanley, 513-733-2127. "To the best of our knowledge the information contained herein is correct. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. Users of any chemical should satisfy themselves that the conditions and methods of use assure that the chemical is used safely. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION CONTAINED HEREIN OR THE CHEMICAL TO WHICH THE INFORMATION REFERS." DO 085840 CONFTDFNTTAl MATERIAL SAFETY DATA. SHEET ADVASTAB TM--2080 Heat Stabilizer . Morton Thiokol, Inc. Carstab Division 2000 West Street Cincinnati, Ohio 45215 I. PRODUCT IDENTIFICATION Emergency Phone No. General Information MSDS Reference No. Rev. Date 11/15/85 513-733-2218 513-733-2100 6220 Rev. No. 1 Product name: Chemical name: Chemical family: ADVASTAB TW-2080 Heat Stabilizer Mixture Alkyltin mercaptoacid ester II. HAZARDOUS CONSTITUENTS CAS No. Chemical 26636-01-1 Dimethyltin bis(2-ethylhexylthioglycolate) 54849-38-6 Methyltin tris(2-ethylhexylthioglycolate) Hazard Data TLV tin-skin, 0.1 mg/m3 TLV tin-skin, 0.1 mg/m3 III. PHYSICAL DATA Boiling point: Vapor pressure: HzO solubility: Viscosity: >430F (decom.) <0.5 mm @ 25C Insoluble 50 cs 6 25C Melting point: Vapor density (air=l): X volatiles by wt.: Specific gravity: Not applicable 4.5 3 e 110C 1.17 6 25C Appear. & odor: Clear colorless liquid with slight mercaptan odor FIRE AND EXPLOSION HAZARD DATA Flash point (method used) Flammable limits in air : Extinguishing media: Fire fighting procedures: Fire & explosion hazards: 260 F (Setaflash - ASTM D3278-78) Unknown Carbon dioxide, water fog or foam Self-contained breathing apparatus with full facepiece in positive pressure mode and impervious suit On burning, may produce irritating or toxic vapors including hydrocarbons, organotins and oxides of carbon and sulfur. DO 085841 CONFIDENTIAL. ADVASTAB IM-2080 Heat Stabilizer Page 2 MSDS Referenc No. 6220 11/15/85 Morton Thiokol, Inc Carstab Division 513-733-2100 V. HEALTH HAZARD INFORMATION Health Hazard Data Based on animal studies of a similar product. No human exposure data. TLV: 0.1 mg tin/m3, tin-skin PEL: 0.1 mg tin/m3, tin-skin LD50: LC50: oral, 1100 mg/kg (rat) dermal, 2150 male and 1000 female mg/kg (rabbit) 240 mg/1 for 1 hour; aerosol (rat) Skin Irritation Index (rabbit): 2.36 (not primary irritant) Eye Irritation Index (rabbit): Not an eye irritant Effects of Overexposure Inhalation: Skin contact: Skin absorption: Eye contact: Ingestion: Chronic: May cause headache, nausea and/or irritation of throat (coughing) or skin (itching). May cause reddening of the skin (erythema), swelling (edema) and irritation (dermatitis). May cause shaking, loss of coordination, ataxia and hypersensitivity. Not an irritant (see above) but good hygiene dictates avoiding any eye contact. May cause depression, excessive salivation, diarrhea, eye and nasal discharge. No known human exposure data. The no-toxic effect level in the diet of rats = 100 ppm in sub-chronic (90 day) toxicity studies. Kidney damage appeared at 300 ppm. Emergency First Aid Procedures Eyes: Skin: Inhalation: Ingestion: Flush with water for 15 minutes. Obtain medical attention. Wash immediately with soap and water. Remove contaminated clothing. Obtain medical attention if contact was prolonged or extensive. Remove to fresh air. Obtain medical attention if any irritation develops. Obtain medical attention immediately. ) .1 DO 08584? CONFTOENTTAI ADVASTAB IM-2080 Heat Stabilizer Page 4 MSDS R ference No. 6220 11/15/85 Morton Thiokol, Inc. Caratab Division 513-733-2100 IX. SPECIAL PRECAUTIONS Do not take internally. Store in cool, dry location. For industry use only. Keep away from children. Remove contaminated clothing immediately and launder before reuse. Contaminated shoes and gloves should be destroyed. For MSDS information contact John L. Hanley, 513-733-2127. "To the best of our knowledge the information contained herein is correct. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. Users of any chemical should satisfy themselves that the conditions and methods of use assure that the chemical is used safely. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION CONTAINED HEREIN OR THE CHEMICAL TO WHICH THE INFOIWATION REFERS." DO 085843 OONFTDFNTTAL ADVASTAB IN-2080 Heat Stabilizer Page 3 MSDS Reference No. 6220 11/15/85 Norton Thiokol, Inc. Caratab Division 513-733-2100 VI. REACTIVITY DATA Stability of compound: Chemical incompatibility: Decomposition products: Hazardous polymerization: Stable Compatible with other stable compounds. Hydrocarbons, organotins and oxides of carbon and sulfur may be produced when burned. Will not occur. VII. SPILL OR LEAK PROCEDURES If material is spilled: Spills may be removed with any absorbent: sand, sponge, cloth, paper, etc. Use detergent with water for final cleanup. Wear prescribed protective equipment (see section VIII) to prevent vapor inhalation or skin contact. Waste disposal method: Place absorbed material in an appropriate, closed container for disposal of in accordance with local, state and federal regulations. Reportable quantities: Not applicable VIII. SPECIAL PROTECTION INFORMATION Ventilation requirements: Adequate to prevent vapor accumulation & keep below TLV/PEL. Equipment Respiratory: If vapors are irritating, wear NIOSH-approved cartridge respirator with organic vapor cartridges. Where large vapor concentrations are suspected, wear NIOSH-approved air-supplied breathing equipment. Eye: Safety goggles (and/or safety glasses) and face shield Gloves: Rubberized gloves Other: Impervious suit or rubber apron QO 0B5844 CONFTDF-NTTAl