Document GKLek2kjxkna648aMrM4Y7DDx
()</ It.., / 0B:62:*i3
H A P 1 A N ANALYTICAL S It R V I C K S K | A S HKPOKT
T A II I. K OP CONTKNT&
Client DOW CltKMlCAl. CO, FaciliLy PLAQPKMIND, LA Client Code DOW FLAP
Report Form
Work Order Summary Work Order Comments
Flag Definitions Protocol Summary for Volatile Orqanics SWB260A Results Summary Initial Calibration
Analysta batch Summary Results Laboratory Blank Information Laboratory Control Samples Matrix Spikes Ca1ihiM ion Veiifh>i ion
Commenls/Nai i at ive
Analytical Uatch ID MSMSPA709251B1601
<?>:n >a
Pages
From
To
11 22 JJ 44 S9 10 IB 19 19 20 23 24 27 28 31 32 32 3) 16 37 yt
A
DO tofntT Al
oonf
09/10/97 00:52:53
lieooit RADIAN INTERNATIONA!. To P.O.Box 201088 Austin. TX 78720-1068
Attention lit;IUf KRAl.l.
Pi cptiied ny
Radian Internal tonal, LLC 14046 Summit Dr., Bldq, B
P. O. Hox 201(188 Austin. TX 70720*1088
('Si ` PJ*MAXWKLL
Piojd'l Sample ID/ Deaniption
DOW-VP ClS* 33'VI DOW*VP-CLS* 33-V2 DOW-VP*CLS-3 3 -V3 DOWVP-CI*S-33"V4 dow-vp-cls* u-vb DOW vi* OliS 33 VG 1>0W*VP-CliS- 3 i-V7 now-vp-ci.S'33-va DOW-VP-OLS-33-V9 DOW VP-CLS 33 V10 DOW* VP-CLS- 3 3 VI1 DOW-VP CLS-33V12 DOW-VP-CLS* 33 * VI 3 HOW-VP CLS 33-VI4 DOW* VP- CI*S - 3 3 - VIS IK)W-VP CDS-33-V16 DOW VP-CLS* 31-VI7 DOW-VP-CDS-3 3-Vl/Vl7
MUKK
order
summary
Client Code DOW PLAQ Client DOW CHEMICAL CO. Facility PliApUbMINE. i.A Work ID DIP TRIAL BURNS
('.mo 8 NA SDG 8 NA WAS 8 7n0()7ADPM
Work Order II 9709444 Page 1 mi
RCN 000117 . 5000
New Yotk SLAP ID 8; 1091b
Lab Sample ID
01 A 02 A 03A 04 A OSA 0GA 07A 08A 09A 10A 11A 1 2A 13A 14A 15A 16A 17A 18A COMPOSITE
1RH COMPOSITE
Test Code )
COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO 826SWACM SPAREB0U
Method Description
Compositing (or GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Composi Iny for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Volatile Organics by GC/MS Spn o Sample
oAq<*45
oo ft
OFNTTftl
CONF T
09/ IO/' i
MOKK OKDHH CUMHHNTS
The standard Method B260A surrogate loletances ate laboialoiy deiived from histoiical data. Project specific tolerances may diffet.
Woik Order M 9709444 Page 2_
00 A 049946 OONFTOFNTTAl
U9/IU/9/ OH . S2 : r )
ANALYTICAL I* R T C O I. SUMMARY FI. AH OKFINITIONS
work order R 97094*9 Page 3.
ring
IX'f i iii I ion
ni. Result less than staled Detection Limit and greatet than or equal to zeio
NA Analyte concentat ion not available for this analysis.
NC RPD and/oi \ Recovery not calculated See Narrative for explanation
NI) Not detected No instrument response for analyte or result less than zeio, NR Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
NS Analyte not spiked. n Analyte detected In method blank at concent rat ion qrealei than the Reporting Limit land greater than zero).
C Confirming data obtained using second GC column or GCMS.
K Analyte concentration exceeded calibration range.
Intet(erence or coelution suspected. See Narrative for explanation
M Presence of analyte previously confitmed by histoijral data
1 Analyte identification suspect. See Narrative for explanation. J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteiia. Analyte not detected on otluM GC column.
M Result modified fiom previous Report
See Natralivo tor explanation
P Arialyle not confirmed. Results from piimary and scuomlaiy GC column# diflci by qieulet than a lacLor of J.
0 QC icsult does not meet tolerance in Protocol Specification,
l( Result reported elsewhere.
5 Analyte concentration obtained using Method of Standard Additions (MSA)
T Second column confirmational analysis not performed.
X See Narrative foi explanation.
Y See NaitdLtvu (or explanation.
V. Sor Nnrrnt ive fot explanat ion.
DO A 049947 OONFTOFNTTAI
09/ it,
08 52 ;> J
Client now CMHMICMj CO.____________ Kiici lily PLAQUKMINP. LA r I ient Code DOW P|A0 Method Volatile Organics SW8260A
Ptoject Sample 1 D/Deact ipt ion now vi n.s- n vi/vi t
A N A l Y f 1 C A I. i d <> T O C O I. S U H H A K Y
Wot k Order ft 9709444 Page
l<al> Sample ID 9/09444 1 BA
Te.st Code (h) 826SWACM
Kxltaclion/Diycst ion Hatch ft
NA
Analysis Hatch ft MSMSDA70925181601
00 A 049948 GONFTDFNTTAl.
09/30/97 08`52:53
R K S U I. T S SUMMARY
Method Volatile organics SW8260A Test Code 826SWACM
Project, Sample ID:
1,,-ib IP: rill? IP: Pate Collected: Pate Prepared: Pate Analyzed: Pilulion Factor: Matrix: Units: Report as: Co1umn: Analyte
Acetone AceLonitrile Acrolein Acrylonitrile Benzene
1 - Hr omo- 2 -chloroethane
Hiomohenzene Browochlorometbane H romodich1oromet Pane Hiomofoim Bioroomethane 2 Ihtl anuneiMEK) n-Hutyibenzene Her'hul ytheir/ene t ei t.-Butylbenzene Ctirlton disulfide c'.nbon Lettaehiorido 2 Chloro l,3 - butadiene fhlorobcnzrno Chloi net pane
DOW-VP-CliS- 33 V1/V17
9709444-16A COMPOS A0925726 09/16/97
09/26/97 05:35: 00
10 Water ng/i.
received
Cone.
DL
NO ND ND ND ND ND ND ND ND 14 , 3 ND ND ND ND ND ND NP NP ND ND
7.57
51 0
16.6 2,20 0.766 0.756 1.25 1 12 1 17 1.33 2.22 7,29 3.69 2 61 1 74 1.06 1.68 0.631 0.966 1 . 72
Cone
Work Order it 9 J09444 Page 5.
Cone.
DP
Cone.
DL
DO A 049949 GONFTDFNTTAl
09/ 7 08:52:53
HKSUI. TS NUMMARY (Cont'd)
MeLhod Volatile Organics SW8260A Test Code 826SWACM
Pioject sample ID:
Dab ID: File ID: Date Collected: Date Prepared: Date Analyzed: Dilution Factor; Matrix: Un i t s; Report, as: <\liwm: Analyte
DOW-VP-CDS- 33 -VI/V17
9709444-18A COMPOS A0925726 09/16/97
09/26/97 05:35:00 10 Water ug/li
received
Cone .
Db
Cone,
Cone.
2 Chlorocthyl vinyl otbci Chloroform 1Chlorohexano Chloromcithane 3 Chloropropene l chloroi oluene 4 -chlorol oluene
1,2 - hibi omo-3 chloropropane
Pi bromooh lorome thane 1,2 Dihromopthann Dihroroometbane t i arts -1,4 -Dlchloro-2-buteoe l,2. Diohlorobonzene 1,3'Dichlorobenzene 1,4-Dichlurobenzene Dichliirodi f 1 vioromet bane 1,1 Dichloroethano 1,2-Dichloroethane
1,1 -Dichioroel bene
cis -1.2-Dichloroethcne
ND 2,25 ND 0.927 ND 1.66 ND 1.15 ND 1 . 12 ND 2.09 ND 2.45 ND 12.4 ND 1 . 34 Nl) 1.68 ND 1 .75 ND 7.07 ND 1.28 ND 0.938 ND 1 77 ND 0.783 ND 0.566 ND 1 . 16 ND 1.45 ND 1 .52
Work Order M 9709444 Page 6_
Db
Cone.
DU
0499F>0
DO A Qp-^TT Al
COHFT
l>9/3l>/97 08:52:53
HKSU1. TS SIIMMAKV (OcmL 'd)
Method Volatile Omanica SW8260A Tost Code B26SWACM
Project Sample 10;
hah 10: Pile 10: Date Collected: Date Prepared: Date Analyzed: Oi lul ion Factor' Mat i i * : Unit n: Uepovt asColumn: Analyte
turns l, 2-Dichloioethene \,7 Oichlocopiupane 1,3 Dichlotopropane 2, 2-Dichloropropana
l, 1-Pichloropropene
ci3 1, 1 'DicMoropiopene train)' 1, J-Dlchloropropeno Ktlryl methacrylate Ethylbenzene Hexaehloiobutadiene
2-Uexanone
Iodometbane isopropylbenzene p- Iflopropyltoluene Methyl methacryl*^ Methyl t butyl ethei 4-Methyl 7 pcmtauoitolMUlKl Methylene chloride Naphl ha lone Propane-nilil
DOVt-VP-CLS-33 V1/V17
9709444-1BA COMPOS A0925726 09/16/97
09/26/97 05;35;00 10 Mater aq/L
received
Cone.
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND 6.06 B ND ND
DD
2.21 0 84 7
1.31 2.53 1 - St 1.23 0,582 2 20 2.06 7.68 314 0 866 1,78 1.88 2.42 1 . 39 2 94
1 ,22 1 91 16.0
Db
Work Order M 9709444 __ Page 7___
Cone.
DL
049ABA.
DO A dFMttai
C0NP'':
09/ . , n 00 :S2 ;!i3
H K S (I I' T 3 SUMMARY (Cont'd)
Met hot! Volatile Organics SWB260A Test (ode 826SWACM
Piojoct Sample ID:
Ud> ID: Kile ID. M,n e Col lecied: Mat o l*i epai*-d: Mate Analyzed: f)i lut ion Factor : Mdlrin: Unit 3 Report as: Column: Ana 1yt e
DOW-Vp-CLS-33 - V1 / V1 7
9709444 -18A COMPOS A092S726 09/16/97
09/26/97 09:35 00 10 Water ug/L
received
Com;
Dl,
('one
Ml.
CuiU'.
u I'l opy 1 benzene SLyiene
ND 2. 18 ND 1.24
1,1,1,2 Tetrachloroethane
ND 2.24
i,l, 2,2-Tet rachloroethane
ND 1 ,73
Tel lachloioethenp
ND 1.84
letrahydiofuran
ND 4.37
Toluene
ND 0.973
1,2,3 Tiichlorohcnzenc
ND 3.43
l,2,1-Tiichlorobenzene
ND 2.63
1,1,1 -'I'i ichloroethane
ND 1 . 68
l,\,2-Tv 1chloroetbane
ND 1.47
Trichloroethene
ND 1.81
Ti ichlorofluoromethane
ND 1.03
1,2,1Tiichloropropane
ND 2 32
1,1.2-Trichlorotrifluorocthane
ND
1,23
1,2,4-Tr line t by 1 benzene
ND 1.1/
1.1,h-Tvimethylbenzene
ND 1.49
Vinyl acetate
ND 2. >3
Vinyl chloride
ND 1.28
in&p Xylene
ND 2. 10
Work Order 0 9709444 Paye B
Ml.
Cone.
m,
DO A 04995? 00NFT0FNTT Al
09/30/9 / 09:52.bi
R K 8 IH. T E SUMMARY (ConL'd)
Me I hod Volatile Organics SW826QA Tost Code 926SWACM
Pkoject Sample ID:
l.ab ID; File ID: Date Collected; Date Prepared; Date Analyzed: Dilution Factor; Matrix; Onita* Report as; Column Analyte
DOW'VP'CttS- 33 'VI/VI7
970944 4 -19A COMPOS A0925726 09/16/97
09/26/97 05:3S:00 10 Water ug/L
received
Cone.
DL
Cono.
1>L
Cone.
O'Xylene
HD 1.26
Work Order N 9709444 Page 9
DL
Cone.
DL
Surrogate(s)
1,4 Dtomofluorohenzene 1,2 l)i ch loroct hano-<14 Toluene-dO
Recovery t
9ft 101 102
Recoveiy 1
Recovery 1
Recovery %
HO A 049953
CONFTOFNTTAl
09/10/9/ 08 : 52 : S3
I N I T 1 A I.
C A I, It H A T I O N
Sol*n H IIMS-VQA-STD-6______________________________________________ Met bod Volatile Organics SWB2G0A Test Code 826SWA00
Initial Calibialion If MSDA970917000000 Calibration l>ale Q9/I7/97 00:00:00
Work Order N 9709444 Page 10
Instrument MSDA Analyst MLR Reviewer APS
Analytes Michlorodi f luoroinethane
t'h 1 oromet bane Spec Vinyl chloride crc Hiomomethane
Ch I o not h<nifi
Trichlorof)uoromet bane
Act olein
At'f'Loni trile
Response Factor
Refetence Cone. ug/L
Response Factor
Refetence Cone. ug/L
1.442 0.5
1.589 5
2.554 0.5
1.513 0.5
2.190 5
1.652 5
1.210 . 0.5
1.251 5
0.902 0.5
0.901 5
1.534 0.5
1.506 5
0.056 2.6
0.062 25
Response Factoi
Ref eience Cone. ug/l.
1.752 20
2,200 20
1.719 20
1 .129 20
0.895 20
1.616 20
0 064 100
Response Fact ol
Refetence Cone. ug/l.
1.876 50
2.253 50
1,804 50
1 400 50
0,912 50
1 667 50
0.061 250
Response Fact oi
Reference Cone, ug/L
1.996 100
2.3J3 100
1.915 100
1 454 100
0.98J 100
1 78 3 100
0,063 500
Response
Refetence Cone,
Response
Reference Cone.
Correlation
RF
% USD
Coefficient
1.73
12.8
2.31
6.60
1.72
8.84
1.33
7.61
0.919
3.95
1.62
6.84
0.0612
5,09
0.999
Act't onr*
0,998
Tcxlnmct bane
|
. 183 0.5
1 .478 5
1 614 20
1 6 35 50
1 .644 100
1.51
12.9
DO A 049954 OONFTDFNTTAl
09/ .10/9'/ 08:52:53
I N I T I A I,
C A I. I I) H A T I o N Cont'd
Sol'n N HMs-voA-STD-t
__________ ________________
Method Volatile Organics SWB260A
Test Code 826SWAQO
Initial Calibration H MSUA97Q91700OQ00 Calibration Date Q9/i//j>7 00.00.00
Work Order # 9709444 Page 11 .
Instrument MSPA . Analyst MER Reviewer APS
Analytes
Response Factor
Reference Cone. ug/Ii
Response Factor
Reference Cone. ug/l,
l,1-Dichloroethene oce
0,911 0,5
0.841 5
Carbon disulfide
1,1,2 7 richlorotit fluoioctban*
3,515 0.5
0.960 0.5
3-430 5
O.B65 5
Acrylonit ri1e
0.270 1
0.240 5
3 Chloiopropene
1.6U4 0.5
1,6J4 5
Methylene <:h lot ide
Response Factor
Reference Cone. uy/l.
0.844 20
3.656 20
0,930 20
0.247 20
1.719 20
Response FacLoi
Reference Cone ug/b
0.875 50
3.717 50
0. 962 50
0.240 50
1.738 50
Re|x>nse Fact oi
Reference Cone. ng/L
0.927 100
3 867 100
0.997 100
0.237 100
1.761 100
Response
Reference Cone.
Response
Reference Cone,
Correlation
RF
\ RSD
Coefficient
0,880
4 .41
3,64
4.71
0.943
5.26
0.24 7
5.46
1.71
2.91
1.00
r rans -1.2 -UJchloroethene
Pi np.m<-n i I i i 1 e
1 , l Dirhloiopth.ute
SPCC Methyl t-butyl el her
0.992 0.5
0.071 25
1.610 0.5
1. 366 0,5
0.908 5
0.0/5 25
1 . 600 5
1.560 6
0.948 20
0 0 /6 100
1.645 20
1 809 20
0.976 50
0 074 250
1 .669 SO
1 696 50
1.013 100
0.074 500
1 /58 100
1.630 100
0.967
4.22
0.0740
2.53
1,66
3.72
1.61
10.3
DO A 049955 00NFTDFNTTAL
09/ 10
08 ' 52 : 5 3
I N 1 T I A I.
C A I, | i K A T t N
ConL'd
Sol'n M RMS-VOA-STD-6Calibration Date 09/1 //97 00,00:00 Method Volatile Omanics SWB260A Test Code 826SWA0Q
tml i<)l t'al Mn At Kn 11 MSDA9IQ91 /000UQ0
Hoik Onhri H 9 /Q944I Page 1 A
Instrument MSDA Analyst MCR Reviewer APS
Ana 1yt ca Vinyl acetate 2-Chloro-1,3 - butadiene 3-Uutanone(MRK)
Response Pact oi
Reteience Cone. ug/L
Response Fact or
Reference Cone. ug/L
1 .274 0.5
0.910 5
0.765 0.5
0,690 5
Response Fact or
Relet once Cone. ug/L
1 0B 3 20
0.742 20
Response Feel or
Refeicnoc Cone. tig/I.
0.952 60
0,768 50
Response Factor
Releience Cone. uy/l.
0.938 1(10
0.78 3 100
Response
Kefetcncc Cone.
Response
Refeience Cone.
Correlation
RF
\ RSD
Coefficient
1.03
14.6
0.751
4.41
1.00
Tot rahydrofuran
(i a 1,2 -1)irhloioethene
2,2 htchloropropanc
Hiomoc 111orome t ha ne
<1i 1 rn of oim rex' 1,1,1 'I t ichloroel hane
l, ? - Du'h 1 oi t>e( hone
0.266 0.5
0.945 0.5
0.750 0.5
0.621 0.5
1 553 0.5
1.205 0.5
1.105 0.5
0.261 5
0.966 5
0.719 5
0.621 5
1.4/9 5
1. 142 5
1.227 5
0.196 20
0 977 20
0.048 20
0.604 20
1 450 20
L . 230 20
1 210 20
0.147 50
0.972 50
0.820 50
0.601 50
1.457 50
1.250 50
1 .215 50
0.131 100
0.980 100
0.761 100
0.597 100
1 . 526 100
I . 301 100
1 228 100
0.200
31 . 3
0.968
1.44
0.780
6.79
0.609
1.07
1.49
3.00
1.23
4 78
1.20
4 . 34
00 A 049956 00NFT0FNTT Al
07/ JO/9 I Oft ;S2 : 53
N IT I A 1,
C A III K A 'M O N Coiil.1 (1
finl'n M DMH VOA-STH-t______________________ ________________________ Method Volatile Omanica SWB260A lost Code 826SWAQ0
Initial Calibration tt MSDA9709I tGQQQQQ Calibration p.lt <- U 9/11/9 > 00: CIO. Oil
Work Older M 97091*14 Page 13
tnatrujnent MSDA _ Analyst MKH Reviewer APS
Annlytes j,i Dichioropropene Hoiuene cailxm tetrachloride
2 -Hoxanono
response Factor
Hefei once Cone. ug/l.
Response Factor
Reference Cone, uy/L
0.320 0.5
0.300 5
1.030 0.5
0.986 5
0 239 0.5
0.232 5
Response Factor
Heteicnee Cone. Ulj/i,
0.310 20
0.982 20
0.242 20
Response Factor
Refeience Cone, utj/l.
0,325 50
1 009 50
0,249 50
Response Kacloi
Rnfei i'ticft Cone. uy/b
0 132 100
U . 998 100
0.240 100
Response
Ref et ence Cone.
Response
Reference Cone.
Correlation
RF
1 RSI)
Coefficient.
0.319
4.23
1.00
1 93
0.240
2,54
1.00
1 Methyl 2 pentanoiie (MIBK)
1.00
1 , 2 pichlmopLop'iiic CCC Trt:h loroethene
hibroHiotncthane
Hromod i eh 1 oromet hane
Mot liy 1 mei hncrylate
0.296 0.5
0.235 0,5
0.139 0.5
0.313 0.5
0.279 5
0.240 5
0.145 5
0,304 s
0.28* 20
0.243 20
0.143 20
0.307 20
0-292 50
0.258 50
0 M3 50
o. m 50
0.290 100
0 260 100
0. ) 37 100
0.312 100
0.294
1 .94
0.247
4 52
0.141
2.32
0309
1.22
1.00
DO A 049057
1 CONFTDFNTTAl
09/10/ 0 8 : 5 2 53
IHITIA
C A I, II K A T 1 O N Cont'd
Sol'n tf DMS-VOA-5TP-6___________ ___________________________________ Method Volatile Organics SW8260A Teat Code 626SWA00
initial Calibration tt MSPA9/091/Qooooo Calibration Date U9/1//97 00:00:00
Work Order N 9709444 Page 14
Instrument MSPA Analyst MER Reviewer APS
Analytes 2-Chlotoethyl vinyl ether
l rana 1,1-Pichloropropcne
eis 1,3 Dichloropropene
Toluene crc
1,1,2-Trlchloroethane
El hy 1 hum h<u* y\M o
Response Factor
Reteionce Cone. ug/l.
Response Factor
Kefeience Cone ug/L
0,112 0.5
0.113 5
0.549 0.5
0.571 5
0.337 0.5
0.316 5
1.661 0.5
1.446 5
0.504 05
0,473 5
Response Fact or
Reference Cone. ug/L
0.117 20
0 696 20
0.357 20
1.455 20
0.488 20
Response Factor
Reference Cone. ug/l.
0.119 50
1) 7)1 50
0.362 50
1.519 50
0.496 SO
Response Factor
Reference Cone ug/l.
0.121 100
0.728 100
0,352 too
1.539 100
0.498 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSP
Coefficient
0, llfi
3.30
0.655
13.5
0.345
5.17
1.52
5.67
0.492
2.43
0.999
l,3 PIehlotopropane n i bromoch 1 oromo t ha nc*
1,2 Pi hroiooet hane
'UM i aeh lot ocl hone
0.836 0.5
0.539 0.5
0 465 05
0.417 0.5
0.812 5
0,577 5
0.481 5
0 432 5
0.817 20
0 592 20
0.482 20
0 440 20
0.834 50
0,621 50
0 4 94 50
0.469 SO
0.843 too
0,629 100
0 4 94 100
0,500 100
0.028
1,60
0,592
6.12
0.484
2.46
0.453
7,95
DO A 049958 OONFTDFNTTAI
119/ 10/97 08 : 52 6 i
Sol'ii N HMS-VOA-STD'6 ___ Mot hod Volatile Omanica 5W8260A Test code B26SWAOQ
INITIAL
C A I. I l H A T I O N
tout'd
Initial Calibration tt MSDA970917Q00Q00 Calibration Date 09/1 //9j_0U lQ0:0o
Work Order N 9 <U9H4 Page lj^
Instrument MSDA _ Analyst MLR Reviewer APS
Analytes
Response Factor
Reference cone. ug/L
Response Factor
Reference Cone. ug/L
<1l lorobenrone SPCC
1.672 06
1.640 5
1.1,1.? Tetrachloroethane
0.560 0.5
0.519 5
\ -Chlorohexan*
0.731 0.5
0.740 5
Ethyl benzene
0.870 0,5
0.819 5
m4p Xylene
1 .011 1
0.992 10
Dtomofoi m spec
styrene
1.669 0.5
1.663 5
o Xylene t. rans 3 , 4 -Dichloro -2 - butene
0.978 0.5
0.120 1
1.007 5
0.116 5
1,1,2,2 Tetrachloroethane spec
0.536 0.5
0.540 5
Response Factor
Reference Cone. ug/L
1.636 20
0.530 20
0.777 20
0 B07 20
0.985 40
1.683 20
0.994 20
0.1 34 20
0.554 20
Response Factor
Reference Cone. ug/L
l .726 50
0.554 50
0 919 50
0 658 50
1 048 100
1.74 1 50
1 04 J 50
0.137 50
0.549 50
Response Factor
Reference Cone. ug/L
1 .806 100
0.589 100
0.879 100
0.893 100
1.072 200
1.839 100
1, 102 100
0.144 100
0,561 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSI)
Coefficient
1.70
4.20
0.548
4.90
0.789
7,74
0.849
4.21
1.02
3.65
0.999
1.72
4,30
1.02
4.80
0.130
9.06
0.548
1.86
DO A 0499S9 CONFTDFNTTAl.
09/10/ ,0:52:53
Sol'n H MMS-V0A-Sn> 6_____ Method Volatile Organics SW8260A Test Code 826SWAU0
INITIAL
C A li I a NATION Cont'd
Inilial Calibration M MSDA970917000000 Calibration Date 09/17/97 00;00;00
Work Order H 9709444 Page lb
Instrument MSDA Analyst MER Reviewer APS______ .
Analytce \, 7,, 3 - Tr i oli loropropane Isopropylbenzene Hromohonzenc 7 Cli 1 oi oi o 1 uone n l'i opy l ln,nzt,no 4 Chlomtoluene 1, 1,5 -Tr imothylbcn/.ene 1,2,4 1iimethylbenzene t eit but y1 benzene 1, 3 bichlorohenzenc
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone, ug/L
0.36b o.s
0.361 5
2.542 0.5
2.325 5
0.7 76 0.5
0.759 0,5
0.802 5
0.731 5
0.009 0.5
0.791 5
0.759 0.5
0.770 5
2.629 0.5
2.42B 5
2.625 0.5
2.426 5
2.276 0.5
2.108 5
1 .471 0.5
1.461 5
Response Factor
Reference Coiic ug/L
0 JI3 20
2.329 20
0.001 20
0.756 20
0.807 20
0.763 20
2 391 20
2.517 20
2.274 20
t 475 20
Response Factor
Reference Cone. ug/l-
0 102 50
2.496 50
0 80 ; 50
0.79J 50
0.8)9 50
0.019 50
2-526 50
2 596 50
2.329 50
l 506 50
Response Factot
Retuieuce Cone. uq/L
0 366 100
2.574 100
0.043 100
0 B10 100
0.869 100
0.8 32 100
2,607 100
2.627 100
2 . 184 100
1.561 100
Response
Reference Cone,
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
0.373
2.86
2,45
4.83
0.006
2.98
0.770
4.09
0.023
3.77
0.789
4.34
2,52
4 . 19
2,56
3 37
2.28
3 . 38
1.49
2.72
DO A 049960 C0NFT0FNTTAI
0<)/10/97 08:52:51
Sol'ii H WMSVOA-STO-6 Method Volatile Organicg SW8260A Teat Code 826SWA00
I M l T I A 1.
CALIBRATION Cont'd
Initial Cci I i l>i ill i on H MSDA97091 /OOOOm) Calibration Date 09/17/9/ 00.00:00
Work Order 9/09444
Pag* H-_
Instritment MSDA Analyst MER Reviewer APS
Analytes hcl Hut y1benzene
1.4 Dichlorobenzene
Response
Response
Reference Cone. ug/L
Reference Cone. ug/l.
3 , J8J 0.5
3,086 5
Response Pact or
Reference Cone, g/I,
3. 100 20
Response Pad oi
Reference Cone. ug/I.
3,334 50
Response Pact or
Reference Cone. ug/I,
3.391 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
3.26
4,69
1.00
p 1sopropy1 toluene 1,2 pt< hloiobenzeiiO n Itm <' 1 benzene 1,2-Dlbiomo*3-chloropropsnc
1,2,4-Tr ichloiobenzene
Nfiphl ha lone 1,2,1 Trichlorobenzene Hexarhlorobutadiene
2,676 0,5
1.31/ 0,5
2.654 0.5
0.061 2
0.605 0.5
I .481 0.5
0.639 0,5
0.377 0,5
2,482 5
1 . 340 5
2.462 5
0.0/6 5
0.758 5
1.539 5
0 682 5
0. 301 5
2.473 20
1.341 20
2,487 20
0.095 20
0.791 20
1.610 20
0.718 20
0313 20
2.624 50
1,411 50
2.595 50
0.098 50
0.8 34 50
l .658 50
0.739 50
0 3 37 50
2.744 100
1.447 100
2.664 10Q
0.096 100
0 859 100
1 665 100
0 752 100
0.350 100
2.60
4.60
1,37
4.05
2.56
g.83
0.0896
11.6
0.809
4.77
1.59
4.96
0.706
6.50
0.336
8.96
DO A 049961 OONFIDFNTTAI.
.8 * '> 2 : * )
N I T I A I.
C A I,
H AT 1 ON
Cont'd
Sol'n II HMS VOA-STP 6
___________________________________
Method Volatile Organics SWB260A Tost Code 826SWA00
Initial Cel 1 ibi at ion tf MS1)A97Q917000000
Calibration bate 09/17/97 QU:00:00
Work Order H 9709444 Paye IB
Instrument MSDA Analyst MFR Reviewer APS
Aiwilyt es 1 ill oino- 2 - chioroetbane
Response Factor
Reference Cone . uy/L
Response Factor
Reference Cone. uy/L
0.297 0.5
0 325 5
Response Factor
Reference ('one uy/L
0.321 20
Response Factor
Reference Cone uy/b
0.323 50
Response Factor
Retetence Cone. uy/l.
0.311 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
\ RSD
Coefficienl
0.315
3.68
DO A 04996? OONFTOFNTTAl
09/30/9? 0B:S2.S3
Met hod Volatile Organics SWB260A Test Code B26SWAOO Initial (\i l l b at ion H MSPA970917000000 Calibration Date 09/17/97
analysis hatch summary
Analysis Batch H MsnSI>A*O92518U0i
Analysis Start uate/Tlme U9/2S/9/_i;16:00 Analysis Stop Date/Time 09/26/97 06.05.00
Hoik Older H 9709444 Page H.
instrument mSda Analyst ME)[ Reviewer APS
Sequcnce/Artalysis Time
1 09/25/97 17;4B:O0 2 09/25/97 10:16:00 3 09/25/97 18:16:00 4 09/25/97 18:44:00 5 09/25/97 19:13:00 b 09/25/97 19:41:00 7 09/25/97 20:09:00 & 09/25/97 20:37:00 9 09/25/97 21.06:00 10 09/25/97 21 : 34 j00 1 1 09/25/97 22:02:00 12 09/25/97 22:30:00 13 09/25/97 22-59:00 14 09/25/97 23:27:00 15 09/25/97 23:55:00 \6 09/26/97 00:24:00 17 09/26/97 00=52:00 IB 09/26/97 01:20:00 19 09/26/97 01 :48:00 20 09/26/97 02:17:00 2 l 09/26/97 02.45:00 22 09/26/97 03:13:00 23 09/26/97 (11:4 1 00 21 09/26/97 04:1U:00 25 09/26/97 04:18:00 26 09/26/9* 05:06:00 7 7 (19/26/9 / 05:35:00
2ft 09/26/97 06:05:00
Project Sample IP DOW-VP-CI.S- 31 VI/VI 7
hab Sample IP Sample Type
SB HKD VSTDCAP I.CS9 *6894 LCSD976895 BLK973847 9709J46-01A 9709346-02A 9709346-03A 9 *09346 - 04A 9709356-018 970935 3 - 01A 97G9353'02A 9709353 -Q3A 970936601A 9709366-02A 9709366 * 03A 9709366-04A 9 *09366 -05A 9709366-06A 9*09395'OJA 9709395*01A 9709)95'02A 9 *09449 1 BA 9*09455-18A
9*09454 18A 9*09441 1 BA 9*09429-ISA
Blank, System (JC/MS tune [Ilea Continuing Calibration Verification L>ab Control Sample bab Control Sample Duplicate Blank, Method Sample Matiix Spike MaLrix Spike Duplicate Sample Sample Sample Sample Sample Sample Sample Sample Sampie Sample Sample Sample Sample
Sample Sample Sample Sample Sample Sample
Analysis Kile It
A0925701 A0925702 A0926/02 A09257Q3 A0925701 A092&705 A092&706 A0925707 A0925708 A0925709 A0925710 A0925711 A0925712 A0925713 A092S714 A0925715 A0925716 A0925717 A092571& A0925719
A0925720 A0925721 A0925722 A0925723 A0925724 A0925725 A0925726 A0925727
DO A 049963 f.ONFTDFNTTAl.
00/ > I 08:52:53
Extinction Match K Analysis Batch ft
H K S U I. T S ___________ _____
MSMSDA/U9251B1601
Work order N 9709444 Page 20,
Project Sample IP DQW-VP-CLS-33-V1/V17 L.ib Sample ID 9709444 -18A COMPOS Fite It AQ92S726 Method Volatile Organics SW6260A Tent Code 826SWACM
Date Collected 09/16/97
Date Received 09/19/91
Date Prepared
__________________
Date Analyzed 09/26/97 Q5;35i00
Instumcnt MSDA Column Analyst MER Reviewei APS
Aliquot Mass/Volume
15.0 (mid
Extract/Pigcstate Volume
ISO (mid
Dilution Factor
10
Analyte
Acetone Acetonitrile Acrolein Acrylonitrile Benzene l'Bromo 2-chloroethane Hromohimzone Miomochloiomel hano Mromodichloromet bane Dromofoim Mtomomot hme ?. But anonc* (MEK) n Uutylbenzenn fi<*c Mul ylhnnfcnni*
l in t (lut y 11)011/.cue
Cailx>n riisn 1 fide Cat bon tel rachloi idc 2-Chloro-1fi hul adione Chlorobenzene chlm out banc 7 Cbloioetbyl vinyl ether Chlorofoim l Chlotohcxane Chloromethanc 3 Cbloropropene
CAS 0
67-64-1 75-OS-B 107-02 8 107-13-1 71-432 107-04-0 108-86 1 74-97-9 75-27 4 75-25-2 71-83-9 78-93-3 104-SI 6 135-980 98-066 75-15-0 56-23-5 126-99-8 106 90 7 75 00 1 110-75 8 67-66-3 544 -10-5 74 -87-3 107-05-1
Measured Concentration uq/l.
ND ND ND ND ND ND ND ND ND 14 . 3 ND ND ND Nl) ND ND ND ND ND ND ND ND ND ND ND
Reporting Subset Spikes Subset LJ, Specs Subset
Matrix W RepoiL A9 received % Moisture ___________
Detection Limit ug/L
7,57 51,0 16.6 2.20 0,786 0.756 1.25 1.12 1-17 1 . 33 2,22 7.29 3 69 2.61 1.74 1.06 1.68 0.831 0.968 1.72 2.25 0 927 1 .66 1 . 15 1 . 12
Reporting Limit ug/L
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0C
(5, oA^AAA fDFNTTAl
09/30/97 08:52:53
K K s U I. T s (com *d) Extraction Hatch W ___________________ __
Analysis Haleb |i MSMSDA70925181601
Work Order N 9709444 _ Page 21
Project Sample ID DOW-VP-CI.5-13- Vl/VI 7 I .ah Sample ID 9/Q9444-1BA COMPOS File H A0925726 Met hod Volatile Organics SHB26QA T.-nI Cndi* 826SWACM
Date Collected 09/16/97 Date Received 09/19/9 / Date Prepared _ Date Analyzed 09/26/97 05; 35'00
Instrument MSDA Column Analyst MLR Reviewer APS
Atiquut Masu/Volume
15.0 (mb)
Extraci/Digestate Volume
lb.0 (ml.)
Dilution Factor
30
Analyte
2 -Chlorotoluene 4-Chlorotoluene
1.2-pibromo-3-ehloropropane
Dihi omochlotomethane 1.2-Dibromoethane Dl In otnomet bane lrans 1,4-Dichloro-2-butene l.2 pirhlorobenzene 1,3 Dichlorobenzene 1,4 Difhlorobenstene Dich1o rodif1uorometha ne 1,1 Dlc'hluroethtine 1,2-Dichloroethane 1,1-Dichloroethonc cia -1,2-Diehloroethone 1r ans1,2Pirhloioe>hene
1,2-Dichloropropane
1,3-Dlchloropropane 2,2 -Dichloropropane
1, l Dlchloroptopene
cis l, l-Dichloiopiopene
1ans-1,3 -Diehloropropcne
Ethyl methacrylatc Ethyl benzene
`Xcu.lilorobutadiene
CAS N
9549-8 106-43-4 96-12-8 124-48-1 106-93-4 74-95-3 110-57-6 95-50-1 541-73-1 106-46-7 75-71 6 75-34-3 107-06-2 75-J5-4 156-59-2 156-60 5 78 87-5 142-2B-9 594-20- / 563-58-6 10061-01-5 1006V-Q2-6 97-63-2
100-41-4 B7-68-1
Measured Concent rat ion ug/L
ND ND NO ND ND ND Nl) ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND
Reporting Subset __ Spikes Subset Specs Subset _
Matrix W Report As received % Moisture ____
Detection Limit ug/L
2.09 2.45 12.4 1 .34 1,68 1.75 7.07 1.28 0.938 1.77 0.783 0.566 1 .16 1.45 1.52 2.21 0.847
1.31 2.53 1.51 1.23 0,582 2.20 2 06 7.68
Reporting Limit ug/L
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 DO A 049965 CONFTDFNTTAL
tig/ in
OH `>2-5 1
Kxt r.icl ion Hatch M Ana lysis Hatch #
H K 8 III. r S |Ccnt`t|)
^______ _________ MSMSDA/Q725 181 601
Wot k Order H 9709444 PciqC 22
Project Sample !U DOW - VP - CLS. 3 3 VI / Vl 7 Lab Sample ID 9 /Q9444-18A COMPOS I't It; ft A0925726 Method Volatile Oman lea SWB260A Test Tode B26SWAOM
Date Collected 09/16/97 Date Received 09/19/97 Date Prepared Date Analysed 09/26/9/ 05:lb.00
Instiument MSDA Column Analyst HER Kevtewn APS
Aliquot Mjo/Volume IS Q tint/)
bxtiact/Digogtatc Volume IS 0 (ml.)
Dilut ion Factor 11)
Ana 1yte
CAS N
A - Mexaitone lodomethane ISopiopy1 benzene p I gopropy 11 o 1 uene M*-*t tty 1 methacrylate Methyl I butyl ether 4 Methyl 2 pentanone (MIUK) Methylene chloride Naphtha lone IT upanen 11 i i le n I't cpy 1 benzene St y t t'lie 1.1.1.2 Tetiachloioelhane 1 . 1 . 2 , 7. - Tel i ach lot oet ha lie 'l et i a eh lo* ocl hene l et t ahydrofuran lolueiu! 1,2,3 `l'r irhlnrohf in > tie 1,2.4-Trichlorobenzene 1,1,1-Tricbloroethane 1.1.2 Tricbloroethane Tirhlot oevhene ITichlorofluoiomci hane 1,2, i - 'I'r ichloroproparie 1.1.2 'IT cli I tt ol i i f 1 uoroethane
591-78-6 74-88-4 98-B2-8 99-8 ?-6 80 62-6 1614-04-4 108 10-1 7S 09-2 91-20-1 107 12 0 101 65 1 100-42-5 6)0-20-6 79-34 5 127-18 4 109-99-9 108-88-3 87-61-6 120-82-1 71-55-6 7900-5 79 01-6 75-69 4 96-18-4 76-13-1
Mea silted Concentialion uq/L
NO ND ND ND N|) ND ND 6.06 0 ND Nl> Nl> ND ND ND ND NI) ND ND ND ND ND ND ND ND ND
Reporting Subset Spikes Subset Specs Subset ___
Matrix W Report As received \ Moisture __________
Detection Limit ug/L
3.X4 0.866
1.70 1.88 2.42 1.39 2 94 1.22 1.81 16.0 2 3*8 1.24 2.24 1 73 1.84 4.37 0 973 3.43 2.63 1.68 1,47 1 81 1.03 2.32 1,23
Reporting Limit ug/L
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Q 0 0 0 0
0
DO A 049966 OONFTOFNTTAL
09/ >!>/*); 08:52;53
Extraction Hatch It Analysis Batch II
H K S U I. T 8 (CtniL pd)
__________ ______________ MSMSUA7Q9251B16Q1
Work Older It 9709444 Page 23
I'roif-rt Samp 1 ft ID DOW-VP'CIS- 33-V1/V17 Lab Sample W 9709444->8A COMPOS Pile N AG92S726 Method Volatile Oioanics SW026OA Test Code 826SWACM
Date Collected 09/16/9'! Date Received 09/19/9'! Date Prepared Date Analysed 09/26/97 06:35:00
1 rial t timerit MSDA Column Analyst MtiK Reviewer APS
Al iquot Masa/VoUime
15.0 (ml.)
Extract/Digest ate Volume
15.0 (ml.)
Dilution Factor
10
Analyte
1,2,4 Trimethylbenzene l,3,5-Trimethylbenzene Vinyl acetate Vinyl chlotide mtp-Xylcne o -Xylene
CAS H
95-63-6 100-67-8 108-05-4 75-01-4
mocas
95-47-6
Measured Concent-rat ion ikj/L
NO Nl) Hi) HD ND ND
Repoitinq Subset Soikes Subset Specs Subset
Matiix W Report As received % Moisture
Detection Limit ug/L
1.37 1.49 2 73 128 2.30 1.26
Reporting Limit ug/L
0 0 0 0 0 0
Sin roqate(a)
1,4-Hromofluorobenxene
1,2-Dichloroethaue d4
Toluene-d8
CAS N
460-00-4 i7060-07 - 0 2037-26-5
Spiked Cone. ug/I.
167 16 I 167
Measured Concentiat ion ng/l.
164 168 170
Recovery %
98 101 102
Specification Limits
Low %
High \
77 117 61 14 3 87 11J
D0 A 049967
00NFTDFNTTA1
09/ / 08 :52 :53
I. A II ORATORY II I. a N K
INFORMATION
Extraction Batch N Analysis Batch H MSMSPA/092S1B1601
Work Older ft 9709444 Page 24_
Lab Sample IP BLK9/3847 File ft A0925705 Method Volatile Orqanics SH8260A Test code 826SWACM
Date Prepared Date Analyzed 09/25/97 19.41:Q0
Inst rumeut MSDA Column Analyst MER Reviewer APS
ReDortina Subset Spikes Subset Specs Subset
.
Matrix W
Aliquot Mass/Volume
t`4 0 (mb)
Extract/Diyeslafe Volume
15.0 (mb)
Dilution Factor
1
Analyte
Measured Cunc. ug/b
Detection Limit ug/L
Reporting Limit ug/L
Acetone Acetonitrile Arrolnin Acrylonitrile Benzene 1 Uromo-2 chloroethane llrnmohenzcne
1) romoe h 1 o i ome 11 ia ne
Biomodichloromct hone Bromoform Diomomethane 7 - But anoneIMEK) M'Butylhenzene sec - Butyl benzene l ert -hiity 1 benzene Carbon disulfide Cat bon tetrachloride 2-Chloio-1,1-butadiene Chlorobenzene Cliloinet hnne 2.-Chlocoethy 1 vinyl ether Chloroform 1 Chlorohexane ('hloromethune 1 Chloropropene
ND NO HI> ND ND NI> Nil ND ND ND N[) ND 0.539 0271 ND ND ND ND ND ND ND ND ND ND ND
0,757 5.10 1 6<,
0.220 0.0786 0.0/56
0.125 0.112 0.117 0.1)3 0.222 0,729 0.369 0,261 0 174 0.106 0 168 0.0811 0.0968 0.172 0.225 0 0927 0 166 0.115 0.112
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 DO A 049968 CONFIDENTIAL
oy/JO/`)-> 00:52.S3
LABORATORY III. K N K
nforHATion (coni 'ri)
inn H.il Hi W ________________________ Analysis Batch It MMKDA7092M*llt01
Woik order H 9709444 Page 25
Lab Samnle ID BLK973847 I'ile * A092S705 Method Volatile Oruanics SW6260A Teat Code 826?WACM
Date Preoared Date Analyzed 09/25/97 19:41:00
Instrument MUDA Column Analyst MER Reviewer APS
ReporLjnq Subset Spikes Subset Specs Subset ___
A1iquot Mass/Volume
15 0 (mb)
Extract/Digestaie Volume
15.0 <tnU
Dilution Eactoi
1
Analyte
Measured Cone. ug/L
Detection Limit ug/L
Reporting Limit ug/L
2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo*3chloropiopane Dibtomochloromethane 1<2 Dlbromoethane Dibkou>ni''l hanc t rans-1,4-Dloh loro-2 butene 1,2-Dichlorobonzene 1,3 Dichlorobenzene 1,4- Dichlorobenzene Dichlorodifluoromethane 1,I-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cia-1,2*Diehloroethene I rans-1,7. - Di ohloroathene 1,2-Dichloropropane 1,3 Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis -1,3 Dichloropropene ltans-1,3 Dichloropropene Ethyl methacrylate
Et hy1benzene Hexachlorobutadtene
Nb
0.209
0
m
0.245
0
ND
1.24
0
ND
0.134
0
ND
0U8
0
ND
0.175
0
ND
0.707
0
ND
0.120
0
NO 0.0938
Q
ND
0.177
0
ND 0.0703 0
ND 0.0566
0
ND
0.116
0
ND
0.145
0
ND
0.152
0
ND
0.221
0
ND 0.0847 ND 0.131 ND 0.253 ND 0.151
0 0 0 0
ND
0.123
0
ND 0-0582 0
ND
0.220
0
OO A 049969
ND
0.206
0
CONFIDENTIAL
ND
0.768
0
<)9/3o, ,/ 08:52:53
ADORATOHY HI. A N K 1 NKOKMAT 1 ON (cont'd)
Work Order H 9709444
Extraction Batch H Analysis Batch 8 MSMSDA70925181601
Mb Sample ID B1.K97J847 Kile A092S705 Method Volatile Otaanlcs SW8260A lest Code e^6SWACM
bate Prepared Date Ana 1yzed
09/25/97 19:41:00
Inst rument MSDA Column Analyst MLR Reviewer APS
Reporting Subset Spikes Subset Specs Subset ____
Matrix
Aliquot Mass/Vo)umc
15 0 (mb>
Kxt i net/Dlgeslale Volume
lb.O (mb)
Dilution Kactor
1
Analyte
Measured Cone. ug/b
Detection Limit ug/L
Reporting Limit ug/L
2 Itexanone lodomethanc 1sopropylbenzene p-IsopropylLoluene Methyl methacrylate Methyl t-butyl ether 4-Methyl-2-pentanone(MIUK) Methylene chloride Naphthalene Ptopanenitrile n-Propyl benzene Styrene 1,1,1,2-Tet rachlnroethane 1,1,2,2 Tetrachloroethane Tel tachloroetheiie Tel tahytlrofuian Toluene 1,2,3-Trichlorobenzene 1,2,4-Tr tchlorobcnzene 1,1,1-Trichloroei hane
1,1,2 Tiichioroelhnne
Trichi oroethene Tnchloiof luoromelhane 1,2,3 Trichloropropanc 1,1,2*Ttichlorot ifluoroethane
ND ND NO ND ND ND ND 0.370 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.314 0.0866
0.178 0.188 0.242 0.139 0.294 0.122 0.181
1.60 0.238 0,124 0 224 0 113 0.184 0 4 37 0.0973 0.343 0.263 0 168 0 147 0.181 0.103 0.232 0.123
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 DO A 049970 CONFIDENTIAL
0
00/10/97 OB.S2:S3
I. A H O K A T O N Y
tl |. A N K
NKOUMATION (conL'd)
Kxtmetion (latch N ______
_
Analysis Batch ti MSMSDA/092MU1601
Work Order tf 9 /09444 Page 27
l.,il> saint)le 11) BI.K9/3B4/ I'll.) H A0925705 Method Volatile Oiuanics SW8260A Test Code 826SWACM
Halo Prepared Date Analyzed
09/25/97 19:41.00
1 nt ruinenl MKDA Column Analyst MLR Reviewer APS
Reporting Subset __ _ Spikes Subset Specs Subset ____
Matrix W
Al iquot Mass/Volgnte
1S.0 (mL>
KxLt aet/lMgcfit at o Volume
ISO (mid
Dilution Factor
1
Analyte
Mi'asLued Cone ng/l.
Detection Limit ug/b
Reporting Limit ug/L
1,2,4-Trimothylbenzene ),3,5-Trimethylbenzene Vinyl acetate vinyl chloride mip-Xylene o-Xylene
0.124 J ND ND Nil ND ND
0.137 0. 149 0.273 0 128 0.230 0.126
0 0 0 0 0 0
Surrogate(si
1,4 -Droroofluorobenzene 1,2*i)ichloroethane-<l4 Toluene-<18
Spiked Cone, Ut)/L
16.7 16.7 16,7
Measured Cone. ug/L
36.3 16 9 16.7
Recovery \
98 101 100
Specification Limits
Low \
ll 61 87
High \
117 143 m
D0 A 049971 CONFTOFNTTAl
iV*0/9.
:52:53
laboratory
control
fi A H V L K
F)xl ract I on Batch H
__________________
Analysis Hatch tf MSMSPA7O9251B1601
Work order M 9709444 Rage 2^
Method Volatile 0rcianic9 SW026OA Teat Code 826SWACM
Date Prepared Date Analyzed
09/25/91 19;13;00
Instrument MSUA Column Analyst MER Reviewer APS
Reporting Subset Spikes Subset Specs Subset
Matrix If Report As received \ Moisture __ Aliquot Maas or Vol Extract Mass or Vol
15.0 (nU 15.0 (mid
Control Std. N LCS1 LCS 2
Vol. Added
5.0
ul,
5.0
uL
Surrogate Sol'n H 1,2 -DCA-d4 Toluene-dft
1.4-BFB
Vol. Added 1 uL l uL 1 uL
Analyte
LCS Lab Sample ID
LCS976894 File it A0925703
Spiked Cottc. ug/L
Measured Cone. ug/l.
LCS Duplicate Lab Sample IP
LCS0976B9S File 11 AU925704
Hec. \
Spiked Cone. ug/l.
Measured Cone. ug/l.
Recovery Spec.
Limits
RPD
Rec. 1
Low \
High %
Result \
Spec. Limit
%
Acetone Benzene Drppkj)>ni t z eno Uromoehloromethane Hiornodichloromet hane Ul onKyf oi m Hionmmet hane 2 Butanonc(MKK) n Butylbenzene sec -But y1benzene tort Butylbenzene Carbon disulfide Carbon teLrachloride Chlorobenzene Chloroethane Chloroform Chlmomethane 2 chlorololuene 4 ( hlorotoluene | 1,?bibi inno- 3-chloropi opane
20 0 20.0 20,0 20.0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20 0 20.0
19 7 20.9 21.4 19.9 21.0 16,9 1 t.2 19,5 21.1 20.5 22.3 18.7 21.7 20 7 18.4 20.7 14 , 3 21 . 6 20 5 1ft.6
98 104 107
99 105
84 86 97 106 102 112 93 109 103 92 104 72 108 102 9J
20.0 30.0 20.0 20 0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20-0 20.0 20,0 20,0 20.0 20.0
20.0 20.8 21,8 20.5 21 4 17.7 17,7 19.8 20.8 20.2 21.9 19.1 21.9 21.1 16,4 21.2 14.7 21.5 21.3 17.9
100 104 109 103 107
89 8B 99 104 101 110 95 110 105 92 106 73 107 106 89
0.1 71 67
240 133 127
57 23 34 0.1
136 151 128 214
29 223 46 iso 77 129 39 Ul 64 146 18 140
2,0 0
1 -fl 4.0 1.9 5.8 2.3 2.0 1.9 0.98 1.8 2.1 0,91 1,9
0 1.9 1.4 0.93 3,8 4.4
71 17 12
19 17 25 39
23 23 14 27 16 26
r>0 A 04997? CONFTOFNTTAI,
(19/JO/9I 0B:5Z:S3
I. AHORATORV C O N T K O I. S A H P I. K Extraction Batch If Page 29_ Analysis Batch N MSMSDA707?6t1601
Oont'd
Work Order S709644
Mel Inal Volatile Oman I ..a SW826UA Test Code 826SWACM
Bate Plcpdied ________________ ____ Date Analyzed 09/2S/97 19tHiO<>
llisl nirauin MSDA Column ^ Analyst MKR Reviewer APS
Repul t in<j Subnet. __ ____ Spiked Subset __ _ _ Speed Subnet.
Matrix W Renorl. As received % Moisture Aliquot Mass or Vol Extract Mass or Vol
15.0 (mL) 15.0 (mb)
Control $td. 8 LCS1 LCS2
Vol, Added
5.0
uL
5.0
ub
Surrogate Sol'n 8 1.2 -DCA-d4 Toluene-dB
1.4-DFB
Vol Added 1 uL 1 u^
1 UL
Ana 1yt c
U i b i tiiftoc h 1 oi om thane
1,2-Uibromoethane
Dl b> oiiwxneLhane 1,2-Dichlorobenzene
1,i-pichlovnbenzene
1,4-Pichlorobcnzene Dlchlorodifluoromelhane
1, 1 bicltlorocl hone 1,2-LJii'hloioethone
1,1 DichloroeLhene cis-1,2-DichloroeLhene
11ans-1,2Plchloroet hene
lr? pichlntopmpano
1,3'Dlchloropropanc
2,2 plrhlornptnpane
1,1 pichloroptopene
cia-1,1 Dic-liloropropene
11ans-1.3pichloiopropene
fit hylbenzene
Mrxochlo!obut adiene
LC.N Lab Sample ID
LCiiS 76894 Kile 11 A0925703
Spiked Cone. ug/i.
Measured Cone.^ ug/l.
20 0 20 0 20 0 20.0 20 D 20.0 20.0 20 0 20 0 20.0 20,0 20.0 20.0 20 0 70 0 20.0 20.0 20.0 20,0 20.0
19.3 12.2 21 3 20.7 20.3 20.0 14 , 1 20 9 19 8 23-6 17.9 22.1 21.0 lb .2 22,1 23 . 16. / 17.3 20. 3 19,-4
LL S Duplicate La b Sample ID
L CS0976B95 Kile IP A092S704
Rec. t
Spiked Cone. ug/l.
Measured Cone. ug/l.
96 61 106 104 101 100 14 105 99 118 90 111 105 91 1 10 1 10 83 66 101 97
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20-0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20 0 20.0 20.0 20.0
19.9 12.6 21.7 21.1 20.5 20.3 15.0 21.6 20.3 23.7 18.3 72.5 21.2 18.8 23.3 33.3 17.1 IB . 1
19.8
19,2
Recovery Spec.
Limits
RPD
Rec. \
Low 1
High i
Result \
Spec Limit
%
100 63
108 105 103 101
75 108 101 118
91 ill 106
94 116 117
B5 91 99 96
45 137
52 67 68 70 0,1 66 48 47 66 62 61
13B 135 134 132 166 13A 152 175 144 146 133
63 113 34 138 75 131
4.1 3.2 1.9 0.96 20 1.00 1.3 2.8 2.0
0 1,1 1.8 0,95 3.2 5.3 0.B5 24 56 20 1.0
15
21 14 14 13 26 19 23 25 IB 22 17
16 21 14
DO A 049973 CONFTDFNTTAl
09/30/97 ,.:52:53
I. AH ORATORY C O NT H O I. 8 A M I* I, K Extraction Hatch H_________ __ ________________ Analysis Hatch H MSMSDAVO^jIBlfrOi
cont*d
Work order M 9/P9444 Page 30 _
Met hod Volatile Organics SWB260A Teat Code 826SWACM
Date Prepared ______ Date Analyzed 09/25/97 19.13.00
Instrument MSUA Column Analyst MER Ki'Vicwi'i APS
Reporting Subset Spikes Subset Specs subset
Matrix W Repot l As received \ Moist me ___________ Aliquot Maas or Vol Extract Mass or Vol
15. 0 trot*) 15.0 (mL)
Control Std, N LCSl I.CS2
Vol. Added
5.0
uh
5.0
uL
Surrogate Sol'n tt J. 2 ~DCA-d4 Toluene-da
1.4DFB
Vol. 1 l
1
Added uL
ul
uL
Alta lyte
2-llexanone
Isopropylbenzene
p-Isopropyltoluene
4 -Met hyl-2-pentanone 1MFHK)
Mot by lenc cliloi Idc
Napht ha lent*
it Propy 1 benzene
St yiene
1 , 1,
'Id i ,n`h 1 oi out h*um
1, 1,2,2 Tet rachloiooUiane
Totiarhloroethene
Toluene
1,21 J Trichlorobenzene
1,2,4 Trichlorobenzciie
1,1,1-Trichloroothano
1,1,2-Tiichloiuethane
Ti ichloinoth*ne
Tt iohlotofluoiomet hane
1,2,J-Trichloiopiopanc
i,?,4Trimethyl benzene
M'S |,ab Sample 1L>
LCS976094 Pile 11 A0925703
Spiked Cone, ug/L
Measured Cone. ug/L
20.0 20.0 20.0 20.0 20.0 20.0 20,0 20 0 20 0 20.0 20.0 20,0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
15.9 19.7 19.1 19.0 19.6 20.1 20.4 19.6 19 2 21 . 1 21.8 20.8 22.2 22 0 20,9 20.4 22.1 18.2 20 0 21.1
LCS Duplicate Lab Sample IP
LCSD976895 File It A0925704
Rec. %
Spiked Cone. ug/L
Measured Cone. ug/L
79 98 95 95 98 101 102 98 96 105 109 104 111 110 104 102 110 91 100 106
20.0 20.0 20.0 20 Q 20.0 20.0 20.0 20.0 20 0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 200 20.0 20.0
16.1 20.3 19.2 10.4 20.5 20.9 20.3 19 5 19.6 22.3 22.1 22.0 22.5 21 4 21.4 21.2 21.8 18.2 20.6 20.8
Recovery Spec.
Limits
RPD
Rec. \
LOW %
High %
Result %
Spec. Limit
1
80 22 164
101
96
92 27 149
102 36 166
104
101
98 68 136 98
112 4 7 143
110 69 137 110 70 132
113
107
107 49 155
106 67
135
109 /I 129
91 39 147
103
104
1.3 3.0 1, Q 3.2 4.0 2.9 0.98
0 2.1 6.4 0.91 5.6 1.8 2.8 2.8 3.8 0.91
0 3.0 1.9
34
36 23
14 20 16 17
24 17 17 29
D0 A 049974 C0NFIDFNTTA1.
1)9/10/9 1 OH :S2.S 3
I. A II O K A T 0 K Y C O N T R O ! S A M P b K Ext race ion batch U ________________________ Analysis batch M MSMfibA/0925181601
Cont. *d
Work Order N 9709444 Page 31
Method Volatile Organics SW026OA TtBL Code B26SWACM
Date Prepaied Date Analyzed 09/28/97 19:12:00
Insr.iutneiiL MSIiA Column Analyst mbr Rev1ewet APS
KeuoitirKt Subset Spikes Subset Specs Subset ____ ____
Matrix w Report As received \ Moisture Aliouot Maos or Vol Extract Maas or Vol
15.0 (mL) 5.0. lmL>
C'ontiol Std. N LCS1 J.CS2
Vol. Added
SO
ul.
5.0
uL
Surrogate Sol'n R 1,2-DCA- d4 Toluene'dH
1.4-BFB
Vol. Added 1 uL 1 uh
1 ub
Analyte
1,1,5-Ti
by 1 benzene
Vinyl acetate
Vinyl chloride
mip-Xylene
n Xylene
bCS Lab Sample ID
LCS9/6894 Pile ir) A092570J
Spiked Cone. uy/l.
Measured Cone. ny/t.
20 0 20.0 20.0 40.0 20.0
21 6 o. in
17.6 39.6 19. S
LCS Duplicate Lab Sample ID
LCSD9/6895 Kile 1C) A0925704
Rec . %
Spiked Cone. UCj/l,
Measured Cone. ug/I.
106 1.9
66 99 96
20.0 20.0 20.0 40.0 20.0
21,1 0.850
17. S 39.6 19.9
Recovery Spec.
Limits
RFU
Rec. 1
Low t
High \
Result \
Spec. Limit
t
105 4.3
Aft 99 99
0.1 164 24 US 76 134 77 131
2.8 9.8
0 0 1.0
31 27 15 IS
Suriocjate (fl)
1,4 hinmofluorobenacne l,2 DlchioroeLhane-d4 Toluene-(18
16.7 16.7 16.7
IS 9 16.4 I/ 7
95 16.7 98 16. 1 10) 16.7
16.2 16.6 17.0
97 77 117 100 61 143 102 B7 113
Dn A 04997
rn FNTTAl
09/J0/9J t.w.b2.Sl
HAT MIX S
ftExt tact ion Batch
I KK (S)
Analysis Batch ft HSMSA7092blB160l
Work Order It 9709444 Page 32
Project Sample 10____________ ________ Method Volatile Organics 5W6260A Test Code 8265WAMS
Date Collected 09/17/97 Date Received 09/18/97 Date Prepared Date Alta 1 yzed 09/29/97 21:06:00
Instrument MSDA Co Iumn Ana}y&t HER Rev Jewel APS
Reporting Subset ___ ____ Spikes Subset ____ ____ Specs Subset ____ ____
Matrix W Report As received % Moisture
Spike Snl'n ft LCSl U'S2
Vol , Added 5.0 uL 5,0 UL
Suiiogale Sol'n 1,2-DCAd4 Toluene de 1.4-BFH
Vol. Added
1 uL 1 uL
i uL
Samp)o
Lab Sample ID
9709346-01A
File ft A0925/06
Aliquot Mass/Vol
15.0
(mb)
Extract Mass/Vol
15.0
(mLl
Oil Fact.
1
Spiked Sample-
hub Sample 11)
970934 6 * Q2A MS
File ft A092S707
Aliquot Mass/Vol
15.0
(ml,)
Extract Mass/Vol
15.0
(ml.)
Oil Fact.
1
Spiked Sample Dup
Lab Sample ID
9709346-03A MSD
File A0925708
Aliquot Mass/Vol
15.0
ImL)
Extract Mass/Vol
15 D Dll Face.
(mb)
1
Recovery SpeclCication Limits
RPD
Analyte
Spike Sol1 n Cone
ug/L
Measured Cone ug/L
Spiked Cone. ug/l.
Measured Cone. uy/l,
Kec %
Spiked Cone. ug/l.
Measured Cone. ug/L
Kec. \
Low %
High l
Result \
Specif >cat ion
Limit \
Benzene ChlorobiMiscnc 1,1 -lUchloroethent! Toluenr Ti ichloiorthcne
200000 200000 200000 200000 2000Q0
HD ND NO NO 1.06
20.0 20.0 20 0 20.0 20.0
21.6 21 0 24 l 21,0 25.2
108
20.0
22.6
1 05
20.0
21.7
122
20.0
26.0
109
20 0
22.2
111
20.0
26.9
113 71 108 77 130 47 111 70 119 71
133 129 175 132 129
4.5 2.8 6.4 1.8 7,0
17 U 25 17 17
Surrogate Is)
1 , 4 - Bi oimif luorobeiv/.ene 1,2 Dichloroethane-d4 ToltiPttc-dB
250000 250000 250000
15.7 17 3 16.4
J 6,7 16.7 16.7
15.2 16.3 16 f
91
16.7
15.5
98
16.7
16.3
100
16 7
17 0
93 77 98 61 102 87
117 143 11 1
00 A 049976 C0NFTDFNTTAI
119/10/97 08-52;53
COWTIWUlMCi 90U 1> A I . * ) CM. lBTIOH
vbripication
Analysis Dali.li H M.SMSDA7O925181601 Initial Calibration # MSDA910917000000
Work Order H 9709999
Page 33,
Lab Sample N) VSTDCAL
Date Analyzed
Pile * A092S7Q2___________
Metliod volatile Organics SWB260A
09/2S/97 18.16; 00
Test Code 836SWA00
Reporting Subset -----Spikes subset -----Specs Subset ------
Instrument MSPA_ Analyst MER Reviewer APS
Analyte -- * --- --
--
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Denzene
1-Bromo-2-chloroethane
Rromobenzene
Dromochlo rome tha ne
Bromod1ch1oromethane
Bromoform
Uromomethane
2-ButanoneIMEKl
n-Uutylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloio-liJ-butadiene
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
1-Chiorohexane
Chloromethane
3-Ch1oropropene
Mcaam od Concentiav ion
ug/l,
18.3 88.8 91.4 20.9 21.0 20.3 22.0 19.6 21.0 n.o 17.1 19.6 20 D 21 5 22.7 20.3 21.1 20.7 21 .0
18.0 13.2 20.8 20.3 14 .4 21.6
<; encv? Concentration
ug/i.
20.0 100 100 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20 0 20.0 20.0 20.0 20.0
20.0 20.0 20,0
Recovery t
92 09 91 104 105 102 110 90 105 05 06 90 105 108 113 102 105 104 105
90 66 104 102 72 108
Recovery Specification
Limits
bow t
High \
80 120
DO A 049977 CONFTDFNTTAI
09/ 10/ // OH : 52 : 53
CORTINUIKOIOR ll A I t. Y > C A I. I tt NATION VERIFICATION (Cont'd)
Anal ye is naUii 6 MSMSPA70925 I fl 1 6ui Initial Calibration |J MSUA97091 fOOOOOO
bab Sample ID VSTDCAL # A09257Q2
Method Volatile Organics SW8360A Test Code 926SWAQ0
Date Analysed
09/25/97 16:16:00
Repotting Subset Spikes Subset ___ Specs Subset ____
Work Order tf 9709444 rage H
Instrument MSDA Analyst MER Reviewer APS
Analyte
2-Chlorotoluene 4-Chlorotoluene
1,2-Dibromo-3'chloropropane
Dibromochloromethane l,2~Dibromoethano DLbromomethane
trans>1,4-DichJoro-2-butene
1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1- bichloroethariG
1,2-Uichloroethane
1,1`Dichlorocthene cis-1,2 -Dichloroethene tians-1,2 Pichlorocthene 1,2 - t)i ch 1 oropropane 1,3 Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-l,3-Dichloropiopcne irans-l,3 -Dichloropropene Ethyl methacrylate Ethylbenzene Hexachlorobnt adiene
Measured Concentration
ug/L
Ref eience Concentration
u9/b
22.3 22.0 17.2 19.8 14.3 21.1 13.7 21.6 21,4 20 6 11. 3 21.3 21.2 21.7 20 1 19.5 20.9 19.5 23.3 22 7 16.5 18.0 21.6 20,3 21 0
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 2 0.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20 0 20.0 20.0 20 0 20.0 20.0
Recovery %
111
no
86 99 71 105 66 108 107 103 57 106 106 109 101 97 105 98 117 1H 82 90 106 102 10S
Recovery Specification
Limits
Low %
(Ugh \
80 120 60 120
80 120
00 A 049978 CONFTOFNTTAI
09/30/97 08:S2:53
C O N T inUINO((>K U A I l> Y )
CAI. IbKATIOH
V K fPICATION ICQOl'llI
Analysts Batch MSMSPAl0925Ullb01
Initial Calibration II MSUA97Q91 1000000
Work order H 9709444_ Page 35.
Mb sample ID VSTDCA1, File K A0925702___________ Method Volatile Organics SW9Z60A
Date Analysed
09/25/91 10:U:QU
Test code 826SHA00
Deporting Subset -----Spikes Subset -----Specs Subset ------
Instrnir
MSDA
Analyst HHR
Reviewer APS
Analyte
Measured Concentration
ug/L
Reference Concentration
ug/b
Recovery \
Recovery specification
Limits
Low \
High t
2 -Hexanone lodumethane Isopropylbenzene p- isopropyltoluene Methyl methacrylate Methyl t-butyl ether 4-Methyl-2-pentanoiifi(MIUK) Methylene chloride Naphthalene i'ropanenitrlle it' Ptopy Ibenr.ene St yrene 1,1,1,2 Tctrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,2,3 -Trichlorobenzcne 1,2,4-Trichlorobenzene 1,1.1-Trichloroethane
l,l,2-Tiichloroethane Tr ich1oroet hene T i chlo of luoroinct hone 1,2.3-Trirh1oropropane l,l,2 `Tr it'hlo* ot vif luoroethane
16,2 17.0 19 B 20.3 21.8 19.fi 18.1 19,2 20.1
103 21.1 19.6 19.2 21.1 22.3 18.5 2T . 7 22 1 21.6 21 1 22.0 21,5 20,0 20,1 21.0
20.0 20 0 20.0 20,0 20.0 20.0 20.0 20.0 20.0 too 20.0 20,0 20.0 20.0 20.0 20.0 20.0 20 0 20.0 20 0
20.0 20.0 20.0 20 0 20.0
81 95 99 102 109 99 91 96 101 103 10b 98 96 106 111 92 108 no 108 10G no 108 100 101 I0S
80 120
DO A 049979
oonftdfntta;.
09/30,
00-52:53
CONTINUING (OK DAILY) C A 1, ttIRATtON V K m C A t I o N (Confd)
Analysis Batch N MSMSDA?0925191501 Initial Calibration ft MSDA970917000000
Lab Sample H> VSTOCAL Kile it A0925702___________ Method Volatile Organics SW8260A Teat Code B26SWA00
Date Analyzed
09/25/97 10: lb: 00
Reporting Subset Spikes Subset ___ Specs Subset
Work Order N 9709444 Page 36^
Instrument MSDA Analyst MBA Reviewer APS
Analyte
1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene
Measured Concent rot ion
Reference Concent rat ion
u.j/l.
21 9 22.9 26-0 17,0 41 , 1 20 5
20 0 20 0 20 0 20 0 40 0 20 0
Recover y \
109 115
no
95 101 102
Kmivi'i y Specifical ion
Limits
Low \
High %
80 120
Surrogate(a)
1,4 Broinof luorohenzene 1,2 -Pichloroethane <14 Toluene-dO
15.8 16 3 16.9
16 7 16.7 16.7
95 77 m 97 61 141 101 87 113
DO A 0499B0 C0NF T DFNT T Al
09/10/9'' 08:52.S3
Meihtul Volatile OtuaniCB SVM1260A RnocificatlonR
l,ab Sample in File io
Project Sample 10/Descript ion
Analyte
A H A I. Y T 1 C A 1. PWOTOCOI, SOHMAKT COMMKNTS/NAHKATIVIC
Work Ordci 8 9_i0jMli-- ^,,
, .. Flag Comment/N*u i at Wo
corrective Action
HO A 0499R1 OONFTDFNTTA1,
