Document G5YdNMnkpJed3LqmabQ6zJ0ox

EMISSION TEST REPORT NEW REACTOR D-745 CONOCO CHEMICALS COMPANY P.0. BOX 91 ABERDEEN, MISSISSIPPI 39730 APRIL 7, 1982 A VAB.0001115754 EMISSIONS TEST * NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN. MISSISSIPPI I. INTRODUCTION A. Source Information B. Testing Personnel C. Process Description II. SAMPLING RESULTS SUMMARY A. Emissions Test Results B. FVC Production During Tests III, SAMPLING PROCEDURES A. Sampling Apparatus B. Sampling Procedures IV. ANALYTICAL PROCEDURES A. Analytical' Apparatus 1. Slurry Samples 2. Reactor Opening Loss Samples 3. Reagent s B. Analytical Procedures 1. Slurry Samples 2. Reactor Opening Loss Samples V. CHAIN OF CUSTODY VI. APPENDIX Operating Data Sheets Sampling Data Sheets Analytical Calculations Analytical Data Standard Gas Certifications Reactor Opening Loss Calculations A VAB.0001115755 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI I. INTRODUCTION In accordance with 40 CFR 61, Section 61.67, an emissions test was conducted on March 9 and 10, 1982 for the newly constructed PVC polymerization reactor D-745. The purpose of the test was to demonstrate compliance with 40 CFR 61, Sections 61.64 (a) (2) and 61.64 (e) (1) (ii). A. * Source Information The emissions test was conducted at: Conoco Chemicals Company Highway 25 Aberdeen, Mississippi 39730 Questions concerning the testing or this report should be directed to: R. A. Frohreich, Chief Process Engineer Telephone Number (601) 369-8111, extension 2239 Dave Mahler, Environmental Engineer Telehone Number (601) 369-8111, extension 2285 B. Testing Personnel The testing and analytical work was conducted by Conoco Chemicals Company personnel at the Aberdeen facility. Mr. Jerry Banks of the Mississippi Department of Natural Resources, Bureau of Pollution Control observed testing on March 10, 1982. Personnel involved in sampling and sample analysis were: Dan Cash - Engineering Co-Op Student Dave Cox - Manufacturing Chemist Jimmy Grace - Quality Control Technician Dave Mahler - Environmental Engineer Veldon Messick - Senior Process Engineer C. Process Description Vinyl chloride monomer is received at the plant site in railroad tank cars and is transferred by compressors to the VCM storage sphere. The VCM is then pumped to fresh VCM batch tanks which are located in each of the two reactor areas. VAB.0001115756 MISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI A I. INTRODUCTION (CONTINUED) C. Process Description (Continued) PVC is produced batchwise from the vinyl chloride monomer. The plant produces only one type of resin; that by the suspension polymerization process. The reactor is first . evacuated to remove air and inert gases and is then charged with carefully measured quantities of VCM, water and a suspension agent. The reaction is initiated with a peroxidetype catalyst. Following completion of polymerization, the reaction is killed and the unreacted VCM is removed from the reactor in the recovery sequence. The recovery system is designed to recover unreacted VCM for recycle to subsequent batches. During the pressure recovery phase, VCM vapors are pulled from the reactor and compressed, condensed and liquified. The liquified VCM is routed to the recovered monomer tanks. As a part of the recovery operation, steam is injected into the slurry to aid in the removal of residual VCM in the slurry. When the reactor pressure approaches atmospheric pressure, vacuum pumps are started and the reactor pressure is reduced to a vacuum. These VCM vapors are also compressed and liquified and the liquified VCM is routed to the recovered monomer tanks. By this time the slurry has been brought to a boiling condition by action of the steam injection and the vacuum. The steam blows through the slurry and purges the vapor space above the slurry before being pulled out of the reactor by the recovery system. Cooling water is then put on the reactor in order to cool the slurry down prior to dumping the reactor. When the recovery step is complete, the PVC/water slurry is dumped through a slurry screen which removes oversize material. The slurry is then pumped to blend tanks. After product pumpout, the reactor is rinsed to the blend tanks, which completes the reaction batch cycle. The PVC/water slurry is pumped from the blend tanks to a centrifuge in the drying area, and the extracted water is discharged to the process sewer. Wet cake is fed to a dryer in which- the resin is dried. The dried resin flows through a product sifter where oversize material is again separated and collected. Resin is then pneumatically conveyed to storage silos and eventually shipped from the plant in trucks or hopper cars. VAB.0001115757 * t EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI II. SAMPLING RESULTS SUMMARY A. Emissions Test Results The following is a summary of results from sampling and analyzing the reactor D-745 vapor space and dumped slurry for each of three reactor batches. D-745 Batch No. D-745-155 D-745-156 D-745-157 Date 3/9/82 3/10/82 3/10/82 Resin Grade 5265 5385 5385 Vinyl Chloride Emissions (Lbs. VCM/MM Lbs. PVC) Slurry Total 65 88 153 43 67 110 210 136 346 The process employed at this plant utilizes the reactor for poly merization and stripping. Because VCM flashes out of the slurry and into the vapor space while the reactor is being dumped, it is impossible to accurately segregate the slurry residual and the reactor opening loss. The standard specifies maximum emissions of 400 lbs. VCM/MM lbs. PVC from the slurry and 20 lbs. VCM/MM lbs. PVC from the reactor vapor space. Thus, a maximum emission of 420 lbs. VCM/MM lbs. PVC from the entire reactor is applicable to reactor D-745. The results of the emission tests summarized above demonstrate that reactor D-745 was in compliance with Sections 61.64 (a) (2) and 61.64 (e) (1) (ii) for each of the three reactor batches tested. The .total emissions from reactor D-745 did not exceed 420 lbs. VCM/MM lbs. PVC produced. B. PVC Production During Tests . The Aberdeen plant had a nominal PVC production capacity of 400 MM lbs. PVC/year at the time of the D--745 emission test. This corresponds to a daily average of 1,096 M lbs. PVC/day. During the two days of emission testing, the plant produced 971 M lbs. PVC/day, which is less than the nominal plant capacity. The maximum production rate can only be achieved in the-winter time when colder cooling water temperatures are available which allow for higher catalyst loadings. Futhermore, the maximum production rate requires perfect reactor scheduling without any reactor or dryer downtime due to maintenance or other delays. VAB.0001115758 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI II. SAMPLING RESULTS SUMMARY (CONTINUED) B. PVC Production During Tests (Continued) Since the plant utilizes a batch polymerization process, the plant*s production rate is increased or decreased by processing more or less reactor batches per unit time. The size of the reactor batches is varied only slightly over long periods of time for any specific grade of resin produced. During the emission testing, reactor D-745 was charged with quantities of VCM which are representative of the current batch size for reactor D-745. A VAB.0001115759 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI III. SAMPLING PROCEDURES A. Sampling Apparatus Reactor opening loss samples were taken with the apparatus shown on Figure 1. The components of the apparatus are described as follows: * 1. New, unused teflon tubing; 6.4 mm OD. 2. Stainless steel plug valves with teflon plugs, stainless steel hose connectors and interconnecting tubing. i 3. 15 liter Calibrated Instruments multilayer gas bags. 4. Rigid container, sealed airtight with RTV gel sealant. 5. Gast vacuum pump. 6. Calibrated MSA sampling pump rotameter. 7. Needle valve 8. V Tygon tubing. B. Sampling Procedures The reactor slurry samples were obtained from a sample tap on the reactor dump line. Prior to taking the samples, the sample line was purged for approximately 10 seconds with slurry. The three slurry samples were grabbed 5, 8, and 11 minutes into the dump period. 2-ounce sample bottles with screwed on covers were used to collect the samples. Immediately following sampling, the sample bottles were taped shut with electrical tape and labeled with the date, time and reactor batch number. The samples were then stored under refrigeration and analyzed within 24 hours of collection. Reactor vapor space samples were taken immediately after the slurry dump land rinse. The sampling train was tightly assembled, using a sample bagtwhich had been leak checked overnight. The sample bag was evacuated until the rotameter indicated zero flow, and the valve was shut. Reactor D-745Ts top manway was then opened, and the sampling line was lowered into the top of the reactor. The sampling line was purged at a rate of 1 to 2 liters per minute for approximately 1 minute. Immediately following this purge, the sample was taken. The top of the reactor, the middle of the reactor and the bottom of the reactor (within 6 inches of the bottom) were each sampled for 5 minutes, in that order. Flow VAB.0001115760 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI III. SAMPLING PROCEDURES A. Samp1in aratus (Continued) through the sampling train was maintained at 0.5 liters per minute throughout the sampling period. At the end of sampling, the valve above the sample bag was shut, the pump turned off and the sampling apparatus disassembled. The sample bag was trans ferred to the plant*s laboratory and analyzed within 24 hours of sample collection. VAB.0001115761 1a FIGURE 1 REACTOR OPENING LOSS SAMPLING APPARATUS A Tygon Vacuum Pump. VAB.0001115762 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN. MISSISSIPPI IV. ANALYTICAL PROCEDURES A. Analytical Apparatus 1. Slurry Samples The following apparatus was used to analyze slurry samples for residual VCM: a) Vials, unused with Septa and aluminum seals. b) Analytical balance, with minimum sensitivity of 0.001 gram. c) Syringe, 100 *il, Hamilton #710. d) Vial Sealer, P-E No. 105-0106 e) Filter Flask, 250 ml capacity. f) Buchner funnel, 7 cm. g) Filter paper, Whatman No. 4 h) , disposable aluminum i) Cork borer j) Oven, Blue-M natural draft k) Gas chromatograph, P-E F-42 Headspace Analyzer 1) Chromatographic column, stainless steel 2 m X 3.2 mm, containing 0.4% Carbowax 1500 on Carbopak C. m) Thermometer, minimum range 0-100C, minimum sensitivity 0.1 C. n) Sample Tray Thermostat System, Haake Model N3B. o) Integrating Computer, Spectra Physics, SP 4000. P) Barometer, sensitivity 0.1 mm Hg. q) Thermometer, accurate to 1C, near GC. r) Recorder, Houston Instruments potentiometric strip chart recorder set on 1 mm full-scale response and 1 cm per minute chart speed. 2 Reactor Opening Loss Samples The following apparatus was used to analyze gas bags for VCM: a) Gas chromatograph, HP model 5711 A with a 1.0 ml heated sampling loop in a manual sample valve and flame ionization detector. b) Recorder, Perkin Elmer potentiometric strip- chart recorder set on 1 mv full-scale response and 1 cm per minute chart speed. A VAB.0001115763 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI IV. ANALYTICAL PROCEDURES (CONTINUED) A. Analytical Apparatus (Continued) 2 Reactor Opening Loss Samples (Continued) c) Chromatographic column, stainless steel, 2.0 m X 3.2 mm, containing 80/100 mesh chromosorb 102. d) Flow meter, rotameter type with 0-200 ml/minute capacity, with control valve. e) 6 gas regulators, dual stage brass. f) Thermometer, mercury type, accurate to 1 C, mounted near the sample loop. g) Barometer, accurate to 0.1 mm Hg. h) Pump, ITT diaphram. i) Tubing, teflon, 6.4 mm O.D. j) Sample bags, Calibrated Instruments multilayer bag of aluminized Mylar. k) Data Processor, Spectra Physics SP4000. 3. Reagents The following reagents were used to analyze slurry samples and gas bags for VCM: a) b) c) d) e) f) Nitrogen Gas, zero grade. Hydrogen Gas, zero grade. Compressed Air, zero grade. Calibration Gas, 496 ppm VCM in nitrogen, certified. Calibration Gas, 2188 ppm VCM in nitrogen, certified. Calibration Gas, 4015 ppm VCM in nitrogen, certified. B. Analytical Procedures 1. Slurry Samples The following procedure was used to analyze slurry residual VCM: a) Sample Storage + Slurry samples must be stored under refrigeration. Analyses will be performed after sample has cooled to at least 30 C and within 24 hours of collection. VAB.0001115764 It I EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN. MISSISSIPPI A IV. ANALYTICAL PROCEDURES (CONTINUED) B. Analytical Procedures (Continued) 1'. Slurry Samples (Continued) b) Slurry Samples % Tareavial with septum and seal and record weight. Tare and record the weight of an aluminum pan (label pan). Set up vacuum aspirator and filter flask assembly. Pour slurry into funnel and start vacuum until steady stream of water stops (15 sec.). Remove vacuum. Use the cork borer transfer about 1.5 g. to the vial and seal it. Take another plug for solids and transfer to an aluminum pan. Quickly weigh and record the pan and save this sample for determination of total solids. Weigh and record the vial weight. c) Preparation of Gas Chromatograph Flame should be lit at least one hour prior to analyses. Nitrogen pressure of 1.4 kg/cm gives 32 cc/minute. Set hydrogen at 2.1 bar and air at 2.8 bar. The oven should be set at 65 C, the neddle at 150 C, and the injector and detector at 150C. d) Programming the -Chromatogrpah Set "1" at 3 seconds, "A" at 07, "BF" at 09 and "S" at 2 minutes. Set ''Analysis + Backflush Times" toggle switch at "X0.1" position. Both range and attenuation should be at a value of "1". e) Preparation of Sample Turntable The bath should have been on at least 4 hours prior to use. Check the temperature in the turntable to insure it is at 90+0.5 C. Insert vials in turntable as follows: Positions 1 and 2 are old standards in the vials from a previous run; positions 3-6 are the calibration standards; positions 7-30 may be samples of any type.- Condition all samples including standards at least one hour (not to exceed five hours).before analyzing. After conditioning, start the chromatograph program and recorder. VAB.0001115765 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI ANALYTICAL PROCEDURES (CONTINUED) B. Analytical Procedures (Continued) 1. Slurry Samples (Continued) A f) Determination of Total Solids Place the label aluminum pans in the oven. The oven should be at 110+5 C. Allow the samples to dry for 45 minutes. Remove and cool to room temperatures. Record the weight and calculate the fraction of total solids (dry weight divided by wet weight). Record this value on the data sheet. g) Calibration Standards Calibration standards are prepared by filling the vials (at least two sets per series of samples) with the vinyl chloride/nitrogen standards, rapidly seating the septum and sealing with the aluminum seal. Use only stainless steel lines from the cylinder to the vial. The sample line from the cylinder must be purged into the hood prior to filling vials. After line purging, place the end of the tubing into the vial near the bottom and allow purging of the vial for one minute at 1000 cc/minute. (Hold the vial with finger tips only to minimize temperature affect of hand). Slowly remove tubing and quickly cap the vial with the septum and seal. Inject 100 ul of deionized water into vial. 2. Reactor Opening Loss Samples The following procedure was used to anlayze reactor opening loss samples for VCM: a) Sample Storage * Samples must be kept out of direct sunlight during storage. Analysis will be performed after the bag has equilibrated to laboratory temperature and within 24 hours of sample collection. b) Sample Recovery Connect the sample bag to the GC sample valve inlet direct with Teflon ferrules. Prepare the equipment such that the sample gas- will pass through the bag, through the sample loop, through the pump, rotameter, and flow control valve at a rate of 100 ml/minute. VAB.0001115766 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI h ANALYTICAL PROCEDURES (CONTINUED) B. Analytical Procedures (Continued) 2 Reactor Opening Loss Samples (Continued) c) Analysis The GC column should be oven and previously sample loop prepared such that are equilibrated atthe130oWC and 100 respectively. The hydrogen flame should be ignited < at least one hour prior to analysis using constant and previously optimized flow rates for both hydrogen and air. Carrier flow at 30 ml/minute should also be established at least one hour prior to analysis. (Leave instrument on overnight during routine use.) Observe the baseline to determine both noise level and drift at the 1 x 10^ sen sitivity are acceptable. * With the recorder on and an attenuator setting of 1 x 10 2 , purge the sample loop with the sample gas at least 30 seconds at 100 ml/minute. Stop the pump, and when the rotameter just indicates no flow, activate the sample valve to inject the sample gas. Mark the injection point on the chart and read the loop temperature and laboratory pressure and temperature. Record all conditions on the chart. Start the SP4000. With the laboratory pressure and temperature, determine the water content of the sample at analysis from a water saturation vapor pressure table (assume 100% relative humidity in the sample). d) Instrument Calibration Fill evacuated Calibrated Instruments bags with the standard gases, always using the sample bag for the same concentration, daily. Use only stainless steel or the appropriate Teflon tubing connectors. Allow bags to equilibrate to laboratory temperature. m fcr Measure each standard gas in duplicate each day using the same GC conditions and procedures described in the above analysis section. Record all conditions as described earlier for each analysis. VAB.0001115767 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN, MISSISSIPPI A V. CHAIN OF CUSTODY Slurry samples and gas bags were handled as follows: Slurry Samples Sample Run No. 1 2 3 Taken By Dave Mahler Dan Cash Dave Mahler Transported By Dave Mahler Veldon Messick Dan Cash Analyzed By Jimmy Grace Dave Cox Jimmy Grace Reactor Opening Loss Gas Bags Sample Run No, Taken By 1' 2 3 Dave Mahler Dave Mahler Dave Mahler Transported By Veldon Messick Dan Cash Dan Cash Analyzed By Dave Cox Dave Cox Dave Cox VAB.0001115768 EMISSIONS TEST NEW REACTOR D-745 CONOCO CHEMICALS COMPANY ABERDEEN. MISSISSIPPI VI. APPENDIX The Appendix of this report contains the raw data and calculations used to obtain the sampling results. This information is pre sented In the following order: * Operating data sheets for reactor D-745 during the three-batch sampling period. Sampling data sheets. Reactor Opening Loss and Slurry Residual Analytical Calculations. Integrator and GC printout data. Standard Gas Certifications. Reactor Opening Loss Calculations A VAB.0001115769 REACTOR . Water Tk. FORMULA I Colloid <i VC Tank LLjCatalyst TYPE tints Inches Counts M O Type 4- 'DATE S' -DURA SEAL Counts RVCM 02'Lcvel -PH Pressure Seal Water Seal Water Press t A Inches GPM Pre-charge Amps lv Running Temp. A rPVA IN. Pressure pa TIME INITIAL Reactor & Material OX. For Charge Evacuation Start <?V k Before Net *riAL * Standard 10 Minutes Evacuation Stop Inches Hs Actual Dev Charge Start tStandard 11 Minutes Charge Complete Catalyst Start Time Reaction Temperature Reached Actual Dev Standard 3 Minutes Catalyst Complete Turn Around Time Recovery Start Run Time Ilrs. * Recovery Complete Amt. Recovered To Mi Actual Dev Standard 68 Minutes Actual + * Dump Start To Tank Bldg. No. Standard 25 Minutes mments: Dump Stop Chcm Wash Start Chem Wash Finish Rinse Start Rinse Complete Swirl Start Swirl Complete iwi Total Stripping Steam Time Reaction Killed I O^/o " * Actual Dev Standard 25 Minutes Actual Dev Standard 10 Minutes Actual Sfend&r,j fttiuaJ -Tblii STj. Dcy jfl Minifies De T)e /- VAB.0001115770 + ,_ t" * 4 4. i <1 v*K -v ;r'* 'S-. ; - jfc'*T* i + * * l * *V -, h - *' . J -. :* -(/> * -`.\ t r.f-: A*^' .1 I . k * ` ` * \r\. * " . l * j_ i t- ^ * ' v *." '1 - ,fc ' 4* *i * l. ` ^ , . _ '' * J, ***./.. ' '0 m * ,,< - f, . m '+ - - -* . ** *. - ,, , - -* - * m ^ j i * . , . . ' ^I * *.+ +**"*-* * * . ,, * .v * * i - **'*\?: ; A 4 ; rF . 5 ^ * /. *. * 'Z^Z ->J ". ' --Sfc. : * V- ' * r* * 'J . < '**J* V- *; -- i -v*. t . V4` I-'* 1 p -.-^V* n ' .r . a. * * -- . * * ^ - T.J* - **v*`,'j t: ' *T* * - l j .h **' 11 ."''b VT't .. '. s- * ."+ *- l ^ * X * *""* ' V-, - -At-..- - v - -. ~ _' ':' v .--* * j* - * . ~z "' ' : r?r^" r .'.* " * i J* _" 4 r ,*, ,, . --^^ , M *, ^--- <- `-TU. ^ -*r-* -- . - * .** ^f ' ~ *._ '* - - >* vi i*^'V *:-!--* T i: v - ^ ** - '*V*F 4F1 *'#.* *-- .* r i'<rW> '/ r* B- ^ j . . .. * " , "V " ,, ' k 'i . *' * ., _ M f. -* .* - T . ^^ V .4 .*, . *r ' - m^_ VAB.0001115771 ilEACTOR FORMULA TYPE DATE O' JOURA SEAL Water CoIIoid^Mi^LGa] VC Tank Counts Inches Cbunts FVC\ Cbunts RVCM OH* Level OH Pressure Seal Water Inches GPM JCatalj GaL ScalW Psig Re-charge Amps A rPVA IN. `Running Tpmp /{3 7 F Pressure / / S' -pa* Stf/E i 0~fcL W, H ~fls; r.wJ TIME INITIAL el? Sh /?JD /79~o Vk bso \%S \is!?-To izm. /7Yt> \yh /?*' 1fe- _,_ 0JC For Charse Start Evacuation Stop. Inches H Charge Start Charge Complete Catalyst Start Time Reaction Temperature Reached Catalyst Complete Turn Around Time Recovery Start Run Time M~RGrt .Before "P^T* L is *i-&CTTlE f<& .Net l & Standard ctual Dev. 11 Minutes Actual Dev Standard 3 Minutes Actual * -Dev. Standard Minutes SL3<s>&\ Recovery Complete Amt. Recovered Tn C " Actual Dump Start To Tank Fldg >Jn Standard 25 Minutes XX < r' mments: Dump Stop Chem Wash Start Chem Wash Finish Rinse Start Rinse Complete Swirl Start Swirl Complete Total Stripping Steam O Time Reaction Killed Actual Dev Standard 25 Minutes Actual Dev Standard 10 Mimites Actual SiandorJ /)cuaj_ Tota l SlJ. - Dev _ Dei' 1TT5772 vVJ-sPi.l V'" f * - . ' ** * ^ ' r _ - . -- ' ~ 1 - h ^ ' . *- vs f' 'r>* t' .? * - , -.- t t r ^ * I J- . ^ *- * *I L---vrf ii: i + - * -; rv-<V I. V . s. 1 ' *',,* *,* ***. . > Ti , .* L' '- V , ;.v` -1 * =' NoV-' *:.- > *; '.: j* * ^-- *-*-: **- *1 - * ' ,r* ~ - 1 ' . - ' \, , t % ;p ' V' 1 J. f- /> ~* + -v '_ r -- I r-. '*-' A I, * J TM 1. l 1 1 m' .* V* '' ' * ' l I Ji V * V` 1 v-T mrnm**:% %iv, Vi1* \ j #. J A .- v w I I I 'V r- !< " r "*,>'- -- ' VV ' ' -- - v * - . VN't-*.- - * fV - i i* j * i i *I *, * .r v ,. * 4 - j . ` * ": * *l pi h *>y.% ; '^ i J _i ^ ^ K ^ ^^; VV ^ ^; SiS'y: *i.\Tf^rJT5 " ^ >- V- ^ :> bf j * -: 1 * r 1 . * . . J. V+ . 'vr' * 1 * * r VAB.OOOl115773 REACTOR FORMULA TYPE DATE /& ~ J3URA SEAL ColloidHal VC Tank % -Catalyst - Cal Pre-charge Amps unts .Inches. Counts FVCM. Type A Counts RVCM OR* Level -t)R Pressure Seal Water Seal Water Press rPVA IN Inches GPM t M~RG, -/Jc y' `Punning Temp. F Pressure pa S/ec.T6T? SkSiTC H Hj/He/J TIME INITIAL SH> Reactor & Material OJC For Charge .Before 7prr L is ^*er* ^4. &. .Net aIa ie Prcsscl Evacuation Start 10 Minutes Evacuation Stop nchesH Actual -Dev Charge Start ^Standard 11 Minutes Charge Complete Catalyst Start Time Reaction Temperature Reached Catalyst Complete Turn Around Time His.^2 Recoveiy Start Run Time 6L Recovery Complete Amt. Recovered To Mi H Actual Dev Standard 3 Minutes Actual Dev Standard ^BMSnutcs Actual /JDtv3z>I7 Dump Start To Tank Bldg. Noj Standard 25 Minutes Dump Stop Chem Wash Start Chem Wash Finish Rinse Start Rinse Complete Swirl Start Swirl Complete Total Stripping Steam Time Reaction Killed Actual Dev Standard 25 Minutes Actual Dev Standard 10 Minutes Actual Standard /9ct wai -- To/a-/ SU, _ -Dev Dei'. VjffiobK1TI3774 r I' * -JlK-j&*nK#43i r jv- r r r r r i r. ' i * , >' . 3 1 J * . .* J. -***': p -* . ^: ... *; / '' _ . 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I' L I [ ;; c*j-<` ** frv* * /i.y,-*c-' > -V -1-' '; r l^^ii t -* 3? * .r y- . ^ p ; * - * m * rr 4 - . r h ^. * J 1* , 1 * l t ,x L * -\ * i* * *. v' , ^ J ,..:; ,--.,.,: L - ,r ^ t w ?*- * * 4 ^ a ,4 L. r^" *4 A. V- ? ^ --r>rC j- *i ^* * t< *4 > i^ fc kf * A REACTOR D-7U5 COMPLIANCE TEST 3DATE , = BLEND NO.: RESIN: 2. SLURRY SAMPLES DUMP STARTED: 7: MM Sample / 3 Time Taken By 7' 27frH 7,' ^6 t>ib Transported By Analyzed By Wt MH**- C<ra<rc. trn#*- jv*y iyud'Uffltex- <r/***f 6r*"- REACTOR OPENING LOSS Time Started Taken By Transported By OfH'b MttHU/C 1/hiVCH Analyzed By VAB.0001115776 REACTOR D-7U5 COMPLIANCE TEST DATE : $ BLEND NO.: u <3 V3ffX. RESIN: SLURRY SAMPLES DUMP STARTED: 33 ??rA Sample / Time Taken By 2 f cf % pM P fatf ^ 2r 4^?^ Transported By s/glbOfil I/&m tfgSSttK. Analyzed By 0QVC Cof DvC Cf REACTOR OPENING LOSS Time Started pa Taken By pft\/- mmjML. DAf>r C/H. & Transported By p c/te ^ Analyzed By (kce. ^0/ ` VAB.0001115777 REACTOR B-7^5 COMPLIANCE TEST Z/lDATE: C BLEND NO.: RESIN: 5"35 SLURRY SAMPLES DUMP STARTED: Sample / Time z //' l('(f 3 Taken By Ot-t7 pen ferl Transported By C D 0C Analyzed By GraO^ P a. REACTOR OPENING LOSS Time Started //:3S- Taken By ' /fc/y * Transported-By - * 1 VAB.OOOl115778 PPM, VCM IN AIR BAG * SAMPLE ID: ~?X>VS SleAjJ u 5^37? f DATE: 3Z/o/ s , %/ OjOJt^KV Sample Loop Temperature for Standard (Tr) Sample Loop Temperature for Sample (Ts) Barometric Pressure for Standard (Pr) Barometric Pressure for Sample (Ps) % Water Vapor Content of Bag (B) Response Factor (Rf) * Area Standard PPM, VCM in Standard Area of Sample (As) C vcm As X PR X Ts X 1 RF Ps Tr /OO /OP 7 12 llonolr Bag Temperature (B) VAB.0001115779 M CONFIDENTIAL'4 ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM. VCM SAMPLE TYPE: DATE: >b- g~Z- P-EACTOR: ~74 $ LOT #: ^</-^7g- Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -J- wet weight (TS) SW x TS *= Resin Weight (RW) RW -J- 1.4 - Resin Volume (RV) SW - RW = Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV * Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K * C + 273 = (T) 1 - TS * Water Fraction (TW) /9a, s . 'M J. .7*7 . H9S -1 -a-S A at .7/ft RVCM (dry) VV x 10 -3 RW + (tS x 2.36 x 10-3) RVCM of Sample Dry Basis li.Tl \hi VAB.0001115780 1 CONFIDENTIAL IB ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM.L VCM SAMPLE TYPE: S3 -5__________ DATE: _______ 3 -SO __________ REACTOR: ?4S LOT #: J* > g" Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -f- wet weight (TS) SW x TS " Resin Weight (RW) RW -J- 1.4 Resin Volume (RV) SW - RW = Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K = C 4- 273 (T) 1 - TS - Water Fraction (TW) RVCM (dry) W x 10 -3 + ITS x 2.36 x 10-3) RW RVCM of Sample Dry Basis 2V S '.M*V /3g, s <5 S5 2 I 4U=i .3 IS _______i uu S v1 3i. 7 ? _____>_3_Z_ h As P STt VAB.0001115781 ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM, VCM SAMPLE TYPE: DATE: S'Z.LS_________ _______________ * F.EACTOR: LOT #: 75 3 <-) I'Vfj Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -J- wet weight (TS) SW x TS * Resin Weight (RW) RW 1.4 = Resin Volume (RV) SW - RW Water Weight (WW) RV + WW - Sample Volume (SV) 23.0 - SV = Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K = C + 273 = (T) 1 - TS = Water Fraction (TW) RVCM (dry) W X 10-'3^ + (TS X 2.36 X 10-3) ml RVCM of Sample Dry Basis As P VAB.0001115782 I PPM, VCM IN AIR BAG A Sample Loop Temperature for Standard (Tr) Sample Loop Temperature for Sample (Ts) Barometric Pressure for Standard (Pr) Barometric Pressure for Sample (Ps) * Water Vapor Content of Bag (B) Response Factor (Rf) - Area Standard PPM, VCM in Standard Area of Sample (As) C vcm = As X PR X Ts X 1 SF Ps Tr I^B Bag Temperature (B) /do 76 ^ a ^ 3 4*2,3 VAB.0001115783 ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM. VCM SAMPLE TYPE: DATE: 3 to- a REACTOR: 7S LOT #: 3g3gl Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -J- wet weight (TS) SW x TS = Resin Weight (RW) RW -- 1.4 ~ Resin Volume (RV) SW - RW - Water Weight (WW) RV + WW - Sample Volume (SV) 23.0 - SV = Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) J Lab Temperature at Time Standards were Prepared in K * C + 273 * (T) 1 - TS = Water Fraction (TW) RVCM (dry) VV x 10 -3 RW + (tS x 2.36 x 10`3) RVCM of Sample Dry Basis 3tm 2 2,)) 15 lJlL TW x 1.82 x 10-3 As P EFT VAB.0001115784 I -d ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM. VCM SAMPLE TYPE: S.5. DATE: _____l-/0-XT_ REACTOR: 7V S LOT #: 4 38"L- Response Factor (RF) Area of Sample (As) n Whole Sample Weight (SW) Dry Weight -J- wet weight (TS) SW x TS - Resin Weight (RW) RW -- 1.4 * Resin Volume (RV) SW - RW - Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV * Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K * C + 273 (T) 1 - TS = Water Fraction (TW) /*<=! 7 a U? _Lj>32____ . 7g h bu If RVCM = (dry) VV x 10 -3 RW + (tS x 2.36 x 10-3) + RVCM of Sample Dry Basis = TW x 1.82 x 10 94,o *i. *~7 .5r .c?xl As P R3TT VAB.0001115785 S CL ANALYSIS .................................................................................................................................... " OF PVC 1 --"M SLURRY AND WET --- ' -- M CAKE FOR PPM. - -M - II ! ! f VCM SAMPLE TYPE: S1ZS DATE: 3-/0- R-a- REACTOR: ~7 </ S LOT #: 3M3 8X Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -f- wet weight (TS) SW x TS - Resin Weight (RW) RW 1.4 Resin Volume (RV) SW - RW * Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV - Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K - C + 273 * (T) 1 - TS = Water Fraction (TW) 9 Of Soy jrtoy 't*5 L|hg___ >7?; >S?L / 5sr7 PI % UI 3 73 a qs *3 S RVCM = /VV x 10 (dry) \~~RW----- x 2.36 x 10 RVCM of Sample Dry Basis * As P RF"T VAB.0001115786 zp# ROL- ^ PPM, VCM IN AIR BAG d a SAMPLE ID: ? *f 3g& S3&S Ja.~->. ? H S DATE: 3^Jb- Pi______________________ Sample Loop Temperature for Standard (Tr) -*- Sample Loop Temperature for Sample (Ts) Barometric Pressure for Standard (Pr) Barometric Pressure for Sample (Ps) % Water Vapor Content of Bag (B) Response Factor (Rf) Area Standard PPM, VCM h" Standard Area of Sample (As) C vcm * As X PR X Ts X 1 RF Ps Tr T^B Bag Temperature (B) T>$7 A VAB.0001115787 * ANALYSIS OF PVC SLURRY AND VIET CAKE FOR PPM. VCM SAMPLE TYPE: S3 S^ DATE: ?--/P-- AT- 'RiS-ll-gX Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -f- wet weight (TS) SW x TS Resin Weight (RW) RVJ 1.4 = Resin Volume (RV) SW - RW * Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV - Vial Volume (W) X Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K = C + 273 (T) 1 - TS * Water Fraction (TW) RVCM (dry) VV x 10 -3 RW + (TS x 2.36 x 10 -3 RVCM of Sample Dry Basis + (TW x 1.82 x 10 140 * As P ITT VAB.0001115788  CONFIDENTIAL ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM. VCM SAMPLE TYPE: DATE: S- >0- gx 'Rfirro 3-n-Zi- REACTOR: LOT #: ?5 Response Factor (RF) V Area of Sample (As) Whole Sample Weight (SW) Dry Weight --wet weight (TS) SW x TS 3 Resin Weight (RW) RW -J- 1.4 * Resin Volume (RV) SW - RW * Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV 33 Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K 38 C + 273 = (T) 1 - TS * Water Fraction (TW) * = - " - - = /S*7'*f O.3KT fgS .C 1 .SQ7 .`SfcX .uiz 23^ 7&Q .3g RVCM (dry) /VV x 10"3\ + (TS x 2.36 x 10"3) + (TW x 1.82 x 10 \ RW ) RVCM of Sample Dry Basis M4. \. *v. As P EFT VAB.0001115789 1 A ANALYSIS OF PVC SLURRY AND WET CAKE FOR PPM. VCM SAMPLE TYPE DATE : 3-IQ- ff"2- REACTOR: LOT f: 7? 5 Response Factor (RF) Area of Sample (As) Whole Sample Weight (SW) Dry Weight -J- wet weight (TS) SW x TS * Resin Weight (RW) RW -J- 1.4 Resin Volume (RV) SW - RW - Water Weight (WW) RV + WW = Sample Volume (SV) 23.0 - SV * Vial Volume (W) Lab Barometric Pressure at the Time the Standards were Prepared (P) Lab Temperature at Time Standards were Prepared in K = C + 273 (T) 1 - TS * Water Fraction (TW) a ii 0.81S , 53 xM t ip RVCM (dry) VV x 10 -3 RW + ITS x 2.36 x 10-3) + (tw x 1.82 x 10 RVCM of Sample Dry Basis /3X W.i , e> V % As F VAB.0001115790 1 kJ 6 i TOTRLS 291 264 X1 m ^w1JL7I *** * w *-* .* 1 Oi *^r 117 4556 1814 T1 OC wl X --* --* O *. 7i OiC xO. F L V v OCiTjc 2936 OQ-TC X. RUCM 1982 MRR 18 14=23=33 CHRHNEL 2 RUN 46 FILE 2 METHOD 5 X HDEX S.RMT= 1* \ 1 SRMPLE * 588 XF= 1 NOME CQNC RT RRER KF 1 UCM 4 . 173 - 565 38.32 2. 418 48 58 72 182 589 1660 89828 7102 F F L 2936 2936* 2936 2936 TOTRLS 33 47 98291 RUCM CHRHNEL I NDEX 1 S-RMT= 1 NRME 1 UCM TOTRLS 1932 MRR 10 14=26= 12 RUN 47 FILE 2 METHOD 5 SRMPLE 4852 4 D 1S * CONC XF= 1 RT RRER KF . 051 268. 5 8.426 49 72 183 151 765812 24741 F * 2936 2936 2936 268.9 789984 VAB.0001115791 % RUCM CHANNEL INDEX NAME 1 UCM 3 TOTALS 1982 MAR 10 11542:84 RUN 3 FILE 2 METHOD 5 CALIBRATION CONC RT AREA KF 142 49 71 102 261 418933 10619 L > 2950 142 429753 A4 NEW FILE NAME UCM RT 71 KF 2950 ROL UCM CHANNEL INDEX 4 NAME 1 UCM TOTALS CQNC 73 73 RT 44 AREA 114 L 485531 405645 KF 1 ,I 7U0 0 RUCM CHANNEL o I NDEX o RUN 4 CALIBRATION 1982 MAR 10 11:45:07 FILE METHOD NAME CONC RT AREA KF 1 UCM 43 142 14 71 415081 29^ 101 10397 > VAB.0001115792 CHANNEL 2 RUN 2 f H o H r3) w cn C-4 C-4 *fc- t- ih)ll * K) "-J O C-4 C-4 OS CO VO C -4 - Q* k"'I cAo A Q '0 C-4 Cfl hj cr> W Q to K-t -p * C-4 C-4 -J ~n T1 r~ *n to K) Is) K' * vD VO C-4 cr> C-4 C(T-4. C-4 CTn n r-o a? C-4 Ch FILE 2 METHOD - ' VAB.0001115793 -.i-PNN-hL 2 RUN 29 FILE 2 METHOD 5 INDEX 1 SRMPLE DM1 3.RMT= 1.597 XF= 1 NAME CONC RT BRER KF 1 O ucr*r 4 5 6 .831 .813 63.84 .911 1.779 .448 48 58 71 87 162 115 145 60 295623 4273 8342 2182 F F F > 2936 2936* 2936 2936 2936 2936 TOTRLS bb .21 % 318545 RUCM 1982 MAR 10 13:36:55 CHANNEL 2 RUN 38 FILE METHOD 5 INDEX 1 SAMPLE DM2 S. AMT= 1.469 XF= NAME CONC RT AREA KF 1 2 UCM 4 5 6 .825 .027 59. 16 uO"i? 1.654 . 417 48 58 71 86 101 115 186 116 255228 3755 7133 1881 F F F > 2936 2936 2936 2936* 2936 2936 TOTALS 62. 15 263131 RUCM * CHANNEL 2 RUN 31 198!2 MflR 18 13:48:38 FILE 2 METHOD 5 INDEX 1 SRMPLE DM3 S.RMT= NAME 1.493 CONC KF = * 1 RT AREA KF 1 2 UCM 4 5 6 .829 .817 59.44 . 373 1.742 . 417 43 58 71 37 101 115 126 75 260581 3325. 7638 1327 F F F > 2936 2936 2936 2936 2936 TOTALS 62. 51 274077 , -- VAB.0001115794 TOTRLS * I 4G52 660101 NEW FILE NOME UCM RT 303 KF 162-9 RUCM CHANNEL 2 RUN 43 MAR 10 16s 58s 44 FILE 2 P METHOD 5 NAME 1 UCM 3 4 5 TOTRLS CONC .092 61.56 3.539 5- 143 . 543 7. S3 RT 49 1 36 102 112 AREA 345 230237 13237 19261 2050 F F F > 265130 KF 2936 2936 2936 2936 2936 ROL UCM CHANNEL 1 INDEX 2 NAME 1 o RUN 93 CONC 4 UCM TOTRLS 4691 4691 1932 MRR 18 lb* 55* 44 FILE 5 METHOD 5 RT 29 50 134 194 382 AREA 441 134 54 1560 764065 % 766254 F L y * KF 162.9 A VAB.0001115795 SAMPLE 62 MAR 10 17:06509 METHOD 5 CONC .075 42.05 2.089 3.414 1. 'W* 47. 93 RT 49 72 87 183 112 RRER 266 149744 7439 12160 1114 S % F \ 178723 2936 2936 2936 2936 2936 FILE MRR 10 2 METHOD CONC .07 40.27 2. o41 1. l%it' . 19 44.01 RRER A '* A VAB.0001115796 O RLJH 31 1932 MRR II 12=21:03 METHOD 5 SRMPLE ERR 3-1 1.261 KF 1 COWC 0w> 1 226 91.3 7.279 2.67 . 444 . %_f i' 102.5 RT ZCf 43 I 37 102 113 116 RRER 115 0*v 36323 26354 y52 1639 2102 r-I7Q-> l Q F > F F > KF 2925 29^5 JI > 1932 MRR 11 12:23:55 2 RUN 32 FILE 2 METHOD 5 SRMPLE EPR 3-2 . 313 KF= 1 CONC RT RRER KF . 044 . 253 . 023 90.25 7.433 7.402 1.317 33 49 33 72 37 102 113 106* 617 56 215935 17300 1 *' 15 3151 F > F > 2925 2925 2925 9**Q^OjChW*. 2925 2925 2925 10t>. 255430 1932 MRR 11 12:26:39 RUM ** % METHOD 5 SRMPLE WoiXc; EPR 3-3 CONC RT RRER * ** 4 F F F J OCr"cr VAB.0001115797 <7 1> *f ROL UCM CHANNEL 1 INDEX 4; NOME 1 UCM T QTALS RUN 7a *u0 1982 MfiR METHOD ft ROL UCM CHANNEL 1 INDEK 43 NAME UCM TOTALS ROL UCM CHANNEL * INDEX NOME RUN 79 1932 MfiR 10 CONC J RT AREA 745202 745202 l MAR METHOD CONC TOTALS A VAB.0001115798 ROL UCM CHfiNNEL f* 1 RUN 75 INDEX NR ME 44 1 CONC 1 UCM p * * TOTALS ROL UCM CHANNEL 1 4 > RUN 77 INDEX 46 NRME CONC UCM 19S2 MAR 18 FILE METHOD RT 44 ftREB 138 96183 \ y KF i;70 FILE 5 METHOD 5 RT ftREfi TOTftl-S CHfiNNEL 1 INDEX 39 NAME UCM TOTALS RUH 78 FILE 5 METHOD CONC RT 299 ftREfi * w * 384566 > KF 1 78 384566 ROL. UCM CHANNEL 1 INDEX 41 HR ME 1 UCM TOTALS RUN 72 1982 MftR 10 FILE yj METHOD J COHC RT 47 382 ftREfi 49 L 81469 > 381518 KF i 70 AI W * *I * VAB.0001115799 RGL UCM CHANNEL i INDEX 5 HOME h 1 UCM TOTALS UCM CHANNEL 1 INDEX 51 NAME 1 UCM TOTALS ROL UCM CHANNEL 1 I NDEX NAME 1 UCM TOTALS RUN o 1 1982 MAR 1QT METHOD CONC RUN RT AREA 47 12 1 248 45 607 1117242 L > 1118142 1982 MAR 10 FILE wl METHOD CONC RT AREft 143 7025 L 296 1898791 V 1105816 RUN OT CONC i VAB.0001115800 t ROL UCM CHANNEL 1 INDEX 60 NAME UCM totals * RUN 91 CGNC 1982 MRR 10 FILE J METHOD ** RT 305 BREA * 647915 > KF 647915 % ROL UCM CHANNEL 1 INDEX 61 NfiME ULM totals RUN 92 CONC 19;S2 MAR 10 FILE 5 METHOD ! RT 305 AREA 660185 > 668105 tKF :OL UCM HAN NEL N l.*EX SAME -1t o 1 4 *CM OTALS RUN 93 h 1982 MAR FILE 5 10 * METHOD - 5 RT 29 5S 134 IP* AREA 441 134 54 1560 764G65 F L > 162. ^ Se>Y 4 < 7~r *t oti *a K VAB.0001115801 B1- f ROL UCM CHRNNEL 1 INDEX 33 NAME UCM TOTRLS RUN CONC 1932 MfiR 10 J METHOD yj RT 99 RRER 3201 3201 > KF I lz* k) ROL UCM CHANNEL 1 INDEX 39 NAME UCM TOTRLS RUN CONC w L 1932 MflR 10 yj METHOD sJ RT RRER l4 Ut111 S14566 KF *' * ' t VAB.0001115802 4 tL> fS>m 3 ROL UCM CHANNEL I k IT'jw i n-^Ci 'i NAME UCM FOTALS L UCM ANNEL DE X M M TRLS 1 1 ROL UCM t* CHANNEL * 1 INDEX hi it ii_ UCM T OTALS RUN I 1932 MAR 11 METHODI COHC RUN t- RT AREA 38 61750 61750 KF 1932 MAR 11 FILE METHOD ji CQNC RT 02 AREA 264510 > 264510 KF RUN 95 1932 MAR 11 FI METHOD CONC i RT 302 AREA / 502405V7 > 50248 I KF 4 ri f h ROL UCM CHANNEL INDEX 1 'll li iL UCM TOTALS 1 F RUN 96 1982 MAR 11 FILE 5 METHOD 5 CONC RT 362 AREA r 510652 > 518652 TM KF m . 7u VAB.0001115803 ROL. UCM CHftNNEL INDEX NAME 1 RUN CONC 1982 MRR 11 FILE J METHOD RT flREft KF rOTRLS ROL UCM CHftNNEL 1 INDEX 3 NRME 1 *"r * T 4 UCM TGTftLS RUN 4 1932 MRR 11 FILE 5 METHOD 5 CONC * RT RRER 29 58 134 194 296 622 140 135 7503 2935021 F L > 2993421 w KF CHANNEL 1 X NDEX 4 NRME J RUN 5 FILE MRR 11 5 METHOD 5 -- CONC RT 26 50 143 191 296 RRER 566 105 40105 10151 2778334 F F F L > KF **' 3 VAB.0001115804 mm 0 4 o k> \A Q U Ul * <o * ki o * GC <x w ti *s4 > \A * \A "2 0 *4J * O1 <b < oc -4 c K o O' -I 1 VS V O *0 ' o' > K *4. c VAB.0001115805 > CONFIDENTIAL 1 C I- 4 * VAB.OOOl115806 * CONFIDENTIAL VAB.OOOl115807 Q S lrn S -f/JW <* C' - + V 0 J -l' A tl i l li n o y7 7 V * S/N 0 1-d.V 'ilO j h CONFIDENTIAL Q * * \A ^0 t: c ^ V: O 0^ -4 : V Ot <v ) u. c VAB.0001115808 CHART NO. 056-7300 It m mm fV <1PV \ CONFIDENTIAL ~t------------------------------- i -- V --^ W "^ > ..I I # ' * * I mm m * -B + * - - *-J i4 # '** *4 ^ * * Oil . - I 4 M- I * * T IM - - I ^ M* - ^ _!.... r.:.l:: *'i - j--------- t~ "il '_M * f * *1 * *# * ' * * i 4 i* -----------m--m--r-------------------r ------------ 1 V *IV * * V .44 *. ^1 4 *i --:f J * ** __i___ .!_. i l.._ -t,,. -- ,, ** - -J..-- M *'fit *M >*< ---------- J--------- J ' MBMM* IM -- Up \ **# Im i ____ L 4 H * tvi_ .... .... J_ _ _ _ _ _ _ i,, ? L J____ !J J______(_____ _i liM 4 >h 4 4- *+ * ____i .* V 4 o r-. j C-,: J T* * . ri '*-4- .... J_____ t* i * 4j 4' J I L----- - J 4 f* -- \7 T" ... . * ~4S 11 -m *- i- _r m i ^4-* * *' ririJcL __ I 4 4'V *fd :_t_: iv m * <. J_____ '41 l* ** 1 .j----------------------------------- ^ ; -- *-*--------------------------- f M 1 HfM m T * w4* -al^H- .v M a-. :. *-- * . * 1 .BMto ta4 i :. r... !__ -X "''J * *' _ :j lU-_______________________~~ " " f*. 'B 1^** *. *ytrrTrr ^i _ -- 'TpS,\ I r7*. % j* "* 4 k P * I r + 4> *^ * * m, --. - - .* . t *-* -- - i- ---i ... b i * m % * _____ J I IjT..cT _Sl.j cp. l#** 4 i V -J* h* t t- ___ !______ }_______: 1 . I 1i J _. __i i . Up jk1 w \ I. '* *# 1 -Jt __ i :_..J]___ 1 t _J 4144 *-4 _..'.'! I,, *, ". **+1p J j1' '.' .""' --i -W'-* 'i # T t ^ w-*-- ^ _ ____j.. .. _J*_______i3 - . --|\ -----* * 4 * ^......- ~l------ i-------] ..Tl-".-J"TMi !_. j ____I.............. j_ I --* 4- _ ' * 4*a 1 ai ____J ---1-----------1-* -- ____________ ^_ "11 -.- - ^ .. - - 4 Ihi i x! -------J---------j-----------------~3Z r.7ZJ" TMj............................................................................................................................................................................................. 1 4. * t-b4*ri I " ... -- "*" *- J ' "1 -- __ !..... i ) c: i' * l - 4 f* ...i____O..LO___I ' 4k W:_to * 4- <4 a-4 ** t-- i ^ f - 4 I w .B J ? __ i Jj---------- .. V \rdrA- _ii_.:;.:.T____ J_ ! < __ j __ _'2. 'I ____|^ ______|_______j____ JJ ______ ^jWt B *. * +- + * -* - 1 -- 4-- * .M *p . .. k*. 4|, - ' ^--s~r~t------ -------- !-------{ it! ~iTJ I .rr. " jt :*:; r H 4 nMN JI 'f" * ^ tv * * 4 * \ . I___ m % ------------------------------- ^,T-r^j - ^ , .!____ 1_____ i____ J * -B M-H-a -- I r--* > B fMMM - M ~. IriZlTiL__ rX|-:- ^hF ^ - *4 BB B I V +af ---'I i'r-X:-..'" M * H -*#. 4 1* BkM MB *-V '*'*1 f:.:;x;:i|...M an 4a - ka WM a 4- a rnm ** 1 --I-jaf-f * b -Mt --------------------------------------------- 1 wMBf Ma-4* * ------------------------------------------------------------------ -----------------------------------------------a- --------------------------------------- m-m * * 1-4 M-W . M- f a ptMBl -MB an B mbmi f-- i icrXJ ^ r i<MpW * ** ^_____________________ . * M * vaB.0(]01115* 09 t 4 CHART NO. 056-7300 T ^ r> k 1 ip M'1 ** CONFIDENTIAL 4 W* ^ *r4^ i *F * , V ' - * -* - 4 _____________1 # p*4 ^ __ -< * W 4 - " * 'i I `'I-----------------------------------------4* 4-> * * i. # # -- j------------------------------------------------------------------- f t ;r .....-i- i f l \W It V . * ! *- * p p ^ 'w l mi imp 4k** nv p * <*- -44 I i"*-W Vkp *m ** W * - 4 * 4 * -- -- * P *. I _____ i I "i........ J * * J *-** MB4- ^4** 4 * 1 W - * wf Wf4d *4 | ;I _ _ iri rS ~ "-"-jj--.........--. --| j -- ...... T* 4 *** 4* * b >- k i 1" 44 # 4 4V - *4 4 *1 44- t r-- p ^ 4 * j 4 -- - 4 ! *_ 4 *4 * - *f * M- L 1 ? .".z"vjpr..-ii-.--.'i;!:...:-> 4 jTM 4 h 4* IW t r * ' ri- 4 4* * h *4M r <| 4 *wrJ p4 *i ' AA A* ^ 4t*ir^ | | 1 "" J * * I. -* - J~ k - -T 4" --* -- d * -- N I *. I P f* I 4d V M * V ......._ I !#*-* p- J S 4 * * * jI Ij***- ' \ J -- t*____ B ' >-** i .. . 4t ^ V ->- - -W"4- L ........ iI _____ \J r* i ^ 41- * <6 * tm ` i * * m m' * lb 4 V p-l r, -m . -k - -4 i* M>< 44 4 I1 * w 4 IP I *4 4 . J._ . ..,,I...................... _i 1 b *m.V - ' " " ^ ^ 1 fc* ^ * V--^bv 4 ^V -- b^b ^ ^ MV i 4^-04 m * - *, * * M* 4* J .. j.-------------------------------------------------------------- f . l,,.... j,, ,-*(1 ... ^ ----------------- "T..........T <- ' t*- 4 I I 4* / fcvd - -| t - -I \m Wk P >1 - -*<- .t 1 V4 iW v 4 * 4 *1 4 - - m 4* ! f____ OJXT>___ l* P - N * *44* lW ll k MiP*4ft * ^ i p* * * ^.. . 4 <i v * --------- v .. .j I W 4 B B f * ' ft# H r ** IV * #4--- 1 ^ &4 *1 f*J k VI 1*4 t M Mt r * > | i 1^ ___<_-_4_____________________4___4___#___4_____P___4___*___jJ i *--. ....................................................................... ._ . ^ j __ ...ii_,v_!____________________________________________________i_,,.__________________________ - d v * T * m w -P _______ 1 \!______ ! w * *' A .-BI ^ *4 A> 4* -H 1--;l----------------------------------------------------------------- f^rp* # rt "**1^* 1- -v k- * tf s-- __***- * j-- -- |,+ * >* ( - + JB I -------r _-J .. i------ j-- -| - TM ------------------------------------------------------------------------------1. -4 + ,,..I * 4* ^ 4- 4 4. - I_____________________ ...i - 14 ' ** I 4 jiff * % 4 lift* aK i *' * v^*4 d M pi h ^>4* * 4 f *4 * - M . * HI k. -v^ikV*^ Ip 4^ r -^ T ! * * | *W'f -_ *4t4 4 ** I---------------------------------------------------------------------------------------------------------------------------------------------------------------------- g f ** ' *-. *4 i * / O. ' \ | lO I isj |_ -------------------------------------------------- fM >pf k | 4 *- ^V P . P W* >4I-4V j * - ----------------------- ^ ' I* -* ' a - r 't**** W *4 - {^ W J l|4 x 4 * 4^ i> > * 1* - 4 . i. W ^1 *** . I_.... f 4*!*1 * f * md * J i ^ v i -* * <- . *- * * -- 4 * " r I * *+. i. k/ A pi- f y i '" ij-"---"-----TT|-....r....'.'.....~'". * % 41 #r * i ** J_ _ _ ___ ...I h ' ^ f ' "f * %. i. .j A i* -M 4b f________________________________ -......-i -- r- ** ' *p * . ** * r ^ * t f f r ;i? t;~:ti.................................. 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T *4 * t % * B4 +.M I * *!b4 K|* * ^ Pm i^m * ' l -.-r- -- Lf ____________________________________ * * % - S *+ <* J l ^* 1 I" 4* *4 T0 kk** t* k * < 4* Lw f |M 4 * b Pk ' * f <* * V. j 4 >1 - Mb* .M . ., 4 I *+ * BB ' * PH4PP- 4'4*p -W k -44^* f - *M H. -M ^ 4 f *- .-i- *4 > <r ^ 4 fc * ^ _ * H v 'MP V 4 * B4P^ M 1 !- . * B m m- * 4 * < IH f* . 4- MV 1 j t k* iPH * -* J 4 4* -VI _t B- % ^ p pk W*#i *i B * - -, *. p * M **t w 4 p ff 4B .# W + ip l - I * t r V 4 k aB V + f * * ' v #* r^*M . 1 4 -p _ | _ ' .* - 4 H*, *M p-p -i .m b ; ----- - -f - --~j j f * * . W * t ------------------------------------ B. :_. i__:::' :.: "/ \ J 1 4 * ^ j' "/ , \ J *' J"" 4 * ' i " 'j t * 4* *4 ~ m / B4 4*1 * " t Wl * BT f f| 14* '* bj "" *rv 1 i*^pv ^pi |^*1 rw1 "y ^ it:1 i* m * P * M I 14 - H * hi *^*i " --*--*-.** *PP' M t f V**- til la <5 Co u 0 v\ > Vj o Co Of > *N< > vO * \A H. a \4j O w 4^ s a K o 0* Oh V5 ^cr V O U) O' > K u. P im BPBMWiVP m * *p CONFIDENTIAL A CHART NO. Co * * * <4* \A Ki a Vu o V* I t 'S oc o K O 0O l: V$ V ci 10 O' > 4_ C lT -* * 115813 9 4 CONFIDENTIAL .RE-j r~ ~T # f * 'W i h . !* J` * 1 ,4 * i4 4 r P * -t * * 1 I 1 - +m - *i :_r.--i______i - * i #- ** *iw ______? + -^4 44* -m - M (* a -i a f- 1 4 d - f * | 4* U' 4f - 4- <rA 4*4 M # **>1 F 4 1' I| | --j-----------------------|-------.---------------- # V ,4 i ~A. * m w* H* i . 4* >* I* _ I ^ 'H ill __________________ j ^ ________ * --^ ** I Y _______________ t %* i 1^ I....___ B . * + r1 ' -* p 7 :tz: -4 V ^ P ^ a -- < * * i - * * V--^ t **_ -t - - * ' ^ 1 * IF * i * + * 4| " * ** 'M 4 4 * i 4 1 - * 44# * * fU l * i 1 j 1) 1 \ i ( I I i1 I i_ * I l _____( i t - * * *4 J . 4b. 4 - r%' b \ ' F r . 4 44* i ^ i* 4 4 . 4 *a jM -- < . b ^ * w k *' , ---- < "7 71, _____1 ___,, } ! ,j I_i ^ ^ ^ ! ^ i 7, | 777'7 r?. 7 ,, 7 Tp7 7- __ Ii"7Xf71i71"ii7'1.7" 7Xi17 4** -m*- J1 * --V- - * 4+ .. 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V > i . * f-- * ;.i J_ 4 _ -4 kta ,4*4* * ^ . -I .w iry m k ` 4 k* 4 ta 4 - I I + dm f* t ^ F 4 4 4 -- I. r iJ ,i K * i* * * < * 4 a 4 4 % * 4*1 4- >4 I| `` ---- 4 - ' - * 4-' WBt * i.f -rfP4irt< * ^ < i !& < *1* *44 4-4 Bk k "- ^ * * * 4* ' -F| - --p - _._7_Xt\_7_7_;__ (--------------------------------------- * ' + w J VM - -- ^- 1i!i71 --77m-1li I)1r~._1_*7.77.1_77: If k- _ 4 #4 I 4 - 4k a B-F ___l 1 ^ t b J*B B^ - ^H rn M4rtt k ^ 1 J ^ I * > *B|M4 v ,, * '** "- | "* --- - j --- "" | -* *`| | JJ -- " * *** I - . - - . i ^i JH i ;J I ^ j p.a -F.*p - p. yr j -p - y r --------- 1----------- 'ijl ~_:~14'Z* 1~T.~ I',----------------------------------------------------------------------- . .4 JW * J *r * ** Jf . *-* *. i I I '1 1 __JJ, _ ! r* * Ir 1 * L_i k(t-*a * d m * Ir *. t( T1 _________________-J -- j-----* j- 4 4 4* -1 ** i ** * 4*r j .* F-F* ^ *4fc _ -4.1 %* ' ^-- 4 *4 I** ......j______ IT 4 1 * a .* m --* - 4 M * r. . ^ * * * l --MMM- * **4 B i A B *4 r -. * * T H |* ** b V i i !* HI * _! 4* * .* % 4 k H *- - - i i A ____i_ V | Tl *% ' * ____ I 4 \ \ *-^ J J D<C\&<; ?."** *osl wc ' Runted in u.s.A.^{^|n form cyl ^ANALYSIS I W>Jv MM32W f =*39^ BMafeoif v -J <cyy ' J (Ml WV. SJWlMCMPROOUCTSUSA.INC. "SS, GAS analysis "T --" glt-OgfL.'SA^ L,Vri -- 2: ] CONTROL NO. j , 3S8g*^Zr------- "------------- I VOLUME PERCENT WONOXIDE --------------- _ 1 GAS REQUESTED ANALYSIS tVTROQN ' Z' &?T'.----------------- -- -- L CARBON .P^ DIOXIDE * ' > ** '** , MCTli Hane UUM r ~ &7tsr&f--~. ] hydrogen \ ' ' .,!.;...;;:.J[^....,,,:i.~J ~yrx-ra--------- | carbon v.,:. . s . . ' . i; c;n oate 4---------- T^O r>^ r f MONOXIDE ~________ _____ _ * tf* <a ^ ( *'* W' i sp i J ~7T----------- J NITROGEN JzJiLL&L_____________________ ARGON------------------------------------------------------------------------------------------------------------------------------------------------ I I ^NALyzeo BY /7^g;A^r j PRESSURE 1 air------------------------------------ MEIHANE-------------------------------------------------- k % t < "~>&F0RE USE, . ......... ^ / J COMPONENT MAY LIQUEFY ATF ANALYZED BY ________________________ _ PRESSURE & & 3E CONTENTS 7^ ^ CUBIC FEET READ OTHER SIDE BEFORE USE. /* -- CONFIDENTIAL r / PRINTED IN U.S.A. { ! #>. jjljg, FORM MA-03-10/77-A ^ Mathesori<3> adiv^ion op v/illross. inc I f GAS ANALYSIS /&<{. cyl. no. fAtfaO/^&ft/T-r',NVn0o,C. E 39^9i7n2 CONTROL NO. *51 VOLUME PERCENT GAS REQUESTED Al carbonfd.- contents of ini> cy- dioxidejjnd^r Is oi .!she if oxygeniife. Use is recommended HYDROGWithin one year trcm date 80CAR Nr\f monoxide nr>pA:jf act Lift* '"^nuTdciuru 1 NITROGEN ARGON AIR METHANE T I i COMPONENT MAY LIQUEFY AT ANALYZED BY PRESSURE 2iQ<asr)^ CONTENTS CUBIC FEET READ OTHER SIDE BEFORE USE. 2, - >'-#/ f I VAB.0001115816 REACTOR OPENING LOSS CALCULATION Data 3 Volume of reactor, V 4,487 ft. Barometric pressure, P = 30.08 in. Hg. Reactor temperature, T =* 582R Molecular Weight of VCM, M * 62.5 lb. lb.-mole Gas Constant, R = 21.9 (in. Hg) (ft.3) (lb.-mole) (R) Density of VCM at reactor conditions, D D = PM = (30.08) (62,5) - 0.147 lb. RT (21.9) (582) ft.3 Fraction of water vapor in reactor gas, W = 0.122 FVC Production, Z = 56,986 lbs. for 5265 resin 64,521 lbs. for 5385 resin Concentration of vinyl chloride in reactor3 C *= 6368ppm for batch 745 - 155 4823ppm for batch 745 - 156 = 23357ppm for batch 745 - 157 dry basis, C Reactor Opening Loss Calculations The reactor opening loss, R0L, is calculated by the following equation. ROL = (C) (1-W) (V) (D) (Z) - (ft.3 VCM) X (ft'.j dry gas) x (MM ft.J dry gas) (ft.""" reactor gas) (lb. VCM (ft.3 VCM) x (1) = lbs. VCM lbs. PVC MM Lbs. VCM reactor gas) X Batch No. 745-155 ROL = (6368) (1-0.122) (4.487) (56,986) = 65 lbs. VCM MM lbs. VCM (0.147) A VAB.0001115817 * * * / REACTOR OPENING LOSS CALCULATION (Continued) Batch No. 745-156 ROL = (4823) (1-Q.122) (4.487) (0.147) (64,521) = 43 Lbs. VCM MM lbs. PVC Batch No. 745-157 ROL = (23,357) (1^0.122) (4.487) (0.147) (64,521) = 210 lbs. VCM MM lbs. PVC A VAB.0001115818 A TO: BRENDA FROM: PLEASE ADD THE FOLLOWING ENGINEERING FILE: FILE TYPE: (check one) 0*; CORRESPONDENCE DATE PROJECT ADD FILE UNDER THE FOLLOWING MAIN HEADING: (check one) 1.0.0 2.0.0 3.0.0 4.0.0 5.0.0 6.0.0 7.0.0 AFE REQUESTS & BUDGETS VINYL DRYERS COMPOUNDS DRY BLEND PLASTICIZER UTILITIES & AUXILIARY FACILITIES JL 8.0.0 9.0.0 10.0.0 11.0.0 12.0.0 13.0.0 14.0.0 ENVIRONMENTAL ENERGY CONSUMPTION SAFETY ACCOUNTING BUSINESS AREA QUALITY ADMINISTRATION SHOULD THIS FILE GO UNDER A SUB-HEADING? IF SO, GIVE FILE NUMBER AND NAME: 9 I A******************************************************************************** V rV \ VAB.0001115819