Document G5YK5Gd9mLy9bGGzOONqqZzz7

> ARCGL0R* PLASTICIZERS A series of inert, chemically-resistant, fire-retarding plasticizers compatible with wide variety of resins. mm PLASTICIZERS *KolMr( cnt>inrd tinfn li leb*eoslfued tiK0fnmfijn#rii6 vie inj pr^uc( Jit conflict witt mi t-llirit MONSANTO MAKES NO WARRANTIES AS TO THE TIT NESS OR MERCHANTABILITY OF ANT RROCUCTS RE I ERRED TO. M |uun!h ol MMlidon 'twill Korn rtMno upon Ulnrtlnlc'mjlionirtcmmini3H>eni, iniliKliimillli6ilil|lo(jnjrtujllinjloiiwaimi|." Organic Chemicals Division / 600 N. Lindbergh Blvd. / St Louis, Missouri 63166 rvi.726^8 . TOWOLDMONOQ32844 AROCLOR PLASTICIZERS A series of inert, chemically resistant, fire retarding plasti cizers compatible with a w.ide variety of resins. annas'* TOWOLDMONOQ32845 -2- Propertles as Plasticizers The Aroclor resins/plasticizers and their blends have a very unusual set of properties which make them extremely useful products. Their most important characteristics are: ' . Low Cost Highly Compatible Chemically Stable Fire Retardant Excellent Adhesion Another very useful aspect of this product line is the fact that a continuous range of properties can be achieved by using combinations of the Aroclors and their blends. Some of the physical properties which can be controlled through product selection-are shown on the following pages. 0<,7Z8t TOWOLDMON0032846 -3- Key to Nomenclature 5400 Series These products are chlorinated terphenyls. The last two digits indicate the chlorine content of the material, e.g., Aroclor 5460 is a chlorinated terphenyl with 60 percent chlorine. Undlstllled Aroclors are available and are designated by a 5000 series vs. the 5400 series. They are somewhat higher in color but otherwise have product characteristics similar to the distilled products. 6000 Series . These products are blends of Aroclor 5460 and Aroclor 1221, a biodegradable mono chlorinated biphenyl, the last two digits indicate the percentage of Aroclor 5460 in the blend, . e.g., Aroclor 6062 is'a .blend containing 62 percent Aroclor 5460 and 38 percent mono chlorinated biphenyl.' Miscellaneous Blends Other product blends containing such other materials as Santicizer 140 for improved fire retardancy, or toluene/ xylene for lower viscosities will also be made available as the demand for these specialty products develops. 0*72861 TOWOLDMON0032847 -4- AROCLORS Adhesion/Tack Hardness Flexibility Fire Retardance Volatility Chlorine Content Viscosity Density ' Permanence Compatibility 5432 5442__________5460 increasing---------------- S>-increasing-----------------Bdecreasing---------------- -increasing---------------- sa decreasing---------------- >-lncreaslng---------------- increasing---------------increasing--------------- Bdecreaslng--------------- O- 0'|7Z862 TOWOLDMONOQ32848 -5- AROCLOR BLENDS 6o4o Adhesion/Tack --------- Hardness --------- Flexibility -------- Fire Retardance --------- Volatility --------- Chlorine Content -------- Viscosity --------- Density --------- Permanence -------- Compatibility -------- 6050 6062 6070 -------- Increasing---------------- -------- increasing----------------- -------- decreasing---------------- -------- increasing---------------- ----- --decreasing---------------- :--------- increasing--------------- ---------increasing--------------- -------- increasing---------------- -------- increasing---------------- ------- decreasing--------------- 6090 0*i72at>3 TOWOLDMONOQ32849 -6- Applloablons Listed below are some of the applications where these products can be used: . Aroclor Blends 60k0 Polyvinyl Acetate Emulsion Adhesives ' ' SBR Adhesives Miscellaneous applications where a high degree of flexibility Is- required. 6050 Chlorinated Rubber and other Resin systems for coating^. Inks 6062 Polysulfide Sealants/Adhesives Chlorinated Rubber Coatings and Adhesives SBR Coatings and Adhesives Miscellaneous- applications where high chlorine content, high tack, are required. Inks 6070 Polysulfide Adhesives - Chlorinated Rubber Adhesives Miscellaneous applications where very high chlorine content and very high tack are required. 6090 Radiation Curing Applications 0 v?*8b`' TOWOLDMON0032850 -7- Aroclors 5432 Polysulfide Sealants/Adhesives . Chlorinated Rubber Coatings and Adhesives SBR Coatings and Adhesives 5442 ' ' Surface Coatings . 5460 Hot Melt Adhesives, Surface Coatings 0^7^665 TOWOLDMON0032851 PHYSICAL PROPERTIES OF AHOCLORS AND AROCLOR BLENDS Property Aroclor 1221 Appearance Clear, mobile oil AROCLORS Aroclor Aroclor 5432 5442 Clear, yellow viscous liquid Clear, yellow sticky resin Aroclor 5460 Aroclor 6040 Clear, yellow to amber brittle resin or flakes Clear, light yellow . mobile oil AROCLOR BLENDS Aroclor Aroclor Aroclor 6050 6062 6070 Clear, light yellow mobile oil Clear, yellow viscous liquid Light yellow sticky resin. Aroclor 6090 Light yellow ' resin Color, Maximum *100 APHA 2 NPA 2 NPA 2 NPA (Molten) (Molten) (Molten) 2 NPA 2 NPA 2 NPA 2 NPA 2 NPA Specific Gravity *1.182 - 1.263 - 1.470 1.192 1.290 (25y x (25 / % (90/ . V 25 c) 15-5 c) 15-5 C) 1.670 (ssy , 25 C) 1.330 - 1.342 - 1.405 - 1.418 - 1.35 1.362 1.425 1.438 (25/ 0 , (65/ . , (65/ ^ (90/ . . 15-5 c) 15.5 C) 15-5' C) 15-5 c) Acidity, *0.014 Maximum (Mg KOH/Gm .05 .05 0:035 .035 0.035 . .035 .035 Moisture ppm Maximum _ - ' 250 250 250 250 - PHYSICAL PROPERTIES OF AROCLORS AND AROCLOR BLENDS Property Aroclor 1221 AROCLORS Aroclor Aroclor 5432 5442 Viscosity *38-41 (ASTM D-88) (100 F SUS) 50-60 (210 F SUS) 300-400 (210 F SUS) Aroclor 5460 ' Aroclor 6040 122-132 (100 F SUS) AROCLOR BLENDS Aroclor Aroclor Aroclor 6050 6062 6070 105-115 (130 F SUS) 50-60 (210 F SUS) 82-92 (210 F SUS) Aroclor 6090 " Flash Point 286-302 F Minimum (Cleveland Open Cup) 477 None to 270 290 Boiling 340 Fire Point 349 F Minimum (Cleveland Open Cip) >662 None to Boiling 300 335 550 Softening - - 46-52 98-105 - '' - Point C " 64-70 rCcuD- *Monsanto Specifications PRODUCT CODES AND PRIM WEIGHTS Product AROCLORS 5060 5432 5442 5460 Code Container Net Weight Pounds 1040-450-04-009 Multi-wall Bag 1040-460-04-009 55-Gallon Metal Drum 5-Gallon Metal Drum 1040-470-04-009 40-Gallon Meta'l Drum 5-Gallon Metal Drum 1040-480-04-009 Multi-wall Bag 50 600 60 450 50 50 Gross Weight Pounds Approximate Volume FT-5 50j " 0.97 648 65 10-3/4 1 469 56 7-2/3 1-1/12 50-1/2 0.97 AROCLOR BLENDS 6040 1045-040-04-009 6050 6062 O o60s5 1045-050-04-009 1045-062-04-009 * 55-Gallon Metal Drum 5-Gallon Metal Drum 55-Gallon Metal Drum 5-Gallon Metal Drum 55-Gallon Metal Drum 5-Gallon Metal Drum 600 55 600 55 600 60 648 60 ' 648 60 648 65 10-3/4 1 10-3/4 1 10-3/4 l PRODUCT CODES AND DRUM WEIGHTS Product 6070 6090 Code Container Net Weight Pounds 1045-070-04-009 55-Gallon.Metal Drum 5-Gallon Metal Drum . 600 60 1045-090-04-009 40-Gallon Metal Drum 5-Gallon Meta-l Drum 500 . 50 Gross Weight Pounds 648 65 519 56 Approximate Volume 10-3/4 1 7-2/3 1-1/12 Z l*'0 <ax> ,0 TOWOLDMONOQ32855 -12- Toxlclty and Safe Handling Inhalation At ordinary temperatures, the Aroclor chlorinated poly phenyls have not presented industrial toxicological pro blems. The hazard of potential toxic exposure varies with their volatility: the lower-chlorinated, more volatile ones present more of a potential problem from the standpoint of both inhalation and skin contact. When Aroclor plasticizers are used at elevated tempera tures, engineering controls must be applied, either by the use of closed systems or by effective local-exhaust ventilation together with general workroom exhaust. Vapor of the liquid Aroclor plasticizers at room tempera ture should not be breathed in a confined space, and no vapor of any Aroclor evolved at elevated temperatures should be allowed to be dispersed into the general work room. Skin Contact Continuous or repeated skin contact with the Aroclor plasticizers must be avoided by the use of gloves and protective garments, because of the possible occurrence of a condition called chlqracne. Although reports of this condition caused by Aroclor are rare, it can be produced by excessive skin contact. If any Aroclor is spilled on the skin, the skin should be washed in the usual manner with a soap solution. A burn caused by contact with a hot Aroclor should be treated like any ordinary burn. Aroclor plasticizer adhering to the burned area need not be removed immed iately, unless treatment of the burn demands it, in which case either soap and water or repeated washings with a vegetable oil are recommended. VIZ*10 o TOWOLDMONOQ32856 DISTRICT SALES OFFICES ALL DIVISIONS ATLANTA, GEORGIA 30326 Lenox Towers Bast 3400 Peachtree Rd. N. E. -- Suite 1711 Tel: (404) 577-2260 BOSTON, MASSACHUSETTS 02149 Everett Station Tel. (617) 337-5010 CHICAGO, ILLINOIS 3)56 Dcs Plaines Ave, Des Plaines, Illinois 60018 Tel (3)7.) 296-6688 CINCINNATI, OHIO 45206 1501 Madison Road Tct. (513) 751-6707 CLEVELAND, OHIO 44122 3645 Warrens v/lle Center Rd. Tel. (216) 991-5400 DETROIT, MICHIGAN 48235 500 Northland Towers Bast Tel. (313) 357-0910 HONOLULU, HAWAII 96812 205 Pacific International Bldg. 677 Ada Moana Bivd., P. O. 8ox 3824 Tel. (808) 512-744 HOUSTON, TEXAS 77002 1300 Main Street Tel. (713) Capitol 3-4011 LOS ANGELES, CALIFORNIA 90022 6670 B. Flotilla St. Tcf. (213) 723-2492 MINNEAPOLIS/ MINNESOTA 55402 912 Northstar Center 110 S. SevenOt St. Tel. (612) 339-4651 NEW YORK, NEW YORK 10017 277 Park Avenue Tel. (2)2) 922-4111 PITTSBURGH, PENNSYLVANIA 15222 No. 4 Gateway Center Bldg. Room 534 Tel. (412) 261-2156 t ST. LOUIS, MISSOURI 63766 ` 800 N. Lindbergh Bivd. Tel. (314) Oxford 4-1000 SAN FRANCISCO BAY AREA ' 2710 Lafayette, Santa data, Calif. 95052 Tel. (408) 243-0414 SEATTLE, WASHINGTON 98104 911 Western Avenue Te). (206) Main 2-4203 SPRINGFIELD, MASSACHUSETTS 01101 730 Worcester Ave. Tel. (413) 788-6911 WILMINGTON, DELAWARE 19803 2005 Concord Pike, Fairfax Tel. (302) Olympia 8-6531 Additional District Offices 0 aro maintained by: Agricultural Division 1 LULING. LOUISIANA 70070 P.O.Box 174 o Tel. (604) 784-6263 MEMPHIS. TENNESSEE 38113 + 1023 Riverside Drive o P.O.Box 13248 J Tel. (901) Whitehall 7-3151 . * Textiles Division 5 AKRON. OHIO 44313 * 3030 West Merkel St * Tel. (216) 836-7941 , i ATLANTA. GEORGIA 30303 Atlanta Merchandise Mart - 240 Peachtree St.. N.W. Tel. (404) 577-2260 * CHARLOTTE, NORTH CAROLINA28202 Wachovia Bank Building - 129 West Trade St * Tet. (704) 376-9871 9 ENGLEWOOO CLIFFS. N. J. 07631 c 661 Palisades Ave. $ Tel. (201) 568-2151 * NET/ YORK. NEW YORK ^ 350 Fifth Ave. I Tet. (201) 656-5100 f Hydrocarbons & Polymers 4'* Divislon*Llon Oil \ EL DORADO. ARKANSAS 71730 o lion Oil Building \ Tel. (501) Union 3-3111 ' JACKSON. MISSISSIPPI 39209 * P.O.Box 10937 *? Westland Station * Tel. (601) 352*3648 * LITTLE ROCK, ARKANSAS 72203 * 1515 West Seventh Sl (, Tel. (501) Franklin 6-2437 ? MEMPHIS. TENNESSEE 38113 . 1023 Riveisido Drive i- P. O.80X 13248 ` J Tel. (901) Whitehall 7-3161 __ Organic Chemicals Division (Rubber Industry) AKRON. OHIO 44311 920 Brown Street , P. 0. Box 2307 i Tel. (216) Hemlock 4-1921 MONSANTO, BOO N. LINDBERGH BLVD,, ST. LOUIS. MISSOURI 63166 ! <? *j ;J ;\ :J H ;.J vj ,-i `j M j -J '; i ' ' ,* : .j * j .! .1 I *I [ ?j J J i .i .; I .j ; `j ' | ' r \ o <72Bn TOWOLDMONOQ32857