Document EdYkqLgZgMgQVbmbymJZRvQZR

conoco) Interoffice Communication To File Oate Subject Lorraine E. Lewis December 15, 1986 TRANSFER OF DOCUMENTS TO IBM AT AND IBM 3812 PRINTER The IBM System 36 and Xerox 2700 II printer have been used for printing and distribution of all MSDSs. In December 1986, all MSDSs were transferred to an IBM 3270 AT which resulted in slight changes to the content of some MSDSs (i.e. the MSDS code was added to the lower left hand corner of all pages of the MSDSs which did not currently have the MSDS code in that area). Starting December 22, 1986, the IBM 3270 AT using an IBM 3812 printer will be used for printing and distribution of all MSDSs. This will also result in a different appearance to the MSDSs. Attached are MSDSs from both systems. The MSDS with the section headings shaded was printed on the Xerox 2700 II. Lorraine E. Lewis Staff Assistant, Hazard Communication Att. 2 MCD 000023531 Cconoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name; Crude Oil (Sweet) Chemical Family: Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Registry No.: 8002-05-9 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II, HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) Potential to cause kidney toxicity and tumors of the liver, skin and kidney in laboratory animals. Benzene (71-43-2) Studies have indicated that workers exposed to high concentrations of benzene for many years have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Depending on Flash III. PHYSICAL DATA Variable--Flammable or Combustible depending on flash point. Could be as hazardous as Class IA Flammable Liquid per NFPA Code No. 30-1984. Appearance and Odor: Usually greenish-black liquid; aromatic or sulfide odor. Boiling Point (F) 50 - > 1100 Specific Gravity (H 0=1) 0.7 - 1.1 Vapor Pressure (mmHg), 68 F 1Q0-80Q (Variable) Evaporation Rate (Ether=l) Variable IV. REACTrvrTV DATA ~ ~ ~ ~ Stable X Un^abtz* Hazardous Decomposition Products: Normal combustion forms carbon dioxide; incomplete combustion may produce carbon monoxide. Conditions To Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. FIRE AMP EXPLOSION HAZARD DATA ~ ~~ LVU < ? UFL * 10 Flash Point (Method used): Less than Ambient (Variable) Flashpoint is variable; handle and store in accordance with NFPA procedures. Could be as hazardous as a Class IA Flammable Liquid per NFPA Code No. 30-1984. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. April 4, 1986/MISC0011 MCD 000023532 </. FIRE AA/P EXPLOSION HAZARD VATA (continued) Special Fire Fighting Procedures: Water may be ineffective, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Agency (NFPA) CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VI. TRANSPORTATION MID STORAGE POT HklKW CLkSS: * ^Combustible liquid or flammable liquid (depending on flash point). Precautions To Be Taken In Handling And Storing: Product is either Combustible Liquid or Flammable Liquid (depending on flash point) per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Crude Oil, petroleum, Combustible liquid, UN 1267 or Flammable liquid, UN1267. Placard: Combustible or Flammable. D.O.T. Label: Flammable liquid or no label depending on hazard class. OSHA Label: CAUTION: Minimize exposure. This product may contain benzene and certain other hydrocarbons which may be toxic or cause cancer. The workplace should be well ventilated. Wash thoroughly with soap and water after contact. Flammable or Combustible Liquid (depending on flash) VTT. HEALTH HAZARD INFORMATION ~ PEL Not Established. TLV Not Established. Ceiling Value Not Established. AEL Not Established. Primary Route(s) of Exposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated By Exposure: Health effect information from animal or human studies has been included on re lated materials, even through health experts may disagree as to the significance of this data. April 4, 1986/MISC0011 MCD 000023533 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that certain petroleum hydrocarbons have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that some crude oils caused a low incidence of tumors. However, these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No nil. ~EMERGBbiCV ANV FIRST MV PROCEVURBS ~~ Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Washexposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. If exposed to hot oil, immediately cool with cold water. Do not attempt to remove oil but continue to cool exposed areas with cold packs and seek medical assistance immediately. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effortto prevent vomitus from entering lungs. Immediately consult a physician. Do not attemptto give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AM) DISPOSAL PROCEDURES RCRA HAZARDOUS WASTE: Yes ** No *The flashpoint of this material is variable and, therefore, based on the RCRA characteristics of ignitability, can be considered as a hazardous waste for some runs (< 140 F) and nonhazardous for other runs (> 140 F). Any of this material being handled as a waste should be treated as a RCRA hazardous waste unless flash* point analysis indicates otherwise (> 140 F). April 4, 1986/MISC0011 MCD 000023534 IX. SPILL,. LEAK ANP VISPOSAL PROCEDURES {ConUnuzd) In Case Of Spill Or Leak: Protect from ignition. Contain spill immediately in smallest area possible, being careful to avoid potential ignition sources. Recover as much of the product as possible by such methods as vacuuming, followed by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper container for disposal. The area may be washed down with water, as needed, but steps should be taken to avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material by such methods as controlled incineration, complying with federal, state and local regulations. X. PRECAUTlMARy MEASURES Respiratory Protection: None normally required. See Section V for use in emergency situations. Ventilation: Mechanical ventilation required only in emergency or extreme conditions, such as confined spaces. Protective Gloves: Neoprene or NBR gloves should be worn to protect against chronic skin contact. Eye Protection: Safety glasses with side shields and/or face shield where splashing is present. Other Protective Equipment: Coveralls if splashing is probable. The above data is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE nR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHAM. CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THF. PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KVWN TO CONOCO. April 4, 1986/MISC0011 MCD 000023535 (conoco) MATERIAL SAFETY DATA SHEET I. MATERIAL IDENTIFICATION Name: Crude Oil (Sweet) Chemical Family: Petroleum Hydrocarbon Manufacturer: Conoco Inc. Address: P.0. Box 1267, Ponca City, OK 74603 CAS Registry No.: 8002-05-9 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS Hazard Determination: Health Effect Properties: Hydrocarbons (Aromatic and paraffinic hydrocarbons) HAZARD DATA Potential to cause kidney toxicity and tumors of the liver, skin and kidney In laboratory animals. Benzene (71-43-2) Studies have Indicated that workers exposed to high concentrations of benzene for many years have a slightly higher incidence of leukemia. Physical Effect Properties: Product/Mixture: Depending on Flash Variable--Flammable or Combustible depending on flash point. Could be as hazardous as Class IA Flammable Liquid per NFPA Code No. 30-1984. III. PHYSICAL DATA Appearance and Odor: Usually greenish-black liquid; aromatic or sulfide odor. Boiling Point F 50 -> 1100 Specific Gravity (HpO=ll 0.7 - 1.1 Vapor Pressure (mmHg), 68*F 100-800 (Variable) Evaporation Rate (Ethersl) Variable IV. REACTIVITY DATAStables X Unstable: Hazardous Decomposition Products: Normal combustion forms carbon dioxide; incomplete combustion may produce carbon monoxide. Conditions To Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. V. FIRE AMD EXPLOSION HAZARD DATALFL: < 1 Flash Point (Method used): Less than Ambient (Variable) OFL: 10 Flashpoint Is variable; handle and store in accordance with NFPA procedures. Could be as hazardous as a Class IA Flammable Liquid per NFPA Code No. 30-1984. Extinguishing Media: Use dry chemical, foam, or carbon dioxide. April 4, 1986/MISC0011 MCD 000023536 CAS Registry Mo.: 8002-05-9 V. FIRE AMD EIPLOSIOH HAZARD DATA (continued) ~ Special Fire Fighting Procedures: Water may be ineffective, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. Mational~Flre Protection Agency (NFPA> CLASSIFICATION HAZARD RATING Health 1 Fire 3 Reactivity 0 Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 TI. TRANSPORTATION AMD STORAGE DOT HAZARD CLASS: "Combustible liquid or flammable liquid (depending on flash point). Precautions To Be Taken In Handling And Storing: Product is either Combustible Liquid or Flammable Liquid (depending on flash point) per NFPA Code No. 30-1984. Store and handle accordingly. Shipping Paper Description: Crude Oil, petroleum, Combustible liquid, UN 1267 or Flammable liquid, UN1267. Placard: Combustible or Flammable. D.O.T. Label: Flammable liquid or no label depending on hazard class. OSHA Label: CAUTION: Minimize exposure. This product may contain benzene and certain other hydrocarbons which may be toxic or cause cancer. The workplace should be well ventilated. Wash thoroughly with soap and water after contact. Flammable or Combustible Liquid (depending on flash) 11. HEALTH HAZARD INFORMATION PEL Not Established. TLV Not Established. Ceiling Value Not Established. AEL Not Established. Primary Route(s) of Bxposure/Entry: Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated By Exposure: Health effect information from animal or human studies has been included on re lated materials, even through health experts may disagree as to the significance of this data. April 4, 1986/MISC0011 MCD 000023537 CAS Registry No.: 8002-05-9 VII. HEALTH HAZARD INFORMATION (continued) Studies with rodents have shown that certain petroleum hydrocarbons have caused kidney damage and kidney or liver tumors. However, the kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Several studies evaluating petroleum workers have not shown significant increases of kidney damage nor kidney or liver tumors. Mouse skin painting studies have shown that some crude oils caused a low incidence of tumors. However, these studies involved repeated exposure of shaved skin which was never washed free of test material. The product may cause irritation to eyes, lungs, or skin after prolonged or repeated exposure. Overexposure may cause central nervous system depression. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC No OSHA No VIII. EMERGENCY AND FIRST AID PROCEDURES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. If exposed to hot oil, immediately cool with cold water. Do not attempt to remove oil but continue to cool exposed areas with cold packs and seek medical assistance immediately. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If this material is swallowed, do not induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt to give liquid to an unconscious person. Note to Physicians: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. II. SPILL. LEAF AMP DISPOSAL PHOCBDUHBS RCRA HAZARDOUS WASTE: Yes * No *The flashpoint of this material is variable and, therefore, based on the RCRA characteristics of lgnitability, can be considered as a hazardous waste for some runs (< 140 F) and nonhazardous for other runs (> 140 F). Any of this material being handled as a waste should be treated as a RCRA hazardous waste unless flash point analysis Indicates otherwise (> 140 F). April 4, 1986/MISC0011 MCD 000023538 CAS Registry No.: 8002-05-9 II. SPILL, LEAK AND DISPOSAL PROCEDORES (Continued) In Case Of Spill Or Leak: Protect from ignition. Contain spill immediately in smallest area possible, being careful to avoid potential ignition sources. Recover as much of the product as possible by such methods as vacuuming, followed by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper container for disposal. The area may be washed down with water, as needed, but steps should be taken to avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material by such methods as controlled incineration, complying with federal, state and local regulations. I. PRECAUTIONARY MEASURES Respiratory Protection: None normally required. See Section V for use in emergency situations. Ventilation: Mechanical ventilation required only in emergency or extreme conditions, such as confined spaces. Protective Gloves: Neoprene or NBR gloves should be worn to protect against chronic skin contact. Eye Protection: Safety glasses with side shields and/or face shield where splashing is present. Other Protective Equipment: Coveralls if splashing is probable. The above data Is based on tests and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. April 4, 1986/MISC0011 MCD 000023539