Document BNMg79x3vLbVQEzkm1ozKaqk

AR226-1536 The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Material Safety Data Sheet Page 1 5970PP ZONYL" FSP Fluorosurfactant Revised 29-AU6-2003 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification "ZONYL" is a registered trademark of DuPont. Corporate MSDS Number : DU002501 Company Identification MANUFACTURER/DISTRIBUTOR DuPont 1007 Market Street Wilmington, DE 19898 PHONE NUMBERS Product Information Transport Emergency Medical Emergency : 1-800-441-7515 (outside the U.S. 302-774-1000) : CHEMTREC 1-800-424-9300(outside U.S. 703-527-3887) : 1-800-441-3637 (outside the U.S. 302-774-1000) COMPOSITION/INFORMATION ON INGREDIENTS Components Material CAS Number 65530-71-4 Telomer B Phosphate Ammonium Salt (1:1:1) 65530-72-5 Telomer B Phosphate Ammonium Salt (1:1:2) 65530-70-3 Telomer B Phosphate Ammonium Salt (2:1:1) Isopropyl Alcohol 67-63-0 Water 7732-18-5 % 3-7 17-21 11-15 18-22 40-45 HAZARDS IDENTIFICATION Potential Health Effects Eye contact with Zonyl FSP may cause slight eye irritation with discomfort, tearing, or blurring of vision. Print Datfv D P - 1 7 - 5970PP DuPont Material Safety Data Sheet Page 2 (HAZARDS IDENTIFICATION - Continued) Inhalation of large amounts of respirable particles may be toxic to the lungs. Symptoms may be modest initially, followed in hours by severe shortness of breath requiring prompt medical attention. Gross overexposure may cause fatality. A possible ingestion hazard due to the Isopropyl Alcohol component is aspiration (liquid entering the lungs during ingestion or vomiting) which may result in "chemical pneumonia". Symptoms include coughing, gasping, choking, shortness of breath, bluish discoloration of the skin, rapid breathing and heart rate, and fever. Pulmonary edema or bleeding, drowsiness, confusion, coma and seizures may occur in more serious cases. Symptoms may develop immediately or as late as 24 hours after exposure, depending on how much chemical entered the lungs. Repeated ingestion of large amounts may cause liver damage. Carcinogenicity Information The following components are listed by IARC, NTP, OSHA or ACGIH as carcinogens. Material Isopropyl Alcohol IARC NTP OSHA ACGIH A4 FIRST AID MEASURES First Aid INHALATION If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT Flush skin with water after contact. Wash contaminated clothing before reuse. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician. Print Date 5970PP DuPont Material Safety Data Sheet Page 3 (FIRST AID MEASURES - Continued) Notes to Physicians Activated charcoal mixture may be administered. To prepare activated charcoal mixture, suspend 50 grams activated charcoal in 400 mL water and mix thoroughly. Administer 5 mL/kg, or 350 mL for an average adult. FIRE FIGHTING MEASURES Flammable Properties Flash Point Method : 24 C (75 F) : PMCC Flammable liquid. Hazardous decomposition products including carbon dioxide, carbon monoxide, hydrogen fluoride, toxic gases or particles may be formed during combustion. These products may cause severe eye, nose, throat, and lung irritation or toxic effects. Extinguishing Media Water Spray, Foam, Dry Chemical, C02. Fire Fighting Instructions Evacuate personnel to a safe area. Wear self-contained breathing apparatus. Avoid breathing decomposition products. Use water spray. ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Spill Clean Up Soak up with sawdust, sand, oil dry or other absorbent material. Shovel or sweep up. Accidental Release Measures Flush spill area with water. Print Datfi- OP - 17 - ?nn 5970PP DuPont Material Safety Data Sheet Page 4 HANDLING AND STORAGE Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with eyes. Wash thoroughly after handling. Do not store or consume food, drink, or tobacco in areas where they may become contaminated with this material. Avoid circumstances that produce respirable particles unless suitable ventilation and respirator are used. Storage Store in a well ventilated place. Keep container tightly closed. Freezing will affect physical condition but will not damage. Thaw and mix before using. Keep away from open flames and heated surfaces above 200 degrees C (392 deg F). EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Keep container tightly closed. Use only with adequate ventilation. Vent heated extruder or dryer fumes outside work area. Do not aerosolize. In spray applications, use airless type pressure spray equipment at less than 60 psi, and exhaust ducts, drip pans, or other design features to minimize worker exposure to mists and overspray. Personal Protective Equipment EYE/FACE PROTECTION Wear safety glasses or coverall chemical splash goggles. RESPIRATORS Where there is potential for airborne exposures wear NIOSH approved respiratory protection. PROTECTIVE CLOTHING Where there is potential for skin contact have available and wear as appropriate, impervious gloves, apron, pants, and jacket. # Exposure Guidelines Print Date- 0 9 - 1 7 - 9009 5970PP DuPont Material Safety Data Sheet Page 5 Exposure Limits "ZONYL" FSP Fluorosurfactant AEL * (DuPont) : 0.1 mg/m3, 8 & 12 Hr. TWA, Respirable Other Applicable Exposure Limits Isopropyl Alcohol PEL (OSHA) : 400 ppm, 980 mg/m3, 8 Hr. TWA TLV (ACGIH) : 200 ppm, 8 Hr. TWA, A4 STEL 400 ppm AEL * (DuPont) : 400 ppm, 8 & 12 Hr. TWA * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. Exposure Guideline Comments Air monitoring studies conducted at customer sites indicates that the use of the recommended low pressure (less than 60 psi) airless type, garden type or deck specific hand pump sprayer with spray tip orifice minimum of 0.031 inches in diameter does not produce respirable size aerosol particle concentrations near the AEL. PHYSICAL AND CHEMICAL PROPERTIES Physical Data % Volatiles Solubility in Water PH Odor Form Color Specific Gravity Density 65 WT% Slight 6-8 Alcoholic Clear to Slightly Hazy Liquid Amber to Dark Brown 1.15 9.6 lbs./gal. STABILITY AND REACTIVITY Chemical Stability Stable at normal temperatures and storage conditions. Incompatibility with Other Materials None reasonably foreseeable. Decomposition Hazardous decomposition products including carbon dioxide, carbon monoxide, hydrogen fluoride, toxic gases or particles may be formed during combustion. These products may cause severe eye, nose, throat, and lung irritation or toxic effects. Print Datfi- 09 17 - ?Df)3 597OPP DuPont Material Safety Data Sheet (STABILITY AND REACTIVITY - Continued) Polymerization Polymerization will not occur. Page 6 TOXICOLOGICAL INFORMATION Animal Data Zonyl FSP Oral LD50: > 25,000 mg/kg in rats Inhalation 4 hour ALC: 57 mg/m3 in rats Zonyl FSP is not a skin irritant or skin sensitizer, but is a very slight eye irritant in animal tests. In repeated ingestion studies Zonyl FSP caused liver, kidney and thyroid changes in rats. Repeated inhalation exposure caused irritation to the larynx and lung inflammation. Repeated dermal exposures caused mild changes in liver enzymes. No animal data are available to define the carcinogenicity hazard of Zonyl FSP. Animal data on the active ingredient show developmental effects only at exposure levels producing other toxic effects in the adult animals. A reproduction study conducted in rats with the active ingredient resulted in reproductive effects at levels above those showing histopathology effects in adult animals. Zonyl FSP did not cause genetic damage in bacterial cell cultures. ECOLOGICAL INFORMATION Ecotoxicological Information The product has low toxicity. The 96 hr. TL50, rainbow trout: > 1,000 mg/L. The 48 hr. EC50, Daphnia Magna: >1,000 mg/L (not toxic). DISPOSAL CONSIDERATIONS Waste Disposal Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Print Date- n p - 1 7 - ? n n 5970PP DuPont Material Safety Data Sheet Page 7 TRANSPORTATION INFORMATION Shipping Information DOT Proper Shipping Name Hazard Class I.D. No. (UN/NA) DOT Label(s) DOT/IMO Proper Shipping Name Hazard Class UN No. DOT/IMO Label Special Information Packing Group Flammable Liquid, N.O.S. (Contains Isopropanol) Flammable Liquid UN 1993 Flammable Liquid Flammable Liquid, N.O.S. (Contains Isopropanol) 3 UN 1993 Flammable Liquid Flash Point: 24 degC III REGULATORY i n f o r m a t i o n U.S. Federal Regulations TSCA Inventory Status : Reported/Included. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute : Yes Chronic : No Fire : Yes Reactivity : No Pressure : No OTHER INFORMATION NFPA, NPCA-HMIS NPCA-HMIS Rating Health Flammability Reactivity :1 :3 :0 Personal Protection rating to be supplied by user depending on use conditions. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS : MSDS Coordinator Print Date 5970PP DuPont Material Safety Data Sheet Page 8 (Continued) Address Telephone DuPont Chemical Solutions Enterprise Wilmington, DE 19898 800-441-7515 # Indicates updated section. This information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and experience is gained. End of MSDS Print Datfi- 09 17