Document 99J7YKoNdKjk8D04QBpYKX1Yp

Annex 1: documents, data tables and figures referred to from the text Annex 1.1: Documents In 2021 the 5 member states working on the broad PFAS restriction under REACH have published multiple reports in which they collected information on the different uses and production of PFAS. Report summary Report summary Report summary Report summary F Report summary Report summary Report summary Report summary construction productsc2o0s2m1e-0ti7cs-3j0u.lpy d2f021.pdeflectronics and energyg.apsdfuses july 2021.pdffood contact materialsluabnrdicapnatcskjauglyin2g02ju1l.yp2dm0f 2e1d.ipcdalf devices july 20m2e1d.picdinfal products july 2021.pdf Report summary Report summary Report summary Report summary ski Report summary Report summary Report summary Report summary metal plating july 2021p.petdrfoleum and miningpjruolydu2c0t2io1n.pjdufly 2021.ptdrefatment july 2021.pdtfransportation july 2021T.UpLdAfC july 2021.pdf waste july 2021.pdf cleaning agents polishes waxes july 2021.pdf Annex 1.2: Tables Table 13 Total fluoride emissions in Belgium (2017), source: https://prtr.eea.europa.eu/#/pollutantreleases Transfers per country Facilities Facilities Air (Accidental) Air (Accidental) Water Water (Accidental) Soil Soil (Accidental) Belgium 26 26 - - 118467 0 - - Bruxelles- 1 1 Capitale / Brussels Hoofdstedelijk Gewest - - 18300 - - - Lige 2 2 - - 919650 - - - Hainaut 5 5 Antwerpen 12 12 Limburg 4 4 East Flanders 2 2 Total 26 0 - - - - - - - - 0 0 18750 165340 22570 40060 - 1185 t 0 - - - - - 0 Table 14 Total fluoride emissions in Belgium per sector (2017), source: https://prtr.eea.europa.eu/#/pollutantreleases Transfer per industrial activities Facilities Facilities Air (Accidental) Air Water Water Soil (Accidental) (kg) (Accidental) Soil (Accidental) 1 Energy sector 2 2 - - 10350 - - - 1.(a) Mineral oil 2 2 and gas refineries - - 10350 - - - 2 Production and 5 5 processing of metals - - 59270 - - - 2.(e) Production 3 3 of non-ferrous crude metals from ore, concentrates or secondary raw materials 2.(b) Production 2 2 of pig iron or steel including continuous casting 4 Chemical 12 12 industry 4.(b) Industrial 3 3 scale production of basic inorganic chemicals 4.(b) Industrial 2 2 scale production of basic inorganic chemicals 4.(b) Industrial 1 1 scale production of basic inorganic chemicals 4.(a) Industrial 8 8 scale production - - - - - - - - - - - - - - 18240 - 41030 - 106858 0 931350 19350 912000 134520 - - - - - - - - - - - - - - - of basic organic chemicals 4.(a) Industrial 7 7 scale production of basic organic chemicals 4.(a) Industrial 1 1 scale production of basic organic chemicals 4.(c) Industrial 1 1 scale production of phosphorous, nitrogen or potassium based fertilizers 5 Waste and 6 6 waste water management 5.(f) Urban 5 5 waste-water treatment plants 5.(a) Disposal or 1 1 recovery of hazardous waste - - - - - - - - - - - - 130690 3830 2710 - 40980 38160 2820 - - - - - - - - - - - - - 6 Paper and 1 1 wood production processing 6.(b) Production 1 1 of paper and board and other primary wood products Total (ton) 26 0 - - - - 0 0 5490 5490 - 1185 t 0 - - - - 0 0 Table 15: Range, median and mean for each analyte in pg g-1 ww: detection frequency (%) for the food categories and total, for the individual countries. Median and means are calculated using the positive detects only. Source: D'Hollander et al. (2015). Table 16: (please see the excel file "List_substances_ShortChainPFASs.xlsx" below) The first sheet gives an overview of recently available information on short-chain PFASs from all over the world, regarding human biomonitoring (concentrations in blood, urine, tissues, ...) and ecological monitoring (concentrations in air, groundwater, drinking water, soil, ...). Information in the table is preceded by a number which refers to the scientific paper in which the information can be found. The numbers corresponding to the scientific papers can be seen in the second sheet. This table is updated each year with the most recent scientific papers, and is thus constantly adapted and following the newest information. Please save this `scPFAS_CCIEP_report' first on your computer in order to be able to open the link below. List_substances_Short ChainPFASs.xlsx Table 17: List of fluorinated compounds from the EU regulation 10/2011 from 14 January 2014 regarding materials and products in plastic Substance name (Dutch) 1,1-difluorethaan Vinylideenfluoride Chloordifluormethaan Chloortrifluorethyleen Tetrafluoretheen Hexafluorpropeen 4,4'-difluorbenzofenon perfluormethyl-perfluorvinylether perfluorpropyl-perfluorvinylether ammoniumperfluoroctanoaat CAS number 0000075-37-6 0000075-38-7 0000075-45-6 0000079-38-9 0000116-14-3 0000116-15-4 0000345-92-6 0001187-93-5 0001623-05-8 0003825-26-1 magnesiumnatriumfluoridesilicaat 2,2'-ethylideenbis(4,6-di-tertbutylfenyl) fluorfosfoniet 9,9-bis(methoxymethyl)fluoreen perfluorazijnzuur, -gesubstituteerd met het copolymeer van perfluor1,2- propyleenglycol en perfluoro-1,1- ethyleenglycol, getermineerd met chloorhexafluorpropyloxygroepen perfluor[2-(poly(npropoxy))propaanzuur] perfluor[2-(n-propoxy)propaanzuur] 3H-perfluor-3-[(3-methoxypropoxy) propaanzuur], ammoniumzout 2H-perfluoro- [(5,8,11,14-tetramethyl)-tetraethyleenglycol ethyl propyl ether] perfluor[(2-ethyloxy-ethoxy)azijnzuur],ammoniumzout (perfluorbutyl)ethyleen 0037296-97-2 0118337-09-0 0182121-12-6 0329238-24-6 0051798-33-5 0013252-13-6 0958445-44-8 37486-69-4 0908020-52-0 0019430-93-4 Table 18: Non-exhaustive list of active substances following current PFAS definition authorized as plant protection products at ECHA Substance name Triflumoron/ tritosulfuron (ISO) (containing 0,02 % 2-amino-4-methoxy-6(trifluormethyl)-1,3,5-triazine); 1-[4methoxy-6-(trifluoromethyl)-1,3,5-triazin-2yl]-3-[2(trifluoromethyl)benzenesulfonyl]urea (containing 0,02 % 2-amino-4-methoxy-6(trifluormethyl)-1,3,5-triazine) indoxacarb (ISO); methyl (4aS)-7-chloro-2{(methoxycarbonyl)[4(trifluoromethoxy)phenyl]carbamoyl}-2,5dihydroindeno[1,2-e][1,3,4]oxadiazine4a(3H)-carboxylate EC / List no 604-291- 0 CAS no 14246914-5 605-6834 17358444-6 CLH status Withdrawn Adopted isoxaflutole (ISO); 5-cyclopropyl-1,2-oxazol4-yl ,,- trifluoro-2-mesyl-p-tolyl ketone 604-2224 14111229-0 Adopted Submitted triflusulfuron-methyl; methyl 2-({[4(dimethylamino)-6-(2,2,2- trifluoroethoxy)1,3,5-triazin-2- yl]carbamoyl}sulfamoyl)-3methylbenzoate trifloxystrobin( ISO); methyl (E)methoxyimino-{(E)--[1-(,,-trifluoro-mtolyl)ethylideneaminooxy]-o-tolyl}acetate 603-1469 12653515-7 604-2376 14151721-7 Adopted Adopted Classification adopted or proposed Skin Sens. 1B, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Submitter Slovenia Regulatory Program Active substance in biocidal and plant protection products Acute tox 3 H301 Acute tox 4 H332 Skin Sens 1 H317 STOT RE 1 H372 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 M- factor: 1 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Repr. 2, H361d*** STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Lact. Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic United Kingdom Netherlands Italy France United Kingdom Active substance in biocidal and plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products tefluthrin (ISO); 2,3,5,6-tetrafluoro-4methylbenzyl (1RS,3RS)-3-[(Z)-2-chloro3,3,3-trifluoroprop-1-enyl]-2,2dimethylcyclopropanecarboxylate Sedaxane Reaction mass of 3-(difluoromethyl)-1methyl-N-[(1RS,4SR,9RS)-1,2,3,4tetrahydro-9-isopropyl-1,4methanonaphthalen-5-yl]pyrazole-4carboxamide and of 3-(difluoromethyl)-1methyl-N-[(1RS,4SR,9SR)-1,2,3,4tetrahydro-9-isopropyl-1,4methanonaphthalen-5-yl]pyrazole-4carboxamide; isopyrazam pyroxsulam (ISO);N-(5,7dimethoxy[1,2,4]triazolo[1,5-a]pyrimidin-2yl)-2-methoxy-4-(trifluoromethyl) pyridine3-sulfonamide pyridalyl (ISO); 2,6-dichloro-4-(3,3dichloroallyloxy)phenyl 3-[5(trifluoromethyl)-2-pyridyloxy]propyl ether picolinafen (ISO); N-(4-fluorophenyl)-6-[3(trifluoromethyl)phenoxy]pyridine-2carboxamide; 4-fluoro-6-[(,,-trifluoro-mtolyl)oxy]picolinanilide penthiopyrad (ISO); (RS)-N-[2-(1,3dimethylbutyl)-3-thienyl]-1-methyl-3(trifluoromethyl)pyrazole-4-carboxamide 616-6996 688-3312 632-6192 610-0076 605-8454 604-0300 606-0018 79538-322 87496767-6 88168558-1 42255608-9 17910181-6 13764105-5 18367582-3 Adopted Adopted Opinion Development Acute Tox. 2, H300 Acute Tox. 2, H310 Acute Tox. 1, H330 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 000 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 000 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 2, H411 Skin Sens. 1B, H317 Repr. 1B, H360D Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Germany Active substance in plant protection products France United Kingdom Active substance in plant protection products Active substance in plant protection products Opinion adapted Opinion development Submitted Adopted Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Skin Sens. 1, H317 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 United Kingdom Netherlands Germany United Kingdom Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2yl]ethyl}-2-(trifluoromethyl)benzamide; fluopyram (ISO) 619-7977 65806635-4 N-methoxy-N-[1-methyl-2-(2,4,6trichlorophenyl)-ethyl]-3-(difluoromethyl)-1methylpyrazole-4-carboxamide; pydiflumetofen* 817-8521 122828464-7 N-(cyanomethyl)-4(trifluoromethyl)pyridine-3-carboxamide; flonicamid (ISO) 605-1270 15806267-0 N-(5-chloro-2-isopropylbenzyl)-Ncyclopropyl-3-(difluoromethyl)-5-fluoro-1methyl-1H-pyrazole-4-carboxamide; isoflucypram* - 1255734- 28-1 Fluxapyroxad 620-0413 90720431-3 flutolanil (ISO); N-[3-(propan-2yloxy)phenyl]-2-(trifluoromethyl)benzamide; ,,-trifluoro-3-isopropoxy-o-toluanilide 613-9213 66332-965 flutianil (ISO); (2Z)-{[2-fluoro-5(trifluoromethyl)phenyl]thio}[3-(2methoxyphenyl)-1,3-thiazolidin-2ylidene]acetonitrile flurochloridone (ISO); 3-chloro-4(chloromethyl)-1-[3(trifluoromethyl)phenyl]pyrrolidin-2-one 812-8884 95864710-4 262-6613 61213-250 Adopted Pending Adopted Pending Adopted Intention Adopted Adopted protection products Aquatic Chronic 2, H411 Carc2 Repro 2 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Acute Tox. 4, H302 Acute Tox. 4, H332 Skin Sens. 1B, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Lact. Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, Mfactor=100 Acute Tox. 4, H302 Skin Sens. 1, H317 Repr. 1B, H360Df Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Germany France France United Kingdom United Kingdom Netherlands United Kingdom Spain Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products fluopicolide (ISO); 2,6-dichloro-N-[3-chloro5-(trifluoromethyl)-2pyridylmethyl]benzamide 607-2856 23911015-7 flazasulfuron (ISO): 1-(4,6dimethoxypyrimidin-2-yl)-3-(3trifluoromethyl-2-pyridylsulfonyl)urea 600-5140 10404078-0 diflufenican (ISO); N-(2,4-difluorophenyl)-2[3-(trifluoromethyl)phenoxy]-3pyridinecarboxamide 617-4462 83164-334 cyflumetofen (ISO); 2-methoxyethyl (RS)-2(4-tert-butylphenyl)-2-cyano-3-oxo-3-(,,trifluoro-o-tolyl)propionate 642-9745 40088207-7 carfentrazone-ethyl (ISO); ethyl (RS)-2chloro-3-[2-chloro- 4-fluoro-5-[4difluoromethyl-4,5-dihydro-3-methyl-5-oxo1H-1,2,4-triazol-1-yl]phenyl]propionate benzovindiflupyr (ISO); N-[9(dichloromethylene)-1,2,3,4-tetrahydro-1,4methanonaphthalen-5-yl]-3(difluoromethyl)-1-methyl-1H-pyrazole-4carboxamide 603-2918 12863902-1 691-7194 107295771-1 Benfluralin 217-4652 1861-40-1 [methyl(oxo){1-[6-(trifluoromethyl)-3pyridyl]ethyl}-6-sulfanylidene]cyanamide; sulfoxaflor (ISO) 807-3668 94657800-3 Adopted Intention Adopted Adopted Intention Adopted Opinion development Adopted Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, Mfactor=100 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1000 Aquatic Chronic 1, H410 Aquatic Chronic 1, Mfactor=100 Skin Sens. 1A, H317 Carc. 2, H351 Carc. 2, H351 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Acute Tox. 3, H301 Acute Tox. 3, H331 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M- factor=100 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Carc. 2, H351 Repr. 2, H361d Lact., H362 STOT SE 2, H371 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Acute Tox. 4, H302 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Austria Spain United Kingdom Netherlands Belgium France Norway Ireland Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 protection products 4-{[(6-chloropyridin-3-yl)methyl](2,2difluoroethyl)amino}furan-2(5H)-one; flupyradifurone 804-3738 95165940-8 3-chloro-N-[3-chloro-2,6-dinitro-4(trifluoromethyl)phenyl]-5(trifluoromethyl)pyridin-2-amine; fluazinam (ISO) 616-7125 79622-596 2-{2-chloro-4-(methylsulfonyl)-3-[(2,2,2trifluoroethoxy)methyl]benzoyl}cyclohexane1,3-dione; tembotrione (ISO) 608-8798 33510484-2 1-[[](Z)-[[]2-(4-cyanophenyl)-1-[[]3(trifluoromethyl)phenyl]ethylidene]amino]1-[[]4-(trifluoromethoxy)phenyl]urea Metaflumizone (ISO) 1-(4-{4-[[]5-(2,6-difluorophenyl)-4,5dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2yl}piperidin-1-yl)-2-[[]5-methyl-3(trifluoromethyl)-1H-pyrazol-1-yl]ethan-1one Oxathiapiprolin (ISO) (2RS)-2-[4-(4-chlorophenoxy)-2(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol1-yl)propan-2-ol; mefentrifluconazole 604-1676 801-2631 - 13996849-3 100331867-9 141778203-6 *The approval of these substances is pending. Adopted Adopted Adopted Adopted Adopted Adopted Acute Tox. 4, H302 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 Repr. 2, H361 STOT SE 3, H335 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=10 Aquatic Chronic 1, H410 Skin Sens. 1B, H317 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=100 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=10 Repr. 2, H361d Lact., H362 STOT RE 2, H373 Aquatic Chronic 1, H410 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Acute 1, M-factor=1 Aquatic Chronic 1, H410 Aquatic Chronic 1, M-factor=1 Netherlands Austria Austria United Kingdom Ireland United Kingdom Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Active substance in plant protection products Table 19: Non- exhaustive list of active substances following current PFAS definition authorised as biocides at ECHA Substance name 1-(3,5-dichloro-4-(1,1,2,2tetrafluoroethoxy)phenyl)-3-(2,6difluorobenzoyl) urea (Hexaflumuron) 4-bromo-2-(4-chlorophenyl)-1-ethoxy methyl-5-trifluoromethylpyrrole-3carbonitrile (Chlorfenapyr) Bifenthrin Fipronil Flocoumafen Fludioxonil EC/List no. -; 401-400-1 - -; 424-610-5 -; 421-960-0 -; 603-476-3 CAS no. 86479-06-3 122453-73-0 82657-04-3 120068-37-3 90035-08-8 131341-86-1 Indoxacarb (enantiomeric mass S:R 75:25) lambda-cyhalothrin Tralopyril reaction -; 415-130-7 - 91465-08-6 122454-29-9 BAS number Product-type Approval start date 1314 66 8 33 34 1416 64 41 1403 PT18-Insecticides, acaricides and 01/04/2017 products to control other arthropods PT08-Wood preservatives, PT18-Insecticides, acaricides and products to control other arthropods PT08-Wood preservatives PT18-Insecticides, acaricides and products to control other arthropods PT14-Rodenticides PT07-Film preservatives, PT09-Fibre, leather, rubber and polymerised materials preservatives, PT10Construction material preservatives PT18-Insecticides, acaricides and products to control other arthropods PT18-Insecticides, acaricides and products to control other arthropods PT21-Antifouling products 01/05/2015 01/02/2013 01/10/2013 01/10/2011 01/04/2018 01/01/2010 01/10/2013 01/04/2015 Table 20 RMOA list of PFAS for which an RMOA either is under development or has been completed since the start of the implementation of the SVHC Roadmap in 2013 Substance Tetrafluoroethylene C9-C14 perfluoroalkyl carboxylic acids including their salts and precursors (PFNA/PFDA/PFUnDA/PFDoDA/PFTrDA/PFTDA) EC/list no 204126-9 206203-2 CAS no 11614-3 30755-1 Concern Follow up CMR (reprotox) CLH PBT/vPvB(reprotox) widespread use restriction Undecafluorohexanoic acid (PFHxA), its salts and related substances Perfluorobutane sulfonic acid (PFBS) and its salts - CMR (reprotox) SVHC (withdrawn) ELoC (PMT) CLH restriction - ELoC (PMT) SVHC restriction 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]diphenol; bisphenol AF 4-chloro-,,-trifluorotoluene (3,3,4,4,5,5,6,6,7,7,8,8,8tridecafluorooctyl)silanetriol and any of its mono-, di- or tri-O-(alkyl) derivatives 216036-7 202681-1 - 1478- ELoC (ED) 61-1 CLH 9856-6 - CMR (carcinogenic) Risks of acute lung injury from spray No suggestion yet restriction 2,3,3,3-tetrafluoro-2- - (heptafluoropropoxy)propionic acid, its salts and its acylhalides covering any of their individual isomers and combinations thereof (GenX) - ELoC (PMT) SVHC 2,4,6-trimethyl-2,4,6-tris(3,3,3trifluoropropyl)cyclotrisiloxane (F-D3) 219154-7 2374- PBT (human tox) 14-3 CLH Notes: reprotox = reproductive toxicant; PMT = persistence, mobility, and toxicity; CMR = carcinogenic, mutagenic, or toxic to reproduction; ED = endocrine disruption; ELoC = equivalent level of concern Table 21 PFAS identified as SVHC and on the Candidate list for REACH Authorisation Substance 2,3,3,3-tetrafluoro-2(heptafluoropropoxy)propionic acid, its salts and its acyl halides (HFPO-DA) covering any of their individual isomers and combinations thereof (GenX) Perfluorobutane sulfonic acid and its salts (PFBS) ECno - - CASno - Concern ELoC having probable serious effects to human health and environment (Article 57(f) human health) - ELoC having probable serious effects to human health and environment (Article 57(f) - human health) PFHxS Perfluorononan-1-oic-acid and its sodium and ammonium salts (PFNA) Nonadecafluorodecanoic acid (PFDA) and its sodium and ammonium salts Henicosafluoroundecanoic acid (PFUnDA); Tricosafluorododecanoic acid (PFDoDA); Pentacosafluorotridecanoic acid (PFTrDA); - 206-400-3 218-165-4 206-203-2 276-745-2 - 335-76-2 2058-94-8 307-55-1 72629-948 vPvB (Article 57e) Toxic for reproduction 57c) PBT (Article 57d) Toxic for reproduction 57c) PBT (Article 57d) vPvB (Article 57e) (Article (Article vPvB (Article 57e) vPvB (Article 57e) Table 22: PFAS substances on the CoRAP list as of August 2020 Substance 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl) phosphates, ammonium salt (HGC-TLF) reaction mass of 2,2,3,3,5,5,6,6-octafluoro-4-(1,1,1,2,3,3,3heptafluoropropan-2-yl)morpholine EC/list no 700-161-3 473-390-7 CAS no - - HFE 7000 (Trade name: 3M(TM) NOVEC(TM) ENGINEERED FLUID HFE-7000) HFE 7100 (Reaction mass of 1,1,2,3,3,3-hexafluoro-1methoxy-2-(trifluoromethyl)propane and 1,1,2,2,3,3,4,4,4nonafluoro-1-methoxybutane), Process related name: HFE7100 3M BRAND SPECIALITY LIQUID Potassium 2-(3-trifluoromethoxy-1,1,2,2,3,3hexafluoropropoxy)-2,3,3,3-tetrafluoropropionate (MV31Potassium salt) Polyhaloalkene 484-450-7 422-270-2 - 444-340-1 468-710-7 754-12-1 Perfluamine 206-420-2 338-83-0 Authority NL BE ES ES Year Concern 2013 Suspected PBT/vPvB 2016 2019 Suspected PBT/vPvB, Exposure of environment, Wide dispersive use Suspected PBT/vPvB 2019 Suspected PBT/vPvB Status ongoing follow-up suspended suspended DE 2017 Suspected PBT/vPvB, concluded Exposure of environment DE 2012 Other hazard based information concern, exposure of requested environment, high (aggregated) tonnage, wide dispersive use BE 2020 Suspected PBT/vPvB, ongoing Exposure of environment Hexafluoropropene Bis(nonafluorbutyl)phosphinic acid 204-127-4 116-15-4 IT 700-183-3 52299-25-9 DE Amphoteric Fluorinated Surfactant - - BE Ammonium salts of mono- and bis[3,3,4,4,5,5,6,6,7,7,8,8,8tridecafluorooctyl and/or poly (substituted alkene)] phosphate ammonium difluoro[1,1,2,2-tetrafluoro-2(pentafluoroethoxy)ethoxy]acetate ammonium 2,3,3,3-tetrafluoro-2(heptafluoropropoxy)propanoate (GenX/ C3 dimer salt) Ammonium 2,2,3 trifluor-3-(1,1,2,2,3,3-hexafluoro-3trifluormethoxypropoxy), propionate (Adona) 700-403-8 700-323-3 700-242-3 480-310-4 - BE 908020-520 62037-80-3 DE DE/NL DE HFE 7500 (3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2(trifluoromethyl)-hexane), processed fluid 435-790-1 297730-93- ES 9 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl methacrylate (6:2 218-407-9 2144-53-8 DE FTMA) 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl acrylate (6:2 FTA) 241-527-8 17527-29-6 DE 2H-Tricosafluoro-5,8,11,14-tetrakis(trifluoromethyl)3,6,9,12,15-pentaoxaoctadecane (TFEE-5) - 37486-69-4 DE 484-410-9 - ES 2015 Suspected CMR, High (aggregated) tonnage 2018 2018 2013 2017 2017 2017 2018 2016 2016 2017 2019 Suspected PBT/vPvB, other hazard based concern, exposure of environment Suspected PBT/vPvB, Exposure of environment, Wide dispersive use Suspected PBT/vPvB, consumer use, wide dispersive use Suspected PBT/vPvB, Exposure of environment Suspected PBT/vPvB, Exposure of environment Suspected PBT/vPvB, Exposure of environment, Wide dispersive use Suspected PBT/vPvB, Exposure of environment, Wide dispersive use Potential endocrine disruptor, Suspected PBT/vPvB, Other hazard based concern, Exposure of environment, Wide dispersive use Potential endocrine disruptor, Suspected PBT/vPvB, Other hazard based concern. Exposure of environment, wide dispersive use Suspected PBT/vPvB, Exposure of environment Suspected PBT/vPvB conclusion under preparation concluded ongoing ongoing ongoing information requested ongoing ongoing information requested information requested conclusion under preparation ongoing HFE 7800 (2-Ethoxy-3,3,4,4,5-pentafluoro-2,5-bis[(1,2,2,2- tetrafluoro-1-trifluoromethyl)ethyl] tetrahydrofuran), Trade name: 3M(TM) NOVEC(TM) ENGINEERED FLUID 2-bromo-3,3,3-trifluoroprop-1-ene (2-BTP) 627-872-0 1514-82-5 ES 2-[methyl[(nonafluorobutyl) sulpho-nyl]amino]ethyl acrylate (N-Me FBSEA) 266-733-5 67584-55-8 DE 2019 2018 Suspected reprotoxic, potential endorcrine disruptor Suspected PBT/vPvB, other hazard based concern, exposure of environment, wide dispersive use concluded concluded Table 23: CLH processes on PFAS substances that are developed or under development Substance name* 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10heptadecafluorodecan-1-ol EC / List no 211-648- 0 CAS no 678-39-7 CLH status Opinion adopted Reaction mass of 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]diphenol and benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]bis[phenol] (1:1) Reaction mass of 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]diphenol and benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4hydroxyphenyl)propan-2-yl]phenolate (1:1) Perfluoroheptanoic acid Benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1(trifluoromethyl)ethylidene]bis[phenol] (1:1) benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4hydroxyphenyl)propan-2-yl]phenolate 947-3687 943-2656 206-7989 278-3055 479-1005 - - 375-85-9 75768-65-9 577705-90-9 Opinion Development Opinion Development Opinion Development Opinion development Opinion development Classification adopted or proposed Proposal: Repr. 1B, H360D Opinion concluded no harmonised class. for this endpoint Repr. 1B, H360F Submitter Norway Sweden Regulatory Programme Chemical REACH Chemical REACH Repr. 1B, H360F Sweden Chemical REACH Repr. 1B, H360D STOT RE 1, H372 Repr. 1B, H360F Repr. 1B, H360F Belgium Sweden Chemical REACH Chemical REACH Sweden Chemical REACH Ammonium pentadecafluorooctanoate 223-320- 3825-26-1 Adopted Adopted (5. ATP); Norway Chemical REACH 4 Carc 2; H351 Repr 1B; H360D Lact; H362 Acute Tox. 4; H332 Acute Tox. 4; H302 STOT RE1; H372 (liver) Eye Dam 1; H318 Pentadecafluorooctanoic acid 206-397- 335-67-1 Adopted Adopted (5. ATP); Norway Chemical REACH 9 Carc 2; H351 Repr 1B; H360D Lact; H362 Acute Tox. 4; H332 Acute Tox. 4; H302 STOT RE1; H372 (liver) Eye Dam 1; H318 * Listed are only CLH intentions for substances under REACH for which no RMOA has been established or is ongoing (CLH intentions for substances used in biocide and plant protection products are excluded). Annex 1.3: Figures Figure 3: Comparison of dietary exposure to PFIA (left) and PFOS (right) estimated by PERFOOD and EFSA (2012) for adults and children based on lower-bound (LB) estimates (upper figures and upper-bound (UB) estimates (lower figures). Source: Kenlow et al.( 2013). Figure 4: Comparison of mean concentrations of PFAAs (pg g -1 ww) in 7 different food groups sampled in the Czech Republic, Italy, Norway and Belgium. Error bars represent the standard errors of the mean. *: levels < LOQ; /: not sampled. Note: the respective food groups can differ in composition between the regions. Source: D'Hollander 2015. Figure 5: Comparison of the sum of PFAA concentrations (pg g-1 ww) between the Czech Republic, Italy, Norway and Belgium in apples, pears and strawberries (ns: not sampled; < LOQ: levels in apples and pears from Norway were below LOQ). Source: D'Hollander et al. (2015). Figure 6: Contribution of the individual PFAAs (>LOQ) to the total sum of PFAAs that were detected in apples (left side) and pears (right side) sampled in the Czech Republic, Italy, Norway and Belgium. Pears sampled in Norway are not shown as all the analysed PFAAs-levels were <LOQ. Source: D'Hollander et al. (2015).