Document 995ypBO8wOeeZb6xOMoyxd8ee
AGC Y0111 Dreams, 0111- Ch,lHerlge
SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
According to REACH Regulation (EC) No 1907/2006, as amended by UK REACH Regulations SI 2019/758 and SI 2020/1577
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifier
Product Name
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified Use(s)
Fluoropolymer polymerisation aid.
Uses Advised Against
Not known.
1.3 Details of the supplier of the safety data sheet
Manufacturer
Company Identification
AGC Inc.
Address of Manufacturer
AGC Chemicals
1-5-1, Marunouchi
Chiyoda-ku
Tokyo 100-8405
Japan
Postal code
100-8405
Telephone
E-mail
@agc.com
Office hours
08:00 - 18:00
Supplier
Company Identification
AGC Chemicals Europe, Ltd.
Address of Supplier
York House, Hillhouse International, Fleetwood Road North,
Thornton -Cleveleys, Lancashire
United Kingdom
Postal code
FY5 4QD
Telephone
E-mail
@agc.com
Office hours
08:00 - 18:00
1.4 Emergency telephone number
Emergency Phone No.
Contact
NCEC
National response centre
Address
NHS Direct
Emergency Phone No.
+44 111
SECTION 2: HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
GB CLP Regulation, UK SI 2019/720 and Acute Tox. 4 :Harmful if swallowed.
UK SI 2020/1567
Eye Dam. 1 :Causes serious eye damage.
Repr. 2 :Suspected of damaging the unborn child.
2.2 Label elements
According to GB CLP Regulations, UK SI 2019/720 and UK SI 2020/1567
Product Name Hazard Pictogram(s)
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
Signal Word(s) Hazard Statement(s)
Precautionary Statement(s)
GHS05
GHS08
GHS07
Danger H302: Harmful if swallowed. H318: Causes serious eye damage.
H361d: Suspected of damaging the unborn child.
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood.
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SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
2.3 Other hazards 2.4 Additional Information
P264: Wash hands and exposed skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Harmful if swallowed. Severe irritant to the eye. Possible risk of harm to the unborn child.
For full text of H/P Statements see section 16.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
3.2 Mixtures HAZARDOUS INGREDIENT(S)
Ammonium difluoro[1,1,2,2tetrafluoro-2(pentafluoroethoxy)ethoxy]acetate
Not applicable.
CAS No. 908020-52-0
EC No. / Registration %W/W
number(s)
700-323-3
25 - 35
UK-01-5845916918-
9-X
Hazard Statement(s)
Acute Tox. 4 H302 Eye Dam. 1 H318 Repr. 2 H361d
Hazard Pictogram(s) GHS05 GHS08 GHS07
For full text of H/P Statements see section 16.
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures
Inhalation
Remove patient from exposure, keep warm and at rest. If breathing is laboured,
administer oxygen. Obtain medical attention.
Skin Contact
Remove contaminated clothing and wash all affected areas with plenty of water. If
symptoms persist, obtain medical attention.
Eye Contact
Immediately irrigate with eyewash solution or clean water, holding the eyelids apart,
for at least 15 minutes. Obtain immediate medical attention.
Ingesti on
Do not induce vomiting. Provided the patient is conscious, wash out mouth with
water and give 200-300ml (half a pint) of milk or water to drink. Obtain immediate
medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Severe irritant to the eye.
4.3 Indication of any immediate medical attention and special treatment needed Symptomatic treatment and supportive therapy as indicated.
SECTION 5: FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable Extinguishing media
As appropriate for surrounding fire. Water spray should be used to cool containers.
Unsuitable extinguishing media
None.
5.2 Special hazards arising from the substance or mixture
Non-combustible. Thermal decomposition will evolve toxic and corrosive vapours.
(Carbon monoxide, Carbon dioxide, hydrogen fluoride).
5.3 Advice for firefighters
A self contained breathing apparatus and full protective clothing must be worn in
fire conditions.
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SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Ensure suitable personal protection during removal of spillages.
6.2 Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3 Methods and material for containment and cleaning up Adsorb spillages onto sand, earth or any suitable adsorbent material. Transfer to a lidded container for disposal or recovery.
6.4 Reference to other sections See Also Section 8, 13.
SECTION 7: HANDLING AND STORAGE
7.1 Precautions for safe handling Avoid contact with skin and eyes. Do not spray. Avoid generation of aerosols or mist. Wash hands thoroughly after handling. Contaminated clothing should be thoroughly cleaned.
7.2 Conditions for safe storage, including any incompatibilities Keep in a cool, well ventilated place. Keep container tightly closed and dry.
Storage temperature Storage life Incompatible materials 7.3 Specific end use(s)
Ambient. Stable under normal conditions. Oxidising agents, reducing agents.
Fluoropolymer polymerisation aid.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters 8.1.1 Occupational Exposure Limits
The AGC EAL of 0.01 mg/m3 for EEA-NH4 is an interim level based on the NCEL set by the US EPA in 2008. It should be used as the occupational hygiene tool to manage exposure to the substance during its use. More recently, as part of its registration under REACH, a DNEL of 0.32 mg/m3 for workplace exposure has been derived for EEA-NH4 using the currently available data. The DNEL is defined in the REACH Regulation as the level of exposure to the substance above which humans should not be exposed.
Occupational Exposure Limits SUBSTANCE.
Ammonium difluoro[1,1,2,2-tetrafluoro-2(pentafluoroethoxy)ethoxy]acetate
CAS No. 908020-52-0
LTEL (8 hr TWA ppm)
LTEL (8 hr TWA STEL
mg/m)
(ppm)
0.01
STEL (mg/m)
Note Comp,
Region United Kingdom
Source UK Workplace Exposure Limits EH40/2005 (Fourth edition, published 2020)
8.2 Exposure controls 8.2.1. Appropriate engineering controls
8.2.2. Personal protection equipment
Aerosol or mist generation will pose an inhalation hazard. Atmospheric concentrations should be 3xidizing and kept as low as reasonably practical below the occupational exposure limit by the use of suitable handling methods and local exhaust ventilation. Wear suitable protective clothing, gloves and eye/face protection. Use only in well ventilated areas. Where engineering controls are not fitted or inadequate wear suitable respiratory protective equipment.
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SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
Eye Protection
Wear close fitting goggles or full face shield.
Skin protection
Wear protective clothing and gloves: Impervious gloves (EN 374). Gloves should be changed regularly to avoid permeation problems. Breakthrough time of the glove material: refer to the information provided by the gloves' producer.
Respiratory protection Where the use of a cartridge/canister respirator is appropriate use Type P2
Thermal hazards
Not applicable.
8.2.3. Environmental Exposure Controls Do not allow to enter drains, sewers or watercourses.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Except where stated all data are from the solution.
9.1 Information on basic physical and chemical properties
Appearance
Aqueous solution
Colour: Colourless.
Odour
Odourless.
Odour threshold
Not known.
pH
Not known.
Melting point/freezing point
Not known.
Initial boiling point and boiling range circa. 100C
Flash Point
Not known.
Evaporation rate
Not known.
Flammability (solid, gas)
Not known.
Upper/lower flammability or explosive Not known.
limits
Vapour pressure
Not known.
Vapour density
Not known.
Density (g/ml)
Not known.
Relative density
Not known.
Solubility(ies)
Solubility (Water): Miscible.
Solubility (Other): Not known.
Partition coefficient: n-octanol/water
1.18 (fluorinated surfactant)
Auto-ignition temperature
Not known.
Decomposition Temperature (C)
Not known.
Viscosity
Not known.
Explosive properties
Not explosive.
Oxidising properties
Not oxidizing.
9.2 Other information
Specific Gravity
1.15 @ 20C
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Revision: CLP05
SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
Stable under normal conditions.
10.2 Chemical Stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions May react violently with: oxidising agents, reducing agents.
10.4 Conditions to avoid
Heat and direct sunlight.
10.5 Incompatible materials
Oxidising agents, reducing agents.
10.6 Hazardous decomposition products Thermal decomposition will evolve toxic and corrosive vapours. (Carbon monoxide, Carbon dioxide, hydrogen fluoride).
SECTION 11: TOXICOLOGICAL INFORMATION
All data are from the main component (fluorinated surfactant).
11.1 Information on toxicological effects
Acute toxicity - Ingestion
Calculation method : Harmful if swallowed.
Calculation method : Calculated acute toxicity estimate (ATE) Calc ATE - 1666.67
LD50 (rat) =500mg/kg
Acute toxicity - Skin Contact
Acute toxicity - Inhalation Skin corrosion/irritation Serious eye damage/irritation
Calculation method : Not classified. Unlikely to be hazardous by skin absorption. LD50 (rat) >2000mg/kg Calculation method : Not classified. Calculation method : Not classified. Calculation method : Causes serious eye damage. Severe irritant to the eye.
Skin sensitization data
Calculation method : Not classified. Not sensitising
Respiratory sensitization data
Calculation method : Not classified.
Germ cell mutagenicity Carcinogenicity
Calculation method : Not classified. In vitro bacterial cell reverse mutation assay (OECD 471): Negative In-vitro mammalian cell chromosome aberration assay (OECD 473 - V79 cells)): Positive In vitro mammalian cell gene mutation assay (OECD 476): Negative In vivo erythrocyte micronucleus test in rats (OECD 474): Negative Based on a weight of evidence assessment, it is concluded that the fluorinated surfactant is not mutagenic. Calculation method : Not classified.
Reproductive toxicity
Lactation STOT - single exposure STOT - repeated exposure
Calculation method : Suspected of damaging the unborn child. In a reproduction/developmental toxicity screening study in the rat with the fluorinated surfactant, 100 mg/kg/day was considered to be the NOAEL for effects on fertility due to the lack of effects on parental reproductive parameters. The NOAEL for neonatal toxicity was 5 mg/kg/day based on reduced postnatal survival and lower mean male and female pup body weights in the 25 mg/kg/day group. Calculation method : Not classified. Calculation method : Not classified. Calculation method : Not classified. The results from an oral 90-day repeated dose toxicity study in the rat showed that the fluorinated surfactant exerted effects on the kidney, liver and haematological system. The NOAEL in the study was 10 mg/kg/day.
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Revision: CLP05
SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
Aspiration hazard 11.2 Other information
Calculation method : Not classified. Not known.
SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity
Toxicity - Aquatic invertebrates
Toxicity - Fish Toxicity - Algae
Toxicity - Sediment Compartment Toxicity - Terrestrial Compartment 12.2 Persistence and degradability
EC50 (48 hour) >100mg/l, NOEC (48 hour) >100mg/l (OECD 202), NOEC (21 days) =100mg/l (OECD 211) LC50 (96 hour) >100mg/l, NOEC (96 hour) >100mg/l (OECD 203) EC50 (72 hour) (Growth rate) >100mg/l, EC50 (72 hour) (Biomass) >100mg/l, NOEC (72 hour) <100mg/l (OECD 201) Not classified. Not classified.
Not readily biodegradable.
12.3 Bioaccumulative potential The product has low potential for bioaccumulation. Bioconcentration factor (BCF): <5.8(Fish)
12.4 Mobility in soil The product is predicted to have high mobility in soil. log Koc 1.06 (11.4 l/kg)
12.5 Results of PBT and vPvB assessment Not classified as PBT or vPvB.
12.6 Other adverse effects
Unlikely to have an effect on effluent treatment systems. Bacteria: Activated sludge respiration inhibition test EC50 (mg/l) = >100mg/l (3hour)
SECTION 13: DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods 13.2 Additional Information
Best to recover and recycle. If this is not possible, destruction is to be in an approved facility which is equipped to absorb and neutralize acid gases and other toxic processing products.
Disposal should be in accordance with local, state or national legislation.
SECTION 14: TRANSPORT INFORMATION Not classified as hazardous for transport.
14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user
Not applicable Not applicable Not applicable Not applicable Not classified as a Marine Pollutant.
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SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
Not known 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not known
SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
United Kingdom Regulations - Authorisations and/or Restrictions On Use
UK REACH Candidate List of Substances Not listed
of Very High Concern for Authorisation
UK REACH Authorisation List (Annex XIV) Not listed
list of substances subject to authorisation
UK REACH Restrictions List (Annex XVII) Not listed
Restrictions on the manufacture, placing
on the market and use of certain
dangerous substances, mixtures and
articles
UK REACH Rolling Action Plan (RAP)
Not listed
The Persistent Organic Pollutants
Not listed
Regulations 2007 (SI 2007/3106) as
amended
The Ozone-Depleting Substances and Not listed
Fluorinated Greenhouse Gases
(Amendment etc.) (EU Exit) Regulations
2019 (SI 2019/583)
The Prior Informed Consent (PIC)
Not listed
Regulations concerning the export and
import of hazardous chemicals
SI2008/2108 as amended
European Regulations - Authorisations and/or Restrictions On Use
Community Rolling Action Plan (CoRAP) ammonium difluoro[1,1,2,2-tetrafluoro-2-(pentafluoroethoxy)ethoxy]acetate
(908020-52-0)
15.2 Chemical Safety Assessment
United Kingdom
A REACH chemical safety assessment has been carried out.
SECTION 16: OTHER INFORMATION
The following sections contain revisions or new statements:
1-16
LEGEND
Hazard Pictogram(s)
Hazard classification Hazard Statement(s)
GHS05
GHS08
GHS07
Acute Tox. 4 : Acute toxicity, Category 4 Eye Dam. 1 : Serious eye damage/irritation, Category 1
Repr. 2 : Reproductive toxicity, Category 2
H302: Harmful if swallowed. H318: Causes serious eye damage.
H361d: Suspected of damaging the unborn child.
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Revision: CLP05
SAFETY DATA SHEET
10-01-2023
FLUON SAA-1000 / SAA-1000 U6 / SAA-1000 U8
Precautionary Statement(s)
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P264: Wash hands and exposed skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P312: IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313: IF exposed or concerned: Get medical advice/attention. P310: Immediately call a POISON CENTRE/doctor. P330: Rinse mouth. P405: Store locked up. P501: Dispose of contents in accordance with local, state or national legislation.
Acronyms
ATE : Acute Toxicity Estimate CAS : Chemical Abstracts Service DNEL : Derived No Effect Level EC : European Community EINECS : European Inventory of Existing Commercial Chemical Substances LTEL : Long term exposure limit PBT : Persistent, Bioaccumulative and Toxic PNEC : Predicted No Effect Concentration REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals STEL : Short term exposure limit STOT : Specific Target Organ Toxicity vPvB : very Persistent and very Bioaccumulative
Key literature references and sources for GB CLP Regulation, UK SI 2019/720 and UK SI 2020/1567 data used to compile the SDS
Disclaimers
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose. AGC Chemicals Europe, Ltd. gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. AGC Chemicals Europe, Ltd. accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed. This product is not designed for special applications such as pharmaceutical or medical use. This product is for industrial use only. This product is not suitable for consumer and professional applications.
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registered substance (Annex 1 Section 1.0.1). The DNEL is defined as the "level of exposure to the substance above which humans should not be exposed". DNELs are derived for two sets of potentially exposed groups, workers and the general public. They are derived using guidance set by ECHA, the European Chemicals Agency, taking into account the extent of the then available data and the level of uncertainty that exists at the time (ECHA Guidance on Information Requirements and Chemical Safety Assessment. Chapter R.8: Characterisation of dose [concentration]-response for human health, Version 2.1, November 2012). At the time (May 2012), TNO, the consultant that produced the registration dossier on EEA-NH4 for AGC, derived a DNEL for workers of 0.49 mg/m3 which assumes an exposure period of 8 hours.
Since the submission of the registration dossier on EEA-NH4 to ECHA, the toxicological data base on the substance has been expanded further. The new data reduces the overall level of uncertainty regarding the potential health effects following exposure to EEA-NH4 and a new equivalent DNEL of 0.18 mg/m3 for workers can be derived.
AGC Chemicals Europe, Ltd.
Information contained in this publication (and otherwise supplied to users) is based on our general experience and is given in good faith, but we are unable to accept responsibility in respect of factors that are outside our knowledge or control. All conditions, warranties and liabilities of any kind relating to such information, expressed or implied, whether arising under statute, tort or otherwise are excluded to the fullest extent permissible in law. The user is reminded that his legal responsibility may extend beyond compliance with the information provided. Freedom under patents, copyright and registered designs cannot be assumed. ASAHIKLINTM, AMOLEATM, SURECOTM, SFCOAT and Fluon grades are general industrial grades. It is the responsibility of the purchaser to check that the specification is appropriate for any individual application. Particular care is required for special applications such as pharmaceutical, medical devices or food. Not all grades are suitable for making finished materials and articles for use in contact with foodstuffs. It is advisable to contact the AGC Chemicals Europe, Ltd. sales office for the latest position. Users of ASAHIKLINTM, AMOLEATM, SURECOTM and Fluon are advised to consult the relevant Health and Safety literature which is available from the AGC Chemicals Europe, Ltd. sales office.
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