Document 91O3D3gq8G1wX224L0gDkzGpV

JFPA01 Tables and Images Cross reference - Comment Section 6: Missing Uses Section (a) 6: Missing Uses Section (b) 1. Resin 6: Missing Uses Section (b) 1. Resin (3) Coating of metal parts of valves for chemical solutions. 6: Missing Uses Section (b) 1. Resin (5) Hoses and Tubes 6: Missing Uses Section (b) 1. Resin (7) Adsorption plates 6: Missing Uses Section (b) 2. Greases 6: Missing Uses Section (b) 2. Greases (1) Low wear, low friction and long life. Table / Image Table 0 Tonnage of parts in PFAS materials for industrial automation components. Table 1 Uses of Fluoropolymers Image 1 Example of valves for chemical solutions Table 2 Materials commonly used for hoses and tubes and their chemical and heat resistance properties Image 2 Example of precision suction plate Table 3 Uses of greases Table 4 Base Oil Table 5 Thickener Image 3 Sectional view of cylinder grease 6: Missing Uses Section (b) 2. Greases (3) High speed, high frequency, heat and water resistant. Image 4 Section view of directional control valve 6: Missing Uses Section (b) 3. Rubber, seal 6: Missing Uses Section (b) 4. Surface treatment Table 6 Use of rubber and seals Table 7 Use of surface treatment Table 8 Fluorine lubricant plating film characteristics (PFOA free) JFPA01 Tables and Images Table 0 Tonnage of parts in PFAS materials for industrial automation components. Broad category Functional property Product Applications Industry sector used Chemical name CAS 1. Resin Abrasion resistance, oil repellence, electrical insulation, water repellence, heat resistance, chemical resistance, weather resistance, cleanliness, release properties, coefficient of friction, bending strength, elasticity, nonflammability. Valves, tubes and filters Industrial facilities and equipment Medical equipment Building equipment Transport Semiconductor manufacturing Adsorption transfer, electronics. Food equipment Semiconductor manufacturing PFA 26655-00-5 FEP 25067-11-2 PTFE polyvinylidene fluoride PCTFE 9002-84-0 24937-79-9 9002-83-9 ETFE ECTFE 25038-71-5 25101-45-5 Chemical name (English) POLY[TETRAFLUOROETHYLENE-COPERFLUORO (ALKYL VINYL ETHER)] Perfluoroethylene propylene copolymer Global usage (tonnes) 949.1 212.5 Poly(tetrafluoroethylene) Polyvinylidene fluoride 430.3 2.8 Polychlorotrifluoroethylene 1.8 Poly(ethene-co-tetrafluoroethene) 3.2 poly(ethene-co-chlorotrifluoroethene) 0.4 Usage for the EU (tonnes) 148.0 33.1 67.1 0.4 0.3 0.5 0.1 2.Grease Lubrication, improved sliding properties, low coefficient of friction, heat resistance, chemical resistance, low outgassing Valves, actuators and filters Industrial facilities and equipment Building equipment Transport Vessels Semiconductor manufacturing PTFE 9002-84-0 Poly(tetrafluoroethylene) 7.7 1.2 PFPE 60164-51-4 etc. Perfluoropolyether 18.3 2.9 JFPA01 Tables and Images PVDF/***. 9011-17-0 POLY(VINYLIDENE FLUORIDE-CO- 54.9 8.6 HEXAFLUOROPROPYLENE). Heat and hot water resistance, 2,2-Bis(4- abrasion and corrosion Industrial facilities and Bisphenol AF 1478-61-1 hydroxyphenyl)hexafluoropropane 0.5 0.1 resistance, improved sliding equipment Benzyl(triphenyl)phosphonium 4- properties, environmental General Medical equipment 75768-65-9 [1,1,1,3,3,3-hexafluoro-2-(4- 0.4 0.1 resistance, excellent elongation hydraulic and Building equipment hydroxyphenyl)propan-2-yl]phenolate tracking, durability, flame pneumatic Transport 1-Propene, 1,1,2,3,3,3-hexafluoro-, resistance, low water 3. Rubber, absorption, low moisture equipment Home appliances 25190-89-0 polymer with 1,1-difluoroethene and 24.8 3.9 seals permeability, chemical Ships 1,1,2,2-tetrafluoroethene resistance, low outgassing. PFA 26655-00-5 POLY[TETRAFLUOROETHYLENE-CO- 1.8 0.3 PERFLUORO (ALKYL VINYL ETHER)] PTFE 9002-84-0 Poly(tetrafluoroethylene) 39.0 6.1 Fluororubber 64706-30-5 etc. Family of Fluorocarbon-based Fluoroelastomer Materials 79.7 12.4 Plasma resistant properties FFKM 26425-79-6, etc. Perfluorelastomers 8.9 1.4 FEPM 27029-05-6 Tetrafluoroethylene-propylene copolymer 1.8 0.3 4.Surface treatment Low coefficient of friction, electrical insulation, heat resistance, improved sliding properties, chemical resistance, mould release, improved weather resistance Plating Low coefficient of friction, improved sliding properties, mould release Actuators, boards and product outer surfaces actuator Industrial facilities and equipment Medical equipment Transport Home appliances Industrial facilities and equipment PTFE PTFE 9002-84-0 Poly(tetrafluoroethylene) 9002-84-0 Poly(tetrafluoroethylene) 1.9 0.3 1.8 0.3 JFPA01 Tables and Images Table 1 Uses of Fluoropolymers Examples showing the use of Products and parts body diaphragm Sealing parts Hoses and tubes electronics fluoropolymer PFA FEP PTFE PVDF PCTFE ETFE ECTFE PTFE PFA PTFE PFA PTFE adsorption transfer PCTFE hydraulic and pneumatic equipment (Product group) directional control equipment drive (engine) Cleaning equipment Pressure control equipment Pumps, sensors All hydraulic and pneumatic equipment Piping and fittings equipment Industrial electrical and electronic control equipment Vacuum equipment functional property Abrasion resistance, oil repellence, electrical insulation, water repellence, heat resistance, chemical resistance, weather resistance, cleanliness, release properties, coefficient of friction, bending strength, elasticity, non-flammability. Heat resistance, chemical resistance, cleanliness, bending strength, elasticity, non-flammability Heat resistance, chemical resistance, cleanliness, bending strength, elasticity, non-flammability Excellent dielectric properties, low dielectric constant for microwave permeability, low dielectric loss tangent, non-flammable Cleanliness, mould release, coefficient of friction, bending strength, elasticity, Table 2 Materials commonly used for hoses and tubes and their chemical and heat resistance properties material properties organic solvent PTFE A PU B PP A PA B A: Very good, B: Good, C: Normal, D: Poor alkali A C A B acid heat-resisting property A 260C C 80C A 100C C 120C Table 3 Uses of greases Examples showing the use (Products and parts) fluoropolymer Sliding parts Sliding and fixed sealing section PTFE PFPU hydraulic and pneumatic equipment (Product group) directional control equipment drive (engine) Cleaning equipment pump Vacuum equipment functional property Lubrication, improved sliding properties, low friction, wear resistance, heat resistance, individual lubrication, oxidation resistance, chemical resistance, cleanliness, flame resistance, low outgassing, water resistance, low temperature resistance, affinity to contact materials. JFPA01 Tables and Images Table 4 Base Oil mineral oil heat-resisting property D low temperature characteristics D Affinity for rubber and resins. C A: very good, B: excellent, C: good, D: normal, E: poor. synthetic oil silicone oil B A A PEFE A A A Table 5 Thickener (Max. operating temperature C) heat-resisting property water resistance machine-stabilized (seizure, high speed/high frequency, chemical resistant) A: very good, B: excellent, C: good, D: normal, E: poor. soap-based thickener Li-based 130 C B C Non-soap thickener urea 180 B A B PTFE 260 A A A Table 6 Use of rubber and seals examples showing the use (Products and parts) Exercise and immobilisation sealing section fluoropolymer PTFE PVDF/***. Bisphenol AF hydraulic and pneumatic equipment (Product group) General hydraulic and pneumatic equipment functional property Lubrication, improved sliding properties, low friction, heat and chemical resistance, Table 7 Use of surface treatment examples showing the use (Products and parts) Sealing section, sliding section, electronic board. fluoropolymer PTFE hydraulic and pneumatic equipment (Product group) directional control equipment drive (engine) Vacuum equipment Piping equipment and components functional property Self-lubricating, low friction, abrasion and damage resistance, adhesion, sound deadening effect, water and oil repellent, conductive and anti-static. JFPA01 Tables and Images Table 8 Fluorine lubricant plating film characteristics (PFOA free) Comparative Table of Fluorine Lubricant Plating Film Characteristics (PFOA Free) Plating type Processing type electroless nickel Barrel 10 vol% fluorine lubricated plating Barrel 20 vol% fluorine lubricated plating Barrel Coating layer (wt%) nickel (Ni) phosphorus 90.0~92.0 8.0~10.0 85.0~87.0 8.5~10.5 83.0~86.0 7.5~11.0 PTFE 2.0~4.0 ( 7.0~13.0vol%) 6.5~ 9.0 ( 20.0~26.0vol%) Hardness (Hv) Surface roughness*1 As plated After baking Ra Rz. 500~550 Max1000 350~450 Max680 0.09 0.66 300~350 Max520 1.52 6.31 Contact As plated 73.6 angle (degree) *2 300C 1h 101.9 103.2 107.8 111.6 Static friction coefficients*3 (reference values) As plated 300C 1h Dynamic As plated friction coefficient*4 (reference 300C 1h value) Wearability*5 (mg) (Reference value) 0.189 0.152 108 0.111 0.11 85.2 0.13 0.113 19.8 20 vol% fluorine lubricated plating Rack 83.0~86.0 7.5~11.0 5.5 ~7.5 ( 17.0~23.0vol%) 250~300 Max540 0.13 0.89 108.2 108.6 0.107 30 vol% fluorine lubricated plating Rack 77.0~83.0 7.5~11.0 9.5 ~12.5 ( 27.0~33.0vol%) 200~250 Max340 0.12 1.14 109.7 110.7 0.102 0.101 0.092 45.7 4.3 JFPA01 Tables and Images 1 Measurement material SUS304 Plating thickness 5m Surface roughness: Ra=0.03m Rz=0.3m 2 Measuring material SUS304 Plating thickness: 10m 3 Friction coefficient measurement conditions Material/Halsell plate Indenter 10SUSBall Vertical load: 500g Travel speed: 50mm/min Travel distance: 50mm Plating thickness: 10m (The value varies depending on the indenter material and loading conditions.) 4 Wear test measurement conditions Material: Stainless steel disk Mating material: 10SUSBall Weight: 1kg Rotation distance: 5000m Plating thickness: 10m (Values vary depending on mating material and weighting conditions.) 5 The average size of PTFE particles is 0.2. JFPA01 Tables and Images Image 1 Example of valves for chemical solutions Image 2 Example of precision suction plate. JFPA01 Tables and Images Image 3 Sectional view of cylinder grease JFPA01 Tables and Images Image 4 Section view of directional control valve grease