Document 7MQvNdx2epEjVnL9bM02Kb4N8
+------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- +
Date Printed: 10-07-1996 Page 1 LA-MAR-KA MSDS for METHYLENE CHLORIDE
+ - ~------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ +
1 -PRODUCT IDENTIFICATION
PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.:
CAS NO
NIOSH/RTECS NO.: PRODUCT USE:
METHYLENE CHLORIDE DICHLOROMETHANE; METHYLENE CHLORINATED HYDROCARBONS CH2CL2 84.93 75-09-2 PA8 050000 LABORATORY REAGENT
DICHLORIDE;
METHANE DICHLORIDE
CHEMTREC # (800) 424-9300 LA-MAR-KA, INC.
10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814
EFFECTIVE: 09/14/89 REVISION #06
ISSUED: 04/14/90 REVIEWED 1-1-95
PRECAUTIONARY LABELING
LA-MAR-KA LABELING SYSTEM
HEALTH
- 3 SEVERE (CANCER CAUSING)
FLAMMABILITY - 1 SLIGHT
REACTIVITY
- 1 SLIGHT
CONTACT
- 2 MODERATE
LABORATORY PROTECTIVE EQUIPMENT
GOGGLES Sc SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
U.S. PRECAUTIONARY LABELING
WARNING
MAY BE FATAL IF SWALLOWED OR INHALED. CAUSES IRRITATION. MAY BE HARMFUL IF
ABSORBED THROUGH SKIN. NOTE: REPORTED AS CAUSING CANCER IN LABORATORY ANIMALS. EXERCISE DUE CARE. EXCEPTIONAL CONTACT HAZARD: READ MATERIAL SAFETY DATA
SHEET KEEP AWAY FROM HEAT, MOISTURE, AND DIRECT SUNLIGHT. AVOID CONTACT WITH EYES, SKIN, CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL, SOAK UP WITH SAND OR EARTH.
PRECAUTIONARY LABELING (CONTINUED)
INTERNATIONAL LABELING
HARMFUL BY INHALATION. POSSIBLE RISKS OF IRREVERSIBLE EFFECTS. AVOID CONTACT WITH SKIN.
DO A 056481 CONFIDFNTT AL
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- +
Date Printed: 10-07-1996 Page 2 LA-MAR-KA MSDS for METHYLENE CHLORIDE + _ ---------------------------------------------------------------------------------------------------------------------------------------------------------------- +
1 -PRODUCT IDENTIFICATION (continued)
LA -MAR-KA STORAGE COLOR CODE: BLUE (HEALTH)
2 -COMPONENTS
COMPONENT METHYLENE CHLORIDE
CAS NO. 75-09-2
WEIGHT % 98-100
OSHA/PEL 500 PPM
ACGIH/TLV 50 PPM
3 -PHYSICAL DATA
BOILING POINT: 40 C (104 F) (AT 760 MM HG)
VAPOR PRESSURE (MMHG): 350 (20 C)
MELTING POINT: -95 C (-139 F) (AT 760 MM HG)
VAPOR DENSITY (AIR=1): 2.9
SPECIFIC GRAVITY: 1.32 (H20=l)
EVAPORATION RATE: 27.5 (BUTYL ACETATE = 1)
.UBILITY (H20) : MODERATE (1-10%)
% VOLATILES BY VOLUME: 100 (21 C)
PH: N/A
ODOR THRESHOLD (P.P.M.): N/A
PHYSICAL STATE: LIQUID
COEFFICIENT WATER/OIL DISTRIBUTION: N/A
APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID. ETHER-LIKE ODOR.
4 -FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (CLOSED CUP) : N/A
NFPA 704M RATING: 2-1-0
AUTOIGNITION TEMPERATURE: N/A
FLAMMABLE LIMITS: UPPER - 19 %
LOWER - 12 %
FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE
DO A 056482 CONFIDENTIAL
+------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- +
Date Printed: 10-07-1996 Page 3 LA-MAR-KA MSDS for METHYLENE CHLORIDE
+ - ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------+
4 -FIRE AND EXPLOSION HAZARD DATA (continued)
WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
UNUSUAL FIRE & EXPLOSION HAZARDS CONCENTRATED VAPOR CAN BE IGNITED BY A HIGH INTENSITY IGNITION SOURCE. VAPOR MAY FORM FLAMMABLE MIXTURE IN ATMOSPHERE THAT CONTAINS A HIGH PERCENTAGE OF OXYGEN. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
TOXIC GASES PRODUCED HYDROGEN CHLORIDE, PHOSGENE, CHLORINE, CARBON MONOXIDE, CARBON DIOXIDE
EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED.
EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED.
5 -HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE (TLV/TWA) : 174 MG/M3
(50 PPM)
^ RT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT (PEL):
(500 PPM)
PEL (CEILING) = 1000 PPM.
TOXICITY OF COMPONENTS
ORAL RAT LD50 FOR METHYLENE CHLORIDE
INTRAPERITONEAL MOUSE LD50 FOR METHYLENE CHLORIDE
SUBCUTANEOUS MOUSE LD50 FOR METHYLENE CHLORIDE
INHALATION-30MIN RAT LC50 FOR METHYLENE CHLORIDE
CARCINOGENICITY: NTP: NO
IARC: YES
Z LIST:
NO
OSHA REG:
2136 MG/KG
437 MG/KG
6460 MG/KG 88 G/M3 NO
CARCINOGENICITY THIS SUBSTANCE IS LISTED AS AN IARC PROBABLE HUMAN CARCINOGEN (GROUPS 2A
AND 2B).
REPRODUCTIVE EFFECTS TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY BE MUTAGENIC.
EFFECTS OF OVEREXPOSURE
INHALATION:
HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, WEAKNESS, FATIGUE, IRRITATION OF UPPER RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM DEPRESSION, CAUSES METHEMOGLOBULIN FORMATION IN THE BLOOD, PULMONARY EDEMA, UNCONSCIOUSNESS, AND MAY BE FATAL
^-
DO A 056483 CONF T DENT I A!
+------------------ ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Date Printed: 10-07-1996 Page 4
LA-MAR-KA MSDS for METHYLENE CHLORIDE
+------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ +
5 -HEALTH HAZARD DATA (continued)
SKIN CONTACT:
IRRITATION, MAY BE HARMFUL, PROLONGED CONTACT MAY CAUSE DERMATITIS
EYE CONTACT:
IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE
SKIN ABSORPTION: NONE IDENTIFIED
INGESTION:
HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, WEAKNESS, FATIGUE, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, CAUSES METHEMOGLOBULIN FORMATION IN THE BLOOD, UNCONSCIOUSNESS, AND MAY BE FATAL
CHRONIC EFFECTS: DAMAGE TO LIVER, KIDNEYS, LUNGS, BLOOD, CENTRAL NERVOUS SYSTEM
TARGET ORGANS RESPIRATORY SYSTEM, LUNGS, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM,
LIVER, KIDNEYS, EYES, SKIN
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE CARDIOVASCULAR DISORDERS, HEART DISORDERS, LIVER OR KIDNEY DISORDERS,
( CENTRAL NERVOUS SYSTEM DISORDERS, HEAVY DRINKERS, HEAVY SMOKERS
PRIMARY ROUTES OF ENTRY INHALATION, INGESTION, SKIN CONTACT, EYE CONTACT, ABSORPTION
EMERGENCY AND FIRST AID PROCEDURES
INGESTION:
CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN.
SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE.
EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO
EXTREMELY HAZARDOUS SUBSTANCE: NO
CERCLA HAZARDOUS SUBSTANCE:
YES CONTAINS 2-BUTANONE (RQ = 5000 LBS)
L.
DO A 056484 CONFIDENTIAL
+ *"
----------------------- -- ------------------------------------------
-- -- -- -- - -- -- -- -- -- -- -- -- - -- - -- -- -- -- -- -- -- - -- -- - - -+
LA-MAR-KA MSDS for METHYLENE CHLORIDE
Date Printed: 10-07-1996 Page 5
+ - ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------+
5 -HEALTH HAZARD DATA (continued)
SARA 313 TOXIC CHEMICALS:
YES CONTAINS DICHLOROMETHANE (METHYLENE
CHLORIDE)
GENERIC CLASS:
C02
TSCA INVENTORY:
YES
STATE LISTS: FOR PRODUCTS SOLD IN THE STATE OF CALIFORNIA, THE STATE REQUIRES
THAT WE PROVIDE TO USERS AND THEIR EMPLOYEES THE FOLLOWING MESSAGE: WARNING:
THIS PRODUCT IS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
6 -REACTIVITY DATA
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID:
HEAT, FLAME, OTHER SOURCES OF IGNITION, MOISTURE, LIGHT
INCOMPATIBLES:
ALKALI METALS, STRONG OXIDIZING AGENTS, STRONG BASES, OXIDES OF NITROGEN, ZINC, ALUMINUM, WATER, MAGNESIUM, AMINES, PLASTICS, RUBBER, SODIUM, POTASSIUM
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, PHOSGENE, CHLORINE, CARBON ( MONOXIDE, CARBON DIOXIDE
7 -SPILL & DISPOSAL PROCEDURES
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS.
TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE
INTO CONTAINER FOR LATER DISPOSAL. FLUSH SPILL AREA WITH WATER.
DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER:
U080 (TOXIC WASTE)
8 -INDUSTRIAL PROTECTIVE EQUIPMENT
VENTILATION:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.
RESPIRATORY (
V
PROTECTION:
RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS 100 PPM, A SELF-CONTAINED BREATHING APPARATUS
ABOVE IS
DO A 056485 CONF T DFNT J A[.
+-------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- +
Date Printed: 10-07-1996 Page 6 LA-MAR-KA MSDS for METHYLENE CHLORIDE
+ - ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- +
8 -INDUSTRIAL PROTECTIVE EQUIPMENT (continued)
EYE/SKIN PROTECTION:
ADVISED.
SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, POLYVINYL ALCOHOL GLOVES ARE RECOMMENDED.
9 -STORAGE AND HANDLING PRECAUTIONS
LA-MAR-KA STORAGE COLOR CODE: BLUE (HEALTH)
STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA. KEEP CONTAINERS OUT OF SUN AND AWAY FROM HEAT.
SPECIAL PRECAUTIONS MATERIAL IS HYGROSCOPIC.
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION
IESTIC (D.O.T.)
PROPER SHIPPING NAME: DICHLOROMETHANE (AIR ONLY)
HAZARD CLASS:
ORM-A
UN/NA: UN1593 REPORTABLE QUANTITY: 1000 LBS.
LABELS: NONE
REGULATORY REFERENCES: 49CFR 172.101; 173.500; 173.510
INTERNATIONAL (I.M.O.)
PROPER SHIPPING NAME: DICHLOROMETHANE
HAZARD CLASS:
6.1
UN: UN1593
MARINE POLLUTANTS: NO
LABELS: HARMFUL - STOW AWAY FROM FOOD STUFFS
REGULATORY REFERENCES: 49CFR 172.102; PART 176;
I.M.O. PAGE: 6118 PACKAGING GROUP: III
I MO
AIR (I.C.A.O.)
PROPER SHIPPING NAME: DICHLOROMETHANE
HAZARD CLASS:
6.1
UN: UN1593
PACKAGING GROUP:
LABELS: HARMFUL - STOW AWAY FROM FOOD STUFFS
REGULATORY REFERENCES: 49CFR 172.101; 173.6; PART 175; ICAO/IATA
III
U.S. CUSTOMS HARMONIZATION NUMBER: 29031200000
DO A 05648A CONFIDENTIAL
+------------
"
r
LA-MAR-KA
MSDS for METHYLENE
-- --------- -------------- --------------------------------------------------------------------------------------- ------------------- ------------------- --------- ------------------------------------------------------------------------------------------------------------4
Date Printed: 10-07-1996 Page 7
CHLORIDE
+ - ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- 4
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued)
EPA/TSCA EXPORT NOTIFICATION YES
N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED
THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF
THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS
PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE
HAZARDOUS MATERIALS INFORMATION SYSTEM.
THIS DOCUMENT IS INTENDED ONLY AS A
GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON
TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER
IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL
FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING
INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT
WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES.
EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS
CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO
VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF
USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS.
LA-MAR-KA
WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL.
L\-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO
THE PRODUCT SUPPLIED HEREUNDER, FOR A PARTICULAR PURPOSE.
ITS MERCHANTABILITY OR ITS FITNESS
THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN
DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT
HEEDED.
READ ALL PRECAUTIONARY INFORMATION.
AS NEW DOCUMENTED GENERAL
SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE
THIS MATERIAL SAFETY DATA SHEET.
APPROVED BY LA-MAR-KA, INC.
OO A 056487 CONFIDFNTTAl
