Document 70Ra5LzE01aB8jgQ7553yVwZV

Report Prepared by: Report Approved by: NPDES Pretreatment Compliance Sampling Inspection Report Friesland Campina Ingredients North America, Inc. (FCINA) 40196 State Highway 10 Delhi, NY 13753 NYP002786 & NY0262838 June 29-30, 2022 THUAN TRAN Digitally signed by THUAN TRAN Date: 2022.08.25 08:28:51 -04'00' ________________________________ Thuan Tran; Physical Scientist Date: ______ August 15, 2022_______ Digitally signed by PHILIP PHILIP COCUZZA COCUZZA _________________D_ate_: 2_0_22_.08_.2_5_08_:5_3:5_8_-0_4'0_0'_ Phil Cocuzza, Chief Monitoring Operations Section Date: ________________ FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 1.0 OBJECTIVE On June 29-30, 2022, at the request of the Enforcement and Compliance Assurance Division (ECAD), a Pretreatment Compliance Sampling Inspection (CSI) and a National Pollutant Discharge Elimination System (NPDES) CSI were conducted at Friesland Campina Ingredients North America, Inc (FCINA). The objectives of the Pretreatment CSI and the NPDES CSI were to gather information necessary to determine if the facility is in compliance with the Village of Delhi Industrial User Agreement (EPA ICIS No. NYP002786) and their NPDES Permit; NY0262838, as well as other state and federal regulations. 2.0 KEY PARTICIPANTS Listed below are key inspection participants and contact information, grouped by organization. U.S. Environmental Protection Agency Thuan Tran, Lead Inspector 732-321-4455, email: tran.thuan@epa.gov Robert Morrell, Geologist Neal Johansen, Physical Scientist Friesland Campina Ingredients North America, Inc. (FCINA) Mark Roach, FCINA Plant Engineer 607-746-0198, email: mark.roach@frieslandcampina.com Bob Bernhardt, Maintenance Manager Marc Hammond, Maintenance Supervisor 3.0 FACILITY DESCRIPTION 3.1 General Information Friesland Campina Ingredients North America (FCINA), Inc. is located at 40196 State Highway 10, Delhi, New York and began operations approximately in 1982. FCINA manufacturing occupies an area of 60,000 square feet. FCINA is categorized as Standard Industrial Classification (SIC) 2023 - Dry, Condensed, and Evaporated Dairy Products and the North American Industry Classification System (NAICS) 311514 - Dry, Condensed and Evaporated Dairy Product Manufacturing. FCINA employs 116 personnel and operates 24 hours/day, 7 days/week, 365 days/year with three (3) shifts; 7:00AM - 3:30PM, 3:30PM - 11:00PM, and 11:00PM - 7:00AM. FCINA produces hydrolyzed proteins by mixing pig pancreases with water and casein that undergoes digestion and evaporation. Toluene is added to some products to stop bacterial growth. Enzymes are added to certain products and then deactivated to stop the reaction. The facility manufactures ingredients for different types of baby formulas, as specified by the customers to produce different formulas. FCINA also manufactures Proyield-protein Page 2 of 7 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 hydrolysates that are used in biopharmaceutical application to enhance cell culture growth, and Stedygro-protein hydrolysates that are used in micro diagnostic for Agar growth in laboratories for microbial growth. 3.2 Process Information Raw materials (casein, whey and soy) received at the facility are randomly checked by various testing methods to determine if it meets the facility quality standards. Some raw materials are tested for microbiological contamination, as well. FCINA is a batch manufacturing operation. Raw materials and treated well water are added into a tank/vessel for mixing. The homogenized batched mixture goes through a digestion process. Then, it is transferred into a separate tank for heat pasteurization. After the pasteurization process, the product goes through a filtration system. The filtered product then goes through an evaporation process to remove excess water, followed by drying. The product is packaged and stored in the warehouse or shipped to customers. Groundwater from 4 private wells is used in the manufacturing processes and cleaning, and as non-contact cooling water. The groundwater is pumped into a water storage tank. From the storage tank, the well water is used as non-contact cooling water for heat transfer. The noncontact cooling water discharges via Outfall 001 under the NPDES Permit. A proportion of the well water is diverted for further treatment prior to use in the manufacturing processes and cleaning. Well water is treated through a media filtration system to remove any suspended solids in the water column. The filtrate is disinfected by ultraviolet light (UV) unit. Once disinfected, the treated water is directed to the manufacturing operation where it is use in the batch operation, cleaning process, some laboratory testing, hand washing and drinking. Generated wastewater from the cleaning process and laboratory testing is collected in the process wastewater receiving pit. A lift pump forces the process wastewater across Platner Brook into the equalization (EQ) chamber of the On-Site Process Wastewater Pretreatment System. An anti-foaming agent and a pH control solution are added to the process wastewater. From the EQ chamber, the process wastewater is pumped to the buffer tank. The buffer tank is mainly a holding/storage tank that provides the On-Site Process Wastewater Pretreatment System the capability to receive emergency process wastewater without having to shut down the manufacturing operation. From the buffer tank, the wastewater is pumped into the aeration tanks with fine bubble diffusers. Alum is added into the aeration tank to promote coagulation. The mixed liquor suspended solids (MLSS) in the aeration tanks are conveyed into the aerated Membrane Bioreactors (MBRs). Water within the MLSS is allowed to pass through the fixed plastic media as permeate which leaves a concentrated sludge slurry behind in the MBRs. The permeate is stored in the permeate holding tank. From the holding tank, the pretreated effluent is piped across Platner Brook to the monitoring manhole that houses a Palmer-Bowles flow measuring device with an Page 3 of 7 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 ultrasonic flow sensor. Downstream of the discharged pipe, FCINA pretreated effluent combines with Saputo Dairy Foods pretreated effluent. The combined effluent flows to the Village of Delhi Wastewater Treatment Plant (WWTP) for further treatment. The concentrated sludge slurry in the MBRs is either wasted to the sludge digester as Waste Activated Sludge (WAS) or returned to the aeration tanks as Return Activated Sludge (RAS). The WAS is reclaimed for beneficial reuse. 3.3 Facility Self-Monitoring Information The Village of Delhi WWTP conducts sampling of the FCINA pretreated discharged effluent to determine if FCINA is in compliance wth their Industrial User Agreement. A portable automatic composite sampler is station at the monitoring location. Samples are collected by the Village of Delhi WWTP personnel and are shipped to Phoenix Environmental Laboratories, Inc. located in Manchester, Connecticut. The samples are analyzed for 5-day carbonaceous Biochemical Oxygen Demand (cBOD5), Total Suspended Solids (TSS), Ammonia (NH3), and Phosphorus. Once the Village of Delhi WWTP receives the analytical data, a copy is provided to FCINA. Phoenix Environmental Laboratories, Inc provides sample containers to FCINA for the noncontact cooling water discharge. FCINA QC personnel collects the samples for 5-day Biochemical Oxygen Demand (BOD5) and Phosphorus. The samples are shipped to Phoenix Environmental Laboratories, Inc. for analysis to determine if the facility is in compliance with their NPDES Permit; NY0262838 4.0 EPA SAMPLING/INSPECTION ACTIVITIES 4.1 Sampling Activities An ISCO automatic composite sampler was programmed to take 96 sample aliquots during the 24-hour sampling event of the pretreated discharged effluent at the monitoring location in the wooden shred. The 24-hour composite sample was collected and analyzed for cBOD5, TSS, NH3 and phosphorus. On-site grab samples were collected and analyzed for pH and Total Residual Chlorine (TRC). In addition, grab samples were collected of the non-contact cooling water discharged effluent for compliance with their NPDES Permit. Samples were analyzed for 5-day Biochemical Oxygen Demand (BOD5) and Phosphorus. Furthermore, on-site grab samples were collected and analyzed for pH and temperature at the monitoring locations. As part of the permit required conditions, temperature readings were taken at Outfall 001 to the West Branch of the Delaware River, upstream and downstream of the outfall. Page 4 of 7 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 All sample containers, preservation techniques and holding times were in accordance with USEPA requirements specified in 40 CFR Part 136. Signed and dated custody seals were placed across the lids and along the sides of the sample containers. The custody sealed sample containers were placed inside plastic sample bags and sealed. All samples were transported on ice to the USEPA Laboratory in Edison, New Jersey for analysis. The chainof-custody was emailed to the USEPA Laboratory in Edison, New Jersey, to begin the checkin process prior to arrival. Flow data were provided by FCINA for the pretreated discharge effluent from the On-Site Process Wastewater Pretreatment System and the non-contact cooling water discharge to the West Branch of the Delaware River. The flow monitoring devices for the pretreated discharge effluent and the non-contact cooling water discharge were last calibrated on April 10, 2022. . Split samples were collected and given to the facility representative. 4.2 Inspection Activities A Pretreatment Compliance Sampling Inspection (CSI) of the On-Site Process Wastewater Pretreatment System and a NPDES CSI of the non-contact cooling water discharge at FCINA were conducted on June 29-30, 2022. The inspectors met with Mark Roach, FCINA Plant Engineer. Inspector's credentials were presented, and business cards were provided. The facility's representative was explained that the inspection purpose with supporting on-site activities was to determine if FCINA is in compliance with the Industrial User Agreement and the NPDES Permit, NY0262838, as well as other state and federal regulations. Due to the simultaneous sampling inspections at two (2) other facilities, supporting on-site activities were limited. Supporting on-site activities consist of collecting samples of the pretreated discharge effluent and the non-contact cooling water discharged effluent, observing and evaluating the monitoring locations, observing and evaluating the flow monitoring devices, touring the OnSite Process Wastewater Pretreatment System, as well as limited interview with the facility's representative. The facility's representatives were briefed on the inspection activities throughout the inspection and during the brief closing conference. Page 5 of 7 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 5.0 ANALYTICAL RESULTS Parameters Flow cBOD5 TSS Ammonia Phosphorus pH TRC Friesland Campina Ingredients North America, Inc. (FCINA) Inspection Dates: June 29-30, 2022 On-Site Process Wastewater Pretreatment System Discharge Units User Agreement Limits EPA Results 30-day Avg. 1-day Max. GPD 275,000 350,000 208,995.48 mg/l 200 275 2.10 mg/l 200 275 U mg/l 10 15 U mg/l 20 20 1.41 SU 7.0 - 9.0 8.39 mg/l 0.05 0.04 Friesland Campina Ingredients North America, Inc. (FCINA) Sampling Date: June 30, 2022 Non-Contact Cooling Water Discharge Parameters Units NY0262838 Limits EPA Results 30-day Avg. 1-day Max. Flow GPD 720,000 Monitor 569,646 BOD5 mg/l N/A Monitor U Phosphorus - Effluent mg/l N/A Monitor 0.055 Phosphorus - Influent mg/L N/A Monitor U Temperature - Outfall F (C) Monitor 70 60.8 (16C) Temperature - Upstream F (C) Monitor Monitor 69.8 (21C) Temperature - Downstream F (C) Monitor Monitor 68.9 (20.5C) pH SU 6.0 - 8.5 7.15 Note: U- The analyte was not detected at or above the reporting limit. 6.0 FINDINGS 6.1 Sampling Result Findings The EPA analytical results obtained during this inspection are within the acceptable limits. 6.2 Inspection Findings In addition to the sampling event, a limited inspection of the facility operations was conducted as discussed in Section 4.2 above. Page 6 of 7 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 7.0 ATTACHMENTS Attachment #1. An overview map shows FCINA property boundary. Attachment #2. Well water is treated and disinfected. Attachment #3. The facility manufacturing operation is through batch process. Attachment #4. Process wastewater is pretreated by the On-Site Process Wastewater Pretreatment System before discharging to the Village of Delhi WWTP Attachment #5. The Chain of Custody for Samples was submitted and received by the USEPA Region 2 Laboratory on Thursday, June 30, 2022. Attachment #6. The Analytical Data from the FCINA sampling inspections were received on Friday, July 25, 2022. 8.0 PHOTOGRAPHS Photo #1. Samples were collected of the On-Site Process Wastewater Pretreatment System effluent at the monitoring manhole. Photo #2. Grab samples were collected of the non-contact cooling water from the monitoring manhole. Photo #3. A phosphorus grab sample was collected at the influent monitoring location before well water is treated. Photo #4. No discharges were observed from the stormwater outfalls. Page 7 of 7 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 7.0 Attachments Attachment #1. An overview map shows FCINA property boundary on both sides of Platner Brook. Wastewater Pre-Treatment Plant Approximate Property Boundary Attachment #2. Well water is treated and disinfected before it can be use in the manufacturing processes. Flow Diagram - Treated water used in the plant Water Wells Water Storage Tank (125k gal) Filtration (5 micron) UV Treatment Manufacturing Processes Attachment #3. Manufacturing operation at FCINA is batch process. Typical manufacturing Process Flow Diagram - FCINA, Delhi Mixing - Raw materials added with water Digestion - Mixed product transferred to a tank and heated Pasteurization Filtration Evaporation Drying Packaging Warehouse - send to customer Note: Our manufacturing process is considered a "batch process". We do not have a dedicated "processing line" for each product we produce. Equipment is cleaned after each batch and used for the next product. Multiple pasteurizations, filtrations and evaporations may be required based on the product being produced. This diagram depicts a typical manufacturing process for one of our hydrolyzed protein products. Attachment #4. Process wastewater is treated by the On-Site Process Wastewater Pretreatment System. Wastewater pre-treatment flow diagram - FrieslandCampina, Delhi Wastewater effluent from the manufacturing plant Equalization Tank Buffer Tank Aeration tanks Village POTW via pump station and transmission line MBR's Attachment #5. Samples were checked into the USEPA Laboratory in Edison, New Jersey on Thursday, 6/30/2022. Attachment #6. Analytical Data for the FCINA sampling inspections were recieved on Friday, 7/25/2022. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory 2890 Woodbridge Avenue Edison , New Jersey 08837 732-906-6886 Phone 732-906-6165 Fax July 12, 2022 Thuan Tran Monitoring & Assessment Branch LSASD/MAB Edison, NJ 08837 RE: Friesland Campina - 2206033 Enclosed are the results of analyses for samples received by the laboratory on 06/30/2022. The signature below reflects the laboratory's approval of the reported results. If you have any questions concerning this report, please refer to Project Number 2206033 and contact the laboratory. Sincerely, John R. Bourbon Chief, LSASD/LB Project Narrative: UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 The National Environmental Laboratory Accreditation Conference Institute (TNI) is a voluntary environmental laboratory accreditation association of State and Federal agencies. TNI established and promoted a National Environmental Laboratory Accreditation Program (NELAP) that provides a uniform set of standards for the generation of environmental data that are of known and defensible quality. The EPA Region 2 Laboratory is NELAP accredited. The Laboratory tests that are accredited have met all the requirements established under the TNI Standards. Condition Comments None Comment(s): The "Sample Analysis Date and Time" is included in the results section for any analyte with a prescribed holding time of 72 hours or less. Data Qualifier(s): U- The analyte was not detected at or above the Reporting Limit. J- The identification of the analyte is acceptable; the reported value is an estimate. K- The identification of the analyte is acceptable; the reported value may be biased high. L- The identification of the analyte is acceptable; the reported value may be biased low. NJ- There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. The reported value is an estimate. U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 1 of 9 Reporting Limit(s): UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 The Laboratory was able to achieve the appropriate limit for each analyte requested. Field ID Pretreated Discharge - Comp. Outfall 001 - Grab Influent - Grab SUMMARY REPORT FOR SAMPLES Laboratory ID 2206033-01 2206033-02 2206033-03 Matrix Aqueous Aqueous Aqueous Date Sampled 06/30/2022 08:55 06/30/2022 09:58 06/30/2022 10:13 Date Received 06/30/2022 17:00 06/30/2022 17:00 06/30/2022 17:00 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 2 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Analysis Ammonia [As N] Biochemical Oxygen Demand Biochemical Oxygen Demand, Carb. Phosphorus Residue, Non-Filterable SUMMARY REPORT FOR METHODS Method EPA 350.1 SOP C-80 Rev 2.7 SM 5210B SOP C-21 Rev 2.7 SM 5210B SOP C-21 Rev 2.7 EPA 365.1 SOP C-68 Rev 2.7 SM 2540D SOP C-33 Rev 3.7 Certification NELAP NELAP NELAP NELAP NELAP Matrix Aqueous Aqueous Aqueous Aqueous Aqueous U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 3 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Analyte Field ID: Pretreated Discharge - Comp. Sanitary Ammonia [As N] Biochemical Oxygen Demand, Carb. Phosphorus Total Suspended Solids Field ID: Outfall 001 - Grab Sanitary Biochemical Oxygen Demand Phosphorus Field ID: Influent - Grab Sanitary Phosphorus Result Qualifier Reporting Limit Units Batch Sample ID: 2206033-01 Date and Time of Analysis* --- U 0.100 mg/L B207008 2.10 2.00 mg/L B207002 07/06/2022 07:44 1.41 0.0500 mg/L B207039 --- U 10.0 mg/L B207005 Sample ID: 2206033-02 --- U 2.00 mg/L B207001 07/06/2022 07:08 0.0550 0.0500 mg/L B207039 Sample ID: 2206033-03 --- U 0.0500 mg/L B207039 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 4 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Sanitary - Quality Control Analyte Batch B207001 Blank (B207001-BLK1) Biochemical Oxygen Demand LCS (B207001-BS1) Biochemical Oxygen Demand LCS (B207001-BS2) Biochemical Oxygen Demand LCS (B207001-BS3) Biochemical Oxygen Demand Duplicate (B207001-DUP1) Biochemical Oxygen Demand Matrix Spike (B207001-MS1) Biochemical Oxygen Demand Matrix Spike Dup (B207001-MSD1) Biochemical Oxygen Demand Batch B207002 Blank (B207002-BLK1) Biochemical Oxygen Demand, Carb. LCS (B207002-BS1) Biochemical Oxygen Demand, Carb. Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 2.00 mg/L 168 mg/L 198.0 84.6 84.6-115.4 173 mg/L 198.0 87.4 84.6-115.4 173 mg/L 198.0 87.4 84.6-115.4 Source: 2206033-02 --- U 2.00 mg/L ND 25 Source: 2206033-02 281 2.00 mg/L 264.0 ND 106 75-125 Source: 2206033-02 262 2.00 mg/L 237.6 ND 110 75-125 6.81 200 --- U 2.00 mg/L 176 mg/L 198.0 88.8 84.6-115.4 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 5 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Sanitary - Quality Control Analyte Batch B207002 LCS (B207002-BS2) Biochemical Oxygen Demand, Carb. LCS (B207002-BS3) Biochemical Oxygen Demand, Carb. Duplicate (B207002-DUP1) Biochemical Oxygen Demand, Carb. Matrix Spike (B207002-MS1) Biochemical Oxygen Demand, Carb. Matrix Spike Dup (B207002-MSD1) Biochemical Oxygen Demand, Carb. Batch B207005 Blank (B207005-BLK1) Residue, Non-Filterable Blank (B207005-BLK2) Residue, Non-Filterable LCS (B207005-BS1) Residue, Non-Filterable LCS (B207005-BS2) Residue, Non-Filterable Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 172 mg/L 198.0 86.7 84.6-115.4 179 mg/L 198.0 90.5 84.6-115.4 Source: 2206033-01 2.32 2.00 mg/L 2.10 9.87 25 Source: 2206022-03 512 2.00 mg/L 396.0 57.3 115 75-125 Source: 2206022-03 460 2.00 mg/L 396.0 57.3 102 75-125 10.5 200 --- U 10.0 mg/L --- U 10.0 mg/L 53.0 10.0 mg/L 54.30 56.0 10.0 mg/L 54.30 97.6 85-115 103 85-115 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 6 of 9 Analyte Batch B207005 LCS Dup (B207005-BSD1) Residue, Non-Filterable LCS Dup (B207005-BSD2) Residue, Non-Filterable Duplicate (B207005-DUP1) Residue, Non-Filterable Batch B207008 Blank (B207008-BLK1) Ammonia [As N] Blank (B207008-BLK2) Ammonia [As N] LCS (B207008-BS1) Ammonia [As N] LCS (B207008-BS2) Ammonia [As N] LCS Dup (B207008-BSD1) Ammonia [As N] LCS Dup (B207008-BSD2) Ammonia [As N] UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 56.0 10.0 mg/L 54.30 103 85-115 5.50 20 54.0 10.0 mg/L 54.30 99.4 85-115 3.64 20 Source: 2206033-01 --- U 10.0 mg/L 4.00 20 --- U 0.100 mg/L --- U 0.100 mg/L 14.7 1.00 mg/L 14.90 14.6 1.00 mg/L 14.90 14.6 1.00 mg/L 14.90 14.8 1.00 mg/L 14.90 99 90-110 98 90-110 98 90-110 0.7 20 99 90-110 1 20 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 7 of 9 Analyte Batch B207008 Matrix Spike (B207008-MS1) Ammonia [As N] Matrix Spike (B207008-MS2) Ammonia [As N] Matrix Spike (B207008-MS3) Ammonia [As N] Batch B207039 Blank (B207039-BLK1) Phosphorus Blank (B207039-BLK2) Phosphorus LCS (B207039-BS1) Phosphorus LCS (B207039-BS2) Phosphorus LCS Dup (B207039-BSD1) Phosphorus LCS Dup (B207039-BSD2) Phosphorus UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2206022-01 9.88 0.100 mg/L Source: 2206033-01 5.00 0.100 mg/L Source: 2206034-01 4.97 0.100 mg/L 5.000 7.83 41 90-110 5.000 0.0795 98 90-110 5.000 0.164 96 90-110 --- U 0.0500 mg/L --- U 0.0500 mg/L 2.23 0.250 mg/L 2.220 2.27 0.250 mg/L 2.220 2.24 0.250 mg/L 2.220 2.26 0.250 mg/L 2.220 100 90-110 102 90-110 101 90-110 0.4 20 102 90-110 0.4 20 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 8 of 9 Analyte Batch B207039 Matrix Spike (B207039-MS1) Phosphorus Matrix Spike (B207039-MS2) Phosphorus Matrix Spike (B207039-MS3) Phosphorus UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Friesland Campina - 2206033 Project Number: 2206033 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2206034-01 1.31 0.0500 mg/L Source: 2206022-05 2.50 0.250 mg/L Source: 2206033-01 2.28 0.250 mg/L 1.000 0.344 1.000 1.69 1.000 1.41 97 90-110 81 90-110 87 90-110 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/12/2022 Page 9 of 9 FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 8.0 Photographs FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 Photo #1. A pretreated effluent composite sample was collected at the monitoring location. Photo #2. Grab samples were collected of the Non-Contact Cooling water discharge. FCINA, 40196 State Highway 10 NYP002786 & NY0262838 Inspection Dates: June 29-30, 2022 Photo #3. A grab sample was collected of the groundwater at the influent sample point. Photo #4. No discharge was observed from the stormwater outfalls during the inspection.