Document 5Lrdv36NRmzoV39r8VJeoxVp8

TOTriATrPRODUCT DEVELOPMENT REPORT COATINGS AND RESINS GROUP LABORATORIES FEBRUARY 1966 CONFIDENTIAL PROPERTY OF TME GLIDDEN COMPANY N 2286 61- 00068 26 -17- February, 1966 PIGMENT DISPERSION DATA Information on the dispersion properties of coded pigments has been complied in the following tables. Data was gathered by contacting each supplier and asking for his experience with his materials. In addition, Glidden's past history on pilot plant and plant batches as obtained by M. Malaga with these pigments is shown. In most cases there is good correlation between supplier rating and Glidden results. In a few cases there are some discrepancies. There still are many blank areas where suppliers have not sent in any information or in a number of cases, didn't have any data. These will be supplemented at later dates. Data from M. Malaga's work has been compiled over a period of time on runs made on various pigments. Numerical values indicate Hegman (ll) grind readings that can be obtained on a Cowles Disperser. Abbreviations can be identified as follows: C - Cowles (usually refer to solvent systems) CS - Specifically solvent systems on Cowles CW - Water based dispersions on Cowles S - Sand Mill NC - Not recommended for Cowles NS - Not recommended for Sand Mill GL D006827 -18- Pigment Dispersion Data February, 1966 r-No. Material 1 White Lead Sublimed 4 #8 Zinc Oxide 6 #352 Leaded Zinc Oxide 10 Barytes 10 Barytes 1.1 Nytal 200 11 Asbestine FT 3.1 Fibrene c400 11 Cal Fibre 16 Superwhite Silica 16 #39 Silica 16 Velveteen F 16 Becco #4lO 36 #ll60 Silica 18 Silver Bond B Silica 21 Magnesium Carbonate 21 Magnesium Carbonate 25 Antimony Oxide 33 601 Zinc Oxide 33 AZO-ZZZ33 33 AAA-427W 35 Chewet #301 ZnO 35 Ozark 12-88 ZnO 39 45-3 A3.bacar CaCO^ 4l Whitcarb W 62 Commercial Whiting 63 C55 - CaC03 Supplier Eagle-Picher N. J. Zinc Eagle-Picher Nat. Lead CK Williams R. T. Vanderbilt Int. Talc Sierra Talc Southern Calif. C .K. Williams C. A. Wagner Tamms E. S. Browning Innes Speiden Tamms Whittaker Clark Philip Carey Nat. Lead N. J. Zinc Am. Zinc Eagle Picher Am. Chemet Sherwin-Williams C. K. Williams Witco (Wyandotte) C. A. Wagner H. T. Campbell Micron Range .06-16 Supplier Informat. Glidden CS CW NC l .06-16 5-7 NC 5.5 6 2-44 1-44 1-44 1-2 2 1 if2 1-53 10 3-44 1 3-5 3 .03-.16 NC C \ 2 4.5 4.5 4 4.5 2-44 NC,NS 2-2 1/2 2 2 GlOOOfo028 W-No. Material 63 63 63 69 69 75 91 91 91 94 io4 104 104 108 119 121 121 121 121 126 126 120 128 128 l4o l4i i4i 154 154 154 154 158 161 #10 Whiting #1 White CC100 Whiting HO-Lithopone Permolith 60H Calcium Sulphate Ti Pure FF Zopaque SD Titanox AMO Kaolloid Clay IO978 White Lead A White Lead HTS White Lead A Surfex MM Lithopone 96 LO Cameltex Calwhite Micro White #50 Snowflake #6 Talc #6 Talc Zinc Oxide #500 ZnO AZO ZZZ 77 Multifex MM Talc "A" Talc "A" Atomite Micro White #25 Camel White Gamaco Mica 3X Mica #12 -19- Supplier Georgia Marble T. Weinman Sylacauga Baltimore Pig. Sherwin-Williams Harshaw DuPont Baltimore Pig. Titanium Pig. T. Weinman Eagle Picher Nat. Lead Hammond Lead Diamond Alkal Baltimore Pig. H. T. Campbell Georgia Marble Sylacanga T. Weinman C. A. Wagner R. T. Vanderbilt N. J. Zinc Eagle Picher Am. Zinc. Diamond Alkali Georgia Talc Stoller Chem. T. Weinman Sylacanga H. T. Campbell Georgia Marble Mineralite Sales Alsibronz February, 1966 Micron Range Supplier Informat. Glidden CS CW 1-44 2-2 1/2 3-4 4.5 4 .03-8 .05-1 3.5 NC c,s c,s 33 7 2-20 1-30 4-4.5 5-5-5 4.5 NC, NS 5-7 .06-16 C .03-.15 NC, S 6-6.5 6-6,5 2-8 6-6.5 5 5.5 4.5 4 66 88 0 4-6 4 6.5 6.5 Franklin Mineral GL0006829 -20- W-Ko. Material Supplier 163 Tipure R 110 163 Titanox RA 163 Unitane OR 342 DuPont Titanium Pig Am. Cyan. 364 TiPure R 510 164 Unitane OR 540 164 RA 50 166 Celite #266 DuPont Am. Cyan Titanium Pig. Johns-Manvilie 168 Mica C 3000 ]68 Mica C 3000 Witco English Mica 170 TiPure R 6l0 170 Unitane OR 640 170 Titanox RANC 170 Titanox RANC imp. DuPont Am. Cyan. Titanium pig. Titanium Pig. 172 ZZZ 22 Zinc Oxide 173 ASP 4oo 173 Al-Sil-Ate LO Am. Zinc Minerals & Chem. Freeport Kaolin 3 79 Ti Cal RCHT Titanium Pig. 180 Ti Cal R 60 180 Titanox RC DuPont Titanium Pig. 186 Le-Semite 186 Albacar 1R8 Nytal 300 188 325 Asbestine 188 Fibrene C 400 188 #5*3 Desert Talc T. Weinman C. K. Williams R. T. Vanderbilt Internat. Talc Sierra Talc Desert Minerals 189 3X Asbestine Internat. Talc 191 #425 Asbestine 3 91- Nytal 400 Internat. Talc R. T. Vanderbilt 192 1767 Talc Whittaker Clark 199 #399 Magnesium silicate Whittaker Clark 199 Mistron Monomix Sierra Talc 202 #22 Barytes T. Weinman February, 1966 Micron Range Supplier Informat. Glidden CS cw S C,S 6.5 6.5 S c,s 5*5 7-5 c,s 7 7 8 7.5 00 5-6 6 5.5 c,s 7.5 7 s 7.5 7 5.5 5 7.5 7.5 3H 5.5 5 6.5 7-5 1-30 1-30 1-44 1-44 1-20 1-10 4-4.5 4-4.5 2-3 0-1 5-5.5 6.5 2-r2.5 55 4 3 1 5.5 5-5 2.5 2 7.5 6.5 6 GVOOOb^0 W-No. Material 208 209 210 212 213 2l4 215 216 219 220 221 222 223 223 223 234 235 236 237 238 239 24l 242 244 246 Zopaque R 88 Titanox A-l68 LO 45X Lead Silicate Barytes Chloride Rutile R 100 Titanox C 50 Cab-O-Lite PI Cab-O-Sil M5 XX505 Xinc Oxide ASP 100 ASP 900 ASP 101 Al-Sil-Ate W Glomax LL Satintone #1 Mistron T-O76 5X Asbestine 45X Lead Silicate Micro-Cel E Zopaque R 11 Camel Carb Ruby Talc #400 Ti Pure R 510 Ti Pure R 900 FFFF Pumice -21- Supplier Baltimore Pig. Titanium Pig. National Lead C. K. Williams DuPont Titanium Pig. Cabot Cabot N. J. Zinc Minerals Chem. Minerals Chem. Minerals Chem. Freeport Kaolin Georgia Kaolin Minerals & Chem. Sierra Talc Internat. Talc National Lead J ohns-Manvilie Baltimore Pig. H. T. Campbell Am. Chemet DuPont DuPont Tamms February, 1966 Micron Range Supplier Informat. Glidden C8 CW S 7 77 C, S .015-.02 4-6 .7-7 4.5 .5-10 1-44 5-6 0-1 33 00 88 2 5.5 5.5 6 3-44 C, S C, S 33 33 1.5 4.5 88 7.5 GL DO 06 831 W-No. Material . 247 249 249 251 253 255 256 257 259 261 262 263 267 270 271 272 273 276 277 278 280 281 284 285 Hydrite MP 18m Ozlo #118 Leaded ZnO MicroCel "C" Hydrite 10 Zopaque R 55 Hydrite R Lu Fil Ti Pure FFR Rutile RCHTX Drikalite #8 White CaCO^ #421 Fibrous Filler Ti Pure R 6l0 Ti Pure R 9^1 ASP 600 Mistron 139 Al-Sil-Ate NC Zopaque R 77 Optiwhite Zopaque LD-C Busan 11-M-l #2620 Talc Fibrene C ^00 -22- Supplier Georgia Kaolin Sherwin Williams Am. Chemet Johns Manville Georgia Kaolin Baltimore Pig. Georgia Kaolin United Clay Mines DuPont Titanium Pig. T. Weinman Georgia Marble Whittaker Clark DuPont DuPont Minerals & Chem. Sierra Talc Freeport Kaolin Baltimore Pig. Burgess Pig. Baltimore Pig. Buckrnan Lab. Whittaker Clark Sierra Talc February, 1966 Micron Range Supplier Informat. Glidden cs CW 4-5 2.5-3-5 5 NC, NS .1-5 5-6 C 7.5 2.5 (Solv.) 6 (Water) C, S 3.5-4 NC c, s c, s .2-4 C C 1-30 4 3-4 0 7 4 7 3 GLD006832 W-No. Material 288 Titanox RA 45 288 Tioxide RH D3 290 Zopaque R 885 291 Titanox RA 51 292 Santocel FR-C 293 Tioxide R-CR3 294 E. P. 4l4 ZnO -23- Supplier Titanium pig. Tioxide Canada Baltimore Pig, Titanium Pig, Monsanto Tioxide Canada Eagle Picher February, 1966 Micron Range Supplier Informat, Glidden CS CW S C, S .01-.02 .03-16 C 7 8 mrmmm Gl D006833 -24- February, 1966 B-No. Material IB Superba Spec. Beads IB Black Pearls 70 Supplier Columbian Carbon Cabot Micron Range Supplier Informat Glidden CS CW s NC 2 Hoover Black #6 4 IVO #3 Bone Black 4 8311 Y Bone Black Hoover Color Columbian Carbon Hoover Color 6 0 3.5 6 7 BTA Lampblack 8 Mapieo Black 9 Super Spectra Monsanto Columbian Carbon Columbian Carbon 3.5 3 0 7 15 Keystone Filler Penn Paint & Filler 26 Raven Black #11 26 Monarch #8l 26b Raven 11 Beads 26b Spheron #6 26b Texas RC 83 BD Columbian Carbon Cabot Columbian Carbon Cabot Sid Richardson 04 1 NC 29 #1843 Black Oxide Reichard Coulston 31 #928 Graphite Cummings Moore 31 Super Flake Superior Graphite 31 #85 Air Floated Graphite Pacific Graphite 3-3.5 NC 51 Thermax R. T. Vanderbilt 96 101 101 loin 10 IB 110 115 M 1011 Jet Lampblack Neo Spectra Mark II Carbolac #2 Neo Spectra Beads Black Pearls 46x Lampblack SM Antimony Black #1 C. K. Williams Columbian Carbon Cabot Columbian Carbon Cabot Monsanto Rare Metal Products 007 5-6 0 6 NC 4 116 Micalith "G" English Mica 124 Graphite Powder GP-38-P9 Wat. Carbon 12.6 #10273 Bone Black Hoover Color 6 GL0006834 B-Ho. Material -25- Supplier 131 Continex F-l Witco 132 F-1335 Black Ferro Corp. 133 Acetylene Black 50% comp. Shawinigan Prod. 137 #607 Black Pearls Cabot Micron Range February, 1966 Supplier Informat. Glidden CS CW S 3.0 6.0 NC GL OOQfe 835 -26- February, 1966 BL No. Material 2 Prussian Blue Supplier Micron Range Imperial (Hercules) Supplier Informat. Glldden CS CW S 4 Ultramarine Blue UB5050 Holland Suco 4 Ultramarine Blue #59_3440 United Ultramarine NC, S 7 Sublimed Blue Lead 16 F2F-59-5340 Ultram. 16 UB-5627 Ultram 51 X-1467 Sicilian Purple 58 BT-284D Monastral 58 NC-X2371 Monarch Blue Eagle Picher United Ultramarine Holland Suco Imperial (Hercules) DuPont Imperial (Hercules) NC NC, S NC, S 00 61 Indo Blue B-l Harmon Colors 74 Blacktone Alkalori Blue Amer. Cyanamid 50-4070 74 C. P. Iron Blue X2243 Imperial (Hercules) 74 Milori Blue #4015 Reicbold 74 Milori Blue BA 9420 Holland Suco S CO 0 S3 77 UB5341 Ultramarine Holland Suco NC, S 78 UB6156 Ultramarine 78 #59-8460 Ultramarine Holland Suco United Ultramarine NC, S 82 Ramapo Blue BP366D DuPont NC, S 84 SP Indotoner Blue B79 Harmon Colors 85 Platinum Violet BL333D DuPont 89 Cyan Blue BNF 55-3750 Am. Cyanamid S 91 Monastral BF-BT425D DuPont 93 Fast Violet Iiake B4043 Harmon Colors NC, S 2 0 5.5 GLD006836 BN No. Material 17 801 Burnt Utober 17 513 Burnt Ubnber 17 Burnt Umber 17 OB Burnt Utaber 18 #775 Raw Utaber 20 1373 Van Dyke Brown 43 #9123 Hoover Brown 44 #9124 Hoover Brown 45 #9125 Hoover Brown 47 #780 Brown Iron Oxide 49 #9650 Hoover Brown 54 F 6ll5 Dark Buff 56 #762 Brown 58 #4195 Metallic Brown 59 #759 Brown 6o Bontone Brown Y 6i WF, B2093F Metallic 62 #6l3-B Brown oxide 62 575 Brown oxide 63 #2344 Midas Gold 64 L-439 Erco 65 BU'5250F Utaber -27- February, 1966 Supplier Micron Range Supplier Informat. Glidden CS CW 8 Prince Mfg. Reichard Coulston Imperial (Hercules) J. Lee Smith 4 4.5 0 6 2 Reichard Coulston 4 0 0 5.5 Reichard Coulston 0 Hoover Color 6 Hoover Color 6 Hoover Color 6 Imperial (Hercules) Hoover Color 6 Ferro Corp. Reichard Coulston Mineral Pigments 5 Reichard Coulston Harshaw Chem. C. K. Williams Imperial (Hercules) Reichard Coulston 6.5 6.5 Interchem, Corp. Reichard Coulston Chas, Pfizer 7.5 7 GLD006837 No. Material 2 Norwood Green M10-8505 2 C 359 2 DCC-1900 3 Norwood Green D-lO-8705 3 DCC-1975 Ii6 Velvet Green DDD A II69 m Chrome Green #10-8100 1*8 Chrome Green #8862 18 Chrome Green #4258 18 Chrome Green #01816 18 Chrome Green #1249 18 Chrome Green DCC-I7OO 51 Chrom. oxide #10-9003 54 Chrorn. oxide X1010 66 Permanent Green X1284 73 Chrom. oxide G6099 73 Chrom. oxide J5351 73 Chrom. oxide X1134 74 Phthalo. Green GT-67I-D 7l Phthalo. Green 48-238 74 Phthalo. Green 15-3100 74 Phthalo. Green GT-422 74 Phthalo. Green G4-7039 80 Olive Drab #3753 -28- February, 1966 Supplier Micron Range Supplier Informat. Glidden CS cw S Amer. Cyanamid Imperial (Hercules) Dominion Colour S 00 Araer. Cyanamid Dominion Colour S Imperial (Hercules Araer. Cyanamid Kentucky Color W. R. Eakins Reichold Western Dry Color Dominion Colour NC, S 00 00 Amer. Cyanamid Imperial (Hercules) Imperial (Hercules) C. Pfizer Mineral Pigments Imperial (Hercules) 37 DuPont Federal Color Lab Amer. Cyanamid Holland Suco Ansbacher Siegle (Sun, Ch) S NC, S 6 33 GLD006838 m ii m >9 i k m n i n n -29- February, 1966 R-No. Material Supplier Range 6 Indian Red R-8099 6 Indian Red 1094-275 C. K. Williams Reichard Coulston 7 Alizarine RE-531 7 Madder Lake X-686 Max Marx Color Imperial ( Hercules) l4 Pare. Toner Y20-1350 Amer. Cyanamid l4 Para Toner X Light S-31H Imperial (Hercules) 15 Para Toner R20-2514 15 Para Toner A-1757 Amer. Cyanamid Imperial (Hercules) 16 Venetian Red V-2425 16 Dark Venet. 11120 C. K. Williams Reichard Coulston 18 Super Aetna Red Oxide 18 N-3872 Persian Gulf 18 Super V Persian Gulf 18 Persian Gulf Oxide Reichard Coulston C. K. Williams Imperial (Hercules) H. L. Blackford (Can.) 21 Burnt Sienna #845 Reichard Coulston 50 V 4040 Venetian Red 50 1135 Venetian Red C. K. Williams Reichard Coulston 62 Metallic Broun 1806 Reichard Coulston 62 Metallic Brown 1105 Imperial (Hercules) 62 Metallic Brown 84-G.G. Prince Mfg. 70 Uncas Maroon X 1972 Imperial (Hercules) 100 Permaton Red Toner Amer. Cyanamid L 120-7018 100 Tanger Red Toner X76l Imperial (Hercules) 100 Blazing Red Toner A6460 H. Kohnstamm 100 Fire Red Toner Harshaw 145 Lithol Toner 20-4180 i 45 Lithc-1 Toner X IO96 145 Lithol Toner RA 2260 Amer. Cyanamid Imperial (Hercules) Holland Suco 151 Indian Red Iron Oxide R 5098 C. K. Williams Informat. Glidden CS CW 4 66 s S 3 00 4 3 4.5 3 3 S NC, S s NC, S 06^q 0*789000 10 R -No. Material 167 167 17? 179 180 180 186 190 191 192 196 201 201 201 202 202 202 204 201+ 210 211 2l4 220 221 opp 22 6 Calcium Lithol Toner 20-4662 Calcium Lithol Toner X-1666 Alizarine Maroon Cadmium Red 220 Mapico Red //110 Red Iron Oxide R-4098 Mapico Red ff^l6 Cadmium Red 210 Cadmium Red 200 Cadmium Red 230 Nippon Orange X 88l Red Lead 95 Grade Red Lead 95 Grade Red Lead 95 Grade Red Lead 97 Grade Red Lead 97 Grade Red Lead 97 Grade 516 Mapico Indian Red RY 5095 Persian Gulf Oxide Metallic Brown B-3093 Red Oxide N-5785 Cuprous Oxide AA Cuprous Oxide A Red Oxide NR 4284 #226 Red Oxide -30- February, 1966 Supplier Range Amer. Cyanamid Imperial (Hercules) Informat. Glidden CS CW S5 s 7 Imperial (Hercules) Aaltimore Pig. Columbian Carbon C. K. Williams Columbian Carbon Baltimore Pig. Baltimore Pig. Baltimore Pig. Imperial (Hercules) National Lead Eagle Picher Hammond Lead .12-16 C c, s National Lead Eagle Picher Hammond Lead c, s .12-16 c Columbian Carbon C. K. Williams Minn. & Mining C. K. Williams C. K. Williams Glidden-Hammond Glidden-Hammond C. K. Williams Reichard Coulston 3 07 6 3.5 0 42 3 5.5 4.5 4 45 Sd 1 0S3 227 233 240 p 4o 250 265 265 265 269 269 270 270 271 272 275 275 277 282 283 284 285 286 290 290 293 294 -31- February, 1966 Material Supplier Micron Range Supplier Informat. Glidden CS CW s Fast Bordeaux MV 7003 Venetian Red #1183 or 83 Harmon Color Reichard Coulston 3 Mapico Crimson #98 Iron Oxide RY 8095 Columbian Carbon C. K. Williams Tuscan Red #3675 Hoover Color 6 Toluidine Toner X 1865 Toluidine Toner Y 790 Toluidine Toner RT 505D Imperial (Hercules) Western Dry Color DuPont NC , S Red Oxide RP899 Mapico Red 344 C. K. Williams Columbian Carbon 4.5 7 I.ithol Rubine X2028 Lithol Rubine 19-4208 Maroon Lithol Toner 20-4990 Imperial (Hercules) Ansbacher Siegle Amer. Cyanamid s Bon Red RT 525-D DuPont NC, S Red Oxide C-1035 Red Oxide R-3387 Minn. & Mining C. K. Williams 445 Ferrite Red #405 Northern Pig. (Can.) Farachlor Red RT-4?7D DuPont C, S Maroon Oxide 1871 Reichard Coulston 5 55 Red Oxide N-4485 C. K. Williams 3.5 6.5 Victoria Maroon MB3 Harmon Color Bon Maroon RT 533-D DuPont NC, S Toluidine Toner 20-3050 Toluidine Toner 10451 Amer. Cyanamid Sherwin Williams S NC, S 2.5 3 7 Metallic Brown B-3652 C. K. Williams Watchung Red RT 428-D DuPont GLD006841 R-No. 295 297 297 29B 300 300 301 301 30? 305 307 309 310 313 313 314 315 316 317 317 318 319 321 322 323 325 326 -32- February, 1966 Material Maroon Gold RT 608-D Supplier DuPont Micron Range Supplier Informat. Glidden CS CW s Kronia Red RO-8097 Softex Red l445 Perm. Carmine FR Extra Kronia Red RO-3097 Softex Red l400 Iron Ore B-OIO85 Iron Ore 909 Bon Red RT-5^5-D C. K. Williams Reichard Coulston Gen. Aniline C. K. Williams Reichard Coulston C. K. Williams Reichard Coulston DuPont 7.5-8 7-5-8 NC, S 6.5 6 7 6.5 7.58 6 G.r> 7.58 3.5 4 Macatawa Red RT 421 Holland Suco NC, S #680 Red Oxide Tamms 6 Tuscan Orange 10395 Hoover Color Mapico #477 Columbian Carbon Lead Silico Chromate M50 National Lead Permex 1-4-3 Eagle Picher .03-32 C 1.5 5.5 Garnet Toner X2433 Imperial (Hercules) #8407 Red Oxide Northern Pig. (Can.) Roman Red #1082 Kentucky Color NC, NS Mercuric Oxide Tech. 1360 Mallinckrodt Mercuric Oxide Red Troy Chem. Thio Fast Red MV 6606 Harmon Color Red Oxide N-7094 C. K. Williams Burnt Sienna #104l Reichard Coulston 1-2 Piper Red 36-T-58 Ansbacher-Siegle Monastral Red Y-RT-759D DuPont Quindo Violet RV-6902 Harmon Color Tuscan Red #10279 Hoover Color GLD0068A2 R-No. Material 327 Burnt Sienna #904 330 Tuscan Red 3670 331 Indian Red R 9998 332 Pyrazolone Red R 6220 333 Duratone Red RM 5912 334 Duratone Red RM 5990 336 Red Oxide J-3110 337 Softex Red l44o 338 Maroon Oxide 1683 339 Red Oxide 1836 34o Red Oxide J-3106 3Ul Irox Red 1360 3^2 Cromophtal Red 3B 343 Thio Fast Red MV-6617 -33- Supplier Reichard Coulston Hoover Color Hoover Color Harmon Color Holland Suco Std. Ultramarine Mineral Pigments Reichard Coulston Reichard Coulston Reichard Coulston Mineral Pigments Reichard Coulston Ciba Harmon Color February, 1966 Micron Range Supplier Informat. Glidden CS CW S 1-2 5 6.5 NC, S NC, S 7.5-8 4.5-5 6 5 6 7.5-8 7.5 7-5-8 GLD 0068 43 -34- February, 1966 YW Ho. Material 1 Chrome Lt. Yell. Y-434D 1 Chrome Lt. Yell. C 202 1 Chrome Lt. Yell. #2701 1 Chrome Lt. Yell. 40-3615 1 Chrome Lt. Yell. 1069 1 Chrome Lt. Yell DCC-1026 1 Chrome Lt. Yell D-3469 Supplier Micron Range DuPont Imperial Kentucky Color Amer. Cyanaraid Reichold Dominion Colour (Can.) Sherwin Williams Supplier Informat. Glidden CS CW C, S S NC, S S 4 5 NC, S s 7 7 2 Chrome Med. Yell #2150 W. R. Eakins 2 Chrome Med. Yell Y 469-D DuPont 2 Chrome Med. Yell. 40-4485 Amer. Cyanamid 2 Chrome Med. Yell IO87 Reichard 2 Chrome Med. Yell X254l Imperial 2 Chrome Med. Yell. 12282 Sherwin Williams 2 Chrome Med. Yell. DCC-1001 Dominion Color (Can.) 2 Chrome Med. Yell J-1238 Mineral Pigments c, s s s NC, S 5-5 2 6.5 0 7 7 7.5 7 22 Chrome Orange #12311 22 Chrome Orange X 819 Sherwin Williams Imperial NC, S 0 7 37 Mapico Lemon LO-NP Columbian Carbon 40 Primrose Yellow Y567D DuPont 4o Primrose Yellow 40-1465 Amer. Cyanamid S 2.5 7 GL00068AA YW-No. Material -35- Supplier February, 1966 Micron Range Supplier Inforaat. Glidden CS CW S 47 Lemon Cadraolith 310 Baltimore Pig. 48 Golden Cadraolith 320 Baltimore Pig. 49 Primrose Cadmolith 300 Baltimore Pig. 56 Orange Cadraolith 330 Baltimore Pig. 61 Horicon Yellow X1351 Imperial 68 Row Sienna RC 451 68 Raw Sienna WS 68 Raw Sienna RS 0362 Reichard Coulston Imperial C. K. Williams 3 77 Zinc Chromate Y 539-D DuPont 77 Zinc Chromate 1310 Mineral Pigments 77 Zinc Chromate 1425 C. D. Reichold 77 Zinc Chromate X2127 Imperial 77 Zinc Chromate Spray Dry W. R. Eakins 09 Mapico Yellow Lemon Ij O Columbian 89 2288b YLO Yell. Iron Ox. C. K- Williams 89 RC 201 Ferrite Yell. Reichard Coulston 7-5-8 7.5-8 67 5 5.5 4.5 33 5.5 5.5 7 5* 7 7 3.06 Mapico Tan #20 108 Sun Yellow N Columbian Carbon Harshaw NC) S 109 109 109 110 Zinc Chromate X2259 Zinc Chromate Y563-D Zinc Chromate 1345 Green Gold YT 562-D Imperial DuPont Minerals Pigments DuPont NC, S 6 7 111 Orange Pigment JO YE637D DuPont 111 Molybdate Orange 0-1874 Reichold 111 Valencia Orange 40-8280 Amer. Cyanamid 111 K 2525 Kentucky Color 111 Rex Orange X 2836 Imperial 111 DCC-1608 Dominion Color (Can.) C, S s NC , S 7 7 112 Yellow Oxide YO-3587 C. K. Williams 112 N Lt. Orange Normal 602 Reichard Coulston 112 Mapico Yellow Orange Columbian Carbon 7.5 5.5 7 GLD006645 -36- February, 1966 YU-No. Material 113 C. P. Chrome Y 661-D 113 C. P. Chrome 40-4500 115 C. P. Chrome 1298 11a Shading Yellow Y-493-D 118 877A 118 DCC-1091 Supplier DuPont Amer. Cyanamid Micron Range Supplier Informat. Glidden CS CW S C, S S Reichold DuPont Western Dry Color Dominion Color (Can.) C, S 119 Orange Lake X1219 Imperial 120 Molybdate Orange YE698D DuPont 120 #2527 Ming Orange E. D. Kentucky Color 3 20 X-2806 Rex Orange 120 T)CC-l607 Imperial Dominion Color (Can.) 120 3427 Molybdate Orange W. R. Eakins 126 #1376 Calcium Chromate Mineral Pigments C, S NC, NS 0 7 128 Sun Yellow C Kentucky Color 129 Empress Yellow X2846 Imperial 129 Peraansa Yell. 12186-A Sherwin Williams 129 Sunglow Yell. 1235 (3D-1840) Kentucky Color NC, NS NC, S 0 0 7 7 131 Chrome Yell. #1245 Mineral Pigments 131 Chrome Yell. #X l8l0 Imperial 131 Chrome Yell. #1290 Reichold 131 Softex RX 2623 Kentucky Color 131 Spray Dry Chrome Yell. W. R. Eakins S c, s 4.5 133 Regal Yellow Lt. X2777 Imperial 134 Regal Yell. Med. X2778 Imperial s 135 Yellow F. G. X 2699 Imperial 136 Softex Ming Orange 2-5 Kentucky Color J. G. Kingston CLD006S46 -68- February, 1966 22. MAINTENANCE TORONTO This is a resume of a lecture delivered by Kenneth Tator, of Kenneth Tator Associates, Coraopolis Pa., before the Toronto Section of the National Association of Corrosion Engineers. Until the advent of sacrificial coatings in the paint industry, all corrosion protection was obtained by interposing a barrier of some chemical resistant material between the corrodable surface and the corrosive medium. Sacrificial coatings such as Galvanizing and Metal Spraying have a long history of successful use in other than the paint industry. In order that a Zinc Rich Coating may be considered a sacrificial coating it is necessary to establish a good degree of electrical contact between the particles of Zinc and between the Zinc and the steel. When this is done, the Zinc Rich Coating becomes a sacrificial anode and eventually errodes away leaving the steel uncorroded as long as the Zinc Rich Coating lasts. We should note that this erroding away of the Zinc Rich Coating shows no rust creep or blistering, therefore spot repair is practical even if it is desirable to wait for more favourable conditions for the repair work. The required high degree of electrical contact between the Zinc particles and between the Zinc and steel is obtained by a close packing of the Zinc particles in the dried film. Obviously, there must be some vehicle present to cement the particles together into a film. For close packing the range of 80^-95^ of the weight of the dried film as Zinc Dust gives the best conductivity. At the 95/6 range for Zinc Dust, rural and semirural protection is achieved. Down at the 8056 Zinc Dust range protection against sea water, etc., can be obtained. The reason for the lower Zinc content where sea water and other strong electrolytes are involved is to allow greater internal resistance so that the sacrificial action will be slowed down to a practical value consistent with protection against corrosion of the steel. Where no top coating of a Zinc Rich coating is to be used, the pH of the surrounding environment should be between pH 6 and pH 12. In this range the corrosion products of the Zinc Dust are largely, if not entirely, insoluble and act as a cement to further harden and toughen the Zinc Rich film. In a rural or semi-rural environment, these corrosion products would be some combination of Sine Oxide, Zinc Hydroxide, Zinc Carbonate and Basic Zinc Carbonate. Where sea water is involved various chlorides, etc., would also form. In the range pH 1 to pH 6, these products would be removed by acids, while in the range pH 12 to pH l4, they would be removed by alkalis. The speaker made it clear that a Zinc Rich Coating is a matter of the percent Zinc on the dried film and not any distinction is made as to whether the vehicle is organic or inorganic. Also, for the reasons cited above, a Zinc Dust/zinc Oxide primer cannot function sacrificially since the chance of electrical contact between the Zinc Dust particles and the Zinc Dust and the steel is too remote. GLD006847 -69- February, 1966 His ideas on vehicle systems are based on their performance upon exposure when top coated. Briefly, vehicle systems for various applications would fall about as shown below. Great flexibility is allowed due to the wide variety of re quirements of service. Vehicles for Atmosphere Types Rural Semi-Rural Sea Chemical Silicate Gl. Rubber Polystyrene Silicate Gl. Rubber Polystyrene Epoxy Ester Silicate Gl. Rubber Polystyrene Epoxy Ester Catal. Epoxy Gl. Rubber Catal. Epoxy Pigments for Atmosphere Types Rural Semi-Rural Sea Chemical Zinc Zinc Zinc Zinc/Lead Zinc Zinc/Lead Zinc/Aluminum As a means of slowing down the rate of errosion of a Zinc Rich Coating, admixture with Lead or Aluminum is suggested. In such a case the total weight of the two metals would fall into the 8C$ - 9%> range of film weight. A Zinc Rich Coating does not always act as a sacrificial coating. Indeed, most of its life it acts as a barrier coating, due to the buildup of Zinc corrosion products acting as a cement to harden and toughen the film. This accounts in part for the very long protective life of Zinc Rich coatings. The fact that whenever there is a break in the film, through to the metal, a fresh generation of sacrificial action is instituted is another factor in long life protection. Top Coating We questioned Mr. Tator about top coating of Zinc Rich Coatings. His answer was that a Zinc Rich Coating should be treated as a Galvanized surface and primed accordingly. Galvanized Iron Primer Y-471 or Zinc Dust/zinc Oxide Primer is suitable. Of course the Primer must not soften the Zinc Rich Coating and the top coat must not lift the primer. Mr. Tator stated that many Zinc Rich Coatings are available which can be primed and finished with 24 hrs. between coats and that such systems can last up to 8 years. Our TGL 14971A Zinc Rich Coating, and its successors, will not accept top coating without the top coats eventually pulling the Zinc Rich Coating from the steel. Since Mr. Tator suggests top coating should be possible, perhaps the reason lies in the extremely slow solvent used in our Zinc Rich Coating remaining sealed in the film by the top coats and eventually destroying the adhesion of the Zinc Ricli Coating to the steel. GLD006848 -70- February, 1966 TGL 16113A Zinc Rich Coating This controversy, wherein we obtained poor weather-o-meter performance, as did Ontario Research Foundation, while Ontario Hydro consistently obtained good weather-o-meter and service performance, might possibly be resolved in this way: we and O.R.F. are essentially chemical laboratories and Ont. Hydro is a physical testing laboratory. This suggests that the pH of the weather-o-meter environment may be outside of pH 6 - pH 12 at C-lidden and O.R.F. most of the time, while Ont. Hydro may be usually in that range. Combining this with the knowledge that linseed oil (part of vehicle in TGL l6ll3A) films swell on exposure to water, it. may be that the Zinc Dust particles were simply separated by the water cycle of the weather-o-meter swelling the linseed oil film while at the same time the water had a pH outside the critical range and with very little Zinc to steel contact available, corrosion of the steel started. D. W. Houston GLD 0068 49