Document 5L2X5675x9BVGjJke9ZV3Ywme
RADIAN ANALYTICAL SKNVICKS F P A S RKPORT
T A D I. K OF CONTKNTS
Client DOW CHEMICAL CO. Facility plaqukmink. la Client Code DOW PLAQ
'
Report Form
Work Order Summary Work Order Comments
Flag Definitions Protocol Summary for Volatile Organics SW6260A Results Summary Initial Calibration
Analysis Batch Summary Results Laboratory Blank Information Laboratory Control Samples Matrix Spikes Calibration Verification
Comment s/Narra tive
Analytical Batch ID MSMSDB710070(M 001
\)P-Ujl)
Pages
From
To
11 22 33 44 5S 14 IS 16 17 lfi 19 19 20 20 21 21 22 29 30 30
I A 05 1 34 y CONFrOF NTTAI.
10/1 3/'y
> : 4 5 : 03
Rcnoi't HADIAN INTERNATIONAL TO P.0 .BOX 201088 Austin. TX 70720-1088 ItCIDl KRA1.1.
Prepared By
Radian International, ULC 14046 Summit Dr.. Bl(|q, B
P. 0. Box 201088 AUfllin. TX 7B720-10BB
CSC UPMAXWELL
Project sample ID/ Descript ion
DOW`VP"LW-41- VI DOW - VP - I.W- 4 1 - V2 POH-VP-bW-41-VI IX1W - VP-LW- 4 1 - V4 DOW-VP-LW-41-V5 DOW - VP' IiW - 4 1 - V6 DOW-VP-LW-41 -V7 DOW-VP - l.W-41 -Vft DOW -VP-LW- 41-VS DOW-VP-liW-41 -V10 DOW-VP-liW-41 -Vll DOW-VP-l.W-41-Vl/Vll
[>OW-VP-l,W-41-Vl/VU
WORK O k 1) K H
~ MHA N Y
Cl lent Cotie DOW PI.AQ Client DOW CHEMlCAl, CO. Facility PI.AQUKMINB. LA Vf'-ik ID BIF TRIAD BURNS
Case II NA sdg m HAS II 70B07ADPM
Work Order N 9709789 Page 1___
RCN 800117.5000
New York EI.AP ID
10915
I.ab Sample ID
01A 02A 0 JA 04 A 05A 06A 07A 08A 09A 10A 11A 12A COMPOSITE 12B COMPOSITE 13A DUP 1JB DUP
Teat Codeia)
COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO 826SWAVP SPAREBOO B26SWAVP SPAREBOO
Method Deaciption
Compositing for OC/MS VQA Compositing for GC/MS VOA Compositing for OC/MS VOA Composit ilig for GC/MS VOA Compositing Cor GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Volatile Organics by OC/MS spare sample Volatile Organics by GC/MS Spare Sample
DO A 05134ft OONFTDt-NTTAl
10/13/97 09;4'j:01
NOHK OHDKH C O M M K NT 8
The standard Method 026OA surrogate tolerances are laboratory derived from historical data, Project specific tolerances may differ.
Work Older H 9709769 Page 2,
A OS1349 OONF TOFNIT T Al
cA
10/13/.
3:40:03
ANAL Y T I C A I. I* JTOCOI, SUMMARY PI, AG IJKPIN1TIONS
Walk Order N 9709789 Page 3
Flay
Definition
< DL NA NC ND NR NS B C E F II I J K M P 0 H S T X Y Z
Result less than stated Detection Limit and greater than or equal to 2ero. Analyte concent* u ton not available for this analysisUPD and/or % Recovery not calculated. See Narrative for explanation. NoL detected. No instrument response for analyte or resulL less than zero. Not reported. Result greater than or equal to stated Detection Limit and les9 titan specified Reporting Limit. Analyte not spiked. Analyte detected in method blank at concentration gieater than Lhe Reporting Limit (and greater than zero). Confirming data obtained using second CC column or GCMS. Analyte concentration exceeded calibration range. Interference or coelution suspected. See Narrative for explanation. Presence of analyte previously confirmed by historical data. Analyte identification suspect. See Narrative for explanation. Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit. Peak did not meet method identification criteria. Analyte not detected on other GC column. Result modified from previous Report. See Narrative for explanation. Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3. QC result does not meet tolerance in Protocol Specification, Result reported elsewhere. Analyte concentration obtained using Method of Standard Additions (MSA). Second column confirmational analysis not performed. See Narrative for explanation. See Narrative for explanation. See Narrative for explanation.
DO A 051350 CONFTDFNTTAl
0/13/97 09;45;0J
Client DOW CHEMICAL CO._____________ Facility P1.A0UEMINK. LA_____________ Client Code DOW PI.AO Method Volatile Organics SW8260A
Project Sample JD/Deacription
now vp i,w-*i vi/vu
DOW-VP-l,W-41 - Vl/Vl 1
ANALYTICAL PROTOCOL SUMMARY
Woik Ok Jet N 9709 /89 Page 4_
Lab Sample 10
9709789 -13A 9709789-12A
Teat codeia)
026SWAVP 826SWAVP
Ext ractlon/Digestion natch N
NA NA
Analysis Batch 8
MSMSDB71007004801 MSMSDB71007004801
D0 A 051381 conftofNTTA(
10/13/
J:45;03
R H 8 U l< T S &
tMAK Y
Method Volatile Organics SW8260A Test Code 826SWAVP
Project Sample ID:
Lab ID: File ID; Date Collected: Date Prepared; Date Analyzed; Dilution Factor; Matrix: Units: Report oa: Column; Analyte
DOW-VP-LW-41 - -
vi/vn
97097B9-13A DUP B1006739 09/24/97
10/07/97 OS:13;00 10000 Water ug/mL
received
Cone.
DL
DOW-VP-LW-41-Vl/Vll
9709789-12A COMPOS B1006751 09/24/97
10/07/97 14:22:00 10000 Water ug/mL
received
Cone.
DL
Chlorobenzene 1,1,2-Trichloroethane
13300 209000
93S 1190
lbSOO 222000
935 1190
Surrogate(s)
1,1-flromofluorobenzene 1,2-Dlehloroethane-d4 Toluene-d8
Recovery \
101 101 101
Recovery %
98 97 102
Walk Oi(lor n 9/09789 Page 5
Cone.
DL
Cone,
DL
Recovery 1
Recovery %
00 A 05135;-'' OONFTDFNTTAl
10/13/97 09-45:03
INITIAL
C A I. f II It A T 1 O N
Sol'll II WMS - VQA-STD- 6
______________________ m
Mo t hod Volatile Omanka SW8260A
lest code B26SWA00
Initial Calibration N MSDD97Q825QQQOOO Calibration Date 08/25/97 00:00:00
Work Order N 9709789 Page 6.
Instrument MSDB Analyst TLS Reviewer APS
Analytes DichlorodiCluoromethane
Chloromettiane spec Vinyl chloride ccc 111 oinomeLhane
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/l.
1.647 1
1.970 5
3.245 0.5
2.825 5
1.944 0.5
2.199 5
Response Factor
Reference Cone. ug/L
1.777 20
2.655 20
1.957 20
Response Factor
Reference Cone. ug/L
1.999 50
2,977 50
2.277 50
Response Factor
Reference Cone, ug/u
2.136 100
3.04 8 100
2,148 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
1.91
10.1
2.95
7.58
2.14
8.64
0.999
Chloroethane Trichiorofluoromethane Acrolein Acetonitrile Acetone lodomct hane
0.736 0.5
1.594 0.5
0.091 2.5
0.061 10
0.313 2
2.555 1
0.923 5
1.739 5
0.106 25
0.061 25
0.269 5
1.988 5
0.922 20
1.529 20
0.104 100
0,059 100
0,225 20
1.828 20
1.051 50
1.721 50
0.113 250
0.065 250
0.238 50
1.908 50
1.090 100
1.758 100
0.105 500
0.067 500
0.254 100
1.990 100
0.944
14.7
1.67
6.05
0.104
7.69
0.0626
5.25
0.260
13.1
2,05
14.0
00 A 05,1 353 V, OONF TOFMT Tai
10/1 \/<r;
.; 01
Sol'n 6 HMS-VOA-STD-6 Method Volatile Organics SN8260A Test Code 826SWA00
IN < T I A 1
C A I. I U
HUN Cont *<l
Initial Calibration Jt MSPb970e25QOOOOO Calibration Pate 08/25/97 00:00:00
Wotk Ontor R 970 Page 2
Instrument MSPB Analyst TLS Reviewer APS
Analytes
Response Factor
Reference Cone. ug/l.
Response Factor
Reference Cone. ug/l.
Response Factor
Reference Cone. ug/L
l,1-Dlchloroethene ccc Carbon disulfide
1,1.2-Trichlorotrifluoroethan*;
0.953 0,5
4.609 0.5
1.151 o.s
1.035 5
5.026 5
1.159 5
0.934 20
4.431 20
1.013 20
Acrylonit rile 3-Chloropropene
0.281 2
2.392 0.5
0.289 5
2.055 5
0.294 20
1.594 20
Methylene chlotIde
1.611 0.5
1 . 333 5
1.195 20
trans-1,2 Dichloroethene
1.079 o.s
1.110 5
0,974 20
Propancnitrile
0.104 2.5
0.085 25
0.080 100
1,1-Dlchloroethane SPCC
1.981 0.5
2.095 5
1 . B04 20
Methyl t*butyl ether
2.167 0.5
2.105 S
2.003 20
Response Factor
Refeience Cone. ug/L
1.007 50
4.772 50
1.097 50
0.307 50
1.956 50
1.251 50
1.075 50
0.093 250
1,741 50
2.236 50
Response Factor
Reference Cone. ug/L
0.966 100
4.640 100
1 . 103 loo
0.294 100
2.038 100
1.206 100
1.076 100
0.090 soo
1.876 LOO
2.170 100
Response
Reference Cone,
Response
Reference Cone.
Correlation
KF
% USD
Coef flcient
0,979
4.21
4,70
4.71
1.10
5.27
0.293
3.23
2.01
14.2
1.32
13.0
1.06
4.64
0.0904
10.0
1.90
7.43
2.14
4.11
00 A 051354
OO/VFTOFNrTAI
1 0 / l 3/97 Cl9:45:Q3
Sol'n H MMS`VQA-STD-6_________________ Method Volatile Organics SWB260A Teal Code 826SHA00
I N I T I A !
CA
II N A T I O N Coni 1 d
Initial Calibration M HSPI197QB250Q00Q0 Calibration Date 08/25/97 00,00:00
Work Order It 9/09789 Page 8
Instrument MSOD Analyst TLS Reviewer APS
Analytes Vinyl acetate 2-Chloro-1,3-butadiene 2`Butanone(MBK) Tet rahyd ro t u ran cis-1,2 >Dichloroethene 2,2Dichloropropane Hi ornoch loromet hane Chloroform
ccc
1,1,l-Trichloroethane 1,2Dlch)oroethane
f
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. u<j/L
1.999 0.5
1.520 5
0.829 O.S
0.430 2
0.954 5
0.396 5
0.227 2
0.187 5
1.043 0.5 .
1.093 5
1.251 0.5
1.0B2 5
0.510 0.5
0.586 5
1.518 0.5
1.568 5
1.305 O.S
1, 399 5
1.245 0,5
) . 319 5
Response Factor
Reference Cone. ug/L
1.404 20
O.B43 20
0.328 20
0.167 20
0.962 20
0.950 20
0.538 20
1.372 20
1.227 20
1.236 20
Response Factor
Reference Cone. ug/L
1.542 50
0.925 50
0.327 50
0.180 50
1.040 50
1.000 so
0.572 50
1.478
so
1.351 50
1 . 316 50
Response Factor
Reference Cone. ug/I.
1.469 100
0.926 100
0.313 100
0.181 100
1.037 100
1.004 100
0,569 100
1.486 100
1.383 100
1.337 100
Response
Reference Cone,
Response
Reference Cone.
Correlation
RP
% RSD
Coefficient
1.61
14.3
0.89S
6.22
0.359
14.3
0.188
12.1
1.04
4.53
1.06
11.2
0.5S5
5.52
1.48
4.86
1.33
5.20
1.29
3.61
DO A 051355 CONFTDFNTTAl
10/13/9/
*: 03
Sol'll H flMS-VOA-STP-6______________ ___ Metbod Volatile Organics SWB260A Test Code 826SWA00
INITIAL
C A L I I*
i` 1 O N Cout'il
Calibration Pate 08/26/97 00.00:00
Woik Otdei II 9 /0.__ Page 9
Instrument MSDB Analyst TLS i-viewer APS
Analytes 1,1-Dlchloropropene Benzene Carbon tetrachloride 2-llexanone 4 Methyl *2-pentanone(MIBK) 1,2-Pichloropropane CCC Trichloroethene Dibrcmomethane 13 vomod i ch 1 o rome thane Methyl methacrylate
Response Factor
Reference Cone, ug/L
Response Factor
Reference Cone. ug/L
0.302 0.5
0.302 5
0.994 0.5
1.025 5
0.184 0.5
0.204 5
0.241 0.5
0.27 5
0.190 05
0.155 5
0.283 0.5
0.244 5
0.244 0.5
0.256 5
0.119 o.s
0.125 5
0.245 0.5
0.251 5
0.094 0.5
0.106 5
Response Factor
Reference Cone. ug/L
0.266 20
0.912 20
0.182 20
0.278 20
0.165 20
0.26/ 20
0.223 20
o. in 20
0.248 20
0.106 20
Response Factor
Reference Cone. ug/L
0.279 50
0.921 50
0.194 50
0.302 50
0.168 50
0.271 50
0.229 50
o.ua 50
0.261 50
0.U1 50
Response Factor
Reference Cone, ug/L
0.285 10 0
0.874 100
0.194 100
0.305 100
0.172 100
0.260 100
0.230 loo
0.117 100
0.264 100
0.112 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
0.287
5.40
0.94 5
6.59
0. 192
4.63
0.279
9.36
0. 172
5.60
0.275
4.91
0.236
5.66
0.119
2.81
0.256
3.38
0.106
6.76
DO A 051 356. CONFTDENTTAl
10/13/97 09:45:03
INITIAL
C A I. 1 II H A T I O N Coil *d
Sol'll A AMS-VOA-STn-6_____________________________________________ Method Volatile Organics BH626QA Test Code 826SWAOO
Initial Calibration N MSDB97Q8250OQO00 Calibration Date 08/25/97 Q0:0g:op
Woik Order W 9709789 Page 10
Instrument MSDB Analyst XL Reviewer APS
Analytes 2Ch1oroethy1 vinyl ether Irans-1,3-Dichloropropene cis-1,3 ^Dichloropropene Toluene ccc 1.1,2 *Ttichloroethane Ft hyl methacrylate l, 3 l)ichloropt opano Dibromoch1o r ome t ha ne 1,2-Dibromoethane Tettachloroethene
Response Factor
Reference Cone. ug/b
Response Factor
Reference Cone. ug/b
0.117 0.5
0.106 5
0.614 0.5
0.672 5
0.307 0.5
0.326 5
1.608 0.5
1.632 5
0.451 0.5
0.495 5
0.545 0.5
0.597 5
0,811 0.5
0.791 5
0.503 0.5
0.506 5
0.423 0.5
0.478 0.5
0.444 5
0.531 5
Response Factor
Reference Cone. ug/L
0.101 20
0.647 20
0.305 20
1 .468 20
0.458 20
0.606 20
0.751 20
0.508 20
0,43 20
0.468 20
Response Factor
Reference Cone. ug/h
o. 106 50
0.662 50
0.315 50
1 .485 50
0.473 50
0.631 50
0.759 50
0.539 50
0.439 50
0,487 50
Response Factor
Reference Cone. ug/L.
0.11 1Q0
0.648 100
0.32 100
1 .431 100
0.474 100
0.648 100
0.765 too
0.545 100
0.445 100
0.493 100
Response
Reference Cone,
Response
Reference Cone.
Correlation
RF
1 RSD
Coefficient
0.106
4.99
0.649
3.38
0.315
2.79
1.52
5.87
0.470
3.61
0.605
6.50
0.775
3.21
0.520
3.86
0.436
2,17
0.491
4.90
DO A 051357 OONFTDFNTTAl
10/13/97 u , : 03
Sol 'n n II MS VOA-STD - 6
Method Volatile OrqanicS SW8260A Test Code 826SWAOO
1 N 1 T I A 1.
C A 1. t II *\ V 1 0 N Cont'd
Inil lal Calibration II MSDI1970825000090 Calibration bate 08/26/9/ 00:00:00
Work Order K 9109. Page 11
Instrument MSDB Analyst TLS Reviewer APS
Analytes ch1orobenzene SPCC 1.1,1,2-Tet rachloroethane
1 Chlorohoxnne
Ethylbenzene
mtp-Xylene
Bromoform spec styrene
o- Xylene
11ans-1,4-Dichloro- 2-butene
Response Factor
Reference Cone. uq/L
Response Factor
Reference Cone. ug/L
1.657 0.5
1.758 S
0,485 0.6
0.534 5
0.761 0,5
0.867 5
0.833 0,5
0.895 5
1.005 1
1 , 10B 10
0.216 0,5
0.258 5
1.498 0.5
1.727 S
1.01 0,5
1.089 5
Response Factor
Reference Cone. ug/1.
1.60) 20
0.499 20
0.775 20
0.612 20
0.992 40
0.264 20
1.639 20
1.006 20
Response Factor
Reference Cone. ug/L
1.667 50
0.532 50
0 04 3 50
0.853 50
1,01 100
0,29 50
1.687 50
1.016 50
Response Factor
Reference Cone, ug/L
1.665 100
0.541 100
0.868 100
0.851 100
0.972 200
0.304 100
1.698 100
1.036 100
Response
Reference Cone.
Response
Reference Cone,
Correlation
RF
1 RSD
Coefficient
1.67
3.34
0.518
4.76
0.823
6.23
0.849
3.61
1.02
5.18
0.266
12.7
1.65
S.49
1.04
3.20
0.998
l,i,2,2-Tetrachloroethane
spec
0.S4 0.5
0.495 5
0.493 20
0.499 50
0.503 100
0.506
3.83
00 A 051358 00NFTDFNTT Al
10/1 1/91 09:45:03
INITIAL
ca i
II K A T 1 O N Oinl-'tl
Sol * n H HMS-V0A-ST0-6
______________________________________
Method Volatile Organics SWB260A
Teat Code B26SWA00
Initial Calibration It MSDB970B25000000 Calibration Date OB/25/97 00:00:00
Hoik Oi (lur 9709789 page 12
Instrument MSDB Analyst TI.S Reviewer APS
Analytes 1,2,1 Tr i <*h)oropropnno Isopropylbenzene Bromobenzene 2Chlorotoluene n Propy1benzene 4 Chlorotoluene 1,3,5-Trimethylbenzene 1.2,4-Trimethylbenzene tert-Hutylbenzene 1,j-DjchJorobenzene
t
Response Factor
Reference Cone. ug/l.
Response Factor
Reference Cone. ug/L
0.299 0.5
0.349 5
2.248 o.s
2.551 5
0.892 0.5
0.865 5
0.879 0.5
0.699 5
0,899 0.5
0.923 5
0.797 0.5
0.876 5
2.723 0.5
2.803 5
2,627 0.5
2.8 5
2.99 0,5
2.643 5
1.479 0.5
1.585 5
Response Factor
Reference Cone. uq/L
0.336 20
2.315 20
0.801 20
0.79 20
0.823 20
0,781 20
2.426 20
2.469 2
2.242 20
1,457 20
Response Factor
Reference Cone. ng/L
0.349 50
2.399 50
0.81 50
0.789 50
0.829 50
0.798 50
2,461 50
2.44 50
2.217 50
1.472 50
Response Factor
Reference Cone. ug/b
0.352 100
2.375 100
0.823 100
0.798 100
O.B34 100
0.806 100
2.409 100
2.366 100
2.138 100
1.502 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
0,337
6.57
2.38
4.76
0.838
4.63
0.831
6.44
0,862
5.34
0,812
4.57
2.56
7,19
2.54
6.83
2.35
9.03
1.50
3.38 -
no A OS13SO OONFTOFNT TAl
10/13/97 l
j j 03
INITIAL
C A I. I II j,
<* I O M Cortt'd
Sol'n H tfMS-VOA-STD-6_____________________________________________ Method Volatile Organics SWB260A lest Code 826SMA0Q
Initial Calibration fl MSPB97U025000000 Calibration Date 08/25/97 00*00:00
Work Order M 97o.> Page 13
Instrument MSDB Analyst ThS Reviewer APS_______
Analytes Sec - But y1 benzene l,4-Dichlorobenzene p- Isopropyl toluene 1,2-Pichlorobenzene n-Buty1benzene 1,2Dlbromo-3-chloropropane \, 2,4 -T irhlmobeti/ene
Response Factor
Reference Cone. ug/t.
Response Factor
Reference Cone. ug/L
3 .161 0.5
3.553 5
1.400 0.5
1.549 5
2.134 0.5
2.705 6
1.346 0.5
1.421 5
1.765 1
2.281 5
0.062 2
0.064 5
Response Factor
Reference Cone. ug/L
3.072 20
1.418 20
2.462 20
1.34 30
2.296 20
0.077 20
Response Factor
Reference Cone. ug/L
3.069 50
1 .444 50
2.512 50
1 . 364 50
2.433 50
0.083 50
Response Factor
Reference Cone. ug/L
3.004 100
1 .437 100
2.517 100
1.367 100
2.489 100
0.087 100
Response
Reference Cone.
Response
Reference Cone.
____ Correlation
RF
t RSD
Coefficient
3.17
6.92
1.45
3.90
2.47
8.41
1.37
2,34
2.25
12.7
0.0746
15.0
0.997
Naphthalene
0.996
1,2,3-Trichlorobenzene
-
0.997
Nexachlorobutadiene
0. 367 1
0.365 5
0.338 20
0-354 50
0.361 100
0.357
3.28
PO A 051360 CONFTDFNTTAl
10/11/97 09:15:03
N I T I A I.
C A L I II R A T I O N Coni 'd
SolMi n 8MS-VOA-STP-6_____________________________________________ Method Volatile Organics SW8260A Test Code B26SWA00
Initial Calibiation 8 MSDH970825000000 Calibration DaLe OB/25/97 00;0Q;00
Wot k Older H 9709789 Page 14
Instrument MSDB Analyst TLS Reviewer APS
Analytes 1Promo- 2-ch1oroet hane
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
0.327 0,5
0.319 5
Response Factor
Reference Cone, ug/L
0.298 20
Response Factor
Reference Cone. ug/L
0.302 50
Response Factor
Refetence Cone ug/L
0.305 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
t RSD
Coefficient
0.310
3.96
.
DO A 051351 I OONFTDFNTTAl. I
10/11/9
.95:01
Method Volatile Organics SWB260A Test Code B26SHA00 Initial Calibration H MSDB970825000000 Calibration Date 08/25/97
ANAI.VS1S I1AT:.. SUMMARY Analysis Hatch 8 MSMSDD71007004801
Analysis Start Date/Time 10/07/97 00:98:00 Analysis Stop Date/Time 10/07/97 20:06:00
Work Order II 911)9789 Page 1_5_
Instrument MSDB Analyst TBS Reviewer KLZ
Sequence/Analysis Time
1 10/07/97 00:19:00 2 10/07/97 00:98:00 3 10/07/97 00:98:00 9 10/07/97 01:17:00 5 10/07/97 01:96:00 6 10/07/97 02:15:00 7 10/07/97 02:99:00 8 10/07/97 01:11:00 9 10/07/97 01:92:00 10 10/07/97 09:12:00 11 10/07/97 09:93:00 12 10/07/97 05:11:00 13 10/07/97 05:92:00 19 10/07/97 06:11:00 15 10/01/97 06.91;00 16 10/07/97 07:10:00 17 10/07/97 07:39:00 18 10/07/97 11:29:00 19 10/07/97 11:53:00 20 10/07/97 12:22:00 21 10/07/97 12:52:00 22 10/07/97 12:52:00 23 10/07/97 13:23:00 29 10/07/97 13:53:00 25 10/07/97 19:22:00 26 10/07/97 19:51:00 27 10/07/97 15:20:00
28 10/07/97 15:99:00 29 10/07/97 17:13:00 30 IQ/07/97 18:08:00
Project Sample ID DOW - VP T t.W- 9 1-V1/V11 DOW-VP-bW-91'Vl/Vll
l.ab Sample ID Sample Type
SB BFB VSTDCAL LCS977354 LCSP9 77355 BLK974099 9709636-02A 9709616 -09A 9709616 -1QA 9709616-08A 9709616-G4A 9709789 -13A 9709790-12A 9709740 - OJA 9709693-QlA 9709693 -02A 9709693 -03A 9709616 -01A 9709616-03A 9709616-06A BFB VSTDCAL 9709616-05A 9709616-OTA
9709789 -12A 9709693 -04A 9709740-04A 970979 0 -05A MIBCSTD 970966302B
Blank, System GC/MS tune files Continuing Calibration Verification Lab Control Sample Lab Control Sample Duplicate Blank, Method Samp1e Matrix Spike Matrix Spike Duplicate Sample Sample Sample Sample Sample Sample Sample Sample Sample Samp 1 e Sample GC/MS tune files Continuing Calibration Verification Sample
Sample Sample Sample Sample Sample Sample Sample
Analysis File 8
B1006729 B1006730 B1O06730 B1006731 B1006732 B10Q6733 B1006734 B1006735 B1006736 B1006737 B1006738 B1006739 B1006740 B1006741 B1006742 B1006743 B1006744 B1006745 B1006746 B1006747 B1006748 B1Q06748 B1006749 BIQ06750
B1006751 B10067S2 B1006753 B1006754 B100675S B1006756
D0 A 05136? OONFTDFNTTAt
lO/l 1/9/ 09:45:01
Method volatile Oraanica SW8260A Teal Code 82GSWA00 Initial Calibration H MSDB970825000000 Calibration Dale 08/25/97
A H A I. Y fi I S B A T C II S U H MART (conL'd) Ana 1yai a Uati.li H MSMSl/DM 007004 001
Analysis start Date/Time 10/07/97 00:40:00 Analysis Stop Date/Time 10/07/97 20:06:00
Hoik Otdei N 9/09789 Page 16
Instrument MSDB Analyst TLS Reviewer KLZ
Sequence/AnalyaIs Time
31 10/07/97 18:37:00 32 10/07/97 19:06:00 33 10/07/97 19:35:00 34 10/07/97 20:06:00
Project Sample ID
Lab Sample ID Sample Type
9709663-01D 9709616-O4B 9709616 07B 9709616-0&B
Sample Sample Sample Sample
Analysis File 8
B1006757 B1006758 B10067B9 B1006760
no A 051305 OONFTDFNTTAl
iu/lJ/v J:15;03
Extraction Hatch fl Analysis Hatch N
R KS L
8
_______________ _________
MSMSDI* MOO/U04801
Wcuk Older tf 9/09 /89 Page XI
Project Sample ID DOWVP-LW-41 -Vl/Vl1 Lab Sample ID 9709789-13A PUP Pile H U1006739 Method Volatile Organics SW6260A Test Code 826SWAVP
Date Collected 09/24/97 Date Received 09/26/9 J Date Prepared Pate Analyzed 10/07/97 05:13:QO
Instrument MSDB Column Analyst TLS Reviewer KLZ
Aliquot Mass/Volume
15.0 InLI
Gxtract/Olgestate Volume
15.0 (ml,)
Dilution Factor
10000
Analyte
Chlorobenzene 1,1.2-Trichloroethane
CAS H
108-90-7 79-00-$
Measured Concentration uq/mlf
13300 209000
Reporting Subset Spikes Subset ____ Specs Subset _
Matrix W Report As received % Moisture
Detection Limit ug/mL
935 1190
Reporting Limit ug/mL
0 0
Surrogate(s)
1.4-Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-<38
CAS n
460-00-4 17060 - 07-0 2037-26-5
Spiked Cone. ug/mL
167000 167000 167000
Measured concentration ug/mL
16BOOO 169000 169U0U
Recovery \
101 101 101
Specification Limits
Low %
High %
77 117 61 143 87 113
no A OBI 364
OONFTOFNTTAl
10/13/97 09:45;0 3
Extraction Batch ft Analysis Batch ft
KKSULTS ________________ _ MSMSDB71007004801
Woik Older ft 9709769 Page lB_
Project Sample ID D0W-VP-LW-41-V1/V11 Lab Sample ID 9709789-13A COMPOS Pile ft D100G7S1 Method Volatile Organics 5W8260A Test Code 826SWAVP
Date Collected 09/24/97 Date Received 09/26/97 Date Prepared1 Date Analyzed 10/07/97 14:22;0Q
Instrument MSDB Column Analyst TLS Reviewer KLZ
Aliquot Mass/Volume
15.0 (mb)
Kxtract/Dlgestate Volume
15.0 (mL)
Dilution Factor
10000
Analyte
CAS ft
Measured Concentration ug/mL
Chlorobenzene 1,1,2-Trichloroethane
108'90-7 79-00-5
15500 222000
Reporting Subset Spikes Subset ____ Specs Subset _wit^
Matrix W Report Ae received % Moisture __________
Detection Limit ug/mL
935 1190
Reporting Limit ug/mL
0 0
Surrogate(s)
1,4-Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-ds
CAS ft
460-00-4 17060-07-0 2037-26-5
Spiked Cone. ug/mL
16/000 167000 16/000
Measured Concentration ug/mL
163000 163000 171000
Recovery %
98 97 102
Specification Limits
Low %
High 1
77 117 61 143 87 113
no ^ nF^f^v
comp 1
f
10/ J 3/9'#
:45;03
Ah ORATORY HI. A
INFORMATION
Ext t act ion natch M
._______ ____i__
Analysis Hatch H MSMSDBMOO7QO4B01
WotK Order A 9709769 Page 19.
Lab Sample ID HLK97-1099____________ Kile n 111006719___________ Mel hod Volatile Organics SWB26QA Test Code B26SWAVP
Prepared ----------------------- -------Analyzed 10/97/9/ 02:15.0)0
Instrument MSDO Column Analyst TLS Reviewer KL2
Reporting Subset i Spikes Subset Specs Subset __
Matiix W
A1iquot Mass/Volume
1S.0 (mU
Extract/DigestaLe Volume
IS O (mU
Dilution Factor
0,001
Analyte
Chlorobenzene 1.1,2 -Trichioroethane
Measured Cone. ug/mb
ND ND
Detection Limit ug/mL
0.000093 0.000119
Reporting Limit ug/mL
0 0
Surrogate(s)
1,4-Bromofluorobenzene l,2-Dichloroechane-d4 To 1 uene - d8
Spiked Cone.
ug/mL
0.0167 0-0167 0 0167
Measured Cone. ug/m!
0.0163 0.0168 0.0172
Recovery t
98 101 103
Specification Limits
Low \
High 1
77 117 61 143 87 113
00 A Of, 1366 CONFTDFNT TAI
JO/IJ/97 03:45.03
Method Volatile Orqanics SW8260A Teat Code 826SWAVI1
LABORATORY CONTROL S A M 1* L K Extract ion Batch H Analysis Batch ft MSMSDU7100/004B01
Date Prepared Date Analyzed
10/07/97 01:46.00
Instrument MSDB Column Analyst TLS Reviewer KLZ
Reportinq Subset Spikes Subset Specs Subset
Wotk Otdei H 9709 *89 Paqe 20
Matrix W Report As received 1 Moisture Aliquot Mass or Vol Extract Mass or Vol
ISO (mL) 15.0 (mL)
Control Std. H LCS1 I.CS2
Vol. Added 5.0 UL 5.0 uL
Surrogate Sol'n H 1.2-DCA-d4 Toluene-d8 1.4-BFB
Vol. Added l UL 1 ul. 1 uL
Analyte
Chlorobenzene 1,1.2-Trichloroethane
LCS Lab Sample ID
LCS977354 File ID D1006731
Spiked Cone ug/1.
2O.0 20,0
Measured Cone. ug/L
20.4 20.8
LCS Duplicate Lab Sample ID
LCSD9773S5 File ID B1006732
Rec. %
Spiked Cone. ug/L
Measured Cone. ug/L
102 20.0 104 20.0
20.2 19.8
Recovery Spec.
Limits
RPD
Rec. 1
Low lllgli Result
%%
1
Spec. Limit
%
101 77 129 99 67 135
0.98 4.9
14 17
Surrogate(9)
1,4-Bromofluorobenzene 1,2*Dichloioethane-d4 Toluene-dfl
16,7 16.7 16.7
17.2 16.7 16.a
103 16.7
too 16.7
101 16.7
16.8 16.4 17.2
100 77 117 9B 61 143
103 B7 113
DO A 051357 f.ONFTDFNTT Al
10/IV9J 09;'* .3
matrix
h
KK (S)
Extraction Batch 8 ___________________________
Analysis Batch # MSMSPBV1007004001
Woik Order N 9709789 Page 21
Ihojcct Sample ID Method Volatile Organics SW8260A Test rode 826SWAMS
Date Collected 09/24/97 Date Received 0_'`j .tb/97 Date Prepared Date Analyzed10/07/97 01:42:00
Instrument MSDB
Column
Analyst TPS
Reviewer
KLZ
Reporting Subset Spikes Subset Specs Subset
Matrix W Report As received % Moisture
Spike SoPn M I.CS1 LCS2
vol. Added
s.o uL
5.0 uL
Surrogat e Sol * n 1,2-DCA-d4 Toluene-dB 1.4-BFB
Vol , Added 1 uL 1 uL 1 ul.
Aria lyt a
Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trich1oroet bene
Sample
L*ab Sample IP
9709616-03A
File U B1006746
Aliquot Mass/vol
15.0
(mL)
Extract Mass/Vol
15.0
(mL)
DU Fact.
1
Spike Sol 1 n Cone.
ug/L
Measured Cone. ug/L
200000 200000 200000 200000 200000
ND ND 1.10 ND 5.84
Spiked Sample
Lab Sample ID
9709616'09A MS
Pile N B1006735
Aliquot Ma&s/Vol
15.0
(mL)
Extract Mass/Vol
15.0
(ml.)
DU Fact.
1
Spiked Sample Dup
Lab Sample ID
9709616 -1OA MSD
File B1006736
Aliquot Mass/vol
15.0
(mL)
Extract Mass/Vol
15.0
(mL)
Di 1 Pact.
1
Recovery Specification Limits
Ri>D
Spiked Cone. ug/L
Measured Cone. ug/L
Rec. \
Spiked Cone. ug/L
Measured Cone. ug/L
Rec. \
Low %
High %
Result l
Specif!cation
Limit \
20.0 20.0 20.0 20.0 20.0
21.4 20.3 24.9 20.6 27.2
107 102 119 103 107
20.0 20.0 20.0 20.0 20.Q
22.6 21.0 25.4 21.0 28.3
113 105 121 105 112
71 77 47 70 71
133 129 175 132 129
5.4 2.9 1.7 1.9 4.6
17 14 25 17 17
Surrogate(s)
1,4-Promofluorobenzene 1,2*Dichloroethane-d4 Toluene*d8
250000 250000 250000
16.4 16.6 17.0
16.7 16.7 16.7
17.1 16.9 17.3
104
16,7
17.0
101
16.7
16.6
104
16.7
17.0
102 99
102
77 61 87
117 143 113
DO A 061368 CONFTOFNTTAl
10/13/97 09;4S;0J
C O N T 1 N II 1 N (i ( O K I) A I I. Y )
ea
VKR 1 KICATION
II H A T I O N
Analysis Batch If MSMSbB/1007004801
Initial Calibration 0 MSDB970825Q00000
Hoik Older ft 9709/09 Page 22
Lab Sample 10 VSTDCAL File ft B1QQ6730 Method Volatile Organics SW8260A Test Code 826SWA00
Date Analyzed
10/07/97 00:48:00
Repotting Subset Spikes Subset _ Specs Subset
Instrument MSDB Analyst TLS Reviewer KL2
Analyte
Acetone Acetonitrile Acrolein Acrylonitrile Benzene l-Hromo-2-chloroethane Bromobenzene Bromochlotomethane Bromodichloromethane Bromoform Bromomethane 2-Butanone(MEK) n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride 2-Chloro-1,3-butadiene Chlorobenzene Chloroethane 2-Chloroethy1 vinyl ether Chloroform 1 Chlorohexane Ch1o tome thane 3'Chloropropene
Measured ConcentratIon
ug/L
Reference Concent rat ion
uy/L
20.a 107
45.5 20.9 20 3 20.4 19.0 20.5 20.6 21.7 16.8 19.8 20.9 19.0 18.7 16.8 18.4 18.8 20.2 20.0 22.3 19.6 18.8 16.8 18.1
20.0 100 100 20.0 20.0 20.0 20 0 20,0 20,0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
Recovery 1
104 107
46 105 102 102
95 102 103 108
84 99 105 95 93 84 92 94 101 100 112 98 94 84 90
Recovery Specification
Limits
IjOw %
High \
80 120
00 A OBI 369 CONFTOENTTAI
XS
Il>/I 1/9
4b.03
COMTIHUlN<OR DA
( | O A 1. > II H A T I O N
VKHIFICATION ICOnL'd)
Analysis Hatch II MSMSOI371007004801
Initial Calibration II MS1)0970825000000
Work Older H 97119789 Page 23
Lab Sample ID VSTDCAL
Date Analyzed
File 8 B1006730___________
Method Volatile Organics SW8260A
Test Code B26SWA00
10/07/97 00:48:00
Reporting Subset ____ Spikes Subset ____ Specs Subset ____
Instrument MSDB Analyst Jit! Reviewer JCj
Analyte
Measured Concentration
ug/L
Reference Concentration
ug/L
Recovery 1
Recovery Specification
Limits
Low 1
High t
2-Chlorotoluene 4-Chlorotoluene 1,2 -Dibromo-3-chloropropane Dibromochloromethane 3,2'Dlbromoethane Dibromomethane trans-l,4-Dlchloro-2-butene 1,2-Dichlorobenzene 1,3-Dlchlorobeneene 1,4-Dichlorobenzene DJ chlorod i f luoronvethane l,1-Diehloroethane 1,2-Dichloroethane 1,1-Dichloroethene cia-J,2-Dichloroethene trnns-1,2-Dichloroethene 1,2-Dichloropropane 1,3'Dichloropropane 2,2-Dichloropropane 1,1 -oichloropropene cis-1,3-Dichloropropcne trans-l, J-Dichlocopropene Ethyl methacrylate ethylbenzene IlexachlorobuLadiene
18.5 19.1 23.1 19.8 21.3 21.4 16.5 20.1 19.5 19.9 15.5 20 0 19.6 16.9 19.5 19. J 20 J 20.4 15.9 19.3 20.1 19.8 21.3 19.7 20.4
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20 0 20*0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0
93 95 116 99 106 107 02 101 98 100 77 100 98 84 98 97 101 102 79 96 100 99 106 99 102
00 120 60 120
80 120
no a OBI 370 CONFTDFNTTAl
0/13/9/ 09:4b s 03
CONTINUING (OH I) A I 1. Y )
CA
I II H A T I O N
VRRIKI CATION (ConL'd)
Analysis Batch H MSMSUP7100/004601
Initial Calibration tt MSDB97Q82&000000
Work Ordei tf 9709769 page
Lab Sample ID VSTDCAL File H Bl006730 Method Volatile Organics SW8260A Test Code 826SWAOO
Date Analyzed
10/07/97 00:48:00
Repotting Subset Spikes Subset Specs Subset
Instrument MSDB Analyst 1Is Reviewer KLZ
Analyte
2-Mexanone Iodomethane Isopropylbenzene P'Isopropyltoluene Methyl methacrylate Methyl t-butyl ether 4-Methyl-2-pentanone(MlUK) Methylene chloride Naphthalene Propanenit r Lie n-Propy1benzene Styrene 1,1,1,2-1'etrachloroethane 1,1,2,2-Tetrachloroethane Tctrachloroethene letrahydrofuran Toluene 1,2,3-Trichlorobenzene 1*2,4*Trichlorobenzene 1,1,1-Trichloroethane 1,1,2Trichloroethane Trlchloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,1,2-Trichlorot rifluoroethane
Measured Concentration
ug/L
Refeience Concentiat ion
ug/L
o tov oo
22.4 16.8 20.0 19.7 22 .S 20.1 21.9 16.4 24.7
102 18.6 20.3 19 6 21 . 1 19.9 19.9 19.8 23.2 22 . 3 19.2 21.3 20.8 19 6 22.0 18.0
20.0 20.0 20.0 20.0 20.0 20.0
20.0 20.0 10Q 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
20.0
Recovery %
112 84
100 99
112 L00
no
92 124 102
93 101
98 105
99 100
99
no
112 96
106 104
98 110
90
Recovery Specification
Limits
Low
High
1%
80 120
r>n A 05 1 CONFiOFNT'
10/13/i 0:15:03
CONTI NUIMU (OH I) A .. V I CALIBRATION VKRIKICATION (Cant'd)
Analysis Batch # MSMSbimooTOOIBQl Initial Calibration 8 MSDII970825000000
Hoik Oidel H 5709789 Cage 25_
I>ab Sample ID VSTDCA1, File 8 01006730___________
Date Analyzed
Method volatile Organics SH8260A
Test Code 826SWA00
10/07/97 00:18:00
Reporting Subset Spikes Subset ___ Specs Subset ____
Analyte
Measured Concent rat ion
ug/L
Reference Concent rat ion
ug/b
Recovery \
Instrument MSDB Analyst TLS Reviewer KLZ
Recovery Specification
Limits
Low t
High 1
1,2,4 Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride roip-Xylene o-Xylene
19.0 16.6 11.9 17.9 40.0 19,7
20.0 20 0 20.0 20.0 40.0 20.0
95 94 60 90 80 120 100 99
Surrogate(s)
1,4-Bromofluorobentene 1,2*Dichloroethaiied4 Toluene-d8
17.1 17.0 17,1
16.7 16,7 16.7
103 77 117 102 61 143 102 87 113
QO A OBI 37? OONFTDFNTTAl.
10/13/97 09:45:03
CONTINUING (OM U A I I. T } CA1. I II RATION VHRIK1CATION
Analysis Hatch W MSMSDD71007004801 Initial Calibration H MSI>B970b25000000
Hoik Older
9709 789 Page 26.
Lab Sample 10 VSTDCAL File It D1006748___________ Method Volatile Organics SWB260A Test Code B26SWA00
Pate Analyz'd
10/07/97 12:52:00
Reportiny Subset Spikes Subset ___ Specs Subset _
Instrument MSPD Analyst TLS Reviewer KL2
Analyte
Measured Concent rat ion
ug/L
Reference Concent rat ion
ug/b
Recovery t
Recovery Specification
Limits
Low %
High 1
Acetone Acetonitrile Acrolein Aery louit `i le benzene 1 - nroino- 2 -chloroethane Bromobenzene Bromochloromethane Dromodichloromc thane Bromoform Bromomethane 2'Butanone(MRK) n-Dutylbenzene sec-Butylbenzene tert-Butyl benzene Caibon disulfide Carbon tet rachloride 2-Chloro-1,3-butadiene Chlorobenzene Chlorocthane 2-Chloroelhyl vinyl ether Chloroform l-Chlorohexane Chloromethane 3 - Chloropropene
17,2 94,8 46.0 19,4 20,0 19.6 19.0 19,7 20.0 20.3 16. 5 19,3 22.0 19.8 19.3 14.7 19.1 16.e 19.8 19.5 19.3 19.4 16.7 16,4 16.8
20.0 100 100 20.0 20.0 20.0 20.0 20.0 20 0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
86 95 46 97 100 98 95 98 100 101 82 96 110 99 96 74 96 84 99 98 96 97 80 120 84
62 HO A 051373 84 OONFTDFNTTAl
10/13/--
.45:03
COHTINUIHOlOR I1A
I I C A I, II R A T 1 0 N
VRRIPIC AXIOM (Ctmfdl
Analysis Batch II MSMSDBI10070048Q1
Initial Calibration II MSDB970825000000
Work Order H 9709789 Page 27
I^b Sample ID VSTDCAL File B100674B___________ Method volatile Organics SWB260A Teat Code 826SWA00
Date Analyzed
10/07/97 12:52:00
Reporting Subset Spikes Subset -- Specs Subset ____
Analyte
Measured Concent rat ion
ug/L
Reference Concentration
ug/L
Recovery %
Instrument MSDB bnalyst TLS Reviewer KLZ
Recovery Specification
Limits
Low %
High %
2-Chlorotoluene 4-Chlorotoluene 1,2-Dlbromo-3-chloropropane Dibromoch1oromet bane 1,2-Dibrorooethane Dibromomethane trans-1,4 - Dlchloro-2-butene 1,2-Dichlorobenaene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Di chlorodifluoromethane 1,1-Dlchloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis -1# 2-Dichloroethene t rans-1,2 -Dlchloroethene 1,2-Dichloropropane 1.3-Dichloropropane 2,2-Dlchloropropane l,]-Dichloropropene cis-l,3-Dichloropropene trans-1,3-Dichloropropene Ethyl methacrylate Ethylbenzene Hexachlorobutadiene
18.8 19.2 22.1 19.3 20.3 20.8 5.90 20.0 19.9 20.1 IS.5 19 .2 19.0 17.5 19.3 10.9 19.0 19,5 19.9 19.6 20,3 19.9 20.2 19.8 20.8
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20 0 20.0
94 96
no
97 102 103
30 100 100 100
77 96 95 07 96 95 99 97 100 98 102 100 101 99 104
80 120 00 120
00 120
r>0 A 051374 CONF TDRNTTA1
10/11/97 09:45:03
CONTINUING (OR DAILY) CALIBRATION VKR1KICAT10N (Oont'd)
Analysis Hatch N MSMSDB71007004801 Initial Calibration 8 MSi>n97oe25000000
Work Order H 9709789 Page 20.
Lab Sample ID VSTDCAL File N P1006748___________ Method Volatile Organics SWB26QA Test Code B26SWA00
Date Analyzed
10/07/97 12 :S2;00
Reporting Subset Spikes Subset ___ Specs Subset ____
Instrument MSDB Analyst TLS Reviewer KL2
Analyte
Measured Concent rat ion
ug/l.
Reference Concentration
ug/L
Recovery \
Recovery Specification
Limits
Low \
High %
2-Hexanone lodomethane Isopropylbenzene p-Isopropyltoluene Methyl methacrylate Methyl t'butyl ether 4-Methyl-2-pentanone(MIllK) Methylene chloride Naphthalene Propanenitrile n-Propylbenzene Styrene l.l.l,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrach1oroet hene Tetrahydrofuran Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Tr1chioroethene Tr ichlorof luoroine thane 1,2,3-Trichloropropane 1,1,2-Trichlorot rifluoroethane
20.7 IS.7 19.8 20.8 21,1 18 2 20 1 18.2 23.3 93.2 19.1 20.1 19.6 20.3 19.7 18.5 19.8 22.1 22.1 18.9 19.9 19.8 20.4 20.6 15.7
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 100 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
104 78 99
104 105
91 101
91 116
93 96 101 98 102 98 92 99 110 111 95 100 99 102 103 79
80 120
DO A 051 37F. CONFIDENTIAL
<*s.
10/13/.
.:4S:03
CONTINUIN') (UK It A
* ) C A I. I II K A T I O N
VHRIP1CATION (Coat'd)
Analysis Batch H MSMSDB71007004801
Initial Callhralion 8 MSUB970825000000
Work Order N 9709789 Page
l,ab sample ID VSTDCAb pile H 01006748___________ Method Volatile Organics SH8260A Test Code 826SWAP0
Date Analyzed
10/07/97 12;52:00
Reporting Subset Spikes Subset ___ Specs Subset ____
Instrument MSDB
Analyst Tl.s
Reviewer Kl.Z
Analyte
Measured Concentration
ug/b
Reference Concentration
ug/b
Recovery %
Recovery Specification
Limits
LOW %
High %
1,2,4 ~Trimethylbenzene 1,3,5-TrimethyIbenzene Vinyl acetate Vinyl chloride mlp-Xylene o-Xylene
19.5 19.1 13.1 17.5 39.9 19.7
20.0 20.0 20.0 20.0 40.0 20.0
90 95 65 86 100 99
80 120
Surrogate(s)
1,4 -Bromofluorobenzene 1r 2-Dichloroethane-d4 Toluene-d8
16.9 16.1 17.0
16.7 16.7 16.7
101 96
102
77 117 61 143 87 113
n0 A 051376 CONFTDFNTTAl
10/1 1/97 09:14:03
Method VolatiJle Omaulcs SW8260A Sped f icat IonII
bab Sample 11) File ID
Project Sample ID/Description
Analyte
A N A I. Y T I C A I. I K O T O C O 1 S II H H A K Y COHHKNTS/NAKKAT IVK
Mark Older N 97097B9 Page 30
Flag Commcnt/Narrative
Corrective Action
DO A 051377 CONFIDENTIAL.
