Document 44X2KBQjebQL542gVEyD9o5oV
= sh rs
TTEECCHHNNIICCAALL RREEPPOORRTT SSUUMMMMAARRYY
Fri Fe-rqs [airen za, 1970
arch 23, 1979
"70T:O: TTEECCHHNNIICCAALL CCOOMMMMUUNNIICCAATTIIOONNSS CCEENNTTEERR --- 220011--22CCNN
important - ago spritad on bo ces of pas, st we cop1e0 TOC.) (Important -- If report i~ l~inted on both ~de~ ofpaper, ~end two copies to TCC.)
T Envirom nmentmael e Laborate ory (EEe & PC) ow 0535 Environmental Laboratory (EE
Pfoj~" t
Fate of Fluorochenicals 5670612643 Fate of Fluorochemicals mown Of Fleorochemlorls L Repot ! Title
FFiHnalLComprehensive Report: FC 143 I oz Final Comprehensive Report:
i REDce To R. A. Prokop
& PC)
FC 143
5--i--f er or 09362 Wel~:er
Dept. N umber
0535
Pro|ect Number
9970612643
Rel)O~t Number
012
En~,loye~ Number(s)
09362
No, of PaBe= Including Coversheet
I SMT GaR contain e=i)Runnion |Er"mHES>S NF o cas11 gFor SECURITY
[] Opan (Company Confidential)
[] Closed {Sl~ia| Authorization)
3M CHEMICAL REGISTRY
11
N~ ~i=l= Re~rt~
ewan: Comment oRReTvE. KEYWORDS: [Rr --- (Select =erm= from 3M
Thesaurus. Suggest other
IEE men | Pinal Report: tEhnecompperaisosde;s 1al9l77-w1o9r7k9"performed during applicable terms.)
CURRENT OBJECTIVE:
Final Report:
Encompasses all work performed during the period; 1977-1979.
EE&PC - Div. EE&PC - Div. Fluorochonical Fluorochemical (Analytical) (Analytical) (amie (Aquatic) (DeRTAdRLION) [aero ReTRACY eT Totree Se TN Soe Go (s0i1) (Degradation)
(soil)
Toxicity Toxicity
Re me TRE REPORT ABSTRACT: (2OO-250
alert 3M'er$ to Company R&D. It
Wea wo~d$) This is Company
Sans mor abstract information is
confidential material.
distributed
>by
Ihe
Technical
Communications
ooCenter
to
ce:cc: RDDI..LLL... BB Boaahccaoonnn R..LPo. thBaophroangadn
Y.Pothapragada
ton em
--titd,
33MM CCOONNFFIIDDEENNTTIIAALL 11220000..00000011
EExxhhiibbiitt
11220000
State of Minnesota v, 3M Co,, Court File No, 27-CV-10-28862
aMAot410327
3MA01410327
IINNTTRROODDUUCCTTIIOONN
oTTnhhee frrlaauttoiirooonncaahlleeemicffaoolrrsppeehrarsffoorbremmeiinnnggdieesnncvvuiisrrosonenmmdeennpttraaellvioeeuffsffleeycct~g2p~gttuuddiieess
on fluorochemicals has been discussed previouslyx J
TTshhueerfasscuutbbajjneetcc,tt wffhlliuucoohrroochcahhseemmiitcchaaell pooofftenttthhiiiassl rreefpporoorrttwidiiessspFFrCCea11d4433,,disaatraainnbiiuootnniiioccn csiionnuartfttaihhcneetgaeennnitvvn,iidrruosowtnnhrmmiyeec,nnhtthhoaaastssh ttthhdhiieossmepmmsoaattttieeecnrratiiliaalallyl aifissnodruuswsieeindddteesbbrypynraetttiahhodeenaTTdleeilffsyllt.oornni((bRRFu))Ctio1n43 ccchoheaemtmiiicncagalllliyynduiissstrttyhh,ee abaommtmmhoonniiduuommmesssaatlllttcalooflfyppeearrnffdl!uuioonrrtooe--roonccatttiaaonnnooaiilcclyaa.cciidd..FC 143 TwThehiiissghtmmaattofeerrii4aa3l1l aiinssd aatwwhhehiittcheeemggirrcaaannluullaasrrtrppuoocwwtddueerrre hshahaovvwiinnnggbeaalommwoo.lleeccuullaarr
weight of 431 and the chemical structure shown below.
, pq CONNE,
C7 F15 CO0-NN4
FFCC 114433
ToTfhhiisswatrreeerppoorsrtot luccbooinnlssiootllyii,ddaatpteeassrtiaatlllilonaavvacaoiiellafabfbilleceieiinnntffsoo,rrmmdaaettgiioronandaiintniottnhh,ee asaorrieelaass
ososfoofrrppw FtCtaiiotoe1nn4r3 saannoiddsluadabeqqifuuliaiantttyeiidc,c. pttooaxxriticciitiittoyy.n.
The probable coefficients, The probable
edennevvgiirrraoodnnam mteieonnntta,all sorriiisslkk
of FC 143 is defined.
MMEETTHHOODDSS
YhWaaavtteeerrbesseoonlluubbtiihlleiittsyyu,,bjebbclitooddeoefggrraatddeaactthniiioocnnalaannddrepssoooiirlltsg~orr~gsiio, onn mmeetthhooddoollooggyy''ss
have been the subject of technical reports~- J.
AA)) AAqquuaattiicc TTooxxiicciittyy TTeessttiinngg
TTahhfeetertteesstthtaiitnnggdpperrsoocttrooiccbooelldssbyuuttUiiSllEiiPzzeAedd (f1fo9orr75)tt(h%i~)s, ssttuuddyy wweerree mmooddeelleedd
after that described by USEPA (1975)"I".
1.
1.
Bluegill
Bluegill
SSuunnffiisshh
sTTsftthhiuueseddhyybbwllew uuwreeeeegrrgieeilhlleololbbdtsstaauuiininnnfnfeeiidsdsfhhibffrer((oLroLmgmeeplpoaoaam smsippi8srrihivvom malaaatdotceeirPnoogchhchaahtitticrca~hunhueskrse)s)yr.ysuuf,agsieelddjeSSdtiitnoonccwkkitththhiiss
Accfiaasdrrhabbioolnwny-e-frfiepilhlttoheeterroledepdderiniwwoeeldfllilbofew waragt1te6learrshsmomauairhinsontltadaliiiinnngegehddt taaaantntkds11844-f-11hi55olulCCre.sd.
with
dark,
ww Atihitrdthhoauiglaayho33u0p0t-h-m moittinhoneuputeteearcioettrdlraianmnoassftiitjt]i.oi6ononnhaoppnudeerrsriitooelddisg,t, hiwnwtagasasnpdm meraaii8ionndtht.aaoiiunnreeTsddhedark,
4tffh8iisrsohhhuoguw whreesroreeuptrffeiethdodreTTetaetoctrrcaaal--inM Mmdinianttihornoddauaigailhnlyyod,u, tteffosototohiddenghtbeeesipintneggrpiowewdriiit.tohhdhh.eTellhddeFish
ww 4e8erreehoaauccrcsclliipmmraaiotteerdd
toffoorrand1144
days prior throughout days prior
to the to
testing test period.
testing.
Fish
wAAcecurutetee pssehhrofoorrrtt-m-tetederrmmon ((gF9CB 6--h1ho4o3uu,rr)) losstttaat3tii4c0c. aaqqCuuaaarttbiicocn-bbfiioiolaatssessaraeyydss ow A Awwfleele]llrllwelaggtw wplleaaaearstsrtfsseeororrraamqooquewffuadaartkkriennoiaoraon,ww, nnpFCl33u55ccsoo1mxxm 4Fp3pCo92, os00is1lio tx4xti3itoo~2nn00c3o4mw wca0m mpa.a,rss, isC ucucesosoadeennrddttbaaaoiaainnnsssiit-nnufttgihdghlyeete11rc66ddehiidalll1umuiitbeeteenn ertrrt..ss.
of water or water plus FC 143 comprised a study chamber.
"Pale
aDale
FFaattttiigg
FFiisshh
FFaarrm m,,
BBrraaddyy,,
NNeebbrraasskkaa
"bCcoommmm erecriciaal] ffiisshh ffoooodd ooff kknnoowwnn ccoommpposoistitiioonn..
11220000..00000022
33MMAA0011441100332288
aon bd
oF d r
,, /
1200.0003
3MA01410329
TTTsSewiiwzsezeetnenttyyaafnniddbsbhllww uueweeeieggigirgihlehltllt,r, assnw wuudneneforrfimeeislshyhtt,e,essatts((eeLsLddieegppnooaaetmmtdiiaseeaatccm omhhaacvcrccarooroocinnahocchiueerisnrnututsrtrs)aea),st,ttiioouunncnnhiifaofoofmofrbrmemFFCrCsiinn114433..
w w Towwexieeiryttsrhegheteiinnnmm faisail33hin0e0nvtteam mw aliiie,ninnnreeueuddtatenerasdsaanttdpffooH11om9l9ll9ojoly2f-owwiia1alnvp5lsCgClgs.i.gFFtnCCeeMsMdto11r44ot3s3troaotlalaailudvdittdtadyyiiri,ot,itoniioosuttennse.m .wmeptpereeerTsTraeteatmsstuetcutrahresetat,eum e,m rmbepddpedeiiresrssrsasaaottotluluvrvreeeedsds
Go22ex44ny--ehghreooanuulrr loeiinbvnesttleee,rrrvvvaaaatlnlissdonoopsrHr ruuonfentltiaailtlllivttoeottetaastltlo G paetnteerranls owbesreervsaitimoinlsarlryelarteicvoerdetod
m mbseooohrlaturtvataililoioirtntyaysl whhoaeaddrreeoomrccerccaauutsrriurrecrededd.swiamtming wbheehnavaipoprraolproirateer.ratiOcrgaswniimsmmsing
aupunssadeetddtefrriinnnese tthw ohfiiessrdeisssttsueuidm adsyyiel.ww aererlryee
considered to recorded when
considered to
be generally appropriate.
be generally
healthy Organisms
healthy
and free of disease.
2. Aquatic Invertebrates - 48 hour Static LCg,
wDA DaeaqprpuhehanntiieiaacxpmmoIaasngeevnndeaar,,tteottbwwFrCeeanntett1y4ys3,oo-rrgg4laao8tnniihss3omm4uss0r
Static LCso
appteerrvattreessyttingcchhaacmmobbneecrre,,ntrations
awiffinonnoedrrrceca4s4a8r8oerblxbouhphonnooonu-isur-felrfsdiisi.iz.ltteteoedrrFFeeiFpiddCrrrsistow wt1re4eli3illntn,lossw twtloaaatatrhrttesseer3r,w aw,40deedwrwriieeaitttthhiccooovnuccuanhhnryteoetefmem indidlgctcaahaalnenclddoDaanadpdpcpddlleaheeancnddcetierdadations
nagna. and solubiltzed
magna.
prior
to
the
addition
of
the
Daphnia
755II566nn0vv,mmeegrgr/1t/t110ee0bb0w wrr,haahittielealeendttevvesse1et3rtr5tte0eccbboomrnrngaacc/tete1eenn.tttrtreeaaststtiitoonnccssoonncw wceeeenrrnteetrra77at.t.i55io,o,nnss1100,ww, eer11re8e8,, 4422330220,, aann556dd600,,
750, 1000, and 1350 mg[1.
sh1LtgCyh,2s~Utu. eUSmSvvEEaaPPllAAuueess((DDwwuuiillttuuhhtthh))9955%PP%rrooccbbooiinnttffiidcdceoeonnmmccppeeuutteellrriimmppiittrrssooggwrrweaearrmmeeoonnccaallttchhceueullaaS3ttHMeeddTTrraauuccssiinngg
system.
RESULTS
RESULTS
GC Canirical relationship heivoon che Sasser sobumilive of a chomical LA woTToaabbatbtbtelaalreieinnees11ddollluiuuibsssslttiienssn,ggw waFF>aCCt2t0eer1r14g43/ss3,ioo,.lluullobobtiFtiClli33itt414y0y40.3. aanwnddhTTehhrippiesasarrtm amtidaitatdtieietoedronriniatalocclooewiiesfasftffeieeirccxxititereraennepm tmpteeeladdlyyraaettdaa
>\/"toabw taoybbasstooafefpororrbrbarmeemrsddot..ualiutgbgieTTelolehlhni,iscsaaoll>tmm te2hah0foatofuetugiegrg]crhihliia.aellffnuutFriirosCstthhfeess1r4llr5i3i.ggaah~hddtdthdllBieyiyattriseioeollnidniapssSpooodnpeopodhffhitllFFhtloiCCelccsew 1144aaas33dstaetww eeraevveriairdeedpietepnnssecciciam eemarddeniidllaarrllyy
Ce ebbbxyeetecacnootnpncacl_liuu_nddrteetitddhioentthehnaaatvt~ irFFcoCCnlm1~ 1e44n33nt.twwoououlCflddhi5o.nhuootteBtbbaisi2ooe1(dcc)o~poqSneenhtnhtatverreaasetteeaedsttaocotariaabnnietdaappcpaapnnrreecciiaabbllee
extent in the environment. Chiou et al"" have ~escribed an
wi20 |"{~ caeannrmddropriiirttisscisabbliciooorecncosloanintdccieeoernnnettsdrrhaatittpiiooonnbbeet~fwaaacepcteptonroror..xthiem"aII~ntnaetl-tt-hyh~eerioirnrseosslysyusesbttdeieem lmri,t,yoftthhoemefagaaanssiccctrhruiiebdbmeee.didcal
error is considered to be approximately one order of magnitude.
YWI g0
tW tfhhahiciesstnormm aapatopeftleryriaiinapalgplrowwdxoaoiutulmaldadtgebbeleenyepprr1ar0oot.ejjdeeccttfeeoddr
toFC
to
possess 143 to
possess
a bioconcentration this proposed relationship, a bioconcentration
factor of approximately 10.
kL4A0e5G0'y
WVe r a he
parameter Tost Results TTAABBLLEE 11 WWaatteerr SSoolluubbiilliittyy aanndd P Paarrttiittiioonn CCooeeffffiicciieenntt ooff FFCC 118433
Sotubitity
Partition Coefficient
Test
CCooaarrssee mmeetthhoodd
n-octanol/water
n-octanol/water
Results
>>2200 g/1
5
ot IF E vR
11220000..00000044
33MMAAO011441100333300
FC 143 was found to be completely paglatant to biodegradation uFunCnddee1rr43ttwhhaeestteefssottundccoonntoddiitbteiioonncssomSpeolmpepitloeoylyeyeadt"F?~)"i..staTTnhhtee 2t2o11b//22lodmmeoognnrttahhdatlon Shake culture. biodorradasion Beudy utilized merobial test shake culture blodegradation study utilized mlcroblal test Eitires derived fron activated sludge inocula optained from cultures derived from activated sludge inocula obtained from the Chemolito, `Dechrur and Tein Cities Kecro Plan waste treatment the Chemolite, Decatur and Twin Cities Metro Plan waste treatment Syston During the fine course of this study a Brain of system. During the time course of this study a strain of A Crones Which coula degrade FC 143 aia not develop, hence microbes which could degrade FC 143 did not develop, hence This material wosld be expected to persist in the Ghvironment this material would be expected to persist in the environment for antonded periods of time unaltered by Birobinl easanotisa. for extended periods of time unaltered by microbial catabolism.
S011 sorption studies have shown that approximately 5%, Soil sorption studies have shown that approximately
(range 2.78), of the FC 143 prevent in 8 wigs solution was (range 2-7%), of the FC 143 present in a wa~ solution was
adsorbed to bril sunsy ons soil (Table 339). "Chnverarty, adsorbed to Brill sandy loam soil (Table 2)
. Conversely,
Spproxiantely 80% of the amount of FC 143 adsorbed to: this approximately 80% of the amount of FC 143 adsorbed to this
SET ould De desorbed after three (3) desorpeion trials soil would be desorbed after three (3) desorption trials
((TTaabbllee 22)).. MM oboiblilltlytyg(~f FFCC 114433 wwaass ccaallccuullaatteedd uussiinngg tthhee sscchheemmee
described by umkot(85 Wheroby"wasorption coefsicients sre described by Hamaker
whereby adsorption coefficients are
Converted to u'constant, Kon: nich reflects the organic converted to a constant E , which reflects the organic
Contant of the Goll. Thisinvestigator has shows hat the content of the soil. T~lsCinvestigator has shown that the
Tolativo mobility of a group of pesticides could be dsternined relative mobility of a group of pesticides could be determined Tn This thehion and that the K: value could be correlated in this fashion and that the K value could be correlated with posticide mobility. In uBS1ying thin tent, FC 14 nad with pesticide mobility. In a~lying this test, FC 143 had
3 Ko value of 17. being alightiy lesa movile than chiarumpen, a K value of 17, being slightly less mobile than chloramben,
E0981" T258 "Wish wan Ene mont Roniie pesticide Based on KH Hf~iaoak~keferr'1'ss2-ww 8o,orrkwk'thi)c).h. was the most mobile pesticide based on
Table 2 Sof Sorption Tests on FC 143
TPaabrlaenot2er Soil Test Sorption Tests on FC 143sotutson
Resuts
PS0a1r1ameStoerrption AdsoTrepsttion
Soil Sorption
Water Solution ~s%, range Results2-7%
DAedssoorrppttiioonn
VWaatteerr 80% ~5%, ofranagmeoun2t-7%adsorbed
KooDesorption
Water
wr80% of amount adsorbed
NRR 3$ie)7eG.sssuuill,tBBtssia7sseoo6adff13oott3hnhneetwthhoaaeeuccluuKdtaoateecqqbuueassattttaiacicctotiinccsttoiodxaxaeiqqircucueiaiadttttyyiiccpccrrattreiceitttsseeittsrrcsiiaaalaalrreyeeessttmttaaaoabbbnbulculiitll1sasoa7hhtrteeejeddded the vertebrates and Lnvertobrascs hued in this cestr).
bbv((yTyrTaabbllee `Fe
NIOSH, FC 143 would the vertebrates and
i870 be noted that the: nvertebrate data corroisce weil with is to be noted that TtihaoscGorRrelaotbitoaninehdashheenentoenssteirnvgonfrersehponwtaerdiyWEBREeTTOogPecies: those data obtained
be considered practically non-tg~c to invertebrates used in this test" ". It the invertebrate data correlate well with
when testing fresh warm w~e~0~pecies.
VaTEaFennehgerdgigo-s-tt(fhrrUhcyyeneotdir?orssrrtteuiuTrlaeaddenistsiieeeuuonssllnttssw wtoeherccareaeoossmmspcbceproeosreinsnin.ststeerraaotccThTbteatsaeebebddlerlvefesefsttodeoc44tErEeGGaa&nbpnsidGdGeaP5FB 5t:eCi.ioodnn1lyoT5To5mm "hhieeica-csecses
".
tsLLsuatuaubbgbdloioerieretaashsttaoolrryy
w Yl(F(eToeaevuvarnneeebtgrlleessusnt4o8od3ann)e.g.rehetasatkIteotcenfhhiasatabonbiGgleaaeiieqntsnyyut1sea:ie,rtasailssslclluuyysrtrhvpveieAaivccvcaiecealeeefl:sp,pfetteacw wadedrteieigtoEghhhqfhtaau.ttiFtCtaaentnhhdd1ees43elleneiim nsnamgigtm ptttahahisttvuuueccbreehhlaaeiononnthrggareiaescslators
young stages of an aqua~cspecies are qulte sensitive indicators
11220000..00000055
worsen 3MA01410331
I
-4-
TTaabbllee 33
FC
FC
114433,,
RReessuullttss
ooff
TTeesstt OOrrggaanniissmmss
BBlluueeggiillll S Suunnffiisshh D Daapphhnniiaa mmaaggnnaa
0966mg/HH1"rr,~LI~C5q0 ,0 mg/1 556690 663322 663322
9966 HHoouurr AAccuuttee SSttaattiicc T Teessttiinngg LLiimmiittss
Lower, mg/l Upper mg/l
Lower, mg/1 Upper mg/1
55O0O0
663366
557700
669999
557700
669988
TTaabbllee 44 PPLeeenrrgccteehnnttaaaggneed EEWeggtgg H HWaeatitcgchhh,t, PPofeerrccPeeantnthtaaeggaeed MSSiuunrrnvvioivwvaalFl,r, yTToottaall
Lc((PoPe~nnimcmgeetehnppthharaalZnaedet~sioWpnpe~rstoommoWefele~iaFagsC#h))t 1dod43uufrr~iFnna&*~gtheEEaxxdppoos~suiunrrneeowttooFvvryaarryyiinngg
CCoonncceennttrraattiicooonnnceHnattrcahtio%nsSuorfviFvC33a00l1DD4a3%ayyss.,LvePPonosgsttthH Hmaatmtcchh Weight mg
m mgg//11
Hatch % Survival % Length mm Weight mg
110000
99%6
88~5
2200..b5
5599..55
5500
9922..55
904
2200
6622..55
2255
~aq9
9022..55
2211
7722
1122..55
9200..55
9977..55
2211
n71
66..22
9944..55
9933
2
21
66q0
C Coonnttrrooll
9966..55
9933..55
2200..55
68.5
68.5
Wawoorrkk ppeerrffoorrmmeedd bbyy EEGG&&GG BBiioonnoommiiccss LLaabboorraattoorryy,, IInncc.. bSsSutum.mmmaaPrrayyul,ttaabbalsleepassruutbbmmiiotfttteefddinattloo EErnenpvvoiirrrtoo.nnmmeennttaall LLaabboorraattoorryy,, 3M,
St. Paul, as part of final report.
ooiffnvccehhsetemimigicacatalillolyyn niinonddusuctceeaddtisttotoixxciiaccilitltyyy.. sigIInnniftthiheceanpptaarradam imfeeftteeerrressncuuennsddeerr w wi1ne0er0vreeemsgoot/ibbg1tt,aaaiitninroeeenddd..ucntoiAAotstntsatthhteeiwsetrhhieiicggahhrleeelscsytotrdFFsCeCigd n1144ii3nf3iccscauoonrnnvctcieevndnatitlfrrfaaetptriieeoronncnceenttetsesstteedd,, aas1nn0udd0ggm w ewseegtii/igg1vh,hett reo33df00udadcaatiyylossantseppnootw sstteornehhsaaetrtcetchch.o.irndeAA tdlhltethhionoduueggvshhuelrovtthphivemeessaeneltdpdaoeatfrtacaecnuaarmrteeulative wsttoueorxxgeigicceioisttbtyysi,v,eervttheohedef ddafooarsslaeeteexllencevevteeedlol,ssnsooe(ffst eFvFinCeCrat11hl44e33ordaatdetevrw weshlhoiipccom hhf emttnhahtegesnsoeieftupcpdhuheeem)nn,uoom mlaiitnnivaae wtthheeere eennovvbiisrreoornvnm meedenntftaeallr eccxooncnceceeednnt,trraa(tstiieoovnnessraoolff oFFrCdCe11rs4433.o. f magnitude),
11220000.00000066
33MMAAO011441100333322
Zs-
- 5 -
R4tBaoaas33se0e0add--bddnaaoooynyrnmaeetthlxxheeppoohssirreuuserrtsseeouulpltatssttthooooolffi1o00g00tthyhemmegg(//hThlliaissbttlFFooeCCppaa511t)44t.hh33oolddlooiiBgddogitichcnnaooaltgtlroececuxooxpannasmttmirrniiionabfbatuutittiooeenn,,
owotaanaronrgdsgdaaanns5b5iie/n/s1se1om0mn0rsmsattirlenreexexaahhhhttoiiieetbsbddhitittoeepgooddrrargogtuahaffpnnoaasilitts,stotm ymgysy3s./.lli1i(v0vTeSSeairrcbimm olieccnlihhtlaara5arn)onrl.gllgyyese,s,s,a,Bng ogd6it6ilh//l1l1l206/g1hrh0oyccyupooppentnestrrrtrpeprolaoolalftalsssesdiaa
Try. was
fry.
seen
in both
groups,
3/10
controls
and
2/10 treated
Table 5
Table 5
FH FH1rr0iiyy0ssttmoo((gppPP/aia~1tntmhheeoFpoplChlhoaoagt1g~ie4lsscc3aa%lpplrPoEEomxmxaa~almm aai#sni)n)aattieeiooxxnnppoosoosefsfddFPa33at00thh--eeddaaaadydyssMMittinononnooww
I00 mg/1FC 143a'b
Test
Test
MMaatteerriiaall
ObsNNeuurmmvbbaeetrriooonffs
HHiissttooFppiaanttdhhioongllsooggiiccaall
Observations
Findings
Control Control
10 10
663///111000 nffaoartttmtyayl lliivveerr cchhaannggeess
3/10 3/10
3/10
gg nioi1rlm 1l ahhlyyppeerrppllaassiiaa
100 mg/1 FC 143
100 mg/1FC 143
10
10
555///111000 25//1100
gnfnTa1ooa1rtrtm t1mtyayalhl yllipivevereprrlaccshhaiananggeess
2/10 gill hyperplasia
DDIiSsCcUuSsSsIioOnN TTssFhhCooeeuurr1ccpp4ee3rriimmaffaanoordrrryyatalolpplluurrppeperoononssvvveeilidrreooooffnmmaeenttnnhhttiiaaassnllalrryeddespaapoitotrsraattoggfeeiissnnpeeorrtttaaooettneepptddrriooavvrrliieeddlleeaeattniiv&anniggrssoiinnnttmoggoellneetal FsCk.]43 and to provide an analysis of potential environmental
risk.
(IIn1n)ddeevveesllcoohppeiminangtgizttehhdiissclaaonnsaaellydyssiisssystttwewoom mmeoonddveeillronttmyyeppneetss wawiinlldll 2)bbeeaddiissccuusssseedd:: ppS(riri)taaeccttaiiaccnsadacllhecmmmoooanSdtseelullzmeedrbbaasspceerlddoodsueoonncdtuusssyueessatgeooeffm. FeFCCnvi11r443o3nmaaettntaa mmaaannnduuff2aa)ccttauurriinngg
site and consumer product usage.
I1.. CClloosseedd sSyysstteemm TsTyhhseeteeemnn,vviirrsoocnnhmmeemenanttticccaaanlnlybbee rcceoopnrnsesisiddeeenrtreeeddd ttaoso: bbee aa cclloosseedd
system, schematically represented as:
SN
S011
Soil
N Vater 7 CCecrhqeqhemuueamiimiillnciiicabbalrrclsiisouunnmfeeinnnbtbteeeeedtrtriwwineenwgeeginnthtthihttniwwisoso aososyrrsysistntaaeglelmlllmem mttcihhigorrghmeehtepetarecectoossmmmtteappanababtrrllttiismmosheeFhnnttaapssnne,,rtubate arallellmaippnhhaassceeossnfioofnfedtthheewitddheeippniiccttaeeddsincegyvclelelee..compartment or pertubate
2120000..00000077
3MMAOAI01441100333333
6 -
Specfically we can represent the impact of FC 143 in the following manner:
to Protodegradatiop__ Ai YOSSI ~.. Volatilit~ gySoil ~ YNoo ddueggrraodtaatiioonn
No Photodegradatio~____ Air
74a
IwerWater
>20 g/1 (gel)
cuto sttrsat Sediment, No biodegradation
sorption phenomena as seen in soil
As illustrated, FC 143 enters the environment primarily
by means of the waterways ana secondarily via the
terrestrial ecosystem and atmosphere. This material
does not adsorb permanently to either soil and/or
sediment, remaining however in the water compartment.
It is not known whether FC 143 is volatile, a fact
which assumes importance in light O~l~eJ_ finding that
FC 143 does not undergo photolysis."
Based on the
foregoing, the waterways apparently are the environmental
sink for FC 143. Intermediate receptors have not been
identified.
2. Manufacturing and Consumer Model
The following construct illustrates various wherein FC 143 may enter the environment at site.
pathways the processing
11220000..00000088
3MA01410334
EA
|
Bayt 2s
Ch 1
5 --
Pod!
/
CT i
[Fy
--&
Ot, INR | i
]
2/4
La
|
Pls
;
bss
Ee 3-1H fEn S
Z, -
1200.0009
3MA01410335
Sh
|
~%~
mTTihhgeehtaabbooevvneteerffiiggtuuhrgreeenddveeipprioiccnttmssenpptrr.oojjeeccIttneedddippsacattuhhswwsaiaynysgs w uwshheeerreoefiinnFCFFCC 141134433
Dm bbryyi.gtthhhMt.ee eTPTnietekfefelrl,oonnt~C"'o'em)n"mccveooiraarctotiiinnanglm g eaaCnnhnddetm. ippchhaoIolnttooDgdgirirvsaaicppsuhhiisioccsnin,iignnddI uuuwssseattsrrioieefissnFfCww oiritm1thhe4d3
Dtbthyhraa. tttMhett.ooTPtetihhfkeleeio,irnr~Ckoopm w o"w)mlcleoeeadrdtcgiginaeegl pCnnroohoecFFmeCCsics11a.44l 33Dww Biaavassistestedieossnownw, ooutIulhlddiwsabbseeininggffeoeonrnrmem earrteaaidtteoendd,
bsIT yighhnaat;hvveeepodT d.eeeppfiilccottneed'd-'cttohhaiisstinnngoo
ww paraosstcteeessssi.ittuuaaBttaiisooendn
bboyyn
the following this information,
the following
sign; ~.
CIInhnemddoiilssicctuuess,ssiinnaggsitthmheielmamraannuoufbfasacectrtuvurareteiooonff FFtCCo 1t14h43a3twwioltuthhtliJJneeerrrdryyabH Hooovfffefeerr,,
was made. Chemolite,
was made.
a similar observation to that outlined above
cIInonncvveiienewtwraootffiotthnheeunaadbbeoorvveecwwoenediccataninonppsrroojwjeehcectrteitthnheealeelnnvvFiirCroonn1m m4e3enntmtaaalnlufactured
Is lost to the environment. concentration under conditions
is lost to the environment.
wherein
all
FC
143
manufactured
SsSiiinnmcpceleisw wtaaittceerrwwmaoaydysesl aarureetiltthiheezineegnnvviairroosnnim mnegenlntetaalploissniintnkksoffouorrrceFFCC fo11r4433,F, Caa 143 saacnniom ddncpeaalnitrrsiritvaviceteirromnwwooodufuelollddrueFetCnnilaaib1bzl4li3eengouonnnedeaertstooinagppwrlreooorjjseeptccottincaaatnnsesoeesussttiricitmeumaaatttfeieododrn.eFeCnnvvi1irr4oo3nnm meennttaall
concentration for FC 143 under a worst case situation.
WWteoe hthahavivsee msmaaiddmeeplissseetvveierrcaallmodaaesslss:uummppttiioonnss wwhhiicchh aarree ccoonnssiiddeerreedd bbaassiicc
to this simplistic model:
1)
1)
TT1osottadalilscpphrraoorddguueccdtt.iioonn iiss aatt CChheemmoloilittee aanndd aallll FFCC 114433 pprroodduucceedd
is discharged.
22)) NNoo FFCC 114433 i1ss rreemmoovveedd bbyy tthhee ttrreeaattmmeenntt ffaacciilliittyy..
3)
3)
A Allll eefffflluueenntt iiss ddiisscchhaarrggeedd iinnttoo tthhee M Misisssiissssiippppii RRiivveerr..
44)) FFCC 114433 iiss ddiisscchhaarrggeedd uunniiffoorrmmllyy..
5)
5)
R Rhieivnvecerer nfflolotowwsuaanbnjddecaatllll toootthhseeerarsoppnaaarrlaam meaetnteder/rsosraarcreelimccaootnnisscttaanntt,,
perturbations. hence not subject
perturbations.
to
seasonal
and/or
climatic
TThhee ffoorrmmuullaaee uusseedd iinn tthheessee pprroojjeeccttiioonnss iinncclluuddee::
11)
MWGo/smmmiiinn
-
=
~(RRiivveerr FFllooww,a CCTFFoMMd))uc(~tCCiooonnnvv,eerrsspileoornn,,aggnaanllu//mfftt33))(~TTiimmee,,mmilnn))
22)) MG/min x 1440 = MG/DayProduction, per annum
3) MLGb/sm/idnay x= 14(4m0g/l= MxGw/tD.ay lbs. HO per gal)(G/Day)
3) Lbs/day = (rag/1 x wt. lbs. H20 per gal)(MG/Day)
M MlioswisssifislssosiwipppprieicRoRriidvveerr1s ffll1oo0ww,00aa0tt
CH HFaaSssttiinnggss,,
MN,
MN,
based
based
on
on
a
a
10
10
year
year
low flow record is I0,000 CFS.
TTChohememettorocttiaalall 55ChyyeeemaarircapplrrsoodduDuiccvttiiiosoninonff.iigguurrIeenss uw wteierlreeizippnrrogovviitddheeeddsebbyyfiDDg.u.RRr.e. sR Riicckkeerr,, MCaainnosmsmeeiesssrttsiciimimpaaaptltieeddCRhieeevnmnevivricirarloobsnnemmleeDonniwtvtaiaCsllhieomccnooo.lnniccteeennIttnrwraaaustttiiioolcnnailzciooufnflgaFFtCCtehde11.s44e33 Dfiiunnirgiuttnrhheeges Mttihheessippseesrriiipoopddi 11R99i77v33e--r119977b88e,,lowtthheCeheEEmEECoClifftooerr wFFCaCs 11c4433alcwwuaalssatcceaadll.ccuullaDattueerdding
11220000..00001100
33MMAA0011441100333366.
whine ae those
fepoct> 7 (as 3)
_--
11220000..00001111
3aMMAA0O1t4110033377
Ll
So-
of 76 Lan" 1E has been determine that this marerial gl ttftfohoooerrbbweettahneet11e..6rp6peepr~rcgigio/oo/m1ed1paraa11ttt99m77eH86Hna-a-tss11tt90ii88inn33sgg"ss1ti,,3sheMpMpnnerr..noo,,vjjieerwccwohtthneeiimddlleeensatttttahhlee22..sEE44iEE~pCnCgk6//ppI1rrf.:ooorjjeeccSFSttiCienencddc1ee43,
otiiftthepitwsrsaotdddeueecrttteeirrcommoniimnnpeeaFddCrtmt1tehh4naa3tttwiaailttsl ttthhhneeeotpeprrnpeevrssloeesrnenotntntmeaannnatddnalppurrnoorsjjeieenaccksttoeenfddaobrllleFeeCvveell1ss43,
oenfviprroondmuecnttioanl FrCisk143undweirllwonrosttpcreasseenstitaunatuinornesa.sonable
environmental risk under worst case situations.
cCOoNnCcLuUsSiIoOnNsS
UsUennlddeeecrrtettdhheephtteyessstticocccoohnneddmiiittciiaoolnnssaneedmmpplleoonyyveeiddroniimnnenccthhaaalrraaccpttreeorpreiirzztiiinneggs
.
selected physlcochemical and environmental properties
of FC 143 it has been determined that this material
1I)) iiss eexxttrreemmeellyy wwaatteerr ssoolluubbllee,, ffoorrmmiinngg aa ggoell aatt 2200 gg//l.17 |:I"
232))) 43))
hhi1assass rreaaennssiissnntt--aaoonnccttttaantntoooollm/m/iwlwcacartrtoeoebrbrilaappllaarrttddiieettggiirroaaonddnaattcciiooooeennffffiicciieenntt is extremely mobile in Brill sandy loam soil
ooffa~ 55NL dey r ~~.. wo~
545))) siiinsunrvaeainnxvtraeeelggm ,gg-e-fllfyrreyyngmtssohttubudidolyyre wddineiididgBhnnrtoolttllfaaofslfafflneeodccwytitnghhloaaatatmcch3ha0sabobidilialliyittyye,,xposure h&e
ssttoiuogrnFFvCiCifvi11ac44la35,ntaalettndegssguuthrbbelleooe.trthhaw alSleiimlgleiehlvvtaeerlfllossyll,ttooownoi&angassdttavaaettrii3ss0stetiidcecaayfafllleleycyxtposure [ed
wwsiainagsdsnucnniefooidttceeaddpnatoothnnodltteoiigsgsrsyseu.ueee. ss
examined for evidence Similarly, no adverse
examined for evidence
of chemical effect
of chemical
6)
6)
hiiinsesdnucttoceoedbbieetspffaoeothuunnonvddilorgppoyrnrimi.m menaatrraiilllyysiiinnnk.tthheeNow waatstepererciccofomimpcpaarirtntmm teeenrntmt,e, diate
7) whrTeoeecuncleecdeppttoohirtarsssvehheaaannvvveeirgohbanetem eeinnmeantiitdedadeelnnetstniiinfvfiiikeer.ddo.n. mNeontsaplecciofniccenintrteartm ioendiate
7) ow oaaifn1flot1luoaaldFpFpCCptprhhreooa11xv44xMi33eim imsaw waasnteetiererseleelysysimm tipa11m apn..ni6ua6u-ft-2efaR2a.dci.4cvt4M te~upurgrnrg./eev/1dd1i,r,oaantutum nnCC ddeheehnreretmamocclioooinclnitdotdeeinittciiaaeoonnnnddntssrddaww iitsihsohcecenhrhraeaerirignngeedd
8)
8)
w wbiniailstloleldntnhoootent ppM prrreeeissssseeeinnnstttsipaaannnpdiuupR nnrrrioeevjaaeessroco. tnneaadbblleeproeednnuvvciirtroionnom mneenlntetavalellsrr,iisskk
ubsaasegde poanttperrenssenettea.nd pro~ected production levels,
usage patterns etc.
BIBLIOGRAPHY
BIBLIOGRAPHY
1. MMeennaddneedll,,SupAA.p.,,ortTT"ee,cchhnnJiiaccnaaullaryRReepp1oo7rr,tt::1079"".AAnnaallyyttiiccaall MMeetthhooddoollooggyy and Support", January 17, 1979.
2. RReeiiSmnteeurrd,,iesEE..AAo..f,, 'FTTleeuccohhrnnoiicccaaarllboRRneesppoo-rrtt1::11",""BBJiiuoolddyeeggrr19aa,ddaatt1li97oo8nn. Studies of Fluorocarbons -III", July 19, 1978.
3. WWeellassnhhd,,'FCSS'..KK1..4,,3 ToTneecchhSnnoiiilcc"aa,ll RRFeeeppboorrrutta::ry "2"7AA,ddssoo1rr97pp8tt.iioonn ooff FFCC 9955 and FC 143 on Soil", February 27, 1978.
44.. UUSS//VEEaPcPrAAo--- iMMneevttehhrootddessbrafftooerrsAAccanuudtteeAmTTpoohxxiiibcciiiattnyys,TTeessEttcowwliiottghihcaFFliisshh,, RMeasceraor-cihnveSretreibersat6e6s0/3a-n7d5-A0m0p9h,ibi1a0n7s5,. Ecological
Research Series 660/3-75-009, 1975.
5. CChhiiaoonuud,, RoCCdaargryyerTT..i,,. VVKioihrrnggeiirllt:HH.. FFPrraeereetddi,,tioDDnaavviiCddoefWW.,ficSSiccehhnmmteeddddaiinnndgg,, BEB Ea1nni9nld7voov7iaai.rcRrcoocconnuudmmm m geueeunlrntalatatLatlii.loonnSK SccoiooihefefnnneccSSreeeet:lleeaannccddtP teeaddTTreetcOO icthrhringngooaoanlnnloioigccgCyyo,cC , ehhfe11efm1~m ii(c(c55ii)cae):al:nlsts,44, 7a75n5-d-447788,,
1977.
1~220000..00~12
M3MAAO01144110033338
.
ET
10-
6. HHaamEmaxakpkeeerrr,i, meJJ..nW Wt.s.,", ""inIInnCttheeerrmppirrceeattlaastt,iioonnHumooaffnSSoHoieilalltLLheeaacachnhidinnggthe VEEEonnxlvvp.iierrroo1inm n, mmeeDnenonttwst,", ChAAinemC CiC ooclhlalleleemcctUitciSioaAolnns, oMofiHfdulDDmaooanwwnd,H S ScceiMaieielnctnhthtiiifgafianiccnd PP4th8aa6epp4ee0rr.ss,,
Vol. 1, Dow Chemical USA Midland, Michigan 48640.
7. RReeg"gi7is6sttrrEyyditooiffonTT,ooxxiCihccriE Esfftffeeenccsttessn,ooffH.CCEhh.ee,mmiciacanaldl SES.uuJbb.ssttaFanancicerescs,h,ild,
E Ea'7dnd6sds.. WEppedl..xifxtvaviorenaa;nn, ddNCaC Chiti,ri,losnUUteaSSnlDsDeeIepnnpa,sartrttH im mt.euE entn.te,t oaofnfofdr H HOeEeca.alcJltu.thph,aF , taiEEiodrdnucuachcaliatltidioo,nn,,
Safety and Health, Washington, and Welfare; National Institute
Safety and Health, Washington,
D.C., for
D.C.,
June, 1976. Occupational June, 1976.
8. WWeellSttteeurrd,,iesAA,..NN..,,FCTTee2cc1hh4nn-ii3cc0aalllotRReepp5oo6rr6tt,:: FeAbAqrquuuaaatrtiyicc 1T6T,ooxxii1cc9ii79tt.yy Studies, FC 214-30 lot 566, February 16, 1979.
9. WWeellSttteeurrd,,iesAA,..NN..P,,C TT23ee2cchhnnliiotccaall610RR,eeppooJrrattn::uaryAAqquu1aa7,ttiicc197TT9oo.xxiicciittyy Studies, FC 232 lot 610, January 17, 1979.
1100.. WWeellRtteeeprro,,rt,AA..NNF..C,,'95TTeecchhMannriiccchaa,ll RR1ee9pp79oo.rrtt:: FFiinnaall CCoommprperehheennssiivvee Report, FC 95 March, 1979.
1111.. TTooddSddt,,udyJJ..WNu..s,,ingTTeeccShhinnmiiucclaaalltedRReeppSoourrnttl::ightFF,CC F11e4433brPuPhahorotytooll2,yyssii1ss079. Study using Simulated Sunlight, February 2, 1979.
1122.. WWeellRtteeeprro,,rtAA..oNNn.. FTMTeecc3hh4n2n2ii,ccaallFebRRreepupooarrrtty:: 2, FFii1nn9aa7l9l. CCoommpprreehheennssiivvee Report on FM 3422, February 2, 1979.
11220000..00001133
33MMAA0011441100333399
