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3 GLP10-01-02 Interim Report 05: Analysis for PFOS, PFHS and PFBS in Avenue A Soils and Sediments Collected June/Julv 2010 Study Title 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program Data Requirement EPA TSCA Good Laboratory Practice Standards 40 CFR Part 792 Study Director Jaisimha Kesari P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Phone: 610-701-3761 Principle Analytical Investigator Cleston C. Lange, Ph.D. 3M Environmental Laboratory Interim Report Completion Date Date of signing Performing Laboratory 3M Environmental Health and Safety Operations Environmental Laboratory 3M Center, Bldg 260-05-N-17 St. Paul, MN 55144 Project Identification GLP-10-01-02-05 Total Number of Pages 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 This page has been reserved for specific country requirements. 3M Study GLP10-01-02 Interim Report 05 Page 2 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 GLP Compliance Statement Report Title: GLP10-01-02 Interim Report 05. Analysis for PFOS, PFHS and PFBS in Avenue A Soils and Sediments Collected June/July 2010. 3M Environmental Laboratory Analytical Protocol GLP-10-01-01: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program. This analytical phase was conducted in compliance with Toxic Substances Control Act (TSCA) Good Laboratory Practice (GLP) Standards, 40 CFR 792, with the exceptions listed below: Exceptions to GLP compliance: Test, control and reference substances were not all characterized under GLPs. As these are real-life environmental samples, there was no dosing and no specific test substance for this study. Gar Hohenstein, Sponsor Representative / Date Jaisimha Kesari, P.E., DEE, Study Director Date 3M Study GLP10-01-02 Interim Report 05 Page 3 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Quality Assurance Statement Report Title: GLP10-01-02 Interim Report 05. Analysis for PFOS, PFHS and PFBS in Avenue A Soils and Sediments Collected June/July 2010. 3M Environmental Laboratory Analytical Protocol GLP-10-01-01: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program. This report and the accompanying data were audited by the 3M Environmental Laboratory Quality Assurance Unit (QAU), as indicated below. The findings were reported to the principal investigator (P.I.), laboratory management and study director. Inspection Dates March 3,2010 March 25,2010 Feb 2-4 & 7-9,2011 Phase Protocol In-phase Report and Data P .l. March 3,2010 March 31,2010 Feb 10, 2011 D ate Reported to Study D irector M anagem ent March 3, 2010 March 31,2010 Feb 10,2011 Study D irector March 3, 2010 March 31,2010 Feb 10,2011 3 - fO- I( Date 3M Study GLP10-01-02 Interim Report 05 Page 4 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table of Contents GLP Compliance Statement.............................................................................................................. 3 Quality Assurance Statement............................................................................................................ 4 1 Study Information......................................................................................................................... 7 2 Summary....................................................................................................................................... 8 3 Introduction..................................................................................................................................13 4 Test, Control and Reference Substances.................................................................................. 14 5 Test System................................................................................................................................ 15 6 Method Summary........................................................................................................................15 6.1 Methods.......................................................................................................................... 15 6.2 Sample Collection............................................................................................................16 6.3 Sample Preparation......................................................................................................... 16 6.4 Percent Soil Moisture Determination...............................................................................17 6.5 LC/MS/MS Analysis........................................................................................................17 7 Analytical Results........................................................................................................................19 7.1 Calibration....................................................................................................................... 19 7.2 Limits of Quantitation (LOQs)......................................................................................... 21 7.3 Continuing Calibration.....................................................................................................21 7.4 Blanks..............................................................................................................................21 7.5 Laboratory Control Spikes (LCSs).................................................................................. 22 7.6 Laboratory Matrix Spikes (LMSs)................................................................................... 24 7.7 Percent Soil Moisture Determinations............................................................................ 24 7.8 Individual Sample Results............................................................................................... 27 8 Conclusion.................................................................................................................................. 50 9 Data/Sample Retention...............................................................................................................51 3M Study GLP10-01-02 Interim Report 05 Page 5 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 10 List of Attachments.................................................................................................................... 51 11 Signatures.................................................................................................................................. 51 List of Tables Table 1. Summarized Results for Decatur Avenue A Soils and Sediments (June/July 2010)........ 8 Table 2. LMS Recoveries for Decatur Avenue A Soils and Sediments (June/July 2010)...............11 Table 4. Instrument Information........................................................................................................18 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053)................................................18 Table 6. Mass Transitions..................................................................................................................18 Table 7. PFOS Calibration Summary...............................................................................................20 Table 8. PFHS Calibration Summary................................................................................................20 Table 9. PFBS Calibration Summary................................................................................................21 Table 10. LCS Results for PFOS (linear + branched isomers) Recovery...................................... 22 Table 11. LCS Results for PFHS (linear + branched isomers) Recovery...................................... 23 Table 12. LCS Results for PFBS Recovery...................................................................................... 23 Table 13. Percent Moistures for Decatur Avenue A Soils & Sediments Collected June/July 2010.24 Table 14. IndividualPFOS Results for Decatur Avenue A Soils (June/July 2010).......................... 27 Table 15. IndividualPFHS Results for Decatur Avenue A Soils (June/July 2010).......................... 35 Table 16. Individual PFBS Results for Decatur Avenue A Soils (June/July 2010).......................... 43 3M Study GLP10-01-02 Interim Report 05 Page 6 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 1 Study Information Sponsor 3M Company Sponsor Representative Gary A. Hohenstein Environmental Manager Special Projects, EHS Operations Bldg 224-5W-03 St. Paul, MN 55144 Phone: (651) 737-3570 gahohenstein@mmm.com Study Director Jaisimha Kesari, P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Study Analytical Testing Facility 3M EHS Operations Environmental Laboratory Building 260-5N-17 St. Paul, MN 55144 Study Personnel (3M Environmental Laboratory) William K. Reagen, Ph.D., Laboratory Manager Cleston C. Lange, Ph.D., Principal Analytical Investigator Gabriel P. McMurtry, Laboratory Technician (Pace Analytical, Professional Services) Kevin J. Eich, Laboratory Technician (Quality Associates, Professional Services) Study Dates Study Initiation: March 24, 2010 Interim Analytical Initiation: October 28, 2010 Interim Analytical Completion: January 05, 2011 Interim Report Completion: February 1,2011 Location of Archives All original raw data and analytical reports have been archived at the 3M Environmental Laboratory according to 40 CFR Part 792. The test substance and analytical reference standard reserve samples are archived at the 3M Environmental Laboratory according to 40 CFR Part 79 3M Study GLP10-01-02 Interim Report 05 Page 7 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 2 Summary One hundred and eleven (111) soils and sediments collected in June/July 2010 from the vicinity of Avenue A at the 3M Decatur, AL site, and two soil trip blanks, were analyzed for PFOS, PFHS and PFBS. Triplicate aliquots of each sample were extracted and analyzed by LC/MS/MS. The third replicate was fortified with a known quantity of the target analytes and served as a laboratory matrix spike (LMS) sample to evaluate the sample-specific analyte recovery. Finally, the percent moisture of each soil was determined and r reported on a dry weight basis, as summarized in Table 1. PFOS was the highest concentration analyte in each sample, and ranged from 5.48 ng/g to 14,600 ng/g. The PFHS and PFBS concentrations were lower than PFOS in all samples, and ranged from BLQ to 1460 ng/g for PFHS and 0.180 ng/g to 171 ng/g for PFBS. The LMS recoveries determined all results were within 100+30%, with the exception of 22 out of 337 reported results in Table 1 which were reported with an expanded uncertainty 100 + 60% as footnoted in results tables. Three results were not reported (NR). The soil trip blanks were BLQ for all analytes, except for one PFOS result in the second trip blank which was slightly above the LLOQ due to possible carryover from a previously injected sample during the analysis. Overall, the results of trip blanks indicated that sample integrity was maintained adequately during shipping and collection. A reliable result could not be attained for PFHS and PFBS in sample GLP10-01-01-095 based on LMS recoveries, therefore, those two analytes were not reported (NR) for that sample. Four aqueous equipment rinseate samples were received with the samples and analyzed by a separate water analysis procedure and reported elsewhere for those sample IDs: DAL SS SD03 RB 1000625, DAL SS SD08 RB 100625, DAL SS GP09 RB 100708 and DAL SS GP11 RB 100708. Analyte concentrations in those equipment rinseates measured at less than the nominal LLOQ for PFBS (< 0.0255 ng/mL), PFHS (< 0.103 ng/mL) and PFOS (< 0.255 ng/mL), and those results reported elsewhere in GLP10-01-02 interim report 06. Table 1. Summarized Results for Decatur Avenue A Soils and Sediments (June/July 2010) L IM S ID GLP10-01-02-05-001 GLP10-01-02-05-002 GLP10-01-02-05-003 GLP10-01-02-05-004 GLP10-01-02-05-005 GLP10-01-02-05-006 GLP10-01-02-05-007 GLP10-01-02-05-009 GLP10-01-02-05-010 GLP10-01-02-05-011 GLP10-01-02-05-012 GLP10-01-02-05-013 GLP10-01-02-05-014 GLP10-01-02-05-015 GLP10-01-02-05-016 GLP10-01-02-05-017 GLP10-01-02-05-018 GLP10-01-02-05-019 GLP10-01-02-05-021 GLP10-01-02-05-022 GLP10-01-02-05-023 GLP10-01-02-05-024 GLP10-01-02-05-025 S a m p le ID DAL SD TRIP1 0 100624 DAL SD SD01 0 0000 DAL SD SD01 0 0005 DAL SD SD02 0 0000 DAL SD SD02 0 0005 DAL SD SD03 0 0000 DAL SD SD03 0 0005 DAL SD SD04 0 0000 DAL SD SD04 0 0005 DAL SD SD05 0 0000 DAL SD SD05 0 0005 DAL SD SD06 0 0000 DAL SD SD06 0 0005 DAL SD SD07 0 0000 DAL SD SD07 0 0005 DAL SD SD08 0 0000 DAL SD SD08 DB 0000 DAL SD SD08 0 0005 DAL SD SD09 0 0000 DAL SD SD09 0 0005 DAL SD SD10 0 0000 DAL SD SD10 0 0005 DAL SD SD11 0 0000 A verag e C o n cen tratio n (ng/g; d ry w eig h t) PFOS BLQ 225 129 6770 1070 897 559 2120 1910 525 310 617 338 [b] 1660 [a] 2430 [c] 521 540 93.2 1300 1250 4570 [a] 7830 [a] 1560 PFHS BLQ 2.78 [b] 1.72 [b, c] 64.5 12.7 48.1 19.0 178 79.0 34.5 26.0 39.6 18.9 51.8 60.9 42.9 [b] 46.0 9.03 135 101 1030 459 156 PFBS BLQ 0.611 0.605 6.03 1.21 7.31 3.41 24.9 8.93 4.72 4.35 6.24 3.37 8.75 [b] 9.48 [b] 5.28 4.80 1.62 27.5 14.0 171 [a] 66.5 [a] 8.42 3M Study GLP10-01-02 Interim Report 05 Page 8 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 1. Summarized Results for Decatur Avenue A Soils and Sediments (June/July 2010) L IM S ID GLP10-01-02-05-026 GLP10-01-02-05-027 GLP10-01-02-05-028 GLP10-01-02-05-029 GLP10-01-02-05-030 GLP10-01-02-05-031 GLP10-01-02-05-032 GLP10-01-02-05-033 GLP10-01-02-05-034 GLP10-01-02-05-035 GLP10-01-02-05-036 GLP10-01-02-05-037 GLP10-01-02-05-038 GLP10-01-02-05-039 GLP10-01-02-05-040 GLP10-01-02-05-041 GLP10-01-02-05-042 GLP10-01-02-05-043 GLP10-01-02-05-044 GLP10-01-02-05-045 GLP10-01-02-05-046 GLP10-01-02-05-047 GLP10-01-02-05-048 GLP10-01-02-05-049 GLP10-01-02-05-050 GLP10-01-02-05-051 GLP10-01-02-05-052 GLP10-01-02-05-054 GLP10-01-02-05-055 GLP10-01-02-05-056 GLP10-01-02-05-057 GLP10-01-02-05-058 GLP10-01-02-05-059 GLP10-01-02-05-060 GLP10-01-02-05-061 GLP10-01-02-05-062 GLP10-01-02-05-063 GLP10-01-02-05-064 GLP10-01-02-05-065 GLP10-01-02-05-066 GLP10-01-02-05-067 GLP10-01-02-05-068 GLP10-01-02-05-069 GLP10-01-02-05-070 GLP10-01-02-05-071 GLP10-01-02-05-072 GLP10-01-02-05-073 GLP10-01-02-05-074 GLP10-01-02-05-075 S a m p le ID DAL SD SD11 0 0005 DAL SD SD12 0 0000 DAL SD SD12 DB 0000 DAL SD SD12 0 0005 DAL SD SD13 0 0000 DAL SD SD13 0 0005 DAL SD SD14 0 0000 DAL SD SD14 0 0005 DAL SD SD15 0 0000 DAL SD SD15 0 0005 DAL SD SD16 0 0000 DAL SD SD16 DB 0000 DAL SD SD16 0 0005 DAL SD SD17 0 0000 DAL SD SD17 0 0005 DAL SS SS01 0 0000 DAL SS SS01 0 0005 DAL SS SS02 0 0000 DAL SS SS02 0 0005 DAL SS SS03 0 0000 DAL SS SS03 0 0005 DAL SS SS03 DB 0005 DAL SS SS04 0 0000 DAL SS SS04 0 0005 DAL SS TRIP1 0 0000 DAL SS SS05 0 0000 DAL SS SS05 0 0005 DAL SS SS06 0 0000 DAL SS SS06 0 0005 DAL SS SS06 DB 0005 DAL SS SS07 0 0000 DAL SS SS07 0 0005 DAL SS SS08 0 0000 DAL SS SS08 DB 0000 DAL SS SS08 0 0005 DAL SS SS09 0 0000 DAL SS SS09 0 0005 DAL SS GP01 0 0000 DAL SS GP01 0 0005 DAL SS GP01 0 0020 DAL SS GP01 0 0060 DAL SS GP02 0 0000 DAL SS GP02 0 0005 DAL SS GP02 0 0020 DAL SS GP02 DB 0020 DAL SS GP02 0 0120 DAL SS GP03 0 0000 DAL SS GP03 0 0005 DAL SS GP03 0 0020 A verag e C o n cen tratio n (ng/g; d ry w eig h t) PFOS 786 3210 3270 451 1250 1480 [b] 9130 5370 14600 13200 7060 8590 3120 10700 7120 750 919 405 [b] 168 NR 2110 2880 506 [a, b] 179 0.305 [d] 10600 4040 331 132 164 747 3140 53.9 46.5 26.2 635 416 366 125 292 29.0 66.3 76.7 195 173 5.48 700 2070 1450 PFHS 57.9 289 293 77.0 123 138 [b] 1450 [b] 1460 399 146 764 830 569 1080 853 4.73 5.06 7.26 54.6 212 [b] 118 109 5.59 [a] 2.03 BLQ 288 67.6 2.61 0.975 1.17 59.6 66.3 4.80 4.01 1.70 7.02 4.53 5.99 4.92 [b] 10.0 3.11 0.175 BLQ 0.113 BLQ 1.58 41.8 252 321 PFBS 4.10 16.9 17.3 5.31 10.4 12.6 [b] 129 [a] 100 [a, e] 52.3 [a] 17.3 27.2 [b] 33.6 22.6 28.2 24.8 0.909 0.452 0.786 4.11 4.09 5.27 3.92 2.61 0.966 BLQ 22.5 6.71 1.27 0.433 0.533 11.6 9.20 1.67 1.42 1.61 1.53 1.44 [a] 5.73 3.86 3.55 2.11 1.37 0.701 0.345 0.392 2.59 5.71 32.6 40.1 3M Study GLP10-01-02 Interim Report 05 Page 9 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 1. Summarized Results for Decatur Avenue A Soils and Sediments (June/July 2010) L IM S ID S a m p le ID A verag e C o n cen tratio n (ng/g; d ry w eig h t) PFOS PFHS PFBS GLP10-01-02-05-076 DAL SS GP03 DB 0020 1240 [a] 417 49.0 GLP10-01-02-05-077 DAL SS GP03 0 0050 352 82.2 12.8 GLP10-01-02-05-078 DAL SS GP04 0 0000 840 [a, b] 3.32 4.51 GLP10-01-02-05-079 DAL SS GP04 0 0005 513 1.55 2.16 GLP10-01-02-05-080 DAL SS GP04 0 0020 99.2 4.83 1.72 GLP10-01-02-05-081 DAL SS GP04 0 0050 33.2 12.8 2.78 GLP10-01-02-05-082 DAL SS GP05 0 0000 346 8.82 12.3 GLP10-01-02-05-083 DAL SS GP05 0 0005 381 12.7 5.29 GLP10-01-02-05-084 DAL SS GP05 0 0020 429 7.95 [b] 1.75 GLP10-01-02-05-085 DAL SS GP05 0 0055 1080 48.6 5.11 GLP10-01-02-05-087 DAL SS GP06 0 0000 209 4.09 1.86 GLP10-01-02-05-088 DAL SS GP06 0 0005 447 2.79 0.801 GLP10-01-02-05-089 DAL SS GP06 0 0020 136 1.46 0.180 GLP10-01-02-05-090 DAL SS GP06 0 0110 41.4 1.86 0.858 GLP10-01-02-05-091 DAL SS GP07 0 0000 599 17.7 1.69 GLP10-01-02-05-092 DAL SS GP07 0 0005 3680 34.7 0.991 GLP10-01-02-05-093 DAL SS GP07 0 0020 1870 [b] 25.3 1.22 GLP10-01-02-05-094 DAL SS GP07 0 0130 14000 [b] 146 [a] 12.7 [a] GLP10-01-02-05-095 DAL SS GP08 0 0000 5160 NR NR GLP10-01-02-05-096 DAL SS GP08 0 0005 770 11.3 0.320 GLP10-01-02-05-097 DAL SS GP08 DB 0005 1010 13.7 0.397 GLP10-01-02-05-098 DAL SS GP08 0 0020 322 7.32 0.231 GLP10-01-02-05-099 DAL SS GP08 0 0050 337 10.7 0.693 GLP10-01-02-05-101 DAL SS GP09 0 0000 3630 [b] 244 17.8 GLP10-01-02-05-102 DAL SS GP09 0 0005 1630 43.1 4.71 GLP10-01-02-05-103 DAL SS GP09 DB 0005 2280 [a] 64.6 [a] 5.73 GLP10-01-02-05-104 DAL SS GP09 0 0020 331 5.23 1.37 GLP10-01-02-05-105 DAL SS GP09 0 0050 64.3 6.26 3.83 GLP10-01-02-05-106 DAL SS GP10 0 0000 734 [b] 141 28.4 GLP10-01-02-05-107 DAL SS GP10 0 0005 581 229 46.5 [a] GLP10-01-02-05-108 DAL SS GP10 0 0020 297 162 99.8 [a] GLP10-01-02-05-109 DAL SS GP10 0 0060 139 [a] 126 [a] 76.6 [a] GLP10-01-02-05-111 DAL SS GP11 0 0000 157 20.9 3.57 GLP10-01-02-05-112 DAL SS GP11 0 0005 123 45.0 6.29 GLP10-01-02-05-113 DAL SS GP11 0 0020 242 30.7 23.8 GLP10-01-02-05-114 DAL SS GP11 0 0065 290 33.2 5.68 GLP10-01-02-05-115 DAL SS GP11 DB 0065 579 55.0 7.68 GLP10-01-02-05-116 DAL SS GP12 0 0000 666 4.77 0.607 GLP10-01-02-05-117 DAL SS GP12 0 0005 407 2.75 0.521 GLP10-01-02-05-118 DAL SS GP12 0 0020 460 6.81 1.88 GLP10-01-02-05-119 DAL SS GP12 0 0170 59.1 9.74 2.01 Sample-specific LMS results were within 100 + 30%, unless noted. NR; not reported because result was outside of 100 + 60% reporting criterion. BLQ; LC/MS/MS analyte response was below the nominal 0.200 ng/g lower limit of quantitation. [a] ; value was reported from a re-assay result when original result had a poor QC result [b] ; LMS recovery was outside of 100 + 30%, but was within reporting limits of 100 + 60%. [c] ; RPD of duplicate sample results was greater than 50% [d] ; Value reported for one result, duplicate result was BLQ. Value likely caused from carryover of PFOS from previous sample [e] ; Value was determined by external standard quant because LMS sample did not receive IS addition._____________ 3M Study GLP10-01-02 Interim Report 05 Page 10 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 2. LMS Recoveries for Decatur Avenue A Soils and Sediments (June/July 2010) L IM S ID GLP10-01-02-05-001 GLP10-01-02-05-002 GLP10-01-02-05-003 GLP10-01-02-05-004 GLP10-01-02-05-005 GLP10-01-02-05-006 GLP10-01-02-05-007 GLP10-01-02-05-009 GLP10-01-02-05-010 GLP10-01-02-05-011 GLP10-01-02-05-012 GLP10-01-02-05-013 GLP10-01-02-05-014 GLP10-01-02-05-015 GLP10-01-02-05-016 GLP10-01-02-05-017 GLP10-01-02-05-018 GLP10-01-02-05-019 GLP10-01-02-05-021 GLP10-01-02-05-022 GLP10-01-02-05-023 GLP10-01-02-05-024 GLP10-01-02-05-025 GLP10-01-02-05-026 GLP10-01-02-05-027 GLP10-01-02-05-028 GLP10-01-02-05-029 GLP10-01-02-05-030 GLP10-01-02-05-031 GLP10-01-02-05-032 GLP10-01-02-05-033 GLP10-01-02-05-034 GLP10-01-02-05-035 GLP10-01-02-05-036 GLP10-01-02-05-037 GLP10-01-02-05-038 GLP10-01-02-05-039 GLP10-01-02-05-040 GLP10-01-02-05-041 GLP10-01-02-05-042 GLP10-01-02-05-043 GLP10-01-02-05-044 GLP10-01-02-05-045 GLP10-01-02-05-046 GLP10-01-02-05-047 GLP10-01-02-05-048 GLP10-01-02-05-049 S a m p le ID DAL SD TRIP1 0 100624 DAL SD SD01 0 0000 DAL SD SD01 0 0005 DAL SD SD02 0 0000 DAL SD SD02 0 0005 DAL SD SD03 0 0000 DAL SD SD03 0 0005 DAL SD SD04 0 0000 DAL SD SD04 0 0005 DAL SD SD05 0 0000 DAL SD SD05 0 0005 DAL SD SD06 0 0000 DAL SD SD06 0 0005 DAL SD SD07 0 0000 DAL SD SD07 0 0005 DAL SD SD08 0 0000 DAL SD SD08 DB 0000 DAL SD SD08 0 0005 DAL SD SD09 0 0000 DAL SD SD09 0 0005 DAL SD SD10 0 0000 DAL SD SD10 0 0005 DAL SD SD11 0 0000 DAL SD SD11 0 0005 DAL SD SD12 0 0000 DAL SD SD12 DB 0000 DAL SD SD12 0 0005 DAL SD SD13 0 0000 DAL SD SD13 0 0005 DAL SD SD14 0 0000 DAL SD SD14 0 0005 DAL SD SD15 0 0000 DAL SD SD15 0 0005 DAL SD SD16 0 0000 DAL SD SD16 DB 0000 DAL SD SD16 0 0005 DAL SD SD17 0 0000 DAL SD SD17 0 0005 DAL SS SS01 0 0000 DAL SS SS01 0 0005 DAL SS SS02 0 0000 DAL SS SS02 0 0005 DAL SS SS03 0 0000 DAL SS SS03 0 0005 DAL SS SS03 DB 0005 DAL SS SS04 0 0000 DAL SS SS04 0 0005 PFOS 102% 103% 109% 105% 112% 103% 96.0% 103% 97.1% 99.8% 96.8% 99.7% 68.0% [b] 91.3% [a] 87.0% [c] 112% 83.1% 96.4% 86.6% 101% 101% [a] 72.8% [a] 112% 97.9% 89.3% 90.2% 90.3% 96.0% 150% [b] 122% 85.4% 113% 124% 98.4% 87.1% 99.1% 75.7% 127% 88.5% 112% 133% [b] 107% NR 78.5% 80.3% 146% [a, b] 104% LM S R ecovery (% ) PFHS 99.1% 43.3% [b] 56.5% [b, c] 95.1% 100% 106% 119% 97.8% 98.8% 112% 120% 109% 102% 97.9% 107% 137% [b] 96.7% 103% 108% 104% 82.4% 76.2% 102% 104% 100% 97.9% 104% 101% 142% [b] 151% [b] 82.0% 102% 107% 110% 113% 101% 91.7% 117% 113% 109% 116% 96.4% 139% [b] 109% 109% 101% [a] 106% PFBS 108% 109% 123% 76.0% 87.9% 105% 130% 113% 119% 111% 109% 118% 114% 131% [b] 131% [b] 105% 107% 109% 106% 110% 86.6% [a] 82.4% [a] 114% 106% 105% 114% 109% 108% 159% [b] 97.9% [a] 94.6% [a] 102% [a, e] 116% 146% [b] 111% 107% 104% 111% 101% 110% 101% 111% 105% 79.4% 103% 98.7% 110% 3M Study GLP10-01-02 Interim Report 05 Page 11 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 2. LMS Recoveries for Decatur Avenue A Soils and Sediments (June/July 2010) L IM S ID GLP10-01-02-05-050 GLP10-01-02-05-051 GLP10-01-02-05-052 GLP10-01-02-05-054 GLP10-01-02-05-055 GLP10-01-02-05-056 GLP10-01-02-05-057 GLP10-01-02-05-058 GLP10-01-02-05-059 GLP10-01-02-05-060 GLP10-01-02-05-061 GLP10-01-02-05-062 GLP10-01-02-05-063 GLP10-01-02-05-064 GLP10-01-02-05-065 GLP10-01-02-05-066 GLP10-01-02-05-067 GLP10-01-02-05-068 GLP10-01-02-05-069 GLP10-01-02-05-070 GLP10-01-02-05-071 GLP10-01-02-05-072 GLP10-01-02-05-073 GLP10-01-02-05-074 GLP10-01-02-05-075 GLP10-01-02-05-076 GLP10-01-02-05-077 GLP10-01-02-05-078 GLP10-01-02-05-079 GLP10-01-02-05-080 GLP10-01-02-05-081 GLP10-01-02-05-082 GLP10-01-02-05-083 GLP10-01-02-05-084 GLP10-01-02-05-085 GLP10-01-02-05-087 GLP10-01-02-05-088 GLP10-01-02-05-089 GLP10-01-02-05-090 GLP10-01-02-05-091 GLP10-01-02-05-092 GLP10-01-02-05-093 GLP10-01-02-05-094 GLP10-01-02-05-095 GLP10-01-02-05-096 GLP10-01-02-05-097 GLP10-01-02-05-098 GLP10-01-02-05-099 GLP10-01-02-05-101 S a m p le ID DAL SS TRIP1 0 0000 DAL SS SS05 0 0000 DAL SS SS05 0 0005 DAL SS SS06 0 0000 DAL SS SS06 0 0005 DAL SS SS06 DB 0005 DAL SS SS07 0 0000 DAL SS SS07 0 0005 DAL SS SS08 0 0000 DAL SS SS08 DB 0000 DAL SS SS08 0 0005 DAL SS SS09 0 0000 DAL SS SS09 0 0005 DAL SS GP01 0 0000 DAL SS GP01 0 0005 DAL SS GP01 0 0020 DAL SS GP01 0 0060 DAL SS GP02 0 0000 DAL SS GP02 0 0005 DAL SS GP02 0 0020 DAL SS GP02 DB 0020 DAL SS GP02 0 0120 DAL SS GP03 0 0000 DAL SS GP03 0 0005 DAL SS GP03 0 0020 DAL SS GP03 DB 0020 DAL SS GP03 0 0050 DAL SS GP04 0 0000 DAL SS GP04 0 0005 DAL SS GP04 0 0020 DAL SS GP04 0 0050 DAL SS GP05 0 0000 DAL SS GP05 0 0005 DAL SS GP05 0 0020 DAL SS GP05 0 0055 DAL SS GP06 0 0000 DAL SS GP06 0 0005 DAL SS GP06 0 0020 DAL SS GP06 0 0110 DAL SS GP07 0 0000 DAL SS GP07 0 0005 DAL SS GP07 0 0020 DAL SS GP07 0 0130 DAL SS GP08 0 0000 DAL SS GP08 0 0005 DAL SS GP08 DB 0005 DAL SS GP08 0 0020 DAL SS GP08 0 0050 DAL SS GP09 0 0000 LM S R ecovery (% ) PFOS 94.0% [d] 111% 79.7% 113% 102% 86.4% 106% 90.2% 79.3% 106% 103% 90.3% 89.8% 77.1% 120% 90.0% 104% 107% 101% 93.6% 117% 109% 79.2% 84.8% 84.6% 101% [a] 93.7% 60.7% [a, b] 107% 118% 91.5% 78.7% 87.7% 70.9% 90.1% 95.0% 81.8% 96.2% 89.3% 85.7% 94.4% 64.4% [b] 43.9% [b] 85.7% 93.8% 103% 108% 91.7% 69.3% [b] PFHS 100% 114% 100% 103% 99.3% 96.7% 97.1% 92.7% 82.5% 105% 102% 100% 96.9% 102% 144% [b] 83.1% 88.2% 94.8% 100% 93.5% 101% 93.9% 102% 114% 128% 96.5% 103% 98.5% 105% 105% 95.5% 84.0% 106% 65.4% [b] 103% 95.5% 96.0% 96.1% 93.1% 99.1% 90.6% 102% 71.4% [a] NR 100% 100% 93.6% 105% 90.9% PFBS 105% 94.0% 111% 108% 117% 108% 97.0% 99.8% 83.2% 105% 102% 103% 106% [a] 98.7% 111% 106% 91.6% 104% 97.0% 104% 110% 114% 105% 101% 93.2% 109% 105% 111% 111% 111% 99.9% 87.7% 116% 88.0% 101% 111% 109% 101% 95.2% 112% 107% 128% 83.3% [a] NR 115% 114% 114% 107% 90.1% 3M Study GLP10-01-02 Interim Report 05 Page 12 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 2. LMS Recoveries for Decatur Avenue A Soils and Sediments (June/July 2010) L IM S ID S a m p le ID PFOS LM S R ecovery (% ) PFHS PFBS GLP10-01-02-05-102 DAL SS GP09 0 0005 84.2% 94.1% 112% GLP10-01-02-05-103 DAL SS GP09 DB 0005 118% [a] 104% [a] 96.3% GLP10-01-02-05-104 DAL SS GP09 0 0020 95.0% 107% 109% GLP10-01-02-05-105 DAL SS GP09 0 0050 80.7% 96.4% 92.9% GLP10-01-02-05-106 DAL SS GP10 0 0000 143% [b] 109% 100% GLP10-01-02-05-107 DAL SS GP10 0 0005 121% 108% 102% [a] GLP10-01-02-05-108 DAL SS GP10 0 0020 88.0% 94.8% 62.6% [a, b] GLP10-01-02-05-109 DAL SS GP10 0 0060 102% [a] 114% [a] 123% [a] GLP10-01-02-05-111 DAL SS GP11 0 0000 84.1% 89.9% 109% GLP10-01-02-05-112 DAL SS GP11 0 0005 102% 119% 118% GLP10-01-02-05-113 DAL SS GP11 0 0020 88.2% 101% 102% GLP10-01-02-05-114 DAL SS GP11 0 0065 115% 106% 113% GLP10-01-02-05-115 DAL SS GP11 DB 0065 106% 106% 109% GLP10-01-02-05-116 DAL SS GP12 0 0000 100% 113% 116% GLP10-01-02-05-117 DAL SS GP12 0 0005 98.9% 94.0% 110% GLP10-01-02-05-118 DAL SS GP12 0 0020 80.0% 84.8% 101% GLP10-01-02-05-119 DAL SS GP12 0 0170 124% 111% 113% [a] ; value reported from a re-assay result when original result had a lower quality QC result [b] ; LMS recovery was outside of typical acceptance limits of 100 + 30%, but was within reporting limits of 100 + 60%. [c] ; RPD of duplicate sample results was greater than 50% [d] ; Value calculated using single result, duplicate result was BLQ. [e] ; Value was determined by external standard quant because LMS sample accidentally did not receive IS addition. n R; not reported because result was outside of 100 + 60% reporting criterion. Note: LMS fortifications were with linear isomers of analyte and at levels comparable to the endogenous analyte level approximated in samples during range finding analysis (i.e. fortified between 0.5- and 10-times the endogenous analyte concentration). 3 Introduction This study was conducted to measure PFOS, PFHS and PFBS concentrations in the Avenue A soils and sediments collected at the 3M facility located in Decatur, Alabama. Samples were collected by Weston Solutions, Inc. personnel in June/July 2010, and sent to the 3M Environmental Laboratory for quantitative analysis. Travel blanks (trip blanks), sample bottles containing between 5 and 25 grams of a control soil, accompanied the empty sample bottles to the site and then accompanied the soil samples back to the laboratory, and were analyzed to determine potential sample contamination during field collections and sample shipping. Four aqueous equipment rinseate samples were also collected at the time of soil/sediment sample collections and were analyzed in a separate water analysis procedure to evaluate whether soil collection equipment was thoroughly rinsed between samplings so as to prevent sample cross-contamination. The aqueous equipment rinseate samples were analyzed with additional groundwater samples collected from Avenue A and reported in GLP10-01-02 interim report 06. This interim report 05 describes the sample shipping, receipt, extraction and quantitative liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) analysis procedures conducted for determination of PFOS, PFHS and PFBS concentrations in the Avenue A soils and sediments and soil travel blanks as project GLP10-01-02-05. Additional results include the evaluation of analytical precision and accuracy of the results, as well as determination of soil percent moisture for reporting concentration results on a dry weight basis. 3M Study GLP10-01-02 Interim Report 05 Page 13 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 4 Test, Control and Reference Substances This study does not have a test or control substance in the classic sense of a GLP study because this study was purely analytical in nature. The analytical reference substances are listed in Table 3. Table 3. Reference Substances R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity PFOS (linear) PFOS (linear + branched) PFHS (linear) n-Perfluorooctane-1Sulfonate Potassium Salt n-C8F17 SO3 K Reference Standard for Calibration and LMSs 2795-39-3 Wellington Laboratories 10/18/13 -20C LPFOSKBM06 Perfluorooctane Sulfonate Potassium Salt C8F17SO3 K Reference Standard for LCSs 2795-39-3 3M 12/14/16 -20C 171 n-Perfluorohexane-1-sulfonate Sodium Salt n-C6F1 3 SO 3 Na Reference Standard for Calibration and LMSs 3871-99-6 Wellington Laboratories 4/2/13 -20C LPFHxSAM08 TCR08-0001-1/1 TCR-696 TCR08-0018-1/1 Crystalline W hite Powder Crystalline 98% PFHS (linear + branched) n-Perfluorohexane-1sulfonate Potassium Salt n-Cg F13 SO3 K Reference Standard for LCSs 3871-99-6 3M 2/12/17 -20C NB 120067-69 TCR-083 86.4% PFBS (predominantly linear) Perfluorobutane-1-sulfonate Potassium Salt n-C4Fg SC>3 K Reference Standard for All PFBS 29420-49-3 3M 1/10/17 -20C 101 TCR-121 >98% [1 ,2 ,3 ,4 -13C 4] -PFOS [1 ,2 ,3 ,4 -13C 4]-P e rflu o ro o c ta n e 1-Sulfonate Sodium Salt 13C412C4F17SO 3 Na S u rro g a te 2795-39-3 W ellington Laboratories 9/9/2012 -20C MPFOS0808 T C R 0 9 -0 0 5 1 -6 /1 5 W hite Powder 98.6% W hite Powder 96.7% Methanol solution, sealed ampule >98% 3M Study GLP10-01-02 Interim Report 05 Page 14 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 3. Reference Substances R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity [1 , 2 ,3 ,4 ,5 ,6 ,7 ,8 - 13C 8] PFOS [13C 8]- P e r flu o r o o c ta n e - 1 Sulfonate Sodium Salt 13C8F17S O 3 Na Internal Standard for PFOS 2795-39-3 W ellington Laboratories 6/17/12 -20 C M8PFOS0609 [18O 2]-PFHS [18O 2]-P e rflu o ro h e xa n e -1 Sulfonate Sodium Salt C 6F13S 18O 216O Na Internal Standard for PFHS 3871-99-6 W ellington Laboratories 7/24/11 -20C MPFHxS0706 T C R 0 9 -0 0 5 1 -3 /1 5 Methanol solution, sealed ampule >98% T C R -1 2 1 7 M ethanol solution, sealed a m p u le >98% [ 18O 2]-PFBS [18O 2]-P e rflu o ro b u ta n e -1 Sulfonate A m m onium Salt c 4f 9s 18o 216o n h 4 Internal Standard for PFBS 29420-49-3 RTI International 9/23/10 -20C 11546-107-2 T C R -1 0 0 4 M ethanol solution, sealed am p u le >99% 5 Test System There was not a test system for this study in the classic sense of a GLP study. This study was conducted for analysis of the Avenue A soils and sediments collected from the Decatur, AL site in June/July 2010. Samples for this study are "real world" environmental samples composed of soil. 6 Method Summary 6.1 Methods Soil extraction and quantitative LC/MS/MS analyses were performed using method ETS-8-053.0. Initially, range finding (screening) analyses were performed on September 03/04 and 09/10, 2010 as analytical runs D100904a and D100908a to estimate the concentrations of PFOS, PFHS and PFBS in the samples. Screening results are not reported herein, but were used for establishing the proper fortification concentrations needed for LMS preparations for the definitive analyses, which are reported herein. The definitive LC/MS/MS analyses were performed on from the period covering October 11, 2010 to January 05, 2011 as analytical runs S101101a, S101104a, S101109s, S101109b, S101122a, S101201a, S101207a, S101214a, S101228a and S110105a 3M Study GLP10-01-02 Interim Report 05 Page 15 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 6.2 Sample Collection On June 17, 2010, 130 empty 250-mL HDPE NalgeneTM sample bottles, six travel blanks (trip blanks) containing between 15 to 20 grams of a control soil TCR-842 in each, and six 1-liter bottles of Milli-QTM water were sent from the 3M Environmental Laboratory to Weston Solutions, Inc. field personnel for collection of soils and sediments in the vicinity of Avenue A at the 3M Decatur, AL facility. Following sample collections, the filled sample bottles and appropriate number of travel blanks were returned back to the laboratory for PFOS, PFHS and PFBS analysis. Samples were received as two shipments, one received on July 02, 2010 and the second received on July 13, 2010. Only two travel blanks were returned, one with each shipment. The soil samples were appropriately shipped in accordance with USDA/APHIS soil permit number P330 09-00125. Upon receipt, samples were logged the laboratory's electronic laboratory information management system (LIMS) and then stored refrigerated until they could be extracted for analysis. Sample nomenclature follows the form DAL-Sx-xxxxx-x-xxxx where the first string defines the Decatur Alabama (DAL) project area, the second string defines the sample media (i.e., SD = sediment, SS = soil sample), the third string defines the specific sampling location. The fourth string defines the sample type (0 = primary sample, DB- field duplicate, RB = equipment rinseate blank). The fifth string indicates the sampling depth range (0000 indicates 0 to 6 inch depth surface sample). 6.3 Sample Preparation Once the soil samples were received at the laboratory, they were stored refrigerated until extraction could be performed. Each soil extraction involved removal of a 1 cubic centimeter (1 cc; 1 mL) soil aliquot (typically ~ 1 gram) from each sample bottle using a fixed volume 1 cc spoon, followed by accurate weight determination of the aliquot on a 5-place balance. Then, known quantities of internal standard (IS; nominal 3.0 ng for each) and surrogate (nominal 3.0 ng) were added to each soil aliquot. For LMS preparations, additional known quantities of PFOS (linear), PFHS (linear) and PFBS were also added. After fortifications were complete, the soil aliquots were each extracted by addition of 8 mL of a 4:1 acetonitrile:water solution followed by sonication for 1 to 2 hours and then centrifugation to remove solids. The supernatant from each was transferred to an autovial for analysis. An accurately measured volume of each supernatant was analyzed by LC/MS/MS. For this study, a range finding (screening) analysis of individually prepared extracts for each soil was initially performed to approximate the concentrations of PFOS, PFHS and PFBS in them. The screening analysis was performed as two analytical runs on September 03/04 and September 09/10, 2010 as analytical runs D100904a and D100908a. The screening results were used to determine the appropriate laboratory matrix spike (LMS) concentrations for the definitive analyses. After the screening analysis was completed, triplicate aliquots of each soil were taken from the bulk samples and extracted for definitive analysis. The third aliquot of each was prepared as a LMS and fortified with known quantities of PFOS (linear), PFHS (linear) and PFBS prior to extraction. Fortifications were performed at a level that was appropriate to the endogenous analyte level in the soils (0.5- to 10-times the endogenous analyte level), and based on results determined during the screening analysis. For those samples with PFOS levels above the range of the curve, a separate set of LMSs were prepared for PFOS only, in order to minimize interferences in quantifying PFBS and PFHS in those same samples. The definitive LC/MS/MS analyses were performed on prepared batches of samples from the period covering October 11,2010 to January 05, 2011 and as analytical runs S101101a, S101104a, S101109s, S101109b, S101122a, S101201a, S101207a, S101214a, S101228a and S110105a. In several instances, samples had to be diluted with extract of method blanks, up to100-fold dilution, to attain results within the calibrated range. The final analysis on January 05, 2011 was conducted as a re-preparation and analysis (reassay) for several samples with poor LMS or RPD results in an attempt to improve those QC results. In most instances for those samples, the reassay results were of a higher quality and those reassay results were reported, and the original results 3M Study GLP10-01-02 Interim Report 05 Page 16 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 disregarded. Those results reported from a reassay value are footnoted in the results tables. Laboratory control spike (LCS) samples were prepared with each sample extraction batch by fortifying a aliquot of control soil with known quantities of PFOS (linear + branched), PFHS (linear + branched) and PFBS; prepared at a 3.0 ng and 30 ng fortification level, with each level prepared in triplicate. A set of calibration standards were prepared by fortifying known quantities of PFOS (linear), PFHS (linear) and PFBS, and surrogate (13C4-PFOS) into 1-cubic centimeter (1 cc; equivalent to 1 mL) aliquots of 3M Environmental Laboratory matrix soil TCR-842. The nominal mass of 1 cc of control soil TCR842 is 1.0 gram (dry). Therefore, the range of calibration standards was nominal concentrations 0.200 ng/cc to 500 ng/cc (equivalent to 0.200 ng/mL to 500 ng/mL). When adjusted for the nominal mass of standard soil TCR-842, the nominal calibration standard range was 0.200 ng/g to 500 ng/g. 6.4 Percent Soil Moisture Determination The percent moisture of each sample was determined and used to calculate the dry weights of the soil aliquots that were extracted and analyzed. Dry weights were determined for separate weighings than the weighings used for LC/MS/MS extract preparations. To determine the percent moisture, duplicate aliquots of each soil sample were removed and the accurate "wet" weight determined for each. Then the aliquots were dried at > 100C until no further mass loss occurred from water evaporation, at which time the accurate dried weights were determined. The difference in mass, attributed to water evaporation, was used to calculate the percent moisture in the original soil. The averaged percent moisture result for each was then used to calculate the soil PFOS, PFHS and PFBS concentrations on a dry weight basis. 6.5 LC/MS/MS Analysis The analysis of soil extracts for PFOS, PFHS and PFBS was performed by liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) as described in method ETS-8053.0. The relative percent difference (RPD) of duplicate sample results was used as a measure of analytical precision. The determined recovery of fortified PFOS (linear), PFHS (linear) and PFBS from LMS samples was used as a measure of analytical accuracy. Recovery of the surrogate (13C4-PFOS) is included within this report in Table 14, and is also part of an on-going method validation aspect in which surrogate recovery is being evaluated in real environmental samples. Details of the specific instrument parameters, the liquid chromatography gradient program, and the specific mass transitions analyzed are detailed in the raw data, and are briefly described below in Table 4, Table 5 and Table 6. For this study, a range finding (screening) analysis of individually prepared extracts for each soil was initially performed to approximate the concentrations of PFOS, PFHS and PFBS in them. The screening analysis was performed as two analytical runs on September 03/04 and September 09/10, 2010 as analytical runs D100904a and D100908a. The screening results were used to determine the appropriate laboratory matrix spike (LMS) concentrations for the definitive analyses. Screening analysis results are not reported herein, but the raw data is included in Attachment A . The definitive LC/MS/MS analyses for data reported herein were performed on prepared batches of samples during the period from October 11,2010 to January 05, 2011 and results acquired from analytical runs S101101a, S101104a, S101109s, S101109b, S101122a, S101201a, S101207a, S101214a, S101228a and S110105a. 3M Study GLP10-01-02 Interim Report 05 Page 17 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 4. Instrument Information Instrument Name A n a lytica l M ethod ID Liquid C hrom atograph Pre-sam pler column Analytical guard column Analytical column Injection Volum e Mass Spectrom eter Ion S ource P o la rity Software ETS-Stan E T S -8 -0 5 3 .0 A gilent 1100 with Binary Pump Prism RP (2.1 x 50 mm, 5 u) Oasis HLB (3 x 20 mm, 25 u); 30C Betasil-C 18 (2.1 x 100 mm, 5 u); 30C 25 uL API 4000 Triple Quadrapole TurbolonTM Electrospray N e g a tiv e A nalyst 1.4.2 ETS-D avey (screening analyses) E T S -8 -0 5 3 .0 A gilent 1100 with Binary Pump Prism RP (2.1 x 50 mm, 5 p) O asis HLB (3 x 20 mm, 25 p); 30C Betasil-C18 (2.1 x 100 mm, 5 p); 30C 25 pL M icrom ass Ultima Triple Q uadrapole Z-Spray Electrospray N e g a tiv e M asslynx 3.5 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053) Step Num ber Total Time [m in] 1 0.0 2 3.0 3 3.5 4 17.0 5 17.5 6 19.5 7 20.0 8 23.0 Flow Rate [m L/m in] 0.400 0.400 0.400 0.400 0.400 0.400 0.400 0.400 Percent A [2 mm Aqueous A m m onium Acetate] 97.0 97.0 70.0 40.0 10.0 10.0 97.0 97.0 Table 6. Mass Transitions A n a ly te Mass Transitions M onitored PFBS 299>99, 299>80 18O 2-P F B S (IS) 303>84 PFHS 399>99, 399>80 18O 2-P F H S (IS) 403>84 PFOS 499>130, 499>99, 499>80 13C 8-P F O S (IS) 507>80 13C4-P F O S (S urrogate) 503>80 Note: Multiple mass transitions are summed to give the instrument response for that analyte. Percent B [ M ethanol] 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0 3M Study GLP10-01-02 Interim Report 05 Page 18 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 7 Analytical Results All results were rounded to three significant figures according to EPA rounding rules. Because of rounding, values may vary slightly from those found in the raw data. Laboratory matrix spikes (LMS) meeting the method acceptance criteria of 100 30% demonstrate that the method was appropriate. LMS results within 100 + 60% were deemed acceptable for reporting, but with a footnote in results tables. That exception was footnoted separately in the results tables. The spiked concentrations were adequate for the given matrix and their respective quantitative ranges of PFOS, PFHS and PFBS measured in the samples. The protocol allows for reporting results when LMS results with a footnote indicating they are within100 + 50%, if outside of 100+ 30%. For this report the LMS criterion was expanded to 100 + 60% with footnotes in the tables and with a protocol deviation, to capture a few select samples that were deemed important enough to be included in the report. Three results were not reported (NR) because LMS recoveries were outside of 100 + 60%. A protocol deviation for the expansion of the reporting range to 100 + 60% was included in the study binder for this project to address the expanded reporting criterion range. 7.1 Calibration A set of calibration standards were prepared by spiking known quantities of PFOS (linear), PFHS (linear), PFBS and surrogate (13C4-PFOS), and a fixed quantity of stable isotope labeled internal standards, into one cubic centimeter (1 cc, 1 mL) aliquots of 3M Environmental Laboratory control soil TCR-842 (nominal soil mass of 1.0 g/mL). A total of twelve (12) calibration standards were prepared as a set and ranged from nominal concentration 0.200 ng/mL to 500 ng/mL (0.200 ng/g to 500 ng/g). Following analysis of the calibration standards, the nominal concentration of each standard was plotted against the measured analyte /IS peak area ratio. A quadratic equation with 1/x weighting was used to fit the data. Calibration curves were not forced through zero. Determining the standard concentration using the resultant calibration curve and comparing to the known concentration confirmed accuracy of each curve point to within the acceptance criteria of 100 30% (+ 35% at the LLOQ). The correlation coefficient (r) was greater than 0.999 for all calibration curves, and the coefficient of determination (r2) was greater than 0.990. Calibration results for PFOS, PFHS and PFBS are summarized in Table 7, Table 8 and Table 9, respectively. Because soil/sediment weights can vary significantly for a 1 cc (1 mL) field sample, depending on soil/sediment composition and moisture content, the instrument response was calibrated for the known concentrations of target analytes based on the mass quantity of each analyte added to a 1 cc soil ( 1 mL) calibration standard prior to extraction (e.g. calibrated in this study for a range of 0.200 ng/mL to 200 ng/mL PFOS, PFHS and PFBS). Because a 1cc aliquot of control soil TCR-842 weighs nominally 1.0 gram (dry weight) and has less than 5% moisture content, the nominal concentration range of the calibration was essentially 0.200 ng/g to 500 ng/g. However, because the sample aliquots typically weigh more than 1.0 gram and contain significant moisture and composition variability, the determined concentrations during the analysis on a ng/mL basis from the calibration curve were adjusted for the accurate determined weight and percent moisture so they could be reported on a ng/g (dry weight) basis. 3M Study GLP10-01-02 Interim Report 05 Page 19 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 7. PFOS Calibration Summary A nalytical Run STD 1 STD 2 STD 3 STD 4 STD 5 PFO S (ng/m L) STD 6 STD 7 STD 8 A c tu a l S101101a S101104a S101109a S101109b S101122a S101201a S101207a S101214a S101228a S110105a 0.200 0.209 0.169 0.199 N/A 0.153 0.171 0.166 0.186 e x c lu d e d 0.236 0.500 0.473 0.500 0.485 N/A 0.459 0.527 0.514 0.402 0.467 0.578 0.750 0.731 0.716 0.787 N/A 0.757 0.722 0.812 0.779 0.658 0.732 1.00 0.986 0.983 0.966 N/A 1.02 1.06 1.05 1.14 0.954 0.706 2.50 2.56 2.69 2.68 N/A 2.68 2.43 2.54 2.51 2.71 2.76 5.00 5.20 5.05 4.83 N/A 5.72 5.37 5.27 5.12 5.32 5.26 10.0 25.0 9.47 24.4 10.2 26.3 9.80 24.4 N/A N/A 10.4 25.2 10.0 24.3 9.34 26.1 10.1 25.4 9.82 27.1 7.10 27.2 A verage 0 .1 8 6 0 .4 8 9 0 .7 4 4 0 .9 8 5 2 .6 2 5 .2 4 9 .5 8 2 5 .6 S td. D eviatio n 0 .0 2 7 0 .0 4 9 0 .0 4 6 0 .1 2 0 .1 1 0 .2 4 0 .9 9 1.1 R S D (% ) A vg . R e c o v e ry (% ) n 15% 93.1% 8 10% 97.9% 9 6.2% 99.2% 9 12% 9 8 .5 % 9 4 .2 % 105% 9 4 .7 % 105% 9 10% 9 5 .8 % 9 4 .4 % 102% 9 N/A; not applicable because analyte was not measured for reporting purposes in the analytical run STD 9 50.0 54.1 55.2 51.0 N/A 52.1 52.7 48.0 52.5 51.9 55.2 5 2 .5 2 .2 4 .3 % 105% 9 STD 10 100 99.7 98.7 101 N/A 101 103 98.1 101 103 89.6 9 9 .5 4.1 4 .1 % 9 9 .5 % 9 STD 11 200 196 192 199 N/A 193 193 204 194 190 207 196 5 .8 2.9% 9 8 .2 % 9 STD 12 500 501 503 500 N/A 502 502 499 502 503 499 501 1.6 0 .3 1 % 100% 9 r NA 0.9997 0.9994 1.000 N/A 0.9997 0.9997 0.9998 0.9998 0.9995 0.9982 0 .9 9 9 5 0 .0 0 0 5 3 0 .0 5 3 % N /A 9 Table 8. PFHS Calibration Summary PFHS (ng/m L) A nalytical Run STD 1 STD 2 STD 3 STD 4 STD 5 STD 6 STD 7 STD 8 A c tu a l S101101a S101104a S101109a S101109b S101122a S101201a S101207a S101214a S101228a S110105a 0.200 0.500 0.750 1.00 2.50 5.00 10.0 25.0 0.216 0.487 0.737 0.976 2.56 4.80 9.95 24.2 0.175 0.508 0.727 0.988 2.63 5.02 10.3 25.1 N/A N/A N/A N/A N/A N/A N/A N/A 0.196 0.482 0.730 0.955 2.67 5.37 9.64 24.3 0.202 0.475 0.722 1.04 2.50 5.23 9.78 24.1 0.148 0.492 0.786 0.974 2.82 5.34 10.5 24.5 0.173 0.480 0.779 1.02 2.52 5.22 10.0 26.0 0.183 0.505 0.817 0.949 2.54 5.15 9.65 25.2 N/A N/A N/A N/A N/A N/A N/A N/A 0.232 0.507 0.773 0.803 2.81 5.22 7.35 26.3 A verage 0 .1 9 1 0 .4 9 2 0 .7 5 9 0 .9 6 3 2 .6 3 5 .1 7 9 .6 5 2 5 .0 S td. D eviatio n 0 .0 2 7 0 .0 1 3 0 .0 3 5 0 .0 7 2 0 .1 3 0 .1 8 0 .9 8 0 .8 4 R S D (% ) A vg . R e c o v e ry (% ) n 14% 95.3% 8 2.7% 98.4% 8 4 .6 % 101% 8 7.4% 9 6 .3 % 8 4 .8 % 105% 8 3.6% 103% 8 10% 9 6 .5 % 8 3.4% 9 9 .9 % 8 N/A; not applicable because analyte was not measured for reporting purposes in the analytical run STD 9 50.0 52.4 54.8 N/A 52.3 51.4 52.2 52.5 51.3 N/A 54.0 5 2 .6 1.2 2 .3 % 105% 8 STD 10 100 101 100 N/A 102 106 99.5 100 100 N/A 93.4 100 3 .5 3.5% 100% 8 STD 11 200 196 191 N/A 194 191 196 193 197 N/A 204 195 4 .2 2 .2 % 9 7 .6 % 8 STD 12 500 501 503 N/A 502 503 502 503 501 N/A 499 502 1.4 0 .2 8 % 100% 8 r NA 0.9999 0.9995 N/A 0.9997 0.9995 0.9998 0.9998 0.9999 N/A 0.9990 0 .9 9 9 6 0 .0 0 0 3 0 0 .0 3 0 % N /A 8 3M Study GLP10-01-02 Interim Report 05 Page 20 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 9. P F B S C a lib ra tio n S u m m a ry A nalytical Run STD 1 STD 2 STD 3 STD 4 STD 5 PFBS (ng/m L) STD 6 STD 7 STD 8 A c tu a l S101101a S101104a S101109a S101109b S101122a S101201a S101207a S101214a S101228a S110105a 0.200 0.500 0.749 0.999 2.50 5.00 9.99 0.175 0.475 0.710 0.943 2.57 5.32 10.4 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.246 0.501 0.743 0.853 2.68 5.26 10.7 N/A N/A N/A N/A N/A N/A N/A 0.171 0.491 0.779 1.04 2.66 4.88 10.2 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.231 0.514 0.794 0.810 2.65 5.22 7.44 25.0 25.0 N/A N/A N/A 23.7 N/A 25.0 N/A N/A 27.2 A veraqe 0 .2 0 6 0 .4 9 5 0 .7 5 7 0 .9 1 2 2 .6 4 5 .1 7 9 .6 9 2 5 .2 S td. D eviation 0 .0 3 8 0 .0 1 6 0 .0 3 8 0 .1 0 0 .0 4 8 0 .2 0 1.5 1.5 R S D (% ) A v q . R e c o v e ry (% ) 19% 103% 3.3% 9 9 .1 % 5.0% 101% 11% 9 1 .2 % 1.8% 106% 3 .8 % 103% 16% 9 6 .9 % 5.8% 101% n 4 4 4 4 444 4 N/A; not applicable because analyte was not measured for reporting purposes in the analytical run STD 9 50.0 52.5 N/A N/A N/A 50.9 N/A 53.4 N/A N/A 52.3 5 2 .3 1.0 2.0% 105% 4 STD 10 99.9 100 N/A N/A N/A 99.7 N/A 95.1 N/A N/A 94.1 97 3.1 3.1% 9 7 .3 % 4 STD 11 200 194 N/A N/A N/A 199 N/A 201 N/A N/A 205 200 4 .6 2 .3 % 9 9 .9 % 4 STD 12 500 503 N/A N/A N/A 500 N/A 501 N/A N/A 499 501 1.7 0 .3 4 % 100% 4 r NA 0.9998 N/A N/A N/A 0.9999 N/A 0.9997 N/A N/A 0.9991 0 .9 9 9 6 0 .0 0 0 3 6 0 .0 3 6 % N /A 4 7.2 Limits of Quantitation (LOQs) The lower limit of quantitation (LLOQ) is the lowest non-zero calibration standard in the curve that met linearity and accuracy requirements (100 + 35%) and for which the area counts were at least 2X that of the average response determined from the method blanks. The LLOQ for this study was the nominal 0.200 ng/g standard for PFBS, PFHS and PFOS, except in run S100426a where the LLOQ for PFOS was raised to 0.500 ng/g. Each sample that gave an analyte response less than the response of the LLOQ calibration standard was reported as BLQ (below the limit of quantitation). The upper limit of quantitation (ULOQ) was nominal concentration 500 ng/g, and samples with endogenous analyte levels at greater than the ULOQ were appropriately diluted to achieve analyte results within the curve range. PFOS was the only analyte requiring dilution for this analysis. 7.3 Continuing Calibration During the course of each analysis, continuing calibration verifications (CCVs) was performed by injection of a mid-level calibration standard to confirm that the instrument response and the initial calibration curve were still in control. All CCVs flanking reported data met the method criteria of 100% 30% (+ 35% at LLOQ). 7.4 Blanks Four types of blanks were analyzed during this analysis, and included the following: three method blanks were prepared with blank matrix soil TCR-842 and were spiked with IS, three method blanks 3M Study GLP10-01-02 Interim Report 05 Page 21 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 without IS were prepared, two travel blanks (trip blanks) prepared from aliquots of the control soil in those blanks samples which accompanied the sample bottle shipments, and several solvent blanks containing extraction solvent. The different blank results are reviewed to evaluate potential contamination during shipment and sampling, to evaluate method performance parameters such as injector carry over and also to establish the LLOQ. One PFOS value for the second trip blank was slightly above the LLOQ, but was likely the result of carryover from relatively high PFOS concentration samples analyzed prior to that sample. The PFHS and PFBS results were always BLQ for trip blanks, but were also typically much lower than the PFOS levels in samples, therefore carryover was not a factor for those analytes in the trip blanks. In addition to the aforementioned blanks, four aqueous equipment rinseate `blank' samples were received with the soils. Those rinseate samples were analyzed by a sensitive water analysis LC/MS/MS method along with Avenue A groundwater samples. The results for those rinseate sample analyses showed they were less than 0.0255 ng/mL PFBS, less than 0.103 ng/mL PFHS and less than 0.255 ng/mL PFOS as reported in GLP10-01-02 interim report 06. 7.5 Laboratory Control Spikes (LCSs) Laboratory control spikes were prepared by spiking known quantities of PFOS (linear + branched), PFHS (linear + branched) and PFBS into 1 cc aliquots of soil TCR-842, fortified with nominal 3.0 ng and 30 ng, and each level prepared in triplicate. The results of the LCS analyses and calculation of analyte measurement accuracies (percent recovery) for PFOS (linear + branched isomers), PFHS (linear + branched isomers) and PFBS are shown in Table 10, Table 11 and Table 12, respectively. Analytical runs conducted to analyzed diluted samples did not include LCSs, since the LCSs associated with those batched samples had been analyzed previously with the undiluted samples The LCS recoveries were calculated using the following equation: TLCS ,,Recovery = -(-D--e-t-e-r-m---i-n-e--d--C--o--n-c-e--n-t-r-a--t-io--n--o--f--L--C--S-)- *. .100%. Spike Concentration Table 10. LCS Results for PFOS (linear + branched isomers) Recovery Measured PFOS (ng) Sample ID 3.0 ng LCS 30 ng LCS Actual Conc. (ng/g) 3.00 30.0 S101101a 3.15 34.6 3.32 32.7 3.25 33.6 S101201a 3.32 30.4 3.37 31.0 3.07 34.9 S110105a 3.12 32.2 3.20 36.1 3.41 31.8 Average 3.25 33.0 Standard Deviation 0.12 1.91 Relative Std. Dev. 3.6% 5.8% Average LCS Recovery 108% 110% Analytical runs S101104a, S101109a, S101109b, S101122a, S101207a, S101214a and S101228a are excluded from the table because LCSs were not analyzed in those runs which were re-analyses of diluted samples. The LCSs associated with those samples were analyzed previously, with the undiluted samples, and are those reported._____________________________________________ 3M Study GLP10-01-02 Interim Report 05 Page 22 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 11. LCS Results for PFHS (linear + branched isomers) Recovery Measured PFOS (ng) Sample ID 3.0 ng LCS 30 ng LCS Actual Conc. (ng/g) 3.00 30.0 3.09 32 S101101a 3.21 31 3.27 31.2 3.16 29.8 S101207a 3.30 33.0 3.07 31.9 3.69 32.8 S110105a 3.21 36.6 3.59 32.6 Average Standard Deviation 3.29 32.3 0.21 1.89 Relative Std. Dev. 6.5% 5.9% Average LCS Recovery 110% 108% Analytical runs S101104a, S101109a, S101109b, S101122a, S101207a, S101214a and S101228a are excluded from the table because LCSs were not analyzed in those runs which were re-analyses of diluted samples. The LCSs associated with those samples were analyzed and determined previously when the undiluted samples were analyzed and are those reported._________________ Table 12. LCS Results for PFBS Recovery Measured PFOS (ng) Sample ID 3.0 ng LCS 30 ng LCS Actual Conc. (ng/g) 3.00 30.0 3.09 32.0 S101101a 3.21 31.0 3.27 31.2 3.10 29.0 S101207a 3.15 30.9 3.15 32.5 3.32 30.6 S110105a 2.90 33.5 3.33 28.6 Average Standard Deviation 3.17 31.0 0.13 1.56 Relative Std. Dev. 4.2% 5.0% Average LCS Recovery 106% 103% Analytical runs S101104a, S101109a, S101109b, S101122a, S101207a, S101214a and S101228a are excluded from the table because LCSs were not analyzed in those runs which were re-analyses of diluted samples. The LCSs associated with those samples were analyzed and determined previously when the undiluted samples were analyzed and are those reported._________________ 3M Study GLP10-01-02 Interim Report 05 Page 23 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 7.6 Laboratory Matrix Spikes (LMSs) Laboratory matrix spikes (LMSs) were generated by adding a known quantity of PFOS (linear), PFHS (linear) and PFBS to an aliquot of soil collected from the field, and then preparing the sample the same as non-spiked samples. For this study, LMSs were spiked at levels that were appropriate for the endogenous analyte levels in the soils, determined from screening analysis. The LMS method acceptance criteria of 100 30% was met for all reported results, with a few exceptions as noted in results tables, and all reported sample values had LMS recoveries within 100 + 60%. The PFOS result for sample GLP10-01-02-05-045, and PFHS and PFBS result for GLP10-01-02-05-095, were not reported due to LMS results outside of 100 + 60%. The LMS recovery results are summarized in Table 2, and individual sample results for PFOS, PFHS and PFBS are shown in Table 14, Table 15 and Table 16, respectively. The PFOS, PFHS and PFBS recovery calculations for LMSs used the following equation: TLM,, ,,S ,,Recovery = -(-D--e-t-e-r-m---i-n-e--d--C--o--n-c-e--n-t-r-a--t-io--n--o--f--L--M--S------D--e--te--r-m--i-n--e-d--C---o-n--c-e-n--t-r-a-t-i-o-n---o-f--F--i-e-l-d--S--a-m--p--le) *.,100%. Spike Concentration 7.7 Percent Soil Moisture Determinations The percent moisture was determined in duplicate for each soil sample. A sample aliquot of each is accurately weighed to determine the "wet" weight. Then the aliquot is dried at > 100C until no further loss in mass occurs (due to water evaporation), and then the dry weight is accurately determined. The average percent moisture and RPD of the duplicate determinations for each soil is reported in Table 13. The percent moisture was calculated by the following equation: ,,Percent ,,M,oi.sture = -(--Orig- -in--a-l--S-o--i-l-W---e--t-M---a-s--s-----D--r-i-e--d--S-o--i-l-M---a-s-s-)- _* 100% Original Soil Wet Mass Table 13. Percent Moistures for Decatur Avenue A Soils & Sediments Collected June/July 2010 3 M L IM S ID GLP10-01-02-05-001 GLP10-01-02-05-002 GLP10-01-02-05-003 GLP10-01-02-05-004 GLP10-01-02-05-005 GLP10-01-02-05-006 GLP10-01-02-05-007 GLP10-01-02-05-009 GLP10-01-02-05-010 GLP10-01-02-05-011 GLP10-01-02-05-012 GLP10-01-02-05-013 GLP10-01-02-05-014 GLP10-01-02-05-015 GLP10-01-02-05-016 S a m p le ID DAL SD TRIP1 0 100624 DAL SD SD01 0 0000 DAL SD SD01 0 0005 DAL SD SD02 0 0000 DAL SD SD02 0 0005 DAL SD SD03 0 0000 DAL SD SD03 0 0005 DAL SD SD04 0 0000 DAL SD SD04 0 0005 DAL SD SD05 0 0000 DAL SD SD05 0 0005 DAL SD SD06 0 0000 DAL SD SD06 0 0005 DAL SD SD07 0 0000 DAL SD SD07 0 0005 Average Percent Relative Percent Moisture (%; w/w) [a] Difference (%) 3.59% [b] 37.4% 26.7% 54.0% 25.6% 48.0% 32.0% 41.3% 23.9% 24.9% 21.7% 29.1% 21.3% 46.3% 50.8% 36% 2.7% 11% 4.4% 0.4% 1.8% 3.3% 0.57% 7.3% 11% 1.9% 7.9% 3.3% 7.1% 1.2% 3M Study GLP10-01-02 Interim Report 05 Page 24 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 1 3 . Percent Moistures for Decatur Avenue A Soils & Sediments Collected June/July 2010 3 M L IM S ID GLP10-01-02-05-017 GLP10-01-02-05-018 GLP10-01-02-05-019 GLP10-01-02-05-021 GLP10-01-02-05-022 GLP10-01-02-05-023 GLP10-01-02-05-024 GLP10-01-02-05-025 GLP10-01-02-05-026 GLP10-01-02-05-027 GLP10-01-02-05-028 GLP10-01-02-05-029 GLP10-01-02-05-030 GLP10-01-02-05-031 GLP10-01-02-05-032 GLP10-01-02-05-033 GLP10-01-02-05-034 GLP10-01-02-05-035 GLP10-01-02-05-036 GLP10-01-02-05-037 GLP10-01-02-05-038 GLP10-01-02-05-039 GLP10-01-02-05-040 GLP10-01-02-05-041 GLP10-01-02-05-042 GLP10-01-02-05-043 GLP10-01-02-05-044 GLP10-01-02-05-045 GLP10-01-02-05-046 GLP10-01-02-05-047 GLP10-01-02-05-048 GLP10-01-02-05-049 GLP10-01-02-05-050 GLP10-01-02-05-051 GLP10-01-02-05-052 GLP10-01-02-05-054 GLP10-01-02-05-055 GLP10-01-02-05-056 GLP10-01-02-05-057 GLP10-01-02-05-058 GLP10-01-02-05-059 GLP10-01-02-05-060 GLP10-01-02-05-061 GLP10-01-02-05-062 GLP10-01-02-05-063 GLP10-01-02-05-064 S a m p le ID DAL SD SD08 0 0000 DAL SD SD08 DB 0000 DAL SD SD08 0 0005 DAL SD SD09 0 0000 DAL SD SD09 0 0005 DAL SD SD10 0 0000 DAL SD SD10 0 0005 DAL SD SD11 0 0000 DAL SD SD11 0 0005 DAL SD SD12 0 0000 DAL SD SD12 DB 0000 DAL SD SD12 0 0005 DAL SD SD13 0 0000 DAL SD SD13 0 0005 DAL SD SD14 0 0000 DAL SD SD14 0 0005 DAL SD SD15 0 0000 DAL SD SD15 0 0005 DAL SD SD16 0 0000 DAL SD SD16 DB 0000 DAL SD SD16 0 0005 DAL SD SD17 0 0000 DAL SD SD17 0 0005 DAL SS SS01 0 0000 DAL SS SS01 0 0005 DAL SS SS02 0 0000 DAL SS SS02 0 0005 DAL SS SS03 0 0000 DAL SS SS03 0 0005 DAL SS SS03 DB 0005 DAL SS SS04 0 0000 DAL SS SS04 0 0005 DAL SS TRIP1 0 0000 DAL SS SS05 0 0000 DAL SS SS05 0 0005 DAL SS SS06 0 0000 DAL SS SS06 0 0005 DAL SS SS06 DB 0005 DAL SS SS07 0 0000 DAL SS SS07 0 0005 DAL SS SS08 0 0000 DAL SS SS08 DB 0000 DAL SS SS08 0 0005 DAL SS SS09 0 0000 DAL SS SS09 0 0005 DAL SS GP01 0 0000 A verage P ercent M o i s t u r e (% ; w / w ) [a] R e la tiv e P e rc e n t D iffe re n c e (% ) 34.8% 32.7% 19.0% 37.5% 22.1% 33.8% 25.0% 29.9% 20.6% 50.4% 50.9% 23.7% 29.1% 18.2% 45.5% 26.5% 35.2% 18.8% 35.6% 37.0% 27.6% 25.3% 22.6% 7.65% 12.4% 8.73% [b] 21.1% 3.31% 12.2% 7.53% 11.7% 7.94% 2.52% 8.33% 7.82% 6.79% 8.50% 8.27% 18.3% 14.6% 6.79% 7.48% 10.4% 10.4% 9.87% 10.5% 6.1% 7.2% 1.7% 16% 11% 0.55% 3.1% 11% 9.5% 0.15% 6.3% 2.3% 7.9% 1.2% 4.5% 8.2% 17% 0.57% 2.6% 6.6% 6.5% 5.1% 6.0% 11% 2.9% 27% 6.4% 17% 1.9% 19% 4.6% 1.9% 11% 12% 6.5% 1.9% 3.3% 5.7% 12% 4.4% 14% 16% 2.5% 2.1% 1.8% 10% 3M Study GLP10-01-02 Interim Report 05 Page 25 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 1 3 . Percent Moistures for Decatur Avenue A Soils & Sediments Collected June/July 2010 3 M L IM S ID GLP10-01-02-05-065 GLP10-01-02-05-066 GLP10-01-02-05-067 GLP10-01-02-05-068 GLP10-01-02-05-069 GLP10-01-02-05-070 GLP10-01-02-05-071 GLP10-01-02-05-072 GLP10-01-02-05-073 GLP10-01-02-05-074 GLP10-01-02-05-075 GLP10-01-02-05-076 GLP10-01-02-05-077 GLP10-01-02-05-078 GLP10-01-02-05-079 GLP10-01-02-05-080 GLP10-01-02-05-081 GLP10-01-02-05-082 GLP10-01-02-05-083 GLP10-01-02-05-084 GLP10-01-02-05-085 GLP10-01-02-05-087 GLP10-01-02-05-088 GLP10-01-02-05-089 GLP10-01-02-05-090 GLP10-01-02-05-091 GLP10-01-02-05-092 GLP10-01-02-05-093 GLP10-01-02-05-094 GLP10-01-02-05-095 GLP10-01-02-05-096 GLP10-01-02-05-097 GLP10-01-02-05-098 GLP10-01-02-05-099 GLP10-01-02-05-101 GLP10-01-02-05-102 GLP10-01-02-05-103 GLP10-01-02-05-104 GLP10-01-02-05-105 GLP10-01-02-05-106 GLP10-01-02-05-107 GLP10-01-02-05-108 GLP10-01-02-05-109 GLP10-01-02-05-111 GLP10-01-02-05-112 GLP10-01-02-05-113 S a m p le ID DAL SS GP01 0 0005 DAL SS GP01 0 0020 DAL SS GP01 0 0060 DAL SS GP02 0 0000 DAL SS GP02 0 0005 DAL SS GP02 0 0020 DAL SS GP02 DB 0020 DAL SS GP02 0 0120 DAL SS GP03 0 0000 DAL SS GP03 0 0005 DAL SS GP03 0 0020 DAL SS GP03 DB 0020 DAL SS GP03 0 0050 DAL SS GP04 0 0000 DAL SS GP04 0 0005 DAL SS GP04 0 0020 DAL SS GP04 0 0050 DAL SS GP05 0 0000 DAL SS GP05 0 0005 DAL SS GP05 0 0020 DAL SS GP05 0 0055 DAL SS GP06 0 0000 DAL SS GP06 0 0005 DAL SS GP06 0 0020 DAL SS GP06 0 0110 DAL SS GP07 0 0000 DAL SS GP07 0 0005 DAL SS GP07 0 0020 DAL SS GP07 0 0130 DAL SS GP08 0 0000 DAL SS GP08 0 0005 DAL SS GP08 DB 0005 DAL SS GP08 0 0020 DAL SS GP08 0 0050 DAL SS GP09 0 0000 DAL SS GP09 0 0005 DAL SS GP09 DB 0005 DAL SS GP09 0 0020 DAL SS GP09 0 0050 DAL SS GP10 0 0000 DAL SS GP10 0 0005 DAL SS GP10 0 0020 DAL SS GP10 0 0060 DAL SS GP11 0 0000 DAL SS GP11 0 0005 DAL SS GP11 0 0020 A verage P ercent M o i s t u r e (% ; w / w ) [a] R e la tiv e P e rc e n t D iffe re n c e (% ) 9.49% 13.5% 19.7% 5.26% 7.36% 15.7% 14.6% 30.5% 9.95% 12.0% 19.9% 21.0% 22.3% 8.39% 10.8% 12.8% 14.6% 12.7% 11.3% 15.6% 22.5% 5.13% 7.20% 13.4% 23.2% 0.964% [b] 5.38% 13.0% 19.8% 9.07% 11.1% 11.4% 15.5% 20.1% 9.09% 14.9% 14.6% 16.4% 19.3% 10.8% 19.1% 17.5% 18.6% 6.50% 13.5% 17.2% 12% 5.4% 3.6% 3.9% 1.3% 2.5% 0.55% 7.7% 10% 0.34% 11% 3.6% 2.0% 3.4% 1.4% 12% 12% 3.6% 13% 6.8% 0.60% 2.0% 6.1% 2.4% 3.8% 29% 0.075% 4.2% 1.4% 2.2% 2.4% 4.9% 4.1% 2.7% 4.4% 16% 0.76% 0.31% 12% 5.4% 10% 11% 0.031% 17% 6.5% 0.36% 3M Study GLP10-01-02 Interim Report 05 Page 26 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Table 13. Percent Moistures for Decatur Avenue A Soils & Sediments Collected June/July 2010 3 M L IM S ID S a m p le ID Average Percent Relative Percent Moisture (%; w/w) [a] Difference (%) GLP10-01-02-05-114 DAL SS GP11 0 0065 17.8% GLP10-01-02-05-115 DAL SS GP11 DB 0065 21.6% GLP10-01-02-05-116 DAL SS GP12 0 0000 8.02% GLP10-01-02-05-117 DAL SS GP12 0 0005 13.9% GLP10-01-02-05-118 DAL SS GP12 0 0020 13.8% GLP10-01-02-05-119 DAL SS GP12 0 0170 22.1% Relative percent difference (RPD) determined from duplicate aliquot moisture determinations for each sample [a] Values are shown at 3 significant figures; but more precise values were used for calculations. [b] RPD of duplicate determinations was greater than 20% 2.6% 0.72% 2.0% 0.87% 7.2% 1.1% 7.8 Individual Sample Results Table 14. Individual PFOS Results for Decatur Avenue A Soils (June/July 2010) LIM S S am ple ID G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 L M S Sam ple Description D A L S D T R IP 1 0 1 0 0 6 2 4 D A L S D T R IP 1 0 1 0 0 6 2 4 D u p lic a te D A L S D T R IP 1 0 1 0 0 6 2 4 L a b M a trix S p ik e D AL SD SD 01 0 0000 D A L S D S D 0 1 0 0 0 0 0 D u p lic a te D A L S D S D 0 1 0 0 0 0 0 L a b M a trix S p ik e D AL SD SD 01 0 0005 D A L S D S D 0 1 0 0 0 0 5 D u p lic a te D A L S D S D 0 1 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 02 0 0000 D A L S D S D 0 2 0 0 0 0 0 D u p lic a te D A L S D S D 0 2 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 02 0 0005 D A L S D S D 0 2 0 0 0 0 5 D u p lic a te D A L S D S D 0 2 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 03 0 0000 D A L S D S D 0 3 0 0 0 0 0 D u p lic a te D A L S D S D 0 3 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 03 0 0005 D A L S D S D 0 3 0 0 0 0 5 D u p lic a te D A L S D S D 0 3 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 04 0 0000 D A L S D S D 0 4 0 0 0 0 0 D u p lic a te D A L S D S D 0 4 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 04 0 0005 D A L S D S D 0 4 0 0 0 0 5 D u p lic a te D A L S D S D 0 4 0 0 0 0 5 L a b M a trix S p ik e S u rro g a te (13C 4 PFOS) R e co ve ry [d] 98.0% 101% 105% 102% 102% 116% 100% 113% 114% 113% 110% 158% 104% 104% 143% 113% 109% 147% 98.7% 106% 146% 114% 110% 152% 109% 106% 138% A c tu a l LMS S p ik e Conc. (ng/g; dry w e ig h t) N /A 1.84 N /A 1020 N /A 915 N /A 7020 N /A 3810 N /A 6100 N /A 3690 N /A 5640 N /A 3500 Measured PFOS C o n c e n tra tio n (ng/g; dry w e ig h t) BLQ BLQ 1.86 272 178 1280 152 107 1130 7090 6450 14200 997 1140 5330 928 867 7210 516 602 4100 1760 2480 7960 1910 1910 5310 R P D / LMS R ecovery [a] N /A 102% 42% 103% 35% 109% 9.4% 105% 14% 112% 6.8% 103% 15% 96.0% 34% 103% 0.30% 97.1% Average PFOS C o n c e n tra tion (ng/g; dry wt.) BLQ N/A 225 N/A 129 N/A 6770 N/A 1070 N/A 897 N/A 559 N/A 2120 N/A 1910 N/A 3M Study GLP10-01-02 Interim Report 05 Page 27 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 D AL SD S D 05 0 0000 D A L S D S D 0 5 0 0 0 0 0 D u p lic a te D A L S D S D 0 5 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 05 0 0005 D A L S D S D 0 5 0 0 0 0 5 D u p lic a te D A L S D S D 0 5 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 06 0 0000 D A L S D S D 0 6 0 0 0 0 0 D u p lic a te D A L S D S D 0 6 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 06 0 0005 D A L S D S D 0 6 0 0 0 0 5 D u p lic a te D A L S D S D 0 6 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 07 0 0000 D A L S D S D 0 7 0 0 0 0 0 D u p lic a te D A L S D S D 0 7 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 07 0 0005 D A L S D S D 0 7 0 0 0 0 5 D u p lic a te D A L S D S D 0 7 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 08 0 0000 D A L S D S D 0 8 0 0 0 0 0 D u p lic a te D A L S D S D 0 8 0 0 0 0 0 L a b M a trix S p ik e DAL SD S D 08 DB 0000 D A L S D S D 0 8 D B 0 0 0 0 D u p lic a te D A L S D S D 0 8 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 08 0 0005 D A L S D S D 0 8 0 0 0 0 5 D u p lic a te D A L S D S D 0 8 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 09 0 0000 D A L S D S D 0 9 0 0 0 0 0 D u p lic a te D A L S D S D 0 9 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 09 0 0005 D A L S D S D 0 9 0 0 0 0 5 D u p lic a te D A L S D S D 0 9 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 10 0 0000 D A L S D S D 1 0 0 0 0 0 0 D u p lic a te D A L S D S D 1 0 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 10 0 0005 D A L S D S D 1 0 0 0 0 0 5 D u p lic a te D A L S D S D 1 0 0 0 0 0 5 L a b M a trix S p ik e D AL SD SD 11 0 0000 D A L S D S D 1 1 0 0 0 0 0 D u p lic a te D A L S D S D 1 1 0 0 0 0 0 L a b M a trix S p ik e D AL SD SD 11 0 0005 D A L S D S D 1 1 0 0 0 0 5 D u p lic a te D A L S D S D 1 1 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 12 0 0000 Surrogate (1 3 C4 PFOS) Recovery [d] 113% 102% 108% 105% 101% 106% 101% 112% 112% 108% 103% 121% 110% 103% 124% 111% 116% 134% 115% 108% 115% 102% 106% 108% 91.9% 104% 106% 109% 102% 130% 117% 78.9% 137% 105% 134% 102% 178% 140% 112% 104% 119% 145% 114% 112% 115% 108% Actual LMS Spike Conc. (ng/g; dry weight) N/A 754 N/A 773 N/A 720 N/A 454 N/A 3418 N/A 6610 N/A 1035 N/A 957 N/A 738 N/A 5300 N/A 4580 N/A 9800 N/A 6150 N/A 4230 N/A 762 N/A Measured PFOS Concentration (ng/g; dry weight) 554 497 1280 337 283 1060 580 655 1340 329 348 647 1580 1730 4780 1790 3080 8190 505 538 1680 509 571 1340 82.4 104 804 1230 1380 5900 1130 1370 5870 4260 4880 14500 6120 9550 12300 1530 1590 6310 910 662 1530 3370 R P D / LMS Recovery [a] 11% 99.8% 17% 96.8% 12% 99.7% 5.6% 68.0% 9.4% [c] 91.3% [c] 53% [b] 87.0% [b] 6.2% 112% 12% 83.1% 23% 96.4% 11% 86.6% 20% 101% 13% [c] 101% [c] 44% [c] 72.8% [c] 3.9% 112% 32% 97.9% 9.9% Average PFOS Concentra tion (ng/g; dry wt.) 525 N/A 310 N/A 617 N/A 338 N/A 1660 [c] N/A 2430 [b] N/A 521 N/A 540 N/A 93.2 N/A 1300 N/A 1250 N/A 4570 [c] N/A 7830 [c] N/A 1560 N/A 786 N/A 3210 3M Study GLP10-01-02 Interim Report 05 Page 28 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 D u p D A L S D S D 1 2 0 0 0 0 0 D u p lic a te D A L S D S D 1 2 0 0 0 0 0 L a b M a trix S p ik e DAL SD SD 12 DB 0000 D A L S D S D 1 2 D B 0 0 0 0 D u p lic a te D A L S D S D 1 2 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 12 0 0005 D A L S D S D 1 2 0 0 0 0 5 D u p lic a te D A L S D S D 1 2 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 13 0 0000 D A L S D S D 1 3 0 0 0 0 0 D u p lic a te D A L S D S D 1 3 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 13 0 0005 D A L S D S D 1 3 0 0 0 0 5 D u p lic a te D A L S D S D 1 3 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 14 0 0000 D A L S D S D 1 4 0 0 0 0 0 D u p lic a te D A L S D S D 1 4 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 14 0 0005 D A L S D S D 1 4 0 0 0 0 5 D u p lic a te D A L S D S D 1 4 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 15 0 0000 D A L S D S D 1 5 0 0 0 0 0 D u p lic a te D A L S D S D 1 5 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 15 0 0005 D A L S D S D 1 5 0 0 0 0 5 D u p lic a te D A L S D S D 1 5 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 16 0 0000 D A L S D S D 1 6 0 0 0 0 0 D u p lic a te D A L S D S D 1 6 0 0 0 0 0 L a b M a trix S p ik e DAL SD S D 16 DB 0000 D A L S D S D 1 6 D B 0 0 0 0 D u p lic a te D A L S D S D 1 6 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 16 0 0005 D A L S D S D 1 6 0 0 0 0 5 D u p lic a te D A L S D S D 1 6 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 17 0 0000 D A L S D S D 1 7 0 0 0 0 0 D u p lic a te D A L S D S D 1 7 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 17 0 0005 D A L S D S D 1 7 0 0 0 0 5 D u p lic a te D A L S D S D 1 7 0 0 0 0 5 L a b M a trix S p ik e D A L SS SS01 0 0000 D A L S S S S 0 1 0 0 0 0 0 D u p lic a te D A L S S S S 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS SS01 0 0005 D A L S S S S 0 1 0 0 0 0 5 D u p lic a te Surrogate (1 3 C4 PFOS) Recovery [d] 109% 161% 108% 114% 134% 111% 102% 140% 108% 107% 134% 116% 90.6% 165% 106% 124% 234% 109% 104% 152% 178% 232% 267% 167% 164% 286% 126% 123% 195% 114% 122% 175% 112% 107% 135% 137% 141% 153% 132% 108% 135% 106% 106% 98.0% 104% 103% Actual LMS Spike Conc. (ng/g; dry weight) 6040 N/A 7140 N/A 3680 N/A 4210 N/A 3080 N/A 25700 N/A 4050 N/A 22000 N/A 20700 N/A 5060 N/A 5700 N/A 5020 N/A 5200 N/A 4950 N/A 819 N/A Measured PFOS Concentration (ng/g; dry weight) 3050 8600 3130 3410 9700 474 428 3770 1260 1250 5290 1590 1370 4630 9540 8730 31300 4720 6030 8830 13400 15800 39500 14100 12200 38800 8140 5990 12000 8770 8420 13600 2380 3860 8100 11400 10100 14700 8270 5970 13400 761 738 1480 986 852 R P D / LMS Recovery [a] 89.3% 8.7% 90.2% 10% 90.3% 0.86% 96.0% 15% 150% [e] 8.9% 122% 24% 85.4% 16% 113% 14% 124% 30% 98.4% 4.0% 87.1% 47% 99.1% 12% 75.7% 32% 127% 3.0% 88.5% 15% Average PFOS Concentra tion (ng/g; dry wt.) N/A 3270 N/A 451 N/A 1250 N/A 1480 [e] N/A 9130 N/A 5370 N/A 14600 N/A 13200 N/A 7060 N/A 8590 N/A 3120 N/A 10700 N/A 7120 N/A 750 N/A 919 3M Study GLP10-01-02 Interim Report 05 Page 29 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 L M S D A L S S S S 0 1 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 02 0 0000 D A L S S S S 0 2 0 0 0 0 0 D u p lic a te D A L S S S S 0 2 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 02 0 0005 D A L S S S S 0 2 0 0 0 0 5 D u p lic a te D A L S S S S 0 2 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 03 0 0000 D A L S S S S 0 3 0 0 0 0 0 D u p lic a te D A L S S S S 0 3 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 03 0 0005 D A L S S S S 0 3 0 0 0 0 5 D u p lic a te D A L S S S S 0 3 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 03 DB 0005 D A L S S S S 0 3 D B 0 0 0 5 D u p lic a te D A L S S S S 0 3 D B 0 0 0 5 L a b M a trix S p ik e DAL SS SS 04 0 0000 D A L S S S S 0 4 0 0 0 0 0 D u p lic a te D A L S S S S 0 4 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 04 0 0005 D A L S S S S 0 4 0 0 0 0 5 D u p lic a te D A L S S S S 0 4 0 0 0 0 5 L a b M a trix S p ik e D A L S S T R IP 1 0 0 0 0 0 D A L S S T R IP 1 0 0 0 0 0 D u p lic a te D A L S S T R IP 1 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 05 0 0000 D A L S S S S 0 5 0 0 0 0 0 D u p lic a te D A L S S S S 0 5 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 05 0 0005 D A L S S S S 0 5 0 0 0 0 5 D u p lic a te D A L S S S S 0 5 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 06 0 0000 D A L S S S S 0 6 0 0 0 0 0 D u p lic a te D A L S S S S 0 6 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 06 0 0005 D A L S S S S 0 6 0 0 0 0 5 D u p lic a te D A L S S S S 0 6 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 06 DB 0005 D A L S S S S 0 6 D B 0 0 0 5 D u p lic a te D A L S S S S 0 6 D B 0 0 0 5 L a b M a trix S p ik e DAL SS SS 07 0 0000 D A L S S S S 0 7 0 0 0 0 0 D u p lic a te D A L S S S S 0 7 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 07 0 0005 D A L S S S S 0 7 0 0 0 0 5 D u p lic a te D A L S S S S 0 7 0 0 0 0 5 L a b M a trix S p ik e Surrogate (1 3 C4 PFOS) Recovery [d] 114% 96.3% 102% 109% 97.3% 101% 98.0% 104% 110% 144% 116% 110% 127% 108% 126% 149% 99.0% 108% 105% 109% 104% 105% 91.6% 99.3% 88.6% 149% 152% 281% 117% 132% 133% 97.7% 93.3% 92.3% 96.6% 85.9% 107% 96.3% 99.0% 103% 102% 98.3% 106% 105% 99.3% 129% Actual LMS Spike Conc. (ng/g; dry weight) 764 N/A 888 N/A 830 N/A NR N/A 2790 N/A 3390 N/A 429 N/A 476 N/A 1.85 N/A 20400 N/A 4650 N/A 494 N/A 484 N/A 475 N/A 621 N/A 4780 Measured PFOS Concentration (ng/g; dry weight) 1780 387 423 1590 207 130 1050 NR NR NR 1990 2240 4300 3300 2450 5600 523 489 1130 179 180 676 0.305 BLQ 2.04 9970 11300 33300 4280 3810 7740 338 324 891 131 133 626 169 159 575 703 790 1400 3170 3120 7453 R P D / LMS Recovery [a] 112% 8.9% 133% [e] 46% 107% NR NR 12% 78.5% 30% 80.3% 6.7% [c] 146% [c, e] 0.73% 104% N/A [f] 94.0% 12% 111% 12% 79.7% 4.2% 113% 2.2% 102% 6.1% 86.4% 12% 106% 1.6% 90.2% Average PFOS Concentra tion (ng/g; dry wt.) N/A 405 [e] N/A 168 N/A NR N/A 2110 N/A 2880 N/A 506 [c, e] N/A 179 N/A 0.305 [f] N/A 10600 N/A 4040 N/A 331 N/A 132 N/A 164 N/A 747 N/A 3140 N/A 3M Study GLP10-01-02 Interim Report 05 Page 30 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 DAL SS SS 08 0 0000 D A L S S S S 0 8 0 0 0 0 0 D u p lic a te D A L S S S S 0 8 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 08 DB 0000 D A L S S S S 0 8 D B 0 0 0 0 D u p lic a te D A L S S S S 0 8 D B 0 0 0 0 L a b M a trix S p ik e DAL SS SS 08 0 0005 D A L S S S S 0 8 0 0 0 0 5 D u p lic a te D A L S S S S 0 8 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 09 0 0000 D A L S S S S 0 9 0 0 0 0 0 D u p lic a te D A L S S S S 0 9 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 09 0 0005 D A L S S S S 0 9 0 0 0 0 5 D u p lic a te D A L S S S S 0 9 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 01 0 0000 D A L S S G P 0 1 0 0 0 0 0 D u p lic a te D A L S S G P 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS G P 01 0 0005 D A L S S G P 0 1 0 0 0 0 5 D u p lic a te D A L S S G P 0 1 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 01 0 0020 D A L S S G P 0 1 0 0 0 2 0 D u p lic a te D A L S S G P 0 1 0 0 0 2 0 L a b M a trix S p ik e D A L SS G P 01 0 0060 D A L S S G P 0 1 0 0 0 6 0 D u p lic a te D A L S S G P 0 1 0 0 0 6 0 L a b M a trix S p ik e D AL SS G P 02 0 0000 D A L S S G P 0 2 0 0 0 0 0 D u p lic a te D A L S S G P 0 2 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 02 0 0005 D A L S S G P 0 2 0 0 0 0 5 D u p lic a te D A L S S G P 0 2 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 02 0 0020 D A L S S G P 0 2 0 0 0 2 0 D u p lic a te D A L S S G P 0 2 0 0 0 2 0 L a b M a trix S p ik e DAL SS G P 02 DB 0020 D A L S S G P 0 2 D B 0 0 2 0 D u p lic a te D A L S S G P 0 2 D B 0 0 2 0 L a b M a trix S p ik e D AL SS G P 02 0 0120 D A L S S G P 0 2 0 0 1 2 0 D u p lic a te D A L S S G P 0 2 0 0 1 2 0 L a b M a trix S p ik e D AL SS G P 03 0 0000 D A L S S G P 0 3 0 0 0 0 0 D u p lic a te D A L S S G P 0 3 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 03 0 0005 Surrogate (1 3 C4 PFOS) Recovery [d] 107% 104% 90.9% 91.6% 95.0% 102% 84.9% 102% 97.3% 100% 108% 103% 101% 98.7% 100% 105% 101% 109% 102% 106% 104% 95.6% 87.2% 102% 85.6% 96.0% 95.0% 100% 90.3% 98.0% 88.9% 92.3% 89.3% 102% 103% 94.6% 104% 101% 93.0% 100% 98% 100% 95.6% 109% 102% 102% Actual LMS Spike Conc. (ng/g; dry weight) N/A 73.2 N/A 77.9 N/A 82.4 N/A 489 N/A 461 N/A 420 N/A 224 N/A 366 N/A 74.3 N/A 80.7 N/A 71.5 N/A 349 N/A 338 N/A 11.5 N/A 483 N/A Measured PFOS Concentration (ng/g; dry weight) 48.8 59.1 112 44.5 48.4 129 26.8 25.7 111 636 634 1080 416 416 830 323 409 690 103 146 393 300 283 621 23.7 34.3 106 71.3 61.2 153 78.8 74.5 149 199 190 522 190 157 569 6.37 4.59 18.0 654 747 1080 2250 R P D / LMS Recovery [a] 19% 79.3% 8.4% 106% 4.0% 103% 0.39% 90.3% 0.055% 89.8% 23% 77.1% 35% 120% 5.9% 90.0% 37% 104% 15% 107% 5.6% 101% 4.7% 93.6% 19% 117% 32% 109% 13% 79.2% 17% Average PFOS Concentra tion (ng/g; dry wt.) 53.9 N/A 46.5 N/A 26.2 N/A 635 N/A 416 N/A 366 N/A 125 N/A 292 N/A 29.0 N/A 66.3 N/A 76.7 N/A 195 N/A 173 N/A 5.48 N/A 700 N/A 2070 3M Study GLP10-01-02 Interim Report 05 Page 31 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 D u p D A L S S G P 0 3 0 0 0 0 5 D u p lic a te D A L S S G P 0 3 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 03 0 0020 D A L S S G P 0 3 0 0 0 2 0 D u p lic a te D A L S S G P 0 3 0 0 0 2 0 L a b M a trix S p ik e DAL SS G P 03 DB 0020 D A L S S G P 0 3 D B 0 0 2 0 D u p lic a te D A L S S G P 0 3 D B 0 0 2 0 L a b M a trix S p ik e D AL SS G P 03 0 0050 D A L S S G P 0 3 0 0 0 5 0 D u p lic a te D A L S S G P 0 3 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 04 0 0000 D A L S S G P 0 4 0 0 0 0 0 D u p lic a te D A L S S G P 0 4 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 04 0 0005 D A L S S G P 0 4 0 0 0 0 5 D u p lic a te D A L S S G P 0 4 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 04 0 0020 D A L S S G P 0 4 0 0 0 2 0 D u p lic a te D A L S S G P 0 4 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 04 0 0050 D A L S S G P 0 4 0 0 0 5 0 D u p lic a te D A L S S G P 0 4 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 05 0 0000 D A L S S G P 0 5 0 0 0 0 0 D u p lic a te D A L S S G P 0 5 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 05 0 0005 D A L S S G P 0 5 0 0 0 0 5 D u p lic a te D A L S S G P 0 5 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 05 0 0020 D A L S S G P 0 5 0 0 0 2 0 D u p lic a te D A L S S G P 0 5 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 05 0 0055 D A L S S G P 0 5 0 0 0 5 5 D u p lic a te D A L S S G P 0 5 0 0 0 5 5 L a b M a trix S p ik e D AL SS G P 06 0 0000 D A L S S G P 0 6 0 0 0 0 0 D u p lic a te D A L S S G P 0 6 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 06 0 0005 D A L S S G P 0 6 0 0 0 0 5 D u p lic a te D A L S S G P 0 6 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 06 0 0020 D A L S S G P 0 6 0 0 0 2 0 D u p lic a te D A L S S G P 0 6 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 06 0 0110 D A L S S G P 0 6 0 0 1 1 0 D u p lic a te Surrogate (1 3 C4 PFOS) Recovery [d] 100% 121% 114% 103% 130% 105% 117% 127% 104% 95.6% 110% 112% 102% 111% 105% 99.3% 116% 105% 103% 100% 94.3% 100% 97.3% 105% 97.0% 94.6% 104% 109% 93.3% 100% 102% 94.6% 103% 97.7% 106% 93.0% 101% 102% 105% 99.3% 94.3% 102% 106% 100% 94.6% 95.3% Actual LMS Spike Conc. (ng/g; dry weight) 4330 N/A 3490 N/A 2910 N/A 564 N/A 762 N/A 480 N/A 78.7 N/A 73.0 N/A 537 N/A 479 N/A 311 N/A 1040 N/A 355 N/A 408 N/A 457 N/A Measured PFOS Concentration (ng/g; dry weight) 1890 5750 1420 1470 4400 1160 1310 4180 338 366 880 811 869 1300 559 467 1028 81.1 117 192 37.5 28.8 100 352 341 769 362 400 801 402 457 650 1100 1060 2020 208 210 546 453 440 780 153 119 575 43.0 39.8 R P D / LMS Recovery [a] 84.8% 3.6% 84.6% 12% [c] 101% [c] 8.1% 93.7% 7.0% [c] 60.7% [c, e] 18% 107% 37% 118% 26% 91.5% 3.2% 78.7% 10% 87.7% 13% 70.9% 4.3% 90.1% 1.2% 95.0% 2.9% 81.8% 25% 96.2% 7.8% Average PFOS Concentra tion (ng/g; dry wt.) N/A 1450 N/A 1240 [c] N/A 352 N/A 840 [c] N/A 513 N/A 99.2 N/A 33.2 N/A 346 N/A 381 N/A 429 N/A 1080 N/A 209 N/A 447 N/A 136 N/A 41.4 3M Study GLP10-01-02 Interim Report 05 Page 32 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 L M S D A L S S G P 0 6 0 0 1 1 0 L a b M a trix S p ik e D AL SS G P 07 0 0000 D A L S S G P 0 7 0 0 0 0 0 D u p lic a te D A L S S G P 0 7 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 07 0 0005 D A L S S G P 0 7 0 0 0 0 5 D u p lic a te D A L S S G P 0 7 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 07 0 0020 D A L S S G P 0 7 0 0 0 2 0 D u p lic a te D A L S S G P 0 7 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 07 0 0130 D A L S S G P 0 7 0 0 1 3 0 D u p lic a te D A L S S G P 0 7 0 0 1 3 0 L a b M a trix S p ik e D AL SS G P 08 0 0000 D A L S S G P 0 8 0 0 0 0 0 D u p lic a te D A L S S G P 0 8 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 08 0 0005 D A L S S G P 0 8 0 0 0 0 5 D u p lic a te D A L S S G P 0 8 0 0 0 0 5 L a b M a trix S p ik e DAL SS G P 08 DB 0005 D A L S S G P 0 8 D B 0 0 0 5 D u p lic a te D A L S S G P 0 8 D B 0 0 0 5 L a b M a trix S p ik e D AL SS G P 08 0 0020 D A L S S G P 0 8 0 0 0 2 0 D u p lic a te D A L S S G P 0 8 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 08 0 0050 D A L S S G P 0 8 0 0 0 5 0 D u p lic a te D A L S S G P 0 8 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 09 0 0000 D A L S S G P 0 9 0 0 0 0 0 D u p lic a te D A L S S G P 0 9 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 09 0 0005 D A L S S G P 0 9 0 0 0 0 5 D u p lic a te D A L S S G P 0 9 0 0 0 0 5 L a b M a trix S p ik e DAL SS G P 09 DB 0005 D A L S S G P 0 9 D B 0 0 0 5 D u p lic a te D A L S S G P 0 9 D B 0 0 0 5 L a b M a trix S p ik e D AL SS G P 09 0 0020 D A L S S G P 0 9 0 0 0 2 0 D u p lic a te D A L S S G P 0 9 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 09 0 0050 D A L S S G P 0 9 0 0 0 5 0 D u p lic a te D A L S S G P 0 9 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 10 0 0000 D A L S S G P 1 0 0 0 0 0 0 D u p lic a te D A L S S G P 1 0 0 0 0 0 0 L a b M a trix S p ik e Surrogate (1 3 C4 PFOS) Recovery [d] 94.0% 94.6% 103% 103% 123% 114% 193% 98.0% 97.3% 107% 174% 163% 241% 118% 216% 154% 108% 115% 113% 101% 93% 103% 100% 94.6% 100% 103% 106% 106% 96.6% 117% 127% 90% 104% 149% 111% 107% 133% 104% 103% 97.0% 95.3% 83.6% 88.6% 100% 89.9% 102% Actual LMS Spike Conc. (ng/g; dry weight) 88.7 N/A 609 N/A 6880 N/A 904 N/A 16100 N/A 17600 N/A 894 N/A 946 N/A 557 N/A 531 N/A 4340 N/A 4680 N/A 3690 N/A 542 N/A 103 N/A 480 Measured PFOS Concentration (ng/g; dry weight) 121 635 563 1120 3900 3470 10200 2040 1690 2450 13900 14100 21100 5700 4630 20300 773 767 1610 1060 950 1980 308 336 926 413 261 824 3790 3480 6640 1550 1710 5570 2750 1800 6630 289 374 847 72 56 148 855 614 1420 R P D / LMS Recovery [a] 89.3% 12% 85.7% 12% 94.4% 19% 64.4% [e] 1.6% 43.9% [e] 21% 85.7% 0.77% 93.8% 11% 103% 8.6% 108% 45% 91.7% 8.5% 69.3% [e] 10% 84.2% 42% [c] 118% [c] 26% 95.0% 25% 80.7% 33% 143% [e] Average PFOS Concentra tion (ng/g; dry wt.) N/A 599 N/A 3680 N/A 1870 [e] N/A 14000 [e] N/A 5160 N/A 770 N/A 1010 N/A 322 N/A 337 N/A 3630[e] N/A 1630 N/A 2280[c] N/A 331 N/A 64.3 N/A 734 [e] N/A 3M Study GLP10-01-02 Interim Report 05 Page 33 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 14. In d iv id u a l P F O S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description Surrogate (13C4 PFOS) Recovery [d] Actual LMS Spike Conc. (ng/g; dry weight) Measured PFOS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFOS Concentra tion (ng/g; dry wt.) G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 D u p D AL SS G P 10 0 0005 D A L S S G P 1 0 0 0 0 0 5 D u p lic a te 102% 98.3% N/A 605 557 8.2% 581 G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 L M S D A L S S G P 1 0 0 0 0 0 5 L a b M a trix S p ik e 109% 565 1270 121% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 D u p D AL SS G P 10 0 0020 D A L S S G P 1 0 0 0 0 2 0 D u p lic a te 98.0% 108% N/A 285 309 8.1% 297 G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 L M S D A L S S G P 1 0 0 0 0 2 0 L a b M a trix S p ik e 95.0% 452 695 88.0% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 D u p D AL SS G P 10 0 0060 D A L S S G P 1 0 0 0 0 6 0 D u p lic a te 107% 136 N/A 33% [c] 139 [c] 93.0% 142 G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 L M S D A L S S G P 1 0 0 0 0 6 0 L a b M a trix S p ik e 96.3% 396 541 102% [c] N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 D u p D A L SS G P 11 0 0000 D A L S S G P 1 1 0 0 0 0 0 D u p lic a te 102% 95.0% N/A 188 125 40% 157 G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 L M S D A L S S G P 1 1 0 0 0 0 0 L a b M a trix S p ik e 96.3% 394 488 84.1% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 D u p D A L SS G P 11 0 0005 D A L S S G P 1 1 0 0 0 0 5 D u p lic a te 98.7% 105% N/A 116 131 12% 123 G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 L M S D A L S S G P 1 1 0 0 0 0 5 L a b M a trix S p ik e 102% 505 636 102% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 D u p D A L SS G P 11 0 0020 D A L S S G P 1 1 0 0 0 2 0 D u p lic a te 91.9% 101% N/A 194 289 39% 242 G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 L M S D A L S S G P 1 1 0 0 0 2 0 L a b M a trix S p ik e 97.0% 400 594 88.2% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 D u p D A L SS G P 11 0 0065 D A L S S G P 1 1 0 0 0 6 5 D u p lic a te 84.9% 110% N/A 244 337 32% 290 G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 L M S D A L S S G P 1 1 0 0 0 6 5 L a b M a trix S p ik e 96.6% 533 905 115% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 D u p D A L SS G P 11 D B 0065 D A L S S G P 1 1 D B 0 0 6 5 D u p lic a te 91.9% 104% N/A 577 580 0.54% 579 G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 L M S D A L S S G P 1 1 D B 0 0 6 5 L a b M a trix S p ik e 108% 588 1200 106% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 D u p D AL SS G P 12 0 0000 D A L S S G P 1 2 0 0 0 0 0 D u p lic a te 99.0% 108% N/A 547 785 36% 666 G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 L M S D A L S S G P 1 2 0 0 0 0 0 L a b M a trix S p ik e 100% 486 1150 100% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 D u p D AL SS G P 12 0 0005 D A L S S G P 1 2 0 0 0 0 5 D u p lic a te 93.0% 102% N/A 376 437 15% 407 G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 L M S D A L S S G P 1 2 0 0 0 0 5 L a b M a trix S p ik e 100% 473 875 98.9% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 D u p D AL SS G P 12 0 0020 D A L S S G P 1 2 0 0 0 2 0 D u p lic a te 101% 101% N/A 470 450 4.3% 460 G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 L M S D A L S S G P 1 2 0 0 0 2 0 L a b M a trix S p ik e 93.0% 499 858 80.0% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 D u p D AL SS G P 12 0 0170 D A L S S G P 1 2 0 0 1 7 0 D u p lic a te 89.6% 86.9% N/A 64.7 53.5 19% 59.1 G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 L M S D A L S S G P 1 2 0 0 1 7 0 L a b M a trix S p ik e 98.3% 119 207 124% N/A [a] LMSs fortified with PFOS (linear isomer). [b] RPD was greater than 50%. [c] The value reported was determined from a re-assay. [d] Surrogate recovery determined for samples fortified with 2.98 ng of 13C4-PFOS and quantified from a 13C4-PFOS calibration curve. [e] LMS recovery was outside of method criteria of 100 + 30%, but within reporting criteria of 100 + 60%. [f] Value reported from single result, duplicate result was BLQ NR; not reported because a reliable value could not be attained based on QC results. N/A; not applicable Note: LMS recoveries and analyte concentration results are reported at 3 significant figures, RPDs are reported at 2 significant figures, but more precise values were used for data calculations 3M Study GLP10-01-02 Interim Report 05 Page 34 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 D A L S D T R IP 1 0 1 0 0 6 2 4 D A L S D T R IP 1 0 1 0 0 6 2 4 D u p lic a te D A L S D T R IP 1 0 1 0 0 6 2 4 L a b M a trix S p ik e D AL SD SD 01 0 0000 D A L S D S D 0 1 0 0 0 0 0 D u p lic a te D A L S D S D 0 1 0 0 0 0 0 L a b M a trix S p ik e D AL SD SD 01 0 0005 D A L S D S D 0 1 0 0 0 0 5 D u p lic a te D A L S D S D 0 1 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 02 0 0000 D A L S D S D 0 2 0 0 0 0 0 D u p lic a te D A L S D S D 0 2 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 02 0 0005 D A L S D S D 0 2 0 0 0 0 5 D u p lic a te D A L S D S D 0 2 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 03 0 0000 D A L S D S D 0 3 0 0 0 0 0 D u p lic a te D A L S D S D 0 3 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 03 0 0005 D A L S D S D 0 3 0 0 0 0 5 D u p lic a te D A L S D S D 0 3 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 04 0 0000 D A L S D S D 0 4 0 0 0 0 0 D u p lic a te D A L S D S D 0 4 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 04 0 0005 D A L S D S D 0 4 0 0 0 0 5 D u p lic a te D A L S D S D 0 4 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 05 0 0000 D A L S D S D 0 5 0 0 0 0 0 D u p lic a te D A L S D S D 0 5 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 05 0 0005 D A L S D S D 0 5 0 0 0 0 5 D u p lic a te D A L S D S D 0 5 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 06 0 0000 D A L S D S D 0 6 0 0 0 0 0 D u p lic a te D A L S D S D 0 6 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 06 0 0005 D A L S D S D 0 6 0 0 0 0 5 D u p lic a te D A L S D S D 0 6 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 07 0 0000 D A L S D S D 0 7 0 0 0 0 0 D u p lic a te D A L S D S D 0 7 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 07 0 0005 D A L S D S D 0 7 0 0 0 0 5 D u p lic a te D A L S D S D 0 7 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 08 0 0000 N/A 1.83 N/A 5.12 N/A 4.58 N/A 140 N/A 76.1 N/A 122 N/A 73.6 N/A 564 N/A 350 N/A 75.3 N/A 77.2 N/A 71.9 N/A 45.3 N/A 117 N/A 132 N/A BLQ BLQ 1.82 3.38 2.18 4.99 2.31 1.14 4.31 67.1 61.9 198 12.4 13.1 89.1 46.9 49.4 177 14.2 23.7 107 150 206 729 80.3 77.7 425 32.6 36.5 119 27.3 24.7 119 40.2 39.0 118 18.5 19.4 65.4 57.7 45.9 167 51.1 70.7 202 43.9 N/A 99.1% 43% 43.3% [d] 68% [b] 56.5% [b, d] 8.1% 95.1% 5.5% 100% 5.1% 106% 50% 119% 31% 97.8% 3.3% 98.8% 11% 112% 10% 120% 3.0% 109% 5.0% 102% 23% 97.9% 32% 107% 4.6% BLQ N/A 2.78 [d] N/A 1.72 [b, d] N/A 64.5 N/A 12.7 N/A 48.1 N/A 19.0 N/A 178 N/A 79.0 N/A 34.5 N/A 26.0 N/A 39.6 N/A 18.9 N/A 51.8 N/A 60.9 N/A 42.9 [d] 3M Study GLP10-01-02 Interim Report 05 Page 35 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 D u p D A L S D S D 0 8 0 0 0 0 0 D u p lic a te D A L S D S D 0 8 0 0 0 0 0 L a b M a trix S p ik e DAL SD S D 08 DB 0000 D A L S D S D 0 8 D B 0 0 0 0 D u p lic a te D A L S D S D 0 8 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 08 0 0005 D A L S D S D 0 8 0 0 0 0 5 D u p lic a te D A L S D S D 0 8 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 09 0 0000 D A L S D S D 0 9 0 0 0 0 0 D u p lic a te D A L S D S D 0 9 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 09 0 0005 D A L S D S D 0 9 0 0 0 0 5 D u p lic a te D A L S D S D 0 9 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 10 0 0000 D A L S D S D 1 0 0 0 0 0 0 D u p lic a te D A L S D S D 1 0 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 10 0 0005 D A L S D S D 1 0 0 0 0 0 5 D u p lic a te D A L S D S D 1 0 0 0 0 0 5 L a b M a trix S p ik e D AL SD SD 11 0 0000 D A L S D S D 1 1 0 0 0 0 0 D u p lic a te D A L S D S D 1 1 0 0 0 0 0 L a b M a trix S p ik e D AL SD SD 11 0 0005 D A L S D S D 1 1 0 0 0 0 5 D u p lic a te D A L S D S D 1 1 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 12 0 0000 D A L S D S D 1 2 0 0 0 0 0 D u p lic a te D A L S D S D 1 2 0 0 0 0 0 L a b M a trix S p ik e DAL SD SD 12 DB 0000 D A L S D S D 1 2 D B 0 0 0 0 D u p lic a te D A L S D S D 1 2 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 12 0 0005 D A L S D S D 1 2 0 0 0 0 5 D u p lic a te D A L S D S D 1 2 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 13 0 0000 D A L S D S D 1 3 0 0 0 0 0 D u p lic a te D A L S D S D 1 3 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 13 0 0005 D A L S D S D 1 3 0 0 0 0 5 D u p lic a te D A L S D S D 1 3 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 14 0 0000 D A L S D S D 1 4 0 0 0 0 0 D u p lic a te D A L S D S D 1 4 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 14 0 0005 D A L S D S D 1 4 0 0 0 0 5 D u p lic a te Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) 103 N/A 478 N/A 73.7 N/A 530 N/A 458 N/A 1960 N/A 1231 N/A 422 N/A 76.1 N/A 604 N/A 713 N/A 367 N/A 420 N/A 308 N/A 2571 N/A 41.9 184 45.0 47.1 508 8.26 9.80 84.8 133 136 708 99 102 578 961 1100 2650 547 370 1400 169 143 587 63.1 52.7 137 270 308 893 274 311 990 81.4 72.7 459 131 115 546 134 142 438 1500 1410 3870 1310 1610 137% [d] 4.6% 96.7% 17% 103% 2.0% 108% 2.9% 104% 14% 82.4% 39% 76.2% 17% 102% 18% 104% 13% 100% 13% 97.9% 11% 104% 13% 101% 6.0% 142% [d] 5.7% 151% [d] 20% N/A 46.0 N/A 9.03 N/A 135 N/A 101 N/A 1030 N/A 459 N/A 156 N/A 57.9 N/A 289 N/A 293 N/A 77.0 N/A 123 N/A 138 [d] N/A 1450 [d] N/A 1460 3M Study GLP10-01-02 Interim Report 05 Page 36 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 L M S D A L S D S D 1 4 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 15 0 0000 D A L S D S D 1 5 0 0 0 0 0 D u p lic a te D A L S D S D 1 5 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 15 0 0005 D A L S D S D 1 5 0 0 0 0 5 D u p lic a te D A L S D S D 1 5 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 16 0 0000 D A L S D S D 1 6 0 0 0 0 0 D u p lic a te D A L S D S D 1 6 0 0 0 0 0 L a b M a trix S p ik e DAL SD S D 16 DB 0000 D A L S D S D 1 6 D B 0 0 0 0 D u p lic a te D A L S D S D 1 6 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 16 0 0005 D A L S D S D 1 6 0 0 0 0 5 D u p lic a te D A L S D S D 1 6 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 17 0 0000 D A L S D S D 1 7 0 0 0 0 0 D u p lic a te D A L S D S D 1 7 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 17 0 0005 D A L S D S D 1 7 0 0 0 0 5 D u p lic a te D A L S D S D 1 7 0 0 0 0 5 L a b M a trix S p ik e D A L SS SS01 0 0000 D A L S S S S 0 1 0 0 0 0 0 D u p lic a te D A L S S S S 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS SS01 0 0005 D A L S S S S 0 1 0 0 0 0 5 D u p lic a te D A L S S S S 0 1 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 02 0 0000 D A L S S S S 0 2 0 0 0 0 0 D u p lic a te D A L S S S S 0 2 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 02 0 0005 D A L S S S S 0 2 0 0 0 0 5 D u p lic a te D A L S S S S 0 2 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 03 0 0000 D A L S S S S 0 3 0 0 0 0 0 D u p lic a te D A L S S S S 0 3 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 03 0 0005 D A L S S S S 0 3 0 0 0 0 5 D u p lic a te D A L S S S S 0 3 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 03 DB 0005 D A L S S S S 0 3 D B 0 0 0 5 D u p lic a te D A L S S S S 0 3 D B 0 0 0 5 L a b M a trix S p ik e DAL SS SS 04 0 0000 D A L S S S S 0 4 0 0 0 0 0 D u p lic a te D A L S S S S 0 4 0 0 0 0 0 L a b M a trix S p ik e Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) 1621 N/A 2203 N/A 517 N/A 2023 N/A 2278 N/A 2010 N/A 2080 N/A 1981 N/A 8.18 N/A 7.63 N/A 8.87 N/A 82.9 N/A 371 N/A 278 N/A 339 N/A 8.58 2790 369 429 2650 158 135 700 830 698 2990 866 794 3400 505 633 2590 1140 1030 2990 958 749 3180 4.35 5.12 14 5.20 4.92 13.4 7.59 6.94 17.6 61.1 48.0 134 225 199 727 98.6 138 422 124 95.0 478 5.60 5.57 14.3 82.0% 15% 102% 16% 107% 17% 110% 8.7% 113% 23% 101% 11% 91.7% 25% 117% 16% 113% 5.5% 109% 8.9% 116% 24% 96.4% 12% 139% [d] 33% 109% 26% 109% 0.63% [c] 101% [c] N/A 399 N/A 146 N/A 764 N/A 830 N/A 569 N/A 1080 N/A 853 N/A 4.73 N/A 5.06 N/A 7.26 N/A 54.6 N/A 212 [d] N/A 118 N/A 109 N/A 5.59 [c] N/A 3M Study GLP10-01-02 Interim Report 05 Page 37 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 DAL SS SS 04 0 0005 D A L S S S S 0 4 0 0 0 0 5 D u p lic a te D A L S S S S 0 4 0 0 0 0 5 L a b M a trix S p ik e D A L S S T R IP 1 0 0 0 0 0 D A L S S T R IP 1 0 0 0 0 0 D u p lic a te D A L S S T R IP 1 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 05 0 0000 D A L S S S S 0 5 0 0 0 0 0 D u p lic a te D A L S S S S 0 5 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 05 0 0005 D A L S S S S 0 5 0 0 0 0 5 D u p lic a te D A L S S S S 0 5 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 06 0 0000 D A L S S S S 0 6 0 0 0 0 0 D u p lic a te D A L S S S S 0 6 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 06 0 0005 D A L S S S S 0 6 0 0 0 0 5 D u p lic a te D A L S S S S 0 6 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 06 DB 0005 D A L S S S S 0 6 D B 0 0 0 5 D u p lic a te D A L S S S S 0 6 D B 0 0 0 5 L a b M a trix S p ik e DAL SS SS 07 0 0000 D A L S S S S 0 7 0 0 0 0 0 D u p lic a te D A L S S S S 0 7 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 07 0 0005 D A L S S S S 0 7 0 0 0 0 5 D u p lic a te D A L S S S S 0 7 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 08 0 0000 D A L S S S S 0 8 0 0 0 0 0 D u p lic a te D A L S S S S 0 8 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 08 DB 0000 D A L S S S S 0 8 D B 0 0 0 0 D u p lic a te D A L S S S S 0 8 D B 0 0 0 0 L a b M a trix S p ik e DAL SS SS 08 0 0005 D A L S S S S 0 8 0 0 0 0 5 D u p lic a te D A L S S S S 0 8 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 09 0 0000 D A L S S S S 0 9 0 0 0 0 0 D u p lic a te D A L S S S S 0 9 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 09 0 0005 D A L S S S S 0 9 0 0 0 0 5 D u p lic a te D A L S S S S 0 9 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 01 0 0000 D A L S S G P 0 1 0 0 0 0 0 D u p lic a te D A L S S G P 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS G P 01 0 0005 Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) N/A 9.51 N/A 1.84 N/A 509 N/A 92.9 N/A 9.88 N/A 1.93 N/A 1.90 N/A 124 N/A 95.5 N/A 7.31 N/A 7.78 N/A 8.24 N/A 9.78 N/A 9.21 N/A 8.39 N/A 2.20 1.87 12.1 BLQ BLQ 1.85 299 277 865 68.3 66.9 161 2.61 2.60 12.8 0.913 1.04 2.90 1.31 1.02 3.00 57.3 61.9 180 66.3 66.3 155 4.26 5.34 10.8 3.87 4.15 12.2 1.77 1.63 10.1 6.78 7.26 16.8 4.36 4.71 13.5 5.17 6.80 14.5 4.11 16% 106% N/A 100% 7.5% 114% 2.0% 100% 0.014% 103% 13% 99.3% 25% 96.7% 7.7% 97.1% 0.037% 92.7% 23% 82.5% 7.0% 105% 8.2% 102% 6.9% 100% 7.7% 96.9% 27% 102% 33% 2.03 N/A BLQ N/A 288 N/A 67.6 N/A 2.61 N/A 0.975 N/A 1.17 N/A 59.6 N/A 66.3 N/A 4.80 N/A 4.01 N/A 1.70 N/A 7.02 N/A 4.53 N/A 5.99 N/A 4.92 [d] 3M Study GLP10-01-02 Interim Report 05 Page 38 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 D u p D A L S S G P 0 1 0 0 0 0 5 D u p lic a te D A L S S G P 0 1 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 01 0 0020 D A L S S G P 0 1 0 0 0 2 0 D u p lic a te D A L S S G P 0 1 0 0 0 2 0 L a b M a trix S p ik e D A L SS G P 01 0 0060 D A L S S G P 0 1 0 0 0 6 0 D u p lic a te D A L S S G P 0 1 0 0 0 6 0 L a b M a trix S p ik e D AL SS G P 02 0 0000 D A L S S G P 0 2 0 0 0 0 0 D u p lic a te D A L S S G P 0 2 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 02 0 0005 D A L S S G P 0 2 0 0 0 0 5 D u p lic a te D A L S S G P 0 2 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 02 0 0020 D A L S S G P 0 2 0 0 0 2 0 D u p lic a te D A L S S G P 0 2 0 0 0 2 0 L a b M a trix S p ik e DAL SS G P 02 DB 0020 D A L S S G P 0 2 D B 0 0 2 0 D u p lic a te D A L S S G P 0 2 D B 0 0 2 0 L a b M a trix S p ik e D AL SS G P 02 0 0120 D A L S S G P 0 2 0 0 1 2 0 D u p lic a te D A L S S G P 0 2 0 0 1 2 0 L a b M a trix S p ik e D AL SS G P 03 0 0000 D A L S S G P 0 3 0 0 0 0 0 D u p lic a te D A L S S G P 0 3 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 03 0 0005 D A L S S G P 0 3 0 0 0 0 5 D u p lic a te D A L S S G P 0 3 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 03 0 0020 D A L S S G P 0 3 0 0 0 2 0 D u p lic a te D A L S S G P 0 3 0 0 0 2 0 L a b M a trix S p ik e DAL SS G P 03 DB 0020 D A L S S G P 0 3 D B 0 0 2 0 D u p lic a te D A L S S G P 0 3 D B 0 0 2 0 L a b M a trix S p ik e D AL SS G P 03 0 0050 D A L S S G P 0 3 0 0 0 5 0 D u p lic a te D A L S S G P 0 3 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 04 0 0000 D A L S S G P 0 4 0 0 0 0 0 D u p lic a te D A L S S G P 0 4 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 04 0 0005 D A L S S G P 0 4 0 0 0 0 5 D u p lic a te D A L S S G P 0 4 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 04 0 0020 D A L S S G P 0 4 0 0 0 2 0 D u p lic a te Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) 5.72 4.47 11.4 144% [d] N/A 10.0 N/A 0.64% 10.0 10.1 7.32 16.1 83.1% N/A 2.89 N/A 14% 3.11 3.33 7.42 9.66 88.2% N/A 0.179 N/A 4.7% 0.175 0.171 1.61 1.70 94.8% N/A BLQ N/A N/A BLQ BLQ 1.43 1.43 100% N/A N/A 0.12 10% 0.113 0.11 1.40 1.42 93.5% N/A BLQ N/A N/A BLQ BLQ 1.35 1.36 101% N/A 1.57 N/A 0.80% 1.58 1.58 2.29 3.72 93.9% N/A 40.9 N/A 4.2% 41.8 42.7 96.6 140 102% N/A 260 N/A 6.3% 252 244 433 746 114% N/A N/A 310 6.6% 321 331 349 768 128% N/A 427 N/A 4.6% 417 407 290 697 96.5% N/A N/A 80.9 3.0% 82.2 83.4 113 198 103% N/A 3.57 N/A 15% 3.32 3.06 7.61 10.8 98.5% N/A N/A 1.63 11% 1.55 1.46 9.59 11.6 105% N/A N/A 4.42 17% 4.83 5.25 3M Study GLP10-01-02 Interim Report 05 Page 39 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 D u p D A L S S G P 0 4 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 04 0 0050 D A L S S G P 0 4 0 0 0 5 0 D u p lic a te D A L S S G P 0 4 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 05 0 0000 D A L S S G P 0 5 0 0 0 0 0 D u p lic a te D A L S S G P 0 5 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 05 0 0005 D A L S S G P 0 5 0 0 0 0 5 D u p lic a te D A L S S G P 0 5 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 05 0 0020 D A L S S G P 0 5 0 0 0 2 0 D u p lic a te D A L S S G P 0 5 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 05 0 0055 D A L S S G P 0 5 0 0 0 5 5 D u p lic a te D A L S S G P 0 5 0 0 0 5 5 L a b M a trix S p ik e D AL SS G P 06 0 0000 D A L S S G P 0 6 0 0 0 0 0 D u p lic a te D A L S S G P 0 6 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 06 0 0005 D A L S S G P 0 6 0 0 0 0 5 D u p lic a te D A L S S G P 0 6 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 06 0 0020 D A L S S G P 0 6 0 0 0 2 0 D u p lic a te D A L S S G P 0 6 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 06 0 0110 D A L S S G P 0 6 0 0 1 1 0 D u p lic a te D A L S S G P 0 6 0 0 1 1 0 L a b M a trix S p ik e D AL SS G P 07 0 0000 D A L S S G P 0 7 0 0 0 0 0 D u p lic a te D A L S S G P 0 7 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 07 0 0005 D A L S S G P 0 7 0 0 0 0 5 D u p lic a te D A L S S G P 0 7 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 07 0 0020 D A L S S G P 0 7 0 0 0 2 0 D u p lic a te D A L S S G P 0 7 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 07 0 0130 D A L S S G P 0 7 0 0 1 3 0 D u p lic a te D A L S S G P 0 7 0 0 1 3 0 L a b M a trix S p ik e D AL SS G P 08 0 0000 D A L S S G P 0 8 0 0 0 0 0 D u p lic a te D A L S S G P 0 8 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 08 0 0005 D A L S S G P 0 8 0 0 0 0 5 D u p lic a te Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) 7.86 N/A 72.9 N/A 10.7 N/A 95.7 N/A 6.22 N/A 104 N/A 7.10 N/A 8.15 N/A 9.12 N/A 8.87 N/A 60.9 N/A 68.7 N/A 90.3 N/A 201 N/A NR N/A 13.1 12.5 13.2 82.4 9.2 8.4 17.8 12.7 12.7 114 7.75 8.15 12.0 49.7 47.5 156 4.24 3.94 10.9 2.84 2.73 10.6 1.63 1.28 10.23 1.83 1.90 10.12 17.0 18.4 78.0 36.3 33.1 97.0 25.7 25.0 118 154 139 290 NR NR NR 11.1 11.5 105% 5.7% 95.5% 8.7% 84.0% 0.68% 106% 5.0% 65.4% [d] 4.4% 103% 7.2% 95.5% 4.1% 96.0% 24% 96.1% 3.9% 93.1% 7.9% 99.1% 9.4% 90.6% 2.8% 102% 10% [c] 71.4% [c] NR NR 3.0% N/A 12.8 N/A 8.82 N/A 12.7 N/A 7.95 [d] N/A 48.6 N/A 4.09 N/A 2.79 N/A 1.46 N/A 1.86 N/A 17.7 34.7 N/A 25.3 N/A 146 [c] N/A NR N/A 11.3 3M Study GLP10-01-02 Interim Report 05 Page 40 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 L M S D A L S S G P 0 8 0 0 0 0 5 L a b M a trix S p ik e DAL SS G P 08 DB 0005 D A L S S G P 0 8 D B 0 0 0 5 D u p lic a te D A L S S G P 0 8 D B 0 0 0 5 L a b M a trix S p ik e D AL SS G P 08 0 0020 D A L S S G P 0 8 0 0 0 2 0 D u p lic a te D A L S S G P 0 8 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 08 0 0050 D A L S S G P 0 8 0 0 0 5 0 D u p lic a te D A L S S G P 0 8 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 09 0 0000 D A L S S G P 0 9 0 0 0 0 0 D u p lic a te D A L S S G P 0 9 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 09 0 0005 D A L S S G P 0 9 0 0 0 0 5 D u p lic a te D A L S S G P 0 9 0 0 0 0 5 L a b M a trix S p ik e DAL SS G P 09 DB 0005 D A L S S G P 0 9 D B 0 0 0 5 D u p lic a te D A L S S G P 0 9 D B 0 0 0 5 L a b M a trix S p ik e D AL SS G P 09 0 0020 D A L S S G P 0 9 0 0 0 2 0 D u p lic a te D A L S S G P 0 9 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 09 0 0050 D A L S S G P 0 9 0 0 0 5 0 D u p lic a te D A L S S G P 0 9 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 10 0 0000 D A L S S G P 1 0 0 0 0 0 0 D u p lic a te D A L S S G P 1 0 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 10 0 0005 D A L S S G P 1 0 0 0 0 0 5 D u p lic a te D A L S S G P 1 0 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 10 0 0020 D A L S S G P 1 0 0 0 0 2 0 D u p lic a te D A L S S G P 1 0 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 10 0 0060 D A L S S G P 1 0 0 0 0 6 0 D u p lic a te D A L S S G P 1 0 0 0 0 6 0 L a b M a trix S p ik e D A L SS G P 11 0 0000 D A L S S G P 1 1 0 0 0 0 0 D u p lic a te D A L S S G P 1 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS G P 11 0 0005 D A L S S G P 1 1 0 0 0 0 5 D u p lic a te D A L S S G P 1 1 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 11 0 0020 D A L S S G P 1 1 0 0 0 2 0 D u p lic a te D A L S S G P 1 1 0 0 0 2 0 L a b M a trix S p ik e Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) 44.7 N/A 47.3 N/A 557 N/A 53.0 N/A 434 N/A 93.6 N/A 244 N/A 10.8 N/A 10.3 N/A 479 N/A 565 N/A 451 N/A 222 N/A 39.4 N/A 50.4 N/A 40.0 56.1 13.2 14.2 61.1 7.75 6.89 528 10.8 10.6 66.6 247 240 638 38.6 47.7 131 77.5 51.8 318 4.79 5.68 16.8 6.68 5.84 16.2 163 119 661 239 219 836 158 167 590 130 121 378 23.8 18.0 56.3 44.8 45.1 105.0 27.7 33.7 71.1 100% 7.2% 100% 12% 93.6% 2.4% 105% 2.9% 90.9% 21% 94.1% 40% [c] 104% [c] 17% 107% 13% 96.4% 31% 109% 9.0% 108% 5.8% 94.8% 6.9% 114% 28% 89.9% 0.60% 119% 20% 101% N/A 13.7 N/A 7.32 N/A 10.7 N/A 244 N/A 43.1 N/A 64.6 [c] N/A 5.23 N/A 6.26 N/A 141 N/A 229 N/A 162 N/A 126 N/A 20.9 N/A 45.0 N/A 30.7 N/A 3M Study GLP10-01-02 Interim Report 05 Page 41 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 15. In d iv id u a l P F H S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFHS Concentration (ng/g; dry wt.) G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 D u p D A L SS G P 11 0 0065 D A L S S G P 1 1 0 0 0 6 5 D u p lic a te 31.4 N/A 11% 33.2 35.0 G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 L M S D A L S S G P 1 1 0 0 0 6 5 L a b M a trix S p ik e 53.3 89.5 106% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 D u p D A L SS G P 11 D B 0065 D A L S S G P 1 1 D B 0 0 6 5 D u p lic a te N/A 52.3 57.7 10% 55.0 G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 L M S D A L S S G P 1 1 D B 0 0 6 5 L a b M a trix S p ik e 58.8 117 106% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 D u p D AL SS G P 12 0 0000 D A L S S G P 1 2 0 0 0 0 0 D u p lic a te 4.06 N/A 30% 4.77 5.47 G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 L M S D A L S S G P 1 2 0 0 0 0 0 L a b M a trix S p ik e 9.72 15.8 113% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 D u p D AL SS G P 12 0 0005 D A L S S G P 1 2 0 0 0 0 5 D u p lic a te N/A 2.56 14% 2.75 2.94 G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 L M S D A L S S G P 1 2 0 0 0 0 5 L a b M a trix S p ik e 9.46 11.6 94.0% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 D u p D AL SS G P 12 0 0020 D A L S S G P 1 2 0 0 0 2 0 D u p lic a te 6.93 N/A 3.4% 6.81 6.69 G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 L M S D A L S S G P 1 2 0 0 0 2 0 L a b M a trix S p ik e 10.0 15.3 84.8% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 D u p D AL SS G P 12 0 0170 D A L S S G P 1 2 0 0 1 7 0 D u p lic a te 10.0 N/A 4.9% 9.74 9.51 G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 L M S D A L S S G P 1 2 0 0 1 7 0 L a b M a trix S p ik e 11.9 22.9 111% N/A [a] LMSs fortified with PFHS (linear isomer). [b] RPD was greater than 50%. [c] The value reported was determined from a re-assay. [d] LMS recovery was outside of method criteria of 100 + 30%, but within reporting criteria of 100 + 60%. n R; not reported because a reliable value could not be attained based on QC results. N/A; not applicable Note: LMS recoveries and analyte concentration results are reported at 3 significant figures, RPDs are reported at 2 significant figures, but more precise values were used for data calculations______________________________________________________________________________ 3M Study GLP10-01-02 Interim Report 05 Page 42 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 0 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 D u p D A L S D T R IP 1 0 1 0 0 6 2 4 D A L S D T R IP 1 0 1 0 0 6 2 4 D u p lic a te D A L S D T R IP 1 0 1 0 0 6 2 4 L a b M a trix S p ik e D AL SD SD 01 0 0000 D A L S D S D 0 1 0 0 0 0 0 D u p lic a te D A L S D S D 0 1 0 0 0 0 0 L a b M a trix S p ik e D AL SD SD 01 0 0005 D A L S D S D 0 1 0 0 0 0 5 D u p lic a te D A L S D S D 0 1 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 02 0 0000 D A L S D S D 0 2 0 0 0 0 0 D u p lic a te D A L S D S D 0 2 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 02 0 0005 D A L S D S D 0 2 0 0 0 0 5 D u p lic a te D A L S D S D 0 2 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 03 0 0000 D A L S D S D 0 3 0 0 0 0 0 D u p lic a te D A L S D S D 0 3 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 03 0 0005 D A L S D S D 0 3 0 0 0 0 5 D u p lic a te D A L S D S D 0 3 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 04 0 0000 D A L S D S D 0 4 0 0 0 0 0 D u p lic a te D A L S D S D 0 4 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 04 0 0005 D A L S D S D 0 4 0 0 0 0 5 D u p lic a te D A L S D S D 0 4 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 05 0 0000 D A L S D S D 0 5 0 0 0 0 0 D u p lic a te D A L S D S D 0 5 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 05 0 0005 D A L S D S D 0 5 0 0 0 0 5 D u p lic a te D A L S D S D 0 5 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 06 0 0000 D A L S D S D 0 6 0 0 0 0 0 D u p lic a te D A L S D S D 0 6 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 06 0 0005 D A L S D S D 0 6 0 0 0 0 5 D u p lic a te D A L S D S D 0 6 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 07 0 0000 D A L S D S D 0 7 0 0 0 0 0 D u p lic a te D A L S D S D 0 7 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 07 0 0005 D A L S D S D 0 7 0 0 0 0 5 D u p lic a te N/A 1.84 N/A 2.05 N/A 1.83 N/A 14.0 N/A 1.52 N/A 12.2 N/A 7.37 N/A 56.4 N/A 35.0 N/A 37.7 N/A 38.6 N/A 7.20 N/A 4.54 N/A 11.7 N/A BLQ BLQ 1.98 0.664 0.559 2.83 0.732 0.477 2.87 6.68 5.38 16.7 1.20 1.22 2.55 7.03 7.58 20.1 2.87 3.94 13.0 19.0 30.9 88.7 8.94 8.92 50.7 4.50 4.94 46.5 4.44 4.25 46.4 6.55 5.93 14.8 3.26 3.48 8.53 9.7 7.83 24.2 8.09 10.9 N/A 108% 17% 109% 42% 123% 21% 76.0% 1.1% 87.9% 7.4% 105% 31% 130% 48% 113% 0.22% 119% 9.2% 111% 4.5% 109% 10% 118% 6.7% 114% 21% 131% [c] 29% BLQ N/A 0.611 N/A 0.605 N/A 6.03 N/A 1.21 N/A 7.31 N/A 3.41 N/A 24.9 N/A 8.93 N/A 4.72 N/A 4.35 N/A 6.24 N/A 3.37 N/A 8.75 [c] N/A 9.48 [c] 3M Study GLP10-01-02 Interim Report 05 Page 43 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 1 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 1 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 2 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 2 L M S D A L S D S D 0 7 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 08 0 0000 D A L S D S D 0 8 0 0 0 0 0 D u p lic a te D A L S D S D 0 8 0 0 0 0 0 L a b M a trix S p ik e DAL SD S D 08 DB 0000 D A L S D S D 0 8 D B 0 0 0 0 D u p lic a te D A L S D S D 0 8 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 08 0 0005 D A L S D S D 0 8 0 0 0 0 5 D u p lic a te D A L S D S D 0 8 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 09 0 0000 D A L S D S D 0 9 0 0 0 0 0 D u p lic a te D A L S D S D 0 9 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 09 0 0005 D A L S D S D 0 9 0 0 0 0 5 D u p lic a te D A L S D S D 0 9 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 10 0 0000 D A L S D S D 1 0 0 0 0 0 0 D u p lic a te D A L S D S D 1 0 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 10 0 0005 D A L S D S D 1 0 0 0 0 0 5 D u p lic a te D A L S D S D 1 0 0 0 0 0 5 L a b M a trix S p ik e D AL SD SD 11 0 0000 D A L S D S D 1 1 0 0 0 0 0 D u p lic a te D A L S D S D 1 1 0 0 0 0 0 L a b M a trix S p ik e D AL SD SD 11 0 0005 D A L S D S D 1 1 0 0 0 0 5 D u p lic a te D A L S D S D 1 1 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 12 0 0000 D A L S D S D 1 2 0 0 0 0 0 D u p lic a te D A L S D S D 1 2 0 0 0 0 0 L a b M a trix S p ik e DAL SD SD 12 DB 0000 D A L S D S D 1 2 D B 0 0 0 0 D u p lic a te D A L S D S D 1 2 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 12 0 0005 D A L S D S D 1 2 0 0 0 0 5 D u p lic a te D A L S D S D 1 2 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 13 0 0000 D A L S D S D 1 3 0 0 0 0 0 D u p lic a te D A L S D S D 1 3 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 13 0 0005 D A L S D S D 1 3 0 0 0 0 5 D u p lic a te D A L S D S D 1 3 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 14 0 0000 D A L S D S D 1 4 0 0 0 0 0 D u p lic a te D A L S D S D 1 4 0 0 0 0 0 L a b M a trix S p ik e Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) RPD/ LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) 13.2 26.9 131% [c] N/A N/A 5.44 5.11 6.2% 5.28 10.3 16.1 105% N/A N/A 4.74 4.85 2.4% 4.80 9.57 15.0 107% N/A N/A 1.49 1.76 17% 1.62 1.48 3.23 109% N/A N/A 27.0 28.1 4.1% 27.5 53.0 83.8 106% N/A N/A 14.2 13.8 3.3% 14.0 45.8 64.5 110% N/A N/A 153 [b] 190 [b] 22% [b] 171 [b] 245 383 [b] 86.6% [b] N/A N/A 56.1 [b] 77.0 [b] 31% [b] 66.5 [b] 154 193 [b] 82.4% [b] N/A N/A 8.90 7.95 11% 8.42 42.3 56.7 114% N/A N/A 4.41 3.79 15% 4.10 7.6 12.2 106% N/A N/A 15.5 18.2 16% 16.9 60.4 80.2 105% N/A N/A 16.6 18.1 9.1% 17.3 71.4 98.9 114% N/A N/A 5.74 4.87 16% 5.31 36.7 45.5 109% N/A N/A 10.9 9.90 9.4% 10.4 42.0 55.7 108% N/A N/A 11.7 13.4 14% 12.6 [c] 30.8 49.0 159% [c] N/A N/A 144 [b] 113 [b] 24% [b] 129 [b] 321 444 [b] 97.9% [b] N/A 3M Study GLP10-01-02 Interim Report 05 Page 44 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 3 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 D AL SD S D 14 0 0005 D A L S D S D 1 4 0 0 0 0 5 D u p lic a te D A L S D S D 1 4 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 15 0 0000 D A L S D S D 1 5 0 0 0 0 0 D u p lic a te D A L S D S D 1 5 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 15 0 0005 D A L S D S D 1 5 0 0 0 0 5 D u p lic a te D A L S D S D 1 5 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 16 0 0000 D A L S D S D 1 6 0 0 0 0 0 D u p lic a te D A L S D S D 1 6 0 0 0 0 0 L a b M a trix S p ik e DAL SD S D 16 DB 0000 D A L S D S D 1 6 D B 0 0 0 0 D u p lic a te D A L S D S D 1 6 D B 0 0 0 0 L a b M a trix S p ik e D AL SD S D 16 0 0005 D A L S D S D 1 6 0 0 0 0 5 D u p lic a te D A L S D S D 1 6 0 0 0 0 5 L a b M a trix S p ik e D AL SD S D 17 0 0000 D A L S D S D 1 7 0 0 0 0 0 D u p lic a te D A L S D S D 1 7 0 0 0 0 0 L a b M a trix S p ik e D AL SD S D 17 0 0005 D A L S D S D 1 7 0 0 0 0 5 D u p lic a te D A L S D S D 1 7 0 0 0 0 5 L a b M a trix S p ik e D A L SS SS01 0 0000 D A L S S S S 0 1 0 0 0 0 0 D u p lic a te D A L S S S S 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS SS01 0 0005 D A L S S S S 0 1 0 0 0 0 5 D u p lic a te D A L S S S S 0 1 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 02 0 0000 D A L S S S S 0 2 0 0 0 0 0 D u p lic a te D A L S S S S 0 2 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 02 0 0005 D A L S S S S 0 2 0 0 0 0 5 D u p lic a te D A L S S S S 0 2 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 03 0 0000 D A L S S S S 0 3 0 0 0 0 0 D u p lic a te D A L S S S S 0 3 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 03 0 0005 D A L S S S S 0 3 0 0 0 0 5 D u p lic a te D A L S S S S 0 3 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 03 DB 0005 D A L S S S S 0 3 D B 0 0 0 5 D u p lic a te D A L S S S S 0 3 D B 0 0 0 5 L a b M a trix S p ik e DAL SS SS 04 0 0000 Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) N/A 203 N/A 275 N/A 51.7 N/A 50.6 N/A 57.0 N/A 50.2 N/A 52.0 N/A 49.5 N/A 1.64 N/A 1.53 N/A 8.88 N/A 8.30 N/A 7.42 N/A 5.57 N/A 6.78 N/A 77.6 [b] 123 [b] 292 [b] 57.4 47.3 333 17.7 17.0 77.1 29.7 24.7 101 33.4 33.9 96.8 21.6 23.6 76.6 28.3 28.0 82.3 25.9 23.6 79.7 0.886 0.932 2.56 0.456 0.448 2.14 0.777 0.795 9.77 4.36 3.86 13.4 4.46 3.73 11.9 4.39 6.15 9.69 4.73 3.11 10.9 3.08 45% [b] 94.6% [b] 19% 102% 4.2% 116% 18% 146% [c] 1.6% 111% 8.6% 107% 0.85% 104% 9.3% 111% 5.1% 101% 1.9% 110% 2.2% 101% 12% 111% 18% 105% 33% 79.4% 42% 103% 36% 100 [b] N/A 52.3 N/A 17.3 N/A 27.2 [c] N/A 33.6 N/A 22.6 N/A 28.2 N/A 24.8 N/A 0.909 N/A 0.452 N/A 0.786 N/A 4.11 N/A 4.09 N/A 5.27 N/A 3.92 N/A 2.61 3M Study GLP10-01-02 Interim Report 05 Page 45 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 4 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 D u p D A L S S S S 0 4 0 0 0 0 0 D u p lic a te D A L S S S S 0 4 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 04 0 0005 D A L S S S S 0 4 0 0 0 0 5 D u p lic a te D A L S S S S 0 4 0 0 0 0 5 L a b M a trix S p ik e D A L S S T R IP 1 0 0 0 0 0 D A L S S T R IP 1 0 0 0 0 0 D u p lic a te D A L S S T R IP 1 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 05 0 0000 D A L S S S S 0 5 0 0 0 0 0 D u p lic a te D A L S S S S 0 5 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 05 0 0005 D A L S S S S 0 5 0 0 0 0 5 D u p lic a te D A L S S S S 0 5 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 06 0 0000 D A L S S S S 0 6 0 0 0 0 0 D u p lic a te D A L S S S S 0 6 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 06 0 0005 D A L S S S S 0 6 0 0 0 0 5 D u p lic a te D A L S S S S 0 6 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 06 DB 0005 D A L S S S S 0 6 D B 0 0 0 5 D u p lic a te D A L S S S S 0 6 D B 0 0 0 5 L a b M a trix S p ik e DAL SS SS 07 0 0000 D A L S S S S 0 7 0 0 0 0 0 D u p lic a te D A L S S S S 0 7 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 07 0 0005 D A L S S S S 0 7 0 0 0 0 5 D u p lic a te D A L S S S S 0 7 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 08 0 0000 D A L S S S S 0 8 0 0 0 0 0 D u p lic a te D A L S S S S 0 8 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 08 DB 0000 D A L S S S S 0 8 D B 0 0 0 0 D u p lic a te D A L S S S S 0 8 D B 0 0 0 0 L a b M a trix S p ik e DAL SS SS 08 0 0005 D A L S S S S 0 8 0 0 0 0 5 D u p lic a te D A L S S S S 0 8 0 0 0 0 5 L a b M a trix S p ik e DAL SS SS 09 0 0000 D A L S S S S 0 9 0 0 0 0 0 D u p lic a te D A L S S S S 0 9 0 0 0 0 0 L a b M a trix S p ik e DAL SS SS 09 0 0005 D A L S S S S 0 9 0 0 0 0 5 D u p lic a te D A L S S S S 0 9 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 01 0 0000 D A L S S G P 0 1 0 0 0 0 0 D u p lic a te Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) 8.59 N/A 1.90 N/A 1.85 N/A 51 N/A 9.30 N/A 1.98 N/A 1.94 N/A 1.90 N/A 12 N/A 10 N/A 7.32 N/A 7.79 N/A 8.24 N/A 9.79 N/A 4.61 N/A 2.13 11.1 1.09 0.839 3.07 BLQ BLQ 1.93 23.3 21.7 70.3 6.53 6.89 17.0 1.24 1.31 3.40 0.440 0.426 2.70 0.549 0.518 2.59 10.8 12.3 23.6 8.25 10.1 18.7 1.72 1.62 7.76 1.36 1.48 9.58 1.67 1.55 10.0 1.48 1.58 11.6 1.41 [bl 1.48 [bl 6.33 [bl 4.62 6.85 98.7% 26% 110% N/A 105% 7.4% 94.0% 5.3% 111% 5.4% 108% 3.4% 117% 5.7% 108% 13% 97.0% 21% 99.8% 6.0% 83.2% 8.8% 105% 7.7% 102% 6.6% 103% 5.2% [b] 106% [b] 39% N/A 0.966 N/A BLQ N/A 22.5 N/A 6.71 N/A 1.27 N/A 0.433 N/A 0.533 N/A 11.6 N/A 9.20 N/A 1.67 N/A 1.42 N/A 1.61 N/A 1.53 N/A 1.44 [b] N/A 5.73 3M Study GLP10-01-02 Interim Report 05 Page 46 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 6 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 6 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 7 9 L M S D A L S S G P 0 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS G P 01 0 0005 D A L S S G P 0 1 0 0 0 0 5 D u p lic a te D A L S S G P 0 1 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 01 0 0020 D A L S S G P 0 1 0 0 0 2 0 D u p lic a te D A L S S G P 0 1 0 0 0 2 0 L a b M a trix S p ik e D A L SS G P 01 0 0060 D A L S S G P 0 1 0 0 0 6 0 D u p lic a te D A L S S G P 0 1 0 0 0 6 0 L a b M a trix S p ik e D AL SS G P 02 0 0000 D A L S S G P 0 2 0 0 0 0 0 D u p lic a te D A L S S G P 0 2 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 02 0 0005 D A L S S G P 0 2 0 0 0 0 5 D u p lic a te D A L S S G P 0 2 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 02 0 0020 D A L S S G P 0 2 0 0 0 2 0 D u p lic a te D A L S S G P 0 2 0 0 0 2 0 L a b M a trix S p ik e DAL SS G P 02 DB 0020 D A L S S G P 0 2 D B 0 0 2 0 D u p lic a te D A L S S G P 0 2 D B 0 0 2 0 L a b M a trix S p ik e D AL SS G P 02 0 0120 D A L S S G P 0 2 0 0 1 2 0 D u p lic a te D A L S S G P 0 2 0 0 1 2 0 L a b M a trix S p ik e D AL SS G P 03 0 0000 D A L S S G P 0 3 0 0 0 0 0 D u p lic a te D A L S S G P 0 3 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 03 0 0005 D A L S S G P 0 3 0 0 0 0 5 D u p lic a te D A L S S G P 0 3 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 03 0 0020 D A L S S G P 0 3 0 0 0 2 0 D u p lic a te D A L S S G P 0 3 0 0 0 2 0 L a b M a trix S p ik e DAL SS G P 03 DB 0020 D A L S S G P 0 3 D B 0 0 2 0 D u p lic a te D A L S S G P 0 3 D B 0 0 2 0 L a b M a trix S p ik e D AL SS G P 03 0 0050 D A L S S G P 0 3 0 0 0 5 0 D u p lic a te D A L S S G P 0 3 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 04 0 0000 D A L S S G P 0 4 0 0 0 0 0 D u p lic a te D A L S S G P 0 4 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 04 0 0005 D A L S S G P 0 4 0 0 0 0 5 D u p lic a te D A L S S G P 0 4 0 0 0 0 5 L a b M a trix S p ik e Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) 8.40 N/A 4.47 N/A 7.33 N/A 7.43 N/A 8.07 N/A 1.43 N/A 1.40 N/A 1.35 N/A 2.29 N/A 9.67 N/A 43.3 N/A 34.9 N/A 29.0 N/A 56.4 N/A 7.62 N/A 9.60 14.0 3.99 3.73 8.81 3.73 3.36 11.3 1.92 2.30 8.92 1.40 1.34 9.77 0.705 0.697 2.09 0.326 0.365 1.79 0.417 0.367 1.89 2.48 2.69 5.19 5.65 5.77 15.9 33.1 32.1 76.3 38.5 41.6 72.6 52.2 45.8 80.8 12.7 12.9 71.9 4.62 4.40 13.0 2.18 2.13 12.8 98.7% 6.8% 111% 10% 106% 18% 91.6% 4.3% 104% 1.2% 97.0% 11% 104% 13% 110% 7.9% 114% 2.0% 105% 3.1% 101% 7.6% 93.2% 13% 109% 1.3% 105% 4.8% 111% 2.3% 111% N/A 3.86 N/A 3.55 N/A 2.11 N/A 1.37 N/A 0.701 N/A 0.345 N/A 0.392 N/A 2.59 N/A 5.71 N/A 32.6 N/A 40.1 N/A 49.0 N/A 12.8 N/A 4.51 N/A 2.16 N/A 3M Study GLP10-01-02 Interim Report 05 Page 47 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 8 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 0 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 D AL SS G P 04 0 0020 D A L S S G P 0 4 0 0 0 2 0 D u p lic a te D A L S S G P 0 4 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 04 0 0050 D A L S S G P 0 4 0 0 0 5 0 D u p lic a te D A L S S G P 0 4 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 05 0 0000 D A L S S G P 0 5 0 0 0 0 0 D u p lic a te D A L S S G P 0 5 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 05 0 0005 D A L S S G P 0 5 0 0 0 0 5 D u p lic a te D A L S S G P 0 5 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 05 0 0020 D A L S S G P 0 5 0 0 0 2 0 D u p lic a te D A L S S G P 0 5 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 05 0 0055 D A L S S G P 0 5 0 0 0 5 5 D u p lic a te D A L S S G P 0 5 0 0 0 5 5 L a b M a trix S p ik e D AL SS G P 06 0 0000 D A L S S G P 0 6 0 0 0 0 0 D u p lic a te D A L S S G P 0 6 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 06 0 0005 D A L S S G P 0 6 0 0 0 0 5 D u p lic a te D A L S S G P 0 6 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 06 0 0020 D A L S S G P 0 6 0 0 0 2 0 D u p lic a te D A L S S G P 0 6 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 06 0 0110 D A L S S G P 0 6 0 0 1 1 0 D u p lic a te D A L S S G P 0 6 0 0 1 1 0 L a b M a trix S p ik e D AL SS G P 07 0 0000 D A L S S G P 0 7 0 0 0 0 0 D u p lic a te D A L S S G P 0 7 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 07 0 0005 D A L S S G P 0 7 0 0 0 0 5 D u p lic a te D A L S S G P 0 7 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 07 0 0020 D A L S S G P 0 7 0 0 0 2 0 D u p lic a te D A L S S G P 0 7 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 07 0 0130 D A L S S G P 0 7 0 0 1 3 0 D u p lic a te D A L S S G P 0 7 0 0 1 3 0 L a b M a trix S p ik e D AL SS G P 08 0 0000 D A L S S G P 0 8 0 0 0 0 0 D u p lic a te D A L S S G P 0 8 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 08 0 0005 Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) N/A 7.87 N/A 7.30 N/A 10.7 N/A 9.58 N/A 6.23 N/A 10.4 N/A 7.10 N/A 1.63 N/A 1.83 N/A 1.77 N/A 6.09 N/A 6.88 N/A 1.81 N/A 20.1 N/A NR N/A 1.68 1.75 10.5 2.81 2.75 10.1 11.4 13.2 21.7 5.23 5.35 16.4 1.83 1.66 7.23 5.16 5.05 15.6 1.95 1.76 9.73 0.865 0.737 2.6 0.216 0.144 2.03 0.809 0.907 2.55 1.68 1.70 8.53 1.00 0.985 8.32 1.24 1.20 3.53 13.1 [b] 12.3 [b] 29.5 [b] NR NR NR 0.320 4.1% 111% 2.0% 99.9% 15% 87.7% 2.3% 116% 10% 88.0% 2.2% 101% 10% 111% 16% 109% 40% 101% 11% 95.2% 1.2% 112% 1.3% 107% 3.7% 128% 6.6% [b] 83.3% [b] NR NR 0.00099% 1.72 N/A 2.78 N/A 12.3 N/A 5.29 N/A 1.75 N/A 5.11 N/A 1.86 N/A 0.801 N/A 0.180 N/A 0.858 N/A 1.69 N/A 0.991 N/A 1.22 N/A 12.7 [b] N/A NR N/A 0.320 3M Study GLP10-01-02 Interim Report 05 Page 48 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -0 9 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 3 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 4 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 5 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 6 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 7 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 8 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 0 9 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 1 1 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 D u p G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 L M S G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 D u p D A L S S G P 0 8 0 0 0 0 5 D u p lic a te D A L S S G P 0 8 0 0 0 0 5 L a b M a trix S p ik e DAL SS G P 08 DB 0005 D A L S S G P 0 8 D B 0 0 0 5 D u p lic a te D A L S S G P 0 8 D B 0 0 0 5 L a b M a trix S p ik e D AL SS G P 08 0 0020 D A L S S G P 0 8 0 0 0 2 0 D u p lic a te D A L S S G P 0 8 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 08 0 0050 D A L S S G P 0 8 0 0 0 5 0 D u p lic a te D A L S S G P 0 8 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 09 0 0000 D A L S S G P 0 9 0 0 0 0 0 D u p lic a te D A L S S G P 0 9 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 09 0 0005 D A L S S G P 0 9 0 0 0 0 5 D u p lic a te D A L S S G P 0 9 0 0 0 0 5 L a b M a trix S p ik e DAL SS G P 09 DB 0005 D A L S S G P 0 9 D B 0 0 0 5 D u p lic a te D A L S S G P 0 9 D B 0 0 0 5 L a b M a trix S p ik e D AL SS G P 09 0 0020 D A L S S G P 0 9 0 0 0 2 0 D u p lic a te D A L S S G P 0 9 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 09 0 0050 D A L S S G P 0 9 0 0 0 5 0 D u p lic a te D A L S S G P 0 9 0 0 0 5 0 L a b M a trix S p ik e D AL SS G P 10 0 0000 D A L S S G P 1 0 0 0 0 0 0 D u p lic a te D A L S S G P 1 0 0 0 0 0 0 L a b M a trix S p ik e D AL SS G P 10 0 0005 D A L S S G P 1 0 0 0 0 0 5 D u p lic a te D A L S S G P 1 0 0 0 0 0 5 L a b M a trix S p ik e D AL SS G P 10 0 0020 D A L S S G P 1 0 0 0 0 2 0 D u p lic a te D A L S S G P 1 0 0 0 0 2 0 L a b M a trix S p ik e D AL SS G P 10 0 0060 D A L S S G P 1 0 0 0 0 6 0 D u p lic a te D A L S S G P 1 0 0 0 0 6 0 L a b M a trix S p ik e D A L SS G P 11 0 0000 D A L S S G P 1 1 0 0 0 0 0 D u p lic a te D A L S S G P 1 1 0 0 0 0 0 L a b M a trix S p ik e D A L SS G P 11 0 0005 D A L S S G P 1 1 0 0 0 0 5 D u p lic a te D A L S S G P 1 1 0 0 0 0 5 L a b M a trix S p ik e D A L SS G P 11 0 0020 D A L S S G P 1 1 0 0 0 2 0 D u p lic a te Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) 1.79 N/A 1.89 N/A 2.23 N/A 2.12 N/A 43.4 N/A 9.37 N/A 9.77 N/A 10.8 N/A 10.3 N/A 48.0 N/A 113 N/A 90.4 N/A 88.8 N/A 7.89 N/A 10.1 N/A 0.320 2.38 0.362 0.433 2.55 0.270 0.193 2.76 0.666 0.720 2.96 17.8 17.7 56.9 4.31 5.11 15.2 5.78 5.69 15.1 1.31 1.44 13.2 4.11 3.54 13.4 30.0 26.7 76.5 50.1 [b] 43.0 [b] 162 [b] 101[b] 98.8 [b] 156 [b] 77.9 [b] 75.4 [b] 186 [b] 3.76 3.38 12.1 5.99 6.60 18.2 22.4 25.2 115% 18% 114% 34% 114% 7.8% 107% 0.5% 90.1% 17% 112% 1.6% 96.3% 9.0% 109% 15% 92.9% 12% 100% 15% [b] 102% [b] 2.0% [b] 62.6% [b, c] 3.3% [b] 123% [b] 10% 109% 9.7% 118% 12% N/A 0.397 N/A 0.231 N/A 0.693 N/A 17.8 N/A 4.71 N/A 5.73 N/A 1.37 N/A 3.83 N/A 28.4 N/A 46.5 [b] N/A 99.8 [b, c] N/A 76.6 [b] N/A 3.57 N/A 6.29 N/A 23.8 3M Study GLP10-01-02 Interim Report 05 Page 49 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 T a b le 16. In d iv id u a l P F B S R e s u lts fo r D e c a tu r A v e n u e A S o ils (J u n e /J u ly 2 0 1 0 ) LIMS Sample ID Sample Description Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) R P D / LMS Recovery [a] Average PFBS Concentration (ng/g; dry wt.) G L P 1 0 -0 1 -0 2 -0 5 -1 1 3 L M S D A L S S G P 1 1 0 0 0 2 0 L a b M a trix S p ik e 40.0 64.7 102% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 D u p D A L SS G P 11 0 0065 D A L S S G P 1 1 0 0 0 6 5 D u p lic a te 5.17 N/A 18% 5.68 6.19 G L P 1 0 -0 1 -0 2 -0 5 -1 1 4 L M S D A L S S G P 1 1 0 0 0 6 5 L a b M a trix S p ik e 10.7 17.7 113% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 D u p D A L SS G P 11 D B 0065 D A L S S G P 1 1 D B 0 0 6 5 D u p lic a te 6.97 N/A 8.38 18% 7.68 G L P 1 0 -0 1 -0 2 -0 5 -1 1 5 L M S D A L S S G P 1 1 D B 0 0 6 5 L a b M a trix S p ik e 11.8 20.5 109% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 D u p D AL SS G P 12 0 0000 D A L S S G P 1 2 0 0 0 0 0 D u p lic a te 0.517 N/A 30% 0.607 0.698 G L P 1 0 -0 1 -0 2 -0 5 -1 1 6 L M S D A L S S G P 1 2 0 0 0 0 0 L a b M a trix S p ik e 1.95 2.86 116% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 D u p D AL SS G P 12 0 0005 D A L S S G P 1 2 0 0 0 0 5 D u p lic a te 0.486 N/A 0.555 13% 0.521 G L P 1 0 -0 1 -0 2 -0 5 -1 1 7 L M S D A L S S G P 1 2 0 0 0 0 5 L a b M a trix S p ik e 1.89 2.60 110% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 D u p D AL SS G P 12 0 0020 D A L S S G P 1 2 0 0 0 2 0 D u p lic a te 1.91 N/A 3.1% 1.88 1.85 G L P 1 0 -0 1 -0 2 -0 5 -1 1 8 L M S D A L S S G P 1 2 0 0 0 2 0 L a b M a trix S p ik e 10.0 12.0 101% N/A G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 D u p D AL SS G P 12 0 0170 D A L S S G P 1 2 0 0 1 7 0 D u p lic a te 2.01 N/A 0.75% 2.01 2.02 G L P 1 0 -0 1 -0 2 -0 5 -1 1 9 L M S D A L S S G P 1 2 0 0 1 7 0 L a b M a trix S p ik e [a] RPD was greater than 50%. 11.9 15.4 113% N/A [b] The value reported was determined from a re-assay. [c] LMS recovery was outside of method criteria of 100 + 30%, but within reporting criteria of 100 + 60%. [d] ; Value was determined by external standard quant because LMS sample accidentally did not receive IS addition. n R; not reported because a reliable value could not be attained based on QC results. N/A; not applicable Note: LMS recoveries and analyte concentration results are reported at 3 significant figures, RPDs are reported at 2 significant figures, but more precise values were used for data calculations______________________________________________________________________________ 8 Conclusion Quantitative analysis for PFOS, PFHS and FPBS in the Avenue A soils collected in June/July of 2010 at the 3M Decatur, AL site was successfully completed following 3M Environmental Laboratory method ETS-8-053.0. The average PFOS, PFHS and PFBS concentration results are summarized in T a b le 1 and the LMS recoveries are summarized in T a b le 2 . The PFOS, PFHS and PFBS results for the individual sample replicates that were successfully extracted and analyzed with reportable results are shown in T a b le 1 4 , T a b le 1 5 and T a b le 1 6 , respectively. The overall results showed that PFOS was the dominant analyte in each of the samples and in several instances exceeded the ULOQ of nominal concentration 500 ng/g. Dilutions of those samples were required to accurately determine PFOS concentrations, and in some instances required up to 500-fold dilution. For some samples, PFHS also had to be diluted to attain a value within the calibration range. The PFOS concentrations ranged over approximately four orders of magnitude, from ~5.48 ng/g (dry weight) to 14,600 ng/g (dry weight). The PFHS and PFBS concentrations were always lower in concentration than the respective PFOS concentration in the same sample. 3M Study GLP10-01-02 Interim Report 05 Page 50 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 9 Data/Sample Retention All samples and associated project data (hardcopy and electronic) will be archived according to 3M Environmental Laboratory standard operating procedures. 10 List of Attachments Attachment A: Raw Data Chromatograms, Preparation Forms and Correspondence. 11 Signatures Report Approval: ___ Cleston C. Lange, Ph.D., Principal Analytical Investigator s / ip / z o ) ! Date Williiam K. Reagen, Ph.D., 3M Environmental Laboratory Management Date 3M Study GLP10-01-02 Interim Report 05 Page 51 of 962 Study: GLP10-01-02, Interim Report 05 Analysis for PFOS, PFHS and PFBS in Avenue A Soils & Sediments Collected June/July 2010 Attachment A Raw Data, LC/MS Chromatograms (Partial Set, Including Range Finding Data) and Preparation Forms 3M Study GLP10-01-02 Interim Report 05 Page 52 of 962 3M Confidential Record of Deviation/N onconformance I. Identification Study / Project No. GLP10-01- Date(s) of Occurrence: Feb 01, Document Number: 02-05 2011 Deviation type SOP (Check one) El Protocol Equipment Procedure Method GPO Other: II. Description (a tta ch e xtra p a g e s a s n ee de d) Method Requirements: L M S a c c e p ta n c e /re p o rtin g rang es: The protocol specifies that normal acceptance criteria for reporting results base don LMS recoveries are within 100 + 30%. Reportable results, with a footnote/flag are those with LMS results within 100 + 50%. S a m p le ID s: The IDs of the samples for study GLP10-01-02-05-xxx, where xxx is a sequential number from 001 and up, were logged into LIMS as GLP10-01-01-05-xxx, however, the same samples are analyzed for two studies with different analyte requirements (GLP10-01-02 and GLP10-01-01). Actual procedure/process: L M S -a c c e p ta n c e /re p o rtin g ra n g e s ex p a n d e d : -Ltb' ForIwe results reported in interim report 05 (Avenue A soils/sediments sulfonates June/July 2010), the f< 0 LMS recoveries were outside of 100 + 50%, but were reported with additional footnoting. Samples reported with this expanded reporting criteria included the following: PFHS result for GLP10-01-02-002, PFBS result for GLP10-01-02-05-031, PFHS result for GLP10-01-02-05-032, PFOS result for GLP10-0102-05-045 and PFOS result for GLP10-01-02-094. The associated LMS recoveries were 43.3% for GLP10-01-02-002 ( PFHS), 159% for GLP10-01-02-031 (PFBS), 151% for GLP10-01-02-032 (PFHS), ($> 4?8%-rur CLP10-01-02-045-fPFOS) and 43.9% for GLP10-01-02-094 (PFOS). S a m p le ID s: The analytical runs for study GLP10-01-02 called the samples GLP10-01-02-05-xxx, but those IDs do are not as listed in LIMS and are simply the same as the analogous GLP10-01-01-xxx samples. The interim report 05 describes the samples as GLP10-01-02-05-xxx, the same as the IDs used in analytical runs for that project, but correspond to the same GLP10-01-01-05-xxxx IDs that are logged into LIMS. III. Actions Taken (such as amendment issued, SOP revision, etc.) Corrective Action ( Yes No) Reference: Acceptability of the nonconforming work: Actions: Halting of Work Client Notification Work Recall Withholding of Report Other: _ __________________________________________ Project Lead/PAI Approval: Study Director (if GLP)l ZJ) Z#)/ Sponsor Approval (for GLP protocol deviations): //i Date: NCIH i Laboratory Department Manager Approval: Date: 2 d /- " S ' IV. Authorization to Resume Work _____Where halting o f work occurred, resum ption o f work m ust first be approved by Laboratory M anagem ent Laboratory Department Manager Approval: N/A Date: W y p h o te - AT l A 'S o fi* ? flfbt Deviation No. (assigned by Study Director o r Team Leader at the end o f study o r project) tfb r r ? T r - J 3M Study GLP10-01-02 ETS-4-008.7 ^ P a 9 e V a g e 53 of 9 6 g _ Documentation of Deviations and Control of Nonconforming Testing Project or Study D escrip tion : LIMS Number: Affected Data: Note To File Decatur Soil Sam pling G L P 10-01-01-05 None On 6/17/10 a bottle order for soil sampling was prepared as follows: Six soil trip blanks in 250 mL Nalgene bottles, closed and sealed with tape, and labeled as Trip Blank 5, Trip Blank 6, Trip Blank 7, Trip Blank 8, Trip Blank 9, and Trip Blank 10. Trip Blank 5 contains 16.1367g of 10 003-127, Trip Blank 6 contains 17.1666g of 10 003-127, Trip Blank 7 contains 16.9224g of 10 003 127, Trip Blank 8 contains 18.7603g of 10 003-127, Trip Blank 9 contains 18.1296g of 10 003-127, Trip Blank 10 contains 18.732lg of 10 003-127 (10 003-127 is an aliquot of TCR-842). The trip blanks were weighed on balance 908 on 6/17/10. Six 1 L bottle containing Milli-Q Gradient water (TNI0-0221) for rinseate samples. 130 empty 250 mL Nalgene bottles (for collecting soil and rinseate samples). Recorded By: Gabriel P. M cM urtry 3M Study G IP 10 -01-02 Interim R eport 05 Date: 6/17/10 Page 54 of 962 E n v iro n m e n ta l L a b o ra to ry Form 38778- A - PWO Shtpplno Addfoaa: Tnlophon*: 3M Center Sample Receiving: (651) 736-6559 ld g . 2 6 0 -5 N -1 7 Alternate: (651)733-9873 St-Paul, MN 55144 FAX: (651) 733-5982 Chain of Custody /Request for Laboratory Analytical Project ID/Project Nam e jQ C C f'T T Z d Tem plate # __ Project Lead Dept. # (m ain) C. / T /? S '/ ( >4 Final Report Due Date Internal Due Date Class/Job/Project # 14916 S o / C. 3M Env. Lab Project. For Internal Use Only <yc=TV' C i r"t.7 O 3 UaJt * ti ~ oa Contact N am e Company M ailing A ddress City, State, Zip H S/JEsU - f T X ! 2 2 V -- T ii) ~ > 3 Telephone # /7 3 '7 - 3 ) FAX# Date Available Date Due Contract Lab --A /d o t - o t - o 3,.y? o L A a, Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) P re s e rv a tiv e s : oo z CO x O w<D (A f| z 4c- _o 5 O o H Analysis Requested: Complete below. Attach any associated Information. Item # C lient Sam ple Identification Da l, r-S P t a p a g o 2. P A L S<> ^ 5 < s ! Q O O T 3. D a t-> <r< ^ < 0 2 o ><~>nc> 4. A U & S S Q Z Ci 0 0 0 5 5. A L <, S'S C '1 O D O O Q 6. SX o ooqr 3M LIM S # 3LL QZ 5 w. D a te T im e 7 - 9 - tiSampled Sampled 7 -% /C .o r^ f 7 - 9 ` iC o f >- o l o rl 2 .; / o 2r g f C / * / r M atrix/ M e d ia Enter the number of containers of each 2L (Enter an 'X1in the box below to indicate request) >L 8. A L. 9. S S o ** Q esC iG O Z Z . 7 - g - / > /z /r 7-7-/ ? -7 -/c /^ 7 V ' < t P I/ 3 j 4 / - > 5 " ~ 5 7 7 ? o Page _ L Interim ReP0rt 05 o< Original Accompanying Samples Last Page - Originator See Reverse Side for Instructions Page 55 of 962 Report Results to: Total Number of Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Form 38778- A -P W O Shipfind Addrots: T o to p h e m ? : 3M Center Sample Receiving: (651) 736*6559 Bldg. 260-5N-17 Alternate: (651) 733-9873 S t Paul, MN 55144 FAX: (651) 733-5982 Contact Name A. A tP roject ID /P roject N am e ?E.CATH /h > *J u - fta .C - Tem plate # Project Lead C.C-L./ Final R eport D ue Date Internal Due Date T E /D e p t.# (m ain) /i / ' ? / / ________________ C la ss/Jo b /P ro je ct # Date Available Company 22.H -JMailing Address / -- -- 3 3 Date Due City, State, Zip T e le p h o n e # 7'JV - 5 5 ''/ 'O Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) FAX# Contract Lab Preservatives: 14917 3M Env. Lab Project # For Internal Use Only 7/rS / e r O i 0 7 , o & U ' os~To > / - ->1 - < 2 i *7 ; < A1 Analysis Requested: Complete below. Attach any associated information. o or> z z O CNO X <0 O c O > o z k> Item 3M Date Tim e M a tr ix / Client Sam ple Identification # 1. 2. 3. 4. fGiAAAALLLl 55555555 5. GAL. 55 6. / 3 A L . < S DAL <5,7. 8. 9. DD fA\LL 55 $510- P a L f5t SS oofftt 55 c A, 55 <<T55scto>f7t iS -Q g a&&Os Oot nn fOot~l o 7 O O oo &!> o o ooo&no ooo ooO o<fr ft O nono i Q G c o q __________ L IM S # fQi f5Z7- Wr ft bft O ftl O$ $f tYi j l 777'7777777S--------a--?77777m7177--p------/-tl1i<1etiitddocoC0oE177/Kt1rf(;S/'i3s4?434ae.mo2tHof!ptst.Olfe<.f0SfroSdtttr M e d ia $* W ,Y S' 5 S' 5 S Enter the number of containers of each ! I 1 I ( I /i X >< _ _ L 5 sk G fit :> (Enter an X in the box below to indicate request) X- Collected by (print): >> *o o Ite m # (A 3 o MO 2* o nmiShed by/Affiliation <^1 -L p E G T o a j Tim e (Q o C ollecto r's signature: Date Shipped Via: 7-/2-/C ^ J t S x r ed by/Affiliation ' s ^* 'r-- T im e D a te t o z o 7/1 ac Sam ple C ondition Upon R eceipt: JK .A cceptable 0 Other: T e m p e ra tu re : Other Associated CoCs: O Received on Ice Copies to; 3M Study G LP10-01-02 Interim R eport 05 Page cJT Original * Accompanying Samples Last Page - Originator See Reverse Side for Instructions Page 56 of 962 Report Results to: Total Number of Containers Environmental Laboratory 14918Chain of Custody /Request for Laboratory Analytical Form 38778 - A - PWO S h ip p in g Address: Telephone: 3M Canter Oldg. 260-5N-17 Sample Receiving: (651) 736-6559 Alternate: (651) 733-9873 St. Paul. MN 55144 FAX: (651) 733-5962 Contact Name f< f_fa y ^ Company / Project ID/Project Nam e Template # Project Lead C C C / Dept. ft (m ain) 7 3 0 * 7 / / -- r , ^ /Z, / <Ufc, J \ 3Tc*i <--- Final R eport Due Date Internal Due Date C lass/Job /P roject ft Date Available 3M Env. Lab Project # For Internal Use Only / O t s f . O f i r t p ~ 'p i -O/"5 S ~ Mailing Address 7 t -- C?2> Date Due City. State, Zip Telephone# / 7 '3 ' 7 * ' * 3 5 ^ 7 0 Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc. ) FAX# Contract Lab P re s e rv a tiv e s : A ' X V U 0 . L . AU\? Analysis Requested: Complete below. Attach any associated Information. JZn O Z Z * O cINo z <A oc o > z0 wV o Item ft Client Sample Identification 3M LIMS# Date Time Sampled Sampled Matrix/ Media Enter the number of containers of each 1. OAL 1 * 5 7 5 o 2 : o o o o <T 2. AL 7 S z s a * ] O O O 7-7-10 /33> 7 -1-/C /OOO X/ i__ / 3. O A l 7 7 7 5 g 9 4. < 5 G / b ry 0 0 3 f 5 O o O O fc j 7 -l- /o o 5 (p y 7 - 2 - c o 7 2C> I/ , 1 5. A 4 < L ^ 5 / 0 l o to . i S <r c 0773 6. a u 7 7 & P c f o o ao 0 1 # 7 - 2 - IC. 0 9 7 7 i 7. A L . < r ^ P o l r t w r 7-Z -/C . a 2 o c > ( 8. / L 7 7 A P o - z . n o o o 7 -K -t ( 9. 10. A L ooor 7 7 (P>Pc>7L. O 0 0 2 O 0 (*f O i >i *D o Ite m # 3 O / - I L 2- o c incjjjlshed by/Affiliation Jes ro a ) ?-P io 7 -S W C 7 6 2 . _ 2 _ C ollector's signature: Tim e D a te Shipped Via: J ? o o 9 -/Z -K { V _" * K S I - f iO (Enter an X in the box below to indicate request) Tim e Date m 7 /y ? /j S am ple Condition Upon Receipt: '^ A cce p ta b le C Other: Tem perature: J `C Other Associated CoCs: O R eceived on Ice Copies to: 3M Study G LP10-01-02 Interim Report 05 Page Original - Accompanying Samples Last Page - Originator Seo Reverse Side for Instructions Page 57 of 962 Report Results | to: ; Total Number of Containers Environmental Laboratory 14919Chain of Custody /Request for Laboratory Analytical Forni 38770 - A -P W O S h ip p in g A d d re s s : 3M Center Bldg. 260-5N-17 SL Paul. MN 55144 T e le p h o n e : Sample Receiving: (551) 736*6559 Alternate: (651) 733*9873 FAX: (651) 733*5982 Contact Name Company Ho H f Project ID /Project Nam e O g L c .A T i.-l/Z. Template # P roject Lead CLC L - f< i /> 1 Dept, it (m ain) T '-t / T r7 i / 5T5L i AA Final R eport Due Date Internal Due Date Class/Job/Project # STo , i - Date Available 3M Env. Lab Project# For Internal Use Only O 'h&Sz-O -A*- 6rLPlO -O h / ~ O S ` Mailing Address - SU - C>3 Date Due City, State, Zip Telephone# 7 7 -- 3 S `"/ ? Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) 0 FAX# Contract Lab P re s e rv a tiv e s : 3 / Y? y:5 o L .A t > Analysis Requested: Complete below. Attach any associated Information. Item # Client Sample Identification 3M LIMS# Date Time Sampled Sampled 1. OAL S<. OPo2_ OP> D O 2 0 0 7 J 'J-Z-tC: o ? c z 2. a AU S S >P'2L O O f X 3. r u t . >Pq 3 0 0 0 0 a 4. A U <<> O P o 3 a 0 0 T 5. A l_ ^ (S f Z O O O 2 - 0 6. L 5 S' 5 / ^ 3 O O O T L O 0 T *~ o-z-tc dJ3<r D U 7-%-ic /S'S' d i y ? - 2 - / C l o o O l T 7 ' ^ / c /o7- Os 1 foTL 7. OAL .S S 8. HAL 9. M l . r s 10. A l < T C <3PO3 7^0 4 ,P><4 0> 0 1 1 0 l t 7 -9 -to d o it O n ^c\P T 0 1 1 0 - 9 - c 07'2jO O / 5 D 2 0 _______ <cd 0-% tc f) O z X Ottn* X <0 0 >0 0c 0 Z 0 Matrix/ Media S s Enter the number of containers of each X < f ( 1 i X i 1 i ( f 5' 51L F < 5 (Entor an 'X' in tho box below to indicate request) >oi o item # to o3 c \b y /A ffilia tio n /j ) ^7 qaJ Tim e 7 Q Q Date Shipped Via: 7-rz-K. 2 2 * id by/A ffiliation S t/7 $ c e Tim e D a te i/is Sam ple C ondition Upon Receipt: JELAcceptable 0 Other: Tem perature: Other Associated CoCs: C 0 R eceived on Ice - Copies to: Page 3M Study G LP10-01-02 Interim R eport 05 -J T Original - Accompanying Samples Comments: Last P age Originator See Reverse Side for Instructions Page 58 of 962 Environmental Laboratory Form 3 8778- A -PW O S h ip p in g A d < Jro * 3M Center Bldg. 260-5N-17 SI. Paul. MN 55144 T o lp M lio n a i Sample Receiving: ($51) 7364559 Alternate: (651) 733-9873 FAX: (651) 733-5982 (Aa Con`actName____ PnAA y 3 (A O e" o a Company Mailing Address City, State, Zip p H ' j - T(.*J ~ ~ a! Telephone # 7 3 ^ 7 ~ 3 C 9 '/ ' ! ) Special Instructions and/or Specific Regulatory Requirements: {method, limit of detection, reporting units, etc.) Chain of Custody /Request for Laboratory Analytical 14920 Project ID/Project Name Template # Project Lead Dept. # (main) DCLfrCU.(L An 9/ i A j P^jULE. <0 Final Report Due Date Internal Due Date Class/Job/Project # i L. J S-THL ) Date Available 3M Env. Lab Project # For Internal Use Only 57737" _ FAX# Date Due Contract Lab Preservatives: o e CO o e I%mO 0 35 - i <o Zc ao o \l/l7 T E v j i' 7 ./1 Analysis Requested: Complete below. Attach any associated information. 6 e >i G AO Item # 1. C A L 5 T 2. f)A L 3. AWSS C lient Sam ple Identification CO T O <r>AO T o c o g G OPo T 3 o ^ o T ' 3M LIM S # D a te T im e Sam pled Sampled < ? < */ Q7Q % 2- a?2% 7*4o o2H3 M atrix/ M e d ia 5 XEnter the number of containers of each 1\ X ! 4. A L . G P& 22 e> n o 2 . 0 5. O A l < S G P o ^ O f l o f r 4Y o7<47 s ~ 7-J-iQ o n H 1 ( 6. PAL- i S G f a i, M i a o 7 # J O/P 0*8 G 7. P A L S*5 GPq & <5 n O O O Oil aZo3 8. Oa L - H GPo C 9. D A L- f t P o & O 10. f ) A u S ' S . G P a , o oooT' o nC o - 2 .0 OfO l i i 3 _____________ o2 o T \ n - i- to ( 3 ^ 2 T I( Xi Collected by (print): m f~ h l.C A K - Collector's signature: Zf " (Enter an `X' in die box below to indicate request) 2, 3 Item # b y /A ffilia tio n Tim e D a te Shipped V ia: R eceiyf^o y/A ffiiia tion Tim e D a te A /z ? / (7 o o 9 -/Z '/C y#///Q c s }0 3 iln / id Chain of Custody Sample Condition Upon Receipt: Temperature: j 2 E l >thor Associated CoCs: ^^A ccep tab le O Other: O Received on Ice Copies to; 3M Study G LP10-01-02 Interim Report 05 %o , Original - Accompanying Samples Comments: Last Pago - Originator S ee Reverse Side for instructions Page 59 of 962 Report Results to: VOCs None Other Total Number of Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical 14921 Form 38778 - A - PWO Shipping Addrona: T elopim m i! 3M Center Sample Receiving: (551) 736-6559 Bldg. 260-5N-17 Alternate: (651) 733-9873 St. Paul, MN 55144 FAX: (651)733-5982 Contact Name Company C%fi/Zu / Project ID /Project N am e PCLATU JL. Template # , Project Lead f it L / S T / v 9 Dept. # (m ain) *?3C> 7 / < Ph> ri -TTK i A A P ^i lL A Final R eport Due Date Internal Due Date C lass/Job/Project # / L. Date Available 3M Env. Lab Project# For Internal Use Only rL f/D ~ o )-O f-O S ' Mailing Address 22^ 5 `t J -- <3 3 Date Due City, State, Zip Telephone# '7 3 ^ 7 -3 5 ''? O Spedal Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) FAX# Contract Lab P re s e rv a tiv e s : 3 , *1 L* a Analysis Requested: Complete below. Attach any associated information. Item # Client Sample Identification 1. Da u <k & Po*7 o o o & e ? 2. r)A L 5 V C M ) & o o o ^ r 3. O a l S S C o r t i O n r & .C > 4. 3/1L 5 C^Por/ <3i 3 C y 5. r,A i ^ O a&<oc> 6. f)A L. S3 < * % > O O o O < r 7. H a l S 5 oa>o$~ 8. n a t ^ 5 & P o Y n> a 0 2 6 9. a L. s s < 3 fo 9 : a 0 0 5 - 0 10. A L 5 5 R. l o 0 70 S ' ' j s>.'\ On zz O UN) z : < c > 3M LIMS# o00 99n7/ OW 09? cMk l o ff ,W Date Time Sampled Sampled 7 -% ic iZ 3 0 flSS-Z. t9z3<r Matrix/ Media < Enter die number of containers of each X f 1 X 3 `4Q 1 N srw 1f ( N r*t ( j /*7 o 3 s i 1 i / W -IO / S " x D -JkL_ --1 K . 'X(Enter an in the box below to indicate request) t4f 3M Study G LP10-01-02 Interim R eport 05 Page 60 of 962 R e p o rt R esults to : VOCs None Other Total Number of Containers Environmental Laboratory Form 3 8 7 7 8 - A -P W O Shipping Addraes: Toiophono: 3M Center Sample Receiving: (651) 736-6559 Bldg. 260-5N-17 Alternate: (651) 733*9873 St. Paul. MN 55144 FAX: (651)733-5982 Contact Name Company (5 , y / M ailing Address S V ,J City, State, Zip T e le p h o n e # 3 y*-- 3 Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) 3 (\) Chain of Custody /Request for Laboratory Analytical 14922 Project ID/Project Nam e ^ Template # __ Project Lead .& / > /" V s "7 iDept. # (m ain) < 3 ' 0 ( 5V / u /E <Te> / C_. Final Report Due Date Internal D ue Date Class/Job/Project # O S-C.A~rU.fL. Date Available 3M Env. Lab Project # For Internal Use Only (jT\ 3 f 0 " |" 9*r it iS i n ^ e rf- 5 FAX# Date Due Contract Lab * > n / .\j O ll x 6 - A nalysis Requested: P re s e rv a tiv e s : Complete below. Attach any associated information. Item # C lient Sam ple Identification 1. 5 5 A / b ? O O O 0 2. c a l . <;<, r k p & l 5 0 0 0 5 - $-53. < 5 /^ ? r? r 4. 5 S A / o 7 O 0 0 -2 .G 5. O fiL . f h j & OC><EO> 6. /U . 5 5 A A 7. / 3 / I 4 - i s A ,/ /o C < 0 0 -5 > C 3 0 (2 > r> 0 'S 8. / U - 5 5 a 9. 5 S 10. Z 3 - 4 - 5 T 5 / V e> 0 >es r t z - 006O /o o 7 F *o too b e d by/A ffiliation 3 o c o Sam ple C ondition Upon Receipt: ^ L A c c e p ta b le 0 Other: Te m pe ratu re: Other Associated CoCs: ' O Received on Ice Copios to: Page 2 _ 3M Study G LP10-01-02 Interim Report 05 = ._ Original - Accompanying Samples Oi*> z z w O (004 X < ~E c5 / 'C y 3M LIM S# /< ? / ( Z. 0 } wk O D a te Tim e S am pled Sam pled 7 -Y -iC / n o /5 ~ 3 * /:T 3 5 /r 3 6 < h io M atrix/ M e d ia < T \ 1 Biter the number of containers of each Xf 1 1 t X i 107 / > f /o o z ta o s ro o 7 I /a /a s Z I (-(C. / 0 3 f :.. i l l ... { / / ii y 2C (Enter an 'X` in the box below to indicate request) zTime D a te Shipped V ia: 2=B d l eceivjd by/Affiliatiom * y * //4 c r Tim e D a te 3. Comments: Last P age Originator See Reverse Side for Instructions Page 61 of 962 Report Results to; VOCs Other Total Number of Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical 14923 Form 38778 - A - PWO S trip p in o A d d r * : Talophono: 3M Conter Sample Receiving: (651) 736-6559 Bldg. 260-5N-17 Alternate: (651) 733-9873 Project ID/Project Name . #Template , /Project Lead CjCZ. A W #Dept. (main) *7 f f A L? f , yA Final Report Due Date Internal Due Date #Ciass/Job/Project S /D -- Contact Name Company //^ y 0 5 T T /^ / Date Available 3M Env. Lab Project # For Internal Use Only Y'& ? i 'd-A 6 (z, Mailing Address City, State, Zip 2 .7 .H -- 3 3 Telephone# 03?-- Special Instructions and/or Specific Regulatory Requirements: (method, limit of dotection, reporting units, etc.) FAX# Date Due Contract Lab P re s e rv a tiv e s : ? 5 J U i 4 Analysis Requested: Complete below. Attach any associated information. Item # Client Sample Identification 1. D a l . C > P fl n oooo 2. D A L . S '? P i O OO S- 3. O A U ? ? G P U 0 ^ 2 . 0 4. O A U C S / W & P ii DA5. f t L . < G C>> ` T " 6. C S Ci PC2. o o o o cy 7. M l < * ; A / 7 z O oo<T 8. ?? A /V 2 - O O Z APrz >9. or? a 10. Collected by (print): > T3 itO Item / > O/ `o c <0 f o 77^ F k y}/<L ed by/Affiliation Sample Condition Upon Receilpiptt:: Temperature: T r Other Associated CoCs: ^ O v c cceeiptable O O ther O Received on Ice Copies to: _______________3M S tudy G L P 1 0 -0 1 -0 2 Interim R eport 05 JLPage JT Original - Accompanying Samples n o z X O (f<04 X e O Z 55 / c 3M UMS# // / y// / / 32 //* r 7/ / { * // !H Date Time Sampled Sampled 7 ^ -/0 f H G Matrix/ Media XEnter the number of containers of each / / X / -7 Z f /o V < / 7 -JP-/ 7 -7 -te U S r /1 O l30 7-7-/0 0?&13/o3 $ Collector's signature: AT I1 .f Ik 9 * * S'z (Enter an X in tho box below to indicate request) 3____ Time Date Shipped Via: Received by/Affiliation Time Date /9 o m iJ ijifd Comments: Last P age Originator Soo Reverse Side for instructions Page 62 of 962 Report Results to: VOCs Other Total Number of Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Forni 3677 * A - PWO Shipping Addr: T l p h o n a : 3M Center Sample Receiving: (551) 736*6559 Bldg. 260-5N-17 Alternate: (651) 733*9873 St. Paul. MN 55144 FAX: (651) 733-5982 Contact Name Company VJ Project ID/Project Name \ J L f . J f e h l Tem plate# t Project Lead \ j jL r \ < ^ T V ^ Dept. # (m ain) O '^ l { l --> \ -> T T \(V yt. Final Report Due Date Internal Due Date Class/Job/Project # Date Available M ailing A ddress Date Due City, State, Zip #Telephone ` 1"T/ O Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) FAX # Contract Lab Preservatives: 4363 /vLPl->l-l~S' 3M Env. Lab Project # For Internal Use Only 7/Y, k\ J . L /t L A nalysis Requested: Complete below. Attach any associated Information. #Item Client S am p le Identification 1. OAL. s TR i PI O / 6 2 .4 - 2. f AL_ SO SO\ a COOO 3. f)A i-- Sbf OOOS" A. A L 5 OO<2> 5. d a l s) o ooar 6- A l. S S 0 o 3 0 0 0 0 6 7. C A L < /) 5 6 3 O O O r 8. AL. x n S 03 A io O>2.S 9. DAL 5 0 S'iOSf 0 <*>noO 10. D a l 5 5t>4- coos- >* C ollected b y (print): OTJ 0+ * Ite m # 3 O WO / ts n f~ / / a/a H. ReJinquistjejj by/Atfiliation a U o<0 Zx V OtXNfi zCo c >( - ) 3M LIM S# Date T im e S am pled Sampled M a trix/ Media Enter tee number of containers of each (Enter an 'X' in the box below to indicate request) -- *Z- `Ztc o 2zc SO 0>3 ogz so OC?Li o2ro $0 o2S ' sn < /X 1 I j I to IO SO O l io /S' S oo^ o9 S~o W oo^ jo 3S~ so I 4>-2S-C /O H O s o f / 1 / >< -- 4 4k ? Collector's signature: ^f Tim e Date Shipped Via: b y /A ffiiia tio n T im e jT J 0/ 7 a Z- /- /6 au f J ? > u r. /Q5 Sam ple Condition Upon Receipt: Temperature: /2 fT ^ Other Associated CoCs: ^ A c c e p ta b le 0 Other: Q Received on Ice Copies to: / - _____________ 3M S tudy G L P 1 0 -0 1 -0 2 ___________________ Interim Report 05 Page J-- o ' _ X Originai Accompanying Samples x Last Pago -Originator 0 .c 0 e, 1 /z i tO f L~ / bo f /0^ ref ,,u4 ft ifaho 0a i t ) & ch->pr tCiJ-0 f $cnu. p i * 5 See Reverso Sido for Instructions Page 63 of 962 Report Results to: VOCs Other Total Number of Containers Environmental Laboratory Form 38778 - A - PWG Shipplno Addrota; Tolophono: 3M Center Sample Receiving: (651) 736-6559 BWg. 260-5N-17 Alternate: (651) 733*9873 St. Paul. MN 55144 FAX: (651) 733-5982 Contact Name tT lP iA r- Company Mailing Address J'^ J b City, State, Zip Telephone# ^T~i 0 Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) feeChain of Custody /Request Laboratory Analytical 14364 ,.^ ' ,'-.. , -- ',-111. t l ' I" Project ID /P roject N am e C vU^oK aA vW 'A .V n ' M _ L \ " A r t ^ T T 'f " m At . T e m piale #__________ A WProject Lead (^a J3 T Final Report Due Date Internal Due Date ' ri u Date Available fcb P lf)-0 \~ 0 \-O S ~ 3M Env. Lab Project # For Internal Use Only Date Due FAX# . Contract Lab P re s e rv a tiv e s : I f X . 4. 3 .t ; Analysis Requested: Complete below. Attach any associated Information. O Z OV) ZX <eD o z S i ir 6 " Item # 1. D A L 57) 2. D v?l s 3. P ^ i _ T <3 4. b / t L S 7 3 5. S/ 6. D al. s n 7. T )al. < 8. 0 4 L S f i 9. d a l r n 10. D a l S O >r O* o 0) 3 o o .c Item ft Client Sample Identification < iOoK t) O 6 S o o o f S> O D O < n^/7 < o (7 so$ f <0 * 2 O Q or o (*o o c > O OooS" o coco /O A o < 3 P ^ > oo^r S - / 0 o 5? A / sn R elinquished by/Affiliation g 3M LIMS# > ll D t L5 o iq O IS " Jk on O lf 019 o t li3a J Date Time Sampled Sampled Matrix/ Media ~2t~fC / S TX) T /r^L < S / ~ t 3 r ' 5s/O /< f^ o & fo &2S-0 ( * r OUiCi ? 3 o f ? :3 0 [ f-S S * sn S r sn sa Enter the number of containers of each X 1 / 1 i 1 i ! 1 X 'X(Enter an m tho box below to indicato rcQuost) ? -/o w/ u 1> -* Tim e D a te Shipped Via: ee/ived by/Affilialion Time D a te /7oo 7-i-tO //o tf l/z h o JC O Sam ple Condition Upon Receipt: Te m pe ratu re: Other Associated CoCs: 7< Acceptable C O th e r 0 Received on Ice - Copies to: y Comments: 0 S^rpf^S il t* y/z/tO, Cue f A c k ^ rC 'c e , j/ 1 i Acfhftffa/ 5 iti 7(9' 3M Study G LP10-01-02 Interim R eport 05 S rv j Page 64 of 962 Page o r_ Original Accompanying Samples Last Pago * Originator S ee Reverse Side (or Instructions Environmental Laboratory Form 38778 * A - PWO Rhipplng 3M Center 8kJg. 260-5N-17 St. Paul, MN 55144 Contact Name to T e le p h o n e : Sample Receiving: (651) 736-6559 Alternate: (651) 733-9873 FAX: (651) 733-5982 -r*............. i I t3n toa ~ o O' .C o m p a n y M ailing A ddress City, State, Zip Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) Chain of Custody /Request fopLaboratory Analytical 14365 Project ID/Project Nam e Template # Project Lead Dept. # (m ain) L tT71C( i ^ Q-- IV . Final Report Due Date Internal Due Date Class/Job/Project # Date Available frL p l ~ ' O - 0 \ ~ S ' 3M Env. Lab Project # For Internal Use Only -f r f c ip io 'O ( P ) o G Q f iJP i-% -> o \..S -^ z s z j < A W t'o Date Due FAX# Contract Lab P re s e rv a tiv e s : Wv - T u i A x J ^ A nalysis Requested: Complete below. Attach any associated information. VOCs Other Total Number of Containers ZZ (XOC*fMt zCOQ> c ly Item # C lient S am p le Identification 1 . OA L. < 0 S o l a 2. H A L 0 O oooo 6005" 3. A L 0 < d i q a < 3 0 0 0 4. D f i L Z SO10 o f t f l o S '" 5. D A L S D S l wO o o o o o6 . OA 1-- * Z U O 6 0 S '" 7. D A L 8. D a l 9. D a l . 1 0 . >A L S 4 o u o SO S 012. P B S O S iZ i o T<CS-DI3 O C D f noO onoST OOOO Collected by (print): /F . h / i J A K %oo Item # 3 O -- /-/o o c w J ^ in q iH s h e d by/Affiliation U e < r- r a 7 3M LIM S# Date Sam pled Tim e Sam pled M atrix/ M edia Enter the number of containers of each 6 2 ^ - / 0 /.*?:<? $ o Xf 727 23 /3'4- l ^ -'OC - s o 1 -( 2 V 6 -U Z -lt .5T 1 07-<r /"\Q> < 0 1 >24 1 /5lfO S 1 /9 ? -7 /S ": .3o < 0 f ozy /< :3 0 r _ 1 f< 0 2 /S l3 r < 2H 'ti N'HO Collector's signature: X1 --L X (Enter an X in the box below to indicate request) Tim e /7oo Date !ved by/Affiliation Tim e A3 Jb ) D a te Sam ple C ondition Upon Recipt: Acceptable C Other: T e m pe ratu re: Other Associated CoCs: ^ 0 Received on Ice Copies to: \ ______________ 3M S tudy G L P 1 0 -0 1 -0 2 __________________ Interim Report 05 - tPage 01 Original - Accompanying Samples ru ) la s t Page - Originator ' SCLiup * S <?/ 7f z /) t l( bu "f A a lt 0 `A* t 5 C / i r / / f f i S ee Reverse Skie for Instructions cc/ & */< " / 7fe /f 2 Page 65 of 962 Report Results to: VOCs Other Total Number of Containers Environmental Laboratory Forni 3677 - A - PWO Shipping Address: 3M Center Bldg. 260-5N-17 St. Paul. MN 55144 Telephone: Sample Receiving: (651) 736-6559 Alternate: (651) 733-9873 FAX: (651) 733-5982 Contact Name Company Mailing A ddress VJ C~7f\A s' City, State, Z ip #T e lepho ne _ G'J D Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) P roject ID /P roje ct N am e v _ ~ 3 T \A A ( \ v\-r^ . O -- T h A J L ' t a T e m p la te # __ \ Project Lead L L \ % s t v O Final Report Due Date Internal Due Date Dept. # (m ain) 11 Class/Job/Project # Date Available 14366 /- G l P io -O S ' 3M Env. Lab Project # For Internal Use Only * f e bf i o J0 i r \ lis h #F A X Date Due Contract Lab P re s e rv a tiv e s : d \ 7 . 1, 5 A nalysis Requested: Complete below. Attach any associated information. Item # 1. A L. < C lient Sam ple Identification s a 13 r-3 00 0S 2. P A L S S l H o c o o 3. A L S S O I4 O c a s ' 4. a l sp s o i< r o o o o o 5. T iA L S $ iS T O 6. T)AU SP SO Id O 7. T)AL. SO S O Id m 8. T a l S'P S O d O 9. T)A l SO < 0 1 7 COOS' oooo ooo ooos oooo 1 0 . 7 ) l. m r 7 a c o o - r Collected b y (print): > o %o Ite m # 3 /-fO o c sto: / fi by/A ffiliation Sam ple Condition Upon Receipt: Temperature: O XS- Other Associated CoCs: Acceptable 0 Other: O Received on Ice Copies tq^ Page , \j~ 3M Study G LP10-01-02 Interim R eport 05 fOf Original - Accompanying Samples on Zz 0<001 z zoC JL ? 3M LIM S# ,o s i OSI.033 o r ns i 03 Y S w Date Tim e Sampled S am pled M atrix/ M e d ia Enter the number of containers of each (Enter an X in the box below to indicate request) A-m-tt rtH <r SP /3 H< X (X f /3 S> M oo i 1 /3 IS /7US~ j r / 3 3LC i 2 -2H -C / Z i S ~ sp i x_ X Tim e D a te Collector's signature: ----------------- ----------- r --------------------------- _ Shipped Via: ^ Received by/Affiliation Tim e D a te / 7 ; q 7 -/-/0 ik h t Last Page - Originator $ 'km pi'ff & rc m 7/zS/, i u f /- /f ffe c /^ , -[f it L>/ < Cf C.f<st' I 11 Cf| '/ / e ' h S ee Reverse Side for Instructions y P~ S*>- *1f> * S Page 66 of 962 3M Confidential Record of Deviation/Nonconformance I. Identification Study / Project No. Date(s) of Occurrence: Document Number: G L P 10-01-01-05' Screening data ETS-8-53.0 C y L fiO -G l- l't a, , , 9-4-10,9-8-10 (d100904a,d 100908a) Sample data s110105a Deviation type s SOP Equipment Procedure Method (Check one) Protocol GPO Other: II. Description (a tta ch e xtra p a g e s a s n e e d e d ) Method Requirements: 1: Method requires this gradient program Table 4. HPLC Mobile Phase Gradient Step 0 1 Time 0.00 3.00 A (%) 97 97 B (%) 3 3 Flow (mL/min) 0.4 0.4 2 3.50 70 30 0.4 3 17.0 40 60 0.4 5 17.5 10 90 0.4 6 19.5 10 90 0.4 7 20.0 97 3 0.4 8 23.0 97 3 0.4 2: This method requires the use of mass-labeled internal standards specific for each target analyte and used for quantification of non-labeled target analytes in the samples. Actual procedure/process: 1: The following gradient was used to allow for a shorter run time. HPLC Mobile Phase Gradient Step 0 1 2 3 4 5 Time 0.00 1.00 11.00 13.50 14.00 17.00 A (%) 90 90 10 10 90 90 B (%) 10 10 90 90 10 10 Flow (mL/min) 0.300 0.300 0.300 0.300 0.300 0.300 2: The internal standard was not used for quantification of non-labeled target analytes in the samples. The response of the internal standard was too low to accurately quantitate the data. 3: Sample GLP10-01-02-05-033 LMS, prepared on 1-3-11, was not properly spiked with internal standard. An external calibration was used to quantify the sample-033, dup, and LMS for PFBS only. 3M Study G LP10-01-02 A te iR e S fli 0 5 ETS-4-008.7 PagePf S ft 67 o f 962 Documentation of Deviations and Control of Nonconforming Testing 3M Confidential Record of Deviation/Nonconformance 1. Identification Study / Project No. GLPT9-Q-1 -01 -05--* m Sie-ouoi-ojT ^ Date(s) of Occurrence: Screening data 9-3-10,9-7-10 (d100903a,d100907a) Document Number: ETS-8-53.0 Deviation type (C heck one) v' SOP Protocol Equipment Procedure Method GPO Other: III. Actions Taken (such as am endm ent issued, S O P revision, etc.) C o rre c tiv e A c tio n ( Yes v No) R efe ren c e : Acceptability o f the nonconform ing work: The changes were made to do a faster screen of the samples on an open instrument. For sample GLP10-01-02-05-033, the LMS will not be reprepared. It willjbe notedin the finaj report Actions: Halting of Work Client Notification Work Recall Withholding of Report Other: Project Lead/PAI Approval: Study Director (if GLP): , Date: / / Sponsor Approval (for G LP protocol deviations): Qlate: Technical Review er (optional): Date: Laboratory Departm ent M anager Approval: Date: / 3 IV. Authorization to Resume Work ______ W here halting o f work occurred, resumption o f work m ust first be approved by Laboratory M anagem ent Laboratory Department M anager Approval: Date: Deviation No. (assig ned b y S tudy D irector o r Team L e a d e r a t the en d o f study o r project) 3M Study G LP10-01-02 M e sm R esoi A5 ETS-4 -008.7 PageP a s e 68 o f 962 Documentation of Deviations and Control of Nonconforming Testing ^ 'TT^ Xua o jDescription: /% / Date Prepared: _ Prepared By: Storage Location: Expiration Date: /-Y __________ - S T '- T 'O ___________ ^ )j MULTI-COMPONENT PREPARATION LOG Book No. 10 006 P a g e N o. ____ 2 Solvent: / 7 < a Q 3M Trace#: j g % ' O Expiration Date: ^ I 3/ y /3 ? ffe& & ay^ ' K : * : " 1 Description: L i n e a r f C M ' i * Date Prepared: | 0 - I ' Z - I D Prepared By: C S G jlgpjf* ', Storage Location: A 5 -7 0 Expiration Date: 2 . - 2 H - 11 MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 7 Solvent: O i t r i 1C, 3M Trace # : T N I O - C 0 8 l ~ u l i Z Expiration Date: M - 7 ~ l Li IHSmPfif''' B f c - Description ^ iF H x S Standard ID# 10 006-7 Component Standard ID# Cone, or Purity 1 0 0 0 5 - q S 3 "W 0 ( Expiration Weight or Date Volume II z - ip - jA U i ^ L m-ix-lHEy Corrected Weight Balance ID ---- Final Concentration I0 0 5 -S I M l&O -- --- /D - O jv u y m L P .P F 0 A Ml 30 1 0 0 0 5 -3 1 )A ^ lm L 2'2 -M -l l P.5)^L -- -- [ f t yiC jifn L pPFO $ iOOOS-SO 3 ^ 1 0 Z - Z l ' t 1 p S ^ i a L- -- -- t-` fJJtel#gp5s ( I I n ^ 1 i '" ro;ycf Cr'ln;! -o2 i Interim iR eeo tt 05 Bi \ r- Final Volume 75m L Approximate Concentration of the mix lO ju jlk u l Reviewed bv: V / VT------- ----- I P / '^ / y O Date Page 70 of 962 Description: Date Prepared: VC- r C F M I X __________ |0 ~I OI ______________ P repared By: Storage Location: CC-TCSr___________________ A * 5 1 0______________ E xpiration D ate: 2 - 2 - 4 ~ 1t_________________ MULTI-COMPONENT PREPARATION LOG Book No. 10 006 P a g e N o. ____ 8 ftS o lv e n t : Tri I 3M T ra c e #: * *117- Expiration D a te: 4 ~ 1 ~ / H _________ D e s c rip tio n PFBS , P F H SCecfO P F 0 A ( F ) P F O S (fCf) Standard ID # 10 0 0 6 -8 Com ponent Standard ID # Cone, or Purity Expiration D ate W eight or Volum e Balance ID C o rrected W eight Final Concentration io c o s - h s 3 1 e/ O 2 - 2 1 - 1 1 t ^(uL- M 0 lm L -- --- jvi0fm L 10005-^% 4 2 S 0 J 1 0 0 0 5 -3 ^ 3 ^ ID Im L -- |0 0 O F -^ O 1FO jkAglmL 2 - 2 1 - n M 3-5^1- -- -- 1 0 -0 ^a.0 1m L -- 10.0 /w 0 J m L -- ID -D ^ g /m L /> Final V olum e Approxim ate 2 F y v \ U Concentration of the mix 1 0 W L Page 71 of 962 CFDescription: I S M i x Date Prepared: P repared By: CSI D - I 1D G _________ S torage Location: Expiration Date: M - I IO MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 9 Solvent: f t c e f o n i t T t ig 3 M T ra c e #: 7 N H 3 Expiration D a te: M - ~ I M ________ Description Sz P F S #S tan d ard ID 10 0 0 6 -9 Com ponent Standard ID # Cone, or Purity Expiration D a te .W eight or Volum e Balance ID C o rrected W eight Final Concentration (|iA>\vr>F) |Ooo5-/feS Si-2 V * H S 3i iaL -- -- .O 1 MPFHxS m PFO A m-3 |D 0 0 5 -I(P ^ lO-ZHH *53^1- -- 1 n oD o o s - 48FI , ID-ZT'12 *31 F U 4 Im L loco s - n \ I ivjL <32-M L --- -- -- -- -- 04 do 0.0^9 8 53 . V /ft------ Final V olum e 'TSSy\C Approxim ate 0- l Concentration of the mix MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 33 Description: Date Prepared: Prepared By: Storage Location: Expiration Date: ____________ / ^ S '~PS>____________ _________ Solvent: f l c j O 3M Trace #: '- /n >9 ">C $t/ ' Y l 2 - Expiration Date: af^~ ^ , Description p ^ f j^ t A r !Sm f f - Standard ID # 10 006-33 Component Standard Cone, or ID # Purity Expiration Date Weight or Volume Corrected Weight Balance ID Final Concentration /O O S ' O /C O O S '- i 3 ! r * . f / 7 0 H -------- O- C-J ^u V /}/? / S) ^ )2 ',/Z ) 1 S Final Volume Approximate v ^ < ~^Concentration of the mix 3M Study GLP10-01-02 Interim Report 05 Page 73 of 962 MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. Reviewed by: Signature, Jh >*-'(> Date Page 74 of 962 MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 25 Page 75 of 962 Description: <$Z>:< o / k w . ' hkT ) D ate Prepared: P repared By: ____________ Storage Location: Expiration Date: (Q~~ *7 ^ -- ' __________ / MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 34 Description /3 & A -3 M ' 1 1<&- Standard ID # 10 006-34 Component Standard ID # Cone, or Purity Expiration Date Weight or Volume Balance ID Corrected Weight Final Concentration V /w H oSS~~ r u t - ------- - ----------- --- ------ y S tA //t iy 0w ) ' ' D / Final Volume 3M Study GLP10-01-02 Interim Report 05 Approximate Concentration of the mix $ : Z d MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 35 D escription: Date Prepared: Prepared By: Storage Location: Expiration Date: ' , ' I4~z, / --V --/ /________________ G ft ' T._________________ A S _______________ 5 _______________ Solvent: 3M Trace #: Expiration Date:___ G HBRL: . 1j j t 1H Description IP jf !5;; Standard ID # 10 006-35 Component Standard Cone, or ID # Purity fle xJr Expiration Date Weight or Volume Corrected Weight Balance ID Final Concentration K o o ^iU -- -- TO% tM /o - ohzA 5'-> -/ Ifo o n L -- -- A y-- I I KxS CopyofCrisis! 3M Study-*GLP1O-0r-02 Interim Report 05 Final Volume Reviewed by Approximate Concentration of the mix Qo '.^ o j'ja - n Date Page 77 of 962 Date: Analyst: SINGLE COMPONENT PREPARATION LOG i Description: _ P i O A - Book No. 10 005 Page No. 36 'TPA-Stock Number: Weight or Volume . /0e?/ JUsed: Balance ID: Concentration or Purity: Corrected Weight: % 0. Ck J Other Correction Factors: Solvent and TN-A Number: 6 !& /O-DOJIS' 3/j> Final Volume: ^---- 1--Final Concentration: ---- - fr------^ ----- Storage Location: Expiration Date: 3M Study GLP10-01-02 Interim Report 05 Reviewed byr At Signature, /j 9 l ( l 10 Date Page 78 of 962 fi Analyst: _ D escrip tion: SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 005 37 P f*% r9 - P / 'n s l a s w ( :Stock Number: -fCKbl- ' W / / { ; Weight or Volume Used: . Balance ID: 9 / 9 - _________________ Concentration or Purity: 99 y <^> Corrected Weight:______ S ' ) . ) Other Correction Factors: Solvent and TN-A Number: /CrZ>9-S" d C & ? ( n n < '7 ^ , / < _ Final Volume: Storage Location: M l/ Final Concentration: Expiration Date:_ 7 / - / / Interim Report '05'" R e v ie w e d by: Signature, Page 79 of 962 Date: -t r^ > SINGLE COMPONENT PREPARATION LOG Book No. 10 010 Weight or Volume Used: / Sv~y ~\ s' / (A J L A y ^ s t Balance ID: Concentration or Purity: f~s / ^ Corrected Weight: y -- Other Correction Factors: '--h o d * ? " O P / Solvent and TN-A Number: /e^ / / Final Volume: / > /V L s ^_ _ _ ^ Storage Location: A A Final Concentration: Expiration Date, S ' s A - / / Cg^ ofCrismi sm . Dul3 3M Study GLP10-01-02 Interim Report 05 Reviewed by: s f.S 2 ^ i- Signature, )~tA ) Date Page 80 of 962 Date: Analyst: Description: SINGLE COMPONENT PREPARATION LOG Book No. 10 010 Page No. 37 / ,l( J / lu X . Stock Number: / 00 ^ ^ -5 Weight or Volume Used: Concentration or Purity: _ Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: ffcK S ) Final Volume: c P S js y l Storage Location: ASK) Final Concentration: 0- 1 / CK s * ' S~61Expiration Date: // 3of Orioni x IK : 3M Study GLP10-01-02 Interim Report 05 Reviewed by: Signature, ^ -------- -- Date Page 81 of 962 SINGLE COMPONENT PREPARATION LOG - 10Hate: Analyst: sJ FF: Description: ^ ' 5+nC/ Book No. 10 005 Page No. 45 T i ^ I I IStock Number: Weight or Volume Used: o.K m c y Concentration or Purity: % nl Corrected Weight: O .Q V j Balance ID: tn Other Correction Factors: 0. f y y Aa / T v o ^ - m o ^ LSolvent and TN-A Number: Final Volume: L Storage Location: As I t ) Final Concentration^ Expiration Date: -1 -II 3M Study GLP10-01-02 Interim Report 05 / / V O -7 0 Reviewed by: Signature, Page 82 of 962 SINGLE COMPONENT PREPARATION LOG Date: Analyst: _ J fk PR)? (CF)Description: Book No. Page No. 10 005 46 TC ( - 1 %Stock Number: Weight or Volume f~\ | ' ) Used:_______ L / ^ | I CX^ Concentration or Purity: _ Corrected Weight: 0 .IV T 7 Balance ID: in Other Correction Factors: O .V n Solvent and TN-A Number / \ t A j 7 / L W ' 0 0 % ' V l ^ Final Volume: Storage Location: Ac no Final Concentration: ^5 0 /rv (_ Expiration Date: >n~n 3M Study GLP10-01-02 Interim Report 05 Page 83 of 962 BateL - t f - i . d% . SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 48 ^inscripti.oonn: _ P F t / S ( e l f ) % , , / Ted- onStock Number: height or Volume Used: ,,-.oncehtration or Purity: _ o .n n - K d 7n Balance ID: 1/2 Other Correction Factors: .V / Corrected Weight: O .fn u 2 Solvent and TN (Numbeirr::_ 4 TaJ 0\- QCflQ-V/A Final Volume: Storage Location: X V t- Final Concentration: TKO ^I Expiration Date: 2 /7 -1 / 3M StudyrGCPl@-Interim Report 05 Reviewed by: Signature, 0 ^ I / o ! '/ Date Page 84 of 962 Date: Analyst: SINGLE COMPONENT PREPARATION LOG to Description: l - P F O S Book No. 10 005 Page No. 50 Stock Number: I C d OV - OMt - Y i Weight or Volume Used: o .\o n & Concentration or Purity: _ \ n 0- Corrected Weight: o. o v i Balance ID: in Other Correction Factors: 0 -!2 9 Solvent and TN-A Number: A c . a / lu M - m - if* Final Volume: Storage Location: Final Concentration: ^ / o MJ > L i Expiration Date: 1 -1 -U Reviewed by: Signature, u ) h d /o Date Page 85 of 962 Analyst: Description: SINGLE COMPONENT PREPARATION LOG -(f) Book No. 10 005 Page No. 51 L - P F l J A % o l' Stock Number: l e f i - O i - 0 01 f - '/l Weight or Volume Used: o. i m , Concentration or Purity: uz Corrected Weight: OAOHAc, J Balance ID: 9 /7 Other Correction Factors: 0.IU Solvent and TN-A Number: f i t c / J T k i o < \ - m a - i n . Final Volume: Final Concentration: H im Storage Location: 4 C 7 q ________________ Expiration Date: > )/ si Cany cf C r r '~:i , , , u y z g r io 3M Study GLP10-01-02 Interim Report 05 Reviewed byf j > 4 i 7 y 3 K \ V sgigrnature, 17 ^7 I/o / / ) Date Page 86 of 962 Date: SINGLE COMPONENT PREPARATION LOG Analyst:_____ ___________________ Description: _ -T'OJ'. - P<v9. Sfa, / Book No. 10 005 Page No. . 122 'Tct^-fysKStock Number: / (fiS . Y S Q l e , Balance ID: Concentration or Purity: Other Correction Factors: Corrected Weight: / ? 5 ~ Y S ! g , Solvent and TN-A Number: 9 > Q Final Volume: Storage Location: Asm Final Concentration: Expiration Date: n 3M -Study G LPia--02 Interim Report 05 Reviewed r-n-n Page 87 of 962 Date: __ Analyst: Description: SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 132 Stock Number: / o 3 0 (j p ~ Weight or Volume Used: Concentration or Purity: / Corrected Weight: Balance ID: Other Correction Factors: Z & c solvent and TN-A A n 0 / ,,, Number. S b n W ' & U ! 3 / y/ /- Final Volume: cQ S 'rylA 1 _ Storage Location:__ Final Concentration: 3 / /A 1 / -- Expiration Date: Cf 3M Study GLP10-01-02 Interim Report 05 Page 88 of 962 Date: tn - Analyst: SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 133 Description: - t i L y - / 3 ^Stock Number: /Q Q o S ' Weight or Volume Used: Balance ID: Concentration or Purity: Corrected Weight: Other Correction Factors: 7M ? ? V i/ Final Volume: /O Storage Location: 5^ Final Concentration: o. --7 Expiration Date: Interim R eport 05 Date: ( Q ~ I ^2.~ I D Analyst: CJ SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 163 Description: F F C M )( Stock Number:_ -JOOOlr.S Weight or Volume Used: \ W '' Concentration or Purity: IQ ml Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A A C C -fv O l T t 1C Number. T N i O ~ O Q % t~ I n . Final Volume: _ I0 n n Storage Location: _ Final Concentration: \ Im L Expiration Date: 2-M - ) | 3M Study GLP10-01-02 Interim Report 05 Page 90 of 962 Date: 10 )O Analyst: CJG SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 164 Description: r C f- F C M X Stock Number: | Q Q Q *5 - I (p 'S Weight or Volume Used: \ W* L Concentration or Purity: \-0 nn L Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A ^ ^ t x I l C. Number: T N i~C >D 1& \ - Final Volume:_ ID Q A l Storage Location: _ Final Concentration: & t 0 1pf\ L Expiration Date: *2~~2M -M 3M Study GLP10-01-02 Interim Report 05 Page 91 of 962 Date: 1D-t7--|D SINGLE COMPONENT PREPARATION LOG Analyst: _ C I S ___________________ Book No. 10 005 Page No. 165 Description: L V T fc Q Y F C M l K Stock Number: I O O P I o ~ ~ l ________ Weight or Volume Used: \ YVA\- Concentration or Purity: _ 1 0 Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A A c e + D t \ f r Number: T / S i l O - P O ^ I - H f l T Final Volume: I 0 VVT L Storage Location: a s :i d . Final Concentration: 1^ I m L Expiration Date: '2 ," t( r .i' 3M Study GLP10-01-02 Interim Report 05 Date: I Q - I 2H Q Analyst: C X G ? SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 166 Description: _ L i n e a f F C K A x Stock Number: \D Q0 5- I>5 Weight or Volume Used: 1 VW L- Concentration or Purity: Corrected Weight: Balance ID: Other Correction Factors: \(LSolvent and TN-A /^cefDniJh-i Number: - n J / a - D O S i - M / i z Final Volume: _ I P m L 5 1 0 .Storage Location: _ f t Final Concentration: IL . Expiration Date: 7 - 3M Study GHP10-01-02^ Interim Report 05 r SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 167 - Uvimvi-ELMJX [D es crip tio n : ,__ I ri A flS - Uok_ .'iS tp kN u m b er. feightorVolume , ^ L B a la n c e ID: ^ C on cen tratio n or . P u rity:, _ O 4 A ^v L - C orrected W eig ht: Final V o lu m e: _ _ _ i j O L . h S l S to r a g e L o c a tio n . O th e r C orrectio n F a c to rs :. s0""'tX .jSSaiSlim- Final C on cen tratio n: n.o\ E xpiration D ate: ^ iM - n 3M Study GLP10-01-02 Interim Report 05 R eview ed Page 94 of 962 Date: |Q - t 7-~ IQ Analyst: CJTQ SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 168 Description: l*S '2_ P F12>S Stock Number: T 6 P . - I P 2 ~ ) Weight or Volume Used: r e A t r v p u V c ___________ Balance ID:_______ ^ O O Concentration or Purity: _ Corrected Weight: % I. 2 j L A ^ I r n L Other Correction Factors: 0. . i Solvent and TN-A Number: Final Volume: I - 2 t v t L Storage Location: _ Final Concentration: < 5 1 . 2 a g i r n e Expiration Date: 5 3M Study G-P10-01-02" ' Interim Report 05 Date: j O - l ' I ' j O Analyst: C J j Description: SINGLE COMPONENT PREPARATION LOG Book No. 10 005 Page No. 169 Stock Number: Weight or Volume Used: g - r v H r e A r w p U l - _______ Balance ID. Concentration or Purity: 50 frAOtIml- Corrected Weight: M l - 3 } u i 0 l n o l Other Correction Factors: Solvent and TN-A Number: Final Volume: \ - ' 2~ FVl L SOStorage Location: Final Concentration: Expiration Date: Im L 3M Study GLP10-01-02 Interim Report 05 Page 96 of 962 Date: I O - 17-- <H Analyst: CCTG?______ SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 005 170 Description: _ M f t P F O A Stock Number: O O C i> ^ ~ ^ /|Q W eigh t or Volum e _ U s e d : b H ~ H f / V m p U I .___________ B alance ID: 10D Concentration or Purity: M ^ / l A g JrT> L Corrected W eight: ^ Im L O th er Correction Factors: 0-^ ^ Solvent and T N -A N um ber: Final Volum e: L.2 - Y Y t CQ^ 0S to rage Location: A Final Concentration: Expiration Date: I t>" 2-7-- I 2- 3M Study GLP10-01-02 Interim Report 05 Page 97 of 962 Date: i f ) - 1 Z - 1 O Analyst: C vfO SINGLE COMPONENT PREPARATION LOG Book No. Page No. 10 005 171 Description: P P iD S Stock Number: T C (2. 0 0 o I ~~S/t <5 Weight or Volume Used: E n f if P A m p u l e Concentration or Purity: _ 50 Corrected Weight: _ Balance ID:______ ^ ? Q Q Other Correction Factors: ___ 0 . Cl 5 `7 Solvent and TN-A Number Final Volume:_____ [ *Z I T I L W Storage Location: Final Concentration^ Expiration Date: 3M Study GLP10-01-02 Interim Report 05 Reviewed Page 98 of 962 SINGLE COMPONENT PREPARATION LOG Date: / I / I j 1 / Q Analyst: Description:______ ~ So, 7 Book No. 10 005 Page No. 244 Stock Number: -T Q JC - < f V ^ Weight or Volume Used: Balance ID: Concentration or Purity: Corrected Weight: ! 1 . 3 ^ T1 Other Correction Factors: Solvent and TN-A Number: Final Volume: Storage Location: Final Concentration: Expiration Date: 3M Study GLP10-01-02 Interim Report 05 Reviewed by: Signature, D a te Page 99 of 962 A Description: / . Date Prepared: / a -yO Storage Location: MULTI-LEVEL PREPARATION LOG Book No. 10 007 Page No. 5 Solvent: Description L - fP o 5 C - P t& Standard ID # 10 007-5-1 Description Component Standards ID# Cone Expiration Date / Std 1 / o o ^ 'S e P -^U / o o o i^ - ! yo o ^x/^ II y J S D O I'S '3 i DS iU d Final Volume Final Concentration / \ftwJ-- /O D 10 007-5-2 cP 10 007-5-3 10 007-5-4 10 007-5-5 10 007-5-6 3 Amount of Component Standard Added 10 007-5-7 10 007-5-8 / / rC+L 00 Std 2 ---- /D o D jtL y Std 3 -- / /o . o / . O Std 4 Std 5 Std 6 Std 7 / --- r w r Z j 0 jo o O /tL .p / 6 . Joo /o / o OioD / y// /7 Description Standard ID# Description Component Standards ID# Cone Expiration Date 10 007-5-9 10 007-5-10 10 007-5-11 10 007-5-12 10 007-5-13 10 007-5-14 10 007-5-15- -^0007-5-16 Std 9 Std 10 Amount of Component Standard--A--d-e-t---d--- Std 11 Std 12 Std 14 Std 15 Std 16 y r ^ iy l S' 1 7^ ( ^ /O r ^^-H^maTvolume Final Concentration Reviewed by:_ ) ! - ' V Description: Date Prepared: Prepared By: //o - ________ - /o>_____ _________ Storage Location: Expiration Date: f) MULTI-LEVEL PREPARATION LOG Book No. 10 007 Page No. ____ 4 ________________ Solvent: ___________ I________________ 3M Trace #: /b R C o j 3 /y L Description L- ft r P P tK /V f H S Standard ID # Description Component Standards ID # Cone Expiration Date j o o 'f ' 5T/ p - n f ju 1i/w ) o jo c o .} - Finai Volume 6)40 Final Concentration ^ S 10 007-4-1 10 007-4-2 10 007-4-3 10 007-4-4 10 007-4-5 10 007-4-6 10 007-4-7 10 007-4-9 / Std 1 / 9 Std 2 y Amount of Component Standard Added Std 3 Std 4 Std 5 Std 6 / / / Std 7 / Std 8 /^ V - /* > - ---------- S 0O c . Jy pt 9/ x ( O \ -9 / /O Cj CfCj / > 0 . 9 9 e} / o /O 0 .0 9 ^ 9 0 .c & ff / Description A \C 1 Standard ID # Description Component Standards , ^ ID # Cone Expiration Date 10 00 7 -4 -9 10 0 0 7-4-10 10 007-4-11 10 0 0 7 -4 -1 2 10 0 0 7-4-13 10 00 7-4-14 10 00 7-4-15 ^JO '007-4-16 Amount of Component Standard-AdHed Std 9 Std 10 Std 11 J^rcT r1 l'u Std 13 Std 14 Std 15 Std 16 stdyiG LP4 01-02 - BnarVolume^ ^ R n a l Concentration Pan e 101 o f 9 6 2 Description: Date Prepared: Prepared By: _____________ ________ Storage Location: ______ Expiration Date: MULTI-LEVEL PREPARATION LOG Book No. 10 007 ._____ _ Page No. ? - o _______________ Solvent: -7/^ZP --<9c9?c^>/ 3 __ 3M Trace#: t~ /X % Description ? P /3 S p6S fn S S ------- -- ~ Standard ID # 10 007-3-1 Description Component Standards ID # Cone Expiration Date ^ Std 1 /o o fiS - ' ' J W y V L f ooon- - 3 - t / o /?a -3- ' -7 O'.1 /C~ 'J T - . 3 . A t 9 --/ y j --T 10 007-3-2 10 007-3-3 10 007-3-4 10 007-3-5 10 007-3-6 sY Amount of Component Standard Added 10 007-3-7 10 007-3-8, / / Std 2 -------- - Std 3 -- se vo y. Std 4 Std 5 ------------ . --------' Std 6 A s t d ^ Std 8 Y j? n X D /` /, ;=s5 y . Final Volume Final Concentration / > ^-- . / / hX 'f / s x X - / o . y _ O o . />o 7. O /O O P 'lh U - `____ /J W * - ^ i-- ' <^ ' / *r*) a ...... Description Standard ID # Description Component Standards ID # Cone Expiration Date 10 007-3-9 10 007-3-10 10 007-3-11 10 007-3-12 10 007-3-13 10 007-3-14 10 0 0 7 -3 ;!$ ' " f0 0 0 7 -3 -1 6 Std 9 Std 10 Amount of ComponentjStafiSard Added Std 11^- -^S td 1 2 Std 13 Std 14 Std 15 Std 16 ^ ^ -> 0 1 3lMStUdG.Pl0-O1-O2 Interim Report 05 ^ ^ in a v o lu m e Final C on cen tratio n ^ -'c fC rf-n ;! ir.:. fY ' u Reviewed by: Signature, " P g u p? of a fi? /^ '^ Date GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil ID W eight Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID LPFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Sonicate Volume 1 hr Centrifuge (m L) C o m m e n ts 1 EC-101203-01 2 0.2 rtg Extracted Curve Point 34 5 67 10 005-244 1.1050 10 005-167 20 1 0 X 6 -1 6 89 30 10 010-38 10 20 11 12 13 14 15 16 EC-101203-02 0.5 nq Extracted Curve Point 10 005-244 1.0924 10 005-167 50 1 0 X 6 -1 6 30 10 010-38 50 EC-101203-03 0.75 nq Extracted Curve Point 10 005-244 1.1255 10 005-167 75 10 006-16 30 10 010-38 75 EC-101203-04 1 nq Extracted Curve Point 10 005-244 1.0858 10 005-167 100 10006-16 30 10 010-38 100 EC-101203-05 2.5 nq Extracted Curve Point 10 005-244 1.0572 10 005-166 25 10 006-16 30 10 010-37 25 EC-101203-06 5 nq Extracted Curve Point 10 005-244 1.1187 10 005-166 50 10 006-16 30 10 010-37 50 EC-101203-07 10 nq Extracted Curve Point 10 005-244 1.1083 10 005-166 100 10 006-16 30 10 010-37 100 EC-101203-08 25 nq Extracted Curve Point 10 005-244 1.1409 10 005-165 25 10006-16 30 1 0 X 6 -3 3 25 EC-101203-09 50 nq Extracted Curve Point 10 005-244 1.0083 10 005-165 50 10006-16 30 10 006-33 50 EC-101203-10 100 nq Extracted Curve Point 10 005-244 1.0902 10 005-165 1 X 1 0 X 6 -1 6 30 10 006-33 100 EC-101203-11 200 nq Extracted Curve Point 10 005-244 1.1317 10 006-7 20 10 006-16 30 10 006-33 2 X EC-101203-12 500 nq Extracted Curve Point 10 005-244 1.1271 10 006-7 50 10 006-16 30 1 0 X 6 -3 3 500 MB-101203-01 Method Blank 1 w/o IS 10 005-244 1.1764 MB-101203-02 Method Blank 2 w/o IS 10 005-244 1.1411 MB-101203-03 Method Blank 3 w/o IS 10 005-244 1.1647 MB-101203-04 Method Blank 4 w / IS 10 005-244 1.1413 10 006-16 30 10 010-37 30 MB-101203-05 Method Blank 5 w / IS 10 005-244 1.1277 10 006-16 30 10 010-37 30 MB-101203-06 Method Blank 6 w/ IS 10 005-244 1.1350 10 006-16 30 10 010-37 30 LCS-101203-01 3 nq LCS in TCR-842 10 005-244 1.1379 10 005-164 30 1 0 X 6 -1 6 30 10 010-37 30 LCS-101203-02 3 nq LCS in TCR-842 10 005-244 1.1543 1 0X 5 -16 4 30 10006-16 30 10 010-37 30 LCS-101203-03 3 nq LCS in TCR-842 10 005-244 1.1568 1 0X 5 -16 4 30 10006-16 30 10010-37 30 LCS-101203-04 30 nq LCS in TCR-842 10 005-244 1.1441 10 005-163 30 10006-16 30 10 010-37 30 LCS-101203-05 30 nq LCS in TCR-842 10 005-244 1.1329 10 005-163 30 10006-16 30 10 010-37 30 LCS-101203-06 30 nq LCS in TCR-842 10 005-244 1.1412 10 005-163 30 10006-16 30 10 010-37 30 GLP10-01-02-05-081 DAL SS GP04 0 0050 1.4943 10006-16 30 10 010-37 30 GLP10-01-02-05-081 Dud DAL SS GP04 0 0050 Duplicate 1.6864 10006-16 30 10 010-37 30 GLP10-01-02-05-081 LMS DAL SS GP04 0 0050 Lab Matrix Spike 1.6053 10006-16 30 10 010-37 30 10 007-3-4 1 X 1 0X 7 -4-3 1 X 10 007-5-3 100 GLP10-01-02-05-082 DAL SS GP05 0 0000 1.0972 10006-16 30 10 010-37 30 GLP10-01-02-05-082 Dup DAL SS GP05 0 0000 Duplicate GLP10-01-02-05-082 LMS DAL SS GP05 0 0000 Lab Matrix Spike 1.1560 . 1.0667 10 006-16 10 006-16 30 10010-37 30 10010-37 30 30 1 0 X 7 -3 -4 100 10007-4-4 1 X 10X7-5-2 50 GLP10-01-02-05-083 DAL SS GP05 0 0005 1.1839 1 0X 6 -16 30 10 010-37 30 GLP10-01 -02-05-083 Dup DAL SS GP05 0 0005 Duplicate 1.1317 10006-16 30 10 010-37 30 GLP10-01-02-05-083 LMS DAL SS GP05 0 0005 Lab Matrix Spike 1.1760 1 0X 6 -16 30 10010-37 30 10 007-3-4 1 X 1 0X 7 -4-3 1 X 1 0X 7 -5-2 50 GLP10-01 -02-05-084 DAL SS GP05 0 0020 1.7118 10006-16 30 10 010-37 30 GLP10-01-02-05-084 Dup GLP10-01-02-05-084 LMS GLP10-01 -02-05-085 DAL SS GP05 0 0020 Duplicate DAL SS GP05 0 0020 Lab Matrix Spike DAL SS GP05 0 0055 lliife i.:.;.. _____ .. 1.2666 1.9024 1.2657 10 006-16 10006-16 1 0X 6 -16 30 10010-37 30 10010-37 30 10 010-37 30 30 1 0 X 7 -3 -4 100 10007-4-4 100 10X 7 -5-2 50 30 GLP10-01-02-05-085 Dup DAL SS GP05 0 0055 Duplicate GLP10-01 -02-05-085 LMS DAL SS GP05 0 0055 Lab Matrix Spike . s i i r a 1.2140 1.2414 10 006-16 1 0X 6 -16 30 10 010-37 30 10010-37 30 30 1 0 X 7 -3 -4 100 10 007-4-3 100 10X 7 -5-2 100 GLP10-01 -02-05-087 DAL SS GP06 0 0000 1.4354 10 006-16 30 10010-37 30 ..... . GLP10-01 -02-05-087 Dup DAL SS GP06 0 0000 Duplicate 1.2935 10 006-16 30 10 010-37 30 GLP10-01 -02-05-087 LMS DAL SS GP06 0 0000 Lab Matrix Spike 1.4837 10 006-16 30 10 010-37 30 1 0X 7 -3-4 100 1X07-4-4 100 10 007-5-2 50 GLP10-01 -02-05-088 DAL SS GP06 0 0005 GLP10-01-02-05-088 Dup DAL SS GP06 0 0005 Duplicate 1.1558 1.0502 10 006-16 10 006-16 30 10 010-37 30 10 010-37 30 30 GLP10-01-02-05-088 LMS DAL SS GP06 0 0005 Lab Matrix Spike 1.3202 10 006-16 30 10 010-37 30 10 007-3-4 20 10007-4-4 100 10X 7 -5-2 50 GLP10-01-02-05-089 DAL SS GP06 0 0020 1.5043 10 006-16 30 10 010-37 30 GLP10-01-02-05-089 Dup DAL SS GP06 0 0020 Duplicate 1.2316 10006-16 30 10 010-37 30 GLP10-01-02-05-089 LMS DAL SS GP06 0 0020 Lab Matrix Spike GLP10-01-02-05-090 DAL SS GP06 0 0110 1.2643 . . 1.4307 1 0 X 6 -1 6 10 006-16 30 10 010-37 30 10 010-37 30 10 X 7-3-4 20 1X07-4-4 100 1 0 X 7 -5-2 50 30 GLP10-01-02-05-090 Dup DAL SS GP06 0 0110 Duplicate 1.3894 10 006-16 30 10 010-37 30 GLP10-01-02-05-090 LMS DAL SS GP06 0 0110 Lab Matrix Spike 1.4665 10 006-16 30 10 010-37 30 20 10007-4-4 100 10 007-5-3 100 GLP10-01-02-05-091 DAL SS GP07 0 0000 1.6376 10 006-16 30 10 010-37 30 GLP10-01-02-05-091 Dup DAL SS GP07 0 0000 Duplicate 1.3976 1 0X 6 -16 30 10 010-37 30 GLP10-01-02-05-091 LMS DAL SS GP07 0 0000 Lab Matrix Spike 1.6577 10006-16 30 10 010-37 30 1 0X 7 -3-4 100 10 007-4-3 100 1 0 X 7 -5-2 100 G LP 10-01-02-05-092 DAL SS GP07 0 0005 1.3563 10006-16 30 10 010-37 30 GLP10-01 -02-05-092 Dup DAL SS GP07 0 0005 Duplicate 1.0837 10006-16 30 10 010-37 30 GLP10-01-02-05-092 LMS DAL SS GP07 0 0005 Lab Matrix Spike 1.5369 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 100 GLP10-01-02-05-093 DAL SS GP07 0 0020 1.1852 10006-16 30 10 010-37 30 GLP10-01-02-05-093 Dup DAL SS GP07 0 0020 Duplicate 1.2006 1 0X 6 -16 30 10 010-37 30 GLP10-01-02-05-093 LMS DAL SS GP07 0 0020 Lab Matrix Spike 1.2714 10006-16 30 10010-37 30 10 007-3-4 20 1 0 X 7 -4-3 1 X 10X 7 -5-2 100 17 18 19 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 20 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil ID W eight Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal S ta n d a rd Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID LPFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Sonicate Volume 1 hr Centrifuge (m L) Comments 1 GLP10-01 -02-05-094 GLP10-01-02-05-094 Dud GLP10-01-02-05-094 LMS GLP10-01 -02-05-095 GLP10-01 -02-05-095 Dup GLP10-01 -02-05-095 LMS GLP10-01-02-05-096 GLP10-01-02-05-096 Dup GLP10-01-02-05-096 LMS GLP10-01-02-05-097 GLP10-01-02-05-097 Oup GLP10-01-02-05-097 LMS GLP10-01 -02-05-098 GLP10-01-02-05-098 Dup GLP10-01 -02-05-098 LMS GLP10-01 -02-05-099 GLP10-01 -02-05-099 Dup GLP10-01-02-05-099 LMS GLP10-01 -02-05-101 GLP10-01-02-05-101 Dup GLP10-01 -02-05-101 LMS GLP10-01-02-05-102 GLP10-01-02-05-102 Dup GLP10-01 -02-05-102 LMS GLP10-01-02-05-103 GLP10-01-02-05-103 Dup GLP10-01-02-05-103 LMS GLP10-01-02-05-104 GLP10-01-02-05-104 Dup GLP10-01-02-05-104 LMS GLP10-01-02-05-105 GLP10-01-02-05-105 Dup GLP10-01 -02-05-105 LMS GLP10-01 -02-05-106 GLP10-01-02-05-106 Dup GLP10-01-02-05-106 LMS GLP10-01 -02-05-107 GLP10-01-02-05-107 Dup GLP10-01 -02-05-107 LMS GLP10-01-02-05-108 GLP10-01 -02-05-108 Dup GLP10-01 -02-05-108 LMS GLP10-01 -02-05-109 GLP10-01-02-05-109 Dup GLP10-01-02-05-109 LMS GLP10-01-02-05-111 GLP10-01-02-05-111 Dup GLP10-01-02-05-111 LMS GLP10-01-02-05-112 GLP10-01 -02-05-112 Dup GLP10-01-02-05-112 LMS GLP10-01-02-05-113 GLP10-01-02-05-113 Dup GLP10-01-02-05-113 LMS GLP10-01-02-05-114 GLP10-01-02-05-114 Dup GLP10-01-02-05-114 LMS GLP10-01-02-05-115 GLP10-01-02-05-115 Dup GLP10-01-02-05-115 LMS GLP10-01-02-05-116 2 DAL SS GP07 0 0130 DAL SS GP07 0 0130 Duplicate DAL SS GP07 0 0130 Lab Matrix Spike DAL SS GP08 0 0000 DAL SS GP08 0 0000 Duplicate DAL SS GP08 0 0000 Lab Matrix Spike DAL SS GP08 0 0005 DAL SS GP08 0 0005 Duplicate DAL SS GP08 0 0005 Lab Matrix Spike DAL SS GP08 DB 0005 DAL SS GP08 DB 0005 Duplicate DAL SS GP08 DB 0005 Lab Matrix Spike DAL SS GP08 0 0020 DAL SS GP08 0 0020 Duplicate DAL SS GP08 0 0020 Lab Matrix Spike DAL SS GP08 0 0050 DAL SS GP08 0 0050 Duplicate DAL SS GP08 0 0050 Lab Matrix Spike DAL SS GP09 0 0000 DAL SS GP09 0 0000 Duplicate DAL SS GP09 0 0000 Lab Matrix Spike DAL SS GP09 0 0005 DAL SS GP09 0 0005 Duplicate DAL SS GP09 0 0005 Lab Matrix Spike DAL SS GP09 DB 0005 DAL SS GP09 DB 0005 Duplicate DAL SS GP09 DB 0005 Lab Matrix Spike DAL SS GP09 0 0020 DAL SS GP09 0 0020 Duplicate DAL SS GP09 0 0020 Lab Matrix Spike DAL SS GP09 0 0050 DAL SS GP09 0 0050 Duplicate DAL SS GP09 0 0050 Lab Matrix Spike DAL SS GP10 0 0000 DAL SS GP10 0 0000 Duplicate DAL SS GP10 0 0000 Lab Matrix Spike DAL SS GP10 0 0005 DAL SS GP10 0 0005 Duplicate DAL SS GP10 0 0005 Lab Matrix Spike DAL SS GP10 0 0020 DAL SS GP10 0 0020 Duplicate DAL SS GP10 0 0020 Lab Matrix Spike DAL SS GP10 0 0060 DAL SS GP10 0 0060 Duplicate DAL SS GP10 0 0060 Lab Matrix Spike DAL SS GP11 0 0000 DAL SS GP11 0 0000 Duplicate DAL SS GP11 0 0000 Lab Matrix Spike DAL SS GP11 0 0005 DAL SS GP11 0 0005 Duplicate DAL SS GP11 0 0005 Lab Matrix Spike DAL SS GP11 0 0020 DAL SS GP11 0 0020 Duplicate DAL SS GP11 0 0020 Lab Matrix Spike DAL SS GP11 0 0065 DAL SS GP11 0 0065 Duplicate DAL SS GP11 0 0065 Lab Matrix Spike DAL SS GP11 DB 0065 DAL SS GP11 DB 0065 Duplicate DAL SS GP11 DB 0065 Lab Matrix Spike DAL SS GP12 0 0000 3 5 B B 1II1 ' 4 1 3293 1 4404 1 5480 1 *: < 1 4501 1 . : 1.8686 1.3628 1 1 2974 1 6925 1.1927 1.0028 1.0997 1.0621 1.2124 1 0931 1.1789 1.3334 1.3221 1.2670 1.3171 1.3691 12 " 1.2489 1,7590 1.1992 1.2759 1.1495 1.1027 1.2677 1,1380 1.2002 1.0680 1.1500 1.1681 1.1210 1.1417 1.0943 1 0840 1 0661 1 3411 1.2096 1.4891 1.3822 1 : .2 1.6919 1.3562 1.4587 1 3500 1.1442 1 5175 1.2941 1.5094 1.2832 1.1730 1.1412 1.2769 1.0657 1 0835 1,6185 5 * 678 9 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10010-37 10 006-16 30 10010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10010-37 10 006-16 30 10010-37 10 006-16 30 10010-37 10 006-16 30 10010-37 10 006-16 30 10 010-37 10 006-16 30 10010-37 10 006-16 30 10010-37 10006-16 30 10010-37 10 006-16 30 10010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10 006-16 30 10 010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10006-16 30 10 010-37 10 006-16 30 10 010-37 10 11 12 13 14 15 16 30 30 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 200 30 30 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 100 30 30 30 10 007-3-4 20 10 007-4-3 50 > 100 30 30 30 10 007-3-4 20 10 007-4-3 50 10 007-5-2 100 30 30 30 10 007-3-4 20 10 007-4-2 50 10 007-5-2 50 30 30 30 10 007-3-4 20 10 007-4-3 f.u 10 007-5-2 50 30 30 30 10007-3-3 !>0 10 007-4-2 50 10 007-5-1 50 30 30 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 30 30 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 30 30 30 10 007-3-4 100 10007-4-4 100 10 007-5-2 50 30 30 30 10 007-3-4 100 10007-4-4 100 10 007-5-3 100 30 30 30 10007-3-3 .',0 10 007-4-2 50 10 007-5-2 50 30 30 30 10 007-3-4 20 10 007-4-2 50 10 007-5-2 50 30 30 30 10 007-3-4 20 10 007-4-2 50 10 007-5-2 50 30 30 30 10 007-3-3 50 10 007-4-2 50 10 007-5-2 50 30 30 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 30 30 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 30 30 30 10 007-3-3 50 10 007-4-3 50 10 007-5-2 50 30 30 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 30 30 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 30 17 18 19 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 6 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 20 3M Study GLP10-01-02 Interim Report 05 Page 2 of 3 Page 104 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil ID W eight Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume <uL) Surrogate Spike ID Surrogate Spike Volume <uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID LPFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume <uL) Extraction Solvent Sonicate Volume 1 hr Centrifuge (m L) Comments 1 GLP10-01-02-05-116 Duo GLP10-01-02-05-116 LMS GLP10-01-02-05-117 GLP10-01-02-05-117 Duo GLP10-01-02-05-117 LMS GLP10-01-02-05-118 GLP10-01-02-05-118 Dup GLP10-01-02-05-118 LMS GLP10-01-02-05-119 GLP10-01-02-05-119 Dup GLP10-01-02-05-119 LMS MB-101203-07 MB-101203-08 2 DAL SS GP12 0 0000 Duplicate DAL SS GP12 0 0000 Lab Matrix Spike DAL SS GP12 0 0005 DAL SS GP12 0 0005 Duplicate DAL SS GP12 0 0005 Lab Matrix Spike DAL SS GP12 0 0020 DAL SS GP12 0 0020 Duplicate DAL SS GP12 0 0020 Lab Matrix Spike DAL SS GP12 0 0170 DAL SS GP12 0 0170 Duplicate DAL SS GP12 0 0170 Lab Matrix Spike Method Blank 5a w/ IS for Dilutions Method Blank 5q w/ IS for Dilutions Col 3 & 4: Balance ID: 900 12/3/2010 mmh r' . ....... . . -V! -iV " l :-;:. ' 4 1.6204 1.1177 1.0248 1.1966 1.2270 1.1291 1.1146 1.1640 1.1006 1.1432 1.0800 5.0127 5.0641 5 67 10 006-16 10006-16 10 006-16 10006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10006-16 Col 7 & 8: pipette:4215537 12/6/10 mmh Col 9 & 10: Col 5 & 6: pipette:4215537 pipette:4215537 12/6/10 mmh pipette:3824414 12/6/10 mmh FN1: not all 8ml o f extraction solvent delivered -7 .5 ml (distracted by hood alarm while delivering) 89 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 10 30 30 30 30 30 30 30 30 30 30 30 150 150 Col 11 & 12: pipette:4215537 12/6/10 mmh 11 12 ' 10 007-3-4 20 13 10007-4-4 14 J '" 100 15 10 007-5-2 16 50 10 007-3-4 20 10007-4-4 100 10 007-5-2 50 10 007-3-4 100 10007-4-4 100 10 007-5-2 50 10 007-3-4 100 10007-4-4 100 10 007-5-3 100 Col 13 & 14: pipette:4215537 12/6/10 mmh Col 15 & 16: C ol 17: 17 8 6 8 8 8 8 8 8 6 8 8 40 40 10006-34 12/6/10 mmh 18 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 19 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 20 FN1 pipette:4215537 pipette:3824414 12/6/10 mmh Sonicator ID: QEJ00595003 C ol 19: Centrifuge ID: 021188-55 10 min @ 3000 RPM Centrifuge ID: 1521430 for method blanks 7&8 3M Study GLP10-01-02 Interim Report 05 Page 3 of 3 Page 105 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample D escription Soil Maxtrix Soil ID W eight Used (g) Spike ID Spike Volume (uL) Internal S ta n d a rd ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID LPFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Sonicate Volume 1 hr Centrifuge (mL) C o m m e n ts 1 2 3 4 5 67 89 10 11 12 13 14 15 16 EC-101203-01 0.2 ng Extracted Curve Point 10 005-244 1.1050 10 005-167 20 10006-16 30 10 010-38 20 EC-101203-02 0.5 no Extracted Curve Point 10 005-244 1.0924 10 005-167 50 10 006-16 30 10 010-38 50 EC-101203-03 0.75 nq Extracted Curve Point 10 005-244 1.1255 10 005-167 75 10 006-16 30 10 010-38 75 EC-101203-04 1 nq Extracted Curve Point 10 005-244 1.0858 10 005-167 100 10 006-16 30 10 010-38 100 EC-101203-05 2.5 nq Extracted Curve Point 10 005-244 1.0572 10 005-166 25 10 006-16 30 10 010-37 25 EC-101203-06 . 5 nq Extracted Curve Point 10 005-244 1.1187 10 005-166 50 10 006-16 30 10 010-37 50 EC-101203-07 10 nq Extracted Curve Point 10 005-244 1.1083 10 005-166 100 10 006-16 30 10 010-37 100 EC-101203-08 25 nq Extracted Curve Point 10 005-244 1.1409 10005-165 25 10 006-16 30 10 006-33 25 EC-101203-09 50 no Extracted Curve Point 10 005-244 1.0083 10 005-165 50 10 006-16 30 10 006-33 50 EC-101203-10 100 nq Extracted Curve Point 10 005-244 1.0902 10 005-165 100 10 006-16 30 10 006-33 100 EC-101203-11 200 nq Extracted Curve Point 10 005-244 1.1317 10 006-7 20 10 006-16 30 10 006-33 200 EC-101203-12 500 nq Extracted Curve Point 10 005-244 1.1271 10 006-7 50 10 006-16 30 10 006-33 500 MB-101203-01 Method Blank 1 w/o IS 10 005-244 1.1764 MB-101203-02 Method Blank 2 w/o IS 10 005-244 1.1411 MB-101203-03 Method Blank 3 w/o IS 10 005-244 1.1647 MB-101203-04 Method Blank 4 w/ IS 10 005-244 1.1413 10 006-16 30 10 010-37 30 MB-101203-05 Method Blank 5 w/ IS 10 005-244 1.1277 10 006-16 30 10 010-37 30 MB-101203-06 Method Blank 6 w/ IS 10 005-244 1.1350 10 006-16 30 10 010-37 30 LCS-101203-01 3 nq LCS in TCR-842 10 005-244 1.1379 10005-164 30 10 006-16 30 10 010-37 30 LCS-101203-02 3 nq LCS in TCR-842 10 005-244 1.1543 10 005-164 30 10 006-16 30 10 010-37 30 LCS-101203-03 3 nq LCS in TCR-842 10 005-244 1,1568 10 005-164 30 10 006-16 30 10 010-37 30 LCS-101203-04 30 nq LCS in TCR-842 10 005-244 1.1441 10 005-163 30 10 006-16 30 10 010-37 30 LCS-101203-05 30 nq LCS in TCR-842 10 005-244 1.1329 10 005-163 30 10 006-16 30 10 010-37 30 LCS-101203-06 30 nq LCS in TCR-842 10 005-244 1.1412 10005-163 30 10 006-16 30 10010-37 30 GLP10-01-02-05-081 DAL SS GP04 0 0050 1.4943 10 006-16 30 10 010-37 30 GLP10-01 -02-05-081 Dud DAL SS GP04 0 0050 Duplicate 1.6864 10 006-16 30 10 010-37 30 GLP10-01 -02-05-081 LMS DAL SS GP04 0 0050 Lab Matrix Spike 1.6053 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-3 100 GLP10-01-02-05-082 DAL SS GP05 0 0000 1.0972 10 006-16 30 10 010-37 30 GLP10-01-02-05-082 Dup DAL SS GP05 0 0000 Duplicate 1.1560 10 006-16 30 10 010-37 30 GLP10-01-02-05-082 LMS DAL SS GP05 0 0000 Lab Matrix Spike 1.0667 10 006-16 30 10 010-37 30 10 007-3-4 100 10007-4-4 100 10 007-5-2 50 GLP10-01-02-05-083 DAL SS GP05 0 0005 1.1839 10006-16 30 10 010-37 30 GLP10-01-02-05-083 Dup DAL SS GP05 0 0005 Duplicate 1.1317 10006-16 30 10 010-37 30 GLP10-01 -02-05-083 LMS DAL SS GP05 0 0005 Lab Matrix Spike 1.1760 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 50 GLP10-01-02-05-084 DAL SS GP05 0 0020 1.7118 10 006-16 30 10 010-37 30 GLP10-01-02-05-084 Dup DAL SS GP05 0 0020 Duplicate 1.2666 10 006-16 30 10 010-37 30 GLP10-01-02-05-084 LMS DAL SS GP05 0 0020 Lab Matrix Spike 1.9024 10 006-16 30 10 010-37 30 10 007-3-4 100 10007-4-4 100 10 007-5-2 50 GLP10-01-02-05-085 DAL SS GP05 0 0055 1.2657 10 006-16 30 10 010-37 30 - GLP10-01 -02-05-085 Dup DAL SS GP05 0 0055 Duplicate 1,2140 10 006-16 30 10 010-37 30 GLP10-01A02-05-085 LMS DAL SS GP05 0 0055 Lab Matrix Spike 1.2414 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 GLP10-01 -02-05-087 DAL SS GP06 0 0000 1.4354 10 006-16 30 10 010-37 30 GLP10-01-02-05-087 Dup DAL SS GP06 0 0000 Duplicate 1.2935 10006-16 30 10 010-37 30 GLP10-01 -02-05-087 LMS DAL SS GP06 0 0000 Lab Matrix Spike 1.4837 10 006-16 30 10 010-37 30 10 007-3-4 100 10007-4-4 100 10 007-5-2 50 GLP10-01-02-05-088 DAL SS GP06 0 0005 1.1558 10 006-16 30 10 010-37 30 GLP10-01 -02-05-088 Dup DAL SS GP06 0 0005 Duplicate 1.0502 10 006-16 30 10 010-37 30 GLP10-01 -02-05-088 LMS DAL SS GP06 0 0005 Lab Matrix Spike 1.3202 10 006-16 30 10 010-37 30 10 007-3-4 20 10007-4-4 100 10 007-5-2 M) GLP10-01-02-05-089 DAL SS GP06 0 0020 1.5043 10 006-16 30 10 010-37 30 GLP10-01 -02-05-089 Dup DAL SS GP06 0 0020 Duplicate 1.2316 10006-16 30 10 010-37 30 GLP10-01 -02-05-089 LMS DAL SS GP06 0 0020 Lab Matrix Spike 1.2643 10 006-16 30 10 010-37 30 10 007-3-4 20 10007-4-4 100 10 007-5-2 50 GLP10-01-02-05-090 DAL SS G P0600110 1.4307 10006-16 30 10 010-37 30 GLP10-01-02-05-090 Dup DAL SS GP06 0 0110 Duplicate 1.3894 10006-16 30 10 010-37 30 GLP10-01-02-05-090 LMS DAL SS GP06 0 0110 Lab Matrix Spike 1.4665 10006-16 30 10 010-37 30 10 007-3-4 20 10007-4-4 100 10 007-5-3 100 GLP10-01 -02-05-091 DAL SS GP07 0 0000 1.6376 10 006-16 30 10 010-37 30 GLP10-01 -02-05-091 Dup DAL SS GP07 0 0000 Duplicate 1.3976 10 006-16 30 10 010-37 30 GLP10-01 -02-05-091 LMS DAL SS GP07 0 0000 Lab Matrix Spike 1.6577 -, 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 GLP10-01-02-05-092 DAL SS GP07 0 0005 1.3563 '- 10 006-16 30 10 010-37 30 GLP10-01 -02-05-092 Dup DAL SS GP07 0 0005 Duplicate 1.0837 10006-16 30 10 010-37 30 GLP10-01-02-05-092 LMS DAL SS GP07 0 0005 Lab Matrix Spike 1.5369 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 100 GLP10-01 -02-05-093 DAL SS GP07 0 0020 1.1852 10006-16 30 10 010-37 30 GLP10-01-02-05-093 Dup DAL SS GP07 0 0020 Duplicate 1.2006 10 006-16 30 10 010-37 30 GLP10-01-02-05-093 LMS DAL SS GP07 0 0020 Lab Matrix Spike 1.2714 10 006-16 30 10 010-37 30 10 007-3-4 20 10 007-4-3 100 10 007-5-2 100 17 18 19 20 8 mmh mmh : 8 mmh mmh 8 mmh mmh 8 mmh . mmh,.,. 8 mmh mmh 8 mmh mmh- 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh m m h 8 mmh mmh 8 mmh mmh 8 mmh mmh y 8 mmh mmh. - 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh::!: 8 mmh mmh - 8 mmh . mmh. 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh s?mmh;:;:: - 8 mmh s mmh 8 mmh mmh ' 8 mmh , mmh ' 8 mmh mmh 8 mmh mmh - 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh ' mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh : mmh 3M Study GLP10-01-02 Interim Report 05- Page 1 of 3 Kf f \* Page 106 of 962 GLP10-01-02-05 ETS-8-053 Sam ple ID Sample Description Soil Maxtrix Soil ID W eight Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume <uL> Surrogate Spike ID Surrogate Spike Volume <uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID LPFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Sonicate Volume 1 hr Centrifuge (m L) C o m m e n ts 1 2 3 4 5 67 8 9 10 11 12 13 14 15 16 17 18 19 20 GLP10-01-02-05-094 DAL SS GP07 0 0130 1.3293 10 006-16 30 10 010-37 30 8 mmh mmh. GLP10-01-02-05-094 Dup DAL SS GP07 0 0130 Duplicate 1.4404 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-094 LMS DAL SS GP07 0 0130 Lab Matrix Spike 1.5480 c. 10006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 200 8 mmh mmh GLP10-01-02-05-095 DAL SS GP08 0 0000 1.3493 10 006-16 30 10 010-37 30 llilliir i 8 mmh mmh GLP10-01 -02-05-095 Dup DAL SS GP08 0 0000 Duplicate 1.4501 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-095 LMS DAL SS GP08 0 0000 Lab Matrix Spike GLP10-01 -02-05-096 DAL SS GP08 0 0005 1.2490 1.8686 J0 006-16 10 006-16 30 10 010-37 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 100 30 -8 mmh mmh - 8 mmh -'mmh GLP10-01 -02-05-096 Dup DAL SS GP08 0 0005 Duplicate 1.3628 10006-16 30 10 010-37 30 8 mmh . mmh GLP10-01-02-05-096 LMS DAL SS GP08 0 0005 Lab Matrix Spike 1.2577 10006-16 30 10 010-37 30 10 007-3-4 20 10 007-4-3 50 10 007-5-2 100 8 mmh mmh GLP10-01 -02-05-097 DAL SS GP08 DB 0005 1.2974 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-097 Dup DAL SS GP08 DB 0005 Duplicate 1.6925 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-097 LMS DAL SS GP08 DB 0005 Lab Matrix Spike 1.1927 10 006-16 30 10 010-37 30 10 007-3-4 20 10 007-4-3 50 10 007-5-2 100 8 mmh mmh G LP 10-01-0 2-05 -098 DAL SS GP08 0 0020 1.0028 10 006-16 30 10 010-37 30 8 mmh m m h GLP10-01-02-05-098 Dup DAL SS GP08 0 0020 Duplicate GLP10-01-02-05-098 LMS DAL SS GP08 0 0020 Lab Matrix Spike 1.0997 1.0621 - 10006-16 10 006-16 30 10 010-37 30 10 010-37 30 30 10 007-3-4 20 10 007-4-2 50 10 007-5-2 50 8 mmh m m h 8 mmh mmh GLP10-01-02-05-099 DAL SS GP08 0 0050 1.2124 10 006-16 30 10 010-37 30 8 mmh ' mmh GLP10-01 -02-05-099 Dup DAL SS GP08 0 0050 Duplicate 1.0931 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-099 LMS DAL SS GP08 0 0050 Lab Matrix Spike 1.1789 10 006-16 30 10 010-37 30 10 007-3-4 20 10 007-4-3 SO 10.007-5-2 50 8 mmh mmh GLP10-01-02-05-101 DAL SSG P09 0 0000 1.3334 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-101 Dup DAL SS GP09 0 0000 Duplicate 1.3221 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-101 LMS DAL SS GP09 0 0000 Lab Matrix Spike 1.2670 10 006-16 30 10 010-37 30 10007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 mmh mmh - GLP10-01 -02-05-102 DAL SS GP09 0 0005 1.3171 10 006-16 30 10 010-37 30 8 mmh mmh * GLP10-01-02-05-102 Dup DAL SS GP09 0 0005 Duplicate 1.3691 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-102 LMS DAL SS GP09 0 0005 Lab Matrix Spike 1.2550 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 8 mmh . mmh GLP10-01 -02-05-103 DAL SS GP09 DB 0005 1.2489 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-103 Dup DAL SS GP09 DB 0005 Duplicate 1.7590 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-103 LMS DAL SS GP09 DB 0005 Lab Matrix Spike 1.1992 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 8 mmh m m h ;." GLP10-01 -02-05-104 DAL SS GP09 0 0020 1.2759 10006-16 30 10 010-37 30 8 mmh ' mmh GLP10-01-02-05-104 Dup DAL SS GP09 0 0020 Duplicate 1.1495 10006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-104 LMS DAL SS GP09 0 0020 Lab Matrix Spike 1.1027 10 006-16 30 10 010-37 30 10 007-3-4 100 10007-4-4 100 10 007-5-2 50 8 mmh mmh G LP 10-01-02-05 -105 DAL SS GP09 0 0050 1.2677 10006-16 30 10 010-37 30 8 mmh : mmh GLP10-01-02-05-105 Dup DAL SS GP09 0 0050 Duplicate 1.1380 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-105 LMS DAL SS GP09 0 0050 Lab Matrix Spike 1.2002 10 006-16 30 10 010-37 30 10 007-3-4 100 10007-4-4 100 10 007-5-3 100 8 mmh mmh GLP10-01 -02-05-106 DAL SS GP10 0 0000 1.0680 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-106 Dup DAL SS GP10 0 0000 Duplicate 1.1500 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-106 LMS DAL SS GP10 0 0000 Lab Matrix Spike 1.1681 10006-16 30 10 010-37 30 10007-3-3 50 10 007-4-2 50 10 007-5-2 50 8 mmh mmh GLP10-01-02-05-107 DAL SS GP10 0 0005 1.1210 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-107 Dup DAL SS G P100 0005 Duplicate 1.1417 10 006-16 30 10 010-37 30 8 mmh mmh . GLP10-01 -02-05-107 LMS DAL SS GP10 0 0005 Lab Matrix Spike 1.0943 10 006-16 30 10 010-37 30 10 007-3-4 20 10 007-4-2 50 10 007-5-2 50 8 mmh 1 mmh GLP10-01-02-05-108 DAL SS GP10 0 0020 1.0840 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-108 Dup DAL SS GP10 0 0020 Duplicate 1.0661 10 006-16 30 10 010-37 30 8 mmh m m h GLP10-01-02-05-108 LMS DAL SS GP10 0 0020 Lab Matrix Spike 1.3411 10 006-16 30 10 010-37 30 10 007-3-4 20 10 007-4-2 50 10 007-5-2 50 8 mmh mmh GLP10-01 -02-05-109 DAL SS GP10 0 0060 1.2096 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-109 Dup DAL SS GP10 0 0060 Duplicate 1.4891 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-109 LMS DAL SS GP10 0 0060 Lab Matrix Spike 1.3822 10 006-16 30 10 010-37 30 10 007-3-3 SO 10 007-4-2 50 10 007-5-2 50 8 mmh .:mmh GLP10-01-02-05-111 DAL SS GP11 0 0000 1.2332 10 006-16 30 10 010-37 30 8 mmh mmh: GLP10-01-02-05-111 Dup DAL SS GP11 0 0000 Duplicate 1.6919 10006-16 30 10 010-37 30 8 mmh mmh GLP10-01 -02-05-111 LMS DAL SS GP11 0 0000 Lab Matrix Spike 1.3562 10006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 8 mmh mmh GLP10-01 -02-05-112 DAL SS GP11 0 0005 GLP10-01-02-05-112 Dup DAL SS GP11 0 0005 Duplicate , 1.4587 1.3500 10 006-16 10 006-16 30 10 010-37 30 10 010-37 30 30 8 mmh mmh 8 mmh mmh GLP10-01-02-05-112 LMS DAL SS GP11 0 0005 Lab Matrix Spike 1.1442 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 SO 10 007-5-2 50 8 mmh mmh GLP10-01-02-05-113 DAL SS GP11 0 0020 GLP1Q-01-02-05-113 Dup DAL SS GP11 0 0020 Duplicate V- -1.5175 1.2941 10 006-16 10 006-16 30 10 010-37 30 10 010-37 30 30 8 mmh mmh ' 8 mmh mmh GLP10-01-02-05-113 LMS DAL SS GP11 0 0020 Lab Matrix Spike 1.5094 10 006-16 30 10 010-37 30 10 007-3-3 50 10 007-4-3 50 10 007-5-2 50 8 mmh mmh GLP10-01-02-05-114 DAL SS GP11 0 0065 1.2832 n 10006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-114 Dup DAL SS GP11 0 0065 Duplicate 1.1730 10 006-16 30 10 010-37 30 8 mmh mmh GLP10-01-02-05-114 LMS DAL SS GP11 0 0065 Lab Matrix Spike 1.1412 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 8 mmh mmh GLP10-01-02-05-115 DAL SS GP11 DB 0065 GLP10-01-02-05-115 Dup DAL SS GP11 DB 0065 Duplicate 1.2769 1.0657 , 10 006-16 10 006-16 30 10 010-37 30 10 010-37 30 30 8 mmh mmh 8 mmh mmh GLP10-01-02-05-115 LMS DAL SS GP11 DB 0065 Lab Matrix Spike 1.0835 10 006-16 30 10 010-37 30 10 007-3-4 100 10 007-4-3 50 10 007-5-2 50 8 mmh mmh GLP10-01-02-05-116 DAL SS GP12 0 0000 1.6185 10006-16 30 10 010-37 30 8 mmh v mmh 3M Study GLP10-01-02 Interim Report 05. . Page 2 of 3 Page 107 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Soil Maxtrix ID W eight Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID LPFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tra c tio n Solvent Sonicate Volume 1 hr Centrifuge <mL) C o m m e n ts 12 GLP10-01-02-05-116 LMS GLP10-01-02-05-117 GLP10-01-02-05-117 Dud GLP10-01-02-05-117 LMS GLP10-01-02-05-118 GLP10-01-02-05-118 Dud GLP10-01-02-05-118 LMS GLP10-01 -02-05-119 GLP10-01-02-05-119 Dud GLP10-01-02-05-119 LMS MB-101203-07 MB-101203-08 DAL SS GP12 0 0000 Lab Matrix Spike DAL SS GP12 0 0005 DAL SS GP12 0 0005 Duplicate DAL SS GP12 0 0005 Lab Matrix Spike DAL SS GP12 0 0020 DAL SS GP12 0 0020 Duplicate DAL SS GP12 0 0020 Lab Matrix Spike DAL SS GP12 0 0170 DAL SS GP12 0 0170 Duplicate DAL SS GP12 0 0170 Lab Matrix Spike Method Blank 5q w/ IS for Dilutions Method Blank 5a w/ IS for Dilutions Col 3 & 4: Balance ID: 900 12/3/2010 mmh 3 4 5 67 1.1177 1.0248 1,1966 1.2270 1.1291 1.1146 1.1640 1.1006 1.1432 1.0800 5.0127 5.0641 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10006-16 10006-16 10006-16 10006-16 10006-16 10006-16 10 006-16 Col 7 & 8: pipette:4215537 Col 9 & 10: Col 5 & 6: pipette:4215537 pipette:4215537 pipette:3824414 FN1: not all 8ml of extraction solvent delivered -7.5 ml {distracted by hood alarm while delivering) _ _ 89 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10 010-37 30 10010-37 30 10010-37 30 10010-37 30 10 010-37 30 10 010-37 30 10 010-37 10 30 30 30 30 30 30 30 30 30 30 150 150 Col 11& 12: pipette:42155 11 12 13 14 15 16 17 18 19 10 007-3 4 10 007-3-4 10 007-3-4 10 007-3-4 20 10007-4-4 100 10 007-5-2 50 20 10007-4-4 100 10 007-5-2 50 100 10007-4-4 100 10 007-5-2 50 100 10007-4-4 100 10 007-5-3 100 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh : m m h 40 mmh m m h 40 mmh mmh v c o i 14 & 14: pipette:4215537 S F A /H W '* - ti /D pipette:4215537 pipette:3824414 SonicatorTOTOEJI 00595003 Col 19: 20 hajy'f Jo&cri 3M Study G LP10-01-02 Interim R eport 05 ....... 3 3P^ e of . . . . . . Page 108 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Welght ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL> Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tr a c tio n Solvent Volume <mL) Sonicate 1 hr Centrifuge Comments 1 2 34 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 EC-101203-01 0.2 ng Extracted Curve Point 10 005-244 1.1050 EC-101203-02 EC-101203-03 EC-101203-04 EC-101203-05 EC-101203-06 EC-101203-07 EC-101203-08 EC-101203-09 EC-101203-10 EC-101203-11 EC-101203-12 MB-101203-01 MB-101203-02 MB-101203-03 MB-101203-04 MB-101203-05 MB-101203-06 LCS-101203-01 LCS-101203-02 LCS-101203-03 LCS-101203-04 LCS-101203-05 LCS-101203-06 GLP10-01 -02-05-081 GLP10-01-02-05-081 Dud GLP10-01-02-05-081 LMS GL P 10-01-02-05-082 GLP10-01-02-05-082 Duo GLP10-01 -02-05-082 LMS GLP10-01 -02-05-083 GLP10-01 -02-05-083 Dud GLP10-01 -02-05-083 LMS GLP10-01 -02-05-084 GLP10-01-02-05-084 Dud GLP 10-01-02-05-084 LMS GLP10-01-02-05-085 GLP10-01-02-05-085 Dud GLP10-01-02-05-085 LMS GLP10-01-02-05-087 GLP10-01-02-05-087 Duo GLP10-01 -02-05-087 LMS GLP10-01 -02-05-088 GLP 10-01-02-05-088 Dud GLP10-01-02-05-088 LMS GLP10-01-02-05-089 GLP10-01-02-05-089 Duo GLP10-01-02-05-089 LMS G LP 10-01-02-05-090 GLP10-01 -02-05-090 Dud GLP10-01 -02-05-090 LMS GLP1O-01-02-05-091 GLP10-01-02-05-091 Dud GLP10-01-02-05-091 LMS G LP 10-01-02-05-092 GLP10-01 -02-05-092 Duo GLP10-01 -02-05-092 LMS GLP10-01 -02-05-093 GLP10-01 -02-05-093 Dud GLP10-01-02-05-093 LMS GLP10-01-02-05-094 GLP10-01-02-05-094 Duo GLP10-01-02-05-094 LMS GLP10-01 -02-05-095 0.5 na Extracted Curve Point 0.75 no Extracted Curve Point 1 no Extracted Curve Point 2.5 nq Extracted Curve Point 5 nq Extracted Curve Point 10 nq Extracted Curve Point 25 nq Extracted Curve Point 50 nq Extracted Curve Point 100 no Extracted Curve Point 200 no Extracted Curve Point 500 no Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 no LCS in TCR-842 3 na LCS in TCR-842 3 nq LCS in TCR-842 30 nq LCS in TCR-842 30 nq LCS in TCR-842 30 nq LCS in TCR-842 DAL SS GP04 0 0050 DAL SS GP04 0 0050 Duplicate DAL SS GP04 0 0050 Lab Matrix Soike DAL SSGP05 0 0000 DAL SS GP05 0 0000 Duplicate DAL SS GP05 0 0000 Lab Matrix Spike DAL SS GP05 0 0005 DAL SS GP05 0 0005 Duplicate DAL SS GP05 0 0005 Lab Matrix Soike DAL SS GP05 0 0020 DAL SS GP05 0 0020 Duplicate DAL SS GP05 0 0020 Lab Matrix Spike DAL SSGP05 0 0055 DAL SS GP05 0 0055 Duplicate DAL SS GP05 0 0055 Lab Matrix Soike DAL SS GP06 0 0000 DAL SS GP06 0 0000 Duplicate DAL SS GP06 0 0000 Lab Matrix Spike DAL SSGP06 0 0005 DAL SS GP06 0 0005 Duplicate DAL SS GP06 0 0005 Lab Matrix Spike DAL SS GP06 0 0020 DAL SS GP06 0 0020 Duplicate DAL SS GP06 0 0020 Lab Matrix Spike DAL SSGP06 0 0110 DAL SS GP06 0 0110 Duplicate DAL SS GP06 0 0110 Lab Matrix Spike DAL SS GP07 0 0000 DAL SS GP07 0 0000 Duplicate DAL SS GP07 0 0000 Lab Matrix Spike DAL SS GP07 0 0005 DAL SS GP07 0 0005 Duplicate DAL SS GP07 0 0005 Lab Matrix Spike DAL SS GP07 0 0020 DAL SS GP07 0 0020 Duplicate DAL SS GP07 0 0020 Lab Matrix Spike DAL SSGP07 0 0130 DAL SS GP07 0 0130 Duplicate DAL SS GP07 0 0130 Lab Matrix Spike DAL SS GP08 0 0000 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 1.0924 1.1255 1.0858 1.0572 1.1187 1.1083 1.1409 1.0083 1.0902 1 1317 1.1271 11-'o4 1.1411 1 1647 1.1413 1 1277 1 1350 1 1379 1.1543 1.1568 1.1441 1.1329 1.1412 1.4943 1.6864 1.6053 1.0972 1.1560 1.0667 1.1839 1.1317 1.1760 1.7118 1.2666 1.9024 1 j-,:1 2140 1.2414 1.4354 1.2935 1.4837 1.1558 1.0502 1.3202 1 5043 1 2316 1.2643 1.4307 1.3894 1.4665 1.6376 1,3976 1.6577 1.3563 1.0837 1.5369 1.1852 1.2006 1.2714 1.3293 1.4404 1.5480 1.3493 ' m m m m :. - .. .. 0 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 Page 1p9 of i/ GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrlx Soil Weight ID Used(g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL> L-PFOS Spike ID L-PFOS Spike Volume <uL) Extraction Solvent Volume Sonicate 1 hr Centrifuge (mL) Comments 1 GLP10-01-02-05-095 Duo GLP10-01-02-05-095 IMS GLP10-01-02-05-096 GLP10-01-02-05-096 Dud GLP10-01-02-05-096 LMS GLP10-01-02-05-097 GLP10-01-02-05-097 Dud GLP10-01 -02-05-097 LMS GLP 10-01-02-05-098 GLP 10-01-02-05-098 DuD GLP 10-01-02-05-098 LMS GLP10-01-02-05-099 GLP10-01-02-05-099 Dud GLP10-01-02-05-099 LMS GLP10-01-02-05-101 GLP10-01-02-05-101 Duo GLP10-01-02-05-101 LMS GLP10-01-02-05-102 GLP10-01-02-05-102 Dud GLP10-01-02-05-102 LMS GLP10-01-02-05-103 GLP10-01-02-05-103 Dud GLP10-01-02-05-103 LMS GLP10-01-02-05-104 GLP10-01-Q2-05-104 Duo GLP10-01-Q2-05-104 LMS GLP10-01-02-05-105 GLP10-01-02-05-105 Dud GLP10-01-02-05-105 LMS GLP10-01-02-05-106 GLP10-01-02-05-106 Dud GLP10-01-02-05-106 LMS GLP10-01-02-05-107 GLP 10-01-02-05-107 Dup GLP10-01-02-05-107 LMS GLP10-01 -02-05-108 GLP10-01-02-05-108 Duo GLP10-01-02-05-108 LMS GLP10-01-02-05-109 GLP10-01-02-05-109 Dud GLP10-01-02-05-109 LMS GLP10-01-02-05-111 GLP10-01-02-05-111 Dup GLP10-01-02-05-111 LMS GLP10-01 -02-05-112 GLP10-01-02-05-112 Duo GLP10-01-02-05-112 LMS GLP10-01-02-05-113 GLP10-01-02-05-113 Dup GLP10-01-02-05-113 LMS GLP10-01-02-05-114 GLP10-01-02-05-114 DuD GLP10-01-02-05-114 LMS GLP10-01-02-05-115 GLP10-01-02-05-115 DuD GLP10-01-02-05-115 LMS GLP10-01-02-05-116 GLP10-01-02-05-116 Dud GLP10-01-02-05-116 LMS GLP10-01 -02-05-117 GLP10-01 -02-05-117 Duo GLP10-01-02-05-117 LMS GLP10-01-02-05-118 GLP10-01-02-05-118 Dud GLP10-01-02-05-118 LMS 2 DAL SS GP08 0 0000 Duplicate DAL SS GP08 0 0000 Lab Matrix Soike DAL SS GP08 0 0005 DAL SS GP08 0 0005 Duplicate DAL SS GP08 0 0005 Lab Matrix Spike DAL SS GP08 DB 0005 DAL SS GP08 DB 0005 Duplicate DAL SS GP08 DB 0005 Lab Matrix Spike DAL SSGP08 0 0020 DAL SS GP08 0 0020 Duplicate DAL SS GP08 0 0020 Lab Matrix Spike DAL SS GP08 00050 DAL SS GP08 0 0050 Duplicate DAL SS GP08 0 0050 Lab Matrix Spike DAL SSGP09 0 0000 DAL SS GP09 0 0000 Duplicate DAL SS GP09 0 0000 Lab Matrix Spike DAL SSGP09 0 0005 DAL SS GP09 0 0005 Duplicate DAL SS GP09 0 0005 Lab Matrix Spike DAL SS GP09 DB 0005 DAL SS GP09 DB 0005 Duplicate DAL SS GP09 DB 0005 Lab Matrix Spike DAL SSGP09 0 0020 DAL SS GP09 0 0020 Duplicate DAL SS GP09 0 0020 Lab Matrix Spike DAL SSGP09 0 0050 DAL SS GP09 0 0050 Duplicate DAL SS GP09 0 0050 Lab Matrix Spike DAL SS GP10 0 0000 DAL SS GP10 0 0000 Duplicate DAL SS GP10 0 0000 Lab Matrix Soike DAL SS GP10 0 0005 DAL SS GP10 0 0005 Duplicate DAL SS GP10 0 0005 Lab Matrix Spike DAL SSGP10 0 0020 DAL SS GP10 0 0020 Duplicate DAL SS GP10 0 0020 Lab Matrix Spike DAL SSGP10 0 0060 DAL SS GP10 0 0060 Duplicate DAL SS GP10 0 0060 Lab Matrix Spike DAL SS GP11 00000 DAL SS GP11 0 0000 Duplicate DAL SS GP11 0 0000 Lab Matrix Spike DAL SSGP11 00005 DAL SS GP11 0 0005 Duplicate DAL SS GP11 0 0005 Lab Matrix Spike DAL SSGP11 0 0020 DAL SS GP11 0 0020 Duplicate DAL SS GP11 0 0020 Lab Matrix Spike DAL SS GP11 0 0065 DAL SS GP11 0 0065 Duplicate DAL SS GP11 0 0065 Lab Matrix Spike DAL SSGP11 DB 0065 DAL SS GP11 DB 0065 Duplicate DAL SS GP11 DB 0065 Lab Matrix Spike DAL SS GP12 0 0000 DAL SS GP12 0 0000 Duplicate DAL SS GP12 0 0000 Lab Matrix Spike DAL SSGP12 0 0005 DAL SS GP12 0 0005 Duplicate DAL SS GP12 0 0005 Lab Matrix Spike DAL SSGP12 0 0020 DAL SS GP12 0 0020 Duplicate DAL SS GP12 0 0020 Lab Matrix Spixe < 3 4 1.4501 1.2490 1.8686 1.3628 1.2577 1.2974 1.6925 1.1927 1.0028 1.0997 1.0621 1.2124 1.0931 1.1789 1.3334 1.3221 1.2670 1.3171 1.3691 1.2550 1.2489 1.7590 1.1992 1.2759 1.1495 1.1027 1.2677 1.1380 1.2002 1.0680 1.1500 1.1681 1.1210 1.1417 1.0943 1.0840 1.0661 1.3411 1.2096 1.4891 1.3822 1.2332 1.6919 1.3562 1.4587 1.3500 1.1442 1.5175 1.2941 1.5094 1.2832 1.1730 1.1412 1.2769 1.0657 1.0835 1.6185 1.6204 1.1177 1.0248 1.1966 1.2270 1.1291 1.1146 1.1640 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 '* " .' ..... , ill ilit s ' . ,- - mmmmm , * ' - -- '' ' ,' , - ' , '''v - s ' v .< ' ' ' f- ' v< e= 3: -- . . '' - * '- 5 3M Study GLP10-01-02 Interim Report 05 ' Page 2 of 3 Page 110 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume <uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL> PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL> L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Sonicate Centrifuge Volume 1 hr (mL) Comments 1 2 34 5 67 8 9 10 11 12 13 14 15 16 17 18 19 20 GLP10-01-02-05-119 DAL SS GP12 0 0170 f... Si Si 1.1006 GLP10-01-02-05-119 Duo DAL SS GP12 0 0170 Duplicate - 1.1432 GLP10-01-02-05-119 LMS DAL SS GP12 0 0170 Lab Matrix Spike 1.0800 MB-101203-07 Method Blank 5a w/ IS for Dilutions 10 005-244 5.0127 MB-101203-08 Method Blank 5a w/ IS for Dilutions 10 005-244 5.0641 ilP lii Col 13 & 14: Coi 17: Col 3 & 4: Col 7 & 8: Balance IO: 900 12/3/2010 mml Col 9 & 10: Col 15 & 16: Col 18: Col 5 & 6: Col 11& 12: Sonicator ID: QEJ100595003 Col 19: Centrifuge ID: 021188-55 10 min @ 3000 RPM Centrifuge ID: 1521430 for method blanks 7to 9 3M Study G LP10-01-02 Interim R eport 05. . . . . . . . . . page3of3 .. P age 111 o f 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple set ID # Lim s # N /A G LP10-01-02-05 S a m p le Description: D ecatur Soils # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 IN T E R N A L C H A IN O F C U S T O D Y 3M Sample IDs Out: storage ID InitJdate G LP 10-01-02-05-081 G LP 10-01-02-05-082 G LP 10-01-02-05-083 G LP 10-01-02-05-084 G LP 10-01 -0 2 -0 5 -0 8 5 G LP 10-01-02-05-087 G LP10-01-02-05-088 G LP10-01-02-05-089 G LP10-01-02-05-090 G LP10-01-02-05-091 G LP10-01-02-05-092 G LP10-01-02-05-093 G LP10-01 -02-05 -09 4 y & o tz t-'/ < ' -- ^ ------------- 2 7 ------------- ___________ ________________ G LP10-01-02-05-095 G LP10-01-02-05-096 G LP10-01-02-05-097 G LP10-01-02-05-098 G LP10-01-02-05-099 G LP10-01-02-05-101 G LP 10-01-02-05-102 G LP 10-01-02-05-103 G LP 10-01-02-05-104 G LP10-01-02-05-105 G LP10-01-02-05-106 G LP 10-01-02-05-107 G LP10-01-02-05-108 G LP10-01-02-05-109 G LP 10-01-02-05-111 G L P 10-01 -02-05 -11 2 G LP10-01-02-05-113 G LP10-01-02-05-114 G LP10-01-02-05-115 In: storage ID k J ? -/ ( IpitJdate -- /j Out: storage ID V InitJdate In: storage ID InitJdate Comments/InltJdate 3M Study GLP10-01-02 Interim Report 05 Page 1 of 2 Page 112 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Urns # N/A GLP10-01-02-05 Sample Description: Decatur Soils IN TE R N A L C H A IN O F C U S T O D Y # 3M Sample IDs Out: storage ID JoiXJdate 33 G LP10-01-02-05-116 34 G LP10-01-02-05-117 35 G LP10-01-02-05-118 36 G LP10-01-02-05-119 V -- _____ ____ In: storage ID /^-tnjtJdate O 2 -/ / t \/ ______ I Out: storage ID InltJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02 Interim Report 05 Page 2 of 2 Page 113 of 962 GLP10-01-02-05 ETS-&-053 Sample ID 1 MB-101101-01 Col 3 & 4: Balance ID: 900 Col 5 & 6: Sample Description 2 Method Blank 5a w/ IS for Dilutions 11/04/10 mmh NA Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e<uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume Sonicate 1 hr Centrifuge (mL) Comments 3 10 005-122 4 5.0053 5 Col 7 & 8: Col 9 & 10: 67 8 9 10 006-9 150 10 005-132 Pipette ID: 265393 11/04/10 mmh Pipette ID: 265893 11/04/10 mmh 10 150 Col 11& 12: NA 11 12 13 14 Col 13 & 14: NA Col 15 & 16: NA 15 16 17 18 19 40 mmh mmh Col 17: Extraction Solvent ID: 10 006-14 Col 18: SonicatorlD: QEJ100595003 Col 19: 10 min @ 3000 RPM Centrifuge ID: 1521430 20 3M Study GLP10-01-02 Interim Report 05. Page 1 of 1 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume <uL) Internal Standard 10 Internal Standard Volume <uL) Surrogate Spike ID Surrogate Spike Volume <uL) PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tr a c tio n Solvent Volume Sonicate 1 hr Centrifuge (mL) Comments 1 EC-101025-01 EC-101025-02 EC-101025-03 EC-101025-04 EC-101025-05 EC-101025-06 EC-101025-07 EC-101025-08 EC-101025-09 EC-101025-10 EC-101025-11 EC-101025-12 MB-101025-01 MB-101025-02 MB-101025-03 MB-101025-04 M B -101025-05 MB-101025-06 LCS-101025-01 LCS-101025-02 LCS-101025-03 LCS-101025-04 LCS-101025-05 LCS-101025-06 G L P 10-01-02-05-001 GLP10-01-02-05-001 Dud GLP 10-01-02-05-001 LMS G L P 10-01 -02-05-002 GLP 10-01-02-05-002 Dud GLP10-01-02-05-002 LMS GL P 10-01 -02-05-003 GLP10-01-02-05-003 Dud GLP10-01-02-05-003 LMS GL P 10-01-02-05-004 GLP10-01-02-05-004 Dud GLP10-01-02-05-004 LMS GLP 10-01-02-05-005 GLP10-01-02-05-005 Dud GLP 10-01-02-05-005 LMS GLP 10-01-02-05-006 GLP 10-01-02-05-006 Dud GLP 10-01-02-05-006 LMS GL P 10-01 -02-05-007 GLP 10-01-02-05-007 Dup GLP10-01-02-05-007 LMS GL P 10-01 -02-05-009 GLP10-01-02-05-009 Dud GLP10-01-02-05-009 LMS GLP10-01-02-05-010 GLP10-01-02-05-010 Dup GLP10-01-02-05-010 LMS GLP 10-01-02-05-011 GLP 10-01-02-05-011 DuD GLP 10-01-02-05-011 LMS GLP 10-01-02-05-012 GLP 10-01-02-05-012 DuD GLP 10-01-02-05-012 LMS GL P 10-01 -02-05-013 GLP10-01-02-05-013 Dud GLP10-01-02-05-013 LMS GLP10-01-02-05-014 GLP 10-01-02-05-014 Dud GLP10-01-02-05-014 LMS GLP10-01-02-05-015 2 0.2 ng Extracted Curve Point 0.5 r>q Extracted Curve Point 0.75 nq Extracted Curve Point 1 no Extracted Curve Point 2.5 no Extracted Curve Point 5 no Extracted Curve Point 10 nq Extracted Curve Point 25 nq Extracted Curve Point 50 nq Extracted Curve Point 100 nq Extracted Curve Point 200 nq Extracted Curve Point 500 nq Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 no LCS in TCR-842 3 na LCS in TCR-842 3 na LCS in TCR-842 30 nq LCS in TCR-842 30 nq LCS in TCR-842 30 nq LCS in TCR-842 DAL SD TRIP1 0 100624 DAL SD TRIP1 0 100624 Duolicate DAL SD TRIP1 0 100624 Lab Matrix Soil DAL SD SD01 0 0000 DAL SD SD01 0 0000 Duplicate DAL SD SD01 0 0000 Lab Matrix Spike DAL SD SD01 0 0005 DAL SD SD01 0 0005 Duplicate DAL SD SD01 0 0005 Lab Matrix Spike DAL SD SD02 0 0000 DAL SD SD02 0 0000 Duplicate DAL SD SD02 0 0000 Lab Matrix Spike DAL SD SD02 0 0005 DAL SD SD02 0 0005 Duplicate DAL SD SD02 0 0005 Lab Matrix Spike DAL SD SD03 0 0000 DAL SD SD03 0 0000 Duplicate DAL SD SD03 0 0000 Lab Matrix Spike DAL SD SD03 0 0005 DAL SD SD03 0 0005 Duplicate DAL SD SD03 0 0005 Lab Matrix Spike DAL SD SD04 0 0000 DAL SD SD04 0 0000 Duplicate DAL SD SD04 0 0000 Lab Matrix Spike DAL SD SD04 0 0005 DAL SD SD04 0 0005 Duplicate DAL SD SD04 0 0005 Lab Matrix Spike DAL SD SD05 0 0000 DAL SD SD05 0 0000 Duplicate DAL SD SD05 0 0000 Lab Matrix Soike DAL SD SD05 0 0005 DAL SD SD05 0 0005 Duplicate DAL SO SD05 0 0005 Lab Matrix Spike DAL SD SD06 0 0000 DAL SD SD06 0 0000 Duplicate DAL SD SD06 0 0000 Lab Matrix Spike DAL SD SD06 0 0005 DAL SD SD06 0 0005 Duplicate DAL SD SD06 0 0005 Lab Matrix Spike DAL SD SD07 0 0000 3 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 -- 1 4 1.1120 1.1575 1.1151 1.1149 1.1114 1.1265 1.1240 1.1478 1.1431 1.2214 1.1146 1.1495 1.1614 1.1311 1.1571 1.1001 1.1012 1.0293 1.1051 1.1211 1.1214 1.0963 1.1424 1.1753 1.0851 1.1187 1.1298 1.6452 1.4694 1.5622 1.8341 1.9958 1.4909 1.5330 1.3529 1.5496 1.9761 1.9316 1.7663 1.5252 1.5505 1.5766 1.5533 1.5120 1.9960 2.0313 1.4837 1.5098 2.1775 1.9464 1.8761 2.0968 1.8726 1.7666 1.7565 1.9126 1.6531 2.1054 2.0318 1.9613 2.1282 2.1432 2.8010 1.6305 5 10 005-167 10 005-167 10 005-167 10 005-167 10 005-166 10 005-166 10 005-166 10005-165 10 005-165 10 005-165 10 006-7 10 006-7 6 20 50 75 100 25 50 100 25 50 100 20 50 10 005-164 10 005-164 10 005-164 10 005-163 10 005-163 10 005-163 30 30 30 30 30 30 v, I f:J : . I I . i. I B B S 1I 533 rI t " " " . ..1 L - * _ S , m im m i -- : ' V A" : . I ~1 -m m w m m m m am c ::~ 1 - ..........- ; -.i:. v - " - 'I 7 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 8 9 10 30 10 005-133 20 30 10 005-133 50 30 10 005-133 75 30 10 005-133 100 30 10 005-132 25 30 10 005-132 50 30 10 005-132 100 30 10 006-002 25 30 10 006-002 50 30 10 006-002 100 30 10 006-002 200 30 10 006-002 500 11 12 13 14 15 16 ; . y .......... . - 30 10 005-132 30 ' 30 10 005-132 30 30 10 005-132 30 30 10005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 20 10 007-4-4 20 10 007-5-4 20 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 20 10 007-4-4 50 10 007-5-2 100 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 20 10 007-4-4 50 10 007-5-2 100 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 100 10 007-4-3 10 007-5-1 50 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 20 10 007-4-3 100 10 007-5-1 50 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 30 ~~1 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 30 10 005-132 30 30 10 005-132 30 ...... i t i 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 30 10 005-132 30 30 10 005-132 30 , 30 10 005-132 30 10 007-3-3 50 10 007-4-3 100 10 007-5-2 100 30 10 005-132 30 , "ill 30 10 005-132 30 30 10 005-132 30 10 007-3-3 50 10 007-4-3 100 10 007-5-2 100 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 30 : 10 005-132 30 30 ! 10 005-132 30 30 ! 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 30 110 005-132 30 17 8 8 8 8 8 8 8 8 8 8 8 8 6 6 6 6 6 8 8 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 18 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 19 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 20 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 Pag; GLP10-01-02-05 ETS-8-053 Sample 10 Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume (uL) Internai Standard ID Internai Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e<uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume Sonicate 1 hr Centrifuge (mL) Comments 1 GLP10-01-02-05-015 Dud GLP10-01-02-05-015 LMS GLP10-01-02-05-016 GLP10-01-02-05-016 Dud GLP10-01-02-05-016 LMS GLP 10-01-02-05-017 GLP10-01-02-05-017 Dud GLP10-01-02-05-017 LMS GLP 10-01-02-05-018 GLP 10-01-02-05-018 Dup GLP 10-01-02-05-018 LMS GLP10-01-02-05-019 GLP10-01-02-05-019 Dud GLP10-01-02-05-019 LMS GLP10-01-02-05-021 GLP10-01-02-05-021 Oup GLP10-01-02-05-021 LMS GLP10-01 -02-05-022 GLP10-01-02-05-022 Dup GLP10-01-02-05-022 LMS GLP10-01-02-05-023 GLP10-01-02-05-023 Dud GLP10-01-02-05-023 LMS GLP10-01-02-05-024 GLP10-01-02-05-024 Dup GLP10-01-02-05-024 LMS GLP10-01-02-05-025 GLP10-01-02-05-025 Dud GLP10-01-02-05-025 LMS GLP10-01-02-05-026 GLP10-01-02-05-026 DuD GLP10-01-02-05-026 LMS GLP10-01-02-05-027 GLP10-01-02-05-027 Dup GLP10-01-02-05-027 LMS GLP10-01-02-05-028 GLP 10-01-02-05-028 Dup GLP10-01-02-05-028 LMS GLP10-01-02-05-029 GLP10-01-02-05-029 Dud GLP10-01-02-05-029 LMS GLP10-01-02-05-030 GLP 10-01-02-05-030 Dup GLP10-01-02-05-030 LMS GLP10-01-02-05-031 GLP10-01-02-05-031 Dud GLP10-01-02-05-031 LMS GLP10-01-02-05-032 GLP10-01-02-05-032 Dup GLP10-01-02-05-032 LMS GLP10-01-02-05-033 GLP10-01-02-05-033 Dud GLP10-01-02-05-033 LMS GLP10-01 -02-05-034 GLP10-01-02-05-034 Dup GLP10-01-02-05-034 LMS GLP10-01 -02-05-035 GLP10-01-02-05-035 Dud GLP10-01-02-05-035 LMS GLP10-01 -02-05-036 GLP10-01-02-05-036 Dud GLP10-01-02-05-036 LMS GLP10-01-02-05-037 GLP10-01-02-05-037 Dud GLP10-01-02-05-037 LMS 23 DAL SD SD07 o oooo Duplicate DAL SD SD07 0 0000 Lab Matrix Spike DAL SD SD07 0 0005 . DAL SD SD07 0 0005 Duplicate DAL SD SD07 0 0005 Lab Matrix Spike DAL SD SD08 0 0000 DAL SD SD08 0 0000 Duplicate :v DAL SD SD08 0 0000 Lab Matrix Spike DAL SD SD08 DB 0000 DAL SD SD08 DB 0000 Duplicate DAL SD SD08 DB 0000 Lab Matrix Spike DAL SD SD08 0 0005 DAL SD SD08 0 0005 Duplicate DAL SD SD08 0 0005 Lab Matrix Spike DAL SD SDQ9 0 0000 DAL SD SD09 0 0000 Duplicate . DAL SD SD09 0 0000 Lab Matrix Spike DAL SD SD09 0 0005 .... DAL SD SD09 0 0005 Duplicate DAL SD SD09 0 0005 Lab Matrix Spike DAL SD SD10 0 0000 DAL SD SD10 0 0000 Duplicate DAL SD SD10 0 0000 Lab Matrix Spike DAL SD SD10 0 0005 DAL SD SD10 0 0005 Duplicate DAL SD SD10 0 0005 Lab Matrix Spike DAL SD SD11 0 0000 DAL SD SD11 0 0000 Duplicate DAL SD SD11 0 0000 Lab Matrix Spike DAL SDSD11 0 0005 DAL SD SD 11 0 0005 Duplicate DAL SD SD11 0 0005 Lab Matrix Spike DAL SD SD12 0 0000 5 ' DAL SD SD 12 0 0000 Duplicate DAL SD SD12 0 0000 Lab Matrix Spike DAL SD SD12 DB 0000 DAL SD SD12 DB 0000 Duplicate DAL SD SD12 DB 0000 Lab Matrix Spike DAL SD SD12 0 0005 DAL SD SD12 0 0005 Duplicate DAL SD SD12 0 0005 Lab Matrix Spike DAL SDSD13 0 0000 I DAL SDSD13 0 0000 Duplicate DAL SDSD13 0 0000 Lab Matrix spike I DAL SDSD13 0 0005 DAL SD SD 13 0 0005 Duplicate DAL SD SD13 0 0005 Lab Matrix Spike DAL SD SD14 0 0000 DAL SD SD 14 0 0000 Duplicate DAL SD SD14 0 0000 Lab Matrix Spike DAL SD SD14 0 0005 DAL SD SD 14 0 0005 Duplicate DAL SD SD14 0 0005 Lab Matrix Spike DAL SD SD15 0 0000 DAL SD SD15 0 0000 Duplicate DAL SD SD15 0 0000 Lab Matrix Spike DAL SD SD15 0 0005 DAL SD SD15 0 0005 Duplicate - DAL SD SD15 0 0005 Lab Matrix Spike -- - DAL SD SD16 0 0000 DAL SD SD16 0 0000 Duplicate DAL SD SD16 0 0000 Lab Matrix Spike DAL SD SD16DB 0000 DAL SD SD16 DB 0000 Duplicate DAL SD SD16 DB 0000 Lab Matrix Spike 4 1.5687 1 5860 1 8495 1 3995 1.5361 1.6988 1f 1.4810 1.8377 1.6169 1.5532 1.4855 1.6127 1 6737 1 6922 1 6586 1 5092 1.9397 1 9852 1.4011 1.4962 1.6585 1.5420 2.1159 1.5490 2.1655 1 7638 1 8130 1 6875 1 5516 1 7726 1,6543 1.5245 1.4150 1 6692 1.8212 1 6185 1.4277 1.5767 1.6677 1.7824 1 8816 1 7963 1 2 0693 2.1050 1.9822 1.3503 1.4301 1 A. \ 1.9467 1.3991 1.6789 1 ~ *4 11.4012 1 1614 1.1970 1.1909 1.2596 1.3751 1.5348 1 3220 1 4040 1.3933 5 6 7 8 9 10 11 12 13 14 15 16 10 006-9 30 10 005-132 30 10006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-2 50 10 007-5-2 100 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-4 20 10 007-4-3 100 10 007-5-2 100 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 w m m vm *? 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 200 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 10 006-9 30 10 005-132 30 ..... ....... 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 200 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 50 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 200 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 200 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-1 20 10 007-5-1 50 10 006-9 30 10 005-132 30 H' 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-1 20 10 007-5-1 50 17 18 19 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 20 3M Study GLP10-01-02 Interim Report 05 Page 2 of 3 Page 116 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume Sonicate 1 hr Centrifuge (mL) Comments 1 GLP 10-01-02-05-038 GLP10-01-02-05-038 Duo GLP10-01-02-05-038 LMS GLP 10-01-02-05-039 GLP 10-01-02-05-039 Duo GLP10-01-02-05-039 LMS GLP10-01 -02-05-040 GLP10-01-02-05-040 Dup GLP10-01-02-05-040 LMS MB-101021-07 MB-101021-08 MB-101021-09 2 DAL SD SD16 0 0005 DAL SD SD16 0 0005 Duplicate DAL SD SD16 0 0005 Lab Matrix Spike DAL SDSD17 0 0000 DAL SD SD17 0 0000 Duplicate DAL SD SD17 0 0000 Lab Matrix Spike DAL SDSD17 0 0005 DAL SD SD17 0 0005 Duplicate DAL SD SD17 0 0005 Lab Matrix Spike Method Blank 5a w/ IS for Dilutions Method Blank 5a w/ IS for Dilutions Method Blank 5a w/ IS for Dilutions 3 r. tM m w w m w l 10 005-122 10 005-122 10 005-122 Col 3 & 4: Balance ID: 900 10/25/10 mmh GLP10-01-02-05-13 to 040 10/26/10 mmh 4 1.5776 1.4068 1.3746 1.4910 1.2794 1.2874 1.2654 1.5152 1.3045 5.0525 5.0114 5.0803 5 Col 7 & 8: Col 9 & 10: Col 5 & 6: Pipette ID: 1093467 10/28/10 mmh 6 7 8 9 10 11 12 13 14 15 16 17 18 19 10006-9 30 10 005-132 30 8 mmh mmh 10 006-9 30 10 005-132 30 8 mmh mmh 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-1 20 10 007-5-1 50 8 mmh mmh 10 006-9 30 10 005-132 30 8 mmh mmh 10 006-9 10 006-9 10 006-9 -am i30 10 005-132 30 30 10 005-132 30 10 007-3-3 50 10 007-4-1 20 10 007-5-1 50 30 10 005-132 30 * 8 mmh mmh 8 mmh mmh 8 mmh mmh 10 006-9 30 10 005-132 30 6 mmh mmh 10 006-9 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-1 20 10 007-5-1 50 150 10 005-132 150 -, 6 mmh mmh 40 mmh mmh 10 006-9 150 10 005-132 150 40 mmh mmh 10 006-9 150 10005-132 150 40 mmh mmh Coi 13 & 14: Coi 17: Pipette ID: 1093467 10/28/10 mmh Pipette ID: 1093467 Extraction Solvent IO: 10 006-14 Pipette ID: 1093467 10/28/10 mmh Col 15 & 16: Col 18: 20 9> Pipette ID: 265893 10/28/10 mir Col 11& 12: Pipette ID: 1093467 Pipette ID: 1093467 Pipette ID: 265893 Sonicator ID: QEJ100595003 Col 19: Centrifuge ID: 021188-55 10 min @ 3000 RPM Centrifuge ID: 1521430 for method blanks 7to 9 r** 3M Study GLP10-01-02 Interim Report 05 page3of3 Page 117 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil W eight ID Used (g) Spike ID Spike Volume (uL) Internal S ta n d a rd ID Internal StandardV o lu m e (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Sonic Ce Solvent ntri Volume ate 1 fug (m L| hr e C o m m e n ts 1 EC-101025-01 EC-101025-02 EC-101025-03 EC-101025-04 EC-101025-05 EC-101025-06 EC-101025-07 EC-101025-08 EC-101025-09 EC-101025-10 EC-101025-11 EC-101025-12 MB-101025-01 MB-101025-02 MB-101025-03 MB-101025-04 MB-101025-05 MB-101025-06 LCS-101025-01 LCS-101025-02 LCS-101025-03 LCS-101025-04 LCS-101025-05 LCS-101025-06 GLP10-01-02-05-001 GLP10-01 -02-05-001 Dup GLP10-01 -02-05-001 LMS GLP10-01 -02-05-002 GLP10-01-02-05-002 Dup GLP10-01 -02-05-002 LMS GLP10-01 -02-05-003 GLP10-01-02-05-003 Dup GLP10-01-02-05-003 LMS GLP10-01 -02-05-004 GLP10-01 -02-05-004 Dup GLP10-01 -02-05-004 LMS GLP10-01 -02-05-005 GLP10-01 -02-05-005 Dup GLP10-01-02-05-005 LMS GLP10-01-02-05-006 GLP10-01-02-05-006 Dup GLP10-01-02-05-006 LMS GLP10-01-02-05-007 GLP10-01-02-05-007 Dup GLP10-01-02-05-007 LMS GLP10-01-02-05-009 GLP10-01-02-05-009 Dup GLP10-01-02-05-009 LMS 23 0.2 ng Extracted Curve Point 10 005-122 0.5 nq Extracted Curve Point 10 005-122 0.75 nq Extracted Curve Point 10 005-122 1 nq Extracted Curve Point 10 005-122 2.5 nq Extracted Curve Point 10 005-122 5 nq Extracted Curve Point 10 005-122 10 nq Extracted Curve Point 10 005-122 25 nq Extracted Curve Point 10 005-122 50 nq Extracted Curve Point 10 005-122 100 nq Extracted Curve Point 10 005-122 200 nq Extracted Curve Point 10 005-122 500 nq Extracted Curve Point 10 005-122 Method Blank 1 w/o IS 10 005-122 Method Blank 2 w/o IS 10 005-122 Method Blank 3 w/o IS 10 005-122 Method Blank 4 w / IS 10 005-122 Method Blank 5 w / IS 10 005-122 Method Blank 6 w / IS 10 005-122 3 nq LCS in TCR-842 10 005-122 3 nq LCS in TCR-842 10 005-122 3 nq LCS in TCR-842 10 005-122 30 nq LCS in TCR-842 10 005-122 30 nq LCS in TCR-842 10 005-122 30 nq LCS in TCR-842 10 005-122 DAL SD TRIP1 0 100624 DAL SD TRIP1 0 100624 Duplicate DAL SD TRIP1 0 100624 Lab Matrix Spike DAL SD SD01 0 0000 DAL SD SD01 0 0000 Duplicate DAL SD SD01 0 0000 Lab Matrix Spike DAL SD SD01 0 0005 DAL SD SD01 0 0005 Duplicate DAL SD SD01 0 0005 Lab Matrix Spike DAL SD SD02 0 0000 DAL SD SD02 0 0000 Duplicate DAL SD SD02 0 0000 Lab Matrix Spike DAL SD SD02 0 0005 DAL SD SD02 0 0005 Duplicate :t DAL SD SD02 0 0005 Lab Matrix Spike DAL SD SD03 0 0000 DAL SD SD03 0 0000 Duplicate DAL SD SD03 0 0000 Lab Matrix Spike DAL SD SD03 0 0005 DAL SD SD03 0 0005 Duplicate DAL SD SD03 0 0005 Lab Matrix Spike DAL SD SD04 0 0000 I- DAL SD SD04 0 0000 Duplicate DAL SD SD04 0 0000 Lab Matrix Spike ...... . GLP10-01-02-05-010 Dup GLP10-01 -02-05-010 LMS GLP10-01 -02-05-011 GLP10-01 -02-05-011 Dup GLP10-01-02-05-011 LMS GLP10-01 -02-05-012 GLP10-01-02-05-012 Dup GLP10-01 -02-05-012 LMS GLP10-01-02-05-013 GLP10-01-02-05-013 Dup GLP10-01 -02-05-013 LMS DAL SD SD04 0 0005 Duplicate DAL SD SD04 0 0005 Lab Matrix Spike DAL SD SD05 0 0000 DAL SD SD05 0 0000 Duplicate DAL SD SO05 0 0000 Lab Matrix Spike DAL SD SD05 0 0005 DAL SD SD05 0 0005 Duplicate DAL SD SD05 0 0005 Lab Matrix Spike DAL SD SD06 0 0000 DAL SD SD06 0 0000 Duplicate DAL SD SD06 0 0000 Lab Matrix Spike > V' 4 1.1120 1.1575 1.1151 1.1149 1.1114 1.1265 1.1240 1.1478 1.1431 1,2214 1.1146 1,1495 1.1614 1.1311 1.1571 1.1001 1.1012 1.0293 1.1051 1.1211 1.1214 1.0963 1.1424 1.1753 1.0851 1.1187 1.1298 1.6452 1.4694 1.5622 1.8341 1.9958 1.4909 1.5330 1.3529 1.5496 1.9761 1.9316 1.7663 1.5252 1.5505 1.5766 1.5533 1.5120 1.9960 2.0313 1.4837 1.5098 5 10005-167 10 005-167 10 005-167 10 005-167 10 005-166 10X5-166 10X5-166 10 005-165 10 005-165 10X5-165 1 0 X 6 -7 1 0 X 6 -7 67 20 10 006-9 50 10 006-9 75 10 006-9 100 10 006-9 25 10 006-9 50 1 0 X 6 -9 100 10 006-9 25 10 006-9 50 10 006-9 100 10 006-9 20 10 006-9 50 10 0 X -9 10 005-164 10 005-164 10X5-164 10X5-163 10 005-163 10 005-163 P. I 30 30 30 30 30 30 '-p 'P H-- -- - , ' 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 1 0 X 6 -9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 1 0X 6 -9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 1.9464 10006-9 1.8761 10006-9 2.0968 10 006-9 1.8726 10 006-9 1.7666 r f i / 1 0X 6 -9 1.7565 10 006-9 1.9126 10 006-9 1.6531 10 006-9 2.1054 10 006-9 2.0318 ' ' 10 006-9 1.9613 1 "V ; ' v.i 10 006-9 8 9 10 30 10 005-133 20 30 1 0 X 5 -13 3 50 30 10 005-133 75 30 10 005-133 100 30 10 005-132 25 30 10 005-132 50 30 10X 5 -13 2 1 X 30 1 0 X 6 -X 2 25 30 1 0 X 6 -X 2 50 30 1 0 X 6 -X 2 1 X 30 1 0 X 6 -X 2 2 X 30 10 006-002 500 30 10005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 1 0 X 5 -13 2 30 1 0 X 5 -13 2 30 10 005-132 30 10 005-132 30 10 005-132 30 1 0 X 5 -13 2 30 10 005-132 30 10 005-132 30 10 005-132 30 1 0X 5 -13 2 30 1 0X 5 -13 2 30 1 0X 5 -13 2 30 1 0X 5 -13 2 30 1 0X 5 -13 2 30 1 0X 5 -13 2 30 10 005-132 30 1 0X 5 -13 2 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 1 0X 5 -13 2 30 30 10 005-132 30 30 10 005-132 30 30 1 0 X 5 -13 2 30 30 1 0 X 5 -13 2 30 30 1 0 X 5 -13 2 30 30 1 0 X 5 -13 2 30 11 1? 13 10 007-3-4 20 10 007-4-4 10 007-3-4 20 ".S.. 1 0 X 7 -3 -4 20 1 0 X 7 -4-4 1 0 X 7 -3 -4 100 10 007-4-3 10 007-3-4 20 1 0 X 7 -4-3 10X7-3-4 1 X 10X7-4-3 10 007-3-4 100 10 007-4-3 10 007-3-3 50 10X7-3-3 50 1 0X 7 -4-2 1 0X 7 -4-2 1 0 X 7 -3 -3 50 10 007-4-3 10 007-3-3 50 1 0X 7 -4-3 1 0 X 7 -3 -4 100 10 007-4-3 14 15 16 20 10 007-5-4 20 10 007-5-2 1X 50 10 007-5-2 1 X 100 10 007-5-1 100 10 007-5-1 50 ... 50 1 X 10 007-5-1 50 100 10 007-5-1 50 50 10 007-5-1 50 50 10X 7 -5-1 50 1X - . ' 100 1 X 1 0 X 7 -5 -2 100 100 10 007-5-2 100 17 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 6 8 8 18 19 20 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 ( GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil W eight ID Used (g) Spike ID Spike Volume (uM Internal Standard ID Internal StandardV o lum e (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Sonic Ce Solvent ate 1 ntri Volume hr fug (m L) e Comments 1 GLP10-01-02-05-014 GLP10-01-02-05-014 Dup GLP10-01-02-05-014 LMS GLP10-01-02-05-015 GLP10-01-02-05-015 Dup GLP10-01-02-05-015LMS GLP10-01-02-05-016 GLP10-01-02-05-016 Dup GLP10-01-02-05-016 LMS GLP10-01 -02-05-017 GLP10-01-02-05-017 Dup GLP10-01-02-05-017 LMS GLP10-01-02-05-018 GLP10-01-02-05-018 Dup GLP10-01-02-05-018 LMS GLP10-01-02-05-019 GLP10-01-02-05-019 Dup GLP10-01-02-05-019 LMS GLP10-01-02-05-021 GLP10-01-02-05-021 Dup GLP10-01 -02-05-021 LMS GLP10-01 -02-05-022 GLP10-01-02-05-022 Dup GLP10-01-02-05-022 LMS GLP10-01 -02-05-023 GLP10-01 -02-05-023 Dup GLP10-01 -02-05-023 LMS GLP10-01 -02-05-024 GLP10-01-02-05-024 Dup GLP10-01-02-05-024 LMS GLP10-01-02-05-025 GLP10-01 -02-05-025 Dup GLP10-01-02-05-025 LMS GLP10-01-02-05-026 GLP10-01-02-05-026 Dup GLP10-01-02-05-026 LMS GLP10-01-02-05-027 GLP10-01-02-05-027 Dup GLP10-01-02-05-027 LMS GLP10-01-02-05-028 GLP10-01-02-05-028 Dup GLP10-01-02-05-028 LMS G LP 10-01-02-05-029 GLP10-01-02-05-029 Dup GLP10-01-02-05-029 LMS GLP10-01-02-05-030 GLP10-01 -02-05-030 Dup GLP10-01-02-05-030 LMS GLP10-01 -02-05-031 GLP10-01-02-05-031 Dup GLP10-01-02-05-031 LMS GLP10-01-02-05-032 GLP10-01-02-05-032 Dup GLP10-01-02-05-032 LMS GLP10-01-02-05-033 GLP10-01-02-05-033 Dup GLP10-01-02-05-033 LMS GLP10-01-02-05-034 GLP10-01-02-05-034 Dup GLP10-01-02-05-034 LMS GLP10-01 -02-05-035 2 DAL SD SD06 0 0005 DAL SD SD06 0 0005 Duplicate DAL SD SD06 0 0005 Lab Matrix Spike DAL SD SD07 0 0000 DAL SD SD07 0 0000 Duplicate DAL SD SD07 0 0000 Lab Matrix Spike DAL SD SD07 0 0005 DAL SD SD07 0 0005 Duplicate DAL SD SD07 0 0005 Lab Matrix Spike DAL SD SD08 0 0000 DAL SD SD08 0 0000 Duplicate DAL SD SD08 0 0000 Lab Matrix Spike DAL SD SD08 DB 0000 DAL SD SD08 DB 0000 Duplicate DAL SD SD06 DB 0000 Lab Matrix Spike DAL SD SD08 0 0005 DAL SD SD08 0 0005 Duplicate DAL SD SD08 0 0005 Lab Matrix Spike DAL SD SD09 0 0000 DAL SD SD09 0 0000 Duplicate DAL SD SD09 0 0000 Lab Matrix Spike DAL SD SD09 0 0005 DAL SD SD09 0 0005 Duplicate DAL SD SD09 0 0005 Lab Matrix Spike DAL SD SD10 0 0000 DAL SD SD10 0 0000 Duplicate DAL SD SD10 0 0000 Lab Matrix Spike DAL SD SD10 0 0005 DAL SD SD10 0 0005 Duplicate DAL SD S D 100 0005 Lab Matrix Spike DAL SD SD11 0 0000 DAL SO SD11 0 0000 Duplicate DAL SD SD11 0 0000 Lab Matrix Spike DAL SD SD11 0 0005 DAL SD SD11 0 0005 Duplicate DAL SD SD11 0 0005 Lab Matrix Spike DAL SD SD12 0 0000 DAL SD SD12 0 0000 Duplicate DAL SD SD12 0 0000 Lab Matrix Spike DAL SD S D12DB0000 DAL SD SD12 DB 0000 Duplicate DAL SD SD12 DB 0000 Lab Matrix Spike DAL SD SD12 0 0005 DAL SD SD12 0 0005 Duplicate DAL SD SD12 0 0005 Lab Matrix Spike DAL SD SD13 0 0000 DAL SD SD13 0 0000 Duplicate DAL SD SD13 0 0000 Lab Matrix Spike DAL SD SD13 0 0005 DAL SD SD13 0 0005 Duplicate DAL SD SD13 0 0005 Lab Matrix Spike DAL SD SD14 0 0000 DAL SD SD14 0 0000 Duplicate DAL SD SD14 0 0000 Lab Matrix Spike DAL SD SD14 0 0005 DAL SD SD14 0 0005 Duplicate DAL SD SD14 0 0005 Lab Matrix Spike DAL SD SD15 0 0000 DAL SD SD15 0 0000 Duplicate DAL SD SD15 0 0000 Lab Matrix Spike DAL SD SD15 0 0005 3 4 2.1282 2.1432 2.8010 1.6305 1.5687 1.5860 1.8495 1.3995 1.5361 1.6988 1.5055 1.4810 1.8377 1.6169 1.5532 1.4855 1.6127 1.6737 1.6922 1.6586 1.5092 1.9397 1.98T2 1.4011 1.4962 1.651 1.5420 2.1159 1.5496 2.16! 1.7638 1.8130 1.687 1.5516 1.7726 1.6543 1.5245 1.4150 1.6692 1.8212 1.6185 1.4277 1.571" 1.6677 1.7824 1.8818 1.7963 1.6779 2.0693 2.1050 1.9822 1.3503 1.4301 1.4272 1.9467 1.3991 1.671*.* 1.7344 1.631 :. 1.4012 1.1614 5 67 8 9 10 11 12 13 14 15 16 17 18 19 20 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 8 10 006-9 30 10 005-132 30 mmmmm 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 8 10 006-9 30 10 005-132 30 6 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-2 50 10 " 1 1 . 100 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-4 20 10 007-4-3 100 10 007-5-2 100 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 !>0 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 50 8 1 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 200 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 10 006-9 30 10 005-132 30 6 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 ' 10 006-9 30 10 005-132 30 8 : 10 006-9 30 10 005-132 30 8 J 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 6 10 006-9 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 200 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 50 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 8 10 006-9 30 10 005-132 30 10 007-3-2 25 10 007-4-1 20 10 007-5-1 200 8 10 006-9 30 10 005-132 30 8 3M Study GLP10-01-02 Interim Report 05 Page 2 o f 3 Page 119 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil W eight ID Used (g) Spike ID Spike Volume <uL) Internal Standard ID Internal StandardV Surrogate olume Spike ID (uL) Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Ce Solvent Sonic ntri Volume ate 1 fug (m L) hr e C o m m e n ts 1 GLP10-01-02-05-035 Dup GLP10-01 -02-05-035 LMS GLP10-01 -02-05-036 GLP10-01-02-05-036 Dup GLP10-01 -02-05-036 LMS GLP10-01-02-05-037 GLP10-01-02-05-037 Dup GLP10-01-02-05-037 LMS GLP10-01-02-05-038 GLP10-01-02-05-038 Dup GLP10-01-02-05-038 LMS GLP10-01-02-05-039 GLP10-01-02-05-039 Dup GLP10-01-02-05-039 LMS GLP10-01-02-05-040 GLP10-01-02-05-040 Dup GLP10-01-02-05-040 LMS MB-101021-07 MB-101021-08 MB-101021-09 2 DAL SD SD15 0 0005 Duplicate DAL SD SD15 0 0005 Lab Matrix Spike DAL SD SD16 0 0000 DAL SD SD16 0 0000 Duplicate DAL SD SD16 0 0000 Lab Matrix Spike DAL SD SD16DB0000 DAL SD SD16 DB 0000 Duplicate DAL SD SD16 DB 0000 Lab Matrix Spike DAL SD SD16 0 0005 DAL SD SD16 0 0005 Duplicate DAL SD SD16 0 0005 Lab Matrix Spike DAL SD SD17 0 0000 DAL SD SD17 0 0000 Duplicate DAL SD SD17 0 0000 Lab Matrix Spike DAL S DSD17 0 0005 DAL SD SD17 0 0005 Duplicate DAL SD SD17 0 0005 Lab Matrix Spike Method Blank 5a w / IS for Dilutions Method Blank 5a w / IS for Dilutions Method Blank 5a w/ IS for Dilutions Col 3 & 4: Balance ID: 900 10/25/10 mmh GLP10-01-02-05-13 to 040 10/26/10 mmh 3 10005-122 10 005-122 10 005-122 Col 5 & 6: Pipette ID: 1093467 10/28/10 mmh \0 4 1.1970 1.1909 1.2596 1.3751 1.5348 1.3220 1.4040 1.3933 1.5776 1.4068 1.3746 1.4910 1.2794 1.2874 1.2654 1.5152 1.3045 5.052" 5.0114 5.08C 5 Col 7 & 8: Col 9 & 10: lv 67 8 9 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10006-9 30 10 005-132 10006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 30 10 005-132 10 006-9 150 10 005-132 10 006-9 150 10 005-132 10 006-9 150 10 005-132 Pipette ID: 1093467 10/28/10 mmh Pipette ID: 1093467 10/28/10 mmh 10 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 150 150 150 1' 10 007-3-3 10 007-3-3 10 007-3-3 10 007-3-3 10 007-3-3 10 007-3-3 Pipette ID: 265893 10/28/10 mm Col 11& 12: Pipette ID: 1093467 50 10 007-4-2 14 50 50 10 007-4-1 20 50 10 007-4-1 20 50 10 007-4-1 20 50 10 007-4-1 20 50 10 007-4-1 20 Col 13 & 14: Pipette ID: 1093467 Col 15 & 16: Pipette 10:1093467 15 10 007-5-1 10 007-5-1 10 007-5-1 10 007-5-1 10 007-5-1 10 007-5-1 16 17 18 19 8 200 8 8 8 50 8 8 8 50 8 8 8 50 8 8 8 50 8 8 8 50 8 40 40 40 Col 17: Extraction Solvent ID: 10 006-14 Col 18: '' 20 \& SonicatorlD: QEJ100595003 p>pu / 3M Study GLP10-01-02 Interim Report 05 . . . .. . . . .page3 of3 . .. Page 120 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soli Weight ID Used (g) 1 EC-101025-01 EC-101025-02 EC-101025-03 EC-101025-04 EC-101025-05 EC-101025-06 EC-101025-07 EC-101025-08 EC-101025-09 EC-101025-10 EC-101025-11 EC-101025-12 MB-101025-01 MB-101025-02 MB-101025-03 MB-101025-04 MB-101025-05 MB-101025-06 LCS-101025-01 LCS-101025-02 LCS-101025-03 LCS-101025-04 LCS-101025-05 LCS-101025-06 GLP10-01-02-05-001 GLP10-01-02-05-001 Dup GLP10-01-02-05-001 LMS GLP10-01-02-05-002 GLP10-01-02-05-002 Dup GLP10-01-02-05-002 LMS G LP 10-01-02-05-003 GLP10-01-02-05-003 Dup GLP10-01-02-05-003 LMS GLP10-01-02-05-004 GLP10-01-02-05-004 Dup GLP 10-01-02-05-004 LMS GLP10-01-02-05-005 GLP10-01-02-05-005 Dup GLP10-01-02-05-005 LMS GLP10-01-02-05-006 GLP10-01-02-05-006 Dup GLP10-01-02-05-006 LMS GLP10-01-02-05-007 GLP10-01-02-05-007 Dup GLP10-01-02-05-007 LMS GLP10-01-02-05-009 GLP10-01-02-05-009 Dup GLP10-01-02-05-009 LMS GLP10-01-02-05-010 GLP10-01-02-05-010 Dup GLP10-01-02-05-010 LMS GLP10-01-02-05-011 GLP10-01-02-05-011 Dup GLP10-01-02-05-011 LMS GLP10-01-02-05-012 GLP10-01-02-05-012 Dup GLP10-01-02-05-012 LMS G L P 10-01-02-05-013 GLP10-01-02-05-013 Dup GLP10-01-02-05-013 LMS G LP 10-01-02-05-014 GLP10-01-02-05-014 Dup GLP10-01-02-05-014 LMS GLP10-01-02-05-015 2 0.2 ng Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 ng Extracted Curve Point 1 ng Extracted Curve Point 2.5 ng Extracted Curve Point 5 ng Extracted Curve Point 10 ng Extracted Curve Point 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 ng Extracted Curve Point 200 ng Extracted Curve Point 500 ng Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 DAL SD TRIP1 0 100624 DAL SD TRIP1 0 100624 Duplicate DAL SD TRIP1 0 100624 Lab Matrix Spike DAL SD SD01 0 0000 DAL SD SD01 0 0000 Duplicate DAL SD SD01 0 0000 Lab Matrix Spike DAL SD SD01 0 0005 DAL SD SD01 0 0005 Duplicate DAL SD SD01 0 0005 Lab Matrix Spike DAL SD SD02 0 0000 DAL SD SD02 0 0000 Duplicate DAL SD SD02 0 0000 Lab Matrix Spike DAL SD SD02 0 0005 DAL SD SD02 0 0005 Duplicate DAL SD SD02 0 0005 Lab Matrix Spike DAL SD SD03 0 0000 DAL SD SD03 0 0000 Duplicate DAL SD SD03 0 0000 Lab Matrix Spike DAL SD SD03 0 0005 DAL SD SD03 0 0005 Duplicate DAL SD SD03 0 0005 Lab Matrix Spike DAL SD SD04 0 0000 DAL SD SD04 0 0000 Duplicate DAL SD SD04 0 0000 Lab Matrix Spike DAL SD SD04 0 0005 DAL SD SD04 0 0005 Duplicate DAL SD SD04 0 0005 Lab Matrix Spike DAL SD SD05 0 0000 DAL SD SD05 0 0000 Duplicate DAL SD SD05 0 0000 Lab Matrix Spike DAL SD SD05 0 0005 DAL SD SD05 0 0005 Duplicate DAL SD SD05 0 0005 Lab Matrix Spike DAL SD SD06 0 0000 DAL SD SD06 0 0000 Duplicate DAL SD SD06 0 0000 Lab Matrix Spike DAL SD SD06 0 0005 DAL SD SD06 0 0005 Duplicate DAL SD SD06 0 0005 Lab Matrix Spike DAL SD SD07 0 0000 3 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 4 1.1120 1.1575 1.1151 1.1149 1.1114 1.1265 1.1240 1.1478 1.1431 1.2214 1.1146 1.1495 1.1614 1.1311 1.1571 1.1001 1.1012 1.0293 1.1051 1.1211 1.1214 1.0963 1.1424 1.1753 1.0851 1.1187 1.1298 1.6452 1.4694 1.5622 1.8341 1.9958 1.4909 1.5330 1.3529 1.5496 1.9761 1.9316 1.7663 1.5252 1.5505 1.5766 1.5533 1.5120 1.9960 2.0313 1.4837 1.5098 2.1775 1.9464 1.8761 2.0968 1.8726 1.7666 1.7565 1.9126 1.6531 2.1054 2.0318 1.9613 2.1282 2.1432 2.8010 1.6305 Spike ID 5 10 005-167 10 005-167 10 005-167 10 005-167 10 005-166 10 005-166 10 005-166 10 005-165 10 005-165 10 005-165 10 006-7 10 006-7 10 005-164 10 005-164 10 005-164 10 005-163 10 005-163 10 005-163 Spike Volume (uL) Internal Internal Standard StandardV Surrogate ID olume Spike ID (uL) Surrogate Spike Volume (uL) PFBS PFBS Spike Spike ID Volume (UL> L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tr a c tio n Solvent Sonicate Centrifuge Volume 1 hr (mL) 6 7 8 9 10 11 12 13 14 15 16 20 10 006-9 30 10 005-133 20 50 10 006-9 30 10 005-133 50 75 10 006-9 30 10 005-133 75 100 10 006-9 30 10 005-133 100 25 10 006-9 30 10 005-132 25 50 10 006-9 30 10 005-132 50 100 10 006-9 30 10 005-132 100 25 10 006-9 30 10 006-002 25 50 10 006-9 30 10 006-002 50 100 10 006-9 30 10 006-002 100 20 10 006-9 30 10 006-002 200 50 10 006-9 30 10 006-002 500 17 18 19 Comments 20 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 3M Study GLP10-01-02 Interim Report 05 Page1oi 3 Page 121 of 96 'nV GLP10-01-02-05 ETS-8-053 Sample ID Sample Descrpton Soil Maxtrix Soil Weight ID Used (g) 1 GLP10-01-02-05-015 Dup GLP10-01-02-05-015 LMS GLP10-01-02-05-016 GLP10-01-02-05-016 Dup GLP10-01-02-05-016 LMS GLP10-01 -02-05-017 GLP10-01-02-05-017 Dup GLP10-01-02-05-017 LMS GLP10-01-02-05-018 GLP10-01-02-05-018 Dup GLP10-01 -02-05-018 LMS GLP10-01-02-05-019 GLP10-01-02-05-019 Dup GLP10-01-02-05-019 LMS GLP10-01 -02-05-021 GLP10-01 -02-05-021 Dup GLP10-01 -02-05-021 LMS GLP10-01-02-05-022 GLP10-01-02-05-022 Dup GLP10-01-02-05-022 LMS GLP10-01 -02-05-023 GLP10-01-02-05-023 Dup GLP10-01-02-05-023 LMS GLP10-01-02-05-024 GLP10-01-02-05-024 Dup GLP10-01-02-05-024 LMS GLP 10-01-02-05-025 GLP 10-01-02-05-025 Dup GLP 10-01-02-05-025 LMS GLP10-01 -02-05-026 GLP10-01-02-05-026 Dup GLP10-01-02-05-026 LMS GLP10-01-02-05-027 GLP10-01-02-05-027 Dup GLP10-01-02-05-027 LMS GLP10-01-02-05-028 GLP10-01-02-05-028 Dup GLP10-01-02-05-028 LMS GLP10-01 -02-05-029 GLP10-01-02-05-029 Dup GLP10-01-02-05-029 LMS GLP10-01-02-05-030 GLP10-01 -02-05-030 Dup GLP10-01-02-05-030 LMS GLP10-01 -02-05-031 GLP10-01-02-05-031 Dup GLP10-01 -02-05-031 LMS GLP10-01-02-05-032 GLP10-01-02-05-032 Dup GLP10-01-02-05-032 LMS GLP10-01-02-05-033 GLP10-01-02-05-033 Dup GLP10-01-02-05-033 LMS GLP10-01-02-05-034 GLP10-01-02-05-034 Dup GLP10-01-02-05-034 LMS GLP10-01-02-05-035 GLP10-01-02-05-035 Dup GLP10-01-02-05-035 LMS G LP 10-01-02-05-036 GLP10-01-02-05-036 Dup GLP10-01-02-05-036 LMS G LP 10-01-02-05-037 GLP10-01-02-05-037 Dup 2 DAL SD SD07 0 0000 Duplicate DAL SD SD07 0 0000 Lab Matrix Spike DAL SD SD07 0 0005 DAL SD SD07 0 0005 Duplicate DAL SD SD07 0 0005 Lab Matrix Spike DAL SD SD08 0 0000 DAL SD SD08 0 0000 Duplicate DAL SD SD08 0 0000 Lab Matrix Spike DAL SD SD08 DB 0000 DAL SD SD08 DB 0000 Duplicate DAL SD SD08 DB 0000 Lab Matrix Spike DAL SD SD08 0 0005 DAL SD SD08 0 0005 Duplicate DAL SD SD08 0 0005 Lab Matrix Spike DAL SD SD09 0 0000 DAL SD SD09 0 0000 Duplicate DAL SD SD09 0 0000 Lab Matrix Spike DAL SD SD09 0 0005 DAL SD SD09 0 0005 Duplicate DAL SD SD09 0 0005 Lab Matrix Spike DAL SD SD10 0 0000 DAL SD SD10 0 0000 Duplicate DAL SD SD10 0 0000 Lab Matrix Spike DAL SD SD10 0 0005 DAL SD SD10 0 0005 Duplicate DAL SD SD10 0 0005 Lab Matrix Spike DAL SD SD11 0 0000 DAL SD SD11 0 0000 Duplicate DAL SD SD11 0 0000 Lab Matrix Spike DAL SD SD11 0 0005 DAL SD SD11 0 0005 Duplicate DAL SD SD11 0 0005 Lab Matrix Spike DAL SD SD12 0 0000 DAL SD SD12 0 0000 Duplicate DAL SD SD12 0 0000 Lab Matrix Spike DAL SD SD12 DB 0000 DAL SD SD12 DB 0000 Duplicate DAL SD SD12 DB 0000 Lab Matrix Spike DAL SD SD12 0 0005 DAL SD SD12 0 0005 Duplicate DAL SD SD12 0 0005 Lab Matrix Spike DAL SD SD 13 0 0000 DAL SD SD13 0 0000 Duplicate DAL SD SD13 0 0000 Lab Matrix Spike DAL SD SD13 0 0005 DAL SD SD13 0 0005 Duplicate DAL SD SD13 0 0005 Lab Matrix Spike DAL SD SD14 0 0000 DAL SD SD14 0 0000 Duplicate DAL SD SD14 0 0000 Lab Matrix Spike DAL SD SD14 0 0005 DAL SD SD14 0 0005 Duplicate DAL SD SD14 0 0005 Lab Matrix Spike DAL SD SD15 0 0000 DAL SD SD15 0 0000 Duplicate DAL SD SD15 0 0000 Lab Matrix Spike DAL SD SD15 0 0005 DAL SD SD15 0 0005 Duplicate DAL SD SD15 0 0005 Lab Matrix Spike DAL SD SD16 0 0000 DAL SD SD16 0 0000 Duplicate DAL SD SD 16 0 0000 Lab Matrix Spike DAL SD SD 16 DB 0000 DAL SD SD16 DB 0000 Duplicate 3 4 1.5687 1.5860 1.8495 1.3995 1.5361 1.6988 1.5055 1.4810 1.8377 1.6169 1.5532 1.4855 1.6127 1.6737 1.6922 1.6586 1.5092 1.9397 1.9852 1.4011 1.4962 1.6585 1.5420 2.1159 1.5496 2.1655 1.7638 1.8130 1.6875 1.5516 1.7726 1.6543 1.5245 1.4150 1.6692 1.8212 1.6185 1.4277 1.5767 1.6677 1.7824 1,8818 1.7963 1.6779 2.0693 2.1050 1.9822 1.3503 1.4301 1.4272 1.9467 1.3991 1.6789 1.7344 1.6352 1.4012 1.1614 1.1970 1.1909 1.2596 1.3751 1.5348 1.3220 1.4040 Spike ID 5 Spike Volume (uL) Internal Internal Standard StandardV Surrogate ID olume Spike ID (uL) Surrogate Spike Volume (uL) PFBS PFBS Spike Spike ID Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tra c tio n Solvent Sonicate Centrifuge Volume 1 h r (mL) 67 8 9 10 11 12 13 14 15 16 17 18 19 Comments 20 3M Study GLP10-01-02 Interim Report 05 Page 2 of 3 Page 122 of 962 GLP10-01 -02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID 1 GLP10-01-02-05-037 LMS GLP10-01-02-05-038 GLP10-01-02-05-038 Dup GLP10-01-02-05-038 LMS GLP10-01-02-05-039 GLP 10-01 -02-05-039 Dup GLP10-01-02-05-039 LMS GLP10-01-02-05-040 GLP10-01-02-05-040 Dup GLP10-01-02-05-040 LMS MB-101021-07 MB-101021-08 MB-101021-09 2 DAL SD SD16 DB 0000 Lab Matrix Spike DAL SD SD16 0 0005 DAL SD SD16 0 0005 Duplicate DAL SD SD16 0 0005 Lab Matrix Spike DAL SD SD17 0 0000 DAL SD SD17 0 0000 Duplicate DAL SD SD17 0 0000 Lab Matrix Spike DAL SD SD17 0 0005 DAL SD SD17 0 0005 Duplicate DAL SD SD17 0 0005 Lab Matrix Spike Method Blank 5q w/ IS for Dilutions Method Blank 5q w/ IS for Dilutions Method Blank 5q w/ IS for Dilutions 3 10 005-122 10 005-122 10 005-122 4 1.3933 1.5776 1.4068 1.3746 1.4910 1.2794 1.2874 1.2654 1.5152 1.3045 5.0525 5.0114 5.0803 5 Col 3 & 4: Balance ID: 900 Col 5 & 6: 10/25/10 mmh -- -n . GLP10-01-02-05-13 to 040 10/26/10 mmh / /u ^ (o /0 Col 7 & 8: Col 9 & 10: Spike Volume (UL) Internal Internal Standard StandardV Surrogate ID olume Spike ID <uL) Surrogate Spike Volume (UL) PFBS PFBS Spike Spike ID Volume (UL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tr a c tio n Solvent Sonicate Centrifuge Volume 1 hr (mL) 67 8 9 10 11 12 13 14 15 16 17 18 19 Comments 20 10 006-9 10 006-9 10 006-9 150 10 005-132 150 10 005-132 150 10 005-132 Col 11: 150 150 150 Col 12: Col 13 & 14: Pipette ID: 1093467 Col 15 & 16: Pipette ID: 1093467 40 40 40 Col 17: Extraction Solvent ID: 09 004-11i Col 13: Col 18: Sonicator ID: QEJ100595003 Col 14: 3M Study GLP10-01-02 Interim Report 05 Page 3 of 3 Page 123 of 962 ETS-8-053 S a m p le ID Sam ple Description Soil Maxtrix Soil W eight ID Used (g) Spike ID 1 EC-101025-01 EC-101025-02 EC-101025-03 EC-101025-04 EC-101025-05 EC-101025-06 EC-101025-07 EC-101025-08 EC-101025-09 E C -10 10 25 -1 0 E C -1 0 1 0 2 5 -1 1 E C -10 10 25 -1 2 M B-1 01 02 50 1 MB-101 02 50 2 MB-101025-03 MB-101025-04 MB-101025-05 MB-101025-06 LCS-101025-01 LCS-101025-02 LCS-101025-03 LCS-101025-04 LCS-101025-05 LCS-101025-06 GLP10-01 -02-05-001 GLP10-01-02-05-001 Dup GLP10-01-02-05-001 LMS GLP10-01-02-05-002 GLP10-01-02-05-002 Dup GLP10-01-02-05-002 LMS GLP10-01-02-05-003 GLP10-01-02-05-003 Dup GLP10-01-02-05-003 LMS GLP10-01-02-05-004 GLP10-01-02-05-004 Dup GLP10-01-02-05-004 LMS GLP10-01-02-05-005 GLP10-01-02-05-005 Dup GLP10-01-02-05-005 LMS GLP10-01-02-05-006 GLP10-01-02-05-006 Dup GLP10-01-02-05-006 LMS GLP10-01-02-05-007 GLP10-01-02-05-007 Dup GLP10-01-02-05-007 LMS GLP10-01-02-05-009 GLP10-01-02-05-009 Dup GLP10-01-02-05-009 LMS GLP10-01-02-05-010 GLP10-01-02-05-010 Dup GLP10-01-02-05-010 LMS GLP10-01-02-05-011 GLP10-01-02-05-011 Dup GLP10-01-02-05-011 LMS GLP10-01-02-05-012 GLP10-01-02-05-012 Dup GLP10-01-02-05-012 LMS GLP10-01-02-05-013 GLP10-01-02-05-013 Dup GLP10-01-02-05-013 LMS GLP10-01 -02-05-014 GLP10-01 -02 -05-014 Dup GLP10-01-02-05-014 LMS GLP10-01-02-05-015 GLP10-01-02-05-015 Dup GLP10-01-02-05-015 LMS GLP10-01-02-05-016 GLP10-01-02-05-016 Dup GLP10-01-02-05-016 LMS GLP10-01-02-05-017 GLP10-01-02-05-017 Dup GLP10-01-02-05-017 LMS GLP10-01-02-05-018 GLP10-01 -02 -05-018 Dup GLP10-01-02-05-018 LMS 2 0.2 ng Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 ng Extracted Curve Point 1 ng Extracted Curve Point 2.5 ng Extracted Curve Point 5 ng Extracted Curve Point 10 ng Extracted Curve Point 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 ng Extracted Curve Point 2 0 0 ng Extracted Curve Point 500 ng Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 ng LC S in TCR-842 3 ng LC S in TCR-842 3 ng LC S in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 DAL SD TRIP1 0 100624 DAL SD TRIP1 0 100624 Duplicate DAL SD TRIP1 0 100624 Lab Matrix Spike DAL SD SD01 0 0000 DAL SD SD01 0 0 000 Duplicate DAL SD SD01 0 0 000 Lab Matrix Spike DAL SD SD01 0 0005 DAL S D SD01 0 0005 Duplicate DAL S D SD01 0 0005 Lab Matrix Spike DAL SD SD02 0 0000 DAL S D SD 02 0 0000 Duplicate DAL S D SD 02 0 0000 Lab Matrix Spike DAL SD SD02 0 0005 DAL SD SD 02 0 0005 Duplicate DAL SD SD02 0 0 005 Lab Matrix Spike DAL SD SD03 0 0000 DAL SD SD03 0 0 000 Duplicate DAL SD SD03 0 0 000 Lab Matrix Spike DAL SD SD03 0 0005 DAL SD SD03 0 0 005 Duplicate DAL S D SD03 0 0005 Lab Matrix Spike DAL SD SD04 0 0000 DAL S D SD04 0 0000 Duplicate DAL S D SD04 0 0000 Lab Matrix Spike DAL SD SD04 0 0005 DAL S D SD04 0 0005 Duplicate DAL S D SD04 0 0 005 Lab Matrix Spike DAL SD SD05 0 0000 DAL SD SD05 0 0 000 Duplicate DAL SD SD05 0 0 000 Lab Matrix Spike DAL SD SD05 0 0005 DAL S D SD05 0 0 005 Duplicate DAL SD SD05 0 0005 Lab Matrix Spike DAL SD SD06 0 0000 DAL S D SD06 0 0000 Duplicate DAL S D SD06 0 0000 Lab Matrix Spike DAL SD SD06 0 0005 DAL SD SD06 0 0005 Duplicate DAL SD SD06 0 0005 Lab Matrix Spike DAL SD SD07 0 0000 DAL SD SD 07 0 0000 Duplicate DAL SD SD 07 0 0000 Lab Matrix Spike DAL SD SD07 0 0005 DAL S D SD 07 0 0005 Duplicate DAL S D SD 07 0 0005 Lab Matrix Spike DAL SD SD08 0 0000 DAL S D SD 08 0 0000 Duplicate DAL S D SD08 0 0000 Lab Matrix Spike DAL SD SD08 DB 0000 DAL SD SD 08 DB 0000 Duplicate DAL SD SD 08 DB 0000 Lab Matrix Spike 3 10005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10005-122 4 1 .1 1 2 0 1.1575 1.1151 1.1149 1 .1 1 1 4 1.1265 1.1240 1.1478 1.1431 1 2214 1.1146 1 1495 1.1614 1.1311 1.1571 1.1001 1.1012 1.0293 1.1051 1.1211 1 .1 2 1 4 1 0963 1 .1 4 2 4 1.1753 1 0851 1 .1 1 8 7 1 .1 2 9 8 1 .6 4 5 2 1 4694 1 5622 1.8341 1 .9 9 5 8 1 4909 1.5330 1 .3 5 2 9 1.5496 1.9761 1.9316 1 .7 6 6 3 1 5252 1 .5 5 0 5 1 .5 7 6 6 1 .5 5 3 3 1.5120 1 .9 9 6 0 2.0313 1 .4 8 3 7 1 5098 2.1775 1 9464 1 8761 2 0968 1 .8 7 2 6 1 7666 1 7565 1 .9 1 2 6 1.6531 5 10 005-167 10 005-167 10 005-167 10 005-167 10 005-166 10 005-166 10 005-166 10 005-165 10 005-165 10 005-165 10 006-7 10 006-7 10 005-164 10 005-164 10 005-164 10 005-163 10 005-163 10 005-163 S p ik e V o lu m e (uL) In te r n a l In te rn a l Standard ID StandardV olume (uL) Surrogate Spike ID Surrogate S p ik e Volum e (uL) PFBS Spike ID PFBS Spike Vo lu m e (uL) 67 20 10 006-9 50 10 006-9 75 10 006-9 100 10 006-9 25 10 006-9 50 10 006-9 100 10 006-9 25 10 006-9 50 10 006-9 100 10 006-9 20 10 006-9 50 10 006-9 8 9 10 30 10 005-133 20 30 10 005-133 50 30 10 005-133 75 30 10 005-133 100 30 10 005-132 25 30 10 005-132 50 30 10 005-132 100 30 10 006-002 25 30 10 006-002 50 30 10 006-002 100 30 10 006-002 200 30 10 006-002 500 11 12 L-PFHxS Spike ID 13 L-PFHxS Spike Volum e (uL) 14 L-PFOS Spike ID 15 L-PFOS Sp ik e Volume (uL) Extraction S o lv e n t V o lu m e (mL) Sonicate 1 hr Centrifuge 16 17 18 19 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 005-132 30 30 10 006-9 30 10 0 0 5 1 3 2 30 Comments 20 3M Study GLP10-01-02 Interim Report 05 Page 1 of 2 Page 124 o',96 2 GLP10-01-01-05 ETS-6-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used(g) 1 GLP10-01-02-05-019 GLP10-01 -02-05-019 Duo GLP10-01-02-05-019 LMS GLP10-01-02-05-021 GLP10-01-02-05-021 Duo GLP10-01-02-05-021 LMS GLP10-01-02-05-022 GLP10-01-02-05-022 Dud GLP10-01-02-05-022 LMS GLP10-01-02-05-023 GLP10-01-02-05-023 Dud GLP10-01-02-05-023 LMS GLP10-01-02-05-024 GLP10-01-02-05-024 Duo GLP10-01-02-05-024 LMS GLP1O-01-02-05-025 GLP10-01 -02-05-025 Dud GLP10-01-02-05-025 LMS GLP10-01-02-05-026 GLP10-01-02-05-026 Dup GLP10-01-02-05-026 LMS GLP10-01-02-05-027 GLP10-01-02-05-027 Dup GLP10-01-02-05-027 LMS GLP10-01-02-05-028 GLP10-01-02-05-028 Dud GLP10-01-02-05-028 LMS GLP10-01-02-05-029 GLP10-01-02-05-029 Dud GLP10-01-02-05-029 LMS GLP 10-01-02-05-030 GLP10-01-02-05-030 Dud GLP10-01-02-05-030 LMS G LP10-01-02-05-031 GLP10-01-02-05-031 Dup GLP10-01-02-05-031 LMS GLP10-01-02-05-032 GLP1O-01-02-05-032 Dud GLP10-01-02-05-032 LMS GLP10-01-02-05-033 GLP10-01-02-05-033 Dud GLP10-01-02-05-033 LMS GLP10-01-02-05r034 GLP10-01-02-05-034 Dud GLP10-01-02-05-034 LMS GLP10-01-02-05-035 GLP10-01-02-05-035 Dud GLP10-01-02-05-035 LMS GLP10-01-02-05-036 GLP10-01-02-05-036 Dud GLP10-01-02-05-036 LMS GLP10-01-02-05-037 GLP10-01-02-05-037 Dud GLP10-01-02-05-037 LMS GLP1O-01-02-05-038 GLP10-01-02-05-038 Dud GLP10-01-02-05-038 LMS GLP10-01-02-05-039 GLP1O-01-02-05-039 Duo GLP10-01-02-05-039 LMS GLP10-01-02-05-040 GLP10-01-02-05-040 Dud GLP10-01-02-05-040 LMS MB-101021-07 MB-101021-08 MB-101021-09 DAL SD SD08 0 0005 DAL SD SD08 0 0005 Duplicate DAL SD SD08 0 0005 Lab Matrix Spike DAL SD SD09 0 0000 DAL SD SD09 0 0000 Duplicate DAL SD SD09 0 0000 Lab Matrix Spike DAL SD SD09 0 0005 DAL SD SD09 0 0005 Duplicate DAL SD SD09 0 0005 Lab Matrix Spike DAL SD SD10 0 0000 DAL SD SD10 0 0000 Duplicate DAL SD SD10 0 0000 Lab Matrix Spike DAL SD SD10 0 0005 DAL SD SD10 0 0005 Duplicate DAL SD SD10 0 0005 Lab Matrix Spike DAL SD SD11 0 0000 DAL SD SD11 0 0000 Duplicate DAL SD SD11 0 0000 Lab Matrix SDike DAL SD SD11 0 0005 DAL SO SD11 0 0005 Duplicate DAL SD SD11 0 0005 Lab Matrix Spike DAL SD SD12 0 0000 DAL SD SD12 0 0000 Duplicate DAL SD SD12 0 0000 Lab Matrix Spike DAL SD SD12 OB 0000 DAL SD SD12 DB 0000 Duplicate DAL SD SD12 DB 0000 Lab Matrix Spike DAL SD SD12 0 0005 DAL SD SD12 0 0005 Duplicate DAL SD SD12 0 0005 Lab Matrix Spike DAL SD SD13 0 0000 DAL SD SD13 0 0000 Duplicate DAL SD SD13 0 0000 Lab Matrix Spike DAL SD SD13 0 0005 DAL SD SD13 0 0005 Duplicate DAL SD SD13 0 0005 Lab Matrix Spike DAL SD SD14 0 0000 DAL SD SD14 0 0000 Duplicate DAL SD SD14 0 0000 Lab Matrix Spike DAL SD SD14 0 0005 DAL SD SD14 0 0005 Duplicate DAL SD SD14 0 0005 Lab Matrix Spike DAL SD SD15 0 0000 DAL SD SD15 0 0000 Duplicate DAL SD SD15 0 0000 Lab Matrix Spike DAL SD SD15 0 0005 DAL SD SD15 0 0005 Duplicate DAL SD SD15 0 0005 Lab Matrix Spike DAL SD SD16 0 0000 DAL SD SD16 0 0000 Duplicate DAL SD S 0 16 0 0000 Lab Matrix Spike DAL SD SD16DB0000 DAL SD SD16 DB 0000 Duplicate DAL SD SD16 DB 0000 Lab Matrix Spike DAL SD SD16 0 0005 DAL SD SD16 0 0005 Duplicate DAL SD SD16 0 0005 Lab Matrix Spike DAL SD SD17 0 0000 DAL SD SD17 0 0000 Duplicate DAL SD SD17 0 0000 Lab Matrix Spike DAL SD SD17 0 0005 DAL SD SD17 0 0005 Duplicate DAL SD SD17 0 0005 Lab Matrix Spike Method Blank 5a w/ IS for Dilutions Method Blank 5a w/ IS for Dilutions Method Blank 5a w/ IS for Dilutions Col 3 & 4: Balance ID: 900 3 10005-122 10 005-122 10 005-122 4 Spike ID Spike Volume (uL) Internal Internal Standard ID StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID 6 7 8 9 10 11 12 13 5 ' -' V. L-PFHxS Spike Volume (uL) 14 L-PFOS Spike ID 15 L-PFOS Spike Volume (uL) Extraction Solvent Volume (mL) Sonicate 1 hr C e n tr ifu g e 16 17 18 * 19 -t - -'- ! <* ' . '. S 10 006 9 150 10 005-132 150 10 006-9 150 10 005-132 150 10 OOb-9 .::S::150-V::' 10 005-13? 150 t' , v -, - ,- Col 13 & 14: Pipette ID: 1093467 Col 15 & 16: Pipette ID: 1093467 5 S'o - 40 X 4U -r Col 17: Extraction Solvent ID: 09 004-116 Col 13: Col 16: Sonicator ID: QEJ100595003 Col 14: Comments 20. 3M Study GLP10-01-02 Interim Report .05.' . ' . .. .. , ' Page 2 of 2 '' . ' . . . Page 125 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S a m p le s e t ID # Lim s # N /A G LP10-01-02-05 S am p le D escription: D ecatur S oils IN T E R N A L C H A IN O F C U S T O D Y # 3M Sample IDs Out: storage ID/ ---InitJdate ln: storage ID Init./date Out: storage ID Ipitjdate In: storage ID ^-inijJdate Comments/InltJdate 1 G LP10-01-01-05-001 O Y ? -- f ( 2 G LP10-01-01-05-002 ' / a) K ~ f /o & > r7 < -/ /o -d -ip 'lis 3 G LP 10-01 -01-05-003 4 G LP10-01-01-05-004 5 G LP 10-01-01-05-005 6 G L P 10-01 -01 -0 5 -0 0 6 fJo . 1 /_______ _______ _____ / _____ 7 G LP10-01-01-05-007 8 G LP10-01-01-05-009 9 G LP 10-01 -01-05-010 1 0 G LP10-01-01-05-011 11 G LP 10-01-01-05-012 1 2 G LP 10-01-01 -05-013 13 G LP 10-01-01-05-014 14 G LP 10-01-01-05-015 15 G LP 10-01-01-05-016 16 G LP10-01-01-05-017 17 G LP 10-01-01-05-018 18 G LP 10-01-01 -05-019 19 G LP 10-01-01-05-021 2 0 G LP10-01-01-05-022 21 G LP10-01-01-05-023 r 2 2 G LP10-01-01-05-024 23 G LP 10-01-01 -05-025 24 G LP 10-01 -01-05-026 25 G LP10-01-01-05-027 26 G LP10-01-01-05-028 27 G LP10-01-01-05-029 28 G LP 10-01-01-05-030 29 G LP 10-01-01-05-031 30 G LP10-01-01-05-032 31 G L P 1 0 -0 1 -0 1 -0 5 -0 3 3 ---- ------ -^ \ \ <aJr~ -- \ J ----------- \ \ \ \ \ \ --- -- 1 -J 3M Study GLP10-01-02 Interim Report 05 Page 1 of 2 Page 126 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Ums # N/A GLP10-01-02-05 Sample Description: Decatur Soils IN T E R N A L C H A IN O F C U S T O D Y # 3M Sample IDs Quti-storage ID InitJdate ln: storage ID jJaiJJdate Out: storage ID InitJdate In: storage ID ^-inUJdate 32 G LP10-01-01-05-034 . 33 G LP10-01-01-05-035 ^ 34 G LP10-01-01 -05-036 35 G LP 10-01-01-05-037 / jT l - / /)t --/ r___ _______ ___________ I_____ __ s fe -/ ) *! 00 / / 36 G LP10-01-01-05-038 37 G LP10-01-01-05-039 38 G LP10-01-01-05-040 On / _____ ______________ ___ v -- -- ri _____ ^ . Comments/lnitJdate 3M Study GLP10-01-02 Interim Report 05 Page 2 of 2 Page 127 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sam ple Description Soil Maxtrix S oil W eight ID Used (g) Spike ID Spike Volume (UL) Internal S ta n d a rd ID Internal StandardV o lum e (uL) Surrogate Spike ID Surrogate Spike Volume (uL> PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tra c tio n Solvent Volume (mL) Sonicate 1 hr Centrifuge C o m m e n ts 1 EC-101116-01 EC-101116-02 EC-101116-03 EC-101116-04 EC-101116-05 EC-101116-06 EC-101116-07 EC-101116-08 EC-101116-09 EC-101116-10 EC-101116-11 EC-101116-12 MB-101116-01 MB-101116-02 MB-101116-03 MB-101116-04 MB-101116-05 MB-101116-06 LCS-101116-01 LCS-101116-02 LCS-101116-03 LCS-101116-04 LCS-101116-05 LCS-101116-06 G L P 10-01-02-05-041 GLP10-01 -02-05-041 Dup GLP10-01 -02-05-041 LMS GLP10-01 -02-05-042 GLP10-01-02-05-042 Dup GLP10-01-02-05-042 LMS GLP10-01-02-05-043 GLP10-01-02-05-043 Dup GLP10-01-02-05-043 LMS G L P 10-01-02-05-044 GLP10-01-02-05-044 Dup GLP10-01-02-05-044 LMS G L P 10-01-02-05-045 GLP10-01 -02-05-045 Dup GLP10-01 -02-05-045 LMS G L P 10-01-02-05-046 GLP10-01-02-05-046 Dup GLP10-01-02-05-046 LMS G L P 10-01-02-05-047 GLP10-01 -02-05-047 Dup GLP10-01-02-05-047 LMS G L P 10-01-02-05-048 GLP10-01 -02-05-048 Dup GLP10-01-02-05-048 LMS G L P 10-01-02-05-049 GLP10-01-02-05-049 Dup GLP10-01-02-05-049 LMS G L P 10-01-02-05-050 GLP10-01-02-05-050 Dup GLP10-01-02-05-050 LMS GLP10-01 -02-05-051 GLP10-01-02-05-051 Dup GLP10-01 -02-05-051 LMS G L P 10-01-02-05-052 GLP10-01 -02-05-052 Dup GLP10-01 -02-05-052 LMS GLP10-01 -02-05-054 2 0.2 ng Extracted Curve Point 0.5 nq Extracted Curve Point 0.75 nq Extracted Curve Point 1 ng Extracted Curve Point 2.5 nq Extracted Curve Point 5 ng Extracted Curve Point 10 nq Extracted Curve Point 25 nq Extracted Curve Point 50 nq Extracted Curve Point 100 nq Extracted Curve Point 200 ng Extracted Curve Point 500 no Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w / IS Method Blank 5 w/ IS Method Blank 6 w / IS 3 ng LCS in TCR-842 3 nq LCS in TCR-842 3 ng LCS in TCR-842 30 nq LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 DAL SS SS01 0 0000 DAL SS SS01 0 0000 Duplicate DAL SS SS01 0 0000 Lab Matrix Spike DAL SS SS01 0 0005 DAL SS SS01 0 0005 Duplicate DAL SS SS01 0 0005 Lab Matrix S pite DAL SS SS02 0 0000 DAL SS SS02 0 0000 Duplicate DAL SS SS02 0 0000 Lab Matrix Spike DAL SS SS02 0 0005 DAL SS SS02 0 0005 Duplicate DAL SS SS02 0 0005 Lab Matrix Spike DAL SS SS03 0 0000 DAL SS SS03 0 0000 Duplicate DAL SS SS03 0 0000 Lab Matrix Spike DAL SS SS03 0 0005 DAL SS SS03 0 0005 Duplicate DAL SS SS03 0 0005 Lab Matrix Spi'C DALSS SS03 DB 0005 DAL SS SS03 DB 0005 Duplicate DAL SS SS03 DB 0005 Lab Matrix Spike DAL SS SS04 0 0000 DAL SS SS04 0 0000 Duplicate DAL SS SS04 0 0000 Lab Matrix S pite DAL SS SS04 0 0005 DAL SS SS04 0 0005 Duplicate DAL SS SS04 0 0005 Lab Matrix S pite DALSS TRIP1 0 0000 DAL SS TRIP1 0 0000 Duplicate DAL SS TRIP1 0 0000 Lab Matrix Spike DAL SS SS05 0 0000 DAL SS SS05 0 0000 Duplicate DAL SS SS05 0 0000 Lab Matrix Spie DAL SS SS05 0 0005 DAL SS SS05 0 0005 Duplicate DAL SS SS05 0 0005 Lab Matrix Spi*c DAL SS SS06 0 0000 3 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 m m m sm sm s mmmm r " i. . .. KM M l . *i .- | M M r a w * r -] | ,5,' P | ' |I 4 1.1188 1.1358 1.0903 1.0883 1.1436 1.1230 1.1271 1.1098 1.0999 1.1434 1.1247 1.1440 1.1494 1.0898 1.1131 1.1323 1.1361 1.1170 1.1303 1.1435 1.1372 1.1305 1.1397 1.1406 1.1942 1.0941 1.3218 2.2162 1.7674 1.4949 1.3157 1.0866 1.2340 1.6277 1.5527 1.5266 1.3271 1.5201 1.3935 2.3556 1.8211 2.0447 1.6152 1.6050 1.5940 1.0411 0.9724 1.3186 1.0339 1.1532 1.1408 1.0997 1.1280 um 1.0336 0.9169 1.0715 0.9833 1.0003 1.1670 1.0830 5 10 005-167 10 005-167 10 005-167 10 005-167 10 005-166 10 005-166 10 005-166 10 005-165 10 005-165 10 005-165 10 006-7 10 006-7 67 20 1 0 006-16 50 1 0 006-16 75 1 0 006-16 100 1 0 006-16 25 1 0 006-16 50 1 0 006-16 100 1 0 006-16 25 1 0 006-16 50 1 0 006-16 100 1 0 006-16 20 1 0 006-16 50 1 0 006-16 : ' " !M ` = .-f < C "***- - 10 005-164 10 005-164 10 005-164 10 005-163 10 005-163 10 005-163 30 30 30 30 30 30 K fS ilS S K M B B S . . .S . ' iV ! - * ' . t " " v* j ~ , . *- r 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 10006-16 10006-16 10006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 10006-16 10006-16 1 0 006-16 1 0 006-16 10006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 10006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 10006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 89 30 10 005-133 30 10 005-133 30 10 005-133 30 10 005-133 30 10 005-132 30 10 005-132 30 10 005-132 30 10 006-002 30 10 006-002 30 10 006-002 30 10 006-002 30 10 006-002 5 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 10 1 1 1 2 13 14 15 16 20 M - 50 i--F / ,, vf- 75 100 mm am m 5 * gi ^ -* , 25 - 50 ,, v u -J" . .v-es f r SjVAJ. vl f 10 0 V - H'" - s 25 -Sr. v.. 50 s ' *** 10 0 'S- 200 ' 1 - - 500 - . v*. s* .'1 - . '- L - -3, ................ -' - ' - - , - i. 30 30 f TU r < ' . ,'.r #!*. 30 30 v- - - -a -- * 30 ET-- 5, - 30 i l 30 - - > -i fJ rK . . . . . - 30 ^ - mmmm k* ' 30 ' ; >o'> 'A ' * 30 m m m m U f f l l i l ; /- i.i* 30 r.V i . w . . c -ii- re . 30 10 007-3-4 20 10 007-4-4 10 0 10 007-5-2 10 0 30 30 a . _ 30 10 007-3-4 20 10 007-4-4 1 10 007-5-2 100 30 _ v&sm,-- V 30 ; 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 10 0 30 30 - * - m m iiTKSR ' 30 10 007-3-4 10 0 10 007-4-3 100 10 007-5-2 100 30 .i \. - - r 30 . * ' tm 30 10 007-3-4 10 0 10 007-4-2 50 10 007-5-1 50 30 . . i - 30 * * * ** ***** " -- ^ 30 10 007-3-4 10 0 10 007-4*2 50 10 007-5-1 50 30 -j w v ' 30 . . . . - - mmmm ~1 30 10 007-3-4 10 0 10 007-4-2 10 007-5-1 50 30 30 S S . aam m m m -. 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 50 30 30 m - m m amm s* ------ ^ ----- 1 --- mmmm. 30 10 007-3-4 20 10 007-4-4 10 0 10 007-5-2 50 30 m m sm m -TJ-.JS -- 30 m M KSm - ......... 30 10 007-3-4 20 10007-4-4 20 10 007-5-4 20 30 3 - * - Wm> mmmm i 30 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 200 30 30 * 30 10 007-3-4 100 10 007-4-3 10 0 10 007-5-1 50 30 17 8 8 8 8 8 6 8 8 8 8 6 8 8 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 8 6 6 18 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh Q 19 20 - m m h * , _ iiiih m h ia i u m rn m m r. mmh51- -"mmh*.' w m m m h ^ k~-3h~^ -;? m m h C SS w '^-im m hP ? 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" 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 Page'128(10f 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix S oil W eight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal StandardV o lum e (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL> L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume (m L) S o n ic a te 1 hr C e n trifu g e Comments 1 GLP10-01-02-05-054 Dup GLP10*01-02-05-054 LMS G LP 10-01-02-05-055 GLP10-01-02-05-055 Dup GLP10-01-02-05-055 LMS G LP 10-01-02-05-056 GLP10-01-02-Q5-056 Dup GLP10-01-02-05-056 LMS G LP 10*01-02-05-057 GLP10-01-02-05-057 Dup GLP10-01-02-05-057 LMS G LP 10-01-02-05-058 GLP10-01-02-05-058 Dup GLP10-01-02-05-058 LMS GLP10-01-02-05-059 GLP10-01-02-05-059 Dup GLP10-01-02-05-059 LMS G LP 10-01-02-05-060 GLP10-01-02-05-060 Dup GLP10-01-02-05-060 LMS G LP 10-01-02-05-061 GLP10-01-02-05-061 Dup GLP10-01-02-05-061 LMS GLP10-01-02-05-062 GLP10-01-02-05-062 Dup GLP10-01-02-05-062 LMS G LP 10-01-02-05-063 GLP10-01-02-05-063 Dup GLP10-01-02-05-063 LMS G LP 10-01-02-05-064 GLP10-01-02-05-064 Dup GLP10-01-02-05-064 LMS G LP 10-01-02-05-065 GLP10-01-02-05-065 Dup GLP10-01-02-05-065 LMS G LP 10-01-02-05-066 GLP10-01-02-05-066 Dup GLP10-01-02-05-066 LMS G LP 10-01-02-05-067 GLP10*01-02-05-067 Dup GLP10-01-02-05-067 LMS G LP 10-01-02-05-068 GLP10-01-02-05-068 Dup GLP10-01-02-05-068 LMS GLP10-01-02-05-069 GLP10*01-02-05-069 Dup GLP10-01-02-05-069 LMS G LP10-01-02-05-070 GLP 10-01-02-05-070 Dup GLP10-01-02-05-070 LMS G L P 10-01-02-05-071 GLP10-01-02-05-071 Dup GLP 10-01-02-05-071 LMS GLP10-01-02-05-072 GLP 10-01-02-05-072 Dup GLP10-01-02-05-072 LMS GLP10-01-02-05-073 GLP 10-01-02-05-073 Dup GLP 10-01-02-05-073 LMS GLP10-01-02-05-074 GLP10-01-02-05-074 Dup 2 DAL SS SS06 0 0000 Duplicate DAL SS SS06 0 0000 Lab Matrix Spike DAL SS SS06 0 0005 DAL SS SS06 0 0005 Duplicate DAL SS SS06 0 0005 Lab Matrix Spike DAL SS SS06 DB 0005 DAL SS SS06 DB 0005 Duplicate DAL SS SS06 DB 0005 Lab Matrix S r DAL SS SS07 0 0000 DAL SS SS07 0 0000 Duplicate DAL SS SS07 0 0000 Lab Matrix Spike DAL SS SS07 0 0005 DAL SS SS07 0 0005 Duplicate DAL SS SS07 0 0005 Lab Matrix Spil e DAL SS SS08 0 0000 DAL SS SS08 0 0000 Duplicate DAL SS SS08 0 0000 Lab Matrix Spike DAL SS SS08 DB 0000 DAL SS SS08 DB 0000 Duplicate DAL SS SS08 DB 0000 Lab Matrix Spike DAL SS SS08 0 0005 DAL SS SS08 0 0005 Duplicate DAL SS SS08 0 0005 Lab Matrix Spike DAL SS SS09 0 0000 DAL SS SS09 0 0000 Duplicate DAL SS SS09 0 0000 Lab Matrix Spike DAL SS SS09 0 0005 DAL SS SS09 0 0005 Duplicate DAL SS SS09 0 0005 Lab Matrix Spike DAL SS GP01 0 0000 DAL SS GP01 0 0000 Duplicate DAL SS GP01 0 0000 Lab Matrix Spi- DAL SS GP01 0 0005 DAL SS GP01 0 0005 Duplicate DAL SS GP01 0 0005 Lab Matrix SpiDAL SS GP01 0 0020 DAL SS GP01 0 0020 Duplicate DAL SS GP01 0 0020 Lab Matrix Spike DAL SS GP01 0 0060 DAL SS GP01 0 0060 Duplicate DAL SS GP01 0 0060 Lab Matrix Spike DAL SS GP02 0 0000 DAL SS GP02 0 0000 Duplicate DAL SS GP02 0 0000 Lab Matrix Spike DAL SS GP02 0 0005 DAL SS GP02 0 0005 Duplicate DAL SS GP02 0 0005 Lab Matrix Spike DAL SS GP02 0 0020 DAL SS GP02 0 0020 Duplicate DAL SS GP02 0 0020 Lab Matrix Spike DAL SS GP02 DB 0020 DAL SS GP02 DB 0020 Duplicate DAL SS GP02 DB 0020 Lab Matrix Spike DAL SSGP02 0 0120 DAL SS GP02 0 0120 Duplicate DAL SS GP02 0 0120 Lab Matrix Spike DAL SS GP03 0 0000 DAL SS GP03 0 0000 Duplicate DAL SS GP03 0 0000 Lab Matrix Spike DAL SS GP03 0 0005 DAL SS GP03 0 0005 Duplicate 3 * - -- ' ,N . is ii iS is i * . -i -- . v -. MSBB : . r :4 --W * j, ' . -, - ey+let-+t-, v" , -m* j:' r "VSW ftVr.T *- * > "n ***ys- -* 4 1.1820 1.0853 1.1637 1.2 12 2 1.1286 1.1208 1.1301 1.1470 1.1920 1.1014 0.9852 1.3799 1.2233 1.2248 1.3989 1.3327 1.4664 1.3445 1.3477 1.3875 1.1974 1.1633 1.3542 1.0438 1.0690 1.1399 1.1509 1.1903 1.2035 1.1717 1.0665 1.3297 2.1050 2.0466 2.4711 1.4448 1.4586 1.5783 1.3694 1.5738 1.6761 1.3687 1.5391 1.3072 1.0942 1.4285 1.5102 1.4163 1.5968 1.6993 1.5718 2.1641 1.7320 1.2109 1.6107 1.2559 0.9906 1.1479 1.1484 1.1901 1.0154 5 67 10 006-16 nl 10 006-16 . -gs 10 006-16 M 10 006-16 10 006-16 . 10 006-16 10 006-16 J i l 10 006-16 K?, 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 rl 10 006-16 .. .& 10 006-16 - 1 - V 10 006-16 10 006-16 .; fig 10 006-16 10 006-16 10 006-16 4 10 006-16 ^ f-j 10 006-16 10 006-16 10 006-16 1 10 006-16 10 006-16 S U M * 2 10 006-16 3 . 10 006-16 10 006-16 'V ?-" 10 006-16 a ilH itliP lItl . N . 10 006-16 10 006-16 1, . V 10 006-16 . &*>'** " n 10 006-16 " 4.. 10 006-16 . .V 10 006-16 10 006-16 * 10 006-16 10 006-16 10 006-16 10 006-16 , 10 006-16 i # 'V 10 006-16 *. * -fSfc 10 006-16 t --J -a--* y s r 10006-16 10 006-16 10 006-16 10 006-16 - . - 4 ! 10 006-16 1, 10 006-16 - 10 006-16 Jkcs. > . s '- 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 . 5a 10 006-16 10 006-16 10 006-16 89 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 10 ' 11 12 13 14 15 16 30 30 10 007-3-4 20 10 007-4-4 10 0 10 007-5-2 50 30 30 - ........... l H H t u s s t a * .- 30 10 007-3-4 20 10007-4-4 2 0 10 007-5-2 50 30 * * w . . , : ' > ' 30 ... - ! & S IM '' 30 10 007-3-4 20 10007-4-4 2 0 10 007-5-2 50 30 -M ' ' , 30 . 30 10 007-3-4 10 0 10 007-4-3 10 0 10 007-5-2 50 30 : - j . m m m 30 w m m . . - 30 10 007-3-4 10 0 10 007-4-3 10 0 10 007-5-1 50 30 iM .:- * . m vm m . 30 30 10 007-3-4 10 0 10 007-4-4 10 0 10007-5-3 10 0 30 30 ..... . wmm . : .- .. 30 10 007-3-4 10 0 10 007-4-4 10 0 10007-5-3 10 0 30 S M B S * *** / "2- m sm s a i 30 ' - , 30 10 007-3-4 10 0 10 007-4-4 10 0 10007-5-3 10 0 30 -a ' .... . 1 30 M M im tim m ............ " n30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 50 30 r " ..V , ------------ 30 s . -.... : 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 30 . ' : S * * * 1 30 s :- - ' . 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 50 30 m ts rn rn M 30 B s _ vi 30 10 007-3-4 10 0 10 007-4-4 " 10 0 10 007-5-2 50 30 30 rMWSH' le* ' ___ -. ' . . : ' 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 30 ____ u "M * 30 ______ 30 10 007-3-4 10 0 10 007-4-4 10 0 10007-5-3 10 0 30 -- -- i . 30 - - - - 30 10 007-3-4 10 0 10 007-4-4 2 0 10007-5-3 10 0 30 30 . j. , ' T.' * * 30 10 007-3-4 20 10 0 0 7 ^ 4 10007-5-3 10 0 30 30 3* " 30 10 007-3-4 20 10 007-4-4 . 4=.2 0 10 007-5-2 30 30 ' n 7 - " . . . - , 30 10 007-3-4 20 10 007-4-4 20 10 007-5-2 50 30 30 M N H tt wmmm . < 30 10 007-3-4 20 10 007-4-4 20 10 007-5-4 10 0 30 mmmm -- ! ' ' 30 I.... : 30 10 007-3-4 10 0 10 007-4-3 10 0 10 007-5-2 50 30 - 30 1k ' 17 8 8 8 8 6 6 8 8 8 8 8 6 8 8 8 8 6 8 8 8 8 8 8 8 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 18 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 19 mmh * 20 . < S t i m m e : smssmmp. m m h^ mmh mmh-' * T in * " ' mmh x ' v, r v " , mmh - - ' r i * F mmh mmh mmh . . r n n i il?# -m m h` ? - mmh ' x m m h ^ a iij-m m h lw yMTimhU: ^ m m h lK m m h -':- mmh ' ., . , , 'sn . mm.-h ' f mmh *- * * mmh .7' * mmh- - - mmh * . n rn 4. - * -m h -- - ; mmh -- mmh w f -A . v ^ iim m h rn w m m m m JiS rn rn h H B H m rrhis. mn h ` mmh ^ *s ^ * mmh . m m h 1 -- - . mmh * i mmh m m i wmmmm. ........ m m m m wam som . ^ m m h `|3 ' . -;mmh<f * 'riv'rrimh^.S r: 3M Study GLP10-01-02 Interim Report 05 Page 2 of 3 Page 129 of 962 GLP10-01-02-05 ETS-8-053 Sample ID 1 GLP 10-01 -02-05-074 LMS GLP10-01-02-05-075 GLP10-01-02-05-075 Dup GLP10-01-02-05-075 LMS GLP10-01-02-05-076 GLP10-01-02-05-076 Dup GLP10-01-02-05-076 LMS GLP10-01-02-05-077 GLP10-01-02-05-077 Dup GLP10-01-02-05-077 LMS G L P 10-01-02-05-078 GLP10-01-02-05-078 Dup GLP10-01-02-05-078 LMS GLP10-01-02-05-Q79 GLP10-01-02-05-079 Dup GLP10-01-02-05-079 LMS G LP10-01-02-05-080 GLP10-01-02-05-080 Dup GLP10-01-02-05-080 LMS M B -1 0 1 116-07 MB-101116-08 Col 3 & 4: Balance ID: 900 Sample Description 2 DAL SS GP03 0 0005 Lab Matrix Spike DAL SS GP03 0 0020 DAL SS GP03 0 0020 Duplicate DAL SS GP03 0 0020 Lab Matrix Spike DAL SS GP03 DB 0020 DAL SS GP03 DB 0020 Duplicate DAL SS GP03 DB 0020 Lab Matrix Spike DAL SS GP03 0 0050 DAL SS GP03 0 0050 Duplicate DAL SS GP03 0 0050 Lab Matrix Spike DAL SS GP04 0 0000 DAL SS GP04 0 0000 Duplicate DAL SS GP04 0 0000 Lab Matrix Spike DAL SS GP04 0 0005 DAL SS GP04 0 0005 Duplicate DAL SS GP04 0 0005 Lab Matrix Spike DAL SS GP04 0 0020 DAL SS GP04 0 0020 Duplicate DAL SS GP04 0 0020 Lab Matrix Spike Method Blank 5a w/ 1S for Dilutions Method Blank 5a w/ IS for Dilutions 11/16/10 mmh Soil Maxtrix S oil W eight ID Used (g) Spike ID Spike Volume (uL) Internal Standard tD Internal StandardV o lu m e (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L-PFHxS Spike V olum e (uL) L-PFOS Spike ID L-PFOS Spike Volume <uL) Extraction Solvent Volume (m L) S o n ic a te 1 hr Centrifuge 0 C o m m e n ts 3* mmmmm > ' * ' 10 005-244 10 005-244 4 1.3113 1.7233 1.6547 1.7893 2.4270 1.9702 2.1796 1.1732 1.1380 1.1412 1.3101 1.0912 1.4330 1.1952 1.3496 1.1671 1.1261 1.3295 1.4580 5.0264 5.0004 5 67 10006-16 .; 1 0 006-16 M 1 0 006-16 1 0 006-16 . 1 0 006-16 10006-16 -. , *- . ~ 1 0 006-16 1 0 006-16 . . 1 0 006-16 1 0 006-16 1 0 006-16 - p 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 W. 1 0 006-16 1 0 006-16 1 0 006-16 1 0 006-16 .. m 10 006-16 ......V 1 0 006-16 Col 7 & 8: . C ol 9 & 10: pipette:4215537 11/18/10 mmh 89 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 30 10 005-132 150 10 005-132 150 10 005-132 10 1 1 1 2 13 14 15 16 17 18 19 20 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 mmh mmh if 30 M B M e 30 ts m m m i 8 mmh # fm m h ^ i' 8 mmh 4ammhS! 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 30 7 8 mmh -r-m m h * ^ 6 mmh 'ffm m h W 30 =% - 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 6 mmh : " 8 mmh S ^ m m h li 30 30 -'i*** x.VjW, -,,-V 1- ^ >. f - " . M - - V -'ft* * * * * 8 mmh ^ m m h S f . 8 mmh fi^m m hS fe 30 10 007-3-3 50 10 007-4-3 10 0 10 007-5-2 50 8 mmh ^ 'm rn h ^ 30 30 & X -V ,/'*?, ' - n - - w * *f r* 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 50 8 mmh "Kim'mhMt 6 mmh ^`S rrim h g ff 6 mmh f ^ y r r im h ^ ... ,,< * 30 ' - -5 - ~ v,~ t r 6 mmh %^mmlffefs 30 y * r *. - t*. . 6 mmh ^ m m h ^ 30 10 007-3-4 10 0 10 007-4-4 10 0 10 007-5-2 50 8 mmh 30 r t ' 'r , -* - ? r , r ~ v ' 8 mmh i^ m r h h l i : 30 -8 mmh '^--mmlViS# 30 10 007-3-4 10 0 10 007-4-4 10 0 10007-5-3 10 0 6 mmh i^ n im h % 'I-v' -"l?'-'"W 150 '^S*\ 150 . # J.-' k--JJ" - * --r & s t *, t ' -j- V ',. T 40 mmh S ^sritm hirf 40 mmh ^ m m lf i- 'f' Col 13 & 14: Col 17: 10 006-25 11/18/10 mmh pipette:4215537 11/18/10 mmh Col 15 & 16: Col 18: 11/18/10 mmh Col 5 & 6 : pipette:4215537 pipette:4215537 11/18/10 mmh pipette:3824414 11/18/10 mmh Col 11& 12: pipette:4215537 11/18/10 mmh pipette:4215537 pipette:3624414 11/18/10 mmh fo iu m n )i r>+ b i, y t i j - c t f ' ^ jts/'ihbn (-u U c'i e ry i ! H cj -- / O , " r h c S a s n f k s - 3M Study GLP10-01-02 Interim Report 05 page3of3 G LP10-01-02-05 ETS-8-053 Sample ID Sample D escription Soil Maxtrix Soil W eight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal S ta n d a rd V o lum e (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume (m L) Sonicate 1 hr C e ntrifug e Comments 1 EC-101116-01 EC-101116-02 EC-101116-03 EC-101116-04 EC-101116-05 EC-101116-06 EC-101116-07 EC-101116-08 EC-101116-09 EC-101116-10 EC-101116-11 EC-101116-12 MB-101116-01 MB-101116-02 MB-101116-03 MB-101116-04 MB-101116-05 MB-101116-06 LCS-101116-01 LCS-101116-02 LCS-101116-03 LCS-101116-04 LCS-101116-05 LCS-101116-06 GLP10-01-02-05-041 GLP10-01 -02-05-041 Dud GLP10-01 -02-05-041 LMS GLP10-01 -02-05-042 GLP10-01-02-05-042 Dud GLP10-01-02-05-042 LMS GLP10-01-02-05-043 GLP10-01-02-05-043 Dup GLP10-01-02-05-043 LMS GLP10-01-02-05-044 GLP10-01-02-05-044 Dud GLP10-01-02-05-044 LMS GLP10-01 -02-05-045 GLP10-01-02-05-045 Duo GLP10-01 -02-05-045 LMS GLP10-01-02-05-046 GLP10-01-02-05-046 Dud GLP10-01-02-05-046 LMS GLP10-01-02-05-047 GLP10-01-02-05-047 Dud GLP10-01-02-05-047 LMS GLP10-01-02-05-048 GLP10-01-02-05-048 Dud GLP10-01-02-05-048 LMS GLP10-01 -02-05-049 GLP10-01 -02-05-049 Dud GLP10-01-02-05-049 LMS GLP10-01 -02-05-050 GLP10-01-02-05-050 Dud GLP10-01-02-05-050 LMS GLP10-01 -02-05-051 GLP10-01 -02-05-051 Dup GLP10-01 -02-05-051 LMS GLP10-01 -02-05-052 GLP10-01-02-05-052 Dud GLP10-01 -02-05-052 LMS GLP10-01 -02-05-054 2 0.2 ng Extracted Curve Point 0.5 nq Extracted Curve Point 0.75 nq Extracted Curve Point 1 nq Extracted Curve Point 2.5 nq Extracted Curve Point 5 nq Extracted Curve Point 10 nq Extracted Curve Point 25 nq Extracted Curve Point 50 nq Extracted Curve Point 100 nq Extracted Curve Point 200 nq Extracted Curve Point 500 nq Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w /IS Method Blank 6 w / IS 3 nq LCS in TCR-842 3 nq LCS in TCR-842 3 nq LCS in TCR-842 30 nq LCS in TCR-842 30 nq LCS in TCR-842 30 nq LCS in TCR-842 DAL SS SS01 0 0000 DAL SS SS01 0 0000 Duplicate DAL SS SS01 0 0000 Lab Matrix Spike DAL SS SS01 0 0005 DAL SS SS01 0 0005 Duplicate DAL SS SS01 0 0005 Lab Matrix Spike DAL SS SS02 0 0000 DAL SS SS02 0 0000 Duplicate DAL SS SS02 0 0000 Lab Matrix Soike DAL SS SS02 0 0005 DAL SS SS02 0 0005 Duplicate DAL SS SS02 0 0005 Lab Matrix Spike DAL SS SS03 0 0000 DAL SS SS03 0 0000 Duplicate DAL SS SS03 0 0000 Lab Matrix Spike DAL SS SS03 0 0005 DAL SS SS03 0 0005 Duplicate DAL SS SS03 0 0005 Lab Matrix Spike DAL SS SS03 DB 0005 DAL SS SS03 DB 0005 Duplicate DAL SS SS03 DB 0005 Lab Matrix Spike DAL SS SS04 0 0000 DAL SS SS04 0 0000 Duplicate DAL SS SS04 0 0000 Lab Matrix Spike DAL SS SS04 0 0005 DAL SS SS04 0 0005 Duplicate DAL SS SS04 0 0005 Lab Matrix Spike DAL SS TRIP1 0 0000 DAL SS TRIP1 0 0000 Duplicate DAL SS TRIP1 0 0000 Lab Matrix Spike DAL SS SS05 0 0000 DAL SS SS05 0 0000 Duplicate DAL SS SS05 0 0000 Lab Matrix Spike DAL SS SS05 0 0005 DAL SS SS05 0 0005 Duplicate DAL SS SS05 0 0005 Lab Matrix Spike DAL SS SS06 0 0000 3 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 - 4 1.1188 1.1358 1.0903 1.0883 1.1436 1.1230 1.1271 1.1098 1.0999 1.1434 1.1247 1.1440 1.1494 1.0898 1.1131 1.1323 1.1361 1.1170 1.1303 1.1435 1.1372 1.1305 1.1397 1.1406 1.1942 1.0941 1.3218 2.2162 1.7674 1.4949 1.3157 1.0856 1.2340 1.6277 1.5527 1.5266 1.3271 1.5201 1.3935 2.3556 1.8211 2.0447 1.6152 1.6050 1.5940 1.0411 0.9724 1.3188 1.0339 1.1532 1.1408 1.0997 1.1280 1.1113 1.0336 0.9169 1.0715 0.9833 1.0003 1.1670 1.0830 5 10 005-167 10 005-167 10 005*167 10 005-167 10 005-166 10 005-166 10005-166 10 005-165 10 005-165 10 005-165 10 006-7 10 006-7 10 005-164 10 005-164 10 005-164 10 005-163 10 005-163 10 005-163 67 20 10 006-16 50 10 006-16 75 10 006-16 100 10 006-16 25 10 006-16 50 10 006-16 100 10 006-16 25 10 006-16 50 10006-16 100 10 006-16 20 10006-16 50 10 006-16 69 30 10 005-133 30 10 005-133 30 10 005-133 30 10 005-133 30 10 005-132 30 10 005-132 30 10 005-132 30 10 006-002 30 10 006-002 30 10 006-002 30 10 006-002 30 10 006-002 10 20 50 75 100 25 50 100 25 50 100 200 500 11 12 13 14 15 16 10006-16 30 10005-132 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 30 10006-16 30 10005-132 30 30 10 006-16 30 10005-132 30 30 10 006-16 30 10 005-132 30 30 10 006-16 30 10005-132 30 30 10006-16 30 10 005-132 30 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 100 10 007-5-2 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 100 10 007-5-2 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 100 10006-16 30 10005-132 30 10 006-16 30 10005-132 30 10006-16 30 10005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 100 10 006-16 30 10005-132 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-2 50 10 007-5-1 50 10 006-16 : ., 10 006-16 30 10 005-132 30 10 005-132 30 30 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-2 50 10 007-5-1 50 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-2 50 10 007-5-1 50 10 006-16 30 10005-132 30 10 006-16 30 10 005-132 30 10006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 ' 10 006-16 30 10 005-132 30 10 006-16 30 10005-132 30 10 006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 100 10 007-5-2 50 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10006-16 30 10 005-132 30 10 007-3-4 20 10007-4-4 20 10 007-5-4 20 10 006-16 30 10 005-132 30 10006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 200 10006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 10 006-16 30 10 005-132 30 3M Study GLP10-01-02 Interim. Report 0. . Page 1 of 3 17 18 19 20 8 mmh mmh 8 mmh . m m h 8 mmh mmh 8 mmh mmh 8 mmh . mmh 8 mmh ' mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mrnh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 6 mmh mmh 6 mmh mmh ' 8 mmh mmh 8 mmh mmh 8 mmh mmh, 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh -m m h 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh - 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mrnh - 8 mmh mmh 8 mmh mmh 8 mmh -,mmh 8 mmh mmh 8 mmh mmh - Page 13 M GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID U sed(g) Spike ID Spike Volume (uL) Internal S ta n d a rd ID Internal StandardV Surrogate olume Spike ID (uL) Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L -P F H x S Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E x tra c tio n Solvent Volume (m L) Sonicate 1 hr C e ntrifug e C o m m e n ts 1 GLP10-01-02-05-054 Dud GLP10-01-02-05-054 IM S GLP10-01-02-05-055 GLP10-01-02-05-055 Duo GLP10-01-02-05-055 LMS GLP10-01-02-05-056 GLP10-01-02-05-056 Duo GLP10-01 -02-05-056 LMS G LP 10-01 -02-05 -057 GLP10-01 -02-05-057 Dup GLP10-01 -02-05-057 LMS GLP10-01-02-05-058 GLP10-01-02-05-058 Dup GLP10-01-02-05-058 LMS GLP10-01-02-05-059 GLP10-01-02-05-059 Dud GLP10-01 -02-05-059 LMS GLP10-01-02-05-060 GLP10-01-02-05-060 Dup GLP10-01-02-05-060 LMS GLP10-01-02-05-061 GLP10-01-02-05-061 Dup GLP10-01 -02-05-061 LMS GLP10-01-02-05-062 GLP10-01-02-05-062 Dup GLP10-01-02-05-062 LMS GLP10-01-02-05-063 GLP10-01 -02-05-063 Dup GLP10-01-02-05-063 LMS GLP10-01-02-05-064 GLP10-01-02-05-064 Dup GLP10-01-02-05-064 LMS GLP10-01 -02-05-065 GLP10-01-02-05-065 Dup GLP10-01 -02-05-065 LMS GLP10-01 -02-05-066 GLP10-01-02-05-066 Dud GLP10-01-02-05-066 LMS GLP10-01-02-05-067 GLP10-01-02-05-067 Dud GLP10-01-02-05-067 LMS G LP 10-01-02-05 -068 GLP10-01-02-05-068 Dud GLP10-01 -02-05-068 LMS GLP10-01-02-05-069 GLP10-01-02-05-069 Dud GLP10-01-02-05-069 LMS GLP10-01-02-05-070 GLP10-01-02-05-070 Dup GLP10-01-02-05-070 LMS G LP 10-01-02-05-071 GLP10-01 -02-05-071 Dup GLP10-01 -02-05-071 LMS GLP10-01-02-05-072 GLP10-01 -02-05-072 Dup GLP10-01-02-05-072 LMS G LP 10-01 -02-05 -073 GLP10-01-02-05-073 Dup GLP10-01 -02-05-073 LMS GLP10-01-02-05-074 GLP10-01-02-05-074 Dup 2 DAL SS SS06 0 0000 Duplicate DAL SS SS06 0 0000 Lab Matrix Spike DAL SS SS06 0 0005 DAL SS SS06 0 0005 Duplicate DAL SS SS06 0 0005 Lab Matrix Spike DAL SS SS06 DB 0005 DAL SS SS06 DB 0005 Duplicate DAL SS SS06 DB 0005 Lab Matrix Spike DAL SS SS07 0 0000 DAL SS SS07 0 0000 Duplicate DAL SS SS07 0 0000 Lab Matrix Spike DAL SS SS07 0 0005 DAL SS SS07 0 0005 Duplicate DAL SS SS07 0 0005 Lab Matrix Spike DAL SS SS08 0 0000 DAL SS SS08 0 0000 Duplicate DAL SS SS08 0 0000 Lab Matrix Spike DAL SS SS08 DB 0000 DAL SS SS08 DB 0000 Duplicate DAL SS SS08 DB 0000 Lab Matrix Spike DAL SS SS08 0 0005 DAL SS SS08 0 0005 Duplicate DAL SS SS08 0 0005 Lab Matrix Spike DAL SS SS09 0 0000 DAL SS SS09 0 0000 Duplicate DAL SS SS09 0 0000 Lab Matrix Spike DAL SS SS09 0 0005 DAL SS SS09 0 0005 Duplicate DAL SS SS09 0 0005 Lab Matrix Spike DAL SS GP01 0 0000 DAL SS GP01 0 0000 Duplicate DAL SS GP01 0 0000 Lab Matrix Spike DAL SS GP01 0 0005 DAL SS GP01 0 0005 Duplicate DAL SS GP01 0 0005 Lab Matrix Spike DAL SS GP01 0 0020 DAL SS GP01 0 0020 Duplicate DAL SS GP01 0 0020 Lab Matrix Spike DAL SS GP01 0 0060 DAL SS GP01 0 0060 Duplicate DAL SS GP01 0 0060 Lab Matrix Spike DAL SS GP02 0 0000 DAL SS GP02 0 0000 Duplicate DAL SS GP02 0 0000 Lab Matrix Spike DAL SS GP02 0 0005 DAL SS GP02 0 0005 Duplicate DAL SS GP02 0 0005 Lab Matrix Spike DAL SS G P 0 2 0 0 0 2 0 DAL SS GP02 0 0020 Duplicate DAL SS GP02 0 0020 Lab Matrix Spike DAL SS GP02 DB 0020 DAL SS GP02 DB 0020 Duplicate DAL SS GP02 DB 0020 Lab Matrix Spike DAL SS GP02 0 0120 DAL SS GP02 0 0120 Duplicate DAL SS GP02 0 0120 Lab Matrix SDike DAL SS GP03 0 0000 DAL SS GP03 0 0000 Duplicate DAL SS GP03 0 0000 Lab Matrix Spike DAL SS GP03 0 0005 DAL SS GP03 0 0005 Duplicate 3 4 1.1820 1.0853 1.1637 1.2122 1.1286 1.1208 1.1301 1.1470 1.1920 1.1014 0.9852 1.3799 1.2233 1.2248 1.3989 1.3327 1.4664 1.3445 1.3477 1.3875 1.1974 1.1633 1.3542 1.0438 1.0690 1.1399 1.1509 1.1903 1.2035 1.1717 1.0685 1.3297 2.1050 2.0466 2.4711 1.4448 1.4586 1.5783 1.3694 1.5738 1.6761 1.3687 1.5391 1.3072 1.0942 1.4285 1.5102 1.4163 1.5968 1.6993 1.5718 2.1641 1.7320 1.2109 1.6107 1.2559 0.9906 1.1479 1.1484 1.1901 1.0154 5 67 8 9 10 11 12 13 14 15 16 17 18 19 29 10 006-16 30 10 005-132 30 6 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 10 006-16 30 10 005-132 30 II 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 20 10007-4-4 20 10 007-5-2 50 6 mmh mmh . 10 006-16 10006-16 30 10 005-132 30 10 005-132 30 30 8 mmh mmh 6 mmh mmh 10006-16 30 10005-132 30 10 007-3-4 20 10007-4-4 20 10 007-5-2 50 8 mmh mmh 10 006-16 30 10005-132 30 8 mmh mmh 10 006-16 30 10005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 50 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh . 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-1 50 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10007-5-3 100 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10007-5-3 100 8 mmh mmh : 10006-16 30 10 005-132 30 8 mmh mmh 1, 10006-16 30 10 005-132 30 10006-16 30 10005-132 30 10 007-3-4 100 10 007-4-4 100 10007-5-3 100 8 mmh mmh 8 mmh mmh.-:"-; 10 006-16 30 10 005-132 30 8 mmh mmh - 10006-16 30 10005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh , mmh 10006-16 30 10 005-132 30 8 mmh mmh > 10006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 10006-16 30 10005-132 30 8 mmh mmh 10006-16 30 10005-132 30 6 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 6 mmh mmh 10 006-16 30 10005-132 30 8 mmh .. mm h. 10006-16 30 10 005-132 30 8 mmh mmh - 10006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 100 10007-5-3 100 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh.is" 10006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-4 20 10007-5-3 100 8 mmh mmh - 10006-16 30 10 005-132 30 * 8 mmh mmh' 10006-16 30 10005-132 30 8 mmh mmh 10006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 20 10007-5-3 100 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 20 10 007-5-2 50 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh 10006-16 30 10 005-132 30 10 007-3-4 20 10 007-4-4 20 10 007-5-2 50 8 mmh mmh 10006-16 30 10 005-132 30 8 mmh mmh 10 006-16 30 10005-132 30 8 mmh mmh 10 006-16 30 10005-132 30 10 007-3-4 20 10 007-4-4 20 10 007-5-4 100 8 mmh mmh , 10 006-16 10 006-16 30 10005-132 30 10 005-132 30 30 8 mmh mmh 8 mmh mmh 10 006-16 30 10 005-132 30 10 007-3-4 100 10 007-4-3 100 10 007-5-2 50 8 mmh mmh 10 006-16 30 10 005-132 30 8 mmh ' mmh 10 006-16 30 10 005-132 30 8 mmh ? fim m h ;,;E. 3M Study GLP10-01-02 Interim Report 05 Page 2 of 3 Page 132 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrlx Soil Weight ID Used (g) Spike ID Spike Volume <uL) Internal Standard ID Internal StandardV Surrogate olum e Spike ID (uL) Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume <mL) S o n ic a te 1 hr Centrifuge C o m m e n ts 1 GLP10-01 -02-05-074 LMS GLP10-01 -02-05-075 GLP10-01-02-05-075 Dup GLP10-01 -02-05-075 LMS GLP10-01-02-05-076 GLP10-01-02-05-076 Dup GLP10-01 -02-05-076 LMS GLP10-01-02-05-077 GLP10-01-02-05-077 Dup GLP10-01-02-05-077 LMS GLP10-01-02-05-078 GLP10-01-02-05-078 Dup GLP10-01-02-05-078 LMS GLP10-01-02-05-079 GLP10-01-02-05-079 Dup GLP10-01-02-05-079 LMS GLP10-01-02-05-080 GLP10-01-02-05-080 Dup GLP10-01-02-05-080 LMS MB-101116-07 MB-101116-08 2 DAL SS GP03 0 0005 Lab Matrix Spike DAL SS GP03 0 0020 DAL SS GP03 0 0020 Duplicate DAL SS GP03 0 0020 Lab Matrix Spike DAL SS GP03 DB 0020 DAL SS GP03 DB 0020 Duplicate DAL SS GP03 DB 0020 Lab Matrix Spike DAL SS GP03 0 0050 DAL SS GP03 0 0050 Duplicate DAL SS GP03 0 0050 Lab Matrix Spike DAL SS GP04 0 0000 DAL SS GP04 0 0000 Duplicate DAL SS GP04 0 0000 Lab Matrix Spike DAL SS GP04 0 0005 DAL SS GP04 0 0005 Duplicate DAL SS GP04 0 0005 Lab Matrix Spike DAL SS GP04 0 0020 DAL SS GP04 0 0020 Duplicate DAL SS GP04 0 0020 Lab Matrix Spike Method Blank 5q w / IS for Dilutions Method Blank 5q w/ IS for Dilutions Col 3 & 4: Balance ID: 900 11/16/10 mmh 3 10 005-244 10 005-244 Col 5 & 6: pipette:4215537 11/18/10 mmh 4 1.311 1.7233 1.6547 1.7893 2.4270 1.9702 2.1796 1.1732 1.1380 1.1412 1.3101 1.0912 1.4330 1.1952 1.3496 1.1671 1.1261 1.3295 1.4580 5.02 4 5.00C-: 5 ', Col 7 & 8: Col 9 & 10: 6 ' , ,,.' ' 7 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 10006-16 10006-16 10006-16 10 006-16 10006-16 10006-16 10 006-16 10 006-16 10 006-16 10006-16 10006-16 10 006-16 10 006-16 10 006-16 10 006-16 10 006-16 pipetle:4215537 11/18/10 mmh pipette:4215537 11/18/10 mmh pipette:3824414 11/18/10 mmh 8 9 10 11 12 13 14 15 16 17 18 19 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 mmh mmh 30 10 005-132 30 8 mmh mmh . 30 10 005-132 30 8 mmh mmh 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 mmh mmh 30 10 005-132 30 8 mmh mmh 30 10 005-132 30 6 mmh mmh 30 10 005-132 30 10 007-3-3 50 10 007-4-2 50 10 007-5-1 50 8 mmh rnrnh 30 10 005-132 30 8 mmh mmh" 30 10 005-132 30 8 mmh mmh 30 10 005-132 30 10 007-3-3 50 10 007-4-3 100 10 007-5-2 50 8 mmh mmh 30 10 005-132 30 8 mmh mmh 30 10005-132 30 8 mmh mmh - 30 10005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 30 10005-132 30 8 mmh mmh 30 10005-132 30 8 mmh mmh 30 10005-132 30 10 007-3-4 100 10 007-4-4 100 10 007-5-2 50 8 mmh mmh 30 10005-132 30 8 mmh mmh ' 30 10 005-132 30 8 mmh mmh 30 10005-132 30 10 007-3-4 100 10 007-4-4 100 10007-5-3 100 8 mmh mmh 150 10005-132 150 40 mmh mmh 150 10 005-132 150 40 mmh mmh C ol 13 & 14: Cot 17: 10006-25 11/18/10 mmh pipette:4215537 11/18/10 mmh C ol 15 & 16: C ol 18: 11/18/10 mmh COM1&12: pipette:4215537 11/18/10mmh /f* ' pipette:4215537 pipette:3824414 11/18/10 mmh A !L> SonicatorlD: QEJ100595003 Col 19: NA 20 3M Study GLP10-01-02 Interim Report .05 - . . Page3of3 Page 133 of 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume <uL) PFBS Spike ID PFBS Spike Volum e(uL) L-PFHxS Spike ID L-PFHxS Spike Volume <uL> L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Sonicate Centrifuge Volume 1 hr <mL) Comments 12 EC-101116-01 0.2 ng Extracted Curve Point EC-101116-02 EC-101116-03 EC-101116-04 EC-101116-05 EC-101116-06 EC-101116-07 EC-101116-08 EC-101116-09 EC-101116-10 EC-101116-11 EC-101116-12 MB-101116-01 MB-101116-02 MB-101116-03 MB-101116-04 MB-101116-05 MB-101116-06 LCS-101116-01 LCS-101116-02 LCS-101116-03 LCS-101116-04 LCS-101116-05 LCS-101116-06 GLP10-01-02-05-041 GLP10-01-02-05-041 Duo GLP10-01-02-05-041 IM S GLP10-01-02-05-042 GLP10-01-02-05-042 DuD GLP10-01-02-05-042 LMS GLP10-01-02-05-043 GLP 10-01-02-05-043 DuD GLP10-01-02-05-043 LMS GLP10-01-02-05-044 GLP10-01-02-05-044 DuD GLP10-01-02-05-044 LMS GLP10-01-02-05-045 GLP 10-01-02-05-045 DuD GLP 10-01-02-05-045 LMS G LP10-01-02-05-046 GLP10-01-02-05-046 Dup GLP10-01-02-05-046 LMS GLP10-01-02-05-047 GLP10-01-02-05-047 DuD GLP10-01-02-05-047 LMS GLP10-01-02-05-048 GLP10-01-02-05-048 Dup GLP10-01-02-05-048 LMS GLP 10-01-02-05-049 GLP10-01-02-05-049 DuD GLP 10-01-02-05-049 LMS GLP 10-01-02-05-050 GLP 10-01-02-05-050 Dup GLP10-01-02-05-050 LMS GLP10-01-02-05-051 GLP10-01-02-05-051 Dup GLP10-01-02-05-051 LMS GLP10-01-02-05-052 GLP10-01-02-05-052 Dup GLP10-01-02-05-052 LMS GLP10-01-02-05-054 GLP 10-01-02-05-054 DuP GLP 10-01-02-05-054 LMS GLP10-01-02-05-055 0.5 nq Extracted Curve Point 0.75 na Extracted Curve Point 1 no Extracted Curve Point 2.5 na Extracted Curve Point 5 na Extracted Curve Point 10 na Extracted Curve Point 25 na Extracted Curve Point 50 na Extracted Curve Point 100 na Extracted Curve Point 200 na Extracted Curve Point 500 na Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 na LCS in TCR-842 3 na LCS in TCR-842 3 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 DAL SS SS01 0 0000 DAL SS SS01 0 0000 Duplicate DAL SS SS01 0 0000 Lab Matrix Spike DAL SS SS01 0 0005 DAL SS SS01 0 0005 Duplicate DAL SS SS01 0 0005 Lab Matrix Spike DAL SS SS02 0 0000 DAL SS SS02 0 0000 Duplicate DAL SS SS02 0 0000 Lab Matrix Spike DAL SS SS02 0 0005 DAL SS SS02 0 0005 Duplicate DAL SS SS02 0 0005 Lab Matrix Spike DAL SS SS03 0 0000 DAL SS SS03 0 0000 Duplicate DAL SS SS03 0 0000 Lab Matrix Spike DAL SS SS03 0 0005 DAL SS SS03 0 0005 Duplicate DAL SS SS03 0 0005 Lab Matrix Spike DAL SS SS03 DB 0005 DAL SS SS03 DB 0005 Duplicate DAL SS SS03 DB 0005 Lab Matrix Spike DAL SS SS04 0 0000 DAL SS SS04 0 0000 Duplicate DAL SS SS04 0 0000 Lab Matrix Spike DAL SS SS04 0 0005 DAL SS SS04 0 0005 Duplicate DAL SS SS04 0 0005 Lab Matrix Spike DAL SS TRIP1 0 0000 DAL SS TRIP1 0 0000 Duplicate DAL SS TRIP1 0 0000 Lab Matrix Spike DAL SS SS05 0 0000 DAL SS SS05 0 0000 Duplicate DAL SS SS05 0 0000 Lab Matrix Spike DAL SS SS05 0 0005 DAL SS SS05 0 0005 Duplicate DAL SS SS05 0 0005 Lab Matrix Spike DAL SS SS06 0 0000 DAL SS SS06 0 0000 Duplicate DAL SS SS06 0 0000 Lab Matrix Spike DAL SS SS06 0 0005 3 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 10 005-244 4 1.1188 1.1358 1.0903 1.0883 1.1436 1.1230 1.1271 1.1098 1.0999 1.1434 1.1247 1.1440 1.1494 1.0898 1.1131 1.1323 1.1361 1.1170 1.1303 1.1435 1.1372 1.1305 1.1397 1.1406 1.1942 1.0941 1.3218 2.2162 1.7674 1.4949 1.3157 1.0866 1.2340 1.6277 1.5527 1.5266 1.3271 1.5201 1.3935 2.3556 1.8211 2.0447 1.6152 1.6050 1.5940 1.0411 0.9724 1.3188 1.0339 1.1532 1.1408 1 0997 1 1280 1,1113 1,0336 0 9169 1 0715 0.9833 1.0003 1.1670 1.0830 1.1820 1.0853 1,1637 5 \ >t 67 8 ' 9 10 11 12 13 14 15 16 17 18 19 . <\ - r ' 20 ; *' - 3M Study GLP10-01-02 . Interim Report .05- Page 1 of 3 Page 13 4 o f 9 GLP10-01-02-05 ETS-e-053 Sample ID Sample Description Soil Maxtrlx Soil Weight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (UL) Extraction Solvent Sonicate Centrifuge Volume 1 hr (mL) Comments 1 GLP1001-02-05-055 Dup GLP1001-02-05-055 LMS GLP10 0 1-02-05-056 GLP1001-02-05-056 Dup GLP1001-02-05-056 LMS GLP1001-02-05-057 GLP1001-02-05-057 Dup GLP1001-02-05-057 LMS GLP1001 -02-05-058 GLP 10 0 1-02-05-058 Duo GLP1O01-02-05-058 LMS GLP 1001-02-05-059 GLP 1001-02-05-059 Dup GLP 1001-02-05-059 LMS GLP 1001-02-05-060 GLP10 0 1-02-05-060 Dup GLP10 0 1-02-05-060 LMS GLP10 0 1-02-05-061 GLP10 0 1-02-05-061 Dup GLP1001-02-05-061 LMS GLP1001-02-05-062 * GLP10 0 1-02-05-062 Dup GLP10 0 1-02-05-062 LMS GLP1001-02-05-063 GLP1001-02-05-063 Dup GLP1001-02-05-063 LMS GLP1001-02-05-064 GLP1001-02-05-064 Dup GLP1001-02-05-064 LMS GLP1001-02-05-065 GLP1001-02-05-065 Dup GLP1001-02-05-065 LMS GLP1001-02-05-066 GLP1001 -02-05-066 Dup GLP1O01-02-05-066 LMS GLP1O01-02-05-067 GLP1001-02-05-067 Dup GLP1001-02-05-067 LMS GLP 1001-02-05-068 GLP1001-02-05-068 Dup GLP10 0 1-02-05-068 LMS GLP10 0 1-02-05-069 GLP10 0 1-02-05-069 Dup GLP10 0 1-02-05-069 LMS GLP10 0 1-02-05-070 GLP1001-02-05-070 Duo GLP1001-02-05-070 LMS GLP1001-02-05-071 GLP1001-02-05-071 Dup GLP1001 -02-05-071 LMS GLP1O01 -02-05-072 GLP 10 0 1-02-05-072 Dup GLP 10 0 1-02-05-072 LMS GLP 10 0 1-02-05-073 GLP10 0 1-02-05-073 Dup GLP1001-02-05-073 LMS GLP1001-02-05-074 GLP1001-02-05-074 Dup GLP10 0 1-02-05-074 LMS GLP1001-02-05-075 GLP10 0 1-02-05-075 DuP GLP1001-02-05-075 LMS GLP1001-02-05-076 GLP1001-02-05-076 Dup GLP1001-02-05-076 LMS 2 DAL SS SS06 0 0005 Duplicate DAL SS SS06 0 0005 Lab Matrix Spike DAL SS SS06 DB 0005 DAL SS SS06 DB 0005 Duplicate DAL SS SS06 DB 0005 Lab Matrix Spike DAL SS SS07 0 0000 DAL SS SS07 0 0000 Duplicate DAL SS SS07 0 0000 Lab Matrix Spike DAL SS SS07 0 0005 DAL SS SS07 0 0005 Duplicate DAL SS SS07 0 0005 Lab Matrix Spike DAL SS SS08 0 0000 DAL SS SS08 0 0000 Duplicate DAL SS SS08 0 0000 Lab Matrix Spike DAL SS SS08 DB 0000 DAL SS SS08 D8 0000 Duplicate DAL SS SS08 DB 0000 Lab Matrix Spike DAL SS SS08 0 0005 DAL SS SS08 0 0005 Duplicate DAL SS SS08 0 0005 Lab Matrix Spike DAL SS SS09 0 0000 DAL SS SS09 0 0000 Duplicate DAL SS SS09 0 0000 Lab Matrix Spike DAL SS SS09 0 0005 DAL SS SS09 0 0005 Duplicate DAL SS SS09 0 0005 Lab Matrix Spike DAL SSGP01 0 0000 DAL SS GP01 0 0000 Duplicate DAL SS GP01 0 0000 Lab Matrix Spike DAL SSGP01 0 0005 DAL SS GP01 0 0005 Duplicate DAL SS GP01 0 0005 Lab Matrix Spike DAL SSGP01 0 0020 DAL SS GP01 0 0020 Duplicate DAL SS GP01 0 0020 Lab Matrix Spike DAL SS GP01 0 0060 DAL SS GP01 0 0060 Duplicate DAL SS GP01 0 0060 Lab Matrix Spike DAL SS GP02 0 0000 DAL SS GP02 0 0000 Duplicate DAL SS GP02 0 0000 Lab Matrix Spike DAL SS GP02 0 0005 DAL SS GP02 0 0005 Duplicate DAL SS GP02 0 0005 Lab Matrix Spike DAL SS GP02 0 0020 DAL SS GP02 0 0020 Duplicate DAL SS GP02 0 0020 Lab Matrix Spike DAL SS GP02 DB 0020 DAL SS GP02 DB 0020 Duplicate DAL SS GP02 DB 0020 Lab Matnx Spike DAL SS GP02 0 0120 DAL SS GP02 0 0120 Duplicate DAL SS GP02 0 0120 Lab Matrix Spike DAL SS GP03 0 0000 DAL SS GP03 0 0000 Duplicate DAL SS GP03 0 0000 Lab Matrix Soike DAL SS GP03 0 0005 DAL SS GP03 0 0005 Duplicate DAL SS GP03 0 0005 Lab Matrix Spike DAL SSGP03 0 0020 DAL SS GP03 0 0020 Duplicate DAL SS GP03 0 0020 Lab Matrix Spike DAL SS GP03 DB 0020 DAL SS GP03 DB 0020 Duplicate DAL SS GP03 DB 0020 Lab Matrix Spike ' ; ' 3 4 1.2122 1.1286 1.1208 1.1301 1.1470 1.1920 1.1014 0.9852 1.3799 1.2233 1.2248 1.3989 1.3327 1.4664 1.3445 1.3477 1.3875 1.1974 1.1633 1.3542 1.0438 1.0690 1.1399 1.1509 1.1903 1.2035 1.1717 1.0685 1.3297 2.1050 2.0466 2.4711 1.4448 1.4588 1.5783 1.3694 1.5738 1.6761 1.3687 1.5391 1.3072 1.0942 1.4285 1.5102 1.4163 1.5968 1.6993 1.5718 2.1641 1.7320 1.2109 1.6107 1.2559 0.9906 1.1479 1.1484 1.1901 1.0154 1.3113 1.7233 1.6547 1.7893 2.4270 1.9702 2.1796 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 -S -- ' ip : ' .'' * v' , " r. -V -> , 20 3M Study GLP10-01-02 Interim Report 05 . , Rage ? n f 3 Page. 1.35 o f 962 GLP10-01-02-05 ETS-8-053 Sample ID Sample Description Soil Maxtrix Soil Weight ID Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal Standard Volume (uL) Surrogate Spike ID S urro ga te Spike Volume (uL) PFBS Spike ID PFBS Spike Volum e (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) E xtra ctio n Solvent Volume (mL) Sonicate Centrifuge 1 hr Comments 1 GLP10-01-02-05-077 GLP10-01-02-05-077 Dud GLP10-01-02-05-077 LMS GLP10-01-02-05-078 GLP10-01 -02-05-078 Duo GLP10-01 -02-05-078 LMS GLP10-01-02-05-079 GLP10-01-02-05-079 Duo GLP10-01-02-05-079 LMS GLP10-01-02-05-080 GLP10-01-02-05-080 Dud GLP10-01-02-05-080 LMS MB-101116-07 MB-101116-08 2 DAL SS GP03 0 0050 DAL SS GP03 0 0050 Duolicate DAL SS GP03 0 0050 Lab Matrix Soike DAL SSGP04 0 0000 DAL SS GP04 0 0000 Duplicate DAL SS GP04 0 0000 Lab Matrix Spike DAL SS GP04 0 0005 DAL SS GP04 0 0005 Duplicate DAL SS GP04 0 0005 Lab Matrix Soike DAL SS GP04 0 0020 DAL SS GP04 0 0020 Duplicate DAL SS GP04 0 0020 Lab Matrix Spike Method Blank 5a w/ IS for Dilutions Method Blank 5q w/ IS for Dilutions Col 3 & 4: Balance ID: 900 11/16/10 mmh Col 5 & 6: 10 005-244 10 005-244 4 1 1732 1.1380 1.1412 1.3101 1.0912 1.4330 1.1952 1.3496 1.1671 1.1261 1.3295 1.4580 5.0264 5.0004 5 Col 7 & 8: Col 9 & 10: 6 7 9 10 11 1? 13 14 15 If* 17 18 19 20 Col 11& 12: Col 13 & 14: Col 15 & 18: Col 17: Col 18: Sonicator ID: QEJ100595003 Col 19: Centrifuge ID: 021188-55 10min@ 3000RPM Centrifuge ID: 1521430 for method blanks 7to 9 3M Study G LP10-01-02 Interim R eport 0 5 .. . - _ . - Page 3 of 3 ` -y.- P age 136 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple se t ID # Lim s # N /A G LP10-01-02-05 S am ple D escription: D ecatur Soils IN T E R N A L C H A IN O F C U S T O D Y # 3M Sample IDs Out: storage ID Jnit/date In: storage ID InitJdate Out: storage ID 1 G LP10-01-02-05-041 / s J - / ____ 2 G LP10-01-02-05-042 3 G LP10-01-02-05-043 4 G LP10-01-02-05-044 5 G LP 10-01 -02-05 -04 5 6 G LP10-01-02-05-046 '/ O ___________t __________ f ________ 1______ 7 G LP10-01-02-05-047 8 G LP10-01-02-05-048 9 GLP10-01 -02-05-049 10 G LP 10-01-02-05-050 11 G L P 1 0 -0 1-0 2-0 5-0 51 12 G LP 10-01-02-05-052 13 G LP 10-01-02-05-054 14 G LP 10-01-02-05-055 15 G LP 10-01-02-05-056 16 G LP 10-01-02-05-057 17 G LP 10-01-02-05-058 18 G LP 10-01-02-05-059 19 G LP 10-01-02-05-060 20 G LP10-01-02-05-061 21 G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 22 G LP10-01-02-05-063 23 G LP10-01-02-05-064 24 G LP10-01-02-05-065 25 G LP10-01-02-05-066 26 G LP10-01-02-05-067 27 G LP10-01-02-05-068 28 G LP10-01-02-05-069 29 G LP10-01-02-05-070 30 G LP10-01-02-05-071 31 G L P 1 0 -0 1 -0 2 -0 5 -0 7 2 32 G LP 10-01-02-05-073 1 -- l InitJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 Page 137 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple set ID # Ums # N /A G LP10-01-02-05 S am ple Description: D ecatur S oils IN T E R N A L C H A IN O F C U S T O D Y # 3M Sample IDs Out: storage ID 33 G LP10-01-02-05-074 34 G LP10-01-02-05-075 1 35 G L P 1 0 -0 1 -0 2 -0 5 -0 7 6 ________ ________ 36 G LP10-01-02-05-077 37 G LP10-01-02-05-078 38 G LP10-01-02-05-079 39 G LP10-01-02-05-080 40 G LP10-01-02-05-081 41 G L P 1 0 -0 1 -0 2 -0 5 -0 8 2 42 G LP10-01-02-05-083 43 G LP10-01-02-05-084 44 G LP10-01-02-05-085 45 G LP10-01-02-05-087 46 G LP10-01-02-05-088 47 G LP10-01-02-05-089 48 G LP10-01-02-05-090 49 G LP10-01-02-05-091 50 G LP 10-01 -02-05-092 51 G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 52 G LP10-01-02-05-094 53 G LP10-01-02-05-095 54 G LP10-01-02-05-096 55 G LP10-01-02-05-097 56 G LP 10-01 -02-05-098 57 G LP 10-01 -02-05-099 58 G LP10-01-02-05-101 59 G LP 10-01 -02-05-102 60 G LP10-01-02-05-103 61 G L P 1 0-01 -0 2 -0 5 -1 0 4 62 G L P 10-01 -02-05-105 63 G LP10-01-02-05-106 64 G LP10-01-02-05-107 InitJdate ln: storage ID /sJ# * / InitJdate Out: storage ID \ _______________ ________ \_______ ______ _________ r\ _____Q ____ i___ InitJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02 Interim Report 05 Page 2 of 3 Page 138 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple set ID # Lims # N /A G LP10-01-02-05 S a m p le Description: D ecatur Soils # 65 66 67 68 69 70 71 72 73 74 75 IN T E R N A L C H A IN O F C U S T O D Y 3M Sample IDs Out: storage ID G LP10-01-02-05-108 G LP10-01-02-05-109 G LP10-01-02-05-111 G LP10-01-02-05-112 -/ _____1_______ G LP10-01-02-05-113 G LP 10-01 -02-05-114 G LP10-01-02-05-115 G LP10-01-02-05-116 G LP10-01-02-05-117 G LP10-01-02-05-118 G LP10-01-02-05-119 7 r/ . InitJdate In: storage ID InitJdate Out: storage ID / -- ____ / _____ ----- ----- 0\ _ InitJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02 Interim Report 05 Page 3 of 3 Page 139 of 962 3 *3 ^ fl) -o O r" 3 - -a eon o^ o K) TJ 0) CQ a> CD O) K) Sample ID Sample Description (Sg). Date of Original Extraction Diluted? Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Sam ple ID Sample Description Date of O rig in a l Extraction Diluted? Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No 1 2 34 5 6 7 8 G L P 10-01 -02*05-009 LMS DAL SD S D 04 0 0000 Lab M atrix Spike 10/2 5/2010 Yes No No No No G IP 10-01 -02-05-010 LMS DAL SD S D 04 0 0005 Lab M atrix Spike 10/25/2010 Yes No No No No GLP 10-01 -02-05-018 LMS DAL SD S D 08 DB 0000 Lab M atrix Spike 10/25/2010 Yes No No No No ' G LP 10-01 -02-05-019 LMS DAL SD S D 08 0 0005 Lab M atrix Spike 10/25/2010 Yes No No No No GLP 10-01-02-05-021 LMS DAL SD SD09 0 0000 Lab Matrix Spike 10/25/2010 Yes No No No No GLP10-01-02-05-022 LMS DAL SD SD09 0 0005 Lab Matrix Spike 10/25/2010 Yes No No No No G LP 1 0 -0 1 -0 2 -0 5 -0 2 3 DAL SD SD10 0 0000 10/25/2010 Yes No No No No GLP10-01-02-05-023 Dup DAL SD SD10 0 0000 Duplicate 10/25/2010 Yes No No No No GLP10-01-02-05-024 DAL SD SD10 0 0005 10/25/2010 Yes No No No No GLP 10-01 -02-05-024 Dup DAL SD SD10 0 0005 Duplicate 10/25/2010 Yes No No No No GLP 10-01 -02-05-025 LMS DAL SD S D 1 1 0 0000 Lab M atrix Spike 10/2 5/2010 Yes No NO No No GLP 10-01-02-05-027 LMS DAL SD SD12 0 0000 Lab Matrix Spike 10/2 5/2010 Yes No No No No GLP 10-01-02-05-028 LMS DAL SD SD12 DB 0000 Lab Matrix Spike 10/25/2010 Yes No No No No G LP 10-01 -02-05-029 LMS DAL SD S D 12 0 0 005 Lab M atrix Spike 10/25/2010 Yes No No No No GLP10-01-02-05-030 LMS DAL SD SD13 0 0000 Lab Matrix Spike 10/25/2010 Yes No No No No GLP10-01-02-05-031 LMS DAL SD SD13 0 0005 Lab Matrix Spike 10/25/2010 Yes No No No No G LP 10-01 -02-05-032 DAL SD SD14 0 0000 10/25/2010 Yes No No No No GLP10-01-02-05-032 Dup DAL SD SD14 0 0000 Duplicate 10/25/2010 Yes No No No No G LP 1 0 -0 1 -0 2 -0 5 -0 3 3 DAL SD SD14 0 0005 10/25/2010 Yes No No No No GLP10-01-02-05-033 Dup DAL SD SD14 0 0005 Duplicate 10/25/2010 Yes No No No No GLP10-01-02-05-034 DAL SD SD15 0 0000 10/25/2010 Yes No No No No GLP10-01-02-05-034 Dup DAL SD SD15 0 0000 Duplicate 10/2 5/2010 Yes No No No No GLP10-01-02-05-035 LMS DAL SD SD15 0 0005 Lab Matrix Spike 10/25/2010 Yes No No No No G LP 10-01 -02-05-036 DAL SD SD16 0 0000 10/25/2010 Yes No No No No GLP10-01-02-05-036 Dup DAL SD SD16 0 0000 Duplicate 10/25/2010 Yes No No No No G L P 1 0 -0 1 -02-05 -0 3 7 DAL SD SD 16D B 0000 10/25/2010 Yes No No No No GLP10-01-02-05-037 Dup DAL SD SD16 DB 0000 Duplicate 10/25/2010 Yes No No No No GLP10-01-02-05-038 LMS DAL SD SD16 0 0005 Lab Matrix Spike 10/25/2010 Yes No No No No G LP 1 0 -0 1 -0 2 -0 5-039 DAL SD SD17 0 0000 10/25/2010 Yes No No No No GLP 10-01 -02-05-039 Dup DAL SD SD17 0 0 000 D uplicate 10/25/2010 Yes No No G LP 10-01 -02-05-040 DAL SD SD17 0 0005 10/25/2010 Yes No No GLP10-01-02-05-040 Dup DAL SD SD17 0 0005 Duplicate 10/25/2010 Yes No No GLP10-01-02-05-023 LMS DAL SD SD10 0 0000 Lab Matrix Spike 10/25/2010 No Yes No GLP10-01-02-05-024 LMS DAL SD SD10 0 0005 Lab Matrix Spike 10/25/2010 No Yes No G L P 10-01 -02-05-032 LMS DAL SD S D 14 0 0 000 Lab M atrix Spike 10/25/2010 No Yes No GLP 10-01-02-05-033 LMS DAL SD S D H 0 0005 Lab Matrix Spike 10/2 5/2010 No Yes No G LP 10-01 -02-05-034 LMS DAL SD S D 15 0 0 000 Lab M atrix Spike 10/2 5/2010 No Yes No GLP 10-01 -02-05-036 LMS DAL SD S D 16 0 0 000 Lab M atrix Spike 10/2 5/2010 No No Yes GLP 10-01-02-05-037 LMS DAL SD SD16 DB 0000 Lab Matrix Spike 10/25/2010 No No Yes GLP 10-01-02-05-039 LMS DAL SD SD17 0 0000 Lab Matrix Spike 10/25/2010 No No Yes GLP10-01-02-05-040 LMS DAL SD SD17 0 0005 Lab Matrix Spike 10/25/2010 No No Yes No No No No No No No No No No No No No No No No No No No No No No No No * if extract to be diluted is a dilution from another previous dilution, enter the colum n num ber o f previous dilution and the final dilution factor in the space provided. Col 4: Volume of sample added*: 100 uL Col 5: Volume of sample added*: 20 uL Col 6: Volume of sample added*: 20 uL Volume of Diluent Added**: 900 uL Volume of Diluent Added**: 980 uL Volume of Diluent Added**: 980 uL Oiluent 10 M B-101021-07_______ Diluent ID M B-101021-07 Diluent ID M B-101021-04 Dilution Factor:__10 Dilution f a c to r__ 50____ Dilution Factor:__ 50 Int/Date. Int/Dato. Int/Date. * Pipette: E po e nd orf_ Model: Research ID .: 42155; /t- 'C * 3M Study GLP10-01-02 Interim Report 05 ** Pipette: E ppendorf____________ Model: Research______ ID .: 3824414 lnt/Date_ / / 'S P age 141 Sam ple ID S a m p le D e s c rip tio n Date o f O rig in a l Extraction D iluted? Yes/No Diluted?* Yes/No Diluted?* Y es/N o Diluted?* Yes/No Diluted?* Yes/No 12 GLP10-01-02-05-002 LMS DAL SD SD01 0 0000 Lab Matrix Spike 3 DF:10 4 Yes 3 No GLP10-01-02-05-003 LMS DAL SD SD01 0 0005 Lab Matrix Spike DF:10 Ye* No GLP 10-01-02-05-006 DAL SD SD03 0 0000 DF:10 Ye No GLP 10-01-02-05-006 Dup GLP 10-01-02-05-007 GLP 10-01-02-05-007 Dup DAL SD SD03 0 0000 Duplicate DAL SD SD03 0 0005 DAL SD SD03 0 0005 Duplicate OF:10 DF:10 DF:10 Yes Ye* Yes No No No GLP10-01-02-05-011 GLP10-01-02-05-011 Dup GLP10-01-02-05-012 DAL SD SD05 0 0000 DAL SD SD05 0 0000 Duplicate DAL SD SD05 0 0005 DF:10 DF:10 DF:10 Yes Yes Yes No No No GLP10-01-02-05-012 Dup DAL SD SD05 0 0005 Duplicate GLP 10-01-02-05-013 DAL SD SD06 0 0000 DF:10 DP: 10 Yes Yes No No GLP10-01-02-05-013 Dup DAL SD SD06 0 0000 Duplicate DF:10 Yes No GLP10-01-02-05-014 DAL SD SD06 0 0005 DF:10 Yes No GLP10-01-02-05-014 Dup GLP 10-01-02-05-017 GLP 10-01-02-05-017 Dup GLP 10-01-02-05-018 GLP 10-01-02-05-018 Dup GLP 10-01-02-05-026 GLP 10-01-02-05-026 Dup GLP 10-01-02-05-038 DAL SD SD06 0 0005 Duplicate DAL SDSD08 0 0000 DAL SD SD08 0 0000 Duplicate DAL SD SD08 DB 0000 DAL SD SD08 DB 0000 Duplicate DAL SD SD11 0 0005 DAL SD SD11 0 0005 Duplicate DAL SDSD16 0 0005 OF: 10 DF:10 OF:10 DF:10 DF:10 DF:t0 DF:10 DF:10 Ye* Yes Yes Yes Yes Ye* Yes Ye* No No No No No No No No GLP 10-01-02-05-038 Dup DAL SD SD16 0 0005 Duplicate GLP10-01-02-05-004 LMS DAL SD SD02 0 0000 Lab Matrix Spike DF:10 DF:100 Yes No No Ye* GLP10-01-02-05-005 LMS DAL SD SD02 0 0005 Lab Matrix Sbike DF:100 No Ye* GLP10-01-02-05-006 LMS DAL SD SD03 0 0000 Lab Matrix Spike DF:100 No Yes GLP10-01-02-05-007 LMS DAL SD SD03 0 0005 Lab Matrix Spike DF:100 No Yes GLP 10-01-02-05-009 LMS DAL SD SD04 0 0000 Lab Matrix Spike GLP10-01-02-05-010 LMS DAL SD SD04 0 0005 Lab Matrix Spike GLP 10-01-02-05-016 LMS DAL SD SD07 0 0005 Lab Matrix Spike GLP10-01-02-05-021 LMS DAL SD SD09 0 0000 Lab Matrix Spike GLP10-01-02-05-022 LMS DAL SD SD09 0 0005 Lab Matrix Spike GLP10-01-02-05-023 LMS DAL SD SD10 0 0000 Lab Matrix Spike GLP10-01 -02-05-024 DAL SDSD10 0 0005 GLP10-01-02-05-024 Dup DAL SD SD10 0 0005 Duplicate GLP10-01-02-05-025 LMS DAL SD SD11 0 0000 Lab Matrix Spike GLP10-01-02-05-027 LMS DAL SD SD12 0 0000 Lab Matrix Spike GLP10-01-02-05-028 LMS DAL SD SD12 DB 0000 Lab Matrix Spike DF:100 DF:100 DF:100 DF:100 DR100 DF:100 DR100 DR 100 DR100 DR100 DR 100 No No No No No No No No No No No Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No GLP 10-01-02-05-029 LMS DAL SD SD12 0 0005 Lab Matrix Spike DR 100 No No GLP 10-01-02-05-030 LMS DAL SD SD13 0 0000 Lab Matrix Spike DF:100 No No GLP 10-01-02-05-031 LMS DAL SD SD13 0 0005 Lab Matrix Spike DF:100 No No GLP10-01-02-05-032 DAL SD SD14 0 0000 GLP10-01-02-05-032 Dup DAL SD SD14 0 0000 Duplicate DF:100 DF:100 No No No No GLP 10-01-02-05-033 LMS DAL SD SD14 0 0005 Lab Matrix Spike DF:100 No No GLP 10-01-02-05-035 DAL SD SD15 0 0005 OF:100 No No GLP10-01-02-05-035 Dup GLP10-01-02-05-036 LMS GLP10-01-02-05-037 LMS GLP10-01-02-05-038 LMS GLP10-01-02-05-039 LMS GLP 10-01-02-05-040 LMS DAL SD SD15 0 0005 Duplicate DAL SD SD16 0 0000 Lab Matrix Spike DAL SD SD16 DB 0000 Lab Matrix Spike DAL SD SD16 0 0005 Lab Matrix Spike DAL SD SD17 0 0000 Lab Matrix Spike DAL SD SD17 0 0005 Lab Matrix Spike DF:100 OFHOO DF:100 DF: M 0F:100 F:100 No No No No No No No No No No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description Col 4: Volume of ample added*: 100 ul. Volume of Diluent Added**: 500 uL Oiluenl ID MB-101021-08__________ Dilution Factor 10 Col 5: Volume o f sample added*: 10 uL Volume of Diluent Added**: 990 uL Diluent ID MB-101021-06___________ Dilution Factor: 100 Int/Date ' Int/Date 67 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No Yes No Yes No Yes No Ye* No Ye* No Yes No Ye* No Ye* No Ye* No Ye* No Ye* No Ye* No Yes No Col 6: Volume of sample ai Volume of Diluent Added**: 990 uL Diluent ID MS-101021-09_______ Dilution Factor: 100 Int/Date_______________ s No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Pipette: Eppendorf___________ Model: Research______ LP: 1093467 Int/Date_ 3M Study GLP10-01-02 Interim Report 05 ** Pipette: Eppendorf Model: Research I.D.: 265893 Int/Date. 2o TJ` S- -o' 3 *3 ^ fl) -o O r" 3 - -a ocn o o o ho p * V \ ! D y c> "0 Q) CQ fl> CO o CD a> ho 3 *3 ^ fl) -o O 3 - r-a" o cn o o o ho V K $ 0 "0 Q) CQ fl> o CD O) ho iI I I i 3i f b 9*1 'S-? 3 - -a < o c? ! I!s Nl C cn o CD O) ho fi CD l i_ T I i'" ' tr ' & t" 5 & s '+ ft o 0 ' ii f s V i yi en a, fa. M \ _Ki rn 8 fa aM o c o c QCo c 0 1 or ^_50 O U o <3 O <;m m : O' o S "" S . c 1 o V c 1 o c a c S o )a ^5 3O 3 O C3 Ci o 5 <;0 c o c o cr^O o K c t oc o ^ oc T) T o c p c oc o c o c o c o c o a g 0 c a S 6 < > i < 6 5 t 66< c t > i > < > ; i i S : i ' S t s S . :n ,l < CC .: ! 1 1 1( i < ? > S > i i6 i6 ^ 5' > i i 6 ' > < ( o6 <c r i < i : < C > i t *' 6 < ( ! < t o c( P 4c i i I 6~1 ( 6 < ( t & ( 6 < 6 j < 6 i 6 6 < 6 < > c 6 < ( < < t 6 i > 3 < i i ifup ii f i" S1 I a<a ( 1 i Oo o Fa O aI ii r s ili :1 1 m i l if S fi i i ' ! i s 1 S%S a 3, S 5 1 S 5l l S ? S2 S ! 3 Sg 2 S S 2 2 gK 1" i 1A 1 i i ! i ! s ! I ! i ' S1 3 : i II i F S2 S 2 Sl aj 1 ! ? 11 i 3! 3j I ^1 n i > * 0 2 1 1S s m i I 11 o> :c O< S< a Sg y O> C> 0 1 oc 8 1o ao a c I< o>r- 0 1 rc> O> c: o a 0> 10 a 1 s 0 1 3 1 o f ^ 1 * r- i M S: Si 8 s i SI > SIS 2 g ! 11 ? 1 ! : i ; si 0 ilijlii 1 ;! 5 tS 6 9 f - M 1 |! i! 5 g ! e O> C 0( 1i i 3 i 0> a 1 1o 0 1 c> t ) Ic o> c> 0! 11 s EI fj s i lc !i o> c> 0( si 11 W i 0 o o< 0 1 II 11 m8. h 1 ;| 1 ?o> c> o> c: > o> c> o> c> ,O 0 <( O 0 i 0o>{ 0 <0 1 1 1 sj 1 1i 3j 1g 3 cgc s 1 op 1 1! i i 8s I 1 s i O> c o> :c s oc >>1 0 < ! i 6f S ' 2 ` 11 8S & rg. i; f s. i0 l g& j? i 11 j a t a 9. t ?i UAL as uH uj ua uuai uuoitcate DAL S S GP03 DB 0020 Lab Matrix S p ik a UALOiUbULKJUaLaDMauixpixa DAL SS SS06 DB OOOSLab Matrix Spike DAL SS GP02 DB 0020 Lab Matrix Spika O> C> a> 0 > r j n > 0 i OOK < c g0 O1 81 11 i g r & g Ii 1 3 3 g g.! S. 1 1 IS I g i j i. Sample ID Sample Description 1 ? 5 I fi v\ 1 J fliH 1 N y Ba * ................... ^ r i i * i 1y ii'i H !! 5 1 r? F? ? F? llf ii1 I ; ; fffM1 . ysaa E 5 F? F; it II i yZ y y 1 ySc S S?3 3 I i ? y 3 e 3 5y 3g i I! 1 i Ii iii a gg 53 8 g i S 3 g 5s ^ 8" Date of Original Extraction F F F F? ? 5 s F F F F F? F 8B * Diluted? Yes/No ? i 8 a 88 8 8 8 8S - Diluted?* Yes/No F? F ; f ' F s F f F- Diluted?* Yet/No C 1M r.L 8 8 ? 8 8 8 8 < F? : ) % < 1 F F? Ff F ' 5 5 I E 5 F F F F F F s e ? c F- Diluted?* Yes/No ? s? F ? F I =? ? ; F - Diluted?* Yes/No Sample ID Sample D e s c rip tio n Date of Original E x tr a c tio n Diluted? Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No 1 GLP10-01-02-05-045 LMS GLP10-01 -02-05-046 LMS GLP 10-01-02-05-047 LMS G LP 10-01-02-05-051 GLP10-01-02-05-051 Dup GLP 10-01-02-05-051 LMS GLP 10-01-02-05-052 LMS GLP10-01 -02-05-058 LMS 2 DAL SS SS03 0 0000 Lab Matrix Spike DAL SS SS03 0 0005 Lab Matrix Spike DAL SS SS03 DB 0005 Lab Matrix Spike DAL SS SS05 0 0000 DAL SS SS05 0 0000 Duplicate DAL SS SS05 0 0000 Lab Matrix Spike DAL SS SS05 0 0005 Lab Matrix Spike DAL SS SS07 0 0005 Lab Matrix Spike 34 5 6 8 11/16/2010 Yes No No No No 11/16/2010 Yes No No No No 11/16/2010 Yes No No No No 11/16/2010 Yes No No No No 11/16/2010 Yes No No No No 11/16/2010 Yes No No No No 11/16/2010 No Yes No No No 11/16/2010 No Yes No No No GLP10-01-02-05-074 LMS GLP 10-01-02-05-075 LMS GLP 10-01-02-05-076 LMS DAL SS GP03 0 0005 Lab Matrix Spike DAL SS GP03 0 0020 Lab Matrix Spike DAL SS GP03 DB 0020 Lab Matrix Spike 11/16/2010 No Yes No No No 11/16/2010 No Yes No No No 11/16/2010 No Yes No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description Col 4: Volume of sample added*: IQ uL Col S: Volume of sample added*: 11 Volume of Diluent Added**: 990 uL Volume of Diluent Added**: 990 uL Diluent ID MB-101116-04_______ Diluent ID MB-101116-05_______ Dilution Facti / atnt/Date. - . = 7 0 * Pipette: Eppendorf_______ Model: Research______ I.D.: 4215537 In t/D n te ^ ** Pipette: Eppendorf Model: Research I.D.: 265893 S"tnt/Date 3M Study GLP10-01-02 Interim Report 05 Page 147 of 962 S am ple ID S am ple D e s c rip tio n Date of O riginal E x tra c tio n D ilu te d ? Yes/No Diluted?* Yes/No D ilu te d ?* Yes/No Diluted?* Yes/No Diluted?* Yes/No 1 GLP10-01-02-05-095 Dup GLP10-01-02-05-101 LMS GLP10-01-02-05-106 LMS GLP10-01-02-05-107 LMS GLP10-01-02-05-108 LMS GLP10-01-02-05-109 LMS GLP10-01-02-05-082 LMS GLP10-01-02-05-083 LMS GLP10-01-02-05-084 G LP10-01-02-05-085 LMS GLP10-01-02-05-088 LMS GLP10-01-02-05-089 LMS GLP10-01-02-05-098 LMS GLP10-01-02-05-099 LMS GLP10-01-02-05-104 LMS GLP10-01-02-05-106 GLP10-01-02-05-106 Oup GLP10-01-02-05-107 GLP10-01-02-05-107 Dup GLP10-01-02-05-1 1 LMS GLP10-01-02-05-112 LMS GLP10-01-02-05-113 LMS GLP10-01-02-05-114 LMS GLP10-01-02-05-115 GLP10-01-02-05-115 Dup GLP10-01-02-05-115 LMS GLP10-01-02-05-116 GLP10-01-02-05-116 Dup GLP10-01-02-05-117 LMS GLP10-01-02-05-118 LMS GLP10-01-02-05-092 LMS GLP10-01-02-05-093 LMS G LP10-01-02-05-094 GLP10-01-02-05-094 Dup G L P 1 0 -0 1 -0 2 -0 5 -0 9 5 G LP10-01-02-05-091 LMS GLP10-01-02-05-092 GLP10-01-02-05-092 Dup G L P 1 0 -0 1 -0 2 -0 5 -0 9 3 GLP10-01-02-05-093 Dup G LP 10-01 -02-05-096 GLP10-01-02-05-096 Dup GLP10-01 -02-05-096 LMS G LP10-01-02-05-097 GLP10-01-02-05-097 Dup GLP10-01-02-05-097 LMS GLP10-01-02-05-102 GLP10-01-02-05-102 Dup GLP10-01-02-05-103 Dup GLP 10-01-02-05-106 LMS GLP10-01-02-05-107 LMS GLP10-01-02-05-116 LMS GLP10-01-02-05-094 LMS GLP10-01-02-05-095 LMS G LP10-01-02-05-101 GLP10-01-02-05-101 Dup GLP10-01-02-05-101 LMS GLP10-01-02-05-102 LMS GLP10-01-02-05-103 GLP10-01-02-05-103 LMS GLP10-01-02-05-094 LMS GLP10-01-02-05-095 Dup 2 DAL SS GP08 0 0000 Duplicate DAL SS GP09 0 0000 Lab Matrix Spike DAL SS GP10 0 0000 Lab Matrix Spike DAL SS GP10 0 0005 Lab Matrix Spike DAL SS GP10 0 0020 Lab Matrix Spike DAL SS GP10 0 0060 Lab Matrix Spike DAL SS GP05 0 0000 Lab Matrix Spike DAL SS GP05 0 0005 Lab Matrix Spike DAL SS GP05 0 0020 DAL SS GP05 0 0055 Lab Matrix Spike DAL SS GP06 0 0005 Lab Matrix Spike DAL SS GP06 0 0020 Lab Matrix Spike DAL SS GP08 0 0020 Lab Matrix Spike ' DAL SS GP08 0 0050 Lab Matrix Spike DAL SS GP09 0 0020 Lab Matrix Spike DAL SS GP10 0 0000 DAL SS GP10 0 0000 Duplicate DAL S SG P10 0 0005 DAL SS GP10 0 0005 Duplicate DAL SS G P11 0 0000 Lab Matrix Spike DAL SS G P11 0 0005 Lab Matrix Spike DAL SS G P11 0 0020 Lab Matrix Spike DAL SS G P11 0 0065 Lab Matrix Spike DAL SS GP11 DB 0065 DAL SS GP11 DB 0065 Duplicate DAL SS G P11 DB 0065 Lab Matrix Spike DAL SS GP12 0 0000 DAL SS GP12 0 0000 Duplicate DAL SS GP12 0 0005 Lab Matrix Spike DAL SS GP12 0 0020 Lab Matrix Spike DAL SS GP07 0 0005 Lab Matrix Spike DAL SS GP07 0 0020 Lab Matrix Spike DAL SS GP07 0 0130 DAL SS GP07 0 0130 Duplicate DAL SS GP08 0 0000 DAL SS GP07 0 0000 Lab Matrix Spike DAL SS GP07 0 0005 DAL SS GP07 0 0005 Duplicate DAL SS GP07 0 0020 DAL SS GP07 0 0020 Duplicate DAL SS GP08 0 0005 DAL SS GP08 0 0005 Duplicate DAL SS GP08 0 0005 Lab Matrix Spike DAL SS GP08 DB 0005 DAL SS GP08 DB 0005 Duplicate DAL SS GP08 DB 0005 Lab Matrix Spike DAL SS GP09 0 0005 DAL SS GP09 0 0005 Duplicate DAL SS G P09 DB 0005 Duplicate DAL SS GP10 0 0000 Lab Matrix Spike DAL SS GP10 0 0005 Lab Matrix Spike DAL SS GP12 0 0000 Lab Matrix Spike DAL SS GP07 0 0130 Lab Matrix Spike DAL SS GP08 0 0000 Lab Matrix Spike DAL SS GP09 0 0000 DAL SS GP09 0 0000 Duplicate DAL SS GP09 0 0000 Lab Matrix Spike DAL SS GP09 0 0005 Lab Matrix Spike DAL SS GP09 DB 0005 DAL SS GP09 DB 0005 Lab Matrix Spike DAL SS GP07 0 0130 Lab Matrix Spike DF:10 DAL SS GP08 0 0000 Duplicate DF:10 3M Study GLP10-01-02 Interim Report 05 3 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 4 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Page 1 of 2 5 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes Yes Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No 6 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No 7 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes Yes Yes Yes Yes Yes Yes No No 8 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes G LP 10-01 *02-05-095 LMS G LP 10-01 -02-05-101 GLP 10-01 -02-05*101 Dup GLP10-01-02-05-101 LMS GLP 10-01 -02-05-102 LMS G LP10-01-02-05-103 GLP10-01-02-05-103 LMS DAL SS GP08 0 0000 Lab Matrix Spike DF:10 DAL SS GP09 0 0000 DF:10 DAL SS GP09 0 0000 Duplicate DF:10 DAL SS GP09 0 0000 Lab Matrix Spike DF:10 DAL SS GP09 0 0005 Lab Matrix Spike DF:10 DAL SS GP09 DB 0005 DF:10 DAL SS GP09 DB 0005 Lab Matrix Spike DF:10 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 12/3/2010 No No No No No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description Col 4: Volume of sample added*: 100 uL Volume of Diluent Added**: 900 uL Col 5: Volume of sample added*: 10 uL Volume of Diluent Added**: 990 uL Dilution Factor: 10 Diluent ID___ MB-101203-07. Lwuuuii No No No No No No No . No No . No No No No No No No No No No No No Col 6: Volume of sample added*: 20 uL Volume of Diluent Added**: 980 uL Diluent ID___ MB-101203-08__ Dilution Factor: 50 Col 7: Volume of sample added*: 100 uL Volume of Diluent Added**: 900 uL MB-101203-08 in F d flo r^ O Col 8: Volume of sample added*: 20 uL Volume of Diluent Added**: 980 uL Diluent ID MB-101104-1 Yes Yes Yes Yes Yes Yes Yes * _ %. * Pipette: Eppendorf Model: Research I.D.: 4215537 y ** Pipette: Eppendorf Model: Reference I.D.: 3624414 _ Int/Date 3M Study GLP10-01-02 Interim Report 05 Page 2 of 2 Page 149 of 962 S am ple ID Sam ple Description Date of O riginal E x tra c tio n D iluted? Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No 1 2 34 5 6 78 G LP 10-01 -02*05*084 LMS DAL SS GP05 0 0020 Lab Matrix Spike 12/3/2010 Yes No No No No G LP 10-01 -02-05-085 DAL SS GP05 0 0055 12/3/2010 Yes No No No No GLP 10-01 -02-05-085 Dup DAL SS G P05 0 0055 Duplicate 12/3/2010 Yes No No No No GLP10-01-02-05-087 LMS DAL SS G P06 0 0000 Lab Matrix Spike 12/3/2010 No No No No No GLP10-01-02-05-091 DAL SS GP07 0 0000 12/3/2010 No No No No No GLP10-01-02-05-Q91 Dup DAL SS GP07 0 0000 Duplicate 12/3/2010 No No No No No G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 DAL SS SS04 0 0000 11/16/2010 No No No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description a new aliquot of the extracted curve from 12/3/10 and method blanks 1& 4 were taken to be analyzed with the dilutions Col 4: Volume of sample added*: 50 uL Col 5: Volume of sample added*: 100uL Col 6: Volume of Diluent Added**: 950 uL Volume of Diluent Added**: 900 uL Diluent ID MB-101203-05 Diluent ID MB-101203-06 Dilution Factor: 20 Oilution Factor: 10 tnt/Dflla fnt/Oate. Col 7: Col 8: * Pipette: Eppendorf____________ Model: Research______ I.D.: 4215537 Inl/D.l. ^ ** Pipette: Eppendorf Model: Reference I.D.: 3824414 InUDato 3M Study G LP10-01-02 Interim R eport 05 Page 1 of 1 Page 150 of 962 G lP lO -0 1 -0 2 -0 5 ETS-8-053 Samples Extracted 4-Jan-2011 3M Study GLP10-01-02 Interim Report 05 Page 1 o f 2 C f* P age 151 o f 962 i-H -U GlPlO-01-02-05 rrs-8-053 Samples Extracted 4-Jan-2011 Sample ID GLP10-01-02-05-076 LMS GLP10-01-02-05-078 GLP10-01-02-05-078 Dup GLP10-01-02-05-078 LMS GLP10-01-02-05-094 GLP10-01-02-05-094 Dup GLP10-01-02-05-094 LMS GLP10-01-02-05-095 GLP10-01-02-05-095 Dup GLP10-01-02-05-095 LMS GLP10-01-02-05-103 GLP10-01-02-05-103 Dup GLP10-01-02-05-103 LMS GLP10-01-02-05-107 GLP10-01-02-05-107 Dup GLP10-01-02-05-107 LMS GLP10-01 -02-05-108 GLP10-01-02-05-108 Dup GLP10-01-02-05-108 LMS GLP10-01 -02-05-109 GLP10-01-02-05-109 Dup GLP10-01-02-05-109 LMS MB-110103-07 Sample Description Soli Matrix ID Soil Weight Used(g) 8pike ID Spike Volume (uL) Internal In te rn a l Standard Standard ID Volume (uL) Surrogate Spike ID ___________________ 2___________________ DAL SS GP03 DB 0020 Lab Matrix Spike 3 DAL SS GP04 0 0000 DAL SS GP04 0 0000 Duplicate DAL SS GP04 0 0000 Lab Matrix Spike -- ......... -- DAL SS GP07 0 0130 DAL SS GP07 0 0130 Duplicate DAL SS GP07 0 0130 Lab Matrix Spike DAL SS GP08 0 0000 DAL SS GP08 0 0000 Duplicate DAL SS GP08 0 0000 Lab Matrix Spike DAL SS GP09 DB 0005 ---- DAL SS GP09 D8 0005 Duplicate DAL SS GP09 DB 0005 Lab Matrix Spike DAL SS GP10 0 0005 DAL SS GP10 0 0005 Duplicate DAL SS GP10 0 0005 Lab Matrix Spike DAL SS GP10 0 0020 .-- - DAL SS GP10 0 0020 Duplicate DAL SS GP10 0 0020 Lab Matrix Spike -- DAL SS GP10 0 0060 DAL SS GP10 0 0060 Duplicate DAL SS GP10 0 0060 Lab Matrix Spike Method Blank w/ IS for Dilutions M 0005-244| 4 1.8394 1.4481 1.6293 1.3933 1.3436 1.1557 1.4493 1.5511 1.5928 1.5770 1.3197 1.5208 1.5694 1.1863 0.9962 1.0652 1.4094 1.6861 1.3786 1.2561 1.3475 1.5500 4.9120 5 67 10 006-16 . * 1' - 10 006-16 . * 10 006-16 M U .~ ri 10 006-16 W s s & u . 10 006-16 10 006-16 10 006-16 UM 1 V; 10 006-16 10 006-16 * ; *' 10 006-16 * V - 10 006-16 *V fih * < i# * i* .* * t * * L l > 10 006-16 iT W K & M .V . . 10 006-16 10 006-16 a-- -- 1 I . `.-4 in -- n 1-- t *" 10 006-16 10 006-16 10 006-16 10 006-16 * ! 10 006-16 B 10 006-16 10 006-16 j ____ > 10 006-16 * 10 006-16 8 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 150 9 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 10 010-37 Col 3 & 4: N/A Balance ID: 800 C0I S & 6: h * - Pipette ID: 3402277 Pipette ID: 265893 (for volumes > 100uL) C ol7 & 8 : Pipette ID: 3402277 Pipette ID: 265893 (for volumes > 100uL) Col 9 & 10: C * * * I ' H - l t Pipette ID: 3402277 Pipette ID: 265893 (for volumes > 100uL) Col 11 & 12: Pipette ID: 3402277 Surrogate Spike Volume (uL) PFBS Spike IO PFBS 8plke Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Extraction Solvent Volume (mL) Sonicate 1 hr Centrifuge 10 11 12 13 14 15 18 30 s 10 007-5-1 5- mmm mmm30 30 * 1 30 ` s a s s m w - - E3 E S R - * H M * * . ' - 10 007-5-2 100 30 m m m m 30 30 10 007-3-3 25 10 007-4-2 30 M W 30 m m m m i i i l i l t t l 30 10 007-3-4 50 10 007-4-2 m m m25 mmmm sV %, :" 25 10 007-5-1 50 30 ' , 'W M H M SS 30 S ui mm* m a r n i30 S i i * 10 007-4-2 10 007-5-1 50 30 m m m m a m 30 mmmm 30 10 007-3-3 b e h 1 v H R * H mmm 30 | v - ,r * S i 30 | 30 | 10 007-3-3 S 2 H100 l i j l f l B B I I i 30 | M M M M 1 30 m a m m a - 1 8--30 \ 10 007-3-3 | ) 007-4-2 25 150 i_____ 10 007-5-2 ! 50 17 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 6 8 8 8 8 8 40 Col 13 & 14: Pipette ID: 3402277 Col 17: /-y -M Extraction Solvent ID: 10 006-35 Col 15 & 16: C r * * Pipette ID: 3402277 * comb: 6 / * * * Sonicator ID: QEJ100595003 16 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM Col 19: r G a w I 1 Centrifuge ID: 021188-55 769613 (for 50mL tubes) 10 min @ 3000 RPM Comments 20 ................................. ( 3M Study GLP10-01-02 Interim Report 05 Page 2 o f 2 Page 152 of 962 G lP lO -0 1 -0 2 -0 5 ETS-8-OS3 Samples W eighed 3-Jan-2011 Sample Description Soli Weight Soil Matrix ID Used (g) Spike ID Spike Volume (uL) Internal Internal Standard Standard ID Volume (uL) Surrogate Spike ID . Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volume <uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL> Extraction Solvent Volume (mL) Sonicate 1 hr EC-110103-05 0.75 ng Extracted Curve Point 1 ng Extracted Curve Point 2.5 ng Extracted Curve Point 5 ng Extracted Curve Point 10 ng Extracted Curve Point EC-110103-08 EC-110103-09 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 ng Extracted Curve Point 200 ng Extracted Curve Point EC-110103-12 MB-110103-01 MB-110103-02 MB-110103-03 MB-110103-04 MB-110103-06 500 ng Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w /o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w / IS L C S -1 1 0 1 0 3 -0 1 LCS-110103-02 LCS-110103-03 LCS-110103-04 LCS-110103-05 LCS-110103-06 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3 ng LCS in TCR-842 30 ng LCS In TCR-842 30 ng LCS In TCR-842 30 ng LCS in TCR-842 GLP10-01-02-05-002 GLP10-01-02-05-002 Dup GLP10-01-02-05-002 LMS GLP10-01-02-05-003 DAL SD SD01 0 0000 DAL SD SD01 0 0 000 Duplicate DAL S D SD01 0 0 000 Lab Matrix Spike DAL SD SD01 0 0005 GLP10-01-02-05-003 Dup G LP10-01-02-05-003 LMS G L P 1 0-0 1-02 -0 5-01 5 G LP10-01-02-05-015 Dup GLP10-01-02-05-015 LMS G L P 1 0-0 1-02 -0 5-02 3 G LP10-0 1-02 -0 50 23 Dup GLP10-01-02-05-023 LMS G L P 1 0-0 1-02 -0 5-02 4 GLP10-01-02-05-024 Dup GLP10-01-02-05024 LMS GLP10-01-02-05-032 G LP10-0 1-02 -0 50 32 Dup GLP10-01-02-05-032 LMS GLP10-01-02-05-033 GLP10-01-02-05-033 Dup GLP10-01-02-05-033 LMS G L P 1 0-0 1-02 -0 5-03 4 GLP10-01-02-05-034 Dup GLP10-01-02-05-034 LMS GLP10-01-02-05-040 GLP10-01-02-05-040 Pup DAL S D SD01 0 0 005 Duplicate DAL S D SD01 0 0 005 Lab Matrix Spike DAL S D SD07 0 0000 DAL SD SD 07 0 0 000 Duplicate DAL S D SD 07 0 0 000 Lab Matrix Spike DAL SD SD10 0 0000 DAL S D SD 10 0 0 000 Duplicate DAL S D S D 10 0 0 000 Lab Matrix Spike DAL SD SD10 0 0005 DAL S D SD 10 0 0005 Duplicate DAL S D SD 10 0 0005 Lab Matrix Spike DAL SD SD14 0 0000 DAL S D SD 14 0 0 000 Duplicate DAL S D SD 14 0 0 000 Lab Matrix Spike DAL SD SD14 0 0005 DAL S D SD 14 0 0005 Duplicate DAL S D SD 14 0 0005 Lab Matrix Spike DAL SD SD15 0 0000 DAL S D SD 15 0 0 000 Duplicate DAL S D SD 15 0 0000 Lab Matrix Spike DAL SD SD17 0 0005 DAL S D SD 17 0 0005 Duplicate GLP10-01-02-05-040 LMS G L P 1 0-0 1-02 -0 5-04 8 DAL S D SD 17 0 0005 Lab Matrix Spike DAL SS SS04 0 0000 GLP10-01-02-05-048 Dup GLP10-01-02-05-048 LMS G L P 1 0-0 1-02 -0 5-06 3 DAL S S SS04 0 0000 Duplicate DAL S S SS04 0 0000 Lab Matrix Spike DAL SS SSOg 0 0005 GLP10-01-02-05-063 Dup GLP10-01-02-05-063 LMS DAL SS SS0S 0 0 005 Duplicate DAL SS SS 09 0 0005 Lab Matrix Spike G L P 1 0-0 1-02 -0 5-07 6 GLP10-01-02-05-076 Dup DAL SS GP03 DB 0020 DAL S S G P 03 PB 0 020 Duplicate 3M Study GLP10-01-02 Interim Report 05 --________ . IM I --- M aw - mi v* --i mm m m 111 Ml J-- a-- mmt- --* -- f ilili * i M l* H K illlS i--s am m a m i -- .g mm a lili --sa M R * * illiplysgli s m -- mmtmm * Sill u mm M__i____ r _____________ ife l ma -- m- if f 'i i* Ml -- - ass-- --I IS M t p rs jl -- -- 1-- warn -- MM M --I a I S r i f l i l i l IIS lA Hrm-- tru sa HI -- m itili ir : ,m n B Pi l l ! 111 i ______ wmmm w o rn -- -- -- -- p im - m m 'm M IM I -- WMMi a 1* a * 11! I-- ---- a M-- ml mam a--B-- I--m m -- -- `________ m r.-m s msmmi mm B if mmmm f H H iS M H b SMI 111 mm *w mw * h im BBBbBB: -- i1 i MM -- mm -- I am M mu WKSm M-- m# < f M iS ll W KSPI Hr f.-m mb-- -- *________ lim i -- W-- f m a MM 8 H /m p m o o m M 8 aa -- MMSMW i -- --a -- mm fi-- m - u--n i im--am _______ i w M Ca* 4 M -= . a 6S-- m i W ff- __________ a-- _____________ ____ H -- MM M il "r n g i r - * mmm&sMm;-- mss&s&wxi BU a wm*m aws HmEaM* mu -- W H hem -- I a M l M b JM y w M il 1111 I -, BiiilBB mm I R M t i W IB B iiB -- --M l l i l 1 mib ; --g - " g l - mm BBBlilll B a i li ai 1M l fg m m m m ---- iis iftiim iii a-- M lili! II -- iM -- IB B B I I B B lilS B il ----i l l I IBIBbBIb IB I!- m im m i -- a---- -- m m m -- i g a ll BM-- 1 -- y w s tm m m -- - mmmsm m m U m ---- Page l o f 2 Page 153 of 962 Qfm 1- 3- Il GLPlO-01-02-05 ETS-8-053 Col 3 1 4 : G fr ~ \ Balance ID: 900 /-}, || Samples W eighed 3-Jan-2011 3M Study GLP10-01-02 Interim Report 05 Page 2 o f 2 Page 154 of 962 S a m p le ID D a te o f O rig in a l E x tra c tio n D ilu te d ? Y es/N o D ilu te d ? * Y es/N o D ilu te d ? * Y es/N o D ilu te d ? * Y es/N o D ilu te d ? * Y es/N o 1 G L P 10-01-0 2 -0 5 -0 1 5 GLP10-01-02-05-015 Dup GLP10-01-02-05-015 LMS G LP10 -01-02-05-023 GLP10-01-02-05-023 Dup GLP10-01-02-05-023 LMS G LP10 -01-02-05-024 GLP10-01-02-05-024 Dup GLP10-01-02-05-024 LMS G L P 10-01-0 2 -0 5 -0 3 2 GLP10-01-02-05-032 Dup GLP10-01-02-05-032 LMS G LP10 -01-02-05-048 GLP10-01-02-05-048 Dup GLP10-01-02-05-048 LMS G LP10 -01-02-05-076 GLP10-01-02-05-076 Dup GLP10-01-02-05-076 LMS G L P 10 -01-02-05-078 GLP10-01-02-05-078 Dup GLP10-01-02-05-078 LMS G LP10-01-02-05-095 GLP10-01-02-05-095 Dup G LP10-01-02-05-095 LMS G LP10 -01-02-05-103 GLP10-01-02-05-103 Dup G LP10-01-02-05-103 LMS G LP10 -01-02-05-109 G LP10-01 -02-05-109 Dup GLP10-01-02-05-109 LMS 2 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 1/4/2011 34567 Yes NO - NO . NO. NO Yes NO NO N= NO Yes NO , NO * NO No Yes No No V No No Yes NO . . . . NO -. U tN . NO Yes No % No - No Yes No f V . . . . ` No t ,i*ftr> N o i * , No - Yes N o V 'V 'i No -.i# -N t> * Y . ' No Yes No No 'i.y S i N o' No - Yes NO NO ' - N O NO Yes NO No . . No No Yes NO,' NO - A n o . NO Yes Yes no A V . . : . No. ; . , ^ - N o ; ,:- ; i . , No' - - Yes N o ' ^ S ' " ' V , No A J H E 'N O ..' : N t,' * Yes n o: V s' n o -.' ^ ' n o :'. 1 ' . no Yes NO- .'-N . < -^ N 0 . N O .- Yes NO , . . . N 0 / N o NO Yes *** - Yes N 0 .f.. / NO , - ( N0 * NO Yes N o i-ftT k 'NO N. - * t.N o -~ Yes ^ - ^ N o ;- Yes 0- ; / . . . ? . - , - . = '^ noA * ' Yes NO - -N O . NO .N i Yes NO . NO A No NO Yes N O , .- T . NO ,/,N 0 ... -No. Yes N o ^ : a : s .':.'N o \ *** Yes li E s / " H Es 1 Yes ' M n ' ^ t *- W *1 J ^ '% Yes .N .W i . r N. ..:.n o .... " *1 * ' * ' N ?W l No no - 'N o - . no '..N o .- No .n o - * If extract to be diluted is a dilution from another previous dilution, enter the column num ber of previous dilution and the final dilution factor in the space provided. Col 3: Volume of sample added*: 10 uL Volume of Diluent Added**: 990 uL Diluent ID MB-110103-07 * Pipette: Eppendorf Model: Research_______ ** Pipette: Eppendorf______ Model: R esearch_______ Dilution Factor 100 G?Int/Date I f I.D.: 3402277 Int/Date / - `f - t ) ID .: 265893 Int/Date 6 / * * * 3M Study GLP10-01-02 Interim Report 05 Page 155 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple se t ID # Lim s # N /A G LP10-01-02-05 S am ple D escription: Decatur S oils # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 IN TER N AL CHAIN OF CUSTODY 3M Sample IDs Out: storage ID G L P 1 0-01 -01 -05-001 G L P 1 0-01 -01 -0 5 -0 0 2 G L P 1 0-01 -01 -0 5 -0 0 3 G L P 10-01 -0 1 -0 5 -0 0 4 l)R o\ \ \ G L P 10-01 -0 1 -0 5 -0 0 5 G LP 10-01-01-05-006 G LP 10-01 -0 1 -0 5 -0 0 7 _____ \_________ G L P 1 0-01 -01 -0 5 -0 0 9 G LP 10-01-01-05-010 G LP10-01-01-05-011 G LP 10-01-01-05-012 G LP 10-01-01-05-013 G L P 1 0-01 -01 -0 5 -0 1 4 G L P 1 0-01 -01 -0 5 -0 1 5 G LP 10-01 -01 -0 5 -0 1 6 G LP 10-01-01-05-017 G LP 10-01-01-05-018 G LP 10-01-01-05-019 G LP 10-01-01-05-021 G LP 10-01-01-05-022 G LP 10-01-01-05-023 G LP 10-01-01-05-024 G LP10-01-01-05-025 G LP 10-01-01-05-026 G LP 10-01-01-05-027 G LP 10-01-01-05-028 G LP 10-01-01-05-029 G L P 10-01-01-05-030 G LP 10-01-01-05-031 G LP 10-01-01-05-032 G LP 10-01-01-05-033 G LP 10-01-01-05-034 V Init./date /- 3 - II \J In: storage ID io # \a \ Init./date C.f'- 1 - 3 - II \ Out: storage ID ___________ Init./date 1 j 1 / / / s/ y / / / / \ J 'N X / ________ In: storage ID Init./date Comments/lnit./date / / / / / / / / / / .V / vV VV */ / / / / / / 3M Study GLP10-01-02 Interim Report 05 Page 1 of 4 Page 156 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple se t ID # Lim s # N /A G L P 1 0-0 1 -0 2 -0 5 S am ple D escription: D ecatur Soils IN TE R N A L CHAIN O F CUSTO DY # 3M Sample IDs Out: storage ID Init./date In: storage ID Init./date Out: storage ID Init./date In: storage ID Init./date Comments/Inlt./date 33 G LP10-01-01-05-035 34 G LP10-01-01-05-036 35 G LP10-01-01-05-037 36 G LP10-01-01-05-038 37 G LP10-01-01-05-039 38 G LP10-01-01-05-040 114 G LP 10-01-02-05-041 115 G LP10-01-02-05-042 116 G LP10-01-02-05-043 117 G LP10-01-02-05-044 118 G LP10-01-02-05-045 119 G LP10-01-02-05-046 120 G LP10-01-02-05-047 121 G L P 1 0 -0 1 -0 2 -0 5 -0 4 8 122 G LP 10-01-02-05-049 123 G LP10-01-02-05-050 124 G LP10-01-02-05-051 Iv' .O l (.e r-1 to -! __ IL M C eri /-3-/I y / / / / / / / / / / / */ \v ^ vV V 125 G LP10-01-02-05-052 126 G LP10-01-02-05-054 127 G LP10-01-02-05-055 128 G LP10-01-02-05-056 129 G LP10-01-02-05-057 130 G LP10-01-02-05-058 131 G L P 1 0 -0 1 -0 2 -0 5 -0 5 9 132 G LP 10-01-02-05-060 133 G LP10-01-02-05-061 134 G LP10-01-02-05-062 135 G LP10-01-02-05-063 136 G LP10-01-02-05-064 137 G LP10-01-02-05-065 138 G LP10-01-02-05-066 139 G LP10-01-02-05-067 l \ 1 V / / / / \/ / / \/ \/ \/ / / \lU / \1> >y y 3M Study GLP10-01-02 Interim Report 05 Page 2 of 4 Page 157 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple set ID # Ums # N /A G L P 1 0-0 1 -0 2 -0 5 S am ple D escription: D ecatur S oils # 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 IN T E R N A L C H A IN O F C U S T O D Y 3M Sample IDs Out: storage /D< !r!vlnlt./date G LP10-01-02-05-068 G LP 10-01 -02-05 -06 9 r.t* )-- GLP10-01 -02-05-070 G LP 10-01 -02-05-071 G LP 10-01 -02-05-072 G LP10-01-02-05-073 G LP 10-01 -02-05-074 G LP10-01-02-05-075 G LP10-01-02-05-076 G LP10-01-02-05-077 G LP10-01-02-05-078 G LP10-01-02-05-079 G LP10-01-02-05-080 G LP10-01-02-05-081 G LP10-01-02-05-082 G LP10-01-02-05-083 G LP10-01-02-05-084 G LP10-01-02-05-085 G LP10-01-02-05-087 G LP10-01-02-05-088 G LP10-01-02-05-089 G LP10-01-02-05-090 G LP 10-01-02-05-091 G LP 10-01 -02-05-092 G LP10-01-02-05-093 I G LP10-01-02-05-094 G LP10-01-02-05-095 G LP10-01-02-05-096 G LP10-01-02-05-097 G LP10-01-02-05-098 G LP10-01-02-05-099 G LP 10-01-02-05-101 -AZ In: storage ID Cj * o\ \ *<s Init./date Out: storage ID Ofim t - l - h Init./date ln: storage ID Init./date Comments/lnit./date / / // / / / / / / / / / / / / \v / n/ \/ .f/ yy / / / / y / / / / Ad - ' _____________ 3M Study GLP10-01-02 Interim Report 05 Page 3 of 4 Page 158 of 962 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer S am ple set ID # Lim s # N /A G LP10-01-02-05 S am ple D escription: D ecatur Soils IN T E R N A L C H A IN O F C U S T O D Y # 3MSample IDs Out: storage ID InitJdate In: storage ID 172 G L P 1 0-01 -02-05-102 173 G LP 10-01-02-05-103 174 G LP 10-01-02-05-104 175 G LP 10-01-02-05-105 < P ' ......... Cm /-!3- H U ftQ '______ \ _____ ______ 176 G LP 10-01-02-05-106 177 G LP 10-01-02-05-107 178 G LP 10-01-02-05-108 179 G LP 10-01-02-05-109 180 G LP 10-01-02-05-111 181 G L P 1 0 -0 1 -0 2 -0 5 -1 1 2 182 G L P 1 0-01-02-05-113 183 G L P 1 0-01-02-05-114 184 G L P 1 0-01-02-05-115 185 G LP 10 -01 -02 -05-116 186 G L P 1 0 -0 1 -0 2 -0 5 -1 17 187 G L P 1 0-01-02-05-118 188 G LP 10-01-02-05-119 \. *4/ \ InitJdate \V Out: storage ID InitJdate sy y _________ ln: storage ID ny * InitJdate Comments/InltJdate __ y 3M Study GLP10-01-02 Interim Report 05 Page 4 of 4 Page 159 of 962 DATA REVIEW SUMMARY FORM Date: 1/5/2011________ Data Analyst: mmh Study #: GLP10-01-02-05 Description: Decatur Soils Batch: s!01122a Results Table: s!01122a.rdb instrument: StanV1660305 Method(s): ETS-8-053.0 Analyte: PFBS Comments/Justifications: _1________________ Acceptable Linear Range: 0,500 ng to 500 ng Internal Standard: MPFBS__________ LOQ: 0,500 ng_____________________ Analyte: PFHS Comments/Justifications: * Acceptable Linear Range: Internal Standard: LOQ: 0,200 ng NA 0,200 ng to 500 ng MPFHS Analyte: PFOS Comments/Justifications: 2_______________ Acceptable Linear Range: 0.200 ng to 500 ng Internal Standard: M8PFOS________ LOQ: 0,200 ng_____________________ Data Review Sign-Off Analyst Review and Accepto Name / Date: Qnual Integratiions -- i/ Technical and Manual Integration Review Name / Date: r.TG> t - L c ' \ I Comments / Justifications: 1 Standard EC-101116-01 0,2 ng was excluded as it was not 2X the area counts of the method blanks. 2 After samples that had high levels of analyte were injected, many of the solvent blanks were above 1/2 the area counts of standardl___________ The blank at slOl 122a077 was the highest, following the highest sample response. The CCV following was at 116% recovery and the__________ blank following it was at twice the LLOQ, The majority of the solvent blanks are below the LLOQ and several of the blanks following high samples are near the LLOQ. The levels in the samples are significant when compared to the potential carryover. The LLOQ will remain at 0.2 ng,_________________________________ Analyte: MPFOS Comments/Justifications: NA_____________ Acceptable Linear Range: 0.200 ng to 5QQ ng Internal Standard: M8PFOS________ LOQ: 0,200 ng____________________ Analyte: N/A Comments/Justifications: N/A Acceptable Linear Range: N/A Internal Standard: N/A LOQ: N/A____________ 3M Study GLP10-01-02 Interim Report 05 Page 160 oP901 of 1 Stan: API4000: V1660305 DATE 11/19/10 ANALYST: GPM/MMH STUDY NUMBER: E l0-01-02-05 Matrix: Soils Injection volume: 25 uL Electrode: Turbo ion spray Mobile Phase: (A12 mM ammonium acetate 1B1 acetonitrile TN-A- or standard number (A) 10 010-16 (B1 tn 10-0180-3/8 page 1/1 Guard (pre-autosampler) column Prism RP Size: 2.1 mm X 50 mm__________ Type: C12 Sphere size: 5______ Part number: 32105-052130 Lot number: 9411 Serial number 0903542V Analytical column 1 Oasis HLB Size: 3 X 20 mm________ Type: NA Sphere size: 25 um Part number: 186002039 serial number: 006A300055105 03 Analytical column 2 Betasil C l8 Size: 2.1 mm X 100 mm_________ Type: C18 Sphere size: 5______ Part number: 70105-102130 Lot number: 10559 Serial number 0701663T Printed: Monday, November 22, 2010 11:21 AM 3M Study GLP10-01-02 Interim Report 05 Pag ETS Stan V16603Q5 P ro je c t: P :\L a b _ ln s tiu m e n t D a ta \S ta n \S ta n D a ta F ile s ^ P ro je c ts \f(u o ro c h e m ic a is \s o ii B a tc h :s 1 0 1 1 2 2 a T a b :S a m p le S e t:S E T 0 1 A c q M e th o d :e ts 8 - 5 3 2 3 m in S u lfo n a te s S a m p le S a m p le N a m e S a m p le ID 1 s101122a001 1 0 0 0 6 -2 5 s o lv e n t b la n k 2 s101122a002 1 0 0 0 6 -2 5 s o lv e n t b la n k 3 s 101 1 2 2 a 0 0 3 .E C -1 0 1 1 1 6 -0 9 5 0 n g W a rm u p s ta n d a rd 4 s 101 1 2 2 a 0 0 4 E C -1 0 1 1 1 6 -0 9 5 0 n g W a rm u p s ta n d a rd 5 s 1 0 l1 2 2 a 0 0 5 1 0 0 0 6 -2 5 s o lv e n t b la n k 6 s 101 1 2 2 a 0 0 6 >10 0 0 6 -2 5 s o lv e n t b la n k 7 s101122a007 1 0 0 0 6 -2 5 s o lv e n t b la n k 8 s 1 0 1 1 2 2 a 0 0 8 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 s 1 0 1 1 2 2 a 0 0 9 1 0 0 0 6 -2 5 s o lv e n t b la n k 10 s 1 0 H 2 2 a 0 1 0 ' E C - 1 0 1 1 1 6 - 0 1 0 . 2 n g E x t r a c te d C u r v e F ta in t 11 s 1 0 l1 2 2 a 0 1 1 E C - 1 0 1 1 1 6 - 0 2 0 . 5 n g E x t r a c te d C u r v e F ta in t 12 s 1 0 1 1 2 2 a 0 1 2 E C - 1 0 1 1 1 6 - 0 3 0 . 7 5 n g E x t r a c te d C u r v e P o in t 13 s101122a013 E C - 1 0 1 1 1 6 -0 4 1 n g E x tra c te d C u r v e P o in t 1 4 s 1 0 1 1 2 2 a 0 1 4 E C - 1 0 1 1 1 6 - 0 5 2 . 5 n g E x t r a c te d C u r v e F ta in t 1 5 s 1 0 1 1 2 2 a 0 1 5 E C - 1 0 1 1 1 6 - 0 6 5 n g E x t r a c t e d C u r v e F ta in t 16 s 1 0 l1 2 2 a 0 1 6 E C - 1 0 1 1 1 6 - 0 7 1 0 n g E x t r a c te d C u r v e F ta in t 1 7 S 1 0 1 1 2 2 a 0 1 7 E C - 1 0 1 1 1 6 - 0 8 2 5 n g E x t r a c te d C u r v e F ta in t 1 8 s 1 0 1 1 2 2 a 0 1 8 E C - 1 0 1 1 1 6 - 0 9 5 0 n g E x t r a c te d C u r v e F ta in t 1 9 s 1 0 1 1 2 2 a 0 1 9 E C -1 0 1 1 1 6 -1 0 1 0 0 n g E x tra c te d C u r v e P o in t 20 s 1 Q 1 1 2 2 a 0 2 0 E C - 1 0 1 1 1 6 - 1 1 2 0 0 n g E x t r a c t e d C u r v e F ta in t 21 s 1 0 1 1 2 2 a 0 2 1 . E C - 1 0 1 1 1 6 - 1 2 5 0 0 n g E x t r a c t e d C u r v e P o i n t 22 s101122a022 1 0 0 0 6 -2 5 s o lv e n t b la n k 23 s1Q 1122a023 1 0 0 0 6 -2 5 s o lv e n t b la n k 2 4 s 1 0 l1 2 2 a 0 2 4 11 0 0 0 6 - 2 5 s o lv e n t b la n k 2 5 s 101 1 2 2 a 0 2 5 .1 0 0 0 6 -2 5 s o lv e n t b la n k 2 6 s 1 0 1 1 2 2 a 0 2 6 [M B - 1 0 1 1 1 6 - 0 1 M e th o d B la n k 1 w / o IS 2 7 ' s 1 0 1 1 2 2 a 0 2 7 M B - 1 0 1 1 1 6 - 0 2 M e th o d B la n k 2 w / o IS 2 8 s 1 0 1 1 2 2 a 0 2 8 - M B - 1 0 1 1 1 6 - 0 3 M e th o d B la n k 3 w / o IS 2 9 s 1 0 1 1 2 2 a 0 2 9 M B - 1 0 1 1 1 6 - 0 4 M e th o d B la n k 4 w / IS 3 0 s 1 0 1 1 2 2 a 0 3 0 i M B - 1 0 1 1 1 6 - 0 5 M e th o d B la n k 5 w / IS 31 s 1 0 1 1 2 2 a 0 3 1 ; M B - 1 0 1 1 1 6 - 0 6 M e th o d B la n k 6 w / IS 3 2 s 1 0 1 1 2 2 a 0 3 2 L C S -1 0 1 1 1 6 -0 1 3 n g L C S in T C R -8 4 2 3 3 s 1 0 1 1 2 2 a 0 3 3 'L C S - 1 0 1 1 1 6 - 0 2 3 n g L C S in T C R -8 4 2 3 4 s 1 0 1 1 2 2 a 0 3 4 i L C S - 1 0 1 1 1 6 - 0 3 3 n g L C S in T C R - 8 4 2 3 5 s 1 0 1 1 2 2 a 0 3 5 L C S -1 0 1 1 1 6 - 0 4 3 0 n g L C S in T C R -8 4 2 3 6 s 1 0 1 1 2 2 a 0 3 6 ! L C S - 1 0 1 1 1 6 - 0 5 3 0 n g L C S in T C R -8 4 2 3 7 s 1 0 1 1 2 2 a 0 3 7 L C S - 1 0 1 1 1 6 - 0 6 3 0 n g L C S in T C R -8 4 2 3 8 s 1 0 1 1 2 2 a 0 3 8 |G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 D A L S S S S 01 0 0 0 0 0 3 9 s 1 0 1 1 2 2 a 0 3 9 G L P 1 0 - 0 1 -0 2 - 0 5 - 0 4 1 D u p D A L S S S S 0 1 0 0 0 0 0 D u p lic a te 4 0 s 1 0 1 1 2 2 a 0 4 0 G L P 1 0 -0 1 -0 2 -0 5 -0 4 1 L M S D A L S S S S 0 1 0 0 0 0 0 L a b M a trix S p ik e 41 s 1Q1 1 2 2 a 0 4 1 ,1 0 0 0 6 - 2 5 s o lv e n t b la n k 4 2 s 1 0 1 1 2 2 a 0 4 2 E C - 1 0 1 1 1 6 - 0 5 2 . 5 n g E x t r a c te d C u r v e F ta in t 4 3 s 1 0 1 1 2 2 a 0 4 3 ; 1 0 0 0 6 -2 5 s o lv e n t b la n k 4 4 s 1 0 1 1 2 2 a 0 4 4 'G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 2 D A L S S S S 0 1 0 0 0 0 5 4 5 s 1 0 1 1 2 2 a 0 4 5 G L P 1 0 - 0 1 -0 2 - 0 5 - 0 4 2 D u p D A L S S S S 0 1 0 0 0 0 5 D u p lic a te 4 6 s 1 0 1 1 2 2 a 0 4 6 G L P 1 0 - 0 1 -0 2 - 0 5 - 0 4 2 L M S D A L S S S S 0 1 0 0 0 0 5 L a b M a trix S p ik e 4 7 s 1 0 1 1 2 2 a 0 4 7 [G L P 1 0 -0 1 -0 2 -0 5 -0 4 3 D A L S S S S 0 2 0 0 0 0 0 4 8 s 1 0 1 1 2 2 a 0 4 8 G L P 1 0 - 0 1 -0 2 - 0 5 - 0 4 3 D u p D A L S S S S 0 2 0 0 0 0 0 D u p lic a te 4 9 s 1 0 1 1 2 2 a 0 4 9 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 3 L M S D A L S S S S 0 2 0 0 0 0 0 L a b M a trix S p ik e 5 0 s 1 0 1 1 2 2 a 0 5 0 ,G L P 1 0 -0 1 -0 2 -0 5 -0 4 4 D A L S S S S 0 2 0 0 0 0 5 51 s101122a051 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 4 D u p D A L S S S S 0 2 0 0 0 0 5 D u p lic a te 5 2 s 1 0 1 1 2 2 a 0 5 2 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 4 L M S D A L S S S S 0 2 0 0 0 0 5 L a b M a trix S p ik e 53 s 1 0 1 1 2 2 a 0 5 3 G L P 1 0 -0 1 -0 2 -0 5 -0 4 5 D A L S S S S 0 3 0 0 0 0 0 5 4 s 1 0 1 1 2 2 a 0 5 4 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 5 D u p D A L S S S S 0 3 0 0 0 0 0 D u p lic a te 5 5 s 1 0 1 1 2 2 a 0 5 5 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 5 L M S D A L S S S S 0 3 0 0 0 0 0 L a b M a trix S p ik e 56 s 1 0 1 1 2 2 a 0 5 6 G L P 1 0 -0 1 -0 2 -0 5 -0 4 6 D A L S S S S 0 3 0 0 0 0 5 5 7 s 1 0 1 1 2 2 a 0 5 7 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 6 D u p D A L S S S S 0 3 0 0 0 0 5 D u p lic a te 5 8 S 1 Q 1 1 2 2 a 0 5 8 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 6 L M S D A L S S S S 0 3 0 0 0 0 5 L a b M a trix S p ik e 59 s1 0 1 1 2 2 a 0 5 9 1 0 0 0 6 -2 5 s o lv e n t b la n k 6 0 , s 1 Q 1 1 2 2 a 0 6 0 i E C - 1 0 1 1 1 6 - 0 6 5 n g E x t r a c te d C u r v e F ta in t 61 s1Q H 22a061 1 0 0 0 6 -2 5 s o lv e n t b la n k 6 2 s 1 0 1 1 2 2 a 0 6 2 .G L P 1 0 -0 1 -0 2 -0 5 -0 4 7 D A L S S S S 0 3 D B 0 0 0 5 Printing Date: Monday, November 22, 2010 V ia l P o s itio n D a ta F ile In j.V o lu m e (M O C o m m e n ts ! 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 * 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 , 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 ! 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 ! 9 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 1 s 1 0 1 1 2 2 a 2 5 .0 0 0 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 3 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 4 s 1 0 1 1 2 2 a 2 5 .0 0 0 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 8 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 10 s 1 0 1 1 2 2 a I2 5 .0 0 0 11 s 1 0 1 1 2 2 a 2 5 . 0 0 0 12 s 1 0 1 1 2 2 a 2 5 . 0 0 0 ' ; 92 s 1 0 1 1 2 2 a 2 5 .0 0 0 92 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 j 13 s 1 0 1 1 2 2 a 2 5 .0 0 0 14 s 1 0 1 1 2 2 a 2 5 .0 0 0 15 s 1 0 1 1 2 2 a 2 5 .0 0 0 16 s 1 0 1 1 2 2 a 2 5 .0 0 0 17 s 1 0 1 1 2 2 a 2 5 .0 0 0 f 18 s 1 0 1 1 2 2 a 2 5 .0 0 0 19 s 1 0 1 1 2 2 a 2 5 .0 0 0 20 s 1 0 1 1 2 2 a 2 5 .0 0 0 21 s 1 0 1 1 2 2 a 2 5 . 0 0 0 22 s 1 0 1 1 2 2 a 2 5 .0 0 0 2 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 2 4 s 1 0 1 1 2 2 a 2 5 .0 0 0 i * 1 2 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 2 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 ; I 2 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 [ 9 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 4 s 1 0 1 1 2 2 a 2 5 .0 0 0 2 8 s 1 0 1 1 2 2 a 2 5 .0 0 0 2 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 3 0 s 1 0 1 1 2 2 a 2 5 .0 0 0 , 31 s 1 0 1 1 2 2 a 2 5 .0 0 0 3 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 3 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 34 s101122a 2 5 .0 0 0 3 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 \\( 36 s 1 0 1 1 2 2 a 2 5 .0 0 0 37 s101122a 2 5 .0 0 0 38 s 1 0 1 1 2 2 a 2 5 .0 0 0 39 s 1 0 1 1 2 2 a 2 5 .0 0 0 4 0 s 1 0 1 1 2 2 a 2 5 .0 0 0 41 s 1 0 1 1 2 2 a 2 5 .0 0 0 4 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 94 s 1 0 1 1 2 2 a 2 5 .0 0 0 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 , 9 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 43 . s 1 0 1 1 2 2 a 2 5 . 0 0 0 Page 1 of 3 -r Printing Time: 11:22:20 AM 3M Study GLP10-01-02 Interim Report 05 ETS Stan V1660305 P ro je c t: P :\L a b _ ln s tr u m e n t D a ta \S ta n \S ta n D a ta F ile s \P ro je c ts \flu o ro c h e m ic a ls \s o il B a tc h :s 1 0 1 1 2 2 a T a b :S a m p le S e t:S E T 0 1 A c q M e th o d :e ts 8 - 5 3 2 3 m in S u lfo n a te s S a m p le Sam ple Name S am p le ID Via! Pos ition Inj.Volum e Data File C om m ents, (MD 6 3 s 1 0 1 1 2 2 a 0 6 3 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 7 D u p D A L S S S S 0 3 D B 0 0 0 5 D u p lic a te 4 4 s 1 0 1 1 2 2 a 2 5 .0 0 0 64 s 1 0 1 1 2 2 a 0 6 4 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 7 L M S D A L S S S S 0 3 D B 0 0 0 5 L a b M a trix S p ik e 45 s 1 0 1 1 2 2 a 2 5 .0 0 0 65 s1 0 1 1 2 2 a 0 6 5 G L P 10 -0 1 -0 2 -0 5 -0 4 8 D A L S S S S 04 0 0 0 0 0 66 s 1 0 1 1 2 2 a 0 6 6 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 8 D u p D A L S S S S 0 4 0 0 0 0 0 D u p l i c a t e 6 7 s 1 0 1 1 2 2 a 0 6 7 i G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 8 L M S D A L S S S S 0 4 0 0 0 0 0 L a b M a trix S p ik e 68 s 1 0 1 1 2 2 a 0 6 8 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 9 D A L S S S S 0 4 0 0 0 0 5 46 47 48 49 s101122a s101122a s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 i 6 9 s 1 0 1 1 2 2 a 0 6 9 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 4 9 D u p D A L S S S S 0 4 0 0 0 0 5 D u p lic a te 70 s101122a070 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 4 9 L M S D A L S S S S 0 4 0 0 0 0 5 L a b M a trix S p ik e 71 s101122a071 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 0 D A L S S T R IP 1 0 0 0 0 0 50 51 52 s101122a s101122a s 101122a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 l 72 s101122a072 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 0 D u p D A L S S T R IP 1 0 0 0 0 0 D u p lic a te 73 s101122a073 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 0 L M S D A L S S T R IP 1 0 0 0 0 0 L a b M a tr ix S p ik e 53 54 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 74 s101122a074 G L P 10 -0 1 -0 2 -0 5 -0 5 1 D A L S S S S 0 5 0 0 0 0 0 75 s101122a075 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 5 1 D u p D A L S S S S 0 5 0 0 0 0 0 D u p lic a te 5 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 56 s 1 0 1 1 2 2 a 2 5 .0 0 0 ; 76 s101122a076 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 5 1 L M S D A L S S S S 0 5 0 0 0 0 0 L a b M a trix S p ik e 57 s 1 0 1 1 2 2 a 2 5 .0 0 0 77 s101122a077 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 7 8 s 1 0 1 1 2 2 a 0 7 8 ;E C - 1 0 1 1 1 6 - 0 7 1 0 n g E x tra c te d C u r v e P o in t 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 79 s101122a079 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 80 s101122a080 G LP 10 -0 1 -0 2 -0 5 -0 5 2 D A L S S S S 0 5 0 0 0 0 5 58 s101122a 2 5 .0 0 0 8 1 s 1 0 1 1 2 2 a 0 8 1 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 2 D u p D A L S S S S 0 5 0 0 0 0 5 D u p l i c a t e 59 s101122a 2 5 .0 0 0 82 s101122a082 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 5 2 L M S D A L S S S S 0 5 0 0 0 0 5 L a b M a trix S p ik e 60 s 1 0 1 1 2 2 a 2 5 .0 0 0 8 3 s 1 0 1 1 2 2 a 0 8 3 1G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 4 D A L S S S S 0 6 0 0 0 0 0 61 s101122a 2 5 .0 0 0 8 4 s 1 0 1 1 2 2 a 0 8 4 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 4 D u p D A L S S S S 0 6 0 0 0 0 0 D u p lic a te 62 s101122a 2 5 .0 0 0 8 5 s 1 0 1 1 2 2 a 0 8 5 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 5 4 L M S D A L S S S S 0 6 0 0 0 0 0 L a b M a trix S p ik e 86 s 1 0 1 1 2 2 a 0 8 6 G LP 10 -0 1 -0 2 -0 5 -0 5 5 D A L S S S S 0 6 0 0 0 0 5 63 64 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 | , 8 7 s 1 0 1 1 2 2 a 0 8 7 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 5 D u p D A L S S S S 0 6 0 0 0 0 5 D u p lic a te 88 s 1 0 1 1 2 2 a 0 8 8 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 5 L M S D A L S S S S 0 6 0 0 0 0 5 L a b M a t r i x S p i k e 65 66 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 I 89 s 1 0 1 1 2 2 a 0 8 9 G L P 10 -0 1 -0 2 -0 5 -0 5 6 D A L S S S S 0 6 D B 0 0 0 5 9 0 s 1 0 1 1 2 2 a 0 9 0 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 6 D u p D A L S S S S 0 6 D B 0 0 0 5 D u p lic a te 67 s 1 0 1 1 2 2 a 2 5 .0 0 0 ; 68 s 1 0 1 1 2 2 a 2 5 . 0 0 0 | 91 s 1 0 1 1 2 2 a 0 9 1 :G L P 1 0 - 0 1 - 0 2 -0 5 - 0 5 6 L M S D A L S S S S 0 6 D B 0 0 0 5 L a b M a trix S p ik e 69 s 1 0 1 1 2 2 a 2 5 .0 0 0 92 s101122a092 G LP 10 -0 1 -0 2 -0 5 -0 5 7 D A L S S S S 0 7 0 0 0 0 0 7 0 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 3 s 1 0 1 1 2 2 a 0 9 3 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 7 D u p D A L S S S S 0 7 0 0 0 0 0 D u p lic a te 71 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 4 s 1 0 1 1 2 2 a 0 9 4 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 5 7 L M S D A L S S S S 0 7 0 0 0 0 0 L a b M a trix S p ik e 72 s 1 0 1 1 2 2 a 2 5 .0 0 0 95 s 101122a095 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 9 6 s 1 0 1 1 2 2 a 0 9 6 ' E C - 1 0 1 1 1 6 - 0 5 2 . 5 n g E x t r a c te d C u r v e F ta in t 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 97 s101122a097 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 98 s 1 0 1 1 2 2 a 0 9 8 G L P 10 -0 1 -0 2 -0 5 -0 5 8 D A L S S S S 0 7 0 0 0 0 5 7 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 99 100 101 102 s101122a099 s101122a100 s 1 0 1 1 2 2 a 1 01 s 101122a102 ; G L P 1 0 -0 1 - 0 2 - 0 5 - 0 5 8 D u p D A L S S S S 0 7 0 0 0 0 5 D u p lic a te G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 8 L M S D A L S S S S 0 7 0 0 0 0 5 L a b M a t r i x S p i k e ,G LP 10 -0 1 -0 2 -0 5 -0 5 9 D A L S S S S 0 8 0 0 0 0 0 : G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 9 D u p D A L S S S S 0 8 0 0 0 0 0 D u p lic a te 74 75 76 77 s101122a s101122a s101122a s 101122a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 103 104 s 101122a103 s101122a104 1G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 5 9 L M S D A L S S S S 0 8 0 0 0 0 0 L a b M a t r i x S p i k e G L P 10 -0 1 -0 2 -0 5 -0 6 0 D A L S S S S 08 D B 0 0 0 0 78 79 s 101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 i. 105 s 1 0 1 1 2 2 a 1 0 5 ;G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 0 D u p D A L S S S S 0 8 D B 0 0 0 0 D u p lic a te 8 0 s 1 0 1 1 2 2 a 2 5 .0 0 0 106 s 1 0 1 1 2 2 a 1 0 6 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 0 L M S D A L S S S S 0 8 D B 0 0 0 0 L a b M a trix S p ik e 81 s 1 0 1 1 2 2 a 2 5 .0 0 0 107 108 s101122a107 s101122a108 G L P 10 -0 1 -0 2 -0 5 -0 6 1 D A L S S S S 0 8 0 0 0 0 5 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 1 D u p D A L S S S S 0 8 0 0 0 0 5 D u p lic a te 8 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 8 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 ; 109 110 111 112 s101122a109 s101122a110 s 1 0 1 1 2 2 a 1 11 s 1 0 1 1 2 2 a 112 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 1 L M S D A L S S S S 0 8 0 0 0 0 5 L a b M a trix S p ik e ,G L P 1 0 -0 1 -0 2 -0 5 -0 6 2 D A L S S S S 0 9 0 0 0 0 0 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 2 D u p D A L S S S S 0 9 0 0 0 0 0 D u p lic a te G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 2 L M S D A L S S S S 0 9 0 0 0 0 0 L a b M a trix S p ik e 84 85 86 87 s 101122a s 101122a s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 * 113 114 s101122a113 s 1 0 1 1 2 2 a 1 14 1 0 0 0 6 -2 5 s o lv e n t b la n k E C -1 0 1 1 1 6 -0 6 5 n g E x tra c te d C u r v e P o in t 97 s 1 0 1 1 2 2 a 2 5 .0 0 0 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 115 s 1 0 1 1 2 2 a 1 15 . 1 0 0 0 6 -2 5 s o lv e n t b la n k 98 s 1 0 1 1 2 2 a 2 5 .0 0 0 116 s 1 0 1 1 2 2 a 1 16 G L P 10 -0 1 -0 2 -0 5 -0 6 3 D A L S S S S 09 0 0 0 0 5 13 s 1 0 1 1 2 2 a 2 5 .0 0 0 117 s 1 0 1 1 2 2 a 1 1 7 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 3 D u p D A L S S S S 0 9 0 0 0 0 5 D u p lic a te 14 s 1 0 1 1 2 2 a 2 5 .0 0 0 118 s 1 0 1 1 2 2 a 1 1 8 ; G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 3 L M S D A L S S S S 0 9 0 0 0 0 5 L a b M a trix S p ik e 15 s 1 0 1 1 2 2 a 2 5 .0 0 0 119 120 121 122 123 124 s101122a119 s101122a120 s101122a121 s 101122a122 s 101122a123 s101122a124 'G LP 10 -0 1 -0 2 -0 5 -0 6 4 D A L S S G P01 0 0 0 0 0 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 4 D u p D A L S S G P 0 1 0 0 0 0 0 D u p lic a te G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 4 L M S D A L S S G P 0 1 0 0 0 0 0 L a b M a trix S p ik e G L P 10 -0 1 -0 2 -0 5 -0 6 5 D A L S S G P01 0 0 0 0 5 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 5 D u p D A L S S G P 0 1 0 0 0 0 5 D u p lic a te G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 5 L M S D A L S S G P 0 1 0 0 0 0 5 L a b M a trix S p ik e Printing Date: Monday, November 22, 2010 16 18 19 20 21 s101122a s 1 1122a s101122a s101122a s 101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 Page 2 of 3 \ , < Printing Time: 11:22:20 AM 3M Study GLP10-01-02 Interim Report 05 Page 163 of 962 ETS Stan V1660305 P ro je c t: P :\L a b _ ln s tru m e n t D a ta \S ta n \S ta n D a ta F ile s \P ro je c ts \flu o ro c h e m ic a ls \s o il B a tc h :s 1 0 1 1 2 2 a T a b :S a m p le S e t:S E T 0 1 A c q M e th o d :e ts 8 - 5 3 2 3 m in S u lfo n a te s S a m p le 125 Sam ple Name S a m p le ID s1 0 1 1 2 2 a 1 2 5 G L P 10 -0 1 -0 2 -0 5 -0 6 6 O A L S S G P01 0 0 0 2 0 V ia l _ , _.. P o s itio n ; 0 3 ,3 Flle 22 s 1 0 1 1 2 2 a Inj.Volum e (MO 2 5 .0 0 0 1C o m m e n ts 126 s 1 0 1 1 2 2 a 1 2 6 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 6 D u p D A L S S G P 0 1 0 0 0 2 0 D u p lic a te 2 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 127 128 s101122a127 s101122a128 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 6 L M S D A L S S G P 0 1 0 0 0 2 0 L a b M a trix S p ik e G L P 10 -0 1 -0 2 -0 5 -0 6 7 D A L S S G P01 0 0 0 6 0 24 25 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 * 129 130 s101122a129 s101122a130 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 7 D u p D A L S S G P 0 1 0 0 0 6 0 D u p lic a te G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 7 L M S D A L S S G P 0 1 0 0 0 6 0 L a b M a trix S p ik e 26 27 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 i 131 s101122a131 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 8 s 1 0 1 1 2 2 a 2 5 .0 0 0 132 s101122a132 E C -1 0 1 1 1 6 -0 7 1 0 n g E x tra c te d C u r v e P o in t 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 133 s 1 0 1 1 2 2 a 1 3 3 ' 1 0 0 0 6 -2 5 s o lv e n t b la n k 9 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 134 s1 0 1 1 2 2 a 1 3 4 G L P 10 -0 1 -0 2 -0 5 -0 6 8 D A L S S G P 02 0 0 0 0 0 2 8 s 1 0 1 1 2 2 a 2 5 .0 0 0 135 s 1 0 1 1 2 2 a 1 3 5 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 8 D u p D A L S S G P 0 2 0 0 0 0 0 D u p lic a te 2 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 136 s 1 0 1 1 2 2 a 1 3 6 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 8 L M S D A L S S G P 0 2 0 0 0 0 0 L a b M a trix S p ik e 30 s 1 0 1 1 2 2 a 2 5 .0 0 0 137 s1 0 1 1 2 2 a 1 3 7 ;G L P 10 -0 1 -0 2 -0 5 -0 6 9 D A L S S G P 02 0 0 0 0 5 31 s 1 0 1 1 2 2 a 2 5 .0 0 0 138 s 1 0 1 1 2 2 a 1 3 8 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 6 9 D u p D A L S S G P 0 2 0 0 0 0 5 D u p lic a te 3 2 . s 1 0 1 1 2 2 a 2 5 .0 0 0 139 s 1 0 1 1 2 2 a 1 3 9 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 6 9 L M S D A L S S G P 0 2 0 0 0 0 5 L a b M a trix S p ik e 33 s 1 0 1 1 2 2 a 2 5 .0 0 0 140 s 1 0 1 1 2 2 a 1 4 0 ;G L P 1 0 -0 1 -0 2 -0 5 -0 7 0 D A L S S G P 0 2 0 0 0 2 0 34 s 1 0 1 1 2 2 a 2 5 .0 0 0 ; 141 s 1 0 1 1 2 2 a 1 4 1 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 0 D u p D A L S S G P 0 2 0 0 0 2 0 D u p lic a te 3 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 142 s 1 0 1 1 2 2 a 1 4 2 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 0 L M S D A L S S G P 0 2 0 0 0 2 0 L a b M a trix S p ik e 36 s 1 0 1 1 2 2 a 2 5 .0 0 0 143 s 1 0 1 1 2 2 a 1 4 3 G L P 10 -0 1 -0 2 -0 5 -0 7 1 D A L S S G P 02 D B 0 0 2 0 37 s 1 0 1 1 2 2 a 2 5 .0 0 0 144 s101122a144 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 1 D u p D A L S S G P 0 2 D B 0 0 2 0 D u p lic a te 3 8 s 1 0 1 1 2 2 a 2 5 .0 0 0 145 s 1 0 1 1 2 2 a 1 4 5 G L P 1 0 -0 1 - 0 2 -0 5 - 0 7 1 L M S D A L S S G P 0 2 D B 0 0 2 0 L a b M a trix S p ik e 39 s 1 0 1 1 2 2 a 2 5 .0 0 0 146 147 s 101122a146 s 101122a147 G L P 10 -0 1 -0 2 -0 5 -0 7 2 D A L S S G P 02 0 0 1 2 0 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 2 D u p D A L S S G P 0 2 0 0 1 2 0 D u p lic a te 4 0 s 1 0 1 1 2 2 a 2 5 .0 0 0 41 s 1 0 1 1 2 2 a 2 5 .0 0 0 j 148 149 s101122a148 s101122a149 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 2 L M S D A L S S G P 0 2 0 0 1 2 0 L a b M a trix S p ik e 1 0 0 0 6 -2 5 s o lv e n t b la n k 42 100 s101122a s 101122a 2 5 .0 0 0 2 5 .0 0 0 150 151 s101122a150 s 1 0 1 1 2 2 a 1 51 E C -1 0 1 1 1 6 -0 5 2 .5 n g E x tra c te d C u rv e ft)in t 1 0 0 0 6 -2 5 s o lv e n t b la n k 5 100 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 152 s1 0 1 1 2 2 a 1 5 2 G L P 10 -0 1 -0 2 -0 5 -0 7 3 D A L S S G P 03 0 0 0 0 0 4 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 153 s 1 0 1 1 2 2 a 1 5 3 G L P 1 0 -0 1 - 0 2 - 0 5 - 0 7 3 D u p D A L S S G P 0 3 0 0 0 0 0 D u p lic a te 4 4 s 1 0 1 1 2 2 a 2 5 .0 0 0 154 s 1 0 1 1 2 2 a 1 5 4 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 3 L M S D A L S S G P 0 3 0 0 0 0 0 L a b M a trix S p ik e 45 s 1 0 1 1 2 2 a 2 5 .0 0 0 155 s1 0 1 1 2 2 a 1 5 5 G LP 10 -0 1 -0 2 -0 5 -0 7 4 D A L S S G P 03 0 0 0 0 5 4 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 156 s 1 0 1 1 2 2 a 1 5 6 : G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 4 D u p D A L S S G P 0 3 0 0 0 0 5 D u p lic a te 4 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 157 s 1 0 1 1 2 2 a 1 5 7 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 4 L M S D A L S S G P 0 3 0 0 0 0 5 L a b M a trix S p ik e 48 s 1 0 1 1 2 2 a 2 5 .0 0 0 158 s101122a158 G LP 10 -0 1 -0 2 -0 5 -0 7 5 D A L S S G P 03 0 0 0 2 0 4 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 159 s 1 0 1 1 2 2 a 1 5 9 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 5 D u p D A L S S G P 0 3 0 0 0 2 0 D u p lic a te 5 0 s 1 0 1 1 2 2 a 2 5 .0 0 0 160 s 1 0 1 1 2 2 a 1 6 0 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 5 L M S D A L S S G P 0 3 0 0 0 2 0 L a b M a trix S p ik e 51 s 1 0 1 1 2 2 a 2 5 .0 0 0 161 s 1 0 1 1 2 2 a 1 6 1 ' G L P 10 -0 1 -0 2 -0 5 -0 7 6 D A L S S G P 03 D B 0 0 2 0 5 2 s 1 0 1 1 2 2 a 2 5 .0 0 0 162 s 1 0 1 1 2 2 a 1 6 2 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 6 D u p D A L S S G P 0 3 D B 0 0 2 0 D u p lic a te 5 3 s 1 0 1 1 2 2 a 2 5 .0 0 0 163 s 1 0 1 1 2 2 a 1 6 3 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 6 L M S D A L S S G P 0 3 D B 0 0 2 0 L a b M a trix S p ik e 54 s 1 0 1 1 2 2 a 2 5 .0 0 0 164 s 1 0 1 1 2 2 a 1 6 4 G L P 10 -0 1 -0 2 -0 5 -0 7 7 D A L S S G P 03 0 0 0 5 0 5 5 s 1 0 1 1 2 2 a 2 5 .0 0 0 165 s 1 0 1 1 2 2 a 1 6 5 IG L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 7 D u p D A L S S G P 0 3 0 0 0 5 0 D u p lic a te 5 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 166 s 1 0 1 1 2 2 a 1 6 6 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 7 L M S D A L S S G P 0 3 0 0 0 5 0 L a b M a trix S p ik e 57 s 1 0 1 1 2 2 a 2 5 .0 0 0 167 168 s101122a167 s101122a168 1 0 0 0 6 -2 5 s o lv e n t b la n k ; E C - 1 0 1 1 1 6 - 0 6 5 n g E x t r a c te d C u r v e F to in t 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 6 s 1 0 1 1 2 2 a 2 5 .0 0 0 169 s101122a169 1 0 0 0 6 -2 5 s o lv e n t b la n k 91 s 1 0 1 1 2 2 a 2 5 .0 0 0 170 s1 0 1 1 2 2 a 1 7 0 G L P 10 -0 1 -0 2 -0 5 -0 7 8 D A L S S G P 04 0 0 0 0 0 5 8 s 1 0 1 1 2 2 a 2 5 .0 0 0 171 s101122a171 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 8 D u p D A L S S G P 0 4 0 0 0 0 0 D u p lic a te 5 9 s 1 0 1 1 2 2 a 2 5 .0 0 0 172 173 s101122a172 s101122a173 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 8 L M S D A L S S G P 0 4 0 0 0 0 0 L a b M a trix S p ik e G LP 10 -0 1 -0 2 -0 5 -0 7 9 D A L S S G P 04 0 0 0 0 5 60 61 s101122a s101122a 2 5 .0 0 0 2 5 .0 0 0 * 174 s 1 0 1 1 2 2 a 1 7 4 G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 7 9 D u p D A L S S G P 0 4 0 0 0 0 5 D u p lic a te 62 s 1 0 1 1 2 2 a 2 5 .0 0 0 175 s 1 0 1 1 2 2 a 1 7 5 G L P 1 0 - 0 1 - 0 2 -0 5 - 0 7 9 L M S D A L S S G P 0 4 0 0 0 0 5 L a b M a trix S p ik e 63 s 1 0 1 1 2 2 a 2 5 .0 0 0 176 s 1 0 1 1 2 2 a 1 7 6 G L P 10 -0 1 -0 2 -0 5 -0 8 0 D A L S S G P 04 0 0 0 2 0 6 4 s 1 0 1 1 2 2 a 2 5 .0 0 0 177 178 .s 1 0 1 1 2 2 a 1 7 7 s101122a178 ;G L P 1 0 - 0 1 - 0 2 - 0 5 - 0 8 0 D u p D A L S S G P 0 4 0 0 0 2 0 D u p lic a te G L P 1 0 - 0 1 - 0 2 -0 5 - 0 8 0 L M S D A L S S G P 0 4 0 0 0 2 0 L a b M a trix S p ik e 65 66 s1 0 1 122a s101122a 2 5 .0 0 0 2 5 .0 0 0 179 180 s101122a179 s101122a180 M B - 1 0 1 1 1 6 - 0 7 M e th o d B la n k 5 g w / IS f o r D ilu tio n s M B - 1 0 1 1 1 6 - 0 8 M e th o d B la n k 5 g w / IS f o r D ilu tio n s 6 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 68 s 1 0 1 1 2 2 a 2 5 . 0 0 0 181 s 1 0 1 1 2 2 a 1 81 1 0 0 0 6 -2 5 s o lv e n t b la n k ' l l s 1 0 1 1 2 2 a 2 5 .0 0 0 182 s101122a182 E C - 1 0 1 1 1 6 - 0 7 1 0 n g E x t r a c te d C u r v e F to in t 7 s 1 0 1 1 2 2 a 2 5 .0 0 0 183 s101122a183 1 0 0 0 6 -2 5 s o lv e n t b la n k 92 s 1 0 1 1 2 2 a 2 5 .0 0 0 i Printing Date: Monday, November 22, 2010 Printing Time: 11:22:20 AM 3M Study GLP10-01-02 Interim Report 05 Page 3 of 3 Page 164 of 962 ETS Stan V1660305 Acquisition Information: A cq u isition Method: C reated : la s t Modified: Garment: Synchronization Mode: A uto-E quilibration: A cquisition Duration: Number Of Scans: Periods In File: A cq uisition Module: Software version A g ilent IC Puip Method P ro p erties Puip Model: Minimum P ressure ( p s i) : Maximum P ressure ( p s i) : Dead Volume ( p i) : Maximum Flow Farrp (ml/min2) : Maximum Pressure Ranp (p s i/s e c ): ETS 8-53 23 min Sulfonates.dam Friday A p ril OS 2010 12: 54: 09 EM Friday A p ril OS 2010 15: 54: 27 EM Method fo r S ulfonates 23 minute g rad ien t 1C Sync Off 2jfriin0sec 2281 1 A cquisition Method Analyst 1.4.2 A gilent 1100 DC Binary Puip 0.0 5801.0 40.0 100.0 290.0 Step Table: Step T otal Time(min) C 0.00 1 3.00 2 3.50 3 17.00 4 17.50 5 19.50 20.00 7 23.00 Flow Rate (pl/min) 400 400 400 400 400 400 400 400 A (%) 97.0 97.0 70.0 40.0 10.0 10.0 97.0 97.0 B (%) 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0 Left C arp ressib ility : 50.0 Right C a rp re s s ib ility : 115.0 L eft Dead Volume ( p i) : 40.0 Right Dead Volime (p i): 40.0 Left Stroke Volute (p i): Right Stroke Volute (p i): le f t Solvent: A1 Right Solvent: B2 - 1.0 - 1.0 A gilent Autosanpler Properties Autosarrpler Model: A gilent 1100 Thermo A utosanpler Syringe Size (p i): 100 In je c tio n Volume (pi) 25.00 Draw Speed (p l/m in ): 200.0 E ject Speed (pl/m in): 200.0 Needle Level (nm): 0.00 T erperature Control Enabled S etpoint (4 - 40 C ): 10 Wash i s not used Use Custcm In je c to r Program A gilent Column Oven P ro p erties Left Temperature (C): Right Temperature (C) : 30.00 Temperature Tolerance + / - (C): 1.00 S ta r t A cquisition Tolerance + /- ( C) : 0.50 Time Table (Used) Column Switching Valve In s ta lle d Position fo r f i r s t sample in th e batch: Right Use same p o s itio n fo r a l l sanples in th e batch T otal Time (min) Valve P o sitio n 0.0C Left 5 .0C Right Period 1: Scans in Period: 2281 R elative S ta r t Time: 0.00 msec Experiments in Period: 1 Period 1 Experiment 1: Scan Type: Polarity: Scan Mode: Ion Source: R esolution Ql: R esolution Q3: Intensity Thres.: S e ttlin g Time: MR Pause: MRM (MRM) Negative N/A Turbo Spray Unit th it 0.00 cps 0.0000 msec 5.0070 msec Printing Date: Monday, November 22, 2010 Printing Time: 11:22:42 AM 3M Study GLP10-01-02 Interim Report 05 Page 1 of 3 ETS Stan V1660305 MCA: No Step Size: 0.00 arnu Q1 Mass (ama) 3 9 9 .0C Q3 to s s (amu) 99.00 Dwell (msec) 50.00 Paran DE CE CXE S ta rt Step -100.00-100.00 -54.00 -54.00 -5.00 -5.00 Q1 to s s (ama) 3 9 9 .0C Q3 to s s (arnu) 80.00 Ewell (msec) 50.00 Paran DE CE CXE S ta rt Step -100.00 -100.00 -82.00 -82.00 -5.00 -5.00 Q1 Mass (ami) 403.0C Q3 to s s (ami) 84.00 Dwell (msec) 50.00 Paran DP CE CXE S ta rt Step -100.00 -100.00 -82.00 -82.00 -5.00 -5.00 Q1 to s s (ami) 2 9 9 .0C Q3 to s s (ama) 99.00 Ewell (msec) 50.00 Paran DE CE CXE S ta r t Stop -65.00 -65.00 -44.00 -44.00 -15.00 -15.00 Q1 to s s (ana) 2 9 9 .OC Q3 to s s (amu) 80.00 Ewell (msec) 50.00 Paran DE CE OCE S ta rt Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00 Q1 to s s (ama) 3 0 3 .OC Q3 to s s (ami) 84.00 Ewell (msec) 50.00 Paran DE CE CXE S ta rt Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00 Q1 to s s (ami) 499.0C Q3 to s s (amu) 80.00 Dwell (msec) 50.00 Paran DE CE CXE S ta rt Step -120.00 -120.00 -98.00 -98.00 -5.00 -5.00 Q1 to s s (ami) 499.0C Q3 to s s (ami) 99.00 EWell (msec) 50.00 Paran DE CE CXE S ta r t Stop -120.00 -120.00 -82.00 -82.00 -5.00 -5.00 Q1 to s s (ami) 499.0C Q3 to s s (ami) 130.0C Ewell (msec) 50.00 Paran DE CE CXE Start Step. -120.00 -120.00 -66.00 -66.00 -7.00 -7.00 Q1 to s s (arnu) 503.0C Q3 to s s (ami) 80.00 Ewell (msec) 50.00 Paran DE CE CXE S ta rt Step -120.00 -120.00 -98.00 -98.00 -5.00 -5.00 Q1 to s s (ami) 507.0C Q3 to s s (amu) 80.00 EWell (msec) 50.00 Paran DE CE OCE S ta rt Step -120.00 -120.00 -98.00 -98.00 -5.00 -5.00 Parameter Table (Period 1 CAD: 6.00 CUR: 35.00 GS1: 45.00 GS2: 60.00 IS: -4500.00 TEM: 450.00 ihe: CN EE -10.00 Experiment 1): Printing Date: Monday, November 22, 2010 Printing Time: 11:22:42 AM 3M Study GLP10-01-02 Interim Report 05 * * Page 2 of 3 Page 166 of 962 ETS Stan V1660305 Printing Date: Monday, November 22, 2010 Printing Time: 11:22:42 AM 3M Study GLP10-01-02 Interim Report 05 Page 3 of 3 Page 167 of 962 *Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample ID 1 s101122a001 10 006-25 solvent blank 2 s101122a002 10 006-25 solvent blank 3 s101122a003 EC-101116-09 50 ng W a rm up standard 4 s101122a004 EC -101116-09 50 ng W a rm up standard 5 s101122a005 10 006-25 solvent blank 6 s101122a006 10 006-25 solvent blank 7 s101122a007 10 006-25 solvent blank 8 s 1 0 1 1 2 2 a0 0 8 10 006-25 solvent blank 9 s101122a009 10 006-25 solvent blank 10 s101122a010 EC-101116-01 0.2 ng E rtracted Curve Point 11 s101122a011 EC-101116-02 0,5 ng Extracted Curve Point 12 s101122a012 E C -101116-03 0.75 ng Extracted Curve Point 13 s101122a013 EC-101116-04 1 ng Extracted Curve Point 14 s101122a014 EC-101116-05 2 .5 ng Extracted C u n Point 15 s101122a015 EC-101116-06 5 ng Extracted Curve Point 16 s101122a016 E C-101116-07 10 ng Extracted Curve Point 17 s101122a017 EC-101116-08 25 ng Extracted Curve Point 18 s101122a018 EC-101116-09 50 ng Extracted Curve Point 19 s101122a019 EC-101116-10 100 ng Extracted Curve Point 20 s101122a020 EC-101116-11 200 ng Extracted Curve Point 21 s101122a021 E C-101116-12 500 ng Extracted Curve Point 22 s101122a022 10 006-25 solvent blank 23 81011228023 10 006-25 solvent blank 24 s101122a024 10 006-25 solvent blank 25 s101122a025 10 006-25 solvent blank 26 s101122a026 M B -101116-01 Method Blank 1 w/o IS 27 s101122a027 M B -101116-02 Method Blank 2 vrfo IS 28 s101122a026 MB-101116-03 Method B la n k 3 v tfo lS 29 s101122a029 M B -101116-04 Method Blank 4 vtf IS 30 s101122a030 M B -101116-05 Method Blank 5 vrf IS 31 s101122a031 M B -101116-06 Method Blank 6 wf IS 32 s101122a032 LCS-101116-01 3 ng LCS in TCR-842 33 si1122a33 L C S M O Ii 16432 3 rig LCS in TCR-842 34 s101122a034 LCS-101116-03 3 ng LCS in TCR-842 35 s101122a035 LCS-101116-04 30 ng LCS in TCR-842 36 s101122a036 LCS-101116-05 30 ng LCS in TCR-842 37 s101122a037 LCS-101116-06 30 ng LCS in TCR-842 38 s101122a38 G LP 10-01-02-05-041 DAL SS SS01 0 0000 39 s101122a039 G LP 10-01-02-05-041 D up DAL SS SS01 0 0000 Duplicate 40 s101122a040 G LP 10-01-02-05-041 LMS DAL SS SS01 0 0 00 0 Lab Matrix Spike 41 s101122a041 10 006-25 solvent blank 42 s101122a042 EC-101116-05 2.5 ng Extracted Curve Point 43 s101122a043 10 006-25 solvent blank 44 s101122a044 G LP10-01-02-05-042 DAL SS SS01 0 0005 45 s101122a045 G LP10-01-02-05-042 D up DAL SS SS01 0 0 005 Duplicate 46 s101122a046 GLP10-01-02-05-042 LMS DAL SS SS01 0 0005 Lab Matrix Spike 47 s 0 2 2 a 0 4 7 GLP10-01-02-05-043 DAL SS SS02 0 0000 48 s101122a048 G LP10-01-02-05-043 D up DAL SS SS02 0 0 000 Duplicate 49 s101122a049 G LP10-01-02-05-043 LMS DAL SS SS02 0 0000 Lab Matrix S pike 50 s101122a050 GLP10-01-02-05-044 DAL SS SS02 0 0005 51 s101122a051 GLP10-01-02-05-044 D u p DAL SS SS02 0 0 005 Duplicate 52 s101122a052 GLP10-01 -02-05-044 LMS DAL SS SS02 0 0005 Lab Matrix S pike 53 s101122a053 GLP10-01-02-05-045 DAL SS SS03 0 0000 54 s101122a054 GLP16-01-02-05-045 Dup DAL SS SS03 0 0000 Duplicate 55 s101122a055 GLP10-01 -02-05-045 LMS DAL SS SS03 0 0000 Lab Matrix S pike 56 s101122a056 GLP10-01-02-05-046 DAL SS SS03 0 0005 Analyte Peak Name Sample Type MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd Standard Standard Standard Standard S ta n d a rd Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Use Record Analyte Concentration (ng/m L) Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Name 0.00 13.195 44 M8PFOS 0.00 13.064 34 M8PFOS 0.00 13.336 792383 M8PFOS 0.00 13.346 820921 M8PFOS 0.00 13.215 261 MBPFOS 0.00 13.326 58 M8PFOS 0.00 13.235 22 " ' MBPFOS 0.00 13.074 34 MBPFOS 0.00 13.185 46 M8PFS 0.200 13.175 4710 M8PFOS E 0.500 13.256 9079 M8PFOS E 0.750 13.215 13556 M8PFOS E 1.00 13.256 17207 MBPFS E 2.50 13.235 45764 M8PFOS K 5.00 13.235 85648 M8PFOS E 10.0 13.225 152708 M8PFOS E 25.0 13.245 432329 M8PFOS E 50.0 13.225 837491 M8PFOS E 100. 13.235 1561807 M8PFOS E 200. 13.225 2889629 M8PFOS E 500. 13.225 5826921 M8PFOS 0.00 13.215 2373 M8PFOS 0.00 13.225 533 M8PFOS 0.00 13.235 94 M8PFOS 0.00 13.195 50 M8PFOS 0.00 13.205 58 M8PFOS 0.00 13.054 35 M8PFOS 0.00 13.215 46 M8PFOS NVA 13.205 51940 M8PFOS N/A 13.215 49695 M8PFOS N /A 13.225 49286 M8PFOS N /A 13.245 55993 M8PFOS N /A 13.205 55131 MBPFOS N /A 13.225 54525 M8PFOS N /A 13.225 56565 M8PFS N /A 13.205 52675 M8PFOS N /A 13.235 55504 M8PFOS N /A 13.205 40017 MBPFOS N /A 13.195 40767 M8PFOS N /A 13.215 28603 MBPFOS 0.00 13.195 22 MBPFOS E 2.50 13.205 45437 MBPFOS 0.00 0.000 0 MBPFOS N /A 13.215 29261 MBPFOS N /A 13.215 33219 MBPFOS N /A 13.195 26474 MBPFOS N/A 13.215 41848 MBPFOS N /A 13.215 44652 MBPFOS N /A 13.185 31682 MBPFOS N /A 13.205 44001 MBPFOS N /A 13.225 47901 MBPFOS N /A 13.185 30034 MBPFOS N /A 13.205 28924 MBPFOS N/A 13.235 29945 MBPFOS N/A 13.205 21317 MBPFOS N/A 13.185 23442 MBPFOS IS Peak Area (counts) 85 363 48045 49402 254 12 194 73 0 47443 47365 45201 48653 50497 46686 47643 47784 50204 47037 43862 32545 48 12 12 jO 24 73 145 52587 48995 52818 51553 55312 54505 53668 51291 52037 37384 38126 28773 48 55328 97 27813 31792 23028 42742 43226 28795 44551 46822 30236 27360 26972 14820 20080 IS C o n c e n tra tio n (ng/mL) IS Retention Time (min) Calculated Concentration (n g /m L ) Accuracy <%) N/A 13.3 N/A N/A N/A 13.7 N/A N/A N/A 13.3 N/A N/A N/A 13.3 N/A N/A N /A 13.3 N/A N/A N /A 13.0 N/A N/A N /A 13.2 N/A N/A N /A 13.3 N/A N/A N /A 0.00 N/A N/A 2.98 13.3 0.172 86.2 2.98 13.3 0.456 91.2 2.98 13.2 0.789 105. 2.98 13.2 0.954 95.4 2.98 13.3 2.65 106. 2.98 13.2 5.50 110. 2.98 13.2 9.70 97.0 2.98 13.2 27.5 110. 2.98 13.2 50.6 101. 2.98 13.2 100. 100. 2.98 13.2 195. 97.5 2.98 13.2 502. 100. N/A 13.2 N/A N /A N/A 13.3 N/A N /A N /A 13.3 N/A N/A N /A 0.00 N/A N/A N /A 13.3 N/A N/A N /A 3 .2 N/A N/A N /A ^ 3 .2 N/A N/A 2.98 13.2 2.90 N/A 2.98 13.2 2.98 N/A 2.98 13.2 2.73 N/A 2.98 13.2 3 20 N/A 2.98 13.2 2.93 N/A 1 2.98 13.2 2.94 N/A 2.98 13.2 3.10 N/A 2.98 13.2 3.02 N/A 2.98 13.2 3.14 N/A 2.98 13.2 3.15 N/A 2.98 13.2 3.15 N/A 2.98 13.2 2.92 N/A N/A 13.4 N/A N/A 2.98 13.2 2.39 95.6 N/A 13.2 N/A N/A 2.98 13.2 3.10 N /A 2.98 13.2 3.08 N /A 2.98 13.2 3.40 N /A 2.98 13 2 2.87 N /A 2.98 13.2 3.04 N /A 2.98 13.2 3.25 N /A 2.98 13.2 2.90 N /A 2.96 13.2 3.01 N /A 2.98 13.2 2.92 N /A 2.98 13.2 3.11 N /A 2.98 13.2 3.28 N /A 2.98 13.2 4.28 N /A 2.98 13.2 3.45 N/A Record M o d ifie d n a E E E E E a E E , E D E E E E E E Rie Name s101122a.w iff s101122a.wiff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a. w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s l 0 1 1 2 2 a.wiff s101122a.wifT s101122a.wiff S101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s i 01 22a.wiff s101122a.w iff s101122a.w iff s101122a.w iff S10 1 122a.w iff 101122a.w iff s101122a.w iff s101122a.w iff s101122a.w iff s101122a.wiff s i 01122a. wiff S101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.w iff S10 122a.w iff s101122a.w iff s101122a.w iff s101122a.w iff S101122a.w iff s101122a.w iff s101122a.w iff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff Printing Time: 10:47:21 AM Printing Date: Wednesday, January 05, 2011 Page 1 of 14 3M Study GLP10-01-02 Interim Report 05 Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample ID 57 s101122a057 58 s1C1122a058 59 s11122a59 60 s101122a060 6 1 . Hs101122a061 62 S1011223062 63 s101122a063 64 S1011223064 65 s101122a065 66 ^s10122a066 67 s101122a067 68 s1 0 1 1 2 2 a068 69 s101122a069 70 s101122a070 71 s101122a071 72 s101122a072 73 s101122a073 74 s101122a074 75 s101122a075 76 s101122a076 77 s101122a077 78 s101122a078 79 s101122a079 80 s101122a080 81 s101122a081 82 s1 0 1 1 2 2 a0 8 2 83 s101122a083 84 s101122a084 85 s101122a065 86 s101122a086 87 s101122a087 88 s101122a088 69 s1011223089 90 s101122a090 91 s101122a091 92 s101122a092 93 s101122a093 94 s101122a094 95 s101122a095 96 s101122a096 97 s101122a097 98 s101122a098 99 s101122a099 100 s101122a100 101 s101122a101 102 s101122a102 103 s101122a103 104 s101122a104 105 s101122a105 106 s101122a106 107 s101122a107 108 s101122a108 109 s101122a109 110 s101122a110 111 s101122a111 112 s101122a112 GLP10-01 -02-05-046 D up DAL SS SS03 0 0005 Duplicate GLP10-01 -02-05-46 LMS DAL SS SS03 0 OSLab M atrix Spike 10 006-25 soKent blank EC-1116436 5 ng Extracted C ur\ Point 10 006-25 solvent blank GLP10-01 -02-05-047 DAL SS SS03 DB 0005 GLP10-01 -02-05-047 Dup DAL SS SS03 DB 0005 Duplicate GLP10-01 -02-05-047 LMS DAL SS SS03 DB 0005 Lab M atrix S pik GLP10-01-02-05-048 DAL SS SS04 0 0000 G LP10-01-02-05-048 D up DAL SS SS04 0 0000 Duplicate GLP10-01-02-05-048 LMS DAL SS SS04 0 0000 Lab Matrix Spike GLP10-01-02-05-049 DAL SS SS04 0 0005 G LP10-01-02-05-049 D up DAL SS SS04 0 0005 Duplicate GLP10-01-02-05-049 LMS DAL SS SS04 0 0005 Lab Matrix Spike GLP10-01-02-05-050 DAL SS TRIP1 0 0000 GLP10-01-02-05-050 Dup DAL SS TRIP1 0 0000 DupBcate GLP10-01-02-05-050 LMS DAL SS 7RIP1 0 0000 Lab Matrix S pike GLP10-01-02-05-051 DAL SS SS05 0 0000 GLP10-01 -02-05-051 Dup DAL SS SS05 0 0000 Duplicate GLP10-01 -02-05-051 LMS DAL SS SS05 0 0000 Lab Matrix S pike 10 006-25 solvent blank EC-101116-07 10 ng Extracted C un Point 10 006-25 solvent blank GLP10-01-02-05-052 DAL SS SS05 0 0005 GLP10-01-02-05-052 D up DAL SS SS05 0 0005 Duplicate GLP10-01 -02-05-052 LMS DAL SS S S05 0 0005 Lab Matrix S pike GLP10-01 -02-05-054 DAL SS SS06 0 0000 GLP10-01 -02-05-054 D up DAL SS SS06 0 0000 DupBcate GLP10-01-02-05-054 LMS DAL SS SS06 0 0000 Lab Matrix Spike GLP1-01 -02-05-055 DAL SS SS06 0 0005 GLP10-01 -02-05-055 D up DAL SS SS06 0 0005 Duplicate GLP10-01-02-05-055 LMS DAL SS SS06 0 0005 Lab Matrix Spike GLP10-01-02-05-056 DAL SS SS06 DB 0005 GLP10-01-02-05-056 D up DAL SS SS06 DB 0005 Duplicate GLP1-01-02-05-056 LMS DAL SS SS06 DB 0005 Lab Matrix Spik GLP10-01-02-05-057 DAL SS SS07 0 0000 G LP10-01-02-05-057 Dup DAL SS SS07 0 0000 Duplicate GLP10-01-02-05-057 LMS DAL SS SS07 0 0000 Lab Matrix Spike 10 006-25 solvent blank E C-101116-05 2.5 ng Ebdracted C u n P oint 10 006-25 solvent blank GLP1-1-02-05-058 DAL SS SS07 0 5 GLP10-01 -02-05-058 Dup DAL SS SS07 0 0005 Duplicate GLP10-01-02-05-058 LMS DAL SS SS07 0 0005 Lab Matrix Spike GLP10-01-02-05-059 DAL SS SS08 0 0000 GLP10-01-02-05-059 D up DAL SS SS08 0 0000 Duplicate GLP10-01 -02-05-059 LMS DAL SS SS08 0 0000 Lab Matrix Spike GLP10-01 -02-05-060 D A L SS SS08 DB 0000 G LP 10-01-02-05-060 D up DL SS SS08 DB 000 DupBcate GLP10-01-02-05-060 LMS DAL SS SS08 DB 0000 Lab Matrix Spik GLP10-01-02-05-061 DAL SS SS08 0 0005 GLP10-01-02-05-061 Dup DAL SS SS08 0 0005 Duplicate GLP10-01-02-05-061 LMS DAL SS SS08 0 0005 Lab Matrix Spike GLP10-01-02-05-062 DAL SS SS09 0 0000 GLP10-01-02-05-062 Dup DAL SS SS09 0 0000 Duplicate GLP10-01 -02-05-062 LMS DAL SS SS09 0 0000 Lab Matrix Spike Analyte Peak Name Sample Type Use Record Analyte Concentration (ng /m L ) Analyte Retention Time (min) Analyte Peak Area (counts) MPFOS Unknown i N/A 13.245 25376 MPFOS Unknown : N/A 13.185 21171 MPFOS Double Blank j . 13.094 67 MPFOS MPFOS Quality Control E Double Blank | 5.00 0.00 13.245 0.000 87276 0 MPFOS Unknown i N/A 13.205 25292 MPFOS IUnknown N/A 13.205 27536 MPFOS MPFOS Unknown Unknown I N/A N/A 13.225 13.205 22340 38249 MPFOS Unknown l N/A 13.235 49009 MPFOS Unknown ; N/A 13.245 37686 MPFOS Unknown ! N/A 13.205 54657 MPFOS Unknown | N/A 13.225 54837 MPFOS Unknown ; N/A 13.235 43194 MPFOS Unknown N/A 13.124 52703 MPFOS Unknown N/A 13.225 53224 MPFOS Unknown N/A 13.215 50175 MPFOS Unknown N/A 13.185 19667 MPFOS Unknown N/A 13.195 20527 MPFOS Unknown N/A 13.114 23433 MPFOS Double Blank 0.00 13.266 22 MPFOS Quality Control K 10.0 13.215 170003 MPFOS Double Blank 0.00 13.326 34 MPFOS Unknown N/A 13.145 26110 MPFOS Unknown N/A 13.145 26363 MPFOS Unknown N/A 13.185 20399 MPFOS Unknown N/A 13.225 45668 MPFOS Unknown N/A 13.185 44488 MPFOS MPFOS Unknown Unknown N/A 13.215 36742 N/A 13.205 50085 MPFOS Unknown N/A 13.185 47271 MPFOS Unknown N/A 13.205 38197 MPFOS Unknown N/A 13.225 47145 MPFOS Unknown N/A 13.225 48364 MPFOS Unknown I N/A 13.185 38244 MPFOS Unknown | N/A 13.205 42094 MPFOS Unknown I N/A 13.215 43543 MPFOS Unknown N/A 13.235 34084 MPFOS Double Blank | 0.00 13.225 46 MPFOS Quality Control E 2.50 13.225 49126 MPFOS Double Blank ; 0.00 0.000 0 MPFOS Unknown | N/A 13.215 26633 MPFOS Unknown ' N/A 13.205 27562 MPFOS Unknown j N/A 13.165 22834 MPFOS Unknown j N/A 13.195 53764 MPFOS Unknown | N/A 13.185 54597 MPFOS Unknown N/A 13.195 - 49453 MPFOS Unknown I N/A 13.195 49923 MPFOS Unknown N/A 13.235 52956 MPFOS Unknown N/A 13.235 50501 MPFOS Unknown N/A 13.185 50280 MPFOS Unknown N/A 13.114 55999 MPFOS Unknown N/A 13.215 47279 MPFOS Unknown N/A 13.195 44429 MPFOS Unknown N/A 13.225 45024 MPFOS Unknown N/A 13.145 35353 IS Peak Name M8PFOS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS ftP F O S M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS IS Peak Area (counts) 22798 16650 36 54543 73 23147 2176 15022 38069 44863 35600 49651 52296 40674 56512 52828 55576 13228 13535 8442 48 50799 156 22053 19928 15286 46020 46877 39094 51100 53840 35176 48153 48207 36501 40653 43630 31664 339 53171 145 24976 27346 17646 49626 52016 53341 53566 54801 48874 58079 54289 47899 43811 41182 33746 IS C o n c e n tra tio n (ng /m L ) IS Retention Urne (min) Calculated C o n c e n tra tio n (n g /m L ) Accuracy <%> 2.98 13.2 3.29 N/A 2 98 13.2 3 77 N/A N/A 13.1 1 N/A N/A 2.98 13.2 4.78 95.6 W 13.1 N/A N/A 2.98 13.2 3 22 N/A 2.98 2 3.76 N/A 2.98 13.2 4.43 N/A 2.98 13.2 2.95 N/A 2.98 13.2 3.22 N/A 2.98 13.2 3.12 N/A 2.98 13.2 3.25 N/A 2.98 13.2 3.09 N/A 2.98 13.2 3.13 N/A 2.98 13.2 2.73 N/A 2.98 13.2 2.96 N/A 2.98 13.2 2.64 N/A 2.98 13.1 4.43 N/A 2.98 13.2 4.52 N/A 2.98 13.2 8.38 N/A N/A 13.4 N/A N/A 2.98 13.2 10.1 101. N/A 13.4 N/A N/A 2.98 13.2 3.50 N/A 2.98 13.2 3.93 N/A 2.98 13.2 3.96 N/A 2.98 13.2 2.91 N/A 2.98 13.2 2.78 N/A 2.98 13.2 2.75 N/A 2.98 13.1 2.88 N/A 2.96 13.2 2.56 N/A 2.98 13.2 3.20 N/A 2.98 13.2 2.87 N/A 2.98 13.2 2.95 N/A 2.98 13.2 3.08 N/A 2.98 13.2 3.05 PN/A 2.98 13.1 2.93 N/A 2.98 '13.2 3.17 N/A N/A 13.2 N/A N/A 2.98 13.2 2.70 108. N/ 13.2 N/A N/A 2.98 13.1 3.14 N/A 2.98 13.1 2.96 N/A 2.98 13.2 3.84 N/A 2.98 13.2 3.19 N/A 2.98 13.2 3.09 N/A 2.98 13.2 2.71 N/A 2.98 13.2 2.73 N/A 2.98 13.2 2.83 N/A 2.98 13.2 3.04 N/A 2.98 13.2 2.53 N/A 2.98 13.2 3.03 N/A 2.98 13.2 2.90 N/A 2.98 ^13.2 2.98 N/A 2.98 13.2 3.22 N/A 2.98 13.2 3.08 N/A Record M o d ifie d E E E E E D E D E E E E E E E E Rie Name s101122a.wiff s101122a.wiff s101122a. w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 0 1 1 2 2 a.wiff s101122a. w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff S101122a.w iff s10 1 122a.w iff s101122a.wiff s10 1 122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s10 1 122a.w iff s10 1 122a.w iff s10 1 122a.w iff s10 1 122a.w iff S10 1 122a.w iff s101122a.wiff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.w iff s10 1 122a.w iff si01122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a. w iff s101122a.wiff s02 2a .w ff s i 0 22a. w iff s10 1 122a.w iff S101122a.w iff s10 1 122a.w iff s101122a.wiff s10 1 122a w iff s10 1 122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff sldl122a.w iff s 1 0 1 1 2 2 a.wiff s101122a.wiff Printing Time: 10:47:22 AM Printing Date: Wednesday, January 05, 2011 Page 2 of 14 3M Study GLP10-01-02 Interim Report 05 Page 169 of 962 Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample ID 113 s101122a113 114 s101122a114 115 s101122a115 116 s101122a116 117 s101122a117 118 s101122a118 119 s101122a119 120 s101122a120 121 s101122a121 122 s101122a122 123 s101122a123 124 s101122a124 125 s101122a125 126 is101122a126 127 s101122a127 1 2 8 1s101122a128 129 s101122a129 130 s101122a130 131 s101122a131 132 s101122a132 133 s101122a133 134 s101122a134 135 s101122a135 '136 s101122a136 137 s101122a137 138 s101122a138 139 s101122a139 140 s101122a140 141 s101122a141 142 s101122a142 143 s101122a143 144 s101122a144 145 s101122a145 146 s101122a146 147 s101122a147 148 s101122a148 149 s101122a149 150 s101122a150 151 s101122a151 152 s101122a152 153 s101122a153 154 s101122a154 155 s101122a155 156 s101122a156 157 s101122a157 158 s101122a158 159 s101122a159 160 s101122a160 161 s101122a161 162 s101122a162 163 s101122a163 164 s101122a164 165 s101122a165 166 s101122a166 167 s101122a167 168 s101122a168 10 006-25 solvent blank EC-101116-06 5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-063 DAL SS SS09 0 0005 GLP10-01-02-05-063 Dup DAL SS SS09 0 0005 Duplicate GLP10-01-02-05-063 LMS DAL SS SS09 0 0005 Lab Matrix Spike GLP10-01-02-05-064 DAL SS GP01 0 0000 GLP10-01 -02-05-064 Dup DAL SS GP01 0 0000 Duplicate GLP10-01 -02-05-064 LMS DAL SS GP01 0 0000 Lab Matrix Spike GLP10-01 -02-05-065 DAL SS GP01 0 0005 GLP10-01 -02-05-065 Dup DAL SS GP01 0 0005 Duplicate GLP10-01 -02-05-065 LMS DAL SS GP01 0 0005 Lab Matrix Spike GLP10-01-02-05-066 DAL SS GP01 0 0020 GLP10-01 -02-05-066 Dup DAL SS GP01 0 0020 Duplicate GLP16-01 -02-05-066 LMS DAL SS GP01 0 0020 Lab Matrix Spike GLP10-01 -02-05-067 DAL SS GP01 0 0060 GLP10-01 -02-05-067 Dup DAL SS GP01 0 0060 Duplicate GLP10-01-02-05-067 LMS DAL SS GP01 0 0060 Lab Matrix Spike 10 006-25 solvent blank EC-101116-07 1 0 n g Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-068 DAL SS GP02 0 0000 GLP10-01 -02-05-068 Dup DAL SS GP02 0 0000 Duplicate GLP10-01-02-05-068 LMS DAL SS GP02 0 0000 Lab Matrix Spike GLP10-01-02-05-069 DAL SS GP02 0 0005 GLP10-01 -02-05-069 Dup DAL SS GP02 0 0005 Duplicate GLP10-01-02-05-069 LMS DAL SS GP02 0 0005 Lab Matrix Spike GLP10-01-02-05-070 DAL SS GP02 0 0020 GLP10-01-02-05-070 Dup DAL SS GP02 0 0020 Duplicate GLP10-01-02-05-070 LMS DAL SS GP02 0 0020 Lab Matrix Spike GLP10-01-02-05-071 DAL SS GP02 DB 0020 GLP10-01-02-05-071 Dup DAL SS GP02 DB 0020 DupBcate GLP10-01-02-05-071 LMS DAL SS GP02 DB 0020 Lab Matrix Spik GLP10-01-02-05-072 DAL SS GP02 0 0120 GLP10^01-02-05-072 Dup DAL SS GP02 0 0120 Duplicate G L p tQ le i-02-054)72 LMS DAL SS GP02 0 0120 Lab Matrix Spike 10 006-25 solvent blank EC-101116-05 2.5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-073 DAL SS GP03 0 0000 ^ p ib ^ b i-6 2 -d 5 4 D 7 3 Dup DAL SS GP03 0 0000 Duplicate GLP10-01-02-05-073 LMS DAL SS GP03 0 0000 Lab Matrix Spike GLP10-01 -02-05-074 DAL SS GP03 0 0005 GLP10-01-02-05-074 Dup DAL SS GP03 0 0005 Duplicate GLP10-01-02-05-074 LMS DAL SS GP03 0 0005 Lab Matrix Spike G LP i 0-01 -02-06-075 DAL SS GP03 6 0020 GLP10-01-02-05-075 Dup DAL SS GP03 0 0020 Duplicate GLP10-01-02-05-075 LMS DAL SS GP03 0 0020 Lab Matrix Spike GLP1 0 1 -02-05-076 DAL SS GP03 DB 0020 GLP10-01 -02-05-076 Dup DAL SS G P03 DB 0020 Duplicate GLP10-01 -02-05-076 LMS DAL SS GP03 DB 0020 Lab M atrix Spik GLP10-01 -02-05-077 DAL S S GP03 0 0050 GLP10-01 -02-05-077 Dup DAL SS G P03 0 0050 Duplicate GLP10-01-02-05-077 LMS DAL SS GP03 0 0050 Lab Matrix Spike 10 006-25 solvent blank EC-101116-06 5 ng Extracted Curve Point Analyte Peak Name Sample Type MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Use Record Analyte C o n c e n tra tio n (n g /m L ) Analyte Retention Time (m in ) Analyte Peak Area (counts) 0.00 13.084 22 K 5.00 13.205 88879 0.00 13.094 22 N/A 13.165 44886 N/A 13.205 42759 N/A 13.225 34789 N/A 13.225 49300 N/A 13.175 46668 N/A 13.195 36964 N/A 13.195 46585 N/A 13.215 45922 N/A 13.155 34664 N/A 13.225 41163 N/A 13.225 41938 N/A 13.215 35658 N/A 13.145 44372 N/A 13.215 41911 N/A 13.175 37943 0.00 13.215 22 E 10.0 13.215 142670 0.00 0.000 0 N/A 13.205 49368 N/A T3.205 49583 N/A 13.195 45209 N/A 13.205 49449 N/A 13.225 53798 N/A 13.225 44327 N/A 13.175 46955 N/A 13.155 47504 N/A "13.175 33581 N/A 13.195 47463 N/A 13.185 43059 N/A 13.195 34402 N/A 13.175 50414 N/A 13.155 50179 N/A 13.205 43231 0.00 0.000 0 E 2.50 13.195 43831 0.00 13.044 22 N/A 13.175 39774 N/A 13.165 41486 N/A 13.185 34080 N/A *"13.175 31088 N/A 13.155 31583 N/A 13.165 19503 N/A 13.205 33508 N/A 13.165 30319 N/A 13.165 22055 N/A 13.235 25152 N/A 13.175 30263 N/A 13.084 22094 N/A 13.124 47299 N/A 13.195 43100 N/A 13.195 36473 0.00 13.397 34 E 5.00 13.135 95013 IS Peak Name M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8F' FO S M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS MBPFOS M8PFOS M8PFOS M8PFOS MBPFOS M8PFOS M8PFOS M8PFOS M8PFOS IS Peak Area (counts) 24 54572 12 43753 42790 34474 46527 45554 33683 45042 42719 32797 42320 47058 34645 50729 43001 39378 48 48993 61 48637 54013 45478 54548 57335 48781 45441 45365 34907 45144 41906 36411 49574 50284 42665 73 53249 109 40919 37565 33062 30022 31014 16015 29224 29086 16886 23713 25750 17306 45059 44431 32833 24 56024 IS C o n c e n tra tio n (ng/m L) IS Retention Time (min) Calculated C o n c e n tra tio n (ng /m L ) Accuracy <%> N/A 13.3 N/A N/A 2.98 13.2 4.87 97.3 N/A 13.3 N/A N/A 2.98 13.1 3.02 N/A 2.98 13.2 2.94 N/A 2.98 13.2 2.97 N/A 2.98 13.2 3.12 N/A 2.98 13.1 3.01 N/A 2.98 13.2 3.24 N/A 2.98 13.2 3.04 N/A 2.98 13.2 3.17 N/A 2.98 13.2 3.11 N/A 2.98 13.2 2.85 N/A 2.98 13.2 2.60 N/A 2.98 13.2 3.03 N/A 2.98 13.2 2.55 N/A 2.98 13.2 2.86 N/A 2.98 13.2 2.83 N/A N/A 13.1 N/A N/A 2.98 13.2 8.80 88.0 N/A 13.2 N/A N/A 2.98 13.2 2.98 N/A 2.98 13.2 2.69 N/A 2.98 13.2 2.92 N/A 2.98 13.2 2.65 N/A 2.98 13.2 2.75 N/A 2.98 13.2 2.66 N/A 2.98 13.2 3.04 N/A 2.98 13.2 3.08 N/A 2.98 13.2 2.82 N/A 2.98 13.2 3.10 N/A 2.98 13.2 3.02 N/A 2.98 13.2 2.77 N/A 2.98 2.98 13.2 13.2 2.99 2.93 N/A N/A 2.98 13.2 2.98 N/A N/A 13.2 N/A N/A 2.98 13.2 2.40 95.8 N/A 13.3 N/A N/A 2.98 13.2 2.85 N/A 2.98 13.2 3.26 N/A 2.98 13.2 3.03 N/A 2.96 13.2 '3.05 N/A 2.98 13.2 2.99 N/A 2.98 13.1 3.61 N/A 2.98 13.2 3.39 N/A 2.98 13.2 3.07 N/A 2.98 13.2 3.88 N/A 2.98 13.2 3.12 N/A 2.98 13.2 3.48 N/A 2.98 13.1 3.79 N/A 2.98 13.2 *3.09 N/A 2.98 13.2 2.85 N/A 2.98 13.2 3.28 N/A N/A 13.3 N/A N/A 2.98 13.2 5.07 101. Record Modified E a E E E E E a E E E E E File Name s 1 011 22a.wri f f s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 01 122a.wriff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff sldl122a.w iff s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.w ifi s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff Printing Time: 10:47:23 AM Printing Date: Wednesday, January 05, 2011 Page 3 of 14 3M Study G LP10-01-02 Interim R eport 05 Page 170 of 962 *Stan V1660305 Results Name: sl01122a.rdb Sample Name Sam ple ID 169 s101122a169 170 s101122a170 171 s101122a171 172 s101122a172 173 s101122a173 174 s101122a174 176 s101122a175 176 s101122a176 177 s101122a177 178 s101122a178 179 s101122a179 180 s 01122a180 8 ^ s101122a181 182 s101122a182 183 s101122a183 184 s101122a001 185 s101122a002 186 s101122a003 187 Sl01122a004 188 s101122a005 189 s101122a006 190 s101122a007 191 s101122a008 192 s101122a009 193 s101122a010 194 s101122a011 195 s101122a012 196 s101122a013 197 s101122a014 198 s101122a015 199 s101122a016 200 s101122a017 201 s101122a018 202 s101122a019 203 s1 0 1 1 2 2 a0 2 0 204 s10122a02 205 s101122a022 206 s101122a023 207 s101122a024 208 s101122a025 209 s101122a026 210 s101122a027 211 s101122a028 212 s10l122a029 213 s101122a030 214 s101122a031 215 s101122a032 216 s101122a033 217 s101122a034 218 s101122a035 219 s101122a036 220 s101122a037 221 s101122a038 222 s101122a039 223 s101122a040 224 s101122a041 10 006-25 soKent blank GLP10-01-02-05-078 DAL SS GP04 0 0000 G LP i 6-01 -02-05-078 Dup DAL SS GP04 0 0000 Duplicate G LP 10-01-02-05-078 LMS DAL SS GP04 0 0 000 Lab Matrix Spike GLP10-01-02-05-079 DAL SS GP04 0 0005 GLP10-01-02-05-079 Dup DAL SS GP04 0 0005 Duplicate G LP t0-01-02-05-079 LMS DAL SS GP04 0 0005 Lab Matrix Spike GLP10-01-02-05-080 DAL SS GP04 0 0020 GLP10-01-02-05-080 Dup DAL SS GP04 0 0020 Duplicate GLP10-01-02-05-080 LMS DAL SS GP04 0 0020 Lab Matrix Spike MB-101116-07 Method Blank 5 g wV IS fo r Dilutions MB-101116-08 Method Blank 5 g wV IS fo r Dilutions 10 006-25 solvent blank EC-101116-07 10 ng Extracted Curve Point 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank EC-101116-09 50 ng W arm up standard EC-101116-09 50 ng W arm up standard 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank To 006-25 solvent blank 10 006-25 solvent blank EC-101116-01 0.2 ng Extracted Curve Point EC-101116-02 0.5 ng Ertracted Curve Point EC-101116-03 0.75 ng E x a c te d Curve Point E C-101116-04 1 ng Extracted Curve Point EC-101116-05 2.5 ng Extracted Curve Point E C-101116-06 5 ng Extracted Curve Point E C-101116-07 10 ng Extracted Curve Point EC-101116-08 25 ng Extracted Curve Point EC-101116-09 50 ng Extracted Curve Point EC-101116-10 100 ng Extracted Curve Point E C -101116-11 200 ng Extracted Curve Point EC-101116-12 500 ng Extracted Curve Point 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank MB-101116-01 Method Blank 1 W o IS MB-101116-02 Method Blank 2 W o IS M B -101116-03 Method Blank 3 W o IS MB-101116-04 Method Blank 4 W IS MB-101116-05 Method Blank 5 W IS MB-101116-06 Method Blank 6 W IS LCS-101116-01 3 ng LCS inTCR-842 LCS-101116-02 3 ng LCS inTCR-842 LCS-101116-03 3 ng LCS inTCR-842 LCS-101116-04 30 ng LCS In TCR-842 LCS-101116-05 30 ng LCS in TCR-842 LCS-101116-06 30 ng LCS inTCR-842 GLP10-01-02-05-041 DAL SS SS01 0 0000 GLP10-01-02-05-041 Dup DAL SS SS01 0 0000 Duplicate GLP10-01 -02-05-041 LMS DAL S S SS01 0 0000 Lab Matrix Spike 10 006-25 solvent blank Analyte Peak Name Sample Type MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Use Record Analyte C o n c e n tra tio n (ng /m L ) Analyte Retention Time (min) Analyte Peak Area (counts) 0.00 13.185 10 N/A 13.165 39730 N/A 13.185 41193 NVA 13.135 37158 NVA 13.165 44293 N/A 13.215 41491 ....... ......... N/A . N /A 13.175 13.084 13.205 3872 55970 52897 NVA 13.195 46227 N/A 13.195 56735 N/A 13.155 56317 0.00 0.000 0 E 10.0 13.124 164316 0.00 13.205 58 0.00 7.758 2885 0.00 7.737 3153 0.00 7.949 6578074 0.00 7.929 7016544 0.00 7.798 3963 0.00 7.808 3600 0.00 7.778 3175 0.00 0.00 7.828 8.181 2947 732 0.200 E 0.500 7.879 7.889 39509 73637 E 0.749 7.889 111617 E 0.999 7.889 139958 E 2.50 7.909 379840 E 5.00 7.889 738838 E 9.99 7.899 1482560 E 25.0 7.889 3428621 E 50. 7.899 7057087 E 99.9 7.889 13396168 E 200. 7.889 24772295 E 500. 7.899 48682348 0.00 7.959 10342 0.00 7.949 2002 0.00 7.980 1367 0.00 7.889 1374 0.00 7.899 4525 . 7.939 3584 .0 7.879 2446 NVA 7.869 21416 NVA 7.899 24201 N/A 7.869 22492 NVA 7.899 475288 N/A 7.879 469906 NVA 7.889 492881 N/A 7.899 4434233 N/A 7.879 4696428 N/A 7.899 4608122 N/A 7.899 139654 N/A 7.879 148565 N/A 0.00 7.899 8.181 472894 1334 IS Peak Name M8PFOS M8PFS BPFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFOS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS IS Peak Area (counts) 12 35046 39880 33140 41859 41215 32590 52490 50669 45453 58477 54979 48 58407 133 194 24 328378 318763 97 36 0 0 0 308460 314419 333174 367425 333370 333716 332213 349576 338728 334707 321863 286556 48 0 0 85 109 157 12 327461 328517 347892 344940 361738 340008 331037 341913 351661 322720 35547 357405 97 IS Concentration (ng /m L ) IS Retention Time (min) Calculated Concentration (n g /m L ) Accuracy <%) N/A 2.98 13.3 13.2 N/A 3.35 N/A N/ 2.98 13.2 3.04 NVA 2.98 13.2 3.31 N/A 2.98 13.2 3.12 NVA 2.98 2.98 13.2 13.1 2 96 *45 N/A N/A 2.98 13.2 3.14 N/A 2.98 13.2 3.07 N/A 2.98 13.2 2.99 N/A 2.98 113.2 2.85 N/A 2.98 13.2 3. N/A N/A 13.2 N/A N/A 2.98 13.2 8.50 85.0 N/A 13.1 N/A N/A N/A 7.94 N/A N/A N/A 8.15 N/A N/A NVA 7.94 N/A NVA NVA 7.93 N/A N/A NVA 7.86 N/A N/A N/A 7.87 N/A N/A N/A 0.00 N/A N/A N/A 0.00 N/A N/A N/A 3.03 0.00 7.89 NVA 0.246 N/A 123. 3.03 7.91 0.501 100. 3.03 7.88 0.743 99.2 3.03 7.89 0.853 85.4 3.03 7.89 2.68 107. 3.03 7.90 5.26 105. 3.03 7.88 10.7 107. 3.03 7.89 23 7 94.7 3.03 7.89 50.9 102. 3.03 7.90 99.7 99.8 3.03 7.88 199. 99.7 3.03 7.90 500. 100. N/A 7.99 NVA N/A N/A 0.00 N/A N/A N/A 0.00 NVA N/A N/A 8.10 N/A N/A N/A 7.90 NVA N/A N/A 7.86 N/A N/A N/A 8.08 NVA N/A 3.03 7.90 0.0956 N/A 3.03 7.89 0.115 N/A 3.03 7.89 0.0938 N/A 3.03 7.89 3.25 N/A 3.03 7.89 3.06 N/A 3.03 7.87 3 42 N/A 3.03 7.89 32 5 N/A 3.03 7.90 33.3 NVA 3.03 7.90 31.8 NVA 3.03 7.96 0.977 N/A 3.03 7.89 0.942 NVA 3.03 7.88 3.12 N/A N/A 7.99 N/A NVA Record Modified E E E E E E E E File Name s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s i 01122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff 8101122a.w iff s101122a.wiff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 0 1 1 2 2 a.wiff s 1 0 1 122a.wiff s101122a.wiff s101122a.w iff s101122a.w iff s101122a.w iff s101122a.wiff s10 1 122a.w iff s10 1 122a.w iff s10 1 122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wfff s101122a.wiff s101122a.wiff S101122a.w iff s101122a.w iff s 1 01122a.w iff Printing Time: 10:47:23 AM Printing Date: Wednesday, January 05, 2011 Page 4 of 14 3M Study GLP10-01-02 Interim Report 05 Page 171 of 962 *Stan V1660305 Results Name: sl01122a.rdb ........................... Sample Name Sample ID 225 s101122a042 226 s i01122a043 227 s101122a044 228 s101122a045 229 s101122a046 230 s101122a047 231 s i 0 1 122a48 232 s101122a049 233 s101122a050 234 s101122a051 235 s101122a052 236 s101122a053 237 s101122a054 238 s101122a055 239 s101122a056 240 s101122a057 241 s101122a058 242 s101122a059 243 s101122a060 244 s101122a061 245 s1 0 1 1 2 2 a062 246 si0122a063 247 s11122a064 248 Sl0 1122a065 249 s101122a066 250 s101122a067 251 s101122a068 252 s101122a069 253 s101122a070 254 s101122a071 255 s101122a072 256 s101122a073 257 s101122a074 258 s101122a075 259 s101122a076 260 si01122a077 261 s101122a078 262 s101122a079 263 s101122a080 264 s101122a081 265 s101122a082 266 s101122a083 267 s101122a084 268 s101122a085 269 s101122a066 270 s101122a087 271 s101122a088 272 si0122a89 273 s101122a090 274 s101122a091 275 s101122a092 276 s101122a093 277 s101122a094 278 s101122a095 279 s101122a096 28 s101122a097 EC-101116-05 2.5 ng Extracted C u n Point 10 006*25 solvent blank GLP10-01 -02-05-042 DAL SS SS01 0 0005 GLP10-01-02-05-042 D u p DAL SS SS01 0 0005 Duplicate GLP10-01 -02-05-042 LM S DAL SS SS01 0 0005 Lab Matrix Spike GLP10-01-02-05-043 DAL SS SS02 0 0000 GLP10-01 -02-05-043 D u p DAL SS SS02 0 0000 Duplicate GLP10-01-02-05-043 LM S DAL SS SS02 0 0000 Lab Matrix Spike GLP10-01-02-05-044 DAL SS SS02 0 0005 GLP10-01-02-05-044 D up DAL SS SS02 0 0005 Duplicate GLP10-01-02-05-044 LMS DAL SS SS02 0 0005 Lab Matrix Spike GLP10-01-02-05-045 DAL SS SS03 0 0000 GLP10-01-02-05-045 D u p DAL SS SS03 0 0000 DupDcate GLP10-01-02-05-045 LM S DAL SS SS03 0 0000 Lab Matrix Spike GLP10-01-02-05-046 DAL SS SS03 0 0005 GLP10-01 -02-05-046 D up DAL SS SS03 0 0005 Duplicate GLP10-01-02-05-046 LMS DAL SS SS03 0 0005 Lab Matrix Spike 10 006-25 solvent blank EC-101116-06 5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01 -02-05-047 DAL SS SS03 DB 0005 GLP10-01 -02-05-047 D u p DAL SS SS03 DB 0005 Duplicate GLP10-01-02-05-047 LMS DAL SS SS03 DB 0005 Lab Matrix Spik GLP10-01 -02-05-048 DAL SS SS04 0 0000 G LP10-01-02-5-048 D u p DAL SS SS04 0 0000 Duplicate GLP10-01 -02-05-048 LMS DAL SS SS04 0 0000 Lab Matrix Spike GLP10-01 -02-05-049 DAL SS SS04 0 0005 GLP10-01-02-05-049 D u p DAL SS SS04 0 0005 Duplicate G LP10-01 -02-05-049 LMS DAL SS SS04 0 0005 Lab Matrix Spike GLP 1-01 -02-05-050 D A L S S 7RIP1 0 0000 GLP10-01 -02-05-050 D u p DAL SS TRIP1 0 0000 Duplicate GLP10-01-02-05-050 LMS DAL SS TRIP1 0 0000 Lab Matrix Spike GLP10-01 -02-05-051 DAL SS SS05 0 0000 GLP10-01-02-05-051 D up D A L SS SS05 0 0000 Duplicate GLP10-01-02-05-051 LMS DAL SS SS05 0 0000 Lab Matrix Spike 10 006 -2 5 solvent blank C-101116-07 10 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01 -02-05-052 DAL SS SS05 0 0005 G LP10-01-02-05-052 D u p DAL SS SS05 0 0005 Duplicate G LP10-01-02-05-052 LMS DAL SS SS05 0 0005 Lab Matrix Spike GLP10-01-02-05-054 DAL SS SS06 0 0000 G L p lo g o i'-02-5-54 Dup' DAL SS SS6 0000 Duplicate G LP10-01-02-05-054 LMS D A L SS SS06 0 0000 Lab Matrix Spike GLP10-01-02-05-055 DAL SS SS06 0 0005 GLP10-01 -02-05-055 D u p D A L SS SS06 0 0005 Duplicate GLP10-01-02-05-055 LMS DAL SS SS06 0 0005 Lab Matrix Spike GLP10-01-02-05-056 DAL SS SS06 DB 0005 GLP10-01-02-05-056 D u p DAL SS SS06 DB 0005 DupDcate GLP10-01-02-05-056 LMS DAL SS SS06 DB 0005 Lab Matrix Spik GLP10-01-02-05-057 DAL SS SS07 0 0000 GLP10-01-02-05-057 D up DAL SS SS07 0 0000 Duplicate GLP10-01-02-05-057 LMS DAL SS SS07 0 0000 Lab Matrix Spike 10 006 -2 5 solvent blank EC-101116-05 2.5 ng E rtra cte d Curve Point 10 006 -2 5 solvent blank Analyte Peak Name Sample Type PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Qualify Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Qualify Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Qualify Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Qualify Control Double Blank Use Record ................ ' Analyte C o n c e n tra tio n (rg/mL) Analyte Retention Time (min) Analyte Peak Area (counts) IS 2.50 7.889 417342 0.00 8.080 594 N/A 7.879 145934 N/A 7.909 112423 N/A 7.889 405086 ] N/A 7.889 155578 i N/A 7.879 25205 | N/A 7.899 1668271 i N/A 7.889 737423 N/A 7.889 710492 N/ 7.889 2234199 N/A 7.879 855170 N/A 7.899 836422 N/A 7.879 2453842 j N/A 7.879 1275431 j N/A 7.889 1450691 ] N/A 7.879 2818523 j 0.00 8.010 1707 IS 5.00 7.869 802433 | 0.00 8.191 1019 | N/A 7.899 1110817 i N/A 7.869 684388 i N/A 7.879 2332578 I N/A \ N/A 7.889 7.879 443914 285288 | N/A 7.879 1866855 | N/A 7.869 158059 | N/A 7.889 154762 N/A 7.879 489148 N/A 7.879 24884 N/A 7.879 23444 N/A 7.869 343361 N/A 7.889 3126129 | N/A 7.879 2755982 i N/ 7.889 9626961 | 0.00 7.990 3365 IS 9.99 7.889 1472073 i 0.00 8.030 1450 t N/A 7.899 915805 N/A 7.869 922158 j N/A 7.879 2516047 N/A 7.879 202622 j N/A 7.879 218346 j N/A 7.879 530649 i N/A 7.899 78960 j N/A 7.899 87789 i N/A 7.699 394544 | N/A 7.879 92525 j N/A 7.889 86709 N/A 7.889 390834 N/A 7.869 1528961 N/A 7.889 1617229 N/A 7.879 2855935 0.00 8.252 1230 K 2.50 7.899 383487 0.00 8.060 586 IS Peak Name MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS IS Peak Area (counts) 339568 48 369792 357815 340268 375468 354050 362277 312969 356739 334145 356001 362692 368598 335483 353292 389840 121 362947 97 374506 3 5 2 2 349321 368922 362039 346186 344170 390301 357733 379919 342116 383808 349 363667 342647 0 344969 85 368347 345801 331369 369932 348376 363850 357473 394912 332818 354981 347635 337267 348358 348419 362676 61 359706 121 IS C o n c e n tra tio n (n g /m L ) IS Retention Time (min) Calculated Concentration (ng /m L ) Accuracy <%) 3.03 N/A 7.89 7.95 2.89 N/A 116. N/A 3.03 7.88 0.886 N/A 3.03 7.88 0.693 N/A 3.03 7.90 2.80 N/A 3.03 7.88 0 933 N/A 3.03 7.89 0.788 N/A 3.03 7.90 11.0 N/A 3.03 7.88 5.60 N/A 3.03 7.90 4.73 N/A 3.03 7.87 16.1 N/A 3.03 7.87 5.72 N/A 3.03 7.88 548 N/A 3.03 7.88 16.0 N/A 3.03 7.89 9.09 N/A 3.03 7.89 9.83 N/A 3.03 7.87 17.4 N/A N/A 7.96 N/A N/A 3.03 7.89 5 25 105. N/A 7.96 N/A N/A 3.03 7.87 7.07 N/A 3.03 7.89 4.61 N/A 3.03 7.88 16.1 N/A 3.03 7.87 2.83 N/A 3.03 7.91 1.83 N/A 3.03 7.88 12.9 N/A 3.03 7.89 1.04 N/A 3.03 7.87 0.891 N/A 3.03 7.97 3.22 N/A 3.03 7.89 0.0959 N/A 3.03 7.87 0.103 N/A 3.03 7.89 2.09 N/A 3.03 7.87 22.1 N/A 3.03 7.88 18.2 N/A 3.03 7.87 69.1 N/A N/A 0.00 N/A N/A 3 03 7.88 10.2 102. N/A 7.95 N/A N/A 3.03 7.89 5.92 N/A 3.03 7.90 6.35 N/A 3.03 7.89 18.3 N/A 3.03 7.89 1 25 \,*v 3.03 7.88 1.44 N/A 3.03 7.98 3.44 N/A 3.03 7.88 0.469 N/A 3.03 7.89 0.472 N/A 3.03 7.91 2.79 N/A 3.03 7.88 0.564 N/A 3.03 7.90 0.537 N/A 3.03 7.91 2.72 N/A 3.03 7.87 10.5 N/A 3.03 7^88 11.1 N/A 3.03 7.89 19.0 N/A N/A 8.06 N/A N/A 3.03 7.89 2.50 100. N/A 7.93 N/A N/A Record Modified Rie Name IS s101122a.wiff s02 2a .w iff s101122a.wiff s101122a.wiff s101122a.w ifi s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff E s101122a.wiff E s101122a.wiff s101122a.wiff S10 1 122a.w iff s101122a.w iff s101122a.wiff s101122a.wiff s101122a. wiff s101122a.wiff S101122a.wiff s101122a.wiff E s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a. wiff s101122a. wiff s101122a.wiff s101122a.wiff s101122a.wiff E s101122a.wiff ts i O il 22a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1022a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff D s101122a.wiff s i 01122a wiff slO liS S aw iff s101122a.wiff E s101122a.wiff s101122a.wiff s101122a.wiff s101122a.w iff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s 1 0 1 122a.wiff s101122a.wiff Printing Time: 10:47:24 AM Printing Date: Wednesday, January 05, 2011 Page 5 of 14 3M Study G LP10-01-02 Interim R eport 05 Page 172 of 962 *Stan V1660305 Results Name: slOH22a.rdb Sample Name Sam ple ID 281 s101122a098 282 si0122a99 283 s101122a100 284 s101122a101 285 s101122a102 286 s101122a103 287 s101122a104 288 s101122a105 269 s101122a106 290 s101122a107 291 s101122a108 292 s101122a109 293 s101122a110 294 s101122a111 295 s1 0 1 1 2 2 a1 1 2 296 s101122a113 297 s101122a114 298 s101122a115 299 s101122a116 300 s101122a117 301 s101122a118 302 s101122a119 303 s101122a120 304 s101122a121 35 s101122a122 306 s101122a123 307 s101122a124 308 s 122a25 309 s101122a126 310 s101122a127 311 s101122a128 312 sio T 2 2 a 2 9 313 s101122a130 314 s101122al31 315 s101122a132 316 s101122a133 317 s101122a134 318 si01122a135 319 s101122a136 320 ~ s101122a137 321 s101122a138 322 s101122a139 323 s101122a140 324 s101122a141 325 s101122a142 326 s101122a143 327 s101122a144 328 si 22a145 329 s101122a146 330 s101122a147 331 s101122a148 332 s101122a149 333 s101122a150 334 s101122a151 335 s101122a152 336 s101122a153 GLP10-01 -02-05-058 DAL SS SS07 0 0005 GLP10-01 -02-05-058 Dup DAL SS SS07 0 0005 Duplicate GLP10-01 -02-05-058 LMS DAL S S SS07 0 0005 Lab Matrix Spike GLP10-01 -02-05-059 DAL SS SS08 0 0000 GLP10-01 -02-05-059 Dup DAL SS S S08 0 0000 Duplicate GLP10-01 -02-05-059 LMS DAL S S SS08 0 0000 Lab Matrix Spike GLP10-01 -02-05-060 DAL SS SS08 DB 0000 GLP10-01 -02-05-060 Dup DAL SS SS08 DB 0000 Dupficate GLP10-01 -02-05-060 LMS DAL S S SS08 DB 0000 Lab Matrix Spik GLP10-01-02-05-061 DAL SS SS08 0 0005 GLP10-01 -02-05-061 Dup DAL SS SS08 0 0005 Duplicate GLP10-01 -02-05-061 LMS DAL S S SS08 0 0005 Lab Matrix Spike G LP 10-01 -02-05-062 DAL SS SS09 0 0000 G LP 10-01 -02-05-062 Dup DAL SS S S09 0 0000 Duplicate GLP 10-01-2-05-062 LMS DAL S S SS09 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101116-06 5 ng Exlracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-063 DAL SS SS09 0 0005 GLP10-01 -02-05-063 Dup DAL SS SS09 0 0005 Duplicate GLP10-01 -02-05-063 LMS DAL S S SS09 0 0005 Lab Matrix Spike GLP10-01 -02-05-064 DAL SS GP01 0 0000 G LP10-01-02-05-064 Dup DAL SS GP01 0 0000 Duplicate G LP10-01-02-05-064 LMS DAL S S GP01 0 0000 Lab Matrix Spike GLP10-01 -02-05-065 DAL SS GP01 0 0005 GLP10-01 -02-05-065 Dup DAL SS GP01 0 0005 Duplicate GLP10-01 -02-05-065 LMS DAL SS GP01 0 0005 Lab Matrix Spike GLP10-01-02-05-066 DAL SS GP01 0 0020 G LP10-01-02-05-066 Dup DAL SS GP01 0 0020 Duplicate G LP10-01-02-05-066 LMS DAL SS GP01 0 0020 Lab Matrix Spike GLP10-01-02-05-067 DAL SS GP01 0 0060 GLP1CL0-02-05^067 Dup DAL SS GP1 06 Duplicate G LP10-01-02-05-067 LMS DAL SS GP01 0 0060 Lab Matrix Spike 10 006-25 solvent blank E C-101116-07 10 ng Exlracted Curve P oint 10 006-25 solvent blank GLP10-01 -02-05-068 DAL SS GP02 0 0000 G LP10-01-02-05-068 Dup DAL SS G P02 0 0000 Duplicate G LP 10-01-02-05-068 LMS DAL SS GP02 0 0000 Lab Matrix Spike GLP10-01-02-05-069 DAL SS GP02 0 0005 G LP10-01-02-05-069 Dup DAL SS GP02 0 0005 Duplicate GLP1-1-02-05^069 LMS DAL SS GP2 6 05 Lab Matrix Spike GLP10-01-02-05-070 DAL SS GP02 0 0020 G LP10-01-02-05-070 Dup DAL SS G P02 0 0020 Duplicate G LP10-01-02-05-070 LMS DAL SS GP02 0 0020 Lab Matrix Spike GLP10-01-02-05-071 DAL SS GP02 DB 0020 G LP10-01-02-05-071 Dup DAL SS G P02 DB 0020 Dupficate G LP10-01-02-05-071 LMS DAL S S GP02 DB 0020 Lab Matrix Spik GLP10-01-02-05-072 DAL SS GP02 0 0120 G LP10-01-02-05-072 Dup DAL SS G P02 0 0120 Duplicate GLP10-01-02-05-072 LMS DAL SS G P02 0 0120 Lab Matrix Spike 10 006-25 solvent blank EC-101116-05 2.5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-073 DAL SS GP03 0 0000 GLP10-01-02-05-073 Dup DAL SS G P03 0 0000 Duplicate Analyte Peak Name Sample Type Use Record Analyte Concentration (ng/m L) Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Name PFBS Unknown N/A 7.889 1418908 MPFBS PFBS Unknown N/A 7.899 1603337 MPFBS PFBS Unknown N /A 7.889 2934446 MPFBS PFBS Unknown N /A 7.889 332634 h /P F B S PFBS Unknown N /A 7.869 311559 MPFBS PFBS Unknown : N /A 7.889 1732934 MPFBS PFBS Unknown N /A 7.879 255480 MPFBS PFBS Unknown i N /A 7.699 301911 MPFBS PFBS Unknown I N /A 7.899 1706784 MPFBS PFBS Unknown j N /A 7.899 264215 MPFBS PFBS Unknown i N /A 7.889 243102 MPFBS PFBS PFBS Unknown Unknown i j N /A TUA 7.889 7.869 1770590 229037 MPFBS MPFBS PFBS Unknown l N /A 7.889 232734 MPFBS PFBS Unknown ; N /A 7.879 1753105 MPFBS PFBS Double Blank i 0.00 7.990 337 MPFBS PFBS Quality Control E 5.00 7.879 " I758074 MPFBS PFBS Double Blank jO.OO 7.980 511 MPFBS PFBS Unknown i N /A 7.889 209359 MPFBS PFBS Unknown l N/A 7.869 217690 MPFBS PFBS Unknown i N /A 7.879 204815 MPFBS PFBS Unknown | N /A 7.879 722637 MPFBS PFBS Unknown i N/A 7.889 903572 MPFBS PFBS Unknown { N /A 7.889 2291660 MPFBS PFBS Unknown { N /A 7.889 919140 MPFBS PFBS Unknown N /A 7.879 946403 MPFBS PFBS Unknown jN/A 7.879 2493419 MPFBS PFBS Unknown i N /A 7.869 641574 MPFBS PFBS Unknown N /A 7.889 685849 MPFBS PFBS Unknown N /A 7.879 2086188 MPFBS PFBS Unknown i N /A 7.899 283528 MPFBS PFBS Unknown ! N /A 7.899 312751 MPFBS PFBS Unknown : N /A 7.889 " l 1410913 MPFBS PFBS Double Blank i 0.00 8.030 542 MPFBS PFBS Quality Control E 9.99 7.899 1437112 MPFBS PFBS Double Blank i 0.00 7.879 30110 MPFBS PFBS Unknown ; N /A 7.889 267942 MPFBS PFBS Unknown | N /A 7.879 305406 MPFBS PFBS Unknown ] N /A 7.889 1700939 MPFBS PFBS Unknown I N /A 7.889 114726 MPFBS PFBS Unknown N /A 7.879 146599 MPFBS PFBS Unknown N /A 7.889 448309 MPFBS PFBS Unknown N /A 7.889 65466 MPFBS PFBS Unknown | N /A 7.889 74589 MPFBS PFBS U ik n o v m [ N /A 7.879 345679 MPFBS PFBS Unknown ! N/A 7.889 81365 MPFBS PFBS Unknown ; N/A 7.899 98596 MPFBS PFBS Unknown l N/A 7.889 377679 MPFBS PFBS Unknown j N /A 7.889 268471 MPFBS PFBS Unknown N /A 7.899 355009 MPFBS PFBS Unknown N /A 7.899 501236 MPFBS PFBS Double Blank 0.00 0.000 0 MPFBS PFBS Quality Control E 2.50 7.889 389202 MPFBS PFBS Double Blank 0.00 7.818 1263 MPFBS PFBS Unknown N/A 7.889 757995 MPFBS PFBS Unknown N/A 7.869 888403 MPFBS IS Peak Area (counts) 349062 362719 361135 347334 360437 390515 349636 380058 332391 342532 349163 350857 382701 356391 352279 48 349228 12 352632 351976 346328 353481 328863 330232 288472 326824 304845 326697 383501 325504 313640 252438 282680 61 328510 170 341902 363612 337254 354599 357836 ^1104 349145 324322 315347 314562 319575 317700 300112 277962 262537 0 337338 61 357346 354619 IS C o n cen tratim i (ng/m L) IS Retention Time (min) Calculated Concentration (ng /m L ) Accuracy <%) 3.03 7.89 9.73 N /A 3.03 7.89 10.6 N /A 3.03 7.90 19.6 N /A 3.03 7.86 2.24 N /A 3.03 7.91 2.01 N /A 3.03 7.89 10.6 N /A 3.03 7.89 1.69 N /A 3.03 7.88 1.85 N /A 3.03 7.88 12.3 N /A 3.03 7.88 1.79 N / 3.03 7.87 1.61 N /A 3.03 7.88 12.1 N /A 3.03 7.88 1.38 N /A 3.03 7.88 1.51 N /A 3.03 7.86 11.9 N /A N/A 7.92 N /A N /A 3.03 7.89 5.16 103. N /A 8.12 N /A N/A 3.03 7.88 1.36 N/A 3.03 7.89 1.42 N/A 3.03 7.89 1.36 N/A 3.03 7.90 4.85 N/A 3.03 7.88 6 55 N/A 3.03 7.89 16.7 N/A 3.03 7.88 7.61 N /A 3.03 7.87 6.91 N/A 3.03 7.88 19.7 N/A 3.03 7.88 4.66 N /A 3.03 7.87 4.24 N/A 3.03 7.87 15.4 N/A 3.03 7.89 2.11 N/A 3.03 7.89 2.91 N/A 3.03 7.88 12.0 N/A N/A 8.05 N/A N/A 3.03 7.89 10.5 105. N/A 8.08 N/A N/A 3.03 7.88 1.82 N/A 3.03 7.90 1.96 N/A 3.03 7.91 12 1 N/A 3.03 7.89 0.715 N/A 3.03 7.89 0.922 N/A 3.03 7.90 2.92 N/A 3.03 7.89 6.389 N/A 3.03 7.91 0.491 N/A 3.03 7.89 2.57 N /A 3.03 7.90 0.560 N /A 3.03 7.88 0.679 N /A 3.03 7.91 2.79 N /A 3.03 7.89 2.09 N /A 3.03 7.89 3.01 N /A 3.03 7.89 4.53 N /A N/A 0.00 N /A N /A 3.03 7.89 2.71 108. N/A 7.91 N /A N/A 3.03 7.89 5.04 N/A 3.03 7.90 5.96 N/A Record Modified File Name s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff 8101122a.wiff s101122a.wiff s lO I 122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s lO II^ 'a w iff e s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a w iff sd2 2a .w iff s101122a.w iff s101122a.wiff s101122a.w iff s101122a.w iff s101122a.wiff s101122a.w iff S10 1 122a.w iff s101122a.wiff s101122a.w iff s101122a.w iff s101122a.wiff s101122a.wiff s101122a.w iff s110011 11 2222aa..wwiiffff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff IS s101122a.wiff s101122a.wiff 8101122a.w iff s101122a.w iff Printing Time 10:47:25 AM Printing Date Wednesday January 05 2011 Page 6 of 14 3M Study GLP10-01-02 Interim Report 05 Page 173 of 962 Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample IO 337 s101122a154 338 s 0 i2 2 a 5 5 339 s101122a156 340 s01122a157 341 s1 01 12 2 al58 342 s101122a159 343 s101122a160 344 s101122a161 345 s101122a162 346 s101122a163 347 s101122a164 348 s101122a165 349 s101122a166 350 s101122a167 351 s101122a168 352 s101122a169 353 s101122a170 354 s101122a171 355 s101122a172 356 s101122a173 357 s101122a174 358 s101122a175 359 s101122a176 360 s101122a177 361 s101122a178 362 s101122a179 363 s101122a180 364 s101122a181 365 s101122a182 366 s101122a183 367 s101122a001 368 s101122a002 369 siri 22a003 370 s101122a004 371 s101122a005 372 s101122a006 373 s101122a007 374 s101122a008 375 s101122a009 376 s101122a010 377 s101122a011 378 s101122a012 379 s101122a013 380 s101122a014 381 s101122a015 382 s101122a016 383 s101122a017 384 s1 0 1 1 2 2 a0 1 8 385 s101122a019 386 s101122a020 387 s101122a021 388 s101122a022 389 s101122a023 390 s101122a024 391 s101122a025 392 s1 0 1 1 2 2 a0 2 6 GLP10-01-02-05-073 LMS DAL SS GP03 0 0000 Lab Matrix Spike GLP16^01-02-05-674 DAL SS GP03 6 0006 GLP10-01-02-05-074 Dup DAL SS GP03 0 0005 Duplicate GLP10-01-02-05-074 LMS DAL SS GP03 0 0005 Lab Matrix Spike GLP10-01-02-05-075 DAL SS GP03 0 0020 GLP10-01-02-05-075 Dup DAL SS GP03 0 0020 Duplicate G LP10-01 -02-05-075 LMS DAL SS G P03 0 0020 Lab M atrix Spike GLP10-01-02-05-076 DAL SS GP03 DB 0020 GLP10-01-02-05-076 Dup DAL SS GP03 DB 0020 Duplicate G LP10-01 -02-05-076 LMS D A L SS GP03 DB 0020 Lab M atrix Spik GLP10-01-02-05-077 DAL SS GP03 0 0050 GLP10-01-02-05-077 Dup DAL SS GP03 0 0050 Duplicate GLP10-01-02-05-077 LMS DAL SS GP03 0 0050 Lab Matrix Spike 10 0 06 -2 5 solvent blank EC-101116-06 5 ng Extracted C u n Point 10 0 06 -2 5 solvent blank GLP10-01-02-05-078 DAL SS GP04 0 0000 GLP10-01-02-05-078 Dup DAL SS GP04 0 0000 Duplicate GLP10-01-02-05-078 LMS DAL SS GP04 0 0000 Lab Matrix Spike GLP10-01-02-05-079 DAL SS GP04 0 0005 GLP10-01-02-05-079 Dup DAL SS GP04 0 0005 Duplicate GLP10-01-02-05-079 LMS DAL SS GP04 0 0005 Lab Matrix Spike GLP10-01-02-05-080 DAL SS GP04 0 0020 GLP10-01 -02-05-080 Dup DAL SS GP04 0 0020 Duplicate GLP10-01 -02-05-080 LMS DAL SS GP04 0 0020 Lab Matrix Spike M B -101116-07 Method Blank 5g w f IS fo r Dilutions M B -101116-08 Method Blank 5g vtf IS fo r Dilutions 10 0 06 -2 5 solvent blank EC-101116-07 10 ng Extracted C u n Point 10 0 06 -2 5 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank EC-101116-09 50 ng W arm up standard E C -101116-09 50 ng W a rm up standard 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 0 06 -2 5 solvent blank EC-101116-01 0.2 ng Extracted Curve Point EC-101116-02 0.5 ng Extracted Curve Point EC-101116-03 0.75 ng Extracted Curve Point EC-101116-04 1 ng Extracted C u n Point EC-101116-05 2.5 ng Ertracted Curve Point EC-101116-06 5 ng Extracted Curve Point EC-101116-07 10 ng Extracted Curve Point EC-101116-08 25 ng Ertracted Curve Point EC-101116-09 50 ng Extracted Curve Point EC-101116-10 100 ng Extracted C u n Point EC-101116-11 200 ng Extracted Curve Point EC-101116-12 500 ng Extracted Curve Point 10 0 06 -2 5 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank M B -101116-01 Method Blank 1 W o IS Analyte Peak Name Sample Type PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Qualify Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown T jn k n o w n Unknown Unknown Unknown Unknown Double Blank Qualify Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank S ta n d a rd S ta n d a rd Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Use Record Analyte Concentration (ng /m L ) Analyte Retention Time (min) Analyte Peak Area (counts) N /A 7.889 2 3 7 1 4 5 0 N/A 7.889 5046257 N /A 7.899 42660 N/A 7.869 11923849 N /A 7.889 6597098 N /A 7.869 7100566 N /A 7.899 13424653 N /A 7.889 12480742 N /A 7.889 8991539 N /A 7.889 16484925 N /A 7.889 1640913 N /A 7.899 1645603 N /A 7.879 8390035 0.00 7.949 1538 E 5.00 7.889 786455 0.00 7.808 2179 N /A 7.899 857362 N /A 7.889 679652 N /A 7.899 2471542 N /A 7.869 354768 N /A 7.889 375241 N /A 7.899 1915427 N /A 7.899 265377 N /A 7.879 314630 N /A 7.889 1839703 N /A 7.879 22837 N /A 0.00 7.879 8.191 22682 557 E 9.99 0.00 0.00 7.889 8.101 10.744 1511763 468 326 0.00 0.00 10.713 10.481 119 4711054 0.00 10.481 4867839 0.00 10.471 595 0.00 10.592 455 0.00 10.552 164 0.00 10.451 203 0.00 10.633 334 E 0.200 10.411 22534 ^ E 0.500 10.421 49571 E 0.750 10.421 70254 E 1.00 10.411 100939 E 2.50 10.411 251412 E 5.00 10.421 507096 E 10.0 10.421 953668 E 25.0 10.411 2424109 E ' 50.0 10.391 5030386 100. 10.401 9895932 E 200. 10.401 18451316 E 500. 10.391 40344124 0.00 10.451 7458 0.00 10.401 1437 .00 10.643 140 0.00 10.623 228 0.00 10.441 1020 IS Peak Name MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS hM P F B S MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFHS MPFHS MPFHS MPFHS MPFHS ^MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS IS Peak Area (counts) 347617 352849 354427 335942 303120 315388 322695 309870 310448 299288 337742 345391 323076 109 349269 169 368189 366056 349370 356401 342561 344629 372537 361711 331732 326650 358656 12 345249 24 34 58 161681 156532 46 70 10 0 0 157925 160584 152955 15565 163274 158272 159869 165759 162378 156561 166002 148312 34 0 0 70 10 IS C o n c e n tra tio n (ng /m L ) IS Retention Urne (min) Calculated Concentration (ng /m L ) Accuracy <%) Record Modified File Name 3.03 3.03 7.89 7.88 16.4 V .7 N/A s101122a.wiff N/A s101122a.wiff 3.03 7.89 28.7 N/A 8101122a.wiff 3.03 7.88 88.0 N/A s101122a.wiff 3.03 7.87 53.2 N /A s101122a.wiff 3.03 7.90 55.1 N /A s101122a.wiff 3.03 7.89 104. N /A s101122a.wiff 3.03 7.90 "lOO. N /A s101122a.wiff 3.03 7.90 71.3 N /A S101122a.w iff 3.03 7.89 139. N / s101122a.wiff 3.03 7.89 11.6 N /A s101122a.wiff 3.03 7.90 11.4 N /A s101122a.wiff 3.03 7.88 63.8 N /A E s101122a.w iff N /A 7.88 N /A N /A S101122a.w iff 3.03 7.90 5.35 107. s101122a.w iff N /A 7.83 N /A N/A s101122a.w iff 3.03 7.88 5.54 N /A s101122a.wiff 3.03 7.90 4.40 N /A s101122a.wiff 3.03 7.88 17.0 N /A s101122a. wiff 3.03 7.88 2 33 N /A s101122a.w iff 3.03 7.89 2.57 N /A s101122a. wiff 3.03 7.87 13.3 N /A s101122a.w iff 3.03 7.88 1.65 1N /A E s101122a.w iff 3.03 7.89 2.03 N /A s101122a.wiff 3.03 7.87 13.3 N /A E s101122a.wiff 3.03 7.90 0.106 N /A s101122a.wiff 3.03 7.88 0.0905 N /A s101122a.wiff N /A 7.94 N/A N /A s101122a.wiff 3.03 N /A 7.89 7.99 10.5 N /A 105. N/A T s101122a.wiff s10t 122a.wiff N /A 10.4 N /A N /A s101122a.wiff N /A 10.4 N/A N /A s101122a w iff N /A 10.5 N/A N/A s 1 2 2 a .w iff N /A 10.5 N /A N/A s101122a.wiff N /A 10.6 N /A N /A s101122a.wiff N /A 10.5 N /A N /A 8101122a.wiff N /A 10.5 N /A N /A s101122a.wiff N /A 0.00 N /A N /A s101 122a.wiff N /A 0.00 N/A N/A s101122a.wiff 3.00 10.4 0.202 101. S101122a.w iff 3.00 10.4 0.475 95.0 s101122a.w iff 3.00 10.4 0.722 96.3 s101122a.wiff 3.00 10.4 1.04 104. s10 1 122a.w iff 3.00 10.4 2.50 99.9 s101122a.w iff 3.00 10.4 5.23 105. s101122a.wiff 3.00 10.4 9.78 97.8 s101122a.wiff 3.00 10.4 24.1 96.4 s101122a.wiff 3.00 10.4 51.4 103. s101122a.wiff 3.00 10.4 106. 106. s101122a.wiff 3.00 10.4 191. 95.3 s101122a.wiff 3.00 10.4 503. 101. s101122a.w iff N /A 10.6 N /A N /A s101122a.wiff N /A 0.00 N /A N /A S101122a.wiff N /A 0.00 N /A N /A s101122a.w iff N /A 10.7 N /A N /A s101122a.wiff N /A 10.5 N /A N /A s101122a.w iff Printing Time: 10:47:25 AM Printing Date: Wednesday, January 05, 2011 Page 7 of 14 3M Study G LP10-01-02 Interim R eport 05 Page 174 of 962 *Stan V1660305 Results Name: sl01122a.rdb Sample Name Sam ple 10 393 s101122a027 394 s101122a028 395 s101122a029 396 s 01122a030 397 s101122a031 398 1s101122a032 399 s101122a033 400 s101122a034 401 s101122a035 402 s101122a36 403 s101122a037 404 s101122a038 405 s101122a039 406 s101122a040 47 s101122a041 408 s101122a042 409 s101122a043 410 s101122a044 411 s101122a045 412 s101122a046 413 s101122a047 414 s101122a048 415 s101122a049 416 s101122a050 417 s101122a051 418 s101122a052 419 s101122a053 420 s101122a054 421 s101122a055 422~ s101122a056 423 s101122a057 424 s101122a058 425 s101122a059 426 s101122a060 427 s101122a061 428 s101122a062 429 s101122a063 430 s101122a064 431 s101122a065 432 s101122a066 433 s i O'i 122a67 434 s101122a068 435 s101122a069 436 s101122a070 437 s101122a071 438 s101122a072 439 s101122a073 440 s101122a074 441 s101122a075 442 s101122a076 443 s101122a077 444 s101122a078 445 s101122a079 446 s101122a080 447 s101122a081 448 s101122a082 M B -101116-02 Method Blank 2 wrfo IS M B-101116-03 Method S la n k 3 v * o IS MB-101116-04 Method Blank 4 W IS M6-101116-05 Msthod Blank 5 W IS M B-101116-06 Method Blank 6 W IS LCS-101116-01 3 ng LCS inTCR-842 LCS-101116-02 3 ng LCS InTCR-842 LCS-101116-03 3 ng LCS inTCR-842 LCS-101116-04 30 ng LCS in TCR-842 LC S -101116-05 30 ng LCS in TCR-842 LC S -101116-06 30 ng LCS in TCR-842 GLP10-01-02-05-041 DAL SS SS01 0 0000 GLP10-01-02-05-041 Dup DAL SS SS01 0 0000 Duplicate GLP10-01-02-05-041 LMS DAL SS SS01 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101116-05 2.5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-042 DAL SS SS01 0 0005 GLP10-01-02-05-042 Dup DAL SS SS01 0 0005 Duplicate GLP10-01-02-05-042 LMS DAL SS SS01 0 0005 Lab Matrix Spike GLP10-01-02-05-043 DAL SS SS02 0 0000 GLP10-01-02-05-043 Dup DAL SS SS02 0 0000 Duplicate GLP10-01-02-05-043 LMS DAL SS SS02 0 0000 Lab Matrix Spike GLP10-01-02-05-044 DAL SS SS02 0 0005 GLP10-01-02-05-044 Dup DAL SS SS02 0 0005 Duplicate GLP10-01 -02-05-044 LMS DAL SS SS02 0 0005 Lab M atrix Spike GLP10-01-02-05-045 DAL SS SS03 0 0000 GLP10-01 -02-05-045 Dup D A L S S SS03 0 0000 Duplicate GLP10-01-02-05-045 LMS DAL SS SS03 0 0000 Lab Matrix Spike GLP10-01-02-05-046 DAL SS SS03 0 0005 GLP10-01 -02-05-046 Dup D A L S S SS03 0 0005 Duplicate GLP10-01-02-05-046 LMS DAL SS SS03 0 0005 Lab Matrix Spike 10 006-25 solvent blank EC-101116-06 5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-047 DAL SS SS03 DB 0005 G LP10-01-02-05-047 Dup DAL SS SS03 DB 0005 DupBcate GLP10-01-02-05-047 LMS DAL SS SS03 DB 0005 Lab Matrix Spik GLP10-01-02-05-048 DAL SS SS04 0 0000 GLP10-01 -02-05-048 Dup DAL SS SS04 0 0000 Duplicate GLP10-01 -02-05-048 LMS DAL SS SS04 0 0000 Lab M atrix Spike GLP10-01-02-05-049 DAL SS SS04 0 0005 GLP10-01 -02-05-049 Dup DAL SS SS04 0 0005 Duplicate GLP10-01 -02-05-049 LMS D A L S S SS04 0 0005 Lab M atrix Spike GLP10-01-02-05-050 DAL SS TRIP1 0 0000 GLP10-01-02-05-050 Dup DAL SS TRIP1 0 0000 Duplicate GLP10-01-02-05-050 LMS DAL SS TRIP1 0 0000 Lab Matrix Spike GLP10-01-02-05-051 DAL SS SS05 0 0000 GLP10-01-02-05-051 Dup DAL SS SS05 0 0000 Duplicate GLP10-01 -02-05-051 LMS D A L SS SS05 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101116-07 10 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-052 DAL SS SS05 0 0005 GLP10-01-02-05-052 Dup DAL SS SS05 0 0005 Duplicate GLP10-01 -02-05-052 LMS DAL SS SS05 0 0005 Lab M atrix Spike Analyte Peak Name Sample Type Use Record Analyte Concentration (ng/m L) Analyte Retention Time (min) Analyte Peak Area (counts) PFHS Double Blank | 0.00 10.481 520 PFHS Double Blank 0.00 10.451 274 PFHS Unknown N/A 10.380 1329 PFHS Unknown ! N /A 10.542 2602 PFHS Unknown I N/A 10.441 1427 PFHS Unknown i N/A 10.405 353679 PFHS Unknown | N /A 10.391 342635 PFHS Unknown | N /A 10.392 342199 PFHS Unknown ! N /A 10.399 3309729 PFHS Unknown N /A 10.402 3447642 PFHS Unknown N /A 10.385 3537859 PFHS Unknown N /A 10.397 513221 PFHS Unknown ; N /A 10.397 514123 PFHS Unknown N /A 10.409 1673989 PFHS Double Blank i 0.00 10.532 1100 PFHS Quality Control E 2.50 10.381 264241 PFHS Double Blank ; 0.00 10.683 74 PFHS Unknown j N /A 10.396 988301 PFHS Unknown i N /A 10.394 792589 PFHS Unknown j N /A 10.397 1750083 PFHS Unknown ! N /A 10.398 991708 PFHS Unknown i N /A 10.395 681660 PFHS Unknown i N /A 0.394 2021395 PFHS Unknown i N /A 10.388 7039459 PFHS Unknown j N /A 10.394 5696416 PFHS Unknown { N /A 10.389 15102695 PFHS Unknown j N /A 10.388 23371276 PFHS Unknown j N /A 10.390 23276597 PFHS Unknown N /A 10.382 55771336 PFHS Unknown N /A 10.388 18416299 PFHS Unknown N /A 10.395 20474898 PFHS Unknown N /A 10.400 49880575 PFHS Double Blank 0.00 10.421 14220 PFHS Quality Control E 5.00 10.401 543431 PFHS Double Blank 0.00 10.512 1800 PFHS Unknown N /A 10.399 19444025 PFHS Unknown N /A 10.397 14249354 PFHS Unknown N /A 10.385 47163997 PFHS Unknown N /A 10.398 1518353 PFHS Unknown N /A 10.394 439358 PFHS Unknown N /A 10.389 1645415 PFHS Unknown N /A 10.383 225151 PFHS Unknown N /A 10.394 222388 PFHS Unknown j N /A 10.394 1310805 PFHS Unknown | N /A 10.461 1918 PFHS Unknown j N /A 10.380 3660 PFHS Unknown i N /A 10.391 231909 PFHS Unknown N /A 10.374 26706584 PFHS Unknown N /A 10.393 21822173 PFHS Unknown N /A 10.386 54842442 PFHS Double Blank 0.00 10.481 13072 PFHS Quality Control E 10.0 10.391 1027574 PFHS Double Blank 0.00 10.481 896 PFHS Unknown N /A 10.393 6242771 PFHS Unknown N /A 10.383 6405185 PFHS Unknown N /A 10.394 15904823 IS Peak Name MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS IS Peak Area (counts) 34 22 174159 151541 159778 170429 178112 167130 170338 181748 168607 174654 162581 161496 22 183764 0 160019 170345 164545 178544 62151 168167 149796 161099 159142 165615 169402 133966 155453 159823 150675 38 165190 34 179585 171458 142091 185496 175124 177980 174478 181434 169965 195385 172226 187251 165250 161836 140148 0 162094 0 167886 172695 156582 IS C o n c e n tra tio n (ng /m L ) IS Retention Time (m in ) Calculated C o n c e n tra tio n (ng/mL) Accuracy (% ) N /A 10.5 N /A N/A N /A 10.5 N/A N/A 3.00 10.4 <0 N/A 3.00 10.4 <0 N /A 3.00 10.4 <0 N /A 3.00 10.4 3.38 N /A 3.00 10.4 3.13 N /A 3.00 10.4 3.33 N /A 3.00 10.4 32.1 N /A 3.00 10.4 31.3 N /A 3.00 10.4 34.7 N /A 3.00 10.4 4.80 N /A 3.00 10.4 5.17 N /A 3.00 10.4 17.1 N /A N /A 10.7 N /A N /A 3 .0 0 110.4 2.33 93.2 N /A 0.00 N/A N/A 3.00 10.4 10.1 N/A 3.00 10.4 7.62 N/A 3.00 10.4 17.5 N /A 3.00 10.4 9.11 N /A 3.00 10.4 6.88 N /A 3.00 10.4 19.8 N /A 3.00 10.4 78.5 N /A 3.00 10.4 58.8 N /A 3.00 10.4 162. N /A 3.00 10.4 245. N /A 3.00 10.4 238. N /A 3.00 10.4 841. N /A 3.00 10.4 204. N /A 3.00 10.4 221. N /A 3.00 10.4 632. N /A N /A . 10.5 N /A N /A 3.00 10.4 5.38 108. N /A 10.6 N/A N/A 3.00 10.4 185. N/A 3.00 10.4 141. N/A 3.00 10.4 634. N/A 3.00 10.4 13.4 N/A 3.00 10.4 4.09 N/A 3.00 10.4 15.2 N /A 3.00 10.4 2.09 N /A 3.00 10.4 1.98 N /A 3.00 10.4 12.7 N /A 3.00 10.4 <0 N /A 3.00 10,4 0.0034 N /A 3.00 10.4 2.00 N /A 3.00 10.4 283. N /A 3.00 10.4 233. N /A 3.00 10.4 777. N /A N /A 0.00 N /A N /A 3.00 10.4 10.4 104. N /A 0.00 N /A N /A 3.00 10.4 61.9 N /A 3.00 ` 10.4 61.7 N /A 3.00 10.4 173. N /A Record M o d ifie d Rie Name D s101122a.w iff s101122a.wiff s101122a.wiff E s101122a.wiff s101122a.wiff E s1 0 1 1 2 2 a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.w iff E s101122a.w iff E s101122a.w iff E s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff E S101122a.w iff E s101122a.wiff E s101122a.wiff E s101122a.w iff E s101122a.w iff E s101122a.w iff E s101122a.w iff E s101122a.wiff E S101122a.w iff s101122a.w iff s101122a.w iff s101122a.w iff E s101122a.wiff E s1 0 1 1 2 2 a.wiff E s101122a.wiff s101122a.wiff s101122a.w iff s101122a.wiff E s101122a.w iff E s101122a.wiff E s101122a.w iff Printing Time: 10:47:26 AM Printing Date: Wednesday, January 05, 2011 Page 8 of 14 3M Study GLP10-01-02 Interim Report 05 Page 175 of 962 *Stan V1660305 Results Name: sl01122a.rdb Sample Name Sam ple ID 449 s101122a083 450 s101122a084 451 S ld l1 2 2 a 0 8 5 452 s10122a86 4531 s101122a087 454 s101122a088 455 s101122a089 456 s11122a9 457 s101122a091 456 s101122a092 459 s101122a093 460 s101122a094 461 s101122a095 462 s101122a096 463 s101122a097 464 s101122a098 465 s101122a099 466 s 1 0 1 1 2 2 a 1 0 0 467 s101122a101 468 s101122a102 469 s101122a103 470 s101122a104 471 s101122a105 472 s101122a106 473 s101122a107 474 s101122a108 475 s101122a109 476 s101122a110 477 s101122a111 478 s101122a112 479 s101122a113 480 s101122a114 481 s101122a115 482 s101122a116 483 s101122a117 484 s101122a118 485 s101122a119 486 s101122a120 487 s101122a121 488 s101122a122 489 s101122a123 490 s101122a124 491 s101122a125 492 s101122a126 493 s101122a127 494 s101122a128 495 s101122a129 496 s101122a130 497 s101122a131 498 s101122a132 499 s101122a133 500 s101122a134 501 s101122a135 502 s101122a136 503 s101122a137 504 s101122a138 GLP10-01-02-05-054 DAL SS SS06 0 0000 G LP I 11-02-05^054 Dup DAL SS SS6 0 0000 Duplicate GLP10-01-02-05-054 LMS DAL S S SS06 0 0000 Lab Matrix Spike G L P I-1-02-05-055 DAL SS SS6 0005 GLP10-01-02-05-055 Dup DAL SS SS06 0 0005 Duplicate GLP10-01-02-05-055 LMS DAL S S SS06 0 0005 Lab Matrix Spike GLP10-01-02-05-056 DAL SS SS06 DB 0005 GLP10-01 -02-05-056 Dup DAL SS SS6 DB 005 D uplcate G L P I0-01 -2-5-56 LMS DAL SS SS6 DB 0005 Lab Matrix Spik GLP10-01-02-05-057 D A l SS SS07 0 0000 GLP10-01-02-05-057 Dup DAL SS SS07 0 0000 Duplicate GLP10-01-02-05-057 LMS D A L SS SS07 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101116-05 2.5 ng E x a c te d C ur\ Point 10 006-25 s o te n t blank GLP10-01-02-05-058 DAL SS SS07 0 0005 GLP10-01-02-05-058 Dup DAL SS SS07 0 0005 Duplicate G LP10-01-02-05-053 LMS DAL SS S S 0 7 0 0005 Lab Matrix Spike GLP10-01-02-05-059 DAL SS SS08 0 0000 GLP10-01 -02-05-059 Dup DAL SS SS08 0 0000 Duplicate GLP10-01 -02-05-059 LMS DAL SS SS08 0 0000 Lab Matrix Spike GLP10-01 -02-05-060 DAL SS SS08 DB 0000 GLP10-01-02-05-060 Dup DAL SS SS08 DB 0000 DupBcate GLP10-01 -02-05-060 LMS DAL S S SS08 DB 0000 Lab Matrix Spik GLP10-01-02-05-061 DAL SS SS08 0 0005 GLP10-01 -02-05-061 Dup DAL SS SS08 0 0005 Duplicate GLP10-01-02-05-061 LMS DAL S S SS08 0 0005 Lab Matrix Spike GLP10-01-02-05-062 DAL SS SS09 0 0000 GLP10-01-02-05-062 Dup DAL SS SS09 0 0000 Duplicate G LP10-01-02-05-062 LMS DAL SS SS09 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101116-06 5 ng Extracted C u n Point . 10 006-25 solvent blank GLP10-01-02-05-063 DAL SS SS09 0 0005 GLP10-01 -02-05-063 Dup D A L SS SS09 0005 Duplicate GLP10-01 -02-05-063 LMS DAL SS SS09 0 0005 Lab Matrix Spike GLP10-01-02-05-064 DAL S S GP01 0 0000 GLP1 CK>1-02-05^064 Dup DAL SS GP1 0000 Duplicate GLP10-01 -02-05-064 LMS DAL SS GP01 0 0000 Lab Matrix Spike GLP10-01 -02-05-065 DAL SS GP01 0 0005 GLP10-01 -02-05-065 Dup DAL SS GP01 0 0005 Duplicate GLP10-01 -02-05-065 LMS DAL SS GP01 0 0005 Lab Matrix Spike GLP10-01-02-05-066 DAL SS GP01 0 0020 GLP10-01-02-05-066 Dup DAL SS GP01 0 0020 Duplicate GLP10-01-02-05-066 LMS DAL SS GP01 0 0020 Lab Matrix Spike GLP10-01-02-05-067 DAL SS GP01 0 0060 GLP10-01-02-05-067 Dup DAL SS GP01 0 0060 Duplicate G LP10-01-02-05-067 LMS D A L SS GP01 0 0060 Lab Matrix Spike 10 006-25 solvent blank EC-101116-07 10 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-068 DAL SS GP02 0 0000 GLP10-01 -02-05-068 Dup DAL SS GP02 0 0000 Duplicate GLP10-01-02-05-068 LMS DAL SS GP02 0 0000 Lab Matrix Spike GLP10-01-02-05-069 DAL SS GP02 0 0005 GLP10-01 -02-05-069 Dup DAL SS GP02 0 0005 Duplicate Analyte Peak Name Sample Type PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Use Record Analyte Concentration (ng/mL.) Analyte Retention Time (min) Analyte Peak Area (counts) N/A 10.385 275178 i N/A 10.385 298964 I N/A 10.399 1407318 N/A 10.396 104403 N /A 10.395 136935 N /A 10.401 329475 N /A 10.377 149141 ! N/ 10.406 114123 N /A 10.384 329711 N/A 10.393 6046858 N/A 10.395 5911696 N/A 10.397 14976349 0.00 10.532 3113 E 2.50 10.391 280389 .00 1.421 1189 N/A 10.394 8402420 N/A 10.378 7566657 N /A 10.385 16968510 N /A 10.392 575085 N /A 10.400 672290 N /A 10.407 1668198 N /A 10.368 512364 N /A 10.387 573954 N /A 10.388 1577621 N /A 10.388 206313 IN /A 10.380 188708 i N/A 10.381 1217004 N/A 10.376 679412 N /A 10.389 728199 [N /A 10.380 1741341 is 0.00 5.00 10.431 10.391 484 553365 0.00 10.623 225 N/A 10.397 502093 N/A 10.374 525148 N /A 10.385 1572979 N/A 10.393 579590 N/A 10.387 691433 N/A 10.387 1654346 N/A 10.405 741136 N/A 10.397 1022457 N /A 10.391 2408221 N /A 10.386 1247032 N /A 10.393 1380803 N/A 10.384 2253199 N/A 10.394 289732 N/A 10.395 335427 N/A 10.407 1123884 0.0 1.370 492 e 10.0 10.411 1000727 0.00 10.471 176 N/A 10.402 26728 N /A 10.382 31271 ! N/A 10.401 220472 N/A 10.387 13646 N/A 10.412 16379 IS Peak Name MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS M PFH S MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS IS Peak Area (counts) 169909 169400 178537 170752 190622 178854 176878 171849 169958 179921 176214 175727 10 167822 10 179396 182017 178127 169512 165812 185498 173713 180921 166470 175399 178727 162003 175347 171196 166159 0 177276 22 181273 170007 177215 174765 173732 157296 155124 158424 156622 163817 179124 168457 148199 129841 . 142351 264 165735 0 166324 183137 169321 185044 174343 IS C o n c e n tra tio n (n g /m L ) 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.0 3.00 3. bo 3.00 3.00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/ 3.00 N/A ' 3.00 3.00 3.00 3.00 3. IS Retention Time (min) Calculated Concentration (ng /m L ) Accuracy (% ) Record Modified 10.4 2.63 N/A E 10.4 2.87 N/A E 10.4 12.9 N/A E 10.4 0.972 N/A E 10.4 1.15 N/A E 10.4 2.99 N/A E 10.4 1.35 N/A E 10.4 1.06 N /A 10.4 3.16 N /A E 10.4 55.8 N /A E 10.4 55.7 N/A E 10.4 145. N/A E 10.6 N/A N/A 10.4 2.71 109. 10.6 N/A N/A 10.4 78.2 N/A E 10.4 69.3 N/A E 10.4 162. N/A E 10.4 5.55 N /A E 10.4 6.63 N /A E 10.4 114.8 N /A E 10.4 4.82 N /A E 10.4 ^ 5.18 N/A E 10.4 15.6 N/A E 10.4 1.90 N/A E 10.4 1.70 N/A E 10.4 12.3 N/A E 10.4 6.34 N/A E 10.4 6.96 N/A E 10.4 17.2 N/A | E 0.00 10.4 N/A 5.10 N/A 102. r 10.4 N/A N/A 10.4 4.52 N/A E 10.4 5.05 N/A E 10.4 14.6 N/A E 10.4 5.42 N/A E 10.4 6.51 N /A E 10.4 17.3 N/A E 10.4 7.83 N/A E 10.4 10.6 N/A E 10.4 25.4 N/A E 10.4 12.5 N/A E 10.4 12.7 N/A E 10.4 22.0 N/A E 10.4 3.18 N/A E 10.4 4.21 N/A E 10.4 13.0 N/A E 10.6 N/A N/A 10.4 9.90 99.0 0.00 N/A N/A 10.4 0.232 N /A E 10.4 0.249 N /A E 10.4 2.11 N /A 10.4 0.0892 N/A E 10.4 0.122 N/A E File Name s101122a.wiff s101122a.wiff s1 0 1 1 2 2 a.wiff s ib V 2 2 a.wff s1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.w itf s101122a.wiff s1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s 1 1 2 2 a .w iff s101122a.wiff s101122a.wiff s101122a.wfff s101122a,wiff s101122a.wiff s 1 0 1 1 2 2 a.wiff s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wlff s101122a.wiff s l0 l l 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s1 0 1 2 2 a .w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wlff s 1 0 1 2 2 a .w iff s101122a.wiff s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff Printing Time: 10:47:26 AM Printing Date: Wednesday, January 05, 2011 Page 9 of 14 3M Study GLP10-01-02 Interim Report 05 Page 176 of 962 Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample ID 505 s101122a139 GLP10-01-02-05-069 LMS DAL SS GP02 0 0005 Lab Matrix Spike 506 s101122a140 GLP10-01 -02-05-070 DAL SS GP02 0 0020 507 s101122a141 GLP10-01-02-05-070 Dup DAL SS GP02 0 0020 Duplicate 508 s101122a142 GLP10-01-02-05-070 LMS DAL SS GP02 0 0020 Lab Matrix Spike 509 s101122a143 GLP10-01-02-05-071 DAL SS GP02 DB 0020 510 s101122a144 GLP10-01 -02-05-071 Dup DAL SS GP02 DB 0020 Dupficate 511 s 0 1 2 2 a 1 4 5 GLP10-01-02-05-071 LMS DAL S S GP02 DB 0020 Lab Matrix Spik 512 s101122a146 GLP10-01-02-05-072 DAL SS GP02 0 0120 513 s101122a147 GLP10-01-02-05-072 Dup DAL SS GP02 0 0120 Duplicate 514 s101122a148 GLP10-01-02-05-072 LMS DAL SS GP02 0 0120 Lab Matrix Spike 515 s101122a149 10 006-25 solvent blank 516 s101122a150 EC-101116-05 2.5 ng Extracted Curv Point 517 s101122a151 10 006-25 solvent blank 518 s101122a152 GLP10-01-02-05-073 DAL SS GP03 0 0000 519 s101122a153 GLP10-01-02-05-073 Dup DAL SS GP03 0 0000 Duplicate 520 s101122a154 GLP10-01 -02-05-073 LMS DAL SS GP03 0 0000 Lab M atrix Spike 521 s101122a155 GLP10-01-02-05-074 DAL SS GP03 0 0005 522 s101122a156 GLP10-01-02-05-074 Dup DAL SS GP03 0 0005 D u p lic a te 523 s101122a157 GLP10-01 -02-05-074 LMS DAL SS GP03 0 0005 Lab M atrix Spike 524 s101122a158 GLP10-01 -02-05-075 DAL SS GP03 0 0020 525 s101122a159 GLP10-01 -02-05-075 Dup DAL SS GP03 0 0020 Duplicate 526 sV l22a60 GLP10-01-02-05-075 LMS DAL SS GP03 0 0020 Lab Matrix Spike 527 s b l2 2 a 1 6 GLP10-01-02-05-076 DAL SS GP03 DB 0020 528 s101122a162 GLP10-01-02-05-076 Dup DAL SS GP03 DB 0020 Duplicate 529 S101122a163 GLP10-01-02-05-076 LMS DAL SS GP03 DB 0020 Lab Matrix Spik 530 s101122a164 GLP10-01-02-05-077 DAL SS GP03 0 0050 531 s101122a165 GLP10-01-02-05-077 Dup DAL SS GP03 0 0050 Duplicate 532 S101122a166 GLP10-01-02-054377 LMS DAL SS GP03 0 0050 Lab Matrix Spike 533 s101122a167 10 006-25 solvent blank 534 s1 0 1 1 2 2 a 1 6 8 E C-101116-06 5 ng Extracted Curve Point 535 s101122a169 10 006-25 solvent blank 536 s101122a170 GLP10-01-02-05-078 DAL SS GP04 0 0000 537 s101122a171 GLP10-01-02-05-078 Dup DAL SS GP04 0 0000 Duplicate 538" 1s101122a172 GLP10-01 -02-05-078 LMS DAL SS G P04 0 0000 Lab M atrix Spike 539 s101122a173 GLP10-01-02-05-079 DAL SS GP04 0 0005 540 s101122a174 GLP10-01-02-05-079 Dup DAL SS GP04 0 0005 Dupficate 541 s101122a175 GLP10-01 -02-05-079 LMS DAL SS GP04 0 0005 Lab Matrix Spike 542 s101122a176 GLP10-01 -02-05-080 DAL SS GP04 0 0020 543 s101122a177 GLP10-01 -02-05-080 Dup DAL SS GP04 0 0020 Duplicate 544 s101122a178 GLP10-01 -02-05-080 LMS DAL SS GP04 0 0020 Lab M atrix Spike 545 s101122a179 MB-101116-07 Method Blank 5g w i IS fo r Dilutions 546 s101122a18 1M B -101116-08 Method Blank 5g wf IS fo r Dilutions 547 s101122a181 10 006-25 solvent blank 548 s101122a182 EC-101116-07 10 ng E x a c te d Curve Point 549 s101122a183 10 006-25 solvent blank 550 s1 0 1 1 2 2 a0 0 1 10 0 06-25 solvent blank 551 s101122a002 10 006-25 s o te n t blank 552 s101122a003 EC-101116-09 50 ng W arm up standard 553 s101122a004 EC-101116-09 50 ng W arm up standard 554 s101122a005 10 006-25 solvent blank 555 s101122a006 10 006-25 solvent blank 556 s101122a007 10 006-25 solvent blank 557 s 1 0 1 1 2 2 a0 0 8 10 006-25 solvent blank 558 s101122a009 10 006-25 solvent blank 559 s 1 0 1 1 2 2 a0 1 0 E C -101116-01 0.2 ng Extracted Curve Point 560 s101122a011 EC-101116-02 0.5 ng Extracted Curve Point Analyte Peak Name Sample Type Use Record Analyte Concentration (ng/m L) Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Name PFHS Unknown N/A 10.391 224757 MPFHS PFHS Unknown N/A 10.401 17387 MPFHS PFHS Unknown N/A 10.353 17603 MPFHS PFHS Unknown N/A 10.360 '198519 MPFHS PFHS Unknown N/A 10.360 14870 MPFHS PFHS Unknown j N/A 10.381 17445 MPFHS PFHS Unknown j N/A 10.391 198023 MPFHS PFHS Unknown I N/A 10.379 123449 MPFHS PFHS Unknown I N/A 10.381 156407 MPFHS PFHS Unknown ! N/A 10.368 276963 MPFHS PFHS Double Blank ; 0.00 10.461 92 MPFHS PFHS Qualify Control E 2.50 10.380 259340 MPFHS PFHS Double Blank j 0.00 10.754 173 MPFHS PFHS Unknown N/A 10.378 3888896 MPFHS PFHS Unknown ! N/A 10.383 4513586 MPFHS PFHS Unknown \ N/A 10.374 14180655 MPFHS PFHS Unknown \ N/A 10.379 24874452 MPFHS PFHS Unknown i N /A 10.375 20739512 MPFHS PFHS Unknown ! N/A 10.374 55329552 MPFHS PFHS Unknown ! N/A 10.379 31498989 MPFHS PFHS Unknown ! N/A 10.384 35675762 MPFHS PFHS Unknown i N/A 10.386 61663759 MPFHS PFHS Unknown ! N/A 10.379 53276624 MPFHS PFHS Unknown j. N/A 10.371 39528876 MPFHS PFHS Unknown | N/A 10.375 71223605 MPFHS PFHS Unknown j N/A 10.376 7376304 MPFHS PFHS Unknown j N/A 10.390 7383685 MPFHS PFHS Unknown j N/A 10.383 16246310 MPFHS PFHS Double Blank l 0.00 10.401 4100 MPFHS PFHS Qualify Control E 5.00 10.380 559995 MPFHS PFHS Double Blank j 0.00 10.431 1102 MPFHS PFHS Unknown IN /A 10.379 454718 MPFHS 'PFHS Unknown i N/A 0.381 336173 MPFHS PFHS Unknown I N/A 10.380 1481624 MPFHS PFHS Unknown j N/A 10.389 195078 MPFHS PFHS Unknown i N/A 10.387 193207 W fhs PFHS Unknown j N/A 10.386 1280436 MPFHS PFHS Unknown j N/A 10.376 485743 MPFHS PFHS Unknown ] N/A 10.379 633973 MPFHS PFHS Unknown i N/A 10.385 1712582 MPFHS PFHS Unknown | N/A 10.502 3518 MPFHS PFHS Unknown j N/A 10.350 3837 MPFHS PFHS Double Blank | 0.00 10.592 206 MPFHS PFHS Qualify Control E 10.0 10.381 1024849 MPFHS PFHS Double Blank [ 0.00 10.401 627 MPFHS PFOS Double Blank i 0.00 13.588 31 M8PFOS PFOS Double Blank i 0.00 13.518 12 M8PFOS PFOS Double Blank i 0.00 13.326 2010999 M8PFOS PFOS Double Blank j 0.00 13.346 1948130 M8PFOS PFOS Double Blank 0.00 13.175 780 M8PFOS PFOS Double Blank 0.00 13.568 12 M8PFOS PFOS Double Blank 0.00 13.578 121 M8PFOS PFOS Double Blank 0.00 13.568 109 M8PFOS PFOS Double Blank 0.00 13.669 24 M8PFOS PFOS S ta n d a rd E 0.200 13.245 10360 M8PFOS PFOS S ta n d a rd E 0.500 13.235 21657 M8PFOS IS Peak Area (counts) 181996 165574 163972 158166 167091 152468 159397 149447 142293 138488 34 159077 10 176407 169652 165440 159911 164137' 132574 133493 147805 125992 125958 131611 131372 166733 167024 157359 76 172844 0 173092 178454 171811 180994 177023 173671 182741 170659 169264 180131 175750 10 172936 34 85 363 48045 49402 254 12 194 73 0 47443 47365 IS C o n c e n tra tio n (n g /m L ) IS Retention Time (min) Calculated Concentration (n g /m L ) Accuracy <%> Record Modified Rie Name 3.00 10.4 2.00 N/A E s101122a.wiff 3. 10.4 0.141 N/A E s101122a.wiff 3.00 10.4 0.144 N/A E s101122a.wiff 3.00 10.4 2.03 N/A s101122a.wiff 3.00 3.00 10.4 10.4 0.114 0.156 N/A N/A s101122a.wiff s101122a.wiff 3.00 10.4 2.01 N/A s101122a.wiff 3.00 10.4 1.32 N/A E s101122a.wiff 3.00 10.4 1.77 N/ E s101122a.wiff 3.00 10.4 3.25 N/A E s101122a.wiff N/A 10.4 N/A N/A s101122a.wiff 3.00 10.4 2.65 106. s11122.wiff N/A 10.5 N/A N/A s101122a.wiff 3.00 10.4 36.5 N/A E s101122a.wiff 3.00 10.4 44.1 N/A E s101122a.wiff 3.00 10,4 145. N/A E s101122a.wiff 3.00 10.4 272. N/A E s10122a.w iff 3.00 10.4 218. N /A E s101122a.wtff 3.00 10.4 843. N/A E s101122a.wiff 3.00 10.4 428. N/A E s101122a.wiff 3.00 10.4 439. N/A E s101122a.wiff 3.00 3.00 10.4 10.4 1050. 858. N/A _ ? _ s101122a.wiff N/A E s101122a.wiff 3.00 10.4 564. N/A E s101122a.wiff 3.00 1.4 1220. N/A E s101122a.wiff 3.00 10.4 73.8 N/A E s101122a.wiff 3.00 10.4 73.8 N/A E s101122a.wiff 3.00 10.4 176. N/A E ____|s101122a.wiff N/A 3.00 10.4 10.4 N/A 5.29 N/A 106. s101122a.wiff s101122a.wiff N/A 0.00 N/A N/A s101122a.wiff 3.00 10.4 4.29 N/A E s101122a.wiff 3.00 10.4 3.06 N/A E s101122a.wiff 3.00 10.4 14.2 N/A E s101122a.wiff 3.00 10.4 1.74 N/A E s101122a.wiff 3.00 10.4 1.76 N/A E s101122a.wiff 3.00 10.4 12.1 N/A E s101122a wiff 3.00 10.4 4.34 N/A E s l lli .w iff 3.00 10.4 6.08 N/A E s101122a.wiff 3.00 10.4 16.6 N/A E s101122a.wiff 3.00 10.4 0.000219 N/A s101122a. wiff 3.00 10.4 0.00399 N/A S101122a.wiff N/A 10.5 N/A N/A s101122a, wiff 3.00 10.4 9.72 97.2 s101122a.wiff N/A 10.4 N/A N/A s101122a.wiff N/A 13.3 N/A N/A s101122a.wiff N/A 13.7 N/A N/A s101122a.wiff N/A 13.3 N/A N/A E s101122a.wiff N/A 13.3 N/A N/A E s101122a.wiff N/A 13.3 N/A N/A E s101122a.wiff N/A 13.0 N/A N/A s101122a.wiff N/A 13.2 N/A N/A s101122a.wiff N/A 13.3 N/A N/A s101122a.wiff N/A 0.00 N/A N/A s101122a. wiff 2.98 13.3 0.153 76.6 E s101122a.wiff 2.98 13.3 0.459 91.8 E s101122a.wiff Printing Time: 10:47:27 AM Printing Date: Wednesday, January 05, 2011 Page 10 of 14 3M Study G LP10-01-02 Interim R eport 05 Page 177 of 962 *Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample ID 661 s101122a012 562 si01122a013 563 s101122a014 564 s101122a015 565 s101122a016 566 s101122a017 567 s101122a018 566 s101122a019 569 s101122a020 570 s101122a021 571 s101122a022 572 s101122a023 573 s101122a024 574 s101122a025 575 s101122a026 576 s101122a027 577 s101122a028 578 s101122a029 579 s101122a030 580 s101122a031 581 s101122a032 582 s101122a033 583 s101122a034 584 s101122a035 585 s101122a036 586 ^1011228037 587 s101122a038 588 s101122a039 589 s101122a040 590 s101122a041 591 s101122a042 592 s101122a043 593 s101122a044 594 s101122a045 595 s101122a046 596 s101122a047 597 s101122a048 598 S l0 il2 2 a 0 4 9 599 s101122a050 60 s101122a051 601 s101122a052 602 s101122a053 603 s101122a054 604 s101122a055 605 s101122a056 606 s101122a057 607 s101122a058 608 s101122a059 69" s101122a060 610 s101122a061 611 s101122a062 612 s101122a063 613 s101122a064 614 s101122a065 615 s101122a066 616 s101122a067 E C-101116-03 0 .7 5 ng Extracted Curve Point E C -101116-04 1 ng Exfracted Curve Point EC-101116-05 2.5 ng E x a c te d Curv Point E C-101116-06 5 ng Extracted Curve Point EC-101116-07 10 ng Extracted Curve Point E C-101116-08 2 5 ng Extracted C u n Point E C -101116-09 5 0 ng Extracted Curve Point E C-101116-10 100 ng Extracted Curve P oint EC-101116-11 2 00 ng Extracted Curve P oint E C-101116-12 500 ng Extracted Curve P oint 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank MB-101116-01 Method Blank 1 W o IS MB-101116-02 Method Blank2 W o IS MB-101116-03 Method Blank 3 W o IS MB-101116-04 Method B lank4 W IS M B -101116-05 Method B la n k s W IS MB-101116-06 Method B la n k s W IS LCS-101116-01 3 ng LC S inTC R -842 LCS-101116-02 3 ng LCS in TCR-842 LCS-101116-03 3 ng LCS in TCR-842 LCS-101116-04 30 ng LCS in TCR-842 LCS-101116-05 30 ng LCS in TCR-842 LCS-101116-06 30 ng LCS in TCR-842 G LP 1CH>1-02 05-041 DAL SS SS01 6 0000 GLP10-01 -02-05-041 Dup DAL SS SS01 0 0000 Duplicate GLP10-01 -02-05-041 LMS DAL SS SS01 0 0000 Lab Matrix Spike 10 006-25 solvent blank E C -101116-05 2.5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01 -02-05-042 DAL SS SS01 0 0005 GLP10-01 -02-05-042 Dup DAL SS SS01 0 0005 Duplicate G LP10-01 -02-05-042 LMS DAL SS SS01 0 0005 Lab M atrix Spike GLP10-01-02-06-043 DAL SS SS02 0 0000 GLP10-01 -0 2 -05-043 Dup DAL SS SS02 0 0000 Duplicate GLP10-01-02-05-043 LMS DAL SS SS02 0 0000 Lab Matrix Spike GLP10-01-02-05-044 DAL SS SS02 0 0005 GLP10-01-02-05-044 Dup DAL SS SS02 0 0005 Duplicate GLP10-01 -0 2 -05-044 LMS DAL SS SS02 0 0005 Lab M atrix Spike GLP10-01-02-05-045 DAL SS SS03 0 0000 GLP10-01 -0 2 -05-045 Dup DAL SS SS03 0 0000 Duplicate GLP10-01-02-05-045 LMS DAL SS SS03 0 0000 Lab Matrix Spike GLP10-01-02-05-046 DAL SS SS03 0 0005 GLP10-01-02-05-046 Dup DAL SS SS03 0 0005 Duplicate GLP10-01-02-05-046 LMS DAL SS SS03 0 0005 Lab Matrix Spike 10 006-25 solvent blank E C-101116-06 5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-02-05-047 DAL SS SS03 DB 0005 GLP10-01-02-05-047 Dup DAL SS SS03 DB 0005 DupBcate GLP10-01-02-05-047 LMS DAL SS SS03 DB 0005 Lab Matrix Spik GLP10-01 -0 2 -05-048 DAL SS SS04 0 0000 GLP10-01 -0 2 -05-048 Dup DAL SS SS04 0 0000 Duplicate GLP10-01 -0 2 -05-048 LMS DAL SS SS04 0 0000 Lab M atrix Spike Analyte Peak Name Sample Type PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS . PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown UriknbvMi Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Use Record Analyte Concentration (n g /m L ) Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Name E 0.750 13.256 31212 M8PFOS E 1.00 13.256 43609 M8PFS E 2.50 13.245 110730 M8PFOS E 5.00 13.235 213451 M8PFS E 10.0 13.245 391448 M8PFOS E 25.0 13.245 950462 M8PFOS E 50.0 13.225 2064859 M8PFOS E 100. 13.235 3790179 M8PFOS E 200. 13.245 6806923 M8PFOS E 500. 0.00 13.235 13.256 13728568 M8PFOS 4952 M8PFOS 0.00 13.235 1587 M8PFOS 0.00 13.215 1064 M8PFOS 0.00 13.609 36 M8PFOS 0.00 13.218 3732 M8PFOS 0.00 13.238 3845 M8PFOS 0.00 13.210 5234 M8PFOS N/A 13.242 7551 M8PFOS N /A 13.214 5467 M8PFOS N /A 13.227 4874 M8PFOS N /A 13.206 142685 M8PFOS N /A 13.204 144241 M8PFOS N /A 13.227 1hi 50393 M8PFOS N /A 13.201 1361568 M8PFOS N /A 13.215 1404520 M8PFOS N /A 13.218 1363662 M8PFOS N /A 13.218 25091556 M8PFS N /A 13.212 22531149 M8PFOS N /A 0.00 13.220 13.225 40339975 M8PFOS 19190 M8PFOS E 2.50 13.215 122536 M8PFOS 0.00 13.205 2310 M8PFOS N /A 13.213 43482879 M8PFOS N /A 13.229 37430583 M8PFOS N /A 13.217 48167371 M8PFOS N /A 13.217 21102300 M8PFOS N /A 13.232 15096531 M8PFOS N /A 13.226 41127394 M8PFS N /A 13.220 9630273 M8PFOS |N/A 13.225 5951460 M8PFOS N /A 13.220 29041382 M8PFOS N /A 13.226 74185978 M8PFOS N /A 13.228 77172875 M8PFOS N /A 13.210 125367848 M8PFOS N /A 13.217 77701642 M8PFOS N /A 13.215 70830609 M8PFOS N /A 13.214 100935171 M8PFOS 0.00 13.214 90150 M8PFOS E 5.00 13.245 235548 M8PFOS 0.00 13.189 10922 M8PFOS N /A 13.218 87847112 M8PFS N /A 13.218 73696638 M8PFOS N /A 13.197 107801986 M8PFOS N /A 13.206 42475502 M8PFOS N /A 13.234 17164131 M8PFOS N /A 13.227 33806113 M8PFOS IS Peak Area (counts) 45201 48653 50497 46686 47643 47784 50204 47037 43862 32545 48 12 12 0 24 73 145 52587 48995 52818 51553 55312 54505 53668 51291 52037 37384 38126 28773 48 55328 97 27813 31792 23028 42742 43226 28795 44551 46822 30236 27360 26972 14820 20080 22798 16650 36 54543 73 23147 21706 15022 38069 44863 35600 IS C o n c e n tra tio n (n g /m L ) IS Retention Time (min) Calculated Concentration (ng /m L ) Accuracy <%) Record Modified File Name 2.98 2.98 13.2 13.2 0.757 1.02 101. 102. E s101122a.wiff E s101122a.wiff 2.98 13.3 268 107. E s101122a.wiff 2.98 13.2 5.72 114. E S10 1 122a.w iff 2.98 l S 2 10.4 104. E s101122a.wiff 2.98 13.2 25.2 101. E s 1 0 1 1 2 2 a.wiff 2.98 13.2 52.1 104. E s101122a.wiff 2.98 13.2 101. 101. E s101122a.w iff 2.98 13.2 193. 96.4 E s101122a.wiff 2.98 13.2 502. 100. E s101122a.wiff N /A 13.2 N /A N /A E s101122a.wiff N /A 13.3 N /A N /A E s101122a.wiff N /A 13.3 N /A N /A E s101122a.wiff N /A 0.00 N /A N /A s101122a.wiff N /A 13.3 N /A N /A E s101122a.wiff N /A 13.2 N /A N /A E s101122a.wiff N /A 13.2 N /A N /A E s101122a.wiff 2.98 13.2 0.0576 N/A E s101122a.wiff 2.98 13.2 0.0166 N/A E s101122a.w iff 2.98 13.2 <0 N/A E s101122a.w iff 2.98 13.2 3.41 N/A E s101122a.wiff 2.98 13.2 3.21 N/A E s101122a.wiff 2.98 13.2 3.40 N /A E s101122a.wiff 2.98 13.2 32.2 N /A E s101122a.wiff 2.96 13.2 34.7 N /A E s101122a.wiff 2.98 13.2 33.7 N/A E S101122a.w iff 2.98 13.2 770. N/A E s101122a.wiff 2.98 13.2 686. N/A E s101122a.w iff 2.98 13.2 1470. N /A E s io i 122aw iff N /A 13.4 N /A N /A E s101122a.w iff 2.98 13.2 2.71 108. E s10 1 122a.w iff N/A 13.2 N/A N /A E s i 0 1 1 2 2 a.wiff 2.98 13.2 1610. N/A E s1O il 22a.w iff 2.98 13.2 1270. N /A E s 1 0 1 1 2 2 a.wiff 2.98 13.2 2050. N /A E s101122a.wiff 2.98 13.2 581. N /A E s101122a.wiff 2 08 13.2 420. N /A E s101122a.wiff 2.98 13.2 1500. N /A E s101122a.wiff 2.98 13.2 266. N /A E s101122a.wiff 2.98 13.2 159. N /A E s101122a.wiff 2.98 13.2 1060. N /A E s 1 0 1 1 2 2 a.wiff 2.98 13.2 2520. N /A E s101122a.wiff 2.98 13.2 2630. N /A " E s101122a.wiff 2.98 13.2 5810. N /A E s101122a.w iff 2.98 13.2 3320. N/A E s101122a.wiff 2.98 13.2 2810. N /A E s101122a.wiff 2.98 13.2 4610. N /A E s101122a.w iff N /A 13.1 N/A N /A E s101122a.wiff 2.98 13.2 5.39 108. E s101122a.w iff N /A 13.1 N/A N /A E s101122a.w iff 2.98 2.98 13.2 13.2 3270. 3000. N /A N /A E s101122a.wiff E s101122a.wiff 2.98 13.2 5190. N/A E s101122a.wiff 2.98 13.2 1210. N/A E si1122a.wiff 2.98 2.98 13.2 13.2 458. 1050. N/A N/A E s101122a.wiff E s101122a.wiff I Printing Time: 10:47:28 AM Printing Date: Wednesday, January 05, 2011 Page 11 of 14 3M Study GLP10-01-02 Interim Report 05 Page 178 of 962 *Stan V1660305 Results Name: sl01122a.rdb Sample Name Sample ID 617 s101122a068 GLP10-01-02-05-049 DAL SS SS04 0 0005 618 s101122a069 GLP10-01-02-05-049 Dup DAL SS SS04 0 0005 Duplicate 619 s101122a070 GLP10-01-02-05-049 LMS DAL SS SS04 0 0005 Lab Matrix Spike 620 s101122a071 GLP10-01-02-05-050 DAL SS TRIP1 0 0000 621 s101122a072 GLP10-01-02-05-050 D up DAL S S TRIP1 0 0000 Duplicate 6 22 js101122a073 G LP10-01-02-05-050 LMS DAL SS 7RIP1 0 0000 Lab M atrix Spike 623 s101122a074 GLP10-01-02-05-051 DAL SS SS05 0 0000 624 s101122a075 GLP10-01-02-05-051 Dup DAL SS SS05 0 0000 Duplicate 625 s101122a076 GLP10-01-02-05-051 LMS DAL SS SS05 0 0000 Lab Matrix Spike 626 s101122a077 10 006-25 soKent blank 627 s101122a078 EC-101116-07 10 ng Extracted Curve P oint 628 s101122a079 10 006-25 solvent blank 629 s101122a080 GLP10-01-02-05-052 DAL SS SS05 0 0005 630 s101122a081 G LP10-01 -02-05-052 D up DAL SS SS05 0 0005 Duplicate 631 1s101122a082 G LP10-01-02-05-052 LMS DAL SS S S05 0005 Lab M atrix Spike 632 $101122a083 GLP10-01-02-05-054 DAL SS SS06 0 0000 633 s101122a084 G LP10-01-02-05-054 Dup DAL SS SS06 0 0000 Duplicate 634 s101122a085 G LP10-01 -02-05-054 LMS DAL SS S S06 0 0000 Lab M atrix Spike 635 s101122a086 GLP10-01-02-05-055 DAL SS SS06 0 0005 636 s101122a087 G LP10-01-02-05-055 D up DAL SS SS06 0 0005 Duplicate 637 s101122a088 GLP10-01-02-05-055 LMS DAL SS SS06 0 0005 Lab Matrix Spike 638 s101122a089 G LP10-01 -02-05-056 DAL SS SS06 DB 0005 639 s101122a090 GLP1-0-2-5-56 Dup DAL SS SS6 DB 0005 Duplicate 640 s101122a091 G LP10-01-02-05-056 LMS DAL SS S S06 DB 0005 Lab M atrix Spik 641 s101122a092 G LP 10-01-02-05-57 DAL SS SS07 0 0000 642 s101122a093 GLP10-01-02-05-057 Dup DAL SS SS07 0 0000 Duplicate 643 s101122a094 GLP10-01-02-05-057 LMS DAL SS SS07 0 0000 Lab Matrix Spike 644 s101122a095 10 006-25 solvent blank 645 s101122a096 E C -1 01 116-05 2.5 ng Eidracted Curve P oint 646 s101122a097 10 006-25 solvent blank 647 s101122a098 GLP10-01-02-05-058 DAL SS SS07 0 0005 648 s101122a099 GLP10-01-02-05-058 Dup DAL SS SS07 0 0005 Duplicate 649 s101122a100 GLP10-01 -02-05-058 LMS DAL SS SS07 0 0005 Lab M atrix Spike 6 5 0 " s101122a101 G LP10-01-02-05-059 DAL SS SS08 0 0000 651 s101122a102 G LP10-01-02-05-059 D up DAL SS SS08 0 0000 Duplicate 652 s101122a103 G LP10-01 -02-05-059 LMS DAL S S SS08 0 0000 Lab M atrix Spike 653 s101122a104 GLP10-01-02-05-060 DAL SS SS08 DB 0000 654 s101122a105 G LP10-01 -02-05-060 D up DAL SS SS08 DB 0000 DupGcate 655 s101122a106 GLP10-01-02-05-060 LMS DAL SS SS08 DB 0000 Lab Matrix Spik 656 s101122a107 GLP10-01-02-05-061 DAL SS SS08 0 0005 657 s101122a108 G LP10-01-02-05-061 D up DAL SS SS08 0 0005 Duplicate 658 s101122a109 G LP10-01 -02-05-061 LMS DAL S S S S08 0 0005 Lab M atrix Spike 659 s101122a110 GLP10-01-02-05-062 DAL SS SS09 0 0000 660 s101122a111 G LP10-01 -02-05-062 D up DAL SS SS09 0 0000 Duplicate 661 s101122a112 G LP10-01 -02-05-062 LMS DAL S S S S09 0 0000 Lab M atrix Spike 662 s101122a113 10 006-25 solvent blank 663 s101122a114 EC-101116-06 5 ng Extracted Curve Point 664 s101122a115 10 006-25 solvent blank 665 s101122a116 GLP10-01-02-05-063 DAL SS SS09 0 0005 666 s101122a117 GLP10-01-02-05-063 Dup DAL SS SS09 0 0005 Duplicate 667 s101122a118 GLP10-01-02-05-063 LMS DAL SS SS09 0 0005 Lab Matrix Spike 668 s101122a119 jG LP 10-01-02-05-064 DAL SS GP01 0 0000 669 s101122a120 G LP10-01-02-05-064 Dup DAL SS GP01 0 0000 Duplicate 670 s101122a121 GLP10-01-02-5-064 LMS DAL SS GP01 0 0000 Lab Matrix Spike 671 s101122a122 G LP10-01-02-05-065 DAL SS GP01 0 0005 672 s101122a123 G LP10-01-02-05-065 D up DAL SS GP01 0 0005 Duplicate Analyte Peak Name Sample Type PFOS PFOS PFOS PFS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS P- c : PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Unknown Unknown Unknown "i Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Qualify Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Use Record Analyte C o n c e n tra tio n (n g /r n L ) Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Name N/A 13.223 6787559 M8PFOS N/A 13.227 8030181 M8PFOS N/A 13".232 24668309 M8PFOS ]N /A 13.219 20014 M8PFOS N/A 13.243 12364 M8PFOS IN/A 13.217 101379 M8PFOS N/A 13.187 f49756184 M8PFOS N /A . 13.206 130544198 M8PFOS I N/A 13.146 29825577 M8PFS 0.00 13.195 334477 M8PFOS E 10.0 13.205 464958 M8PFOS 0.00 13.215 24639 M8PFOS ;N/A 13.213 63349517 MBPFOS !N/A 13.211 66647034 M8PFOS |N/A 13.188 100228926 M8PFOS |N/A 13.207 12890584 M9PFOS N/A 13.221 13767756 M8PFS N/A 13.206 25211241 M8PFOS N/A 13.222 5672354 M8PFOS }N/A 13.230 6379731 M8PFOS |N/A 13.222 19838107 M8PFOS | N/A 13.233 6735368 ~ M8PFOS ;N/A 13.211 6383423 M8PFS IN/A 13.223 19948778 M8PFOS I N/A 13.217 23588582 M8PFOS N/A 13.224 23239000 M8PFOS ;n /a 13.215 31011743 M8PFOS 0.00 13.196 18195 MBPFOS IS 2.50 13.215 121512 M8PFOS 0.00 13.145 2361 MBPFOS N/A 13.212 83772035 M8PFOS N/A 13.222 80011351 M8PFOS N/A 13.194 117947664 M8PFOS N/A 13.222 2494447 M8PFOS N/A 13.213 3020879 M8PFOS N/A 13.203 6549383 M8PFOS N/A 13.219 2343356 M8PFOS N/A 13.207 2617784 MBPFOS N/A 13.218 6520335 M8PFOS N/A 13.197 1315790 M8PFOS N/A 13.222 1145123 M8PFOS N/A 13.220 5159124 M8PFOS N/A 13.212 19862318 M8PFOS N/A 13.204 21975586 M8PFOS N/A 13.209 31051116 M8PFOS 0.00 13.235 12102 M8PFOS IS 5.00 13.215 228747 M8PFOS 0.00 13.266 1348 M8PFS N/A 13.216 15702976 M8PFOS iN/A 13.222 15925928 MBPFOS iN/A 13.222 27036908 M8PFOS IN/A 13.215 12955223 M8PFOS IN/A 13.216 14734651 M8PFOS In /a 13.216 25662836 M8PFOS ;N/A 13.213 7088977 M8PFOS N/ 13.216 9414894 M8PFOS IS Peak Area (counts) 49651 52296 40674 56512 52828 55576 13228 13535 8442 48 50799 156 22053 19928 15286 46020 46877 39094 51100 53840 35176 48153 48207 36501 40653 43630 31664 339 53171 145 24976 27346 17646 49626 52016 53341 53566 54801 48874 58079 54289 47899 43811 41182 33746 24 54572 12 43753 42790 34474 46527 45554 33683 45042 42719 IS C o n c e n tra tio n (ng/mL) IS Retention Time (min) Calculated Concentration (ng/m L) Accuracy <%> 2.98 13.2 170. N/A 2.98 2.98 13.2 13.2 191. 703. N/A N/A 2.98 13.2 0.327 N/A 2.98 13.2 0.173 N/A 2.98 2.98 13.2 13.1 2.21 7070. N/A N/A ]2.98 j 13.2 6350. N/A 2.98 13.2 11700. N/A N/A 13.4 N/A N/A 2.98 N/A 13.2 13.4 11.6 N/A 116. N/A 2.98 13.2 2640. N/A 2.98 13.2 2970. N/A 2.98 13.2 4870. N/A 2.98 13.2 341. N/A 2.98 13.2 357. N/A 2.98 13.2 743. N/A 2.98 13.1 139. N/A 2.98 2.98 13.2 13.2 148. 657. N/A N/A 2.98 13.2 174. N/A 2.98 13.2 165. N/A 2.98 13.2 639. N/A 2.98 2.98 13.2 13.1 675. 624. N/A N/A 2.98 13.2 1080. N/A N/A 13.2 N/A N/A 2.98 N/A 13.2 13.2 2.80 N/A 112. N/A 2.98 13.1 2980. N/A 2.98 13.1 2680. N/A 2.98 13.2 4940. N/A 2.98 2.98 13.2 13.2 63.6 73.4 N/A N/A 2.98 13.2 153. N/A 2.98 13.2 55.4 N/A 2.98 13.2 60.4 N/A 2.98 2.98 13.2 13.2 166. 28.7 N/A N/A 2.98 13.2 26.8 N/A 2.98 13.2 135. N/A 2.98 13.2 537. N/A 2.98 13.2 625. N/A 2.98 13.2 1020 N/A N/A 13.3 N/A N/A 2.96 N/A 2.98 13.2 13.3 13. 5.23 N/A 431. 105. N/A N/A 2.98 2.98 2.98 13.2 13.2 13.2 446. 887. 339. N/A N/A N/A 2.98 2.98 13.1 13.2 391. 864. N/A N/A 2.98 2.98 13.2 13.2 196. 271. N/A N/A Record Modified Rie Name IS IS E E E E E E E E E E E E E "E E E E E" E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a. w iff s101122a.w iff s101122a.wiff s101122a.w iff s101122a.wiff s10 1 122a.w iff s10 1 122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff I s 101122a.w iff s101122a.w iff 101122a.w iff s10 1 122a.w iff s101122a.wiff s101122a.wiff s 1 0 1 1 2 2 a.wiff s i l 122a.w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a. w iff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s1 01 122a.w iff s10 1 122a. w iff s101122a.w iff s101122a.w iff s101122a.wiff s 1 0 1 1 2 2 a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.wiff s101122a.w ifi s101122a.w iff Printing Time: 10:47:28 AM Printing Date: Wednesday, January 05, 2011 Page 12 of 14 3M Study GLP10-01-02 Interim Report 05 Page 179 of 962 Stari V1660305 Results Name: sl01122a.rdb r 1 ...... . Sample Name Sam ple ID 673 s101122a124 674 s'01122a125 675 s101122a126 676 s1022a127 677 s101122a128 678 s101122a129 679 s101122a130 680 s101122a131 681 s101122a132 682 s101122a133 683 s101122a134 684 s101122a135 685 s101122a136 686 s101122a137 687 s101122a138 688 s101122a139 689 s101122a140 690 s101122a141 691 s101122a142 692 s101122a143 693 s101122a144 694 S1122a145 695 si0122a146 696 s101122a147 697 s101122a148 698 s101122a149 699 s101122a150 700 s101122a151 701 s101122a152 72 s101122a153 703^ s101122a154 704 s101122a155 705 s101122a156 706 s101122a157 707 s101122a158 708 s101122a159 709 s101122a160 710 s101122a161 711 s101122a162 712 s10122a163 713 s101122a164 714 s101122a165 715 s101122a166 716 s101122a167 717 s101122a168 718 s101122a169 719 s101122a170 720 s101122a171 721 s101122a172 722 s101122a173 723 s101122a174 724 s101122a175 725 s101122a176 726 s101122a177 727 s101122a178 728 s101122a179 G LP10-01-02-05-065 LMS DAL SS GP01 0 0005 Lab Matrix Spike G LP10-01-02-05-066 D A L SS GP01 0 0020 G LP10-01-02-05-066 Dup DAL SS GP01 0 0020 Duplicate G LP10-01-02-05-066 LMS DAL SS GP01 0 0020 Lab Matrix Spike G LP10-01-02-05-067 D A L SS GP01 0 0060 GLP10-01-02-05-067 D u p D A L SS GP01 0 0060 Duplicate GLP10-01 -02-05-067 LMS DAL SS GP01 0 0060 Lab Matrix Spike 10 0 0 6 -2 5 soKent blank EC-101116-07 10 ng Extracted C u n Point 10 0 0 6 -2 5 solvent blank GLP10-01-02-05-068 DAL SS GP02 0 0000 GLP10-01-02-05-068 D up DAL SS GP02 0 0000 Duplicate GLP10-01-02-05-068 LMS DAL SS GP02 0 0000 Lab Matrix Spike GLP10-01-02-05-069 DAL SS GP02 0 0005 GLP10-01-02-05-069 Dup DAL SS GP02 0 0005 Duplicate GLP10-01-02-05-069 LMS DAL SS GP02 0 0005 Lab Matrix Spike GLP10-01-02-05-070 DAL SS GP02 0 0020 GLP10-01-02-05-070 D up DAL SS GP02 0 0020 Duplicate GLP10-01 -02-05-070 LMS DAL SS GP02 0 0020 Lab Matrix Spike GLP10-01-02-05-071 DAL SS GP02 DB 0020 GLP10-01 -02-05-071 D up DAL SS GP02 DB 0020 Duplicate GLP 1(jli-2-5-71 LMS D A L SS GP2 DB 2 Lab Matrix Spik GLP10-01 -02-05-072 DAL SS GP02 0 0120 GLP10-01-02-05-072 Dup DAL SS GP02 0 0120 Duplicate GLP10-01-02-05-072 LMS DAL SS GP02 0 0120 Lab Matrix Spike 10 006 -2 5 s o te n t blank EC -101116-05 2.5 ng Extracted Curve Point 10 006 -2 5 solvent blank GLP10-01-02-05-073 DAL SS GP03 0 0000 G LP10-01-02-05-073 D up D A L S S rGP03 0 0000 Duplicate GLP10-01 -02-05-073 LMS DAL SS GP03 0 0000 Lab Matrix Spike GLP10-01-02-05-074 DAL SS GP03 0 0005 G LP10-01-02-05-074 D up D A L SS GP03 0 0005 Duplicate GLP10-01-02-05-074 LMS DAL SS GP03 0 0005 Lab Matrix Spike GLP10-01-02-05-075 DAL SS GP03 0 0020 G LP10-01-02-05-075 D up D A L SS GP03 0 0020 Duplicate G LP10-01-02-05-075 LMS D A L SS GP03 0 0020 Lab Matrix Spike GLP10-01-02-05-076 DAL SS GP03 DB 0020 GLP10-01-02-05-076 D up D A L SS GP03 DB 0020 Duplicate GLP10-01-02-05-076 LMS DAL SS GP03 DB 0020 Lab Matrix Spik GLP10-01-02-05-077 DAL SS GP03 0 0050 GLP10-01-02-05-077 D up D A L SS GP03 0 0050 Duplicate GLP10-01-02-05-077 LMS DAL SS GP03 0 0050 Lab Matrix Spike 10 0 0 6 -2 5 solvent blank EC-101116-06 5 ng Extracted Curve Point 10 0 0 6 -2 5 solvent blank . GLP10-01-02-05-078 DAL SS GP04 0 0000 GLP10-01 -02-05-078 D up D A L SS GP04 0 0000 Duplicate GLP10-01-02-05-078 LMS DAL SS GP04 0 0000 Lab Matrix Spike GLP10-01-02-05-079 DAL SS GP04 0 0005 G LP10-01-02-05-079 Dup DAL SS GP04 0 0005 Duplicate GLP10-01 -02-05-079 LMS DAL SS GP04 0 0005 Lab Matrix Spike GLP10-01 -02-05-080 DAL SS GP04 0 0020 GLP10-01 -02-05-080 Dup DAL SS GP04 0 0020 Duplicate GLP10-01 -02-05-080 LMS DAL SS GP04 0 0020 Lab Matrix Spike M B -101116-07 Method B lank 5g wrf IS fo r Dilutions Analyte Peak Name Sample Type Use Record Analyte C o n c e n tra tio n (n g /m L ) Analyte Retention Time (min) Analyte Peak Area (counts) PFOS Unknown I N/A 13.210 23923466 PFOS Unknown i N/A 13.223 13104451 PFOS Unknown N/A 13.202 13827719 PFOS PFOS Unknown Unknown | N/A IT v 13.213 13.212 24377828 1043428 PFOS Unknown N/A 13.220 1470921 PFOS Unknown N/A 13.221 4487392 PFOS Double Blank 0.00 13.195 1976 PFOS Quality Control E 10.0 13.215 392132 PFOS Double Blank 0.00 13.235 755 PFOS Unknown N/A 13.225 3567042 PFOS Unknown N/A 13.210 3824527 PFOS Unknown N/A 13.209 6928777 PFOS Unknown N/A 13.214 3453421 PFOS Unknown N/A 13.205 4488812 PFOS Unknown } N/A 13.215 8173498 jP F O S Unknown i N/A 13.188 8744331 PFOS Unknown j N/A 13.186 9422860 PFOS Unknown i N/A 13.171 20014245 PFOS Unknown { N/A 13.197 9336247 PFOS Unknown i N/A 13.193 9920455 PFOS Unknown ! N/A 13.176 21341305 PFOS Unknown i N/A 13.183 212662 PFOS Unknown i N/A 13.195 207130 PFOS Unknown i N/A 13.200 529099 PFOS Double Blank \ 0.00 13.064 1257 PFOS Quality Control E 2.50 13.195 115048 PFOS Double Blank j 0.00 13.478 36 PFOS Unknown N/A 13.196 19116717 PFOS Unknown N/A 13.187 22882328 PFOS Unknown N/A 13.202 31982082 PFOS Unknown N/A 13.186 48734832 PFOS Unknown N/A 13.154 40157271 PFOS Unknown i N/A 13.171 91179090 PFOS Unknown j N/A 13.198 37829047 PFOS Unknown ; N/A 13.206 46299541 PFOS Unknown : N/A 13.185 87762957 PFOS Unknown i N/A 13.211 60514763 PFOS Unknown j N/A 13.194 46050666 PFOS Unknown ! N/A 13.187 96643689 PFOS Unknown I N/A 13.199 11343228 PFOS Unknown j N/A 13.196 11808753 PFOS Unknown j N/A 13.194 21751782 PFOS Double Blank j 0.00 13.165 12951 PFOS Quality Control E 5.00 13.195 238959 PFOS Double Blank i 0.00 13.155 4001 PFOS Unknown I N/A 13.195 27987669 PFOS Unknown N/A 13.198 23189727 PFOS Unknown : N/A 13.187 34971124 PFOS Unknown N/A 13.201 19341966 PFOS Unknown N/A 13.180 19087870 PFOS Unknown N/A 13.197 29007829 PFOS Unknown N/A 13.193 3310718 PFOS Unknown N/A 13.202 5491758 PFOS Unknown N/A 13.197 8969412 PFOS Unknown N/A 13.143 11166 IS Peak Name M8PFOS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS MBPFS M8PFOS M8PFOS M8PFS fi/BPFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS IS Peak Area (counts) 32797 42320 47058 34645 50729 43001 39378 48 48993 61 48637 54013 45478 54548 57335 48781 45441 45365 34907 45144 41906 36411 49574 50284 42665 73 53240 109 40919 37565 33062 30022 31014 16015 29224 29086 16886 23713 25750 1736 45059 44431 32833 24 56024 12 35046 39880 33140 41859 41215 32590 52490 50669 45453 58477 IS C o n c e n tra tio n (n g /m L ) IS Retention Time (min) Calculated Concentration (ng /m L ) Accuracy <%) 2.98 13.2 831. N/A 2.98 13.2 375. N/A 2.98 13.2 357. / 2.98 13.2 804. N/A 2.98 13.2 26.1 N/A 2.98 13.2 43.4 N/A 2.98 13.2 143. N/A N/A 13.1 N/A N/A 2.98 13.2 10.1 id . N/A 13.2 N/A N/A 2.98 13.2 92.4 N/A 2.98 13.2 89.3 N/A 2.98 13.2 189. N/A 2.98 13.2 79.9 N/A 2.98 13.2 98.6 N/A 2.98 13.2 208. N/A 2.98 13.2 238. N/A 2.98 13.2 256. N/A 2.98 2.98 13 2 13.2 667. 255. N/A /A 2.98 13.2 290. N/A 2.98 13.2 681. N/A 2.98 1 3 2 5.36 N/A 2.98 13.2 5.14 N/A 2.98 13.2 15.7 N/A N/A 13.2 N/A N/A 2.98 13.2 2.64 105. N/A 13.3 N/A N/A 2.98 13.2 552. N/A 2.98 3 .2 705. N/A 2.98 13.2 1070. N/A 2.98 13.2 1670. N/A 2.98 13.2 1380. N/A 2.98 13.1 4400. N/A 2.98 13.2 1380. N/A 2.98 13.2 1640. N/A 2.98 13.2 4120. N/A 2.98 13.2 2410. N/A 2.98 13.2 1800. N/A 2.96 13.1 4340. N/A 2 98 13.2 308. N/A 2.98 13.2 324. N/A 2.98 13.2 761. N/A N/A 13.3 N/A N/A 2.98 13.2 5.33 107. N/A 13.3 N/A N/A 2 98 2.98 13.2 13.2 901. 676. N/A N/A 2.98 13.2 1150. N/A 2.98 13.2 547. N/A 2.98 13.2 548. N/A 2.98 13.1 992. N/A 2.98 2.98 13.2 13.2 79.6 136. N/A N/A 2.98 13.2 244. N/A 2.98 13.2 0.118 N/A Record Modified Rie Name E s101122a.wiff E s101122a.wiff E s101122a.wiff sl122a.w iff E s 1 0 1 1 2 2 a.wiff E s101122a.wiff E s 1 0 1 1 2 2 a.wiff E s101122a.wiff s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff s101122a.wiff s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff s1 0 1 1 2 2 a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s 1 0 1 1 2 2 a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff E s101122a.wiff Printing Time: 10:47:29 AM Printing Date: Wednesday, January 05, 2011 Page 13 of 14 3M Study G LP10-01-02 Interim R eport 05 Page 180 of 962 Stan V1660305 Sample Name Sam ple ID 729 s101122a180 730 si01122a181 731 s 1 0 1 1 2 2 a 1 8 2 732 s101122a183 MB-101116-08 Method Blank 5g vtf IS fo r Dilutions 10 006-25 solvent blank EC-101116-07 10 ng Extracted C u n Point 10 006-25 solvent blank Results Name: sl01122a.rdb Analyte Peak Name Sample Type jP F O S PFOS PFOS PFOS Unknown Double Blank Quality Control Double Blank I e Ul Cseo n !c e An nt ar la* ttei o n Record ; (ng/mL) Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Name jlM/A 13.182 7286 M8PFOS 0.00 3.185 1224 M8PFOS 1. 13.185 435999 M8PFOS .0.00 13.205 1382 M8PFOS \ IS Peak ' Area j (counts) |54979 148 58407 133 IS I Concentration R ls e " * lon Calculated Concentration (ng /m L ) Accuracy (% > 2.98 N/A 2.98 N/A 13.2 13.2 113.2 ;13.1 0.0434 N/A~ 9.41 N/A N/A N/A 94.1 N/A jE jE jE jE ! |s101122a.wiff |s101122a.wiff Is101122a.wiff |s101122a.wiff Printing Time: 10:47:29 AM Printing Date: Wednesday, January 05, 2011 3M Study GLP10-01-02 Interim Report 05 Page 14 of 14 Page 181 of 962 Stan V1660305 Results Name: sl01122a.rdb s101122a.rdb (PFBS): "Quadratic" Regression ("1 / x" weighting): y = -0.00142 xA2 + 1.26 x + 0.0256 (r = 0.9999) Printing Time: 10:21:48 AM Printing Date: Wednesday, January 05, 2011 3M Study GLP10-01-02 Interim Report 05 Page 1 of 1 *Stan V1660305 Results Name: sl01122a.rdb s101122a.rdb (PFHS): "Quadratic" Regression ("1 / x" weighting): y = -0.00122 xA2 + 1.83 x + 0.0194 (r = 0.9995) Printing Time: 10:22:02 AM Printing Date: Wednesday, January 05, 2011 3M Study GLP10-01-02 Interim Report 05 Page 1 of 1 Page Stan V1660305 Results Name: slOH22a.rdb Stan V1660305 Results Name: sl01122a.rdb s101122a.rdb (MPFOS): "Quadratic" Regression ("1 / x" weighting): y = 0.000555 xA2 + 0.97 x + 0.0432 (r = 0.9998) Printing Time: 10:22:26 AM Printing Date: Wednesday, January 05, 2011 3M Study GLP10-01-02 Interim Report 05 Page 1 of 1 Stan V1660305 Results Name: sl01122a.rdb Stan V1660305 ! Sample Name: "s101122a005" Sample ID: *10 006-25 solvent blank" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" I Comment: "" Annotation: "" sample Index: sample Type: Double Blank concentracin: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 1:00:06 PM File: 's 1 0 1 1 2 2 a .w tT Modified: Yes Proc. Algorithm: IntelliQuan - m q i i Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height cps Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 7.798 min 3963 counts 3 .36e +002 CpS 7.677 min 7.939 Sample Name: "s101122a007" Sample ID: "10 006-25 solvent blank" I Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" Comment: "" Annotation: "* sam ple in d e x : File: ''s101122a.wifr Printing Time: 5:45:50 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb (Sample Name: "s101122a006" Sample ID: "10 006-25 solvent blank" Peak Name: "PFBS" Mass(es): *299.0/99.0 am u.299.0/80.0 amu" C o m m e n t"" Annotation: "" Sample Index: 6 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: l: 24:19 PM File: "s101122a.wifT Modified: No MPirno.c. PAelagkorHietihgmh:t: Int0e.l0l0iQuancps- IQA Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 Expected RT: 8.04 Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time : Valley 7.808 min 3600 counts 4.7ie+002 cps 7.677 min 7.949 min Sample Name: "s101122a008" Sample ID: "10 006-25 solvent blank" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" C o m m en t"" Annotation:"" Sample index: Double Blank Sample Type: 0.00 ng/mL Concentration: N/A Calculated cone: 1 1 / 2 2 / 2 0 1 0 Acq. Date: 2:12:36 PM Acq. Time: Modified: NO Proc. Algorithm IntelliQuan IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: NO File: "s101122a.wifT Int. Type: Valley Retention Time: 7.828 min Area: 2947 counts Height: 4.63e+002 Cps Start Time: 7.717 min End Time: 7.919 min Page 2 of 321 Page 187 of 962 *Stan V1660305 Sam ple Name: "s 1 011228009* Sam ple ID: " 10 006-25 solvent blank" I P- eak....N...a..m...e..:..."PFBS* Mass(es): "299.0/99.0 Comment " Annotation: " Sample Index: 9 " 0/80.0 8m iT Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acg. Date: 11/22/2010 Acq. Time: 2:36:44 PM File: "$101122a.wifT Modified: No Proc. Algorithm: IntelliQuan . Min. Peak Height: 0.00 cp: Min. Peak width: 0.00 sei Smoothing width: 3 poii RT Window: 30.0 se< Expected RT: e.04 mil use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time : End Time : valley 8.181 min 732 counts i.6Se+ooi cps 7.9S9 min 6.212 min I Sample Name: "s101122a011'' Sample ID: "C-1011 1 6-0 20 .5 ng Extracted Curve Point" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.O/B0.0 amu" C omment "* Annotation: " Sample Index: 11 Sample Type: Standard Concentration: 0.500 ng/mL Calculated cone: 0.501 ng/mL Acq. Date: 11/22/2010 Acq. Time: 3:2S:06 PM File: "s101122a.wifT Modified: NO Proc. Algorithm: IntelliQuancps- IQA Min. Peak Height: sec Min. Peak Width: points Smoothing Width: : RT window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height : Start Time: End Time : Valley 7.689 min 73637 counts 7. OSe+003 cps 7.766 min 8.212 min Printing Time: 5:45:52 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a010" Sample ID: "EC-101116-01 0.2 ng Extracted Curve Point" Peak Name: "PFBS* Mass(es): "299.0/99.0 amu,299.0/80.0 amu* Comment "* Annotation: "" s a m p le Index: 10 File: "s101122a.wifT T Sample Name: "s101122a012" Sample ID: "EC-101116-03 0.75 ng Extracted Curve Point" Peak Name: "PFBS" Massues): "299.0/99.0 a u,299.0/60.0 amu" Comment " Annotation: Sample Index: 12 Sample Type: Standard Concentration : 0.749 ng/mL Calculated Cone: 0 743 ng/mL A c q . Date : 11/22/2010 9500 A c q . Time : 3:49:18 PM 9000 File: Ms101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: .04 min Use Relative RT: NO 8500 8000 7500 7000 6500 Int. Type: Valley Retention Time: 7.889 min Area: 111617 counts Height : 9. 86e*003 cps Start Time: 7.687 min End Time : 8.292 min 6000 U> 5500 gf 5000 4500 ~ 4000 3500 3000 2500 2000 1500 1000 500 1.05 6-69 19.69 21.28 0 ___,___ _-- - j- ___, 24 68 10 12 14 16 18 20 22 199 398 596 794 992 1191 1389 1587 1785 1984 2162 ________________________________________________Time, min________________________________________________ Page 3 of 321 Page 188 of 962 Stan V1660305 Results Name: slOH22a.rdb Sample Name: "s101122a013" Sample ID: "EC -101116-04 1 ng Extracted Curve Point" 1 Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,2 9 9.0/8 0.0 amu" 1 C om m ent Annotation: "" Sample Index: 13 Sample Type: standard Concentration: 0.999 ng/mL Calculated cone: 0.S53 ng/mL Acq. Date: 11 /2 2/2 01 0 1.20e4 Acq. Time: 4:13:33 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cpa Min. Peak width: 0.00 sec Smoothing width: 3 points RT w i n d o w : 3 0.0 sec Expected RT: 8.04 min Use R e lative RT: No Int. Type: Valley Retention Time: 7.889 min Area: 1399S8 counts Height: i .2 7 e + 0 0 4 cp s start Time: End Time: 7.737 8 .3S3 min min 1.10*4 1 00e4 9000 00 8000.00 ,, 7nnn nn g. 7000.00 . finnn nn | 5000.00 4000.00 3000.00 2000.00 0.00 Jll 2 . 4 6 .... . I 10 12 199 398 596 794 992 1191 Time, min | Sample Name: "s101122a0l5" Sample ID: "EC-101116-06 5 ng Extracted Curve Point" File: "s101122a.wifT 1 Peak Name: "PFBS" Mass(es): '2 99 .0/9 9.0 amu,299.0/80.0 amu" 1 Comment: "" Annotation: "" Sample Index: IS Sample Type: Standard Concentration: s.oo ng/mL Calculated Cone: 5.26 ng/mL 6.5e4 Acq. Date: 11/22/2010 Acq. Time: 5:01:52 PM 6.0e4 . 14 1369 Modified: No Proc. A l gorithm: I n t e l liQuan - I Q A Min. Peak Height: o .oo cps Min. Peak width: o .oo s ec Smoothing width: 3 points RT Window; 30.0 sec Expected RT: s.04 min use R elative RT: No 55e4 5.0e4 4 5e4 Int. Type: Valley Retention Time: 7.889 min Area: 738838 counts Height: 6.7ie*004 cps start Time: 7.707 min End Time: 8.212 min 4.0e4 ,, S' >. ' 3.0e4 E 2.5e4 16 1587 Sample Name: "s101122a014" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" Peak Name: "PFBS' Mass(es): "299.0/99.0 am u.299.0/80.0 amu" C om m ent "" Annotation: "" Sample Index: 14 Sample Type: standard Concentration: 2 . SO ng/mL Calculated Cone: 2 .6 8 ng/mL Acq. Date: 11/2 2/2 01 0 3.4e4-l Acq. Time: 4:37:42 PM 3.2e4 File: "s101122a.wifT 19.83 21.36 18 1785 20 1984 22 2182 Modified: No Proc. Algorithm: IntelliQuan - iq a Min. Peak Height: o.oo cps Min. Peak width: Smoothing Width: 0.00 sec 3 points RT Window: 30.0 sec E x p ected RT: 8.04 min Use Relative RT: No Int. Type: Retention Time: Valley 7.909 min Area: Height: 379840 counts 3.50e*004 cps start Time: 7.687 min End Time: 8.444 min 3.0e4 2.8e4- 2.6e4- 2.4e4- 2.2e4- ,, 2.0e4S' 1-8s4V S 1.6e4J ~ 1.4e4- 1.2e4- 1.0e4- 8000.0- 6000.0- 4000.0- 2000.0- ._______ 0.0 24 6 10 12 199 398 596 794 992 1191 Time, min Sample Name: "s101122a016* Sample ID: "EC-101116-07 10 ng Extracted Curve Point" File: "s101122a.wifr 1 Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" 1 C omment "" Annotation: Sample Index: 16 Sample Type: standard Concentration: 9.99 ng/mL Calculated Cone: 10.7 ng/mL Acq. Date: 11/22/2010 1.3e5 Acq. Time: 5:26:01 PM I Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec E x p ected RT: 8.04 min Use Relative RT: No 1.1e5 , 9.0e4 int. Type: valley Retention Time: 7.899 min Area: 1482560 counts Height: l .3 se + o o s c p s start Time: 7.687 min End Time: 8.474 min ^ ,, 3* 7.0e4 ' e -- . 6.0e4 5.0e4 2.0e4 4.0e4 1. 5 e 4 - 3.0e4 1,0e4 2.0e4 5000.0 0.0 . . k... . .. .. .. .. 2 4 8 10 12 14 16 18 20 22 199 398 596 794 992 1191 1369 1587 1785 1964 2182 Time, min Printing Time: 5:45:55 PM Printing Date: Friday, January 07, 2011 1.0e4 0.0 . 2 199 4 396 . 6 596 !.. 8 794 Page 4 of 321 10 12 992 1191 Time, min .. 14 1389 14 1389 . 16 1587 16 1567 18 1785 , 18 1765 20 1984 , 20 1984 22 2182 22 2182 3M Study GLP10-01-02 Interim Report 05 Page 189 of 962 Stan V1660305 Sample Name: "s101122a017" Sample ID: "EC-101116-08 25 ng Extracted Curve Point" Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/BO.O amu" Comment Annotation: "" Sample Index: 17 Sample Type: Standard concentration: 25.0 ng/mL Calculated cone: 23.7 ng/mL Acq. Date: 1 1 /22/2010 Acq. Time: 5:50:14 PM File: "s 101 122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 epa Min. Peak Width: 0.00 sec Smoothing Width: RT Window: Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.889 min Area: 3428621 counts Height: 3.28eOOS cps Start Time: End Time : 7.717 min 8.373 I Sample Name: "s101122a019" Sample ID: "EC-101116-10100 ng Extracted Curve Point" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" I C om m ent:Annotation: ~ Sample Index : 19 Sample Type: standard Concentrt ion : 99.9 ng/mL Calculated Cone: 99.7 ng/mL Acg. Date: 11/22/2010 Acq. Time: 6:38:37 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: Valley Retention Time 7.889 min Area: 13396168 counts Height : l.i9e+0O6 cps start Time 7.677 min End Time : 8.716 min Printing Time: 5:45:56 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a018" Sample ID: "EC-101116-09 50 ng Extracted Curve Point" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu' Comment "" Annotation: " Sample Index File: "s101122a.wir I Sample Name: "s101122a020" Sample ID: "EC-101116-11 200 ng Extracted Curve Point" | Peak Name: "PFBS* Mass(es): "299.0/99.0 amu.299.0/80.0 amu" m Comment "* Annotation: "" sample index: 20 Sample Type: Standard Concentration: 200 . ng/mL Calculated cone: 199 . ng/mL Acq. Date: 11/22/2010 Acq. Time: 7:02:49 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan IQ/ Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: NO Int. Type: Valley Retention Time: 7.889 min Area: 24772295 counts Height: 2.14e +006 cps Start Time: 7.707 min End Time : 8.756 min Page 5 of 321 Page 190 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 191 of 962 Stan V1660305 I Sample Name: "s10i122a025" Sample ID: '10 006-25 solvent blank" Peak Name: *PFBS' Mass(es): "299.0/99.0 amu.299.0/80.0 amu" I Comment "" Annotation: "* Sample index: 2S Sample Type: Double Blank Concentration: o.oo ng/mL calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:03:42 PM File: "s101122a.wifr Modified: NO Proc. Algorithm: IntelliQuan - XQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.8S9 min Area : 1374 counts Height : 1.29e+002 cps Start Time: 7.657 End Time: a . i n min Sample Name: "s101122a027" Sample ID: "MB-101116-02 Method Blank 2 w/o IS" I Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu* Comment " * Annotation: " sample Index: 27 sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:52:08 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No int. Type : Retention Time: Area : Height : start Time: End Time: Valley 7.939 3 584 CO' 3.63e +002 7.818 8.141 Printing Time: 5:46:00 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a028" Sample ID: "MB-101116-01 Method Blank 1 w/o IS" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment "" Annotation: "" Sample Index: 26 Sample Type : Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:27:S4 PM File: ' s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Area: Height : start Time: End Time : 3 .10e+002 7.737 8.333 ( Sample Name: "s101122a028" Sample ID: "MB-101116-03 Method Blank 3 w/o IS" Peak Name: "PFBS" Mass(es): *299.0/99.0 amu.299.0/80.0 amu" Comment "" Annotation: " Sample Index: 28 Sample Type: Double Blank Concentration: 0.00 ng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 10:16:21 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type : Retention Time: Area : Height : Start Time: End Time: Valley 7.879 min 2446 COUntS 3.20e*002 cps 7.788 min 8.050 min Page 7 of 321 Page 192 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 193 of 962 Stan V1660305 Results Name: sl01122a.rdb S a m p l e N a m e : "s101122a033" S a m p l e ID: "L C S - 1 0 1 116-02 3 n g L O S in T C R-842" 1 P e a k N a m e : " P F B S " Mass(es): "299.0/99.0 a mu,299.0/80.0 a m u " 1 C o m m e n t : "* Annotation: Sample Index: 33 Sample Type : Unknown Concentration: N/A Calculated Cone: 3.06 ng/mL Acq. Date: 11/23/3010 Acq. Time: 12:17:22 AH 4.0e4 File: "s101122a.witr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: o.oo sec Smoothing width: 3 points RT window: 30.0 sec Ex p e c t e d RT: a.04 min Use Relative RT: No 3.5e4 3.0e4 Int. Type: valley Retention Time: 7.879 min Area: 469906 counts Height: 4.4le004 cps Start Time: 7.687 min End Time: 8.373 min m 2.5e4 * S 2.0e4 1.5e4 1.0*4 S a m p l e N a m e : "s101122a034" S a m p l e ID: " L C S - 101116-03 3 ng L C S in T C R - 8 4 2 " I P e a k N a m e : " P F B S " Mass(es): "299.0/99.0 amu.299.0/60.0 a m u " M C o m m e n t "" Annotation: "" Sample Index: 34 Sample Type: Unknown concentration: N/A 5.0e4- Calculated Cone: 3.42 ng/mL Acq. Date: 11/23/2010 Acq. Time: 12:41:35 AM 4 5e4 File: "s101122a.wiT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cp3 1 Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec E x p ected RT: 8.04 min Use Relative RT: No 4.0e4 3 5e4 Int. Type: Valley Retention Time: 7.889 min Area: 492881 counts Height: 5.0ie004 cos Start Time: 7.697 min End Time: 8.413 min 30e4 ,, c ic. 1 0 " 2.0e4 1.5e4 1.0e4 5000.0 5000.0 2 199 4 398 S a m p l e N a m e : "s101 1 2 2 a 0 3 5 " S a m p l e ID: "LCS-101116-04 3 0 ng L C S in T C R-842" 1 P e a k N a m e : " P F B S " Mass(es): "299.0/99.0 a mu,299.0/80.0 a m u " C o m m e n t "" Annotation: "" Sample Index: 35 Sample Type : unknown Concentration: N/A Calculated cone: 32.5 Acq. Date: 11/23/2010 ng/mL 4.0e5' 3.8e5- Acq. Time: 1:05:50 AM 3 6e5 L. . . 6 l 10 12 596 794 992 1191 Time min File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: Min. Peak width: Smoothing Width: 0.00 0.00 3 cps sec points RT Window: Ex p e c t e d RT: Use Relative RT: 3 0.0 8.04 No sec min 34e5 3.2e5 3.0e5 2 Be5 2.6e5 Int. Type: Valley Retention Time: 7.899 min Area: 4434233 counts Height: 4.02e+005 cos Start Time: 7.697 min End Time: 8.514 min 2.4e5 M S ' ZiJei> nn+c. > 1.8e5 " 1.6e5 1.4e5 1.2e5 1.0e5- 8.0e4 6.0e4 4.0e4 2.0e4 14 1389 16 1587 18 1785 _ 20 1984 22 2182 2 199 4 398 S a m p l e N a m e : "s101122a036" S a m p l e ID: "LCS-101116-05 30 ng L C S in T C R - 8 4 2 " 1 P e a k N a m e : " P F B S " Mass(es): "299.0/99.0 amu.299.0/80.0 a m u " 1 C o m m e n t "" Annotation: "" Sample Index: 36 Sample Typ e : unknown Concentration: N/A calculated Cone: 33.3 ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:30:03 AM 4.0e5- . ... 6 596 1 794 10 12 992 1191 Time, min File: "s101122a.wifT ..... 14 1389 16 1587 .. 18 1785 20 1984 | Modified: No D Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No 3.5e5 3.0eS- Int. Type: valley Retention Time: 7.S79 min Area: 4696428 counts Height: 4.40e+005 cps Start Time: 7.717 min End Time: 8.595 min ,, 2.5e5 5 5 2.0e5 " 1.5e5 1.0eS 5.0e4 22 2182 2 199 4 398 6 596 I 794 10 12 992 1191 Time, min 14 1389 16 1587 18 1785 20 1984 22 2182 ^ Printing Time: 5:46:05 PM Printing Date: Friday, January 07, 2011 2 199 4 398 6 596 5 794 10 12 992 1191 Time, min 14 1389 16 1587 18 1785 20 1984 22 2182 Page 9 of 321 3M Study GLP10-01-02 Interim Report 05 Page 194 of 962 Stan V1660305 ISample Name: "s101122a037" Sample ID: "LCS-101116-06 30 ng LCS in TCR-842" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" SamCpolmemeInntd: e""x: Annotatio3n7: "" Sample Type: Unknown Concentration : N/A Calculated Cone: 31.8 ng/mL Acg. Date: 11/23/2010 Acg. Time: 1:54:19 AM File: ' s101122a.wifr' Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height:: 0 . 0 0 CPS Min. Peak Width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.899 Area: 4608122 COUntS Height : 4.31e*005 cps Start Time 7.707 m in End Time : I Sample Name: "s101122a039" Sample ID: "GLP10-01-02-05-041 Dup DAL SS SS01 0 0000 Duplicate " Peak Name: "PFBS* Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment "" Annotation: Sample Index : 39 File: "s101122a.wifr Printing Time: 5:46:07 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: Ns101122a038" Sample ID: "GLP10-01-02-05-041 DAL SS SS01 0 0000" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" Com m ent"" Annotation:"" Sample Index: 38 Sample Type: Unknown Concentration: N/A calculated Cone: 0.977 ng/mL Acg. Date: 1 1 /2 3 /2 0 1 0 Acg. Time: 2:18:32 AM File: "s101122a.wifr Modified: No Min. PPeraokc.HeiAglhgto:rithm: InteclplsiQuan - IQA Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Area : Height : start Time: End Time: valley 7.899 139654 COi 1.37e+004 7.727 8.333 I Sample Name: "st01122a040" Sample ID: "GLP10-01-02-05-041 LMS DAL SS SS01 0 0000 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 a u,299.0/80.0 amu* Comment "" Annotation: "" Sample Index: 40 Sample Type : unknown Concentration: N/A Calculated Cone: 3.12 ng/mL Acg. Date: 11/23/2010 Acq. Time: 3:06:S7 AM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: Use Relative RT: Area: Height: Start Time: End Time : Page 10 of 321 Page 195 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 196 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 197 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 198 of 962 Stan V1660305 I Sample Name: "s101122a053" Sample ID: "GLP10-01-02-05-045 DAL SS SS03 0 0000 " Peak Name: "PFBS" Mass(es): "299.0/99 0 amu,2 99.0/80.0 amu" Comment:"" Annotation: Sample Index: 53 File: "s101122a.witr Results Name: sl01122a.rdb I Sample Name: "s101122a054" Sample ID: "GLP10-01-02-05-045 Dup DAL SS SS03 0 0000 Duplicate" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" Com m ent " Annotation:"" sample Index: 54 Sample Type: Unknown I Concentration: N/A I calculated Cone: 5.48 ng/mL B Acg. Date: 11/23/2010 B Acg. Time: 8:46:17 AM File: "s101122a.w ifr Modified: Yes Min. Peparokc.HeiAglhgto:rithm: InteclplsiQuan - IQA Min. Peak width: sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: j Area: I Height : I Start Time: j End Time: 7.78e+004 7.727 8.292 J Sample Name: "s101122a055" Sample ID: "GLP10-01-02-05-045 LMS DAL SS SS03 0 0000 Lab Matrix Spike" | Peak Name: "PFBS" Mass(es): ' 299.0/99.0 amu,299.0/80.0 amu" Comment:"" Annotation:"" Sample Index: 55 Sample Type: Unknown 7 gg Concentration: N/A Calculated Cone: 16.0 ng/mL Acg. Date: 11/23/2010 Acg. Time: 9:10:29 AM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: CpS Min. Peak Width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Area : Height : Start Time: End Time : Valley 7.879 453842 CO 2.21e+005 7.667 8.444 Printing Time: 5:46:15 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 992 1191 Time, min Sample Name: "s101122a056" Sample ID: "GLP10-01-02-05-046 DAL S S SS03 0 0 0 05 " | Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" I C omment " Annotation: Sample Index: 56 Sample Type: Unknown concentration: N/A calculated cone: 9.09 ng/mL Acq. Date: 11/23/2010 Acq. Time: 9:34:41 AM File: "s101122a.wiff Modified: No proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: sec smoothing width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: valley Retention Time: 7.879 min Area: 1275431 counts Height : 1.22e+005 cps Start Time: 7.717 min End Time : 6.333 min Page 14 of 321 Page 199 of 962 *Stan V1660305 I Sample Name: "s101122a057" Sample ID: "GLP10-01-02-05-046 Dup DAL S S S S03 0 0005 Duplicate " I Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment: "" Annotation: Sample Index: 57 Sample Type : Unknown Concentration: N/A calculated Cone: 9.83 ng/mL Acq. Date: 11/23/2010 Acq. Time: 9:58:56 AM File; 's101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan - IQt Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min use Relative RT: NO Int. Type : valley Retention Time: 7.869 min Area: 1450691 counts Height : 1.37e+005 cps Start Time : 7.727 min End Time : 8.383 min Results Name: sl01122a.rdb (Sample Name: "s101122aOS8" Sample ID: "GLP10-01-02-05-046 Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" C o m m e n t"" Annotation:"" sample Index: 58 Sample Type: Unknown concentration: n /a Calculated Cone: 17.4 ng/mL Acq. Date: 11/23/2010 Acq. Time: 10:23:13 AM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec smoothing width: points RT Window: sec Expected RT: use Relative RT: NO Int. Type: Valley Retention Time: 7.879 min Area: 2818523 counts Height : 2.55e+00S cps start Time 7.717 min End Time: 8.363 min (Sample Name: "s101122a059" Sample ID: "10 006-25 solvent blank" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" C om m ent "" Annotation: "" sam ple In d e x : 59 sam ple T yp e : Double B lan k File: "s101122a.wifT 992 1191 Time, min " TSample Name: "s1D1122a060" Sample ID: "EC-101116-06 S ng Extracted Curve Point" File: "s101122a.wifT Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" Comment Annotation: "" Sample Index: 60 Printing Time: 5:46:17 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 15 of 321 Page 200 of 962 *Stan V1660305 I Sample Name: "s101122a061" Sample ID: ` 10 006*25 solvent blank" Peak Name: "PFBS" Mass(es): '2 99 .0/9 9.0 amu,2 99.0/80.0 amu" Comment: Annotatio6n1: sam ple in d e x : Double B lan k Sample Typ e : 0.00 ng/mL Concentration: N/A Calculated Cone: 11/23/2010 Acq. Date: 11:35:55 AM Acq. Time: Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o .o o cps Min. Peak width: o . o o sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: Use Relative RT: 8.04 No min File: "s101122a.wifr Int. Type : Retention Time: Area: Height : Start Time: End Time: valley 8.191 min 1019 counts 1.40e+002 cps 8.121 8.333 min ( Sample Name: "s101122a063` Sample ID: "GLP10-01-02-5-047 Dup DAL S S SS 03 DB 0005 Duplicate " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment: "" Annotation: "" Sample Index: 63 File: Hs101122a.wtfT Results Name: sl01122a.rdb ISample Name: "s101122a062" Sample ID: "GLP10-01-02-05-047 DAL SS S S 03 D B 0 0 0 5 ' Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/80.0 amu" SamCpolmemIenndt e""x: Annotatio6n2: Sample Type: Unknown Concentration : N/A calculated Cone: 7.07 ng/mL Acq. Date: 11/23/2010 Acq. Time: 12:00:10 PM File: "s101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height:: 0.00 cps Min. Peak width: Smoothing width: RT Window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : .39e +004 7.697 8.413 Sample Name: "s101122a064` Sample ID: "GLP10-01-02-05-047 LMS DAL S S SS03 DB 0005 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" C o m m e n t"" Annotati6o4n:"" Sample Index: Unknown Sample Type: N/A Concentration: 16.1 ng/mL Calculated Cone: 11/23/2010 Acq. Date: 12:48:43 PM Acq. Time: Modified: NO Proc. Algorithm IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No File: "s101122a.w ifr Int. Type : V a lle y Retention Time 7.879 min Area: 2332578 counts Height : 2.3 2e*0 0S cps Start Time: 7.707 min End Time : 8.434 min inting Time: 5:46:19 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 16 of 321 Page 201 of 962 Stan V1660305 I Sample Name: "s101122a06S" Sample ID: "GLP10-01-02-05-048 D A LS SS04 0 00 00 " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" C o m m ent *" Annotation: " Sample Index; 65 Sample Typ e : Unknown Concentration; N/A Calculated Cone: 2.S3 ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:12:58 PM File: "s101122a.wifT Modified: Yea Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: Min. Peak width: Smoothing width: RT Window: Expected RT: Use Relative RT: HO Int. Type: valley Retention Time: 7.8B9 min Area: 443914 counts Height; 4.21e +004 cps Start Time 7.687 min End Tim e : Results Name: sl01122a.rdb I! Sample Name: "s101122a066" Sample ID: "GLP10-01-02-05-048 Dup DAL S S SS04 0 0000 Duplicate " Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/80.0 amu" C omment Annotation: "" Sample Index: 66 Sample Type: Unknown Concentration: N/A Calculated Cone: 1.83 ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:37:12 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height: 0.01 Cps Min. Peak width: 0.01 sec smoothing width: 3 points RT window; 30.0 sec Expected RT: 8.0' min Use Relative RT: No Int. Type: Valley Retention Time 7.879 min Area: 285288 Counts Height : 2 . 82e+004 Cps Start Time: 7.717 min End Time: 8.252 ISample ame: "s101122a067" Sample ID: "GLP10-01-02-05-048 LMS DAL S S SS04 0 0000 Lab MatnxSpike" Peak ame: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Commerrt:"" Annotation: "" Sample Index: Sample Type: Concentration: Unknown N/A Calculated Conc: 11/23/2010 Acq. Date: 2:01:25 PM Acq. Time: Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No File: "s101122a.wifT Int. Type: Valley Retention Time 7.879 min Area : 1866855 counts Height : 1.726+005 cps start Time 7.707 min End Time : 8.363 min I Sample Name: "s101122a068" Sample ID: "GLP10-01-02-05-049 DAL S S SS 04 0 0 005 " File: "s101122a.wifT Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" I Comment Annotation: *" Printing Time: 5:46:21 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Page 17 of 321 Page 202 of 962 Stan VT660305 I Sample Name: "s101122a069" Sample ID: "GLP10-01-02-05-049 Dup DAL SS S S04 0 0 0 05 Duplicate " Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" I Comment: Annotation: " sa m p le In d e x : 69 S am p le T y p e : U nknow n C o n ce n tra tio n : N/A c a lc u la te d co ne: 0.891 I A cq . D ate: 11/23/2010 A c g . T im e : 2:49:50 PM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.889 min Area : 154762 counts Height : 1.50e+004 cps start Time: 7.737 min End Time : 8.161 min I Sample Name: "s101122a071" Sample ID: "G LP10-01-02-05-050 DAL SS TRIP1 0 0 0 0 0 " Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu* Comment: - Annotation:"" Sample Index: 71 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.0959 ng/mL Acq. Date: 11/23/2010 Acq. Time: 3:38:22 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: o.oo sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type : Retention Time: Area : Height : Start Time: Valley 7.879 min 24884 counts 2.4Be+003 cps 7.748 min End Time : 8.282 min Printing Time: 5:46:23 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb (Sample Name: "s101122a07Cr Sample ID: "GLP10-01-02-05-049 LMS DAL S S SS04 0 0005 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" C omment "" Annotation: Sample Index: 70 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.22 ng/mL Acq. Date: 11/23/2010 Acq. Time: 3:14:05 PM File: "s101122a.wifT Modified: No MPirno.c. PAelagkorHietihgmht:: Intoe.loloiQuancps- IQA Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 Use Relative RT: No Area: Height : start Time: End Time : 489148 counts 4.63e*004 CpS 7.717 min 8.333 min I Sample Name: "s101122a072" Sample ID: "GLP10-01-02-05-050 Dup DAL SS TRIP1 0 0000 Duplicate" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment Annotation: Sample Index: 72 Sample Type: Unknown Concentration : N/A Calculated Cone: 0.103 ng/mL Acq. Date: 11/23/2010 Acg. Time: 4:02:36 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 6.04 min Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time : Valley 7.879 min 23444 counts 2.14e+003 cps 7.707 8.141 min Page 18 of 321 Page 203 of 962 Stan V1660305 I Sample Name: "s101122a073" Sample ID: "GLP10-01-02-05-050 LMS DAL S S TRIP1 0 0 0 0 0 Lab Matrix Spike" I Peak Name: "PFBS' Mass(es): *299.0/99.0 amu,2 99.0/80.0 amu* Comment: "* Annotation: "* Sample Index: 73 Sample Type: Unknown Concentration: N/A calculated Cone: 2.09 ng/mL Acq. Date: 11/23/2010 Acq. Time: 4:26:49 PM File: "s101122a.witr Modified: NO Proc. Algorithm: IntelliQuan IQ/ Min. Peak Height : 0.00 Cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: NO Int. Type: Valley Retention Time: 7.869 min Area: 343361 counts Height : 3.19e+004 cps start Time: 7.667 min End Time : ` 8.292 min Results Name: sl01122a.rdb I Sample Name: *s101122a074* Sample ID: "GLP10-01-02-05-051 DAL SS SS05 0 0000 " Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" C om m ent ** Annotation: "* Sample Index: 74 File: "s101122a.wifT T Sample Name: *s101122a075* Sample ID: *GLP1CW)1-O2-0$-OS1 Dup DAL S S S S 05 0 0000 Duplicate ' Peak Name: 'P F B S * Mass(es): "299.0/99.0 am u,299.0/80.0 amu* Comment: "" Annotation: "" Sample Index: 7S Sample Type: Unknown Concentration: N/A calculated Cone: 18.2 ng/mL Acq. Date: 11/23/2010 Acq. Time: 5:15:19 PH File: "s101122a.witr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Area: Height : Start Time: End Time: Valley 7.879 15982 col :.30e*oo5 7.717 8.888 ( Sample Name: "s101122a076* Sample ID: "GLP10-01-02-05-051 LMS DAL SS SSOS 0 0000 Lab Matrix Spike" Peak Name: ' PFBS' Mass(es): "299.0/99.0 amu,299.0/80.0 amu* C omment Annotation: Sample index: 76 Sample Type: Unknown Concentration: N/A Calculated Cone: 69.1 ng/mL Acq. Date: 11/23/2010 Acq. Time: 5:39:33 PM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley ARreetae:ntion Time:96269671.889 coumnitsn Height : 8 .S3e*00S cps Start Time: Bnd Time: Printing Time: 5:46:25 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 19 of 321 Page 204 of 962 *Stan V1660305 Results Name: sl01122a.rdb Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 205 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 206 of 962 Stan V1660305 I Sample Name: "s101122a085" Sample IO: "GLP10-01-02-05-054 LMS DAL S Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment: "" Annotation;"" Sample Index: 85 Sample Typ e : Unknown Concentration: ' N/A Calculated cone: 3.44 ng/mL Acq. Date: 11/23/2010 Acq. Time: 9:17:56 PM Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: points RT Window: 30.0 sec Expected RT: e .04 min Use Relative RT: In t. Type: Valley R e te n t io n T im e : 7.879 min A rea : 530649 COUntS H e ig h t : 5.07e+004 cps S t a r t T im e : 7.627 min End T im e : 8.312 min 6 0 0 000 Lab Matrix Spike" File: "s101122a.wifr I Sample Name: "s101122a087" Sample ID: "GLP10-01-02-OS-055 Dup DAL S S SS06 0 0005 Duplicate ' Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu* Comment: Annotation: "" Sample Index: 87 File: "s101122a.wifr Results Name: sl01122a.rdb ISample Name: "s101122a086" Sample ID: "GLP10-01-02-05-055 DAL SS SS06 0 0005 " Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" C om m ent "" Annotation: "" sample Index: 86 Sample Type: Unknown concentration: Calculated cone: N/A 0.469 ng/mL 8000 Acq. Date: Acq. Time: 11/23/2010 9:42:11 PM 7500 File: "s101122a.wifT Modified: Yes Proc. Algorithm- IntelliQuan - IQA Min. Peak Height : 0.00 cps M i n . Peak width 0.00 sec Smoothing width 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: NO 7000 6500 6000 5500 Int. Type: Retention Time: Area: Height: start Time: Valley 7.899 min 78960 counts 8 .02e+003 cps 7.748 min 5000 * 4500 g- 4000 % 3500 3000 2500 2000 1500 1000 500 0 2 W.piU 66 10 12 14 16 18 20 22 199 596 794 992 1191 1389 1567 1785 1984 2182 ________________________ Time, min________________________________________________ (Sample Name: "s101122a088" Sample ID: "GLP10-01-02-05-055 LMS DAL SS S S06 0 0005 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99,0 am u.299.0/80.0 amu" Comment "" Annotation: "" File: *s101122a.w ifr Sample Index: 88 Sample Type: Unknown concentration: N/A calculated Cone: 2.79 ng/mt Acq. Date: 11/23/2010 Acq. Time: 10:30:39 PM Modified: NO Proc. Algorithm: IntelliQuan - Iq Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.899 min Area: 394544 counts Height: 3.4 6e+004 cps Start Time: 7.717 min End Time: 8.252 min Printing Time: 5:46:31 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 22 of 321 Page 207 of 962 Stan V1660305 Sample Name: "s10 1 122a089" Sample ID: GLP10-01-02-05-056 DAL SS SS 06 DB 0 005 " Peak Name: "PFBS" Mass(es): "299.0/99.0 ,299.0/80.0 amu" Comment: "" Annotation: "" Sample Index: 89 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.564 ng/mL Acq. Date: n/23/2010 Acq. Time: 10:54:53 PM File: "s 1 0l12 2a .w itr Modified: No Proc. Algorithm: IntelliOuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0sec Expected RT: 8.04 min Use Relative RT: No int. Type: Retention Time Area: Height : Start Time: End Time: Valley 7.879 min 92525 counts 8.90e+003 cps 7.727 8.292 min TMSample Name: ns101122a091" Sample ID: 'GLP10-01-02-05-056 IM S DAL S i SS06 DB 0005 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u,299.0/80.0 amu" Comment: Annotation: "" Sample index: 91 Sample Type: Unknown concentration: n /a calculated Cone: 2.72 ng/mL Acq. Date: 11/23/2010 Acq. Time: 11:43:23 PM File: "s101122a.w ifr Modified: No Proc. Algorithm: IntelliOuan - IQ; Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: min Uae Relative RT: Area : Height : Start Time: End Time: min 390834 counts 3.30e*004 cps 7.737 min 8.242 min Results Name: slOH22a.rdb Sample Name: *s101122a090" Sample ID: "GLP10-01-02- Peak Name: "PFBS Massfes) "299.0/99.0 amu,299.0/80 1 Comment "" Annotation: "" sample Index: 90 sample Type: Unknown concentration: N/A Calculated cone: 0. S3 7 ng/mL Acq. Date: 11/23/2010 Acq. Time: 11:19:08 PM 8000 Modified: NO Proc. Algorithm: IntelliOuan - IQA Min. Peak Height 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec 6500 Expected RT: Use Relative RT: 8.04 min No 6000 5500 Int. Type: Valley Retention Time: 7.889 min Area: 86709 counts 5000 Height: 8 .eoe+003 cps 4500 start Time: 7.687 min End Time : 8.181 min 4000 File: "s101122a.witT 3500 3000 2500 2000 1500 1000 500 0 199 HSample Name: "s101122a092" Sample ID: "G LP10-01-02-05457 DAL S : SS07 0 0000 " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment "" Annotation: "" Sample index: 92 8 10 12 14 16 18 20 22 794 992 1191 1369 1587 1785 1984 2182 _____________ Tim e, min_______________________________________________ File: "s101122a.wifT Printing Time: 5:46:34 Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 23 of 321 Page 208 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Date Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 209 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:46:38 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 25 of 321 Page 210 of 962 *Stan V1660305 I Sample Name: " s 1 01 12 2a 10 r Sample ID: "GLP10-01-02-05-059 DAL S S S Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" I Comment: "" Annotation: "" Sample Index 101 sample Typ e : Unknown Concentration: N/A Calculated Cone: 2.24 i Acq. Date: 11/24/2010 Acq. Time: 3 :4S :57 AM 800000" File: "s101122a.w ifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: min Use Relative RT: Area: Height: Start T ime: End Time: Valley 7 .6 8 9 3 3 2 6 3 4 CO' 3 .3 2e*004 7 .7 1 7 6 .3 2 3 Results Name: sl01122a.rdb I Sample Name: "s101122a102" Sample ID: "GLP10-01-02-05-059 Dup DAL S S SS08 0 0 000 Duplicate " Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" I Comment Annotation: "" Sample Index: 102 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.01 I Acq. Date: 11/24/2010 Acq. Time: 4:10:13 AM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: Valley Retention Time: 7.889 min Area: 311559 counts Height : 2.93e+004 cps start Time: 7.727 min End Time: a.323 min Sample Name: "s101122a103" Sample ID: "GLP10-01-02-05-059 LMS DAL S S S S 08 0 0000 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" Com m ent *" Annotation:"" . Sample Index: 103 File: "s101122a.wifT I Sample Name: "s101122a104" Sample ID: "GLP10-01-02-05-060 DAL SS S S 08 DB 0000" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/80.0 amu" Comment Annotation:"" Sample Index: 104 Sample Type: Unknown Concentration: N/A Calculated Cone: 1.69 ng Acq. Date: 11/24/2010 Acq. Time: 4:58:45 AM Modified: NO Proc. Algorithm: IntelliOuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 6.04 min Use Relative RT: No File: "s101122a.wifT Int. Type: Valley Retention Time: 7.879 Area: 255480 counts Height: 2.42e +004 CpS Start Time 7-727 min B End Time: 8.252 min Printing Time: 5:46:40 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 26 of 321 Page 211 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 212 of 962 *Stan V1660305 I Sample Name: "s101122a109* Sample ID: "GLP10-01-02-05-061 LMS DAL SS SS08 0 0005 Lab Matrix Spike* Peak Name: *PFBS" Mass(es): *299.0/99.0 am u.299.0/80.0 amu* I Comment " Sample Index: 109 Sample Type: Unknown Concentration: N/A Calculated Cone: 12.1 ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:00:00 AM File: *s101122a.w ifT Modified: NO Proc. Algorithm: IntelliQuan - i q a Min. Peak Height:: 0.00 CpS Min. Peak width: o.oo sec Smoothing width: 3 points RT Window : 30.0 sec Expected RT: 8.04 min use Relative RT: NO Int. Type: Retention Time Valley 7.889 mm Area: 1770590 coluunntts Height : 1.73e+OOS cps Start Time: 7.707 End Time : 8.393 min Results Name: sl01122a.rdb I Sample Name: *s101122a110" Sample ID: "GLP10-01-02-05-062 DAL SS S S 09 0 0000 * Peak Name: ` PFBS* Mass(es): "299.0/99.0 amu,299.0/80.0 amu* C omment Annotation: Sample Index: no File: *s101122a.w ifr Sample Name: *s101122a111* Sample ID: "GLP10-01-02-05-062 Dup DAL S S S S09 0 0000 Duplicate ' I Peak Name: ' PFBS* Mass(es): *299.0/99.0 am u.299.0/80,0 amu" I Comment: - Annotation: *" Sample Index: ill Sample Type: Unknown Concentration: N/A Calculated cone: l.Sl ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:48:24 AM File: "s101122a.wrfT Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height: o.oo Min. Peak width: o.oo cps sec smoothing width: : points RT Window: sec Expected RT: min use Relative RT: Area: Height : Start Time: End Time : 2.07e+004 7.707 8.292 I Sample Name: "s101122a112" Sample ID: "GLP10-01-02-05-062 LMS DAL SS SS09 0 0000 Lab Matrix Spike' Peak Name: "PFBS" Mass(es): *299.0/99.0 am u.299.0/80.0 amu" I Comment ** Annotation: . sample Index: 112 Sample Type: Unknown Concentration : N/A Calculated Cone: 11.9 ng/mL Acq. Date: 11/24/2010 Acq. Time: 8:12:38 AM File: "s101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: NO Area: Height: Start Time: End Time: 1 .7le*005 7.727 8.343 Printing Time: 5:46:43 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Page 28 of 321 Page 213 of 962 Stan V1660305 I Sample Name: "s101122a113" Sample ID: "10 006-25 solvent blank" Peak Name: "PFBS" Mass(es): "299 0/99.0 am u.299.0/80.0 amu" Comment:"" Annotation:"" Sample Index: 113 CSoanmcpelnetrTytpei:on : Doubol.eooBlankng/raL calculated cone: N/A Acg. Date: 11/24/2010 Acq. Time: 8:36:53 AM File: "s101122a.witf Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 7.990 min 337 counts ..24e+002 cps 7.959 min 8.091 min Sarmr ple Name: "s101122a115" Sample ID: "10 006-25 solvent blank" Peaalk Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/60.0 amu' I Comn ment: *" Annotation: "" Sample Index: 115 Sample Type: Double Blan) Concentration: 0.00 r Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 9:25:25 AM FUe: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height : start Time: End Time: Valley 7.980 min 511 counts l . 3 B e + 0 0 2 cps 7.899 8.050 Printing Time: 5:46:45 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ISample Name: "s101122a114" Sample ID: "EC-101116-06 5 ng Extracted Curve Point" Peak Name: "PFBS" Mass(es): "299.0/99.0 am u.299.0/60.0 amu" SamCpolmemIenndt ex: Annotat1io1n4: Sample Type: QC Concentration: 5.00 ng/mL Calculated Cone: 5.16 ng/mL Acq. Date: 11/24/2010 Acq. Time : 9:01:07 AM File: "s101122a.w iff Modified: No Proc. Algorithm: IntelliQuan - IQ< Min. Peak Height : 0.00 cps Min. Peak Width: .00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: .04 min Use Relative RT: NO Int. Type : Valley Retention Time: 7 879 min Area: 7S8074 counts Height : 6 ,40e*004 cps Start Time: 7.596 min End Time: 8.413 min I Sample Name: "s101122a116" Sample ID: "GLP10-01-02-05-063 DAL SS S S 09 0 0005 " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,2 99.0/80.0 amu" I C omment " Annotation: *" Sample Index: 116 Sample Type: Unknown Concentration : N/A Calculated Cone: 1.36 ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:49:42 AM File: "s101122a.w iff Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: valley Retention Time: 7.889 min Area : 209359 counts Height : 1.93e*004 cps Start Time: 7.707 min End Time : 8.191 min Page 29 of 321 Page 214 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 215 of 962 Stan VT660305 I Sample Name: "s101122a121" Sample ID: " G IP 10-01-02-05-064 LMS D A LS S GP01 0 0000 Lab Matrix Spike' Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/60.0 amu" . Comment: "" Annotation: *" Sample Index: 121 ' Sample Type: Unknown Concentration: N/A Calculated Cone: 16.7 ng/mL Acq. Date: 11/24/2010 Acq. Time: 11:50:56 AM File: ' $101122a.wifr Modified: No Min. PeParkoc.HeiAglhgto:rithm: InteclplsiQuan - IQA Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: NO Int. Type : Valley Retention Time 7.889 min Area: 2291660 counts Height : 2.06e+005 cps Start Time: 7.606 min End Time : 8.323 min Results Name: sl01122a.rdb I Sample Name: "s101122a122* Sample ID: "GLP10-01-02-05-065 DAL SS GP01 0 0005 " Peak Name: *PFBS* Mass(es): "299.0/99.0 am u.299.0/60.0 amu" 1 Comment "" Annotation: *" Sample Index: 122 Sample Type: Unknown Concentration : N/A Calculated Cone: 7.61 ng/mL Acq. Date: 11/24/2010 Acq. Time: 12 :15:12 PM File: "s101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan IQ/ Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window : 30.0 sec Expected RT: 8.04 min Use Relative RT: NO Int. Type : Valley Retention Time: 7.869 min Area: 919140 counts Height : 8.73e-t-004 cps Start Time: 7.727 min End Time: 8.333 min Sample Name: "s101122a123N Sample ID: 'G LP10-01-02-05-065 Dup DAL SS GP01 0 0 005 Duplicate ' Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/80.0 amu" I Comment: "" Annotation: - Sample Index: 123 Sample Type: Unknown Concentration: N/A Calculated Cone: 6.91 ng/mx. Acq. Date: Acq. Time: File: "s101122a.witr Modified: Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: Smoothing width: RT Window: Expected RT: use Relative RT: Area: Height : start Time: End Time: counts 8.60e+004 cps 7.707 8.635 Printing Time: 5:46:49 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 I Sample Name: "s101122a124" Sample ID: "GLP10-01-02-05-065 LMS DAL S : GP01 0 0005 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/80.0 amu" I Com m ent " Annotation: "" Sample Index: 124 Sample Type: Unknown Concentration: N/A Calculated Cone: 19.7 i Acq. Date: 11/24/2010 Acq. Time: 1:03:43 PM File: "s101122a.w ifr Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height: o.oo cps Min. Peak width: o .oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.879 Area: 2493419 counts Height : 2.3 8e +00 5 cps Start Time 7.717 min End Time: B.3B3 min 8.0e4 6.0e4 4.0e4 2.0e4 Page 31 of 321 992 1191 _____ Time, min 20 1964 22 2182 Page 216 of 962 *Stan V1660305 I Sample Name: "s10H22a125" Sample ID: "GLP10-01-02-05-066 DALS ! GP01 00020" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/B0.0 amu" Comment:"" Annotation:"" Sample Index: 125 Sample Type: Unknown Concentration: N/A Calculated cone: 4.66 ng/mL Acq. Date: 1 1 /24/2010 Acq. Time: 1:28:03 PM File: "s101122a.wiff' Modified: ?es Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: ; points RT Window: 30.0 sec Expected RT: 6.04 min Use Relative RT: No Int. Type: valley Retention Time 7.869 min Area : 641574 counts Height : 5.87e+004 CpS start Time : 7.727 min End Time : 8.635 min T Sample Name: "s101122a127" Sample ID: "GLP10-01-02-05-06 Peak Name: "PFBS* Mass(es): "299.0/99.0 amu.299.0/80.0 amu' Comment: *" Annotation: "" Sample Index: 12? Sample Type : Unknown concentration : Calculated cone: N/A IS.4 ng/mL 2.0e5 Acq. Date: Acq. Time: 11/24/2010 2:16:39 PM 1.9e5 Modified : NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: .04 min Use Relative RT: NO 1.8e5 1.7e51.6e5 1.5e5 1.4e5 1.3e5 Int. Type: Valley Retention Time: 7.879 min Area: 2086188 counts Height : 2.06e+00S cps start Time: 7.707 min End Time : 8.323 "i" 1.2e5 1.1e5 1.0e5 1 9.0e4 8.0e4 7.0e4 6.0e4- 5.0e4- 4.0e4- 3.0e4- 2.0e4- 1.0e4- 0.0^ Printing Time: 5:46:51 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 992 1191 Time, min Results Name: sl01122a.rdb [Sample Name: "s101122a126" Sample ID: "GLP10-01-02-05-066 Dup DAL S IGP01 0 0020 Duplicate " Peak Name: "PFBS" Mass(es): ''299.0/99.0 amu,299.0/80.0 amu" SamCpolmemIenndt e""x: Annotat1io2n6: "" Sample Type: Unknown Concentration: N/A Calculated Cone: 4.24 ng/mL Acq. Date: 1 1 /24/2010 Acq. Time: 1:52:20 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT window: sec Expected RT: min Use Relative RT: NO Int. Type : valley ' Retention Time: 7.889 min Area: 685849 counts Height : 6 .S6e*004 Cps start Time: 7.717 min End Time: 8.353 min Sample Name: "s101122a128" Sample ID: "GLP10-01-02-05-067 DAL SS GP01 0 0060" Peak Name: "PFBS" Mass(es): *299.0/99.0 amu.299.0/80.0 amu" Comment "* Annotation: "" Sample Index: 128 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.11 ng/mL Acq. Date: 11/24/2010 Acq. Time: 2:40:57 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan ` Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: Valley Retention Time: 7.899 Area: 283528 counts Height: 2 .SSe *004 cps start Time 7.737 min End Time : 8.222 Page 32 of 321 Page 217 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:46:53 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 33 of 321 Page 218 of 962 *Stan V1660305 [S a m p le Name: "s101122a133" Sam ple ID: ` 10 0 06-25 solvent blank" P eak N a m e :' PFBS' M ass(es): "299.0/99.0 amu,299.0/BO.O am u" I Comment: " * Annotation: "" Sample Index 133 Sample Type: Double Blank Concentration : 0.00 ng/mli Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:42:25 PM File: "s101122a.w rff' Modified; No Proc. Algorithm; IntelliQuan Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: min Uae Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 7.879 min 30110 counts 2.96e+003 cps 7.697 min 8.222 min ISample Name: "s101122a135* Sample ID: "GLP10-01-02-05-068 Dup DAL SS GP02 0 0000 Duplicate " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu' Comment "" Annotation: "" Sample Index: 135 Sample Type: Unknown concentration: N/A Calculated Cone: 1.96 ng/mL Acq. Date: 1 1 /24/2010 Acq. Time: 5:31:02 PM File: "s101122a.wiT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: Valley Retention Time: 7.879 min Area: 305406 counts Height : 2.61e+004 cps Start Time : 7.717 min End Time : 8.353 min Printing Time: 5:46:55 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ( Sample Name: "*101122a134" Sample ID: "GLP10-01-02-05-068 DAL SS GP02 0 0000 " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu* Com m ent"" Annotation: "" Sample Index: 134 sample Type: Concentration: Calculated cone: Acq. Date: Acq. Time: File: "s101122a.wifT Modified: Proc. Algorithm: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: Expected RT: use Relative RT: Int. Type: Retention Time: Area: 26 Height: 2 Start Time: End Time: ( Sample Name: "s101122a136" Sample ID: "GLP10-01-02-05-068 LMS DAL SS GP02 0 0000 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" Comment "" Annotation: "" Sample Index: 136 Sample Type: Unknown Concentration : n /a Calculated Cone: 12.1 m Acq. Date: 1 1 /24/2010 Acq. Time: S:5S:17 PM File: "s101122a.wifr * Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: 0. 00 cpi Min. Peak width: Smoothing width: RT window : Expected RT: use Relative RT: 0. 00 poseiints 30.0 sec 8.04 min No Int. Type : Valley Retention Time: 7.889 min Area: 1700939 counts Height : l.62e+00S cps start Time: 7.697 min End Time : 8.413 min Page 34 of 321 Page 219 of 962 Stan V1660305 I Sam ple N am e: "s101122a137~ Sam ple ID: "G LP10-01-02-05-069 DAL S S G P02 0 0 005 ' Peak Name: "P F BS" Mass(es): "299.0/99 0 amu,2 99.0/80.0 am u" I C om m ent " Annotation: " Sample Index: 137 Sample Type: Unknown Concentration : N/A calculated cone: 0 .7 1 S T Acq. Date: 11/2 4/2 01 0 Acq. Time: 6 : 1 9 : 3 4 PM File: "s101122a.wtfT Modified: No Proc. Algorithm: IntelliOuan IQA Min. Peak Height: cpa Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: Area: Height : Start Time: End Time : Valley 7.889 114726 CO 1.13e+004 cps 7.727 8.272 min Results Name: sl01122a.rdb ISample Name: "s101122a138" Sample ID: "GLP10-01-02-05-069 Dup DAL SS GP02 0 0005 Duplicate " Peak Name: "PFBS" Mass(es): ' 299 0/99.0 amu.299.0/80.0 amu" Comment"* Annotation:" Sample Index: 138 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.922 ng/mL Acq. Date: 11/24/2010 Acq. Time: 6:43:52 PM File: Hs101122a.wifr Modified : NO Proc. Algorithm: IntelliQuan - IQ/ Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: NO Int. Type : Valley Retention Time: 7.879 min Area: 146S99 counts Height : 1 ,46e+004 cps start Time: 7.717 min End Time: 8.191 min Sample Name: "s101122a139" Sample ID: ' GLP10-01-02-05-069 LMS DAL SS GP02 0 0005 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" I Comment: " Annotation: "" Sample Index: 139 Sample Type: Unknown concentrt ion: N/A Calculated cone: 2.92 ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:08:06 PM File: ' s101122a.wifr Modified: NO Proc. Algorithm: IntelliOuan - IQA Min. Peak Height : 0.00 CpS Min. Peak Width: o.oo sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: Area : Height : Start Time : End Time : .296+004 CpS 7.717 min 8.373 min I Sample Name: "s101122a140" Sample ID: "GLP10-01-02-05-070 DAL SS GP02 0 0020 Peak Name: ' PFBS' Mass(es): "299.0/99.0 amu,299.0/80.0 amu' Comment ~ Annotation:" sample Index: 140 Sample Type: Unknown Concentration: N/A calculated cone: 0.389 ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:32:21 PM File: "s101122a.wifT Modified: No MPirno.c. PAelagkorHietihghmt:: IntelliOuancps- IQA Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: valley 7.889 min 6S466 counts s .sse+0 03 cps 7.717 min 8.282 min Printing Time: 5:46:57 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 35 of 321 Page 220 of 962 Stan V1660305 Results Name: sl01122a.rdb I Sample Name: Hs101122a141N Sample ID: "GLP10-01-02-05-070 Dup DAL SS GP02 0 0020 Duplicate ' Peak Name: ' PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu' Comment: "" Annotation:~ Sample Index; 141 CSoanmcpelentrTyptei:on : UnknNo/wAn 7 sq calculated Cone: 0.491 ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:56:39 PM File: "s101122a.witr Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak Width: .00 sec Smoothing width. 3 points RT Window: 30.0 sec Expected RT: .04 min Use Relative r t NO 5500 4500 int. Type : Valley Retention Time: 7.889 min Area: 74589 counts Height : 6.88e+003 cps start Time: 7.727 min End Time: 8.302 min g3500 1 3000 2500 2000 1500 1000 500 6.69 06 596 I Sample Name: "s101122a143" Sample ID: "GLP10-01-02-05-071 DAL SS GP02 DB 0020 " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" I Comment "" Annotation: - Sample Index: 143 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.560 ! Acq. Date: 11/24/2010 Acq. Time: 8:45:11 PM 8 10 12 794 992 1191 Time, min File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: Int. Type: Valley Retention Time: 7.889 min Area: 81365 counts Height: 7.34e+003 Cps start Time: 7.727 rain End Time: 8.272 min 14 1389 16 1587 18 1765 20 1984 22 218: I Sample Name: "s11122a142" Sample ID: "GLP10-01-02-05-070 IM S DAL SS GP02 0 0020 Lab Matrix Spike* Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" I Comment "" Annotation: "" sample index: 142 Sample Type: Unknown Concentration : n /a Calculated Cone: 2.57 ng/mL Acq. Date: 11/24/2010 Acq. Time: 8:20:56 PM File: "s101122a.wifT Modified: No Proc. Algorithm: mtelliQuan - IQA Min. Peak Height: Min. Peak Width: o.oo o.oo cps sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: valley Retention Time: 7.879 min Area: 345679 coiuunntts Height: 3 .03e*004 cps Start Time: 7.717 End Time: 8.423 min I Sample Name: "s101122a144" Sample ID: "GLP10-01-02-05-071 Dup DAL S ; GP02 DB 0020 Duplicate" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/60.0 amu" Comment "* Annotation: "" Sample Index: 144 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.679 ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:09:27 PM File: "s101122a.w i r Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0o..0o0o Min. Peak Width: 3 Smoothing Width: 30.0 RT Window: cspesc points sec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 7.899 min 98596 counts 9.3 8e+003 cps 7.737 min 8.353 min Printing Time: 5:46:59 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 36 of 321 Page 221 of 962 Stan V1660305 Results Name: sl01122a.rdb S a m p l e N a m e : "s101122a145" Sam p l e ID: "GLP10-01-02-05-071 L M S D A L S S G P 0 2 D B 0 0 2 0 L a b Matrix Spike" P e a k N a m e : " P F B S " Mass(es): "299.0/99.0 amu,299.0/80.0 a m u " 1 Comment: Annotation: "* Sample Index: 14S Sample Type: Unknown concentration: N/A 3.6e4- Calculated Cone: 2.79 ng/mL Acq. Date: 11/24/2010 3.4e4- Acq. Time: 9:33:50 PM 3.2e4 File: ,,s101122a.wtff Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Exp e c t e d RT: U s e Relative RT: 8.04 No min '" _. . 94*4 Int. Type: Valley Retention Time: 7 .889 min Area: 377679 counts Height: 3 . 59e+oo4 cps start Time: 7.717 min End Time: 8.413 min 2.2e4 20e4 g>; 1 Se4 * 0 1.6e4 S a m p l e N a m e : "s101122a146* S a m p l e ID: " G L P 1 0-01-02-05-072 D A L S S G P 0 2 0 0 1 2 0 " 1 P e a k N a m e : "P F B S " Mass(es): "299.0/99.0 a m u , 299.0/60.0 a m u " C o m m e n t "* Annotation; "" Sample Index: 146 Sample Type: Concentration: Unknown N/A Calculated cone: 2.09 ng/mL 2.6e4 Acq. Date: 1 1 /24/2010 Acq. Time: 9:58:07 PM File: "s101122a.wifT BM o d i f i e d : No B Proc. Algorithm: IntelliQuan - IQA B Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec E x p ected RT: 8.04 min Use Relative RT: No 22e4- 2.0e41 6e4 Int. Type: . Valley Retention Time: 7.889 min Area: Height: 26 84 71 c o u n t s 2.67e*004 cps Start Time: 7.73 7 min End Time: 8.323 min 1.6e4 ,, < 4 - 4 <' '5 0 1.2e4 1.2e4 1,0e4 6000.0 6000.0 4000.0 6.71 L . AI . 0.0 2 4 8 199 398 596 794 S a m p l e N a m e : "s 1 0 1 122a147" Sample ID: "GLP10-01-02-05-072 D u p D A L S S G P 0 2 0 0 1 2 0 Duplicate " 1 P e a k N a m e : " P F B S " Mass(es): "299.0/99.0 amu.299.0/80.0 a m u " C o m m e n t : "* Annotation: "* Sample Index: 147 Sample Type: Unknown Concentration: n /a 3.2e4 calculated Cone: 3.01 ng/mL Acq. Date: 11/24/2010 3,0e4 Acq. Time: 10:22:25 PM 10 12 992 1191 Time, min 14 1389 File: "s101122a.wiT Modified: No Proc. Algorithm: IntelliQuan * IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec E x p e c t e d RT: 8.04 min U s e Relative RT: No 2.8e4 26e4 _. . ' 2.2e4 2.0e4 Int. Type: Valley Retention Time: 7.899 min Area: 355009 counts Height: 3. l S e + 0 0 4 cps Start Time: 7.697 min End Time: 8.212 min ,, 1.8e4 0 <, 1 6e4 m 1 4e4 -- 1.2e4 1.0e4 6000.0- 16 1587 18 1785 20.91 20 1984 22 2182 1 . , . . .............r................................... .......... . 0.0 2 4 8 10 12 14 16 18 2 0 22 199 396 596 794 992 1191 1389 1587 1785 1984 2182 Time, min S a m p l e N a m e : "s101122a148" S a m p l e ID: "GLP10-01-02-05-072 L M S D A L S S G P 0 2 0 0 1 2 0 L a b Matrix Spike" File: "s 101122a.wifT 1 P e a k N a m e : "P F B S " Mass(es): "299.0/99.0 amu.299.0/80.0 a m u " C o m m e n t "" Annotation: "" Sample Index: 148 Sample Type: Unknown Concentration: N/A Calculated Cone: 4.53 ng/mL Acq. Date: Acq. Time: 11/24/2010 10:46:43 PM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: RT window: 3 30.0 points sec E x p ected RT: 8.04 min Use Relative RT: No Int. Type: valley Retention Time: 7.899 min Area: 501236 counts Height: 4 .8 9 e * 0 04 c p s Start Time: 7.737 min End Time: 8.544 min 40e4- 3.5e4- 3.0e4H w g- 2.5e4'5 0 " 2.0e4- 1.5e4- 4000.0 2000.0 2 199 4 398 Printing Time: 5:47:01 PM Printing Date: Friday, January 07, 2011 16.71 6 596 l 794 10 12 992 1191 Time, min 14 1369 16 1567 18 1785 20 1984 22 2182 3M Study GLP10-01-02 Interim Report 05 5000.0 2 199 4 398 6 596 5 794 10 12 992 1191 Time, min 14 1389 16 1587 18 1765 20 1984 22 2182 Page 37 of 321 Page 222 of 962 Stan V1660305 I Sam ple N a m e :' s101122a149* Sample ID: *10 0 06-25 s olvent blank" Peak N a m e :' PFBS' Wass(es): *299.0/99.0 amu,299.0/80.0 am u" I Com m ent: ~ Annotation: "" sample Index: 149 sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acg. Date: 11/24/2010 Acq. Time: 11:10 :SS PM File; " s 1 0 1 1 2 2 a .w tr Modified: NO I Sample Name: "s101122a151' Sample ID: ' 10 00&-25 solvent blank" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" C o m m e n tA n n o ta tio n : "" Sample Index: isi Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 11:59:32 PM File: "s101122a.wifr Modified: No MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- IQJ Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: Use Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: valley 7.610 min 1263 counts 1.27e +00 2 cps 7.737 min a .091 min Printing Time: 5:47:03 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sample Name: "s101122a150" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Poinf Peak Name: ' PFBS" Mass(es): ' 299.0/99.0 amu.299.0/e0.0 amu" Comment " Annotation: "" Sample Index: ISO Sample Type: QC Concentration: 2.50 ng/mL Calculated Cone: 2.71 ng/mL Acq. Date: 1 1 /24/2010 Acq. Time: 11:35:16 PM File: "s 101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk wHieditghh:t No cps sec Smoothing width: points RT window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : 9 min counts .54e+004 cps 7.737 min 8.333 min I Sample Name: "s101122al52" Sample ID: "GLP10-01-02-05-073 DAL SS GP03 0 0000' Peak Name: ' PFBS' Mass(es): *299.0/99.0 amu.299.0/80.0 amu' Comment " Annotation:"" Sample Index: 152 File: "s101122a.wifT Page 38 of 321 Page 223 of 962 *Stan V1660305 Results Name: sl01122a.rdb Printing Date Friday, January 07 2011 3M Study GLP10-01-02 Interim Report 05 Page 224 of 962 Stan V1660305 I Sample Name: "s101122a157" Sample ID: ''GLP10-01-02-0S-074 LMS DAL SS GP3 0 0005 Lab Matrix Spike" Peak Name: "PFBS* Mass(es): ''299.0/99.0 amu.299.0/80.0 amu" I Comment:"- ' Sample Index: 157 sample Type: Unknown Concentration: N/A calculated cone: 88.0 i Acq. Date: 11/25/2010 Acq. Time: 2:25:24 AM File: "s101122a.wiff Modified: Proc. Algorithm: IntelliQuan - IQA Min. Peak Height 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: valley Retention Time 7.869 min Area: 11923849 counts Height : 9.89e+005 Cps start Time : 7.717 min End Time: 8.544 min Results Name: sl01122a.rdb I Sample Name: "s101122a158" Sample ID: "GLP10-01-02-05-07S DAL SS GP03 0 0020" Peak Name: "PFBS" Mass(es): *299.0/99.0 amu.299.0/80.0 amu" C o m m e n tA n n o ta tio n : *" Sample Index: 158 Sample Type: Unknown Concentration: N/A Calculated Cone: 53.2 ng/mL Acq. Date: 1 1 /25/2010 Acq. Time: 2:49:43 AM Modified: NO Proc. Algorithm IntelliQuan IQA Min. Peak Height: Min. Peak width: 0.00 cps 0.00 sec Smoothing width: points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No File: "s101122a.wifr Int. Type: Valley Retention Time 7.889 min Area: 6597098 counts Height : 5.53e +005 CpS Start Time: 7.727 min End Time : 8.514 Sample Name: "s101122a1S9" Sample ID: "GLP10-01-02-05-075 Dup DAL SS GP03 0 0020 Duplicate* Peak Name: "PFBS* Mass(es): *299.0/99.0 amu.299.0/80.0 amu" I Comment: "" Annotatori: Sample Index: 159 Sample Type: Unknown Concentrt ion : N/A Calculated Cone: 55.1 ng/ml. Acq. Date: 11/25/2010 Acq. Time: 3:14:00 AM File: *s101122a.wtfr Modified: No Proc. Algorithm: IntelliQuan - Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Int. Type: Valley Retention Time: 7.869 Area: 7100566 cc Height: 22e+OOS CpS Start Time: 7.717 min End Time: 8.444 min fSample Name: "s101122a160* Sample ID: "GLP10-01-02-05-075 LMS DAL SS GP03 0 0020 Lab Matrix Spike* Peak Name: 'PFBS* Mass(es): *299.0/99.0 amu.299.0/80.0 amu" SamCpolmemIenndt e"*x: Annota1tio6n0: *" Sample Type: Unknown Concentration: N/A Calculated cone: 104. ng/mL Acq. Date: 11/25/2010 A c q . Time : 3:38:18 AM File: "s101122a.wifr Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height;: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min use Relative RT: No Int. Type: Valley Retention Time: 7.899 Area: 13424653 counts Height: 1 .i6e+006 cps start Time: 7.717 min End Time : 8.474 Printing Time: 5:47:06 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 40 of 321 Page 225 of 962 Stan V1660305 I Sample Name: "s 1 0 H 2 2 a 1 6 1 " Sample ID: "G L P 10-01-02-05-076 DAL S S G P03 DB 0 020 " Peak Name: "PFBS" Mass(es): "299.0/99. amu.299.0/80.0 amu" I C om m ent Annotation: "" Sample Index: 161 Sample T ype: Unknown Concentration: N/A Calculated Cone: 100. ng/mL Acg. Date: 11/25/2010 Acq. Time: 4:02:36 AM File: "s101122a.wiff Modified: NO Proc. Algorithm: IntelliOuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 aec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min use Relative RT: No Int. Type: Valley Retention Time: 7.889 min Area : 12480742 counts Height : l.iee+006 cps Start Time 7.727 min End Time : 8.393 min Results Name: sl01122a.rdb I Sample Name: *s101122a167' Sample ID: "GLP10-01-02-05-076 Dup DAL SS GP03 DB 0020 Duplicate" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Comment "* Annotation: Sample Index: 162 Sample Type: Unknown Concentration: N/A Calculated Cone: 71.3 ng/mL Acq. Date: 11/25/2010 Acq. Time: 4:26:54 AM File: "s101122a.wifT Modified: No MPirno.c. PAelagkorHietihgmh:t: IntelliOuancps- IQA Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: NO Int. Type: valley Retention Time 7.889 min Area: 8991539 counts Height: 7.52e*0 05 cps Start Time 7.727 min End Time: 8.474 min ( Sample Name: "s101122a163" Sample IO: "GLP10-01-02-05-076 IM S DAL SS GP03 DB 0020 Lab Matrix Spike' Peak Name: 'PFBS* Mass(es): *299.0/99.0 amu.299.0/80.0 amu* Comment ~ Annotation: *" Sample Index: File: ' s101122a.wiff I Sample Name: *s101122a164* Sample ID: "GLP10-01-02-05-077 DAL SS GP03 0 0050 * Peak Name: "PFBS* Mass(es): *299.0/99.0 amu,299.0/80.0 amu* I Comment "" Annotation: "" Sample Index: 164 Sample Type: Unknown Concentration : N/A Calculated Cone: Acq. Date: Acq. Time: File: *s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.0( cps Min. Peak width: 0.0< sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.0' min Use Relative RT: No Int. Type: valley Retention Time: 7.889 min Area: 1640913 counts Height: 1.47e+OOS cps Start Time 7.717 min End Time : 8.353 min inting Time: 5:47:08 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 41 of 321 Page 226 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 227 of 962 Stan V1660305 I Sam ple Name: ls101122a169" Sam ple ID: "10 006-25 s olvent blank" Peak Name: " PFBS" Mass(es): "299./99.0 amu,2 99.0/80.0 am u" I Comment: "" Annotation: " Sample Index: 169 Sample Type: Double Blank Concentration: o.oo ng/mL calculated cone: N/A Acq. Date: 11/25/2010 Acq. Time: 7:16:55 AM File: "s 1 0 1 1 2 2 a .w tff Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: RT Window: Expected RT: Use Relative RT: No Int. Type: Retention Time: Area: Height . Start Tim e : End Time: valley 7.608 min 2179 counts 2.79e+002 CpS 7.667 min 6.030 min I Sample Name: "s101122a171" Sample ID: "GLP1-01-02-05-078 Dup DAL S i GP04 0 0000 Duplicate " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299.0/B0.0 amu" I Comment: Annotation: "" Sample Index: 171 Sample Type: Unknown Concentration: N/A Calculated Cone: 4.40 ng/mL Acq. Date: 11/25/2010 Acq. Time: 6:05:35 AM File: "s101122a.wir Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT window: sec Expected RT: use Relative RT: Area: Height : start Time : End Time : .29e*004 7.727 6.373 Printing Time: 5:47:12 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sam ple Name: s101122a170" Sam ple ID: "G LP10-01-02-05-078 D AL SS G P04 0 0000 " Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" Comment "" Annotation: Sample Index: 170 Sample Type: Unknown Concentration: N/A Calculated Cone: 5.54 ng/mL Acq. Date: 11/25/2010 Acq. Time: 7:41:12 AM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - Iq; Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 6.04 min Use Relative RT: NO Int. Type: Valley Retention Time: 7.699 min Area: 857362 counts Height : 9.03e*004 cps start Time: 7.727 min End Time : 8.313 min ( Sample Name: "s101122a172" Sample ID: "GLP10-01-02-05-078 LMS DAL SS GP04 0 0000 Lab Matrix Spike" Peak Name: "PFBS" Mass(es): "299.0/99.0 amu.299.0/80.0 amu" Com m ent"" Annotation:"" Sample Index: 172 File: "s101122a.wifr Page 43 of 321 Page 228 of 962 Stan V1660305 I Sample Name: "s101122a173" Sample ID: "GLP10-01-02-05-079 DAL SS GP04 0 0005 ' Peak Name: "PFBS" Mass(es): *299.0/99.0 amu,299.0/80.0 amu" Comment: "" Annotation: sample index: 173 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.33 ng/mL Acg. Date: 11/2S/2010 Acg. Time: 8:54:07 AM File: ' s101122a.wifT Modified: No Proc. Algorithm: intelliOuan - iq a M in. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 8.04 min Use Relative RT: No Area: Height : start Time : End Time : 669 min 3S4768 counts 3.03e-f004 cps 7.707 min 8.312 min Results Name: s!01122a.rdb I Sample Name: "s101122a174" Sample ID: "GLP10-01-02-05-079 Dup DAL SS GP04 0 0005 Duplicate" Peak Name: "PFBS' Mass(es): "299.0/99.0 amu,299.0/80.0 amu" Com m ent"" Annotation:"" Sample Index: 174 Sample Type; Unknown Concentration: N/A Calculated Cone: 2.57 ng/mL Acg. Date: 11/25/2010 Acg. Time: 9:18:26 AM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o .o o cps Min. Peak width: o .o o sec Smoothing w id th : 3 points RT Window: 30.0 9ec Expected RT: 8.04 min Use Relative RT: No Area: Height : Start Time: End Time : 375241 counts 3.27e +004 CpS 7.566 min 8.292 min I Sample Name: "s101122a175" Sample ID: "GLP10-01-02-05-079 LMS DAL SS GP04 0 0005 Lab Matrix Spike' Peak Name: "PFBS" Masses): "299.0/99.0 amu,299.0/80.0 amu" Com m ent"" Annotation: "" Sample Index: 175 Sample Type: Unknown Concentration: N/A Calculated Cone: 13.3 ng/mL Acg. Date: 11/25/2010 Acg. Time: 9:42:42 AM File: 's101122a.wiT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak Width: o .o o sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: s.04 min Use Relative RT: No Area: Height : start Time : End Time : l.64e*005 cps 7.677 min 8.555 min ISample Name: *s101122a176" Sample ID: ' GLP10-01-02-05-080 DAL SS GP04 0 0020 ' Peak Name: "PFBS* Mass(es): *299.0/99.0 amu.299.0/B0.0 amu" SamCpolmemIenndt e**x: Annotat1io7n6: "" Sample Type : Unknown Concentration : N/A Calculated Cone: 1.65 n< Acg. Date: 11/25/2010 Acg. Time: 10:07:03 AM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.04 min use Relative RT: No Area: Height : Start Time: End Time: 2.20e+004 7.717 8.403 Printing Time: 5:47:14 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 44 of 321 Page 229 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 230 of 962 *Stan V1660305 I Sam ple N ame: "s101122a181" Sample ID: " 10 006-25 solvent blank" Peak Name: ' PFBS" Mass(es): *299.0/99.0 amu.299.0/80.0 amu* I Comment: ** Annotation: "* Sample Index: 181 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acg. Date: 11/25/2010 Acq. Time: 12:08:37 PM File: "s101122a.wtfT Modified: NO Proc. Algorithm: IntelliOuan - IQA Min. Peak Height:: o.oo epa Min. Peak Width: o.oo sec Smoothing width: 3 points RT Window: Expected RT: Use Relative RT: No Int. Type: valley Retention Time: 8.191 min Area: 557 counts Height: ; .95e+002 cps Start Time: 8.151 min End Tim e : 8.262 min I Sample Name: Hs101122a183" Sample ID: *10 006*25 solvent blank* I Peak Name: "PFBS" Mass(es): "299.0/99.0 amu,299,0/80.0 amu" I Comment:"" Annotation: "* Sample Index: 183 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 12:57:18 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: use Relative RT: NO Int. Type: Retention Time: Area: Height: start Time: End Tim e : Valley 8.101 min 468 counts i.SSe+002 cps 8.070 min 8.171 min inting Time: 5:47:18 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sample Name: "s101122a162" Sample ID: "EC-101116-07 10 ng Peak Name: *PFBS* Mass(es): "299 0/99.0 amu,299.0/60.0 amu" Comment "* Annotation: "" Sample Index: 182 Sample Type: QC Concentration: 9.99 ng/mL calculated Cone: 10.5 ng/mL Acq. Date: 11/25/2010 Acq. Time: 12:32:55 PM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Valley Retention Time 7.889 min Area: 1511763 counts Height: 1 . 2 B e * 0 0 5 cps Start Time: 7.687 min End Time : 8.454 min I Sample Name: "s101122a001* Sample ID: *10 006-25 solvent blank* Peak Name: "PFHS* Mass(es): "399.0/99.0 amu.399.0/80.0 amu" Comment "* Annotation: "* Sample Index: l File: "s101122a.wir Page 46 of 321 Page 231 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 232 of 962 Stan V1660305 I Sample Name: "51011223006" Sample ID: "10 006-25 solvent blank" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" Comment:"" Annotation:"" Sample Index: 6 File: "s101122a.wifr I Sample Name: "s101122a008" Sample ID: "10006-25 solvent blank" Peak Name: "PFHS" Mass(es): ` 399.0/99.0 amu,399.0/80.0 amu" SamCpolmemIenndt ex" : Annotation8: " File: "s101122a.wtfT Time, min Results Name: sl01122a.rdb Sam ple Name: "s101122a007" Sample ID: "10 0 06-25 solvent blank" I Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" Com m ent"" Annotation: sam ple index: Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 1:48:28 PM File: "s101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 10.SS2 min 164 counts 7.5le+00l cps 10.522 min 10.623 min 0- 1 I Sample Name: "s101122a009" Sample ID: "10 006-25 solvent blank' Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/60.0 amu" Comment " Annotation: " Sample Index: 9 File: "s101122a.wifT Printing Time 5:47:21 PM Printing Date Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Time, min Page 48 of 321 Time, min Page 233 of 962 Stan V1660305 Results Name: s!01122a.rdb I Sam ple Name: "s101122a010" Sample ID: "EC -101116-01 0.2 ng Extracted C urve P o in r Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" I Com m ent: "" Annotation: Sample Index: 10 Sample Type: Standard concentration: 0.200 ng/mL Calculated Cone: 0 . 2 0 2 ng/mL Acq. Date: 11/22/2010 Acq. Time: 3:00:53 PM File: "s1 01 12 2a .w ifr Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height:: 0 .0 0 CpS Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: NO Int. Type : Valley Retention Time: 10.411 min Area: 22534 counts Height : 1.70e+003 cps Start Time: 10.249 min End Time : 10.885 min I Sample Name: "s101122a012" Sample I0: "EC-101116-03 0.75 ng Extracted Curve Poinr Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu' Comment: Annotation: " Sample Index: Sample Type: standard 0.750 ng/mL Concentration: 0.722 ng/mL Calculated Cone 1 1 / 22/2010 Acq. Date: 3:49:18 PM Acq. Time: 5000 Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cp3 Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No 4500 4000 3500 File: "s101122a.witr Int. Type : Retention Time: Area : Height : Start Time: End Time : Valley 10.421 min 70254 counts 5.3 9e+003 cps 10.280 min 10.855 min 3000 I S a m p le N a m e :"s 1 0 1 1 2 2 a 0 ir Sam ple ID: "E C -1 01 116-02 0.5 ng Extracted C urve P o in f | Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu' M Comment "" Annotation: "" Sample Index: 11 Sample Type: Standard Concentration: 0.500 ng/mL Calculated Cone: 0.475 ng/mL Acq. Date: 11/22/2010 3800 Acq. Time: 3:25:08 PM 3600 File: "s101122a.w ifT Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak Width. 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT. NO 3400 3200 3000 2600 2600 Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 10.421 min 49571 counts 3.956*003 Cp8 10.259 min 10.744 min 2400 g- 2200 g 2000 1- 1800 1600 1400 1200 1000 600 600 1.04 400 1200 gee 7.17 a ->o .*.10 80 10 12 992 1191 Time, r I Sample Name: "s101122a013" Sample ID: "EC-101116-04 1 ng Extracted Curve Poinf File: "s101122a.wiff | Peak Name: "PFHS' Mass(es): "399.0/99.0 amu.399.0/80.0 amu" 1 Comment "" Annotation: ~ Sample Index: 13 Sample Type: Standard Concentration : 1.00 ng/mL Calculated Cone: 1.04 ng/mL Acq. Date: 11/22/2010 6000 Acq. Time: 4:13:33 PM 7500 Modified: NO Proc. Algorithm: IntelliQuan - IQ) Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO 7000 6500 6000 5500 Int. Type: valley Retention Time: 10.411 rain Area: 100939 counts Height : 8.33e +003 cps Start Time: 10.189 min End Time : 10.845 min 5000 4500 4000 3500 14.61 19.46*. V-/ 17.83*. L li.li 14 1369 16 1567 3000 2500 2000 1 P2 6.15 1 1 ^6.60 . 1 .................... . . . . . M V W A k y L .......... 21.88 1500 1000 500 - *III I' . |l ~l l 199 398 Printing Time: 5:47:23 PM Printing Date: Friday, January 07, 2011 992 1191 1389 1587 1785 1964 2162 Time, min__________________________________________ Page 49 of 321 992 1191 1369 1587 1785 1964 2162 Time, min__________________________________________ 3M Study GLP10-01-02 Interim Report 05 Page 234 of 962 Stan V1660305 I Sample Name: "s101122a014" Sample ID: "EC-101116-06 2.5 ng Extracted Curve Point" m Peak Name: "PFHS" Mass(es): *399.0/99.0 amu.399.QmO.O amu* Comment: " Annotation: "" Sample Index: 14 Sample Type: Standard Concentrt ion : 2.50 ng/mL Calculated Cone: 2.50 ng/mL Acq. Date: 11/22/2010 Acq. Time: 4:37:42 :PM File: "s101122a.wtff Modified: NO Proc. Algorithm: IntelliQuan - 10/ Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type : valley Retention Time: 10.411 min Area: 2S1412 counts Height : 1.97e + 004 cps start Time: 10.239 min End Time : 10.905 min I Sample Name: "s101122a016" Sample ID: "EC-101116-07 10 ng Extracted Curve Point* File: "s101122a.w ifT Peak Name: ` PFHS* Mass(es): *399.0/99.0 amu,399.0/80.0 amu* sample Index: 16 Sample Type : standard Concentration: 10 0 ng/mL Calculated Cone: 9.78 ng/mL Acg. Date: 11/22/2010 Acg. Time: 5:26:01 PM 7.0e4 6.5e4 Modified: No Proc. Algorithm: IntelliQuan - IQA 6.0e4 Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points 5.5e4 RT Window: Expected RT: 30.0 sec 10.6 min 5.0e4 U3e Relative RT: NO 4.5e4 Int. Type : Valley Retention Time: 10.421 min Area: 953668 counts < 4.0e4 g- Height : start Time: 7.22e* 004 cps 10.179 min 3.5e4 End Time : 11.066 min 3.0e4 2.5e4 2.0e4 1.5e4 1.0e4 5000.0 0.0 - Printing Time: 5:47:26 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ISample Name: *s101122a015* Sample ID: "EC-101116-06 i Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/60.0 Comment Annotation: *" Sample Index: 15 Sample Type: Standard Concentration: S .00 ng/mL Calculated Cone: 5.23 ng/mL Acg. Date: 11/22/2010 3.8e4 Acq. Time: 5:01:52 PM 3.6e4 Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10 6 min Use Relative RT: NO 3.4e4 3.2e4 3.0e4 2.8e4 2 6e4 Int. Type: Valley Retention Time: 10.421 min Area: 507096 counts Height : t.00e+004 cps start Time: 10.199 min End Time : 10.976 min 2.4e42.2e4 g2 0e4 1.6e4 1.6e4 1.4e4 1.2e4 1.0e4 8000.0 6000.0 4000.0 2000.0 o.o-} ISample Name: " s 1 0 1 1 2 2 a 0 ir Sample ID: "EC-101116-08 25 ng Extracted Curve Point" Peak Name: "PFH S* Mass(es): "399,0/99.0 amu,3 99.0/80.0 amu" C omment Annotation: "" Sample Index: 17 Sample Type: Standard Concentration: Calculated cone: 25.0 24.1 ng/mL ng/mL 1.9e5- Acg. Date: Acq. Time: 11/22/2010 S :50:14 PM 1.8e5- NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No 1.7e51.6e51.5eS1.4e51.3e5- Int. Type : Valley Retention Time: 10.411 Area: 2424109 counts Height : 1.95e +005 cps Start Time: 10.169 min End Time: 11.026 min 1.2e5- 1.1e5g- 1.0e5- 9.0e45 - 8.0e4- File: *s101122a.w iff' 7.0e4- 6.0e4- 5.0e4- 4.0e4- 3.0e4- 2.0e4- 1.0e4- 0.0- 992 1191 Time, min Page 50 of 321 Page 235 of 962 Stan V1660305 I Sample Name: "s101122a018" Sample ID: "EC-101116-09 50 ng Extracted C urve Point" Peak Name: "PFHS" Mass(es): "399.0/99.0 am u.399.0/80.0 amu" Com m ent ~ Annotation: "" Sample Index: 18 Sample Type: Standard Concentration: 50.o ng/mL Calculated Cone: 51.4 ng/mL Acq. Date: 11/22/2010 Acq. Time: 6:14:25 PM File: "s101122a.wifT Modified: IntNeolliQuan - IQA Proc. Algorithm: o .o o cps Min. Peak Height: o .o o sec Min. Peak Width: 3 points Smoothing width: 30.0 sec RT Window: 1 0 . 6 min Expected RT: No Use Relative RT: Area: Height : Start Time: End Time : Valley 10.391 min 10386 counts i.80e+005 cps 10.169 min 11.369 min Sample Name: "s101122a020" Sample ID: "EC-101116-11 200 ng I Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" Comment: Annotation: " Sample Index: 20 Sample Type Standard Concentration: 200. ng/mL Calculated cone: 191. ng/mL Acq. Date: 11/22/2010 Acq. Time: 7:02:49 PM Modified: Proc. Algorithm: IntelliQuan IQA Min. Peak Height: o.oo cps Min. Peak width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Int. Type : Valley Retention Time : 10.401 min Area : 18451316 counts Height : Start Time: 1.43e +006 cps 1 0 . 1 1 8 min End Time : 11.319 min g- 1 Printing Time: 5:47:27 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb | Sam ple N am e: " s101122a019" Sam ple ID: "EC -101116-10 100 ng Extracted C urve Point" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" I Com m ent "" Annotation:"" Sample Index: Sample Type: Standard Concentration: 100. ng/mL Calculated Cone: 106. ng/mL Acq. Date: 11/22/2010 Acq. Time: 6:38:37 PM Modified: Proc. Algorithm: Int Min. Peak Height: Min. Peak Width Smoothing Width RT Window: Expected RT: use Relative RT Int. Type: Retention Time Area: : Height: Start Time: End Time : Sample Name: "s101122a021" Sample ID: "EC-101116-12 500 ng Extracted Curve Point" Peak Name: "PFHS" Mass(es): "399.0/99.0 am u.399.0/80.0 amu" 21C o m m en t"" Annotation: "* sam ple in d e x : Sample Type: standard Concentration: soo. ng/mL Calculated cone: 503. ng/mL 2.6e6- Acq. Date: 11/22/2010 Acq. Time: 7:27:01 PM File: "s101122a.w iffl 1039 Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: Page 51 of 321 Page 236 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 237 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 238 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:47:33 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 54 of 321 Page 239 of 962 *Stan V1660305 I Sample N am e:-,s101122a034" Sample ID: "LCS-101116-03 3 n g L C S in TCR-842" Peak Name: "PFHS" Mass(es): *399.0/99.0 am u,399.0/80.0 amu" m Comment: ~ Annotation: "" Sample Index; 34 Sample Type: Unknown Concentration: H/A Calculated Cone : 3.33 ng/ Acq. Date: 11/23/2010 Acq. Time: 12:41:35 AM File: "s101122a.w ir Modified: RT Window: Expected RT: use Relative RT : Yes 30.0 10.6 No sec rain Int. Type: Manual Retention Time: 10.392 rain Area: 342199 COUntS Height: 2.43e+004 cps start Time: 9.735 rain End Time: 10.9B6 rain I Sample Name: "s101122a036" Sample ID: "LCS-101116-05 30 ng LCS in TCR-842" Peak Name: "PFHS* Mass(es): *399.0/99.0 amu,399.0/B 0.0 amu" Comment: Annotatio3n6: *" Sample Index: Unknown Sample Type: N/A Concentration: 31.3 ng/mL Calculated Cone: 11/23/2010 Acq. Date: 1:30:03 AM Acq. Time: Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 10.6 Ho sec min File: *s101122a.w ifr Int. Type: Manual Retention Time 10.402 rain Area: 3447642 counts Height : 2,2Se+00S cps Start Time; 9.745 min End Time : 1 1 . 0 2 6 min Printing Time: 5:47:35 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a035" Sample ID: "LCS-101116-04 30 ng LCS in TC R-842* | Peak Name: *PFH S* Mass(es): "399.0/99.0 amu,399.0/80.0 amu" mCom m ent "* Annotation: "" Sample Index: 3S Sample Type: Unknown Concentration: N/A Calculated Cone:. 32.1 ng/ Acq. Date: 11/23/2010 Acq. Time: 1:05:50 AM File: "s101122a.wrfT Modified: RT window: Expected RT: Use Relative RT:; Yes 30.0 10.4 NO sec min Int. Type: Manual Retention Time: 10.399 min Area: 3309729 counts Height : 2 .OSe+005 cps Start Time: 9.73 5 min End Time : 11.056 rain I Sample Name: "s101122a037" Sample ID: "L C S-101116-06 30 ng LCS in TC R-842* | Peak Name: *PFHS* Mass(es): "399.0/99.0 amu.399 0/80,0 amu" mComment Annotation: "" sample Index: 37 sample Type: Unknown Concentration: N/A Calculated Cone:: 34.7 ng/ Acq. Date: 11/23/2010 Acq. Time: 1:54:19 AM File: "s101122a.wiT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.365 min Area: 3537659 counts Height: 2.30e +005 cps start Time: 9.735 min End Time: 10.925 min Page 55 of 321 Page 240 of 962 Stan V1660305 I Sample Name: "s101122a038" Sample ID: "GLP10-01-02-05-041 DAL SS SS01 0 0 0 0 0 " Peak Name: "PFHS" Mass(es): "399.0/99.0 am u.399.0/80.0 amu" Comment:"" Annotation: "" Sample Index: sample Type: concentration: Unk3n8own N/A Calculated Cone: 11/23/2010 Acg. Date: 2:18:32 AM Acg. Time: Fite: "s101122a.wiff Modified: RT Window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : 3.55e+004 cps 9.735 min 11.228 min I Sample Name: "s101122a040" Sample ID: "GLP10-01-02-05-041 IM S DAL S S SS01 0 00 00 Lab Matrix Spike" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/BO.O amu" Comment: Annotation: sam ple in d e x : Sample Type: Concentration: Unknown N/A Calculated Cone: Acg. Date: 11/23/: Acg. Time: 3:06:5' Fite: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.i No Int. Type : Manual Retention Time 10.409 min Area: 1673989 counts Height : 1.17e+00S cps start Time 9.755 min End Time : 1 1 . 0 1 6 min Results Name: sl01122a.rdb ! Sample Name: "s101122a039" Sample ID: "GLP10-01-02-05-041 Dup DAL S S SS01 0 0 000 Duplicate " | Peak Name: "PFHS" Mass(es): "399.0/99.0 amu, 399.0/80.0 amu' B Comment: "" Annotation: "" Sample Index: 39 Sample Type: Unknown concentration: N/A Calculated Cone S .17 ng/mL Acg. Date: 11/23/2010 3.6e4 Acg. Time: 2 :42 :4S AM 3.4e4 File: "s1011 2 2 a .w ir Modified: RT window: Expected RT: Use Relative RT Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.397 min Area: 514123 counts Height: 3 .77e*004 cps Start Time: 9.735 min End Time: 10.94S min 3.2e4 3.0e4 2.8e4 2.6e4 2.4e4 2.2e4 2.0e4 1.8e4 1.6e4 1.4e4 1.2e4 t.04 8000.0 6000.0 4000.0 0.04s. 2000.0 0.0 ISample Name: "s101122a041" Sample ID: "10 006-25 solvent blank" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" C o m m e n t"" Annotation: " * Sample Index: Sample Type: Double Blank File: "s101122a.w itr 992 1191 Time, min Printing Time: 5:47:37 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 56 of 321 Page 241 of 962 *Stan V1660305 (Sample Name: "s101122a042" Sample ID: ' EC-101116-05 2.5 ng Extracted Curve Point' Peak Name: "PFHS" Mass(es): ' 399.0/99.0 a mu,399.0/80.0 amu" Comment: "" Annotation: " sample Index: 42 File: ' s101122a.wifT ISample Name: "s101122a044* Sample ID: ' G LP10-01-02-05-042 DAL SS SS01 0 0005" Peak Name: ' PFHS' Mass(es): ' 399.0/99.0 am u.399.0/80.0 amu' Comment: "' Annotation: " ' Sample Index: 44 Sample Type : Unknown Concentrt ion : N/A Calculated Conc: 10.l n Acq. Date: 11/23/2010 Acq. Time: 4:44:01 AH Modified: RT window: Yes 30.0 Expected RT: Use Relative RT: 10.6 File: "s101122a.wrff Area: Height : Start Time: End Time : .S6e*004 cps 9.7SS 10.966 min Printing Time: 5:47:39 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb (Sample Name: "s101122a043" Sample ID: *10 006-25 solvent blank* Peak Name: ' PFHS' Mass(es): ' 399.0/99.0 amu,3 99.0/60.0 amu" C omment " Annotation: ~ Sample Index: 43 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 4:19:46 AM File: 's 101122a.w ifr Modified: NO Min. PPeraokc.HeiAglhgto:rithm: IntelcplsiQuan - iQi Min. Peak Width: sec ISmoothing Width: points IRT Window: sec IExpected RT: Iuse Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 10.683 min 74 counts i .96e +00l cps 10.663 min 10.713 I Sample Name: "s101122a045' Sample ID: "G LP10-01-02-05-042 Dup DAL S S SS01 0 0005 Duplicate' I Peak Name: ' PFHS* Mass(es): ' 399.0/99.0 am u.399.0/80.0 amu" M C omment " Annotation: " Sample Index: 4S Sample Type: Unknown Concentration: N/A Calculated Cone : 7.62 ng/ Acq. Date: 11/23/2010 Acq. Time: S :08 :17 AM File: *s 1 0 11 22 a.w ir Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.394 min Area: 792589 counts Height: s.41e*004 cps Start Time: 9.74S min End Time: 11.046 min Page 57 of 321 Page 242 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 243 of 962 Stan V1660305 (Sample Name: "s101122a050" Sample ID: "G LP10-01-02-05-044 DAL SS SS02 0 0005 Peak Name: ' PFHS" Mass(es): ' 399.0/99.0 amu.399.0/80.0 amu" Com m ent:"" Annotation: "" Sample Index: SO Sample Type: Unknown concentration: N/A Calculated Cone: 78.5ng/mL Acq. Date: ll/23/2010 Acq. Time: 7:09:25 AM Modified: RT Window: Expected RT: Use Relative RT: Yes NO File: "s1 01 12 2a .w ifr Int. Type: Manual Retention Time 10.388 min Area: 7039459 counts Height: 4.66e+005 CpS start Time End Time: 9.745 min 1 1.0 6 6 min Results Name: sl01122a.rdb I Sam ple N ame: "s101122a051" Sample ID: "G LP10-01-02-05-044 Dup DAL S S SS02 0 0005 Duplicate ' Peak Name: ' PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu' C o m m e n t"" Annotation:"" Sample Index: 51 Sample Type: Unknown Concentration: N/A calculated Cone: 58.8 n Acq. Date: 11/23/2010 Acq. Time: 7:33:38 AM Modified: RT Window : Expected RT: Use Relative RT: Yes 30.0 10.6 File: "s 1 0 1 1 2 2 a w iff Area: Height: start Time: End Time: 3.74e*005 cps 9.725 min 11.016 min I Sample Name: ns101122a052" Sam ple ID: "GLP10-01-02-05-044 LMS DAL S S S S 02 0 0005 Lab Matrix S pike" I Peak N ame: "P F H S " Mass(es): "399.0/99.0 amu,3 99.0/60.0 am u" I Com m ent Annotation: "" Sample Inde> S2 Sample Type: Unknown Concentration: N/A calculated cone: 1 6 2 . ng/mL Acq. Date: 11/23/2010 Acq. Time: 7:57:52 AM File: "s101122a.wifT Modified: RT Window: Expected RT: use Relative RT: Area: Height : start Time: End Time : 1.09e*006 9.755 11.188 I Sam ple Name: "s101122a053" Sam ple ID: ''G LP10-01-02-05-045 D AL S S SS03 0 0 000 " Peak N am e: "P F H S " M ass(es): "3 99.0/99.0 am u.399.0/80.0 amu" I C om m ent Annotation: "" Sample Index S3 Sample Type: Unknown Concentration: N/A calculated Cone: 245. ng/mL Acq. Date: 11/23/2010 Acq. Time: 8:22:05 AM File: "s101122a.w ifT Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 10.388 min Area: 23371276 counts Height: 1.56e*006 cps Start Time: 9.755 min End Time : 11.157 min Printing Time: 5:47:43 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 59 of 321 Page 244 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 245 of 962 Stan V1660305 I Sam ple N am e: "s101122a058" Sam ple ID: "GLP10-01-02-06-046 LM S DAL S S SS03 0 0005 Lab M atrix S pike" Peak N am e: ' PFHS' Mass(es): '3 9 9 .0 /9 9 .0 am u.399.0/80.0 amu* Comment: - Annotation: " Sample Index: 58 Sample Type: Unknown Concentrt ion : Calculated Cone: N/A 632. ng/mL 3.0e6- Acq. Date: 11/23/2010 Acq. Time: 10:23:13 AM 2.8e6- File: "s10 11 22 a.w itr Modified: RT Window : Expected RT: Use Relative RT: Yes 30.0 10.6 NO sec min Int. Type : Manual Retention Time: 10.400 min Area: 49880575 counts Height : 3.07e+006 cps start Time : 9.765 min End Time: 11.258 min 26e62.4e62.2e62.0e61.8e6- 1.4e6 1.2e6 1 .0 6 S.OeS 6.0eS 4.0*5 2 .0 5 I Sample Name: " s101122a060" Sample ID: "EC-101116-06 5 ng Extracted Curve P o in t" Peak N ame: "P F H S " Mass(es): "399.0/99.0 amu,399.0/80.0 am u" Comment: A n n o ta tio n :"" Sample Index: 60 Sample Type: Concentration: Calculated Cone: Acq. Date: - Acq. Time: 992 1191 Tim e, min File: "s101 12 2a .w ifr Modified: Proc. Algorithm: Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: 5 Height: < Start Time: End Time: Results Name: sl01122a.rdb Sample N ame: "s101122a059" Sample ID: "10 006-25 solvent blank' Peak Name: ' PFHS" Mass(es): *399.0/99.0 amu,399.0/80.0 amu" C om m ent " Annotation:"" Sample Index: 59 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 10:47:24 AM File: " s101122a.wifT Modified: No MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- XQA Min. Peak Width: sec Smoothing Width: RT Window: points sec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height : start Time: End Time: Valley 10.421 min 14220 counts l .lle+003 cps 10.219 min 10.915 min Sam ple Name: " 7 ic fiT 3 2 ()6 1 " Sam ple ID: "10 006-25 solvent blank" I Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu' M C om m en t " Annotation: " Sample index: 61 Sample Type: Double Blank Concentration : 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 11:35:55 AM File: "s1 01122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time: End Time : valley 10.512 min 1800 counts 1.37e+002 cps 10 .28 0 min 10.723 min Printing Time: 5:47:46 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 61 of 321 Page 246 of 962 Stan V1660305 I Sam ple Name: "s101 122a062" Sample ID: "G LP10-01-02-05-047 D AL SS SS 03 DB 0005 " P eak Name: " PFH S" M ass(es): "399.0/99.0 amu,399.0/80.0 am u" B Com m ent: ~ Annotation: Sample Index: 62 Sample Type : Unknown Concentration : N/A calculated cone: la s . ng/t Acq. Date: 11/23/2010 Acq. Time: 12:00:10 PM File: "s 1 01 12 2a .w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 No sec min Int. Type: Manual Retention Tine: 10.399 min Area: 19444025 <counts Height : 1 .26e+006 cps start Time: 9.755 min End Time: 11.157 min I Sam ple Name: *s101122a064a Sam ple ID: "G LP10-01-02-05-047 LM S D AL S S S S 03 DB 0005 Lab M atrix S pike" I Peak Name: "PFHS" Mass(es): "399.0/99.0 amut399.0/80.0 amu" 1 C om m ent: - Annotation: "* Sample Index: 64 Sample Type: Unknown concentration: N/A calculated cone: 634. ng/f Acq. Date: 11/23/2010 Acq. Time: 12:48 ;43 PM File: "s101122a.w ifT Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.38S min Area: 47163997 counts Height : 3.00e +006 Cp9 Start Time: 9.755 min End Time : 11.309 min Results Name: slOH22a.rdb I Sam ple N am e: "s101122a063" Sam ple ID: "G LP10-01-02-05-047 D up D AL S S SS03 DB 0005 D u p lica le " | Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" ' C om m ent "" Annotation: "" Sample Index: 63 Sample Type : Unknown Concentration : N/A Calculated Cone 141 . ng/mL 9.0eS Acq. Date: Acq. Time: 11/23/2010 12:24:29 PM S.SeS File: ' s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 10.6 NO sec min B.OeS 7.5e5 7.0e5 Int. Type: Manual Retention Time: 10.397 min Area: 14249354 counts Height : 9.31e+005 cps Start Time: 9.745 min End Time: 11.218 min 6.5e5 6.0e5 5.5e5 M 5.0e5 4.5e5 4.0e5 3.5e5 3.0e5 2 5e5 2.0e5 1.5eS 1.0e5 0. 0 2 ^ 5.0e4 0.0 I Sample N ame: "s101122a065" Sample ID: "GLP10-01-02-05-046 DAL SS SS 04 0 00 00 * Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" SamCpolmemIenndt e"*x: Annotatio6nS: " " Sample Type: Unknown Concentration: N/A calculated cone: 13.4 ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:12:58 PM 992 1191 _____ Time, min File: "s101122a.wifT Modified: RT window: Expected RT: use Relative RT: Area : Height : Start Time: End Time: 1.09e+005 9.755 11.177 Printing Time: 5:47:47 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 62 of 321 Page 247 of 962 *Stan V1660305 Results Name: sl01122a.rdb S a m p l e N a m e : "s101122a066" S a m p l e ID: "GLP10-01-02-05-048 D u p D A L S S S S 0 4 0 0 0 0 0 Duplicate " P e a k N a m e : "P F H S " Mass(es): "399.0/99.0 amu.399.0/80.0 a m u " C o m m e n t : "* Annotation: Sample Index: 66 Sample Type: Unknown concentration: N/A Calculated Cone: 4.09 ng/mL 3.2e4 Acg. Date: 11/23/2010 Acq. Time: 1:37:12 PM 3.0e4 File "8l01122a.wifr Modified: RT window: E x pected RT: Use Relative RT: Yes 30.0 10.6 No sec min Int. Type: Manual Retention Time: 10.394 min Area: 439358 counts Height: Start Time: 3.30e+0O4 cps 9.735 min End Time: 11.016 min 2.8e4 2.6e4 2.4e4 22e4 20e4 --^ 1.6e4 c 1.4e4 1.2e4 S a m p l e N a m e : "s 1 0 1 1 2 2 a 0 6 7 " S a m p l e ID: "G L P 1 0-01-02-05-048 L M S D A L S S S S 0 4 0 0 0 0 0 L a b Matrix Spike P e a k N a m e : "P F H S " Mass(es): "399.0/99.0 amu, 399.0/80.0 a m u ' 1 C o m m e n t "" Annotation: "" Sample Index: 67 Sample T y p e : Unknown Concentration: N/A calculated Cone: 15.2 ng/mL 1.20e5- Acq. Date: 11/23/2010 Acq. Time: 2:01:25 PM 1.10e5 Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 10.6 No sec min 1 00e5 ' File: "s101122a.wifT Int. Type: Manual Retention Time: 10.389 min Area: 1645415 counts Height: l .2 4 e + o o 5 c p s Start Time: 9.755 min End Time: 11.147 min 800e4 ,, 7.00e4 6.00e4 E 5.00e4- 80 0 0 , 0 6000.0 4000.0 2000.0 ' 2 199 4 398 i 6 596 S a m p l e N a m e : "s101122a068" S a m p l e ID: "GLP10-01-02-05-049 D A L S S S S 0 4 0 0 0 0 5 " P e a k N a m e : " P F H S " Mass(es): *399.0/99.0 a m u , 399.0/80,0 a m u " Comment: Annotation:"" Sample Index: 68 Sample Type: Unknown Concentration: Calculated Cone: N/A 2.09 ng/mL 1 9e4 Acq. Date: 11/23/2010 1.6e4 Acq. Time: 2:25:37 PM 1.7e4 Modified: RT Window: E x pected RT: Yes 30.0 10.6 sec min 1-6e 4 -- . Use Relative RT: No i M . ___________ 8 794 10 12 992 1191 Time, min File: "s101122a.wifr 4 1389 Int. Type: Manual Retention Time: 10.383 min Area: 225151 counts Height: l.93e+004 cps Start Time: 9.785 min End Time: 11.087 min 1 3e4- 1.2e4J ,, 11e4o. 1.0e4 g 9000.0' 8000.0- 7000.0- 6000.0- 5000.0- 4000.0- 30 0 0 . 0 2000.0- 1000.0 . 2 199 4 398 Printing Time: 5:47:49 PM Printing Date: Friday, January 07, 2011 I ....... i 6 596 8 794 10 12 992 1191 Time min 14 1389 16 1587 16 1587 18 1785 18 1785 20 1984 20 1984 22 2182 22 2162 3.00e4 2.00e4- ' 0.00 2 199 4 398 . 6 596 10.08. 794 >L 10 12 992 1191 Time, min 14 1389 1 S a m p l e N a m e : "s 1 0 1 1 2 2 a 0 6 9 " S a m p l e ID: "GLP10-01-02-05-049 D u p D A L S S S S 0 4 0 0 0 0 5 Duplicate " P e a k N a m e : "P F H S " Mass(es): "399.0/99.0 a m u . 399.0/80.0 a m u " C o m m e n t "* Annotation: *" Sample Index: 69 Sample Type: Unknown concentration: N/A calculated Cone: 1.98 ng/mL Acq. Date: 11/23/2010 1-6 e 4 Acq. Time: 2:49:50 PM 1.5e4- File "s101122a.wifT Modified: RT Window; Expected RT: use Relative RT: Yes 30.0 10.6 No sec min 1.4e41.3e4- Int. Type: Manual Retention Time: 10.394 min Area: 222388 counts Height: i.70e+004 cps Start Time: 9.816 min End Time: 10.945 min 1.2e4- 1.1e4- 1.0e4,, 8- 9000.0 - 7000.0 6000.0 5000.0 4000.0 2000.0 1000.0 6.16 i 10.04, I 2 199 4 398 6 596 8 794 10 12 992 1191 Time min 14 1389 Page 63 of 321 16 1567 16 1567 18 1785 . 20 1984 16 1785 20 1984 22 2162 22 2182 3M Study GLP10-01-02 Interim Report 05 Page 248 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 249 of 962 *Stan V1660305 f Sam ple Name: "s101122a074" Sample ID: "GLP10-01-02-05-051 Peak Name: "PFHS" Mass(es): " 399.0/99.0 amu,399.0/80.0 amu" B C om m en t Annotation: "" Sample Index: 74 Sample Type: Unknown Concentration: N/A 1.6e6- Calculated Cone 283 . ng/mL Acq. Date: Acq. Time: 11/23/2010 4:51:04 PM 1.5e6- Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.374 min Area: Height : 26706584 counts 1 .62e+006 cps start Time: 9.715 min End Time : 11.056 min 1.4e61.3e61.2e61.1e61.0e6 9.0e5- Results Name: sl01122a.rdb Sam ple N ame: "s101122a075" Sam ple ID: "GLP10-01-O2-&-0S1 D up D AL S S SS0S 0 0000 Duplicate " Peak Name: ' PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" m Comment A n n o ta ti o n : sample index: 75 Sample Type: Unknown Concentration: N/A Calculated Cone:: 233 . ng/i Acq. Date: 11/23/2010 Acq. Time: 5:15:19 PM File: "s101122a.wifT Modified: RT window: Expected RT: Use Relative RT:: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.393 min Area: 21822173 counts Height : 1.29e*0 06< cps Start Time: 9.725 min End Time: 11.198 min I Sam ple Name: Ns101122a076" Sample ID: "G LP 10-01-02-05-051 LM S D AL S S SS05 0 0 000 Lab M atrix Spike' I Peak Name: ' PFHS' Mass(es): " 399.0/99.0 am u.399.0/80.0 amu" C o m m e n t:"" Annotation: Sample Index:- Sample Type: Unknown concentration: N/A Calculated Cone 777. ng/mL Acq. Date: 11/23/2010 Acq. Time: 5:39:33 PM File: "s1 01 12 2a .w ifr Modified : RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 No Int. Type: Manual Retention Time: 10.386 min Area: 54842442 counts Height: 3.34e*006 eps Start Time 9.745 min End T ime: 11.319 min Sam ple Name: " s101122a077" Sam ple ID: " 10 006*25 solvent blank" Peak Name: " PFHS" Mass(es): "399.0/99.0 amu,399.0/60.0 amu" C om m ent Annotation:"" sample Index: 77 sample Type: Double Blank File: "s101122a,wifT Printing Time: 5:47:53 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 65 of 321 Page 250 of 962 *Stan V1660305 Results Name: sl01122a.rdb Study GLP10-01-02 rim Report 05 Page 251 of 962 *Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:47:56 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 67 of 321 Page 252 of 962 *Stan V1660305 I S a m p le Name: "s101122a066" Sam ple ID: "GLP10-01-02-05-055 D A L S S S | P eak N am e: ' PFHS" M ass(es): " 399.0/99.0 amu,3 99.0/80.0 amu* 1 Comment: "" Annotation: "" Sample Index: 86 Sample Type: Unknown Concentration: N/A Calculated Cone : 0.972 ng / Acq. Date: 11/23/2010 Acq. Time: 9:42:11 PM 6 0 0 005 " File: "s101 122a.wifT Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.396 min Area: 104403 counts Height: 7.08e*003 cps Start Time: 9.715 min End T ime: 11.066 min r Sample Name: n$101122a088" Sample ID: "GLP10-01-02-05-055 LM S DAL S S SS06 0 0 005 Lab Matrix Spike' File: "s1 01122a.w tr Peak Name; ' PFHS' Mass(es): ' 399.0/99.0 am u.399.0/80.0 amu' Comment: *" Annotation: " Sample Index: 88 Sample Type: Unknown Concentration: N/A Calculated Cone: Acg. Date: 11/23/2010 Acq. Time: 10:30:39 PM Modified: RT Window: Expected RT: Use Relative RT: Tes 30.0 10.6 2.99ng/mL Int. Type: Manual Retention Time:: 10.401 min Area: 329475 counts Height: 2.43e+004 cps Start Time 9.765 min End Tim e : 11.117 Results Name: slOH22a.rdb r Sample Name: "s101122a087" Sample ID: ~GLP10-01-02-05-055 Dup DAL S I SS06 0 0005 Duplicate' | Peak Name: "PFHS" Mass(es): "399.0/99.0 amu, 399.0/80.0 amu" m Comment " Annotation: "" Sample Index: 87 Sample Type: Unknown Concentration : N/A calculated Cone : 1.15 ng/mL Acq. Date: 11/23/2010 Acq. Time: 10:06:25 PM File: "s101122a.wiff' Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 10.6 NO sec min Int. Type : Manual Retention Time: 10.395 min Area: 13 693S counts Height : B.90e+003 cps Start Time: 9.795 min End Time: 10.905 min 1si t I Sample Name: "s101122a089" Sample ID: GLP10-01-02-05-056 D A L S S S S 0 6 D Peak Name: ' PFH S* Mass(es): ' 399.0/99.0 am u.399.0/80.0 amu" Comment " Annotation: " Sample Index: 89 sample Type: Unknown Concentration: N/A Calculated Cone: 1.35 ng/mL Acq. Date: 11/23/2010 Acq. Time: 10:54:53 PM l 0005' 794 992 1191 Time, min File: "s101122a.wift" Modified: r t window: Expected RT: Use Relative RT: Yes 30.0 10.6 No sec min Int. Type : Manual Retention Time: 10.377 min Area: 149141 counts Height : 1.03e+004 cps start Time: 9.806 min End Time: 10.895 1389 1587 1785 1984 2162 Printing Time: 5:47:58 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 68 of 321 Page 253 of 962 Stan V1660305 I Sample Name: "s101122a090" Sam ple IO: "GLP10-01-02-05-056 D up D AL S SS06 DB 0005 Duplicate" Peak N ame: "P F H S " Mass(es): "399.0/99.0 amu,399.0/80.0 a m i/' B Comment: Annotation: " sample index: 90 sample Type: Unknown Concentration: N/A Calculated Cone : 1.06 ng/ Acq. Date: 11/23/2010 Acq. Time: 11:19:08 PM File: "s101122a.w itr Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.406 min Area: 114123 counts Height: 8.01e+003 cps Start Time: 9.775 min End Time: 10.945 min Results Name: sl01122a.rdb I Sample Name: "s101122a091" Sample ID: "GLP10-01-02-05-056 LMS D AL S S SS06 DB 0005 Lab Matrix Spike" | Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" 1 Comment " Annotation: "" Sample Index: 91 Sample Type: Unknown Concentration: N/A Calculated Cone : 3.16 ng/ Acq. Date: 11/23/2010 Acq. Time: 11:43:23 PM File: ',s101122a.wiff Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.384 min Area: 329711 counts Height: 2 .S6e+004 cps Start Time: 9.805 min End Time: 10.976 rain I Sample Name: "s101122a092" Sample ID: "GLP10-01-02-05-057 DAL S S S S07 0 0000 " Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu' 1 C omment "* Annotation: '' Sample Index: 92 Sample Type: Unknown Concentration: N/A Calculated Cone:: S5.8 ng< Acq. Date: 11/24/2010 Acq. Time: 12:07:39 AM File: "s101122a.vnfT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.393 min Area: 6046858 counts Height : 3 . 61e * 00S cps Start Time : 9.745 min End Time : 11.127 min I Sample Name: ' s101122a093" Sample ID: "GLP10-01-02-05-057 Dup DAL S S S S07 0 0000 Duplicate ' | Peak Name: ' PFHS' M a s te s ): ' 399.0/99.0 am u.399.0/80.0 amu' 1 Comment "" Annotation: " Sample Index: 93 Sample Type: Unknown concentration: N/A Calculated Cone:: 55.7 ng/ Acq. Date: 11/24/2010 Acq. Time: 12:31:55 AM File: ' s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.395 min Area: 5911696 counts Height: 3.70e +005 cps Start Time: 9.715 min End Time : 11.238 min Printing Time: 5:48:00 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Page 69 of 321 Page 254 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 255 of 962 Stan V1660305 I Sample Name: "s101122a098" Sample ID; ' G LP10-01-02-05-058 DAL S S SS07 0 0 005 " Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399 0/80.0 amu" I Comment: "" Annotation: "" Sample Index: Sample Type: unknown Concentration: N/A Calculated Cone: 78.2 ng/raL Acq. Date: 11/24/2010 Acq. Time: 2:33:08 AM File: "s101122a.wifr Modified: RT Window: Expected RT: Use Relative RT: Yea 30.0 10.6 No sec min Int. Type: Manual Retention Time: 10.394 min Area: 8402420 counts Height : 5.39e*005 cpS Start Time 9.745 min End Time : 11.177 min Results Name: sl01122a.rdb I Sample Name: "s101122a099" Sample ID: "GLP10-01-02-05-058 Dup DAL S S S S 07 0 0005 Duplicate " Peak Name: "PFHS* Mass(es): "399.0/99.0 amu,399.0/80.0 amu" I Comment Annotation: ~ Sample Index: 99 Sample Type: Unknown Concentration: N/A Calculated cone: 69.3 l Acq. Date: 11/24/2010 Acq. Time: 2:57:24 AM File: "s101122a.wiff Modified: RT window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 10.378 rain Area: 7566657 counts Height: 4.62e*005 cps start Time 9.74S min End Time: 11.117 min Sample Name: "s101122a100" Sample ID: "GLP1D-01-02-05-058 L M S DAL S S SS07 0 0 005 Lab Matrix Spike" File: "s101122a.wiff' Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" Comment: *" Annotation:"" Sample Index: 100 sample Type: Unknown concentration: N/A calculated Cone: 162. Acq. Date: 11/24/2010 Acq. Time: 3:21:43 AM ng/mL Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 Area: Height : start Time : End Time : 1.14e006 cps 9.765 min 11.278 min I Sample Name: "s101122a101" Sample ID: "GLP10-01-02-05-059 DAL S S SS 08 0 0000 " Peak Name: "PFHS" Mass(es): "399.0/99.0 am u.399.0/80.0 amu" I Comment *" Annotation: " Sample Index: 101 Sample Type: Unknown Concentration: N/A Calculated cone: 5.55 ng/mL Acq. Date: 11/24/2010 Acq. Time: 3:45:57 AM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes NO Int. Type: Manual Retention Time: 10.392 min Area: 575085 counts Height: 3.99e+004 cps Start Time: 9.765 min End Time: 11.036 min Printing Time: 5:48:04 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 71 of 321 Page 256 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 257 of 962 *Stan V1660305 I Sample N am e: *s101122a106* Sam ple IO: "G LP 10-01-02-05-060 LMS DAL S S S S 08 DB 0000 Lab M atrix S p ike ' | Peak Name: "PFHS* Mass(es): *399.0/99.0 amu,399.0/80.0 amu" m Comment: Annotation: "* sample index: 106 sample Typ e : Unknown Concentration: N/A Calculated Cone: IS.6 ng, Acq. Date: 11/24/2010 Acq. Time: 5:47:16 AM File: "s1 01 12 2a w ifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.388 min Area: 1577621 counts Height : 1.08e+OOS cps Start Time: 9.755 min End Time : 11.046 min Results Name: sl01122a.rdb [ Sample Name: "s101122a107" Sample ED: "GLP10-01-02-05-061 DAL S S SS06 0 0005 Peak Name: "PFHS' Mass(es): "399.0/99.0 am u.399.0/80.0 amu' 1 C omment *" Annotation: ** Sample Index: 107 Sample Type: Unknown Concentration: N/A Calculated Cone : 1.90 ng/mL Acq. Date: 11/24/2010 1.3e4- Acq. Time: 6:11:32 AM Modified: RT window: Expected RT: Use Relative RT : Yes 30.0 10.6 NO sec min 1.2e41.1e4- Int. Type: Manual Retention Time: 10.388 min Area: 206313 counts Height: 1.3 8e+004 cps Start Time: 9.755 min End Time: 10.976 min 1.0e49 0 0 0 .0 8 0 0 0 .0 - I Sample Name: "s101122a108" Sample ID: "GLP10-01-02-05-061 Dup DAL S S S S 06 0 0005 Duplicate " Peak Name: "PFHS" Mass(es): *399.0/99.0 amu,399.0/80.0 amu* C omment -- Annotation: "* Sample Index: 108 Sample Type: Unknown Concentration: N/A Calculated cone : 1.70 ng, Acq. Date: 11/24/2010 Acq. Time: 6:35:44 AM File: "s101122a.w tr Modified: RT window: Expected RT: Use Relative RT : res 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.380 min Area: :188708 counts Height: 1.19e*004 cps Start T i m e : 9.725 min End Time: 11.006 min 10 12 992 1191 ______Time, min I Sample Name: "s101122a109" Sample ID: "GLP10-01-02-05-061 LMS DAL S S SS08 0 0005 Lab Matrix Spike" File: "s101122a.wiff Peak Name: *PFHS" Mass(es): *399.0/99.0 am u.399.0/80.0 amu* I C om m en tA n no tatio n : Sample Index: 109 sample Type: Unknown Concentration: N/A Calculated cone: 12.3 ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:00:00 AM Modified: RT Window: Expected RT: Use Relative RT: res 30.0 10.6 No sec min Int. Type: Manual Retention Time 10.381 min Area: 1217004 counts Height : 9.54e +004 cps start Time 9.78S min End Time: 11.056 min Printing Time: 5:48:07 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 73 of 321 Page 258 of 962 *Stan V166030S Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 259 of 962 *Stan V1660305 I Sample Name: "s101122a114" Sample ID: "EC -101116-06 5 ng Extracted Curve Point" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399,0/80.0 amu" I Com m ent Annotation: "" Sample Index: Sample Typ e : 114 oc concentration: 5.00 ng/mL Calculated cone: 5.10 ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:01:07 AM File: "s101122a.wifr Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: Min. Peak Width: 0.00 0.00 cps sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Valley Retention Time: 10.391 min Area: S53365 counts Height: 4.62e+004 CpS Start Time: End Tim e : 10.108 min 1 0 .986 min Results Name: sl01122a.rdb [ Sample Name: ` s101122a11Sn Sample ID: "10 006-25 solvent blank" File: "s101122a.wifT Peak Name: "PFHS* Mass(es): "399.0/99.0 amu,399.0/80.0 amu* SamCpolmemIenndt e""x: Annotat1io1n5: "" Sample Type: Double Blank concentration : 0.00 ng/mL calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 9:25:25 AM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type: Retention Time Area: Height: start Time: End Time : Valley 10.623 min 22S counts 6.74e*001 cps 10.S12 min 10.663 min I Sample Name: "s101122a116" Sample ID: "GLP10-01-02-05-063 DAL SS SS09 0 0005 " I Peak Name: "PFHS" Mass(es): "399.0/93.0 amu,399.0/80.0 amu" 1 Comment: "" Annotation: "" Sample Index: 116 sample Type: Unknown Concentration: N/A Calculated Cone 4.52 ng/mL Acq. Date: 11/24/2010 3.2e4 Acq. Time: 9:49:42 AM 3.0e4 Modified: RT window: Expected RT: use Relative RT Yes 30.0 10.6 No sec min 2.6e4 2.6e4 File: "s101122a.w ifr Int. Type: Manual Retention Time: 10.397 min Area: 502093 counts Height: 3.39e +004 cps Start Time: 9.755 min End Tim e : 11.097 min 2.4e4 2.2e4 2.0e4 - 1.8e4 & o -- 1.4e4 1.2e4 1.0e4 6000.0 6000.0 4000.0 2000.0 0.0 Printing Time: 5:48:11 PM Printing Date: Friday, January 07, 2011 X0.02s. 14.2SJ4.61 16.18 992 1191 Tim e, min 17.93 19 36 20.64-21.13 20 1984 22 2162 h Sample Name: "s101122a117" Sample ID: "GLP10-01-02-05-063 Dup O A L S S SS09 0 0005 Duplicate " Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" 1 C omment "" Annotation: "" Sample Index: 117 Sample Type: Unknown Concentration: N/A Calculated Cone : S .05 ng/ Acq. Date: 11/24/2010 Acq. Time: 10:13:58 AM File: " s1 01 12 2a .w ir Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 10.6 No sec min Int. Type: Manual Retention Time: 10.374 min Area: 525148 counts Height: 3.69e*004 cps start Time: 9.745 min End Time: 10.996 min Page 75 of 321 3M Study GLP10-01-02 Interim Report 05 Page 260 of 962 Stan V1660305 Results Name: slOH22a.rdb Printing Time: 5:48:13 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 76 of 321 Page 261 of 962 Stan V1660305 I Sample N a m e :-81011223122" Sample ID: "G LP10-01-02-05-065 D A L S S G P 0 1 0 0 0 0 5 ' Peak N am e: "P F H S ' M ass(es): "399.0/99.0 amu,399.0/80.0 am u' C om m ent:"" Annotation:"" sample index: 122 Sample Typ e : Unknown Concentration: N/A Calculated cone: 7.83 n< Acq. Date: 1 1 /24/2010 Acq. Time: 12:15:12 PM Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 10.6 File: "s 1 01 12 2a .w iff Int. Type : Manual Retention Time 10.405 min Area: 741136 counts Height : S.3Se*004 cps Start Time : 9.755 min End Time : 10.905 min Results Name: slOH22a.rdb I Sam ple Name: "s101122a123" Sam ple ID: "GLP10-01-02-05-065 D up D AL S >GP01 0 0005 Duplicate ' Peak Name: "PFHS" Mass(es): "399.0/99.0 am u.399.0/60.0 amu" m Comment "" Annotation: Sample Index: 123 Sample Type: Unknown Concentration : N/A calculated Cone:: 10.6 ng/ Acq. Date: 11/24/2010 Acq. Time: 12:39:26 PM File: "s101122a.wifT Modified: RT Window: Expected RT: use Relative RT:: Yes 30.0 10.6 NO sec min Int. Type : Manual Retention Time: 10.397 min Area: 1022457 counts Height : 7.08e+004 cps start Time: 9.74 5 min End Time: 10.976 min I Sam ple Name: "s101122a124" Sam ple ID: ' G IP 10 -01-02-05-065 LMS D AL S S GP01 0 0005 Lab Matrix S pike" I Peak N ame: "PFHS" Mass(es): " 399.0/99.0 amu.399.0/80.0 amu" m C o m m e n t Annotation: "" Sample Index: 124 Sample Type: Unknown Concentration : N/A Calculated Cone: 25.4 ng/ Acq. Date: 11/24/2010 Acq. Time: 1:03:43 PM File: "s101122a.w ifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 No sec min Int. Type : Manual Retention Time: 10.391 min Area: 2408221 counts Height : 1.84e+OOS cps start Time: 9.755 min End Time : 11.077 min Sam ple N ame: " s101122a125" Sam ple ID: ' GLP10-01-02-05-066 D AL SS GP01 0 0020 ' Peak Name: "PFHS* Mass(es): "399.0/99.0 amu.399.0/80.0 amu" Comment "" Annotation: Sample Index: 12S Sample Type: Unknown Concentration: N/A Calculated Cone: 12.5 ng/ Acq. Date: 11/24/2010 Acq. Time: 1:28:03 PM File: "s101122a.w ifT Modified: RT Window; Expected RT: use Relative RT:: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.386 min Area: 1247032 counts Height: 8.36e+004 cps Start Time: 9.725 min End Time : 11.046 min Printing Time: 5:48:15 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 77 of 321 Page 262 of 962 `Stan V16 603 05 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 263 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 264 of 962 Stan V1660305 I Sample Name: "s101122a134" Sam ple ID: *GLP10-01-02-05-068 D AL S S GP02 0 0 000 " Peak Name: "PFHS* Mass(es): *399.0/99.0 amu.399.0/80.0 amu* Comment: " Annotation: - Sample Index: 134 Sample Type: Unknown Concentrt ion : N/A calculated cone: 0.232 ng, Acq. Date: 11/24/2010 Acq. Time: 5:06:41 PM File: *s101122a.wnfT Modified: RT Window; Expected RT: Use Relative RT: Yes 30.0 10.6 NO sec min Int. Type: Retention Time: Area : Height : Start Time : End Time: Manual 10.402 min 26728 counts 1.81e-f003 cps 9.785 min 10.865 min Results Name: sl01122a.rdb I Sam ple Name: *s101122a135* Sample ID: 'G LP 10-01-02-05-068 D up D AL S S G P02 0 0000 D uplicate * Peak Name: 'P FHS * Mass(es): *399.0/99.0 amu.399.0/80.0 amu" C om m en t "* Annotation: ** sample Index: 13S Sample Type: Unknown Concentration: N/A Calculated Cone: 0.249 ng/mL Acq. Date: 11/24/2010 Acq. Time: 5:31:02 PM File: "s10 11 22 a.w ifr Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 10.6 Int. Type: Retention Time: Area: Height: Start Time: End Time: Manual 10.332 min 31271 counts l .9Se+0 03 cps 9.816 min 10.905 min Sample Name: "s101122a136" Sam ple ID: "GLP10-01-02-05-068 LMS DAL Peak Name: "P FHS " Mass(es): " 399.0/99.0 am u.399.0/80.0 amu* Comment: " Annotation: Sample Index: 136 Sample Type: Unknown Concentration: N/A calculated cone: 2.11 ng/mL Acq. Date: 11/24/2010 Acq. Time: 5:55:17 PM S GP02 0 0000 Lab Matrix Spike" File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - Iq a M in. Peak Height: o . o o cps Min. Peak width: o . o o sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: No Area: Height : Start Time: End Time: 1.71.004 10.169 11.016 Printing Time: 5:48:20 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 I Sam ple Name: " s101122a137" Sam ple ID: 'G LP10-01-02-05-069 DAL SS G P02 0 0 005 " I Peak Name: ` PFHS* Mass(es): *399.0/99.0 amu.399.0/80.0 amu" m C om m ent "* Annotation: "" Sample Index: 137 Sample Type: unknown Concentration: N/A Calculated Cone 0.0892 ng/mL 1000 Acq. Date: Acq. Time: 11/24/2010 6:19:34 PM 950 File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 10.6 NO sec min 900 650 800 Int. Type: Retention Time: Area: Height: Start Time: End Time: Manual 10.387 min 13646 counts 1.04e+003 cps 9.816 min 10.824 min 750 700 650 600 * Page 80 of 321 992 1191 1389 1587 1785 1984 2182 _____ Time, min________________________________ __ _____________ Page 265 of 962 Stan V1660305 I Sample Name: Ms101122a138" Sample 10: "G LP10-01-02-05-069 D up D AL S S G P 02 0 0005 Duplicate " | Peak Name: "PFHS" M ass(es): "399.0/99.0 amu,399.0/80.0 amu" m Comment: "" Annotation: "" sample Index: 138 Sample Type: Unknown Concentration: N/A calculated Cone: 0.122 ng, Acq. Date: 11/24/2010 Acq. Time: 6:43:52 PM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Ye 3 30.0 10.6 NO sec min Int. Type : Retention Time: Area: Height : start Time: End Time: Manual 10.412 min 16379 counts 1.16e+003 cps 9.795 min 10.895 min I Sample Name: "s101122a140" Sample ID: " GLP10-01-02-05-070 D A L S I G P 02 0 0 020 " I Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/B0.0 amu' 1 Comment: "" Annotation: "" Sample Index: 140 Sample Type: Unknown Concentration: N/A Calculated cone:: 0.141 ng/mL 1100- Acq. Date: 11/24/2010 A c q . Time : 7:32:21 PM 1000- Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 10.6 NO sec min 900- File: " s10 11 22 a.w iT Int. Type : Manual Retention Time: 10.401 min Area: 17387 counts Height : I.12e+003 cps Start Time-. 9.785 min End Time: 10.925 min 800- 700- y- 60 0 500- 400- 300- 200- 1000- -.1 i t, m Printing Time: 5:48:22 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb [Sample N ame: " s101122a139" Sample ID: "GLP10-01-02-05-069 LMS DAL S S GP02 0 0005 Lab Matrix S pike" Peak Name: " PF H S" M ass(es): "399.0/99.0 amu,399.0/80.0 amu" SamCpolmemIenndt e""x: Annotat1io3n9: "" Sample Type: Unknown Concentration: N/A calculated Cone: 2.00 ) Acq. Date: 11/24/2010 Acq. Time: 7 :OB :06 PM File: "s10 11 22 a.w iff Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak*Split. Factor: 9 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: o . o o sec Smoothing Width: 3 points RT Window: 30.0 Expected RT: 10.6 Use Relative RT: No Int. Type : Base To Base Retention Time: 10.391 min Area: 224757 counts Height : i.70e+004 cps Start Time: 9.846 min End Time: 1 1 . 0 2 6 min ISample Name: "s101122a141" Sample ID: "G LPt0-01-02-05-070 D up DAL S I GP02 0 0020 D uplicate ' Peak N ame: "P F H S " M ass(es): "399.0/99.0 amu,399.Q/80.0 amu" SamCpolmemIenndt e""x: Annotat1io4n1: "" Sample Type: Unknown Concentration: N/A calculated cone: 0.144 ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:56:39 PM Tim e jj File: Hs10 1t22 a.w ifT Modified: RT Window: Expected RT: U3e Relative RT: Yes 30.0 10.6 No sec min Int. Type: Retention Time: Height: Start Time: End Time: Manual 10.353 min 17603 counts 1.4 7e+0D3 Cps 9.826 min 10.794 min Page 81 of 321 Page 266 of 962 *Stan V1660305 I Sample Name: "s101122a142" Sample ID: "G LP10-01-02-05-070 LM S DAL S S GP2 0 0020 Lab M atrix S pike" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" Comment: Annotation: ~ Sample Index: 142 Sample Type: Unknown Concentration: N/A calculated cone: 2.03 ng/mL Acq. Date: 11/24/2010 Acq. Time: 8:20:S6 PM File: "s101122a.w ifT Modified: No Proc. Algorithm: intelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec smoothing width: 3 points RT window: 30.0 sec Expected RT: 10.6 min use Relative RT: No Area : Height : Start Time: End Time : man 198519 counts 1.60e +004 cps 10.209 10.855 min Results Name: sl01122a.rdb I Sam ple N am e: "s101122a143" Sam ple ID: "GLP1D-01-02-05-071 D AL S S G P 02 DB 0020 " I Peak Name: " P F H S " M---a--s--s--e--s--)-:---"3--9--9--.-0--/-9--9--.-0 am u.3--9--9--.-0--/-8--0--.-0 am u' I (C o m m e n t "* Annotation: "" sample index: 143 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.114 ng/mL Acq. Date: 11/24/2010 Acq. Time: 8:45:11 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 1 0 . 6 min Use Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: valley 10.360 min 14670 counts i.iSe*O03 cps 10.239 10.784 min JSample Name: "s101122a144" Sample ID: "GLP10-01-02-05-071 D u p D A L S S GP02 DB 0020 D uplicate " Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" C om m ent - Annotation: Sample Index: 144 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.156 ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:09:27 PM File: "s1 01 12 2a .w ifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time : End Time : Valley 10.381 min 17445 counts l.S2e+003 cps 10.189 min 10.794 min I Sam ple N ame: "s101122a14S" Sample ID: "G LP10-01-02-05-071 LMS DAL SS GP02 DB 0020 Lab Matrix S pike" Peak Name: "P F H S " M ass(es): "3 99.0/99.0 am u.399.0/80.0 amu" C om m ent Annotation: "" Sample Index: 145 Sample Type: Unknown Concentration : N/A ACcaql.culDaattee:d Cone: 11/22.40/12010 ' A c q . Time : 9 :33 :S0 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: O.OD sec Smoothing width: points RT Window : Expected RT: use Relative RT: Area: Height: Start Time: End Time : 198023 counts 1 .46e*004 cps 10.209 min 10.834 min Printing Time: 5:48:24 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 82 of 321 Page 267 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:48:26 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 83 of 321 Page 268 of 962 *Stan V1G60305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 269 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 270 of 962 Stan V1660305 Results Name: s l O H 2 2 a .rdb Printing Time: 5:48:31 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 86 of 321 Page 271 of 962 Stan V1660305 I Sam ple Name: "s101122a162" Sam ple ID: "G LP10-01-02-05-076 D up D AL SS G P 03 DB 0020 D uplicate Peak Name: "P F H S " Mass(es): '3 99 .0/99 .0 am u,399.0/B0.0 a m u ' I Comment: Annotation: "" Sample Index: 162 Sample Type: Unknown Concentration: N/A Calculated Cone 564 . ng/mL Acq. Date: 11/25/2010 2.1e6 2.0e6 Acq. Time: 4 :26 :S4 AM 1,9e6 Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 10.6 NO sec min 1.8e6 1.7e6 1,6e6 Int. Type: Manual Retention Time: 10.371 min Area: Height : 39526876 counts 2 .1 2e+006 cps start Time : 9.725 min End Time : 11.208 min 1.5e6 1,4e6 1.3e6 w 1.2e6 I Sam ple Name: "s101122a164" Sample ID: "GLP10-01-02-0E I Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 C o m m e n t " Annotation: "" Sample Index: 164 Sample Type: Unknown Concentration: N/A calculated Cone: 73.8 ng/ Acq. Date: 11/25/2010 Acq. Time: 5:15:24 AM Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.376 min Area: 7376304 counts Height : 4.60e+005 cps Start Time: 9.705 min End Time: 11.188 min Printing Time: 5:48:33 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I B Sample Name: "s101122a163" Sam ple ID: "GLP10-01-02-Q5-076 LM S D AL S ; GP03 DB 0 020 Lab Matrix Spike" " Peak N ame: "PFH S" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" Com m ent "" Annotation: "" Sample Index: 163 Sample Type: Unknown Concentration : N/A Calculated Cone : 1 2 2 0 . ! Acq. Date: 11/25/2010 Acq. Time: 4 :SI :09 AM File: "s101122a.wifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 10.6 No sec min Int. Type : Manual Retention Time : 10.375 min Area: 71223605 counts Height : 3 ,72e*006 cps Start Time: 9.71S min End Time : 11.460 min Sam ple Name: "s101122a165" Sam ple ID: "GLP10-01-02-05-077 Dup D AL S S GP03 0 0050 Duplicate " Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" 1 Com m ent "" Annotation: "" Sample Index:: 165 Sample Type: Unknown Concentratici1: N/A Calculated Cone: 73.8 ng/ Acq. Date: 11/25/2010 Acq. Time: S :39 :44 AM File: "s101122a.w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.390 min Area: 7383685 counts Height : 4 ,60e*005 cps start Time: 9.715 min End Time : 11.157 min Page 87 of 321 Page 272 of 962 Stan V1660305 ISample Name: "s101122a166" Sample ID: "GLP10-01-02-05-077 LMS DAL SS GP03 0 0050 Lab M atrix S pike* Peak Name: "PFHS" M ass(es): *399.0/99.0 amu,3 99.0/80.0 amu* samCpolmemeInntd: ex: Annotat1io6n6: "" sample Type : Unknown concentration : N/A Calculated Cone: 176. ng/mL Acg. Date: 11/25/2010 Acg. Time: 6:04:01 AM File: " s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 sec min Int. Type : Retention Time: 383 min Area : 16246310 counts Height : i.09e+oo6 cps Start Time 9.73S min End Time: 11.137 min Results Name: slOH22a.rdb I Sample N ame: *s101122a167* Sam ple ID: *10 006-25 solvent blank" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" Com m ent Annotation: " sample Index: 167 Sample Type: Double Blank File: "s101122a.wifT nSample Name: *$101122a168* Sample ID: *0-10 11 16 -0 6 5 ng Extracted C urve Point* Peak Name: *PFHS* Mass(es): *399.0/99.0 amu,3 99.0/80.0 amu* Comment: Annotation: "" Sample Index: 168 Sample Type : oc Concentration : 5.00 ng/mL Calculated cone: 5.29 ng/mL 4.2e4 Acg. Date: Acg. Time: 11/25/2010 6:52:35 AM 4.0e4 Modified: NO Proc. Algorithm: IntelliQuan - Iq a Min. Peak Height : 0.00 cps Min. Peak Width: .00 sec 3.8e4 3.6e4 3.4e4- Smoothing Width: RT Window: Expected RT: Use Relative RT: 3 30.0 10.6 NO points sec min 3.2e4 3.0e4 2.8e4 File: *s101122a.w ifT' Int. Type : valley Retention Time: 10.380 min Area: 559995 counts Height : 4.35e*004 cps Start Time: 10.169 min End Time: 11.087 min 2.6e4 2.4e4 2.2e4 2.0e4 1.8e4 1.6e4 1.4e4 1.2e4 1.0e4 8000.0 6000.0 4000.0 2000.0 6.17 0.0 Printing Time: 5:48:34 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 I Sample N ame: Hs101122a169" Sample ID: *10 006-25 solvent blank" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu' C o m m e n t"" Annotation:"" Sample Index: 169 Sample Type: Double Blank File: "s101122a.wifT Page 88 of 321 Time, min Page 273 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 274 of 962 *Stan V1660305 (Sample Name: "s101122a174" Sample ID: "G LP10-01-02-05-079 D up D AL S I GP04 0 0005 Duplicate " Peak Name: ' PFHS" Mass(es): "399.0/990 amu,399.0/80.0 amu* Comment: - Annotation: ~ Sample Index: 174 Sample Type: Unknown Concentration: N/A Calculated Cone: 1.76 ng/mL Acq. Date: 11/25/2010 1.20e4- Acq. Time: 9:16:26 AM Modified: RT Window: Expected RT: Use Relative RT: Tea 30.0 10.6 No 1.10e4 1.00e4 File: "s 1 0 1 1 2 2 a .w tr Int. Type : Manual Retention Time: 10.387 min Area: 193207 COUntS Height : 1.30e+004 cps Start Time 9.765 min End Time : 10.905 min 9 0 0 0 .0 0 e o o o .o o I 7000.00 : 6000.00 5000.00 4000.00 3000.00 2000.00 1000.00 0.00 I Sample Name: "s101122a176" Sample ID: "G LP10-01-02-05-080 D AL S S GP04 0 0 020 " Peak Name: "PFHS" Mass(es): " 399.0/99.0 amu.399.0/80.0 amu" I Comment: "" Annotation: " Sample Index: 176 Sample Type: Unknown Concentration: N/A calculated cone: 4.34 ng/mL Acq. Date: 11/25/2010 Acq. Time: 10:07:03 AM 992 1191 Time, min File: "s l0 1 1 2 2 a .w rff Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 10.6 NO sec min Int. Type: Manual Retention Time: 10.376 min Area: 48S743 counts Height: 3.40e*004 cps Start Time 9.725 min End Time: 11.077 min Results Name: sl01122a.rdb ISample N ame: " s101122a175" Sample ID: "G LP10-01-02-05-079 LMS DAL S ; GP04 0 0005 Lab M atrix Spike" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu, 399.0/60.0 amu* samCpolmemIenndt e"*x: Annota1tio7n5: -- Sample Type: Unknown Concentration: N/A Calculated Cone: 12.1 ng/mL Acq. Date: 11/25/2010 Acq. Time: 9:42:42 AM File: "s1 0 11 22 a.w ifr Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 10.366 min Area: 1280436 counts Height: 1.02e*OOS cps Start Time: 9.775 min End Time: 11.147 min I Sam ple Name: " s101122a177" Sam ple ID: "GLP10-01-02-05-080 D up DAL S S GP04 0 0 020 D uplicate ' P eak N ame: 'P F H S " M ass(es): "399.0/99.0 amu,399.0/80.0 amu" I C om m en t "" Annotation: Sample Index 177 sample Type: Unknown Concentration: N/A Calculated Cone: Acq. Date: I A c q . Time : File: "s1 01 12 2a .w ifr Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 10.6 Int. Type: Manual Retention Time: 10.379 min Area: 633973 counts Height: 4.04e+0 04 start Time 9.705 End Time: 11.157 Printing Time: 5:48:38 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 90 of 321 Page 275 of 962 Stan V1660305 I Sample Name: "s101122a178" Sample ID: "G LP10-01-02-05-080 LMS DAL S S G P04 0 0020 Lab M atrix Spike" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" Comment: "" Annotat1io7n8: Sample Index: Unknown Sample Type: N/A Concentrt ion : 16.6 ng/mL Calculated Cone: 11/25/2010 Acq. Date: 10:55:38 AM Acq. Time: Modified: RT Window; Expected RT: Use Relative RT: Yes 30.0 10.6 No sec min File: "s1 01 12 2a .w ifr , Int. Type: Manual Retention Time:171251802.385 counts Area: 1.25e+005 cps Height : 9.755 min start Time : 11.127 min End Time: Results Name: slOH22a.rdb I Sample Name: "s101 12 2a !7 9" Sample ID: "M B-101116-07 M ethod B lank 5g w / IS for D ilu tions' Peak Name: "PFHS" Mass(es): "399.0/99.0 amu, 399.0/60.0 amu" C om m en t '*" A n no ta tion :"" sample Index: 179 Sample Type: Unknown Concentration: N/A calculated Cone: 0.000219 n Acq. Date: 11/25/2010 Acq. Time: 11:19:55 AM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing Width: points RT window: sec Expected RT: min Use Relative RT: File: "s101122a.w iff' Int. Type: valley Retention Time: 10.502 min Area: 3518 counts Height: 2.83e*002 cps Start Time: 10.249 End Time: 10.673 min ( Sample Name: "s101122a180" Sample ID: "MB-101116-08 M ethod Blank 5g w/ IS fo r D ilutions" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/80.0 amu" Comment: Annotation: Sample Index: ISO Sample Type: Unknown Concentration: n /a Calculated Cone: 0.00399 ng/mL Acq. Date: 1 1 /25/2010 Acq. Time: 11:44:14 AM File: "s101122a.w iff' Modified: No MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- IQA Min. Peak width: sec Smoothing w id th : points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 10.350 min 3837 counts 4.40e+002 10.270 10.693 (Sample Name: "s101122a161" Sample ID: "10 006-25 solvent blank" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu.399.0/60.0 amu" C o m m e n t"" Annotation: Sample Index: 181 Sample Type: Double Blank concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 12:08:37 PM Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps M i n . Peak width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: Use Relative RT: File: Ns101122a.w ifr Int. Type: Valley Retention Time: 10.592 min Area: 206 counts Height: 1 .2 1 e*002 cps start Time: 10.562 min End Time: 10.633 min Printing Time: 5:48:40 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 91 of 321 Page 276 of 962 *Stan V1660305 [Sample Name: -*1011228182" Sample ID: "E C -1 01116-07 10 ng Extracted C urve Point" Peak Name: "PFHS" Mass(es): "399.0/99.0 am u,399.0/80.0 amu" SamCpolmem eInntd: e- x: Annota1tio8n2: Sample Type: QC Concentration: 10.0 ng/mL Calculated Cone: 9.72 ng/mL Acg. Date: 11/25/2010 Acg. Time: 12:32:55 PM File: "s 1 0 1 1 2 2 a .w ir Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: Min. Peak width: 0.00 0.00 cps sec Smoothing width: 3 points RT Window: Expected RT: 30.0 sec 1 0 . 6 min use Relative RT: Area: Height : Start Time: End Time : 1024849 counts 8.24e*004 cps 10.138 min 11.127 min I Sam ple Name: "s 1 0 1 1 2 2 a 0 0 r Sample ID: "1 0 006-25 s olvent blank" File: ,,s101122a.w iff' Peak Name: "PFO S" Mass(es): "499.0/80.0 am u,499.0/99.0 amu,499.0/130.0 amu" I Comment: " Annotation: "" Sample Index: Sample Type : Double Blank Concentration: 0.00 ng/mL calculated cone: N/A Acg. Date: 11/22/2010 Acg. Time: 11:23:16 AM Modified: NO Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.6 min ,, Use Relative RT: No Int. Type: Base To Base Retention Time: 13.588 min Area: 31 counts Height : 2.48e+00l cps Start Time: 13.568 min End Time : 13.619 Printing Time: 5:48:42 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: ns101122a183" Sample ID: "10 006-25 s olvent blank" Peak Name: "PFHS" Mass(es): "399.0/99.0 amu,399.0/80.0 amu" C o m m e n t"" Annotation: -- Sample Index: 183 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: n /a Acg. Date: 1 1 /25/2010 Acg. Time: 12:57:18 PM File: "s 1 0 1 1 2 2 a .w ir Modified: No MPirno.c. PAelagkorHietihgmht:: IntelliQuancps- IQA Min. Peak width: sec Smoothing Width: points RT Window: sec Expected RT: use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 1 0 . 4 0 1 min 627 counts 1.51e*002 cps 10.320 10.552 min ISam ple Name: "s101122a002" Sample ID: "10 006-25 s olvent blank" File: "s101122a.wifT Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" C o m m e n t -- Annotation: -- Sample Index: Sample Type: Double Blank D Concentration: 0.00 ng/mL B Calculated Cone: N/A | Acq. Date: 11/22/2010 U Acg. Time: 11:47:30 AM Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 : Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec - Smoothing Width: 3 points RT Window: 30.0 se Expected RT: 13.6 mi Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End T ime: Base To Base 13.518 min 12 counts 8. B9e+000 cps 13.498 min 13.609 min Page 92 of 321 Page 277 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 278 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:48:46 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 94 of 321 Page 279 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 280 of 962 Stan V1660305 I Sample Name: "s101122a015" Sample ID: "EC-101116-06 5 ng Extracted Curve P o in f Peak Name: "PFOS" Mass(es): *499.0/80.0 amu,4 99.0/99.0 am u.499.0/130.0 amu* I Comment: ~ Annotation: Sample Index: 15 Sample Type: standard Concentration: 5.00 ng/mL calculated Cone: 5.72 ng/mL Acq. Date: 11/22/2010 Acq. Time: 5:01:52 PM File: ''s101122a,wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQI1 Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: c cps Min. Peak width: c sec Smoothing Width: points RT Window: 30.0 Expected RT: Use Relative RT: NO Int. Type: Valley Retention Time: 13.235 min Area: 213451 counts Height: 1.99e+004 cps Start Time: 12.731 min End Time: 13.528 min Samp| le Name: "s101122a017" Sample ID: "EC-101116-08 25 ng Extracted C urve Point" I Peak Name: *PFOS" Mass(es): *499.0/80.0 amu,4 99.0/99.0 am u.499.0/130.0 amu" Commiment '** Annotation: Sample Index: 17 Sample Type: Standard Concentration: 25.0 ng/mL Calculated Cone: 25.2 ng/mL Acq. Date: 11/ 22/2010 Acq. Time: 5:50:14 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: Base. Sub. window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: epa Min. Peak width: sec Smoothing width: points RT Window; 3 Expected RT: Use Relative RT: Area: Height : Start Time: End Time : 9.17e*004 12.973 13.548 inting Time: 5:48:50 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 10 12 14 992 1191 1389 Time, min___________ Results Name: sl01122a.rdb I Sample Nam e:*s101122a016" Sample ID: "EC-101116-07 10 ng Extracted Curve Po in f Peak Name: *PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" C o m m en t"" Annotation:"" j Sample Index: 9 Sample Type: 16 Standard Concentration: 10.0 ng/mL Calculated Cone: 10.4 ng/mL Acq. Date: 11/22/2010 Acq. Time: 5:26:01 PM File: "s101122a.wifr (Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No cps Min. PMiena.k WPiedatkh:Height: o .oo 0.0s0ec Smoothing width: points RT Window: Expected RT: Use Relative RT: Int. Type: Valley Retention Time: 13.245 min Area: 391448 counts Height : .98e*004 Cps Start Time: 12.953 min End Time : 13.508 min I Sample Name: "s101122a018" Sample ID: "EC -101116-09 50 ng Extracted Curve P oinr | Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" 1 Comment "" Annotation:"" Sample Index: Sample Type: Standard Concentration: 50.0 Calculated Cone: 52.1 Acq. Date: 11/22/2010 Acq. Time: 6:14:25 PM 992 1191 Time, min File: "s101122a.wjff' Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 i Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No s* l.jeo 1.2eS 1.1e5 1.0e5 Int. Type: Valley Retention Time: 13.22S min Area: 2064859 counts Height: 1 87e*005 cps Start Time: 12.953 min End Time : 13.740 min 9 0e4 8.064 7.064 6.0e4 5.0e4 4.0e4 3.064 2.0e4 1.0e4 Page 96 of 321 992 1191 _____ Tim e, min Page 281 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 282 of 962 *Stan V166030S Results Name: sl01122a. Study GLP10-01-02 rim Report 05 Page 283 of 962 *Stan V1660305 I Sample Name: "s101122a027" Sample ID: "MB-101116-02 Method Blanlc2w/o IS' Peak Name: "PROS' Mass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu* I Comment: ~ Annotation: Sample Index: 27 Sample Type: Double Blank Concentration : 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:52:06 PM File: "s1 0 1 1 2 2 a .w ir Modified: RT window: Expected RT: uae Relative RT: Yes 30.0 13.2 NO sec min Int. Type : Retention Time: Area: Height : Start Time: End Time : Manual 13.238 min 3845 counts 2.70e*002 cps 12.247 min 13.387 min Sample Name: "s101122a029" Sample ID: "M B-101116-04 Method Blank 4 w / IS' File: "s101122a.wifT m| Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,4 99.0/130.0 amu' Comment: Annotation: Sample Index: 29 Sample Type: Unknown Concentration: N/A Calculated Cone: 0.0576 ng, Acq. Date: 11/22/2010 Acq. Time: 10:40:35 PM Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13 .2 NO sec min Int. Type: Manual Retention Tim e : 13.242 min Area: 7551 counts Height: 5.60e*002 cps Start Time: 12.065 min End Time: 13.387 min Printing Time: 5:48:55 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb Sam ple Name: "s101122a028" Sam ple ID: "M B-101116-03 M ethod Blank 3 w /o IS' Peak Name: "PROS' M ass(es): ` 499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu* I C om m en t "" Annotation: " Sample Index: 28 sample Type: Double Blank concentration: 0.00 ng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 10:16:21 PM File: "s1 01 12 2a .w ifr Modified: RT window: Expected RT: use Relative RT: Yes 30.0 13.2 No sec min Int. Type: Manual Retention Time: 13.210 min Area: 5234 counts Height: 3.lle*002 cps Start Time: 12.136 min End Time: 13.467 min I Sample Name: "s101122a030" Sample ID: "M B-101116-05 Method Blank 5 w / IS' File: "s101122a.wifr m| Peak Name: "PROS* Mass(es): "499.0/80.0 am u.499.0/99.0 amu, 499.0/130.0 amu" Comment ~ Annotation: " sample Index: 30 sample Type: Unknown Concentration: N/A Calculated Cone 0.0166 ng/mL 360 Acq. Date: 11/22/2010 Acq. Time: 11:04:46 PM 340 Modified: RT window: Expected RT: Use Relative RT Yes 30.0 13.2 NO sec min Int. Type: Retention Time: Area: Height: start Time: End Time: Manual 13.214 min 5467 counts 3.4 0e+ 002 cps 12.136 min 13.498 min 320 300 280 260 240 220 Page 99 of 321 20 1984 22 2182 Page 284 of 962 Stan V1660305 I Sam ple Name: "s101122a031" Sample ID: "M B-101116-06 M ethod Blank 6 w / ISM File: Hs 1 0 11 22 a.w iff I Peak Name: "PFO S" M ass(es): "499.0/60.0 a m u.499.0/99.0 am u.499.0/130.0 amu" 1 Comment: "" Annotation: Sample Index: 31 Sample Type: Unknown Concentration: N/A Calculated Cone:' <0 Acq. Date: 11/22/201 0 Acq. Time: 11:28:57 PM Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min I n t . Type: Retention Time: Area: Height: start Time: End Tim e : Manual 13.227 min 4874 counts 2.67e+002 cps 12.106 min 13.498 min I Sample Name: "s101122a033" Sample ID: "LC S-101116-02 3 ng LCS in TCR-842" I Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu" B C omment " Annotation: "" Sample Index: 33 Sample Type: Unknown Concentration: N/A Calculated Cone : 3.21 ng( Acq. Date: 11/23/2010 Acq. Time: 12:17:22 AM File: "s101122a.wtfT Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.204 min Area: :144241 counts Height: 8.94e+003 cps Start Time: 11.964 min End Time: 13.457 min inting Time: 5:48:57 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a032" Sample ID: "LCS-101116-01 3 ng LCS in TCR-842" Peak Name: "PFOS" Mass(es): "499.0/60.0 am u.499.0/99.0 am u.499.0/130.0 amu' C o m m ent "" Annotation: "* Sample Index: 32 Sample Type : Unknown Concentration : N/A 6500 Calculated Cone.- 3.41 ng/mL Acq. Date: 11/22/2010 6000 Acq. Time: 11:53:10 PM Modified: Yes 7500 RT Window: Expected RT: 30.0 13.6 sec min 7000 Use Relative RT: No 6500 Int. Type: Manual Retention Time: 13.206 min Area : 142685 counts Height : e .74e+003 cps start Time: 11.964 min End Time : 13.659 min 6000 5500 5000 File: "s101122a.wiff 4500 4000 3500 3000 2500 2000 1500 1000 500 1.01 -U. [Sample Name: "s101122a034" Sample ID: T C S -1 0 1 116433 3 ng LCS in TCR-842" Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" B C om m ent ~ Annotation: "* Sample Index: 34 sample Type: Unknown Concentratio: N/A Calculated cone : 3.40 ng/ Acq. Date: 11/23/2010 8500 Acq. Time: 12:41:35 AM 8000 Modified: RT window: Expected RT: Use Relative RT : Yes 30.0 13.6 NO sec min 7500 7000 Int. Type: Manual Retention Time: 13.227 min Area: 150393 counts Height : 8. 99e*003 cps Start Time: 11.954 min End Time: 13.619 min 6500 6000 5500 5000 File: "s101122a.wifT 4500 4000 3500 3000 2500 2000 1500 1000 500 1191 Time, min 1389 1587 1785 1984 2162 Page 100 of 321 Page 285 of 962 Stan V1660305 I Sam ple N am e: "s101122a035" Sam ple ID: "LC S-101116-04 30 ng LCS in T C R-842" Peak Name: "PFOS" Mass(es): " 499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" I Comment: Annotation: "" Sample Index: 35 Sample Type: Unknown concentration: N/A Calculated Cone: 32.2 ng, Acq. Date: 11/23/2010 Acq. Time: 1:05:50 AM File: "$ 1 0 1 1 2 2 a .w ir Modified: RT Window; Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.201 min Area: 1361568 counts Height : 8.31e+004 cps Start Time: 11.874 min End Time : 13.669 min MrSample Name: "s101122a037" Sample ID: "LCS-101116-06 30 ng LCS in TCR-842" Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" Comment: "" Annotation: "" Sample Index: 37 Sample T y p e : Unknown Concentration: N/A . Calculated Cone: 33.7 ng, Acq. Date: 11/23/2010 Acq. Time: 1:54:19 AM File: "s101122a.w ir Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.218 min Area: 1383682 counts Height : 8.61e004 cps Start Time : 11.863 min End Time : 13.740 min Printing Time: 5:48:59 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a036" Sample ID: "LCS-101116-05 30 ng LCS in TCR-842" Peak Name: "PFOS" Mass(es); "499.0/60.0 am u.499.0/99.0 am u.499.0/130.0 amu" C omment "" Annotation:"" Sample Index: Sample Type: concentration: Unknown N/A calculated cone: 11/23/2010 Acq. Date: 1:30:03 AM Acq. Time: File: "s101122a.w(fr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.< No Int. Type: Manual Retention Time: 13.215 min Area: 1404520 counts Height: 9.oie+oo4 cps Start Time: 11.904 min End Time: 13.679 min I Sample Name: "s101122a038" Sample ID: "GLP10-01-02-05-041 DAL S S SS01 0 0000 " Peak Name: "PFOS* Mass(es): "499.0/80.0 am u.499.0/99.0 amu.499.0/130.0 amu" I Comment "" Annotation: "" sample Index: 38 Sample Type: Unknown Concentration: N/A Calculated Cone: 770. ng/mt Acq. Date: 11/23/2010 Acq. Time: 2:18:32 AM File: "s101122a.wiff Modified: RT window: Expected RT: use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time 13.218 min Area: 25091556 counts Height: 1.72e+006 cps start Time 11.853 min End Time: 14.436 min Page 101 of 321 Page 286 of 962 Stan V1660305 I Sample Name: "s101122a039" Sample ID: "G LP10-01-02-05-041 D u p D A L S S SS01 0 0000 D uplicate ' m\ Peak N am e: "P F O S " Mass(es): "499.0/80.0 amu,499.0/99.0 am u.499.0/130.0 am u" Comment: Annotation: "" sample Index: 39 sample Typ e : Unknown Concentration: N/A Calculated Cone:: 686. ng/r Acq. Date: 11/23/2010 Acq. Time: 2:42:45 AM File: "s101122a.wiT Modified: RT window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.212 min Area: Height : 122531149 counts . soe+oo6: cps Start Time : 11.904 min End Time: 13.992 min Results Name: sl01122a.rdb I Sample Name: "s101122a040" Sample ID: "GLP10-01-02-05-041 LMS DAL SS SS01 0 0000 Lab Matrix Spike" Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" C omment Annotation: "" sample Index: Unknown sample Type : N/A Concentration : 1470. ng/mL calculated cone: 11/23/2010 Acq. Date: 3 :06 :S7 AM Acq. Time: Modified: RT Window : Expected RT: use Relative RT: File: "s101122a.wifT Area: Height : Start Time: End Time: 2.7le*006 cps 11.974 min 14.113 min I Sample Name: "s101122a041" Sample ID: "10 006-25 solvent blank" File: ''s101122a.w ifr Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" Comment: "" Annotation: "" Sample Index: 41 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 3:31:11 AM Modified: Proc. Algorithm: Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: ' Expected RT: Use Relative RT: NO Cp8 sec points Int. Type : Retention Time: Height : Start Time: End Time : valley 13.225 min 19190 counts 1.70e+003 cps 13.023 min 13.609 min inting Time: 5:49:00 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 I Sample Name: "s101122a042" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" m| Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" C omment Annotation: Sample Index: 42 Sample Type : QC Concentration : 2.50 ng/mL Calculated Cone: 2.71 ng/mL Acq. Date: 11/23/2010 A c q . Time : 3:55:29 AM File: "s101122a.wtfr Modified: Yes 1.10e4 Proc. Algorithm: IntelliQuan - MQII Noise Percentage- 50 Base. Sub. Window : 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: RT window: 3 points 6000.00 30.0 sec Expected RT: 13.2 min .. use Relative RT: NO Int. Type: valley Retention Time: 13.215 min Area: 122536 counts Height: l .30e+004 cps start Time: 12.973 min End Time : 13.588 min 5000.00 4000.00 3000.00 2000.00 1000.00 0.00- Page 102 of 321 992 1191 _____ Time, min 1587 1785 1984 2182 Page 287 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 288 of 962 Stan V1660305 I Sam ple N am e: "s101122a047" Sam ple ID: 'G LP10-01-02-05-043 D AL S S SS02 0 0 000 " Peak Name; "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" I Com m ent: "" Annotation: Sample Index: Sample Type: Unknown Concentrt ion: N/A calculated cone: SSI. ng/mL Acq. Date: 11/23/2010 Acq. Time: 5:56:43 AM Fite: ''s 10 11 22 a.w iff Modified: RT Window: Expected RT: 'se Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.217 Area : 21102300 counts Height : l.30e*O06 cps start Time 11.914 min End Time: 13.911 min Results Name: s!01122a.rdb [ Sam ple N ame: "s101122a048" Sam ple ID: "GLP10-01-02-05-043 Dup D A L S S S S02 0 0 0 0 0 Duplicate " I Peak Name: "P F O S" Mass(es): "499.0/60.0 amu,4 99.0/99.0 amu.499.0/130.0 am u" Comment Annotation: "" Sample Index: 48 Sample Type: Unknown Concentration: N/A Calculated cone:: 420. ng/i Acq. Date: 11/23/2010 Acq. Time: 6:21:00 AM File: "s101122a.wifT . Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.232 min Area: 1S096531 counts Height : 9.6 9e+00Si cps Start Time: 11.904 min End Time: 13.720 min | Saimple Name: "51011223049" Sample ID: "GLP10-01-02-05-043 LMS DAL SS SS02 0 0000 Lab Matrix Spike" I Peiak Name: "PFOS" Mass(es): "499.0/60.0 amu,499.0/99.0 amu,499.0/130.0 amu" Coimment: "" Annotation: "" Sample Index: 49 Sample T ype: Unknown Concentration: N/A Calculated cone: 1500. ng/mL Acq. Date: 11/23/2010 Acq. Time: 6 :4S :12 AM File: "s101122a.wifr Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 13.226 min Area: 41127394 counts Height: 2.57e+O06 cps Start Time: 11.904 min End Time: 13.972 min ( Sample Name: "s101122a050" Sample ID: "GLP10-01-02-05-044 DAL SS SS02 0 0005 Peak Name: "PFOS" Mass(es): "499.0/60.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment "* Annotation: "* Sample index: 50 Sample Type: Unknown Concentration: calculated Cone N/A 266. ng/mL 5.0eS Acq. Date: 11/23/2010 Acq. Time: 7:09:25 AM 4.5e5 Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 13.220 min Area: 9630273 counts Height : 5.09e +005 cps start Time End Time : 11.863 min 1 3 .820 min inting Time: 5:49:03 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 104 of 321 992 1191 _____ Time, min 1389 1567 Page 289 of 962 Stan V1660305 (Sample Name: "s101122a051` Sample ID: "GLP10-01-02-05-044 Dup DAL SS SS02 0 0005 Duplicate " Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" m Comment "" Annotation: " sample Index: 51 Sample Type: Unknown Concentration: N/A Calculated Cone: 1S9 . ng/ Acq. Date: 11/23/2010 Acq. Time: 7:33:38 AM File: " s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13 .6 NO sec min Int. Type: Manual Retention Time : 13.225 min Area: 5951460 counts Height : 3.19e*005 cps Start Time: 11.853 min End Time: 13 .820 min Results Name: sl01122a.rdb ISample Name: *s101122a052" Sample ID: "GLP10-01-02-05-044 LMS DAL SS SS02 0 0005 Lab Matrix Spike" Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" m Comment "* Annotation: "" Sample Index: 52 Sample Type: Unknown Concentration: N/A Calculated Cone:: 1060. ng/i Acq. Date: 11/23/2010 Acq. Time: 7:57:52 AM File: "s101122a.wrff Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.220 min Area: 29041382 counts Height : 2 . 1 8 e *0 06 cps Start Time: 11.904 min End Time : 14.012 min I Sample Name: "s101122a053" Sample ID: "GLP10-01-02-05-045 DAL SS SS03 0 0000" Peak Name: "PFOS" Mass(es): "499.0/60.0 amu,499.0/99.0 amu,499.0/130.0 amu" Com m ent"" Annotation: Sample Index: 53 Sample Type: Unknown Concentration: N/A Calculated Cone: 2520. ng/m: Acq. Date: 11/23/2010 Acq. Time: 8:22:05 AM File: "s101122a.wiff Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 Mo sec min Int. Type: Manual Retention Time: 13.226 min Area: 74185978 counts Height: 2.62e+006 cps Start Time: 11.873 min End Time: 14.073 min I Sample Name: "s101122a054" Sample ID: "GLP10-01-02-05-045 Dup DAL SS SS03 0 0000 Duplicate " Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" I Comment Annotation: Sample index: 54 Sample Type: Unknown Concentration: N/A Calculated Cone: 2630. ng/mL Acq. Date: 11/23/2010 Acq. Time: 8:46:17 AM File: "8101122a.wifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 Mo Int. Type : Manual Retention Time 13.228 min Area: 77172875 counts Height: 2.82e +006 Cps Start Time 11.843 min End Time : 14.285 min Printing Time: 5:49:05 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 105 of 321 Page 290 of 962 *Stan V1660305 ISample Name: "s101122a055" Sample IO: "GLP10-01-02-05-045 LMS DAL SS SS03 0 0000 Lab Matrix Spike* Peak Name: *PFOS* Mass(es): *499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu* U Comment: "" Annotation: "" Sample Index: 55 Sample Type: Unknown concentration: N/A Calculated cone: 5810 . ng/mL Acq. Date: 11/23/2010 Acq. Time: 9:10:29 AM File: ~s101122a.wifr Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.210 min Area: 125367848 counts Height : S .31e +006 cps Start Time : 11.863 min End Time : 14.345 min Results Name: sl01122a.rdb I Sample Name: "s101122a056" Sample ID: "GLP10-01-02-05-046 DAL SS SS03 0 0005 * Peak Name: *PFOS* Mass(es): *499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu' I Comment "* Annotation: *" Sample Index: 56 Sample Type: Unknown Concentration: N/A Calculated Cone: 3320. ng/mL Acq. Date: 11/23/2010 Acq. Time: 9:34 :41 AM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type : Manual Retention Time: 13.217 min Area: 77701642 COUntS Height : 3.59e +006 CpS start Time; 11.863 min End Time : 13.992 min TSample Name: "s101122a057* Sample ID: "GLP10-01-02-05-046 Dup DAL SS SS03 0 0005 Duplicate ' Peak Name: " PFOS" Mass(es): *499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu* Comment: *" Annotation: sample Index: S7 Sample Type: Unknown Concentration: N/A Calculated Cone: 2810. ng/mL Acq. Date: 11/23/2010 Acq. Time: 9 :S8:S6 AM File: "s101122a.witr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 sec min Area: Height : Start Time: End Time : min counts 3.28e*006 cps 11.884 min 14.052 min I Sample Name: *s101122a058* Sample ID: ' GLP10-01-02-05-046 LMS DAL SS SS03 0 0005 Lab Matrix Spike* I Peak Name: *PFOS" Mass(es): *499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu* 1 Comment "" Annotation: "" Sample Index: 58 Sample Type: Unknown Concentration : N/A calculated Cone:: 4610. ng/mL Acq. Date: 11/23/2010 Acq. Time : 10 :23 :13 AM File: "s101122a.wiff Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.214 min Area: 100935171 counts Height : 5.2Se*006 cps Start Time: 11.793 min End Time: 16.342 min Printing Time: 5:49:06 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 10G of 321 Page 291 of 962 Stan V1660305 I Sample Name: "s101122a059" Sample ID: "10 006-25 solvent blank" File: "s101122a.wrfT Peak Name: "PFOS" Mass(es): *499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment:"* Annotation:"" Sample Index: S9 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acq. Date: 1 1 /23/2010 Acq. Time: 10:47:24 AM Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.2 sec min Int. Type: Retention Time: Area: Height: start Time: End Time: Manual 13.214 min 901SO counts ,6le+003 12.OSS 13.810 I Sample Name: "s101122a061" Sample ID: "10 006-25 solvent blank" File: "s101122a.wifT Peak Name: "PFOS" Mass(es): "499.0/60.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment: "* Annotation: "" Sample Index: 61 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 11:35:55 AM Modified: RT Window: Expected RT: Use Relative RT: .Yea 30.0 13.6 NO Int. Type: Manual Retention Time: 13.189 min Area: 10922 counts Height: 7.42e+0O2 cps Printing Time: 5:49:08 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ( Sample Name: "s101122a060" Sample ID: "EC-101116-06 5 ng Extracted Curve Point" Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment "" Annotation: "" Sample Index: 60 File: "s101122a.wifT I Sample Name: "s101122a062" Sample ID: "GLP10-01-02-05-047 DAL SS SS03 DB 0005 " I Peak Name; "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu' Comment "" Annotation: "" Sample Index: 62 Sample Type: Unknown Concentration: N/A calculated Cone: 3270. ng/t Acq. Date: 11/23/2010 Acq. Time: 12:00:10 PM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.218 min Area: 87 847112 counts Height: 3.85e +006 cps Start Time: 11.863 min End Time: 14.022 min Page 107 of 321 Page 292 of 962 *Stan V1660305 I Sample Name: "s101122a063" Sample ID: GLP10-01-02-05-047 Dup DAL SS SS03 DB 0005 Duplicate " I Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" m Comment: "" Annotation: Sample Index: 63 Sample Type : Unknown Concentrt ion : N/A Calculated Cone: 3000. ng/t Acq. Date: 11/23/2010 Acq. Time: 12:24 :29 PM File: "s101122a.wW Modified: RT Window : Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type : Manual Retention Time : 13.218 min Area: Height : 73696638 counts 3.46e+ 006 cps Start Time: 11.863 min End Time : 14.073 min Results Name: sl01122a.rdb I Sam ple Name: "s101122a064" Sample ID: "GLP10-01-02-05-047 LM S D AL SS SS03 DB 0005 Lab M atrix S pike" Peak Name: "PFOS" Mass(es): "499.0/60.0 amu,499.0/99.0 am u.499.0/130.0 amu" m Comment "" Annotation: "" sample index: 64 Sample Type: Unknown Con centrat ion: N/A Calculated Cone:: 5190. ng/mL Acq. Date: 11/23/2010 Acq. Time: 12 :48 :43 PM File: "s1 01 12 2a .w iff Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.197 min Area: 107801986 counts Height : 5.47e+006 cps start Time: 11.863 min End Time: 14.163 min I Sample Name: "s101122a065" Sample ID: 'GLP10-01-02-05-048 DAL SS SS04 0 0000 " Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" Comment: "* Annotation:"" Sample Index: 65 Sample Type: Unknown Concentration: N/A Calculated Cone: 1210. ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:12:58 PM File: "s101122a.wifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 sec 13.6 min No Int. Type: Manual Retention Time : 13.206 min Area: 42475502 counts Height : 2.27e+006 cpS Start Time: 11.884 min End Time : 13.871 I Sample Name: "s101122a066" Sample ID: "GLP10-01-02-05-048 Dup DAL SS SS04 0 0000 Duplicate " Peak Name: "PFOS" Mass(es): "499.0/60.0 a u,499.0/99.0 amu,499.0/130.0 a Com m ent"" Annotation:"" Sample Index: 66 Sample Type: Unknown Concentration : N/A calculated cone: 458. ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:37:12 PM File: "s101122a.wifr Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.6 NO Int. Type: Manual Retention Time 13.234 min Area: Height : 17164131 counts l.iae+006 cps Start Time 11.904 min End Time: 13.810 Printing Time: 5:49:10 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 108 of 321 Page 293 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 294 of 962 Stan V1660305 [ Sample Name: "s 1 0 1 1 2 2 a 0 7 r Sample ID: "GLP10-01-02-6-050 D AL S S TRIP1 0 0 0 0 0 " I Peak N am e: "PFOS" Mass(es): " 499.0/80.0 amu,4 99.0/99.0 a m u.499.0/130.0 a m u ' Comment: "" Annotation: "" Sample Index: 71 Sample Type: Unknown Concentration : N/A Calculated Cone: 0.327 ng, Acq. Date: 11/23/2010 A cq. Time : 3:38:22 PM File: "8101122a.wifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Retention Time: Area: Height : start Time: End Time : Manual 13.219 min 20014 counts 1.28et003 cps 12.015 min 13.609 min Results Name: sl01122a.rdb ISample Name: "s101122a072" Sample ID: "GLP10-01-02-05-050 Dup DAL SS TRIP1 0 0000 Duplicate" Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" 1 Comment "" Annotation: "" Sample Index: 72 Sample Type : Unknown concentration: N/A calculated cone:; 0.173 ng/ Acq. Date: 11/23/2010 Acq. Time: 4:02:36 PM File: "s101122a.wrfT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type : Retention Time: Area: Height : start Time: End Time : Manual 13.243 min 12364 counts 8.49e+002 cps 12.005 min 13.669 min I Sample Name: "s101122a073" Sample ID: "GLP10-01-02-05-050 LMS DAL SS TRIP1 0 0000 Lab Matrix Spike" | Peak Name: "PFOS" Mass(es): *499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" 1 Comment: "" Annotation: " Sample Index 73 Sample Type: Unknown Concentratioi Calculated Cone : N/A 2.21 ng, 8500 Acq. Date: Acq. Time: 11/23/2010 4:26:49 PM 6000 File: "s101122a.wifr 1 3 .1 4 Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 13.6 NO sec min 7500 7000 Int. Type: Manual Retention Time: 13.217 min Area : 101379 counts Height : 8.69e*003 cps Start Time: 12.025 min End Time : 13.679 min 6000 5500 5000 4500 4000 3500 3000 2500 2000 1500 1000 500 1 -P * 2 199 Printing Time: 5:49:13 PM Printing Date: Friday, January 07, 2011 7 .0 4 1 2 .6 9 . f , 54 . 10.49 ,^ 992 1191 Time, min 3M Study GLP10-01-02 Interim Report 05 I Sample Name: "s101122a074" Sample ID: "GLP10-01-02-05-051 DAL SS SS05 0 0000" I Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu" B Comment "" Annotation: "" Sample Index: 74 Sample Type: Unknown Concentration: N/A Calculated Cone:: 7070. ng/mL Acq. Date: 11/23/2010 Acq. Time: 4:51:04 PM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.187 min Area: 149756184 counts Height : 6 ,44e-006 cps Start Time: 11.884 min End Time: 14.103 min 2 0 .7 4 2 0 .0 3 s . i, ,,2 1 .4 7 1785 1984 2182 Page 110 of 321 Page 295 of 962 *Stan V1660305 [ Sample N am e: "s101122a075" Sam ple ID: "GLP10-01-02-OS-051 D up D AL S S S S 05 0 0 0 00 D uplicate " I Peak N am e: "P F O S" Mass(es): "499.0/80.0 amu,4 9 9 0 /9 9 .0 a m u.499.0/130.0 am u" Comment: "" Annotation: "" Sample Index: 75 Sample Type: Unknown Concentration: N/A calculated cone: 63SO. ng/mL Acg. Date: 11/23/2010 Acq. Time: S :15:19 PM File: "s 1 0 1 1 2 2 a .w r Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.206 min Area: 130544198 counts Height : 5.75e+00 6 cps Start Time: 11.684 min End Time : 14.2S4 min I Sample Name: "s101122a077" Sample ID: "10 006-25 so ie n t blank" File: "s101122a.wtr I Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu.499.Q/130.0 amu" Comment: "" Annotation: "" Sample Index: 77 Sample Type: Double Blank Concentration: 0.00 ng, Calculated cone : N/A Acq. Date: 11/23/2010 Acq. Time: 6:03:48 PM Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 13.2 No sec min Int. Type: Manual Retention Time: 13.195 min Area: :334477 counts Height: 2.41e004 cps Start Tim e : 12.368 min End Time: 14.234 min Results Name: sl01122a.rdb [Sample Name: "s101122a076" Sample ID: "GLP10-01-02-05-0S1 LMS DAL SS SS05 0 0000 Lab Matrix Spike" Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" m Comment "" Annotation: "" Sample Index: 76 Sample Type: Unknown Concentration: N/A 9.5e6 Calculated Cone: 11700. ng/mL Acq. Date: 11/23/2010 9.0e6 Acq. Time: 5:39:33 PM B.Se6 Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.146 min Area: 209825577 counts Height: 9 ,57e006 cps Start Time: 11.863 min End Time: 14.355 min B.0e6 7.5e6 7.0e6 6.5e 6.0e6 S.Se6 5.0e- File: "s101122a.wifr c 4.5e6- 1 4.0e6 3.5e6 3.0e6 2.5e6 2.0e6 1.5e6 1.0e6 S.OeS 0.0 - 2 199 ~T Sample Name: "s101122a078" Sample ID: "EC-101116-07 10 ng Extracted Curve Point* Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment "" Annotation:"" Sample Index: 992 1191 Time, min File: "s101122a.wifT Printing Time: 5:49:15 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 111 of 321 Page 296 of 962 Stan V1660305 I Sample Name: "81011223079" Sample ID: " 10 006-25 solvent blank" File: "s101122a.wifT Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499,0/130.0 amu" Comment " Annotation: sample Index: Sample Type: Double Blank concentration 0.00 ng/mL Calculated cone: N/A Acg. Date: 11/23/2010 Acq. Time: :S2:23 PM Modified: Yes Proc. Algorithm: intelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 SC Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Tim e : End Tim e : Valley 13.21S min 24639 counts 2.23e+003 cps 12.963 min 13.437 min I Sample Name: "s101122a081" Sample ID: "GLP10-01-02-5-052 Dup DAL SS SS05 0 0005 Duplicate " I Peak Name: "PFOS" Mass(es): "499.0/60.0 amu.499.0/99.0 amu,499.0/130.0 amu" Comment "" Annotation: "" Sample Index: 81 Sample Type: Unknown Concentration: N/A Calculated Cone: 2970. ng/> Acq. Date: 11/23/2010 Acq. Time: 7:40:58 PM File: "8l01122a.wiff' Modified: RT window: Expected RT: use Relative RT: Yes 30.0 13 .6 NO sec min Int. Type: Manual Retention Time: 13.211 min Area: 66647034 counts Height : 3 . 8 0 e * 0 0 6 : cps Start Time: 11.924 min End Time : 14.163 min Results Name: sl01122a.rdb I Sample Name: "s101122a080" Sample ID: "GLP10-01-02-05-052 DAL SS SS05 0 0005" Peak Name: " PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu" Comment "" Annotation: "" Sample Index: Sample Type: Unknown Concentration: N/A calculated Cone: 2640. ng/mL Acq. Date: 11/23/2010 Acq. Time: 7:16:41 PM File: "s101122a.wifT Modified: RT window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time: 3 .68e*006 cps 11.914 min 14.164 min I Sample Name: "s101122a082" Sample ID: "GLP10-01-02-05-052 LMS DAL SS SS05 0 0005 Lab Matrix Spike" Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu" m Comment "" Annotation: "" Sample index: 82 Sample Type: Unknown Concentration: N/A Calculated Cone:: 4870. ng/mL Acq. Date: 11/23/2010 Acq. Time: 6:05:12 PM File: "s101122a.wifr Modified: RT window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time : 13.188 min Area: 100228926 counts Height : 5.62e+006 cps start Time: 11.884 min End Time: 15.061 min Printing Time: 5:49:17 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 112 of 321 Page 297 of 962 *Stan V1660305 I Sample Name: "s101122a083" Sample ID: "GLP10-01-02-0S-0S4 DAL S S SS06 0 0 000 " Peak Name: "P FO S" Mass(es): "499.0/80.0 amu,4 99.0/99.0 amu,4 99.0/130.0 am u" I Comment: "" Annotation: "" Sample Index: 63 Sample Type: Unknown Concentration: N/A Calculated Cone: 341. ng/mL Acg. Date: 11/23/2010 Acq. Time: a :29:2 8 PM File: " s101122a.wiff' Modified: RT Window: Expected RT: Use Relative RT: Yes 30.o 13.6 NO sec min Int. Type: Manual Retention Time 13.207 min Area: 12890564 counts Height : 8.73e+005 cps start Time 11.904 min End Time : 13.962 min Results Name: slOH22a.rdb I Sam ple Name: " s101122a084" Sample ID: "GLP10-01-02-05-054 Dup D A L S S SS06 0 0000 D up lica te" P eak N am e: "P F O S" M ass(es): "499.0/80.0 am u.499.0/99.0 am u,499.0/130.0 amu" C o m m e n tA n n o ta tio n : Sample Index: 84 Sample Type: Unknown Concentration: N/A Calculated Cone: 3S7. ng/mL Acq. Date: 11/23/2010 Acq. Time: 6:53:43 PM File: "s101122a.w ifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time:137671735.6221 comuinnts Area: 9.3 8e+00S cps Height: 11.914 Start Time 13.972 min End Time: (Sample Name: "s101122a065" Sample ID: "GLP10-01-02-05-054 LMS DAL S S SS06 0 0000 Lab M atrix S pike" Peak Name: "PFOS' Mass(es): "499.0/80.0 amu.499.0/99.0 am u,499.0/130.0am u" C om m ent:"" Annotation: "" Sample Index: 85 Sample Type: Unknown Concentration: N/A Calculated cone: 743. n Acq. Date: ll/23/2010 Acq. Time: 9:17:56 PM Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No File: " s101122a.wifT Int. Type: Manual Retention Time 13.206 min Area: 25211241 counts Height : l .aoe+oo6 cps Start Time : 12.015 min End Time : 13.992 min I Sam ple Name: "s101122a066" Sample ID: "GLP10-01-02-05-055 DAL SS SS 06 0 0 0 05 " Peak Name: "PFO S" M ass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu" C om m en t "* Annotation: Sample Index: 86 Sample Type: Unknown Concentration: N/A Calculated cone: 139. ng/mL Acq. Date: 11/23/2010 Acq. Time: 9:42:11 PM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes No Int. Type: Manual Retention Time 13.222 min Area: 5672354 counts Height: 4.29e+005 CpS start Time 12.015 min End Time: 13.820 min Printing Time: 5:49:18 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 113 of 321 Page 298 of 962 *Stan V1660305 I Sample N am e: "s101122a087" Sample ID: "G LP10-01-02-05-055 Oup DAL SS SS06 0 0005 Duplicate ' Peak Name: "PROS' Mass(es): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu" C o m m e n t:"" Annotation: - Sample Index: S? Sample Type: Unknown Concentration: N/A calculated cone: 146. n Acq. Date: 11/23/2010 Acq. Time: 10:06:25 PM Modified : RT Window: Expected RT: use Relative RT: Ye 3 30.0 13.6 File: "s1 01 12 2a .w itr Area : Height : start Time: End Time : .79e+00 5 11.995 13.820 Results Name: sl01122a.rdb I Sam ple N am e: "s101122a088" Sam ple ID: "GLP10-01-02-05-055 LM S D AL SS SS06 0 0005 Lab M atrix S pike' Peak Name: "P F O S" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" I Com m ent Annotation: " Sample Index: 88 Sample Type: Unknown Concentration: N/A Calculated Cone: 657. ng/mL Acq. Date: 11/23/2010 Acq. Time: 10:30:39 PM File: "s1 0 1 1 2 2 a .w iff Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 sec min Int. Type: Retention Time: Area: I9i Height: 1 .49e*006 Start Time: 11.974 End Time: 14.547 Sample Name: "s101122a089" Sample ID: "GLP10-01-02-05-056 DAL SS SS06 DB 0005 " Peak Name: "PFO S" M ass(es): "499.0/80.0 amu,4 99.0/99.0 am u.499.0/130.0 amu" m Com m ent: Annotation: " Sample Index: 89 Sample Type : Unknown Concentration: N/A Calculated Cone:. 174 . ng, Acq. Date: 11/23/2010 Acq. Time: 10:54:53 PM File: "s101122a.w ifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 No sec min Int. Type : Manual Retention Time: 13 .233 min Area: 6735368 counts Height : 4.8 1 e * 0 0 S cps Start Time: 11.985 min End Time : 13.972 min [Sam ple N ame: ns101122a090" Sample ID: "G LP10-01-02-05-056 Dup DAL SS SS06 DB 0005 Duplicate " Peak N am e: "P F O S " Mass(es): "499.0/80.0 amu,4 99.0/99.0 amu.499.0/130.0 amu" SamCpolmemIenndt e""x: Annotatio9n0: "" Sample Type: Unknown Concentration: N/A Calculated Cone: 165. n< Acq. Date: 11/23/2010 Acq. Time: 11:19:08 PM File: "s1 01 12 2a .w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No se< mi: Int. Type: Manual Retention Time: 13.211 Area: 6383423 counts Height : 4.56e*0C5 cpS Start Time: 11.954 min End Time : 13.952 min inting Time: 5:49:20 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 114 of 321 Page 299 of 962 Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 300 of 962 *Stan V1660305 ISample Name: "s101122a095" Sample ID: ` 10 006-25 s olve nt blank" File: ` s1 0 1 1 2 2 a .w tr Peak N ame: ' PFOS" M ass(es): "499.0/80,0 amu,499 0/99,0 amu,499.0/130.0 am u" M Comment " Annotation: "" Sample Index: 95 Sample Type: Double Blank Concentrt ion: 0.00 ng> Calculated Cone:: N/A Acq. Date: 11/24/2010 Acq. Time: 1:20:23 AM Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.196 min Area: 18195 counts Height : l.ise+003 cps Start Time: 11.863 min End Time : 13.619 min I Sample N ame: "s101122a097" Sam ple ID: "10 006-25 s olvent blank" File: "s101122a.wifT Peak N ame: *PFO S` M ass(es): ` 499.0/80.0 amu,499.0/99.0 am u.499.0/130.0 am u" C om m en t Annotation: " Sample Index: 97 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 2:08:52 AM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 Smoothing Width: 3 RT Window: 30.0 Si Expected RT: 13.1 m. Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time: End Time : Base To Base 13.145 min 2361 counts 1.94e+002 cps 12.983 min 13.508 min Printing Time: 5:49:23 PM . Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sam ple Name: "s101122a096* Sam ple ID: ` EC -101116-05 2.5 ng Extracted Curve P o in t" Peak N a m e :` P F O S ' U ass(es): *499.0/80.0 am u,499.0/99.0 amu,4 99.0/130.0 amu" I C om m ent " Annotation: Sample Index: 96 sample Type: oc Concentration: 2.50 ng/mL Calculated cone: 2.50 ng/mL Acg. Date: 11/24/2010 Acq. Time: 1:44:3? AM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: i.oo min Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: ( cps Min. Peak width: sec Smoothing width: points RT Window; Expected RT: Use Relative RT: NO Int. Type: valley Retention Time: 13.215 Area: 121S12 counts Height: 1.17e+004 cps Start Time: 12.973 min End Time: 13.4S8 min I Sam ple Name: "s101122a098" Sample ID: "GLP10-01-02-05-058 D AL S S SS07 0 0005 ' Peak Name: " PFOS` Mass(es): ` 499.0/80.0 a 9.0/99.0 amu,4 99.0/130.0 amu" C om m ent "" Annotation: "" Sample Index: 98 Sample Type Unknown Concentration: N/A Calculated Cone 2980. ng/mL Acq. Date: 11/24/2010 Acq. Time: 2:33:08 AM File: "s1 01 12 2a .w ifr Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.6 NO Int. Type: Manual Retention Time 13.212 min Area: 83772035 counts Height: 3.28e*006 cps - Start Time 11.894 min End Time: 13.740 min Page 116 of 321 Page 301 of 962 Stan V1660305 I Sample N am e: "s101122a099* Sam ple ID: GLP10-01-02-05-058 D up D AL SS SS07 0 0 005 D uplicate * I Peak N am e: "P F O S" M ass(es): "499.0/80.0 amu,4 99.0/99.0 am u,499.0/130.0 am u" 1 Com m ent: " Annotation: "H sample Index: 99 Sample Type: Unknown concentratioi N/A calculated cone:: 2680. ng/t Acq. Date: 11/24/2010 Acq. Time: 2:57:24 AM File: "s101122a.w tfT Modified: RT Window: Expected RT: use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.222 min Area: 80011351 counts Height : 3.12e+006; cps start Time: 11.874 min End Time : 14.204 min Results Name: sl01122a.rdb I Sample N am e: ~ s101122a100" Sam ple ID: "GLP10-01-02-05-058 LMS D AL S S SS07 0 0 005 Lab M atrix Spike" Peak Name: "P F O S " Mass(es): "499.0/80.0 amu,4 99.0/99.0 am u.499.0/130.0 amu" m C om m ent " Annotation: Sample Index: 100 Sample Type: Unknown Concentration; N/A calculated cone: 4940 . ng/mL Acq. Date: 11/24/2010 Acq. Time: 3:21:43 AM File: "s1 01 12 2a .w ifr Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.194 min Area: 117947664 counts Height: 5.3 9e+006 cps start Time: 11.863 min End Time : 14.295 min I Sample Name: "s101122a101" Sample ID: 'GLP10-01-02-05-059 DAL SS SS08 0 0000 ' Peak Name: "P F O S " M ass(es): "499.0/80.0 am u,499.0/99.0 amu,4 99.0/130,0 amu* Comment: Annotation: Sample Index: 101 Sample T ype: Unknown concentration: N/A Calculated Cone: 63.6 ng/mL Acq. Date: 11/24/2010 Acq. Time: 3 :45:57 AM File: "s1 01 12 2a .w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.222 min Area: 2494447 counts Height: l.69e+005 cps start Time: 12.025 min End Time: 13.820 min I Sample N ame: "s101122a102* Sam ple ID: "GLP10-01-02-05-059 Dup D AL S S SS08 0 0000 Duplicate " I Peak N ame: "P F O S" Mass(es): "499.0/80.0 am u.499.0/99.0 amu,4 99.0/130.0 amu" C om m en t "" Annotation: "" Sample Index: 102 Sample Type: Unknown Concentration: N/A Calculated cone:. 73.4 ng/ Acq. Date: 11/24/2010 Acq. Time: 4:10:13 AM File: "s1 0 1 1 2 2 a .w iff Modified: RT window: Expected RT: Use Relative RT:; Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.213 min Area: 3020879 counts Height : 2.04e*00S cps Start Time: 11.884 min End Time : 13.911 min Printing Time: 5:49:25 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 117 of 321 Page 302 of 962 *Stan V1660305 I Sample N am e: "s101122a103" Sample ID: " GLP10-01-02-05-059 LM S D AL SS SS08 0 0 000 Lab M atrix S pike" I Peak Name: "PFOS" Mass(es): "499.0/60.0 amu.499.0/99.0 amu.499,0/130.0 amu" M Com m ent: "" Annotation: "* Sample Index: 103 Sample Type: Unknown Concentration: N/A Calculated Cone:: 153 . ng/ Acq. Date: 11/24/2010 Acq. Time: 4:34:29 AM File: "*1 0 1 1 2 2 a .w ifr Modified: RT window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13 .203 min Area: 6549383 counts Height : 4.97e*005' cps Start Time: 11.984 min End Time : 13.891 min Results Name : sl01122a.rdb ISample Name: " s101122a104" Sample ID: "GLP10-01-02-05-060 DAL SS S S 08 DB 0000 " Peak Name: "P F O S " Mass(es): ` 499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 am u" C om m ent "" Annotation: "" sample Index: 104 sample Type: Unknown Concentration: N/A Calculated Cone:: 55.4 ng/ Acq. Date: 11/24/2010 Acq. Time: 4:58:45 AM File: "s 1 01 12 2a .w iff Modified: RT Window: Expected RT: use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type : Manual Retention Time: 13.219 min Area: 2343356 counts Height: 1.66e*OOS cps start Time: 12.005 min End Time : 13.780 min I Sample N am e: *s101122a10S" Sam ple ID: "G LP10-01-02-05-060 D up D AL SS SS06 OB 0000 Duplicate " Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amiT I Com m ent "" Annotaton: "" Sample Index: 105 Sample Type: Unknown Concentration: N/A Calculated Cone: 60.4 ng/mL Acq. Date: 11/24/2010 Acq. Time: 5:23:01 AM File: "s101122a.w ifT Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type : Manual Retention Time: 13.207 min Area : 2617784 counts Height : l.BSe+005 CpS start Time 11.914 min End Time: 13.841 min Printing Time: 5:49:26 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 I Sam ple N am e: " s101122a106" Sample ID: "GLP10-01-02-05-060 LM S D AL S S S S 08 DB 0000 Lab M atrix S pike" I P eak Name: "P F O S " Mass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu" Comment "" Annotation: " Sample Index: 106 Sample Type: Unknown Concentration: N/A 5.0e5 Calculated Cone 166 . ng/mL Acq. Date: 11/24/2010 Acq. Time: 5:47:16 AM 4.5e5 File: "s101122a.wrfT Modified: RT Window: Expected RT: use Relative RT Yes 30.0 13.6 NO sec min 4.0e5 Int. Type: Manual Retention Time: 13.218 min Area: 6520335 counts Height : 5.06e*00S cps Start Time: 11.894 min End Time: 14.194 min 3.5e5 3.0e5 ID ? 2.5e5 Page 118 of 321 ii 10 12 992 1191 1389 ______Time, min 1567 18 1785 20 1984 22 2182 Page 303 of 962 Stan V1660305 ISample Name: "s101122a107" Sample ID: "G LP10-01-02-05-061 D A L S S S S 0 8 0 0005 " I Peak Name: "P F O S" Mass(es): "499.0/80.0 a m u.499.0/99.0 a m u.499.0/130.0 am u" 1 Comment: "" Annotation: "" Sample Index: 107 Sample Type : Unknown concentration : N/A calculated cone: 28.7 ng/ Acq. Date: 11/24/2010 Acq. Time: 6:11:32 AM File: "s101122a.wrfT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.197 min Area: 1315790 counts Height : 8.98e+004 cps start Time: 11.863 min End Time : 13.639 min Results Name: sl01122a.rdb I Sam ple Name: "s101122a108" Sample ID: "G LP10-01-02-05-061 Dup DAL S S SS08 0 0005 D up lica te " P eak N ame: "P F O S" M ass(es): "4 99.0/80.0 amu,4 99.0/99.0 am u.499.0/130.0 am u" I C o m m e n t Annotation: "* Sample Index: 108 Sample Type: Unknown Concentration : N/A Calculated cone: 26.a I Acq. Date: 11/24/2010 Acq. Time: 6 :3S:44 AM File: "s1 01 12 2a .w iff Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No S< m: Int. Type: Manual Retention Time: 13.222 min Area: 1145123 counts Height: 8.61e*004 cps Start Time: 12.015 min End Time: 13.649 min I Sample Name: "s101122a109" Sample ID: "GLP1CW31-02-05-061 LM S D AL S S SS08 0 0005 Lab M atrix S pike" Peak N ame: "P F O S " Mass(es): *499.0/80.0 am u,499.0/99.0 amu,499.0/130,0 am u' I Com m ent - Annotation: "* Sample Index: 109 Sample Type: Unknown Concentration: N/A Calculated cone: 135. ng/mL Acg. Date: 11/24/2010 Acq. Time: 7:00:00 AM File: "s1 01 12 2a .w tfr Modified: RT Window; Expected RT: Use Relative RT: NO int. Type: Manual Retention Time 13.220 min Area: 5159124 counts Height : 4.16e*005 CpS Start Time 11.995 min End Time : 14.022 I Sample Name: *s101122a110" Sample I0: "GLP10-01-02-05-062 DAL SS SS09 0 0000 * P eak N ame: "P F O S" M ass(es): "499.0/80.0 a m u.499.0/99.0 amu,499.0/130.0 amu" I C om m ent "" Annotation: "" Sample Index: 110 Sample Type: Unknown concentration: N/A Calculated Cone: 537. ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:24:12 AM File: "s10 11 22 a.w ifr Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.212 min Area: 19862318 counts Height : 1.24e+006 cps Start Time 11.914 min End Time : 13.861 Printing Time: 5:49:28 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 119 of 321 Page 304 of 962 Stan V1660305 I Sample N am e: "$101122a11 r Sample ID: 'G LP10-01-02-05-062 D up D AL S S SS09 0 0000 Duplicata ' Peak N am e: "P F O S" Mass(es): "< 9.0/80.0 amu,4 99.0/99.0 am u,499.0/130.0 amu" I Com m ent: "" Annotation: "" Sample Index: 111 Sample Type : Unknown Concentration : N/A Calculated Cone: 62S. ng/mL Acq. Date: 11/24/2010 Acq. Time: 7:48:24 AM Fite: "s10 1 122a.wrfT Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.6 Ho sec min Int. Type: Manual Retention Time 13.204 min Area: 21975586 counts Height: 1.35e+006 cps Start Time 11.894 End Time: 13 .982 min Results Name: sl01122a.rdb [Sample N ame: " s101122a112* Sam ple ID: "GLP10-01-02-05-062 I M S D AL SS SS 09 0 0000 Lab M atrix Spike" Peak Name: ' PFOS' Mass(es): " 499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" SamCpolmem Ienndt e""x: Annota1tio1n2: "" Sample Type: Unknown concentration: N/A calculated Cone: 1020. ng/mL Acq. Date: 11/24/2010 Acq. Time: 8:12:38 AM File: "s10 11 22 a.w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 sec min Area: Height : start Time: End Time : min counts 2.02e+006 cps 11.964 min 13.941 min I Sample Name: "s101122a113" Sample ID: " 10 006-25 s olvent blank" File: "s101122a.wifT Peak Name: *PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" C o m m e n t "" Annotation: Sample Index: 113 Sample Type: Double Blank Printing Time: 5:49:29 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 I Sam ple Name: "s101122a114" Sam ple ID: ' EC -101116-06 5 ng Extracted Curve P o in t" Peak Name: "PFO S" Mass(es): " 499.0/60.0 amu.499.0/99.0 amu,499.0/130.0 amu" l Com m ent "" Annotation: "" Sample index: 114 Sample Type: QC concentration: 5.00 ng/mL Calculated Cone: 5.23 ng/mL 2.1e4 Acq. Date: Acq. Time: 11/24/2010 9:01:07 AM 2.0e4 Modified: Ye9 Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT window; 30.0 sec Expected RT: 13.2 min , Use Relative RT: No { Int. Type: Base To Base Retention Time: 13.215 min Area: 228747 counts Height: 2.18e+004 cps start Time: 12.913 min End Time: 13.689 min 1.9e4 1.6e4 1.7e4 1.6e4 1.5e4 1.4e4 1.3e4 1.2e4 1.1e4 1.0e4 9000.0 8000.0 7000.0 File: "s101122a.w ifT 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 6.11 20 11 51 70 1 . 14.28 1 6 6 0 -. 1 7 : 5 2 1 9 . 6 & ^ > ^ >a Page 120 of 321 992 1191 _____ Time, m in Page 305 of 962 Stan V16G0305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 306 of 962 *Stan V1660305 I Sample Name: "s101122a119" Sample ID: G LP10-01-02-05-064 DAL SS GP01 0 0000 ' Peak Name: "P FO S * Masses): "499.0/80.0 am u,499.0/99.0 am u,499.0/130.0 amu" C om m ent "" Annotation: " sample Index: 119 Sample Type : Unknown Concentration: N/A Calculated Cone: 339. ng/mL Acq. Date: 11/24/2010 Acg. Time: 11:02:29 AM File: *s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type : Manual Retention Time: 13.215 min Area: 12955223 counts Height: 7.84e+005 cps start Time: 11.904 min End Time: 13.881 min Results Name: sl01122a.rdb I Sam ple N ame: "s101122a120" Sam ple ID: "GLP10-01-02-05-064 D up D A L S S GP01 0 0000 D up lica te " Peak Name: "PFO S" Mass(es): "499.0/80.0 am u.499.0/99.0 amu,4 99.0/130.0 amu" I C o m m e n t * " Annotation: "* Sample Index: 120 Sample Type: Unknown Concentration: N/A Calculated Cone: 391. ng/mL Acg. Date: 11/24/2010 Acq. Time: 11:26:43 AM File: "s 1 01 12 2a .w iff Modified: RT Window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : min 14734651 counts 9.07e*005 cps 11.863 min 13.820 min rSample Name: "s101122a121" Sample ID: GLP10-01-02-05-064 L M S D AL S S GP01 0 0000 Lab M atrix Spike' Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 am u,499.0/130.0 amu' Comment: "* Annotation: "" Sample Index: 121 Sample Type: Unknown Concentration: N/A Calculated Cone: 864. ng/mL Acg. Date: 11/24/2010 Acq. Time: 11:50:56 AM File: " s10 11 22 a.w ifr Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.216 min Area: 25662836 counts Height: 1.76e*006 Start Time: 11.904 End Time: 14.073 I Sam ple N ame: s101122a122" Sam ple ID: "GLP10-01-02-05-065 D AL SS GP01 0 0005 ' I Peak Name: ' PFOS' Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" 1 C om m en t "" Annotation: "" Sample Index: 122 Sample Type: Unknown Concentration : N/A Calculated Cone:: 196 . ng/ Acq. Date : 11/24/2010 Acg. Time: 12:15:12 PM File: ' s101122a.wifT Modified: RT window: Expected RT: Use Relative RT:: Yes 30.0 13.6 No sec min Int. Type : Manual Retention Time: 13.213 min Area: 7088977 counts Height : 4.4 9e+O05 cps Start Time: 11.904 min End Time: 14.002 min Printing Time: 5:49:33 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 122 of 321 Page 307 of 962 Stan V1660305 I Sam ple Name: " s101122a123" Sam ple ID: ''GLP10-01-02-05-065 D up D AL S S GP01 0 0005 D uplicate " I Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 armi,499.0/130.0 amu" 1 C om m en t " Annotation: Sample Index: 123 Sample Type: Unknown Concentration: N/A Calculated Cone: 271. ng / Acq. Date: 11/24/2010 Acq. Time: 12:39:26 PM File: "s101122a.w iff' Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.216 min Area: 9414894 counts Height : 5.9Se+00S cps Start Time: 11.884 min End Time : 13.8SL min Results Name: sl01122a.rdb (Sample N ame: ,,s101122a124" Sample ID: "GLP10-01-02-05-065 LMS DAL SS GP01 0 0005 Lab M atrix Spike" Peak N am e: "P F O S" M ass(es): "499.0/60.0 am u.499.0/99.0 amu,499.0/130.0 am u" C om m en t " Annotat1io2n4: "" Sample Index: Unknown Sample Type: N/A Concentration : 831. ng/mL calculated Cone: 11/24/2010 Acq. Date: 1:03:43 PM Acq. Time : Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.6 sec min File: " s101122a.wifT Int. Type: Manual Retention Time: 13.210 min Area: 23923466 counts Height : 1.63e+006 Start Time: 11.894 End Time: 13.911 T Sample Name: "s101122a125` Sample ID: "G LP10-01-02-05-066 DAL SS GP01 0 0 020 " Peak Name: "PFOS" Mass(es): ` 499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" Com m ent: " * Annotation: "" Sample Index: 125 Sample Type: Unknown Concentration : N/A Calculated cone: 375. ng/mL Acq. Dace: 11/24/2010 Acq. Time: 1:28:03 PM File: ` 8101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 sec min Area: Height : Start Time: End Time : 131044 SI counts 8.14e+OOS cps 11.914 min 13.942 min ISample Name: "s101122a126" Sample ID: ` G LP10-01-02-05-066 Dup D A L S S GP01 0 0020 D uplicate " Peak Name: ` PFOS' Mass(es): " 499.0/80.0 am u,499.0/99.0 amu.499.0/130.0 amu" SamCpolmemIenndt e""x: Annota1tio2n6: "" Sample Type: Unknown Concentration: N/A Calculated cone: 357. ng/mL Acq. Date: 11/24/2010 Acq. Time: 1:52:20 PM File: " s101122a.w iff' Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 sec min Area: Height : Start Time: End Time : 8 ,20e*005 11.894 13.921 Printing Time: 5:49:34 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 123 of 321 Page 308 of 962 *Stan V1660305 I Sam ple Name: "s101122a12T Sam ple ID: "G LP10-01-02-05-066 IM S D AL S S GP01 0 0020 Lab Matrw S p ike" P eak Name: "PFO S" Mass(es): "499.0/80.0 amu,4 99.0/99.0 amu,4 99.0/130.0 am u" I C o m m e n t"" Annotation: " sample index: 127 sample Type: Unknown Concentration: N/A Calculated cone: 804. ng/mL Acg. Date: 11/24/2010 Acg. Time: 2:16:39 PM Fife: "s 1 0 1 1 2 2 a .w ir Modified: RT Window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : 1.70e*006 cpS 12.015 min 13.861 min Results Name: sl01122a.rdb I Sam ple Name: "s101122a128" Sam ple ID: ''GLP10-1-02-05-067 D AL S S GP01 0 0060 * P eak N am e: "PFO S" M ass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu" 1 C om m en t "" Annotation: "" Sample Index: 128 Sample Type: Unknown Concentration: N/A Calculated Cone: 26.1 ng/ Acg. Date: 11/24/2010 Acg. Time: 2:40:57 PM File: "s101122a.wifT Modified: RT Window: Expected R T ; use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.212 min Area: 1043428 counts Height : 5.97e+004 cps Start Time: 11.863 min End Time: 13.760 min Sample Name: "s101122a129" Sample ID: ' GLP10-01-02-05-067 D up DAL S S GP01 0 0060 Duplicate " P eak N ame: "PFO S" Mass(es): "499.0/80.0 amu,4 99.0/99.0 am u.499.0/130.0 am u" 1 Comment: "" Annotation: "" Sample Index: 129 Sample T ype: Unknown Concentration: N/A Calculated Cone: 43.4 ng/mL 6.5e4 Acg. Date: 11/24/2010 Acg. Time: 3 :OS :12 PM 8.0e4 File: "s101122a.w ifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.220 min Area: 1470921 counts Height: 8.81e*004 cps Start Time: 11.884 min End Time: 13.730 min 7.5e4 7.0e4 6.5e4 6.0e4 5.5e4 5-0e4 I Sam ple N am e: "s101122a130" Sam ple ID: "G LP10-01-02-05-067 LM S D AL SS GP01 0 0 060 Lab M atrix S pike" Peak Name: "P F O S" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,4 99.0/130.0 am u" I C o m m e n t"" Annotation: ~ Sample Index: 130 Sample Type: Unknown Concentration: N/A Calculated cone: 143. ng/mL Acg. Date: 11/24/2010 Acg. Time: 3:29:31 PM File: "s101122a.wifT Modified: RT window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : 4487392 counts 3.58e+00S cps 11.924 min 13.911 min Printing Time: 5:49:36 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 10 12 14 16 992 1191 1389 1567 Time, min____________________ Page 124 of 321 Page 309 of 962 *Stan V1660305 I Sam ple Name: " s101122a131" Sample 10: *10 006*25 s olvent blank* File: ' s10 11 22 a.w itr P eak Name: "PFO S" M ass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu* I C om m ent:"" Annotation:"" Sample Index: 131 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 3:53:48 PM Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: l.oo Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec smoothing width: 3 points RT window: 30.0 se Expected RT: 13.2 mi use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.195 min 1976 counts 2.13e+002 cps 13.094 min 13.576 min I Sample Name: "s101122a133" Sample ID: ` 10 006-25 s olve nt blank" File: "s101122a.wtfT P eak N ame; "P F O S" M ass(es): "4 99.0/80.0 amu,499.0/99.0 amu.499.0/130.0 am u" Comment: "* Annotation: "* Sample Index: 133 Sample Type: Printing Time: 5:49:38 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sample N ame: "s101122a13Z' Sam ple ID: "EC-101116-07 10 ng Extracted Curve P o in t" Peak N am e: "P F O S" M ass(es): "499.0/80.0 a m u,499.0/99.0 amu.499.0/130.0 amu" Com m ent Annotation: " Sample Index: 132 Sample Type: Concentration: Calculated Cone: QC 10.0 lo.i ng/mL ng/mL Acq. Date: 11/24/2010 Acq. Time: 4:18:04 PM File: "s101122a.wtfT Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing width: No 0.00 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Area: Height : Start Time: End Time : 3 ,58e+004 12.923 13.488 rSample N ame: " s101122a134" Sam ple ID: "GLP10-01-02-05-068 DAL SS GP02 0 Peak N am e: "P F O S" Mass(es): "4 99.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" m C om m ent "" Annotation: "" Sample Index: 134 Sample Type: Unknown Concentration: Calculated Cone N/A 92.4 ng/mL 2.6e5- Acq. Date: 11/24/2010 Acq. Time: 5:06:41 PM 2.4e5- Modified: RT Window; Expected RT: Use Relative RT Yes 30.0 13.6 NO sec min 2.2e52.0e5- Int. Type: Manual Retention Time: 13.225 min Area: 3567042 counts Height: 2.67e+00S cps Start Time: 11.884 min End Time: 14.153 min 1.8e5- 1.6e5 Page 125 of 321 10 12 992 1191 Time, min Page 310 of 962 *Stan V1660305 Sample Name: "s101122a135" Sample ID: "GLP10-01-02-05-068 Dup D AL S S GP02 0 OOOO D uplicate " Peak Name: "PFOS" M ass(es): "4 99.0/80.0 am u,499.0/99.0 amu,4 99.0/130.0 amu" C om m en t:" A n n o ta tio n :"" Sample Index: Sample Type: Un13k5nown N/A concentration: 89.3 ng/mL Calculated Cone 11/24/2010 Acg. Date: 5:31:02 PM Acg. Time: File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: yes 30.0 13.< No Int. Type: Manual Retention Time 13.210 min Area: 3824527 counts Height : 2.74e*oo5 cps Start Time: 11.984 min End Time: 13.800 Results Name: sl01122a.rdb (Sam ple N ame: "s101122a136" Sample ID: "GLP10-01-02-05-068 LMS D A L SS GP02 0 0000 Lab M atrix S pike" Peak Name: "P F O S" Mass(es): "499.0/80.0 am u,499.0/99.0 amu,4 9 9.0/130.0 amu" C o m m e n t"" Annotation: " * Sample Index: 136 Sample Type: Unknown Concentration: N/A Calculated Cone: 189. ng/r Acq. Date: 11/24/2010 Acq. Time: 5:SS:17 PM File: "s101122a.w ifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.209 min Area: 6928777 counts Height: 5.59e +00S cps Start Time 11.995 min End Time: 14.234 min ISample Name: "s 1 0 1 1 2 2 a 1 3 r Sample ID: "GLP10-01-02-05-069 DAL SS G P 02 0 OOOS ' Peak N ame: "P F O S" Mass(es): "499.0/80.0 am u,499.0/99.0 a mu,499.0/130.0 am u" C om m en t "" Annotation: "" Sample Index: 137 Sample Type: Unknown Concentration: N/A calculated Cone: 79.9 ng/i Acq. Date: 11/24/2010 Acq. Time: 6:19:34 PM File: "s 1 01 12 2a .w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 sec min Height : Start Time : End Time : .214 min 3453421 counts 2.64e00S cps 11.924 min 13.861 min ISample Name: "s101122a138" Sample ID: "G LP10-01-02-05-069 Dup DAL S S GP02 0 0005 D up lica te " P eak N ame: "P F O S" Mass(es): "499.0/80.0 a m u,499.0/99.0 am u.499.0/130.0 amu" sample index: C om m e13n8t "* Annotation: "" Sample Type: Unknown Concentration: N/A Calculated Cone 98.6 ng/mL Acq. Date: 11/24/2010 Acq. Time: 6:43:52 PM File: "s101122a.wifT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time 13.205 min Area: 4488812 counts Height: 3 .3Be+005 cps Start Time 12.025 min End Time: 13.780 min Printing Time: 5:49:39 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 126 of 321 Page 311 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Date: Friday January 07 2011 3M Study GLP10-01-02 Interim Report 05 Page 312 of 962 Stan V1660305 ISample Name: "s101122a143" Sam ple ID: GLP10-01-02-05-071 DAL SS G P 02 DB 0 020 " Peak N am e: "P F O S " Mass(es): "499.0/80.0 amu,499.0/99.0 am u,499.0/130.0 am u" 1 C om m en t " Annotation: "" Sample Index: 143 Sample Type: Unknown Concentration: N/A calculated cone: 255. ng; Acq. Date: 11/24/2010 Acq. Time: 8:45:11 PM File: "s 1 01 12 2a .w ifr Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 NO sec min Int. Type: Manual Retention Time: 13.197 min Area: 9336247 counts Height : 6.56e*005 cps Start Time: 12.035 min End Time : 13.891 min Results Name: slOH22a.rdb I Sam ple N am e: "s101122a144" Sam ple ID: "G LP10-01-02-06-071 Dup D AL S S GP02 DB 0020 D uplicate ' I Peak N am e: "P F O S" M a sse s): "499.0/80.0 amu,499.0/99.0 arnu.499.0/130.0 amu" 1 C om m en t *" Annotation: "" Sample Index: 144 Sample Type : Unknown Concentration: N/A calculated cone:: 290. ng/ Acq. Date: 11/24/2010 Acq. Time: 9:09:27 PM File: "s101122a.wrtT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.6 No sec min Int. Type : Manual Retention Time: 13.193 min Area: 9920455 counts Height : 6 .64e+005 cps Start Time: 11.985 min End Time: 13.911 min I Sample N am e: "s101122a145" Sam ple ID: 'G LP10-01-02-05-071 LMS DAL S S G P 02 DB 0020 Lab M atrix S pike" Peak N am e: "PFO S" Mass(es): " 499.0/80.0 amu,499.0/99.0 am u,499.0/130.0 am u" I Comment: "" Annotation: Sample Index: 145 Sample Type: Unknown Concentration: N/A Calculated cone: 681. ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:33:50 PM File: "s101 12 2a .w iff' Modified: RT Window: Expected RT: Use Relative RT: Yes Area : Height ; Start Time: End Time : 21341305 counts l.Sle+006 cps 11.904 min 14.365 min (Sample Name: "s101122a146" Sample ID: "GLP10-01-02-05-072 DAL SS G P 02 0 0 1 2 0 " Peak Name: "P F O S" M ass(es): "499.0/80.0 amu,499.0/99.0 am u,499.0/130.0 amu" Com m ent "" Annotation: "" sample Index: 146 sample Type: Unknown Concentration : N/A calculated Cone: 5.36 ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:58:07 PM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No sec min Int. Type: Manual Retention Time: 13.183 min Area: 212662 counts Height: 1.3 0e+004 cps Start Time: 11.904 min End Time: 13.508 min Printing Tinte: 5:49:42 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 128 of 321 Page 313 of 962 *Stan V1660305 I Sam ple Name: "s101122a147" Sample ID: "G LP 10-01-02-05-072 D up DAL SS GP02 0 0 120 D uplicate " Peak Name: "PFO S" M ass(es): "4 99.0/80.0 a m u,499.0/99.0 amu,499.0/130.0 am u" I C om m ent "" Annotation: sample index: 147 Sample Type: Unknown Concentration: N/A Calculated cone: Acq. Date: Acq. Time: 1,104 Modified: RT window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 13.195 Area: 207130 counts Height : 1.23e+004 cps 11.974 min 1 3.saa eiin 1.00e49000.00 8000.00 m 7000.00 File: "s101122a.wifT ^ 6000.00 I " 5000.00 4000.00 Results Name: sl01122a.rdb I Sam ple N am e: "s101122a148" Sam ple ID: "G LP10-01-02-05-072 IM S D AL SS GP02 0 0120 Lab M atrix S pike" IPeak Name: " PFOS` Mass(es): "499.0/80.0 a C om m en t " " Annotation: "" Sample Index: 148 9.0 amu,4 99.0/130.0 amu" Sample Type: Unknown Concentration: N/A Calculated Cone: 15.7 ng/mL Acq. Date: 11/24/2010 Acq. Time: 10:46:43 PM File: "s101122a.w ifT Modified: RT Window: Expected RT: use Relative RT: Yes Area: Height : Start Time : End Time: Manual 13.200 9099 COi 1.06e+004 11.974 13.699 Samr ple Name: ''s101122a149'' Sample ID: "1 0 0 06-25 solvent blank" File: "s101122a.w iff' I Peaak Name: "PFO S" M ass(es): "4 99.0/80.0 am u,499.0/99.0 am u.499.0/130.0 amu" Comr m ent: " Annotation: " Sample Index: 149 Sample Type: Double Blank 992 1191 Time, min 1389 1984 2182 1Sample N ame: " s101122a150" Sam ple ID: "E C -101116-05 2.5 ng Extracted Curve Po int' Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu' Com m ent "* A nnotation:"" Sample Index: ISO File: "s101122a.w iff' Printing Time: 5:49:44 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 129 of 321 Page 314 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 315 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 316 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 317 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 318 of 962 Stan V1660305 I Sample N am e: "s101122a167" Sample ID: "10 006-25 solvent blank" File: "s101122a.w iff' Peak N ame: "P F O S" Mass(es): "499.0/80.0 amu,4 99.0/99.0 am u,499.0/130.0 am u" I C om m en t "" Annotation: "* Sample index: 167 Sample Typo: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 6 :2& :17 AM Modified: Yes Proc. Algorithm: IntelliOuan Noise Percentage: so Base. Sub. Window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time Area : Height : Start Time: End Time : Valley 13.165 min 12951 counts l.l6e+003 cps 12.983 min 13.488 I Sample Name: "s101122a169" Sample ID: "10 006-25 solvent blank" File: "s101122a.w iff Peak Name: "PFOS* Mass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu" I Comment "" Annotation: sample Index: 169 Sample Type : Double Blank Concentration: 0.00 ng/raL Calculated cone: N/A Acg. Date: 11/25/2010 Acg. Time: 7:16:55 AM Modified: Yes Proc. Algorithm: IntelliQuan - M0II Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o .oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: NO o Int. Type: valley Retention Time: 13.1S5 min Area: 4001 counts Height: 4 .6Se+002 cps start Time: 13.013 min End Time: 13.387 min inting Time: 5:49:52 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a168" Sample ID: "EC -101116-06 5 ng Extracted Curve Point" Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.4 u,4 99.0/130.0 amu" I Comment Annotation: Sample Index: 168 Sample Type: QC Concentration: 5.00 ng/mL 2.1e4 Calculated cone: 5.33 ng/mL Acg. Date: 11/25/2010 Acq. Time: 6:52:35 AM 1.9e4 File: "s101122a.wiff Modified: Yes P r o c . Algorithm: IntelliOuan - m o i I Noise Percentage: SO Base. Sub. Window : 1.00 min Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: NO o' 1.8e4 1.7e4 1.4e4 1.3e4 1.1e4 Int. Type: valley Retention Time: 13.195 min Area: 238959 counts Height: 2 .lle+004 cps Start Time: 12.933 min End Time: 13.679 min 1.0e4 7000.0 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 0.0 I Sample Name: "s101122a170" Sample ID: "GLP10-01-02-OS-078 DAL S S G P 04 0 0 000 " I Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 amu,499.0/130.0 amu" B C omment "* Annotation: " Sample Index: 170 Sample Type: Unknown Concentration: N/A 1.7e6- Calculated cone 901. ng/mL Acg. Date: 11/25/2010 1.6e6 Acq. Time: 7:41:12 AM 1.5e6 Modified: RT Window: Yes 30.0 sec 1.4e6 Expected RT: 13.6 min Use Relative r t No 1,3e6 10 12 992 1191 Time, min File: "s101122a.wiff' Int. Type: Manual Retention Time: 13.195 min Area: 27987669 counts Height: i.7ie*oo cps start Time: 11.863 min End Time: 14.224 min 1.2e6 1.1e61.0e6 o g.oeS 17.80s 20.74s. 21.52 20 1964 Page 134 of 321 12.70. 12.17s. M ^ 10 12 992 1191 1: ______Time, min______ 20 1964 22 2182 Page 319 of 962 Stan V1660305 I Sample Name: "s101122a171" Sample ID: "GLP10-01-02-05-078 Dup DAL SS G P 04 0 0000 Duplicate " Peak Name: "PROS' Mass(es): "499.0/80.0 am u.499.0/99.0 amu.499.0A130.0 amu" C om m ent:"" Annotation:"" Sample Index: 171 Sample Type: Unknown Concentration: N/A calculated cone: 676. ng/mL Acg. Date: 11/25/2010 Acg. Time: 8:05:35 AM File: "s101122a.wtfT Modified: r t window: Expected RT: Use Relative RT: Yes 30.0 13.6 Mo sec min Int. Type : Manual Retention Time: 13.198 rain Area: 23189727 counts Height: 1.43e*006 cps Start Time: n . 9 2 4 min End Time: 14.083 min Results Name: sl01122a.rdb I Sam ple N ame: "s101122a172" Sam ple ID: "GLP10-01-02-05-078 LMS D A L S S G P 0 4 0 0000 Lab M atrix S pike" Peak Name: "P F O S " M ass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 am u" I Com m ent *" Annotation: "" Sample Index 172 Sample Type: Unknown Concentration: N/A Calculated Cone: 1150. ng/mL Acg. Date: 11/25/2010 Acg. Time: 8:29:50 AM File: "s1 01 12 2a .w iff Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 13.187 min Area: 34971124 counts Height: 2.16e-*006 cps start Time 11.904 min End Time: 14.113 min [Sample Name: "s101122al73" Sample ID: "GLP10-01-02-0S-079 DAL S S G P04 0 0005 " Peak Name: "PFOS" Mass(es): "499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" SamCpolmemeinntd: ex: Annotat1io7n3: " Sample Type: Unknown Concentration: N/A Calculated Cone: 547. ng/mL Acg. Date: 11/25/2010 Acg. Time: 8:54:07 AM File: "s101122a.w ifr Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.6 NO sec rain Int. Type: Manual Retention Time 13.201 min Area: 19341966 counts Height: l.2 2e* o o6 epa start Time 11.904 min End T ime: 14.012 min (Sample Name: "s101122a174" Sample ID: "GLP10-01-02-05-079 Dup DAL S S GP04 0 0005 Duplicate" Peak Name: "PFOS" Mass(es): ' 499.0/80.0 am u.499.0/99.0 am u.499.0/130.0 amu" SamCpolmemienndt e"*x: Annotat1io7n4: "" Sample Type: Unknown Concentration: N/A Calculated Cone: S48. ng/mL Acg. Date: 11/25/2010 Acg. Time: 9:18:26 AM File: "s101122a.wifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.6 No 9ec min Area: Height : Start Time: End Time: 1 .2 0 e * 0 0 6 cps 11.954 min 13.942 min Printing Time: 5:49:53 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 135 of 321 Page 320 of 962 *stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 321 of 962 Stan V1660305 I Sample Name: "s101122a179" Sample ID: ' M B-101116-07 Method Blank 5g w / IS for Dilutions" | Peak Name: 'PFO S " Mass(es): '4 99 .0/8 0.0 am u.499.0/99.0 amu,499.0/130.0 amu" Comment: " Annotation: "" Sample Index: 179 Sample Type : Unknown concentration: N/A 650 Calculated Cone:: 0.116 ng, Acq. Date: Acq. Time: 11/25/2010 11:19 :55 AM 600 File: "s10 1 122a.wiff Modified: RT Window: Expected RT: Use Relative RT:. Yes 30.0 13.6 NO sec min 550 500- Int. Type : Retention Time: Area : Height : Start Time: End Time : Manual 13.143 min 11166 counts 6.16e+002 cps 12.116 min 13.639 min 4S0400 [ 350 I Sample Name: "s101122a181" Sample ID: "10 006-25 solvent blank" File: 's101122a.w ifr Peak Name: 'P F O S ' M asses): '499 .0/8 0.0 am u.499.0/99.0 amu,499.0/130.0 amu* Comment: " Annotation: " Sample Index: 181 992 1191 Time, min Results Name: sl01122a.rdb I Sample Name: "s101122a180" Sam ple ID: "M B-101116-08 M ethod Blank 5g w / IS fo r D ilutions' | Peak N a m e :'P F O S * M ass(es):'4 99 .0/80 .0 am u.499.0/99.0 amu,4 99.0/130.0 a m u ' 1 Comment Annotation: " Sample Index: 160 Sample Type: Unknown concentration: N/A Calculated cone 0.0434 ng/mL Acq. Date: Acq. Time: 11/25/2010 11:44:14 AM 750 File: "s101122a.w ifT Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 13.6 NO sec min Int. Type; Retention Time: Area: Height: Start Time: End Time: Manual 13.182 min 7266 counts 4.99e*0 02 cps 12.095 min 13.417 rain 700 650 600 550 500 a, 450 I Sample Name: "s101122a182" Sample ID: "EC-101116-07 10 ng Extracted Curve Point* Peak Name: 'P F O S ' Mass(es): "499.0/80.0 amu,499.0/99.0 amu,4 99.0/130.0 amu" Comment Annotation: "" Sample Index: 182 992 1191 Time, min File: "s101122a.wtfT 20 1984 22 2162 Printing Time: 5:49:57 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 137 of 321 Page 322 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 323 of 962 Stan V1660305 I Sample Name: "81011223004* Sample ID: "EC-101116-09 50 ng W arm up standard Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment: "" Annotation: "" Sample Index: sample T y p e : concentration: Double Blank o.oo ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 12:35:56 PM File: "s101 l2 2a .w iff Modified: No Min. PPeraokc.HeAilgghotr:ithm: Min. Peak Width: Smoothing w i d t h : RT Window: Expected RT: Use Relative RT: IntelclpsiQuan sec points sec - IQA Int. Type: valley Retention Time : 13.346 min Area: 820921 counts Height : 7.62e+004 cps Start Time : 12.963 min End Time : 13.851 min I Sample Name: "s101122a006" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "" Annotation: Sample Index: Sample Type: Double Blank o.oo ng/mL Concentrt ion : N/A Calculated Cone: 11/ 22/2010 Acq. Date: 1:24:19 PM Acq. Time: Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No File: *s101122a.w ifr Int. Type: Retention Time; Area : Height : Start Time : End Time : Valley 13.326 min 58 counts .60e+00l cps 13.306 min 13.387 min Printing Time: 5:50:00 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a005" Sample ID: "10 006-25 solvent blank* Peak Name: "M PFOS" Mass(es): "503.0/80.0 amu" C omment "* Annotation: "" Sample Index: 5 Doubol.eoo Blankng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 1:00:06 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec smoothing width: points RT window: sec Expected RT: min Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time : valley 13.21S min 261 counts 5.80e*001 cps 13.14S 13.326 min (Sample Name: "s101122a007" Sample ID: "10 006-25 solvent blank" Peak Name: "M PFO S* Mass(es): "503.0/80.0 amu' C omment "" Annotation: "" sample Index: Double Blank sample Type: 0.00 ng/mL Concentration : N/A calculated cone 1 1 /22/2010 Acq. Date: Acq. Time: 1:48:28 PM Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: 3 points RT window: : sec Expected RT: Use Relative RT: File: "s101122a.wifT Int. Type : Retention Time: Area : Height : Start Time: End Time: i.7 o e + o o i 13.215 13.266 Page 139 of 321 Page 324 of 962 Stan V1660305 I Sample Name: *s101122a008" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu' Com m ent: Annotation: - Sample Index: 8 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acg. Date: 11/22/2010 Acg. Time: 2:12:36 PM File: "s101122a.wrfT Modified: No Proc. Algorithm: XntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Valley Retention Time: 13.074 min Area: 34 counts Height: 2.60e+ooi cps start Time: 13.054 min End Time: 13.104 min I Sample Name: "s101122a010" Sam ple ID: "E C-101116-01 0.2 ng Extracted Curve Point" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Com m ent: - Annotation: "" Sample Index: 10 File: *s1 01 12 2a .w iff Results Name sl01122a.rdb I Sample Name: "s101122a009" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "" Annotation: "" sample Index: Sample Type : Double Blank Concentration ng/mL Calculated cone: n /a Acg. Date: 11/22/2010 Acg. Time: 2:36:44 PM File; "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Valley Retention Time: 13.18S Area: 46 counts Height : 3. S0e+00l cps Start Time 13.165 min End Time: 13.225 min I Sam ple N ame: "s101122a011" Sample ID: "EC-101116-02 0.5 ng Extracted C urve Point" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" C om m ent "" Annotation: " Sample Index: 11 File: "s101122a.w ifT Printing Time: 5:50:01 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 140 of 321 Page 325 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 326 of 962 Stan V1660305 I Sample Name: "s101122a016" Sample ID: "EC-101115-07 10 ng Extracted Curve Point" File: "s101122a.wifr Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment: *" Annotation:"" Results Name: sl01122a.rdb I Sam ple N ame: "s101122a017" Sample ID: ' EC-101116-06 25 ng Extracted Curve Point* Peak Name: ' MPFOS* Mass(es): "503.0/80.0 amu' C om m ent ** Annotation: *" Sample Index: File: ' s101122a.wifT I Sample Name: *sl0 1 1 2 2 a 0 1 8 " Sample ID: "EC-101116-09 50 ng Extracted C urve Point* Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu" Comment: " A n n o ta tio n :"" sample index: 16 Sample Type: standard Concentration: 50.0 ng/mL Calculated cone: 50.6 ng/mL Acq. Date: 11/22/2010 Acq. Time: 6:14:25 PM File: ' s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: 0.00 0.00 3 30.0 13.2 No cps sec points sec min Int. Type: Valley Retention Time: 13.225 min Area: 837491 COUnta Height: 7.76e*004 cps Start Time: 12.092 min End Time: 13.760 min Printing Time: 5:50:05 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 I Sam ple Name: "s101122a019* Sample ID: ' EC -101116-10 100 ng Extracted Curve Point" Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu" I C o m m e n t"" Annotation:"" File: " s101122a.w rfr Page 142 of 321 Page 327 of 962 Stan V1660305 I Sample Name: "s101122a020" Sample ID: "EC-101116-11 200 ng Extracted Curve P oinf Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "* Annotation: "" Sample Index: 20 Sample Type: standard Concentration: 200. ng/mL Calculated cone: 19S. ng/mL Acq. Date: 11/ 22/2010 Acq. Time: '7:02:49 PM File: "s101122a.wifT Modified: Proc. Algorithm: : Min. Peak Height: 0.00 Min. Peak width: o.oo Smoothing width: RT Window: 30.0 Expected RT: 13.2 Use Relative RT: No cps sec points sec min Int. Type: Valley Retention Time: 13.225 min Area: 2889629 counts Height: 2.S4e+Q05 cps Start Time: 12.902 min End Time: 13.8S1 min Sample Name: "s101122a022" Sam ple ID: "10 006-25 solvent b lank" Peak Name: "M PFOS" Mass(es): "503.0/80.0 amu" C om m ent Annotation: - Sample Index: 22 Sample Type Double Blank Concentration: 0.00 ng/mL calculated cone N/A Acq. Date: Acq. Time: File: "s 1 0 1 1 2 2 a .w ir Modified: Yes Proc. Algorithm: intelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time : Valley 13.215 min 2373 counts 2.66e+002 Cps 13.024 min 13.720 min Printing Time: 5:50:06 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ( Sam ple N ame: "s 1 0 1 1 2 2 a 0 2 r Sample ID: "EC-101116-12 500 ng Extracted C urve P o in f P eak Name: "M PFO S" M ass(es): "5 03.0/80.0 am u" C om m ent "" Annotation: "" Sample Index: 21 Sample Type: Standard Concentration: 500. ng/mL calculated cone: 502. ng/mL Acq. Date: 11/22/2010 Acq. Time: 7 :27:01 PM File: "s1 01 12 2a .w ifr Modified: IntNeolliQuan IQA Proc. Algorithm: 0.00 cps Min. Peak Height: o.oo sec Min. Peak width: 3 points Smoothing Width: 30.0 sec RT Window : 13.2 min Expected RT: Use Relative RT: Int. Type: Valley Retention Time: 13.225 Area: 5826921 CO Height: 4.76e*00S cps start Time: 12.842 min End Time: 13.982 min (Sam ple Name: "s101122a023" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" SamCpolmem Ienndt e"*x: Annotatio2n3: "" Sample Type: Double Blank Concentration : 0.00 ng/mL Calculated cone: N/A Acq. Date: 11/ 22/2010 A c q . Time : 8:15:23 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min , Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time : Base To Base 13.225 min S33 counts 9.25e*00l cps 13.074 min 13.427 Page 143 of 321 Page 328 of 962 Stan V1660305 Sample Name: "s101122a024" Sample ID: " 10 006-25 s olvent blank" Peak Name: "M PFO S " M ass(es): "5 03.0/80.0 amu" C o m m e n t:A n n o ta tio n :"" sample Index: 24 Sample Type: Double Blank Concentration: 0.00 ng/mL calculated cone: N/A Acg. Date: 11/22/2010 Acq. Time: 8:39:32 PM File: "s101122a.wifT Modified: No MPirno.c. PAelagkorHietihgmh:t: Int0e.l0l0iQuancps- IQA Min. Peak Width: 0.00 sec Smoothing Width: I points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type : Retention Time: Area: Height: Start Time: End Time : Valley 13.235 min 94 counts 3.70e+001 cps 13.215 min 13.316 I Sample Name: " s101122a026" Sample ID: "M B-101116-01 M ethod Blank 1 w /o IS' Peak Name: "M PFOS" Mass(es): "503.0/80.0 amu' Comment: "" Annotation: "" Sample Index: 26 sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acg. Date: 11/22/2010 Acg. Time: 9:27:54 PM File: "s 1 01 12 2a .w iff Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 see Expected RT: 13.2 min Use Relative RT: No Int. Type: Valley Retention Time: 13.205 Area: Height: 4.40e+001 Start Time: 13.185 End Time: 13.245 min 58counts cps min min Printing Time: 5:50:08 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb 1| Sample N ame: "s101122a025" Sample ID: "10 006-25 solvent blank" I Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I C om m ent "" Annotation: "" Sample Index: 25 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acg. Date: 11/22/2010 IAcg. Time: Modified: 9:03:42 PM NO MPirno.c. PAelagkorHietihgmht:: IntelliQuancps- IQA Min. Peak width: sec smoothing width: points RT Window: sec Expected RT: min Use Relative RT: No File: "s101122a.wifT Int. Type: Retention Time: Area: Height: Start Time: End Time: valley 13.195 min SO counts >.S6e+0Ol cps 13.165 min 13.215 min Sample N ame: "s101122a027" Sample ID: "M B-101116-02 Method Blank 2 w /o IS" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Com m ent " * Annotation: "" sample Index: sample Type: Double Blank Concentration: 0.00 ng/mL calculated Cone: N/A Acg. Date: 11/22/2010 Acg. Time: 9:52:08 PM File: "s1 01 12 2a .w ifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area : Height: Start Time: End Time: Valley 13.0S4 min 35 counts 2.26e0 01 cps 13.034 min 13.114 min Page 144 of 321 Page 329 of 962 Stan V1660305 Sample Name: "s101122a028" Sam ple ID: "M B-101116-03 M ethod Blank 3 w /o IS" Peak Name: "M PFO S " Mass(es): "5 03.0/60.0 amu" Com m ent: ~ Annotation: Sample Index: 2B File: "s1 01122a.w iff` I Sample Name: "s101122a030" Sample ID: 'M B-10 11 16 -05 M ethod Blank S w / IS' Peak N am e: "M PFO S " M ass(es): "5 03.0/80.0 amu" C o m m e n t"" Annotation:"" Sample Index: 30 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.98 ng/mL Acq. Date: 11/22/2010 Acq. Time: 11:04:46 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: intelliQuan - IQA MMiinn.. PPeeaakk Hwieditghh:t: 00..0000 cspesc Smoothing Width: 3 points RT window: 30.0 sec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13 .21S min 4969S counts 5.6Se+003 13.023 13.477 Printing Time: 5:50:09 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Kme: sl01122a.rdb I Sample Name: "s101122a029" Sample ID: "M B -1 01116-04 Method Blank 4 w / IS" Peak Name: "MPFOS" Mass(es): "503.0/80,0 amu" C om m ent "" A nnotation:"" Sample Index: 29 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.90 ng/mL Acq. Date: 11/22/2010 Acq. Time: 10:40:35 PM File: ''s10 11 22 a.w ifr Modified: No MPirno.c. PAelagkorHietihgmht:: IntelliQuancps- IQA Min. Peak width: sec smoothing width: points RT window: sec Expected RT: min Use Relative RT: Int. Type: valley Retention Time: 13.205 min Area: 51940 counts Height: 4 .69e+003 cps Start Time 12.973 min End Time: 13.467 min (Sample N ame: "s101122a031" Sample ID: "M B-101116-06 Method Blank 6 w / IS" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu* C om m ent "" Annotation:"" Sample Index: 31 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.73 ng/mL Acq. Date: 11/22/2010 Acq. Time: 11:28:S7 PM Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No File: "s1 01 12 2a .w ifr Int. Type: valley Retention Time: 13.225 min Area: 49286 counts Height: 5.90e*0 03 cps Start Time: 12.973 min End Time: 13.427 min Page 145 of 321 Page 330 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 331 of 962 *Stan V1660305 I Sample Name: "s101122a036" Sam ple ID: "LC S-101116-05 30 ng LOS in TC R-842" Peak Name: "M PFOS" Mass(es): "503.0/80.0 amu" I Comment: "" Annotation: "" sample index: 36 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.02 1 Acq. Date: 11/23/2010 Acq. Time: 1:30:03 AM File:'s101122a.w ifT Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 eps Min. Peak width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start T ime: End Time: Valley 13.205 min 52675 counts 4.73e+003 CpS 13.013 13 . rSample Name: "s101122a038" Sample ID: ''GLP10-01-02-05-041 DAL Peak N ame: "M PFO S" M ass(es): "S03.0/80.0 am u" Comment: Annotation: " Sample Index: 3B Sample Type : Unknown Concentration: N/A Calculated cone: 3.15 ng/mL Acg. Date: 11/23/2010 Acg. Time: 2:16:32 AM 5 SS01 0 0000 " File: "s1 0 1 1 2 2 a.w ifr Modified: No Proc. Algorithm: IntelliQuancps- IQA Min. Peak Height: sec Min. Peak Width: points Smoothing Width: : sec RT Window: min Expected RT: Use Relative RT: Int. Type: Retention Time: Area : Height : Start Time: End Time : valley 13.205 min 40017 counts 3.4 5e+003 CpS 12.963 min 13.548 min Printing Time: 5:50:13 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a037" Sample ID: "LCS-101116-06 30 ng LCS in TCR-&42" Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu" I Comment "" Annotation: "" sample Index Sample Type: Unknown Concentration: N/A Calculated cone: Acg. Date: Acg. Time: File: "s101122a.wrfr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time Area: Height : start Time: End Time: Valley 13 .235 min 55504 counts 5.14e+003 cps 12.973 min 13.477 TSample N ame: "s101122a039" Sample ID:"GLP10-01-02-05-041 Dup OAL SS SS01 0 0000 D up lica te " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" C o m m e n tA n n o ta t io n :"" Sample Index: 39 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.15 ng/mL Acq. Date: 11/23/2010 Acq. Time: 2:42:45 AM Tim e, min File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o . o o cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.o sec Expected RT: 13.2 min Use Relative RT: NO Int. Type: Valley Retention Time: 13.195 min Area: 40767 counts Height: 3.54e003 cps Start Time: 12.943 min End Time: 13.427 min Page 147 of 321 Page 332 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 333 of 962 *Stan V1660305 I Sample Name: "s101122a044" Sample ID: "GLP10-01-02-05-042 DAL SS SS01 0 0005 Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment " Annotation: Sample Index: 44 Sample Type : Unknown Concentration: N/A Calculated Cone: 3.10 ng/mL Acg. Date: 11/23/2010 Acq. Time: 4:44:01 AM File: "s101122a.wifr Modified: No MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- IQA Min. Peak Width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: No Int. Type: Valley Retention Time: 13.21S min Area: 29261 counts Height : 2.3 9e*003 Cps Start Time: 12.973 min End Time : 13.407 min I Sample Name: "s101122a046" Sample ID: "GLP10-01-02-05-042 IM S DAL SS SS01 0 0005 Lab Matrix Spike" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment: Annotation:"" Sample Index: 46 File: "s101122a.wifr Results Name: sl01122a.rdb I Sample Name: "s101122a045" Sample ID: "GLP10-01-02-( Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "* Annotation:"" Sample index: 45 sample Type: Unknown concentration: N/A Calculated Cone: 3.os ng/mL Acg. Date: 11/23/2010 Acg. Time: 5:08:17 AM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Pactor: 2 Report Largest Peak: No Min. Peak Height: < cps Min. Peak width: 1 sec Smoothing width: : points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT:: NO o Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 13.215 min 33219 counts 2.73e +003 cps 12.983 min 13.498 min . 199 398 596 794 992 1191 Time, min I Sample Name: "s101122a047" Sample ID: "GLP10-01-02-05-043 DAL SS SS02 0 0000" File: "s101122a.wifT Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment *" Annotation:"" Sample Index: 47 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.87 ng/mL Acg. Date: 11/23/2010 Acg. Time: S:S6:43 AM Modified: No MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- IQA Min. Peak Width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: Int. Type : Retention Time: Area: Height : Start Time: End Time : Valley 13.215 min 41848 COUntS 3 .86e +003 cps 12.963 min 13.467 min 20 22 1984 2182 Printing Time: 5:50:16 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 149 of 321 Page 334 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 335 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 336 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 337 of 962 Stan V1660305 I Sample Name: "s101122a060" Sample ID: "EC-101116-(X I Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" 1 Comment: - Annotation: Sample Index: 60 Sample Type : QC Concentration: 5.00 ng/mL Calculated Cone: 4.78 ng/mL Acq. Date: 11/23/2010 Acq. Time: 11:11:39 AM Modified: Yes Proc. Algorithm: IntelliQuan * IQj Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Ti m e : End Time: Valley 13.24S 8 72 7 6 CO 8.02e+003 12.953 13.SS8 I Sample Name: "s101122a062" Sample ID: "GLP10-01-02-05-047 DAL SS SS03 DB 0005" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "" Annotation: "" Sample Index: 62 File: "s101122a.wir Printing Time: 5:50:22 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb Sample Name: "s101122a061" Sample ID: "10 006-25 solvent blank* Peak Name: "MPFOS" Mass(es): "503,0/80,0 amu' Comment "" Annotation: "* Sample Index: 61 Sample Type: Double Blank Concentration: o.oo ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 11:35:55 AM File: "s101122a.wifr Modified: NO Sample Name: "s101122a063" Sample ID: "GLP10-01-02-05-047 Dup DAL SS SS03 DB 0005 Duplicate* Peak Name: "MPFOS" Masses): "503.0/80.0 amu" Comment Annotation: "" Sample Index: 63 Unknown N/A Calculated cone: 3.76 ng/mL Acq. Date: 11/23/2010 Acq. Time: 12:24:29 PM Time, min File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps M i n . Peak width: sec Smoothing Width: points RT Window: sec Expected RT: Use Relative RT: NO Int. Type: Retention Time: Area: Height: start Time: End Time: valley 13.205 min 27536 counts 2.34e+003 cps 12.943 min 13.518 Page 153 of 321 Page 338 of 962 Stan V1660305 Results Name: sl01122a.rdb I Sample Name: "s101122a064" Sample ID: "GLP10-01-02-05-04? LMS DAL SS SS03 DB 0005 Lab Matrix Spike" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment: ~ Annotation: ~ Sample Type: Concentration: Sample Index: UnknNo/wAn Calculated Cone 4.43 ng/mL 64 1700- Acq. Date: 11/23/2010 Acq. Time: 12:46:43 PM File: "s101122a.wjfT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 90 Base. Sub. window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height : 0. 00 CpS Min. Peak Width: 0. 00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13 .2 min Use Relative RT: NO o Int. Type: Valley Retention Time: 13.22S min Area: 22346 counts Height: 1.71e+003 cps start Time: 12.662 min End Time: 13.S08 min 1 e j: ii . a i.l.J.i, i IL __l a . I Sample Name: "s101122a066" Sample ID: "GLP10-01-02-05-048 Dup DAL SS SS04 0 0000 Duplicate* Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment Annotation: " Sample Index: 66 Sample Type: Unknown Concentration: N/A calculated Cone: 3.22 ng/mL Acq. Date: 11/23/2010 Acq. Time: 1:37:12 PM 4000- File: *s101122a.wifr Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak width: .00 sec Smoothing width: 3 points RT Window; 30.0 sec Expected RT: 13 .2 min use Relative RT: NO 35003000- Int. Type: Valley Retention Time: 13 .235 min Area: 49009 counts Height : 4.430003 cps Start Time : 12.963 min End Time : 13.397 min 25008- 2 2000- 1500- 20.23 1000- 500- 0- ___ ,___ ,____.___ ,___ ,- V - Printing Time: 5:50:23 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 --r tL- 12 992 1191 Time, min L ., - , i. .. .. 16 1587 18 1785 I Sample Name: "s101122a065" Sample ID: "GLP10-01-02-05-048 DAL SS SS04 0 0000 " I Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment " Annotation: "" Sample Index: 6S Sample Type : Unknown Concentration : N/A 3800 calculated cone: 2.95 ng/mL A c q . Date : 11/23/2010 3600 A c q . Time : 1:12:58 PM 3400- Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window : 30.0 sec Expected RT: 13.2 min Use Relative RT: NO 3200 3000 2800 26002400- Int. Type : Retention Time: Area: Height : Start Time: End Time: Valley 13.205 min 38249 counts 3 ,47e*003 cps 12.973 min 13.417 min 2200g- 2000t 1800- 1 1600- File: "s101122a.wifT 1400- 1200- 1000- 800600- 10.85 400- 10.6 -L .L l1 .0 2 200- . . i l i 2 -67i 10 12 992 1191 Time. I Sample Name: "s0122067" Sample iDr"Gl>l^T- 2- 5^8TM S^DAL SSSS04 0~00 L ib Matrix Spike" Peak Name: "MPFOS* Masses): "503.0/80.0 amu" I Comment "* Annotation: Sample Index: 67 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.12 ng/mL Acq. Date: 11/23/2010 6000 Acq. Time: 2:01:25 PM File: "s101122a,wrff " Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height : 0.00 cps Min. Peak Width: o.oo sec 5500 5000 Smoothing Width: RT Window: Expected RT: use Relative RT: 3 30.0 13.2 No points sec min 4500 4000 Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 13.245 min 37686 counts 3. ioe+003 cps 12.983 min 13.496 min mg- 3500 1 3000 ! 2500 2000 1500 1000 500 0- Page 154 of 321 992 1191 _____Time, min Page 339 of 962 Stan V1660305 I Sample Name: "s101122a068" Sample I0: "GLP10-01-02-05-049 DAL SS SS04 0 0005 " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment Annotation: "" Sample Index: 68 Sample Type : Concentrt ion: Calculated Cone: Acq. Date: Acq. Time: File: "s101122a.wifT Modified: IntelliOuan i q a Proc. Algorithm: 0.00 cps Min. Peak Height: o.oo sec Min. Peak width: 3 points Smoothing Width: 30.0 sec RT window : Expected RT: Use Relative RT: Int. Type : Retention Time: Height : Start Time: End Time : Valley 13.20S min 54657 counts 5.16e+003 12.963 13.488 _ T jm efcr ISample Name: "s101122a070" Sample ID: "GLP10-01-02-05-049 LMS DAL SS SS04 0 0005 Lab Matrix Spike' Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu' File: "s W l2 2 a .w tfr Comment: "" Annotation:"" Sample Type: Sample Index: concentration: Unknown calculated cone: N3/.A13 ng/mL 70 Acq. Date: Acq. Time: Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o .o o cps Min. Peak width: sec Smoothing width: points RT window: 30 .o sec Expected RT: min use Relative RT: No Int. Type: Valley Retention Time: 13.235 Area: 43194 counts Height : 3.60e +003 cps start Time: 12.933 min End Time : 13.508 min Results Name: sl01122a.rdb I Sample Name: "s101122a069" Sample ID: "GLP10-01-02-05-049 Dup DAL SS SS04 0 0005 Duplicate" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "" Annotation: "" Sample Index: 69 Sample Type : Unknown Concentration : N/A Calculated Cone: 3.09 ng/mL Acq. Date: 11/23/2010 Acq. Time: 2:49:50 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliOuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time : Valley 13.22S min 54837 counts s . i a e * 0 0 3 Cps 1 2 . 9 9 3 min 1 3 . 4 6 7 min J Sample Name: "s101122a071" Sample ID: "GLP10-01-02-05-050 DAL SS TRIP1 0 0000' Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu' B Com m ent"" Annotation:"" Sample Index: 71 Sample Type: Unknown Concentration: N/A Calculated Cone: Acq. Date: 11/23/2010 Acq. Time: 3:38:22 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT window: sec Expected RT: min Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.124 min 52703 counts 4 .77e+003 cps 12.963 min 13.457 min Printing Time: 5:50:25 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 155 of 321 Page 340 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 341 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 342 of 962 Stan V1660305 I Sample Name: "s101122a080" Sample ID: "GLP10-01-02-05-052 DAL SS S S 05 0 0 0 0 5 B Peak Name: "M PFOS" Mass(es): '5 03.0/80.0 amu' Comment:"" Annotation: " sample index: 80 Unknown N/A Calculated Cone: 3.SO ng/raL Acg. Date: 11/23/2010 Acg. Time: 7:16:41 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuacnps- IQA Min. Peak Height: 0.0i sec Min. Peak Width: o.oi points Smoothing Width: 3 sec RT Window: 30.0 Expected RT: 13 Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time: End Time : Valley 13.14 5 min 26110 counts 2.2Se+003 cps 12.973 min 13.4 S7 Results Name: sl01122a.rdb I Sample Name: "s101122a081" Sample ID: 'G LP10-01-02-05-052 Dup DAL S S SS05 0 0005 Duplicate ' Peak Name: 'M P F O S ' Mass(es): ' 503.0/80.0 amu' C omment ~ Annotation: "" Sample Index: 81 Sample Type: Unknown Concentration : N/A Calculated Cone: 3.93 ng/mL Acq. Date: 11/23/2010 Acq. Time: 7:40:58 PM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time Area: Height: Start Time: End Time: Valley 13.145 min 26363 counts 2.12e+003 cps 12.953 min 13.518 min I Sample Name: "s101122a082" Sample ID: "GLP1D-01-02-05-052 LMS DAL S S SS05 0 0005 Lab Matrix Spike' Peak Name: 'M P F O S ' Mass(es): '5 03.0/80.0 amu" Comment "* Annotation: "" Sample Index: 82 Sample Typ e : Unknown Concentration: n /a Calculated Cone: 3.96 ng Acq. Date: 11/23/2010 Acq. Time: 8:05:12 PM File: 's101122a.w ifr Modified: No MPirno.c. PAelagkorHietihgmht:: IntelliQuacnps- Min. Peak width: sec Smoothing width: points RT window: sec Expected RT: use Relative RT: No Int. Type: Valley Retention Time: 13.185 Area: 20399 counts Height : l.70e*003 cps start Time End Time : I Sample Name: "st01122a083" Sample ID: "GLP10-01-02-05-054 DAL SS SS06 0 0000 " Peak N am e :'M P FO S * Mass(es): "503.0/80.0 amu" I C om m ent "" Annotation: "* Sample Index: 83 Sample Type: Unknown Concentration : N/A calculated Cone: 2.91 ng/mL Acg. Date: 11/23/2010 Acq. Time: 8:29:28 PM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window : 30.0 sec Expected RT: 13.2 min use Relative RT: NO Int. Type: Valley Retention Time: 13.225 Area: 45668 Height : 3 .94e+003 Start Time 12.933 End Time : 13.498 Printing Time: 5:50:30 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 158 of 321 Page 343 of 962 *Stan V1660305 I Sample N am e: "s101122a0S4" Sam ple ID: "G LP10-01-02-05-054 Dup DAL S S SS06 0 0 000 Duplicate Peak N am e: "M P F O S ' M ass(es): " 503.0/80.0 amu" I Com m ent: ~ Annotation: Sample Index: 84 Sample Type: Unknown Concentration: N/A . Calculated cone: 2.78 ng/mL Acq. Date: 11/23/2010 Acq. Time: 8:53:43 PM Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak Width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No 4000 Int. Type : Retention Time: Area : Height : Start Time: End Time: Valley 13.185 min 44488 counts 3.82e+003 cps 12.963 min 13.417 min 3500 g- 3000 2500 2000 1500 1000 500 0- ISample N a m e :` s101122a086` Sample ID: "GLP10-01-02-05-055 DAL SS SS06 0 0 0 05 " Peak Name: ' M P F O S ' Mass(es): ' 503.0/80.0 amu* Comment: "* Annotation: " Sample Index: 86 File: "s101122a.wifr Printing Time: 5:50:31 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "81011223085' Sample ID: "GLP10-01-02-05-054 LMS DAL S S S S 06 0 0000 Lab Matrix Spike" Peak Name: ` M PFOS' Mass(es): "503.0/80.0 amu' C omment " Annotation: ~ Sample Index: File: "s101122a.w iff I Sample Name: 's 1 0 1 1 2 2 a 0 8 r Sample ID; "GLP10-01-02-05-05S Dup DAL S S S S06 0 0005 Duplicate Peak Name: ' M PFOS' Mass(es): "503.0/80.0 amu" C omment "" Annotation: "" sample Index: 87 sample Type: Unknown Concentration : N/A Calculated Cone: 2.56 ng/mL Acq. Date: 11/23/2010 Acq. Time: 10:06:25 PM File: ' s101122a.wifT Modified: InteNolliQuan IQA Proc. Algorithm: o.oo cps Min. Peak Height: o.oo sec Min. Peak Width: 3 points Smoothing Width: 30.0 sec RT Window: 13.2 min Expected RT: No Use Relative RT: Int. Type: Retention Time: Area: Height : Start Time: End Time: Valley 13.185 min 47271 counts 4.12e +003 cps 12.973 min 13.387 min Page 159 of 321 Page 344 of 962 *Stan V16 603 05 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 345 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 346 of 962 Stan V1660305 I Sample Name: Ms101122a096" Sample ID: "EC -101116-052.5 ng Extracted Curve Point" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I C omment "* Annotation:"" Sample Index: Sample Type : QC concentration : 2.50 ng/mL Calculated Cone: 2.70 ng/mL Acq. Date: 11/24/2010 Acq. Time: 1:44:37 AM File: "s101122a.witr Modified: Proc. Algorithm: I Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: Expected RT: Use Relative RT: NO LQuan - IQA 3 CpS 3 sec points sec Int. Type: Retention Time: Area : Height : start Time: End Time: Valley 13.225 min 49126 COlintS 4.75e+003 cps 12.963 min 13.477 min TSample Name: "s101122a098* Sample ID: "GLP10-01-02-05-058 DAL S S S S 07 0 0 0 0 5 " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment: Annotation: "" Sample Index: 98 Sample Type : Unknown Concentration: N/A Calculated Cone: 3.14 ng/mL Acq. Date: 11/24-/2010 Acq. Time: 2:33:08 AM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o .o o cps Min. Peak width: o .o o sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: valley Retention Time: 13.215 min Area: 26633 counts Height : 2.09e+003 cps start Time: 12.973 min End Time : 13.498 min inting Time: 5:50:36 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sam ple Name: "s101122a097" Sam ple ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I C om m en t "" Annotation: *" Sample Index: 97 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 2:08:52 AM File: "s101122a.wifP Modified: NO rSample Name: "s101122a099" Sample ID: "GLP10-01-02-05-058 Dup DAL S S SS07 0 0005 Duplicate" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu' C o m m en t"" Annotation:"" Sample Index: 99 Sample Type: Unknown Concentration: n /a calculated Cone: 2.96 ng/mL Acq. Date: 11/24/2010 Acq. Time: 2:57:24 AM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: Time, min File: "s101122a.wifT Int. Type: Retention Time: Area: Height: Start Time: End Time: 27562 counts 2 .47e003 12.953 13.447 Page 162 of 321 Page 347 of 962 Stan V1660305 I Sam ple Name: "s101122a100" Sample IO: "GLP10-01-02-05-058 LM S D AL S S SS07 0 0 005 Lab M atrix S pike" I Peak Name: "M PFOS" Mass(es): "503.0/80.0 amu" I C om m ent:"" A nnotation:"" sample Index: 100 sample Type: Unknown concencraclon: N/A Calculated Cone: 3.84 I Acq. Date: 11/24/2010 Acq. Time: 3 :21: 43 AM Modified: Proc. Algorithm: Noise Percentage: Base. Sub. Window: Peak-Split. Pactor: Report Largest Peak: Min. Peak Height: Min. Peak Width: smoothing width: RT Window: 30.0 Expected RT: 13.2 use Relative RT:: No cps sec points sec min o Int. Type: Retention Time: Area: Height: Start Time: Bnd Time: Valley 13.165 min 22834 counts l.ese+oo3 cps 12.902 min 13.598 min ji ( Sample Name: "s101122a102" Sample ID: ' GLP10-01-02-05-059 Dup DAL SS SS 08 0 0000 Duplicate Peak Name: "M PFOS' Mass(es): "503.0/80.0 amu" Comment:"" Annotation:"" Sample Index: 102 File: "s101122a.wiff Printing Time: 5:50:38 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb Sample Name: "s101122a101" Sample ID: "GLP10-01-02-05-059 D A LS ; S S 08 0 0 000 " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu' Comment "" Annotation: "" sample Index: 101 sample Type : Unknown Concentration : N/A Calculated Cone: 3.19 ng/mL Acq. Date: 11/24/2010 Acq. Time: 3:45:S7 AM Fiie: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: Use Relative RT: No Int. Type: Retention Time Area: Height: start Time: End Time: Valley 13.195 min 53764 counts 4.6 8e+003 cps 12.963 min 13.498 | Sample Name: ''s101122a103' Sample ID: "GLP10-01-02-05-059 LMS DAL S S SS08 0 0000 Lab Matrix Spike" | Peak Name: "MPFOS" Mass(es): ' 503.0/80.0 amu' I C omment"" Anne Sample Index: 103 Sample Type: Unknown Concentration: N/A calculated Cone: 2.71 ng/mL Acq. Date: 11/24/2010 Acq. Time: 4:34:29 AM -iie: "s101122a.wiff Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: o .o o sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.195 min 49453 COUntS 3.86e+003 cps 12.923 min 13.498 min Page 163 of 321 Page 348 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 349 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 350 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 351 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 352 of 962 *Stan V1660305 Results Name: sl01122a.rdb . 3M Study GLP10-01-02 Interim Report 05 Page 353 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 354 of 962 *Stan V1660305 I Sample Name: "s101122a126' Sample ID: "GLP10-01-02-0S-067 DAL SS GP01 0 0060 Peak Name: "MPFOS" Masses): '503.0/80.0 amu" Comment "" Annotation: "" Sample Index: 128 Sample Type: Unknown calculated cone: C2o.5n5centrnagt/imoLn: N3/8A00 Acq. Date: 11/24/2010 Acq. Time: 2:40:57 PM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0. 00 cps Min. Peak Width: 0. 00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min use Relative RT: No 3400 3200 3000 2800 2600 Int. Type: Valley Retention Time: 13.145 min Area: 44372 counts Height: 3.92e+003 cps Start Time: 12.943 min End Time: 13.538 min 2400 2200 g 2000 --1 1800 1600 992 1191 Time, min Sample Name: "s101122a130" Sample ID: "GLP10-1-02-05-067 LMS DAL SS GP01 0 0060 Lab Matrix Spike' File: "s101122a.wifT Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "" Annotation: " * sample Index: 130 sample Type: Unknown Concentration : N/A Calculated Cone: 2.83 ng/mL Acq. Date: 11/24/2010 Acq. Time: 3:29:31 PM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.: min Use Relative RT: No I nt. Type : Retention Time: Area: Height : start Time: End Time : valley 13.175 min 37943 counts 3.22e+003 cps 12.933 min 13 .48S min Printing Time: 5:50:48 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 992 1191 _____Time, min Results Name: sl01122a.rdb Sample Name: *s101122a129" Sample ID: "GLP10-01-02-05-067 Dup DAL SS GP01 0 0060 Duplicate " Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu" Comment " Annotation: Sample Index: 129 Sample Type: Unknown Concentration : N/A Calculated Cone: 2.86 i Acq. Date: 11/24/2010 Acq. Time: 3:05:12 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time : Valley 13.215 min 41911 counts 4.02e+003 cps 12.963 min 13.417 min I Sample Name: "s101122a131" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "" Annotation: "" Sample Index: 131 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 3:53:48 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.215 min 22 counts i.70e*ooi cps 13.195 min 13.245 min Page 170 of 321 Page 355 of 962 Stan V1660305 I Sample Name: "s101122a132" Sample ID: "EC-101116-07 10 ng Extracted Curve Point" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu* Comment: "" Annotation: " Sample Index: 132 Sample Type : qc Concentration: 10.0 ng/mL Calculated cone: e.eo ng/mL Acq. Date: 1 1 /24 /20 10 Acq. Time: 4:18:04 PM File: "s101122a.wjfr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0. 00 cps Min. Peak width: 0. 00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type : Valley Retention Time : 13.215 min 142670 coiuunntts Height : 1.3 Se+004 cps start Time: 12.892 End Time: 13.488 min I Sample Name: "s101122a134" Sample ID: "GLP10-01-02-05-068 DAL SS GP02 0 0000 " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment: "" Annotation: " Sample Index: 134 Sample Type : Unknown Concentration: N /A Calculated Cone: 2.98 ng/mL Acq. Date: 11/24/2010 Acq. Time: 5:06:41 PM File: " s101122a.wtff Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0 . 00 Min. Peak width: 0. 00 cps sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: valley Retention Time: 13.205 min Area : 49368 counts Height : 4.67e*003 cps Start Time: 12.973 min End Time : 13.518 min Printing Time: 5:50:50 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a133" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" t Comment *" Annotation: "" Sample Index: 133 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:42:25 PM File: "s101122a.wiff Modified: NO ISample Name: "s101122a135" Sample ID: "GLP10-01-02-05-068 Dup DAL SS GP02 0 0000 Duplicate" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Sample Index Comme1n35t *" Annotation: "" Sample Type: Unknown concentration: N/A Calculated cone: 2.69 ng/mL Acq. Date: 11/24/2010 Acq. Time: S :31: 02 PM File :" s1 0 1 1 2 2 a .w ifr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: NO Int. Type: Valley Retention Time: 13.205 min Area: 49S83 counts Height: 4.55e*003 cps start T ime: 12.953 min End Time: 13.548 min Page 171 of 321 Page 356 of 962 Stan V1660305 I Sample Name: "81011228136" Sample ID: "GLP10-01-02-05-068 LMS DAL SS GP02 0 0000 Lab Matrix Spike' Peak Name: "MPFOS" Mass(es): ` 503.0/80.0 amu" I Comment "" Annotation: "" Sample Index: 136 Sample Type : Unknown Concentrt ion : N/A calculated cone: Acq. Date: Acq. Time: File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0. 00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: use Relative RT: nt. Type : valley Retention Time: 13.195 min Area: 45209 counts Height : 4.06e*003 cps Start Time: 12.963 min End Time: 13.437 min Results Name: sl01122a.rdb I Sample Name: "s101122a137" Sample ID: "GLP10-01-02-05-069 DAL SS GP02 0 0005" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "" Annotation: "" Sample Index: 137 Sample Type: Unknown Concentration : N/A Calculated Cone: 2.65 ng/mL Acq. Date: 11/24/2010 Acq. Time: 6:19:34 PM File: "s101122a.wifT Modified: No MPirno.c. PAelagkorHietihgmht:: IntelliQuancps- IQA Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: NO Int. Type: Valley Retention Time: 13.205 min Area: 49449 counts Height: 4.67e+oo3 cps Start Time: 12.923 min End Time: 13.477 min Samir ple Name: "s101122a138" Sample ID: "GLP10-01-02-05-069 Dup DAL SS GP02 0 0005 Duplicate " Peaalk Name: "MPFOS" Mass(es): "503.0/80.0 amu" 1 Comrr ment: "" Annotation: "" Sample Index: 138 Sample Type: Unknown Concentration : N/A Calculated Cone: 2.75 ng/mL Acq. Date: 11/24/2010 Acq. Time: 6:43:52 PM File: "s101122a.witr Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.225 min 53798 counts 5.48e+003 cps Sample Name: "s101122a139" Sample ID: "GLP10-01-02-05-069 LMS DAL SS GP02 0 0005 Lab Matrix Spike" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "" Annotation: "" Sample Index: 139 Sample Type: Unknown Concentration : N/A Calculated cone: Acq. Date: A c q . Time : File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - IQ. Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time: valley 13.225 min 44327 counts 3 .85e+003 CpS 12.953 min 13.447 min Printing Time: 5:50:51 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 172 of 321 Page 357 of 962 Stan V1660305 Results Name: sl01122a.rdb I Sample Name: "s101122a140" Sample ID: "GLP10-01-02-05-070 DAL SS GP02 0 0020 " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment: Annotation: Sample Index: 14 0 sample Type: Unknown Concentration : N/A Calculated cone: 3.04 ng/mL 4000 Acq. Date: Acq. Time: 11/24/2010 7:32:21 PM 3800 Modified: No Proc. Algorithm: IntelliQuan IQA Min. Peak Height::: 0.00 cps Min. Peak width:: 0.00 sec Smoothing width:: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT:: NO 3600 3400 3200 3000 2800 2600 Int. Type: Valley Retention Time: 13.17S min Area: 46955 counts Height: 4.13e+003 cps start Time: 12.892 min End Time: 13.467 min 2400 g- 2200 2000 1 1800 File: "s101122a wrfT 1600 1400 1200 1000 800 600 400 200 ............ ................. 12 992 1191 _____Time, min .......... I Sample Name: "s101122a142" Sample ID: "GLP10-01-02-05-070 LMS DAL SS GP02 0 0020 Lab Matrix Spike" Fite: "s101122a.wtff Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment: "" Annotation: "" Sample Index: 142 Sample Type: Unknown Concentration: N/A calculated Cone: 2.82 i Acq. Date: 1 1 /24/2010 Acq. Time: 8:20:56 PM Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0 . 00 cps Min. Peak width: 0 . 00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min use Relative RT: No Int. Type: Retention Time: Area : Height: Start Time: End Time: Valley 13.17S min 33S81 counts 2.9le*003 cps 12.923 min 13.467 min U.. 20.23 ---- I Sample Name: "s101122a141" Sample ID: 'GLP10-01-02-06-070 Dup DAL SS GP02 0 0020 Duplicate " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "" Annotation: "" Sample Index: 141 ScaonmcpelnetrTaytpieo:n: UnknNo/wAn calculated cone 3.08 ng/mL Acq. Date: 11/24/2010 4200 Acq. Time: 7:56:39 PM 4000 File: "s101122a.wil Modified: NO Proc. Algorithm IntelliQuan - IQA Min. Peak Height : 0. 00 cps Min. Peak width o.oo sec smoothing width 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT NO 3600 3600 3400 3200 3000 2800 Int. Type: Valley Retention T ime: 13.155 min Area: 47504 counts Height: 4.3 7e+003 cps start Time: 12.963 min End Time: 13.397 min 2600 2400 o f 2200 2000 1800 1600 1400 1200- 1000 800 600 400 200 . ... (Sample Name: "s101122a143" Sample ID: "GLP10-01-02-05-071 DAL SS GP02 DB 0020* Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment Annotation: "* File: "s101122a.wifT inting Time: 5:50:53 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 173 of 321 Page 358 of 962 Stari V1660305 I Sample Name: "s101122a144" Sample ID: "GLP10-01-02-05-071 DupDALSS GP02 DB 0020 Duplicate " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "" Annotation: "" Sample Index: 144 Sample Type: Unknown Concentration: N/A calculated cone: 3.02 I Acq. Date: 11/24/2010 Acq. Time: 9:09:27 PM File: "s101122a.wtff Modified: No Proc. Algorithm: intelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: NO int. Type: valley Retention Time: 13.185 min Area: 43059 counts Height: 3.90e*003 cps start Time: 12.903 min End Time: 13.488 min 1 1400 1200 1000 I Sample Name: "s101122a146" Sample ID: "GLP10-01-02-05-072 DAL SS GP02 0 0120 ' Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu" I Comment: "" Annotation: "" Sample Index: 146 Sample Type: Unknown Concentration : N/A Calculated Cone: 2.99 ng/mL Acq. Date: 11/24/2010 Acq. Time: 9:58:07 PM 992 1191 Time, min File: "$101122a.wifT Modified: Proc. Algorithm: Min. Peak Height: Min. Peak Width: Smoothing width: RT Window: Expected RT: Use Relative RT: 0.00 ; 30.0 13.2 No sec points sec min In t . Type : Valley Retention Time: 13.175 min Area : 50414 counts Height : 4.85e+003 CpS Start Time: 12.902 min End Tine: 13.498 min Results Name: sl01122a.rdb I Sample Name: "s101122a145" Sample IO: "GLP10-01-02-05-071 LMS DAL SS GP02 DB 0020 Lab Matrix Spike" Peak Name: "MPFOS* Mass(es): "503.0/80.0 amu" Comment "" Annotation: "" Sample Index: 14S File: "s101122a.wifT ISample Name: "s101122a147* Sample ID: "GLP10-01-02-05-072 Dup DAL SS GP02 0 0120 Duplicate " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" samCpolmemIenndt e""x: Annota1tio4n7: ** sample Type: Unknown Concentration : N/A Calculated Cone: 2.93 ng/mL Acq. Date: 11/24/2010 A c q . Time : 10:22:25 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type : Retention Time Area: Height : start Time : End Time: valley 13.155 min 50179 counts 4.87e+003 CpS 12.943 min 13.417 rain Printing Time: 5:50:54 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 174 of 321 Page 359 of 962 Stan V16G0305 ( Sample Name: "a101122a148" Sample ID: "GLP10-01-02-05-072 LMS DAL SS GP02 0 0120 Lab Matrix Spike" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment:"" Annotation: Sample Index: 148 Sample Type: Unknown Concentration: N/A - Calculated Cone: 2.96 ng/mL Acq. Date: 1 1 /24/2010 Acq. Time: 10:46:43 PM Fite: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0. 00 epa MSimno.othPienagk WWiiddtthh:: 0.00 psoeicnts RT Window: sec Expected RT: Use Relative RT: Int. Type: Valley Retention Time: 13.205 min Area: 43231 counts Height: 3.89e+003 cps start Time: 12.933 min End Time: 13.427 min Results Name: sl01122a.rdb [ Sample Name: "s101122a149" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment "" Annotation: " Sample Index: 149 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 11:10:56 PM File: "s101122a.wifT Modified: I Sample Name: "s101122a150" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment: "" Annotation: "" Sample Index: 150 Fite: "s101122a.wiff I Sample Name: "s101122a151" Sample ID: "10 006-25 solvent blank' Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "* Annotation:"" Sample Index: 151 sample Type: Double Blank File: "s101122a.wifT Printing Time: 5:50:56 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 175 of 321 Page 360 of 962 Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 361 of 962 Stan V1660305 I Sample Name: "s101122a156" Sample ID: "GLP10-01-02-05-074 Dup DAL SS GP03 0 0005 Duplicate " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" I Comment: " Annotation: "" Sample Index: 156 Sample Type: Unknown concentration: N/A calculated Cone: 2.99 ng/mL Acq. Date: 11/25/2010 Acq. Time: 2:01:05 AM File: "s101122a.wifT Modified: Mo Proc. Algorithm: IntelliQuan - IQA l. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: Use Relative RT: Int. Type: Retention Time Area: Height : Start Time : End Time : Valley 13.155 min 31593 counts 2.60e+003 cps 12.913 min 13.346 min I Sample Name: "s101122a158" Sample ID: "GLP10-01-02-05-075 DAL SS G P03 0 0020 " Peak N am e:' MPFOS" Mass(es): "503.0/80.0 amu" I Com m ent: " Annotation: "" Sample Index: 158 Sample Type: Unknown concentrat ion: N/A calculated cone: 3.39 ng/mL Acq. Date: 11/25/2010 Acq. Time: 2:49:43 AM Fite: "s101122a.wtfT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo Min. Peak width: o.oo cps sec Smoothing width: points RT Window: 30.0 sec Expected RT: use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.205 min 33508 counts 2.85e*003 cps 12.943 min 13.447 min nting Time: 5:50:59 PM nting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s 1 0 1 1 2 2 a 1 5 r Sam ple ID: "GLP10-01-02-05-074 LMS DAL S S GP03 0 0005 Lab M atrix S pike" Peak Name: "MPFOS" Mass(es): "503,0/80.0 amu" Com m ent "" Annotation: "" Sample Index: 157 Sample Type : Unknown Concentration : N/A Calculated Cone: 3.61 ng/mL Acq. Date: 11/25/2010 Acq. Time: 2:25:24 AM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time: End Time : Valley 13.165 min 19503 counts l.4le+003 cps 12.923 min 13.397 min T Sample N ame: "s101122a159" Sample ID: "GLP10-01-02-05-075 D up D AL SS G P03 0 00 20 D uplicate " Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" C om m en t "* Annotation: "" Sample Index: 1S9 Sample Type : Unknown Concentration : N/A Calculated Cone: 3.07 ng/mL Acq. Date: Acq. Time: File: "s 1 0 1 1 2 2 a .w ir Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: sec Smoothing Width: : points RT Window: 30.0 sec Expected RT: 13.2 Use Relative RT: No Int. Type : Retention Time: Area: Height: Start Time: End Time: Valley 13.165 min 30319 counts 2.7 9e+003 cps 12.963 min 13.427 min Page 177 of 321 Page 362 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:51:01 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 178 of 321 Page 363 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 364 of 962 *Stan V1660305 I Sample Name: "s101122a168" Sample ID: "E C-101116-06 5 ng Extracted Curve P o int' Peak Name: "M PFOS" Mass(es): "503.0/80.0 amu" Comment: ~ A n no ta tion :"" Sample Index: 168 File: Ms101122a.w iff' I Sample Name: "s101122a170" Sample ID: "G LP 10-01-02-05-078 DAL Peak Name: "MPFOS' Mass(es): ' 503.0/80.0 amu' Comment: "" Annotation:" Sample index: 170 sample Type: unknown Concentration: N/A Calculated cone: 3.35 ng/mL Acg. Date: 11/25/2010 Acg. Time: 7:41:12 AM S GP04 0 0000' File: "s1 01 12 2a .w ifr Modified: No Min. PePraokc.HeAilghgto:rithm: InteclplsiQuan - IQA Min. Peak Width: sec Smoothing Width: points RT window: sec' Expected RT: min Use Relative RT: No int. Type: Retention Time Area: Height : start Time: End Time: valley 13.165 min 39730 counts 3.24e+003 cps 12.923 min 13.548 min inting Time: 5:51:04 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a169" Sample ID: "10 006-25 solvent blank' Peak Name: "MPFOS" Mass(es): ' 503,0/80,0 amu" I Comment " Annotation: "" sample Index 169 sample Type: Double Blank concentration: 0.00 ng/mL calculated Cone: N/A Acg. Date: 11/25/2010 Acq. Time: 7:16:55 AM File: "s101122a.wiff Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End T ime: valley 13.185 min 10 counts s .o o e + o o o 13.165 13.205 Sam ple Name: "s101122a171" Sam ple ID: "GLP10-01-02-05-078 D up D AL S S GP04 0 0000 D uplicate" Peak N am e:' MPFOS" Mass(es): "503.0/80.0 amu' I C om m ent "" Annotation: "" Sample Index: 171 Sample Type: Unknown Concentration: N/A Calculated Cone: Acq. Date: Acq. Time: File: "s10 11 22 a.w ifr Modified: Yes Proc. Algorithm IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time: End Time : valley 13.185 min 41193 counts .69e+003 cps 12.902 min 13.508 min Page 180 of 321 Page 365 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 366 of 962 Stan V166030S Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 367 of 962 *stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 368 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 369 of 962 Stan V1660305 I Sample Name: "s101122a005n Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(IS)" Mass(es): "303.0/64.0 amu" Comment:"" Annotation: " Sample Index: S Sample Type: Double Blank concentration: 1.00 ng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 1:00:06 PM File: "s101122a.wiff` Modified: Yes Proc. Algorithm: IntelliQuan - MQ: Noise Percentage: SO Base. Sub. window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing width: No 0.00 0.00 3 cps sec points RT Window: 30.0 s Expected RT: 8.03 m Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Base To Base 7.86 min 7.84 min 8.20 min Sample Name: "s101122a007" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(tS)' Mass(es): "303.0/84.0 amu" I Comment: "* Annotation: "" Sample Index: Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 1:48:28 PM File: "s101122a.wifT Modified: Yes Printing Time: 5:51:11 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a006" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(IS)" Mass(es): "303.0/64.0 amu" C o m m e n t "" Annotation:"" Sample Type Concentration: Calculated Cone: Acq. Date: Acq. Time: sample Index: Double Blank l.oo ng/mL N/A 11/22/2010 1:24:19 PM 6 Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: l.oo Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window; 30.0 se Expected RT: 8.03 mi Use Relative RT: No File: "s101122a.wifT Int. Type: Retention Time: Area: Height : start Time: End Time: Base To Base 7.87 min 36 counts 1.78e+001 cps (Sample Name: "s101122a008" Sample ID: "10 006-25 soK/ent blank" Peak Name: "M P F B S flS f Mass(es): "303.0/64.0 amu' C o m m en t"" Annotation:"" Sample Index: 8 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated cone: n /a Acq. Date: 11/22/2010 Acq. Time: 2:12:36 PM Modified: NO File: ' s101122a.wiff' Page 185 of 321 Page 370 of 962 *Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:51:13 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 186 of 321 Page 371 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 372 of 962 *Stan V1660305 I Sample Name: " s 1 0 1 1 2 2 a 0 ir Sample ID: "EC-101116-08 25 ng Extracted Curve Point" Peak Name: "M P F B S (IS f Mass(es): "303.0/84.0 amu" Comment: "" Annotation:"" Sample Index: 17 Sample Type: standard Concentration: 3.03 ng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 5:S0:14 PM File: "s101122a.w iff Modified: Ho Proc. Algorithm: intelliQuan - MQII Noise Percentage: so Base. Sub. window: l.oo min Peak-Split. Factor: 4 Report Largest Peak: MMiinn.. PPeeaakk wHieditghh:t No 0.00 cps sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Base To Base Retention Time: 7.89 min Area: 49576 counts Height: 3.27e+004 cps start Time: 7.73 min End Time: 9.10 min I Sample Name: "s101122a019" Sample ID: "E C -10 11 16 -1 0100 ng Extracted Curve Point" Peak N am e:'M P FB S (IS )" Mass(es): "303.0/84.0 amu" I Comment:"" Annotation: Sample Index: 19 Sample Type: Standard Concentration: 3.03 r Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 6:38:37 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: cps Min. Peak width: . 0 0 sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: No Int. Type: valley Retention Time: 7.90 min Area: 334707 counts Height: 3.19e+004 cps Start Time: 7.72 min End Time: 8.46 min Printing Time: 5:51:16 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a016" Sample ID: "EC-101116-09 50 ng Extracted Curve Point" Peak Name: "M P F B S (IS f Mass(es): "303.0/84.0 amu" Comment "* Annotation: "* Sample Index: 18 Sample Type: standard Concentration: 3.03 ng/mL Calculated Cone: N/A ' Acq. Date: 11/22/2010 Acq. Time: 6:14:25 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Pactor: 4 Report Largest Peak: MMiinn.. PPeeaakk wHieditghh:t N0o.00 0.00 cps sec Smoothing width: 3 points RT Window: 30 sec Expected RT: 8.03 min ,, Use Relative RT: No I Area: Height : Start Time: End Time: .ose+oo4 7.71 8.84 I Sample Name: "s101122a020" Sample ID: "EC-101116-11 200 ng Extracted Curve Point" Peak Name: "MPFBS(IS)" Mass(es); "303.0/84.0 amu" C o m m e n t"" Annotation: Sample Index: File: "s101122a.wifT Page 188 of 321 Page 373 of 962 Stan V1660305 (Sample Name: "s101122a021" Sample ID: "E C -101116-12 500 ng Extracted Curve Point" Peak Name: "M PFBS(IS)" Mass(es): "303.0/84.0 amu" Comment "" Annotation:"" Sample Index: 21 Sample Type: Standard Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 2.2e4 Acq. Time: 7:27:01 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Pactor: 4 Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing width: No 0.00 0.00 3 cps sec points RT Window: 30.0sec Expected RT: 8.03 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.90 min Area: 286S56 counts Height: 2.36e+004 cps Start Time: 7.72 min End Time: 8.73 min I Sample Name: "s101122a023" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(IS)" M ass(es):` 303.0/84.0 amu" 1 Comment: "* Annotation: " Sample Index: 23 Sample Type : Double Blank Concentration: 1.00 ng/mL calculated cone: N/A Acq. Date: 11/ 22/2010 Acq. Time: 8:15:23 PM File: *s101122a.vwfT Modified: NO Results Name: slOH22a.rdb I Sample Name: "s101122a022" Sample ID: "10 006-25 sotv. Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu' Comment -- Annotation: " sample Index: 22 Double Blank ng/mL Calculated cone: N/A Acq. Date: 11/22/2010 50- Acq. Time: 7:51:11 PM Modified: NO Proc. Algorithm: IntelliQuan - MQII Noise Percentage so Base. Sub. Window: l.oo min Peak-Split. Facte r: 4 Report Largest Peak: No Min. Peak Height 0.00 cps Min. Peak Width: o.oo sec Smoothing Width: points RT Window: 30.0 sec Expected RT: 8.03 min use Relative RT: No o' Int. Type: Retention Time: Area: Height: start Time: End Time: Base To Base 7.99 min 48 counts i .78e*001 cps 7.97 min 9.06 min 45403530252015- 10- 5- oJ rSample Name: "s101122a024" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(IS)" Mass(es): *303.0/84.0 a " SamCpolmemIenndt e""x: Annotatio2n4: "" Sample Type: Double Blank Concentration: 1.00 ng/mL calculated cone: N/A Acq. Date: 11/ 22/2010 Acq. Time: 8:39:32 PM File: "s1 01122a.w ir Modified: NO 992 1191 Time, min Printing Time: 5:51:17 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Page 189 of 321 Page 374 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 375 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 376 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 377 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 378 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Date Friday, January 07 2011 3M Study GLP10-01-02 Interim Report 05 Page 379 of 962 *stan V1660305 I Sample Name: "s101122a045" Sample ID: "GLP1Q-01-02-05-042 Dup DAL S ; SS01 0 0005 Duplicate " Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment: Annotation:"" sample Index: 45 ' Sample Type: Unknown concentration: 3.03 ng/mL Calculated Cone: N/A A cq. Date: 11/23/2010 Acq. Time: 5:08:1? AM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan M Q H Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: MMiinn.. PPeeaakk wHieditghh:t: No 0.00 cps sec Smoothing width: points RT Window: Expected RT: use Relative RT: Area : Height : Start Time: End Time: .69e+004 cps 7.75 min 8.71 min T Sample Name: "s101122a047" Sample ID: "GLP10-01-02-05-043 DAL SS SS02 0 0000" Peak Name: "M P F B S (IS f Mass(es): "303.0/84.0 amu" Comment: "* Annotation: " Sample Index: Sample Type: Unknown Concentration: 3.03 n calculated cone: n /a Acq. Date: 11/23/2010 Acq. Time: 5:56:43 AM File: "s101122a.w ifr Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 se Expected RT; 8.03 mi Use Relative RT: No Int. Type: Valley Retention Time: 7.88 mi Area: 375468 counts Height: 3.76e+004 Cps Start Time 7.72 min End Time: min Printing Time: 5:51:26 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb (Sample Name: "s101122a046" Sample ID: "GLP10-01-02-05-042 LMS DAL SS SS01 0 0005 Lab Matrix Spike' Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent "* Annotation: Sample Index: 46 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 3.1 Acq. Time: 5:32:30 AM Modified: No 2.1 Proc. Algorithm: IntelliQuan - MQII 21 Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 4 ' Report Largest Peak: No Min. Peak Height: 0.00 cps ** Min. Peak width: o.oo sec Smoothing width: 3 points 2.1 RT Window: 30.0 sec Expected RT: 8.03 min 1.1 Use Relative RT: No g- Area: Height : Start Time: End Time: 7.90 min 340268 counts 3.20e*004 CpS ( Sample Name: "s101122a048" Sample ID: "GLP10-01-02-05-043 Dup DAL S S SS02 0 0000 Duplicate " Peak Name: " M P F B S (IS f M asses): "303.0/84.0 amu" Comment " Annotation: "" sample Index: 48 sample Type : Unknown Concentration: 3.03 ng/mL Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 6:21:00 AM 10 12 992 1191 Time min File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window: l.oo min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.03 min use Relative RT: No Int. Type: Base To Base Retention Time: 3540507.89coumnitns Area: 3.S2e+004 cps Height: 7.71 min Start Time: 8.76 min End Time: Page 195 of 321 Page 380 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 381 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 382 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 383 of 962 Stan V1660305 I Sample Nam: "s1 0 1 1 2 2 a 06 r Sample ID: "10 006-25 solvent blank" Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" C o m m e n t : A n n o t a t io n : "" Sample Index: 61 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 11:35:55 AM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: S.03 min v Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Base To Base 7.96 min 97 counts :.67e+ooi cps 7.62 min 8.97 min I Sample Name: "s101122a063" Sample ID: "GLP10-01-02-05-047 Dup DAL S S SS03 DB 0005 Duplicate" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment: Annotation: *" Sample Index: 63 File: "s101122a.w ifr Results Name: sl01122a.rdb I Sample Name: "s101122a062" Sample ID: "GLP10-01-02-05-047 DAL SS SS03 DB 0005" Peak Name: "M PFBS(lsr Mass(es): "303.0/84.0 amu' Comment:"" Annotatio62n:"" sample Index: Unknown Sample Type: 3.03 n< Concentration: N/A Calculated Cone: 11/23/2010 Acq. Date: 12:00:10 PM Acq. Time: Modified: NO Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: Expected RT: Use Relative RT: NO File: "s101 t22 a.w iff Int. Type: Base To Base Retention Time: 7.87 min Area: 374506 counts Height: 3 .86e+004 cps start Time: 7.70 min End Time: 8.72 min I Sample Name: "s101122a064" Sample ID: "GLP10-01-02-05-047 LMS DAL SS SS03 DB 0005 Lab Matrix Spike" Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu' Comment "* Annotation: " Sample Index: 64 ' File: "s101122a.w ifr Lnting Time: 5:51:32 PM Lnting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 199 of 321 Page 384 of 962 Stan V1660305 I Sample Name: "s101122a065" Sample ID: "GLP10-01-02-05-048 DALS ; SS 04 0 00 00 " Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" C o m m e n t:A n n o ta tio n : "" Sample Index: 65 Sample Typ e : Unknown Concentration: 3.03 ng/ Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 1:12:58 PM Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. window: l.oo Peak-Split. Factor: 6 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 se Expected RT: 8.03 mi Use Relative RT: No File: "s101122a.w tfr Area : Height : start Time : End Time : .S2e+004 7.70 8.72 I Sample Name: "$101122a067" Sample IO: "GLP10-01-02-5-048 LMS DAL S S SS04 0 0000 Lab Matrix Spike' Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent:"" Annotation:"" Sample Index: 67 File: "s101122a.wtfT Printing Time: 5:51:33 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb Sample Name: "s101122a066" Sample ID: "GLP10-01-02-05-048 Dup DAL S S S S04 0 0000 Duplicate " Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" C o m m e n t A n n o t a t io n : "" Sample index: 66 sample Type: Unknown concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 1:37:12 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: MMiinn.. PPeeaakk HWeiidgthh:t: No .00 cps sec smoothing width: points RT Window: Expected RT: use Relative RT: Area : Height : Start Time: End Time: I Sample Name: "s10 1 122a068" Sample ID: "G LP10-01-02-05-049 DAL SS SS 04 0 0005 ' Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" C o m m en t"" Annotation: "* Sample Index: 68 Sample Type: Unknown Concentration: 3.03 ng/ Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 2:25:37 PM Modified: NO Proc. Algorithm: Int Noise Percentage: Base. Sub. window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing width: RT Window: 3 Expected RT: Use Relative RT No Cps sec points File: "s101122a.wiff' Int. Type: Base To Base Retention Time: 7.89 min Area: 344170 counts Height: 3.3 Be+004 cps start Time 7.69 min End Time: Page 200 of 321 Page 385 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 386 of 962 Stan V1660305 I Sample Name: "s101122a073" Sample ID: "GLP10-01-02-05-050 I M S D A LS S TRIP1 0 0000 Lab Matrix Spike" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment:"" Annotation:"" Sample Index: 73 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 4:26:49 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: MMiinn.. PPeeaakk Hwieditghh:t No cps sec Smoothing width: points RT Window: Expected RT: Use Relative RT: NO Int. Type: Base To Base Retention Time: 7.89 min Area: 383808 counts Height: .S7e +004 cps Start Time: 7.70 min End Time: 8.79 min I Sample Name: "s101122a075" Sample ID: "GLP1U-01-02-05-051 Dup DAL S S SS05 0 0000 Duplicate " Peak Name: 'M PFB S(IS)" Mass(es): "303.0/64.0 amu" Comment: " Annotation: "" Sample Index: 75 File: "s101122a.wrfT Printing Time: 5:51:36 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sample Name: "81011228074* Sample ID: "GLP10-01-02-05-051 DAL SS S S 05 0 0000 " Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" I Comment "" Annotation: "" Sample Index 74 Sample Type: concentration: Unkn3o. 0w3n I Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 4 :SI :04 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 se Expected RT: 6.03 mi use Relative RT: No Area: Height : Start Time: End Time : I Sample Name: "s101122a076" Sample ID: "GLP10-01-02-05-051 LMS DAL S S S S05 0 0000 Lab Matrix Spike" Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent *" Annotation: "* Sample Index: 76 Sample Type: Unknown Concentration: 3.03 n calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 5:39:33 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: l . o o Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak width: smoothing width: No 0.00 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 8.03 mi Use Relative RT: No Area: Height : Start Time: End Time : 3 .18e+004 7.73 6.75 Page 202 of 321 Page 387 of 962 Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 388 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 389 of 962 Stan V1660305 I Sample Name: "s101122a065" Sample ID: "GLP10-01-02-05-054 LMS OAL SS SS06 0 0000 Lab Matrix Spike' Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" I Comment: "" Annotation: *" Sample Index: as Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 9:17:S6 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 8.03 min Use Relative RT: No Int. Type: Base To Base Retention Time: Area: 363650 counts Height: 3.17e*004 cps Start Time: 7.72 End Time: min TSample Name: "s101122a087" Sample ID: "GLP10-01-02-05-055 Dup DAL SS SS06 0 0005 Duplicate ' Peak Name: "MPFBS(tS)' Mass(es): "303.0/84.0 amu" Comment "" Annotation: " Sample Index: Sample Type: Concentration: Calculated Conc: N/A Acq. Date: 11/23/2010 Acq. Time: 10:06:25 PM File: "s101122a.wifP Modified: NO Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: l.oo Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps i . Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 se Expected RT: 8.03 mi Use Relative RT: No Int. Type: Base To Base Retention Time: 7.89 min Area: 394912 Counts Height : 3.56e+004 Cps Start Time: 7.69 min End Time: 9.14 min nting Time: 5:51:40 PM nting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sample Name: "$1011228086" Sample ID: "GLP10-01-02-05-055 DAL S Peak Name: "MPFBS(IS)' Mass(es): "303.0/84.0 amu" Comment"" Annotation: Sample Index: 86 Sample Type: Unknown concentration: 3.03 i Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 9:42:11 PM Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. sub. window: 1.00 Peak-split. Factor: S Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: No 0.00 o.oo 3 cps sec points RT window: Expected RT: 30.0 i mSiin Use Relative RT: l S 0 0005 ' File: "s101122a.wifT Area: Height : start Time: End Time : rSample Name: "s101122a088" Sample ID: "GLP10-01-02-05-055 LMS DAL SS SS06 0 0005 Lab Matrix Spike' Peak Name: 'MPFBS(IS)" Mass(es): "303.0/84.0 amu' Comment ~ Annotation: " Sample Index: 88 File: "s101122a.wifT Page 205 of 321 Page 390 of 962 *Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 391 of 962 Stan V1660305 I Sample Name: "s101122a093" Sample ID: "GLP10-01-02-05-057 Dup DAL SS SS07 0 0000 Duplicate " Peak Name: "MPFBS(IS)' Mass(es): "303.0/84.0 amu" Comment "" Annotation: "" Sample index: 93 sample Type: Unknown concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 12:31:5S AM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. MPiena.k WPiedatkh:Height C cps sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 6.03 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.68 min Area: 348419 counts Height: 3.1504-004 cps start Time: 7.72 min End Time: 9.11 min I Sample Name; "s101122a095" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(IS)" Mass(es): "303.0/64.0 amu" Comment:"" Annotation:"" sample Index: 95 Sample Type: Double Blank Concentration: 1.00 ng/mL calculated Cone: N/A A c q . Date: 11/24/2010 Acq. Time: 1:20:23 AM File: "s101122a.wiff` Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing Width: 3 points r t window: 30.0 sec Expected RT: Use Relative RT 8N.O03 min , Int. Type: Retention Time: Area: Height: start Time: End Time: Base To Base 8.06 min 61 counts l.56e*001 cps 7.93 min 8.71 min Printing Time: 5:51:43 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a094" Sample ID: "GLP10-01-02-05-057 IM S DAL SS SS07 0 0000 Lab Matrix Spike" Peak Name: "MPFBS(ISf Mass(es): "303.0/84.0 amu" Comment " Annotation:"" Sample Index: 94 Sample Type: Unknown concentration: 3.03 nc Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 12:56:11 AM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. Window: 1.00 r Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: No 0.00 0.00 3 cps sec points RT Window: 30.0sec Expected RT: 8.03 min Use Relative RT: No Int. Type: valley Retention Time: 7.89 min Area: 362676 counts Height: 3.1Se+0O4 cps Start Time: 7.72 min End Time: 8.54 min I Sample Name: "s101122a096" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" Peak Name: 'MPFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent"" Annotation:"" Sample Index: 96 File: "s101122a.wifr Page 207 of 321 Page 392 of 962 *Stan V1660305 I Sample Name: "s101122a097" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment:"" Annotation:"" Sample Type Concentration: Calculated cone Acq. Date: Sample Index: Double Blank 1.00 11/N2/4A/2010 97 ng/mL Acq. Time: 2:08:52 AM File: "s101122a.wifT Modified: No Proc. Algorithm: intelliQuan - MQII Noise Percentage: 50 Base. sub. window: l . o o min Peak-split. Factor: 4 Report Largest Peak: No Min. Peak Height: cps Min. Peak width: sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Retention Time: Area : Height : Start Time: End Time : Base To Base 7.93 min 121 counts ..95e+00l cps 7.89 min 3.28 min Sample Name: "s101122a099" Sample ID: "GLP10-01-02-05-058 Dup DAL SS SS07 0 0005 Duplicate" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" m Comment: " Annotation:"" Sample Index: 99 File: "8101122a.wiff inting Time: 5:51:45 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb [Sample Name: "s101122a098" Sample ID: "GLP10-01-02-05-058 DAL SS SS07 0 0005" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent"" Annotation: I sample Index: 98 9 sample Type: Unknown 9 concentration: 3.03 ng/mL | Calculated Cone: N/A Acq. Date: 11/24/2010 | Acq. Time: 2:33:08 AM File: "s101122a.wiff* Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak MMiinn.. PPeeaakk wHieditghh:t o.oo cps o .oo sec smoothing width: 3 points RT Window: sec Expected RT: 3 min use Relative RT: Area: Height : Start Time: End Time: 9 min counts 3 ,31e+004 7.70 8.37 ISample Name: "s101122a100" Sample ID: "GLP10-01-02-05-058 LMS DAL SS SS07 0 0005 Lab Matrix Spike" Peak Name: "MPFBS(IS)' Mass(es): "303.0/84.0 amu" Comment Annotation:"" Sample Index: 100 Sample Type: Concentration: calculated Cone: Acq. Date: Acq. Time: 3 .03 ng/mL N/A 11/24/2010 3:21:43 AM 9 Modified: No 9 Proc. Algorithm: IntelliQuan | Noise Percentage: so 9 Base. Sub. Window: 1.00 j Peak-Split. Factor: 4 9 Report Largest Peak: No | Min. Peak Height: 0.00 cps I Min. Peak width: o.oo sec J smoothing width: 3 points I RT Window: 30.0 se 9 Expected RT: 8.03 mi j use Relative RT: No File: "s101122a.wifr Int. Type: Base To Base Retention Time: 7.90 min Area: 361135 counts Height: 3 .47e*004 cps start Time: 7.70 min End Time: Page 208 of 321 Page 393 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 394 of 962 Stan V1660305 Sample Name: ''$1011223105" Sample ID: "GLP10-01-02-05-060 Dup DAL SS SS06 D6 0000 Duplicate" Peak Name: "MPFBS(IS)1' Mass(es): "303.0/84.0 amu" Comment:"" Annotation: "" Sample Index: 105 Sample T ype: Unknown 7gg Concentration: 3.03 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:23:01 AM File: "s101122a.wtff Modified: No Proc. Algorithm: IntelliQuan - MQI Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window; 30.0 sec Expected RT: 8.03 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.88 min Area: 380058 counts Height: 3.57e+004 cps Start Time: 7.71 min End Time: 8.81 min I Sample Name: "s101122a107" Sample ID: "GLP10-01-02-05-061 DAL SS SS08 0 0005" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84,0 amu" Comment: "* Annotation: Sample Index: 107 File: "$101122a.wifr Results Name: slOH22a.rdb Sample Name: "s101122a106" Sample ID: "GLP10-01-02-05-060 IMS DAL SS SS06 DB 0000 Lab Matrix Spike" Peak Name: "MPFBS(ISf Mass(es): "303.0/84.0 amu" Comment"" Annotation:"" Sample Index: 106 Sample Type: Unknown Concentration: 3.03 n Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:47:16 AM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. Window: 1.00 Peak-split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: No 0.00 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 8.03 mi use Relative RT: No Valley Area: Height : Start Time: End Time: .06e*004 7.68 8.56 199 (Sample Name: ''s101122a108" Sample ID: "GLP1Q-01-02-05-61 Dup DAL S i SS08 0 0005 Duplicate" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment Annotation: sample in d e x : 108 File: "s101122a.wifT inting Time: 5:51:48 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 210 of 321 Page 395 of 962 *Stan V1660305 I Sample Name: "s101122a109" Sample ID: "G LP10-01-02-05-061 LM S DAL i 3 SS08 0 0005 Lab Matrix Spike" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" I Com m ent: Annotation: "" Sample Index: 109 Sample Type: Unknown Concentrt ion : 3.03 I Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 7:00:00 AM File: "s101122a.wiff' Modified: NO Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. Window; i.oo i Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak width: o.oo Smoothing width: 3 RT window: 30.0 se< Expected RT: 8.03 mil Use Relative RT: No Int. Type: Base To Base Retention Time. 7.as min Area: 350857 counts Height: 3.20e+004 cps Start Time: 7.70 min End Time: 8.79 (Sample Name: "s101122a111" Sample ID: "GLP10-01-02-05-062 Dup DAL SS SS09 0 0000 Duplicate " Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment: "" Annotation: " Sample Index: ill File: "s101122a.wiff' Results Name: sl01122a.rdb (Sample Name: "$101122a110" Sample ID: "GLP10-01-02-05-062 DAL SS SS09 0 0000' Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment " Annotation:"" sample Index: 110 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 7:24:12 AM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window: l.oo min Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: No o 0 3 cps sec points RT window: 30.0 Expected RT: 8.03 Use Relative RT: No Int. Type: Retention Time: Area: Height: 33.7ie004 start Time: End Time: cps 1Sample Name: "s101122a112" Sample ID: "GLP10-01-02-05-062 LMS DAL SS SS09 0 0000 Lab Matrix Spike" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent"" Annotation:" sample index: 112 Sample Type: Unknown concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 8:12:38 AM File: ,,s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: l.oo Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: Min. Peak width: o.oo o.oo cps sec Smoothing width: 3 points RT Window: 30.0 se Expected RT: 8.03 mi Use Relative RT: No Area: Height : Printing Time: 5:51:49 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 211 of 321 Page 396 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:51:51 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 212 of 321 Page 397 of 962 *Stan V166030S Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 398 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 399 of 962 Stan V1660305 I Sample Name: "s101122a125M Sample ID: "GLP10-01-02-05-066 DAL SS GP01 0 0020 " Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" I Comment: Annotation: "" Sample Index: 125 Sample Type: Unknown Concentration: 3.03 i Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:28:03 PM File: "s101122a.wifr Modified: Yea Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 5 Report Largest Peak: No Min. Peak Height: c cps Min. Peak width: c sec Smoothing Width: 3 points RT window: 30.0 Expected RT: 7.88 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.88 min Area: 328697 counts Height: 2.90e+004 cps Start Time: 7.72 min End Time: 8.79 min (Sample Name; "s101122a127" Sample ID: "GLP10-01-02-05-066 LMS DAL SS GP01 0 0020 Lab Matrix Spike" Peak Name: 'MPFBS(IS)" Mass(es): "303.0/84.0 amu" C om m ent"" Annotation: "" sample Index: 127 File: "s101122a.wtff Printing Time: 5:51:55 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a126" Sample ID: "GLP10-01-02-05-066 Dup DAL S I GP01 0 0020 Duplicate" Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment ~ Annotation:"" Sample Index: 126 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:S2:20 PM 3.2e4 Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: 1.00 Peak-Split. Pactor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window; 30.0 sec Expected RT: 8.03 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.87 min Area: 383501 counts Height: 3.6 oe+004 cps Start Time: 7.72 min End Time: 8.84 min 3.0e4 2.8e4 2.6e4 2.4e4 2.2e4 2.0e4 1.8e4 1.6e4 1.4e4 1.2e4 File: "s101122a.wiff 1.0e4 ISample Name: "s101122a128" Sample ID: "GLP10-01-02-05-067 DAL SS GP01 0 0060' Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" SamCpolmemIenndt e""x: Annota1tio2n8: *" Sample Type: Unknown concentration: 3 .0 3 j calculated Cone: N/A Acq. Date: 11 /2 4/2 01 0 Acq. Time: 2 : 4 0 : 5 7 PM 992 1191 Time, min File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height Min. Peak width: 0 . 00 cps sec smoothing width: points RT Window: Expected RT: Use Relative RT: Area: Height : start Time: End Time: 2.96e +004 7.69 8.81 1587 1785 1984 2182 Page 215 of 321 Page 400 of 962 *Stan V1660305 I Sample Name: "s101122a129" Sample ID: "GLP1Q-01-02-05-067 Oup DAL S i GP1 0 0060 Duplicate " Peak Name: "MPFBS(IS)" Mass(es): "303.0/64.0 amu" I Comment Annotation: Sample Index: 129 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 3:05:12 PM 2.2e4- Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: l.oo Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 se Expected RT: 6.03 mi Use Relative RT: No 2.0e41.8*41.6e4 1.4e4- File: "*101122a.wifr Int. Type: Valley Retention Time : 7.89 min Area : 2 5243 6 counts Height : 2.47e+004 cps start Time : 7.68 End Time: 8.25 min 1.2*41.0*46000.0 6000.0- 2 199 Sample Name: "s101122a131* Sample ID: *10 006-25 solvent blank" Peak Name: "MPFBS(IS)' Mass(es): *303.0/64.0 amu* I Comment: "* Annotation: "" Sample Index: 131 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 3:53:48 PM File: "s101122a.wiff Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: l.oo min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 3o.o sec Expected RT: 8.03 min v Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time : End Time : Base To Base 8.05 min 61 counts .84e+001 cps 8 . 0 0 min 9.11 min J inting Time: 5:51:57 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 a 794 Results Name: sl01122a.rdb I Sample Name: "81011223130" Sample ID: "GLP10-01-02-05-067 LMS DAL SS GP01 0 0060 Lab Matrix Spike" Peak Name: *MPFBS(IS)" Mass(es): "303.0/64.0 amu" Com m ent"" Annotation:"" Sample Index: 130 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 3:29:31 PM File: "s101122a.wifr Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window; 1.00 min Peak-split. Factor: 4 Report Largest Peak: No Min. MPiena.k wPiedatkh:Height 0. 0 0 cps sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Area: Height: Start Time: End Time : 2.80e*004 7.69 9.39 I Sample Name: *s101122a132* Sample ID: "EC-101116-07 10 ng Extracted Curve Point" Peak Name: *MPFBS(ISr Mass(es): *303.0/64.0 amu" I Comment "* Annotation: "" Sample index: 132 Sample Type: QC Concentration: 3.03 n Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:18:04 PM File: *s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 se Expected RT: a.03 mi Use Relative RT: No Area: Height: Start Time: End Time: .90e+004 7.72 8.77 Page 216 of 321 Page 401 of 962 Stan V1660305 Sample Name: "s101122al33" Sample ID: ` 10 006-25 solvent blank" I Peak Name. "M PFBS(lSf Mass(es): "303.0/84,0 amu" I Comment ~ Annotation: *" Sample Index: 133 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:42:25 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.03 min , Use Relative RT: No Int. Type: Base To Base Retention Time: 8.08 min Area: 170 counts Height: 4.ooeooi cps Start Time: 7.84 min End Time: 8.90 min I 1 I Sample Name: "s101122al35" Sample ID: "GLP10-01-02-05-068 Dup DAL SS GPQ2 0 0000 Duplicate " I Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu" I Comment: "" Annotation: *" Sample Index: Sample Type : Concentration: 3.03 ng/mL calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:31:02 PM File: "s101122a.wrfT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. window: 1.00 Peak-split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 se Expected RT: 8.03 mi Use Relative RT: No Int. Type: Base To Base Retention Time: 7.90 min Area : 363612 counts Height : 3.40e*0 04 cps Start Time : 7.72 min End Time : 8.73 min Printing Time: 5:51:58 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a134" Sample ID: "GLP10-01-02-05-068 DAL SS GP02 0 0000 " Peak Name. "MPFBS(lSy Mass(es). "303.0/84.0 amu" Comment "* Annotation; sample Index: 134 Sample Type: Unknown concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:06:41 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Pactor: 4 Report Largest Peak: MMiinn.. PPeeaakk HWieditghh:t No 0.00 cps sec Smoothing width: points RT Window: 30.0 sec Expected RT: 8.03 min use Relative RT: No Int. Type: Base To Base Retention Time: 7.88 min Area: 341902 counts Height: 3.fi7e004 cps Start Time: 7.71 min End Time: 8.77 min _________________________________________________ Time, r Sample Name: "s101122ai36" Sample ID: "GLP10-01-02-C Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment "" Annotation: Sample Index: 136 Sample Type: Unknown Concentration: calculated Cone: 3.03 N/A ng/mL 3.0e4 Acq. Date: 11/24/2010 Acq. Time: 5:55:17 PM Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: So Base. Sub. Window: 1.00 Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT Window: 30.0 se Expected RT: 8.03 mi use Relative RT: No Int. Type: Base To Base Retention Time: 7.91 min Area: 337254 counts Height: 3.07e004 CpS Start Time: 7.72 min End Time: 8.83 min Page 217 of 321 10 12 992 1191 Time, min Page 402 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 403 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 404 of 962 Stan V1660305 I Sample Name: "s101122a145" Sample ID: "GLP10-01-02-05-071 LMS DAL S S GP02 DB 0020 Lab Matrix Spike" Peak Name: "MPFBS(IS)' Mass(es): "303.0/84.0 amu" Com m ent"* Annotation: *" Sample Index: 145 Sample Type: Unknown Concentration: 3.03 ng/; Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 9:33:50 PM Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. Window: l.oo Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window; 30.0 se Expected RT: S.03 mi use Relative RT: No File: "s101122a.wiT Area: Height : Start Time: End Time : 2.9Se+004 7.71 8.79 I Sample Name: "s101122a147" Sample ID: "GLP10-01-02-05-072 Dup DAL SS GP02 0 0120 Duplicate " Peak Name: 'MPFBS(IS)' Mass(es): "303.0/84.0 amu* Comment:"" Annotation: ~ Sample Index: 147 File: "s101122a.wifT Printing Time: 5:52:02 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl0H22a.rdb I Sample Name: "s101122a146" Sample ID: "GLP10-01-02-05-072 DAL SS GP02 0 0120" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment "* Annotation: " Sample Index: 146 Sample Type: Unknown concentration: 3.03 n Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 9:58:07 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: 1.00 Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak width: smoothing width: No 0.00 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 8.03 mi Use Relative RT: No Valley Area : Height : start Time: End Time: 2 ,77e*004 7.72 8.79 Sample Name: "s101122a148" Sample ID: "GLP10-01-02-05-072 LMS DAL S GP02 0 0120 Lab Matrix Spike' Peak Name: *MPFBS(lsr Mass(es): "303.0/84.0 amu" I Comment "" Annotation: Sample Index: 148 Sample Type: unknown Concentration: 3.03 nc Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 10:46:43 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: < cps Min. Peak width: ( sec Smoothing width: : points RT Window: 30.0 Expected RT: s.o: Use Relative RT: No int. Type: Retention Time: Area: Height: Start Time: End Time: 9 min counts 2 .31e004 cps min min Page 220 of 321 Page 405 of 962 Stan V1660305 Results Name: slOH22a.rdb Printing Time: 5:52:04 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 221 of 321 Page 406 of 962 *Stan V1660305 I Sample Name: "s101122a1S3" Sam ple ID: "G LP10-01-02-05-073 Dup D AL S S G P 03 0 0 000 D u p lic a te " Peak N ame: "M PFB S(IS)" M ass(es): '3 03 .0/84 .0 am u' I Comment: ~ A n no ta tion :"" Sample Index: 1S3 Sample Type: Unknown Concentration: 3.03 ng/mL calculated Cone: N/A Acq. Date: ' 11/2S/2010 Acq. Time: 12:48:14 AM File: "s101122a.wtfT Modified: Ho Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 point: RT Window: 30.0 sec Expected RT: 8.03 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.90 min Area: 354619 counts Height: .29e +004 cps Start Time: 7.70 min End Time: 8.85 min I Sample N am e: "s101122a155" Sam ple ID: "GLP10-01-02-05-074 DAL S S G P 03 0 0 0 0 5 ' Peak Name: "M PFBS(IS)" Mass(es): "303.0/84.0 amu' I C om m ent:"" Annotation: " Sample Index: 155 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 1:36:46 AM Fite:' s101122a.wtfr j Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: Report Largest Peak Min. Peak Height: 0 . 0 0 cps Min. Peak Width: 0. 00 sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Area: Height : Start Time: End Time : .07e*004 7.71 8.63 inting Time: 5:52:05 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample N ame: "s101122a154* Sample ID: "G IP 1 0-01-02-05-073 LMS DAL SS G P03 0 0000 Lab M atrix S pike" Peak Name: 'M P F B S (IS f Mass(es): "303.0/84.0 amu" Com m ent "* Annotation:"" Sample Index: 154 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 1:12:31 AM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: cps Min. Peak Width: Smoothing Width: 3] RT Window: 30.0 sec Expected RT: 8.03 min Use Relative RT: No Int. Type: Valley Retention Time: 7.89 min Area: 347617 counts Height: 3.33e+004 cps Start Time: 7.71 min End Time: 8.53 min I Sample Name: "s101122a156" Sam ple ID: 'G LP10-01-02-05-074 Dup DAL S S G P03 0 0005 D up lica te " Peak Name: "MPFBS(ISF Mass(es): "303.0/84.0 amu" Com m ent "" Annotation: " sample index: 156 File: "s101122a.w jfT Page 222 of 321 Page 407 of 962 *Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:52:07 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 223 of 321 Page 408 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 409 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:52:09 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 225 of 321 Page 410 of 962 Stan V1660305 (Sample Name: " s i 01122a 169" Sample ID: *10 006-25 s olvent blank" Peak Name: "MPFBS(IS)* Mass(es): *303.0/04.0 amu* C o m m e n t " * Annotation: *" Sample Index: 169 Sample Type: Double Blank * Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/2S/2010 Acq. Time: 7:16:5S AM File: "s101122a.wifT Modified: . No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Pactor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: Expected RT: Use Relative RT: 30.0 6.03 No sec min ,, Int. Type: Base To Base Retention Time: 7.83 min 169 counts Height : 3.S6e+001 cps Start Time: 7.72 min End Time : 8.73 min Results Name: slOH22a.rdb I Sample Name: *s101122a170* Sample ID: "GLP10-01-02-05-078 DAL S 5G P 04 0 0 0 00 " Peak Name: *M P F B S (IS f Mass(es): *303.0/84.0 amu* C om m en t *" Annotation: Sample Index: File: *s101122a.wtfT T Sample Name: *s101122a171* Sample ID: 'G LP10-01-02-05-078 D up D AL SS G P 04 0 0000 Duplicate " Peak Name: *MPFBS(IS)* Mass(es): ` 303.0/84.0 amu* Com m ent: -- Annotation: ** Sample Index: Sample Type: Concentration : Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 6:05:35 AM 10 12 992 1191 Tim e, min File: " s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height cps Min. Peak Width: sec Smoothing Width: points RT window: Expected RT: Use Relative RT: Area: Height : Start Time : End Time : cps min min 16 1587 20 1984 22 2182 I Sample Name: *s101122a172* Sample ID: 'G LP10-01-02-05-078 LMS DAL SS G P 04 0 0000 Lab M atrix S pike* Peak Name: "M P F B S (IS f Mass(es): *303.0/84.0 amu' Comment ** Annotation: *" sample Index: 172 Sample Type: Unknown Concentration: 3.03 n Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 6:29:50 AM File: *s1 01 12 2a .w ifr Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: l.oo Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: No o.oo o.oo 3 cps sec points RT window: 30.0 se Expected RT: 8.03 mi use Relative RT: No valley Area: Height : start Time: End Time : cps min min Printing Time: 5:52:11 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 226 of 321 Page 411 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:52:12 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 227 of 321 Page 412 of 962 *Stan V1660305 Sample Name: "s101122a177" Sample ID: "G UP 10-01-02-05-080 Dup DAL SS GP04 0 0 020 D u p lica te " Peak Name: "M PFBS(IS)" Mass(es): "303.0/84.0 amu" C om m ent:"" Annotation: "" Sample Index: 177 Sample Type: Unknown Concentration: 3.03 nt calculated cone: N/A Acq. Date: 11/2S/2010 Acq. Time: 10:31:20 AM Pile: "s101122a.w iff' Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. sub. window: 1.00 i Peak-split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak width: smoothing width: No 0.00 0.00 3 cps sec points RT window: 30.0 set Expected RT: 6.03 mi) Use Relative RT: No Area: Height : Start Time: End Time : rSample Name: "s101122a179" Sample ID: "M B -1 01116-07 M ethod Blank 5g w 1 1S fo r D ilu tions" Peak Name: 'M PFBS(IS)" Mass(es): "303.0/84.0 amu" Com m ent:"" A nnotation:"" Sample Index: 179 Sample Type: Unknown Concentration: 3.03 ng/mL Calculated cone: N/A Acq. Date: 11/25/2010 Acq. Time: 11:19:55 AM File: "s 1 01 12 2a .w ifr Modified: No Proc. Algorithm: IntelliQuan - MQi: Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.03 min use Relative RT: No Int. Type: Valley Retention Time: 7.90 min Area : >266S0 counts Height : 2.79e*004 cps Start Time: End Time : Printing Time: 5:52:14 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a178" Sam ple ID: "GLP10-01-02-05-080 LMS DAL S S GP04 0 0020 Lab M atrix Spike" Peak Name: " M PFBS(IS)" Mass(es): "303.0/84.0 amu" C o m m e n t"" Annotation: " . sample Index: 178 Sample Type: Unknown concentration: 3.03 n< calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 10:55:36 AM File: "s 101122a .w ifr Modified: Yes proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: 1.00 1 Peak-Split. Factor: 5 Report Largest Peak: Min. Peak Height: Min. Peak width: smoothing width: No cps sec points RT Window: 30. ( Expected RT: 8.( use Relative RT: No Area: Height: Start Time: End Time : 2.96e +004 cps 7.67 min 8.73 min (Sample Name: "s101122a180" Sample ID: "MB-101116-06 P eak Name: "MPFBS(!Sr Mass(es): "303.0/84.0 amu' C o m m e n t"" Annotation: " . sample Index: 180 sample Type: Unknown Concentration: 3.03 ng/mL calculated Cone: N/A 3 Acq. Date: 11/25/2010 Acq. Time: 11:44:14 AM Modified: No proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min peak-split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT Window: 30.0 sec Expected RT: 8.03 min Use Relative RT : NO int. Type: Valley 0 # Retention Time: 7.88 min 0 Area: 358656 counts B Height: 3 ,12e*004 cps Start Time: 7.73 min End Time: 6.69 min Page 228 of 321 992 1191 Time, m in Page 413 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 414 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 415 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:52:18 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 231 of 321 Page 416 of 962 *Stan V1660305 I Sample N ame: "s101122a010" Sample ID: "E C -101116-01 0.2 ng Extracted Curve Point" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment: "" A n n o ta tio n :"" Sample Index: 10 Sample Type: concentration: 3.00 N/A ng/mL Calculated Cone: 1 1 / 22/2010 Acg. Date: 3:00:53 PM Acq. Time: Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: Expected RT: sec min Use Relative RT: File: "s 1 01 12 2a .w ifr Area : Height : Start Time : End Time : Valley 10.4 157925 CO' 1.36e+004 10.2 10.9 I Sample Name: "s101122a012" Sample ID: "E C -1 01116-03 0 .75 ng Extracted Curve P o in t Peak Name: "MPFHS(IS)" Mass(es): " 403.0/84.0 amu" 1 Comment: "" Annotation: Sample Index: 12 Sample Type: Standard Concentration: 3.00 ng/mL calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 3:49:18 iPM File: "s 1 0 1 1 2 2 a .w ift Modified: NO Proc. Algorithm: IntelliQuan - IQ/ Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type: Valley Retention Time: 10.4 min Area: 152955 counts Height : 1.32e+004 cps Start Time : 10.2 min End Time : 11.0 min Printing Time: 5:52:20 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: slOH22a.rdb I Sample Name: "s101122a011" Sample ID: "EC-101116-02 0.5 ng Extracted C urve P o in t Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C om m ent Annotation: "" Sample Index: ll Sample Type: standard concentration: 3.oo n< Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 3:25:08 PM File: "s1 0 1 1 2 2 a .w iff Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: 0.00 cp: Min. Peak Width: 0.00 poseitnts Smoothing Width: : sec RT Window: Expected RT: Use Relative RT: Height : start Time: End Time: 1.32e+004 10.2 11.0 ( Sample N ame: "s101122a013" Sample ID: "EC-101116414 1 ng Extracted Curve P o in t Peak Name: "MPFHS(IS)" Mass(es): *403.0/84.0 amu" C om m en t "" Annotation: Sample Index: 13 File: "s1 01 12 2a .w ifr Page 232 of 321 Page 417 of 962 *Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 418 of 962 Stan V1660305 [Sample Name: "s101122a018" Sample ID: "E C-101116-09 50 ng Extracted C urve Point" Peak Name: " M PFHS(IS)" M ass(es): "4 03.0/84.0 armT Comment: " A n n o ta tio n :"" Sample Index: IB Sample Type: Standard Concentration: 3.00 ) Calculated Cone: N/A Acq. Date: 11/ 22/2010 Acq. Time: 5:14:25 PM File: "s 1 0 1 1 2 2 a .w iff Modified: Proc. Algorithm: Min. Peak Height Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: No IntelliQuan IQA 0.00 CpS o . oo sec points 30.0 sec 1 0 . 6 min No Int. Type: Valley Retention Time: 10.4 min Area: 16237B counts Height: 1.31e+004 cps start Time: 10.2 min End Time: 10.9 min I Sample Name: "s101122a020" Sample ID: "E C-101116-11 200 ng Extracted Curve Point" Peak Name: "M PFH S(IS )" M ass(es): "403.0/84.0 am u" Comment: "" Annotation: " Sample Index: 20 Sample Type : Concentrt ion: Calculated Cone: Acq. Date: Acq. Time: File: "s101122a.w tfT Modified: Proc. Algorithm: Min. Peak Height Min. Peak width: Smoothing width: RT Window: Expected RT: Use Relative RT: Int. Type : Retention Time: Area : Height : Start Time : End Time : Printing Time: 5:52:23 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ( Sample Name: "s101122a019" Sample ID: "EC-101116-10 100 ng Extracted Curve Po int' Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C o m m e n t"" A nnotation:"" sample Index: 19 Sample Type: Concentration: Calculated Cone: Acq. Date: Acq. Time: N/A 11/22/2010 6 :3B :37 PM Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing Width: points RT Window: 30.0 sec Expected RT: 10.6 Use Relative RT: File: "s101122a.wtfT Area: Height: start Time: End Time : 1.14e+004 10.2 11.0 I Sample Name: "s101122a021" Sample ID: "EC-101116-12 500 ng Extracted Curve Po int' Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Com m ent "" Annotation: "" Sample Index: 21 File: "s101122a.w iff' Page 234 of 321 Page 419 of 962 *Stan V1660305 I Sample Name: "s101122a022" Sam ple ID: " 10 006-25 solvent b lank" I Peak Name: "M P F H S (IS )' Mass(es): "403.0/84.0 amu" 1 Comment: "" Annotation: ~ Sample Index: 22 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 7:51:11 PM File: "s101122a.w iff' Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 10.6 min 34 counts 2.60e+001 cps 10.6 min 10.7 min g% I Sample Name: "s101122a024" Sample ID: "1 0 006-25 solvent blank" Peak Name: ' MPFHS(IS)" Mass(es): "403.0/84.0 amu* I Comment: "* Annotation: Sample Index: 24 Sample Type: Double Blank Concentration: 1.00 ng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 0:39:32 PM File: "s 1 0 1 1 2 2 a .w iff Modified: No inting Time: 5:52:24 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sam ple Name: "s101122a023" Sam ple ID: "10 0 06-25 solvent blank" Peak Name: "M PFH S(IS f Mass(es): "403.0/84.0 amu" I C om m en t "" Annotation: "* sample Index 23 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/ 22/2010 Acq. Time: 8:15:23 PM File: "s1 01 12 2a .w iff Modified: No I Sam ple Name: "s101122a025" Sample ID: *10 006-25 solvent blank" Peak Name: "M P F H S fIS f Mass(es): "403.0/84.0 amu" C om m ent "* Annotation:"" Sample Index: 25 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:03:42 PM File: "s101122a.wifT Modified: No proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0o.. o00o M i n . Peak width: 3 Smoothing width: 30.o RT Window: 10.6 Expected RT: cspesc points sec min Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time : Valley 10.7 min 70 counts S.30e*ooi cps 10.7 min 10.7 min Page 235 of 321 Page 420 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 421 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 422 of 962 Stan V1660305 (Sample Name: "s101122a034" Sample ID: "LC S-101116-03 3 ng LCS in TCR-842" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C om m ent:"" Annotation:"" Sample Index: 34 sample Typ e : Unknown Concentration: 3.00 ng/mL calculated cone: . n /a Acq. Date: 11/23/2010 Acq. Time: 12:41:35 AM File: "s 101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10. min Use Relative RT: No Int. Type: Valley Retention Time: 10.4 min Area: 167130 counts Height : l.50e+004 cps Start Time 10.2 min End Time: 11.0 min T Sample Name: "s101122a036" Sample ID: "LC S-101116-05 30 ng LC S in TCR-842" Peak N am e: ' MPFHS(IS)' Mass(es): "403.0/84.0 amu" Com m ent: "" Annotation: "" Sample Index: File: "s 1 0 1 1 2 2 a .w ir Results Name: sl01122a.rdb I Sam ple N am e: "s101122a035" Sam ple ID: "LC S-101116-04 30 ng LCS in T C R-842" Peak Name: "M P F H S (IS f Mass(es): "403.0/84.0 amu" I C om m en t "" Annotation: Sample Index: 35 Sample Type: Unknown concentration : calculated Cone: .00 N/A ng/mL 1.20e4- Acq. Date: 11/23/2010 Acq. Time: 1:05:50 AM 1.10e4- Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO 1.00e49 0 0 0 .0 0 8 0 0 0 .0 0 - File: " s10 11 22 a.w iff Int. Type: valley Retention Time: 10.4 min Area: 170338 counts Height : 1.23e004 cps start Time: 10.2 End Time: 11.0 min b 7000.00g- | f 6000.00 I Sample Name: " s l O l ^ a O S r Sample ID: "LC S-101116-06 30 ng LCS in T C R -6 42 " Peak Name: "M PFHS(lsr Mass(es): "403.0/84.0 amu" C om m ent "" Annotation: "" Sample Index: 37 10 12 902 1191 _____ Time, min File: "s1 01 12 2a .w ifr Printing Time: 5:52:29 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 238 of 321 Page 423 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:52:31 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 239 of 321 Page 424 of 962 *Stan V1660305 ( Sample Name: "s101122a042" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" Peak Name: "M PFHS(lsr Mass(es): "403.0/64.0 amu" Comment: " * Annotation: " Sample Index: 42 Sample Type: Concentration: QC 3.00 ng/mL calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 3:55:29 AM File: "s101122a.wiff io.38 Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Area: Height : start Time: End Time : l.4Se+004 cps min min I Sample Name: "s101122a044" Sample ID: "GLP10-01-02-OS-042 DAL SS SS01 0 0005 " Peak Name: 'MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment: "" Annotation: "" Sample Index: 44 File: "s101122a.wfT inting Time: 5:52:32 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: *s101122a043" Sample ID: "10 006-25 solvent blank" Peak Name: ' MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment "" Annotation: "" Sample Index: Sample Type: Concentration: Calculated Cone Acq. Date: Acq. Time : Do4u3ble Blank 1.00 ng/mL N/A 11/23/2010 4 :19:46 AM Modified: No File: "s101122a.wifT ( Sample Name: "s101122a045" Sample ID: "GLP10-01-02-05-042 Dup DALSSSS01 0 0005 Duplicate" Peak Name: "MPFHS(ISr Mass(es): "403.0/84.0 amu" Comment "" Annotation: Sample Index: 45 Sample Type: Concentration: N/A Calculated Cone: 11/23/2010 Acq. Date: 5:08:17 AM Acq. Time: Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No File: "s101122a.wifT Int. Type : Valley Retention Time : 10.4 min Area: 170345 counts Height : i.3Oe+004 cps Start Time: 10.2 min End Time : 11.0 min Page 240 of 321 Page 425 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 426 of 962 Stan V1660305 I Sample Name: "s101122a050" Sample ID: "GLP10-01-02-05-044 DAL Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment:"" Annotation:" * Sample Index: SO Sample Type: Unknown Concentration: 3.00 ng/mL calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 7:09:25 AM 5 SS02 0 0005 " File: "s101122a.wifr Modified: Yes MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- IQA Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: use Relative RT: NO Int. Type: Valley Retention Time: 10.4 min Area: 149796 counts Height : 1.31e*004 cps Start Time: 10.1 End Time: 10.9 min Results Name: sl01122a.rdb ISample Name: "s101122a051" Sample ID: "GLP10-01-02-05-044 Dup DAL SS SS02 0 0005 Duplicaten Peak Name: "MPFHS(ISy Mass(es): "403.0/84.0 amu" samCpolmemIenndt e""x: AnnotatioSnI: Sample Type: Unknown Concentration: 3.00 i Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 7:33:38 AM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Valley Retention Time: 10.4 min Area: 161099 counts Height: 1.2 6e*004 cps Start Time: 10.2 min End Time : 10.9 min I Sample Name: "s101122a052" Sample ID: "GLP10-01-02-05-044 LMS DALSS SS02 0 0005 Lab Matrix Spike" Peak Name: "MPFHS(IS)" Mass(es): "403.0/64.0 amu" Comment " Annotation:"" sample in d e x : 52 File: "s101122a.wifT Sample Name: "s101122a053" Sample ID: "GLP1D-01-02-05-045 DAL SS SS03 0 0000" File: "s101122a.wifT T Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment "* Annotation: *" Printing Time: 5:52:35 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 242 of 321 Page 427 of 962 Stan V1660305 I Sample Name: "s101122a054" Sample ID: "GLP10-01-02-05-045 Dup DAL SS SS03 0 0000 Duplicate " Peak Name: *MPFHS(IS)' Mass(es): *403.0/84.0 amu* Comment *" Annotation: Sample Index: S4 Sample Type: Unknown Concentration: 3.oo ng calculated cone: n /a Acq. Date: 11/23/2010 Acq. Time: 9:46:17 AM File: "s101122a.wifr Modified: Yes Min. PeParkoc.HeiAglhgto:rithm: InteclplsiQuan - Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Int. Type: Valley Retention Time 10.4 min Area : 169402 counts Height : 1.23e+004 cps Start Time: 10.1 min End Time : 10.9 min I Sample Name: "s101122a056* Sample ID: *GLP10-01-02-05-046 DAL SS SS03 0 0005" Peak Name: "MPFHS(IS)" Mass(es): *403.0/84.0 amu* Comment: " * Annotation:"" Sample Index: 56 File: "s101122a.wiff Results Name: sl01122a.rdb Sample Name: " s101122a0S5" Sample ID: "GLP10-01-02-05-045 LMS DAL SS SS03 0 0000 Lab Matrix Spike* Peak Name: *MPFHS{IS)" Mass(es): *403.0/84.0 amu* Comment Annotation:"" Sample Index: S5 File: "s101122a.wifr ISample Name: Hs101122a057" Sample ID: "GLP10-01-02-05-046 Dup DAL SS SS03 0 0005 Duplicate" Peak Name: "MPFHS(IS)" Mass(es): *403.0/84.0 amu* Comment "* Annotation:"" Sample Index: 57 File: " s101122a.wifr Printing Time: 5:52:36 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 243 of 321 Page 428 of 962 Stan V1660305 Sample Name: "s101122a058* Sample ID: "GLP10-01-02-05-046 LWIS DAL SS SS03 0 0005 Lab Matrix Spike" Peak Name: "MPFHS(IS)' Mass(es): *403.0/84.0 amu" Comment:"" Annotation:"" sample index: 56 File: "$101122a.wifr Results Name: slOH22a.rdb Sample Name: "s101122a059" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFHS(ISr Mass(es): *403.0/84.0 amu" Comment"" Annotation:"" Sample Index: S9 Sample Type Double Blank Concentration: 1.00 ng/mL calculated Cone N/A Acq. Date: 11/23/2010 Acq. Time: 10:47:24 AM File: s101122a.wtfT' Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 10.5 min 36 counts 2 , 8 6 e *001 cps min I Sample Name: "s101122a060" Sample ID: "EC-101116-06 5 ng Extracted Curve P oint" Peak Name: "MPFHS(tS)" Mass(es): *403.0/84.0 amu" Comment:"" Annotation:"" Sample Index: 60 File: *s101122a.wifT I Sample Name: "s101122a061" Sample ID: "10 006-25 solvent blank" Peak Name: ' MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment Annotation: "" sample index: 61 sample Type: Double Blank ' concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 11:35:55 AM File: "s101122a wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0o..0o0o cspesc MSimno.othPienagk Wwiiddtthh:: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type: Retention Time: Area: Height: start Time: End Time: valley 10.6 min 34 counts 2 .60e+ooi cps 10.5 min 10.6 min Printing Time: 5:52:38 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 244 of 321 Page 429 of 962 *Stan V1660305 I Sample Name: "s101122a062" Sample ID: "GLP10-01-02-05-047 DAL Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment Annotation:"" Sample Index: 62 Sample Type: Unknown Concentration: 3.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 12:00:10 PM Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height; 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No 3 SS03 DB 0005 " File: Ms101122a.wifT Area: Height: Start Time : End Time : Results Name: slOH22a.rdb I Sample Name: "$101122a063" Sample ID: "GLP10-01-02-05-047 Dup DAL Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Com m ent"" Annotation:"" sample Index: 63 sample Type: unknown Concentration: 3.00 ng/mL Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 12:24:29 PM 3 SS03 DB 0005 Duplicate " File: "s101122a.wiff' Modified: Yes MPirno.c. PAelagkorHietihgmh:t: IntelliQuancps- IQA Min. Peak Width: sec Smoothing Width: points RT Window; sec Expected RT: Use Relative RT: Int. Type: valley Retention Time: 10.4 min Area: 1714S8 counts Height: l.27e*004 cps start Time: 10.2 min End Time : 11.0 min Sanmple Name: "s101122a064" Sample ID: "GLP10-01-02-05-047 LMS DALSS SS03 DB 0005 Lab Matrix Spike" I Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Im CConmment "" Annotation: "" sample Index: 64 Sample Type : Unknown concentration: 3.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 12:48:43 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - i q ; Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type: valley Retention Time: 10.4 min Area: 142091 counts Height : 9.75e*003 cps start Time : 10.2 min End Time : 11.0 min ( Sample Name: "s101122a065" Sample ID: "GLP10-01-02-05-048 DAL SS SS04 0 0000" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment "" Annotation: "" Sample Index: 6S Sample Type: Unknown Concentration: 3.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 1:12:58 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type: Valley Retention Time: 10.4 min Area: 185496 counts Height: l .54e+004 cps Start Time: 10.2 min End Time: 10.9 min inting Time: 5:52:39 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 245 of 321 Page 430 of 962 Stan V1660305 I Sample Name: "s101122a066" Sample IO: "GLP10-01-02-05-048 Dup DAL SS SS04 0 0000 Duplicate' Peak Name: ' MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment: "" Annotation: "" sample index: 66 File: Hs101122a.wifT Results Name: sl01122a.rdb I Sample Name: "s101122a06r Sample ID: "GLP10-01-02-05-048 LMS DAL SS SS04 0 0000 Lab Matrix Spike' Peak Name: "MPFHS(ISf Mass(es): '403.0/84.0 amu" Comment Annotation: "* sample Index: 67 File: Hs101122a.wifT I Sample Name: "s101122a068* Sample ID: ' GLP10-01-02-05-049 DAL SS SS04 0 0005 ' Peak Name: ' MPFHS(IS)' Mass(es): "403.0/84.0 amu" Comment: Annotation: "" Sample Index: 68 File: "s101122a.wifT Printing Time: 5:52:41 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Sample Name: 's101122a069" Sample ID: 'GLP10-01-02-05-049 Dup DAL SS SS04 0 0005 Duplicate ' Peak Name: ' MPFHS(IS)" Mass(es): ' 403.0/84.0 amu' ffComment: ~ Annotation: "* sample index: sample Type: concentration: I calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 2:49 :SO PM File: "s101122a.wifT Modified: Yes proc. Algorithm: intelliQuan Min. Peak Height: 0.00 cp: Min. Peak width: 0.00 sei Smoothing Width: 3 poii rT window: 30.0 sei Expected RT: 10.6 mil use Relative RT: No Int. Type : Valley Retention Time: 10.4 min Area : 181434 counts Height : 1.45e +004 cps start Time 10.2 min End Time : 10.9 min Page 246 of 321 Page 431 of 962 Stan V1660305 I Sample Name: "s101122a070" Sample ID: "GLP10-01-02-05-049 LMS DAL SS SS04 0 0005 Lab Matrix Spike' Peak Name: 'MPFHS(IS)' Mass(es): '403.0/84.0 amu* C o m m e n t:A n n o ta tio n :"" Sample Index: 70 Sample Type: Concentration: Calculated Cone: Acq. Date: Acq. Time: File: ns101122a.wiT Modified: Proc. Algorithm: Min. Peak Height: Min. Peak width: smoothing width: RT Window: Bxpected RT: Use Relative RT: Int. Type: Retention Time: Area: l< Height: ] Start Time: End Time: Results Name: slOH22a.rdb I Sample Name: "s101122a071" Sample ID: "GLP10-01-02-05-050 DAL SS TRIP1 0 0000" Peak Name: "MPFHS(ISr Mass(es): "403.0/84.0 amu" C o m m e n tA n n o ta tio n :"" Sample Index: 71 Sample Type: Unknown Concentration: 3.00 ng/ml. Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 3:38:22 PM File: "s101122a.wifT Modified: No Proc. Algorithm: intelliQuancps- IQA Min. Peak Height: sec Min. Peak width: points Smoothing width: : sec RT window: min Expected RT: Use Relative RT: Area: Height: start Time: End Time : 1.67e+004 10.2 10.9 Sample Name: "s101122a072" Sample ID: "GLP10-01-02-05-050 Dup DAL SS TRIP1 0 0000 Duplicate " Peak Name: 'MPFHS(IS)" Mass(es): '403.0/84.0 amu" I Comment " * Annotation: sample Index: 72 Sample Type: Unknown Concentration: 3.00 I Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 4:02:36 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type: Retention Time: Area: 172226 counts Height : 1.37e+004 cps start Time: End Time: ISample Name: "s101122a073" Sample ID: "GLP10-01-02-05-050 LMS DAL SS TRIP1 0 0000 Lab Matrix Spike' Peak Name: 'MPFHSOSf Mass(es): '403.0/84.0 amu' samCpolmemIenndt e""x: Annotatio7n3: " sample Type: Unknown Concentration : 3.00 I Calculated Cone : N/A Acq. Date: 11/23/2010 Acq. Time: 4:26:49 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT window: sec Expected RT: Use Relative RT: min Area: Height : start Time: End Time: 1.36e+004 cps 10.2 min 11.0 min Printing Time: 5:52:42 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 247 of 321 Page 432 of 962 *Stan V1660305 I Sample Name: "s101122a074" Sample ID: "GLP10-01-02-05-051 I Peak Name: 'M P F H S (IS )" Mass(es): "403.0/84.0 amu" Comment: "" Annotation: ~ Sample Index: 74 Sample Type: Unknown Concentration : 3.00 ng/mL Calculated Cone: N/A Acq. Dace: 11/23/2010 Acq. Time: 4:51:04 PM DAL SS SS05 0 0000 " File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - IQ/ Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: NO Int. Type: valley Retention Time : 10.4 min Area: 165250 counts Height : 1.2Se-f004 cps Start Time: 10.2 min End Time : 11.0 min Results Name: sl01122a.rdb I Sample Name: us101122a07S" Sample ID: "GLP10-01-02-05-051 Dup DAL S S SS05 0 0000 Duplicate" Peak Name: "M P F H S (IS r Mass(es): "403.0/84.0 amu" Com m ent " Annotation: "" Sample Index: 75 Concentration : calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 5:15:19 PM File: "s101122a.wifT Sample Type: Modified: Yes Proc. Algorithm: intelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT Window: 30.0 sec Expected RT: use Relative RT: Unknown Area: Height: Start Time: End Time: .19e004 10.2 11.0 Time, min I Sample Name: Hs101122a076" Sample ID: "GLP10-01-02-0&-051 LMS DAL S S SS05 0 0000 Lab Matrix Spike" Peak Name: "M PFHS(IS)" Mass(es): "403.0/84.0 amu" C o m m en t"" Annotation: File: "$101122a.wifT sample index: sample Type: Concentration: Calculated cone: Acq. Date: Acq. Time: Modified: Proc. Algorithm: Min. Peak Height Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Int. Type: Retention T im e : Area: Height: start Time: End Time: I Sample Name: "s101122a077" Sample ID: "10 006-25 soNent blank" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C om m ent Annotation: Sample Index: 77 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 5:03:48 PM File: "s101122a.wiff` Printing Time: 5:52:44 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 248 of 321 Page 433 of 962 Stan V1660305 I Sample Name: "s101122a078" Sample ID: "EC -101116-07 10 ng Extracted Curve Point ` Peak Name: ' MPFHS(IS)" Mass(es): "403.0/34.0 amu" Comment: " Annotation: "" Sample Index: 76 File: "s101122a.wifr Results Name: sl01122a.rdb I Sample Name: "s101122a079" Sample ID :'1 0 006-25 solvent blank" Peak Name: "MPFHS(lSr Mass(es): "403.0/84.0 amu" C o m m e n t"" Annotation: "* Sample Index: Sample Type: Concentration: Calculated Cone Acq. Date: Acq. Time: Double Blank 1.00 ng/mL N/A 11/23/2010 6:52:23 PM Modified: Ho File: "s101122a.wiff I Sample Name: "s101122a080" Sample ID: "GLP10-01-02-05-052 DAL S S SS 05 0 0005 ' Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment: Annotation:"" Sample Index: 60 Sample Type: unknown Concentration: 3.00 ng Calculated cone: H/A Acq. Date: 11/23/2010 Acq. Time: 7:16:41 PM File: "s101122a.wifT Modified: Yes Min. PeParokc.HeiAglhgto:rithm: inteclplsiOuan - Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type: valley Retention Time 10.4 min Area : 167886 counts Height : l.l9e+004 cps Start Time : 10.1 min End Time : 10.9 min Printing Time: 5:52:45 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 (Sample Name: "s101122a081" Sample ID: "GLP10-01-02-05-052 Dup DAL SS SS05 0 0005 Duplicate" Peak Name: "MPFHS(ISr Mass(es): "403.0/84.0 amu" C o m m e n t"" Annotation: "* Sample Index: 81 Sample Type: Unknown Concentration: 3.oo ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 7:40:58 PM Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 10.6 min use Relative RT: No File: "s1 01122a.w ir 103A Int. Type: Valley Retention Time: 10.4 min Area: 172695 counts Height: i.35e+004 cps start Time: 10.2 End Time: 11.1 min Page 249 of 321 Page 434 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 435 of 962 Stan V1660305 Sample Name: Ms101122a086" Sample ID: "GL.P10-01-02-05-055 DAL SS S S 06 0 0 0 05 " Peak Name: MMPFHS(IS)" Mass(es): "403.0/84.0 amu" C om m ent:A nnotation: " Sample Index: 86 Sample Type: concentracion: Calculated Cone: Acq. Date: Acq. Time: File: Ms101122a.wiff' Modified: Proc. Algorithm: Min. Peak Height: Min. Peak width: Smoothing width: RT Window; Expected RT: Use Relative RT: Int. Type: Retention Time: Area: 17 Height: l start Time: End Time: Results Name: sl01122a.rdb (Sample Name: "s101122a067" Sample ID: "GLP10-01-02-05-055 Dup DAL S S SS06 0 0005 Duplicate" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C o m m e n t"" Annotation: Sample Index: 87 Sample Type: Unknown Concentration: N/A Calculated cone: 11/23/2010 Acq. Date: 10:06:25 PM Acq. Time: Modified: Yes Proc. Algorithm IntelliQuan - IQA Min. Peak Height: cps Min. Peak width: 0. 0 0 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: min Use Relative RT: NO File: "s101122a.wiff' Area : Height: Start Time: End Time : 4 min counts .59e*004 10.2 11.0 I Sample Name: "s101122a08a" Sample ID: "GLP10-01-02-05-055 LMS D A LS S SS06 0 0005 Lab Matrix Spike" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu' Comment: " Annotation:"" Sample Index: 38 File: *s 1 0 1 1 2 2 a .w ir ( Sample Name: "s101122a089" Sample ID: "GLP10-01-02-05-056 DAL SS S S 06 DB 0005" Peak Name: "MPFHS(ISr Mass(es): "403.0/84.0 amu" C o m m e n t"" Annotation: Sample Index: 89 File: "s101122a.wifT inting Time: 5:52:48 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 251 of 321 Page 436 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 437 of 962 *Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 438 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 439 of 962 Stan V1660305 Sample Name: ''s101122a107' Sample ID: "GLP10-01-02-05-059 Dup DAL SS SS 08 0 0000 Duplicate" Peak Name: "M PFH S(IS)' Mass(es): "403.0/84.0 amu" C om m ent:A nnotation: Sample index: 102 Sample Type: Unknown Concentration: 3.00 ng/mL calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:10:13 AM File: "s101122a.wlfT Modified: Yes MPirno.c. PAelagkorHietihgmh:t: int0e.l0l0iQuancps- IQA Min. Peak width: 0.00 sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Area: Height : Start Time: End Time : Valley 10.4 min 165B12 counts 1.3ie+004 cps 10.2 min 10.9 min T Sample Name: Hs101122a104H Sample ID: "GLP10-01-02-05-060 DAL SS SS08 DB 0000 " Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment: "" Annotation: "" Sample Index: 104 Sample Type: Unknown Concentration: 3.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:58:45 AM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Area : Height : start Time : End Time : valley 10.4 173713 counts l.S2e+004 cps 10.2 min 11.1 min Printing Time: 5:52:54 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a103" Sample ID: ''GLP1Q-01-02-05-059 IM S DAL ! 3 SS08 0 0000 Lab Matrix Spike" Peak Name: "M P F H S (ls r Mass(es): "403.0/84.0 amu" C o m m en t"" Annotation:"" Sample Index: 103 File: "s101122a.wiff I Sample Name: "s101122a105" Sample ID: "GLP10-01-02 Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" I Comment "" Annotation: "" Sample Index: 10s Sample Type: Unknown Concentration: 3.00 1 Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:23:01 AM Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 1.47e*004 10.2 10.9 "s 1 0 1 1 2 2 a .w ifr Page 255 of 321 Page 440 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 441 of 962 Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 442 of 962 Stan V1660305 I Sample Name: "s101122a114" Sample ID: "EC-101116-06 5 ng Extracted Curve Point" File: "s101122a.wjff Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" I Comment: Annotation: "* I Sample Name: "s101122a116" Sample ID: "GLP10-01-02-05-063 DAL SS SS09 0 0 0 05 " Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu' Comment: "" Annotation: "" Sample Index: 116 File: ,-s101122a.wiff Lnting Time: 5:52:58 PM Lnting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a115" Sample ID: "10 006-25 solvent blank" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" 1 C omment "" Annotation: Sample Index: 115 Sample Type; Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acg. Date: 11/24/2010 Acg. Time: 9:25:25 AM File: "s101122a.wifT Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height : 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 10.4 min 22 counts l .70e*00l cps 10.4 min 10.5 min gi I Sample Name: " s 1 0 1 1 2 2 a 1 ir Sample ID: "GLP10-01-02-05-063 Dup DAL S S SS 09 0 0005 Duplicate' Peak Name: "M P F H S (IS f Mass(es): "403.0/84.0 amu" C omment "" Annotation: " sample Index: 117 Sample Type : Unknown Concentration: 3.00 ng/mL Calculated Cone: N/A Acg. Date: 11/24/2010 Acg. Time: 10:13:56 AM File: "s101122a.w1fr Modified: Yes Proc. Algorithm: intelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type: valley Retention Time : 10.4 min Area: 170007 counts Height : 1.34e*004 cps Start Time: 10.2 min End Time: 11.0 min Page 258 of 321 Page 443 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 444 of 962 *Stan V1660305 I Sample Name: "s101122a122" Sample ID: "GLP10-01-02-05-065 DAL SS GP01 0 0005 " Peak Name: "MPFHS(IS)' Mass(es): "403.0/84.0 amu" I Comment: Annotation: Sample Index; 122 Sample Type: Unknown Concentration: 3.00 ng/mL calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 12:15:12 PM File: "s101122a.wtfr Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 3ec Expected RT: Use Relative RT: Int. Type: Retention Time: Area: 155124 counts Height: 1.27e+004 cps Start Time: 10.2 min End Time: Results Name: sl01122a.rdb Sample Name: "s101122a123" Sample ID: 'G LP10-01-02-05-065 Dup DAL S S GP01 0 0005 Duplicate " Peak Name: "MPFHS(!Sr Mass(es): "403.0/84.0 amu" C o m m entA nnotation: Sample Index: 123 Sample Type: Unknown Concentration: 3.00 ng Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 12:39:26 PM Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No File: "s101122a.wiff Int. Type: Valley Retention Time: 10.4 Area: 1584 24 COUntS Height: 1.34e+004 cps Start Time 10.2 min End Time: I Sample Name: "$101122a124" Sample ID: "GLP10-01-02-05-065 LMS D A L S S GP01 0 0005 Lab Matrix Spike" Peak Name: " M PFH S(IS)' Mass(es): "403.0/84.0 amu' Comment: - Annotation:"" Sample Index: 124 Sample T ype: Unknown Concentration: 3.oo Calculated Cone: N/A Acq. Date: 11/24/20 Acq. Time: 1:03: Modified: Proc. Algorithm: I. Min. Peak Height: Min. Peak width: Smoothing width: RT Window: Expected RT: use Relative RT: Yes File: "s101122a.wifT Area : Height : Start Time: End Time : 1.16e+004 I Sample Name: "s101122a125" Sample ID: "GLP10-01-02-05-066 DAL SS GP01 0 0020 " Peak Name: *M PFH S(IS)" Mass(es): "403.0/84.0 amu" C o m m en t"" Annotation: "* Sample Index: 125 Sample Type: Unknown Concentration: 3.00 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:28:03 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Width: Min. Peak Height: Smoothing Width: 3 0.00 posiencts RT window: 30.0 sec Expected RT: 10.6 min Use Relative RT: 0.00 cps Area: Height : start Time: End Time : 10.4 min 163817 counts 1 .3le+004 cps 10.2 min ll.l min Printing Time: 5:53:01 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 260 of 321 Page 445 of 962 Stan V1660305 I Sample Name: "s101122a126" Sample I0: "GLP10-01-02-05-066 Oup DAL S S GP01 0 0020 Duplicate" Peak Name: "MPFHS(IS)" Mass(es): ' 403.0/84.0 amu" Comment "" Annotation: "* Sample Index: 126 Sample Type: Concentration: calculated Cone: Acq. Date: Acq. Time: File: "s101122a.wiff' Modified: Proc. Algorithm: Min. Peak Height Min. Peak width: smoothing width: RT Window; Expected RT: use Relative RT: Int. Type: Retention Time: Area: : Height: Start Time: End Time: I Sample Name: "s101122a126" Sample ID: "GLP10-01-02-05-067 DAL Peak Name: "MPFHS(IS)" Mass(es): "403.0/64.0 amu" Comment: "* Annotation; " sample Index: 128 sample Type: Concentration: Calculated cone Acq. Date: Acq. Time: SGP01 0 0060' File: "s101122a.wifT Modified: Proc. Algorithm Min. Peak Heigh Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: Printing Time: 5:53:03 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb Sample Name: "s101122a127" Sample ID: "GLP10-01-02-05-066 LMS DAL SS GP01 0 0020 Lab Matrix Spike' Peak Name: ' MPFHS(IS)" Mass(es): "403.0/84.0 amu" C o m m e n t"" Annotation:"" Sample Index: 127 Sample Type: Unknown Concentration: 3.00 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 2:16:39 PM File: "s101122a.wiff Modified: Yes MPirno.c. PAelagkorHietihghmt:: IntelliQuancps- IQA Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: Use Relative RT: NO Int. Type: valley Retention Time: 10.4 min Area: 168457 counts Height : 1.32e*004 cps Start Time 10.2 min End Time: 10.9 min ( Sample Name: "s101122a129~ Sample ID: "GLP10-01-02-05-067 Dup DAL S S GP01 0 0060 Duplicate " Peak Name: "MPFHS(ISr Mass(es): ' 403.0/84.0 amu" Com m ent " Annotation: "" Sample Index: 129 File: "s101122a.wifT - Page 261 of 321 Page 446 of 962 *Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 447 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 448 of 962 Stan V1660305 [ Sample Name: "s101122a138" Sample ID: "GLP10-01-02-05-069 Dup DAL SS GP02 0 0005 Duplicate" File: "s101122a.wiff I Peak Name: "MPFHS(IS)* Mass(es): "403.0/84.0 amu" I Comment: "" Annotation: ~ T Sample Name: "s101122a140" Sample ID: "GLP10-01-02-05-070 DAL SS GP02 0 0020 ` Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Comment: "" Annotation: "" Sample Index: File: "s101122a.wjfT Printing Time: 5:53:07 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a139" Sample ID: "GLP10-01-02-05-069 LMS DAL SS GP02 0 0005 Lab Matrix Spike" Peak Name: "M P F H S (IS f Mass(es): "403.0/84.0 amu" C om m ent "" Annotation: "" sample Index: 139 sample Type: Unknown Concentration: 3.00 ng/mL calculated cone: N/A Acg. Date: 11/24/2010 Acg. Time: 7:08:06 PM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: No Area: Height : Start Time: End Time: 1.43e+004 cps 10.2 min 11.0 min I Sample Name: "s101122a141" Sample ID: "GLP10-01-02-05-070 Dup DAL Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C o m m e n t"" Annotation:"" Sample Index: 141 Sample Type: Unknown Concentration: 3.00 ng/mL Calculated Cone: N/A Acg. Date: 11/24/2010 Acg. Time: 7:56:39 PM S GP02 0 0020 Duplicate " File: "s101122a.wifT Modified: Yes Min. PeParokc.HeiAglhgto:rithm: InteclplsiQuan - IQA Min. Peak width: sec Smoothing width: points RT Window: sec Expected RT: Use Relative RT: No Int. Type: Valley Retention Time: 10.4 163972 counts Height : 1.37e+004 cps start Time: 10.1 min End Time : 10.9 min Page 264 of 321 Page 449 of 962 Stan V1660305 I Sample Name: "s101122a142" Sample ID: "GLP10-01-02-05-070 LMS DAL SS GP02 0 0020 Lab Matrix Spike" Peak Name: ' MPFHS(IS)* Mass(es): "403.0/84.0 amu" I C om m ent"" Annotation: Sample Index: 142 Sample Type: Unknown concentrat ion: .00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 8:20:56 PM File: "s101122a.wifr Modified: NO Proc. Algorithm: IntelliQuan IQA Min. Peak Height : 0.00 Cps Min. Peak Width: .00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type: valley Retention Time: 10.4 min Area: 158166 counts Height : l.ile+004 cps Start Time: 10.2 min End Time : 11.1 min Results Name: slOH22a.rdb I Sample Name: ,,s101122a143" Sample ID: "GLP10-01-02-05-071 DAL S S G P 02 DB 0 0 20" Peak Name: "MPFHS(IS)" Mass(es): "403.Q/B4.0 amu` C o m m e n t"* Annotation: ** Sample index: 143 Sample Ty p e : Unknown concentration: 3.00 ng/mL calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 8:45:11 PM File: *8101122a.wiff' Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0o..0o0o cspesc MSimno.othPienagk wwiiddtthh:: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: Area: Height : start Time: End Time : 1 ,32e+004 10.2 10.8 Sanmple Name: Hs101122a144* Sample ID: ' GLP10-01-02-0S-071 Dup DAL SS GP02 DB 0 020 Duplicate * Pea k Name: "MPFHS(IS)" Mass(es): *403.0/84.0 amu" I Conmment: *" Annotation: "" Sample Index: File: "s101122a.wifr (Sample Name: "s101122a145" Sample ID: "GLP10-01-02-05-071 LMS DAL S S G P02 DB 0020 Lab Matrix Spike' Peak Name: ' MPFHS(IS)" Mass(es): *403.0/84.0 amu* C o m m e n t A n n o t a t io n : "" Sample Index: 145 File: *s 10 11 22 a.w ir Printing Time: 5:53:09 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 265 of 321 Page 450 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 451 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Date: Friday, January 07 20 11 3M Study GLP10-01-02 Interim Report 05 Page 452 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 453 of 962 *Stan V1660305 I Sample Name: "s101122a158" Sample IO: "GLP10-01-02-05-075 DAL S S GP03 0 0 020 " Peak Name: "M PFHS(IS)' Mass(es): "403.0/84,0 amu- 1 Comment " Annotation: "" Sample Index: 158 Sample Type: Unknown concentration: 3.00 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 2:49:43 AM Fite: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - IQ/ Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO Int. Type: Valley Retention Time: 10.4 min Area: 133493 counts Height : 9.60e+003 cps Start Time: 10.2 min End Time: 10.8 min Results Name: sl01122a.rdb I Sample Name: Ms101122a159" Sample ID: "GLP10-01-02-05-075 Oup DAL S S GP03 0 0020 Duplicate* Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" Com m ent Annotation: "* Sample Index: 1S9 File: "s101122a.vviff' I Sample Name: "s101122a160" Sample ID: "GLP1G-01-02-05-075 LMS DAL S S G P03 0 0020 Lab Matrix Spike" I Peak Name: "M PFHS(IS)' Mass(es): "403.0/84.0 amu" I Comment: - Annotation: " Sample Index: 160 Sample Type: Unknown Concentrat ion: 3.00 ng/mL calculated cone: N/A Acq. Date: 11/25/2010 Acq. Time: 3:38:18 AM File: "s10t122a.w tfT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: o .o o cps Min. Peak width: o .o o sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min use Relative RT: NO Area: Height : Start Time: End Time : Valley 10.4 1 25992 COI 8.18e+003 10.1 10.9 ISample Name: Hs101122a161" Sample ID: "GLP10-01-02-05-076 DAL S S GP03 DB 0 0 2 0 " Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" SamCpolmemiendt e""x: Annotat1io6n1: Sample Type: Unknown Concentration: 3.00 : Calculated cone: N/A Acq. Date: 11/25/2010 Acq. Time: 4:02:36 AM File: Ns101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: cps Min. Peak Width: sec Smoothing Width: points RT Window: sec Expected RT: min Use Relative RT: No Int. Type : valley Retention Time: 10.4 ' min Area: 125958 counts Height : 8.1Se+003 cps start Time: 10.2 min End Time: 10.9 min Printing Time: 5:53:15 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 269 of 321 Page 454 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 455 of 962 *Stan V1660305 Sample Name: "s101122a166" Sample ID: "GLP10-01-02-05-077 LMS DAL S S G P03 0 0 0 50 Lab Matrix Spike" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" ' File: "s101122a.wifT Comment: Annotation: "" Sample Index: 166 sample Type: Unknown 1037 concentration: 3.oo i Calculated Cone: N/A Acq. Date: 11/2S/2010 Acq. Time: 6:04:01 AM Modified: Yes Proc. Algorithm: IntelliOuancps Min. Peak Height: sec Min. Peak width: points Smoothing Width: sec RT Window: min Expected RT: No Use Relative RT: Int. Type: Valley Retention Time 10.4 Area: 1S7359 counts Height : 1.14e+004 cps Start Time: 10.2 min End Time : 11.2 min Results Name: slOH22a.rdb ISample Name: "s101122a167" Sample ID: "10 006-25 solvent blank" Peak Name: ' MPFHS(IS)" Mass(es): "403.0/84.0 amu" 1 Comment "" Annotation: "" Sample Index: 167 Sample Type: Double Blank Concentration: 1.00 ng/mL calculated cone: N/A Acq. Date: 11/25/2010 Acq. Time: 6:28:17 AM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQ/ Min. Peak Height : 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: NO int. Type: valley Retention Time: 10.4 min Area: 76 counts Height: 1.73e +001 cps start Time: 10.4 min End Time: 10. S min TSample Name: "s101122a166" Sample ID: "EC-101116-06 5 ng Extracted Curve Point" Peak Name: "MPFHS(IS)" Mass(es): "403.0/84.0 amu" C o m m en t"" Annotation:"" sample Index: Sample Type: Concentration: Calculated Cone: Acq. Date: Acq. Time: File: "s101122a.w iff Modified: Proc. Algorithm: Min. Peak Height Min. Peak Width: smoothing width: RT Window: Expected RT: U3e Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: I Sample Name: "s101122a169" Sample ID: "10 006-25 solvent blank" Peak Name: "M P F H S (IS f Mass(es): "403.0/84.0 amu" C o m m en t"" Annotation: "* sample Index: 169 Sample Type: Double Blank Concentration: 1.00 ng/mL CAcaql.culDaattee:d Cone: 11/N2/SA/2010 Acq. Time: 7:16 :SS AM File: "s1 01122a.w ir Printing Time: 5:53:18 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 271 of 321 Page 456 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 457 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 458 of 962 Stan V1660305 I Sample Name: "s101122a176" Sample ID: "GLP10-01-02-05-080 LMS DAL S S GP04 0 0020 Lab Matrix Spike' Peak Name: ' M P F H S (IS )' Mass(es): ' 403.0/64.0 amu* File: "s101122a.w ifr C omment "" Annotation: " Sample Index: 17b Sample Type: Unknown 10.39 concentration: 3.00 ng/mL Calculated Cone: N/A A c g . Date: 11/25/2010 Acq. Time: 10:55:38 AM Modified: Yes Proc. Algorithm: IntelliQuan * IQA Min. Peak Height: 0.00 cps Min. Peak Width: Smoothing Width: RT window: o.ot 3 30.0 points sec Expected RT: 10. ( Use Relative RT: No Int. Type: Valley Retention Time: 10.4 min Area: 169264 counts Height: i.33e+O04 cps Start Time: 10.2 min Results Name: sl01122a.rdb I Sample Name: ' s101122a179" Sample ID: "MB-101116-07 Method Blank 5g w / IS for Dilutions" Peak Name: ' M P F H S (IS f Mass(es): ' 403.0/84.0 amu' C om m ent "" Annotat1io7n9: "" Sample Index: Unknown Sample Type: 3.00 ng/mL concentration: N/A calculated cone: 11/25/2010 Acq. Date: 11:19:55 AM Acq. Time: Modified: NO Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak width: o .oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.6 min Use Relative RT: File: ' s101122a.wrfT Area: Height : Start Time: End Time: l ,48e+004 10.2 10.8 ISample Name: "s101122a16Cr Sample ID: ` M B-101116-06 Method Blank 5g w IS for Dilutions' Peak Name: ' M PFH S(IS)' Mass(es): "40 3.0/8 4.0 amu" T Comment: ~ Annotation: "* Sample Index: 180 File: "s101122a.wiff" Sample Name: ' s101122a181' Sample ID: "10 006*25 solvent blank" Peak N am e :' MPFHS(IS)" Mass(es): "403.0/84.0 amu" I C omment Annotation: " Sample Index: 181 Sample Type : Double Blank concentration : 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/25/2010 Acq. Time: 12:08:37 PM File: "s101122a.wifT Modified: No Proc. Algorithm: IntelliQuan - IQA Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 10.6 min Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time : End Time: valley 10.5 min 10 counts .ooe+ooo cps lo.s min 10.6 min Printing Time: 5:53:22 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 274 of 321 Page 459 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 460 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 461 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 462 of 962 Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 463 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:53:30 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 279 of 321 Page 464 of 962 Stan V1660305 I Sample Name: "s101122a019" Sample ID: "EC-101116-10 100 ng Extracted Curve Point" Peak Name: " M8PFOS(IS)' Mass(es): "507.0/80 0 amu" Com m ent"" Annotation: Sample Index: 19 Sample Type: Standard Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 6:38:37 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: No Min. PMeina.k wPiedatkh:Height 0.00 cps sec Smoothing width: points RT Window: Expected RT: Use Relative RT: NO Int. Type: Valley Retention Time: 13.2 Area: 47037 Height: 26e+003 Start Time 13.0 End Time: 13 .4 I Sample Name: "s101122a021" Sample ID: "EC-101116-12 500 ng Extracted Curve Poinf Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment: Annotation:"" Sample Index: 21 File: Hs101122a.wifT Printing Time: 5:53:32 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ( Sample Name: "s101122a020" Sample ID: "EC-101116-11 200 ng Extracted Curve Point" Peak Name: "M8PFOS(ISf Mass(es): "507.0/80.0 amu" Comment "" Annotation: Sample Index: 20 Sample Type: standard Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 7:02:49 PM File: "s101122a.witr Modified: Yes Proc. Algorithm: IntelliQuan - MQi: Noise Percentage: 85 Base. Sub. Window: 1.00 min Peak-Split. Factor: 4 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min use Relative RT: No Int. Type: Base To Base Retention Time: 13.2 min Area: 43862 counts Height: 4.2ie+003 cps Start Time: 13.0 min End Time: 13.5 min ( Sample Name: "s101122a022" Sample ID: "10 006-25 solvent blank" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Com m ent"" Annotation:"" Sample Index: 22 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 7:51:11 PM File: Hs101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk Hwieditghh:t No 0.00 cps sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Retention Time: Area: Height: start Time: End Time: Base To Base 13.2 rail 48 counts 1.78e+001 cps 13.1 min 13.3 min Page 280 of 321 Page 465 of 962 *Stan V1660305 I Sample Name: "s101122a023" Sample ID: "10 006-25olvent blank" Peak Name: "M8PFOS(IS)* Mass(es): "507.0/80.0 amu" Comment:"" Annotation: "" Sample Index: 23 Sample Type: Double Blank Concentration: l.oo ng/mL calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 8:15:23 PM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec smoothing width: 3 points RT window: 30.0 sec Expected RT: 13.2 min , Use Relative RT: No { Area: Height : Start Time: End Time : 6.89e+000 cps Sammpple Name: "s101122a025" Sample ID: *10 006-25 solvent blank" I Peak Name: "M8PFOS(1S)" Mass(es): "507.0/80.0 amu" B Commr ent: Annotation: "" sample Index: 25 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:03:42 PM File: "s101122a.wifr Modified: Printing Time: 5:53:34 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a024" Sample ID: "10 006-25 solvent blank" Peak Name: "M8PFOS(lsy Mass(es): "507.0/80.0 amu" I Comment Annotation: "" Sample Index: 24 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 8:39:32 PM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. window: 1.00 rain Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time: Base To Base 13.3 min 12 counts 8.89e*000 cps 13.2 rain I Sample Name: "s101122a026" Sample ID: "MB-101116-01 Method Blank 1 w/o IS" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" I Comment Annotation: *" Sample Index: 26 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9:27:54 PM File: ns101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 s< Expected RT: 13.2 m: Use Relative RT: No Area: Height : Start Time: End Time : 1. 7Se+001 13.2 13. S Page 281 of 321 Page 466 of 962 Stan V1660305 I Sample Name: Hs101122a027" Sample ID: "MB-101116-02 Method Blank2w/o IS" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment: "* Annotation: "" . SSaammppllee TIynpdee:x: Double Blank Concentrat ion: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 9 :S2:08 PM File: "s101122a.wiff' Modified: Yea Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 Expected RT: 13.: Use Relative RT: No Int. Type: Retention Time: Height: Start Time: End Time: Baae To Base 13.2 min 73 counts I Sample Name: "s101122a029" Sample ID: "MB-101116-04 Method Blank 4 w/ IS" Peak Name: "M8PFOS(IS)a Mass(es): "507.0/80.0 amu" Comment:"" Annotation:"" Sample Index: 29 File: "s101122a.wifT Printing Time: 5:53:35 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ( Sample Name: "s101122a028" Sample ID: "MB-101116-03 Method Blank 3w/o IS" Peak Name: "M8PFOS(IS)' Mass(es): "507.0/80.0 amu" C o m m e n tA n n o ta tio n :"" Sample Index: 28 Sample Type: Double Blank Concentration: 1.00 ng/mL calculated Cone: N/A Acq. Date: 11/22/2010 Acq. Time: 10:16:21 PM File:"s101122a.wiff' Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk WHieditghh:t No cps sec Smoothing width: points RT Window: Expected RT: use Relative RT: Int. Type: Retention Time: Area: Height: 3.85e*001 Start Time: 13.2 End Time: 13.4 Sample Name: "s101122a030" Sample ID: "MB-101116-05 Method Blank 5 w/ IS" I Peak Name: "M8PFOS(lsy Mass(es): "507.0/80.0 amu" Comment " Annotation:"" Sample Index: 30 Sample Type: Unknown Concentration: 2.98ng/mL Calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 11:04:46 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQ: Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: o cps Min. Peak width: 0 sec Smoothing width: 3 points RT Window: 30.0 Expected RT: 13.2 Use Relative RT: No Int. Type: Retention Time: Area: Height: start Time: End Time: Valley Cp9 min min Page 282 of 321 Page 467 of 962 Stan V1660305 I Sample Name: "s101122a031" Sample ID: "MB-101116-06 Method Blank 6 w/ IS" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment:"" Annotation: *" Sample Index: 31 Sample Type: Unknown Concencracion: 2.98 ng/mL calculated cone: N/A Acq. Date: 11/22/2010 Acq. Time: 11:20:57 PM File: "s101122a.wiff' Modified: Proc. Algorithm: Noise Percentage: 5( Base. Sub. Window: i. Peak-Split. Factor: 2 Report Largest Peak: l Min. Peak Height: ( Min. Peak Width: ( Smoothing Width: : RT Window: 30.0 Expected RT: 13.: Use Relative RT: No cps sec points Int. Type: valley Retention T ime: Area: 5281S counts Height: 5.69e* 003 cps Start Time: 12.9 min End Time: 13 .4 min Sample Name: "s101122a033" Sample ID: "LCS-101116-02 3 ng LCS in TCR-842' I Peak Name: "MSPFOS(IS)" Masses): "507.0/80.0 amu" Comment "" Annotation: " Sample Index: 33 File: "s101122a.wifT Results Name: sl01122a.rdb ISample Name: "s101122a032' Sample ID: MLCS-101116-Ot 3 ng LCS in TCR-842" Peak Name: "M8PFOS(ISF Mass(es): "507.0/80.0 amu" SamCpolmemIenndt e""x: Annotatio3n2: "* Sample Type : Unknown Concentration : 2.98 n< Calculated Cone: N/A Acq. Date: 11/ 22/2010 Acq. Time: 11:53:10 PM File: "i101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.2 min 11553 counts :.77e*003 cps 596 ( Sample Name: "s101122a034M Sample ID: "LCS-101116-03 3 ng LCS in TCR-842" Peak Name: "M8PFOS(ISr Mass(es): "507.0/80.0 amu" Comment "" Annotation: "" Sample Index: 34 File: Ms101122a.wifT Printing Time: 5:53:37 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 283 of 321 Page 468 of 962 Stan V1660305 I Sample Name: "s101122a035" Sample ID: "LCS-101116-04 30 ng LCS in TCR-842" Peak Name: "M 8PFO S(IS)" Mass(es): "507.0/80.0 amu" Comment: * Annotation: "" Sample Index: 3S File: "s101122a.wtfr ( Sample Name: "s101122a037" Sample ID: "LCS-101116-06 30 ng LCS in TCR-842" Peak Name: "M8PFO S(IS)" Mass(es): "507.0/80.0 amu" Comment: "" Annotation: "* sample Index: 37 Sample Type: Unknown Concentration: 2.98 ng/mL Calculated cone: N/A A c g . Date: 11/23/2010 Acq. Time: 1:54:19 AM File: "s101122a.wiff Modified: Yes Proc. Algorithm: intelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. MPiena.k wPiedatkh:Height: 0 . 0 0 CpS sec Smoothing width: points RT Window: Expected RT: use Relative RT: NO Int. Type: valley Retention Time: 13.2 min Area: 52037 counts Height: 4.97e+003 cps start Time: 13.0 min End Time: 13.6 min Printing Time: 5:53:39 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a036" Sample ID: "LCS-101116-05 30 ng LCS in TCR-842" Peak Name: "M 8PFOS(IS)" Mass(es): "507.0/80.0 amu" C om m ent "* Annotation: "" Sample Index: 36 Sample Type: Unknown Concentration: 2.98 n Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 1:30:03 AM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: 1.00 Peak-split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: No 0.00 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time: valley 13.2 min S1291 counts S.66e+003 cps 12.9 min (Sample Name: "s101122a038" Sample ID: "GLP10-01-02-05-041 Peak Name: "M 8PFO S(IS)" Mass(es): "507.0/60.0 amu" C omment "" Annotation: Sample Index: 38 DAL SS SS01 0 0000H File: "s101122a.wiff Page 284 of 321 Page 469 of 962 *Stan V1660305 I Sample Name: ' 51011223039" Sample ID: "GLP10-01-02-05-041 Dup DAL SS SS01 0 0000 Duplicate' Peak Name: "M8PFOS(IS)" Mass(es): "507,0/80,0 amu" Com m ent ~ Annotation: Sample Index: 39 Sample Type: Unknown Concentration: 2.98ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 2:42:45 AM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: MSimno.otPhienagk Wwiiddtthh:: No ( ( cps sec points RT Window: 30.0 Expected RT: Use Relative RT: Int. Type: Retention Time: 2 min Area: : counts Height: 3.29e+003 CpS Start Time; End Time: Results Name: sl01122a.rdb (Sample Name: "s101122a040" Sample ID: "GLP10-01-02-05-041 LMS DAL S S SS01 0 0000 Lab Matrix Spike' Peak Name: "M 8P F O S (iS r Mass(es): "507.0/80.0 amu" C omment " Annotation:"" Sample Type Concentration: Calculated cone Acq. Date: Sample Index: 40 Unknown 2.98 ng/mL 11/N2/3A/2010 Acq. Time: 3:06:57 AM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time: Valley 13.2 min 28773 counts I Sample Name: "s101122a041" Sample ID: ` 10 006-25 solvent blank' Peak Name: "MSPFOS(IS)" Mass(es): "507,0/80,0 amu' Com m ent " Annotation: "" Sample Index: 41 Sample Type: Double Blank Concentration: 1.00 ng/mL calculated Cone 2 N/A ` Acq. Date: Acq. Time: 11/23/2010 3:31:11 AM 140 Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: Report Largest Peak; Min. Peak Height: cps Min. Peak width: sec Smoothing width: points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT NO o 130 90 80 Int. Type: Retention Time: Area: Height: Start Time: End Time: Base To Base 13.4 48 counts 1.79e+001 cps 13.3 min 13.5 min t 70 60 50 Printing Time: 5:53:40 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Sample Name: ' s101122a042* Sample ID: "EC -101116-05 2.5 ng Extracted Curve P o in t' Peak Name: "M8PFOS(ISJ" Mass(es): "507.0/80.0 amu" C omment "" Annotation: "" sample index: 42 ` File: "s101122a.wifr 1984 2162 Page 285 of 321 Page 470 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:53:42 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 286 of 321 Page 471 of 962 *Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 472 of 962 Stan V1660305 I Sample Name: "s101122a051" Sample ID: "GLP1(W>1-02-05-044 Dup DAL SS S S 02 0 0005 Duplicate " Peak Name: "M 8PFO S(IS)* Mass(es): "507.0/80.0 amu* Comment:"" Annotation: "" Sample Index: Si Sample Type: Unknown Concentration: 2.96 ng/mL calculated cone: n /a Acq. Date: 11/23/2010 Acq. Time: 7:33:38 AM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQi: Noise Percentage: Base. Sub. Window: so 1.00 min Peak-split. Factor: 3 Report Largest Peak: No Min. Peak Height: 0.00 cpa Min. Peak width: Smoothing width: RT window: Expected RT: Use Relative RT: o.oo sec 3 points 30.0 sec 13.2 min No Int. Type: Retention Time: Area: Height : start Time: End Time : Valley 13.2 min 46622 counts 4.27e+003 CpS 13.0 min 13.7 min T Sample Name: "s101122a053" Sample ID: "G LP10-01-02-05-045 DAL SS SS 03 0 0000 Peak Name: MM 8PFO S(lS)' Mass(es): "507.0/80.0 amu" Comment: Annotation: " sample Index: S3 sample Typ e : Unknown Concentration: 2.98 ng/mL Calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 6:22:05 AM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: i.oo min Peak-Split. Pactor: 3 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Int. Type: valley Retention Time: 13.2 min Area: 27360 counts Height: start T im e : End Time: File: "s101122a.wifr Printing Time: 5:53:45 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a052" Sample ID: "GLP10-01 -02-05-044 LMS DAL S S SS02 0 0005 Lab Matrix Spike" Peak Name: "M 8 P F O S (ls r Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: Sample Index: 52 Sample Type: Unknown Concentration: 2.98 n calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 7:S7:52 AM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: l.oo Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: No o.oo 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height: start T ime: End Time: Valley 13.2 mi 13.o 13.4 I Sample Name: "s101122a054" Sample ID: "GLP10-01-02-05-045 Dup DAL S S SS03 0 0000 Duplicate" Peak Name: "M 8PFO S(IS)" Mass(es): "507.0/80.0 amu' C o m m en t"" Annotation: Sample Index: 54 File: "s 1 01 12 2a .w ir Page 288 of 321 Page 473 of 962 *Stan V1660305 I Sample Name: "s101122a055" Sample ID: "GLP10-01-02-05-045 LMS DAL S S SS03 0 0000 Lab Matrix Spike" Peak Name: BM 8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment:"" Annotation: "" Sample Type Sample Index: 55 Concentration: Unknown Calculated Cone: 2.98 ng/mL Acq. Date: 11/N2/3A/2010 Acq. Time: 9:10:29 AM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time Area: Height: start Time: End Time: Valley 13.2 min 14S20 counts 1.33e+003 cps 13.0 13.6 1Sample Name: "s 1 01 12 2a 05 r Sample ID: "GLP10-01-02-05-046 Dup DAL SS SS 03 0 0005 Duplicate Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: " sample Index: S7 sample Type: Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 9:58:56 AM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - MQ: Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing width: No 1 1 : cps sec points RT Window: 30.0 Expected RT: 13.: use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time : valley 13.2 min 22798 counts l.aie+003 cps 13.0 min 13.7 min Printing Time: 5:53:47 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a056" Sample ID: "GLP10-01-02-05-046 DAL SS SS 03 0 0005" Peak Name: "M6PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment " Annotation: Sample Index: 56 Sample Type: Unknown Concentration: 2.98ng/mL calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 9:34:41 AM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQ' Noise Percentage: 50 Base. Sub. window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width; No 1 1 : cps sec points RT Window: 30.0 Expected RT: 13.: Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time : valley min counts 103 CpS 0 min 4 min I Sample Name: "s101122a058" Sample ID: "GLP10-01-02-05-046 LMS DAL SS SS03 0 0005 Lab Matrix Spike" Peak Name: "M 6PFO S(lsr Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: Sample Index: 58 File: *s101122a.w itr Page 289 of 321 Page 474 of 962 *Stan V166030S Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 475 of 962 *Stan V1660305 ISample Name: "s101122a063" Sample IO: "GLP10-01-02-05-047 Dup DAL S S SS03 DB 0005 Duplicate " Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" SamCpolmemeInntd: ex: Annotatio6n3: "" Sample Type : Unknown Concentration: 2.90 ng( Calculated cone:: N/A Acq. Date: 11/23/2010 Acq. Time: 12 :24 ;29 PM File: "s101122a.wifT Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.2 NO sec min Int. Type : Retention Time: Area : Height : start Time : End Time : Manual 13.2 min 21706 counts 1.64e+003 cps 13.0 min 13 .6 min I Sample Name: "s101122a065" Sample ID: "GLP10-01-02-05-048 DAL SS SS04 0 0000 " Peak Name: "M 8PFOS(IS)' Mass(es): "507.0/80.0 amu* I Comment: "" Annotation: "" Sample Index: 65 Sample Type: concentration: Unknown 2.98 t calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 1:12 :S8 PM File: "s101122a.w ift Modified: Yes Proc. Algorithm: IntelliQuan MOII Noise Percentage: SO Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: Min. Peak Width: cps o .00 sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start T i m e : End Tim e : 3 3. 60e*003 cps Printing Time: 5:53:50 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a064" Sample ID: "GLP10-01-02-05-047 LMS DAL SS SS03 DB 0005 Lab Matrix Spike" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" m Comment "" Annotation: "" Sample Index: 64 Sample Type: Unknown Concentration: 2.98 calculated Cone: N/A ng/mL 2100- Acq. Date: Acq. Time: 11/23/2010 12:48:43 PM 20001900- Modified: Yes Proc. Algorithm: IntelliQuan - HQII 1800- Noise Percentage : Base. sub. window: Peak-split. Factor: 50 1.00 2 min 17001600 Report Largest Peak: No Min. Peak Height : 0 . 0 0 Cps Min. Peak width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec 150014001300- Expected RT: Use Relative RT: 13.2 min No in 12001100- Int. Type: Retention T ime: Area: Height: start Time: valley 13.2 min 15022 counts l.i7e*003 cps 13.0 min 1000 o 900 BOO End Time: 13.4 min 700 File: "s101122a.wifT 600- 500- 400- 300 200 6.18 , L100 0 199 596 794 I Sample Name: "s101122a066" Sample ID: "GLP10-01-02-05-048 Dup DAL S S SS04 0 0000 Duplicate ' Peak Name: "M 6PFO S(lsr Mass(es): "507.0/80.0 amu" Comment "" Annotation: "" sample Index: 6 992 1191 Time, min File: "s101122a.wiff Page 291 of 321 Page 476 of 962 *Stan V1660305 Results Name: slOH22a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 477 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 478 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 479 of 962 Stan V1660305 I Sample Name: ' 81011223079'' Sample ID: *10 006-25 solvent blank* Peak Name: *M 8P FO S(IS)' Mass(es): "507.0/80.0 amu* Comment " Annotati7o9n:"" Sample Index: Double Blank sample Type: 1.00 ng/mL concentration: N/A Calculated Cone: 11/23/2010 Acg. Date: 6:52:23 PM Acq. Time: Modified: Yes Proc. Algorithm: intelliQuan Noise Percentage: 50 Base. Sub. window: l.oo Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No File: 's101122a.wifT Int. Type: Retention Time: Area: Height : start Time: End Time : valley 13.4 min 156 counts ,65e+O0l cps 13.3 13.5 min (Sample Name: 's 101122a061' Sample ID: ' GLP10-01-02-05-052 Dup DAL SS SS05 0 0 0 05 Duplicate' Peak Name: "MSPFOS(IS)' Mass(es): "507.0/80.0 amu' Comment:"" Annotation: "" Sample Index: 81 Sample Type: Unknown File: Hs101122a.wifT Printing Time: 5:53:57 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a080* Sample ID: "GLP10-01-02-05-052 DAL SS S S 05 0 0005 " Peak Name: "M8PFOS(!Sr Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: "* Sample Index: so Sample Type: concentration: Calculated Cone: Acq. Date: Acq. Time: 2.98 ng/mL N/A 11/23/2010 7:16:41 PM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: ( cps Min. Peak Width: sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: NO File: "s101 12 2a .w ir Int. Type: Retention Time: Height: start Time: End Time: valley 13.2 min 22053 counts 2.04e+003 cps 13.0 min 13.6 min f Sample Name: "s101122a082" Sample ID: "GLP10-01-02-05-052 LMS DAL S S S S05 0 0005 Lab Matrix Spike" Peak Name: "M 8P F O S (IS f Mass(es): "507.0/80.0 amu" I Comment "" Annotation: "" Sample Index 82 Sample Type: Unknown Concentration: 2.98 I Calculated Cone: N/A Acq. Date: 11/23/2010 Acq. Time: 8:05:12 PM File: "s101122a.wifr Modified: Y Proc. Algorithm: Inte Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: 30 Expected RT: 1 Use Relative RT: N cps sec points Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.2 min 15286 counts 1.17e+003 cps 13.0 min 13.6 min Page 295 of 321 Page 480 of 962 Stan V1660305 I Sample Name: ' s101122a083" Sample ID: "GLP10-01-02-05-054 DAL SS SS06 0 0 0 0 0 " Peak Name: "M8PFOS{IS)" Mass(es): ' 507.0/80.0 amu' Comment: "" Annotation: *" sample Index: 83 sample Type: Unknown Concentration: 2.98 i Calculated cone: N/A A c q . Date: 11/23/2010 Acq. Time: 8:29:28 PM File: *s101122a.w ifr Modified: Yes Proc. Algorithm: XntelliOuan Noise Percentage: so Base. Sub. Window: 1.00 Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak Width: 0.00 Smoothing Width: 3 RT Window: 30.0 S< Expected RT: 13.2 m: Use Relative RT: No cps sec points Int. Type: Retention Time: Area: Height: start Time: End Time: valley 13.2 46020 co 3.90e+003 cps min min I Sample Name: ' s101122a085' Sample ID: ' GLP10-01-02-05-054 LMS DAL SS SS06 0 0 000 Lab Matrix Spike' Peak Name: ' M 8PFO S(IS)' Mass(es): ' 507.0/80.0 amu' Comment: " Annotation: ~ Sample Index: 8S sample Type: Unknown File: "s101122a.wifT Printing Time: 5:53:59 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: ' s101122a084' Sample ID: "GLP10-01-02-05-054 Dup D A LS S SS06 0 0000 Duplicate Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" C o m m e n t"" Annotation: " Sample Index: 84 Sample Type: Unknown Concentration: 2.98 ng/mL calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 8:53:43 PM Modified: Yes Proc. Algorithm: IntelliQuan - M Q H Noise Percentage: 50 Base. Sub. window: l.oo min Peak-split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk Hwieditghh:t: No C cps sec Smoothing width: points RT window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: 4 .89e*003 12.8 13.8 Cp9 min min File: ' s101122a.wiff' I Sample Name: *s101122a086* Sample ID: ' G LP10-01-02-05-055 DAL SS S S 06 0 0 0 0 5 ' Peak Name: "M8PFOS(IS)" Mass(es): ' 507.0/80.0 amu" Comment " Annotation: "" Sample Type: Sample Index: 86 Concentration: Unknown Calculated cone 2.98 Acq. Sate: 11/2N3//A2010 ng/mL Acq. Time: 9:42:11 PM File: "s101 12 2a .w ir Modified: Y Proc. Algorithm: Inte Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: 30 Expected RT: l Use Relative RT: N cps sec points I Int. Type: Retention Time: Area: S H O O counts Height: 4. S6e+003 cps Start Time: End Time: Page 296 of 321 Page 481 of 962 Stan V1660305 I Sample Name: ' s101122a087" Sample ID: "GLP10-01-02-05-055 Dup DAL S S S S06 0 0005 Duplicate Peak Name: "M 8PFO S(IS)' Mass(es): ' 507.0/80.0 amu' Comment "" Annotation: " Sample Type: Concentracin: Calculated cone: Acq. Date: sam ple in d e x : Unknown 2.98 11/2N3//A2010 87 ng/mL Acq. Time: 10:06:25 PM Modified: Yes Proc. Algorithm: intelliQuan - MQ1I Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height cps Min. Peak Width: 0 . 0 0 sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: ! Height: 4.98e+003 start Time: End Time: cps File: "s101122a.w rr I Sample Name: "81011223089" Sample ID: "GLP10-01-02-05-056 DAL SS SS06 DB 0005 ' Peak Name: "M 8PFO S(IS)" Mass(es): "507.0/80.0 amu" Comment " Annotation: Sample Index: 89 File: "s101122a.wifr Results Name: sl01122a.rdb I Sample Name: "s101122a088' Sample ID: "G LP10-01-02-05-055 IM S DAL SS SS06 0 0005 Lab Matrix Spike' Peak Name: "M 8P F O S (IS r Mass(es): "507.0/BO.O amu' C omment " Annotation: " sample Index: 88 Sample Type: Unknown Concentration: 2.98 ng/mL calculated cone: N/A Acq. Date: 11/23/2010 Acq. Time: 10:30:39 PM File: ' s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk HWieditghh:t No o .oo cps sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: 35176 counts 3.06e+003 cps rSample Name: "s101122a090" Sample ID: "GLP10-01-02-05-056 Dup DAL S S SS06 DB 0005 Duplicate" Peak Name: "M 8PFO S(lSy Mass(es): "507.0/80.0 amu" Comment " Annotation: "" sample Index: 90 File: "s101122a.wifT Printing Time: 5:54:01 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Page 297 of 321 Page 482 of 962 Stan V1660305 (Sample Name: "s101122a091" Sample ID: "GLP10-01-02-05-056 IM S DAL S S SS06 DB 0005 Lab Matrix Spike" Peak Name: ' M 8PFOS(IS)' Mass(es): "507.0/80.0 amu" Comment: " Annotation: "" Sample Index: 91 Sample Typ e : Unknown Concentration: 2.98 ng/mL calculated Cone: n /a Acq. Date: ll/23/2010 Acq. Time: 11:43:23 PM File: "s101122a.w iT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.2 No sec min Int. Type: Manual Retention Time: 13.2 min Area: 36501 counts Height: 3.ue*003 cps start Time: 13.0 min End Time: 13.5 min I Sample Name: "s101122a093" Sample ID: "GLP10-01-02-05-057 Dup DAL S S SS 07 0 0000 Duplicate ' Peak Name: ' MSPFOS(IS)" Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: "" Sample Index: 93 File: "s101122a.wiff Printing Time: 5:54:02 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a092" Sample ID: "GLP10-01-02-05-057 DAL SS SS07 0 00 00 " Peak Name: " M B P FO SpSf Mass(es): "507.0/80.0 amu" Comment "* Annotation:"" Sample Index: 92 Sample Type: unknown concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 12:07:39 AM File: "s101 12 2a .w ir Modified: Yes Proc. Algorithm: intelliQuan - MQi: Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Paetor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: start Time: End Time: valley min counts .S5e+003 cps 12.9 min 13.6 min ( Sample Name: "s101122a094" Sample ID: "GLP10-01-02-05-057 LMS DAL S S SS07 0 0000 Lab Matrix Spike" Peak Name: "M 8 P F O S (IS r Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation:"" Sample Index: 94 Sample Type: Concentration: N/A Calculated Cone: 11/24/2010 Acq. Date: 12:56:11 AM Acq. Time: Modified: Y< Proc. Algorithm: Inte Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window; 30 cps sec points Expected RT: Use Relative RT: 1 N File: "s101122a.vnfr Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.2 min 31664 counts 2.73e*003 cps Page 298 of 321 Page 483 of 962 Stan V1660305 I Sample Name: "s101122a095" Sample ID: "10 006-25 solvent blank" Peak Name: "M 8PFOS(IS)" Mass(es): "507.0/80.0 amu* I Comment: Annotation: " Sample Index: 95 Sample T ype: Double Blank Concentration: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:20:23 AH File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT window: 30.0 sec Expected RT: 13.2 min ,, use Relative RT: No Int. Type: Valley Retention Time: 13.2 min Area: 339 counts Height: 5.11e+00l cps Start Time: 13.0 min End Time: 13.7 min ' - I Sample Name: "s101122a097" Sample ID: "10 006-25 solvent blank" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu' Comment: *" Annotation:"" Sample Index: 97 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 2:09:52 AM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: smoothing width: RT Window: 3 cps sec points Expected RT: Use Relative RT NO File: "s101122a.wifr Int. Type: Retention Time: Area: Height : start Time: End Time : Base To Base 13.2 min 14 5 counts .S6e+00l cps Printing Time: 5:54:04 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb ISample Name: "s101122a096" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" Peak Name: "M 8P F O S (IS r Mass(es): "507.0/80.0 amu" Comment Annotation: "" sSaammppllee TIynpdeex:: QC Concentration: 2.99 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:44:37 AM File: "s101122a.wjfT Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. window: l.o o : Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak Width: 0.00 Smoothing width: 3 RT Window: 30.0 sei Expected RT: 13.2 mi: use Relative RT: No Int. Type : valley Retention Time : 13.2 min Area: S3171 counts Height: 4.94e+003 cps Start Time: 12.9 min End Time : Sample Name: "s101122a098" Sample IO: "GLP10-01-02-05-058 DAL S S SS 07 0 0 005" Peak Name: "M8PFOS(ISJ" Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: "* Sample Index: 99 Sample Type: Unknown Concentration: 2.98 ng, Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 2:33:08 AM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan - Noise Percentage: SO Base. Sub. Window: 1.00 m. Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 i Min. Peak width: 0.00 : Smoothing width: 3 RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type : Retention Time: Area: Height : Start Time: End Time : Valley 13.1 min 24976 counts Page 299 of 321 Page 484 of 962 Stan V1660305 Results Name: s l O H 2 2 a .rdb 3M Study GLP10-01-02 Interim^Report 05 Page 485 of 962 Stan V1660305 Sample Name: "s101122a 103" Sample ID: "GLP10-01-02-05-059 LMS DAL S Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment: "* Annotation: Sample Index: 103 Sample Type: Unknown Concentration: 2.98 ng/ calculated cone: N/A Acg. Date: 11/24/2010 A c g . Time: 4:34:29 AM Modified: Yes Proc. Algorithm: IntelliOuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: cps Min. Peak Width: 0 . 0 0 sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 13.2 min S3341 counts S.04e+003 cps 12.9 min 13.3 min 8 0 0000 Lab Matrix Spike" File: Hs101122a.wTff' Results Name: sl01122a.rdb I Sample Name: "s101122a104" Sample ID: "GLP10-01-02-05-060 D A LS Peak Name: "M 8P F O S (IS r Mass(es): "507.0/80.0 amu" I C omment "" Annotation: "" Sample Index 104 Sample Type: Unknown Concentration: 2.98 1 Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4 :58:45 AM Modified: Yes Proc. Algorithm: IntelliOuan Noise Percentage: 50 Base. sub. window: i.oo Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec smoothing width: 3 points RT window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.2 min 53566 counts 8 DB 0000 " File: "s101122a.wifT I Sample Name: "s101122a105" Sample ID: "GLP10-01-02-05-060 Dup DAL SS SS 08 DB 0000 Duplicate " Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment:"" Annotation: "* Sample index: 105 Sample Type: unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:23:01 AM File: "s101122a,wiff Modified: Yes Proc. Algorithm: IntelliOuan - MQi: Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area : Height : Start Time: End Time : valley cps min min 199 398 Printing Time: 5:54:07 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 1389 1587 I Sample Name: "s101122a106" Sample ID: "GLP10-01-02-05-060 LMS DAL S S SS08 DB 0000 Lab Matrix Spike' Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" C o m m e n t"" Annotation: "" Sample Index: 106 Sample Type: Concentration: N/A Calculated Cone: 11/24/2010 Acq. Date: 5:47:16 AM Acq. Time: Modified: Yes Proc. Algorithm: IntelliOuan Noise Percentage: so Base. Sub. window: i.oo Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: o.oo sec smoothing width: 3 points RT window: 30.0 se Expected RT: 13.2 mi use Relative RT: No File: 's101122a.w ifr Int. Type: Retention Time: Area: Height: Start Time: End Time: valley min counts 4.3 9e+003 cps 12.8 min 13.7 min Page 301 of 321 Page 486 of 962 Stan V1660305 I Sample Name: "s101122a107" Sample ID: "GLP1lW)1-02-05-061 DALSS SS08 0 0005" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment:"" Annotation: Sample index: 107 Sample Type: Unknown Concentration: 2.98 n Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 6:11:32 AM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: No o.oo 0.00 3 cps sec points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 5807913.2counmtis 5.79e+003 cps I Sample Name: "s101122a109" Sample ID: "GLP10-01-02-05-061 LMS DAL SS SS0S 0 0005 Lab Matrix Spike" Peak Name: "M6PFOS(IS)* Mass(es): "507.0/80.0 amu' Comment: "" Annotation:"" Sample Index: 109 File: ' s101122a.wifT Results Name: sl01122a.rdb I Sample Name: "s101122a108" Sample ID: "GLP10-01-02-05-061 DupDALS ; SS08 0 0005 Duplicate" Peak Name: "M6PFOS(!Sr Mass(es): "507.0/80.0 amu" Comment "* Annotation:"" Sample Index: 108 Sample Type: Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 1 1 /24/2010 Acq. Time: 6:3S:44 AM File: "s101122a.wiff' Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: Base. Sub. Window: 50 1 . 0 0 min Peak-Split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk WHieditghh:t No cps sec Smoothing width: points RT Window: Expected RT: Use Relative RT: NO Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.2 min 54289 counts 5.68e +003 cps 1 2 . 8 min 13.4 min Sample Name: "s101122a110" Sample ID: "GLP10-01-02-05-062 DAL SS SS09 0 0000" Peak Name: "M 8 P F O S (IS r Mass(es): "507.0/80.0 amu" Comment"" Annotation:"" Sample Index: File: ' s101122a.wifT Printing Time: 5:54:09 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 302 of 321 Page 487 of 962 *Stan V1660305 Results Name: s!01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 488 of 962 Stan V1660305 Results Name: s!01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 489 of 962 *Stan V1660305 Sample Name: "s101122a119" Sample I0: "GLP10-01-02-05-064 DAL SS GP01 0 0000" Peak Name: "M8PFOS(IS)' Mass(es): "507.0/80.0 amu' Comment: "" Annotation:"" Sample Index: 119 Sample Type: Unknown Concentration: 2.98 nc Calculated cone: N/A Acq. Date: 1 1 /24 /2 0 10 Acq. Time: 11:02:29 AM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - Noise Percentage: Base. Sub. window: SO 1.00 t Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing width: No cps sec points RT window: 30.i Expected RT: Use Relative RT: 13 No Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 13 .2 46527 CO 3.85e+003 13.0 13.S Sample Name: "s101122a121" Sample ID: "GLP10-01-02-05-064 LMS DAL SS GP01 0 0000 Lab Matrix Spike" Peak Name: "MBPFOS(IS)" Mass(es): "507.0/80.0 amu" I Com m ent"" Annotation: "" Sample index: 121 File: "s101122a.wifr Results Name: sl01122a.rdb I Sample Name: "s101122a120* Sample ID: "GLP10-01-2-05-064 Dup DAL SS GP01 0 0000 Duplicate" Peak Name: "M8PFOS(ISr Mass(es): "507.0/80.0 amu" I Comment "" Annotation: "" Sample Index: 120 sample Type: Unknown concentration: 2.98 nc calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 11:26:43 AM FUe: "s101122a.v, Modified: Yes Proc. Algorithm: IntelliQuan - m q i i Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing width: 3 point: RT Window: 30.0 sec Expected RT: 13.2 rain Use Relative RT: No Int. Type: Base To Base Retention Time: 13.l mi: Area: 45554 counts Height: 3 . 66e +003 CpS Start Time: 12.7 min End Time: I Sample Name: "s101122a122" Sample ID: "GLP1Q-1-02-05-065 DAL SS GPOt 0 0005 " File; "s101122a.wifr Peak Name:' M8PFOS(IS)" Mass(es): "507.0/80.0 amu" I Comment Annotation: "" Printing Time: 5:54:14 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 305 of 321 Page 490 of 962 *Stan V1660305 Sample Name: ''s101122a123" Sample ID: "GLP10-01-02-05-065 Dup DAL SS GP01 0 0005 Duplicate ' Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment: " Annotation:"" Sample Index: 123 Sample Type: Unknown Concentration: 2.98 ng/mL Calculated cone: n /a Acq. Date: 1 1 /24/2010 Acq. Time: 12:39:26 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 Peak-split. Factor: 2 min Report Largest Peak: Min. Peak Height: MSimno.othPienagk wwiiddtthh:: No 1 1 cps sec points RT window: 30.0 Expected RT: Use Relative RT: Int. Type: Retention Time: Area: 42719 counts Height: 3.73e+003 cps Start Time: End Time: ( Sample Name: "s101122a125M Sample ID: "GLPtO-01-02-05-066 DAL SS GP01 0 0020" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment:"" Annotation: Sample Index: 125 Sample Type: Unknown Concentration: 2.98 ng/ Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:28:03 PM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak Min. Peak Height: cps Min. Peak width: sec Smoothing Width: points RT window: : Expected RT: Use Relative RT: No File: "s101122a.wifr Int. Type: valley Retention Time: 13.2 min Area: 42320 counts Height: 4.09e*003 cps Start Time: End T i m e : 13.6 Printing Time: 5:54:15 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: ns101122a124H Sample ID: "GLP10-01-02-05-06S IM S DAL SS GP01 0 0005 Lab Matrix Spike" Peak Name: "MSPFOS(IS)" Mass(es): *507.0/80.0 amu" I Comment Annotation: "* Sample Index: 124 sample Type: Unknown Concentration: 2.98 n Calculated cone: n /a Acq. Date: 11/24/2010 Acq. Time: 1:03:43 PM File: "s101122a.wifr Modified: Yea Proc. Algorithm: IntelliQuan Noise Percentage: SO Ba9e. Sub. Window: 1.00 Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0. 00 sec Smoothing Width: 3 points RT Window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time: Valley 2.85e*003 I Sample Name: "s101122a126" Sample ID: 'GLP1D-01-02-05-066 Dup DAL SS GP01 0 0020 Duplicate" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" Com m ent"" Annotation: sample Index: 126 Sample Type: Unknown concentration: 2.98 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 1:52:20 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0 . 00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: start Time: End Time: Valley 13.2 min 47056 counts 4.47e*003 cps 13.0 min 13.8 min Page 306 of 321 Page 491 of 962 Stan V1660305 Results Name: s!01122a.rdb Printing Time: 5:54:17 PM P r i n t i n g Date: Friday, J a n u a r y 07, 2 0 1 1 3M Study G LP10-01-02 Interim R eport 05 Page 307 of 321 Page 492 of 962 Stan V1660305 I Sample Name: "s101122a131" Sample ID: "10 006-25 solvent blank" Peak Name: "M8PFOS(IS)" Mass(es): ' 507.0/80.0 amu' I Comment: "" Annotation: "" Sample Index: 131 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated cone: N/A Acq. Date: 11/24/2010 Acq. Time: 3:53:48 PM File: "s101122a.wiff' Modi fied: Yes Proc. Algorithm IntelliQuan Noise Percentage: Base. sub. window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: rt window: : Expected RT: Use Relative RT: Int. Type: Retention Time: Area : Height : start Time : End Time : Base To Base 13.1 min 48 counts l.78e+001 cps 13.1 min I Sample Name: "s101122a133" Sample ID: "10 006-25 solvent blank" Peak Name:' MBPFOS(IS)' Mass(es): "507.0/80.0 amu" I Comment: ~ Annotation: " Sample Index: 133 Sample Type: Double Blank concentration: 1.00 ng/mL calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 4:42:25 PM File: "s101122a.wtr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: o.oo sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min , Use Relative RT: No l Int. Type: Base To Base 1 Retention Time: 13.2 min | Area: Height: 61 counts 2.67e+ooi cps - start Time: 13.2 min End Time: 13.5 min Printing Time: 5:54:19 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a132" Sample ID: ' EC-101116-07 10 ng Extracted Curve Point' Peak Name: "M 8 P F O S (ls r Masses): "507.0/80.0 amu" Comment "" Annotat1io3n2: *" Sample Index: QC Sample Type: 2.98 ! Concentration: N/A Calculated Cone: 11/24/2010 Acq. Date: 4:18:04 PM Acq. Time: Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height cps Min. Peak Width: sec Smoothing Width: points RT window: Expected RT: Use Relative RT: No File: "s101122a.wiff int. Type: valley Retention Time: 13.2 48993 counts Height: 4 .48e+003 cps start Time End Time: 13.8 I Sample Name: "s101122a134" Sample ID: ' GLP1D-01-02-05-068 DAL S >GP02 0 0000 ' Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" I Comment Annotation: "" Sample Index: 134 Sample Type: Unknown Concentration: 2.98 r Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 5:06:41 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT window: 3o.o se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time: Valley cps min min Page 308 of 321 Page 493 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 494 of 962 *Stan V1660305 I Sample Name: "s101122a139" Sample ID: "GLP10-01-02-05-069 LMS DALSS GP02 0 0005 Lab Matrix Spike" Peak Name: ' M8PFOS0S)" Mass(es): "507.0/80.0 amu" Comment: Annotation:"" Sample Index: 139 Sample Type: Unknown Concentration: 2.98 ng/mL calculated cone: n /a Acq. Date: 11/24/2010 Acq. Time: 7:08:06 PM File: "s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: 0. 00 Min. MPiena.k wPiedatkh:Height: 0 . 00 cps sec Smoothing Width: 3 points RT window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time Area: Height: Start Time: End Time: Valley 13.2 min 48781 counts 4 .30e+003 cps 13.0 min 13.7 min [ Sample Name: "s101122a141" Sample ID: "GLP10-01-02-05-070 Dup DAL SS GP02 0 0020 Duplicate " Peak Name: "M6PFOS(IS)" Mass(es): '507.0/80.0 amu" Comment "" Annotation: ~ Sample Index: 141 File: "s101122a.wifr Printing Time: 5:54:22 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a140" Sample ID: "GLP10-01-02-05-070 DAL SS GP02 0 0020 " Peak Name: "M8PFOS(ISr Mass(es): "507.0/80.0 amu" I Comment "* Annotation: "" Sample Inde> Sample Type: Concentration: 2.98 ng/mL calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 7:32:21 PM File: "s101122a.wiff Modified: Yes Proc. Algorithm: IntelliQuan MQII Noise Percentage: Base. sub. window: Peak-split. Factor: 50 1.00 2 min Report Largest Peak: No Min. Peak Height: Min. Peak width: 0.00 cps 0. 00 sec Smoothing Width: 3 point: RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: valley 13.2 min 45441 counts 4. oie+003 cps 13.0 13.5 I Sample Name: ',s101122a142" Sample ID: "GLP10-01-02-05-070 LMS DAL SS GP02 0 0020 U b Matrix Spike" Peak Name: "M6PFOS(ISr Mass(es): "507.0/80.0 amu" Comment " Annotation: Sample Index: 142 Sample Type : Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 8:20:S6 PM File: "s101122a.wtfT Modified: Yes Proc. Algorithm: IntelliQuan - MQi: Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 3490713.2coumnitns 2 .92e +003 cps 13 .S Page 310 of 321 Page 495 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 496 of 962 Stan V1660305 ! Sample Name: "s101122a147" Sample ID: "GLP10-01-02-05-072 Dup DAL S i G P 02 0 0120 Duplicate " Peak Name: "M 8PFO S(IS)N Mass(es): "507.0/80.0 amu" I Comment: Annotation: " Sample Index: 147 Sample Type: Unknown Concentration: 2.98 nt Calculated Cone: N/A Acq. Date: 11/24/2010 Acq. Time: 10:22:25 PM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: l.oo r Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak Width: 0.00 Smoothing Width: 3 RT window: 30.0 sei Expected RT: 13.2 mil Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time: valley 13.2 min 502S4 counts 5.00e+003 CpS 12.9 min I Sample Name: "s101122a149" Sample ID: "10 006-25 solvent blank" Peak Name: "MBPFOS(IS)'' Mass(es): "507.0/80.0 amu" Comment: Annotation: "" File: "s101122a.wifT Sample Index: 149 Concentration: Calculated Cone: 1.00 N/A Sample Type: ng/mL Double Blank Acq. Date: 11/24/2010 Acq. Time: 11:10:58 PM Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: Min. Peak Height: Min. Peak Width: No 0.00 0.00 cps sec Smoothing Width: 3 points RT Window: 30.i sec Expected RT: 13 Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Base To Base 13.2 min 73 counts 5.33e+0Ol cps 13.2 min 13.4 min inting Time: 5:54:25 PM inting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: "s101122a148" Sample ID: "GLP10-01-02-05-072 IM S DAL S S GP02 0 0120 Lab Matrix Spike" Peak Name: "M 8PFOS(IS)" Mass(es): "507.0/80.0 amu" I C o m m en t"" Annotation:"" I Sample Index: 148 Sample Type: Unknown Concentration: 2.98 ng/mL I Calculated Cone: N/A | Acq. Date: 11/24/2010 Acq. Time: 10:46:43 PM File: "s101122a.vwfT H Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: No H Min. Peak Height cps Min. Peak width: 0 . 0 0 sec Smoothing Width: points RT Window: Expected RT: U9e Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: valley 13.2 rain 42665 counts 4.20e+003 cps 13.0 min 13.8 min I Sample Name: "s101122a150" Sample ID: "EC-101116-05 2.5 ng Extracted Curve Point" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation:"" Sample Index: 150 File: ns101122a.wifT Page 312 of 321 Page 497 of 962 Stan V166030S Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 498 of 962 *Stan V1660305 I Sample Name: ' s101122a155" Sample ID: "GLP1Q-01-02-05-074 DAL S S GP03 0 0005 Peak Name: ' M 8PFOS(IS)" Mass(es): ' 507.0/80.0 amu" Com m ent:"" Annotation:"" sample index: 155 Sample T y p e : Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 1:36:46 AM Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. MPiena.k WPiedatkh:Height: 0 . 0 0 cps sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: No Int. Type: Retention Time: Area: Height: start Tim e : End Time: Valley 13.2 min 30022 counts 2.28e+ 003 cps 13.0 min 13 .4 min File: "s101122a.w ifr Time, min I Sample Name: ' s101122a157" Sample ID: ' GLP10-01-02-05-074 LMS DAL S S GP03 0 0005 Lab Matrix Spike* Peak Name: "MSPFOS(IS)" Mass(es): "507.0/80.0 amu* Comment: Annotation:"" Sample Index: 157 Fite: "s101122a.wifT Luting Time: 5:54:28 PM Lnting Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb I Sample Name: ' s101122a156" Sample ID: "GLP10-01-02-05-074 Dup DAL S S GP03 0 0005 Duplicate' Peak Name: ' M8PFOS(IS)" Mass(es): ' 507.0/80.0 amu" C omment " Annotation: "" Sample Index: 155 sample Type: Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 2:01:05 AM File: ' s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan - MQi: Noise Percentage: Base. Sub. Window: 50 1.00 min Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: Smoothing width: RT Window: Expected RT: use Relative RT: 0.00 sec 3 points 30.0 sec 13.2 min No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley cps min min ISample Name: ' s101122a158" Sample ID: "G LP10-01-02-05-075 DAL SS G P 03 0 0020 " Peak Name: ' M8PFOS(!Sr Mass(es): "507.0/80.0 amu' SamCpolmemIenndt ex: Annotat1io5n8: " Sample Type: unknown Concentration: 2.98 i calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 2:49:43 AM File: ` s101122a.wifT Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. window: l.oo B Peak-Split. Factor: 3 Report Largest Peak: No Min. Peak Height: o .oo cps Min. Peak width: o .oo sec smoothing width: 3 points RT window: 30.0 se Expected RT: 13.2 mi Use Relative RT: No Int. Type: Retention Time: Area: Height : start Time: End Time : valley 13.2 min 29224 counts 2.37e+003 cps 12.9 min 13.9 min Page 314 of 321 Page 499 of 962 Stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 500 of 962 *stan V1660305 Results Name: sl01122a.rdb 3M Study GLP10-01-02 Interim Report 05 Page 501 of 962 *Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:54:34 PM Printing Date: Friday, January 07, 2011 3M Study G LP10-01-02 Interim R eport 05 Page 317 of 321 Page 502 of 962 Stan V1660305 ( Sample Name: ' s101122a171" Sample ID: 'G L P 10-01-02-05-078 Dup DAL SS GP04 0 0000 Duplicate " Peak Name: "M8PFO S(IS)" Mass(es): "507.0/80.0 amu* Comment: ~ Annotation: Sample Index: 171 Sample Type: Unknown Concentration: 2.98ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 8:05:35 AM Pile: ''s101122a.wiff' Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window: l . o o min Peak-Split. Factor: 4 Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: No c C : cps sec points RT Window: 30.0 Expected RT: 13.: Use Relative RT: No Int. Type: Base To Base Retention Time: Area: 39880 counts Height : 3.12e+003 cps start Time : End Time : I Sample Name: "s101122a173" Sample ID: "GLP10-01-02-05-079 DAL SS GP04 0 0005 " Peak Name: "M8PFO S(IS)' Mass(es): "507.0/80.0 amu" Comment "" Annotation: "" sample index: 173 File: "s101122a.wiff Results Name: sl01122a.rdb I Sample Name. "s101122a172" Sample ID: "G LP10-01-02-05-076 LMS DAL SS GP04 0 0000 Lab Matrix Spike" Peak Name: "M 6PFO S(IS)" Mass(es): "507.0/80.0 amu" C omment "" Annotation:"" Sample Index: 172 File: "s101122a.wiff' ISample Name: "s101122a174" Sample ID: 'G LP10-01-02-05-079 Dup DAL SS GP04 0 0005 Duplicate" Peak Name: "M 8PFO S(lS)" Mass(es): "507.0/80.0 amu" SamCpolmemIenndt e""x Annotation: "" Sample Type : File: "s101122a.wifT Printing Time: 5:54:35 PM Printing Date: Friday, January 07, 3M Study GLP10-01-02 Interim Report 05 Page 318 of 321 Page 503 of 962 Stan V1660305 Results Name: sl01122a.rdb Printing Time: 5:54:37 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Page 319 of 321 Page 504 of 962 Stan V1660305 I Sample Name: "s101122a179" Sample ID: "MB-101116-07 Method Blank Sg w / IS for Dilutions" Peak Name: "M8PFOS(IS)" Mass(es): "507.0/80.0 amu" C o m m en t"" Annotation: "" Sample Index: 179 Sample Type: Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 11:19:55 AM File: "$101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQ21 Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: MMiinn.. PPeeaakk wHieditghh:t No cps sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: 13.2 min Area: 58477 counts Height: 4.85e+003 cps Start Time: End Time: I Sample Name: "s101122a181" Sample ID: "10 006-25 solvent blank* Peak Name: "M6PFOS()Sr Mass(es): "507.0/80.0 amu" I Comment "" Annotation: " Sample Index: 181 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 12:08:37 PM File: "s101122a.wifT Modified: Proc. Algorithm: Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: RT window: 3 Expected RT: use Relative RT: NO cps sec points int. Type: Base To Base Retention Time: 13.2 min Area: 48 counts Height: 2.22e*ooi cps start Time: 13.2 min End Time: 13.4 min Printing Time: 5:54:39 PM Printing Date: Friday, January 07, 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01l22a.rdb I Sample Name: "s101122a160" Sample ID: "MB-101116-08 Method Blank Sg w / IS for Dilutions" Peak Name: "M6PFOS(IS)" Mass(es): "507.0/80.0 amu" Comment ~ Annotation:"" Sample Index: 180 Sample Type: Unknown Concentration: 2.98 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 11:44:14 AM File: "s101122a.wifr Modified: Yes Proc. Algorithm: IntelliQuan - MQi: Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: use Relative RT: 13.2 No min Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.2 min 54979 counts 5.2 3e +003 cps 1 2 . 8 min 13.6 min ISample Name: *s101122a182" Sample ID: "EC-101116-07 10 ng Extracted Curve Point" Peak Name: "M8PF0S(ISJ" Mass(es): '507.0/80.0 amu" Sample Index: Comme1n8t2"" Annotation: "" Sample Type: QC Concentration: 2.98 n< Calculated Cone: N/A Acq. Date: 11/25/2010 Acq. Time: 12:32:55 PM File: "s101122a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: l.oo Peak-Split. Pactor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 points RT Window: 30.0 se Expected RT: 13.2 mi use Relative RT: No Int. Type: Retention Time: Area: Height : Start Time: End Time : valley 13.2 min 58407 counts 5.41e+003 cps 1 2 . 8 min 13.4 min Page 320 of 321 Page 505 of 962 *Stan V1660305 Sample Name: "s101122a183" Sample ID: "10 006-25 solvent blank" Peak Name: *M8PFOS(lsr Mass(es): "507.0/60.0 amu" Comment: *" Annotation: Sample index: 163 Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 11/25/2010 70- Acq. Time: 12:57:18 PM 65 Modified: Yes Proc. Algorithm: IntelliQuan - MQli Noise Percentage 50 Base. Sub. window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height o.oo cps Min. Peak width: o.oo sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.2 min Use Relative RT: NO o 6055504540- File: "s101122a.witr' Int. Type: Retention Time: Area: Height: Start T i m e : End T i m e : Valley 13.1 min 133 counts l.98e+0Ol cps 13.1 min 13.5 min f 35- S 30- 25- 20 15' IQ S' 0 J -------i -----------------------r-- 24 -199 398 6 596 8 794 10 12 992 1191 Time, min 14 1389 16 1587 16 1785 20 1984 22 2182 Printing Time: 5:54:39 PM Printing Date: Friday, January 07 2011 3M Study GLP10-01-02 Interim Report 05 Results Name: sl01122a.rdb Page 321 of 321 Page 506 of 962 GLPlO-01-02-05 Range Finding (Screening) Analysis Data 3M Study GLP10-01-02 Interim Report 05 Page 507 of 962 3 M E n v ir o n m e n t a l L a b o r a t o r y Note to File Project or Study Number: G LP10-01-02-05 LIM S Number: G L P10-01-02-05 A ffected Data: A ll sam ples 3M Study GLP10-01-02 Interim Report 05 P a g a g ! 508 of 962 GLP10-01-01-05 ETS-8-053 Sam ple ID Sample Description 1 EC-100831-01 EC-100831-02 E C -100831-03 EC-100831 -04 EC-100831-05 E C -1 00831-06 E C -1008 31-07 E C -100831-08 E C -1 00831-09 E C -1 00831-10 EC-100831-11 E C -100831-12 M 8-100831-01 MB-100831-02 MB-100831-03 MB-100831-OJ M B -100831-05 M B -100831-06 LCS-100831-01 LCS-100831-02 LCS-100831-03 L C S -100831-04 LCS-100831-05 LCS-100831-06 G LP 10-01-01-05-001 G LP10-01-0 1 -0 5 -0 0 2 G LP10-01-0 1 -0 5 -0 0 4 G LP10-01-0 1 -0 5 -0 0 5 G LP 10-01-01-05-006 G LP 10-01-01-05-007 G LP10-01-01-05-009 G LP10-01-0 1 -0 5 -0 1 0 G L P 10-01-01-05-011 G LP10-01-0 1 0 5 -0 1 2 GLP10O10 1 0 5 0 1 3 GLP10O10 1 0 5 0 1 4 GLP10 0 1 0 1 0 5 0 1 5 GLP10O10 1 0 5 0 1 6 GLP10 0 1 0 1 0 5 0 1 7 GLP10 0 1 0 1 0 5 0 1 8 GLP10O10 1 0 5 0 2 1 G LP 1G 01-01-05-022 G LP 10-01-01-05-023 GLP10 0 1 0 1 0 5 0 2 4 GLP10O10 1 0 5 0 2 5 GLP10O10 1 0 5 0 2 6 GLP10 0 1 0 1 0 5 0 2 7 GLP10 0 1 0 1 0 5 0 2 8 GLP10 0 1 0 1 0 5 0 2 9 GLP10 0 1 0 1 0 5 0 3 0 GLP10 0 1 0 1 0 5 0 3 1 G LP10010105032 GLP10 0 1 0 1 0 5 0 3 3 2 0.2 na Extracted Curve Point 0.5 no Extracted Curve Point 0.75 no Extracted Curve Point 1 na Extracted Curve Point 2.5 na Extracted Curve Point 5 ng Extracted Curve Pom 10 na Extracted Curve Point 25 na Extracted Curve Point 50 na Extracted Curve Point 100na Extracted Curve Point 200 na Extracted Curve Point 500 na Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w / IS 3 na LCS in TCR-842 3 na LCS In TCR-642 3n q LCS in TCR-842 30 nq LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 DAL SDTRIP1 0 100624 DAL SD SD01 000 00 DAL SD SD02 0 0000 DAL SD SD02 0 0005 DAL SD SD03 0 0000 DAL SD SD 03 0 0005 DAL SD SD 04 000 00 DAL SD SD04 0 0005 DAL SD SD05 0 0000 DAL SDSD05 0 0005 DAL SD SD06 0 0000 DAL SD SD 06 0 0005 DAL SD SD07 0 0000 DAL SD SD07 0 0005 DAL SD SD08 0 0000 DAL SD SD08 DB 0000 DAL SD S D 0900000 DAL SO SD09 0 0005 DAL SD SD10 0 0000 DAL SD SD 10 0 0005 DAL SD SD11 00000 DAL SD SD11 0 0005 DAL SD SD12 0 0000 DAL SD SD 12D B0000 DAL SD SD12 0 0005 DAL SD SD13 0 0000 DAL SD SD13 0 000S DAL SD SD 14 0 0000 DAL SD SD14 0 0005 Soil Maxtrlx Soil W eight ID Used (g ) Spike ID Spike Volum e (u L ) Internai Internai Standard ID StandardV olum e (uL) Surrogate Spike ID S u rro g a te S p ike Volum e (u L ) Add B mL Extraction Sonicate 1 hr C e n trifu g e S o lv e n t C om m ents 3 1 0 0 0 3 -2 3 8 1 0 0 0 3 -2 3 8 10 003-238 10 003-236 10 003-236 1 0 0 0 3 -2 3 8 10 003-238 10 003-236 10 003-238 10 003-236 10 003-238 10 003-236 10 003-238 10 003-238 10 003-236 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 1 0 0 0 3 -2 3 8 10 003-238 4 1.1383 1.1550 1.1297 1.1258 1.0776 1.0968 1.0946 1.1772 1.1080 1.1115 1.1120 1.1064 1.1401 1.1230 1.1088 1.1285 1.1270 1.1288 1.0965 1.1281 1.1281 1.1253 1.0829 1.1442 1.0868 1.4575 ssw ssnH H iB H H H s is fflflH n jOS&HBTBmSSii SSSSRBBiS! T 'iW C i.m ilM l m a m smuxirmiJUMVJeeuieu &6St&tBBRg fijg ttaS iS B s B ns m rrra T n rrfin smsus&ms s ia ssm m saa 1.3921 1.8422 1.8003 1.5896 1.7681 1.9192 2.0961 2.3719 1.8051 2.4128 1.8941 1.6432 1.8240 1.5876 2.0053 1.6580 1.2246 2.0841 2.1081 1.3349 1.7775 1.7962 2.8711 2.5859 2.3395 1.8981 1.8783 5 10 001-151 10001-151 67 8 9 20 09 004-173 30 10003-218 50 09 004-173 30 10 003-216 10 3500 10001-151 75 09 004-173 30 10 003-218 75 10 001-151 100 09 004-173 30 10003-218 1X 10 001-150 25 09 004-173 30 10 003-217 25 1 0 0 0 1 -1 5 0 50 09004-173 30 10003-217 SO 10 001-150 10 001-149 10 001-149 100 09 004-173 30 1 0 X 3 -2 1 7 1 X so25 09 004-173 30 X 004-172 25 50 09004-173 30 09004-172 10 001-149 100 09 004-173 30 X 004-172 1X 09 004-118 20 09 004-173 30 X 004-172 200 09 004-118 m m sas mmtoem gSSaiT'a:50 09 004-173 ia e s s s a s B a & itts a M 30 M X 004-172 SX s e s ts s a S s $ fi S B gtmamt0.ii stsmsmmaamm 3332000010 001-148 s & s a c ra p e a s a s jts s K s s s a 0 9 0 0 4 -1 7 3 30 09 004-173 30 09 004-173 30 30 09 004-173 30 B B S S * 10X 3-217 10003-217 10 003-217 10003-217 10 001-148 30 09 004-173 30 10 003-217 30 10 001-148 30 09 004-173 30 10 003-217 30 10 001-147 30 09 004-173 30 10003-217 30 10 001-147 30 09 004-173 30 10 003-217 30 10 001-147 30 09 004-173 30 10003-217 30 30aM B tes ; 09 004-173 30 10003-217 30 ir w n n w iM iu r 'if i SSBBMBS 09 004-173 30 10003-217 -- wwmULm ie.xm ai B 9 M B 9 !! 09 004-173 30 10 003-217 30 30i M M i i r n r e r n S B 06 09 004-173 30 10 003-217 30 H n s m s a i 09 004-173 30 10 003-217 30g ffa rm g iiin iiti i jh 09004-173 30 10 X 3 -2 1 7 30a n & n s x s is s s s s 09 004-173 30 10 X 3 -2 1 7 20!SBIS99HNSil^9S3@ 09 004-173 30 10 X 3 -2 1 7 2009 004-173 30 1 0 X 3-217 wassmm 2009 004-173 30 10 003-217 s& ssm 2009 004-173 30 10 003-217 WBUSB&I&BS823S.osmizem 2009 004-173 30 10 003-217 nmaam 09 004-173 30 10 003-217 30 HMvmnF 2200t a s s a * 09 004-173 30 10 003-217 30 iiT* h T n r u T T iiin i B S S S IS 09 004-173 30 10 003-217 09 004-173 30 10003-217 20H H r e S f lS S g 09 004-173 30 10 003-217 2009 004-173 30 1 0 X 3-217 2009 004-173 30 10X 3-217 20S B B fiinM S tjB B S B 09 004-173 30 10 X 3 -2 1 7 20fflE is s 09 004-173 30 1 0 X 3-217 20S H W iilS iS S S S S sss s a 09 004-173 30 10003-217 20RSSCB&gg 09 004-173 30 10 003-217 205 S W tT O 1 W B 2 S S S S k s w m s s 09 004-173 30 10 003-217 SHtKgSasSB 09 004-173 30 10 003-217 30 SSoegM dml f e f e t e 09 004-173 30 10 003-217 30 mmm&smem S B S R ^ b 09 004-173 30 10 003-217 30 #i*mgggs 09 004-173 30 10003-217 30 mmmstmsmm *'vS 09 004-173 30 10 003-217 30 11 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 12 13 14 m ay have spiked 20 t i o i 10001-150 w aters rocks clav "thin milk shake" clav water Sorass &Bg&1 )' Oi:L3 Page 1 of 3 GLP1-01-01-05 ETS-S-053 Sam ple ID Sampte Description 1 GLP10-01-01-05-034 G LP1001-01-05-035 GLP10-01-01-05-036 G LP 10-01-01-05-037 GLP10-01-01-05-038 GLP10 0 1 -0 1 -0 5 -0 3 9 GLP10 0 1 -0 1 -0 5 -0 4 0 GLP10 0 1 0 1 -0 5 -0 4 1 GLP10 0 1 0 1 05 -0 4 2 GLP10 0 1 0 1 -0 5 0 4 3 GLP10 0 1 0 1 -0 5 0 4 4 GLP10 0 1 0 1 0 5 0 4 5 GLP10 0 1 0 1 0 5 0 4 6 G LP10010105047 G L P 10010105-048 GLP1001010 5 0 4 9 GLP1001010 5 0 5 0 GLP10 0 1 0 1 0 5 0 5 1 GLP1001010 50 52 GLP10O10 1 0 5 0 5 4 GLP10-01-01-05-055 GLP10 0 1 0 1 0 5 0 5 6 GLP100101050 57 GLP10 0 1 0 1 0 5 0 5 8 GLP10 0 1 0 1 0 5 0 5 9 GLP10 0 1 0 1 0 5 0 6 0 GLP1001-01-05-061 GLP1001010 5 0 6 2 GLP10 0 1 0 1 0 5 0 6 3 G LP10 0 1 -0 1 -0 5 -0 6 4 GLP10 -0 1 0 1 0 5 0 6 5 GLP10O10 1 0 5 0 6 6 GLP10 0 1 0 1 0 5 0 6 7 GLP10 0 1 0 1 0 5 0 6 8 GLP10 0 1 0 1 0 5 0 6 9 GLP10 0 1 0 1 0 5 0 7 0 GLP10 0 1 0 1 0 5 0 7 1 GLP10-01-01-05-072 GLP10 0 1 0 1 0 5 0 7 3 GLP10 0 1 0 1 0 5 0 7 4 GLP10 0 1 0 1 0 5 0 7 5 GLP10 0 1 0 1 0 5 0 7 6 GLP10 0 1 0 1 0 5 0 7 7 GLP1001010 5 0 7 9 GLP10 0 1 0 1 0 5 0 8 0 GLP10010 1 0 5 0 8 1 GLP10 0 1 0 1 0 5 0 8 2 GLP10 0 1 0 1 0 5 0 8 3 G LP100101-OS-084 GLP10 0 1 0 1 0 5 0 8 5 GLP100101050 87 GLP100101050 88 GLP1001010 50 89 GLP10O10 1 0 5 0 9 0 2 DALSD SD15 0 0000 DAL SD SD15 0 0005 DAL SD SD16 0 0000 DALSD SD16DBOOOO DAL SD SD16 0 0005 DAL SD SD17 0 0000 DAL SD SD17 0 0005 DAL SS SS01 0 0000 DAL SS SS01 0 0005 DAL SS SS02 0 0000 DAL SS SS02 0 0005 DAL SS SS03 0 0000 DAL SS SS03 0 0005 DAL SS SS03 DB 0005 DAL SS SS04 0 0000 DAL SS SS04 0 000S DAL SS TRIP1 0 0000 DAL SS $$05 0 0000 DAL $S $$05 0 0005 DAL SS SS06 0 0000 DAL SS SS06 0 0005 DAL SS SS06 DB 0005 DAL SS SS07 0 0000 DAL SS SS07 0 0005 DAL SS SS08 0 0000 DAL SS SS08 DB 0000 DAL SS SS08 0 0005 DAL SS SS09 0 0000 DAL SS SS09 0 0005 DAL SS GP01 00000 DAL SS GP01 00005 DAL SS GP01 00020 DAL SS GP01 00060 DAL SS GP02 0 0000 DAL SS GP02 00005 DAL SS GPQ2 0 0020 DAL SS GP02 DB 0020 DAL SS GP02 0 0120 DAL SS GP03 0 0000 DAL SS GP03 00005 DAL SS GP03 00020 DAL SS GP03 DB 0020 DAL SS GP03 0 0050 DAL SS GP04 0 0005 DAL SS GP04 0 0020 DAL SS GP04 0 0050 DAL SS GP05 0 0000 DAL SS GPQ5 0 0005 DAL SS GP05 0 0020 DAL SS GP05 0 0055 DAL SS GP06 0 0000 DAL SS GP06 0 0005 DAL SS GP06 0 0020 DAL SS GP06 0 0110 "^Copy o Orft'rd jtu d y G ts Ifi i j p f T n fe rim Re|go'rt]05 Soil Maxtrix Soil W eight ID Used (g) Spike ID Spike Volum e (u L ) Internai Standard ID Interna! StandardV olum e (uL) Surrogate Spike ID Surrogate Spike Volum e (uL) Add 8 mL Extraction Sonicate 1 Solvent hr C e n trifu g e Comments 34 S 6 7 8 9 10 ummoemSSiJSSSSffi! 1.8443 ifa s w s m w sasssw a 09 004-173 30 10003-217 30 1.9699 09 004-173 30 10003-217 30 1.4316 ifSHSiaea 09 004-173 30 10003-217 30 r nnniiiiTi' aanum s. 1.5784 1.3628 1.7467 7 aam[ ^f[TgmtrJJ.'iJiriiiwiitu. 09004-173 30 10 003-217 30 09004-173 30 10 003-217 30 09004-173 30 10 003-217 30 m onm .1.1280 1.1180 K s a s s M t s a 09004-173 30 10 003-217 30 09 004-173 30 10 003-217 30 2.0737 m w a w ii/iT ii'r 'iiiS y iw ig r*B 5 09004-173 30 10 003-217 30 ti riiiinnr|fn^||i 1.2658 9 B M S S & * 09 004-173 30 10 003-217 30 tn iiiira n rp T i 1.3200 n o s a s 09004-173 30 10 003-217 30 1.6667 09004-173 30 10 003-217 30 1.4266 vvQistnuwBNBBneQiWE oimwxwo**- 09004-173 30 10 003-217 30 1.3072 s e s js s s a s s s 09 004-173 30 10 003-217 30 9iK B B B 88 1.2135 e ^ a @ W B B a g p i ffinBIM Tirl? 09 004-173 30 10 003-217 30 1.1052 09 004-173 30 10 003-217 30 0.9770 a a m e a a a s iM ^ a -- iim f iim h ni 09 004-173 30 10 003-217 30 msaesom^mmwemsm1.3540 g W n ed llvW W S B i RR5SSJ? 09 004-173 30 10 003-217 30 1.0577 09004-173 30 10 003-217 30 0.9166 09 004-173 30 10 003-217 30 1.4281 A5MPMisaIB(?HeR*fMliKB*S6^S^e*ss C B VaK H R 09 004-173 30 10 003-217 30 b ss* h m s 1.2000 09 004-173 30 10 003-217 30 SSXBSIBBKSaSSRSSn&^lim irwiri1itiniin 0.7298 1.3845 09 004-173 30 10 003-217 30 09 004-173 30 10 003-217 30 0.8510 09 004-173 30 10 003-217 30 jUSM B B C fiB i 1.2892 asWxaCixHimenMBaUBHtfManrnatt MsaUnMRMKBsBBHXei 09 004-173 30 10 003-217 30 1.3253 B^SBWS8S 09 004-173 30 10003-217 30 0.9353 09 004-173 30 10003-217 30 1.2071 a a s > B tifin ffit n i w . ii 09 004-173 30 10003-217 30 0.9749 r i r t B a M m n w oe 09 004-173 30 10003-217 30 ^ B M K K K 1.6303 H E S U H S M S S S S IS B flM iS i 09004-173 30 10 003-217 30 mmsaamm 1.8162 3ittMSSBE&iKS K fiiflffilliB 09 004-173 30 10 003-217 30 1.2598 SIMBBWBBWiV.ffHB M M 53HW 1 09 004-173 30 10 003-217 30 N M M gm M : 0.9835 g8MSMWMHrSggt 09004-173 30 10 003-217 30 m a B n Z B lK 1.1816 >ggMBMaB,<t,rMri*ef i !WT H fM irrrynT 09004-173 30 10003-217 30 S B 3 I9 B B K K 1.6807 09004-173 30 10 003-217 30 'HSSBtSSSi &BBBS3BBIBKMM1.4875 09004-173 30 10 003-217 30 S&BBtSSSR 1.0289 09004-173 30 10 003-217 30 $23BBB5fS& 1.3355 s a s w w s s s s * asaw fiK U t 09 004-173 30 10 003-217 30 gvmexmetfPfA 0.9734 iBMimSiSi 09 004-173 30 10 003-217 30 IfiSHHHEKBKI 1.6619 g E E -- BESBBi lEMIttBHBn 09 004-173 30 10 003-217 30 a n n s a B s 1.9399 iiiiM iJiTiW B irrrnm ii b u b b m 09 004-173 30 10 003-217 30 MmBSicasBosi 1.1241 09 004-173 30 10 003-217 30 fam e*tiS S S !*S a 0.9464 1.6996 B B c a a M w g a g m i 09 004-173 30 10003-217 30 09 004-173 30 10003-217 30 'mmmismS S W S S S R 1.4762 1 ism bso m sk 09 004-173 30 10 003-217 30 1.1435 ^ W fW *ffifflg W fffifl^ lHHTH'ifW ff 09 004-173 30 10 003-217 30 SBMKIKigS! 1.1599 1.0476 M jeM n iB in K H ^aC l 09004-173 30 10 003-217 30 09 004-173 30 10 003-217 30 m m m m 1.5518 09 004-173 30 10 003-217 30 m m m sssm 1.5498 & & is3gaistm m m m o 09 004-173 30 10 003-217 30 1.3319 09 004-173 30 10 003-217 30 1.4154 fe a s is s iiis 09 004-173 30 10 003-217 30 m s m m is 1.5505 09 004-173 30 10 003-217 30 11 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 12 13 14 day day w/qrass day Page 2 of 3 Page 510 of 962 GUM 0-01-01-05 ETS-8-053 Sample ID Sam ple Description 1 GLP10-01-01-05-091 GLP10-01-01-05-092 GLP10-01 -01-054)93 GLP10-01-01-05-094 GLP10-01-01-05-095 GLP10-01-01-05-096 G LP 1D 01-0 1 -0 5 0 9 7 G LP 10-01-01-05-098 G LP 10O 1-01-05-099 GLP10-01-01 -05-101 GLP10-01 -01-05-102 GLP10-01 -0105-103 GLP10-01 -01 -05-104 GLP10O1 -01-05-105 GLP10-01-01-05-106 G LP10 0 1 -0 1 -0 5 -1 0 7 GLP10-01 -01 -05-108 GLP10O1 -01 -05-109 GLP10-01-01-05-111 GLP10-01 -01 -05-112 G LP1001-01-05-113 G LP1001-01-05-114 GLP10-01 -01 -05-115 GLP10-01 -01 -05-116 GLP10-01-01-05-117 GLP10-01-01-05-118 GLP10-01 -01 -05-119 2 DAL SSG P07 00000 DAL SSG P07 00005 DAL SSG P07 0 0020 DAL SSG P07 0 0130 DAL SSG P08 00000 DAL SSG P08 0 0005 DAL SS GP8 DB 0005 DAL SSG P08 0 0020 DALSS GP08 0 0050 DAL SSG P09 00000 DAL SSG P09 0 0005 DAL SS GP09 DB 0005 DALSS GP09 0 0020 DALSS GP09 0 0050 DAL SS GP10 0 0000 DALSS G P1000005 DAL SSG P10 0 0020 DALSS GP10 0 0060 DALSS GP11 00000 DALSS GP11 00005 DALSS GP11 00020 DAL SSGP11 0 0065 DAL SS GP11 DB 0065 DAL SSG P12 0 0000 DALSS GP12 0 0005 DALSS GP12 00020 DALSS GP12 00170 Soil M axtrix Soil W eight ID Used (g) Spike ID Spike Volum e (uL) Internai Standard ID Internal StandardV olum e (uL) Surrogate Spike ID Surrogate Spike Volum e (uL) Add 8 mL Sonicate 1 Extraction hr Centrifuge S o lv e n t msmmwb: mimtmasmm.'3 4 1.3775 5 6 7 8 9 10 S S S S S S e 09 004-173 30 10 003-217 30 is a a s s s s s 1.4943 09 004-173 30 10 003-217 30 g s m u iim a 1.0292 fieaaimHflacBiMwwam 09 004-173 30 10 003-217 30 -v s w s b s b s s 1.0736 n s 09 004-173 30 10 003-217 30 1.1834 s a f e s s * f 09 004-173 30 10 003-217 30 1.5616 Il V M IT iw i|ihim >' tssssssss 09 004-173 30 10003-217 30 tismseam mmaam1.0702 lin iiiM iin iriiirfP i 09 004-173 30 10 003*217 30 isa&sm 1.1992 M M M w rrv ra r iron s m s s ; 09 004-173 30 10003-217 30 mmsasm . 1.1408 |0B6ifefiSS^MnBlRar B.*;SSf 09 004-173 30 10003-217 30 wmmmm w&mm1.2337 aaBaaiaseMPB^gm 09 004-173 30 10 003-217 30 1.2441 09 004-173 30 10 003-217 30 moammass 1.0558 g g H M B B B & S M 8EUffHfiSt 09 004-173 30 10 003-217 30 mmss&mlaaSWiBri-^grffaBft 1.3573 09 004-173 30 10003-217 30 \i mms&m1.1493 s w e r n v i n ' v w 09 004-173 30 10003-217 30 w&mmmMM-- 1.2765 09 004-173 30 10 003-217 .3 0 1.0924 n iiiiiin iiiiim iM im iiii a s -B e ssst 09 004-173 30 10 003-217 30 ovsmc ma mm u s a s *** 1.1045 1.2671 1.1741 1.0671 1.0533 1.0158 a !K 5 e : 09 004-173 30 10003-217 30 U S S H 09 004-173 30 10003-217 30 09 004-173 30 10 003-217 30 3300SKSS3S 09 004-173 30 10 003-217 30 s s a w 09 004-173 30 10 003-217 09 004-173 30 10 003-217 4 S K S S S S 1.0658 a n 09 004-173 30 10 003-217 30 s e s a a e s a f 1.0137 s sx e 09 004-173 30 10 003-217 30 s s b m s s * 1.0120 09 004-173 30 10 003-217 30 m m m m aam1.0709 1.0103 StWSSBSW 9 004-173 s s s b m s 9 004-173 30 10003-217 30 10003-217 30 30 11 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 12 13 C om m ents 14 Co! 3 & 4: Balance ID: 900 Co! 5 & 6: Pipette ID: 4215537 8/31/2010 mmh GLP10-01-Q1-Q5-070 to 119 9/1/10 mmh 9/1/10 mmh Col 7 & 8: Pipette ID: 4215537 91/10 mmh Col 9 & 10: Pipette ID: 4215537 91/10 mmh Pipette ID: 3624414 Col 11: Extraction Solvent 09004-182 Col 12: Sonicator ID: QEJ10059500>33 ^ ------ C o l13: Centrifuge ID: 021188-55 10 min @ 3000 RPM C oM 4: $ ^ ^ 0 -0 1 -0 2 , Page 3 of 3 Page 511 of 962 GLP10-01-01-05 ETS-8-053 Sam ple ID Sample Description 1 EC-100831-01 EC-100831-02 EC-100831-03 EC-100831-04 EC-100831-05 E C -100831-06 EC-100831-07 EC-100831-08 E C -100831-09 EC-100831-10 EC-100831-11 EC-100831-12 MB-100831-01 MS-100831 -02 MB-100831-03 MB-100831-04 MB-100831-05 M8-100831-06 LCS-100831-01 LCS-100831-02 LCS-100831-03 LCS-100831-04 LCS-100831-05 LCS-100831-06 GLP10-01-01-05-001 GLP10-01-01-05-002 GLP10-01-01-05-003 GLP10-01-01-05-004 GLP10-01-01-05-005 GLP10-01 -01 -0 5 0 0 6 GLP10-01-01-05-007 GLP10-01-01-05-009 G LP10-01-01-05 -0 1 0 GLP10-01-01 -05-011 GLP10-01-01-05-012 G LP10-01-01-05-013 GLP10-01-01-05*014 GLP10-01-01-05-015 GLP10-01-01-05-016 GLP10-01-01-05-017 G LP 10-01-01-05-018 GLP10-01 -01 -05*019 GLP10-01-01-05-021 GLP10-01 -01 -05-022 GLP10-01-01-05-023 GLP10-01-01-05-024 GLP10-01-01-05-025 GLP10-01-01-05-026 G LP10 -0 1 -0 1 -0 5 0 2 7 G LP10O 101-0 5 0 2 8 G L P 100101-05029 GLP10O10 1 0 5 0 3 0 G LP 10-010105031 GLP10 0 1 0 1 0 5 0 3 2 G LP10010105033 02 2 na Extracted Curve Point 0.5 no Extracted Curve Point 0.75 na Extracted Curve Point 1 no Extracted Curve Point 2.5 na Extracted Curve Point 5 na Extracted Curve Point 10 na Extracted Curve Point 25 no Extracted Curve Point 50 no Extracted Curve Point 100 nq Extracted Curve Point 200 na Extracted Curve Point 500 na Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w / IS Method Blank 6 w /IS 3 na LCS In TCR-842 3 na LCS in TCR-842 3 no LCS in TCR-842 30n aLC S in TCR-842 30 na LCS In TCR-842 30 na LCS in TCR-842 DAL SDTRIP1 0100624 DAL SDSD01 0 0000 DAL SDSD01 0 0005 DAL SDSD02 0 0000 DAL SD SD02 0 0005 DAL SD SD03 0 0000 DAL SD SD03 0 0005 DAL SDSD04 0 0000 DAL SD SD04 0 0005 DAL SD SD05 0 0000 DALSD SD05 0 0005 DAL SD SD06 0 0000 DALSD SD06 0 0005 DALSD SD07 0 0000 DALSD SD07 0 0005 DAL SD SD08 0 0000 DALSD SD08 DBOOOO DAL SD SD08 0 0005 DALSD SD09 0 0000 DAL SD SD09 0 0005 DAL SD SD10 0 0000 DALSD SD10 0 0005 DAL SD SD11 0 0000 DALSD SD11 0 0005 DAL SD SD12 0 0000 DALSD SD12 DBOOOO DALSD SD12 0 0005 DALSD SD13 0 0000 DAL SD SD13 0 0005 DAL SD SD14 00000 DAL SD SD14 0 0005 S o il M axtrlx Soil Weight ID Used (g) Spfee ID Spike Volum e (uL) In te rn a l Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volum e (uL) _Ad_d 8 mL E x tractio n Son. i.c.ate. 1 _^ C e n trifu g e S o lv e n t Comments 3 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 'c r n f i 7* V M 8 v. B u t . J V iT Si 1M HM 9M 66? aMrsamrnstzem- ti H X M C S F .I MiS lJt - i fmc-SrnEirMmS'ii 'V ii.:. EftsessawBBsKs msw a rn wmmmassmmmzmm 4 1.1383 1.1550 1.1297 1.1258 1.0776 1.0966 1.0946 1.1772 1.1060 1.1115 1.1120 1.1064 1.1401 1.1230 1.1088 1.1285 1.1270 1.128B 1.0965 1.1281 1.1281 1.1253 1.0829 1.1442 1.0868 1.4575 1.6477 1.3921 1.6422 1.6003 1.5896 1.7661 1.9192 2.0961 2.3719 1.8051 2.4128 1.8941 1.6432 1.6240 1.5876 2.1718 2.0053 1.8560 1.2246 2.0841 2.1081 1.3349 1.7775 1.7962 2.8711 2.5859 2.3395 1.8981 1.8783 5 10001-151 10 001-151 10 001-151 10 001-151 10 001-150 10 001-150 6789 20 09004-173 30 10 003-218 mm-10 11 12 13 30 ' M K i - a B H X H 14 50 09004-173 30 10 003-218 50 M E2^S ESMBiiSK mmmsmmmgm75 09004-173 30 10003-218 75 a a a n r a r mmtmm mmsess i". tl100 09 004-173 30 10003-218 100 S m a ll V -25 09 004-173 30 10 003-217 25 % ! mayhavespited 20 d of 10001-150 50 09 004-173 30 10 003-217 50 r V T - - r T f * * . V f-' 10 001-150 100 09 004-173 30 10 003-217 100 * r 10 001-149 10 001-149 10 001-149 09 004-118 09 004-118 25 09 004-173 30 09 004-172 25 50 09 004-173 30 0 9 0 0 4 -1 7 2 50 LMJT*.100 09 004-173 30 09 004-172 100 -je20 0 9 0 0 4 -1 7 3 30 09 004-172 200 s-mtmamws&mmsaumimwa50 09 004-173 30 09 004-172 500 . ' M r tb i f ' i . - T^r r ; iCSJKi *r; V .-r.v v p f i r - 's rx m r*' arm** msmam mmmtmft* r c -, m fis s a n s m JW v -i - w x k . m nnn *- jr w a a e v s fc a s a S B S =* v k t s ta s s '. i * -jr a ' r a : ? 'd ie H i _M l Jf i s - - e* 09 004-173 30 10 003-217 30 ^ L? !M S ' . W ! * -a * -. *v 09004-173 30 10 003-217 30 be * 09 004-173 30 10 003-217 30 t t J M ! <Mb " 10 001-148 30 09004-173 30 10 003-217 30 10 001-148 30 09 004-173 30 10003-217 30 10 001-148 10 001-147 30 09 004-173 30 10 003-217 30 30 09 004-173 30 10 003-217 30 sziu t-? 10 001-147 10 001-147 -- XXX30 09 004-173 30 10003-217 30 U V M t b K A S lS -- > 30 09 004-173 30 10003-217 30 -- .IM S -- "I1 P S -*S ! l l E l " 09 004-173 30 10 003-217 30 i-ti-ytwmx-iisitizxjm mm a s 09 004-173 30 10 003-217 30 M t M i n lo a s jw r . wmriKH09 004-173 30 10 003-217 30 r a n s n v - iu ! m - . r - - . i s l i t l h 09 004-173 30 10 003-217 30 ' r - i . 1 s a n s m mis , mmumma rt . . i 09 004-173 30 10 003-217 30 a B a a B a a e a a a 1..setter.e w ;. ; 09 004-173 30 10 003-217 30 JB K Si mt mmmm> '9 *\ r 09 004-173 30 10 003-217 30 r %*->* t-xvr#ms/- 09 004-173 30 10 003-217 30 a m n v e w m c wamawem,s n -- a it iH 09 004-173 09 004-173 0 9 0 0 4 -1 7 3 30 30 30 10 003-217 10 003-217 10 003-217 30 ' . O H I S H T l.-.> 30 30 I B B B K H B H n T-.-TsjtiM '.'JZ: mH H M R B n m H i 09 004-173 a -- 09 004-173 30 30 10 003-217 10 003-217 30 30 s w msssFism: water & rocks -`tmrsm> Psi-'wi/irjEeJtir*sMawjrnr1>s* - w *aw 09 004-173 30 10 003-217 30 * f S ii' ,? -ii E jh .in .-I. ->.* . 09004-173 30 10 003-217 30 H H a a n a r is s a a a a n o K 09 004-173 30 10 003-217 30 y-z*--09 004-173 30 10 003-217 30 S 3 ? !' a' *? ,. xam m gi09 004-173 30 10 003-217 30 ' : * o . > * -4 U i xmm k t t: m h r i i n a v e 09 004-173 30 10 003-217 30 V * t\ mum* -1 , 09004-173 30 10 003-217 30 ^ . ta a a a g B S S iS aavi 09004-173 30 10 003-217 30 I B M H i day fm r n ir M r r w T iiw b k b k ib m 09 004-173 30 10 003-217 X 'in i' a-- m a M B a i w a ;tlT aF 'f f l''afF fffT ~ lirgT T T fP W T 1 09004-173 30 10 003-217 X 3BESSM12! f0BlfiB5SE 'thin milk shake" 09004-173 30 10 003-217 X B i f m n a K i t a m day memmes msomssmmmm-xi a n w a a n wmsmmmmmsmmmmtmut mmm.-:.k v t 09 004-173 30 10 003-217 X I^ M H M I water & grass 09 004-173 30 10 003-217 X 09 004-173 30 10 003-217 30 saa B B S * e *rf- 09 004-173 30 10 003-217 30 * i n r t i i i s i l. v ::- . L..i`Wm mmsmr- -r V a t* - * Q *r * - 09 004-173 30 10 003-217 X a m a r: 09 004-173 30 10 003-217 X a s M a a u 09 004-173 30 10 003-217 30 a s - - .y Page 1 of 3 G L P 10-01-01-05 ETS-8-053 SampleID 1 GLP10-01-01-05-034 GLP10-01-01-05-035 GLP10-01-01-05-036 GLP10-01-01-05-037 GLP10-01-01-05-038 GLP10-01-01-05-039 GLP10-01-01-05*040 GLP10-01-01-05-041 GLP10-01-01-05-042 GLP10-0101-05-043 GLP10010105044 GLP10-01-01-05-045 GLP10010105046 GLP10O1O105047 GLP1001010504S GLP10010105049 GLP10010105050 GLP10010105051 GLP10010105052 GLP10010105054 GLP10010105055 GLP10010105056 GLP10010105057 GLP10010105058 GLP10010105059 GLP10010105060 GLP10010105061 GLP10010105062 GLP10010105063 GLP10010105064 GLP10010105065 GLP10010105066 GLP10010105067 GLP10010105068 GLP10010105069 GLP10010105070 GLP10010105071 GLP10010105072 GLP10010105073 GLP10010105074 GLP10010105075 GLP10010105076 GLP10010105077 GLP10010105078 GLP10010105079 GLP100101-05080 GGLLPP1100001100110055008812 GLP10010105083 GGLLPP1100001100110055008845 GLP10010105087 GLP10010105088 GGLLPP1100001100110055009809 SampleDescription SoilMaxtrtx SoilWeight ID Used(g) SpikeID Spike Volume (uL> StaInntdearnrdalIDoShtIanimntedran(raudlLV) Surrogate SpikeID Surrogate .Spike Volume (uL) E_Axd.tdra8c.tm.ioLn Seoniu.catte(1 C_en.tri.f.uge Solvent Comments 2 DALSDSD1500000 DALSDSD1500005 DDAALLSSDDSSDD11660D0B0O0O0OO DALSDSD600005 DALSDSD1700000 DALSDSD1700005 DALSSSS0100000 DALSSSS0100005 DALSSSS0200000 DALSSSS0200005 DALSSSS0300000 DALSSSS0300005 DALSSSS03DB0005 DALSSSS0400000 DALSSSS0400005 DALSSTRIP100000 DALSSSS0500000 DALSSSS0500005 DALSSSS0600000 DALSSSS0600005 DALSSSS06DB0005 DALSSSS0700000 DALSSSS0700005 DALSSSS0800000 DALSSSS08DB0000 DALSSSS0800005 DALSSSS0900000 DALSSSS0900005 DALSSGP0100000 DALSSGP0100005 DALSSGP0100020 DALSSGP0100060 DALSSGP0200000 DALSSGP0200005 DALSS6P0200020 DALSSGP02DB0020 DALSSGP0200120 DALSSGP0300000 DALSSGP0300005 DDAALLSSSSGGPP00330D0B0020020 DALSSGP0300050 DALSSGP0400000 DALSSGP0400005 DALSSGP0400020 DALSSGP0400050 DALSSGP0500000 DALSSGP0500005 DALSSGP0500020 DALSSGP0500055 DALSSGP0600000 DALSSGP0600005 DALSSGP0600020 DALSSGP0600110 3 KB 4 1.8443 56 -tlF r ii' . 090074-173 8 30 9 10003-217 10 30 11 HE 12 'V. 13 .M S 14 * mtammessm wmeamms mmtzm 1.9699 1.4316 wm-- .<-t Hr*w a m n m 09004-173 a. at - v m :n u n 09004-173 1.5784 >' 14 . .tr ' V -mi 09004-173 30 30 30 10003-217 10003-217 10003-217 30 M R H S H IHBBHH1day 30 M B B K H i wmmmam davw/grass 30 m N m n m g M day 1.3628 'm a s * 09004-173 30 10003-217 30 *C|VHHI KHHHHSHBHHHH PvHHB 1.7467 r n m m m m m m m m m a m 09004-173 30 10003-217 30 '*Ji;4M KMHMS IM M 1.1280 MFMMMMM'Ml MMMM 09004-173 30 10003-217 30 SK.WSf HRSKSK*SHWIRHHH . x th 1.1180 09004-173 30 10003-217 30 it >5*M r* *. 2.0737 M H U K BHHHKi 09004-173 30 10003-217 30 m t m m m m * - m h mamoota m m m m s 1.2658 09004-173 30 10003-217 30 <' * tSZ` * tu.-. m-*. * 1.3200 son -.rm.-am n w 09004-173 30 10003-217 30 1.6667 srv> ?-<>m hmkk 09004-173 30 10003-217 . 30 mmmmt 1.4266 *7\ 14 4M HMMail 09004-173 30 10003-217 30 mi.*''**-*'..Mri:4V> 1.3072 asrasiiapsH hhhwbi 09004-173 30 10003-217 30 IP ^ f t 1.2135 09004-173 30 10003-217 30 )k'- 1.1052 MHKR 09004-173 30 10003-217 30 S3BCMI -IMkbiVJk 0.9770 amramm-nm *** 09004-173 30 10003-217 30 MM A IBM..TP 1.3540 ISM^MMiSvJIHia'' 09004-173 30 10003-217 30 NEf-HH **> .'-h 'K H B 1.0577 r-- M 'llii! 09004-173 30 10003-217 30 FM&mm K .`3FEHHB' x m* it.m 0.9166 iW. . it 09004-173 30 10003-217 30 Rtwi. MM f*'Mkft UHU iu y W ii 11..42208010 ^ f V . >J-- 7.MW 09004-173 am H aw s: - m m 09004-173 30 10003-217 30 30 10003-217 30 3UMmnm mc.m m m v. -aV- v-.-i-.iSan? 0.7298 rmm TMITTMT' 09004-173 30 10003-217 30 vs-'vMnra 1.3845 m m m s K 09004-173 30 10003-217 30 .a. 0.8510 `^sb'-h i hhh i 09004-173 30 10003-217 30 .iw&'-r*. m ; *'x 1.2892 : a / w m m m m m m 09004-173 30 10003-217 30 /iW ft M 1Ti* -.'i f t . * * *s 1.3253 0.9353 -t imam *#* Hi mcakmam KHMHI k k SiS 09004-173 09004-173 30 30 10003-217 10003-217 30 '3*- JM li -Ui*-..* 30 MMS.MS'MV-'M OrtHfcrrWflfrW i 1.2071 ;- H* K I H I 09004-173 30 10003-217 30 MH'-!MH.1ax v. r; -e 0.9749 i *1Mfc iI PmIMT M M M 09004-173 30 10003-217 30 MM MM .Jfe*Mb'MM >?>--w* 1.6303 MMMMI 09004-173 30 10003-217 30 1.8162 M M M H B M^MMI 09004-173 30 10003-217 30 M S I 1.2598 0.9835 M M M M fii IBMS^K 09004-173 p r *- w a a m e s f 09004-173 30 30 10003-217 10003-217 30 30 :w : m*,;t, J V' --imwxs KXiMliaMf 1.1816 M s m m m m m m & x 09004-173 1.6807 'e- w h i 09004-173 30 30 10003-217 10003-217 30 30 wsa:smh am-..-**,- at> ..:u ~-'. * ,-> 1.4875 . z. -ae ; 09004-173 mKKtosKmKKmSmmm 1.0289 1.3355 '*.jsk*-l.vwv ; * nehesusm* 09004-173 09004-173 30 30 30 10003-217 10003-217 10003-217 30 30 BMKWi^ a;. 30 lHirniTfMTM--1im ii msmmmm. 0.9734 fUTMMr'ii'lililW' P W i 09004-173 30 10003-217 30 mamssmam 1.6819 09004-173 saamsasssmim 1.9399 m m m m m m m m m m m m 09004-173 30 30 10003-217 10003-217 30 30 tfdHVHKHHKV1?kBaMBGSKMHnUwHvM3RMOfn*CrMmtI 1.1241 .-t-virs#**; y **,v 09004-173 30 10003-217 30 M B I& I MMMM HMMMS sarassaa 1.1913 >*'.*.MM#'tii L*r-- Sto 09004-173 *B8Msia 0.9464 09004-173 s**..x .;< 1.6996 . *m~ '-xt.'L.m w a m n 09004-173 30 30 30 10003-217 10003-217 10003-217 30 30 30 mMMmHNvH mil--mMEmIHramqMWmmS9sHHrHnHHmHHn|H tmmsmum sa^aaiSisH B f new asi 1.4762 1.1435 K H K flBMKBUS! 09004-173 i n H i 09004-173 30 30 10003-217 10003-217 30 30 m m m m o h h b ass$$i ^h hh S B a a i H m . m m m m 1.1599 09004-173 30 10003-217 30 9hhhset marnami msmamm Kara*Hm mmmamm mmmmm mmmmni 1.0476 1.5518 1.5498 M M M M M im MBB 09004-173 'iiin'iT'i'iTH'naai ssssshbsi 09004-173 09004-173 1.3319 1.4154 SBBB88M'BBMJBLMWE1I ' - 09004-173 09004-173 30 30 30 30 30 10003-217 10003-217 10003-217 10003-217 10003-217 30 O B H i m i r a i S 30 MMM3M MM^SES 3300 W M H H H mmmmam W HHSHHH """ IHH' 30 iiimehh rnmmm a m m a a m m e m m m 1.5505 B B 09004-173 30 10003-217 30 B i 1 m smtmaxe Page 2 of 3 GLP1O-01-0 1 -05 ETS-8-053 Sample ID 1 GLP10-01-01-05-091 GLP10-01-01-05-092 GLP10-01-01-05-093 GLP10-01-01-05-094 GLP10-01-01-05-095 GLP10-01-01-05-096 GLP10-01-01-05-097 GLP10-01-01-05-098 GLP10-01-01-05-099 GLP1001-01-05-101 GLP10O1O105-102 GLP10O1O105-103 GLP10O1O105-104 GLP10O1O10 5 -1 0 5 G LP10010105-106 GLP1001O105-107 GLP10O1O10 5 -1 0 8 GLP10 0 1 0 1 0 5 -1 0 9 G L P 100 10105 -11 1 G L P 10 0 1 0 1 0 5 -1 1 2 GLP10 0 1 0 1 0 5 -1 1 3 GLP10 0 1 0 1 0 5 -1 1 4 GLP10 0 1 0 1 0 5 -1 1 5 GLP10 0 1 0 1 0 5 -1 1 6 GLP10 0 1 0 1 0 5 *1 1 7 GLP10 0 1 0 1 0 5 -1 1 8 G L P 100 10105 -11 9 Col 3 & 4: Balance ID: 900 Col 5 & 6: Pipette ID: 4215537 Sample Description 2 DAL SS GP07 0 0000 DAL SS GP07 0 0005 DAL SSGP07 0 0020 DAL SS GP07 0 0130 DAL SSGP08 0 0000 DAL SSGP08 0 0005 DALSSGP08 DB 0005 DAL SS GP08 0 0020 DAL SS GP6 0 0050 DAL SS GP09 0 0000 DAL SS GP09 0 0005 DAL SSGP09DB 0005 DAL SSGP09 0 0020 DAL SSGP09 00050 DAL SSGP10 0 0000 DAL SS GP1 0 0005 DAL SSGP10 0 0020 DAL SS GP10 0 0060 DAL SS GP11 0 0000 DAL SSGP11 0 0005 DAL SS GP11 0 0020 DAL SS GP11 0 0065 DALSSGP11 DB 0065 DAL SSGP12 0 0000 DAL SS GP12 0 0005 DAL SSGP12 0 0020 DAL SS GP120 0170 Soil Maxtrtx Soli Weight ID Used (g) Spike ID Spike Volume (uL) Internal Internal StandardV Standard ID ottime (uL) Surrogate Spike ID Surrogate Spike Volume (uL) Add 8 mL . Extraction Solvent . .. n. 6 Centrifuge 34 5 6 7 8 9 10 11 12 13 om m m m 1.3775 a s r - i ! R ' - M . ! i a ' 1 % 09 004-173 30 10 003-217 30 WS mzszsmm* 1.4943 B68BBMK9I9MSHKH tr 44Ki 09 004-173 30 10 003-217 30 m m s a m t s a ' . : WttfM1.0292 m -- -- f i i * i . 5 W 09 004-173 30 10 003-217 30 f l H M i S , * -v Tb'l'r maamm m1.0736 I H M M e t kI' 09 004-173 30 10 003-217 30 sm k mum* v r -* 1.1834 n - - * * ? - .......... 09 004-173 30 10 003-217 30 AS}'. ? * ' *1`l m m -' 1.5616 5T i n ' . . 09 004-173 30 10 003-217 30 r *- m *? 1 * mmsam1.0702 ' M J.N } 09 004-173 30 10 003-217 30 * ** - *.* 1.1992 ; n * * - ' l *. * e 09 004-173 30 10 003-217 30 U M H i m m 1.1408 ' & . B B -- i 09 004-173 30 10 003-217 30 m m m1.2337 s 09 004-173 30 10 003-217 30 B s a s M i m s 1.2441 iAneBgj S H M S H 09 004-173 30 10003-217 30 m a i M i B M n fCT-Cj .K`0k1.0558 .... ; H U H 1 09 004-173 30 10003-217 30 N H B C M i S E n -m M H M 3 S 1.3573 -.--.r - 09 004-173 30 10 003-217 30 s a b -j b b s r r j - ' C r > 1.1493 1.2765 T. > as.-w w aoemoem Wtsam09 004-173 30 10003-217 30 09 004-173 30 10003-217 30 a o K garaeesfe m -vtar- m.-rn musom1.0924 1.1045 1.2671 09 004-173 30 10003-217 30 M B II-- B -- i l 8*518 09 004-173 30 10003-217 30 B 9 i BK aBB E# H M m . 09 004-173 30 10 003-217 30 B B B B M B H M 1.1741 B W ' i . 09 004-173 30 10 003-217 30 B m ^ S b b s <w 1.0671 -- E. f* 09 004-173 30 10 003-217 30 B B S i > i -S ?: ' 4 M ' '* ^ * r; 1.0533 m i -- n r i r a v s a a s t # 09 004-173 30 10 003-217 30 i s s a s i s a s s 5 smaa^mmEmmamsm* .-`Mr' 1.0158 09 004-173 30 10 003-217 30 a m b s s t -- mM&msmsmmm-iawmm1.0658 09 004-173 30 10 003-217 30 B B B B M H B ~J Z' manosai/T 5 1.0137 r w v - i n F * r -- e * 09 004-173 30 10 003-217 30 n a n BM m T 1.0120 1.0709 .-sr: mama-JE f l -- T109 004-173 30 10 003-217 30 -- W * * - . M B 9 004-173 30 10 003-217 30 IB -- . - s ; ' 'W l.' > : S 8 S M B F5S B 1.0103 9 004-173 30 10 003-217 30 n e s s i a i it 8/31/2010 nrmh GLP10-01-01-05-070 to 119 9/1/10 mrrh Col 7 & 8: Pipette 10:4215537 91/10 mmh Col 9 & 10: Pipette ID: 4215537 91/10 mmh Pipette ID: 3824414 Col 11: Col 12: Col 13: Col 14: Comments 14 K S tudy. G L P 1 0 0 U O 2 . Interim R eport 05 Page 3.of 3 . 6L P 10-01-01-04 ETS-8-053 Samples Extracted 29-Jul-2010 Sample ID Sample Description 1 EC-100831-01 EC-100831-02 EC-100831-03 EC-100831-04 EC-100831-05 EC-100831-06 EC-100831-07 EC-100831-08 EC-100831-09 EC-100831-10 EC-100831-11 EC-100831-12 MB-100831-01 MB-100831-02 MB-100831-03 MB-100831-04 MB-100831-05 MB-100831-06 LCS-100831-01 LCS-100831-02 LCS-100831-03 LCS-100831-04 LCS-100831-05 LCS-100831-06 GLP10-01-01-05-001 GLP10-01-01 -05-4)02 GLP10-01*01-05-003 GLP10-01-01-05-004 GLP10-01-01-05-005 GLP10-01-01-05-006 GLP10-01*01-05-007 GLP10-01-01-05009 GLP10-01-01-05-010 GLP10-01-01-05-011 GLP10-01-01-05-012 GLP10-01-01-05-013 GLP10-01-01-05-014 GLP10O1O105-015 GLP10-01-01-05-016 GLP10-01-01-05017 GLP10 0 1 0 1-05018 GLP10 0 1 0 1 0 5 0 1 9 GLP10 0 1 0 1 0 5 0 2 1 GLP10 0 1 0 1 0 5 0 2 2 GLP10 0 1 0 1-05023 GLP10 0 1 0 1 0 5 0 2 4 GLP10O101050 2 5 GLP1001 0105-026 GLP10O1O10 5 0 2 7 G L P 100 101-0502 8 GLP10O1010 50 29 GLP10O10 1 0 5 0 3 0 G LP 10-010105031 G LP10010105-032 GLP10O10 1 0 5 0 3 3 2 0.2 ng Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 ng Extracted Curve Point 1 ng Extracted Curve Point 2.5 ng Extracted Curve Point 5 ng Extracted Curve Point 10 ng Extracted Curve Point 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 na Extracted Curve Point 200 ng Extracted Curve Point 500 ng Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 DALSDTRIP1 0100624 DAL SD SD01 0 0000 DAL SD SD01 0 0005 DAL SDSD02 00000 DAL SDSD02 0 0005 DAL SD SD03 0 0000 DALSD SD03 0 0005 DAL SD SD04 0 0000 DAL SD SD04 0 0005 DAL SD SD05 0 0000 DALSD SD05 00005 DALSD SD06 0 0000 DALSD SD0600005 DAL SD SD07 0 0000 DALSD S007 0 0005 DAL SD SD08 0 0000 DALSDSD08DB 0000 DALSD SD08 0 0005 DALSD SD09 0 0000 DALSD SD09 0 0005 DAL SD SD 10 0 0000 DAL SD SD 10 0 0005 DALSD SD11 00000 DALSD SD 110 0005 DAL SD SD 120 0000 DAL SD SD12DBOOOO DAL SD SD12 0 0005 DALSD S D 130 0000 DALSD S D 130 0005 DAL SD SD14 0 0000 DAL SD SD14 0 0005 ficrj cf Cn;!::i ' | 1-n|ef[m 'R e ort'p 5=' Soil Maxtrfx Soil Weight ID Used (Q) Spike ID Spike Volume (uL) Internal Internal StandardV Surrogate Standard ID Spike ID olume (uL) Surrogate Spike Volume (uL) AddBmL Sonicate 1 Extraction hr Solvent Centrifuge Comments 3 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 10 003-238 .**j*i-. - mwmm wmmmmmmmtsmammmm& itvR & M IB H i a r-w r fS H @ w ra e ,w -- u n m ass as B O BR BSijSam h beb stss B H 9S l a r a i bsk nnn IM S K 3 E nB S B H B 4 1.1383 1.1550 1.1297 1.1258 1.0776 1.0968 1.0946 1.1772 1.1080 1.1115 1.1120 1.1064 1.1401 1.1230 1.1088 1.1285 1.1270 1.1288 1.0965 1.1281 1.1281 1.1253 1.0829 1.1442 1.0868 1.4575 1.6477 1.3921 1.8422 1.8003 1.5896 1.7681 1.9192 2.0981 2.3719 1.8051 2.4128 1.8941 1.6432 1.8240 1.5876 2.1718 2.0053 1.6580 1.2246 2.0841 2.1081 1.3349 1.7775 1.7962 2.8711 2.5859 2.3395 1.8981 1.8783 mmssm w-v-Ahat5 6 7 8 i * W tv ,-zn * M B m m p * ; QMGBSHS^ JBf'Vt'L. W a! ? I 9 10 K l> d & MS *M M M E j M R atfUSf:i.11 12 13 imbues SSsiSI?vrtRP-- 5 r w r ' * : fS-fXKifi i * ! s .'s ra s p ^ - jf.ia w r . . i w , 14 : i 1 ferNMTjH E - - a v 33 P . T M ' J K " ! 9 '4 " <: > 3 r l M %* ' * -# jK -a '.u: "5 i% A '- .-..S S H ia *. ' 9 . v * r * M .. i n V w . *9 ? ms'sty-am&eHs&m-'tmixm-i mi-Msm&f&samm ms&Mmrm * * -i - i . * * B M M |w R 8M lfra& S JK l M rw a M r T '' M :" M BB M W . /. "H P * M i 9ssaaBa Ti a n a a w ff is ii; K JK m c .; - ta a s M * a v K a 9 b * "-V - : s S r s tifr '; iiS" j .U S * *t 1- .... --a M 3Uqo.T i M .m b E .7 - 499 . 'c & g g & Z a > * ; wmvmmtasmm &$&sam sszvwm wxmm;-RRMHBS|BRJRM3HI ass* H i BB O IK S I KKi B S E tmgsssgsmmKm wmamet mmb&ert am-USMEBK n mmmmi^ V M M I M M ; t O H w t - s a w HRHMR n m m an i . 4' . * # - ; f-SBtaal MTL a f-C ilt- a **r. * * - jin 's ' ' * r - v -2 'T ' . . r .g a c a i O S i-*- ; :j s u a i * " -**"* s: m -am mw a r f t d s s * 1 & M T M o m a& sm iS M S M S S immmxmana& SEED'S*; imammmmmi p ^a sp '-- tmsmmmmmm wmv*r.r; 1 R .. i i i - t r h k m :- ' t - i *ssl : a -- a . : a E S irls y -J H c j a a -- nn 'I'r r E^M.SSP * M M M M 3 k m i o r /r ^ v ) v. M Q W N 3 M M K t i r - : , '4! ^ wKsm^S fS M H H B IB S H R i ;&*>. mm . O tM N M - m a s tic f c . - -- K M * * r * v : '& Z 9 ? * ' * f 9 ju r u M i1 * . - 9M *v - . f !T ' -- - 1 *L M ' / '--!" E .. . W S'-Xi'-* V t-vm sm M K I W r j stsuifsmtmxmn wismit- a s m a M K I stv9h8IIIE3 H M ia iiiT ; M *C *i tF J 3i:JIRS *> m M f;-a 's w a - T ' ---a e ra w aters rocks aS E s m g m m w s s m K m m m w a H 'j'- n ** M M f 4 K ? 'H B M W r . i* ^ a s fa a ' r s i n ? ` a i fm s m s m m is s m 'A W f e .r : r v , ' m - ' v s w r .* a .y x z ite i t t v r . i M I J M r - w S - '. r . a J * * w a s *? . i' * ah: a m i m f, . *: k & *< m - <MM i 4 !a i 4 5 ^ .: :L t6 5 * IH H K I -- M B sva u ca x MMMMMMMM w mm j j n w t j n '. e s w ^ .' r >9~i EC ci-!,? .; n asm a..w m IS X B R S f K X J S iM i ? ^.r-V dfc sn&v r 1-a a r tm p s fa a r s ig v iw a a W .-- i T U K M m i : : s s saaaaK aM iB g dav wmsssam B M K S s S B ;tiSStiiBSSW Thin milk shake" g ira r*! p. W - '. - r EaraHJ-.i i i - i S S S MEfeSsSE ' clay ? ..u v :.' SHKSBSi ra n a g e HEE**V ;j> ' ' a w * ; . ". * M R BSMr-r?. : i a n IK '- V r . T i l l " ^ i asasn ffiM H E S 3.';:*-* ? M r i ri^ 3 M e K M M K S U f i i l l water & grass msmsmmn M M B >S?t- iiH R S ra m -s s r-m s t m K .-K ii: asaM ^E tfM M M B M R M S B * F K S >,, ...-saaKi t e r s a jt H H f HMNMRK M S M R ^ iM B S S I B C B Pace 1 of 3 GLP10-01-01 04 ETS-8-053 Sam ples Extracted 2 9 -JuI-2010 SampleID SampleDescription 1 GLP10-01-01-05-034 GLP10-01-01-05-035 GLP10-01-01-05-038 GLP10-01-01-05-037 GLP10-01-01-05-038 GLP10-01-01-05-039 GLP10-01-01-05-040 GLP10-01-01-05-041 6LP10-01-01-05-042 GGLLPP1100--0011--D011--0055--004443 GLP10-01-01-05-045 GLP10-01-01-05-046 GLP10-01-01-05-047 GLP10-01-01-05-048 GLP10-01-01-05-049 GGLLPP1100--0011--0011--0055--005510 GLP10-01-01-05-052 GLP10-01-01-05-054 GLP10-01-01-05-055GLP10-01-01-05-056 GLP10-01-01-05-057 GLP10-01-01-05-058 GLP10-01-01-05-059 GLP10-01-01-05-060 GLP10-01-01-05-061 GLP10-01-01-05-062 GLP10-01-01-05-063 GLP10-01-01-05-064 GLP10-01-01-05-065 GLP10-01-01-05-066 GLP10-01-01-05-067 GLP10-01-01-05-068 GLP10-01-01-05-069 GLP10-01-01-05-070 GLP10-01-01-05-071 GLP10-01-01-05-072 GLP10-01-01-05-073 GLP10-01-01-05-074 GLP10-01-01-05-075 GLP10-01-01-05-076 GLP10-01-01-05-077 GLP10-01-01-05-078 GLP104)1-01-05-079 GGLLPP1100--0011--0011--0055--008810 GLP10-01-01-05-082 GLP10-01-01-05-083 GLP10-Q1-01-05-084 GLP10-01-01-05-085 GGLLPP1100--0011--0011--0055--008878 GLP10-01-01-05-089 GLP10-01-01-05-090 DALSDSD15000200 DALSDSD1500005 DALSOSD1600000 DALSDSO16DB0000 DALSDSD1600005 DALSDSD1700000 DALSDSD17000S DALSSSS0100000 DALSSSS0100005 DALSSSS0200000 DALSSSS0200005 DALSSSS0300000 DALSSSS0300005 DDAALLSSSSSSSS0034D0B00000005 DALSSSS0400005 DALSSTRIP100000 DALSSSS0500000 DALSSSS0500005 DDAALLSSSSSSSS00660000000005 DALSSSS06DB0005 DDAALLSSSSSSSS00770000000005 DALSSSS0800000 DDAALLSSSSSSSS00880DB00000500 DALSSSS0900000 DALSSSS0900005 DALSSGP0100000 DALSSGP0100005 DALSSGP0100020 DALSSGP0100060 DALSSGP0200000 DALSSGP0200005 DALSSGP0200020 DALSSGP02DB0020 DALSSGP0200120 DALSSGP0300000 DALSSGP0300005 DALSSGPQ300020 ODAALLSSSSGGPP00330DB00050020 DALSSGP0400000 DALSSGP0400005 DALSSGP0400020 DALSSGP0400050 DALSSGPOS00000 DALSSGP0500005 DALSSGP0500020 DALSSGP0500055 DDAALLSSSSGGPP00660000000005 DAL SS GP06 0 0020 DAL SS GP06 0 0110 Esstey ci C::-;.': * ln i n le rim RePe.ctP5 SoilMaxtrlx SoliWeight s,,ik,,iD ID Used(g) S- telD vt?,TM ~ Stlanntedrnaarld*" Surrogate Spike** Spike Volun* Sonicate1 hr Comments 3 4 5 6 7 8 9 10 11 12 13 14 R N K B i 1.8443 BeSHEZvyx, >vr- - * esc at ?j w -c- . , * w m . i -.r s u i-- H mm&mm iir a i 11..94639169 m-- m m a> >-= a w v r' n *-.-- lar-aH, 1 ^ m m m m day n..s-*ss n n n k - > K ; r:\i-v *. *.* ***."- davw/prass B a t s 1.5784 -*v>i *7 xnis* 'nr.w day -- lira 1.3628 areaaiasBEM -- m m -- a w a-- m y a a a at - - * ; ~w '-r. - 8K *s a 1.7467 m m m m m m M m m m m m -- m m m m m m w t . - aiagj.r.-e > r c >: - -- iw wp&xsm. 1.1280 1.1180 w m m e a s m B m mrrnrnm m a m m m m b -- mm.'.****m m * ^ s-r-"Av?...v. *'r.f w a r n n n i kssbsb --Mis;' 2.0737 m m s m m m m s ffl-- E i-- b k bb-- Btsaai -- s -*> t: * c* * *> *`4--.-a.-* 1.2658 SU* R.'>'!* IBPf**----JO"M'-V.** iB '.iV 'S r - -.''1 -.W CSi 1.3200 -tW B B B . f'-B R I V i a X '' !T| rV .W ti.4SSCut'K K IIW . .> ' rr v i S 1.6667 in r.* - a * * - --g>---- - 1 mss 1.4266 KCi'& l C M . 4B . v- - 1.3072 m m m m w m m & m msm-sm m m m m m m m m m m m m m m m m --w-.- smsmsmm 11..12015325 mw >'mravi w m m m m m m m m h h b sI h ISS m b ssmsm. t M u a m m u x m tm n m m m m m m m m m m -- w m m m m m m m amam&u mmmmm Bn-- n bkbb 0.9770 11..30554707 b m b h b i a--sbss m m m m m m m m m m m m m m m s a m m m m m m me k w -- B iB M B s n iB R s n B e in a iin M iB K -- m -- smxzam m m m m msmmmi m s msmsmm m s wmsmsm mmtmmm m m m m m 0.9166 m m m s s m m m a m sK sm b b b i b k b s tsmmtssi m m m m m m s m a m m m m m a mmeamxm mmmmmm mmmmmm 14201 1.2000 0.729a aw----hbb gaasu m m m m m -- a m m m m m b b h m p ik w m m m m m m m m m m m m b k b rmammem -- b-- m m m m mmmm1 m a mm m m 1mbmbm--skmoso he-tm -- :am mmmm mmmmmmmmm -- ---- m a m m tmmtsm m m m m m 1.3345 h -- k i -- m h -- a s m I n w m m m m m m m m wwsmemm m m m m m o.ssio w o s w m m m m m m m m m m m m m m m m m s m m m m s m m m m m t m m m m m m m m am m m m w'i*aifsas 11..32285932 m b EKaakuuwa awb t o m -- cate-- -- a-- i-- sb-- io-- rwi'B-- i n m mmmm n -- Mmmsm. m m m m z m m s m mmstsms: rm -- m m m1 012.9037513 wbomM e-- i a-- am-- 1kb-- 1E H w e K i n n r a e s H B i t -- -- t s iB M -- -- MMiaEBim b anasai rf-- wrtr sB^aaa-- -- eb-- i B U B l 0.9749 f M -- M -- H -- --n w r-- 1.6303 -- m m m o a m m m w m s m m m 1-- s , siSEM m m a m m m m s m m m m m m -- ii-- wi mmmmm 11.^8519682 mmmmmmmm mmmmm -- w wlyinmnnn im w it iMmiin a1sisrri^wKt~svnr-nsisieirsr&..m..m. s m . ii mMmin& s1 wm m ibbo-- itt i---- iii -- nwr i am -- 01..913B3165 --H i-- -- B B O H M B I-- EH-- n o n H ^ -- I S -- i n s ^ s n s s 'irq'Tinimi "in-- Birri-- -- -- B 3B M i B a a B i i mmssmsi m m s m m m s s m a m m m m m m m m wsmmmm tssmmm -- -- iw ssssas m m m m m m wsmomm mmmmmmmmems m s m m msmmrm m m s m -- r -- rm-- wi B i r o w m m s m , 'm m m m f m B m s m m i m m m m m ^ ^ m i g m m m m s g m m w m i g m m & . m s m B m w i i m m m a m a m m m w m i m m m m m m m s m Bi-- m m m m m m ms-- -- -- a sams&m m m m m m m m m mmssrn -- bm -- m m m m m m mmmmm -- i --h -- skb-- ia-- tsmmmm mb-- msszsm m m m m g w a -- -- a--m is m a m m a -- a -- a b tib o 'i wi--am sssaaot w m m m m w m s m m i g-- ftBaOil^m^ffTWWmBHiHfeliiiiBWIIIBiaH--BBBM--BBB------a-- BBaWBESSai USSeS m m m -- a m m m m m m m s m m m m m m m m m mmmmm mm m m m m m m m m m m m m ' m m m m m m m m s m m S m -- m o m m m m m mammesm, m m m m m m m m m messm?. % s m a m m m m m .*iso*ai m a m m mammam m s m m w m m m m m bm-- b--gwm mmmmsimigi m m s m m w m m &smims m m s c m m m m a ssmmmisn m m m m simmsm- mtasgamwwiaB--eKmeoaHmhE--mMwmws--tmeeSaimHsaKimwSds--ffiawMusjiSKScfsfsTSO--igS'eWMSBBMBeiBaweimB--mmis~Mwncml-r~simni~K-wmsswwmxraaf.mirsMam.iJmowwm^wm?j.a3sWmskf.awjaiim.w--mmptmtb!sBsssmaosssm*--smssgmsabscm--obbm----mmobolss;smswmsmssisssks&sa--i&sm--m--mBB--m--Mmpa3, -- wi a-- bb wea&sm m m m m m w m a m m m m m m m m a m m m m s m iaa-- m m m m m m mmsmmssm s m t i m m s&ts&m smmmsi m m m & s msmmtm m m m m m m m m m m m m b-- tm rs m a m m mmmmmmmmsam mssaam tmmmmu w a m e m m s & m m --bban -- b -- imsmsa m m m m a mmsseegm m s s a m m m t m M m m m m m m m m m m m m m o m b h -- sm m m i m m m w m n s m s s m m m sa--earnsm m m m m m m m mamsmm m m m -- rasssasssgma--s m m m m m -- ra iiiw n m w t u m m m m m n w tnmior k skew s m m s a m wsmmii m m m m m m a m m m m m m m m m m m m m w m m m m 'emsmmmS'Mm Ms&g&sm w m m s m m m m s w&s&aa>'m m m m i -- r -- a -- -- -- i Page 2 of 3 Page 516 GLP10-01-01-04 ETS-8-053 Samples Extracted 29-JuI-2010 Sample ID Sample Description 1 GLP10-01-01-05-091 GLP10-01-01-05-092 GLP10-01-01-05-093 GLP10-01-01-05-094 GLP10-01-01-05-095 GLP10-01-01-05-096 GLP10-01-01-05-097 GLP10-01*01-05-098 GLP10-01-01-05-099 GLP10-01-01-05-101 GLP10-01-01-05-102 GLP10-01 -01 -05-103 GLP10-01-01-05-104 GLP10-01-01-05-105 GLP10-O1-01-05-106 GLP10-01-01-05*107 GLP10-01-01-05-108 GLP10-01-01-05-109 GLP10-01-01-05-111 GLP10-01-01-05-112 GLP10-01-01-05-113 GLP10-01-01-05-114 GLP10-01-01-05-115 GLP10-01-01-05-116 GLP10-01-01-05-117 GLP10-01-01-05-118 GLP10-01-01-05-119 Col 3 & 4: Balance ID: 900 Col 5 & 6: 2 DAL SS GP07 0 0000 DAL SS GP07 0 0005 DAL SS GP07 0 0020 DAL SS GP07 0 0130 DAL SS GP08 0 0000 DAL SS GP08 0 0005 DALSSGP08 DB 0005 DAL SS GP08 0 0020 DAL SS GP08 0 0050 DAL SS GP09 0 0000 DAL SS GP09 0 0005 DAL SS GP09 DB 0005 DAL SS GP09 0 0020 DAL SS GP09 0 0050 DAL SS GP10 0 0000 DAL SS GP10 0 0005 DAL SS GP10 0 0020 DAL SS GP10 0 0060 DAL SS GP11 0 0000 DAL SS GP11 0 0005 DAL SS GP11 0 0020 DAL SS GP11 0 0065 DAL SS GP11 DB 0065 DAL SS GP12 0 0000 DAL SS GP12 0 0005 DAL SS GP12 0 0020 DAL SS GP12 0 0170 Soil Maxtrlx Soil Weight IO Used (g) c .it.in Sp,kelD Spike Volume (uL) Internai Internai Standard ID StandardV olume (uL) Surrogate Spike ID Surrogate Spike wVoltane Add 8 mL Sonicate 1 Extraction Solvent hr Centrifuge 34 5 6 7 8 9 10 11 12 13 M-3J V I S mimmi-- `,, . I S K M d t S M K ^ I V M M B m m ern. n w E tS S W K I la s s r E t - T I * ! * * ' % * ' /'- V T O fw r i: .,,..e fP ' B i .a m m ism mpr<*y:: 1 jx-m s s-mstam ffis s is a SSSStS! * *' : - < ' mattarne.i- ? ?s ih m e !.'> R5s*Stf& i i i f t l M B Bsssgms b b b ^ {' 'US -i +8 mtm&m f'J " M *V*?T*V2 I V M C . ~ . mmssssi u n : '; :^ U T illiS a n ' . T i - / ; / B O M E f t M B " ti m m m sm wasm tm xi<ag#amm -a sa a s B H SI B a i xmaa&m H H ui l K i ' 7?T5iT*i M K Bi wms&m: msm&gim. mmmm */>* mmimm I M M mmznw. `tWU4*. n>,P5m& mmmm mamma S* ts& sam tmssmm m m m ss ISi: -. b e v b j u e l "- t i a a a v s i'.-. *-f *"< 1' V'(*?'* C i -:* A i .K V t-: '** M E 'IF * : <V . : M W " W M g&SM&Pl msm&m KSesRE inaBBsmss M M 3 w 5L13)KI K S i S ^ E m <>r * k & w * - : a * ..m e * mmm m m m m * L*1^*: ' &SS&S9 * m i a .K M i S O B ssse.i!"tK EW ^ s BKHXM I muissmfrr- M issm m w h h b b h B M M M sa ( M B K 'JC E .k .-."T-vn-s: " S S SK *JK S -, * < 8 - M B I H IP.T?- i^z&s b b *#*ifc '.1* ^ V m b b SSS5BVM ; - ; a p - M .-A. .r rJhfi a -.- .- Y r,. M I f f & T ' i a-'." p 4 # .S 1 . b b b e L ^ rl98B B RM B VfSWnUm mM G flB R S H t -VA .'M H iiil-- :* ^"ar 4: r n mmmmmmmM immmsssmmaBm T . - - ' V W ,- -rxm o t !i':;.!!v i VEaraaM aaM i a o B m *xm * 1 m m m m rxsne; I V M V B i Si W O E S M lsejszaxxmamm -Ktmmmmsmta a -- -- mmimmsmmm m -'ss*-.- H .'V O E l ** ` :in i * * ',2e jcsm v B H M M w n mi. IS S W V E 3 f- BS B f f i U i S 5 - p SSKSdsSS** M I Col 7 & 8: C o lli: COM3: Col 9 & 10: Col 12: CoM4: Comments 14 L '/ DAVEY:Quattro Ultima: #9261QB DATE: 09-08-10 STUDY: GLP10-01-0T-05 ANALYSTmmh '^ U Mobile Phase: (A-) 2 mM ammonium acetate (B) Acetonitrile TN-A- or standard number(A) 10005-78______________(B) TN-08-0289 2/4 Guard column (pre-autosampler) : Prism RP Size: 2.1mm X 50 mm__________ Type: NA Sphere size:_____ 5______ Part number: 32105-052130 :Lot number: 9411 Serial number: 0195559V On-line SPE cartidge: waters HLB Size: 3.0mm X 20 mm__________ Type: HLB Sphere size:_____ 25 um Part number: 186002039 :Lot number: NA Serial number: 006A36131107 02 Analytical column: Betasil C18 Size: 2.1mm X 100 mm_________ Type: C18 Sphere size: 5______ V Part number: 70305-102130 :Lot number: 8606 Serial number: 1273481L PAGE 1 of 1 Printed: Wednesday, September 08, 2010 4:08 PM /-/& V / 3M Study GLP10-01-02 Interim Report 05 Tuning Method Report Method: D:\MASSLYNX\DAVEY2010.PRO\ACQUDB\PFOS Printed: Wed Sep 08 16:03:51 2010 Page 1 MS MS SOURCE ( ESP- ) Capillary Cone Hexapole 1 Aperture 1 Hexapole 2 Source Block Temp. Desolvation Temp. Pressures Analyser Vacuum Gas Cell MS MS Set 2.97 60 0.0 0.0 0.0 150 250 Rdbk -2.89 -60 148 249 Rdbk OFF 2.7e-3 Analyser LM Res 1 HM Res 1 IEnergy 1 Entrance Collision Exit LM Res 2 HM Res 2 IEnergy 2 Multiplier Gas Flows Cone Gas Desolvation Set Rdbk 15.0 15.0 0.5 0 41 2 15.0 12.0 0.5 650 45 44 46 -651 Rdbk 324.1 729.3 3M Study GLP10-01-02 Interim Report 05 Page 519 Scanning Method Report Method: D :\MASSLYNX\DAVEY2 010.PRO\ACQUDB\17MIN-PFBS-PFHS-PFOS Last Modified: Fri Sep 03 lli56:55 2010 Printed: Wed Sep 08 16:04:48 2010 Solvent Delay ( mins ) : 0.00 Function : 1 MRM of 2 Mass Pairs 1! ESP- :) Inter Channel Delay i[ Secs ) : Span ( Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V 1 299.00 80.00 0.25 2 299.00 99.00 0.25 45 45 60 60 Function : 2 MRM of 2 Mass Pairs 1I ESP- ) Inter Channel Delay i{ Secs ) : Span ( Daltons ) : Start Time < Mins ) : End Time { Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V 1 399.00 80.00 0.25 2 399.00 99.00 0.25 45 45 60 60 Function : 3 MRM of 2 Mass Pairs 1I ESP- ) Inter Channel Delay i[ Secs ) : Span { Daltons ) : Start Time { Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V 1 499.00 80.00 0.25 2 499.00 99.00 0.2S 45 45 60 60 Function : 4 MRM of 1 Mass Pair ( ESP- ) Inter Channel Delay 1[ Secs ) : Span ( Daltons ) : Start Time { Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy <eV) Cone ( V 1 S03.00 80.00 0.20 45 60 Function : 5 MRM of 1 Mass Pair ( ESP- ) Inter Channel Delay i( Secs ) : Span { Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone 1( V 1 403.00 84.00 0.20 45 60 Function : 6 MRM of 1 Mass Pair ( ESP- ) Inter Channel Delay i[ Secs ) : Span ( Daltons ) : Start Time ( Mins ) End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V 1 303.00 84.00 0.20 45 60 Function : 7 MRM of 1 Mass Pair ( ESP- ) Inter Channel Delay \[ Secs ) : Span ( Daltons ) : Start Time ( Mins ) : End Time { Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V 1 507.00 80.00 0.20 45 60 3M Study GLP10-01-02 Interim Report 05 Page 1 Page 5 2 0 o f Method Report Method File: Last Modified: Printed: Page 1 D:\masslynx\DAVEY2010.PRO\ACQUDB\17min prism-C18 W ednesday, Septem ber 08,2010 16:03:51 W ednesday, Septem ber 08, 2010 16:05:16 HP1100 LC Pump Initial Conditions Solvents A% B% C% D% 90.0 10.0 0.0 0.0 Valve A set to channel Valve B set to channel Flow (ml/min) Stop Time (mins) Min Pressure (bar) Max Pressure (bar) . Oven Temperature Left(C) Oven Temperature R ightfC ) 0.300 17.0 0 400 30.0 30.0 HP1100 LC Pump Gradient Timetable The gradient Timetable contains 6 entries which are : Time A% B% C% D% 0.00 90.0 10.0 0.0 0.0 1.00 90.0 10.0 0.0 0.0 11.00 10.0 90.0 0.0 0.0 13.50 10.0 90.0 0.0 0.0 14.00 90.0 10.0 0.0 0.0 17.00 90.0 10.0 0.0 0.0 Flow 0.300 0.300 0.300 0.300 0.300 0.300 Pressure 400 400 400 400 400 400 HP1100 LC Pump External Event Timetable The Timetable contains 3 entries which are : Time Initial 0.00 0.10 Column Switch Off Off Off On Off Off Contactl Off On Off Contact2 Off Off Off Contact3 Off On Off Contact4 HP1100 Autosam pler Initial Conditions Draw Speed Eject Speed (pl/min) Draw Position (mm) Stop Time (mins) Injection Volume(pl) Vial Number Thermostat On Thermostat Temperature(C) 200.0 200 0.00 17.00 10.0 3 23.0 3M Study GLP10-01-02 Interim Report 05 Page 521 ,1 Masslynx - Sample List S am p le List: D :\m a sslynx\d a ve y2 0 1 0 .P R O \S a m p le D B \d 1 0 0 9 0 8 a .S P L P rinted: W e d S ep 08 16:06:21 2010 Page 1 P age P osition: (1 ,1 ) File Name Sam ple ID MS File Inlet File Bottle Inject Volum e Sam ple Type Cone 1 d100908a001 09004-182 80:20 A C N :H 2 0 2 d100908a002 09004-182 80:20 A C N :H 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 91 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 91 3 d100908a003 E C -100831-01 0.2 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 18 1 4 d100908a004 E C -100831-02 0 .5 ng E xtracted C urve P oint 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 2 5 d100908a005 E C -100 831 -03 0.75 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 3 6 d100908a006 E C -100 831-04 1 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 18 4 7 d100908a007 E C -100831-05 2 .5 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 18 5 8 d100908a008 E C -100 831-06 5 ng E xtracted C urve P oint 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 6 9 d100908a009 E C -100831-07 10 ng E xtracted C urve P oint 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 7 10 d 1 0 0 9 0 8 a 0 1 0 E C -1 0 0 8 3 1 -0 8 2 5 ng E x tra c te d C u rv e P o in t 11 d 1 0 0 9 0 8 a 0 1 1 E C -1 0 0 8 3 1 -0 9 5 0 n g E x tra c te d C u rv e P o in t 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 8 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 9 12 d 1 0 0 9 0 8 a 0 1 2 E C -1 0 0 8 3 1 -1 0 1 0 0 ng E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 1 7 m in p r is m - C I 8 10 13 d 1 0 0 9 0 8 a 0 1 3 E C -1 0 0 8 3 1 -1 1 2 0 0 ng E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 11 14 d 1 0 0 9 0 8 a 0 1 4 E C -1 0 0 8 3 1 -1 2 5 0 0 ng E x tra c te d C u rv e P o in t 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 12 15 d 1 0 0 9 0 8 a 0 1 5 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 91 16 d 1 0 0 9 0 8 a 0 1 6 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 91 17 d 1 0 0 9 0 8 a 0 1 7 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C I 8 91 18 d 1 0 0 9 0 8 a 0 1 8 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 92 19 d 1 0 0 9 0 8 a 0 1 9 M B -1 0 0 8 3 1 -0 1 M e th o d B la n k 1 w /o IS 20 d1 0 0 9 0 8 a 0 2 0 M B -1 0 0 8 3 1 -0 4 M e thod B la n k 4 w / IS 21 d 1 0 0 9 0 8 a 0 2 1 G L P 1 0 -0 1 -0 1 -0 5 -0 7 0 D A L S S G P 0 2 0 0 0 2 0 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17m in prism -C 18 17m in prism -C 18 17m in p rism -C 18 13 14 15 22 d 1 0 0 9 0 8 a 0 2 2 G L P 1 0 -0 1 -0 1 -0 5 -0 7 1 D A L S S G P 0 2 D B 0 0 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p r is m - C I 8 16 23 d 1 0 0 9 0 8 a 0 2 3 G L P 1 0 -0 1 -0 1 -0 5 -0 7 2 D A L S S G P 0 2 0 0 1 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p r is m - C I 8 17 24 d 1 0 0 9 0 8 a 0 2 4 G L P 1 0 -0 1 -0 1 -0 5 -0 7 3 D A L S S G P 0 3 0 0 0 0 0 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 18 18 25 d 1 0 0 9 0 8 a 0 2 5 G L P 1 0 -0 1 -0 1 -0 5 -0 7 4 D A L S S G P 0 3 0 0 0 0 5 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 19 26 d 1 0 0 9 0 8 a 0 2 6 G L P 1 0 -0 1 -0 1 -0 5 -0 7 5 D A L S S G P 0 3 0 0 0 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 0 27 d 1 0 0 9 0 8 a 0 2 7 G L P 1 0 -0 1 -0 1 -0 5 -0 7 6 D A L S S G P 0 3 D B 0 0 2 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 21 28 d 1 0 0 9 0 8 a 0 2 8 G L P 1 0 -0 1 -0 1 -0 5 -0 7 7 D A L S S G P 0 3 0 0 0 5 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 2 29 d 1 0 0 9 0 8 a 0 2 9 G L P 1 0 -0 1 -0 1 -0 5 -0 7 8 D A L S S G P 0 4 0 0 0 0 0 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 3 30 d 1 0 0 9 0 8 a 0 3 0 G L P 1 0 -0 1 -0 1 -0 5 -0 7 9 D A L S S G P 0 4 0 0 0 0 5 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 4 31 d 1 0 0 9 0 8 a 0 3 1 G L P 1 0 -0 1 -0 1 -0 5 -0 8 0 D A L S S G P 0 4 0 0 0 2 0 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 5 32 d 1 0 0 9 0 8 a 0 3 2 G L P 1 0 -0 1 -0 1 -0 5 -0 8 1 D A L S S G P 0 4 0 0 0 5 0 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 26 33 d 1 0 0 9 0 8 a 0 3 3 G L P 1 0 - 0 1 -0 1 -0 5 -0 8 2 D A L S S G P 0 5 0 0 0 0 0 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 7 34 d 1 0 0 9 0 8 a 0 3 4 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 92 35 d 1 0 0 9 0 8 a 0 3 5 E C -1 0 0 8 3 1 -0 8 2 5 n g E x tra c te d C u rv e P o in t 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 8 36 d 1 0 0 9 0 8 a 0 3 6 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 93 37 d 1 0 0 9 0 8 a 0 3 7 G L P 1 0 - 0 1 -0 1 -0 5 -0 8 3 D A L S S G P 0 5 0 0 0 0 5 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 28 38 d 1 0 0 9 0 8 a 0 3 8 G L P 1 0 -0 1 -0 1 -0 5 -0 8 4 D A L S S G P 0 5 0 0 0 2 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 29 39 d 1 0 0 9 0 8 a 0 3 9 G L P 1 0 -0 1 -0 1 -0 5 -0 8 5 D A L S S G P 0 5 0 0 0 5 5 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 30 40 d 1 0 0 9 0 8 a 0 4 0 G L P 1 0 -0 1 -0 1 -0 5 -0 8 7 D A L S S G P 0 6 0 0 0 0 0 17 M I N -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 31 41 d 1 0 0 9 0 8 a 0 4 1 G L P 1 0 - 0 1 -0 1 -0 5 -0 8 8 D A L S S G P 0 6 0 0 0 0 5 17 M I N -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 3 2 42 d 1 0 0 9 0 8 a 0 4 2 G L P 1 0 -0 1 -0 1 -0 5 -0 8 9 D A L S S G P 0 6 0 0 0 2 0 17M I N -P F B S -P F H S -P F O S 17m in prism -C 18 33 1 0 .0 0 0 10.000 10.000 10.000 1 0 .0 0 0 1 0 .0 0 0 10.000 10.000 1 0 .0 0 0 1 0 .0 0 0 10.000 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 10.000 1 0 .0 0 0 10.000 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 _ -- S tandard S tandard S tandard S tandard S tandard S tandard S tandard S tandard S tandard S tandard S tandard S tandard -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- QC -- -- -- -- -- -- -- _ -- 0.2 0.5 0 .7 5 1 2.5 5 10 25 50 100 200 500 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 25 -- -- -- -- -- -- -- 3M Study G LP10-01-02 Interim R eport 05 Page 522 of 962 M asslynx - Sam ple List S a m p le List: D :\m a sslyn x\d a ve y2 0 1 0 .P R O \S a m p le D B \d 1 0 0 9 0 8 a .S P L P rinted: W ed S ep 08 16:06:21 2010 Page 2 P age P osition: (1 ,2 ) File Nam e Sam ple ID MS File In le t F ile B o ttle In je c t V o lu m e S a m p le T yp e C o n e A 43 d 1 0 0 9 0 8 a 0 4 3 G L P 1 0-01-0 1 -0 5 -0 9 0 D A L S S G P 0 6 0 0 1 1 0 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 34 44 d 1 0 0 9 0 8 a 0 4 4 G L P 1 0-01-0 1-0 5-0 91 D A L S S G P 0 7 0 00 00 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 35 45 d 1 0 0 9 0 8 a 0 4 5 G L P 1 0 -0 1 -0 1 -0 5 -0 9 2 D A L S S G P 0 7 0 0 0 0 5 17M I N -P F B S -P F H S -P F O S 17m in prism -C 1 8 36 46 d 1 0 0 9 0 8 a 0 4 6 G L P 1 0 -0 1 -0 1 -0 5 -0 9 3 D A L S S G P 0 7 0 0 0 2 0 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 37 47 d 1 0 0 9 0 8 a 0 4 7 G L P 1 0-01 -01 -0 5 -0 9 4 D A L S S G P 0 7 0 0 1 3 0 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 38 48 d 1 0 0 9 0 8 a 0 4 8 G L P 1 0-01-0 1 -0 5 -0 9 5 D A L S S G P 0 8 0 0 0 0 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 39 49 d 1 0 0 9 0 8 a 0 4 9 G L P 1 0 -0 1 -0 1 -0 5 -0 9 6 D A L S S G P 0 8 0 0 0 0 5 17 M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 40 50 d 1 0 0 9 0 8 a 0 5 0 G L P 1 0 -0 1 -0 1 -0 5 -0 9 7 D A L S S G P 0 8 D B 0 0 0 5 1 7 M I N -P F B S -P F H S -P F O S 1 7 m in p r is m - C I 8 41 51 d 1 0 0 9 0 8 a 0 5 1 G L P 1 0 -0 1 -0 1 -0 5 -0 9 8 D A L S S G P 0 8 0 0 0 2 0 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 4 2 52 d 1 0 0 9 0 8 a 0 5 2 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I 8 93 53 d 1 0 0 9 0 8 a 0 5 3 E C -1 0 0 8 3 1 -0 7 1 0 n g E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 7 54 d 1 0 0 9 0 8 a 0 5 4 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 94 55 d 1 0 0 9 0 8 a 0 5 5 G L P 1 0 -0 1 -0 1 -0 5 -0 9 9 D A L S S G P 0 8 0 0 0 5 0 17M I N -P F B S -P F H S -P F O S 17m in prism -C 1 8 43 56 d 1 0 0 9 0 8 a 0 5 6 G L P 1 0 -0 1 -0 1 -0 5 -1 0 1 D A L S S G P 0 9 0 0 0 0 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 44 57 d 1 0 0 9 0 8 a 0 5 7 G L P 1 0 -0 1 -0 1 -0 5 -1 0 2 D A L S S G P 0 9 0 0 0 0 5 17M I N -P F B S -P F H S -P F O S 17m in prism -C 1 8 45 58 d 1 0 0 9 0 8 a 0 5 8 G L P 1 0 -0 1 -0 1 -0 5 -1 0 3 D A L S S G P 0 9 D B 0 0 0 5 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 4 6 59 d 1 0 0 9 0 8 a 0 5 9 G L P 1 0 -0 1 -0 1 -0 5 -1 0 4 D A L S S G P 0 9 0 0 0 2 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 47 60 d 1 0 0 9 0 8 a 0 6 0 G L P 1 0 -0 1 -0 1 -0 5 -1 0 5 D A L S S G P 0 9 0 0 0 5 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 48 61 d 1 0 0 9 0 8 a 0 6 1 G L P 1 0 -0 1 -0 1 -0 5 -1 0 6 D A L S S G P 1 0 0 0 0 0 0 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 4 9 62 d 1 0 0 9 0 8 a 0 6 2 G L P 1 0 -0 1 -0 1 -0 5 -1 0 7 D A L S S G P 1 0 0 0 0 0 5 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 50 63 d 1 0 0 9 0 8 a 0 6 3 G L P 1 0 -0 1 -0 1 -0 5 -1 0 8 D A L S S G P 1 0 0 0 0 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p ris m -C 1 8 51 64 d 1 0 0 9 0 8 a 0 6 4 G L P 1 0 -0 1 -0 1 -0 5 -1 0 9 D A L S S G P 1 0 0 0 0 6 0 17M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 52 65 d 1 0 0 9 0 8 a 0 6 5 G L P 1 0 -0 1 -0 1 -0 5 -1 1 1 D A L S S G P 1 1 0 0 0 0 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 53 66 d 1 0 0 9 0 8 a 0 6 6 G L P 1 0 -0 1 -0 1 -0 5 -1 1 2 D A L S S G P 1 1 0 0 0 0 5 17M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 54 67 d 1 0 0 9 0 8 a 0 6 7 G L P 1 0 -0 1 -0 1 -0 5 -1 1 3 D A L S S G P 1 1 0 0 0 2 0 68 d 1 0 0 9 0 8 a 0 6 8 G L P 1 0 - 0 1 -0 1 -0 5 -1 1 4 D A L S S G P 1 1 0 0 0 6 5 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 1 8 55 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 1 8 56 69 d 1 0 0 9 0 8 a 0 6 9 G L P 1 0 - 0 1 -0 1 -0 5 -1 1 5 D A L S S G P 1 1 D B 0 0 6 5 1 7 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 5 7 70 d 1 0 0 9 0 8 a 0 7 0 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 94 71 d 1 0 0 9 0 8 a 0 7 1 E C -1 0 0 8 3 1 -0 8 2 5 n g E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 8 72 d 1 0 0 9 0 8 a 0 7 2 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 1 8 95 73 d 1 0 0 9 0 8 a 0 7 3 G L P 1 0 -0 1 -0 1 -0 5 -1 1 6 D A L S S G P 1 2 0 0 0 0 0 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 58 74 d 1 0 0 9 0 8 a 0 7 4 G L P 1 0 - 0 1 -0 1 -0 5 -1 1 7 D A L S S G P 1 2 0 0 0 0 5 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 59 75 d 1 0 0 9 0 8 a 0 7 5 G L P 1 0 - 0 1 -0 1 -0 5 -1 1 8 D A L S S G P 1 2 0 0 0 2 0 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 60 76 d 1 0 0 9 0 8 a 0 7 6 G L P 1 0 -0 1 -0 1 -0 5 -1 1 9 D A L S S G P 1 2 0 0 1 7 0 1 7 M IN -P F B S -P F H S -P F O S 17 m in p ris m -C 1 8 61 77 d 1 0 0 9 0 8 a 0 7 7 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 1 7 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 95 78 d 1 0 0 9 0 8 a 0 7 8 E C -1 0 0 8 3 1 -0 7 1 0 n g E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 18 7 79 d 1 0 0 9 0 8 a 0 7 9 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 Q 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 96 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 10.000 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 ___ -- -- -- -- -- -- -- -- -- QC -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- QC -- -- -- -- -- -- QC -- ___ -- -- -- -- -- -- -- -- -- 10 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 25 -- -- -- -- -- -- 10 -- 3M Study G LP10-01-02 Interim R eport 05 Page 523 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dlOO908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:39:50 2010 Compound 1: PFBS Sample List: dl00908a Method File: dl00906a Coefficient of Determination: 0.999395 Calibration curve: -0.0689062 * x'2 + 229.088 * x + 95.0285 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a001 dl00908a002 dl00908a003 dl00908a004 dl00908a005 dl00908a006 dl00908a007 dl00908a008 dl00908a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl00908a014 dl00908a015 dl00908a016 dl00908a017 dl00908a018 dl00908a019 dl0090Ba020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 dl00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dl00908a034 dl00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 dl00908a040 dl00908a041 dl00908a042 dl00908a043 dl00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 d!00908a051 dl00908a052 dl00908a053 dl00908a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 M B -100831-01 Method Blank 1 w/o IS M B -100831-04 Method Blank 4 w/ IS GLP10-01-01-05-070 DAL SS GP02 0 0020 GLP10-01-01-05-071 DAL SS GP02 DB 0020 GLP10-01-01-05-072 DAL SS GP02 0 0120 GLP10-01-01-05-073 DAL SS GP03 0 0000 GLP10-01-01-05-074 DAL SS GP03 0 0005 GLP10-01-01-05-075 DAL SS GP03 0 0020 GLP10-01-01-05-076 DAL SS GP03 DB 0020 GLP10-01-01-05-077 DAL SS GP03 0 0050 GLP10-01-01-05-078 DAL SS GP04 0 0000 GLP10-01-01-05-079 DAL SS GP04 0 0005 GLP10-01-01-05-080 DAL SS GP04 0 0020 GLP10-01-01-05-081 DAL SS GP04 0 0050 GLP10-01-01-05-082 DAL SS GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLPlO-01-01-05-083 DAL SS GP05 0 0005 GLP10-01-01-05-084 DAL SS GP05 0 0020 GLPlO-01-01-05-085 DAL SS GP05 0 0055 GLP10-01-01- 05 -087 DAL SS GP06 0 0000 GLPlO-01-01-05-088 DAL s s GP06 0 0005 GLPlO-01-01-05-089 DAL s s GP06 0 0020 GLPI 0-01-01-05-090 DAL s s GP06 0 0110 GLP10-01-01-05-091 DAL s s GP07 0 0000 GLP10-01-01-05-092 DAL s s GP07 0 0005 GLP10-01- 01-05-093 DAL s s GP07 0 0020 GLP10-01-01-05-094 DAL s s GP07 0 0130 GLP10-01-01-05-095 DAL s s GP08 0 0000 GLP10-01-01-05-096 DAL s s GP08 0 0005 GLPlO-01-01-05-097 DAL s s GP08 DB 0005 GLP10-01-01-05-098 DAL s s GP08 0 0020 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN-.H20 GLP10-01-01-05-099 DAL SS GP08 0050 GLP10-01-01-05-101 DAL SS GP09 0 0 0 0 GLP10-01-01-05-102 DAL SS GP09 0005 Type STD Conc.(ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 QC RT 9.211 8.819 9.261 9.085 8.994 9.076 8.985 8.990 9.033 9.075 9.257 9.046 8.997 9.252 8.987 9.425 9.519 9.035 9.428 9.216 9.130 8.952 8.958 9.136 9.134 9.038 9.046 8.909 9.003 8.912 9.085 8.996 9.080 8.650 8.912 9.435 9.087 8.995 8.994 9.042 9.130 9.215 9.087 9.043 9.177 9.175 9.303 9.346 8.953 9.212 9.087 9.080 9.042 9.126 9.215 9.259 8.998 q u a n tita tif o Q J n B o / 20/ 10 mmh Interim R eport 05 Area Plags 116. 90 bb 21. 86 bb 143 .79 bb 224 .01 bb 238 ..16 bb 308 .74 bb 503 .98 bb 1252 .28 bb 2759..77 bb 6905 .37 bb 11826 .79 bb 20387..59 bb 42939 .32 bb 97776..80 bb 26..35 MM 72 .20 bb 200..89 bb 47 .50 MM 125..43 bb 85..12 bb 143 .43 MM 175..84 bb 321..36 bb 1337 .25 bb 6356 .88 bb 10269 .03 bb 12730 .60 bb 2257 .19 bb 1030 .07 bb 411 .36 bb 474 .79 bb 1041 .78 bb 2146 .07 bb 87..70 bb 6995 .28 bb 70 .23 bb 1398 .98 bb 387 .40 bb 1007 .35 bb 631 .71 bb 244 .18 MM 158 .56 bb 306..15 MM 673 .87 bb 558 .22 MM 236 .32 bb 2209 .62 bb 847 .51 bb 132 .56 bb 110 .11 bb 74 .41 bb 95 .08 bb 2712 .96 bb 148 .82 bb 181 .34 bb 3721 .79 MM 987 .67 bb ng/mL %Rec Mod Comment 0. 10 0. 00 0. 21 106 0. 56 113 0. 62 83 0. 93 93 1. 79 71 5..06 101 11..67 117 30..00 120 52..02 104 91..07 91 198..92 99 502..28 100 0..00 ab 0..00 0..46 0..00 b 0..13 0 .00 0..21 b 0 .35 0 .99 5 .43 27 .56 45..02 56 .10 9 .47 4 .09 1 .38 1 .66 4 .14 8 .98 0 .00 30 .40 122 0 .00 5 .70 1 .28 3 .99 2 .34 0..65 ab 0 .28 0 .92 ab 2 .53 2 .02 a 0 .62 9 .26 3 .29 0 .16 0 .07 0 .00 0 .00 11 .47 115 0 .23 0 .38 15 .91 a 3 .90 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List< D:\masslynx\davey2010.PRO\SampleOB\dlO0908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010. PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:39:50 2010 Compound 1: PFBS Sample List: dl00908a Method File: dl00908a Coefficient of Determination: 0.999395 Calibration curve: -0.0689062 * x A2 229.088 * x 95.0285 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a058 dl00908a059 dl00908a060 dl00908a061 dl00908a062 dl00908a063 dl00908a064 dl00908a065 dl00908a066 dl00908a067 dl00908a068 dl00908a069 dl00908a070 dl00908a071 dl00908a072 dl00908a073 dl00908a074 dl00908a075 dl00908a076 dl00908a077 dl00908a078 dl00908a079 Samplelist ID GLP10-01-01-05-103 DAL SS GP09 DB 0005 GLP10-0 1-01-05 -104 DAL SS GP09 0 0020 GLP10-0 1-01- 05 -105 DAL SS GP09 0 0050 GLP10-01- 01- 05 -106 DAL SS GP10 0 0000 GLP10-0 1-01-05-107 DAL SS GP10 0 0005 GLP10-01-01-05-108 DAL SS GP10 0 0020 GLP10-01-01-05-109 DAL SS GP10 0 0060 GLP10-0 1-01-05 -111 DAL SS G P U 0 0000 GLP10-01-01-05-112 DAL SS G P U 0 0005 GLP10-0 1-01-05 -113 DAL SS G P U 0 0020 GLP10-0 1-01-05-114 DAL SS G P U 0 0065 GLP10-01-01-05-115 DAL SS G P U DB 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-116 DAL SS GP12 0 0000 GLP10-01- 01- 05 -117 DAL s s GP12 0 0005 GLP10-01- 01- 05 -118 DAL s s GP12 0 0020 G L PI0-01-01-05-119 DAL s s GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type STD Conc.(ng/mL) QC 25.0000 QC 10.0000 RT 9.214 9.170 9.440 9.087 9.609 9.215 9.391 9.482 9.434 9.393 9.350 9.255 9.174 9.563 9.519 9.297 9.258 9.346 9.379 9.215 9.395 9.260 i n ( p i a n t i t ^ i y b ^ J ^ i 'J i i P i i f i P f y t r ^ 1 0 / 2 0 / 1 0 mmh 1. ' Interim R e n o rt 0 5 WF1F A m m Area Flags 1248 .37 bb 366 .20 bb 988 .70 bb 4203 .89 bb 130 .93 bb 64 .60 bb 18309 .68 bb 1015 .96 bb 1358 .98 bb 4234 .41 bb 1347 .30 bb 1559 .65 bb 36 .97 bb 7323 .16 MM 117 .66 bb 294 .30 bb 189..06 MM 510 .79 bb 448 .05 bb 53 .41 bb 2525..27 bb 74 .53 bb ng/mL %Rec Mod Comment 5..04 1..18 3.,91 18..03 0..16 0..00 81..51 4 .02 5..53 18..17 5..48 6..41 0..00 31..86 0..10 0..87 0..41 1. 82 1.,54 0..00 10..64 0. 00 Page 2 Page 525 of 962 Quantify Compound Summary Report GLP10-01-2-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modified: Wed Sep 08 11:46:49 2010 Method: D : \ m a s s l y n x \ d a v e y 2 0 1 0 .PRO\ M e t h D B \ d l 0 0 9 08a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:39:50 2010 Compound 2: PFHS Sample List: dl00908a Method File: dl00908a Coefficient of Determination: 0.999290 Calibration curve: -0.0274503 * x"2 + 176.227 * x + 115.051 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting 1/x, Axis trans: Mone Name dl00908a001 dl00908a002 dl00908a003 dl009Q8a004 dl00908a005 dl00908a006 dl00908a007 dl00908a008 dl00908a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl00908a014 dl00908a015 dl00908a016 dl00908a017 dl00908a018 dl00908a019 dl00908a020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 dl00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dl00908a034 dl00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 dl00908a040 dl00908a041 dl00908a042 dl00908a043 dl00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 dl00908a051 dl00908a052 dl00908a053 dl00908a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID> 20 ACN:H20 20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point 10 ng Extracted Curve Point 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 ng Extracted Curve Point 200 ng Extracted Curve Point 500 ng Extracted Curve Point 20 A C N :H20 20 ACN:H20 20 A C N :H20 20 A C N :H20 Method Blank 1 w/o IS MB -1008 3 Method Blank 4 w/ IS GLP10-01-01-05-070 DAL SS GP02 0 0020 GLP10-01-01-05-071 DAL SS GP02 DB 0020 GLPIO-01-01-05-072 DAL SS GP02 0 0120 GLP10-01-01-05-073 DAL SS GP03 0 0000 GLP10-01-01-05-074 DAL SS GP03 0 0005 GLP10-01-01-05-075 DAL SS GP03 0 0020 GLP10-01-01-05-076 DAL SS GP03 DB 0020 GLP10-01-01-05-077 DAL SS GP03 0 0050 GLP10-01-01-05-078 DAL SS GP04 0 0000 GLP10-01-01-05-079 DAL SS GP04 0 0005 GLP10-01-01-05-080 DAL SS GP04 0 0020 GLP10-01-01-05-081 DAL SS GP04 0 0050 GLP10-01-01-05-082 DAL SS GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-083 DAL SS GP05 0 0005 GLP10-01- 01-05-084 DAL SS GP05 0 0020 GLP10-01- 01-05 -085 DAL SS GP05 0 0055 GLP10-01-01-05-087 DAL SS GP06 0 0000 GLP10-01-01-05-088 DAL SS GP06 0 0005 GLP10-01-01-05-089 DAL SS GP06 0 0020 GLP10-01-01-05-090 DAL SS GP06 0 0110 GLP10-01-01-05-091 DAL SS GP07 0 0000 GLP10-01-01-05-092 DAL SS GP07 0 0005 GLP10-01- 01- 05 -093 DAL SS GP07 0 0020 GLP10-01-01-05-094 DAL SS GP07 0 0130 GLP10-01-01-05-095 DAL SS GP08 0 0000 GLP10-01-01-05-096 DAL SS GP08 0 0005 GLP10-01-01-05-097 DAL SS GP08 DB 0005 GLP10-01-01-05-098 DAL s s GP08 0 0020 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05 -099 DAL SS GP08 0 0050 GLPlO-01-01-05-101 DAL SS GP09 0 0000 GLP10-01-01-05-102 DAL SS GP09 0 0005 Type STD Cone.(ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 RT 9.960 10.048 10.140 9.877 9.874 9.999 9.863 9.999 9.824 9.910 10.135 9.969 9.876 10.044 9.780 10.174 9.485 10.565 10.178 10.050 9.965 9.747 9.881 9.971 9.884 9.832 9.840 9.701 9.969 9.748 9.876 9.831 9.959 9.660 9.747 10.096 9.880 9.831 9.829 9.966 9.968 9.919 9.835 9.837 9.926 10.100 10.053 10.008 9.918 10.049 9.836 10.307 9.791 10.443 9.964 10.006 9.879 G LP10-01-02 0 and printefl 10/20/10 mmh sporfCfo -\'H Area Flags 57..65 bb 125..27 bb 162 .05 bb 187 .29 bb 242 .26 bb 252 .28 bb 483..58 bb 998 .59 bb 2053 .71 bb 5332 .84 bb 9513 .20 bb 15656..73 bb 34276..56 bb 81611..69 bb 104 .16 bb 68 .47 bb 83 .71 bb 23..10 bb 67 .47 bb 66 .50 bb 74 .53 bb 108 .30 bb 277 .74 bb 6176 .19 bb 34322..44 bb 56523..51 bb 69496..98 bb 13076..36 bb 470 .52 bb 338..98 bb 929..87 bb 3165..97 bb 1298 .78 bb 66..10 bb 5446 .79 bb 35..23 bb 2157 .60 bb 999..28 bb 9901..32 bb 1059..52 bb 828 .56 bb 367..19 bb 375..59 MM 4369..30 bb 10118..60 db 3702 .45 MM 20252..18 bb 19551..21 bb 2162 .91 bb 2073 .44 MM 1481 .12 bb 42 .33 bb 2218 .46 bb 133 .06 bb 2131 .08 bb 39934..04 bb 6455 .97 bb ng/mL %Rec Mod Comment 0 .00 0 .06 0 .27 133 0 .41 82 0 .72 96 0 .78 78 2 .09 84 5 .02 100 11 .02 110 29 .75 119 53 .78 108 89 .44 89 200 .08 100 501 .65 100 0 .00 0 .00 0 .00 0 .00 0 .00 0 .00 0 .00 0 .00 0 .92 34 .58 200 .36 337 .87 421 .36 74 .41 2 .02 1 .27 4 .63 17 .36 6 .72 0 .00 30 .40 122 0 .00 11..61 5 .02 56 .02 5 .36 4 .05 1..43 1..48 a 24 .23 57 .28 20..42 116 .38 112 .25 11 .64 11 .13 7 .76 0 .00 11 ,.96 120 0..10 11 .46 234 .52 36..19 v Page 3 Page 526 of 962 Quantify Compound Summary Report GLP10-01-02-0S screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D: \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:39:50 2010 Compound 2: PFHS Sample List: dl00908a Method Pile: dl00908a Coefficient of Determination: 0.999290 Calibration curve: -0.0274503 * x A2 + 176.227 * x + 115.051 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a058 dl00908a059 dl00908a060 dl00908a061 dl00908a062 dl00908a063 dl00908a064 dl00908a065 dl00908a066 dl00908a067 dl00908a068 dl00908a069 dl00908a070 dl00908a071 dl00908a072 dl00908a073 dl00908a074 dl00908a075 dl00908a076 dl00908a077 dl00908a078 dl00908a079 Samplelist ID GLP10-01- 01-05-103 DAL SS GP09 DE1 0005 GLP10-01- 01-05-104 DAL SS GP09 0 0020 GLP10-01- 01-05-105 DAL s s GP09 0 0050 GLP10-01- 01-05-106 DAL s s GP10 0 0000 GLP10-01- 01-05-107 DAL s s GP10 0 0005 GLP10-01- 01- 05 -108 DAL s s GP10 0 0020 GLP10-01- 01- 05 -109 DAL s s GP10 0 0060 GLP10-01- 01-05-111 DAL s s G P U 0 0000 GLP10-01- 01-05-112 DAL s s G P U 0 0005 GLP10-01- 01-05-113 DAL s s G P U 0 0020 GLP10-01-01-05-114 DAL s s G P U 0 0065 GLP10-01- 01- 05 -115 DAL s s G P U DE1 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10- 01-01-05-116 DAL s s GP12 0 0000 GLP10-01-01-05-117 DAL s s GP12 0 0005 GLP10- 01- 01-05-118 DAL s s GP12 0 0020 GLP10-01-01-05-119 DAL s s GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type QC QC STD Conc.(ng/mL) 25.0000 10.0000 RT 10.006 10.050 10.101 10.009 11.183 10.489 10.139 10.099 10.140 10.056 10.187 10.047 10.098 10.312 10.311 10.131 10.006 10.097 10.129 9.224 10.144 quanti Interirp R'port.OB 10/20/10 Ai Area Flags 10942.42 bb 1042.78 bb 1296.68 bb 21804.46 bb 41865.12 MM 19387.94 MM 25685.71 bb 5040.51 bb 7388.53 bb 4781.15 bb 5011.96 bb 11192.76 bb 62.70 bb 5829.46 MM 93.85 bb 900.38 bb 461.82 bb 1371.09 bb 1739.54 bb 16.19 bb 1964.10 bb ng/mL %Rec Mod Comment 62.04 5.27 6.71 125.53 246.36 111.29 148.54 28.07 41.54 26.59 27.91 63.49 0.00 32.59 0.00 4.46 1.97 7.14 9.23 0.00 10.51 Page 4 V5' Page 527 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Lists Dt\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modifieds Thu Sep 09 13:46:21 2010 Job Code s Printeds Wed Oct 20 09s39s50 2010 Compound 3t PFOS Sample Lists dl00908a Method File: dl00908a Coefficient of Determinations 0.999387 Calibration curves -0.00787523 * x A2 + 140.661 * x + 37.7333 Response types External Std, Area Curve types 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a001 dl00908a002 dl00908a003 dl00908a004 dl00908a005 d!00908a006 dl00908a007 dl00908a008 dl00908a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl0908a014 dl00908a015 dl00908a016 dl00908a017 dl00908a018 dl00908a019 dl00908a020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 d!00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dl00908a034 dl00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 dl00908a040 dl00908a041 dl00908a042 dl00908a043 dl00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 dl00908a051 dl00908a052 dl00908a053 dl00908a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831*01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-04 Method Blank 4 w/ IS GLP10-01-01- 05-070 DAL SS GP02 0 0020 GLP10-01-01- 05-071 DAL SS GP02 DB 0020 GLPIO-01-01- 05-072 DAL SS GP02 0 0120 GLPlO-01-01-05-073 DAL SS GP03 0 0000 GLP10-01-01- 05-074 DAL SS GP03 0 0005 GLP10-01-01- 05-075 DAL SS GP03 0 0020 GLP10-01-01-05-076 DAL SS GP03 DB 0020 GLP10-01-01-05-077 DAL SS GP03 0 0050 GLPlO-01-01-05-078 DAL SS GP04 0 0000 GLP10-01-01-05-079 DAL SS GP04 0 0005 GLP10-01- 01- 05 -080 DAL SS GP04 0 0020 GLP10-01-01-05-081 DAL SS GP04 0 0050 GLP10-01-01-05-082 DAL SS GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLPlO-01-01-05-083 DAL SS GP05 0 0005 GLP10-01-01-05-084 DAL SS GP05 0 0020 GLPlO-01-01-05-085 DAL SS GP05 0 0055 GLPlO-01-01-05-087 DAL SS GP06 0 0000 GLP10-01-01-05-088 DAL SS GP06 0 0005 GLP10-Q1-01-05-089 DAL SS GP06 0 0020 GLPlO-01-01-05-090 DAL SS GP06 0 0110 GLPlO-01-01-05-091 DAL SS GP07 0 0000 GLP10-01-01-05-092 DAL SS GP07 0 0005 GLPlO-01-01-05-093 DAL SS GP07 0 0020 GLP10-01-01-05-094 DAL SS GP07 0 0130 GLP10-01-01-05-095 DAL SS GP08 0 0000 GLPlO-01-01-05-096 DAL SS GP08 0 0005 GLPlO-01-01-05-097 DAL SS GP08 DB 0005 GLPlO-01-01-05-098 DAL SS GP08 0 0020 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLPlO-01-01-05-099 DAL SS GP08 0 0050 GLP10-01-01-05-101 DAL SS GP09 0 0000 GLP10-01-01-05-102 DAL SS GP09 0 0005 Type STD Conc.(ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 QC 25.0000 QC 10.0000 RT 10.534 10.710 10.714 10.626 10.798 10.790 10.655 10.747 10.617 10.747 10.928 10.761 10.668 10.837 10.702 10.793 10.840 10.662 11.057 10.582 10.672 10.583 10.716 10.808 10.764 10.712 10.633 10.580 10.808 10.715 10.713 10.536 10.710 11.280 10.584 10.931 10.674 10.667 10.666 10.758 10.672 10.669 10.715 10.630 10.633 10.674 10.932 10.801 10.799 10.798 10.627 10.663 10.627 10.799 10.755 10.714 10.672 Area Flags 123.13 bb 86.37 bb 57.09 MM 131.77 MM 119.15 MM 139.43 bb 403.38 bb 882.34 db 1545.40 bb 4277.69 bb 7481.55 bb 12727.83 bb 27442.48 bb 68740.85 bb 62.10 MM 69.22 MM 108.26 MM 34.65 bb 64.47 bb 69.66 bb 19511.22 bb 32173.02 bb 932.83 bb 70083.20 bb 173972.50 bb 156590.59 bb 208195.23 bb 48336.75 bb 63621.06 bb 44475.15 bb 11962.65 bb 3445.12 bb 35055.79 bb 64.04 bb 4190.23 bb 84.19 bb 45874.27 bb 28881.15 bb 136844.02 bb 29974.68 bb 69311.39 bb 15103.14 bb 6282.26 bb 83446.47 bb 608497.56 bb 176309.89 bb 983242.88 bbl 614738.81 bb 114758.04 bb 120852.34 bb 46250.53 bb 172.22 bb 1631.05 bb 100.01 bb 54659.29 bb 406110.84 bb 203844.41 bb ng/mL %Rec Mod Comment 0.61 0.35 0.14 69 ab 0.67 134 a 0.58 77 ab 0.72 72 2.60 104 6.01 120 10.72 107 30.19 121 53.08 106 90.68 91 197.00 99 502.57 101 0.17 ab 0.22 ab 0.50 a 0.00 0.19 0.23 139.53 231.46 6.37 512.69 1336.57 1192.61 1628.30 350.24 464.09 321.71 85.18 24 .26 252.52 0.19 29.57 118 0.33 332.04 207.47 1032.25 215.43 506.87 107.75 44.51 614.09 7351.71 1356.14 7626.62 856.67 904.74 334.82 0.96 11.33 0.44 397.15 3620.97 1590.57 113 Page 5 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dlQ0908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dlQ0908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:39:50 2010 Compound 3: PFOS Sample List: dl00908a Method File: dl00908a Coefficient of Determination: 0.999387 Calibration curve: -0.00787523 * x * 2 + 140.661 * x + 37.7333 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a058 dl00908a059 dl00908a060 dl00908a061 dl00908a062 dl00908a063 dl00908a064 dl00908a065 dl00908a066 dl00908a067 dl00908a068 dl00908a069 dl00908a070 dl00908a07l dl00908a072 dl00908a073 dl00908a074 dl00908a075 dl00908a076 dl00908a077 dl00908a078 dl00908a079 Samplelist ID GLP10-01- 01- 05 -103 DAL SS GP09 DEI 0005 GLP10-01- 01-05-104 DAL SS GP09 0 0020 GLP10-01-01- 05 -105 DAL SS GP09 0 0050 GLP10-01-01-05 -106 DAL SS GP10 0 0000 GLP10-01- 01-05-107 DAL SS GP10 0 0005 GLP10-01-01-05-108 DAL s s GP10 0 0020 GLP10-01-01-05-109 DAL s s GP10 0 0060 GLP10-01-01-05-111 DAL s s G P U 0 0000 GLP10-01-01-05-112 DAL s s G P U 0 0005 GLP10-01-01-05-113 DAL s s G P U 0 0020 GLP10-01-01-05-114 DAL s s G P U 0 0065 GLP10-01-01-05-115 DAL s s G P U DE, 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-116 DAL s s GP12 0 0000 GLP10-01-01-05-117 DAL s s GP12 0 0005 GLP10- 01- 01- 05 -118 DAL s s GP12 0 0020 GLP10-01-01-05-119 DAL s s GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Ext L'acted Curve Point 09004-182 80:20 ACN:H20 Type QC QC STD Conc.(ng/mL) 25.0000 10.0000 RT 10.756 10.844 10.938 10.715 11.932 11.063 10.976 10.850 10.888 10.762 10.936 10.882 10.890 11.017 10.798 10.880 10.711 10.889 10.921 10.409 10.937 11.151 Area Flags 228999.98 bb 31273.16 bb 11364.45 bb 64100.77 bb 61163.62 MM 23432.95 MM 30042.87 bb 26633.04 bb 15318.47 bb 24696 -91 bb 23564.01 bb 91359.80 bb 136.61 bb 4734.98 MM 83.71 bb 91921.01 bb 39471.07 bb 56035.77 bb 13793.88 bb 66.52 bb 1859.53 bb 67.58 bb ng/mL %Rec Mod Comment 1811.48 224.89 80.89 467.69 445.68 167.90 215.93 191.12 109.30 177.06 168.85 674.72 0.70 33.46 0.33 679.04 284.89 407.40 98.34 0.20 12.96 0.21 Page 6 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified* Wed Sep 08 11:46*49 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46:21 2010 Job Codes Printed: Wed Oct 20 09:39:50 2010 Compound 4: 1802 PFBS (IS) Sample List* dl00908a Response Factor: 166.164 RRF SD: 22.9916, % Relative SD: 13.8367 Response type* External Std, Area Curve type: RF Method File: dl00908a Name dl00908a001 dl00908a002 dl00908a003 dl00908a004 dl00908a005 dl00908a006 dl00908a007 dl00908a008 dl00908a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl00908a014 dl00908a015 dl00908a016 dl00908a017 dl00908a018 dl00908a019 dl00908a020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 dl00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dl00908a034 dl00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 d!00908a040 dl00908a041 dl00908a042 dl00908a043 d!00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 dl00908a051 dl00908a052 dl00908a053 dl00908a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID 09004-182 80 :20 ACN:H20 09004-182 80 :;20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-04 Method Blank 4 vj/ IS GLP10-01- 01-05 -070 DAL SS GP02 0 0020 GLP10-01- 01-05 -071 DAL SS GP02 DB 0020 GLP10-01-01-05-072 DAL SS GP02 0 0120 GLP10-01-01-05-073 DAL ss GP03 0 0000 GLP10-01-01- 05 -074 DAL ss GP03 0 0005 GLP10-01-01-05-075 DAL ss GP03 0 0020 GLP10-01-01- 05 -076 DAL ss GP03 DB 0020 GLP10-01-01-05-077 DAL ss GP03 0 0050 GLP10-01-01-05-078 DAL ss GP04 0 0000 GLP10-01-01-05-079 DAL ss GP04 0 0005 GLP10-01-01-05-080 DAL ss GP04 0 0020 GLP10-01-01- 05 -081 DAL ss GP04 0 0050 GLP10-01-01-05-082 DAL ss GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLPlO-01-01-05-083 DAL SS GP05 0 0005 GLPlO-01-01-05-084 DAL SS GP05 0 0020 GLPlO-01-01-05-085 DAL ss GP05 0 0055 GLPlO-01-01-05-087 DAL ss GP06 0 0000 GLPlO-01-01-05-088 DAL ss GP06 0 0005 GLPlO-01-01-05-089 DAL ss GP06 0 0020 GLP10-01-01-05 -090 DAL ss GP06 0 0110 GLP10-01-01-05-091 DAL ss GP07 0 0000 GLP10-01-01-05-092 DAL ss GP07 0 0005 GLP10-01-01-05-093 DAL ss GP07 0 0020 GLP10-01-01-05-094 DAL ss GP07 0 0130 GLP10-01-01-05-095 DAL ss GP08 0 0000 GLP10-01-01- 05 -096 DAL ss GP08 0 0005 GLPlO-01-01-05-097 DAL ss GP08 DB 0005 GLP10-01-01- 05 -098 DAL ss GP08 0 0020 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-099 DAL SS GP08 0 0050 GLP10-01-01-05-101 DAL SS GP09 0 0000 GLP10-01-01-05 -102 DAL SS GP09 0 0005 Type STD Cone.(ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 QC QC RT 8.850 9.248 9.028 8.981 9.063 9.015 8.977 9.019 9.062 9.244 9.032 8.983 9.238 9.028 9.116 8.939 8.988 9.122 9.165 9.025 9.033 8.896 8.989 8.942 9.072 9.027 9.066 9.074 8.982 9.024 9.028 9.117 9.158 9.117 9.030 9.207 9.205 9.290 9.333 8.939 9.199 9.074 9.029 9.113 9.202 9.245 8.985 q u a n t i t ^ ^ > ^ d 3 l i f i 1 ^ ^ f i l 0 / 2 0 / l 0 mah. Interim Report 05 Area Plags 14.82 511.00 497.84 588.01 343.49 462.25 551.42 535.90 592.21 505.75 456.06 502.46 435.49 bb bb bb bb bb bb bb bb bb bb bb bb bb ng/mL %Rec 0.09 3.08 3.00 3.54 2.07 2.78 3.32 3.23 3.56 3.04 2.74 3.02 2.62 3 103 100 118 69 93 111 108 119 101 91 101 87 492.00 394.63 426.36 505.51 406.17 451.01 310.38 318.48 345.49 397.24 487.54 458.23 462.18 465.61 bb bb bb bb bb bb bb bb bb bb bb bb bb bb 544.87 bb 484.92 452.94 399.23 626.56 619.98 510.70 356.95 562.42 680.20 604.63 394.63 539.58 485.02 560.00 525.10 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 599.18 12.84 560.96 569.59 467.62 bb bb bb bb bb 2.96 2.37 2.57 3.04 2.44 2.71 1.87 1.92 2.08 2.39 2.93 2.76 2.78 2.80 99 79 86 101 81 90 62 64 69 80 98 92 93 93 3.28 109 2.92 2.73 2.40 3.77 3.73 3.07 2.15 3.38 4.09 3.64 2.37 3.25 2.92 3.37 3.16 97 91 80 126 124 102 72 113 136 121 79 108 97 112 105 3.61 0.08 3.38 3.43 2.81 120 3 113 114 94 Page 7 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: Last modified: Method: Last modified: Job Code: D:\masslynx\davey2010.PRO\SampleDB\dl00906a Wed Sep 08 11:46:49 2010 D:\masslynx\davey2010.PRO\MethDB\dl00908a Thu Sep 09 13:46:21 2010 Printed: Wed Oct 20 09:39:50 2010 Compound 4: 1802 PFBS (IS) Response Factor: 166.164 RRF SD: 22.9916, % Relative Response type: External Std, Curve type: RF Sample List: SD: 13.8367 Area dl00908a Method File: dl00908a Name dl00908a058 dl00908a059 dl00908a060 dl00908a061 dl00908a062 dl00908a063 dl00908a064 dl00908a065 dl00908a066 dl00908a067 dl00908a068 dl00908a069 dl00908a070 dl00908a071 dl00908a072 dl00908a073 dl00908a074 dl00908a075 dl00908a076 dl00908a077 dl00908a078 dl00908a079 Samplelist ID GLP10-01-01-05-103 DAL SS GP09 DE1 0005 GLP10-01-01-05-104 DAL SS GP09 0 0020 GLP10-01-01-05-105 DAL s s GP09 0 0050 GLP10-01-01-05-106 DAL s s GP10 0 0000 GLP10-01-01-05-107 DAL s s GP10 0 0005 GLP10-01-01-05-108 DAL s s GP10 0 0020 GLP10-01-01-05-109 DAL s s GP10 0 0060 GLP10-01-01-05-111 DAL s s G P U 0 0000 GLP10-01-01-05-112 DAL s s G P U 0 0005 GLP10-01-01-05-113 DAL s s G P U 0 0020 GLP10-01-01-05-114 DAL s s G P U 0 0065 GLP10-01-01-05-115 DAL s s G P U DB 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-116 DAL s s GP12 0 0000 GLP10-01-01-05-117 DAL s s GP12 0 0005 GLP10-01-01-05-118 DAL s s GP12 0 0020 GLP10-01-01-05-119 DAL s s GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type QC OC STD Conc.(ng/mL) RT 9.201 9.201 9.427 9.117 10.595 9.899 9.377 9.469 9.421 9.380 9.337 9.285 3.0000 9.549 3.0000 9.284 9.288 9.377 9.365 9.593 9.382 Area Flags 473..16 bb 450 .72 bb 511 .34 MM 561..73 bb 498 .97 MM 544 .21 MM 469 .64 bb 612 .76 MM 484 .23 MM 574 .47 bb 472 .60 bb 497 .30 bb 594 .88 MM 632 .28 481 .19 594..04 442 .66 11 .89 543 .12 bb bb bb bb bb bb g/mL %Rec Mod Comment 2..85 95 2 .71 90 3..08 103 3..38 113 3 .00 100 ab 3..28 109 2..83 94 3..69 123 2..91 97 ab 3..46 115 2..84 95 2 .99 100 3..58 119 ab 3 .81 2 .90 3 .58 2 .66 0 .07 3 .27 127 97 119 89 2 109 Page 8 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Lists Last modified: Methods Last modified: Job Codes D s\masslynx\davey2010.PRO\SampleDB\dlO0908a Wed Sep 08 11:46:49 2010 D:\masslynx\davey2010.PRO\MethDB\dl00908a Thu Sep 09 13:46:21 2010 Printed Wed Oct 20 09:39:50 2010 Compound 5: 1802 PFHS (IS) Sample List: dl00908a Response Factor: 102.287 RRF SD: 19.5744, % Relative SD: 19.1368 Response type: External Std, Area Curve type: RF Method File: dl00908a Name dl00908a001 dl00908a002 d!00908a003 dl00908a004 d!00908a005 dl00908a006 dl00908a007 dl00908a008 dl00908a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl00908a014 dl00908a015 dl00908a016 dl00908a017 dl00908a018 dl00908a019 dl00908a020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 dl00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dl00908a034 d!00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 dl00908a040 dl00908a041 dl00908a042 dl0Q908a043 dl00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 dl00908a051 dl00908a052 dl00908a053 dl00908a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID 09004-182 80: 20 A C N :H20 09004-182 80: 20 A C N :H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80: 20 A C N :H20 09004-182 80: 20 A C N :H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 M B -100831-01 Method Blank 1 w/(D IS M B -100831-04 Method Blank 4 w / IS GLP10-01-01-05-070 DAL SS GP02 0 0020 GLP10-01-01-05-071 DAL SS GP02 DB. 0020 GLP10-01-01-05-072 DAL SS GP02 0 0120 GLP10-01-01-05-073 DAL SS GP03 0 0000 GLP10-01-01-05-074 DAL ss GP03 0 0005 GLP10-01-01-05-075 DAL ss GP03 0 0020 GLP10-01-01-05-076 DAL ss GP03 DB. 0020 GLP10-01-01-05-077 DAL ss GP03 0 0050 GLP10-01-01-05-078 DAL ss GP04 0 0000 GLP10-01-01-05-079 DAL ss GP04 0 0005 GLP10-01-01-05-080 DAL ss GP04 0 0020 GLP10-01-01-05-081 DAL ss GP04 0 0050 GLP10-01-01-05-082 DAL ss GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-083 DAL SS GP05 0 0005 GLP10-01- 01-05-084 DAL SS GP05 0 0020 GLP10-01-01-05-085 DAL s s GP05 0 0055 GLP10-01-01-05-087 DAL s s GP06 0 0000 GLP10-01-01-05-088 DAL s s GP06 0 0005 GLP10-01-01-05-089 DAL s s GP06 0 0020 GLP10-01-01-05-090 DAL s s GP06 0 0110 GLP10-01-01-05-091 DAL s s GP07 0 0000 GLP10-01-01-05-092 DAL s s GP07 0 0005 GLP10-01-01-05-093 DAL s s GP07 0 0020 GLP10-01-01-05-094 DAL s s GP07 0 0130 GLP10-01-01-05-095 DAL s s GP08 0 0000 GLPlO-01-01-05-096 DAL s s GP08 0 0005 GLP10-01-01-05-097 DAL s s GP08 DB 0005 GLP10-01-01-05-093 DAL s s GP08 0 0020 09004*182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004 182 80:20 ACN:H20 GLP10 01-01-05-099 DAL SS GP08 0 0050 GL P 1 0 -01-01-05-101 DAL SS GP09 0 0000 GLP10 01-01-05-102 DAL SS GP09 0 0005 Type STD Cone. (ng/mL) RT Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 10.113 9.894 9.848 10.016 9.837 10.016 9.841 9.927 10.152 9.943 9-849 10.061 9.802 9.807 9.896 9.721 9.854 9.988 9.901 9.849 9.857 9.718 9.987 9.852 9.893 9.892 9.933 QC 9.854 9.805 9.846 9.939 9.985 9.936 9.852 9.811 9.943 10.117 10.070 9.981 9.935 10.065 9.853 9.981 10.023 9.896 3M Study GLP10-01-02 9 U" t i | ^ r t W 9^ ^ ' ^ 0 e r i n t e d 1 0 / 2 0 / 1 0 a i- K 2 ,U U ,.A Area Flags 277.46 230.41 318.82 291.62 402.01 243.23 422.22 335.34 297.41 320.38 250.71 292.72 bb bb bb bb bb bb bb bb bb bb bb bb 19.90 bb 32.95 310.83 241.91 327.62 273.55 303.65 370.51 238.17 242.19 236.55 250.31 273.59 274.14 241.49 318.77 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 299.74 bb 234 .20 306.00 188.93 380.73 366.37 319.98 161.54 308.88 310.38 229.63 300.71 280.81 359.38 383 .42 300.80 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 298.80 bb 264.95 334.79 367.56 bb bb bb ng/mL %Rec Mod Comment 2.71 2.25 3.12 2.85 3.93 2.38 4.13 3.28 2.91 3.13 2.45 2.86 90 75 104 95 131 79 138 109 97 104 82 95 0.19 6 0.32 3.04 2.37 3.20 2.67 2.97 3.62 2.33 2.37 2.31 2.45 2.67 2.68 2.36 3.12 11 101 79 107 89 99 121 78 79 77 82 89 89 79 104 2.93 98 2.29 2.99 1.85 3.72 3.58 3.13 1.58 3.02 3.03 2.24 2.94 2.75 3.51 3.75 2.94 76 100 62 124 119 104 53 101 101 75 98 92 117 125 98 2.92 97 2.59 86 3.27 109 3.59 120 Page 9 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:39:50 2010 Compound 5: 1802 PFHS (IS) Response Factor: 102.287 RRF SD: 19.5744, % Relative Response type: External Std, Curve type : RF Sample List: SD: 19.1368 Area dl00908a Method File: dl00908a Name dl00908a058 dl00908a059 dl00908a060 dl00908a061 dl00908a062 dl00908a063 dl00908a064 dl00908a065 dl00908a066 dl00908a067 dl00906a068 dl0090Sa069 dl00908a070 dl00908a071 dl00908a072 dl00908a073 dl00908a074 dl00908a075 dl00908a076 d!00908a077 dl00908a078 Samplelist ID GLP10-01- 01- 05 -103 DAL SS GP09 DE; 0005 GLP10-01-01-05-104 DAL SS GP09 0 0020 GLP10-01-01-05-105 DAL SS GP09 0 0050 GLP10-01- 01- 05-106 DAL SS GP10 0 0000 GLP10-01- 01-05-107 DAL SS GP10 0 0005 GLP10-01- 01- 05-108 DAL SS GP10 0 0020 GLP10-01-01-05-109 DAL SS GP10 0 0060 GLP10-01- 01-05-111 DAL SS G P U 0 0000 GLP10-01-01-05-112 DAL SS G P U 0 0005 GLP10-01- 01-05-113 DAL SS G P U 0 0020 GLP10-01- 01-05-114 DAL SS G P U 0 0065 GLP10-01-01-05-115 DAL SS G P U DB 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-116 DAL SS GP12 0 0000 GLP10-01-01-05-117 DAL SS GP12 0 0005 GLP10-01-01-05-118 DAL SS GP12 0 0020 GLP10-01-01-05-119 DAL ss GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point Type QC QC STD Cono.(ng/mL) RT 9.979 10.111 10.162 10.027 11.157 10.549 10.156 10.073 10.157 10.073 10.204 10.064 3.0000 10.285 10.105 10.023 10.114 10.146 3.0000 10.161 Area Flags 338.03 bb 211.27 bb 319.16 bb 213.32 bb 408.93 MM 221.47 MM 277.83 bb 334.24 bb 354.47 bb 299.78 bb 226.62 MM 263.05 bb 326.77 bb 308.31 302.81 332.79 303.93 bb bb bb bb 345.04 bb ng/mL %Rec Mod Comment 3.30 110 2.07 69 3.12 104 2.09 70 4.00 133 2.17 72 b 2.72 91 3.27 109 3.47 116 2.93 98 2.22 74 ab 2.57 86 3.19 106 3.01 2.96 3.25 2.97 100 99 108 99 3.37 112 b Page 533 of 9 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:39:50 2010 Compound 6: MPFOS (Surr) Sample List: dl00908a Method File: dl00908a Coefficient of Determination: 0.999816 Calibration curve: -0.00275490 * x A2 + 81.7176 * x + -2.83385 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a001 dlQ0908a002 dl00908a003 dl00908a004 dl00908a005 dl00908a006 dl009Q8a007 dl00908a008 dl009Q8a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl00908a014 dl00908a01S dl009Q8a016 dl00908a017 dl00908a018 dl00908a019 dl00908a020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 dl00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dlQ0908a034 dl00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 dl00908a040 dl00908a041 dl00908a042 dl00908a043 dl00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 dl00908a051 dl00908a052 dl00908a053 dl009C8a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB -100831- 01 Method Blank 1 w/o IS MB-100831-04 Method Blank 4 w/ IS GLP10-01-01-05-070 DAL SS GP02 0 0020 GLP10-01-01-05-071 DAL SS GP02 DB 0020 GLP10-01-01-05-072 DAL SS GP02 0 0120 GLP10-01-01-05-073 DAL SS GP03 0 0000 GLP10-01-01-05-074 DAL SS GP03 0 0005 GLP10-01-01-05-075 DAL SS GP03 0 0020 GLP10-01-01-05-076 DAL SS GP03 DB 0020 GLP10-01- 01-05-077 DAL SS GP03 0 0050 GLP10-01-01-05-078 DAL SS GP04 0 0000 GLP10-01-01-05-079 DAL SS GP04 0 0005 GLP10-01-01-05-080 DAL SS GP04 0 0020 GLP10-01-01-05 -081 DAL SS GP04 0 0050 GLP10-01-01-05 -082 DAL SS GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05 -083 DAL SS GP05 0 0005 GLP10-01-01-05 -084 DAL SS GP05 0 0020 GLP10-01-01-05-085 DAL SS GP05 0 0055 GLP10-01-01-05-087 DAL SS GP06 0 0000 GLP10-01-01-05-088 DAL SS GP06 0 0005 GLP10-01-01-05-089 DAL SS GP06 0 0020 GLPlO-01-01-05-090 DAL SS GP06 0 0110 GLP10-01-01-05-091 DAL SS GP07 0 0000 GLPlO-01-01-05-092 DAL SS GP07 0 0005 GLPlO-01-01-05-093 DAL SS GP07 0 0020 GLP10-01-01-05-094 DAL ss GP07 0 0130 GLPI0-01-01-05-095 DAL ss GP08 0 0000 GLPI0-01-01-05-096 DAL ss GP08 0 0005 GLP10-01-01-05-097 DAL ss GP08 DB 0005 GLP10-01-01-05-098 DAL ss GP08 0 0020 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-099 DAL SS GP08 0 0050 GLP10-01-01-05-101 DAL SS GP09 0 0000 GLP10-01-01-05-102 DAL SS GP09 0 0005 Type STD Co n e .(ng/mL) RT Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard QC 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 10.453 10.762 10.673 10.758 10.751 10.659 10.621 10.751 10.932 10.765 10.628 10.841 10.532 10.448 10.714 10.709 11.104 10.630 10.675 10.587 10.677 10.812 10.768 10.716 10.637 10.540 10.767 10.719 10.716 10.627 10.714 10.848 10.588 10.066 10.678 10.671 10.670 10.762 10.676 10.673 10.674 10.590 10.636 10.809 10.936 10.761 10.803 10.802 10.631 10.0000 10.631 10.759 10.804 10.676 3MLStudy GLP10-01-Q2 tIantteedri9m/9/RieOpaonrtd_upori,nktea Area Flags 48.07 55.48 47.38 66.42 80.96 284.14 bb bbX bb bb bb bbX 448.86 3151.56 4189.44 8437.09 12782.58 40104.06 32.62 21.24 18.26 15.43 15.96 350.63 205.24 255.67 229.32 282.20 276.67 254.94 228.69 189.65 146.78 280.09 159.51 283.99 355.63 10.68 3554.65 16.34 250.69 351.52 175.64 289.36 291.32 368.44 354.70 287.71 255.36 244.21 182.52 268.15 254.50 321.95 306.72 bb bbx bb bb bbx bb bb bb bb bb bb bb bb bb bb bb bb bb MM bb bb bb MM bb bb bb bb bb bb bb MM bb bb bb bb bb bb bb bb bb bb bb bb 381.36 bb 314.89 233.19 222.54 bb bb bb ng/mL %Rec Mod Comment 0.62 0.71 0.61 0.85 1.03 3.51 357 123 113 103 140 5.53 38.65 51.39 103.64 157.29 499.20 0.43 0.29 0.26 0.22 0.23 4.33 2.55 3.16 2.84 3.49 3.42 3.15 2.83 2.36 1.83 3.46 1.99 3.51 4.39 0.17 43.60 0.23 3.10 4.34 2.18 3.58 3.60 4.54 4.38 3.56 3.16 3.02 2.27 3.32 3.15 3.97 3.79 55 155 103 104 79 100 174 b a a 4.70 47 3.89 2.89 2.76 Page 11 Pagete34 of 962 a\ Aw Jb,.. :'iim k y . -nfexn\ w s miwsraw Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: Last modified: Method: Last modified: Job Code: D :\masslynx\davey2010.PRO\SampleDB\dl00908a Wed Sep 08 11:46:49 2010 D:\masslynx\davey2010.PRO\MethDB\dl00908a Thu Sep 09 13:46:21 2010 Printed: Wed Oct 20 09:39:50 2010 Compound 6: MPFOS (Surr) Sample List: dl00908a Method Pile: dl00908a Coefficient of Determination: 0.999816 Calibration curve: -0.00275490 * x A2 + 81.7176 * x + -2.83385 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00908a058 dl00908a059 dl00908a060 dl00908a061 dl00908a062 dl00908a063 dl00908a064 dl00908a065 dl00908a066 dl00908a067 dl00908a068 dl00908a069 dl00908a070 dl00908a071 dl00908a072 dlOO 908a073 dl00908a074 dl00908a075 dl00908a076 dl00908a077 dl00908a078 dl00908a079 Samplelist ID GLP10-01- 01-05 -103 DAL SS GP09 DB 0005 GLP10-01- 01-05 -104 DAL SS GP09 0 0020 GLP10-01-01-05 -105 DAL SS GP09 0 0050 GLP10-01-01-05-106 DAL SS GP10 0 0000 GLP10-01- 01-05-107 DAL SS GP10 0 0005 GLP10-01-01-05 -108 DAL ss GP10 0 0020 GLP10-01-Q1-05-109 DAL ss GP10 0 0060 GLP10-01- 01-05 -111 DAL ss G P U 0 0000 GLP10-01- 01- 05 -112 DAL ss G P U 0 0005 GLP10-01- 01-05-113 DAL ss G P U 0 0020 GLP10-01- 01-05-114 DAL ss G P U 0 0065 GLP10-01- 01-05-115 DAL ss G P U DB 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01- 01-05-116 DAL ss GP12 0 0000 GLP10-01- 01-05-117 DAL ss GP12 0 0005 GLP10-01- 01- 05 -118 DAL ss GP12 0 0020 GLP10-01-01-05-119 DAL ss GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type QC QC STD Conc.(ng/mL) 25.0000 RT 10.760 10.891 10.942 10.806 11.980 11.154 11.110 10.854 11.022 10.854 10.940 10.886 10.893 11.020 10.884 10.715 10.893 11.013 10.0000 10.941 Area Flags 275 .24 bb 239..54 bb 409 .64 bb 206 .96 bb 256 .67 MM 315 .58 MM 264..08 MM 304..33 bb 307..16 bb 294 .24 bb 245..13 bb 230..80 bb 15 .53 bb 3381 .59 bb 332..72 318..42 358..90 296..63 bb bb bb MM 501..60 bb ng/mL %Rec Mod Comment 3 .40 2 .97 5 .05 2 .57 3 .18 ab 3 .90 b 3 .51 ab 3 .76 3 .79 3 .64 3 .03 2 .86 0 .22 41 .47 166 4 .11 3 .93 4 .43 3 .67 ab 6 .17 62 Page 12 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List* D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:39:S0 2010 Compound 7: 13C8 PFOS (IS) Sample List: dl00908a Response Factor: 77.3782 RRF SD: 8.77473, % Relative SD: 11.3401 Response type: External Std, Area Curve type : RF Method File: dl00908a Name dl00908a001 dl00908a002 dl00908a003 dl00908a004 dl00908a005 dl00908a006 dl00908a007 dl00908a008 dl00908a009 dl00908a010 dl00908a011 dl00908a012 dl00908a013 dl00908a014 dl00908a015 dl00908a016 dl00908a017 dl00908a018 dl00908a019 dl00908a020 dl00908a021 dl00908a022 dl00908a023 dl00908a024 dl00908a025 dl00908a026 dl00908a027 dl00908a028 dl00908a029 dl00908a030 dl00908a031 dl00908a032 dl00908a033 dl00908a034 dl00908a035 dl00908a036 dl00908a037 dl00908a038 dl00908a039 dl00908a040 dl00908a041 dl00908a042 dl00908a043 dl00908a044 dl00908a045 dl00908a046 dl00908a047 dl00908a048 dl00908a049 dl00908a050 dl00908a051 dl00908a052 dl00908a053 dl00908a054 dl00908a055 dl00908a056 dl00908a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB -100831- 01 Method Blank 1 w/o IS MB -100831- 04 Method Blank 4 w/ IS GLP10-01-01-05-070 DAL SS GP02 0 0020 GLP10-01- 01- 05 -071 DAL SS GP02 DB 0020 GLP10-01-01-05-072 DAL ss GP02 0 0120 GLP10-01-01-05-073 DAL ss GP03 0 0000 GLP10-01-01-05-074 DAL ss GP03 0 0005 GLP10-01-01-05-075 DAL ss GP03 0 0020 GLP10-01-01-05-076 DAL ss GP03 DB 0020 GLP10-01-01-05-077 DAL ss GP03 0 0050 GLP10-01-01-05-078 DAL ss GP04 0 0000 GLP10-01-01-05-079 DAL ss GP04 0 0005 GLP10-01-01-05-080 DAL ss GP04 0 0020 GLP10-01-01-05-081 DAL ss GP04 0 0050 GLP10-01-01-05-082 DAL ss GP05 0 0000 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 - GLP10-01-01-05-083 DAL SS GP05 0 0005 GLP10-01-01-05-084 DAL SS GP05 0 0020 GLP10-01-01-05-085 DAL SS GP05 0 0055 GLP10-01-01-05-087 DAL ss GP06 0 0000 GLP10-01-01-05-088 DAL ss GP06 0 0005 GLPlO-01-01-05-089 DAL ss GP06 0 0020 GLPlO-01-01-05-090 DAL ss GP06 0 0110 GLP10-01- 01-05-091 DAL ss GP07 0 0000 GLP10-01- 01-05-092 DAL ss GP07 0 0005 GLP10-01-01-05-093 DAL ss GP07 0 0020 GLP10-01-01-05-094 DAL ss GP07 0 0130 GLP10-01-01-05-095 DAL ss GP08 0 0000 GLP10-01-01-05-096 DAL ss GP08 0 0005 GLP10-01-01-05-097 DAL ss GP08 DB 0005 GLP10-01-01-05-098 DAL ss GP08 0 0020 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-099 DAL SS GP08 0 0050 GLP10-01-01-05-101 DAL SS GP09 0 0000 GLP10-01-01-05-102 DAL SS GP09 0 0005 Type STD Cone.(ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 0000 0000 0000 0000 0000 RT 11.027 10.377 10.817 10.641 10.770 10.762 10.627 10.762 10.632 10.762 10.944 10.733 10.640 10.809 11.022 10.808 10.812 10.641 10.687 10.598 10.688 10.780 10.779 10.684 10.648 10.552 10.780 10.731 10.728 10.638 10.682 10.164 10.599 10.690 10.639 10.638 10.774 10.687 10.684 10.687 10.645 10.605 10.821 10.861 10.816 10.771 10.769 10.642 11.158 QC 10.642 10.770 10.816 10.687 q u a n t i t i S ! V k ^ ) Jr i M . ( P i J d 1 f i y t ' ? l 0 / 2 0 / l 0 mnh i, Interim Report 05 srara Area Flags 16.88 bb 10.53 bb 216.46 bb 258.12 bb 191.38 bb 218.80 bb 266.70 bb 261.36 bb 222.15 bb 210.49 bb 254.96 MM 248.79 bb 195.20 bb 241.20 bb 16.85 bb 32.66 bb 10.78 bb 265.95 265.63 232.21 253.78 247.51 234.89 278.33 225.60 319.96 254.68 248.25 320.84 256.72 220.84 10.82 241.40 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 199.69 232.48 205.89 200.88 311.32 236.57 138.36 192.55 316.57 291.05 263.16 246.25 208.87 277.90 278.62 13.91 210.15 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 345.17 224.59 268.05 MM bb bb ng/mL %Rec 0.22 7 0.14 5 2.80 93 3.34 111 2.47 82 2.83 94 3.45 115 3.38 113 2.87 96 2.72 91 3.29 110 3.22 107 2.52 84 3.12 104 0.22 7 0.42 14 0.14 5 3.44 3.43 3.00 3.28 3.20 3.04 3.60 2.92 4.14 3.29 3.21 4.15 3.32 2.85 0.14 3.12 115 114 100 109 107 101 120 97 138 110 107 138 111 95 5 104 2.58 3.00 2.66 2.60 4.02 3.06 1.79 2.49 4.09 3.76 3.40 3.18 2.70 3.59 3.60 0.18 2.72 86 100 89 87 134 102 60 83 136 125 113 106 90 120 120 6 91 4.46 2.90 3.46 149 97 115 Page 13 Page 536 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Listi D t \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11i4 6 i49 2010 Methodt D i \masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13i4 i21 2010 Job Code I Printed: Wed Oct 20 09i39t50 2010 Compound 7i 13C8 PFOS (IS) Sample List: d!00908a Response Factor: 77.3782 RRF SD: 8.77473, % Relative SD: 11.3401 Response typei External Std, Area Curve type: RF Method File: d!00908a Name dl00908a058 dl00908a059 d!00908a060 dl00908a061 dl00908a062 dl00908a063 d!00908a064 dl00908a065 dl00908a066 dl00908a067 dl00908a068 dl00908a069 dl00908a070 dl00908a071 dl00908a072 dl00908a073 dl00908a074 dl00908a075 dl00908a076 dl00908a077 dl00908a078 dl00908a079 Samplelist ID GLP10-01-01- 05-103 DAL SS GP09 DB 0005 GLP10-01-01-05-104 DAL SS GP09 0 0020 GLP10-01-01-05-105 DAL SS GP09 0 0050 GLP10-01-01-05 -106 DAL ss GP10 0 0000 GLP10-01-01-05-107 DAL ss GP10 0 0005 GLP10-01-01-05-108 DAL ss GP10 0 0020 GLP10-01-01-05-109 DAL ss GP10 0 0060 GLP10-01-01-05-111 DAL ss G P U 0 0000 GLP10-01-01-05-112 DAL ss G P U 0 0005 GLP10-01-01-05-113 DAL ss G P U 0 0020 GLP10-01-01-05-114 DAL ss G P U 0 0065 GLP10-01-01-05-115 DAL ss G P U DB 0065 09004-182 80:20 ACN:H20 EC-100831-08 25 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-116 DAL ss GP12 0 0000 GLP10-01-01-05-117 DAL ss GP12 0 0005 GLP10-01-01-05-118 DAL ss GP12 0 0020 GLP10-01-01-05-119 DAL ss GP12 0 0170 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type OC OC STD Conc.(ng/mL) RT 10.772 10.859 10.910 10.774 11.948 11.165 11.078 10.865 10.990 10.865 10.952 10.897 3.0000 10.988 10.896 10.726 10.905 10.981 3.0000 10.909 Area Plags 161.81 bb 230.15 bb 294.56 bb 336.79 bb 215.00 MM 257.11 MM 291.93 MM 339.37 bb 248.16 MM 359.36 bb 272.57 bb 232.50 bb 269.41 bb 237.86 213.52 319.29 317.86 bb bb bb bb 277.08 bb ng/mL %Rec Mod Comment 2.09 70 2.97 99 3.81 127 4.35 145 2.78 93 3.32 111 ab 3.77 126 ab 4.39 146 3.21 107 b 4.64 155 3.52 117 3.00 100 3.48 116 3.07 2.76 4.13 4 .11 102 92 138 137 3.58 119 Page 14 Quantify Calibration Report GLP10-01-02-05 screening data Calibration! D:\masslynx\davey2010.PRO\CurveDB\dl00908a Last modified: Wed OCt 20 09:20:27 2010 Printed: Wed Oct 20 09:40:05 2010 Compound 1 name: PFBS Method File: d100908a Coefficient of Determination: 0.999395 Calibration curve: -0.0689062 * xA2 + 229.088 * x + 95.0285 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None /6 '4 - ge 1 Quantify Calibration Report GLP10-01-02-05 screening data Calibration! D:\masslynx\davey2010.PRO\CurveDB\dl00908a Last modified! Wed Oct 20 09i2027 2010 Printed: Wed Oct 20 09:40t05 2010 Compound 2 name: PFHS Method File: d100908a Coefficient of Determination: 0.999290 Calibration curve: -0.0274503 * xA2 + 176.227 * x + 115.051 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None 8.16e4n Page 2 Response- X 0.0o - * - 50.0 100.0 150.0 200.0 250.0 300.0 350.0 400.0 450.0 Cone 500.0 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D : \masslynx\davey2010.PRO\CurveDB\dl00908a Last modified: Wed Oct 20 09:20:27 2010 Printed: Wed Oct 20 09:40:05 2010 Compound 3 name: PFO S Method File: d100908a Coefficient of Determination: 0.999387 Calibration curve: -0.00787523 * xA2 + 140.661 * x + 37.7333 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None 6.87e4-i Response- Page 3 Quantify Calibration Report GLP10-01-02-05 screening data Calibration D:\masslynx\davey2010.PRO\CurveDB\dl00908a Last modified: Wed Oct 20 09:20:27 2010 Printed: Wed Oct 20 09:40:05 2010 Compound 4 name: 1 8 0 2 PFBS (IS) Method File: d100908a Response Factor: 166.164 ;RRF SD: 22.9916, % Relative SD: 13.8367 Response type: External Std, Area Curve type: RF 592n Response 3M Study G LP10-01-02 q u a n titifn {e riM iR epapta0 5 in te d 's. t ' ffe J ! * ok isz iikkY* ,ti Page 4 X X X 3 X X -- r ~ --i Cone 2.6 2.8 3.0 962Page 541 o f Quantify Calibration Report GLP10-01-02-05 screening data Calibrations D:\masslynx\davey2010.PRO\CurveDB\dl00908a Last modified! Wed Oct 20 09s20:27 2010 Printed Wed Oct 20 09:40:05 2010 Page 5 quantitated 9/9/10 and printed 10/20/1Q mmh', .1-. ` J A ". " #< f t Laivrir'-sr.'A\^rr. P ft. at- p i Quantify Calibration Report GLP10-01-02-05 screening data Calibration! D:\masslynx\davey2010.PRO\CurveDB\dlOO908a Last modified! Wed Oct 20 09t20i27 2010 Printed! Wed Oct 20 09i40i05 2010 3M Study G LP10-01-02 Page 6 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D:\masslynx\davey2010.PRO\CurveDB\dl00908a Last modified: Wed Oct 20 09:20:27 2010 Printed: Wed Oct 20 09:40:05 2010 Page 7 Page 544 of 962 lu3/.9/io tana ' Quantify Method Report Method File: D :\masslynx\davey2010.PRO\MethDB\dl00908a.mdb Last Modified: Thu Sep 09 13:46:21 20100 Printed: Wed Oct 20 09:18:40 2010 PFBS Internal Ref: 1802 PFBS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 9.119, Enabled RT Reference: [None] Peak Selection: Largest General Parameters Propagated Response Based On: Areas, Primary Polynomial Type: Quadratic Fit Weighting: 1/X Units: Integration parameters Propagated ApexTrack Integ: Disabled Peak-to-peak Amp: 98, Enabled Smoothing Enabled Wnd Size (scans): 2 Smoothing Method: Mean Peak Detection Standard Join Valley Thresh: 25.00 Raise B.line Max: 1.00 Detect Shoulders: Disabled Response Threshold Relative Height: 50.00, Disabled Relative Area: 3.00, Disabled Acq. Func. Number: 1 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.500 Response Type: Point of Origin: Axis Transform: External Exclude None Auto Noise Measure: Disabled Num. of Smooths: 1 Reduce Peak Tail: Draw Vert. Thresh: Shoulder Thresh: Absolute Height: Absolute Area: 60.00 5.00 5.00 0.00, Disabled 10.00, Enabled PFHS Internal Ref: 1802 PFHS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 9.824, Enabled RT Reference: (None] Peak Selection: Largest Integration Parameters Propagated Acq. Func. Number: 2 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 1.500 General Parameters Propagated PFOS Internal Ref: 13C8 PFOS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Pea): Location Ret. Time (mins): 10.616, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated Acq. Func. Number: 3 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 1.500 General Parameters Propagated 1802 PFBS (IS) Internal Ref: [None] Quantify Trace: TIC Cone, of Stds: Fixed User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 8.998, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated Acq. Func. Number: 6 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 1.800 General Parameters Propagated 1802 PFHS (IS) Internal Ref: [None] Quantify Trace: TIC Cone, of Stds: Fixed User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 9.798, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated Acq. Func. Number: 5 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 1.500 General Parameters Propagated MPFOS (Surr) Internal Ref: 13C8 PFOS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 10.598, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated Acq. Func. Number: 4 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 1.500 General Parameters Propagated 3M Study GLP10-01-02 Interim Report 05 ' 1 Page 545 of 962 Quantify Method Report Method File: D:\masslynx\davey2010.PRO\MethDB\dl00908a.mdb Last Modified: Thu Sep 09 13:46:21 20100 Printed: Wed Oct 20 09:18:40 2010 13C8 PFOS (IS) Internal Ref: [None] Quantify Trace: TIC Cone, of Stds: Fixed User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: S/N Quantify Flag: 08.. 000 to 0.00 mins Peak Location Ret. Time (mins): 10.631, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated Acq. Fune. Number: 7 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 1.500 General Parameters Propagated Page 2 ri*** 3M Study GLP10-01-02 Interim Report 05 Page 546 of 962 Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a001 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 547 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a001 Text: 5: 1802 PFHS (IS)________________________ 09004-182 80:20 ACN:H20 3M d100908a001 6: MPFOS (Surr) _____________ ___ Davey070799 09004-182 80:20 ACN:H20 08-Sep-2010 11:49:23 3M 5: MRM of 1 Channel ES- d100908a001 TIC 425 100- Page 2 Davey070799 08-Sep-2010 11:49:23 11.104: MRM of 1 Channel ESTIC 10.58 457 % 7: 13C8 PFOS (IS) 09004-182 80:20 ACN:H20 3M d100908a001 Time 74 Davey070799 08-Sep-2010 11:49:23 7: MRM of 1 Channel ES- TIC 445 Area Time 5JOO ^ moo ' i !oo Time Quantify Sample Report GLP10-01-2-Q5 screening data Sample Listi D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a002 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 3 Quantify Simple Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 ll:46s49 2010 Me thod: D t\mas slynx\davey2010.PR0\Me thDB\dl00908a Last modified! Thu Sep 09 13s46s21 2010 Job Codei Printed: Wed Oct 20 09s40sl7 2010 Names dl00908a002 Texts 7; 13C8 PFOS (IS) 09004-182 80:20 ACN:H20 3M d100908a002 Davey070799 08-Sep-2010 12:07:29 7: MRM of 1 Channel ESTIC 481 Area Time Page 4 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifieds Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a003 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page S Interim R eport 05 ' '' _t.iqnd .yj Page 551 tof 962 Quantify Sample Report 6LP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a003 Text: 5: 1802 PFHS (IS) ._ 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 6 N't Quantify Sample Report GLP10-01-02-05 screening data Sample List 9 D*\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 Ilt46t49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a004 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) V q u a n tit^^d ^.. _ Interim I Page 7 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a004 Text: 5: 1802 PFHS (IS) . 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3M Study G LP10-01-02. Page 8 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D :\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a005 Text: 1 : PFBS 2 : PFHS EC-100831-03 0.75 ng Extracted Curve Point Davey070799 3M 08-Sep-201013:01:49 d100908a005 1: MRM of 2 Channels ES- 3 : PFOS 4: 1802 PFBS (IS) Page 9 Quantify Sample Report GLP10-01-02-05 screening data Sample List! D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 Ili46>49 2010 Methodi D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a005 Text: Page 10 6 : MPPOS (Surr) EC-100831-03 0.75 ng Extracted Curve Point Davey070799 3M 08-Sep-201013:01:49 d100908a005 4: MRM of 1 Channel ES- TlCt 712j Area! 7: 13C8 PFOS (IS) EC-100831-03 0.75 ng Extracted Curve PointDavey070799 3M 08-Sep-201013:01:49 d100908a005 100 7: MRM of 1 Channel ES- 10.77 TIC 191 ] 1,26e3 Area % _ 2 g -f\/vyy\jyy\fV v\ / v v y ) f ^ y ^ f ^ : . 5.00 3M St udy G L P 1 0 -0 1-0 2----------------------Interim R eport 05 quantitated 9/9/10 a n d :priat:edvl0/20/10 mmh * 1 trv. . 10.'00 15.00 Time *AuP&kvWx'k', s . 5.00 10.00 'it 15.00 Time Page 556 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a006 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) 3M Study G LP10-01-02 Page 11 Page 557 of 962 guantix u i- *uc Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a006 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 12 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 ll:46s49 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a007 Text: 1: PFBS 2: PFHS Page 13 Report 05 10/ 20/10 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a007 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 14 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modified! Wed Sep 08 11:46:49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modifieds Thu Sep 09 13s46s21 2010 Job Code s Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a008 Text: Page 15 EC-100831-06 5 ng Extracted Curve Point Davey070799 EC-100831-06 5 ngExtracted Curve Point Davey070799 3M 08-Sep-2010 13:56:04 3M 08-Sep-2010 13:56:04 d100908a008 100i 1: MRM of 2 Channels ES- d100908a008 8.99 1252 TIC 100 5.95e3 10.00_ 999 I 2: MRM of 2 Channels ES- tic 5.04e3 Area Area %% 3: PFOS 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time q u a n titi ^i k R eport 05 10/20/10 nmh Page 561 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 1 1 i46!49 2010 Method! D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13:46i21 2010 Job Code i Printed: Wed Oct 20 09:40:17 2010 Namet dl00908a008 Text: 5: 1802 PFHS (IS) 6; MPFOS (Surr) 7: 13C8 PFOS (IS) Page 16 '/S k rtT Quantify Sample Report GLP10-01-02-05 screening data Sample Listt Dt\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ils46t49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13t46s21 2010 Job Codes Printeds Wed Oct 20 09s40sl7 2010 Names dl00908a009 Texts Is PFBS . 2: PFHS Page 17 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifieds Wed Sep 08 11:46:49 2010 Method! D i\masslynx\davey 2010. PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a009 Text: 7: 13C8 PFOS (IS) Page 18 6 : MPFOS (Surr) EC-100831-07 10 ng Extracted Curve Point Davey070799 3M 08-Sep-2010 14:14:09 d100908a009 100n i10.62 449 4: MRM of 1 Channel ESTIC 2.20e3 Area i% Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 ll:46i49 2010 MethodI Dt\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13i46:21 2010 Job Code i Printedt Wed Oct 20 09 i40:17 2010 Namet dl00908a010 Text: Page 19 EC-100831-08 25 ng Extracted Curve Point Davey070799 3M 08-Sep-201014:32:16 d100908a010 100- ] 9.91 5333 2: MRM of 2 Channels ES TIC 2.37e4 Area %- Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D\maeslynx\davey2010.PRO\SampleDB\dl00908a Last modified' Wed Sep 08 Ili46'49 2010 Method' Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13>46:21 2010 Job Code: Printed' Wed Oct 20 09>40'17 2010 Name' d!00908a010 Text' 5; 1802 PFHS (IS) 6: MPFOS (Surr) 7s 13C8 PFOS (IS) tuntitSMa i t f y G LP dl0f! SbO/aO^lO. mmh t.t - 5 Interim R e p o rt 05 Page 20 Quantify Sample Report GLP10-01-02-05 screening data Sample List* D* \masslynx\davey2010 .PRO\SampleDB\dlO0908a Last modifiedt Wed Sep 08 llt46:49 2010 Method < Di\masslynx\davey2010.PRO\MethDB\dl009 08a Last modifiedi Thu Sep 09 13:46:21 2010 Job Code t Printed: Wed Oct 20 09:40:17 2010 Name: d!00908a011 Text: 3: PFOS Page 21 EC-100831-09 50 ng Extracted Curve Point Davey070799 3M 08-Sep-2010 14:50:22 d100908a011 100- 10.14 9513 j 2: MRM of 2 Channels ESTIC 4.38e4 Area %- 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a011 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13CB PPOS (IS) EC-100831-09 50 ng Extracted Curve Point Davey070799 3M 08-Sep-201014:50:22 d100908a011 100 10.94 255 7: MRM of 1 Channel ESTIC 1.52e3 Area % 5.00 , .yvvv\-vJJsA A A A A A M fW v y ^ ^ - Tjm e 10.00 15.00 Page 22 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a012 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 23 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di \masslyxxx\davey2010 .PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11*46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Page 24 Name: dl00908a012 Text* 5: 1802 PFHS (IS) 6= MPFOS (Surr) EC-100831-10 100 ng Extracted Curve Point Davey070799 EC-100831-10 100 ng Extracted Curve Point Davey070799 3M 08-Sep-201015:08:30 3M 08-Sep-2010 15:08:30 d100908a012 100 5: MRM of 1 Channel ES- d100908a012 9.94 320 TIC 100 1.70e3 10.77 8437 4: MRM of 1 Channel ESTIC 3.80e4 Area Area %% 17 7: 13C8 PFOS (IS) 5.00 10.00 / x^^ v v ^ V A A a a a a Time 15!oO Time 5.00 10.00 15.00 3M Study G LP10-01-02 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified] Wed Sep 08 Ili46<49 2010 Method] Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13i46i21 2010 Job Codei Printed! Wed Oct 20 09]40il7 2010 Namet dl00908a013 Textt Page 25 EC-100831-11 200 ng Extracted Curve Point Davey070799 EC-100831-11 200 ng Extracted Curve Point Davey070799 3M 08-Sep-201015:26:36 3M 08-Sep-2010 15:26:36 d100908a013 100- 9.00 42939 ! 1: MRM of 2 Channels ES- d100908a013 TIC 100- 1.92e5 Area 9.88 34277 2: MRM of 2 Channels ES TIC 1.54e5 Area %- % 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) 5.00 A _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Time 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List D i \masslynx\davey201 0 .PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Method D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 094017 2010 Name dl00908a013 Text 5: 1802 PFHS (IS) Page 26 6: MPFOS (Surr) EC-100831-11 200 ng Extracted Curve Point Davey070799! 3M 08-Sep-2010 15:26:361 d100908a013 i 100n 10.63 12783 4: MRM of 1 Channel E S -! TIC1 5.54e4: Area %- 7; 13C8 PFOS (IS) EC-100831-11 200 ng Extracted Curve Point Davey070799 3M 08-Sep-2010 15:26:36 d100908a013 100- 10.64 195 7: MRM of 1 Channel ESTIC 1.20e3 Area % s j Z . ^\zvwI vI vr\-Aq wI sIAIAA' AI A' ^I AIyv'--v1--v'-%-'--v'-V-1-1-/vi-i-L'-j-j\'-/-V' V'VI-V-'-\A-'-A-'-A-'rVIvV'--,^'--/V' ^ TIM:,,M_C 5.00 10.00 15.00 Time 5.00 10.00 15.00 7|P agej572 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D :\masslynx\davey2010PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Page 27 Name: dl00908a014 Text: 1: PFBS EC-100831-12 500 ng E xtracted C urve P o in t 2: PFHS Davey070799 EC-100831-12 500 ng E xtracte d C urve P oint Davey070799 3M d100908a014 100n 9.25 97777] 08-S ep-201015:44:44 3M 1: MRM of 2 Channels ES- d100908a014 TIC 100-1 4.44e5 Area 10.04 816121 08-S ep-201015:44:44 2: MRM of 2 Channels ESTIC 3.67e5 Area %- %- 1 I 1 3: PFOS 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time interim R eport 'j10/20/10 mmh . Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a014 Text: Page 28 6: MPFOS (Surr) EC-100831-12 500 ng E xtracted C urve P o int Davey070799 3M 08-S ep-201015:44:44 d100908a014 100- 10.84 40104 4: MRM of 1 Channel ESTIC 1.73e5 Area %- 7: 13CB PFOS (IS) EC-100831-12 500 ng E xtracted C urve P o int Davey070799 3M 08-Sep-2010 15:44:44 1 - <D CO d100908a014 100 10.81 241 7: MRM of 1 Channel ES- Area - %- 5.00 10.00 15.00 Time 04 . I if*. : 1 ' i ' 1 1 1 i 1 1 1 Time 5.00 ' 10l00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D :\masslynx\davey2010.PRO\SampleDB\dl009Q8a Last modified! Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Marne: dl00908a015 Text: 1 : PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) Page 29 Page 5 7 5 0 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List Ot\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Hed Sep 08 Ils46i49 2010 Metbodt D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13!46i21 2010 Job Codei Printed! Wed Oct 20 09i40!l7 2010 Name: dl00908a01S Texti 5s 1802 PFHS (IS) . 6s MPFOS (Surr) 7s 13C8 PFOS (IS) Page 30 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11<46i49 2010 Method: D:\masslyux\davey2010.PRO\MethDB\dl0Q908a Last modified! Thu Sep 09 13:46i21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a016 Text: 1 : PFBS 2 : PFHS 3: PFOS . 4: 1802 PFBS (IS) Page 31 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslyox\davey2010.PR0\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dlO0908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a016 Text: 7 : 13C8 PFOS (IS) Page 32 Quantify Sample Report GLP10-01-02-05 screening data Sample List D\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modified Wed Sep 08 114649 2010 Method: O:\masslynx\davey2010.PRO\NethDB\dl00908a Last modified Thu Sep 09 13:46<21 2010 Job Code Printed Wed Oct 20 09:40:17 2010 Name: dl00908a017 Text: 1: PFBS 3: PFOS Page 33 2: PFHS 09004-182 80:20 A C N :H 20 3M d100908a017 Davey070799 08-Sep-2010 16:38:59 2: MRM of 2 Channels ES- 4: 1802 PFBS US ) 5.00 ' 1o!oO 1 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List* D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46*49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a017 Text: Page 34 6: MPFOS (Surr) 09004-182 80:20 A C N :H 20 3M d100908a017 Davey070799 08-Sep-2010 16:38:59 4: MRM of 1 Channel ES- 7: 13C8 PFOS (IS) quantitated 9./9/10 and printed 10/20/10 mmh Page 580 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 ll:46s49 2010 Method! D t \masslynx\davey2010.PRO\MethDB\dl009O8a Last modified! Thu Sep 09 13:46t21 2010 Job Code! Printed: Wed Oct 20 09:40il7 2010 Name I dl00908a018 Text! 1: PPBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) 3M Study G LP10-01-02 * u* n " t f r t e tsSr.m' K .. p d * o s ^ t o 10/2 Page 35 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a018 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Time Page 36 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a019 Text: 1 : PFBS 2 : PFHS Page 37 3 M S tu d y G L P 1 0 -0 1 -0 2 .q u a n titM e riW R e p O r t< 0 5 rin te d 1 0/2 0 /1 0 ,, ft -s fe Page 583 o f 962 i Quantify Sample Report GLP10-01-02-05 screening data Sample List* Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ils46s49 2010 Methods Dt\masslynx\davey2010.PRO\MethDB\dl00908a Last modifieds Thu Sep 09 13s46s21 2010 Job Codes Printed! Wed Oct 20 09s40sl7 2010 Names dl00908a019 Texts 7: 13C8 PFOS (IS) Page 38 Quantify Sample Report GLP10-01-02-05 screening data Sample List: 0< \masslynx\davey201Q.PRO\SampleDB\dlQ0908a Last modified: Wed Sep 08 11*46:49 2010 Method* D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13*46:21 2010 Job Code: Printed: Wed Oct 20 09*40:17 2010 Name* dl00908a020 Text: 1: PFBS ' 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 39 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 06 Ili46i49 2010 Method : D:\masslynx\davey2010 .PRO\MethDB\dl00908a Last modified! Thu Sep 09 13i46i21 2010 Job Code t Printed! Wed Oct 20 09:40il7 2010 Name: dl00908a020 Text: 5; 1802 PFHS (IS) MB-100831 -04 Method Blank 4 w/ IS 3M d100908a020 100 9.81 311 6: MPFOS (Surr) Davey070799 MB-100831 -04 Method Blank 4 w/ IS 08-Sep-2010 17:33:17 3M 5: MRM of 1 Channel ES- d100908a020 TIC 1.69e3 100- 10.63 351 Area Page 40 Davey070799 08-Sep-2010 17:33:17 4: MRM of 1 Channel ES- TIC 1.84e3 Area %% 7: 13C8 PFOS (IS) 5.00 lav 'v!---v y v v '' 10.00 15.00 Time Time 5.00 10.00 15.00 P a g e 5 8 6 p fj6 2 ^ i Quantify Sample Report GLP10-01-02-0S screening data Sample List; D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: - Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a021 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) . e k (P ^ o S ^ t S ^ lO /J O /lO In te rim R e p o rt 0 . i '' Page 41 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D s \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 Ils46s49 2010 Methods D s \masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13s46t21 2010 Job Code: - Printeds Wed Oct 20 09:40sl7 2010 Names dl00908a021 Texts 5: 1802 PPHS (IS) Page 42 6: MPFOS (Surr) GLP10-01-01 -05-070 DAL SS GP02 0 0020 Davey070799 3M 08-Sep-201017:51:23 d100908a021 4: MRM of 1 Channel ES- 7: 13C8 PFOS (IS) IQ10. quantit^ ' - n R e b 'O tt 0 5 muta \ ^i . , V . 'P a g e 5 8 8 o f 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List D \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:46*49 2010 Method D \masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13:46*21 2010 Job Code Printed Wed Oct 20 09:4017 2010 Name d!00908a022 Text 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 43 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 11*46*49 2010 Method* D * \masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46*21 2010 Job Code* Printed* Wed Oct 20 09*40*17 2010 Name* dl00908a022 Text* 7: 13C8 PFOS (IS) Page 44 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a023 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 45 _ica tl. 9/9 /UOr-Anc P age 591 o f 962 '' Quantify Sample Report GLP10-01-02-05 screening data Sample List* D*\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 134621 2010 Job Codes Printed Wed Oct 20 09:40sl7 2010 Names dl00906a023 Texts 5: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 46 6; MPFOS (Surr) GLP10-01 -01 -05-072 DAL SS GP02 0 0120 Davey070799 3M 08-Sep-2010 18:27:33 d100908a023 100n 10.68 229 4: MRM of 1 Channel ESTIC 1.05e3 Area % 15 / \ W v^ v W W V v v v 'w v ^ ' 5.00 10.00 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 Quantify Sandle Report GLP10-01-02-05 screening data Sample Lists Dt \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ili46t49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modifieds Thu Sep 09 13:46i21 2010 Job Codes Printeds Wed Oct 20 09s40sl7 2010 Names dl00908a024 Texts Is PFBS 2s PFHS 3: PFOS 4: 1802 PFBS (IS) 2 l0 / _ 2 0 / 1 0 mmh Page 47 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ilt46i49 2010 Method: DI\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Page 48 Marne: dl00908a024 Text: 5: 1802 PFHS (IS) 6; MPFOS (Surr) GLP10-01 -01 -05-073 DAL SS GP03 0 0000 Davey070799 GLP10-01-01 -05-073 DAL SS GP03 0 0000 Davey070799 3M 08-Sep-2010 18:45:38 3M 08-Sep-2010 18:45:38 d100908a024 5: MRM of 1 Channel ES- d100908a024 TIC 100 1.67e3 4: MRM of 1 Channel ES- 10.81 TIC 282 1,56e3 Area Area % 7: 13C8 PFOS (IS). Time 23 5.00 10.00 15.00 Time In te rim R e p o rt 0 5 t quantitated 9/9/10 and printed lQ/^MtliftiiinDhs # 1 Kr f Lquantit^te itlljSS1 '` `IRiii' Page 594 o f 962 : ..quantitate. \ \4 ' Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 lls46:49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13s46>21 2010 Job Codes Printed! Wed Oct 20 09:40:17 2010 Names dl00908a025 Texts 1: PFBS 2: PFHS Page 49 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Dt\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifieds Wed Sep 08 Ils46s49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13:46s21 2010 Job Codes Printeds Wed Oct 20 09s40sl7 2010 Names dl00908a025 Texts 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 50 Quantify Sample Report GLP10-01*02-05 screening data Sample List: D*\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 11*46*49 2010 Method* D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46*21 2010 Job Code* Printed* Wed Oct 20 09*40*17 2010 Name* dl00908a026 Text* Page 51 GLP10-01 -01 -05-075 DAL SS GP03 0 0020 Davey070799 GLP10-01 -01 -05-075 DAL SS GP03 0 0020 Davey070799 3M 08-Sep-2010 19:21:47 3M 08-Sep-2010 19:21:47 d100908a026 100- 9.04 _ 10269 1:MRM of 2 Channels ES- d100908a026 TIC 4.68e4 100- 9.83 56524 i 2:MRM of 2 Channels ESTIC 2.22e5 Area Area %- %- 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-0S screening data Sample Listi Dt\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ilt46t49 2010 MethodI Dt\masslynx\davey2010.PRO\MethDB\dlOQ908a Last modifiedt Thu Sep 09 13t46i21 2010 Job Code : Printed: Wed Oct 20 09i40il7 2010 Namei dl00908a026 Text! 5: 1802 PFHS (IS) 6s MPFOS (Surr) 7 : 13C8 PFOS (IS)_______________________________________________________________________________ ______ IGLP10-01-01 -05-075 DAL SS GP03 0 0020 Davey070799 3M 08-Sep-201019:21:47 Id100908a026 7: MRM of 1 Channel ES- Page 52 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt Ds\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Methods Dt \masslynx\davey2010. PRO\MethI>B\dl00908a Last modified: Thu Sep 09 13:46t21 2010 Job Code: Printed Wed Oct 20 09:40:17 2010 Name: dl00908a027 Text: Page S3 GLP10-01 -01 -05-076 DAL SS GP03 DB 0020 Davey070799 3M 08-Sep-2010 19:39:56 d100908a027 100 9.84 69497 2: MRM of 2 Channels ESTIC 2.74e5 Area %- Time 5.00 10.00 15.00 4: 1802 PFBS (IS) GLP10-01 -01 -05-076 DAL SS GP03 DB 0020 Davey070799 GLP10-01 -01 -05-076 DAL SS GP03 DB 0020 Davey070799l 3M 0 8 -S e p -2 0 1 0 19:39:56 3M 08-Sep-201019:39:56j d100908a027 100- 3: MRM of 2 Channels ES- d100908a027 10.63 208195] TIC 7.85e5 100- 6: MRM of 1 Channel ES9.03 TIC 318 1.74e3 Area Area %- % 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 ` j ^ g u a n t i t l n ^ p j m R g p Q r t u r *'t e - f ! w Inn^ 1 10.00- U 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D :\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:46:49 2010 Method: D :\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a027 Text: 5: 1802 PFHS (IS) Page 54 ' 6: MPFOS (Surr) G LP 10-01 -01 -05-076 D A L SS 3M d100908a027 100 GP03 DB 0020Davey070799 08-Sep-2010 19:39:56 4: MRM of 1 Channel ES- 10.64 TIC 229 1 1.31e3 Area % 7; 13C8 PFOS (IS) G L P 1 0-01 -01 -05-076 D A L SS GP03 D B 0020 D avey070799 3M 08-S ep-201019:39:56 d100908a027 100 10.65 226 I 7: MRM of 1 Channel ESTIC 1.23e3 Area 10.0021 ,VvM f V v v v V ' f t T O A ' v y ; . - ' A / ' W w v ' 5.00 Time'VNA/VV-^V\AA/C/\r^'/ T - _ -i....-i- t - t- t--r.....i . 15.00 % 22 5.00 10.00 q ua nltltS M jS iW S ty l. P L ^ IQ r Q A E i.lO /a q /io .iiim li f . ' In te rim R e p o rt 0 5 1 jR \' 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List D>\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a028 Text: 1: PFBS 2: PFHS Page SS 3 M S tu d y G L P 1 0 -0 1 -0 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Ds \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 Ils46s49 2010 Methods O s \m a s s l y n x \ d a v e y 2 0 1 0 .PR O \ M e t h D B \ d l 0 0 9 0 8 a Last modifiedi Thu Sep 09 13:46s21 2010 Job Codes Printeds Wed Oct 20 09:40sl7 2010 Names dl00908a028 Texts 5: 1802 PFHS (IS) 6s MPFOS (Surr) 7s 13C8 PFOS (IS)______________________________________________________________________________ G LP 10-01 -01-05-077 D A L SS GP03 0 0050 Davey070799 3M 08-Sep-2010 19:58:03 d100908a028 7: MRM of 1 Channel ES- Page 56 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dlO0908a Last modifiedi Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Marne: dl00908a029 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 57 Quantify Sample Report GLP10-01-02-05 screening data Sample List> D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D :\masslynx\davey2010.PRO\MethDB\dlO0908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a029 Text: Page 58 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modifiedi Wed Sep 08 Ili46:49 2010 Methodt D t \masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 1 3 i46:21 2010 Job Codet Printed Wed Oct 20 09i40:17 2010 Name: dl00908a030 Text: 1: PFBS ' 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 59 MV-/a.0 a&d.'i.rjU. -u. % I t P a g e 6 0 5 o f 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11:46:49 2010 Methods D s\masslynx\davey2010.PRO\MethDB\dlO0908a Last modified! Thu Sep 09 13s46<21 2010 Job Code s Printed! Wed Oct 20 09:40sl7 2010 Name: dl00908a030 Text: S: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 q u i m t i t a i n r i W R e p o r t 0 5 in t e a 10/20/10 mmh i Page 60 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D: \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a031 Text: 1 : PFBS 2 : PFHS Page 61 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Method Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13:4621 2010 Job Code: Printed: Wed Oct 20 09:4017 2010 Name dl00908a031 Text 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 62 Quantify Sample Report GLP10-01-Q2-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dlOQ908a Last modified! Wed Sep 08 ll46t49 2010 Methodt D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13t46i21 2010 Job Code t Printedt Wed Oct 20 09s40>17 2010 Namei dl0090Sa032 Text! Is PFBS 2: PFHS 3s PFOS 4: 1802 PFBS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 63 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 1 1 i4 6 i49 2010 Methods D \masslynx\davey2010.PRO\NethSB\dl00908a Last modified! Thu Sep 09 13s46i21 2010 Job Code: Printed! Wed Oct 20 09s40sl7 2010 Names dl00908a032 Texts 5: 1802 PFHS (IS) 6s MPFOS (Surr) 7: 13C8 PFOS (IS) Page 64 Quantify Sample Report GLP10-01>02>05 screening data Sample Listi D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ilt46i49 2010 Method D t \masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13i46i21 2010 Job Codei Printed! Wed Oct 20 09i40il7 2010 Namei dl00908a033 Text I 1: PFBS 2 : PFHS Page 65 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D : \ m a s s l y n x \ d a v e y 2 0 1 0 .PRO\ M e t h D B \ d l 0 0 9 0 8 a Last modifiedi Thu Sep 09 13:46:21 2010 Job C o d e : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a033 Text: 5: 1802 PFHS (IS) 6= MPFOS (Surr) 7: 13C8 PFOS (IS) Page 66 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 Ili46>49 2010 Me thod: D <\masslynx\davey2010.PR0\MethDB\dl00908a Last modifiedt Thu Sep 09 13t46t21 2010 Job Code: Printedt Wed Oct 20 09:40tl7 2010 Namet dl00908a034 Text: 1: PFBS 2: PFHS 3: PFOS 4s 1802 PFBS (IS) Page 67 Quantify Sample Report GLP10-01-02-05 screening data Sample List Ds\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a034 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 68 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: W e d Sep 08 1 1 i4 6 i49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a035 Text: 1 : PFBS 2 : PFHS 3= PFOS 4: 1802 PFBS (IS) Page 69 / 2 0 , '. i ( ^ ) i u n t i t 3 M S u d y l P L i1l3 Q lt & ? 1 0 /2 0 /1 0 - n ` *' ` T In te rim R e p o rt 0 5 -i-itated 9/9/10 i . Page 615 o f 962 ` Quantify Sample Report GLP10-01-02-0S screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Methods D s \ m a s s l ynx\davey2010.P R O \Meth D B \ d l O O 908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a035 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 i Page 70 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifieds Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a036 Text: 1: PFBS 2: PFHS Page 71 * 4: 1802 PFBS (IS) 09004-182 80:20 ACN:H20 3M d100908a036 Davey070799 08-Sep-2010 22:22:50 6: MRM of 1 Channel ES- 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt 0:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified; Wed Sep 08 11;4649 2010 Methodi D s\mas8lynx\davey2010.PR0\MethDB\dl00908a Last modified; Thu Sep 09 13;46;21 2010 Job Codei Printed; Wed Oct 20 09:40;17 2010 Name; dl00908a036 Text; Page 72 ' Quantify Sample Report GLP10-01-02-05 screening data S am ple L is t D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 09 0 8a L a s t m o d if ie d : Wed Sep 08 1 1 :4 6 :4 9 2010 M ethod: D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M eth D B \d l0 0 90 8a L a s t m o d ifie d : Thu Sep 09 1 3 :4 6 :2 1 2010 Job Code: P rin te d : Wed O c t 20 0 9 :4 0 :1 7 2010 Name: d l0 0 9 0 8 a 0 3 7 T e x t: 1: PFBS 2: PFHS Page 73 * y q u a n t i t M d S y ^ y i ^ k ^ 1 0 - 0 1 - 0 2 1 0 / 2 0 / 1 0 mmh Page 619 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a037 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 74 Quantify Sample Report GLP10-01-02-05 screening data Sample List* Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethPB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a038 Text: 1: PFBS 2: PFHS Page 75 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a038 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 76 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Page 77 Name: dl00908a039 Text: 1: PFBS 2 : PFHS_____________________________________________________________________ _________________________ IGLP10-01 -01 -05-085 DAL SS GP05 0 0055 Davey070799 GLP10-01 -01 -05-085 DAL SS GP05 0 0055 Davey070799 3M 08-Sep-2010 23:17:11 3M 08-Sep-2010 23:17:11 d100908a039 1: MRM of 2 Channels ES- d100908a039 100"i 9.83 9901] 2: MRM of 2 Channels ESTIC 3.96e4 Area %- 3: PFOS 2 4: 1802 PFBS (IS) ioo - A - v" - `--i - Time 10.00 15.00 q u a n t i t A e L ^ H ^ ' O ^ k S l& P n t- K ^ .lO /iO /a iO . mmh : In te rim R e p o rt 0 5 V 'and iPbnTia-ted ' - Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D t \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a039 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS {IS) quantitated 9/9/10 ai^l.printed^l0/20/10 mmh 1 A; .tfiS t- i Page 78 Page 624 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds \masslynx\davey2010.PRO\SampleOB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Methods D:\mas8lynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13s46<21 2010 Job Codes Printedi Wed Oct 20 09:40:17 2010 Page 79 Names d!00908a040 Texts 1: PFBS 2: PFHS GLP10-01 -01 -05-087 DAL SS GP06 0 0000 Davey070799 GLP10-01 -01-05-087 DAL SS GP06 0 0000 Davey070799 3M 08-Sep-2010 23:35:16 3M 08-Sep-2010 23:35:16 d100908a040 1: MRM of 2 Channels ES- d100908a040 2: MRM of 2 Channels ES- 3: PFOS 4: 1802 PFBS (IS) in aod^p: Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 1 1 i4 i49 2010 Method! Di \masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13t46>21 2010 Job Code i Printed! Wed Oct 20 09 i4 0 i17 2010 Namei dl00908a040 Text: 5s 1802 PFHS (IS) 6: MPFOS (Surr) Page 80 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a041 Text: 1: PFBS 2 : PFHS Page 81 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified* Wed Sep 08 11*46*49 2010 Method* D*\masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46:21 2010 Job Code * Printed* Wed Oct 20 09*40*17 2010 Name* dl00908a041 Text* 5s 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 82 6: MPFOS (Surr) GLP10-01 -01 -05-088 DAL SS GP06 0 0005 Davey070799 3M 08-Sep-2010 23:53:24 d100908a041 4: MRM of 1 Channel ES- 100~i 10.68 291 ] TIC 1.69e3 Area %- Time 5.00 10.00 15.00 Page 628 o f 962 1 /' Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 ll:46i49 2010 MethodI D t \masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13:46i21 2010 Job Code : Printed! Wed Oct 20 09i40il7 2010 Name: dl00908a042 Text! 1: PFBS 2: PFHS Page 63 q u a n t i t S M d S i V ^ y ^ U ^ ^ ^ i Q i t Q 2 1 0 / 2 0 / 1 0 mmb in fa h fri R e p o rt Q5 V IA ' A Page 629 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11 i4 6 i49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: d!00908a042 Text: 5: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 84 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 1 1 i4 6 i49 2010 Methodi Di\ma8Slynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 1 3 i4 6 i21 2010 Job Code : Printed: Wed Oct 20 09t40il7 2010 Namet dl00908a043 Textt 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 85 Quantify Sample Report GLP10-01-02-05 screening data Sample List D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:46:49 2010 Method: D: \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a043 Text: 7: 13C8 PFOS (IS) Page 86 G L P 1 0 - 0 1 0 2 1 0 / 2 0 / 1 0 inaflted.,.9lS /1.0 " 1 In te rim R e p o rt 0 5 ;, f - ' 1 ` .citated 9/9/10- i . icit&ted 9/9/10 Page 632 o f 962 -,f' ' Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Me thod: D :\mas slynx\davey2010.PR0\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a044 Text: 1 : PFBS 3: PFOS Page 87 GLP10-01 -01 -05-091 DAL SS GP07 0 0000 Davey070799 3M 09-Sep-2010 00:47:42 d100908a044 100- 9.84 4369 2: MRM of 2 Channels ESTIC 1.85e4 Area % 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D * \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46>49 2010 Me thodI O t\mas slynx\davey2010.PROVMe thDB\dl00908a Last modifiedi Thu Sep 09 13t46i21 2010 Job Code: Printedi Wed Oct 20 09:40il7 2010 Name: dl00908a044 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 88 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11:46*49 2010 Method D s \masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13:46t21 2010 Job Code Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a045 Text: 1: PFBS 2: PFHS Page 89 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.FRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Codei Printed: Wed Oct 20 09:40:17 2010 Name: d!00908a045 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 90 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl0090Sa Last modified! Wed Sep 08 Ils46t49 2010 Methods D : \ m a s s l y n x \ d a v e y 2 0 1 0 . PR O \ M e t h D B \ d l 0 0 9 0 8 a Last modified: Thu Sep 09 13:46:21 2010 Job Codes Printedi Wed Oct 20 09t40sl7 2010 Name: dl00908a046 Text: 1: PFBS 2: PFHS 3: PFOS 4s 1802 PFBS (IS) Page 91 Quantify Sample Report GLP10-01-02-05 screening data Sample List; Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified; Wed Sep 08 11:46:49 2010 Method; Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified; Thu Sep 09 13:46:21 2010 Job Code: , Printed: Wed Oct 20 09;40;17 2010 Name; dl00908a04 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 92 3 M S tu d y G L P 1 0 -0 1 -0 2 10/20/10 mmh " .,V_i ia teM fe- ft 3t 'n - P age 6 3 8 o f 962 Quantify Sample Report GLP10-01-02-Q5 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Il:46i49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a047 Text: 1: PFBS Page 93 GLP10-01-01 -05-094 DAL SS GP07 0 0130 Davey070799 3M 09-Sep-2010 01:41:58 d100908a047 2: MRM of 2 Channels ES- 100 10.05 20252 TIC 8.13e4 Area %- Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Ds \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Il>46s49 2010 Method! D! \masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13:46121 2010 Job Codei Printed! Wed Oct 20 09:40il7 2010 Name: dl00908a047 Text: 5: 1802 PFHS (IS) 6s MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 94 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified* Wed Sep 08 Il:46i49 2010 Methodt D t \masslynx\ d a v e y 2 0 1 0 .P R O \ M e t h D B \ d l O 0 9 0 8 a Last modified: Thu Sep 09 13:46i21 2010 Job Codei Printedi Wed Oct 20 09:40il7 2010 Names dl00908a048 Texts 1: PFBS 3: PFOS Page 95 2 : PFHS__________________________ ___________________________________ ___________________ ____________ GLP10-01 -01 -05-095 DAL SS GP08 0 0000 Davey070799 3M 09-Sep-2010 02:00:02 d100908a048 10On 10.01 19551 2: MRM of 2 Channels ESTIC 8.17e4 Area %- 1 4s 1802 PFBS (IS) 5.00 -- ' -r i . .-i Time 10.00 15.00 xruanfcitatd .(9/ P age 641 o f 9 6 % : ; ' =.-i Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: d!00908a048 Text: 5: 1802 PFHS (IS) 6: MPFOS {Surr) Page 96 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Dt\masslynx\davey2010.PRO\SampleDB\dlOO908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a049 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) d ^ 0 / ; 2 0 y|1 0 '. 1 0 / 2 0 / 1 0 mmh Page 97 f#43 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11i46i49 2010 Methodi Dt\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13i46i21 2010 Job Code! Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a049 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) ^ Page 96 7: 13C8 PFOS (IS) q u a n t it 3 M dS U d^L G L p 1 8 0 l t 2 tl (f2O /lO .in m b In te rim R e p o rt T ' /lO -'a b S i Quantify Sample Report GLP10-01-02-05 screening data Sample List: Dt\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Hed Sep 08 11:46:49 2010 Method: D:\masslymc\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a0S0 Text: 1: PFBS 3: PFOS Page 99 G L P 1 0-01 -01 -05-097 D A L SS G P08 D B 0005 Davey070799 3M 09-Sep-2010 02:36:17 d100908a050 100n 10.05 2073 2: MRM of 2 Channels ESne 9.15e3 Area %. 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List* D*\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified* Wed Sep 06 11*46*49 2010 Method* D * \ m a s 8 l y n x \ d a v e y 2 0 1 0 .P R O \ M e t h D B \ d l O O 908a Last modified* Thu Sep 09 13*46*21 2010 Job Code * Printed* Wed Oct 20 09*40*17 2010 Page 100 Name* dl00908a050 Text* 5: 1802 PFHS (IS) 6: MPFOS (Surr) G L P 1 0-01 -01 -05-097 D A L SS G P08 DB 0005 D avey070799 G LP 10-01 -01 -05-097 D A L SS G P08 D B 0005 Davey070799 3M 09-Sep-2010 02:36:17 3M 09-Sep-2010 02:36:17 d100908a050 100 10.07 383 1 5: MRM of 1 Channel ES- d100908a050 TIC 100 2.11e3 Area 10.80 322 4: MRM of 1 Channel ESTIC 1,64e3 Area %% 14 7s 13C8 PFOS (IS) 5.00 10.00 15.00 Time 18 5.00 ' ' -- j - f '- ' - f , ' 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed* Wed Oct 20 09:40:17 2010 Name: d!00908a051 Text: 1 : PFBS 2 : PFHS Page 101 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: d!00908a051 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) In te rim R e p o rt 0 5 quantitated 9/9/10 and printed lO/fiO/.lO.mmhJi\ Page 102 Page 648 o f 962 - ; 'f Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 0940>17 2010 Name: dl00908a052 Text: 1: PFBS 2: PFHS Page 103 ,iq u a n ti P U t d 1 0 - 0 1 - 0 2 1 0 / 2 0 / 1 0 mmhV ' I n t e r i m R e p o r t 0 5 1' Page 649 o f 96~2i " f " ' " Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ils46i49 2010 Methods D s\masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13:46s21 2010 Job Codes Printed Wed Oct 20 09s40sl7 2010 Names dl00908a052 Texts 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) - In te rim R e p o rt 0 5 o/lCL rmguantitated 9/9/10 andaprif Page 104 Page 650 o f 962 )i Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 Ils46s49 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13s46s21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Names dl00908a053 Texts 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 105 Quantify Sample Report GLP10-01-02-05 screening data Sample List D*\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modified* Wed Sep 08 11*46*49 2010 Methods D*\masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46*21 2010 Job Code* Printed* Wed Oct 20 09*40*17 2010 Names dl00908a053 Texts 7: 13C8 PFOS (IS) ^iv/i c t i i/-i\/ n i D in _ m _ r lo Page 106 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 Ili46t49 2010 Method i Dt \masslynx\davey2010. PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 094017 2010 Name dl00908a054 Text 1 S PFBS 2: PFHS Page 107 iH quantity io/20/io -- p a g e 6 5 3 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\HethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a054 Text: 5: 1802 PFHS (IS) Page 108 6j MPFOS (Surr) __________________________ 09004-182 80:20 ACN:H20 3M d100908a054 100- 193 1.36 2.80 4M a Ai1 % Davey070799 09-Sep-2010 03:48:48 4: MRM of 1 Channel ES- 11.33 12.20 TIC 16.51 331 * 1424 16.94 16.33 ' r 75 Time 5.00 10.00 15.00 3 M S tu d ' G L P 1 0 -0 1 -0 2 quanti ta ted,9 / -1 0 andiprinted 1 0 / 2 0 / 1 0 m a h Quantify Sample Report GLP10-01-02-05 screening data Sample List: D :\masslyxuc\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a055 Text: 1 : PFBS 3: PFOS Page 109 GLP10-01 -01 -05-099 DAL SS GP08 0 0050 Davey070799 3M 09-Sep-2010 04:06:58 d100908a055 100- 2: MRM of 2 Channels ES- 9.96 TIC 2131 9.36e3 Area % 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-0S screening data Sample List: D \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 1146:49 2010 Method D \masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 094017 2010 Name: dl00908a055 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS)________________________ ____________________________________________________________ GLP10-01-01-05-099 DAL SS GP08 0 0050 Davey070799 3M 09-Sep-2010 04:06:58 d100908a055 7: MRM of 1 Channel ES- Page 110 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D\masslynx\davey2010.PRO\SampleDB\dlO0908a Last modified* Wed Sep 08 11*46*49 2010 Method* Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46*21 2010 Job Code* Printed* Wed Oct 20 09*40*17 2010 Name: dl00908a056 Text: Page 111 GLP10-01-01-05-101 DAL SS GP09 0 0000 Davey070799 GLP10-01 -01 -05-101 DAL SS GP09 0 0000 Davey070799 3M 09-Sep-2010 04:25:07 3M 09-Sep-2010 04:25:07 d100908a056 100- 1: MRM of 2 Channels ES- d100908a056 9.26 TIC 3722 1.69e4 1 0 0 - 10.01 39934] 2: MRM of 2 Channels ESTIC 1.58e5 Area Area %- %- 3: PFOS 5.00 10.00 15.00 Time 5.00 -1A0.00- 15.00 Time 4: 1802 PFBS (IS) Quantify Sample Report GLP10-01-02-05 screening data Sanq>le Listi D*\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a0S6 Text: 5: 1802 PFHS {IS) 6: MPFOS {Surr) Page 112 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o ft 0 5 quantitated 9/A/lp^aniLprinted 10/20/10 ssnl. s 'l l : ;riated.\li. ; Paae 658 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ilt46i49 2010 Methodt Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13i46t21 2010 Job Codet Printed! Wed Oct 20 09i40il7 2010 Namet dl00908a057 Texti 1: PFBS 2 : PFHS GLP10-01 -01-05-102 DAL SS GP09 0 0005 Davey070799 3M 09-Sep-2010 04:43:13 d100908a057 1: MRM of 2 Channels ES- 3s PFOS 4: 1802 PFBS (IS) Page 113 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11146:49 2010 Method: D:\ma88lynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13:46i21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a057 Text: 7: 13C8 PFOS (IS) q u a n tit^ i^ d ^ ly i ' *' 1 re p o rt r 1 0 / 2 0 / 1 0 mmh Page 114 Quantify Sample Report GLP10-01-02-05 screening data Sample List< D t\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ili46>49 2010 Method > D t\masslynx\davey2 0 1 0 .PRO\MethDB\dlO 0908a Last modified Thu Sep 09 1 3 t 4 6 i 2 1 2 0 1 0 Job Code: Printed! Wed Oct 20 0 9 i40>17 2010 Namei dl00908a058 Text! 1: PPBS 2: PFHS 3s PFOS 4: 1802 PFBS (IS) Page 115 quantitate* 9/9/^jO and printed ./a m &A - j i - tad ,9/,9/i Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a058 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 .v - h t^ n a n tl^ ilB ta r im s R a p a ^ ^ in ta d 1 0 /2 0 /1 0 Page 116 Quantify Sample Report GLP10-01-02-05 screening data Sample List Dx\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ilt46t49 2010 Method] D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13x46i21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a059 Text: 1: PFBS 3: PFOS Page 117 2 : PFHS________________________________________________________________ _ _ _ __________________________ GLP10-01 -01 -05-104 DAL SS GP09 0 0020 Davey070799 3M 09-Sep-2010 05:19:26 d100908a059 2: MRM of 2 Channels ES- 4: 1802 PFBS (IS) 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D i \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ilt46i49 2010 Method I Dt\masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13i4i21 2010 Job Code I Printed! Wed Oct 20 09i40tl7 2010 Name: dl00908a059 Text I 7: 13C8 PFOS (IS) Page 116 6; MPFOS (Surr) GLP10-01 -01 -05-104 DAL SS GP09 0 0020 Davey070799 3M 09-Sep-2010 05:19:26 d100908a059 4: MRM of 1 Channel ES- 100- 10.89 240 TIC 1.32e3 Area % I Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a060 Text: Page 119 GLP10-01-01 -05-105 DAL SS GP09 0 0050 Davey070799 3M 09-Sep-2010 05:37:32 d100908a060 2: MRM of 2 Channels ES 100- 10.10 1297 TIC 5.45e3 Area % 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:46:49 2010 Me thod Di\mas slynx\davey201 0.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13:46t21 2010 Job Code! Printed Wed Oct 20 09:4017 2010 Name: d!00908a060 Text: 5 1802 PFHS (IS) . 6: MPFOS {Surr) 7 13C8 PFOS (IS) Page 120 Quantify Sample Report GLPlO-01-02-05 screening data Sample List! D*\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 11i46i49 2010 Method Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 1 3 i4 6 i21 2010 Job Code! Printed! Wed Oct 20 09!40il7 2010 Namet dl00908a061 Text! Is PFBS . 2: PFHS Page 121 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a061 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 122 Quantify Sample Report GLP10-01-02-05 screening data Sample List D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Me thod s D \mas slynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13<46>21 2010 Job Code Printed Wed Oct 20 09>4017 2010 Name dl00908a02 Text 1: PFBS 2: PFHS 3= PFOS 4s 1802 PFBS (IS) Page 123 Quantify Sample Report GLP10-01-02>05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a062 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 124 q u a n t i t ^ M S U d y <PiD:p 1 I r P J t i0 2 1 0 / 2 0 / 1 0 nmh In te rim iR fiP O rt^ J \ i. ( 'J P a g e 6 7 0 o f 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D s\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a063 Text: 1: PFBS 2s PFHS 3; PFOS 4s 1802 PFBS (IS) Page 125 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslyxuc\davey2010.PRO\SampleDB\dl0Q908a Last modifiedi Wed Sep 08 11*46:49 2010 Method > Di\masslynx\davey2010.PRO\MethDB\dlO0908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Page 126 Name: dl00908a063 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) GLP10-01 -01-05-108 DAL SS GP10 0 0020 Davey070799 GLP10-01-01-05-108 DAL SS GP10 0 0020 Davey070799 3M 09-Sep-2010 06:31:46 3M 09-Sep-2010 06:31:46 d100908a063 100 5: MRM of 1 Channel ES- d100908a063 10.55 TIC 100 221 1 1.38e3 4: MRM of 1 Channel ES- 11.15 TIC 316 1,78e3 Area Area %% 27 7: 13C8 PPOS (IS) 5.00 10.00 15.00 Time 21 A 5.00 10.00 15.00 Time 3 m S tu d y G L P 1 0 -0 1 -0 2 . . f i t fn fe d rP m 9R l 0p 5 f f i Q 5 i B t e t 1^ 0/ 1 ?'.!" mh \ i. Page 672 0 f|6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SainpleDB\dl00908a Last modified] Wed Sep 08 Ils46s49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a064 Text: 3: PFOS Page 127 GLP10-01-01-05-109 DAL SS GP10 0 0060 Davey070799 3M 09-Sep-2010 06:49:55 d100908a064 100- 10.14 25686 2: MRM of 2 Channels ESTIC 9.14e4 Area % 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data , Sample List D *\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified* Wed Sep 08 11*46*49 2010 Method* D * \masslynx\davey2010.PRO\MethDB\dl00908a Last modified* Thu Sep 09 13*46:21 2010 Job Code* Printed* Wed Oct 20 09*40*17 2010 Name* dl00908a064 Text* 7s 13C8 PPOS (IS) Page 128 . Quantify Sample Report GLP10-01-02-0S screening data Sample List D>\masslynx\davey2010.PRO\SampleDB\dl00906a Last modifiedt Wed Sep 08 11*46:49 2010 Method: D:\ma8Slynx\davey2Q10.PRO\MethOB\dlQ0908a Last modified* Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a065 Text: 1 : PFBS 2 : PFHS Page 129 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Dt \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified] Wed Sep 08 Ili46s49 2010 Method] D]\masslynx\davey2010.PRO\MethDB\dl00908a Last modified] Thu Sep 09 13<46i21 2010 Job Code: Printed] Wed Oct 20 09t40:17 2010 Name] dl00908a065 Textt 7s 13C8 PFOS (IS) Page 130 Quantify Sample Report GLP10-01-02-05 screening data Sample List Ds \xnasslynx\davey2010 .PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D j\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a066 Text: Page 131 ~ GLP10-01-01-05-112 DAL SS GP11 0 0005 Davey070799 GLP10-01 -01-05-112 DAL SS GP11 0 0005 Davey070799 3M 09-Sep-2010 07:26:08 3M 09-Sep-2010 07:26:08 d100908a066 100 1: MRM of 2 Channels ES- d100908a066 9.43 1359 TIC 100 6.25e3 2: MRM of 2 Channels ES- 10.14 TIC 73891 2.92e4 Area Area % %- Time 5.00 10.00 15.00 Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedt Wed Sep 08 Ils46s49 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13s46s21 2010 Job Codes Printed: Wed Oct 20 09t40:17 2010 Page 132 Names dl00908a066 Texts 5; 1802 PFHS (IS) 6; MPFOS (Surr) GLP10-01-01-05-112 DAL SS GP11 0 0005 Davey070799 GLP10-01-01-05-112 DAL SS GP11 0 0005 Davey070799 3M . 09-Sep-2010 07:26:08 3M 09-Sep-2010 07:26:08 d100908a066 5: MRM of 1 Channel ES- d100908a066 4: MRM of 1 Channel ES- 7: 13C8 PFOS (IS) Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D : \masslynx\davey20l0.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a067 Text: 1: PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) Page 133 3 M S tu d y G L P 1 0 -0 1 -0 2 t Ui s` m F f . i ,r f i f e r i m 9R e p f l f t a0 5 i n t e d 1 0 / 2 0 / 1 0 . '# . | ^ Page 679 o f 962 i1 ' Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D : \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ili46t49 2010 Hethodi D i \masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13t46t21 2010 Job Codet Printedi Wed Oct 20 09t40tl7 2010 Namet d!00908a067 Text i Am 'B te rrm R e p o rt r " ............. Page 134 Quantify Sample Report GLP10-01-02-0S screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 Ils46s49 2010 Method: D s\masslynx\davey2010.PR0\Me thDB\d!0 0908a Last modified Thu Sep 09 13s46s21 2010 Job Code: Printed: Wed Oct 20 09s40sl7 2010 Names dl00908a068 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 135 U & 1 0 i0 A t0 2 1 0 / 2 0 ^ In te rim R e p o rt 0 5 ' - ^ _ jx tita te d ^ S / : . anc P a g e 6 8 1 o f 9 S 2 V .'r *| Quantify Sample Report GLP10-01-02-05 screening data Sample List D> \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 Ilt46t49 2010 Methodi Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13s46t21 2010 Job Code: Printed! Wed Oct 20 09:40!l7 2010 Namei dl00908a068 Text! 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 quanti t i f f t t g r i m R e p e f t 1Q & inted j Page 136 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00906a Last modified: Wed Sep 08 Ili46t49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a069 Text: I t PFBS 2 : PFHS Page 137 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified^ Wed Sep 08 Ili46t49 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a069 Text: Page 138 6: MPFOS (Surr) GLP10-01 -01 -05-115 DAL SS GP11 DB 0065 Davey070799 3M 09-Sep-2010 08:20:31 d100908a069 4: MRM of 1 Channel ES- 100 10.89 231 TIC 1.51e3 Area % 29 Time 5.00 10.00 15.00 lu a n tit M S J y d y P L & lt ft-10/ Q /lO mmh In te rim R e p o rt 0 5 $ \\h ` i ' x ils Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Marne: dl00908a070 Text: 1: PFBS 2: PFHS Page 139 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified* Wed Sep 08 Ils46i49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a070 Text: 5: 1802 PFHS (IS) 6s MPFOS (Surr) 7s 13C8 PFOS (IS) Page 140 Quantify Sample Report GLP10-01-02-05 screening data Sample List D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Method D\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 0940tl7 2010 Name dl00908a071 Text 1: PFBS 2: PFHS 3s PFOS 4s 1802 PFBS (IS) 3 M s S tu d v G L P 1 0 -0 1 -0 2 Page 141 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifieds Wed Sep 08 11:46:49 2010 Me thod: D t\masslynx\davey2010.PRO\MethDB\dlO 0 908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a071 Text: q u a n t it S M i& H ^ M . ( P L & ' r f iii t 0 2 1 0 /2 0 /0 .0 . m n lu -.y ^ ln te c jm R e p o rt 0 5 i* ^ Page 142 Quantify Sample Report GLP10-01>02>0S screening data Sample List D \masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Method D \masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13 46*21 2010 Job Code Printed Wed Oct 20 094017 2010 Name dl00908a072 Text 1 PFBS ... 2: PFHS 3; PFOS 4: 1802 PFBS (IS) Page 143 Quantify Sample Report GLP10-01-02-Q5 screening data Sample List D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114>49 2010 Method Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 094017 2010 Name dl00908a072 Text: 5: 1802 PFHS (IS) ...... 6: MPPOS (Surr) 7: 13C8 PPOS (IS) Page 144 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010,PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ili46t49 2010 Method: Di\masslynx\davey2010,PRO\MethDB\dlO0908a Last modified! Thu Sep 09 13i46t21 2010 Job Code: Printed! Wed Oct 20 09i40il7 2010 Namei dl00908a073 Text! Is PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 145 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modifiedi Wed Sep 08 11:46:49 2010 Method: D\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a073 Text: 7: 13C8 PFOS (IS) GLP10-01-01-05-116 DAL SS GP12 0 0000 Davey070799 3M 09-Sep-2010 09:33:02 d100908a073 7: MRM of 1 Channel ES- Page 146 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di \masslynx\davey2010.PRO\SampleDB\dl00908a Last modifieds Wed Sep 08 ll<46s49 2010 Method t D iVisasalynx\davey 2010. PR0\Me thDB\dlO 0908a Last modifieds Thu Sep 09 13s46s21 2010 Job Codes Printedi Wed Oct 20 09t40sl7 2010 Names dl00908a074 Texts Is PFBS 2: PFHS Page 147 3M Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Dt\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code: Printed Wed Oct 20 0940sl7 2010 Name dl00908a074 Text S: 1802 PFHS (IS) Page 148 6: MPFOS (Surr)_______________________________ _________________________________________________ GLP10-01-01-05-117 DAL SS GP12 0 0005 Davey070799 3M 09-Sep-2010 09:51:09 d100908a074 100n 10.71 318 4: MRM of 1 Channel ESTIC 1.75e3 Area % 20 7 i 13C8 PFOS (IS) |GLP10-01 -01 -05-117 DAL SS GP12 0 0005 Davey070799 |3M 09-Sep-2010 09:51:09 |d100908a074 7: MRM of 1 Channel ES- 5.00 10.00 15.00 Time q u a n tL t^ M i M In te rim ' R e p o rt 0 5 : ............... Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey20l0.PRO\SampleDB\dl00906a Last modified: Wed Sep 08 11:46:49 2010 Method: 0:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a075 Text: 1: PFBS 2: PFHS Page 149 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 Ili46:49 2010 Methods Di\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13i46!21 2010 Job Code t Printed! Wed Oct 20 09i40!l7 2010 Page 150 Namei dl00908a075 Text! 5; 1802 PFHS (IS) 6; MPFOS (Surr) GLP10-01 -01-05-118 DAL SS GP120 0020 Davey070799 GLP10-01-01-05-118 DAL SS GP12 0 0020 Davey070799 3M 09-Sep-201010:09:14 3M 09-Sep-201010:09:14 d100908a075 100- 10.11 333 ! i 5: MRM of 1 Channel ESTIC 1.71e3 Area d100908a075 100 10.89 359 ' 4: MRM of 1 Channel ESTIC 1.88e3 Area % 5.00 10.00 15.00 Time 7: 13C8 PFOS (IS) GLP10-01-01-05-118 DAL SS GP12 0 0020 Davey070799 3M 09-Sep-2010 10:09:14 d100908a075 100 7: MRM of 1 Channel ES- 10.90 TIC 319] 1.58e3 Area . 13 ^ ... 5.00 ^__ L 10.00 15.00 Time % -46 .00 5.00 10.00 15.00 Time l :> . lb.. Quantify Sample Report GLP10-01-02-05 screening data Sample List: O:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a076 Text: 1 : PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) : ?quan^ti3tMat,eSdJ.u9/d9v/10G aL nRd1re0 r- 0in1t-e0a2 ,3 r T n V ' Y- I n t e r i m R e p o r T O S Page 151 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified! Wed Sep 08 11146:49 2010 Methodi Dt\masslynx\davey2010.PRO\MethDB\dl00908a Last modified! Thu Sep 09 13i46:21 2010 Job Code: Printed! Wed Oct 20 09t40il7 2010 Name: dl00908a076 Text! 5: 1802 PFHS (IS) 6 s MPFOS (Surr) 7: 13C8 PFOS (IS) Page 152 Page 698 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a077 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 153 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dlOO908a Last modifiedt Wed Sep 08 Ils46s49 2010 Methods D \masslynx\davey2010.PRO\MethDB\dl00908a Last modifiedi Thu Sep 09 13t46:21 2010 Job Codes Printeds Wed Oct 20 09s40sl7 2010 Names dl00908a077 Texts 5: 1802 PFHS {IS} 6: MPFOS (Surr) 7: 13C8 PFOS (IS) . . 3 M ,S tu d y GUP1C 10/20/10 mmh Page 154 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code : Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a078 Text: 1: PFBS 2: PFHS 3 : PFOS 4: 1802 PFBS (IS) Page 1SS Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified: Wed Sep 08 11:46:49 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00908a Last modified: Thu Sep 09 13:46:21 2010 Job Code: Printed: Wed Oct 20 09:40:17 2010 Name: dl00908a078 Text: 5: 1802 PFHS (IS) 6: MPPOS (Surr) 7: 13C8 PFOS (IS) Page 156 Quantify Sample Report GLP10-01-02-05 screening data Sample List D\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 11:4649 2010 Method D\masslynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 13:4621 2010 Job Code Printed Wed Oct 20 09:4017 2010 Name dl00908a079 Text Is PFBS 2: PFHS 3: PFOS 4; 1802 PFBS (IS) Page 157 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dl00908a Last modified Wed Sep 08 114649 2010 Method Di\ma88lynx\davey2010.PRO\MethDB\dl00908a Last modified Thu Sep 09 134621 2010 Job Code Printed Wed Oct 20 09>4017 2010 Name dl00908a079 Text: Page 158 DAVEY:Quattro Ultima: #9261QB DATE: 09-03-10 STUDY: GLP10-01-0^-05 ANALYsTTmmh / / if / 0 Mobile Phase: (A) 2 mM ammonium acetate (B) Acetonitrile TN-A- or standard number(A) 10003-173______________(Bl TN-08-0289 2/4 Guard column (pre-autosampler) : Prism RP Size: 2.1mm X 50 mm__________ Type: NA Sphere size:_____ 5______ Part number: 32105-052130 :Lot number: 9411 Serial number: 0195559V On-line SPE cartidge: waters HLB Size: 3.0mm X 20 mm__________ Type: HLB Sphere size:_____ 25 urn Part number: 186002039 :Lot number: NA Serial number: 006A36131107 02 Analytical column: Betasil C18 Size: 2.1mm X 100 mm_________ Type: C l8 Sphere size: 5______ Part number: 70305-102130 :Lot number: 8606 Serial number: 1273481L PAGE 1 of 1 /vor 1^2 ,A -^ v Printed: Friday, September 03, 2010 1:14 PM 3M Study GLP10-01-02 Interim Report 05 P age 705 o f 96] Tuning Method Report Method: D:\MASSLYNX\DAVEY2010.PRO\ACQUDB\PFOS Printed: Fri Sep 03 13:15:45 2010 80.00 ' , ' x64- 99.00 - ,130.00 x53 180.00 . ' x25 Page 1 '* r ~h 8 MS 1 1 1 1 1 1 1 1 1 1 1 r - 1 I-- I-- I-- i-- 80 ,, 8 ' . 98 100 28 130 i : i ?8 ' 180 ~ MS MS MS SOURCE ( ESP- ) Capillary Cone Hexapole 1 Aperture 1 Hexapole 2 Source Block Temp. Desolvation Temp. Set Rdbk 2.97 60 0.0 0.0 0.0 150 250 -2.89 -20 148 249 Pressures Analyser Vacuum Gas Cell Rdbk OFF 2.8e-3 Analyser LM Res 1 HM Res 1 IEnergy 1 Entrance Collision Exit LM Res 2 HM Res 2 IEnergy 2 Multiplier Gas Flows Cone Gas Desolvation Set Rdbk 15.0 15.0 0.5 0 41 2 15.0 12.0 0.5 550 18 16 19 -549 Rdbk 323.4 729.3 3M Study GLP10-01-02 Interim Report 05 Method Report Method File: Last Modified: Printed: Page 1 D:\masslynx\DAVEY2010.PRO\ACQUDB\17min prism-C18 Friday, Septem ber 03,2010 13:12:07 Friday, Septem ber 03,2010 13:16:42 HP1100 LC Pump Initial Conditions Solvents A% B% C% D% 90.0 10.0 0.0 0.0 Valve A set to channel Valve B set to channel Flow (ml/min) Stop Time (mins) Min Pressure (bar) Max Pressure (bar) Oven Temperature Left(C) Oven Temperature Right(C) 0.300 17.0 0 400 30.0 30.0 HP1100 LC Pump Gradient Timetable The gradient Timetable contains 6 entries which are : Time A% B% C% D% 0.00 90.0 10.0 0.0 0.0 1.00 90.0 10.0 0.0 0.0 11.00 10.0 90.0 0.0 0.0 13.50 10.0 90.0 0.0 0.0 14.00 90.0 10.0 0.0 0.0 17.00 90.0 10.0 0.0 0.0 Flow 0.300 0.300 0.300 0.300 0.300 0.300 Pressure 400 400 400 400 400 400 HP1100 LC Pump External Event Timetable The Timetable contains 3 entries which are : Time Initial 0.00 0.10 Column Switch Off Off Off On Off Off Contactl Off On Off Contact2 Off Off Off Contact3 Off On Off Contact4 HP1100 Autosam pler Initial Conditions Draw Speed Eject Speed (pl/min) Draw Position (mm) Stop Time (mins) Injection Volume(pl) Vial Number Thermostat On Thermostat Temperature(C) 200.0 200 0.00 17.00 10.0 6 23.0 3M Study GLP10-01-02 Interim Report 05 Pag Scanning Method Report Method: D:\MASSLYNX\DAVEY2010.PRO\ACQUDB\17MIN-PFBS-PFHS-PFOS Last Modified: Fri Sep 03 11:56:55 2010 Printed: Fri Sep 03 13:25:13 2010 Solvent Delay ( mins ) : 0.00 Function : 1 MRM Of 2 Mass Pairs 4! ESP- ) inter Channel Delay i[ Secs ) : Span ( Daltons ) : Start Time ( Mins ) : End Time { Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V ) 1 299.00 80.00 0.25 2 299.00 99.00 0.25 4S 45 60 60 Function : 2 MRM of 2 Mass Pairs \[ ESP- ) Inter Channel Delay i( Secs ) : Span { Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V ) 1 399.00 80.00 0.25 2 399.00 99.00 0.25 45 45 60 60 Function : 3 MRM of 2 Mass Pairs (! ESP- ) Inter Channel Delay i( Secs ) : Span ( Daltons ) : Start Time ( Mins ) : End Time { Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone { V ) l 499.00 80.00 0.25 2 499.00 99.00 0.25 45 45 60 60 Function : 4 MRM of 1 Mass Pair < ESP- ) Inter Channel Delay l[ Secs ) : Span ( Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V ) 1 503.00 80.00 0.20 45 60 Function : 5 MRM of 1 Mass Pair ( BSP- ) Inter Channel Delay i( Secs ) : Span ( Daltons ) : Start Time ( Mins ) ; End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V ) 1 403.00 84.00 0.20 45 60 Function : 6 MRM of 1 Mass Pair ( e s p ;- ) inter Channel Delay i[ Secs ) : Span ( Daltons ) : Start Time ( Mins ) ; End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( v ) 1 303.00 84.00 0.20 45 60 Function : 7 MRM of 1 Mass Pair ( ESP- ) inter Channel Delay iI Secs ) : Span ( Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats : Channel Parent Daughter 0.03 0.00 0.00 17.00 1 Dwell (Secs) Coll Energy (eV) Cone ( V ) l 507.00 80.00 0.20 45 60 3M Study GLP10-01-02 Interim Report 05 Page 1 0- r f i . P a g e /7 0 8 ffi9 6 2 Masslynx - Sample List Sample List: D:\masslynx\davey2010.PRO\SampleDB\d100904a.SPL Printed: Fri Sep 03 13:28:52 2010 Page 1 Page Position: (1 ,1 ) File Name Sample ID M S F ile In le t F ile B o ttle In je c t V o lu m e S a m p le T yp e C o n e A 1 d100904a001 09004-182 80:20 A C N :H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 99 2 d100904a002 09004-182 80:20 A C N :H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 99 3 d 1 0090 4a0 03 E C -100831-01 0.2 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 1 4 d 1 0090 4a0 04 E C -100831-02 0.5 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 2 5 d 1 0 0 9 0 4 a 0 0 5 E C -100 831 -03 0.7 5 ng E xtracted C u rve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 3 6 d 1 0090 4a0 06 E C -100 831-04 1 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 4 7 d 1 0090 4a0 07 E C -100831-05 2.5 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 5 8 d 1 0090 4a0 08 E C -100 831-06 5 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 6 9 d 1 0090 4a0 09 E C -100831-07 10 ng E xtracted C urve P oint 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 7 10 d 1 0 0 9 0 4 a 0 1 0 E C -1 0 0 8 3 1 -0 8 2 5 n g E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 8 11 d 1 0 0 9 0 4 a 0 1 1 E C -1 0 0 8 3 1 -0 9 5 0 n g E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 9 12 d 1 0 0 9 0 4 a 0 1 2 E C -1 0 0 8 3 1 -1 0 1 0 0 ng E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 10 13 d 1 0 0 9 0 4 a 0 1 3 E C -1 0 0 8 3 1 -1 1 2 0 0 ng E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 1 7 m in p r is m -C 1 8 11 14 d 1 0 0 9 0 4 a 0 1 4 E C -1 0 0 8 3 1 -1 2 5 0 0 ng E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 12 15 d 1 0 0 9 0 4 a 0 1 5 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 99 16 d 1 0 0 9 0 4 a 0 1 6 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 99 17 d 1 0 0 9 0 4 a 0 1 7 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17M IN -P F B S -P F H S -P F O S 17m in p ris m -C I8 99 18 d 1 0 0 9 0 4 a 0 1 8 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 100 19 d 1 0 0 9 0 4 a 0 1 9 M B -1 0 0 8 3 1 -0 1 M e th o d B la n k 1 w /o IS 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 13 20 d 1 0 0 9 0 4 a 0 2 0 M B -1 0 0 8 3 1 -0 2 M e th o d B la n k 2 w /o IS 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 14 21 d 1 0 0 9 0 4 a 0 2 1 M B -1 0 0 8 3 1 -0 3 M e th o d B la n k 3 w /o IS 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 15 22 d 1 0 0 9 0 4 a 0 2 2 M B -1 0 0 8 3 1 -0 4 M e th o d B la n k 4 w / IS 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 16 23 d 1 0 0 9 0 4 a 0 2 3 M B -1 0 0 8 3 1 -0 5 M e th o d B la n k 5 w / IS 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 17 24 d 1 0 0 9 0 4 a 0 2 4 M B -1 0 0 8 3 1 -0 6 M e th o d B la n k 6 w / IS 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 18 25 d 1 0 0 9 0 4 a 0 2 5 L C S -1 0 0 8 3 1 -01 3 n g L C S in T C R -8 4 2 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 19 26 d 1 0 0 9 0 4 a 0 2 6 L C S -1 0 0 8 3 1 -0 2 3 n g L C S in T C R -8 4 2 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 20 27 d 1 0 0 9 0 4 a 0 2 7 L C S -1 0 0 8 3 1 -0 3 3 ng L C S in T C R -8 4 2 17 M IN -P F B S -P F H S -P F O S 17m in prism -C 1 8 21 28 d 1 0 0 9 0 4 a 0 2 8 L C S -1 0 0 8 3 1 -0 4 3 0 n g L C S in T C R -8 4 2 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 22 29 d 1 0 0 9 0 4 a 0 2 9 L C S -1 0 0 8 3 1 -0 5 3 0 n g L C S in T C R -8 4 2 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 23 30 d 1 0 0 9 0 4 a 0 3 0 L C S -1 0 0 8 3 1 -0 6 3 0 n g L C S in T C R -8 4 2 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 24 31 d 1 0 0 9 0 4 a 0 3 1 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 92 32 d 1 0 0 9 0 4 a 0 3 2 E C -1 0 0 8 3 1 -0 6 5 n g E x tra c te d C u rv e P o in t 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 6 33 d 1 0 0 9 0 4 a 0 3 3 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 93 34 d 1 0 0 9 0 4 a 0 3 4 G L P 1 0 -0 1 -0 1 -0 5 -0 0 1 D A L S D T R IP 1 0 1 0 0 6 2 4 17 M IN -P F B S -P F H S -P F O S 1 7 m in p ris m -C 1 8 2 5 35 d 1 0 0 9 0 4 a 0 3 5 G L P 1 0 -0 1 -0 1 -0 5 -0 0 2 D A L S D S D 0 1 0 0 0 0 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 26 36 d 1 0 0 9 0 4 a 0 3 6 G L P 1 0 -0 1 -0 1 -0 5 -0 0 3 D A L S D S D 0 1 0 0 0 0 5 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 27 37 d 1 0 0 9 0 4 a 0 3 7 G L P 1 0 -0 1 -0 1 -0 5 -0 0 4 D A L S D S D 0 2 0 0 0 0 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 28 38 d 1 0 0 9 0 4 a 0 3 8 G L P 1 0 -0 1 -0 1 -0 5 -0 0 5 D A L S D S D 0 2 0 0 0 0 5 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 29 39 d 1 0 0 9 0 4 a 0 3 9 G L P 1 0 -0 1 -0 1 -0 5 -0 0 6 D A L S D S D 0 3 0 0 0 0 0 17M IN -P F B S -P F H S -P F O S 17m in prism -C 18 30 40 d 1 0 0 9 0 4 a 0 4 0 G L P 1 0 -0 1 -0 1 -0 5 -0 0 7 D A L S D S D 0 3 0 0 0 0 5 1 7 M IN -P F B S -P F H S -P F O S 17 m in p ris m -C 1 8 31 41 d 1 0 0 9 0 4 a 0 4 1 G L P 1 0 -0 1 -0 1 -0 5 -0 0 9 D A L S D S D 0 4 0 0 0 0 0 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 32 42 d 1 0 0 9 0 4 a 0 4 2 G L P 1 0 -0 1 -0 1 -0 5 -0 1 0 D A L S D S D 0 4 0 00 0 5 17 M IN -P F B S -P F H S -P F O S 17m in p rism -C 18 33 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 10.000 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 1 0 .0 0 0 10.000 1 0 .0 0 0 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 _ -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- _ -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 3M Study GLP10-01-02 Interim Report 05 Page 709 of 962 Masslynx - Sample List Sample List: D:\masslynx\davey2010.PRO\SampleDB\d100904a.SPL Printed: Fri Sep 03 13:28:52 2010 Page 2 Page Position: (1, 2) File Name Sample ID M S F ile In le t F ile B o ttle In je c t V o lu m e Sample Type Cone A 43 d 1 0 0 9 0 4 a 0 4 3 G L P 1 0-01-0 1 -0 5 -0 1 1 D A L S D S D 0 5 0 0 0 0 0 44 d 1 0 0 9 0 4 a 0 4 4 G L P 1 0 -0 1 -0 1 -0 5 -0 1 2 D A L S D S D 0 5 0 0 0 0 5 45 d 1 0 0 9 0 4 a 0 4 5 G L P 1 0-01 -01 -0 5 -0 1 3 D A L S D S D 0 6 0 00 0 0 46 d 1 0 0 9 0 4 a 0 4 6 G L P 1 0 -0 1 -0 1 -0 5 -0 1 4 D A L S D S D 0 6 0 00 0 5 47 d 1 0 0 9 0 4 a 0 4 7 G L P 1 0 -0 1 -0 1 -0 5 -0 1 5 D A L S D S D 0 7 0 00 0 0 48 d 1 0 0 9 0 4 a 0 4 8 G L P 1 0 -0 1 -0 1 -0 5 -0 1 6 D A L S D S D 0 7 0 0 0 0 5 49 d 1 0 0 9 0 4 a 0 4 9 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 50 d 1 0 0 9 0 4 a 0 5 0 E C -1 0 0 8 3 1 -0 7 10 ng E x tra c te d C u rv e P o in t 51 d 1 0 0 9 0 4 a 0 5 1 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 52 d 1 0 0 9 0 4 a 0 5 2 G L P 1 0-01 -01 -0 5 -0 1 7 D A L S D S D 0 8 0 0 0 0 0 53 d 1 0 0 9 0 4 a 0 5 3 G L P 1 0 - 0 1 -0 1 -0 5 -0 1 8 D A L S D S D 0 8 D B 0 0 0 0 54 d 1 0 0 9 0 4 a 0 5 4 G L P 1 0 -0 1 -0 1 -0 5 -0 1 9 D A L S D S D 0 8 0 0 0 0 5 55 d 1 0 0 9 0 4 a 0 5 5 G L P 1 0 -0 1 -0 1 -0 5 -0 2 1 D A L S D S D 0 9 0 0 0 0 0 56 d 1 0 0 9 0 4 a 0 5 6 G L P 1 0 -0 1 -0 1 -0 5 -0 2 2 D A L S D S D 0 9 0 0 0 0 5 57 d 1 0 0 9 0 4 a 0 5 7 G L P 1 0 -0 1 -0 1 -0 5 -0 2 3 D A L S D S D 1 0 0 0 0 0 0 58 d 1 0 0 9 0 4 a 0 5 8 G L P 1 0 - 0 1 -0 1 -0 5 -0 2 4 D A L S D S D 1 0 0 0 0 0 5 59 d 1 0 0 9 0 4 a 0 5 9 G L P 1 0 -0 1 -0 1 -0 5 -0 2 5 D A L S D S D 1 1 0 0 0 0 0 60 d 1 0 0 9 0 4 a 0 6 0 G L P 1 0 -0 1 -0 1 -0 5 -0 2 6 D A L S D S D 1 1 0 0 0 0 5 61 d 1 0 0 9 0 4 a 0 6 1 G L P 1 0 - 0 1 -0 1 -0 5 -0 2 7 D A L S D S D 1 2 0 0 0 0 0 62 d 1 0 0 9 0 4 a 0 6 2 G L P 1 0 - 0 1 -0 1 -0 5 -0 2 8 D A L S D S D 1 2 D B 0 0 0 0 63 d 1 0 0 9 0 4 a 0 6 3 G L P 1 0 - 0 1 -0 1 -0 5 -0 2 9 D A L S D S D 1 2 0 0 0 0 5 64 d 1 0 0 9 0 4 a 0 6 4 G L P 1 0 -0 1 -0 1 -0 5 -0 3 0 D A L S D S D 1 3 0 0 0 0 0 65 d 1 0 0 9 0 4 a 0 6 5 G L P 1 0 -0 1 -0 1 -0 5 -0 3 1 D A L S D S D 1 3 0 0 0 0 5 66 d 1 0 0 9 0 4 a 0 6 6 G L P 1 0 -0 1 -0 1 -0 5 -0 3 2 D A L S D S D 1 4 0 0 0 0 0 67 d 1 0 0 9 0 4 a 0 6 7 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N :H 2 0 68 d 1 0 0 9 0 4 a 0 6 8 E C -1 0 0 8 3 1 -0 6 5 n g E x tra c te d C u rv e P o in t 69 d 1 0 0 9 0 4 a 0 6 9 0 9 0 0 4 -1 8 2 8 0 :2 0 A C N : H 2 0 70 d 1 0 0 9 0 4 a 0 7 0 G L P 1 0 -0 1 -0 1 -0 5 -0 3 3 D A L S D S D 1 4 0 0 0 0 5 71 d 1 0 0 9 0 4 a 0 7 1 G L P 1 0 - 0 1 -0 1 -0 5 -0 3 4 D A L S D S D 1 5 0 0 0 0 0 72 d 1 0 0 9 0 4 a 0 7 2 G L P 1 0 -0 1 -0 1 -0 5 -0 3 5 D A L S D S D 1 5 0 0 0 0 5 73 d 1 0 0 9 0 4 a 0 7 3 G L P 1 0 -0 1 -0 1 -0 5 -0 3 6 D A L S D S D 1 6 0 0 0 0 0 74 d 1 0 0 9 0 4 a 0 7 4 G L P 1 0 -0 1 -0 1 -0 5 -0 3 7 D A L S D S D 1 6 D B 00 0 0 75 d 1 0 0 9 0 4 a 0 7 5 G L P 1 0 -0 1 -0 1 -0 5 -0 3 8 D A L S D S D 1 6 0 0 0 0 5 76 d 1 0 0 9 0 4 a 0 7 6 G L P 1 0 -0 1 -0 1 -0 5 -0 3 9 D A L S D S D 1 7 0 0 0 0 0 77 d 1 0 0 9 0 4 a 0 7 7 G L P 1 0 -0 1 -0 1 -0 5 -0 4 0 D A L S D S D 1 7 0 0 0 0 5 78 d 1 0 0 9 0 4 a 0 7 8 G L P 1 0 -0 1 -0 1 -0 5 -0 4 1 D A L S S S S 0 1 0 0 0 0 0 79 d 1 0 0 9 0 4 a 0 7 9 G L P 1 0 -0 1 -0 1 -0 5 -0 4 2 D A L S S S S 0 1 0 0 0 0 5 80 d 1 0 0 9 0 4 a 0 8 0 G L P 1 0 -0 1 -0 1 -0 5 -0 4 3 D A L S S S S 0 2 0 0 0 0 0 81 d 1 0 0 9 0 4 a 0 8 1 G L P 1 0 - 0 1 -0 1 -0 5 -0 4 4 D A L S S S S 0 2 0 0 0 0 5 82 d 1 0 0 9 0 4 a 0 8 2 G L P 1 0 -0 1 -0 1 -0 5 -0 4 5 D A L S S S S 0 3 0 0 0 0 0 83 d 1 0 0 9 0 4 a 0 8 3 G L P 1 0 -0 1 -0 1 -0 5 -0 4 6 D A L S S S S 0 3 0 0 0 0 5 84 d 1 0 0 9 0 4 a 0 8 4 G L P 1 0 -0 1 -0 1 -0 5 -0 4 7 D A L S S S S 0 3 D B 00 0 5 3M Study GLP10-01-02 Interim Report 05 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M I N -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17m in p rism -C 18 17m in p rism -C I 8 17m in p rism -C 18 17m in p rism -C I 8 17 m in p rism -C 18 17m in p rism -C I 8 17m in p rism -C I 8 17m in p rism -C 18 17m in p ris m -C I 8 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17 m in p rism -C 18 17m in p rism -C 18 17 m in p rism -C 18 17m in p rism -C 18 17 m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in p rism -C 18 17m in prism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p ris m -C I8 17 m in p rism -C 18 17 m in p rism -C 18 17 m in p rism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 34 35 36 37 38 39 93 7 94 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 94 6 95 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 Page 710 of 962 Masslynx - Sample List Sample List: D:\masslynx\davey2010.PRO\SampleDB\d100904a.SPL Printed: Fri Sep 03 13:28:52 2010 Page 3 Page Position: (1, 3) File Name Sample ID 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 d100904a085 d100904a086 d100904a087 d100904a088 d100904a089 d100904a090 d100904a091 d100904a092 d100904a093 d100904a094 d100904a095 d100904a096 d100904a097 d100904a098 d100904a099 d100904a100 d100904a101 d100904a102 d100904a103 d100904a104 d100904a105 d100904a106 d100904a107 d100904a108 d100904a109 d100904a110 d100904a111 d100904a112 d100904a113 d100904a114 09004-182 80:20 A C N :H 2 0 E C -100831-07 10 ng E xtracted C urve P oint 09004-182 80:20 A C N :H 2 0 G LP 10-01-01-05-048 DAL SS SS04 0 0000 G LP 10-01-01-05-049 DAL SS SS04 0 0005 G LP 10-01-01-05-050 D A L SS TR IP1 0 0000 G LP 10-01-01-05-051 D AL SS S S05 0 0000 G LP 10-01-01-05-052 DAL SS SS05 0 0005 G LP 10-01-01-05-054 DAL SS SS06 0 0000 G LP 10-01-01-05-055 DAL SS SS06 0 0005 G LP 10-01-01-05-056 DAL SS SS06 DB 0005 G LP 10-01-01-05-057 DAL SS SS07 0 0000 G LP 10-01-01-05-058 DAL SS SS07 0 0005 G LP 10-01-01-05-059 DAL SS SS08 0 0000 G LP 10-01-01-05-060 DAL SS SS08 DB 0000 G LP 10-01-01-05-061 D AL SS S S08 0 0005 G LP 10-01-01-05-062 DAL SS SS09 0 0000 G LP 10-01-01-05-063 DAL SS SS09 0 0005 09004-182 80:20 A C N :H 2 0 E C -100831-06 5 ng E xtracted C urve Point 09004-182 80:20 A C N :H 2 0 G LP 10-01-01-05-064 DAL SS GP01 0 0000 G LP 10-01-01-05-065 DAL SS GP01 0 0005 G LP 10-01-01-05-066 DAL SS GP01 0 0020 G LP 10-01-01-05-067 DAL SS GP01 0 0060 G LP 10-01-01-05-068 DAL SS G P02 0 0000 G LP 10-01-01-05-069 DAL SS G P02 0 0005 09004-182 80:20 A C N :H 2 0 E C -100831-07 10 ng E xtracted C urve P oint 09004-182 80:20 A C N :H 2Q MS File In le t F ile B o ttle In je c t V o lu m e S a m p le T yp e C o n e A 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P F H S -P F O S 17M IN -P FB S -P F H S -P F O S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P FH S -P FO S 17M IN -P FB S -P F H S -P F O S 17M IN -P FB S -P F H S -P F O S 17M IN -P FB S -P F H S -P F O S 17M IN -PFBS-PFH S-PFO S 17M IN -P FB S -P F H S -P F O S 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in p rism -C 18 17m in prism -C 18 17m in p rism -C 18 17m in prism -C 18 17m in prism -C 18 17m in prism -C 18 95 7 96 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 96 6 97 85 86 87 88 89 90 98 7 99 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 1 0 .0 0 0 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 ___ -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- ___ -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 3M Study GLP10-01-02 Interim Report 05 Page 711 of 962 Methodi D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 1: PFBS Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.999494 Calibration curve: -0.0237965 * x A2 + 82.5526 * x + 20.3908 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a001 dl00904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl00904a007 dl00904a008 dl00904a009 dl00904a010 dl00904a011 dl00904a012 dl00904a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dl00904a025 d!00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl00904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a051 dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-02 Method Blank 2 w/o IS MB-100831-03 Method Blank 3 w/o IS MB-100831-04 Method Blank 4 w/ IS MB-100831-05 Method Blank 5 w/ IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR-842 LCS-100831-02 3 ng LCS in TCR-842 LCS-100831-03 3 ng LCS in TCR-842 LCS-100831-04 30 ng LCS in TCR-842 LCS-100831-05 30 ng LCS in TCR-842 LCS-100831-06 30 ng LCS in TCR-842 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-001 DAL SD TRIP1 0 100624 GLP10-01-01-05-002 DAL SD SD01 0 0000 GLP10-01-01-05-003 DAL SD SD01 0 0005 GLP10-01-01-05-004 DAL SD SD02 0 0000 GLP10-01-01-05-005 DAL SD SD02 0 0005 GLP10-01-01-05-006 DAL SD SD03 0 0000 GLP10-01-01-05-007 DAL SD SD03 0 0005 GLP10-01-01-05-009 DAL SD SD04 0 0000 GLP10-01-01-05-010 DAL SD SD04 0 0005 GLP10-01-01-05-011 DAL SD SD05 0 0000 GLP10-01-01-05-012 DAL SD SD05 0 0005 GLP10-01-01-05-013 DAL SD SD06 0 0000 GLP10-01-01-05-014 DAL SD SD06 0 0005 GLP10-01-01-05-015 DAL SD SD07 0 0000 GLP10-01-01-05-016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DAL SD SD08 DB 0000 GLP10-01-01-05-019 DAL SD SD08 0 0005 GLP10-01-01-05-021 DAL SD SD09 0 0000 GLP10-01-01-05-022 DAL SD SD09 0 0005 GLP10-01-01-05-023 DAL SD SD10 0 0000 Type STD Co n e . (ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 250000 50.0000 100.0000 200.0000 500.0000 QC 5.0000 QC 10.0000 RT 8.522 8.780 8.563 8.688 8.641 8.518 8.654 8.611 8.648 8.647 8.652 8.692 8.734 8.866 8.563 8.565 8.697 8.605 8.817 8.569 8.650 8.563 8.912 8.648 8.687 8.608 8.738 8.604 8.605 8.605 8.651 8.652 8.564 8.608 8.651 8.653 8.610 8.737 8.649 8.647 8.693 8.607 8.733 8.820 8.822 8.611 Area Flags 18.07 55.57 98.84 84.52 188.50 513.41 840.49 2255.22 4426.29 7382.72 15599.36 35426.80 bbX bb MM MM MM bb bb bb bb bb bb bb 12.72 MM 11.19 bb 23.79 284.44 354.13 278.95 2676.43 2758.10 2759.89 bb bb bb bb bb bb bb 511.82 38.37 56.31 85.47 277.65 164.50 542.91 271.40 2194.91 1202.48 821.70 884.87 655.58 622.88 533.73 697.40 16.75 906.17 16.91 655.63 574.52 103.99 2991.79 1615.58 14294.50 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb ng/mL %Rec Mod Comment 0.00 0.43 0.95 0.78 2.04 5.98 9.96 27.29 54.22 91.60 200.28 501.35 0 85 127 78 82 120 100 109 108 92 100 100 b b a 0.00 0.00 ab 0.04 3.20 4.05 3.13 32.48 33.49 33.51 5.96 119 0.22 0.44 0.79 3.12 1.75 6.34 3.04 26.54 14.38 9.73 10.50 7.71 7.31 6.23 8.22 0.00 10.76 0.00 7.71 6.73 1.01 36.38 19.43 182.51 108 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 1: PFBS Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.999494 Calibration curve: -0.0237965 * x*2 + 82.5526 * x + 20.3908 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a058 dl00904a059 dl00904a060 dl00904a061 dl009Q4a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 dl00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904a!00 dl00904al01 dl00904al02 dl00904a!03 dl00904al04 dl00904al05 dl00904al06 dl00904al07 dl00904al08 dl00904al09 dl00904all0 dl00904alll dl00904all2 dl00904all3 dl00904all4 Samplelist ID GLP10-01-01-05-024 DAL SD SD10 0 0005 GLP10-01-01-05-025 DAL SD SDII 0 0000 GLP10-01-01-05-026 DAL SD SDII 0 0005 GLP10-01-01-05-027 DAL SD SD12 0 0000 GLP10-01-01-05-028 DAL SD SD12 DB 0000 GLP10-01-01-05-029 DAL SD SD12 0 0005 GLP10-01-01-05-030 DAL SD SD13 0 0000 GLP10-01-01-05-031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-033 DAL SD SD14 0 0005 GLP10-01-01-05-034 DAL SD SD15 0 0000 GLP10-01-01-05-035 DAL SD SD15 0 0005 GLP10-01-01-05-036 DAL SD SD16 0 0000 GLP10-01-01-05-037 DAL SD SD16 DB, 0000 GLP10-01-01-05-038 DAL SD SD16 0 0005 GLP10-01-01-05-039 DAL SD SD17 0 0000 GLP10-01-01-05-040 DAL SD SD17 0 0005 GLP10-01-01-05-041 DAL SS SS 01 0 0000 GLP10-01-01-05-042 DAL SS SS01 0 0005 GLP10-01-01-05-043 DAL SS SS02 0 0000 GLP10-01-01-05-044 DAL ss SS02 0 0005 GLP10-01-01-05-045 DAL ss SS03 0 0000 GLP10-01-01-05-046 DAL ss SS03 0 0005 GLP10-01-01-05-047 DAL ss SS03 DB; 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-048 DAL ss SS04 0 0000 GLP10-01-01-05-049 DAL ss SS04 0 0005 GLP10-01-01-05-050 DAL ss TRIP1 01 0000 GLP10-01-01-05-051 DAL ss SS05 0 0000 GLP10-01-01-05-052 DAL ss SS05 0 0005 GLP10-01-01-05-054 DAL ss SS06 0 0000 GLP10-01-01-05-055 DAL ss SS06 0 0005 GLP10-01-01-05-056 DAL ss SS06 DE1 0005 GLP10-01-01-05-057 DAL ss SS07 0 0000 GLP10-01-01-05-058 DAL ss SS07 0 0005 GLP10-01-01-05-059 DAL ss SS08 0 0000 GLP10-01-01-05-060 DAL ss SS08 DE; 0000 GLP10-01-01-05-061 DAL ss SS08 0 0005 GLP10-01-01-05-062 DAL ss SS09 0 0000 GLP10-01-01-05-063 DAL ss SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01- 05-064 DAL ss GP01 GLP10-01-01-05-065 DAL ss GP01 GLP10-01-01-05 -066 DAL ss GP01 GLP10-01-01-05-067 DAL ss GP01 GLP10-01-01-05-068 DAL ss GP02 GLP10-01-01-05-069 DAL ss GP02 0 0000 0 0005 0 0020 0 0060 0 0000 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type STD Cone.(ng/mL) QC 5.0000 QC 10.0000 QC 5.0000 QC 10.0000 RT 8.648 8.653 8.565 8.566 8.611 8.649 8.826 8.521 8.823 8.520 8.691 8.782 8.517 8.605 8.603 8.649 8.737 8.650 8.518 8.516 8.481 8.698 8.601 8.605 8.689 8.738 8.564 8.737 8.649 8.738 8.645 8.649 8.647 8.653 8.559 8.567 8.780 8.651 8.691 8.476 8.736 8.695 8.689 8.649 8.696 8.648 8.732 8.602 8.559 8.655 Area Flag 9716.20 bb 1009.73 bb 364.03 bb 1551.82 bb 1758.05 bb 973.54 bb 1890.02 bb 941.69 bb 6672.14 bb 42.48 bb 521.21 bb 38.07 bb 7295.83 bb 6609.90 bb 1330.65 bb 1953.24 bb 2317.06 bb 1285.98 bb 1680.80 bb 1113.48 bb 64.07 MM 62.56 bb 111.86 MM 257.20 bb 505.38 bb 594.05 bb 578.09 bb 988.67 bb 219.11 bb 98.50 bb 2696.85 474.26 84.30 65.89 54.96 627.19 731.68 126.35 179.52 163.25 154.24 154.68 bb bb bb bb bb bb bb bb bb bb bb bb 483.59 bb 280.49 482.64 334.60 158.61 102.62 62.65 bb bb bb bb bb bb 1027.80 bb ng/mL %Rec Mod Comment 121.72 12.03 4.17 18.65 21.18 11.58 22.80 11.20 82.54 0.27 6.08 122 0.21 90.49 81.75 15.95 23.57 28.05 15.40 20.23 13.29 0.53 b 0.51 1.11 b 2.87 5.88 6.96 6.77 11.77 118 2.41 0.95 32.73 5.51 0.77 0.55 0.42 7.37 8.64 1.28 1.93 1.73 1.62 1.63 5.62 112 3.15 5.61 3.81 1.68 1.00 0.51 12.25 122 Page 2 Page 713 o f 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 2: PFHS Sample List: dl00904a Method Pile: dl00904a Coefficient of Determination: 0.999048 Calibration curve: -0.0149532 * x*2 + 67.1258 x + 24.1617 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a001 dl00904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl00904a007 dl00904a008 dl00904a009 dl00904a010 dl00904a011 dl00904a012 dl00904a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dl00904a025 dl00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl00904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a051 dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80: 20 ACN:H20 09004-182 80: 20 A C N :H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80: 20 ACN:H20 09004-182 80: 20 A C N :H20 09004-182 80: 20 ACN:H20 09004-182 80: 20 A C N :H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-02 Method Blank 2 w/o IS MB-100831-03 Method Blank 3 w/o IS MB-100831-04 Method Blank 4 w/ IS MB-100831-05 Method Blank 5 w / IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR-842 LCS-100831-02 3 ng LCS in TCR-842 LCS-100831-03 3 ng LCS in TCR-842 LCS-100831-04 30 ng LCS in TCR-842 LCS-100831-05 30 ng LCS in TCR-842 LCS-100831-06. 30 ng LCS in TCR-842 09004-182 80: 20 A C N :H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80: 20 A C N :H20 GLP10-01-01-05-001 DAL SD TRIP1 I0 100624 GLP10-01- 01-05 -002 DAL SD SD01 0 0000 GLP10-01-01-05-003 DAL SD SD01 0 0005 GLP10-01-01-05-004 DAL SD SD02 0 0000 GLP10-01-01-05-005 DAL SD SD02 0 0005 GLP10-01-01-05-006 DAL SD SD03 0 0000 GLP10-01-01-05-007 DAL SD SD03 0 0005 GLP10-01-01-05-009 DAL SD SD04 0 0000 GLP10-01-01-05-010 DAL SD SD04 0 0005 GLP10-01-01-05-011 DAL SD SD05 0 0000 GLP10-01-01-05-012 DAL SD SD05 0 0005 GLP10-01-01- 05-013 DAL SD SD06 0 0000 GLP10-01- 01-05-014 DAL SD SD06 0 0005 GLP10-01-01-05-015 DAL SD SD07 0 0000 GLP10-01-01-05-016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DA SD08 DB 0000 GLP10-01-01-05-019 DAL SD SD08 0 0005 GLP10-01- 01- 05-021 DAL SD SD09 0 0000 GLP10-01-01-05-022 DAL SD SD09 0 0005 GLP10-01-01-05-023 DAL SD SD10 0 0000 Type STD Cone.(ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 QC 5.0000 RT 9.616 9.488 9.569 9.562 9.439 9.532 9.535 9.615 9.570 9.533 9.571 9.618 9.836 9.529 9.487 9.534 9.484 9.653 9.492 9.484 9.399 9.527 9.480 9.487 9.574 9.396 9.484 9.529 9.573 9.616 9.443 9.487 9.488 9.533 9.576 9.531 9.484 9.617 9.486 9.569 9.570 9.573 9.490 3M Study GLP10-01-02 q u a n t i t a ^ ^ o0p^!|' jginted ,10/18/10 nnnh Area Flags ng/mL %Rec Mod Comment 51 .53 80 .05 98 .46 176 .78 332 .66 708 .24 1949 .87 3492..32 5847 .00 13242..41 29812..60 bb bb bb bb bb bb bb bb bb bb bb 22..12 bb 16..90 bb 12..43 bb 0..41 0 .83 1..11 2 .27 4 .60 10 .21 28 .87 52..28 88 .49 206..41 499..31 82 111 111 91 92 102 115 105 88 103 100 0..00 0..00 0..00 235.43 213.48 299.24 2587.54 2485.46 2347.82 bb bb bb bb bb bb 457.77 MM 240.33 183.44 3106.04 1215.83 3304.31 1451.67 12570.29 8586.67 4562.57 4806.88 3119.85 2512.00 2819.74 4253.22 18.44 802.76 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 4438.54 7692.32 1610.92 11963.67 9375.35 43290.91 bb bb bb bb bb bb 3.15 2.82 4.10 38.52 36.97 34.89 6.47 129 3.22 2.37 46.39 17.82 49.41 21.37 195.41 131.41 68.66 72.42 46.60 37.37 42.04 63.91 0.00 11.63 116 66.76 117.30 23.76 185.54 143-92 780.14 Page 3 Page 714 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Lists Last modified: Methods Last modified: Job Code: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Tue Sep 07 09:28:22 2010 D:\masslynx\davey2010.PRO\MethDB\dl00904a Tue Sep 07 13 :49:4 2010 Printed: Tue Oct 19 16:33:39 2010 Compound 2s PFHS Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.999048 Calibration curve: -0.0149532 * x"2 + 67.1258 * x + 24.1617 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a058 dl00904a059 dl0Q904a060 dl00904a061 dl00904a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 dl00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904al00 dl00904al01 dl00904al02 dl00904al03 dl00904al04 dl00904al05 dl00904al06 dl00904al07 dl00904al08 dl00904al09 dl00904all0 dl00904alll dl00904all2 dl00904all3 dl00904all4 Samplelist ID GLP10-01-01-05-024 DAL SD SD10 0 0005 GLP10-01-01-05-025 DAL SD SDII 0 0000 GLP10-01-01-05-026 DAL SD SDII 0 0005 GLP10-01-01-05-027 DAL SD SD12 0 0000 GLP10-01-01-05-028 DAL SD SD12 DB 0000 GLP10-01-01-05-029 DAL SD SD12 0 0005 GLP10-01-01-05-030 DAL SD SD13 0 0000 GLP10-01-01-05-031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-033 DAL SD SD14 0 0005 GLP10-01-01-05-034 DAL SD SD15 0 0000 GLP10-01-01-05-035 DAL SD SD15 0 0005 GLP10-01-01-05-036 DAL SD SD16 0 0000 GLP10-01-01-05-037 DAL SD SD16 DB 0000 GLP10-01-01-05-038 DAL SD SD16 0 0005 GLP10-01-01- 05-039 DAL SD SD17 0 0000 GLP10-01-01-05-040 DAL SD SD17 0 0005 GLP10-01-01-05-041 DAL SS SS01 0 0000 GLP10-01-01-05-042 DAL SS SS01 0 0005 GLP10-01-01- 05-043 DAL SS SS02 0 0000 GLP10-01-01- 05-044 DAL SS SS02 0 0005 GLP10-01-01-05-045 DAL SS SS03 0 0000 GLP10-01-01-05-046 DAL SS SS03 0 0005 GLP10-01-01-05-047 DAL SS SS03 DB 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01- OS -048 DAL SS SS04 0 0000 GLP10-01-01- 05 -049 DAL SS SS04 0 0005 GLP10-01-01-05-050 DAL s s TRI PI 0 0000 GLP10-01-01- 05 -051 DAL s s SS05 0 0000 GLP10-01-01- 05 -052 DAL s s SS05 0 0005 GLP10-01-01- 05 -054 DAL s s SS06 0 0000 GLP10-01-01- 05 -055 DAL s s SS06 0 0005 GLP10-01-01- 05 -056 DAL s s SS06 DB 0005 GLP10-01-01- 05 -057 DAL s s SS07 0 0000 GLP10-01-01-05-058 DAL s s SSQ7 0 0005 GLP10-01-01-05-059 DAL s s SS08 0 0000 GLP10-01-01-05-060 DAL s s SS08 DB 0000 GLP10-01-01-05-061 DAL s s SS08 0 0005 GLP10-01-01-05-062 DAL s s SS09 0 0000 GLP10-01-01-05-063 DAL s s SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-064 DAL s s GP01 0 0000 GLP10-01- 01-05-065 DAL s s GP01 0 0005 GLP10-01- 01-05-066 DAL s s GP01 0 0020 GLP10-01-01-05-067 DAL s s GP01 0 0060 GLP10-01-01-05-068 DAL s s GP02 0 0000 GLP10-01-01-05-069 DAL s s GP02 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type STD Co n c . (ng/mL) QC 5.0000 QC 10.0000 QC 5.0000 QC 10.0000 RT 9.571 9.532 9.443 9.445 9.447 9.572 9.620 9.486 9.615 9.400 9.528 9.443 9.441 9.527 9.526 9.487 9.616 9.572 9.441 9.437 9.448 9.576 9.438 9.615 9.569 9.617 9.487 9.133 9.572 9.752 9.573 9.531 9.523 9.486 9.570 9.489 9.524 9.448 9.571 9.617 9.570 9.444 9.530 9.574 9.613 9.573 9.574 9.571 9.700 9.612 9.663 3M Study GLP10-01-02 quantit^t^d^9^7^y)^an^l^:inted 10/18/10 mmh Area Flags 43952.43 bb 15506.19 bb 3034.65 bb 19675.58 bb 17501.59 bb 16583.80 bb 16546.64 bb 7863.35 bb 90470.95 bbl 41.42 bb 419.91 bb 11.01 bb 97953.80 bbl 37150.08 bb 8314.25 bb 38613.29 bb 42204.82 bb 24308.65 bb 42474.01 bb 31626.10 bb 348.84 bb 606.94 bb 579.03 MM 4352.56 bb 16756.27 bb 11273.47 bb 11031.40 bb 12.51 bb 785.45 bb 14.92 bb 332.37 bb 152.73 bb 24261.52 3535.53 177.50 64.85 71.67 2604.68 4716.76 320.39 460.92 147.67 315.72 334.78 bb bb bb bb bb bb bb bb bb MM bb bb 405.64 bb 316.23 605.24 807.90 192.85 29.71 bb MM bb bb MM 831.65 bb ng/mL %Rec Mod Comment 795.32 243.89 45.31 314.84 277.53 261.99 261.36 119.99 0.26 5.90 0.00 118 646.06 127.10 676.97 755.55 396.86 761.60 534.41 4.84 8.70 8.28 65.44 264.90 174.36 170.45 0.00 11.37 0.00 4.60 1.92 114 b 396.01 52.93 2.29 0.61 0.71 38.78 71.03 4.42 6.52 1.84 4.35 4.63 b 5.69 114 4.36 8.67 11.71 2.51 0.08 b a 12.06 121 Page 4 Page 715 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Listt D t \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 3: PFOS Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.999052 Calibration curve: -0.000561508 * x A2 + 51.2225 * x + 23.3229 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a001 dl00904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl00904a007 dl00904a008 dl00904a009 dl00904a010 dl00904a011 dl00904a012 dl00904a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dl00904a025 dl00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl00904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a051 dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-02 Method Blank 2 w/o IS MB-100831-03 Method Blank 3 w/o IS MB-100831-04 Method Blank 4 w/ IS MB-100831-05 Method Blank 5 w/ IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR-842 LCS-100831-02 3 ng LCS in TCR-842 LCS-100831-03 3 ng LCS in TCR-842 LCS-100831-04 30 ng LCS in TCR-842 LCS-100831-05 30 ng LCS in TCR-842 LCS-100831-06 30 ng LCS in TCR-842 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-001 DAL SD TRIP1 0 100624 GLP10-01-01-05-002 DAL SD SD01 0 0000 GLP10-01-01-05-003 DAL SD SD01 0 0005 GLP10-01-01-05-004 DAL SD SD02 0 0000 GLP10-01-01-05-005 DAL SD SD02 0 0005 GLP10-01-01-05-006 DAL SD SD03 0 0000 GLP10-01-01-05-007 DAL SD SD03 0 0005 GLP10-01-01-05-009 DAL SD SD04 0 0000 GLP10-01-01-05-010 DAL SD SD04 0 0005 GLP10-01-01-05-Oil DAL SD SD05 0 0000 GLP10-01-01-05-012 DAL SD SD05 0 0005 GLP10-01-01-05-013 DAL SD SD06 0 0000 GLP10-01-01-05-014 DAL SD SD06 0 0005 GLP10-01- 01- 05 -015 DAL SD SD07 0 0000 GLP10-01- 01- 05-016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01- 01- 05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DAL SD SD08 DB 0000 GLP10-01-01- 05 -019 DAL SD SD08 0 0005 GLP10-01-01-05-021 DAL SD SD09 0 0000 GLP10-01-01- 05 -022 DAL SD SD09 0 0005 GLP10-01-01- 05-023 DAL SD SD10 0 0000 Type STD Cone.{ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 RT 10.364 10.367 10.368 10.408 10.324 10.406 10.398 10.363 10.413 10.416 10.450 10.448 10.412 10.451 10.360 10.323 10.446 10.323 Area Flags 39.69 bb 14.08 bb 60.66 MMX 33.75 bbx 86.78 bbX 66.52 bb 129.58 bb 290.84 bb 583.65 bb 1564.69 bb 2850.59 bb 4528.84 bb 10197.40 bb 25594.87 bb 24.07 bb 25.66 bb 31.40 bb 19.29 bb 10.366 10.192 10.449 16.00 23.73 12.56 bb bb bb 10.452 11.67 bb 10.279 177.11 bb 10.415 171.81 bb 10.277 183.34 bb 10.489 1811.55 bb 10.373 1794.32 bb 10.321 1788.94 bb 10.363 24.58 bb QC 5.0000 10.320 297.38 bb 10.456 21.65 bb 10.362 12455.45 bb 10.316 11149.27 bb 10.367 181786.55 bb 10.322 57585.29 bb 10.318 32194.37 bb 10.362 30417.51 bb 10.366 124010.22 bb 10.409 123872.95 bb 10.497 35952.61 bb 10.322 33892.76 bb 10.410 38738.40 bb 10.323 26416.69 bb 10.368 62390.79 bb 10.413 95279.35 bb 10.410 82.57 bb QC 10.0000 10.320 643.88 bb 10.275 53.79 bb 10.368 30490.08 bb 10.323 59983.15 bb 10.363 18691.24 bb 10.405 79050.02 bb 10.407 71514.23 bb 10.283 193821.80 bb ng/mL %Rec Mod 0.32 0.00 0.73 364 0.20 41 1.24 165 0.84 84 2.07 83 5.22 104 10.94 109 30.10 120 55.23 110 88.04 88 199.06 100 501.99 100 0.01 0.05 0.16 0.00 0.00 0.01 0.00 0.00 3.00 2.90 3.12 34.92 34.59 34.48 0.02 5.35 107 0.00 243.36 217.73 3698.45 1137.96 632.45 597.29 2488.43 2485.60 706.91 666.08 762.19 518.21 1234.28 1899.19 1.16 12.12 0.59 598.72 1185.99 365.92 1569.83 1417.73 3954.92 121 Page 5 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: Last modified: Method: Last modified: Job Code: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Tue Sep 07 09:28:22 2010 D:\masslynx\davey2010.PRO\MethDB\dl00904a Tue Sep 07 13:49:46 2010 Printed: Tue Oct 19 16:33:39 2010 Compound 3: PFOS Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.999052 Calibration curve: -0.000561508 * x A2 + 51.2225 * x + 23.3229 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a058 dl00904a059 dl00904a060 dl00904a061 dl00904a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 dl00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904al00 dl00904al01 dl00904al02 dl00904al03 dl00904al04 dl00904al05 dl00904al06 dl00904al07 dl00904al08 dl00904al09 dl00904all0 dl00904alll dl00904all2 dl00904all3 dl00904all4 Samplelist ID GLP10-01-01-05 -024 DAL SD SD10 0 0005 GLP10-01-01-05 -025 DAL SD SDII 0 0000 GLP10-01-01-05 -026 DAL SD SDII 0 0005 GLP10-01-01-05 -027 DAL SD SD12 0 0000 GLP10-01-01- 05 -028 DAL SD SD12 DB 0000 GLP10-01-01-05-029 DAL SD SD12 0 0005 GLP10-01-01-05 -03 0 DAL SD SD13 0 0000 GLP10-01-01-05-031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 I:H20 GLP10-01- DAL SD SD14 0 0005 GLP10-01- DAL SD SD15 0 0000 GLP10-01- DAL SD SD15 0 0005 GLP10-01- DAL SD SD16 0 0000 GLP10-01- DAL SD SD16 DE; 0000 GLP10-01- DAL SD SD16 0 0005 GLP10-01- DAL SD SD17 0 0000 GLP10-01- DAL SD SD17 0 0005 GLP10-01- DAL SS SS01 0 0000 GLP10-01- DAL SS SS 01 0 0005 GLP10-01- DAL SS SS02 0 0000 GLP10-01- DAL SS SS02 0 0005 GLP10-01- DAL SS SS03 0 0000 GLP10-01GLP10-01- DAL SS SS03 0 0005 DAL ss SS03 DEi 0005 09004-182 I:H2Q EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-048 DAL SS SS04 0 0000 GLP10-01-01-05-049 DAL SS SS04 0 0005 GLPlO-01-01-05-050 DAL SS TRIPI 0' 0000 GLP10-01- 01- 05 -051 DAL SS SS05 0 0000 GLP10-01-01-05-052 DAL SS SS05 0 0005 GLP10-01-01-05 -054 DAL SS SS06 0 0000 GLP10-01- 01-05 -055 DAL SS SS06 0 0005 GLPlO-01-01-05-056 DAL SS SS06 DE; 0005 GLPlO-01-01-05-057 DAL SS SS07 0 0000 GLP10-01-01-05-058 DAL SS SS07 0 0005 GLP10-01- 01-05 -059 DAL SS SS08 0 0000 GLPlO-01-01-05-060 DAL SS SS08 DE1 0000 GLPlO-01-01-05-061 DAL SS SS08 0 0005 GLP10-01-01-05 -062 DAL SS SS09 0 0000 GLP10-01-01-05-063 DAL SS SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve! Point 09004-182 80:20 ACN:H20 GLPlO-01-01-05-064 DAL SS GP01 0 0000 GLP10-01- 01-05 -065 DAL SS GP01 0 0005 GLP10-01-01-05-066 DAL SS GP01 0 0020 GLP10-01-01-05-067 DAL SS GP01 0 0060 GLP10-01-01-05-068 DAL SS GP02 0 0000 GLP10-01-01-05-069 DAL SS GP02 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type QC STD Cone.(ng/mL) 10.0000 5.0000 10.409 10.411 10.278 10.282 10.328 10.276 10.457 10.408 10.408 10.281 10.409 10.278 10.234 10.406 10.406 10.280 10.408 10.367 10.277 10.272 10.329 10.455 10.276 10.406 10.317 10.452 10.322 10.315 10.451 10.326 10.452 10.454 10.449 10.491 10.366 10.406 10.413 10.360 10.285 10.450 10.452 10.406 10.324 10.366 10.452 10.450 10.449 Area Flags 438713.47 bb 103615.52 bb 23901.36 bb 130134.23 bb 103524.86 bb 57339.45 bb 109771.51 bb 51493.48 bb 339720.53 bb 203.31 bb 389.30 bb 62.55 bb 229050.64 bb 608059.31 bb 361344.50 bb 194227.02 bb 219608.59 bb 66649.19 bb 218678.67 bb 158579.23 bb 40123.04 bb 63165.21 bb 29130.45 bb 10329.41 bb 121684.05 bb 100588.97 bb 120537.97 bb 94.00 bb 683.27 bb 31.51 bb 17036.49 bb 11695.58 bb 66.46 bb 475351.31 bb 137533.02 bb 15236.04 bb 6632.87 bb 8072.81 bb 26438.86 bb 125733.45 bb 2648.56 bb 3448.52 bb 1505.64 bb 22390.66 bb 23046.98 bb 35.58 bb 375.75 MM 10.410 10.366 10.406 10.406 10.404 10.360 10.450 10.499 10.366 16052.99 9640.34 16569.16 1446.14 3490.77 5451.12 22.74 659.54 21.61 bb bb bb bb bb bb bb bb bb .q u a n tit GLP10-01-02 ^ a n ^ ^ ^ i n t e a ,10/18/10 ng/mL %Rec Mod Comment 9567.93 2069.34 468.57 2615.08 2067.48 1133.04 2195.41 1016.15 7200.08 3.51 7.15 143 0.77 4714.91 14027.51 7704.68 3963.59 4509.84 1319.81 4489.70 3208.27 789.69 1249.82 571.83 201.65 2440.43 2007.49 2416.79 1.38 12.89 129 0.16 333.36 228.45 0.84 10484.73 2768.58 297.97 129.22 157.42 518.65 2524.03 51.28 66.92 28.95 438.78 451.72 0.24 6.88 138 ab 314.02 188.14 324.17 27.79 67.74 106.09 0.00 12.42 0.00 124 Page 6 Page 717 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 4: 1802 PFBS (IS) Sample List: dl00904a Response Factor: 57.1735 RRF SD: 9.20195, % Relative SD: 16.0948 Response type: External Std, Area Curve type: RF Method File: dl00904a Name dl009Q4a001 dl00904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl00904a007 dl00904a008 dl00904a009 dl00904a010 dl00904a011 dl00904a012 dl009Q4a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dlQ0904a02S dl00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl00904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a051 dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80:20 ACN-.H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-02 Method Blank 2 w/o IS MB-100831-03 Method Blank 3 w/o IS MB-100831-04 Method Blank 4 w/ IS MB-100831-05 Method Blank 5 w / IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR-842 LCS-100831-02 3 ng LCS in TCR-842 LCS-100831-03 3 ng LCS in TCR-842 LCS-100831-04 30 ng LCS in TCR-842 LCS-100831-05 30 ng LCS in TCR-842 LCS-100831-06 30 ng LCS in TCR-842 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-001 DAL SD TRIP1 0 100624 GLP10-01-01-05-002 DAL SD SD01 0 0000 GLP10-01-01-05-003 DAL SD SD01 0 0005 GLP10-01-01-05-004 DAL SD SD02 0 0000 GLP10-01-01-05-005 DAL SD SD02 0 0005 GLP10-01-01-05-006 DAL SD SD03 0 0000 GLP10-01- 01-05-007 DAL SD SD03 0 0005 GLP10-01-01-05-009 DAL SD SD04 0 0000 GLP10-01- 01-05-010 DAL SD SD04 0 0005 GLP10-01- 01-05-011 DAL SD SD05 0 0000 GLP10-01- 01-05-012 DAL SD SD05 0 0005 GLP10-01-01-05-013 DAL SD SD06 0 0000 GLP10-01-01-05-014 DAL SD SD06 0 0005 GLP10-01-01-05-015 DAL SD SD07 0 0000 GLP10-01-01-05-016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DAL SD SD08 DB 0000 GLP10-01-01-05-019 DAL SD SD08 0 0005 GLP10-01-01-05-021 DAL SD SD09 0 0000 GLP10-01-01-05-022 DAL SD SD09 0 0005 GLP10-01- 01-05-023 DAL SD SD10 0 0000 Type STD Co n e . (ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 QC 3.0000 QC 3.0000 RT 8.595 8.766 8.550 8.718 8.628 8.504 8.640 8.598 8.678 8.634 8.639 8.722 8.546 8.723 8.636 8.552 8.684 8.592 8.804 8.556 8.637 8.549 8.682 8.635 8.674 8.595 8.725 8.590 8.635 8.635 8.638 8.639 8.551 8.638 8.681 8.596 8.596 8.636 8.679 8.593 8.720 8.807 8.809 8.598 Area Flag 133.35 150.60 175.87 142.59 181.54 148.79 173.13 235.03 189.65 178.09 157.69 191.92 bb bb bb bb bb bb bb bb bb bb bb bb 194.61 185.00 178.23 184.74 235.93 251.34 222.92 242.09 222.91 bb bb bb bb bb bb bb bb bb 178.48 bb 274.71 199.68 147.13 180.29 197.17 130.85 187.85 192.39 208.43 221.83 181.82 200.95 199.10 169.42 207.61 bb bb bb bb bb bb bb bb bb bb bb MM bb bb bb 189.84 bb 220.85 235.41 272.73 172.02 184.67 191.57 bb bb bb bb bb bb q u a n tit ? ^ W o Q in li ^ T & lS & O /lS /lO Interim Report 05 ng/mL %Rec Mod Comment 2.33 2.63 3.08 2.49 3.18 2.60 3.03 4.11 3.32 3.11 2.76 3.36 78 88 103 83 106 87 101 137 111 104 92 112 3.40 3.24 3.12 3.23 4.13 4.40 3.90 4.23 3.90 113 108 104 108 138 147 130 141 130 3.12 104 4.80 3.49 2.57 3.15 3.45 2.29 3.29 3.37 3.65 3.88 3.18 3.51 3.48 2.96 3.63 160 116 86 105 115 76 110 112 122 129 106 117 116 99 121 3.32 111 3.86 4.12 4.77 3.01 3.23 3.35 129 137 159 100 108 112 Page 718 of 962 Quantify Compound Summary Report GLP10-01'02-05 screening data Sample List: Last modifiedt Method: Last modified: Job Code: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Tue Sep 07 09:28:22 2010 D:\masslynx\davey2010.PRO\MethDB\dl00904a Tue Sep 07 13:49:46 2010 Printed: Tue Oct 19 16:33:39 2010 Compound 4: 1802 PFBS (IS) Sample List: dl00904a Response Factor: 57.1735 RRF SD: 9.20195, % Relative SD: 16.0948 Response type: External Std, Area Curve type: RF Method File: dl00904a Name dl00904a058 dl00904a059 dl00904a060 dl00904a061 dl00904a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 dl00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904al00 dl00904al01 dl00904al02 dl00904al03 dl00904al04 dl00904al0S dl00904al06 dl00904al07 dl00904al08 dl00904al09 dl00904all0 dl00904alll dl00904all2 dl00904all3 dl00904all4 Samplelist ID GLP10-01- 01- 05 -024 DAL SD SD10 0 0005 GLP10-01- 01- 05 -025 DAL SD SDII 0 0000 GLP10-01- 01-05-026 DAL SD SDII 0 0005 GLP10-01- 01-05 -027 DAL SD SD12 0 0000 GLP10-01- 01-05 -028 DAL SD SD12 DBi 0000 GLP10-01- 01-05 -029 DAL SD SD12 0 0005 GLP10-01-01-05-030 DAL SD SD13 0 0000 GLP10-01-01- 05 -031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01-01-05 -033 DAL SD SD14 0 0005 GLP10-01-01-05-034 DAL SD SD15 0 0000 GLP10-01- 01- 05 -035 DAL SD SD15 0 0005 GLP10-01- 01- 05 -036 DAL SD SD16 0 0000 GLP10-01-01-05-037 DAL SD SD16 DB1 0000 GLP10-01- 01- 05 -038 DAL SD SD16 0 0005 GLP10-01-01-05-039 DAL SD SD17 0 0000 GLP10-01-01- 05 -040 DAL SD SD17 0 0005 GLP10-01-01- 05 -041 DAL SS SS01 0 0000 GLP10-01- 01- 05 -042 DAL SS SS01 0 0005 GLP10-01-01-05-043 DAL SS SS02 0 0000 GLP10-01-01-05-044 DAL SS SS02 0 0005 GLP10-01-01-05-045 DAL SS SS03 0 0000 GLP10-01- 01- 05 -046 DAL SS SS03 0 0005 GLP10-01-01-05-047 DAL SS SS03 DE1 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-048 DAL SS SS04 0 0000 GLP10-01- 01- 05 -04 9 DAL ss SS04 0 0005 GLP10-01- 01- 05 -050 DAL ss TRIP1 0: 0000 GLP10-01-01-05-051 DAL ss SS05 0 0000 GLP10-01- 01- 05 -052 DAL ss SS05 0 0005 GLP10-01-01-05-054 DAL ss SS06 0 0000 GLP10-01- 01- 05 -055 DAL ss SS06 0 0005 GLP10-01- 01- 05 -056 DAL ss SS06 DB1 0005 GLP10-01- 01- 05 -057 DAL ss SS07 0 0000 GLP10-01- 01- 05 -058 DAL ss SS07 0 0005 GLP10-01- 01- 05 -059 DAL ss SS08 0 0000 GLP10-01- 01- 05 -060 DAL ss SS08 DB; 0000 GLP10-01- 01- 05 -061 DAL ss SS08 0 0005 GLP10-01-01-05-062 DAL ss SS09 0 0000 GLP10-01- 01- 05 -063 DAL ss SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01- 01- 05 -064 DAL ss GP01 0 0000 GLP10-01- 01- 05 -065 DAL ss GP01 0 0005 GLP10-01- 01- 05 -066 DAL ss GP01 0 0020 GLP10-01- 01- 05 -067 DAL ss GP01 0 0060 GLP10-01-01-05-068 DAL ss GP02 0 0000 GLP10-01- 01-05-069 DAL ss GP02 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type STD Conc.(ng/mL) QC 3.0000 QC 3.0000 QC 3.0000 QC 3.0000 RT 8.635 8.683 8.552 8.553 8.598 8.635 8.813 8.551 8.809 8.678 8.548 8.592 8.590 8.636 8.724 8.680 8.548 8 .503 8.511 8.685 8.632 8.591 8.676 8.769 8.595 8.724 8.636 8.725 8.589 8.632 8.635 8.677 8.683 8.632 8.597 8.767 8.637 8 .721 8.506 8.679 8.682 8.676 8.679 8 .727 8.634 8.806 8.589 8.502 8.641 Area Flags 210.22 bb 189.47 bb 201.83 bb 187.95 bb 182.30 bb 136.25 bb 177.04 bb 82.44 bb 204.54 bb 221.70 bb 185.43 168.72 171.40 194.67 166.33 144.46 171.52 151.64 210.84 163.29 198.54 223.09 192.13 197.73 192.06 bb bb bb bb MM bb bb bb bb bb bb bb bb bb bb 215.45 bb 245.64 183.81 268.02 175.86 206.04 182.68 171.62 195.21 167.92 165.60 222.58 211.48 263.30 193.22 206.88 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 222.71 bb 152.96 149.24 152.10 94.95 196.18 191.91 bb bb bb bb bb bb 172.42 bb ng/mL %Rec Mod 3.68 123 3.31 110 3.53 118 3.29 110 3.19 106 2.38 79 3.10 103 1.44 48 3.58 119 3.88 129 3.24 2.95 3.00 3.40 2.91 2.53 3.00 2.65 3.69 2.86 3.47 3.90 3.36 3.46 3.36 108 98 100 113 97 84 100 88 123 95 116 130 112 115 112 3.77 126 4.30 3.21 4.69 3.08 3.60 3.20 3.00 3.41 2.94 2.90 3.89 3.70 4.61 3.38 3.62 143 107 156 103 120 107 100 114 98 97 130 123 154 113 121 3.90 130 2.68 2.61 2.66 1.66 3.43 3.36 89 87 89 55 114 112 3.02 101 guantita? M S t U d y oG L p 1 0 i 0 l :eQ2 LO/18/:i.O mmh . In te rim R e p o rt 0 5 Page 8 Page 719 o f 962 * "f t Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:2822 2010 Methodt Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed! Tue Oct 19 16:33:39 2010 Compound 5i 1802 PFHS (IS) Response Factor: 39.6869 RRF SD: 7.91154, % Relative Response type: External Std, Curve type: RF Sample List: SD: 19.9349 Area dl00904a Method Pile: dl00904a Name dl00904a001 dl00904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl00904a007 dl00904a008 dl00904a009 dl00904a010 dl00904a011 dl00904a012 dl00904a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dl00904a025 dl00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl00904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a0Sl dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831'06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank 1 w/o IS MB-100831-02 Method Blank 2 w/o IS MB-100831-03 Method Blank 3 w/o IS MB-100831-04 Method Blank 4 w/ IS MB-100831-05 Method Blank 5 w/ IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR-842 LCS-100831-02 3 ng LCS in TCR-842 LCS-100831-03 3 ng LCS in TCR-842 LCS-100831-04 30 ng LCS in TCR-842 LCS-100831-05 30 ng LCS in TCR-842 LCS-100831-06 30 ng LCS in TCR-842 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05- 001 DAL SD TRIP1 0 100624 GLP10-01-01-05-002 DAL SD SD01 0 0000 GLP10-01-01-05-003 DAL SD SD01 0 0005 GLP10-01-01- 05 -004 DAL SD SD02 0 0000 GLP10-01- 01- 05 -005 DAL SD SD02 0 0005 GLP10-01-01-05-006 DAL SD SD03 0 0000 GLP10-01-01-05-007 DAL SD SD03 0 0005 GLP10-01- 01- 05 -009 DAL SD SD04 0 0000 GLP10-01-01-05-010 DAL SD SD04 0 0005 GLP10-01-01-05-011 DAL SD SD05 0 0000 GLP10-01-01-05-012 DAL SD SD05 0 0005 GLP10-01-01- 05 -013 DAL SD SD06 0 0000 GLP10-01-01- 05 -014 DAL SD SD06 0 0005 GLP10-01-01-05-015 DAL SD SD07 0 0000 GLP10-01-01-05-016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DAL SD SD08 DB 0000 GLP10-01-01-05-019 DAL SD SD08 0 0005 GLP10-01-01- 05 -021 DAL SD SD09 0 0000 GLP10-01-01-05-022 DAL SD SD09 0 0005 GLP10-01-Q1-05-023 DAL SD SD10 0 0000 Type STD Co n e . (ng/mL) Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 QC 3.0000 QC 3.0000 RT 9.505 9.634 9.505 9.542 9.535 9.456 9.549 9.552 9.589 9.587 9.506 9.588 9.544 9.591 9.547 9.461 9.551 9.502 9.670 9.509 9.501 9.416 9.549 9.544 9.497 9.505 9.591 9.457 9.501 9.546 9.547 9.633 9.460 9.504 9.505 9.506 9.593 9.457 9.634 9.459 9.630 9.631 9.633 9.507 Area Flags 74.59 134.37 131.68 96.96 114.45 145.75 107.80 121.81 116.25 166.66 109.55 108.86 bb bb bb bb bb bb bb bb bb bb bb bb 89.79 126.82 143.23 115.50 134.53 178.70 151.46 140.55 87.35 bb bb bb bb bb bb bb bb bb 106.86 bb 155.46 128.60 140.74 85.31 146.17 101.18 93.89 148.79 113.00 119.25 110.10 143.15 91.00 94.45 118.80 bb bb bb bb bb bb bb bb bb bb MM bb bb bb bb 95.27 MM 89.13 93.51 104.50 155.11 163.15 123.63 bb bb bb bb bb bb ng/mL %Rec Mod 1.88 3.39 3.32 2.44 2.88 3.67 2.72 3.07 2.93 4.20 2.76 2.74 63 113 111 81 96 122 91 102 98 140 92 91 2.26 3.20 3.61 2.91 3.39 4.50 3.82 3.54 2.20 75 107 120 97 113 150 127 118 73 2.69 90 3.92 3.24 3.55 2.15 3.68 2.55 2.37 3.75 2.85 3.00 2.77 3.61 2.29 2.38 2.99 131 108 118 72 123 85 79 125 95 100 92 120 76 79 100 2.40 80 2.25 2.36 2.63 3.91 4.11 3.12 75 79 88 130 137 104 3 M S tu d y G L P 1 0 -0 1 -0 2 ,u" t i t YnT e p g r f g i n t e d 1 0 /1 8 /1 0 nnnh er?m7 R Page 9 Page 720 o f 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 5: 1802 PFHS (IS) Sample List: dl00904a Response Factor: 39.6869 RRF SD: 7.91154, % Relative SD: 19.9349 Response type: External Std, Area Curve type: RF Method File: dl00904a Name dl00904a058 dl00904a059 dl00904a060 dl00904a061 dl00904a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 d!00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904al00 dl00904al01 dl00904al02 dl00904al03 dl00904al04 dl00904al05 dl00904al06 dl00904al07 dl00904al08 dl00904al09 dl00904all0 dl00904alll dl00904all2 dl00904all3 dl00904all4 Samplelist ID GLP10-01-01-05-024 DAL SD SD10 0 0005 GLP10-01-01-05-025 DAL SD SDII 0 0000 GLP10-01-01-05-026 DAL SD SDII 0 0005 GLP10-01-01-05-027 DAL SD SD12 0 0000 GLP10-01-01-05-028 DAL SD SD12 DB. 0000 GLP10-01-01-05-029 DAL SD SD12 0 0005 GLP10-01-01-05-030 DAL SD SD13 0 0000 GLP10-01-01-05-031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-033 DAL SD SD14 0 0005 GLP10-01-01-05-034 DAL SD SD15 0 0000 GLP10-01- 01-05 -035 DAL SD SD15 0 0005 GLP10-01- 01- 05-036 DAL SD SD16 0 0000 GLP10-01-01-05-037 DAL SD SD16 DB; 0000 GLP10-01-01-05-038 DAL SD SD16 0 0005 GLP10-01- 01-05 -03 9 DAL SD SD17 0 0000 GLP10-01- 01-05 -040 DAL SD SD17 0 0005 GLP10-01- 01-05 -041 DAL SS SS01 0 0000 GLP10-01-01-05-042 DAL ss SS01 0 0005 GLP10-01-01-05-043 DAL ss SS02 0 0000 GLP10-01-01-05-044 DAL ss SS02 0 0005 GLP10-01-01-05-045 DAL ss SS03 0 0000 GLP10-01-01-05-046 DAL ss SS03 0 0005 GLP10-01-01-05-047 DAL ss SS03 DB. 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-048 DAL ss SS04 0 0000 GLP10-01-01-05-049 DAL ss SS04 0 0005 GLP10-01-01-05-050 DAL ss TRIPI 01 0000 GLP10-01-01-05-051 DAL ss SS05 0 0000 GLP10-01- 01-05-052 DAL ss SS05 0 0005 GLP10-01- 01-05 -054 DAL ss SS06 0 0000 GLP10-01- 01-05 -055 DAL ss SS06 0 0005 GLP10-01-01-05-056 DAL ss SS06 DE1 0005 GLP10-01- 01-05 -057 DAL ss SS07 0 0000 GLP10-01-01-05 -058 DAL ss SS07 0 0005 GLP10-01-01-05-059 DAL ss SS08 0 0000 GLP10-01-01-05-060 DAL ss SS08 DE1 0000 GLP10-01-01-05-061 DAL ss SS08 0 0005 GLP10-01-01-05-062 DAL ss SS09 0 0000 GLP10-01-01-05-063 DAL ss SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01-01-05 -064 DAL ss GP01 0 0000 GLP10-01-01-05-065 DAL ss GP01 0 0005 GLP10-01-01-05-066 DAL ss GP01 0 0020 GLP10-01-01-05-067 DAL ss GP01 0 0060 GLP10-01-01-05-068 DAL ss GP02 0 0000 GLP10-01-01-05-069 DAL ss GP02 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type STD Conc.(ng/mL) QC 3.0000 QC 3.0000 QC 3.0000 QC 3.0000 RT 9.632 9.506 9.460 9.419 9.464 9.589 9.637 9.503 9.632 9.545 9.458 9.500 9.544 9.504 9.633 9.546 9.458 9.498 9.465 9.593 9.499 9.632 9.586 9.634 9.460 9.589 9.591 9.548 9.499 9.540 9.503 9.587 9.550 9.541 9.465 9.588 9.591 9.543 9.417 9.547 9.591 9.630 9.590 9.548 9.588 9.717 9.499 9.411 9.637 Area Flags 106.01 bb 118.51 bb 95.72 bb 101.01 bb 125.35 bb 98.77 bb 140.51 bb 55.75 bb 119.19 MM 159.17 bb 136.90 162.23 124 .S8 88.51 127.33 107.67 123.54 83.02 146.37 111.93 142.47 163.88 117.03 137.38 117.66 bb bb bb MM bb bb bb bb bb bb MM bb bb bb bb 106.41 bb 122.93 143.85 130.19 158.39 156.15 153.53 157.65 124.77 128.46 124.86 125.77 106.94 100.00 11 1 .14 125.41 bb bb bb bb bb bb MM bb bb bb bb bb bb bb bb 139.29 bb 99.38 105.71 98.56 105.31 136.83 127.21 bb bb bb bb bb bb 122.54 bb ng/mL %Rec Mod Comment 2.67 89 2.99 100 2.41 80 2.55 85 3.16 105 2.49 83 3.54 118 1.40 47 3.00 100 b 4.01 134 3.45 4.09 3.14 2.23 3.21 2.71 3.11 2.09 3.69 2.82 3.59 4.13 2.95 3.46 2.96 115 136 105 74 107 90 104 70 123 94 120 138 98 115 99 b 2.68 89 3.10 3.62 3.28 3.99 3.93 3.87 3.97 3.14 3.24 3.15 3.17 2.69 2.52 2.80 3.16 103 121 109 133 131 129 132 105 108 105 106 90 84 93 105 a 3.51 117 2.50 2.66 2.48 2.65 3.45 3.21 83 89 83 88 115 107 3.09 103 quantitated 9/7/10 Land printed 10/18/10 mmh 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o rt 0 5 iK - fmffS-VmS*'*-w f w m f,1a-HVAa iv:i\i u. s Page 10 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: Last modified: Method: Last modified: Job Code: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Tue Sep 07 09:28:22 2010 D:\masslynx\davey2010.PRO\MethDB\dlO0904a Tue Sep 07 13:49:46 2010 Printed: Tue Oct 19 16:33:39 2010 Compound 6: MPFOS (Surr) Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.995207 Calibration curve: -0.00232308 * x*2 + 29.4033 * x + -2.49902 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a001 dlQ0904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl00904a007 dl00904a008 dl00904a009 dl00904a010 dl00904a011 dl00904a012 dl00904a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dl00904a025 dl00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl00904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a051 dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-1008 31- 01 Method Blank 1 w/o IS MB-100831-02 Method Blank 2 w/o IS MB-100831-03 Method Blank 3 w/o IS M B -100831-04 Method Blank 4 w/ IS MB -1008 31- 05 Method Blank 5 w/ IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR-842 LCS-100831-02 3 ng LCS in TCR-842 LCS-100831-03 3 ng LCS in TCR-842 LCS-100831-04 30 ng LCS in TCR-842 LCS-100831-05 30 ng LCS in TCR-842 LCS-100831-06 30 ng LCS in TCR-842 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-001 DAL SD TRIP1 0 100624 GLP10-01-01-05-002 DAL SD SD01 0 0000 GLP10-01- 01-05-003 DAL SD SD01 0 0005 GLP10-01-01-05-004 DAL SD SD02 0 0000 GLP10-01- 01-05-005 DAL SD SD02 0 0005 GLP10-01- 01-05-006 DAL SD SD03 0 0000 GLP10-01-01-05-007 DAL SD SD03 0 0005 GLP10-01- 01-05-009 DAL SD SD04 0 0000 GLP10-01-01-05-010 DAL SD SD04 0 0005 GLP10-01-01-05-011 DAL SD SD05 0 0000 GLP10-01- 01-05-012 DAL SD SD05 0 0005 GLP10-01- 01-05-013 DAL SD SD06 0 0000 GLP10-01- 01-05-014 DAL SD SD06 0 0005 GLP10-01- 01-05-015 DAL SD SD07 0 0000 GLP10-01- 01-05-016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01- 01-05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DAL SD SD08 DB 0000 GLP10-01- 01-05-019 DAL SD SD08 0 0005 GLP10-01-01-05-021 DAL SD SD09 0 0000 GLP10-01- 01-05-022 DAL SD SD09 0 0005 GLP10-01- 01-05-023 DAL SD SD10 0 0000 Type STD Cone.(ng/mL) RT Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 0.2000 0.5000 0.7500 1.0000 2.5000 5.0000 10.0000 25.0000 50.0000 100.0000 200.0000 500.0000 10.412 10.328 10.279 10.402 10.281 10.416 10.419 10.411 10.452 10.373 10.455 10.453 10.415 10.456 10.326 10.419 10.368 10.493 10.420 10.369 QC 5.0000 10.460 10.366 10.319 10.371 10.369 10.322 10.366 10.370 10.412 10.544 10.326 10.414 10.371 10.372 10.416 QC 10.0000 10.324 10.415 10.327 10.411 10.452 10.454 10.331 Area Flags 11.08 26.40 37.88 71.23 12.08 179.95 1177.82 1687.02 2964.06 5046.41 14362.68 bb bb bb bb bb bb bb bb bb bb bb 107.22 91.97 87.26 121.92 84.37 122.74 135.53 102.09 128.60 bb bb bb MM MM bb bb bb bb 99.83 94.59 106.01 95.93 113.50 87.60 148.89 149.91 90.12 136.32 91.22 112.91 135.66 96.44 74.89 140.11 110.35 104.13 111.48 92.64 104.42 95.40 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb ng/mL %Rec 0.46 0.98 1.37 2.51 0.50 6.21 40.27 57.72 101.71 174.11 509.03 92 131 137 100 10 62 161 115 102 87 102 3.73 3.21 3.05 4.23 2.95 4.26 4.70 3.56 4.46 3.48 3.30 3.69 3.35 3.95 3.06 5.15 5.19 3.15 4.72 3.19 3.93 4.70 3.37 2.63 4.85 3.84 3.63 3.88 3.24 3.64 3.33 49 guantit 10/18/10 mmh Page 11 Page 722 o f 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 6: MPFOS (Surr) Sample List: dl00904a Method File: dl00904a Coefficient of Determination: 0.995207 Calibration curve: -0.00232308 * x A2 + 29.4033 * x + -2.49902 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Name dl00904a058 dl00904a059 dl00904a060 dl00904a061 dl00904a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 dl00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904al00 dl00904al01 dl00904al02 dl00904al03 dl00904al04 dl00904al05 dl00904al06 dl00904al07 dl00904al08 dl00904al09 dl00904all0 dl00904alll dl00904all2 dl00904all3 dl00904all4 Samplelist ID GLP10-01-01-05-024 DAL SD SD10 0 0005 GLP10-01-01-05-025 DAL SD SDII 0 0000 GLP10-01-01-05-026 DAL SD SDII 0 0005 GLP10-01-01-05-027 DAL SD SD12 0 0000 GLP10-01- 01-05-028 DAL SD SD12 DE; 0000 GLP10-01- 01-05 -02 9 DAL SD SD12 0 0005 GLP10-01- 01-05-030 DAL SD SD13 0 0000 GLP10-01- 01-05-031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-033 DAL SD SD14 0 0005 GLP10-01-01-05-034 DAL SD SD15 0 0000 GLP10-01-01-05-035 DAL SD SD15 0 0005 GLP10-01-01-05-036 DAL SD SD16 0 0000 GLP10-01-01-05-037 DAL SD SD16 DE; 0000 GLP10-01-01-05-038 DAL SD SD16 0 0005 GLP10-01-01-05-039 DAL SD SD17 0 0000 GLP10-01-01-05-040 DAL SD SD17 0 0005 GLP10-01-01-05-041 DAL SS SS01 0 0000 GLP10-01-01-05-042 DAL ss SS01 0 0005 GLP10-01-01-05-043 DAL ss SS02 0 0000 GLP10-01-01-05-044 DAL ss SS02 0 0005 GLP10-01-01-05 -045 DAL ss SS03 0 0000 GLP10-01-01-05-046 DAL ss SS03 0 0005 GLP10-01-01-05-047 DAL ss SS03 DEi 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-048 DAL ss SS04 0 0000 GLP10-01-01-05-049 DAL ss SS04 0 0005 GLP10-01-01-05-050 DAL ss TRIP1 0i 0000 GLP10-01-01-05-051 DAL ss SS05 0 0000 GLP10-01-01-05-052 DAL ss SS05 0 0005 GLP10-01-01-05 -054 DAL ss SS06 0 0000 GLP10-01-01-05-055 DAL ss SS06 0 0005 GLP10-01-01-05-056 DAL ss SS06 DEi 0005 GLP10-01-01-05-057 DAL ss SS07 0 0000 GLP10-01-01-05-058 DAL ss SS07 0 0005 GLP10-01-01-05-059 DAL ss SS08 0 0000 GLP10-01-01-05-060 DAL ss SS08 DEI 0000 GLP10-01-01-05-061 DAL ss SS08 0 0005 GLP10-01-01-05-062 DAL ss SS09 0 0000 GLP10-01-01-05-063 DAL ss SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-064 DAL ss GP01 0 0000 GLP10-01-01-Q5-065 DAL ss GP01 0 0005 GLP10-01-01-05-066 DAL ss GP01 0 0020 GLP10-01-01-05-067 DAL ss GP01 0 0060 GLP10-01-01-05-068 DAL ss GP02 0 0000 GLP10-01-01-05-069 DAL ss GP02 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type QC QC QC QC STD Conc.(ng/mL) RT 10.456 10.415 10.326 10.373 10.375 10.368 10.504 10.500 10.455 5.0000 10.326 10.410 10.410 10.328 10.499 10.457 10.324 10.320 10.286 10.458 10.323 10.454 10.365 10.456 10.326 10.0000 10.455 10.456 10.458 10.453 10.495 10.369 10.410 10.417 10.320 10.332 10.453 10.413 10.410 10.328 10.413 10.499 5.0000 10.414 10.413 10.410 10.453 10.408 10.363 10.0000 10.503 ^ a n t i t # SM ^ 0 G k 5 1& P n 1t e 10/18/10 mmh Interim Reportas Area Flags 66.95 MM 68.54 bb 132.81 bb 114.30 bb 112.40 bb 89.97 bb 101.84 MM 50.91 bb 68.56 bb ng/mL %Rec Mod Comment 2.36 b 2.42 4.60 3.97 3.91 3.15 3.55 b 1.82 2.42 76.25 87.80 81.91 62.87 84.56 60.37 86.17 85.61 100.44 71.82 112.96 111.78 113.13 86.54 105.60 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 143.77 bb 97.38 147.80 107.73 70.39 86.86 144.97 78.81 102.70 111.60 57.22 96.30 114.26 108.79 110.89 119.73 bb bb bb bb bb bb bb bb bb bb bb MM MM bb bb 2.68 3.07 2.87 2 .22 2.96 2.14 3.02 3.00 3.50 2.53 3.93 3.89 3.93 3.03 3.68 4.98 3 .40 5.11 3.75 2.48 3.04 5.02 2.77 3.58 3.88 2.03 3.36 3.97 3.79 3.86 4.16 99.25 71.69 82.12 66.90 114.62 131.59 206.21 bb bb bb bb MM bb bb 3.46 2.52 2.88 2.36 3.98 4.56 7.10 Page 12 Page 723 of 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample Lists Last modified: Method: Last modified: Job Code: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Tue Sep 07 09:28:22 2010 D:\masslynx\davey2010.PRO\MethDB\dl00904a Tue Sep 07 13:49:46 2010 Printed: Tue Oct 19 16:33:39 2010 Compound 7: 13C8 PFOS (IS) Sample List: d!00904a Response Factor: 30.7999 RRF SD: 6.24032, % Relative SD: 20.2609 Response type: External Std, Area Curve type: RF Method File: dl00904a Name dl00904a001 dl00904a002 dl00904a003 dl00904a004 dl00904a005 dl00904a006 dl009Q4a007 dl00904a008 dl00904a009 d!00904a010 dl00904a011 dl00904a012 dl00904a013 dl00904a014 dl00904a015 dl00904a016 dl00904a017 dl00904a018 dl00904a019 dl00904a020 dl00904a021 dl00904a022 dl00904a023 dl00904a024 dl00904a025 dl00904a026 dl00904a027 dl00904a028 dl00904a029 dl00904a030 dl00904a031 dl00904a032 dl00904a033 dl00904a034 dl00904a035 dl0Q904a036 dl00904a037 dl00904a038 dl00904a039 dl00904a040 dl00904a041 dl00904a042 dl00904a043 dl00904a044 dl00904a045 dl00904a046 dl00904a047 dl00904a048 dl00904a049 dl00904a050 dl00904a051 dl00904a052 dl00904a053 dl00904a054 dl00904a055 dl00904a056 dl00904a057 Samplelist ID 09004-182 80: 20 ACN:H20 09004-182 80::20 ACN.-H20 EC-100831-01 0.2 ng Extracted Curve Point EC-100831-02 0.5 ng Extracted Curve Point EC-100831-03 0.75 ng Extracted Curve Point EC-100831-04 1 ng Extracted Curve Point EC-100831-05 2.5 ng Extracted Curve Point EC-100831-06 5 ng Extracted Curve Point EC-100831-07 10 ng Extracted Curve Point EC-100831-08 25 ng Extracted Curve Point EC-100831-09 50 ng Extracted Curve Point EC-100831-10 100 ng Extracted Curve Point EC-100831-11 200 ng Extracted Curve Point EC-100831-12 500 ng Extracted Curve Point 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 09004-182 80:20 ACN:H20 MB-100831-01 Method Blank w/o IS MB-100831-02 Method Blank w/o IS MB-100831-03 Method Blank w/o IS MB-100831-04 Method Blank 4 w/ IS MB-100831-05 Method Blank 5 w/ IS MB-100831-06 Method Blank 6 w/ IS LCS-100831-01 3 ng LCS in TCR- 842 LCS-100831-02 3 ng LCS in TCR- 842 LCS-100831-03 3 ng LCS in TCR- 842 LCS-100831-04 30 ng LCS in TCR -842 LCS-100831-05 30 ng LCS in TCR -842 LCS-100831-06 30 ng LCS in TCR -842 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve: Point 09004-182 80:20 ACN:H20 GLP10-01- 01-05-001 DAL SD TRIP1 0 100624 GLP10-01- 01- 05-002 DAL SD SD01 0 0000 GLP10-01-01-05-003 DAL SD SD01 0 0005 GLP10-01- 01-05-004 DAL SD SD02 0 0000 GLP10-01- 01-05-005 DAL SD SD02 0 0005 GLP10-01-01-05-006 DAL SD SD03 0 0000 GLP10-01-01-05-007 DAL SD SD03 0 0005 GLP10-01-01-05-009 DAL SD SD04 0 0000 GLP10-01-01-05-010 DAL SD SD04 0 0005 GLP10-01-01-05-011 DAL SD SD05 0 0000 GLP10-01-01-05-012 DAL SD SD05 0 0005 GLP10-01-01-05-013 DAL SD SD06 0 0000 GLP10-01-01-05-014 DAL SD SD06 0 0005 GLP10-01-01-05-015 DAL SD SD07 0 0000 GLP10-01- 01- 05 -016 DAL SD SD07 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-017 DAL SD SD08 0 0000 GLP10-01-01-05-018 DAL SD SD08 DB 0000 GLP10-01-01-05-019 DAL SD SD08 0 0005 GLP10-01-01-05-021 DAL SD SD09 0 0000 GLP10-01-01-05-022 DAL SD SD09 0 0005 GLP10-01-01-05-023 DAL SD SD10 0 0000 Type STD Cone. (ng/mL) RT Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 3.0000 10.340 10.380 10.339 10.378 10.370 10.380 10.385 10.431 10.422 10.463 10.384 10.466 10.421 10.383 10.424 10.338 10.430 10.380 10.504 10.388 10.337 QC 3.0000 10.292 10.428 10.377 10.331 10.295 10.381 10.334 10.334 10.381 10.424 10.512 10.338 10.382 10.339 10.383 10.428 QC 3.0000 10.336 10.383 10.338 10.379 10.420 10.422 10.298 Area Flag. 83.00 64.92 99.47 107.53 70.45 136.83 91.84 104.06 86.21 91.28 90.68 82.52 bb bb bb bb bb bb bb bb bb bb bb bb 81.80 86.93 136.63 93.42 125.79 103.22 137.30 95.15 63.86 bb bb bb bb bb bb bb bb bb 110.44 bb 135.31 94.84 104.78 97.43 128.20 76.43 131.73 123.53 80.60 82.21 94.46 75.60 79.92 63.28 109.11 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb 94.84 bb 85.46 88.79 152.72 87.63 106.09 96.41 bb bb bb bb bb bb ng/mL %Rec Mod Comment 2.69 2.11 3.23 3.49 2.29 4.44 2.98 3.38 2.80 2.96 2.94 2.68 90 70 108 116 76 148 99 113 93 99 98 89 2.66 2.82 4.44 3.03 4.08 3.35 4.46 3.09 2.07 89 94 148 101 136 112 149 103 69 3.59 120 4.39 3.08 3.40 3.16 4.16 2.48 4.28 4.01 2.62 2.67 3.07 2.45 2.59 2.05 3.54 146 103 113 105 139 83 143 134 87 89 102 82 86 68 118 3.08 103 2.77 2.86 4.96 2.85 3.44 3.13 92 96 165 95 115 104 St/Hd y o G m p j 0 `0 Ve0 2 lO /1 8 /lO In te rim R e p o rt 0 5 Page 13 Page 724 o f 962 Quantify Compound Summary Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:33:39 2010 Compound 7: 13C8 PFOS (IS) Response Factor: 30.7999 RRF SD: 6.24032, % Relative Response type: External Std, Curve type: RF Sample List: SD: 20.2609 Area dl00904a Method File: dl00904a Name dl00904a058 dl00904a059 dl00904a060 dl00904a061 dl00904a062 dl00904a063 dl00904a064 dl00904a065 dl00904a066 dl00904a067 dl00904a068 dl00904a069 dl00904a070 dl00904a071 dl00904a072 dl00904a073 dl00904a074 dl00904a075 dl00904a076 dl00904a077 dl00904a078 dl00904a079 dl00904a080 dl00904a081 dl00904a082 dl00904a083 dl00904a084 dl00904a085 dl00904a086 dl00904a087 dl00904a088 dl00904a089 dl00904a090 dl00904a091 dl00904a092 dl00904a093 dl00904a094 dl00904a095 dl00904a096 dl00904a097 dl00904a098 dl00904a099 dl00904al00 dl00904al01 dl00904al02 dl00904a!03 dl00904al04 dl00904al05 dl00904a!06 dl00904al07 dl00904al08 dl00904al09 d l 0 0 9 0 4 a l 10 dl00904alll d l 0 0 9 0 4 a l 12 dl00904all3 dl00904all4 Samplelist ID GLP10-01-01-05-024 DAL SD SD10 0 0005 GLP10-01-01-05-025 DAL SD SD11 0 0000 GLP10-01-01-05-026 DAL SD SD11 0 0005 GLP10-01-01-05-027 DAL SD SD12 0 0000 GLP10-01-01-05-028 DAL SD SD12 DB 0000 GLP10-01- 01-05 -029 DAL SD SD12 0 0005 GLP10-01-01-05-030 DAL SD SD13 0 0000 GLP10-01-01-05-031 DAL SD SD13 0 0005 GLP10-01-01-05-032 DAL SD SD14 0 0000 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-033 DAL SD SD14 0 0005 GLP10-01-01-05-034 DAL SD SD15 0 0000 GLP10-01-01-05-035 DAL SD SD15 0 0005 GLP10-01-01-05-036 DAL SD SD16 0 0000 GLP10-01-01-05-037 DAL SD SD16 DB 0000 GLP10-01-01-05-038 DAL SD SD16 0 0005 GLP10-01-01-05-039 DAL SD SD17 0 0000 GLP10-01-01-05-04 0 DAL SD SD17 0 0005 GLP10-01-01-05-041 DAL SS SS01 0 0000 GLP10-01-01-05-042 DAL SS SS01 0 0005 GLP10-01-01-05-043 DAL SS SS02 0 0000 GLP10-01-01-05-044 DAL SS SS02 0 0005 GLP10-01-01-05-045 DAL SS SS03 0 0000 GLP10-01-01-05-046 DAL SS SS03 0 0005 GLP10-01-01-05-047 DAL SS SS03 DB 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05-048 DAL SS SS04 0 0000 GLP10-01-01-05-049 DAL SS SS04 0 0005 GLP10-01-01-05-050 DAL SS TRIP1 0 0000 GLP10-01-01-05-051 DAL SS SS05 0 0000 GLP10-01-01-05-052 DAL SS SS05 0 0005 GLP10-01- 01-05 -054 DAL SS SS06 0 0000 GLP10-01-01-05-055 DAL SS SS06 0 0005 GLP10-01- 01-05-056 DAL SS SS06 DB 0005 GLP10-01- 01-05 -057 DAL SS SS07 0 0000 GLP10-01-01-05-058 DAL SS SS07 0 0005 GLP10-01-01-05-059 DAL SS SS08 0 0000 GLP10-01-01-05-060 DAL SS SS08 DB 0000 GLP10-01-01-05-061 DAL SS SS08 0 0005 GLP10-01- 01-05-062 DAL SS SS09 0 0000 GLP10-01- 01-05-063 DAL SS SS09 0 0005 09004-182 80:20 ACN:H20 EC-100831-06 5 ng Extracted Curve Point 09004-182 80:20 ACN:H20 GLP10-01-01-05 -064 DAL SS GP01 0 0000 GLP10-01-01-05-065 DAL SS GP01 0 0005 GLP10-01-01-05-066 DAL SS GP01 0 0020 GLP10-01-01-05-067 DAL SS GP01 0 0060 GLP10-01-01-05-068 DAL SS GP02 0 0000 GLP10-01- 01- 05-069 DAL SS GP02 0 0005 09004-182 80:20 ACN:H20 EC-100831-07 10 ng Extracted Curve Point 09004-182 80:20 ACN:H20 Type QC QC QC QC STD Cone.(ng/mL) RT 10 -424 10.383 10.293 10.384 10.387 10.379 10.472 10.467 10.423 3.0000 10.424 10.294 10.421 10.378 10.382 10.424 10.382 10.249 10.244 10.300 10.427 10.291 10.466 10.376 10.424 10.294 3.0000 10.467 10.467 10.469 10.421 10.462 10.381 10.378 10.385 10.375 10.344 10.465 10.467 10.422 10.340 10.382 10.468 3.0000 10.464 10.426 10.381 10.378 10.465 10.376 10.375 3.0000 10.471 Area Flags 63.36 bb 108.28 MM 84.46 MM 98.64 bb 121.18 bb 78.37 bb 66.03 bb 45.20 bb 115.76 bb 114.18 bb 94.66 101.63 80.22 100.36 89.45 85.07 131.61 115.10 128.91 99.37 78.58 121.91 76.99 97.22 83.03 bb MM bb bb bb bb bb bb bb bb bb bb bb bb bb 123.29 bb 74.44 104.87 108.27 96.30 85.37 92.87 104.17 87.75 78.94 107.16 75.58 99.20 98.56 110.32 108.49 bb bb bb bb bb bb bb bb bb bb MM bb bb bb bb 120.54 bb 88.28 61.53 59.96 88.25 89.54 92.21 bb bb bb bb bb bb 112.96 bb ng/mL %Rec Mod Comment 2.06 69 3.52 117 a 2.74 91 a 3.20 107 3.93 131 2.54 85 2.14 71 1.47 49 3.76 125 3.71 124 3.07 3.30 2.60 3.26 2.90 2.76 4.27 3.74 4.19 3.23 2.55 3.96 2.50 3.16 2.70 102 110 87 109 97 92 142 125 140 108 85 132 83 105 90 a 4.00 133 2.42 3.41 3.52 3.13 2.77 3.02 3.38 2.85 2.56 3.48 2.45 3.22 3.20 3.58 3.52 81 114 117 104 92 101 113 95 85 116 82 107 107 119 117 b 3.91 130 2.87 2.00 1.95 2.87 2.91 2.99 96 67 65 96 97 100 3.67 122 Page 14 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D:\masslynx\davey2010.PRO\CurveDB\dl00904a Last modified: Mon Oct 18 17:27:31 2010 Printed: Tue Oct 19 16:34:07 2010 Compound 1 name: PFBS Method File: d100904a Coefficient of Determination: 0.999494 Calibration curve: -0.0237965 * xA2 + 82.5526 * x + 20.3908 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None 3.54e4n Response- Page 1 i 0-K 0 .0 50.0 1 0 0 .0 q u a n tit 3 ^ In te rim R e p o rt 0 5 e0 2 l O / 1 8 / l O mnh 150.0 2 0 0 .0 250.0 300.0 350.0 400.0 450.0 Cone 500.0 Page 726 o f 962 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D:\oasslynx\davey2010.PRO\CurveDB\dl00904a Last modified: Mon Oct 18 17:27:31 2010 Printed: Tue Oct 19 16:34:07 2010 Compound 2 name: PFHS Method File: d100904a Coefficient of Determination: 0.999048 Calibration curve: -0.0149532 * xA2 + 67.1258 * x + 24.1617 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ! 2.98e4-i I I I Response- quantit ' V v -' 10/18/10 mmh % Page 2 Page 727 o f 962 f .-li u Quantify Calibration Report GLP10-01-02-05 screening data Calibration! Di\masslynx\davey2010.PRO\CurveDB\dl00904a Last modified! Mon Oct 18 17 i27!31 2010 Printed! Tue Oct 19 16t34t07 2010 Compound 3 name: PFOS Method File: d 100904a Coefficient of Determination: 0.999052 Calibration curve: -0.000561508 * xA2 + 51.2225 * x + 23.3229 Response type: External Std, Area Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Page 3 quantit' 0 r P iit In te rim R e p o rt 0 5 1 10/18/10 mmh Page 728 o f 962 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D:\masslynx\davey2010.PRO\CurveDB\dl00904a Last modified: Mon Oct 18 17:27:31 2010 Printed: Tue Oct 19 16:34:07 2010 Page 4 3 M S tu d y G L P 1 0 -0 1 -0 2 ^ " t i t U l g n t t 7 R b0p 8 ,r f 0 5 l n t e d 1 0 / 1 8 / 1 0 " mh - Page 729 o f 962 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D:\masslynx\davey2010.PRO\CurveDB\dl00904a Last modified: Mon Oct 18 17:27:31 2010 printed: Tue Oct 19 1:34:07 2010 Compound 5 name: 1802 PFHS (IS) Method File: d100904a Response Factor: 39.6869 RRF SD: 7.91154, % Relative SD: 19.9349 Response type: External Std, Area Curve type: RF 167-1 quantit 10/18/10 mmh Page 5 x X XX\ ' Page 730 o f 962 Quantify Calibration Report GLP10-01-02-05 screening data Calibration: D:\masslynx\davey2010.PRO\CurveDB\dl00904a Last modified: Mon Oct 18 17:27:31 2010 Printed: Tue Oct 19 16:34:07 2010 Page 6 Quantify Calibration Report GLP10-01-02-05 screening data Calibrations D:\masslynx\davey2010.PRO\CurveDB\dl00904a Last modifieds Mon Oct 18 17:27 s31 2010 Printed: Tue Oct 19 16:34:07 2010 Compound 7 name: 13C8 PFOS (IS) Method File: d100904a Response Factor: 30.7999 RRF SD: 6.24032, % Relative SD: 20.2609 Response type: External Std, Area Curve type: RF 137n 3 M S tu d y G L P 1 0 -0 1 -0 2 . q u a n tita |n e p jm 7 R e p o r t 0 5 * nte<* nnnh Page 7 X X X X Page 732 o f 962 PFBS Internal Ref: 1802 PFBS (IS) Quantity Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 8.631, Enabled RT Reference: [None] Peak Selection: Largest General Parameters Propagated Response Based On: Areas, Primary Polynomial Type: Quadratic Fit Weighting: 1/X Units: Integration parameters Propagated ApexTrack Integ: Disabled Peak-to-peak Amp: 98, Enabled Smoothing Enabled Wnd Size (scans): 2 Smoothing Method: Mean Peak Detection Standard Join Valley Thresh: 25.00 Raise B .line Max: 1.00 Detect Shoulders: Disabled Response Threshold Relative Height: 50.00, Disabled Relative Area: 3.00, Disabled PFHS Internal Ref: 1802 PFHS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 9.555, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated PFOS Internal Ref: 13C8 PFOS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 10.260, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated 1802 PFBS (IS) Internal Ref: [None] Quantify Trace: TIC Cone, of Stds: Fixed User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 8.574, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated 1802 PFHS (IS) Internal Ref: [None] Quantify Trace: TIC Cone, of Stds: Fixed User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 9.550, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated MPFOS (Surr) Incernal Ref: 13C8 PFOS (IS) Quantify Trace: TIC Cone, of Stds: Cone. A User Peak Factor: 1 .0 0 00 00 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8 .0 Peak Location Ret. Time (mins): 10.351, Enabled RT Reference: [None] Peak Selection: Largest Integration Parameters Propagated Acq. Func. Number: 1 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.414 Response Type: Point of Origin: Axis Transform: External Exclude None Auto Noise Measure: Disabled Num. of Smooths: 1 Reduce Peak Tail: Draw Vert. Thresh: Shoulder Thresh: Absolute Height: Absolute Area: 60.00 5.00 5.00 0.00, Disabled 10.00, Enabled Acq. Func. Number: 2 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.501 General Parameters Propagated Acq. Func. Number: 3 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.501 General Parameters Propagated Acq. Func. Number: 6 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.283 General Parameters Propagated Acq. Func. Number: 5 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.348 General Parameters Propagated Acq. Fue. Number: 4 User RF Valu: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.282 General Parameters Propagated 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o rt 0 5 J Page 733 o f 962 Quantify Method Report Method File: D:\masslynx\davey2010.PRO\MethDB\dl00904a.mdb Last Modified: Tue Sep 07 13:49:46 2010D Printed: Wed Oct 20 09:13:42 2010 13C8 PFOS (IS) Internal Ref: (None] Quantify Trace: TIC Cone, of Stds: Fixed User Peak Factor: 1.000000 Chrom. Mass Wnd: 1.0000 Da Chrom. Noise Wnd: 0.00 to 0.00 mins S/N Quantify Flag: 8.0 Peak Location Ret. Time (mins): 10.319, Enabled . RT Reference: [None) Peak Selection: Largest Integration Parameters Propagated Acq. Fune. Number: 7 User RF Value: Integ. Wnd. Fac: Chrom. Noise Fac: S/N Detection Flag: 1.000000, Disabled 2.000 3.0 3.0 Relative Ret. Time: 0.000, Disabled Time Window (mins): 0.250 General Parameters Propagated Page 2 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o rt 0 5 Page 734 o f 962 Quantify Sample Report GLP10-01-02-05 screening data S am ple L is t D \ m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \dl0 0 90 4a L a s t m o d ifie d T ue Sep 07 0 9 :2 8 :2 2 2010 M ethod D\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M eth D B \d l0 0 90 4a L a s t m o d ifie d T ue Sep 07 1 3 :4 9 :4 6 2010 Job Code: P rin te d : T u e O c t 19 1 6 :3 4 :1 9 2010 Harne d l0 0 9 0 4 a 0 0 1 T e x t: 1 : PPBS 2 : PFHS Page 1 , 3 M .S tu d y G L P 1 0 q u a n t i t a t e d . 9 / ^ 0 0~f' t ^ 5 0l 1n - 0^. 2 ,1 0 / 1 8 / 1 0 mmh In te rim Page 735 o f 962 Quantify Sample Report GLP10-01*02*05 screening data Sample Listi D \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a001 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) q u a n tit 3 ^ <G J J d 1 0 f i t 'i S 2 l O / l 8 / l O In te rim R e p o rt 0 5 .\ Page 2 Page 736 o f 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a002 Text: Page 3 09004-182 80:20 ACN:H20 3M d100904a002 100 10.37 4: 1802 PFBS (IS) Davey070799 09004-182 80:20 ACN:H20 04-Sep-2010 21:47:07 3M 3: MRM of 2 Channels ES- d100904a002 TIC 586 Area % 85 5.00 1 0 .0 0 3 M S tu d y G L P 1 0 -0 1 -0 2 ated 9/7/10 and-printed 10/18/10 mmh < In te rim R e p 0 rT 0 o :i> iiik iA1-..-tigftWqj w asss& ai 15.00 Time Davey070799 04-Sep-2010 21:47:07 6 : MRM of 1 Channel ES- B t i '-.a*. ja 9 / \ Page 737 o 9 W if Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a002 Text: 7: 13C8 PFOS (IS) 109004-182 80:20 ACN:H20 |3M Davey070799 04-Sep-2010 21:47:07 3 M S tu d y G L P 1 0 -0 1 -0 2 q u " t i t 1 t t i r i M 7 R y >p f 10 5 i n t :e<1 1 0 / 1 8 / 1 0 Page 4 Page 738 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\mas8lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a003 Text: 1: PFBS 2 : PFHS 3: PFOS . 4: 1802 PFBS (IS) Page S quantita3 M S t 4 d y oG L p 1 8 r fii1 iQ 2 10/18/10 In te rim R e p o rt 0 5 W ife \ ' ' Page 739 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi 0:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09<28:22 2010 Method! D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34il9 2010 Name: dl00904a003 Text: 7: 13C8 PFOS (IS) EC-100831-01 0.2 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 22:05:13 d100904a003 100- 10.34 83 7: MRM of 1 Channel ESTIC 638 Area % 39 | ! I i I | I -- 5.00 1 0 .0 0 . 3M titatea S tu d y G L P 1 0 -D 1 -Q 2 ?/t 2Ao andinrintea 10/18/10 mmh In te rim R e p o rt 0 5 15.00 Time Page 6 PMge 7 40 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D *\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified* Tue Sep 07 09*28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a004 Text: Page 7 4; 1802 PFBS (IS) EC-100831-02 0.5 ng Extracted Curve Point Davey070799 EC-100831-02 0.5 ng Extracted Curve Point Davey070799 I3M 04-Sep-2010 22:23:20 3M 04-Sep-2010 22:23:20 ;d100904a004 3: MRM of 2 Channels ES- d100904a004 TIC 100- 670 8.77 151 ,! 6: MRM of 1 Channel ESTIC 961 Area Area % quanti In te rim R e p o rt 0 5 10/18/10 mnh Time 27 5.00 1 0 .0 0 -A - 15.00 Time Page 741 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D i \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a004 Text: 5: 1802 PFHS (IS) 6; MPFOS (Surr) Page 8 7: 13C8 PFOS (IS) EC-100831-02 0.5 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 22:23:20 d100904a004 7: MRM of 1 Channel ES- 5X) ~ mOO quantit In te rim . R e p o rt 0 5 mrnh 15^00 - ifltt " ^ Page 742 o f 962 Quantify Sample Report GLP10-01-02*05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethOB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a005 Text: Page 9 4: 1802 PFBS (IS) EC-100831-03 0.75 ng Extracted Curve Point Davey070799l EC-100831-03 0.75 ng Extracted Curve Point Davey070799! 3M 04-Sep-2010 22:41:25i !3M 04-Sep-2010 22:41:25 d100904a005 100 10.32 87 ] 3: MRM of 2 Channels ES- ;d100904a005 TIC; 100- 8421 Area: 6; MRM of 1 Channel ES- : 8.55 T IC 176 1.04e3i Area %% 53 r' A 5.00 q u a n t i t a t e d !> 7 7 2 O G m p J 0 r 0 i1 e0 2 l O / 1 8 / l O In te rim ' R e p o rt 0 5 1 0 .0 0 v / x y - ' v m / \ JO ! 15.00 Time I 22 5.00 1 0 .0 0 ^ Time ' 15.00 Page 743 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a005 Text: 5 : 1 8 0 2 PFHS ( I S ) Page 10 6 : MPFOS ( S u r r ) EC-100831-03 0.75 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 22:41:25 d100904a005 100 10.33 26 4: MRM of 1 Channel ESTIC 394 Area it % 60 7 : 13C8 PFOS ( I S ) EC-100831-03 0.75 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 22:41:25 d100904a005 100- 10.34 99 i 7: MRM of 1 Channel ESTIC 692 Area % a A A -, ' 5.00 1 0 .0 0 15.00 Time ^ W^ v r \ ^ A A v y v. ^ / S 33 Time 5.00 10.00 15.00 3 M S tu d y G L P 1 0 -0 1 -0 2 , , q u a n tit^ n te rim K e p o T t -*-0 / 1 8 / 1 0 mmh fa ? /* */!>> = -1 Page 744 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifieds Tue Sep 07 09:28s22 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00904a Last modifieds Tue Sep 07 13:49s46 2010 Job Code s Printeds Tue Oct 19 16:34:19 2010 Names dl00904a006 Texts quantit^M i S U d y G L f 1 @ r S ^ t- 2 10/18/10 mnh In te rim R e p o rt 0 5 ,' Page 11 EC-100831-04 1 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 22:59:33 d100904a006 100- 2: MRM of 2 Channels ES9.57 n e 1.13e3 Area % 'j U 64 5.00 1 0 .0 0 15.00 Time ! 4: 1802 PFBS (IS) EC-100831-04 1 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 22:59:33 d100904a006 100- 6: MRM of 1 Channel ES- 8.72 143 t ic ; 1.04e3; Area % 35 Time 5.00 1 0 .0 0 15.00 Page 745 o f 962 , v , t ; l. .. . 1 . Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \m a s s l y n x \ d a v e y 2 0 1 0 . PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job C o d e : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a006 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) EC-100831-04 1 ng E xtracted C urve P o in t Davey070799 3M 04-Sep-2010 22:59:33 d100904a006 7: MRM of 1 Channel ES- Page 12 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a007 Text: Page 13 EC-100831-05 2.5 ng Extracted Curve Point Davey070799 EC-100831-05 2.5 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:17:36 3M 04-Sep-2010 23:17:36 d100904a007 100 8.64 188 I 1: MRM of 2 Channels ES- d 100904a007 TIC 1.60e3 1 0 0 - 2: MRM of 2 Channels ES9.56 TIC 177 1.57e3 Area Area %% 5.00 1 0 .0 0 15loo Time 46 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) EC-100831-05 2.5 ng Extracted Curve Point Davey070799 EC-100831-05 2.5 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:17:36 3M 04-Sep-2010 23:17:36 d100904a007 100 10.40 130 3: MRM of 2 Channels ES d100904a007 TIC 100 1.39e3 8.63 182 !| 6: MRM of 1 Channel ESTIC 1,20e3 Area | Area % 52 , ^ V 5.00 1 0 .0 0 A rS 15!00 Time- 30 Is- 5.00 1 0 .0 0 15.00 Time % "P a g e 7 4 7 o f 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a007 Text: 7: 13C8 PFOS (IS) Page 14 6: MPFOS ( S u r r ) _____ ______ _________________________________________________________ ______________ EC-100831-05 2.5 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:17:36 d100904a007 100~i 10.40 71 I 4: MRM of 1 Channel ESTIC A7r1e6a % i/ ^ v V - V 51 5.00 1 0 .0 0 U n , - / Time 15.00 quantit In te rim R e p o rt 0 5 i ' 10/18/10 mmh P age'748 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a008 Text: 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 15 EC-100831-06 5 ng 3M d100904a008 100 Extracted Curve Point Davey070799 04-Sep-2010 23:35:41 2: MRM of 2 Channels ES9.44 TIC 333 1 .9 9 e 3 Area 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) EC-100831-06 5 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:35:41 d100904a008 100 6: MRM of 1 Channel ES8.50 n e 149 944 Area % 5.00 1 0 .0 0 15.00 Time Page 7 4 9 o f 962a Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D :\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a008 Text: 7: 13C8 PFOS (IS) EC-100831-06 5 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:35:41 d100904a008 7: MRM of 1 Channel ES- quantitM In te rim R e p o rt 0 5 10/18/10 mmh H M fl Page 16 Page 750 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 17 Name: dl00904a009 Text: EC-100831-07 10 ng 3M d100904a009 100- 2 : PFHS _____ ________________ ___ __________________________________________ ______________ Extracted Curve Point Davey070799 EC-100831-07 10 ng Extracted Curve Point Davey070799 04-Sep-2010 23:53:43 3M 04-Sep-2010 23:53:43 8.65 840 : 1: MRM of 2 Channels ESTIC 4.56e3 Area d100904a009 1 00~I 2: MRM of 2 Channels ES9.53 TIC 708 4.02e3 Area %% 16 3: PFOS 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time li.-i.' qua n t i t ^M i In te rim R e p p ft 0 5 10/18/10 nmh Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 18 Name: dl00904a009 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) EC-100831-07 10 ng Extracted Curve Point Davey070799 EC-100831-07 10 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:53:43 3M 04-Sep-2010 23:53:43 d100904a009 100- 5: MRM of 1 Channel ES- d100904a009 9.55 108 TIC 100880 10.42 180 4: MRM of 1 Channel ESTIC 1.22e3 Area Area %% 40 Time 5.00 1 0 .0 0 15.00 7: 13C8 PFOS (IS) EC-100831-07 10 ng Extracted Curve Point Davey070799 3M 04-Sep-2010 23:53:43 d100904a009 7: MRM of 1 Channel ESTIC 778 Area 5.00 1 0 .0 0 i--- -- -- Time 15.00 . g u a n tit ',,G L P 1 0 -0 1 -0 2 .p ^^o |x Q ^ra-nteoT 10/18/10 mmh Time Page 752 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a010 Text: Page 19 EC-100831-08 25 ng Extracted Curve Point Davey070799 EC-100831-08 25 ng Extracted Curve Point Davey070799i 3M 05-Sep-2010 00:11:52 3M 05-Sep-2010 00:11:52 d100904a010 100 8.61 22551 1: MRM of 2 Channels ES- d100904a010 TIC 1.08e4 1 0 0 199.5530"1 2: MRM of 2 Channels ESTIC 9.38e3 Area Area %- 5.00 1 0 .0 0 15.00 Time 5.00 1 1 i 1 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28>22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a010 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS)______________________________ ____________ ___ _______________________________________ EC-100831-08 25 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 00:11:52 d100904a010 1 0 0 -1 10.43 104 I 7: MRM of 1 Channel ESTIC 751 Area % I! j; v \A -. 32 Time 5.00 1 0 .0 0 15.00 Page 20 Page 754 o f 962 Quantify Sample Report GLP10-Q1-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a011 Text: Page 21 EC-100831-09 50 ng E xtracted C urve P oint Davey070799 EC-100831-09 50 ng E xtracted C urve P o in t Davey070799 3M 05-Sep-2010 00:30:01 3M 05-Sep-2010 00:30:01 d100904a011 100- 8.65 4426" 1: MRM of 2 Channels ES- d100904a011 TIC 100n 2.05e4 Area 9.61 3492 ! li ;I 2: MRM of 2 Channels ESTIC 1.65e4 Area %- %. 5.00 l 1 0 .0 0 _ Time 15.00 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) EC-100831-09 50 ng E xtracted C urve P oint Davey070799 EC-100831-09 50 ng E xtracted C urve P o in t Davey070799 3M 05-Sep-2010 00:30:01 3M 05-Sep-2010 00:30:01 d100904a011 100- 3: MRM of 2 Channels ES- d100904a011 10.45 2851 ! TIC 100- 1.33e4 6: MRM of 1 Channel ES- 8.68 TIC 190 1.24e3 Area Area %_ % 5.00 1 0 .0 0 15.00 Time - 29 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a011 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) EC-100831-09 50 ng Extracted Curve Point Davey070799l 3M 05-Sep-2010 00:30:01 d100904a011 100- 10.42 86 7: MRM of 1 Channel E S - 1 TIC! 770 ! Area i I % -46- Time 5.00 1 0 .0 0 15.00 Page 22 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:26:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a012 Text: Page 23 EC-100831-10 100 ng Extracted Curve Point Davey070799 EC-100831-10 100 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 00:48:08 3M 05-Sep-2010 00:48:08 d100904a012 1: MRM of 2 Channels ES- d100904a012 TIC 100- 3.40e4 9.57 58471 2: MRM of 2 Channels ES TIC 2.72e4 Area Area %- Time 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 R e p O ff 0 5 in te d 1 0 /1 8 /1 0 mnh ` n Page 757 o f 962 Quantify Sample Report GLP10-01-02-0S screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 0 9 i28s22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 1 6 s34s19 2010 Page 24 Names dl00904a012 Texts 5: 1802 PFHS (IS) 6: MPFOS (Surr) EC-100831-10 100 ng Extracted Curve Point Davey070799 EC-100831-10 100 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 00:48:08 3M 05-Sep-2010 00:48:08 d100904a012 100- 5: MRM of 1 Channel ES- d100904a012 9.59 167 TIC 100- 1.11 e3 10.45 2964 ; 4: MRM of 1 Channel ESTIC 1.37e4 Area Area % %- 32 Time 5.00 1 0 .0 0 15.00 7: 13C8 PFOS (IS) EC-100831-10 100 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 00:48:08 d100904a012 100- 10.46 91 7: MRM of 1 Channel ESTIC 776 Area % 5.00 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 q u a n tita jn tirm R lp o t 0 5 in te d j\r~< 1 0 .0 0 15.00 Time a . a a a & s a u iu s s cuannjita r.ed.: 1 i 'V 1 0 .0 0 ^ -r 15.00 Time P a g e 7 5 8 o f 9 6 2 ^ \ ta ce d - 1 i.1 . "a Quantify Sample Report GLP10-01-02-05 screening data Sample List; D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified; Tue Sep 07 0928;22 2010 Method; D;\masslynx\davey2010.PRO\MethDB\dl00904a Last modified; Tue Sep 07 13:49:46 2010 Job Code; Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a013 Text: Page 25 4: 1802 PFBS (IS) EC-100831-11 200 ng Extracted Curve Point Davey070799 EC-100831-11 200 3M 05-Sep-2010 01:06:16 3M d100904a013 100 10.41 10197; 3: MRM of 2 Channels ES- d100904a013 TIC 100- 4.54e4 Area ng Extracted 8 64 158 %- % Curve PointDavey070799 05-Sep-2010 01:06:16 6: MRM of 1 Channel ESJIG 987 Area 5.00 1 0 .0 0 15.00 Time 5.00 1 0 .0 0 15.00 Time P age 7 5 9 o f9 6 2 ' Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a013 Text: 5: 1802 PFHS (IS) Page 26 6; MPFOS (Surr) EC-100831-11 200 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 01:06:16 d100904a013 100- 10.37 5046 1 4: MRM of 1 Channel ESTIC 2.27e4 1 Area %- 7: 13C8 PFOS (IS) EC-100831-11 200 ng Extracted Curve Point Davey070799i 3M 05-Sep-2010 01:06:16; d100904a013 100- 10.38 91 1 7: MRM of 1 Channel ES- j T IC 1 640; Area; % 37 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 - q u a n t i t ^ d r m R e 0 o f Q 5 in t:e d in /ift/in im m h . 1 0 .0 0 J W V y^^lY Time 15.00 5.00 ti_wat.ec. i , 7/ . 1 0 .0 0 15.00 Time ira te a 5 /7 /2 . Page 760 o f 9 6 7 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Last modified: Method: Last modified: Job Code: D : \massl y n x \ d a v e y 2 0 1 0 . PR O \ S a mpleDB\dl00904a Tue Sep 07 09:28:22 2010 D:\masslynx\davey2010.PRO\MethDB\dl00904a Tue Sep 07 13:49:46 2010 Printed: Tue Oct 19 16:34:19 2010 Page 27 Name: dl00904a014 Text: 1: PFBS 2 : PFHS EC-100831-12 500 ng Extracted Curve Point Davey070799 EC-100831-12 500 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 01:24:24 3M 05-Sep-2010 01:24:24 d100904a014 100 8.69 35427" 1: MRM of 2 Channels ESTIC 1.60e5 Area d100904a014 100- 957 298*131 2: MRM of 2 Channels ESne 1.33e5 Area % %- 1 _________________ Time 5.00 1 0 .0 0 15.00 4: 1802 PFBS {IS} EC-100831-12 500 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 01:24:24 d100904a014 100 10.45 255951 3: MRM of 2 Channels ES TIC 1.14e5 Area % 5.00 1 0 .0 0 15.00 Time 5.00 I 1 0 .0 0 q u a n tita 3 M OG Jsp t 0 r P n ti0 2 lO /18/10 mmh In te rim R e p o rt 0 5 ; 15.00 Time P age 761 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 28 Name: dl00904a014 Text: 5: 1802 PFHS (IS) 6 : MPFOS (Surr) EC-100831-12 500 ng E xtracte d C urve P o in t Davey070799 EC-100831-12 500 ng E xtracted Curve P oint Davey070799 3M 05-Sep-2010 01:24:24 3M 05-Sep-2010 01:24:24 d100904a014 100 5: MRM of 1 Channel ES- d100904a014 9.59 109 TIC 100- 876 10.45 14363 4: MRM of 1 Channel EST ic 6.45e4 Area Area %- %- 5.00 1 0 .0 0 15.00 Time 7: 13C8 PFOS (IS) EC-100831-12 500 ng E xtracte d C urve P o in t Davey070799 3M 05-Sep-2010 01:24:24 d100904a014 100 10.47 83 7: MRM of 1 Channel ES TIC 726 Area % V \i -49 Time 5.00 1 0 .0 0 15.00 isquantit e c i ^ y y .P a 1 0 - 0 ! - 0 2 10/18/10 mmh In te rim R e p o rt 0 5 ' . j mt.n. 5.00 1 0 .0 0 15.00 Time i . ; / t i b / i C i nur-h I r a g e 762 o f 9 6 2 & Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09>28>22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a015 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 29 quantita3t M W In te rim R e p o rt 0 5 V ' t at 10/18/10 mmh P ge'7 6 3 o f 962 Quantify Sample Report GLP10-01-02-05 screening data sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\ma88lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a015 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 30 Quantify Sample Report 6LP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a016 Text: 1 : PFBS 2 : PFHS 3= PFOS 4: 1802 PFBS (IS) Page 31 ' Page 765 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job C o d e : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a016 Text: 5: 1802 PFHS (IS) Page 32 6; MPFOS (Surr) 09004-182 80:20 ACN:H20 3M d100904a016 100- 8.15 % Davey070799 05-Sep-2010 02:00:40 4: MRM of 1 Channel ESTIC 280 13.94 16.29 16.68 82 Time 5.00 1 0 .0 0 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a017 Text: 1: PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) Page 33 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:4 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a017 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o rt 0 5 quantitated 9/7/10 and printed 10/18/10 mmh j. V J ' / aai p < ,r l. Page 34 Page 768 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a018 Text: 1: PFBS 2: PFHS 3; PFOS 4: 1802 PFBS (IS) cfuantit 10/18/10 """>y Y *\ Page 35 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dlQ0904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a018 Text: 7: 13C8 PFOS (IS) Page 36 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a019 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 37 Qu&ntify Sample Report GLP10-01-02-05 screening data Sandle List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28i22 2010 Metbodt D i \ m a s s l y n x \ d a v e y 2 0 l 0 .P R O \ M e t h D B \ d l 0 0 9 0 4 a Last modifiedi Tue Sep 07 13i49i46 2010 Job Codei Printedi Tue Oct 19 1i34i19 2010 Name> dl00904a019 Textt 6: MPFOS {Surr) 7: 13C8 PFOS {IS) Page 38 P age 7 j2 } p ) 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a020 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 39 -i) q u a n t i t i S ^ l ^ i ^ r t y P k l P r P d t P l O / l i / l O L i m n h r . e In te rim R e p o rt 0 5 si a V quancicaced .1 - i t e d $ 1$ / X 8 /,j-(J Vi: .anticated Page 773 o f 9 6 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a020 Text: 7: 13C8 PFOS (IS) Page 40 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 41 Name: dl00904a021 Text: 1: PFBS_________ MB-100831 -03 Method Blank 3 w/o IS 3M d100904a021 2 ! PFHS Davey070799 MB-100831-03 Method Blank 3 w/o IS 05-Sep-2010 03:31:17 3M 1: MRM of 2 Channels ES- d100904a021 Davey070799 05-Sep-2010 03:31:17 2: MRM of 2 Channels ES- 3: PFOS 4: 1802 PFBS (IS) / LQ ,'ii -v \ \ \ . H! : P a g e ffj^ o f 9 62 " Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a021 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) Page 42 Quantify Sample Report GLP10-01-02-5 screening data Sample List D* \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a022 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) q u a n tita tif ( P b & ' P f & i t f ^ l O / i a / l O mnih In te rim R e p o rt 0 5 Page 43 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a022 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 44 P ag e 7 7 8 9 6 2 tita t= Quantify Sample Report GLP10-01-02-05 screening data Sample List Oi\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09'28!22 2010 Method! D t \masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed! Tue Oct 19 1 6 i34:19 2010 Name: d!00904a023 Text: 4: 1802 PFBS (IS) Page 45 quantity OG L p j 0r 0 Ve0 2 lO / 1 8 / 1 0 In te rim R e p o rt 0 5 v A *'. " *1 k P ag e 7 7 9 o f 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D: \masslyzuc\davey2010 .PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a023 Text: 7: 13C8 PFOS (IS) Page 46 auar.treated Page 780 o f 962 Quantify Sample Report GLP10-01-02-05 screening data S am ple L is t s D * \m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d ifie d Tue Sep 07 0 9 s 2 6 s 22 2010 M ethods D s\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M eth D B \d l0 0 90 4a L a s t m o d ifie d : Tue Sep 07 1 3 :4 9 :4 6 2010 Job Codes P rin te d : Tue O c t 19 1 6 :3 4 :1 9 2010 Marne: d l0 0 9 0 4 a 0 2 4 T e x t: 1* PFBS ... . 2: PFHS 3s PFOS 4s 1802 PFBS (IS) Page 47 q u a n t i t ^ M i ^ i ^ ^ ^ . . P L ^ 0 - 0 1 0 2 1 0 / 1 8 / 1 0 mmh In t e r im R e p o r t 0 5 . y ^ . . if . P ag e ^.7 83 } o f 9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifieds Tue Sep 07 09 : 2 8 t22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modifieds Tue Sep 07 13:49:46 2010 Job Codes Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a024 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 48 Quantify Sample Report GLP10-01-02-05 screening data ' Sample List: D :\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 49 Name: dl00904a025 Text: 1: PFBS LCS-100831-01 3 ng LCS in TCR-842 3M d100904a025 1 0 (h 8.56 284 2: PFHS Davey070799 LCS-100831-01 3 ng LCS in TCR-842 05-Sep-2010 04:43:36 3M 1: MRM of 2 Channels ES- d100904a025 TIC 100n 1.88e3 9.49 235 Area Davey070799 05-Sep-2010 04:43:36 2: MRM of 2 Channels ESTIC 1.58e3 Area %% 3: PFOS 5.00 10.00 15.00 Time 37 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 r` \ i 3 ! Quantify Sample Report GLP1001-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last xnodifiedt Tue Sep 07 09:28:22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedt Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a025 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 50 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a026 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 51 mv Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 0 9 :28s22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a026 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 52 Quantify Sample Report GLP10-01>02~05 screening data Sample Listi Dt \xnasslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: ' Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a027 Text: 1 : PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) Page 53 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09 2 8 i22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: d!00904a027 Text: 5: 1802 PFHS (IS) 7s 13C8 PFOS (IS) Page 54 6: MPFOS (Surr) LCS-100831-03 3 ng LCS in TCR-842 3M d100904a027 1m0 0u --1i 1 20 33 7 Davey070799 05-Sep-2010 05:19:47 4: MRM of 1 Channel ESTIC 883 Area % 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D i \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: d!00904a028 Text: 1: PFBS 2: PFHS Page 55 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D* \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a028 Text: 5: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 56 6: MPFOS (Surr) LCS-100831 -04 30 ng LCS in TCR-842 Davey070799 3M 05-Sep-2010 05:37:54 d100904a028 100 10.49 136 ' 4: MRM of 1 Channel ESHC 933 Area % 32 Time 5.00 1 0 .0 0 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method: D:\mas8lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a029 Text: 1: PFBS 2: PFHS Page 57 1 I n t e r im R e p o rt 0 5 10 /IS /10 mmh . i /ltp_ ana :priiu J ti r 'Y '^ .V . /10_ ana -prior . .aii Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 13s49s46 2010 Job Code s Printed: Tue Oct 19 16:34:19 2010 Page 58 Names dl00904a029 Texts 5 ; 1802 PFHS (IS) LCS-100831-05 30 ng LCS in TCR-842 3M d100904a029 100 9.51 141 6; MPFOS (Surr) Davey070799 LCS-100831-05 30 ng LCS in TCR-842 05-Sep-2010 05:55:59 3M 5: MRM of 1 Channel ESTIC 975 Area d100904a029 100 Davey070799 05-Sep-2010 05:55:59 4: MRM of 1 Channel ESTIC 789 Area % 33 7: 13C8 PFOS (IS) 5.00 10.00 15.00 Time 5.00 1 0 .0 0 15.00 Time , quantit2 M l S i u d y iG L p d1 9 r 0 1 tQ (? 10/18/10 mu h l ^ , In te rim R e p o rt 0 5 Page 792 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Dt \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09 t28s22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a030 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 59 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\ma88lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a030 Text: 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 R e p o r t 10 5 i n t ? d | ^ 1 8 / 1 0 " mi1 te i- Page 60 P a g e 7 9 4 l0 f 9 6 2 * i l L V i , t , VA Quantify Sample Report GLP10-01-02-05 screening data Sample List* D* \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09*28*22 2010 Method* D*\masslynx\davey2010.PRO\MethDB\dl00904a Last modified* Tue Sep 07 13*49*46 2010 Job Code* Printed: Tue Oct 19 16*34*19 2010 Name: dl00904a031 Text* 1* PFBS 2: PFHS Page 61 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethOB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a031 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 62 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a032 Text: Page 63 EC-100831-06 5 ng E xtracted C urve P o int Davey070799 EC-100831-06 5 ng E xtracted C urve P o in t Davey070799 3M 05-Sep-2010 06:50:12 3M 05-Sep-2010 06:50:12 d100904a032 100 8 .5 6 512 1 : M R M o f 2 C h a n n e ls E S T IC 2 .6 6 e 3 A re a d100904a032 100 9 .4 0 458] 2 : M R M o f 2 C h a n n e ls E S HC 2 .4 5 e 3 A re a %% 3: PFOS 5 .0 0 1 0 .0 0 1 5 .0 0 T im e 16 4= 1802 PFBS (IS) 5 .0 0 10.00 1 5 .0 0 T im e i Ii / fc,'i'U : q d a n t it 3 M dSl u d y 4* In te rim R e c O rt 1 0 / 1 8 / 1 0 mmh . *_i jp/.l/X'O aniit* . ? - ... i, R a h e 7 9 7 o f 9 6 2 Quantify Sample Report GLP10>01>02>05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dlOO904a Last modified Tue Sep 07 092822 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 134946 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a032 Text: 7: 13C8 PFOS (IS) Page 4 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method : 0 :\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a033 Text: 1: PFBS 2: PFHS Page 65 . Quantify Sample Report GLP10-01*02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a033 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 66 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a034 Text: Page 67 G LP 10-01 -01 -05-001 D A L SD TRIP1 0 100624 D avey070799 3M 05-Sep-2010 07:26:26 d100904a034 2 : M R M o f 2 C h a n n e ls E S T IC 693 3: PFOS . 4: 1802 PFBS (IS) T im e Quantify Sample Report GLP10-01-02-05 screening data Sample Listt Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 :28s22 2010 Me thod t D t\mas slynx\davey2010.PR0\Me thDB\dl00904a Last modified! Tue Sep 07 13:49i46 2010 Job Codei Printed! Tue Oct 19 1 6 i3419 2010 Names dl00904a034 Text! 5: 1802 PFHS (IS) Page 68 6 : MPFOS (Surr) GLP10-01 -01 -05-001 DAL SD TRIP1 0 100624 Davey070799 3M 05-Sep-2010 07:26:26 d100904a034 4: MRM of 1 Channel ES- 7: 13C8 PFOS (IS) Quantify Sample Report GLP10-01-02-05 screening data Sample List: D\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:26:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a035 Text: 1: PFBS Page 69 2 : PFHS GLP10-01 -01 -05-002 DAL SD SD01 0 0000 Davey070799 3M 05-Sep-2010 07:44:34 d100904a035 2: MRM of 2 Channels ES- 3: PFOS 4: 1802 PFBS (IS) Quantify Sample Report GLP10-01-02-05 screening data Sandle Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifieds Tue Sep 07 09t28t22 2010 Methods Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modifieds Tue Sep 07 13t49s46 2010 Job Code s Printeds Tue Oct 19 16*34sl9 2010 Names dl00904a035 Texts 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7; 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o rt 0 5 quantitated 9/7/10'-and printed 10/18/10.m m l m k V ** V .l _ . .J - V Page 70 Page 804 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dlO0904a Last modifiedt Tue Sep 07 09 :28s22 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Namei dl00904a036 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 71 V f t . '1 In te rim R e p o rt 0 5 mmh -9/.7/ith ii.il r' Page 805 o f 962 C3d .9/7/10: and |; Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010. PRO\SampleDB\dl00904a Last modifieds Tue Sep 07 09s28t22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a036 Text: 5: 1802 PFHS (IS) 7; 13C8 PFOS (IS) GLP10-01 -01 -05-003 DAL SD SD01 0 0005 Davey070799 3M 05-Sep-2010 08:02:38 d100904a036 7: MRM of 1 Channel ES- Page 72 Page 806 o f 962 ) Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09>28:22 2010 Method Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 13i49i46 2010 Job Code: Printed: Tue Oct 19 16i34:19 2010 Mamet dl00904a037 Text I Is PFBS 2: PFHS Page 73 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D s \aasslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09s28i22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a037 Text: 5: 1802 PFHS (IS) 6; MPFOS (Surr) 7: 13C8 PFOS (IS) Page 74 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a038 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 75 P L & ^ i& J t Q ? 10/18/10 nmh In te rim R e p o rt 0 5 A- Page 809 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28i22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a038 Text: 7: 13C8 PFOS (IS) Page 76 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09>28s22 2010 Method: 0:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a039 Text: Page 77 GLP10-01-01-05-006 DAL SD SD03 0 0000 Davey070799 GLP10-01 -01 -05-006 DAL SD SD03 0 0000 Davey070799 3M 05-Sep-2010 08:56:49 !3M 05-Sep-2010 08:56:49 d100904a039 100- ' . 1: MRM of 2 Channels ES- d100904a039 8.60 TIC 543 3.12e3 Area : 0o1 9.40 3304j j: 2: MRM of 2 Channels ESTIC 1.39e4 Area I % | %- _ 20 3: PFOS 5.00 ' i 1 0 .0 0 ` 15.00 Time 4 i ~i `1 I-" 4: 1802 PFBS (IS) 5.00 - " ' p i1 0 .0 0 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 v p ^ " ^ i t ^ f e r i M 7Rfe(P 5 f t ^ 5 i t e d *** -LUs. V 'v P a g e 8 1 1 f `9 6 2 - Quantify Sample Report GLP10-01-02-0S screening data Sample Listi Di \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09t28t22 2010 Method! D \masslyxuc\davey2010.PRO\Me t h D B \ d l 0 0 9 0 4 a Last modified! Tue Sep 07 13t49t46 2010 Job C o d e : Printed! Tue Oct 19 16i34il9 2010 Name: dl00904a039 Text: 7: 13C8 PFOS {IS) Page 78 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D: \masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a040 Text: Page 79 GLP10-01 -01 -05-007 DAL SD SD03 0 0005 Davey070799 GLP10-01 -01 -05-007 DAL SD SD03 0 0005 Davey070799 3M 05-Sep-2010 09:14:56 3M 05-Sep-2010 09:14:56 d 100904a040 100 1: MRM of 2 Channels ES- d100904a040 8.61 TIC 271 100 1.91e3 9.48 14521 2: MRM of 2 Channels ESTIC 6.71e3 Area Area %% 34 Time 10 5.00 1 0 .0 0 15.00 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) GLP10-01 -01 -05-007 DAL SD SD03 0 0005 Davey070799 GLP10-01 -01-05-007 DAL SD SD03 0 0005 Davey070799 3M 05-Sep-2010 09:14:56 3M 05-Sep-2010 09:14:56 d100904a040 100- 10.36 304181 3: MRM of 2 Channels ES- d100904a040 TIC 100 1.16e5 6: MRM of 1 Channel ES- 8.64 TIC 188 1.21e3 Area Area %- % 5.00 1 0 .0 0 15.00 Time 28 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List D \masslynx\davey201 0 .PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0928:22 2010 Methodt Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13i49:46 2010 Job Codet Printed! Tue Oct 19 16i34!l9 2010 Name: dl00904a040 Text! 5: 1802 PFHS (IS) 6: MPFOS (Surr) Page 80 q u a n titS M ^ iU ^ y i^ L iS iQ ltQ 2 lO /lS /1 0 In te rim .'R e p Q rt 0 5 . v>\ Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a041 Text: 1: PFBS 3: PFOS Page 81 2 ; PFHS_______________ ________________________________________________________________________ ________ GLP10-01 -01-05-009 DAL SD SD04 0 0000 Davey070799 3M 05-Sep-2010 09:33:03 d100904a041 100n 9.53 12570] 2: MRM of 2 Channels ESTIC 5.10e4 Area % 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time I '] Page 815 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:26:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a041 Text : 7: 13C8 PFOS (IS) Page 82 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a042 Text: 1: PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) Page 83 i.0/1 quantit^ M i ^ i ^ ^ y ( P b S I 0 - 0 1 0 2 10/18/10 mmh In te fim S jR e p o rt (0 5 1 "p a g e 8 1 7 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a042 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 84 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 s2 8 i22 2010 Methods D s \masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 1 3 :49s46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a043 Text: 1: PFBS 2 : PFHS 3: PFOS 4: 1802 PFBS (IS) quantitated 9/7'/10 and printed 10/18/10 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim iR e p o rt 0 5 -ii' `" ( " rated ' / ' 7 / X ( j \ : v . -1 I iv Page 85 Quantify Sample Report GLP10>01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a043 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) Page 86 V i\ '^ 1 3 M S tu d y G L P 1 0 -0 1 -0 2 5 inted 10/18/10 mmhj/7i/l.a ' -ii LY ski 10.arid pr..l/. & ; Page 820 o f 962 9/7^10.and pri &` ' Quantify Sample Report GLP10-01-02-05 screening data Sample List< Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09i28i22 2010 Methodt Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13t49!46 2010 Job Codei Printed! Tue Oct 19 16t34!l9 2010 Name: dl00904a044 Text: Page 87 GLP10-01-01-05-012 DAL SD SD05 0 0005 Davey070799 3M 05-Sep-2010 10:27:17 d100904a044 2: MRM of 2 Channels ES- 9.44 TIC 100- 4807 1.98e4 Area %- 5.00 1 0 .0 0 15.00 Time 4: 1602 PFBS (IS) GLP10-01-01-05-012 DAL SD SD05 0 0005 Davey070799 GLP10-01-01-05-012 DAL SD SD05 0 0005 Davey070799 3M 05-Sep-2010 10:27:17 3M 05-Sep-2010 10:27:17 d100904a044 3: MRM of 2 Channels ES- d100904a044 6: MRM of 1 Channel ES- 10.32 TIC 8.55 TIC 100- 33893 100 1.20e5 182 1.20e3 Area Area %- % 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 qu" t i t a fn fe fim R e p o rt 0 5 in to d LL 1 0 .0 0 15.00 Time 31 5.00 1 0 .0 0 15.00 Time P age 821 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 092822 2010 Method D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified Tue Sep 07 134946 2010 Job Code Printed Tue Oct 19 163419 2010 Name dl00904a044 Text 5s 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) a.,\aiquantitated 9/7/10 and printed yl0/4&s/10 mah ; 3 M S tu d y G L P 1 0 - 0 0 |'lV v , "` I n t e r i m R e p o r t 0 5 " ` i? q u a :: % z\\ Page 88 i V.- - q iiar. t^ L \e Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SarnpleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a045 Text: 1: PFBS Page 89 GLP10-01-01 -05-013 DAL SD SD06 0 0000 Davey070799 3M 05-Sep-2010 10:45:21 d100904a045 2: MRM of 2 Channels ES- 100 9.49 3120 TIC 1.32e4 Area %- 5.00 1 0 .0 0 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 P a g e 8 2 3 o f 9 J 2 'ia n ,;ic a te Quantify Sample Report GLP10-01-02-05 screening data Sample List D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified' Tue Sep 07 09>2Bi22 2010 Method' D '\masslynx\davey2010.PRO\MethDB\dl00904a Last modified' Tue Sep 07 13'49:46 2010 Job Code' Printed: Tue Oct 19 163419 2010 Name: dl00904a045 Text* 7: 13C8 PFOS (IS) Page 90 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 092822 2010 Method D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified Tue Sep 07 134946 2010 Job Code Printed Tue Oct 19 16:3419 2010 Name dl00904a046 Texts 1: PFBS 2: PFHS Page 91 Quantify Sample Report GLP10-01-02-05 screening data Sample List* D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09x28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a046 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) GLP10-01-01-05-014 DAL SD SD06 0 0005 Davey070799 3M 05-Sep-2010 11:03:27 d100904a046 7: MRM of 1 Channel ES- 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 10.00 15.00 Page 92 Page 826 o f 962 to Quantify Sample Report GLP10-01-02>05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a047 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 93 Quantify Sample Report GLP10-01-02-Q5 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D: \masslynx\davey2010 .PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a047 Text i 7: 13C8 PFOS (IS) Page 94 6: MPFOS (Surr) GLP10-01 -01 -05-015 DAL SD SD07 0 0000 Davey070799 3M 05-Sep-201011:21:31 d100904a047 4: MRM of 1 Channel ES- 100- 1 0 .3 7 96 ! TIC 695 Area % 36 Time 5.00 1 0 .0 0 15.00 quantitated 9/7/10.and printed 10/18/10 mmh: It i'A ii Jr 5 Page 828 o f 962 ) 1 \ K J" .Uii l\ S \ Quantify Sample Report GLP10-01-02-05 screening data . Sample Listi Dt\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method : D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a048 Text: 1 : PFBS 2 , PFHS G L P 1 0-01 -01 -05-016 D AL SD SD07 0 0005 Davey070799 3M 05-Sep-2010 11:39:37 d100904a048 1PQ 1: MRM of 2 Channels ES8.61 TIC 697 3.86e3 Area % 5.00 10.00 15.00 Time 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 95 Page 829 o f 962 j y/7/lO-anc Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a048 Text: 7: 13C8 PFOS (IS) Page 96 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D:\masslynx\davey201 0 .PRO\SampleDB\dlOO904a Last modified: Tue Sep 07 09<28:22 2010 Method > D :\mas slynx\davey2010.PR0\Me thDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a049 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 97 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified; Tue Sep 07 09:28<22 2010 Method: D t \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a049 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 98 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dlOO904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\HethDB\dlOO904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a050 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 99 :i-intitated: 9/7'/li Page 833 o f 962 $ Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Codei Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a050 Text: Page 100 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D> \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09:28:22 2010 Methodi Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13i49!46 2010 Job Codei Printed! Tue Oct 19 16:34:19 2010 Name: dl00904a051 Text! 1: PFBS . 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 101 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a051 Text: Page 102 3 M S tu d y G L P 1 0 -0 1 -0 2 In te rim R e p o rt 0 5 quantitated^9/7/10 and printed 10/16/10 4 V' wt T V*V i . . Page 836 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List Ds \masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified! Tue Sep 07 09s28s22 2010 Methodi D i \masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13s49*46 2010 Job Codes Printed Tue Oct 19 1 6 i34:19 2010 Names dl00904a052 Texts 1: PFBS 2: PFHS Page 103 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 s2 8 22 2010 Method: D s\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49i4 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a052 Text: S: 1802 PFHS {IS} 7: 13C8 PFOS (IS) Page 104 6 : MPFOS {Surr) GLP10-01 -01 -05-017 DAL SD SD08 0 0000 Davey070799 3M 05-Sep-2010 12:52:07 d100904a052 100- 10.42 no : 4: MRM of 1 Channel ES- TIC 897 Area % 5.00 'J\ A ^ 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\mASSlynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09s28s22 2010 Method: D s \masslyxuc\davey2010.PRO\MethDB\dl00904a Last modifieds Tue Sep 07 13s49s46 2010 Job Codes Printed: Tue Oct 19 16s34sl9 2010 Names dl00904a053 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 105 P a g e 18 3 9 o f 9 6 2 v V" Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a053 Text: 5: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 106 6: MPFOS (Surr) GLP10-01 -01 -05-018 DAL SD SD08 DB 0000 Davey070799 3M 05-Sep-2010 13:10:18 d100904a053 100- 10.33 104 ] 4: MRM of 1 Channel ESTIC 898 Area 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D * \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09>28<22 2010 Methods D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a054 Text: 1: PFBS _ 2: PFHS Page 107 P age 841 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MetbOB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a054 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) q u a n t i t a t ^ 9/7/10 .and printed 10/18/&0lnqnhsd %y--/ : 3 M |S tu d y iG L P 1 0 -0 1 -0 2 ` ` i R e p o rt 0 5 5* Page 108 ruantit^ted 59/ /. \ Page 842 o f 9 6 2 jiM k & W \ Quantify Sample Report GLP10-01-02-05 screening data S am ple L i s t : D *\m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d ifie d : Tue Sep 07 0 9 :2 8 122 2010 M e tho d : D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M eth D B \d l0 0 90 4a L a s t m o d ifie d : Tue Sep 07 1 3 :4 9 :4 6 2010 Job Code : P rin te d : Tue O c t 19 1 6 :3 4 :1 9 2010 Name: d !0 0 9 0 4 a 0 5 5 T e x t: 1: PFBS 3: PFOS Page 109 . 2 : PFHS_______________________________ ___________________________________________ ________________________________________ GLP10-01 -01 -05-021 DAL SD SD09 0 0000 Davey070799 3M 05-Sep-2010 13:46:32 d100904a055 1 0 0 "i 9.57 _ 119641 2: MRM of 2 Channels ESTIC 4.86e4 j Area %- 4: 1802 PFBS (IS) 5.00 I...>........>...<...>......................................i-.1.....'..-.. T- rime 10.00 15.00 o u a n tita 3 M S tU d ^ o G L P .l0 i0 le Q 2 io /1 8 /1 0 rnm hzuW v., / -A li- V - Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a055 Text: 7: 13C8 PFOS (IS) Page 110 6= MPFOS (Surr) GLP10-01 -01 -05-021 DAL SD SD09 0 0000 Davey070799 3M 05-Sep-2010 13:46:32 d100904a055 4: MRM of 1 Channel ES- 100- 10.45 93 t ic 695 Area % 37 Time 5.00 1 0 .0 0 15.00 3 M S tu d y G L P 1 0 -0 1 -0 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09x28x22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Codei Printed: Tue Oct 19 16x34:19 2010 Name: dl00904a056 Texti 1: PFBS 2: PFHS Page 111 4: 1802 PFBS (IS) GLP10-01 -01 -05-022 DAL SD SD09 0 0005 Davey070799 GLP10-01-01-05-022 DAL SD SD09 0 0005 Davey070799 3M 05-Sep-201014:03:37 3M 05-Sep-2010 14:03:37 d100904a056 100 10.41 71514 3: MRM of 2 Channels ES- d100904a056 TIC 100n 2.57e5 6: MRM of 1 Channel ES- 8.81 n e 185 1.24e3 Area Area %- % 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 quanti R e p f i r l 0 5 inted lO/18/JLOinmhd, 1- : U \r 1 0 .0 0 -Time15.00 5.00 1 0 .0 0 15.00 Time- T 'P a g e 8 4 5 o f 9 6 2 ti'fc ^ *G d ,9 /f,7 ' V l r .v Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 09i2822 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13s49i46 2010 Job Codes Printed! Tue Oct 19 16s34s19 2010 Kmet dl00904a056 Texts 5s 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) GLP10-01 -01 -05-022 DAL SD SD09 0 0005 Davey070799 3M 05-Sep-2010 14:03:37 d100904a056 10 0 "! 1 0 .4 2 106 7: MRM of 1 Channel ESTIC 891 Area %- 5.00 1 0 .0 0 15.00 Time Page 112 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Page 113 Name: dl00904a057 Text: 2: PFHS______________________________________________________________________________ __________________ GLP10-01 -01 -05-023 DAL SD SD10 0 0000 Davey070799 GLP10-01 -01 -05-023 DAL SD SD10 0 0000 Davey070799 3M 05-Sep-201014:21:41 3M 05-Sep-201014:21:41 d100904a057 100 8.61 14295 1: MRM of 2 Channels ES- d100904a057 TIC 6.36e4 1 0 0 t Area 9.49 43291 l 2: MRM of 2 Channels ESTIC 1.65e5 Area %- % ^ " r' '-- r 1` 1 '' l 1 J 1 1 1" ` l Time 0 5.00 io !o o ' 15!oO 3: PFOS 4: 1802 PFBS (IS) 5.00 A10.00 I Time 15.00 3 M S tu d y G L P 1 0 -0 1 -0 2 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 0 9 :28s22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a057 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 114 Quantify Sample Report GLP10-01-02-05 screening data Sample List D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified* Tue Sep 07 09*28*22 2010 Method* D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified* Tue Sep 07 13*49*46 2010 Job Code* Printed: Tue Oct 19 16:34*19 2010 Name* dl00904a058 Text * 1* PFBS 2: PFHS Page 115 3 * PFOS___________________________ ___________________________________________________________________ 4: 1802 PFBS (IS)___________________________________________________________________ ___________ GLP10-01 -01 -05-024 DAL SD SD10 0 0005 Davey070799 GLP10-01 -01 -05-024 DAL SD SD10 0 0005 Davey070799 3M 05-Sep-2010 14:39:50 3M 05-Sep-2010 14:39:50 d100904a058 100n 10.41 43871371 3: MRM of 2 Channels ES- d100904a058 TIC 1.48e6 1 0 0 - 6: MRM of 1 Channel ES- 8.63 TIC 210] 1.21e3 Area Area %- % 5.00 3 M S tu d y G L P 1 0 -0 1 -0 2 q u a n t i t a j n t e n m R e p o ^ r t '` 0 5 n te < ^ ' O /IS /IO mmh i\ 10.00 15.00 Time - 2 0 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a058 Text: 7: 13C8 PFOS (IS) quantit3 M S u d y G L & 1 9 r 0 1 8 2 10/18/10 mnh In te rim R e p o rt 0 5 , , ,, Page 116 , Page 850 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D * \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 He tbod: D :\mas slynx\davey2010.PR0\Me thDB\dl0 0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a059 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS {IS) Page 117 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D :\masslynx\davey2010.PRO\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a059 Text: Page 118 7: 13CS PFOS (IS)______________________________________________________________ __ _____ IGLP10-01 -01 -05-025 DAL SD SD11 0 0000 Davey070799 !3M 05-Sep-2010 14:57:54 id100904a059 100n 10.38 108 7: MRM of 1 Channel ESTIC 867 Area % i 44 T 5.00 1 0 .0 0 10/18/10 mmh i\ J < A 15.00 Time s T a w r^sfett- Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a060 Text: 1 : PFBS 2 : PFHS Page 119 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a060 Text: 5 : 1802 PFHS ( IS ) Page 120 6 : MPFOS ( S u r r ) _______ ___________________________________________ _________________________ __________ ______ _ GLP10-01 -01-05-026 DAL SD SD11 0 0005 Davey070799 3M 05-Sep-201015:15:59 d100904a060 100n 10.33 133 4: MRM of 1 Channel ESTIC 903 Area % 7 : 13C8 PFOS ( I S ) GLP10-01 -01 -05-026 DAL SD SD11 0 0005 Davey070799 3M 05-Sep-201015:15:59 d100904a060 7: MRM of 1 Channel ES- 5.00 %! 1 0 .0 0 W V W A i 1. 15.00 Time q u a n t i t S M i ^ W A P k 1 0 - ? 1 !:0 2 1 0 / 1 8 / 1 0 mmh In te rim R e p o rt O r Page 854 o f 962 ig r.;. . . ___________ Quantify Sample Report GLP10-01- 02 -05 screening data Sample List Dx\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28x22 2010 Method: Dx\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13x49:46 2010 Job Code: Printed: Tue Oct 19 16x34:19 2010 Harnet dl00904a061 Text: 1: PFBS 2: PFHS GLP10-01-01-05-027 DAL SD SD12 0 0000 Davey070799 3M 05-Sep-2010 15:34:02 d100904a061 1: MRM of 2 Channels ES- 3: PFOS 4: 1802 PFBS (IS) Page 121 quantitated 9/7*710 and printed 10/18/10 mmhzedt ),- v/J.i 3 M S tu d y fc L P t0 -0 1 -0 2 In te rim jilB o rt 0 5 '' itf.tedx')/ "t/ja itatedi 0/7/J.i Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 0 9 :28s22 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Codes Printeds Tue Oct 19 16:34:19 2010 Names d!00904a061 Texts 5: 1802 PFHS (IS) 6-. MPFOS (Surr) 7 j 13C8 PFOS (IS) Page 122 Quantify Sample Report QLP10-01-02-05 screening data Sample List: D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28<22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 123 Name: dl00904a062 Text: 1: PFBS 2: PFHS_______________________________________________________________________________________________ GLP10-01-01-05-028 DAL SD SD12 DB 0000 Davey070799 GLP10-01-01-05-028 DAL SD SD12 DB 0000 Davey070799 3M 05-Sep-201015:52:07 3M 05-Sep-2010 15:52:07 d100904a062 10CH 8.61 17587 1: MRM of 2 Channels ES- d100904a062 TIC 100- 8.60e3 9.45 17502] 2: MRM of 2 Channels ESTIC 7.11e4 Area Area %% 5.00 1 0 .0 0 15.00 Time 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data S am ple L i s t : D : \m a s s ly n x \d a v e y 2 0 1 0 .PR O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d if ie d : Tue Sep 07 0 9 :2 8 i2 2 2010 M ethod: D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M e th D B \d l0 0 9 0 4 a L a s t m o d ifie d : Tue Sep 07 1 3 :4 9 :4 6 2010 Job Code: P rin te d : Tue O ct 19 1 6 :3 4 :1 9 2010 Name: d l0 0 9 0 4 a 0 6 2 T e x t: 7: 13C8 PFOS (IS) !GLP10-01-01-05-028 DAL SD SD12 DB 0000 Davey070799 3M 05-Sep-2010 15:52:07 id100904a062 7: MRM of 1 Channel ES- q u a n tit^ ^ l ^ b 1 0 - 0 1 - 0 2 1 0 / 1 8 / 1 0 mmh Page 124 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a063 Text: Page 125 GLP10-01 -01-05-029 DAL SD SD12 0 0005 Davey070799 GLP10-01-01-05-029 DAL SD SD12 0 0005 Davey070799 3M 05-Sep-2010 16:10:12 3M 05-Sep-201016:10:12 d100904a063 100- 1: MRM of 2 Channels ES- d100904a063 8.65 974 TIC 1 0 0 4.96e3 9.57 16584 2: MRM of 2 Channels ESTIC 6.97e4 Area Area %% 11 Time 5.00 1 0 .0 0 15.00 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) GLP10-01 -01-05-029 DAL SD SD12 0 0005 Davey070799 GLP10-01-01-05-029 DAL SD SD12 0 0005 Davey070799 3M 05-Sep-201016:10:12 3M 0 5 -S e p -2 0 1 0 16:10:12 d100904a063 100 10 .28 57339 3: MRM of 2 Channels ES- d100904a063 TIC 100 1.93e5 8.64 136(1 6: MRM of 1 Channel ESTic 923 Area Area %- % 5.00 1 0 .0 0 15.00 Time tit Interim Report' 05 10/18/10 xmnh . .5.0 . 1 1 , l u m u 5.00 1 0 .0 0 10 / l c . I'J na\ 15.00 Time L \Paqe 859 of 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a063 Text: 7 ; 13C8 PFOS (IS) GLP10-01-01-05-029 DAL SD SD12 0 0005 Davey070799 ;3M 05-Sep-2010 16:10:12 id100904a063 : 100 10.38 78 J 7: MRM of 1 Channel ESUC 633 Area I i % rJ--\Aw\ yv 43 Time ' io!oo 15.00 Page 126 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D :\mas slynx\davey2010.PR0\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a064 Text: Page 127 G LP10-01-01-05-030 DAL SD SD13 0 0000 D avey070799 G LP 10-01 -01 -05-030 D A L SD S D 13 0 0000 Davey070799 3M 05-Sep-2010 16:28:20 3M 05-Sep-2010 16:28:20 d100904a064 100- 8.83 1890 1: MRM of 2 Channels ES- d100904a064 TIC 100 8.89e3 9.62 _ 16547 2: MRM of 2 Channels ESne 6.84e4 Area Area %% 5.00 J_ L 1 0 .0 0 15.00 Time 5.00 I 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) G LP 10-01 -01-05-030 DAL SD SD13 0 0000 D avey070799 G L P 1 0-01 -01 -05-030 D A L SD S D 13 0 0000 Davey070799 3M 05-S ep-201016:28:20 3M 05-S ep-201016:28:20 d100904a064 100- 10.46 109772 3: MRM of 2 Channels ES d100904a064 TIC 100 3.68e5 6: MRM of 1 Channel ES- 8.81 TIC 177 1.11e3 Area Area %% 5.00 1 0 .0 0 3 M S tu d y G L P 1 0 -0 1 -0 2 q u a n t i t i n t e r m n e p 0 f t 0 ^ ^ nte<^ 10/18/10 mmh . 15.00 Time 5.00 1 0 .0 0 5Sr..Ufi.U U - ? 15.00 Time P age '861 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a064 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 128 Quantify Sample Report GLPlO-01-02-05 screening data Sample List: D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09*28i22 2010 Method: D * \ m a s s l y n x \ d a v e y 2 0 1 0 .PRO\ M e t h D B \ d l O 0 904a Last modified* Tue Sep 07 13*49*46 2010 Job Code * . Printed* Tue Oct 19 16*34*19 2010 Page 129 Name: dl00904a065 Texts 1: PFBS 2 : PFHS GLP10-01 -01 -05-031 DAL SD SD13 0 0005 Davey070799 GLP10-01 -01 -05-031 DAL SD SD13 0 0005 Davey070799 3M 05-Sep-2010 16:46:26 3M 05-Sep-201016:46:26 d100904a065 1: MRM of 2 Channels ES- d100904a065 1 0 0 -1 19.49 7863 2: MRM of 2 Channels ESTIC 3.14e4 Area %- 2T ............, i- Time 5.00 io!oo 15.00 1802 PFBS (IS) GLP10-01 -01 -05-031 DAL SD SD13 0 0005 Davey070799 GLP10-01 -01 -05-031 DAL SD SD13 0 0005 Davey070799 3M 0 5 -S e p -2 0 1 0 16:46:26 3M 0 5 -S e p -2 0 1 0 16:46:26 d100904a065 100 10.41 _ 51493ft 3: MRM of 2 Channels ES- d100904a065 TIC 1.75e5 1 0 0 - 6: MRM of 1 Channel ES- 8.55 TIC 82 659 Area Area %- % 5.00 -W 1 0 .0 0 15.00 Time 5.00 1 0 .0 0 15.00 -Time- Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a065 Text: 5: 1802 PFHS (IS) 6; MPFOS (Surr) Page 130 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a066 Text: Page 131 GLP10-01-01-05-032 DAL SD SD14 0 0000 Davey070799 3M 05-Sep-2010 17:04:35 d100904a066 100- 9.62 904711 2: MRM of 2 Channels ESTIC 3.65e5 Area % 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) GLP10-01 -01 -05-032 DAL SD SD14 0 0000 Davey070799 GLP10-01-01-05-032 DAL 3M 05-Sep-201017:04:35 !3M d100904a066 100 10.41 339721 3: MRM of 2 Channels ES id100904a066 TIC ; 100- 1 .1 1 e 6 Area SD SD14 0 0000 Davey070799 05-Sep-2010 17:04:35 6: MRM of 1 Channel ES8.81 TIC 205] 1,36e3 Area % i% 5.00 1 0 .0 0 3 M S tu d y G L P 1 0 -0 1 -0 2 ,, -r 0 i - 0 2 't r n i e !i m R e p o r t <b r l n t e i i 1 0 / 1 8 / 1 0 lm ,lh \' , 5 15.00 -Time 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List : D>\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 0 9 s28 22 2010 Method: D:\mas8lynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a066 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) g u a n t i t 3 M d S t U d y G b P 1 0 - 0 4 t 0 2 1 0 / l B - / i 0 itimnhfit ^ ! .in te rim * R e p o rt 0 5 " 5, A V V il* M Page 132 Quantify Sample Report GLP10-01-02-05 screening data S am ple L i s t : D : \m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d ifie d : Tue Sep 07 0 9 :2 8 :2 2 2010 M ethod: D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M eth D B \d l0 09 0 4a L a s t m o d ifie d : Tue Sep 07 1 3 :4 9 :4 6 2010 Job Code: P rin te d : Tue O c t 19 1 6 :3 4 :1 9 2010 Name: d l00 9 04 a 06 7 T e x t: 1 : PFBS 2 : PFHS 3 : PFOS 4 : 1 8 0 2 PFBS ( IS ) o u a n titS ^ i^ H ^ M . 1 0 /1 8 /1 0 m a in V' Page 133 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last siodified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a067 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 134 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a068 Text: Page 135 EC-100831-06 5 ng Extracted Curve Point Davey070799 EC-100831-06 5 ng Extracted Curve Point Davey070799 3M 05-Sep-2010 17:40:50 3M 05-Sep-201017:40:50 d100904a068 100 8.69 521 1: MRM of 2 Channels ES- d100904a068 TIC 100- 2.88e3 9.53 420 2: MRM of 2 Channels ESTIC 2.52e3 Area Area %% 3: PFOS 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a068 Text: 5: 1802 PFHS (IS) 6: MPFOS {Surr) 7: 13C8 PFOS (IS) Page 136 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010. PRO\SampleDB\dlOO904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a069 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 137 Page 8 7 1 ^ f S T " " Quantify Sample Report GLP10-01-02-05 screening data Sample List! D t \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a069 Text: Page 138 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:48 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a070 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 139 q u a n t i t 3 M S u d y G L p 1 9 r 0 1 t 2 l / l 8 / l O mmh '^ in te rim R e p o rt 0 5 Page 873 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D\masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified: Tue Sep 07 09i28t22 2010 Methodi D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13i49>46 2010 Job Code I Printed Tue Oct 19 16:34tl9 2010 Namei dl00904a070 Text: 7: 13C8 PPOS (IS) Page 140 Quantify Sample Report GLP10-01-02 -05 screening data Sample Listt D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 - Page 141 Name: dl00904a071 Text: 1 : P F B S ________________________________________________________________________________ 2: PFHS____________________ ______________________________________________________________________ GLP10-01-01 -05-034 DAL SD SD15 0 0000 Davey070799 GLP10-01 -01 -05-034 DAL SD SD15 0 0000 Davey070799 3M 05-Sep-2010 18:35:13 3M 05-Sep-2010 18:35:13 d100904a071 100n 8.61 661Oj !j 1: MRM of 2 Channels ESTIC 2.94e4 Area d100904a071 1 0 0 -1 9.53 37150 2: MRM of 2 Channels ESTIC 1.46e5 Area %- %- 2 3: PFOS 5.00 1 0 .0 0 15.00 ' Time 0 4: 1802 PFBS (IS) 5.00 !U 1 0 .0 0 --I 15.00 J jm e Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a071 Text: 5: 1802 PFHS {IS) 7: 13C8 PFOS (IS) Page 142 6: MPFOS (Surr) GLP10-01-01-05-034 DAL SD SD15 0 0000 Davey070799 3M 05-Sep-2010 18:35:13 d100904a071 4: MRM of 1 Channel ES- 100- 10.41 88 1 t ic 626 Area % 46 Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: d!00904a072 Text: 1: PFBS 3: PFOS Page 143 GLP10-01-01 -05-035 DAL SD SD15 0 0005 Davey070799 3M 05-Sep-2010 18:53:21 d100904a072 100- 9.53 8314 2: MRM of 2 Channels ESTIC 3.30e4 Area %- 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-0205 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a072 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 144 P ag e 8 7 8 o f9 6 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 145 Name: d!00904a073 Text: 1; PFBS_______________________________ ________________________________________________________________ 2 : PFHS ______________________________________________________________________ __________________ GLP10-01 -01 -05-036 DAL SD SD16 0 0000 Davey070799 GLP10-01-01-05-036 DAL SD SD16 0 0000 Davey070799 3M 05-Sep-201019:11:29 3M 05-Sep-201019:11:29 d100904a073 100n 8.65 19531 1: MRM of 2 Channels ESTIC 9.20e3 Area d100904a073 100n 9.49 38613] 2: MRM o f 2 Channels ESTIC 1.56e5 Area %. %- 3: PFOS 5.00 10.00 15.00 Time 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Dt\masslynx\davey201Q.PRO\SampleDB\dlO0904a Last modified! Tue Sep 07 09:28122 2010 Methods D s \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49s46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: d!00904a073 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 146 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a074 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 147 ' P age 881 o f 962 is Quantify Sample Report GLP10-01-02-05 screening data Sample List D 3\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a074 Text: 5: 1802 PFHS (IS) 6 : MPFOS (Surr) 7: 13C8 PFOS (IS) Page 148 Quantify Sample Report GLP10-01-02-05 screening data Sample Listt D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09t28>22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49t46 2010 Job Code : Printed: Tue Oct 19 16:34il9 2010 Name: dl00904a075 Text: 3: PFOS Page 149 GLP10-01 -01 -05-038 DAL SD SD16 0 0005 Davey070799 3M 05-Sep-201019:47:39 d100904a075 100n 9.57 243091 2: MRM of 2 Channels ES- TIC 9.73e4 Area %- 4: 1802 PFBS (IS) 5.00 1 0 .0 0 15.00 Time 3M L quantitated .9/7, In te rim I *10/18/10.n V i/ . / i a % *x i .ord .o rd : ta g e 8 3 b f 962! i ' Quantify Sample Report GLP10-01-02 -05 screening data Sample List : D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method : D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a075 Text: 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 150 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Dt \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D t \masslynx\ d a v e y 2 0 1 0 . PR O \ M e t h D B\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code t Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a076 Text: Page 151 IGLP10-01-01-05-039 DAL SD SD17 0 0000 Davey070799 3M 05-Sep-2010 20:05:48 Id100904a076 2: MRM of 2 Channels ES- 9.44 TIC 100 424741 1 ,69e5 Area % 5.00 1 0 .0 0 15.00 Time 4: 1802 PFBS (IS) GLP10-01 -01 -05-039 DAL SD SD17 0 0000 Davey070799 GLP10-01 -01 -05-039 DAL SD SD17 0 0000 Davey070799 3M 05-Sep-2010 20:05:48 3M 05-Sep-2010 20:05:48 d100904a076 100 10.28 218679 3: MRM of 2 Channels ES- d100904a076 TIC 100 7.30e5 Area 8.55 1721 6: MRM of 1 Channel ESTIC 1.09e3 Area %% 5.00 10.00 -Time 15.00 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-0S screening data Sample Listi Dt\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D\mas8lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a076 Text: 5: 1802 PFHS {IS) q u a n t i tjttjie irim ^ 3 L R 1 0 -0 1 -0 2 "i^ d o g rin te a 10/18/10 ' nar 7 Page 1S2 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\mas6lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 . Name: dl00904a077 Text: Page 153 IGLP10-01-01-05-040 DAL SD SD17 0 0005 Davey070799 GLP10-01 -01-05-040 DAL SD SD17 0 0005 Davey070799 I3M 05-Sep-2010 20:23:57 3M 05-Sep-2010 20:23:57 d100904a077 100- 9.44 31626 2: MRM of 2 Channels ESTIC 1.27e5 Area % 5.00 1 0 .0 0 15.00 Time q u a n titS ^ J In te rim R e p o rt 0 5 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D: \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a077 Text: 7: 13C8 PFOS (IS) 3 M S tu d y G L P 1 0 -0 1 -0 2 Page 154 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: . Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a078 Text; 1: PFBS 2: PFHS Page 155 3 : PFO S ___________________________________ __________ ___________________________________________________ 4: 1802 PFBS (IS)______________________________________________________________________________________ GLP10-01-01 -05-041 DAL SS SS01 0 0000 Davey070799 GLP10-01-01-05-041 DAL SS SS01 0 0000 Davey070799 3M 05-Sep-2010 20:42:02 3M 05-Sep-2010 20:42:02 d100904a078 100 10.33 40123] 3: MRM of 2 Channels ES- d100904a078 TIC 1.62e5 1 0 0 n Area 6: MRM of 1 Channel ES8.51 TIC 2 1 1 1.28e3 Area %% 5.00 1 0 .0 0 15.00 Time 5.00 1 0 .0 0 -Time 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List* D\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified* Tue Sep 07 09:28*22 2010 Method* D*\masslynx\davey2010.PRO\MethDB\dl00904a Last modified* Tue Sep 07 13:49*46 2010 Job Code* Printed* Tue Oct 19 16:34:19 2010 Name* dl00904a078 Text: Page 156 Quantify Sample Report GLP10-01-02-05 screening data S am ple L i s t i D : \m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d if ie d ! Tue Sep 07 0 9 :2 8 :2 2 2010 M e tho d : D :\m a s s ly n x \d a v e y 2 0 1 Q .P R O \M eth D B \d l0 0 90 4a L a s t m o d if ie d : Tue Sep 07 1 3 :4 9 :4 6 2010 Job Code : P rin te d : Tue O c t 19 1 6 :3 4 :1 9 2010 Name: d l0 0 9 0 4 a 0 7 9 T e x t: Page 157 GLP10-01 -01 -05-042 DAL SS SS01 0 0005 4 : 1802 PFBS (IS) Davey070799i !GLP10-01-01-05-042 DAL SS SS01 0 0005 Davey070799 3M 05-Sep-2010 21:00:08! 3M 05-Sep-2010 21:00:08 d100904a079 100- 10.45 63165 3: MRM of 2 Channels ES- j id100904a079 TIC i !. 1 0 0 - 2.48e5> Area; 6: MRM of 1 Channel ES- 8 .6 8 163 TIC 1.06e3 Area %- % -0 5 .0 0 ______ 1 0 .0 0 quanti t< a p 1 0 r 0 n t 0 2 1 0 / 1 8 / 1 0 mmh r In t rim R e p o rt 0 5 15.00 -Time :! 26 5.00 1 0 .0 0 15.00 Time P age 891 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a079 Text: 7: 13C8 PFOS (IS) |GLP10-01 -01 -05-042 DAL SS SS01 0 0005 Davey070799 3M 05-Sep-2010 21:00:08 d100904a079 7: MRM of 1 Channel ES- 5.00 10.00 15.00 Page 158 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09>28:22 2010 Methodi D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a080 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 159 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Dt\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09i28i22 2010 Method: Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13t49t46 2010 Job Code: Printed: Tue Oct 19 16i34:19 2010 Name: dl00904a080 Text: 5: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 160 6; MPFOS (Surr) GLP10-01 -01 -05-043 DAL SS SS02 0 0000 Davey070799 3M 05-Sep-2010 21:18:18 d100904a080 100" 10.32 113 4: MRM of 1 Channel ESTIC 812 Area % 36 ~ A / v V Time 5.00 1 0 .0 0 15.00 3 M S tu d y G L P 1 0 -0 1 -0 2 10/18/10 rnmlx ^ p * X T O s S je a itu ^ :tiS ' Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09*28*22 2010 Methodi D i \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a081 Text: 1: PFBS 2: PFHS Page 161 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Ds \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Page 162 Name: dl00904a081 Text: 5: 1802 PFHS (IS)______________________________________________________________________________________ 6: MPFOS (Surr) GLP10-01 -01 -05-044 DAL SS SS02 0 0005 Davey070799 GLP10-01 -01 -05-044 DAL SS SS02 0 0005 Davey070799 3M 05-Sep-2010 21:36:31 3M 05-Sep-2010 21:36:31 d100904a081 5: MRM of 1 Channel ES- d100904a081 4: MRM of 1 Channel ES- 5.00 10.00 15.00 5.00 10!00 ' 15!00 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D* \masslyxuc\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 0 9 j2 8 i22 2010 Hetbodi D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 1 3 : 4 9 i 4 6 2010 Job Codes Printed! Tue Oct 19 16:34il9 2010 Name: dl00904a082 Text: Page 163 GLP10-01 -01 -05-045 DAL SS SS03 0 0000 Davey070799 3M 05-Sep-2010 21:54:42 d100904a082 1 0 CH 9.57 16756(1 2: MRM of 2 Channels ESne . 7.12e4 Area % 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a082 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 164 Quantify Sample Report GLPlO-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09t28:22 2010 Method: Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13i49t46 2010 Job Code! Printed: Tue Oct 19 16i34:19 2010 Name: dl00904a083 Text! 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 165 U1 y Quantify Sample Report GLP10-01-02-05 screening data Sample List D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D: \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a083 Text: 7: 13C8 PFOS (IS) a. q u a n t l t A ^ i S u d y < P L 1 f i - S 1t< 2 l 0 / l 8 / l 0 mmh \ \ 1' ! I n t e r i m R e p o r t 0 5 Page 166 Page 900 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09>28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a084 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 167 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34tl9 2010 Name: dl00904a084 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 168 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslyxuc\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a085 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 169 Quantify Sample Report GLP10-01'02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a085 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) Page 170 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09*28*22 2010 Methods D s\masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 13*49*46 2010 Job Code * Printed* Tue Oct 19 16*34*19 2010 Names dl00904a066 Texts 1* PFBS 2: PFHS 3: PFOS ' 4: 1802 PFBS (IS) Page 171 Quantify Sample Report GLP10-01-02-05 screening data Sample List D \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 092822 2010 Method D\masslynx\davey2010.PRO\MethDB\dl00904a Last modified Tue Sep 07 1349>46 2010 Job Code Printed Tue Oct 19 163419 2010 Harne dl00904a086 Text 7: 13C8 PFOS (IS) Page 172 . Page 9 6 2 '' Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a087 Text: 1: PFBS 2: PFHS 3 : PFOS 4: 1802 PFBS (IS) Page 173 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Me thod: D :\ma8 slynx\davey2010.PR0\Me thDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a087 Text: 5: 1802 PFHS (IS) , 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 174 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified] Tue Sep 07 09t28t22 2010 Me thod : D t\mas slynx\davey2010.PR0\Me thDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 175 Name: dl00904a086 Text: 1: PFBS 2: PFHS________________________________________________________________________________________________ GLP10-01 -01 -05-048 DAL SS SS04 0 0000 Davey070799 GLP10-01 -01 -05-048 DAL SS SS04 0 0000 Davey070799 3M 05-Sep-2010 23:43:21 3M 05-Sep-2010 23:43:21 d100904a088 1: MRM of 2 Channels ES- d100904a088 2: MRM of 2 Channels ES- 5 . 0 0 ......................... 10!00 ' ' ' 1 5 'oC) Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a088 Text: 5; 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 176 6: MPFOS (Surr) GLP10-01 -01 -05-048 DAL SS SS04 0 0000 Davey070799 3M 05-Sep-2010 23:43:21 d100904a088 100 10.46 97 4: MRM of 1 Channel ESTIC 794 Area % 5.00 1i l ^ v v 1 0 .0 0 15.00 Time iiH q u a n tit^ ^ i IP L & I f i- fi^ lO /ii/iO '. ,; In te rim R e p o rt 0 5 -J - i i n d `b r Jints.!Qv.lt, i' " A U . -V Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Methods D :\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code > Printed: Tue Oct 19 16:34:19 2010 Page 177 Harne: dl00904a089 Text: 1: PFBS 2 : PFHS GLP10-01 -01 -05-049 DAL SS SS04 0 0005 Davey070799 GLP10-01 -01 -05-049 DAL SS SS04 0 0005 Davey070799 3M 06-Sep-2010 00:01:29 3M 06-Sep-2010 00:01:29 d100904a089 1: MRM of 2 Channels ES- d100904a089 2: MRM of 2 Channels ES- 3: PFOS 4: 1802 PFBS (IS) Quantify Sample Report GLP10-01-02-05 screening data 1Sample Listi Dt\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 2 8 22 2010 Method: Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49i46 2010 Job Code: Printed: Tue Oct 19 16s34il9 2010 Name: d!00904a089 Texts 7: 13C8 PFOS (IS) Page 178 3 M S tt u d y G L P 1 0 - Q 1 - 0 2 quantitated 10/18/10-mmh M 7 R e 0p o O ? o 5 * n t e " ;V .iH u '3. \ ' .Li. . ,r 'P a g e 9 1 2 o f 9 6 2 t f V Quantify Sample Report GLP10-01-02-05 screening data Sample List: D \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 13t49i4 2010 Job Code I Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a090 Text: 1: PFBS 2: PFHS Page 179 3: PFOS 4: 1802 PFBS (IS) GLP10-01 -01 -05-050 DAL SS TRIP1 0 0000 Davey070799 GLP10-01-01-05-050 DAL SS TRIP1 0 0000 Davey070799 3M 06-Sep-2010 00:19:41 3M 06-Sep-2010 00:19:41 d100904a090 3: MRM of 2 Channels ES- d100904a090 6: MRM of 1 Channel ES- Page 913 o f 962 Y -1Y 1 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Methodi D t \ m a s s l y n x \ d a v e y 2 0 1 0 .PRO\MethD B \ d l 0 0 9 04a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a090 Texti 7: 13C8 PFOS (IS) quantit^ ^ d ^ ^ y ^ y i^ L f d1 0 - 0 1 - 0 2 10/18/10 mmh * In te rim .R e p o rt 0 5 Page 180 Quantify Sample Report GLF10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a091 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 181 Quantify Sample Report GLP10-01-02-05 screening data Semple List: D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a091 Text: 5: 1802 PFHS {IS) 6s MPFOS {Surr) 7s 13C8 PFOS (IS) Page 182 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a092 Text: 1: PFBS 2: PFHS 3: PFOS 4s 1802 PFBS (IS) Page 183 Quantify Sample Report GLP10-01-02-05 screening data S am ple L i s t : D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d if ie d : T ue Sep 07 0 9 :2 8 :2 2 2010 M e tho d : D :\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M e th D B \d l0 0 9 0 4 a L a s t m o d ifie d : Tue Sep 07 1 3 :4 9 :4 6 2010 Job Code: P rin te d : Tue O ct 19 1 6 :3 4 :1 9 2010 Name: d l0 0 9 0 4 a 0 9 2 T e x t: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 184 6; MPFOS (Surr) GLP10-01 -01 -05-052 DAL SS SS05 0 0005 Davey070799 3M 06-Sep-2010 00:55:55 d100904a092 100- 10.37 87 1 4: MRM of 1 Channel ESTIC 708 Area % 5.00 10.00 15.00 Time q u a n tit jj^C piO inp.j^fPnt- 0 2 1 0 / 1 8 / 1 0 tn n n h ^ 9 /7 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D i \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09>28>22 2010 Methods D s \masslynx\davey2010.PRO\MethDB\dl00904a Last modifieds Tue Sep 07 13>49i46 2010 Job Code > Printed! Tue Oct 19 16>34>19 2010 Names dl00904a093 Texts 1: PFBS 2; PFHS 3: PFOS 4s 1802 PFBS (IS) q u a n titS M i G L & 18 r2 iitS iL lO p .. In te rim R e p o rt 0 5 8 iK 1 Page 18S Quantify Sample Report GLP10-01-02-05 screening data Sample List D :\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a093 Text: 7: 13C8 PFOS lIS) GLP10-01 -01-05-054 DAL SS SS06 0 0000 Davey070799 3M 06-Sep-2010 01:14:06 d100904a093 7: MRM of 1 Channel ES- 100 1 0 .3 8 93 T IC 745 A rea % I 10.00 15.00 T im e M .v j w q u a n t i t S M d ^ ^ ^ M . ( p L R l I Q r O J e t ^ l O / l f i / i f t . im a lrd 9./.V / In te rim R e p o rt 0 5 jjp 3 'd ^ L O 'A ^ d /'lQ , man,'. Page 186 Quantify Sample Report GLP10-01-02-05 screening data Sample List* Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28(22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a094 Text: 1: PFBS 2: PFHS Page 187 3 M S tu d y G L P 1 0 -0 1 -0 2 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D*\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 i2 8 t22 2010 Method! D < \ m a s s l y n x \davey2010.PRO\MethDB\dlO0904a Last modified! Tue Sep 07 1 3 i 4 9 i 46 2010 Job Code! Printed! Tue Oct 19 1 6 i 3 4 : 1 9 2010 Name! dl00904a094 Text: 5s 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 188 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a09S Text: 1: PFBS 2: PFHS Page 189 3; PFOS 4: 1B02 PFBS (IS) GLP10-01 -01 -05-056 DAL SS SS06 DB 0005 Davey070799 GLP10-01 -01 -05-056 DAL SS SS06 DB 0005 Davey070799 3M 06-Sep-2010 01:50:22 3M 06-Sep-2010 01:50:22 d100904a095 3: MRM of 2 Channels ES- d100904a095 6: MRM of 1 Channel ES- ) Page 923 o f 962 T V 'f i? .< Quantify Sample Report GLP10-01-02-0S screening data S am ple L i s t i D : \m a s s ly n x \d a v e y 2 0 1 0 .P R O \S a m p le D B \d l0 0 9 0 4 a L a s t m o d ifie d ! Tue Sep 07 0 9 i2 8 i2 2 2010 M ethod! D i\m a s s ly n x \d a v e y 2 0 1 0 .P R O \M eth D B \d l0 09 0 4a L a s t m o d ifie d ! Tue Sep 07 1 3 i 4 9 i 46 2010 Job Code: P rin te d ! Tue O ct 19 1 6 i 3 4 i 19 2010 Name: d l0 0 9 0 4 a 0 9 5 T e x t! 5: 1802 PFHS (IS) 6: MPFOS (Surr) Page 190 q uiaanntit iitt3tfMtj SdviiUy dv py i P<yI'as hai1Q^5i Q i e i 1 0 / 1 8 / 1 0 mmh k R e Po rt 0 5 /j.0 .and prim:c 0'/i and prim: . /-*. Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09(28:22 2010 Method: D*\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a096 Text: 1: PFBS 2; PFHS 3: PPOS 4: 1802 PPBS (IS) Page 191 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 0 9 i28>22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13>49>46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a096 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 192 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: O :\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a097 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 193 . 3 M S tu d y G L P 1 0 -0 1 -0 2 i d , l O l ' / i g , a i u a n t i t m e H W ' R i p O f t ,tD S r i n t e d k at" ' S at, :-,V / . L' ' r.ed lOl'3/10. a_ : .\v'- P age 9 2 7 o f 9 2 ftita te d -s /- " Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09s28s22 2010 Methods Ds \masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13s49s46 2010 Job Codes Printed! Tue Oct 19 16s34sl9 2010 Page 194 * Names d!00904a097 Texts 5; 1802 PFHS (IS) 6: MPFOS (Surr) GLP10-01 -01 -05-058 DAL SS SS07 0 0005 Davey070799 GLP10-01 -01 -05-058 DAL SS SS07 0 0005 Davey070799 3M 06-Sep-2010 02:26:39 3M 06-Sep-2010 02:26:39 d100904a097 5: MRM of 1 Channel ES- d100904a097 4: MRM of 1 Channel ES- Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified Tue Sep 07 09<2822 2010 Method Di \mas8lynx\davey2010.PRO\MethDB\dl00904a Last modified Tue Sep 07 13<49<46 2010 Job Code Printed: Tue Oct 19 16<34:19 2010 Name: dl00904a098 Text: Is PFBS 2: PFHS Page 195 Quantify Sample Report GLP10-01-02-0S screening data Sample Lists D t \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09s28s22 2010 Methods Ds\masslynx\davey2010.PRO\MethDB\dl00904a Last modified Tue Sep 07 13<49:46 2010 Job Code s Printed: Tue Oct 19 1 6 i3 4 i19 2010 Name: dl00904a098 Text: 5: 1802 PFHS (IS) 7: 13C8 PFOS (IS) Page 196 6: MPFOS (Surr) GLP10-01 -01 -05-059 DAL SS 3M d100904a098 100 SS08 0 0000 Davey070799 06-Sep-2010 02:44:46 10.41 4: MRM of 1 Channel ES- T ic 96 ] 763 Area %- 40 Time 5.00 10.00 15.00 Quantify Sample Report GLP10-01-02-0S screening data Sample List: D \masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09<28>22 2010 Hethodi Di\masslynx\davey2010.PRO\MethDB\dlO0904a Last modified! Tue Sep 07 13:49:46 2010 Job Codet Printed! Tue Oct 19 16>34>19 2010 Marne: dl00904a099 Texti 1 : PFBS 2: PFHS GLP10-01 -01 -05-060 DAL SS SS08 DB 0000 Davey070799 3M 06-Sep-2010 03:02:57 d100904a099 1: MRM of 2 Channels ES- Page 197 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09>26s22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904a099 Text: 5: 1802 PFHS (IS) Page 198 6; M PFOS (Surr)________________________________________________________ ________________________ GLP10-01 -01 -05-060 DAL SS SS08 DB 0000 Davey070799| 3M 06-Sep-2010 03:02:57 d100904a099 4: MRM of 1 Channel ES- Quantify Sample Report GLP10-01~02-05 screening data Sample Lists Dt\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09*28*22 2010 Method: D:\ma8slynx\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 1 3 i 4 9 i 4 6 2010 Job Code: Printedi Tue Oct 19 16*34*19 2010 Namei dl00904al00 Texts 1: PFBS 2 s PFHS Page 199 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D: \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al00 Text: 7: 13C8 PFOS (IS) GLP10-01 -01 -05-061 DAL SS SS08 0 0005 Davey070799 3M 06-Sep-2010 03:21:04 d100904a100 7: MRM of 1 Channel ES- Page 200 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 0 9 i2 8 i22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al01 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) q u a n tit ^ . iP L ^ ffi^ t' ^ .J O /lS /lO In te rim R e p o rt 0 5 dl Page 201 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D :\masslynx\davey2010.PRO\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al01 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) GLP10-01 -01 -05-062 DAL SS SS09 0 0000 Davey070799 3M 06-Sep-2010 03:39:08 d100904a101 5: MRM of 1 Channel ES- Page 202 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D j\masslynx\davey20l0.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 0 9 28<22 2010 Methodi D<\ma88lynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al02 Text: 1: PFBS 2: PFHS Page 203 4: 1802 PFBS (IS) GLP10-01 -01 -05-063 DAL SS SS09 0 0005 Davey070799 GLP10-01 -01 -05-063 DAL SS SS09 0 0005 Davey070799 3M 06-Sep-2010 03:57:16 3M 06-Sep-2010 03:57:16 d100904a102 100 3: MRM of 2 Channels ES- d100904a102 10.45 230477 TIC 1009.08e4 6: MRM of 1 Channel ES8.68 TIC 207 ` 1.27e3 Area Area %- %- Time n ' 5.00 1 0 .0 0 15.00 5.00 10.00 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:4 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al02 Text: 5: 1802 PFHS (IS) Page 204 6: MPFOS (Surr) GLP10-01 -01 -05-063 DAL SS SS09 0 0005 Davey070799 3M 06-Sep-2010 03:57:16 d100904a102 100 10.50 120 4: MRM of 1 Channel ESTIC 771 : Area % 7 : 13C8 PFOS (IS) GLP10-01-01-05-063 DAL SS SS09 0 0005 Davey070799 3M 06-Sep-2010 03:57:16 d100904a102 100- 10.47 108 7: MRM of 1 Channel ESTIC 794 Area % 5.00 1 0 .0 0 15.00 Time 36 5.00 is -Ab u . . u J 'V q u a n tit3 M In te rim R e p o rt 0 5 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Dt\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 0 9 s2 8 i22 2010 Methods Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49>46 2010 Job Code: Printed: Tue Oct 19 16:34tl9 2010 Names dl00904al03 Text: I s PFBS 2 : PFHS 3 : PFOS 4 : 1802 PFBS (IS ) Page 205 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al03 Text: 7: 13C8 PROS (IS) Page 206 6: MPFOS (Surr) 09004-182 80:20 ACN:H20 3M d100904a 103 100 % 0.14 6.41 3.32 4 -|5 \ ? ' h 5.54 Davey070799 06-Sep-2010 04:15:21 4: MRM of 1 Channel ES- 13.02 TIC 386 16.54 81 Time 5.00 1 0 .0 0 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dlO0904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al04 Text: Page 207 EC-100831-06 5 ng Extracted Curve Point Davey070799 EC-100831-06 5 ng Extracted Curve Point Davey070799 3M 06-Sep-2010 04:33:30 3M 06-Sep-2010 04:33:30 d100904a 104 100- 1: MRM of 2 Channels ES- d100904a104 8.69 TIC 100- 4 8 4 2.71e3 9.61 406 1 2: MRM of 2 Channels ESTIC 2.51 e3 Area Area %- % 5.00 1 0 .0 0 15.00 Time 5.00 -L U -. io!oo 15.00 Time quantit M d S t U d y L P . 1 0 r Q 4 t 2 .1O/18/lO mmh In te rim R e p o rt$ 5 -r-rf P age 941 o f 962 T, ^ Quantify Sample Report GLP10-01-02-0S screening data Sample Lists Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09s28s22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al04 Text: 7s 13C8 PFOS (IS) Page 208 Quantify Sample Report GLP10-01>02-05 screening data Sample Listj Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28t22 2010 Methodi Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49]46 2010 Job Code] Printed: Tue Oct 19 16:34]19 2010 Name: dl00904al05 Text: 1: PFBS 2: PFHS 3: PFOS 4: 1802 PFBS (IS) Page 209 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 0 9 i28s22 2010 Methods Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Codes Printed: Tue Oct 19 16:34:19 2010 Name: d!00904al05 Text: q u a n t i t 3 M l S J U d y P k l ' S r i i l t 0 2 10/18/10 : In te rim .,,R e p o p t 0 5 Page 210 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al06 Text: 1: PFBS 2 : PFHS Page 211 Quantify Sample Report GLP10-01-02-05 screening data Sample List Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09:28:22 2010 Method: D : \masslyxuc\davey2010.PRO\MethDB\dl00904a Last modifiedi Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Namei dl00904al06 Text i 7; 13C8 PFOS (IS) GLP10-01-01 -05-064 DAL SS GP01 0 0000 Davey070799 3M 06-Sep-2010 05:09:44 d100904a106 7: MRM of 1 Channel ES- Page 212 Quantify Sample Report GLP10-01>02-05 screening data Sample List* Di \masslyxuc\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09>28>22 2010 Methodi Di\masslynx\davey2010.PRO\MethDB\dl00904a Last modifiedt Tue Sep 07 13t49i46 2010 Job Codei Printed Tue Oct 19 16i34:19 2010 Name: dl00904al07 Text: 1: PFBS 2: PFHS Page 213 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D :\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D :\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al07 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) Page 214 ' 7: 13C8 PFOS (IS) Quantify Sample Report GLP10*01>02-05 screening data Sample Listt Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedt Tue Sep 07 09t28t22 2010 Methodi Dt\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13t49i46 2010 Job Code: Printed! Tue Oct 19 16i34:19 2010 Namet dl00904al08 Text: 1: PFBS 2: PFHS Page 215 Quantify Sample Report GLP10-01-02-05 screening data Sample Listi D: \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al08 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) GLP10-01-01-05-066 DAL SS GP01 0 0020 Davey070799 3M 06-Sep-2010 05:45:55 d100904a 108 7: MRM of 1 Channel ES- Page 216 Quantify Sample Report GLP10-01-02-05 screening data Sample List * Di\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D \mas slynx\davey2010.PR0\MethDB\dlO0904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al09 Text: 1: PFBS Page 217 2: PFHS GLP10-01 -01 -05-067 DAL SS GP01 0 0060 Davey070799 3M 06-Sep-2010 06:03:58 d100904a109 2: MRM of 2 Channels ES- 3: PFOS 4: 1802 PFBS (IS) >. jl .niF ai -kMT&i Vkit ittU m int t ^i J i ^! P age 951 o f 962 Quantify Sample Report GLP10-01-02-05 screening data Sample List: Di \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09:28:22 2010 Method: D i \masslyxuc\davey2010.P R O \ M ethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code! Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al09 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 218 Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds \masslynx\davey2010.PRO\SampleDB\dlO0904a Last modifiedt Tue Sep 07 0 9 t2 8 i22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13t49i46 2010 Job Codei Printed: Tue Oct 19 16i34il9 2010 Names d!00904all0 Texts 1: PFBS 2s PFHS 3: PFOS 4s 1802 PFBS (IS) GLP10-01 -01 -05-068 DAL SS GP02 0 0000 Davey070799 3M 06-Sep-2010 06:22:03 d100904a110 3: MRM of 2 Channels ES- Page 219 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\mas8lynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Page 220 Name: dl00904a!10 Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) GLP10-01 -01 -05-068 DAL SS GP02 0 0000 Davey070799 GLP10-01-01-05-068 DAL SS GP02 0 0000 Davey070799 3M 06-Sep-2010 06:22:03 3M 06-Sep-2010 06:22:03 d100904a110 100 5: MRM of 1 Channel ES- d100904a110 9.50 137 TIC 100928 10.41 115 4: MRM of 1 Channel ES TIC 820 Area Area %% 7: 13C8 PFOS (IS) 5.00 10.00 15.00 Time 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modifiedi Tue Sep 07 09>28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: printed: Tue Oct 19 16:34:19 2010 Name: dl00904alll Text: 1: PFBS 2: PFHS Page 221 4: 1802 PFBS (IS) GLP10-01 -01 -05-069 DAL SS GP02 0 0005 Davey070799l GLP10-01-01-05-069 DAL SS GP02 0 0005 Davey070799 3M 06-Sep-2010 06:40:14 3M 06-Sep-2010 06:40:14 d100904a 111 100- 10.36 5451' 3: MRM of 2 Channels ES-I d100904a111 t ic ; 2.28e4| 1 0 0 - 6: MRM of 1 Channel ES8.50 TIC 192 1.17e3 Areai Area %- % 5.00 '1 0 .0 0 15.00 T im e i - 2 5 5.00 1 0 .0 0 15.00 Time Quantify Sample Report GLP10-01-02-05 screening data Sample Lists Ds\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 09t28s22 2010 Methods D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904alll Text: 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) GLP10-01 -01 -05-069 DAL SS GP02 0 0005 Davey070799 3M 06-Sep-2010 06:40:14 d100904a111 100- 10.37 92 7: MRM of 1 Channel ES- TIC 702 Area % 42-c V ~x, 5.00 3M . S tu d y G L P 1 0 -0 1 -0 2 g u a n t i t i n t ^ j m 7w i : 1'->i'W^nBr i n t e ^ 1 0 / 1 8 / 1 0 nmh 1 0 .0 0 15.00 T -. T im e Page 222 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D : \masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Name: dl00904all2 Text: 1: PFBS 2: PFHS Page 223 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslyax\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904all2 Text: Page 224 P age 9 5 8 'o f 9 62 4i J fa f r . s i i & `g A V * A a- Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Me thod: D :\mas slynx\davey2010.PR0\Me thDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904al!3 Text: 1: PFBS 2: PFHS Page 225 4: 1802 PFBS (IS) EC-100831-07 10 ng Extracted Curve Point Davey070799 EC-100831-07 10 ng Extracted Curve 3M 06-Sep-2010 07:16:28 3M d100904a 113 100- 10.50 660 ~ 3: MRM of 2 Channels ES- d100904a113 TIC 100 3.53e3 Area 8.64 1721 Point Davey070799 06-Sep-2010 07:16:28 6: MRM of 1 Channel ES- ne 1.11e3 Area %% quantit 5.00 0G aLnPd1.p0r-i0n1t-e0d2^10/18/10 mmh e p o rt 0 5 ' A 1'. i iU . ___________________ Time 1 0 .0 0 15.00 M 1 0 .0 0 15.00 Time P a g e 9 5 9 ' o f `'9 6 2 1 '.1 i Quantify Sample Report GLP10-01-02-05 screening data Sample List D : \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904all3 Text: 5: 1802 PFHS (IS) Page 226 6: MPFOS (Surr) EC-100831-07 10 ng Extracted Curve Point Davey070799 3M 06-Sep-2010 07:16:28 d100904a113 100 10.50 206 " 4: MRM of 1 Channel ESne 1.28e3 Area % 24 7: 13C8 PFOS (IS) ____________________________________________________________________________ ______ EC-100831-07 10 ng Extracted Curve Point Davey070799 3M 06-Sep-2010 07:16:28 d100904a113 100 10.47 113 7: MRM of 1 Channel ESTIC 835 Area 5.00 i 1 0 .0 0 15.00 Time % .Vn A ' - 'vz-v, V. 37 Time 5.00 1 0 .0 0 15.00 Quantify Sample Report GLP10-01-02-05 screening data Sample List: D:\masslynx\davey2010.PRO\SampleDB\dl00904a Last modified: Tue Sep 07 09:28:22 2010 Method: D:\masslynx\davey2010.PRO\MethDB\dl00904a Last modified: Tue Sep 07 13:49:46 2010 Job Code: Printed: Tue Oct 19 16:34:19 2010 Name: dl00904all4 Text: 1: PFBS 2: PFHS Page 227 3 : PFOS 4: 1802 PFBS (IS) 09004-182 80:20 ACN:H20 3M d100904a 114 Davey070799 06-Sep-2010 07:34:35 6: MRM of 1 Channel ES- Quantify Sample Report GLP10-01-02-05 screening data Sample Listi Di \masslynx\davey2010.PRO\SampleDB\dl00904a Last modified! Tue Sep 07 Q9i28i22 2010 Methodi DI\masslynx\davey2010.PRO\MethDB\dl00904a Last modified! Tue Sep 07 13i49:46 2010 Job Code : Printed: Tue Oct 19 16:34:19 2010 Namei dl00904all4 Text! 5: 1802 PFHS (IS) 6: MPFOS (Surr) 7: 13C8 PFOS (IS) Page 228