Document 3N9xZ5dMdXqKn0vxgEKqog340

~TVb .1^ MAI4I4 O/MpOMfr Chtesfto. Illinois 60636 * 7300 South Central Awm* 313 767-4600 Memphis Tsnnsssss 36113 . 9.0. Bon 13303 901 - 648*6663 stow, Ohio 44224.4460 Hudson 0r<VS * 216 - 926-6311 Tortsnc*, C'rfoml 90603 444 Ai***s Av*nus < 213 - 776*6666 TECHNICAL KATA PARAPLEX G-25 ^Polyester Sebacatfe Specifications Property Test Method Acid Value, mg KOH/g Appearance AOCS Cd 3a-63 Visual Color, Gardner 1963 Moisture, wt. percent Refractive Index @25C Viscosity 625C, Gardner Holt tx' 3> ASTM D-1544 ASTM E-203 ASTM D-1045 ASTM 154-73 Limits 2.0 Maximum Clear to Slightly Opalescent 4 Maximum 0.1 Maximum 1.4662-1.4697 R-U Typical Properties Property Test Method Values Acid Value, mg KOH/g Appearance Color, Gardner 1963 <x) Flash Point, F Freezing Point, F Moisture, wt. percent Refractive Index @25C Saponification Value Specific Gravity @25C/25C . Viscosity @25C, CPS Viscosity @25C, Gardner Holt <:L' 3> AOCS Cd 3a-63 Visual ASTM D-1544 ASTM D-92 CPH Method ASTM E-203 ASTM D-1045 AOCS Cd 3-25 CPH Method .. ASTM D-2849 ASTM 154-73 1.5 Clear 2 600 12 0.05 1.4680 457 1.06 160,000 S-T <x> Measured as a 50% solution in Ethylene Dichloride Meets the requirements of ASTM D-154-73; D-555-70; D-1131-53(1970); D-1545-63(1970); D-1725-62(1970); FTMS 141a.Method4271; AOCS Ka 6-63 00 0866?? ( CONFTDFNTTAI.. PARAPLEX is a registered trademark of The C. P. Hall Company. Thu technical information and uuffoutlenu for mi contained horaln arc baliavad to ba roliablo. but th]r ara not to bo eonttruod a* warrantloo and no patent liability can bo aftumod. Compatibility of Paraplex G-25 with Plastics Compatibility Plastic/Plasticizer Plastic 9/1 3/1 1/1 Polyvinyl Chloride Nitrocellulose Ethyl Cellulose Cellulose Acetate Cellulose Acetate Propionate Cellulose Acetate Butyrate Polyvinyl Acetate Polyvinyl Butyral Chlorinated Rubber Nitrile Rubber CC C Cc c III III c- c- c- III cI I III cc c cI Key: C c I Compatible Slight Incompatibility Incompatible REV. V 08/17/88 DO 0866?3 CONFIDENTIAL MATERIAL SAFETY DATA SHEET ************************** The C.P. Hall Comp ny 7300 S. Central Avenue, Chicago, IL 60638 Emergency Telephone No: 312/458-2367 SECTION I Chemical Name:^Polyester Sebacate ' Plasticiser Product Name: PARAPLEX G-25 Chemical Family: Polyester Formula: Proprietary HMIS Number: 110 Gloves & Safety Goggles SECTION II - HAZARDOUS INGREDIENTS None SECTION III - PHYSICAL DATA Boiling Point (F): Vapor Pressure: @25C Vapor Density: (Air=l) Solubility in Water: >600 0.01 25 Negligible Specific Gravity: 1.06 (HaO=l at 25/25C) % Volatile by Vol: Nil Evaporation Rate: 0.1 (But. Ace. = 1) Appearance & Odor: Amber colored, viscous liquid; mild odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 600F (C.O.C.) Extinguishing Media: CO2, Dry Chemical, Water Fog, Foam Flammability Limits: Not available Special Fire Fighting Procedures: Wear MESA/NIOSH approved selfContained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid in contact with the eyes will cause a mild irritation. Prolonged or repeated skin contact may cause an irritation. Emergency & First Aid Procedures and Routes of Entry: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation presists. Wash affected skin areas with soap and water. N/A = NOT AVAILABLE DO 006624 OONFIDFNTTAL Product Nam : PARAPLEXf) G-25 SECTION VI - REACTIVITY DATA Stability Unstable: Conditions to Avoid: Not Available Stable: X Incompatibility (Materials to Avoid): Strong oxidizing agents. Hazardous Decomposition Products: None under normal use conditions; oxides of carbon when burned. Hazardous Polymerization May Occur: Conditions to Avoid: Will Not Occur: X Not Available SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dik and contain spill with inert material (sand, earth, fuller's earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reuse. Wash affected skin areas with soap and water. Keep spills out of all sewers and open bodies of water. Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulation. SECTION VIII- SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): None required for normal operations. Ventilation Local Exhaust: Normal room ventilation Mechanical (General): Special: Other: Protective Gloves: Impervious Eye Protection: Splash goggles (ANSI Z87.1,1968) Other Protective Equipment: Impervious Apron Eyewash facility SECTION IX ~ SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: For easier pumping store up to 130F, otherwise store at room temperature. Other Precautions: None Revision Date: 6/89 JTH 3739 Supersedes: 6/88 JTH DO 086625 CONFTDFNTTAl CODE NO. DATE __ IS.'1-82- SAFETY DATA SHEET DISTRIBUTION RECORD COPIES _SEN_T TO: AKRON W. C. 3achte1 AVON LAKE GENERAL CHEMICAL R. A. Conc'neck 3. Krupp M. Jarnevic AVON LAKE TECHNICAL CENTER R. D. Hardesty CLEVELAND OFFICE H. Waltemate 3. 3odamer LONG BEACH R. Vanko E. Clifford LOUISVILLE A. Simpson PEDRICKTQWN 0. W. Goetsch HENRY A. W. Otto PLcASE NOTE: The attached MSDS sheet is either I *.s\ ai revision of an existing sheet or [ I a new MSDS sheet. If this is a revised sheet, please use this sheet to replace the MSDS you now have on file. If you have any questions, please contact me. C. V. Purks 0590R/pl j DO 086626 CONFIDENTIAL V r U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration Form Approved OMB No. 44-R13S7 MATERIAL SAFETY DATA SHEE^ A8/ Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION 1 . MANUFACTURER'S NAME TIJE C. P. HALL COMPANY EMERGENCY TELEPHONE NO. 312-767-4605 ADDRESS (Number, Street, CUy, State, and ZIP Code). ___ 7300 S. Central Avenue, Chicago, IL 60638 CHEMICAL NAME AND SYNONYMS , Polyester Plasticizer CHEMICAL FAMILY Plasticizer TRAOE NAME AND SYNONYMS ,, PARAPLEXW G-57 FORMULA _Pro. pr,ie.tary SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES. & SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS PIGMENTS BASE METAL CATALYST ALLOYS VEHICLE SOLVENTS ADDITIVES OTHERS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES TLV % (Unltsl TLV X (Units) SECTION III PHYSICAL DATA BOILING POINT ("P., VAPOR PRESSURE (mm Hg.) VAPOR density (a,Rij SOLUBILITY IN WATER Above : 00F BelOW 1mm Heavier ti an air JJeC ligi'ble SPECIFIC GRAVITY (HjO-l) PERCENT, VOLATILE BY VOLUME <%) E(BVAuPOt.RATAIOcNeR. A.T1E) 1.10 0 Neg. .igible appearance and odor to yellow viscous liquid; mild inoffensive odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) COC 530F FLAMMABLE LIMITS EXTINGUISHING MEDIA CO?, Dry Chemical, Wager Fog SPECIAL FIRE FIGHTING PROCEDURES Wear MESA/NIOSH approved self-contained breathing Use water spray to cool fire-exposed containers. L*l apparatus U*l (Sch. 13 UWNUaSUteArL fmireayancdaEuXPsLeOSIfOrNoHtAhZAi.nRDgS . DO 086627 rnMPinPMTTAi PAGE (1) (Continued on reverse side) Form OSHA-20 SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VAt_UE Not determined by the ACGIH, EFFECTS OF OVEREXPOSURE ... , L , ,. . Liquid may cause eye irritation and repeated or prolonged skin conta may cause an irritation. emergency and first aid procedures Inhalation: Move subject to fresh air\ Eya and Skin 15 mins, and Contact: Flush eyes consult a physician with large amts., of water fpr at. St if irritation persists. Wash affects.a -9kin--roas with ooap and water.-----.----------------------------------------------------------- SECTION VI REACTIVITY DATA STABILITY UNSTABLE STABLE incom patAbi li*i y (Muterials to avoid) CONDITIONS TO AVOID X hazardous decomposition products None under normal use conditions; HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR X oxides of carbon when burned. CONDITIONS TO AVOID SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Dike and contain spill with inert material (sand, earth, fuller's earth, etc.) and transfer liquid and solid diking material to separa :e containers for recovery or disposal. Bprnnvp rontaTni nat^d clothing__ and wash before reuse. Wash affected skin areas with water. Keep spill rmt nf ell__ gpwers snd npen hndies nf water--------------------------------------------------------------------------- Incinerate liquid m approved equipment. Landfill contaminated diking material, according to current local, state and federal regulat-ion-SH-------------------------------------------------------------- ------------------------------------------------- SECTION VIM - SPECIAL PROTECTION INFORMATION respiratory protection (Specify type) None^reauired for normal operations.,,____________________________ _____ ________ VENTILATION LOCAL EXHAUST Normal room ventilation SPECIAL MECHANICAL (General) OTHER PROTECTIVE GLOVES ImperviOUS OTHER PROTECTIVE EQUIPMENT Eyewash facility EYE PROTECTION Splash qoqqles (ANSI Z87.1, 1968) SECTION IX * SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Recommend storage at 60-80F for easier handlmq. OTHER PRECAUTIONS DO -- oonftdfntiai PAGE (2) CFO 930 . 340 Form OSHA-20 Rav. May 71 IVt/ ].l* HAIalj Q/mtyoMifr Ch-cifO, lihnof 60638 . 7300 South Cfntnl AvfDi*t <312- 767*4600 Mn>pht*. Ten****** 361 13 P O Box 13303 * 901 946-6663 Stow, Ohio 44224 . 4460 Hudson Dnvl * 216 - 929*831 1 Ton-one*. California QQ503.444 a***m* Av*nu * 213 * 776-6666 TECHNICAL KATA PLASTHALL P-7046 Polyester Glutarate Specifications Property Acid Value, mg KOH/g Appearance Color, Gardner 1963 Moisture, wt. percent Refractive Index @25 C Specific Gravity @25C/25C Viscosity @25C, CPS Typical Properties Property Acid Value, mg KOH/g Appearance Color, Gardner 1963 Flash Point, F Freezing Point, F Moisture, wt. percent Refractive Index @25C Saponification Value Specific Gravity @25C/25C Viscosity @25C, CPS Viscosity @25c TBR REV II 08-24-88 Test Method AOCS Cd 3a-63 Visual ASTM D-1544 ASTM E-203 ASTM D-1045 CPH Method ASTM D-2849 Test Method AOCS Cd 3a-63 Visual ASTM D-1544 ASTM D-92 CPH Method ASTM E-203 ASTM D-1045 AOCS Cd 3-25 CPH Method ASTM D-2849 ASTM D-1545 Limits 3.0 Maximum Clear to Slightly Opalescent 6 Maximum 0,1 Maximum 1.4652-1.4676 1.1005-1.1116 9,000-14,000 Values 1.0 Clear 3 510 -25 0.05 1.4663 538 1.1060 11,500 95 0866P9 CONFTOFNTTAL PLASTHALL is a registered trademark of The C. P. Hall Company. The technic*! information and suggestions for us* contained herein are believed to be reliable, but they are not to be construed as warranties and no patent liability can be assumed. s W I T C 0 MATERIAL SAFETY DRAPEX 429 <! CAS NO:63149-79-l NFPA HAZARD RATING 4 - Extreme 3 - High 2 - Moderate 1 - Slight 0 - Insignificant DATA F i re SHEET PAGE 1 Reactivity HMIS HAZARD INDEX Hazardous 4 - Severe Materials 3 - Serious Identification 2 - Moderate System 1 - Slight 0 - Minimal HMIS RATINGS Health............................................. 0 Flammability...............................1 Reactivity................................... 0 Personal protection........... B* *See last page for Code Table. DIVISION AND LOCATION-----SECTION I Division: ARGUS Location: BROOKLYN, NY 633 COURT ST.,BROOKLYN,NY,11231*2193 Emergency Telephone Number: 718-858-5678 Transportation Emergency: CHEMTREC 1 -(800) 424*9300 (U.S. and Canada) CHEMICAL AND PHYSICAL PROPERTIES-----SECTION II Chemical Name: &*' Polyester of adipic acid Formula: 99% polyester Hazardous Decomposition Products: none Incompatibility (Keep away froml: strong oxidizers such as hydrogen peroxide, bromine, and chromic acid. Toxic and Hazardous Ingredients: none Form: liquid Odor: mild Appearance: clear,oily Color: pale yellow Specific Gravity (water=li: 1.09 Boiling Point: not distillable Melting Point: pour point -18'C (0F) Solubility in Water (by weight %i : negligible at 25 eC Volatile fbv weight %) : not applicable Evaporation Rate: (butyl acetate = 1) 1 ess than 1 Vapor Pressure (mm Hg at 20C): less than .1 Vapor Density (air=li: not applicable pH (as is) : not applicable stability: Product is stable under normal conditions Viscosity SUS at 1QQF: Greater than or = to 100 (Continued on next page) DO 086630 CONFIDENTIAL DRAPEX 429 PAGE 2 FIRE AND EXPLOSION DATA-----SECTION III Special Fire Fighting Procedures: Wear self-contained breathing apparatus in confined spaces. Unusual Fire and Explosion Hazards: none Flashpoint: (Method Used) Cleveland open cup 288"C (550*F) Flammable limits %: no data available Extinguishing agents: Drychemical or Waterspray or Waterfog or CO2 or Foam or Sand/Earth Closed containers exposed to fire may be cooled with water. HEALTH HAZARD DATA-----SECTION IV Permissible concentrations (airi: not applicable Chronic effects of overexposure: no data available Acute toxicological properties: slightly irritating to rabbit eyes practically non-irritating to rabbit skin Emergency First Aid Procedures: Eves: Immediately flush with large quantities of water for at least 15 minutes and call a physician. Skin Contact: Wash with soap and water. Inhalation: Remove victim to fresh air. If Swallowed: Contact a physician immediately. SPECIAL PROTECTION INFORMATION-----SECTION V Ventilation Type Required (Local.mechanical.special!: local Respiratory Protection (Specify tvpel: none Protective Gloves: vinyl or neoprene Eve Protection: chemical safety goggles Other Protective Equipment: none HANDLING OF SPILLS OR LEAKS-----SECTION VI Procedures for Clean-Up: Wear protective clothing and equipment during cleanup. Absorb spills on an inert (Continued on next page) DO 086601 CONFIDENTIAL DRAPEX 429 PAGE 3 (Section VI continued) material such as earth, sand or vermiculite; sweep up and dispose of in accordance with federal, state and local regulations. Waste Disposal: Controlled incineration or landfill subject to applicable federal, state and local regulations. SPECIAL PRECAUTIONS-----SECTION VII Precautions to be taken in handling and storage: Do not store near strong oxidizing agents. Keep container closed until ready for use. TRANSPORTATION DATA-----SECTION VIII D.0.T. : Not Regulated Reportable Quantity: not applicable Freight Classification: Resin Plasticizer ST C 2818967 Special Transportation Notes: ENVIRONMENTAL/SAFETY REGULATIONS-----SECTION IX Section 313 (Title III Superfund Amendment and Reauthorization Act): This product does not contain any chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Signature: Otto Kauder Title: Vice President, Technical Original Date: 05/30/84 Sent to: Revision Date: 08/07/89 _____ Supersedes : 01/02/86 _____ Date Sent_____: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, express or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. (Continued on next page) OO 086632 CONFIDENTTAI WITCO DRAPEX 429 MATERIAL SAFETY DATA SHEET PAGE 4 ************************************************************************* * LETTER DESIGNATIONS OF PERSONAL PROTECTIVE EQUIPMENT * * Safety Glasses..............................................................................................................A * * Safety Glasses, Gloves..............................................................................................B * * Safety Glasses, Gloves, Synthetic Apron...........................................................C * * Face Shield, Gloves, Synthetic Apron.................................................................D * * Safety Glasses, Gloves, Dust Respirator...........................................................E * * Safety Glasses, Gloves, Synthetic Apron, Dust Respirator....................... F * * Safety Glasses, Gloves, Vapor Respirator........................................................ G * * Splash Goggles, Gloves, Synthetic Apron, Vapor Respirator..................... H * * Safety Glasses, Gloves, Combination Dust and Vapor Respirator............. I * * Splash Goggles, Gloves, Synthetic Apron, Combination Dust and ........... * * Vapor Respirator.............J * * Airline Hood or Mask, Gloves, Full Protective Suit, Boots.....................K * ** **S*i*tu*a**ti*o*n*s***R*e*q*u**ir*in*g***S*p*e*c*i*a*l*iz*e*d***H*a*n*d**li*n*g*..*..*..*..*..*..*..*..*..*..*...*..*..*..*..*..*..*..*..*..*..*..*..*...*..*..*X**** co^ ( "TIu/ C. R IIAIiL ComjxMtjj, TECHKIGAL Chic0. mtooift 60638 7300 South Central Avwut >12 767-40* Mtmphll, T*noaft# 30113 P O Box 13303 * 001 * 040-0003 stow, onto 04224.4460 Hudson Ofiv . 210 020*0311 KATA Torrooco. CHtfornt* 00503.444 Alak Avsnu* * 213 * 775-0000 PARAPLEX G-51 ^-PolyestferAdipate Specifications Property Acid Value, mg KOH/g Appearance Color, Gardner 1963 Moisture, wt. percent Refractive Index @25C Viscosity @25C, TBR sec. Test Method AOCS Cd 3a-63 Visual ASTM D-1544 ASTM E-203 ASTM D-1045 ASTM D-1545 Typical Properties Property Acid Value, mg KOH/g Appearance Color, Gardner 1963 Flash Point, F Freezing Point, F Moisture, wt. percent Refractive Index @25C Saponification Value Specific Gravity @25C/25C Viscosity @25C, CPS Viscosity @25C, TBR sec. Test Method AOCS Cd 3a-63 Visual ASTM D-1544 ASTM D-92 CPH Method ASTM E-203 ASTM D-1045 AOCS Cd 3-25 CPH Method ASTM D-2849 ASTM D-1545 Limits 2.5 Maximum Clear 3 Maximum 0.1 Maximum 1.4626-1.4659 20 - 28 Values 1.5 Clear 1 550 -24 0.05 1.4643 541 1.1000 3,000 24 00 086634 confidential PARAPLEX is a registered trademark of The C. P. Hall Company. The technical Information and tufieatlont for uaa contained karoin aro believed to bo reliable, but they are net to bo conatrued ai warrantiei and no patent liability can be aaaumed. Compatibility of Faraplex G-51 with Plastics Compatibility Plastic/Plasticizer Plastic IZIi/ll/l Polyvinyl Chloride Nitrocellulose Ethyl Cellulose Cellulose Acetate Cellulose Acetate Propionate Cellulose Acetate Butyrate Polyvinyl Acetate Polyvinyl Butyral Chlorinated Rubber Nitrile Rubber CC C CC C CI I III C- C- C CC C CC I III CC C cc I-C Key: C C I Compatible Slight Incompatibility Incompatible REV. Ill 9/21/88 DO 086635 CONFIDENTIAL Tkt' C. R HALL C&utyaMjfr | * C 60430.7300 SOOth Central Avtnu* *312- 707*4000 . oMemphis, Tennessee 36113 P Bok 13309 * BOl 040-0663 tow. Ohto 44224.4400 Hudson Dftv* * 216 - 920-631 1 orranee. California 0QO* * aaa **** Avarua 213 * 775-0000 i 0 1 TECHHICAl. rvn PLASTHALL P-670 Polyester Adipate Specifications Property Acid Value, mg KOH/g Appearance Color, APHA Moisture, wt. percent Refractive Index @25C Specific Gravity @25C Viscosity @25C, CPS Typical Properties Property Acid Value, mg KOH/g Appearance Color, APHA Flash Point, F Freezing Point, F Moisture, wt. percent Refractive Index 25C Saponification Value Specific Gravity @25C Viscosity 625C, CPS C Test Method AOCS Cd 3a-63 Visual ASTM D-1209 ASTM E-203 ASTM D-1045 CPH Method ASTM D-2849 Test Method AOCS Cd 3a-6 3 Visual ASTM D-1209 ASTM D-92 CPH Method ASTM E-203 ASTM D-1045 AOCS Cd 3-25 CPH Method ASTM D-2849 Limits 2.0 Maximum Clear 200 Maximum 0.1 Maximum 1.4624-1.4662 1.0720-1.0862 1000-1500 Values 0.5 Clear 100 510 -45 0.05 1.4643 506 1.0791 1250 REV IV 10/10/89 CDOONF0l 8o0f0^3T^1PA- PLASTHALL is a registered trademark of The C. P. Hall Company. rssaviBbw The technical information and sugiestions for us* contained herein are believed to be reliable, but they are not to be construed as warranties and no patent liability can be assumed. ------ MATERIAL SAFETY DATA SHEET The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Information 708/594-6000 Emergency 708/594-5999 SECTION I Product Name: PLASTHALL P --7046 Chemical Name: Polyester Glutarate Chemical Family: Polyester HMIS Number: SECTION II - COMPONENTS 110 Gloves & Safety Goggles PLASTHALL P-7046 NJEIN: 8009285023 SECTION III - PHYSICAL DATA Boiling Point (F): Vapor Pressure: Vapor Density: Solubility in Water: N/A N/A N/A Insoluble Specific Gravity: 1.1060 (HaO=l at 25/25C) % Volatile by Vol: Nil Evaporation Rate: N/A Appearance & Odor: Viscous light colored liquid; very slight odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 510F (C.O.C.) Extinguishing Media: CO2, Dry Chemical, Water Fog Flammability Limits: Not available Special Fire Fighting Procedures: Wear MESA/NIOSH approved s lf- contained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation. Emergency & First Aid Procedures and Routes of Entry: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. Wash affected skin areas with soap and water. N/A = NOT AVAILABLE DO 086637 CONFIDENTIAL Product Nam : PLASTHALL -- 7046 SECTION VI - REACTIVITY DATA Stability Unstable: Conditions to Avoid: Not Available Stable: X Incompatibility (Materials to Avoid): Strong oxidizing agents Hazardous Decomposition Products: None under normal use conditions; oxides of carbon when burned. Hazardous Polymerization May Occur: Conditions to Avoid: Not Available Will Not Occur: X SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dik and contain spill with inert material (sand, earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reuse. Wash affected skin areas with soap and water. Keep spill out of all sewers and open bodies of water. Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulations. SECTION VIII- SPECIAL PROTECTION INFORMATION Respiratory Protection: None required for normal operations. Ventilation Local Exhaust: Normal room ventilation Special: Mechanical (General): Other: Protective Gloves: Impervious Eye Protection: Splash goggles (ANSI 287.1,1968) Other Protective Equipment: Eyewash facility. Impervious apron SECTION IX - SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: Avoid open flames, excessive heat. Other Precautions: None Revision Date: 3/90 JTH 7046 Supersedes: 8/89 JTH DO 006630 conftofNttai MATERIAL SAFETY 3DATA SHEET The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Information 708/594-6000 Emergency 708/594-5999 SECTION I Product Name: PLASTHALL 4141 Chemical Name: Triethylene Glycol Caprate Caprylate Chemical Family: Diester HMIS Number: 110 Gloves & Safety Goggles SECTION II - COMPONENTS_______________________________________ ____ Triethylene Glycol Caprate Caprylate CAS# 68130-48-3 SECTION III - PHYSICAL DATA Boiling Point (F): Vapor Pressure: Vapor Density: Solubility in Water: 392-510 N/A N/A None Specific Gravity: 0.970 (H20=1 at 25/25*0 % Volatile by Vol: Nil Evaporation Rate: N/A Appearance & Odor: Clear liquid. mild fatty odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA. Flash Point (Method used): 400F (C.O.C.) Extinguishing Media: CO2, Dry Chemical, Water Fog Flammability Limits: Not available Special Fire Fighting Procedures: Wear MESA/NIOSH approved selfcontained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Solid streams of water dir cted at burning liquid may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation. Emergency & First Aid Procedures and Routes of Entry: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. Wash affected skin areas with soap and water. (continued) 086639 CONFIDENT TAI., Product Name: PLASTHALL 4141 SECTION VI - REACTIVITY DATA Stability Unstable: Stable: X Hazardous Polymerization May Occur: Will Not Occur: X Incompatibility (Materials to Avoid): Oxidizers. Conditions to Avoid: N/A Hazardous Decomposition Products: None under normal use conditions, oxides of carbon when burned. SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dik and contain spill with inert material (sand, earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reus . Wash affected skin areas with soap and water. Keep spill out of all sewers and open bodies of water. Waste Disposal Method: Landfill or incinerate liquid and/or contaminated diking material according to current local, state and federal regulations. SECTION VIII- SPECIAL PROTECTION INFORMATION Respiratory Protection: Use an appropriate NIOSH approved respirator if handling is likely to generate vapors or mists. Ventilation Local Exhaust recommended when handling generates mist or vapor. Protective Gloves: Neoprene or Viton Eye Protection: Splash goggles (ANSI Z87.1,1968) Other Protective Equipment: Eyewash facility, Impervious apron SECTION IX - SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: Normal precautions common to good manufacturing practice should be used in handling and storage. Other Precautions: Any use of this product in elevated temperatur processes should be evaluated to establish and maintain safe operating procedures. Revision Date: 9/90 JTH 3556 Supersedes: 5/88 JTH DO 086640 CONFIDENTIAL. M**A*T*E*R*IA**L**S*A*F*E*TY***D*A*T*A**S*H*E*E*T The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Emergency Telephone No: 312/767-4605 ______________________SECTION I ________ Chemical Name: Polyester Plasticizer Product Name: PLASTHALL 7068 Chemical Family: Plasticizer Formula: Proprietary HMIS Number: 110 Gloves & Safety Goggles SECTION II - HAZARDOUS INGREDIENTS___ None SECTION III - PHYSICAL DATA Boiling Point (F): Vapor Pressure: Vapor Density: Solubility in Water: >300 N/A N/A Negligible Specific Gravity: 1.03 (HaO--1 at 25/25C) % Volatile by Vol: Nil Evaporation Rate: Negligible (But. Ace. = 1) Appearance & Odor: Lt. yellow viscous liquid; mild inoffensive odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 470F (C.O.C.) Extinguishing Media: Foam, C02, Dry Chemical, Water Fog Flammability Limits: Not Available Special Fire Fighting Procedures: Wear self contained breathing apparatus MESA/NIOSH approval (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid contact with eyes may cause irritation. Repeated or prolonged skin contact may cause irritation. Emergency & First Aid Procedures: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of watdY for 5 minutes. Consult a physician if irritation persists. Wash affected skin areas with soap and water. N/A = NOT AVAILABLE 1 00 086641 CONFIDENTTAI Product Name: PLASTHALL 7068 SECTION VI - REACTIVITY DATA Stability Unstable: Conditions to Avoid: Not Available Stable: X Incompatibility (Materials to Avoid): Hazardous Decomposition Products: None under normal use conditions; oxides of carbon when involved in a fire. Hazardous Polymerization May Occur: Conditions to Avoid: Not Available Will Not Occur: X SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dike and contain spill with inert material (sand, earth, fuller's earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Remove contaminated clothing and wash before reuse. Wash affected skin areas with water. Keep spill out of all sewers and open bodies of water. Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): None required for normal operations. Ventilation Local Exhaust: Normal room ventilation Mechanical (General): Special: Other: Protective Gloves: Impervious Eye Protection: Splash Goggles Other Protective Equipment: Eyewash facility (ANSI Z87.1, 1968) SECTION IX - SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: Satisfactory to store in stainless steel and aluminum. Other Precautions: Store above 50F for easier handling. Do not store above 100F for long periods. Revision Date: 8/86 JTH 3544 Supersedes: 00 086642 CONFIDENTIAL 2 M**A*T*E*R*I*A*L**S*A*F*E*T*Y**D*A*T*A**S*H*E*E*T The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Emergency Telephone No: 312/458-2367 __________________SECTION I_________________________ Chemical Name: Butoxyethoxyethyl Product Name: PLASTHALL 83SS ester of mixed dibasic acids Chemical Family: Ester Formula: Proprietary HMIS Number: 110 Gloves & Safety Goggles SECTION II - HAZARDOUS INGREDIENTS None SECTION III - PHYSICAL DATA Boiling Point (F): Vapor Pressure: Vapor Density: Solubility in Water: N/A N/A N/A @10% Specific Gravity: 0.990 (H20=1 at 25/25C) % Volatile by Vol: 10 Evaporation Rate: N/A (But. Ace.=l) Appearance & Odor: Clear amber liquid, alcohol odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 285F (C.O.C.) Extinguishing Media: CO2, Dry Chemical, Water Fog Flammability Limits: Not available Special Fire Fighting Procedures: Wear MESA/NIOSH approved self- contained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation. Emergency & First Aid Procedures and Routes of Entry: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. Wash affected skins areas with soap and water. N/A = NOT AVAILABLE CONFIDENTIAL Product Name: PLASTHALL 83SS r. SECTION VI - REACTlVlftY DATA Stability Unstable: Stable: X Conditions to Avoid: Not Available . -- Incompatibility (Materials to Avoid): Strong oxidizing agents Hazardous Decomposition Products: None under normal use conditions; oxides of carbon when burned. Hazardous Polymerization May Occur: Conditions to Avoid: Not Available Will Not Occur: X SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reuse. Wash affected skin areas with soap and water. Keep spill out of all sewers and open bodies of water. Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulations. SECTION VIII- SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): None required for normal operations. Ventilation Local Exhaust: Normal room ventilation Special: Mechanical (General): Other: Protective Gloves: Impervious Eye Protection: Splash goggles (ANSI Z87.1,1968) Other Protective Equipment: Eyewash facility Impervious apron SECTION IX - SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: Avoid open flames, excessive heat. Other Precautions: None Revision Date: 5/88 JTH 3578 Supersedes: 4/87 JTH DO 086644 CONFIDENTIAL. MATERIAI, SAFETY DATA SHEET Th C.P. Hall Company 7300 S. Central Avenu , Chicago, IL 60638 Information 708/594-6000 Emergency 708/594-5999 SECTION I Product Name: PLASTHALL DOZ Chemical Name: Di(2-ethylhexyl) Azelate Chemical Family: Ester HMIS Number: 110 Gloves & Safety Goggles SECTION II - COMPONENTS Di(2-ethylhexyl) Azelate CAS# 103-24-2 SECTION III - PHYSICAL DATA Boiling Point (C) @5mmHg: 237 Vapor Pressure: #150*C 0.1 Vapor Density: N/A solubility in Water: N/A Specific Gravity: (H20=1 at 25/25C) % Volatile by Vol: Evaporation Rate: 0.917 Nil N/A Appearance & Odor: Colorless, mild odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 415F (C.O.C.) Extinguishing Media: co2. Dry Chemical, Water Fog Flammability Limits: Not available Special Fire Fighting Procedures: Wear MESA/NIOSH approved selfcontained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation. Emergency & First Aid Procedures and Routes of Entry: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. Wash affected skin areas with soap and water. N/A = NOT AVAILABLE nO 08&M5 C onftdential Product Nam : PLASTHALL DOZ SECTION VI - REACTIVITY DATA stability Unstable: Conditions to Avoid: Not Available Stable: X Incompatibility (Materials to Avoid): Strong oxidizing agents Hazardous Decomposition Products: Thermal decomposition may yield oxides of carbon. Hazardous Polymerization May Occur: Conditions to Avoid: Not Available Will Not Occur: X SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dike and contain spill with inert material (sand, earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reuse. Wash affected skin areas with soap and water. Keep spill out of all sewers and open bodies of water. Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulations. SECTION VIII- SPECIAL PROTECTION INFORMATION Respiratory Protection: None required for normal operations. Ventilation Local Exhaust: Normal room ventilation Special: Mechanical (General): Other: Protective Gloves: Impervious Eye Protection: Splash goggles (ANSI Z87.1,1968) Other Protective Equipment: Eyewash facility Impervious apron SECTION IX - SPECIAL PRECAUTIONS _______________________________ Precautions To Be Taken In Handling And storing: Satisfactory to store in stainless steel. Other Precautions: None Revision Date: 3/90 JTH 6555 Supersedes: 10/89 JTH rmr-086646 Co^tofNttai HERCULES INCORPORATED Hercules Plaza Wilmington, Delaware, 19894 MATERIAL SAFETY DATA SHEET Phone Number: (302) 594-5000 (all hours) MSDS No.: 866 2001 1300-1 Date: 12/27/85 Page: 1 of 3 1. PHODUCT mfcHlinCATlON ------- CAUTION' FLAMMABLE DUST WHEN FINELY OIVIDED AND SUSPENDED IN AIR. PICCO 6100 Hydrocarbon resin Polymerized C7 to C, aromatic monomer CAS Number: [68240-01-7] HMIS* Health hazard: Flanmability hazard: Reactivity hazard: Rating 0 Minimal 1 Slight 0 Minimal Appearance and odor: Amber-colored solid or flake; typical hydrocarbon odor 11. HA/AK1)(HI5~'1NGRED1EN1!> & EXPOSURE'LIMIT? Chemical & Common Names of Hazardous Inaredients ----------- X Recommended Air-borne levels -------- TLV*-TwA 1985-86--------- Petroleum hydrocarbon oil [64742-52-5] [64741-88-4] - 12 5 mg/m3 If these materials are used in a manner that could generate particulates (dust), Hercules recommends that the resin dust be treated as a nuisance particulate according to the American Conference of Governmental Industrial Hygienists (ACGIH). 111. TYPICA'L -PHYSICAL i CHEMICAL CHARACTERISTICS Boiling point: N/A Vapor pressure $ 20C: Not determined Vapor density: N/A X volatile (vol.): Negligible at 20C Softening point: 100C (212F) ---------- Solubility in water: Negligible Specific gravity: pH: 1.06 N/A Evaporation rate: Slower than butyl acetate IV. FIRE. EXPLOSION. I REACTIVITY HA2ARD DATA CAUTION! FLAMMABLE OUST WHEN FINELY DlVIOEO AND SUSPENDED IN AIR. Flash point: 246C (475F) COC Flanmable limits: N/A Autoignition temperature: Not determined Continued... *HMIS (Hazardous Materials Indentification System) Rating for the product as it is supplied. *TLV is a registered trademark of Amer, Conf. of Gov. Indust. Hygienists for Threshold Limit Values. N/A - not applicable We cannot anticipate all conditions under which this information and our products, or the products of other manufacturers in combination with our products, may be used. We accept no responsibility for results obtained by the application of this information or the safety and suitability of our products, either alone or in combination with other products. Users are advised to make their own tests to determine the safety and suitability of each such product or product combination for their own purposes. Unless otherwise agreed in writing, we sell the products without warranty, and buyers and users assume all responsibility and liability for loss or damage arising from the handling and use of our products, whether used alone or in combination with other products. 0 086647 cnfio efntja,. USDS No. 866 2001 1300-1 Date: 12/27/85 page 2 of 3 IV. FIRE. EXPLOSION.'! REACTIVITY HAZARtTWTT ...Continued Extinguishing media: Water spray, dry chemical, foam, or carbon dioxide Special fire-fighting procedures: None Unusual fire & explosion hazards: Flammable dust when finely divided and suspended in air. Stability considerations: Stable Incompatibility with: None Hazardous decomposition products: None Hazardous products of combustion: Carbon monoxide and carbon dioxide. Depending on conditions, some aliphatic aldehydes and carboxylic acids also may be formed. Hazardous polymerization: Will not occur. V. HEALTOfl/AM) UAf* Signs & symptoms of overexposure in the workplace: Eyes (dust): May cause mild transient eye Irritation. Skin: Prolonged contact may cause mild skin irritation. Inhalation (dust): May cause irritation of the respiratory tract. Ingestion: None known. EMERGENCY & FIRST AID PROCEDURES: EYES (dust): In case of contact, immediately flush with plenty of low pressure water for at least 15 minutes. Remove any contact lenses to ensure thorough flushing. Call a physician. SKIN: Wash with soap and running water. MOLTEN RESINS: If molten material comes in contact with the skin, cool under a running stream of water. Do not attempt to remove the resin from the skin. Removal could result in severe tissue damage."TJet medical attention. INHALATION (dust): Remove to fresh air. Treat any irritation symptomatically. Call a physician. INGESTION: If swallowed, do NOT induce vomiting. Call a physician. NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. Medical conditions generally recognized as being aooravated by exposure: None known. Primary Routes of Entry: Dust - Eyes, Skin, Inhalation Picco Resin: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA (Occupational Safety & Health Administration); not evaluated by IARC (International Agency for Research on Cancer). Petroleum Hydrocarbon Oil: The Interational Agency for Research on Cancer (IARC) has determined that there is no evidence to show that this type of oil causes cancer in man or experimental animals. Continued... 08^648 DO CONF IOENTTAl- USDS No. 866 2001 1300-1 V. HEALTH HAZARD DATA ...Continued REPORTED HUMAN EFFECTS: Picco Resin: None known. Petroleum Hydrocarbon Oil: None reported. Date: 12/27/85 page 3 of 3 REPORTED ANIMAL EFFECTS: Picco 6100 Resin: Based on studies with similar resins, the acute Oral LD_ rats - > 5,000 mg/kg 6wT Gross necropsy revealed effects on the kidneys at test levels exceeding 1,000 mg/kg. An Inhalation study was conducted with the fumes generated by heating to about 180C Picco 6100 resin. Rats were exposed for 6 hours at a nominal concentration of 1.17 mg/1 air. No adverse effects were noted. Petroleum Hydrocarbon Oil: LDJO, rats is estimated to be > 30 g/kg. VI. SPILL 4 LEAK PROCEDURE? STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If material is not contaminated, scoop into clean containers for use. If contaminated, scoop into containers for disposal. Waste Disposal Method: Incineration of waste material in a permitted facility in accordance to local, state, and federal regulations is the recommended disposal method. Landfilling in a licensed facility equipped with leachate collection is a suitable alternative. This product is not listed in federal hazardous waste regulations 40CFR261.33 paragraphs (e) or (f), i.e. chemical products that are considered hazardous if they become wastes. It does not exhibit any of the hazardous characteristics listed in 40CFR261 Subpart C. State or local hazardous waste regulations may apply if different from the federal. VII. APPLICABLE CONTROL MEASURE? Appropriate hygienic practices: Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling, and before eating, drinking or smoking. Personal protective equipment: Safety glasses Appropriate respirator selected and used in accordance with OSHA Subpart I (29CFR1910.134) required when exposure to airborne contaminant is likely to exceed acceptable limits. Work practices: Eyewash fountains and safety showers should be easily accessible. Handling and storage precautions: Keep away from sparks and open flame. Flaked forms are prone to gradual oxidation. Control inventory. Use oldest material first. Engineering controls: Adequate ventilation should be provided to keep dust concentrations below acceptable exposure limits. Protective measures during repair & maintenance: Eliminate dust and sources of ignition. fnc 1266s D0 086649 conftdfnttal Safety I Information PHOSFLEX' 390 Flame Retardant Plasticizer (Isodecyl Diphenyl Phosphate) This Product Safety Information Sheet is principally di rected to managerial, safety, hygiene and medical personnel. The description of physical, chemical and toxicological properties and handling advice is based on experimental results and past experience. It is intended as a starting point for the development of health and safety procedures. CAS Registry Number 29761-21-5 I. PHYSICAL AND CHEMICAL PROPERTIES Formula; (C,HsO), P(0)OC,gH,, Contains triphenyl phosphate (10-12%); CAS Registry Number 115-86-6 Formula Weight: 390 (approximate) Physical State/Description: Clear transparent liquid Decomposition Temperature: 460.4 F (238.2 C) Flash Point. 320F (160C) Cleveland Open Cup Odor Essentially odorless Specific Gravity: 1.064 -- 1.066 at 77F/77F (25C/25C) Vapor Pressure: 1.4 mmHg at 77 F (25 C) 16.0 mmHg at 201.2 F (94 C) 65.0 mmHg at 302F (150C) Viscosity: 23 centistokes at 77 F (25 C) Water Solubility: Practically insoluble at 77F (25C) II. CHEMICAL REACTIVITY Relatively nonreactive. III. STABILITY Stable at ambient temperatures and atmospheric pressure. IN CASE OF SUSPECTED POISONING, REFER TO THE INFORMATION IN SECTION VII: HUMAN HEALTH AND THE PROCEDURE AND EMER GENCY CONTACTS IN SECTION VIII: FIRST AID. IN CASE OF SPILLAGE, REFER TO THE PROCEDURE AND EMERGENCY CONTACTS IN SECTION X: SPILL HANDLING OR CALL CHEMTREC (800) 424-9300. IV. FIRE HAZARD The product may support combustion under fire condi tions and decompose to give off toxic materials, primarily phosphorus oxides. V. FIREFIGHTING TECHNIQUE This product contains triphenyl phosphate. Exposure to triphenyl phosphate may cause cholinesterase inhibition (refer to SECTION VII: HUMAN HEALTH AND SECTION VIII. FIRST AID). Products of combustion are irritating to the respiratory tract and may cause breathing difficulty and pulmonary edema. Symptoms may be delayed several hours or longer depending upon the extent of exposure. As in any fire, prevent human exposure to fire, smoke. ^ fumes or products of combustion. Evacuate nonessential personnel from the fire area. Firefighters should wear fullface, self-contained breathing apparatus and impervious protective clothing. Use standard firefighting techniques to extinguish fires involving this material -- use water spray, dry chemicals or carbon dioxide. If not leaking, keep fire-exposed containers cool with a water spray to prevent rupture due to excessive heat. High pressure water hose may spread product from broken con tainers increasing contamination or fire hazard. Contaminated buildings, area and equipment must not be used until they are properly decontaminated. VI. TOXICOLOGY Ingestion The acute oral LD50 is greater than 5000 mg/kg in male and female rats. A single oral dose of 5000 mg/kg produced a mild to moderate decrease in physical activity, wet and stained fur, and no mortality in male rats. A single oral dose of 5000 mg/kg produced a mild decrease in physical activ ity, piloerection, stained fur and no mortality in female rats. Skin Contact The acute dermal LD50 is greater than 2000 mg/kg in rabbits. A single dermal application of 2000 mg/kg did not produce signs of toxicity in rabbits. Mild irritant to rabbit skin following a 4-hour exposure. Eye Contact Mild irritant to rabbit eyes. T-11460 VII. HUMAN HEALTH The principal routes of exposure are skin contact and inhalation. Skin and eye contact with the product may result in irritation. Inhalation of vapors may cause respira tory irritation. There are no data available which address medical conditions that are generally recognized as being aggravated by exposure to this product. (Reader should consult SECTION VI: TOXICOLOGY for effects observed in experimental animals under controlled laboratory con ditions using this product.) This product contains triphenyl phosphate. Exposure to triphenyl phosphate has been reported to cause cholines terase inhibition in humans.m Exposure may also cause minor symptoms of gastrointestinal distress and symptoms affecting the neuromuscular systems.!*) 'The American Conference of Governmental Industrial Hygien ists (ACGIH). (1980). Documentation ot the Threshold Limit Values for Substances in Workroom Air, 4th Ed. ACGIH Cincin nati, Ohio, pg 420. <*)Proctor, Ph.O. Nick H. and Hughes. M.D., James P. (1978). Chemi cal Hazards of the Workplace. J.B. Lippincott Company Philadeiphia. PA. y All information is offered in good faith, without guarantee or obligation tor the accuracy or sufficiency thereof, or the results obtained, and is accepted at user's risk The uses referred to are for the purpose of illustration only: user should investigate and establish the suitability of such use(s) in every case Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license under valid patents Printed in U.S.A. Stauffer Stauffer Chemical Company Specialty Chemical Group Westport, Connecticut 06881 Telephone: (203) 222-Mnn DO 086650 CONFIDENT! At- PHOSFLEX! 390 VIII. FIRST AID CALL A POISON CENTER OR A PHYSICIAN IMMEDIATELY If a known exposure occurs or is suspected, immediately start the recommended procedures below. Simultaneously contact a Poison Center, a physician or the nearest hospital. NOTE: Be sure to advise the person contacted that tri phenyl phosphate, which comprises 10-12% of this prod uct, has been reported to be a cholinesterase inhibitor in humans.to Inform the person contacted of the type and extent of exposure, describe the victim's symptoms and follow the advice given. FOR ADDITIONAL MEDICAL OR TOXICOLOGICAL INFORMATION, CALL COLLECT, DAY OR NIGHT. STAUFFER CHEMICAL COMPANY. (203) 226-6602 _________ OR CHEMTREC (800) 424-9300. Note To Medical Personnel Exposure to this product may cause cholinesterase inhibi tion. If cholinesterase inhibition is suspected, atropine by injection is antidotal. 2-PAM (Protopam Chloride) is also antidotal when administered early and in conjunction with atropine. Ingestion If swallowed, immediately give several glasses of water and induce vomiting by gagging the victim with a finger placed on the back of the victim's tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Skin Contact Flush all affected areas with plenty of water for several minutes. Remove and clean any contaminated clothing and shoes. Seek medical attention if skin irritation occurs. Eye Contact Flush the eyes with plenty of running water for at least 15 minutes Hold the eyelids apart during the flushing to ensure rinsing of the entire surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation If inhaled, remove to fresh air. Seek medical attention if respiratory irritation occurs or if breathing becomes difficult. IX. INDUSTRIAL HYGIENE The recommendations described in this section are pro vided as general guidance for minimizing exposure when handling this product Because use conditions will vary depending upon customer applications, specific safe han dling procedures should be developed by a person knowl edgeable of the intended use conditions and equipment. During the development of safe handling procedures, con sideration should be given to the need for cleaning of equipment and piping systems to render them nonhazardous before maintenance and repair activities are per formed. Engineering Controls In those cases where engineering controls are indicated by the use conditions, the following traditional exposure con trol techniques may be used to effectively minimize em ployee exposure: local exhaust ventilation or enclosed system design in combination with appropriate use of per sonal protective equipment. 2 Ingestion All food should be kept in a separate area away from the storage/use location. Eating, drinking and smoking should be prohibited in areas where there is a potential for signifi cant exposure to this material. Before eating, hands and face should be thoroughly washed. Skin Contact Skin contact with liquid or its aerosol should be minimized through the use of gloves and suitable long-sleeved cloth ing selected with regard for use condition exposure potential. Eye Contact Eye contact with liquid or its aerosol should be avoided through the use of chemical safety glasses, goggles or a face shield selected with regard for use condition exposure potential. Inhalation If use conditions generate airborne vapor or aerosol, the material should be handled in an open (e g., outdoor) or well ventilated area. Where adequate ventilation is not available, use NlOSH-approved organic vapor respirators with dust, mist and fume filters to reduce exposure. Where exposure potential under the use conditions necessitates a higher level of protection, use a positive-pressure, airsupplied respirator. Exposure Limits No exposure limits have been established for this product However, the product contains triphenyl phosphate for which the following exposure limits apply. The Federal OSHA Permissible Exposure Limit (PEL) is 3 mg/m3 as an 8-hour, time-weighted average.!** The Threshold Limit Value (TLV) is the same as the PEL and the Short Term Exposure Limit (STEL) is a 6 mg/m3 for triphenyl phosphate.*4* PEL'S and TLV's refer to airborne concentrations mea sured in the breathing zone by appropriate sampling techniques X. SPILL HANDLING Make sure all personnel involved in the spill cleanup follow good industrial hygiene practices (refer to SECTION IX: INDUSTRIAL HYGIENE). Any person entering either a significant Spill area or an unknown concentration of a vapor or aerosol should use a positive-pressure, self-contained breathing apparatus or a positive-pressure, supplied-air respirator with escape pack. Small spills can be handled routinely. Use adequate ven tilation and/or wear a NlOSH-approved respirator with dust, mist and fume filter to prevent inhalation exposure. Wear protective clothing to prevent skin and eye contact. Use the following procedures: Soak up pooled liquid with a suitable absorbent such as clay, sawdust or kitty litter. Sweep up absorbed material and place in a chemical waste container for disposal (refer to SECTION XIII: DISPOSAL OF UNUSED MATERIAL). Generously cover contaminated area with a slurry of common household powdered laundry detergent and water. Using a stiff brush, work the slurry into cracks and crevices. Allow to stand for 2-3 minutes then flush with water Repeat if necessary. Large spills should be diked and pumped to salvage according to a predetermined plan. For assistance in developing a plan, contact the Specialty Chemical Di vision, Stauffer Chemical Company, Westport, CT 06881 **29 CFR 1910.1000 <4* The American Conference Of Governmental Industrial Hygien ists (ACGIH) (1984) Threshold Limit Values for Chemical Substances and Physical Agents in the Workroom Environment and Biological Exposure Indices with intended Changes tor 1984-85. ACGIH. Cincinnati, Ohio DO 086651 CONFIDFNTTAl PHOSFLEX*- 3M IN CASE OF SPILL EMERGENCY. DAY OR NIGHT. _____ CALL (800) 424-9300 CHEMTREC. XI. CORROSIVITY TO MATERIALS OF CONSTRUCTION Noncorrosive lo materials commonly used in the construc tion of process equipment and storage and shipping containers. XII. STORAGE REQUIREMENTS Containers should be stored in a cool. dry. well ventilated area away from flammable materials and sources of heat or flame. Store away from foodstuffs or animal feed. Exercise due caution to prevent damage to or leakage from the container XIII. DISPOSAL OF UNUSED MATERIAL Material that cannot be used as directed on the product label must be disposed of according to any applicable regulations under the Resource Conservation and Recov ery Act. NOTE: State and local regulations may be more stringent than Federal XIV. DISPOSAL OF CONTAINER Dispose of empty containers according to any applicable regulations under the Resource Conservation and Recov ery Act NOTE: State and local regulations may be more stringent than Federal XV. PRECAUTIONARY STATEMENTS CAUTION! May cause irritation May release harmful vapors at elevated temperatures. Avoid contact with eyes, skin and clothing Wear safety glasses or goggles, rubber gloves and appropriate protective clothing when handling Wash thoroughly after handling Use with adequate ventilation FOR NONEMERGENCY HANDLING INFORMATION. CONTACT THE SPECIALTY CHEMICAL DIVISION STAUFFER CHEMICAL COMPANY. WESTPORT. CT 06881 OR PHONE (203) 222-3000. New Issue 2/85 Supercedes MSDS Dated 12/83 PH0.183.S > ) DO DO/vp* TOf;htxAl 3