Document 2jqG41gZ0RjZNex1V34gqN2Xg

CWA COMPLIANCE EVALUATION INSPECTION REPORT U.S. ENVIRONMENTAL PROTECTION AGENCY, REGION 5 Purpose: Compliance Evaluation Sampling Inspection Facility: Richter Dairy Farm 14113 St. Rose Road Breese, Illinois 62230 Clinton County, Illinois 38.62797657159176, -89.55355561706052 NPDES ICIS Tracking Number: ILA000349 Date of Inspection: Site Inspection - September 14th, 2022 Operator Interview - September 27th, 2022 EPA Representatives: Benjamin Atkinson, Agronomist, 312-353-8243 atkinson.ben@epa.gov Cheryl Burdett, Life Scientist, 312-886-1463 burdett.cheryl@epa.gov State Representatives: Bruce Rodely, Inspector, 618-318-1376, bruce.rodely@illinois.gov Facility Representatives: Keith Richter, Owner/Operator, 618-791-6434 Atkinson, Benjamin Digitally signed by Atkinson, Benjamin Inspector Signature: ___________________________D_a_te_: _20_2_2_.1_1_.2_8_1_3_:1_3_:2_7_-_06_'0_0_' ____ Approver Signature and Date: Ryan Bahr Digitally signed by Ryan Bahr _______________________D_a_te_: _20_2_2_.1_1_.2_8_1_4_:3_0_:3_3_-0_6_'0_0_' 1 1. BACKGROUND Richter Dairy September 14th and September 27th The purpose of this report is to describe, evaluate and document Richter Dairy Farm's (the facility's) compliance with the Clean Water Act (CWA) at its Breese, Illinois facility on September 14th, 2022. This inspection was performed pursuant to Section 308(a) of the Federal Water Pollution Control Act, as amended. The facility is a medium dairy Animal Feeding Operation located in Clinton County, Illinois. At the time of the inspection, the facility confined approximately 230 mature dairy cows (milking and dry), 105 heifers, and 35 calves. A dairy animal feeding operation is considered medium if it stables or confines 200 to 699 mature dairy cows, whether milked or dry. Surface runoff from the facility flows to Bull Branch, an intermittent stream which flows directly through the facility. Bull Branch is listed as impaired for Aquatic life in the 2022 303(d) list. The impaired parameters include dissolved oxygen, total phosphorus, sedimentation/siltation, and total suspended solids. 2. SITE INSPECTION Table 1: Site Entry and Opening Conference Arrival Time: Approximately 9:15 AM. Temperature: 76 F Precipitation: No precipitation on the day of or the day prior to the inspection. Presented credentials? Yes. Credentials presented to whom and at what time? Presented credentials to the operator at 9:15 AM Was an opening conference held? With whom? Yes, an opening conference was held with the operator. If photographs or documents were taken, does the facility consider any to be Confidential Business Information (CBI)? EPA vehicle parked in approved location? Location where EPA vehicle was parked? Disposable boots worn? Other bio-security measures taken: No CBI claim was made at the time of the inspection. Yes. Adjacent to the calf hutch area. Yes. The state veterinarian office was contacted, and no infectious disease outbreaks were reported. The EPA vehicle was washed following the inspection. 2 Richter Dairy September 14th and September 27th 2.1 Records Review (The following Records Review tables reflect information provided before the walk-through of the facility, unless otherwise noted.) Table 2: Documents Checklist(s) Used R5 CAFO Inspection Checklist Table 3: Facility Description Type of Animal Number of Animals Mature dairy cows 230 (milking and dry) Capacity 260 Heifers 105 105 Calves 35 35 Minimum Number of Animals in previous 5 years: Maximum Number of Animals in previous 5 years: Number of Animals that are stabled/confined and/or fed/maintained for 45 days or more in previous 12 months: Amount of Liquid Manure Generated per year: Amount of Solid Manure Generated per year: (Illinois Only) Name of Certified Livestock Manager for facility: (if 300 animal units or greater): Does the facility have an NPDES Permit? SIC or NAICS code: Do animals have direct access to WOUS? Are crops, vegetation, forage growth, or post harvest residues sustained in the normal growing season over any portion of the lot or facility where animals are kept? What is the area (acres) of the production area? What is the area (acres) of the pasture? How many employees (not counting family members)? Other facilities under common ownership (name and address): Type of Confinement Total confinement except for limited outdoor lots for dry cows Total confinement Total confinement 185 mature, 85 heifers, 20 calves Current numbers Current numbers Operator was unsure - estimated 2 million gallons a year 80 loads - 12 ton per load The operator is the Certified Livestock Manager No SIC 0241 No No 8 3 1 full time 4 part time no 3 Richter Dairy September 14th and September 27th Table 4: Livestock Waste Storage Type of Dimensions Type of Storage Liner Pit 1 40'x 50'x10' Concrete Pit 2 16'x40'x10' Concrete Pit 3 16'x40'x10' Concrete Pit 4 60'x80'x10' Concrete Pit 5 140'x140x10' Concrete Depth Markers Present Yes Yes Yes Yes Yes Last Time Waste was Removed Late September Records at site of storage structure design? Yes Is manure stored for the short term? No. If yes, describe where it is stored, how it is drained and where it drains to. Amount Days of of Waste Storage Removed 1.1 million gallons ~1 year Are records kept of the level of manure in the storage structures? When was the last time a storage structure was emptied, either partially or completely? What amount of manure or process wastewater was removed the last time the storage structure was emptied, either partially or completely? Do the facility personnel inspect and keep records of all diversion devices? Do the facility personnel inspect and keep records of all impoundments? Do the facility personnel inspect and keep records of all the water lines? Do the facility personnel perform routine visual inspections and keep records of the production area? Does the waste storage system have a managed outfall or discharge point? If yes, provide a description of the outfall and a description of the area receiving the discharge. Has the facility had any documented discharges of livestock waste to surface water in the past year? Yes, has depth gauges, just visual checks Late September 1.1 million gallons The operator stated that inspections were conducted but records were not kept No The operator stated that they had not 4 Are there safety devices installed around any manure storage ponds? (Barriers at the end of manure push off platforms, fences around pond, signage.) Richter Dairy September 14th and September 27th Yes Table 5: Livestock Waste Management Describe the way manure is collected and disposed of at the facility: Manure from the milk cow barns is pushed to Manure Pit 4 and then pumped to Manure Pit 5. Manure from the dry cow and heifer cow barns is pushed to Manure Pit 1. Leachate and runoff from the feed storage area on the east side of the facility flows to pits 2 and 3 which are pumped to pit 5. Describe the way used bedding is collected and disposed of at the facility: Solids are scraped and land applied as needed. Are mortality records kept? yes Describe the way mortalities are managed at the facility: Small carcasses are composted, and large carcasses are picked up by a rendering service. What type of method is used to provide Automatic waterers are used. Overflow is drinking water for the animals? collected with manure. Describe the way mist cooling water is collected and disposed of at the facility: No mist cooling is used. Describe how chemicals are stored and how used or spilled chemicals are collected and disposed of at the facility: Chemicals are stored in the milk parlor and any spilled chemicals would be collected with parlor wash water. Describe the way water that has been used to wash/flush barns is collected and disposed of at the facility: No flush water is used. Describe the way feed is contained and how runoff from feed is collected and disposed of at the facility: Leachate and runoff from the feed storage area on the east side of the facility flows to pits 2 and 3 which are pumped to pit 5. If a dairy, describe how process wastewater from the cleaning of the milking parlor is collected and disposed of at the facility: Wash water flows to septic tank which is pumped to Pit 5. 5 Richter Dairy September 14th and September 27th If a dairy, describe how process wastewater from the cleaning of the milk tanks is disposed of at the facility: Collected with wash water and pumped to Pit 5. If a dairy, how many times per day are 2x a day cows milked? Table 6: Land Application and Disposal of Manure and Process Wastewater Does the facility perform and keep records of the Yes manure testing? When was the last time a sample was taken of the Late September when hauling manure and/or process wastewater? occurred Describe the process to take the manure and/or Grab sample as hauling process wastewater sample. Number of acres available for land application: Are land application records kept? Who applies the manure and process wastewater to the fields? Are weather conditions at time of application kept? (24 before - 24 after) Does the facility perform and keep records of the soil testing? Is manure transferred off-site to another party? 415 acres Yes Metro Ag No Yes no Table 7: Receiving Surface Waters Describe the surface flow pathways: Bull Branch is an intermittent waterway that flows southwest through the facility. All uncontained runoff from the site flows directly to Bull Branch or, on the west side of the facility, to the roadside ditch along St. Rose Road and then to Bull Branch. How many months out of the year is there flow in the nearest surface water pathway: Are there any storm water pathways entering the facility? Are there any clean water ponds on site? What is the name of the first waterway that is identified as a Traditional Navigable Water (TNW) for surface flow from the facility? The operator stated that Bull Branch is flowing 20 times a year and has standing water 80 percent of the time. No No The Kaskaskia River is the first TNW 6 Is the surface water pathway nearest to the facility considered to be ephemeral, intermittent or perennial? Has the surface water pathway nearest to the facility been assessed for water quality? Richter Dairy September 14th and September 27th Intermittent Yes - it is listed as impaired for Aquatic life in the 2022 303(d) list. The impaired parameters include dissolved oxygen, total phosphorus, sedimentation/siltation, and total suspended solids. Table 8: Nutrient Management Plan NMP on site? Yes Planner Name/Company: Mauer and Stutz Note: A Nutrient Management Plan Review was not completed for this facility due to its size. 2.2 Walkthrough of the Facility Ben Atkinson and Cheryl Burdett (the Inspectors) met with Bruce Rodely (the IEPA Inspector) offsite and proceeded to the facility arriving at approximately 9:15 AM. The Inspectors donned their biosecurity boots and found Mr. Keith Richter (the Operator). The Inspectors presented their credentials and held an opening conference. During the opening conference, the Inspectors explained that the purpose of the inspection was to evaluate the facility's compliance with the Clean Water Act, discussed what areas of the facility would be inspected, and explained the Operator's right to claim CBI. The Operator stated that prior engagements made the timing of the inspection unacceptable. The Inspectors asked if it would be possible to conduct the walkthrough of the facility and schedule a time to complete the interview portion of the inspection by phone at a more convenient time. The Operator agreed and the walkthrough of the facility began. The walkthrough began on the west side of the Dry Cow Barn. The Inspectors observed manure solids and dark brown liquid around the exterior of the gate located in the southwest corner of the Dry Cow Barn. The Inspectors also observed that the roof gutter downspout outlet was located in the same area (photo 1). The Inspectors noted that if stormwater were to come into contact with manure and discharge that it would be violation of the CWA. The Inspectors then walked east along the south side of the Dry Cow Barn past manure Pit 1 and observed the Hospital Barn (photos 2 and 3). The Operator stated that manure from the Dry Cow Barn and the Heifer Barn was pushed to Pit 1. The Inspectors observed manure solids and dark brown liquid around the entrance to the Hospital Barn and around the outdoor lot area attached to the south side of the Hospital Barn (photos 4 and 5). There was no containment for any manure or process wastewater around the Hospital Barn Pen. The Inspectors noted that, given the proximity to Bull Branch, it 7 Richter Dairy September 14th and September 27th seemed likely that runoff from the area could potentially discharge. The Operator stated that he had been intending to abandon the Hospital Barn but had not done so. The Inspectors walked north along the east side of the Heifer barn to the north side of the facility. The Inspectors observed an apparent flow path from the north end of the feed bags toward the north end of the property (photos 12-14). The Inspectors did not observe the flow path continuing into the field to the north. The Inspectors then walked east along the north side of the facility to the west bank of Bull Branch and observed water within the Bull Branch (photos 15 and 16). The Inspectors then walked south along the west bank of Bull Branch. The Inspectors observed a mound of manure solids north of the Hospital Barn (photo 17). The Inspectors also observed dark colored leachate (photo 25) and manure solids in the access road and along the west bank of Bull Branch (photos 18-28). The Inspectors also observed further manure solids around the outdoor pen on the southside of the Hospital Barn (photos 29-31). The Inspectors then walked east across the access road culvert over Bull Branch to the feed storage area on the east side of Bull Branch. The Inspectors observed fibrous solids on the culvert (photos 33 and 58). The Inspectors observed Pit 2 and Pit 3 which collect the runoff from the feed storage areas on the east side of Bull Branch (photos 34 and 35). The Inspectors walked north along the east bank of Bull Branch and observed a solid manure stack on the northwest corner of the feed storage area (photos 39-41, and 44). It appeared that the runoff from the manure pile was being collected by Pit 2 (photo 40). The Inspectors also observed the Commodity Barn and a mound of organic solids (photos 45 and 46). The Inspectors walked south on the east side of the silos and then west to the Hay Barn. The Inspectors observed Pit 3 (photos 49-51). The Inspectors walked south to the south end of Pit 3 and observed a hose attached to a pump sitting at the south end of Pit 3. The opposite end of the hose was lying on the ground and oriented toward Bull Branch (photos 52-56). When asked what the pump was for, the Operator stated that he did not know why it was there and that his father had been put it there. At the Inspectors request, the hose was moved onto the Pit 3 area so it could not discharge to Bull Branch (photo 57). The Inspectors stated that they intended to walk along the west bank of Bull Branch. The Operator stated that it wouldn't be passable due to overgrown vegetation and suggested that the Inspectors look along the east side of the outdoor lot connected to the East Milk Cow Barn by looking through the barn. The Inspectors stated that they would still like to try to walk along the exterior wall of the outdoor lot and Pit 4. The Operator stated that it would be best to start from the south side and that he would not be able to join the Inspectors. The Inspectors walked west past the East Milk Cow Barn, the Milking Parlor, and the West Milk Cow Barn (photos 59 and 60). The Inspectors walked to the west side of the facility. The Inspectors observed a white pipe protruding from the east side of the roadside ditch (photo 61). The Inspectors walked south along the outside of the white 8 Richter Dairy September 14th and September 27th fence along the west side of the facility. The Inspectors observed a depression that appeared to be a flow path for runoff from the denuded outdoor lot west of the West Milk Cow Barn (photos 62-64). The Inspectors continued south and observed a blue pipe protruding from the east side of the roadside ditch. The pipe appeared to be in line with a blue pipe connected to the downspout of the roof gutters on the West Milk Cow Barn (photos 65 and 66). The Inspectors observed that the outdoor lot was denuded (photos 68 and 69). The Inspectors continued walking south along the west fence and observed burnt vegetation and manure solids in a path from the area west of the Pit 4 ramp down to the roadside ditch (photos 70 - 77). The Inspectors then walked east toward Bull Branch. The Inspectors observed manure solids and burnt vegetation in a path from the area south of the Pit 4 ramp towards Bull Branch (photos 79-84). The Inspectors walked north along the east side of Pit 4 and observed manure solids deposited on the fence along Pit 4 (Photos 88 and 89). The Inspectors also observed Bull Branch was covered in foam (photos 92-97). The Inspectors continued north and observed manure deposited on top and exterior side of the east concrete wall of Pit 4 (photos 99-102). The Inspectors continued north and observed manure solids in the channel of Bull Branch (photos 109 and 110). The Inspectors also observed manure on the top of and along the exterior edge of the concrete wall on the east side of the outdoor lot south of the East Milk Cow Barn (photos 111 - 113). The Inspectors continued walking north and observed a hole in the concrete wall east of the East Milk Cow Barn which was allowing manure to flow down through a channel into Bull Branch (photos 117 - 131). The Inspectors observed liquid manure flowing in the channel and into Bull Branch. The Inspectors walked north and met with the Operator informing him of the active flow of manure to Bull Branch. The Inspectors asked if the Operator could take immediate steps to stop the flow of manure. The Operator stated that he would. The Inspectors then walked across the culvert over Bull Branch to the east side of Bull Branch and started walking south to observe Pit 5. The Inspectors observed an area west between Pit 5 and Bull Branch where there were multiple animal bones and decomposing animal carcasses (photos 134 -139). The Inspectors walked around Pit 5 and returned north to the EPA Vehicle. The Inspectors met the Operator and informed him that they would be taking samples and offered split samples. The Operator declined the split samples. The Operator notified the Inspectors that he had filled the area around the concrete hole with soil to stop the flow of manure. The Inspectors provided the Operator with a summary of the areas of concern they had observed which included the lack of containment for manure and runoff from the 9 Richter Dairy September 14th and September 27th Hospital Barn, the lack of containment for manure and runoff for the mound of manure north of the Hospital Barn, the paths of organic material and burned vegetation from the denuded earthen lot on the west side of the facility, and manure that had been flowing from the cracked wall into Bull Branch. The Inspectors then collected their sampling equipment and went to the north end of the facility to collect an upstream sample from Bull Branch (photos 170 - 171). The Inspectors then returned to confluence of the channel conveying manure from the cracked wall to Bull Branch and collected a sample from Bull Branch at the confluence with the channel (photos 177 - 181). The Inspectors observed that fill had been placed over the hole in the concrete wall (photos 182 and 183). The Inspectors then returned to their vehicle, preserved the samples, and exited the site. A follow up call to complete the interview portion of the Inspection was held on September 27th, 2022. The operator's responses during the interview portion of the Inspection were used to complete the checklist. During the interview, the Operator stated that the crack in the wall has been there for "a few months". 2.3 Closing Conference and Post-Inspection Table 9: Post Walk-Through Was a closing conference held? With whom? ______________________________________________________________________ A brief closing conference was held with the Operator and a tenative time was set up to complete the interview portion of the Inspection at a later date. Were specific Areas of Concern discussed with facility personnel? Yes Who were the Areas of Concern The Operator discussed with? Were any deficiencies or areas of During the Inspection, the Operator concern addressed or fixed during the moved the hose from the pump in Pit 3 so inspection? If so, list what was done. that it could not discharge. Additionally, the Operator took steps to stop the flow of manure to Bull Branch. Following the site visit, the Operator notified EPA that he had blocked Bull Branch, flushed the channel with fresh water, and used a vacuum truck to remove the manure which was then placed in Pit 5. Exit Time: 12:30 PM Disposable Boots Left at Facility? Yes Vehicle Washed after leaving facility? Yes 10 Richter Dairy September 14th and September 27th Table 10a: Sampling Information Were samples taken? Were samples split with facility? Number of samples taken? Was a trip blank created (done prior to entering the facility)? Identify which sample is the trip blank. Were field duplicate samples taken (1 duplicate per 20 samples)? List chain of custody for fecal coliform samples: List chain of custody for nutrient and general chemistry samples: Location where samples were preserved: Name of people involved with sample preservation: Time of sample preservation: Were samples shipped to a lab? Yes No 2 Yes Sample B01 No Chain of Custody sheet number 5-65974 Chain of Custody sheet number 5-65976 Facility Ben Atkinson, Cheryl Burdett 12:15 PM No 11 Table 10b: Facility Sample Information Number Name Location Date SO1 Upstream 38.62951526 09/14/2022 319047, - 89.55206039 818188 S02 Confluence 38.62754301 09/14/2022 396082, - 89.55274426 28533 B01 Field Blank 38.62809818 09/14/2022 201452, - 89.55341482 436322 Time 11:45 AM 11:58 AM 12:04 PM Collector BA CB BA CB BA CB Color/ Smell Slight brown color. No smell noted Dark Brown/ smelled of manure None/no ne Photo # 170 171 179 - 181 None Photographer CB Method of Collection Grab CB Grab Grab # of Sulfuric Acid Drops 20 35 5 Name of Laboratory where fecal coliform/E.coli samples were taken: Pace Analytical Services, LLC Name of Laboratory where nutrients and general chemistry samples were taken: Chicago Regional Laboratory Table 10c: Richter Dairy Inspection Sampling Results Sample ID Sample Location Fecal coliform bacteria MPN/100mL Nitrate-Nitrite Ammonia N N mg/L mg/L Upstream at S01 north end of 712 property U 0.41 Confluence S02 with manure >242,000 U 46.6 channel B01 Blank NA U U Total Dissolved Solids mg/L 154 1580 U Total Suspended Solids mg/L Biochemical Oxygen Demand 19 3 550 640 U 6 Total Kjeldahl Nitrogen mg/L 1.31 69.5 U Total Phosphorus mg/L 2.09 21.5 U 12 3. AREAS OF CONCERN EPA observed these areas of concern: 1. Manure was observed flowing out of a hole in the concrete wall along the east side of Pit 4 in a channel approximately 50 feet into Bull Branch. 2. Manure solids were observed in the channel of Bull Branch. 3. A path of burnt vegetation and organic material was observed from the area west of the Pit 4 ramp to the roadside ditch. 4. A path of burnt vegetation and organic material was observed from the area south of the Pit 4 ramp toward the Bull Branch. 5. The mound of solid manure stacked north of the Hospital Barn did not have containment. 6. The Hospital Barn Pen area lacks containment. 7. The mortality pile west of Pit 5 did not have containment. 8. Manure and feed solids were observed uncontained on and around the culvert over Bull Branch. 9. A pump with a hose from manure Pit 3 was observed directed toward Bull Branch. 10. The denuded earthen lot west of the West Milk Cow Barn lacked containment. 11. Manure was observed outside of the gate to the Dry Cow Barn in close proximity to the roadside ditch and a roof gutter downspout. List of appendices: Appendix A - Aerial Map Appendix B - Photo Log Appendix C - Sampling Results 13 APPENDIX A . Richter Dairy Farm 14113 St. Rose Road Breese, Illinois 62230 Clinton County, Illinois 38.62797657159176, -89.55355561706052 Legend Bull Branch !. sampling location Pit 1 Dry Cow Barn Milking Parlor Richter Dairy Farm West Milk Cow Barn Pit 4 !. Sampling Point S01 Heifer Barn Hospital Barn Pit 2 Pit 3 Hay Barn Eastt Milk Cow Barn Machine Shed Sampling Point S02 !. Crack in concrete wall with channel to Bull Branch Pit 5 Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community APPENDIX B Richter Dairy EPA Inspection September 14, 2022 All photos taken by Cheryl Burdett, Environmental Scientist, U.S. EPA Camera: Olympus TG-4 1: P9140092 Description: Looking north along the west side of the Dry Cow Barn. Note there are manure solids around the gate to the animal area as well a downspout outlet in the same area. Location: Southwest corner of the Dry Cow Barn Camera Direction: North Date/Time: September 14, 2022 9:36 AM Page 1 Richter Dairy Farm September 14, 2022 2: P9140093 Description: Looking north across Pit 1 (behind the fence where the vegetation is seen) toward the south end of the Heifer Barn. Location: Southwest corner of Pit 1. Camera Direction: North Date/Time: September 14, 2022 9:37 AM 3: P9140094 Description: Looking west along the south side of the Dry Cow Barn (right) and the calf hutch area (left). Location: Southwest corner of Pit 1. Camera Direction: West Date/Time: September 14, 2022 9:37 AM Page 2 Richter Dairy Farm September 14, 2022 4: P9140095 Description: Looking north at the south side of the Hospital Barn. Location: East of Pit 1. Southwest corner of the Hospital Barn. Camera Direction: North Date/Time: September 14, 2022 9:38 AM 5: P9140096 Description: Looking southeast from the southwest corner of the Hospital Barn. Note that there is no containment around the south end of the Hospital Barn. Also note the proximity of the waterway (blue arrow). Location: Southwest corner of the Hospital Barn. Camera Direction: Southeast Date/Time: September 14, 2022 9:38 AM Page 3 Richter Dairy Farm September 14, 2022 6: P9140097 Description: Looking south along the east side of the Heifer Barn (right). Location: East side of the Heifer barn. Camera Direction: South Date/Time: September 14, 2022 9:40 AM 7: P9140098 Description: Looking south along the west side of the Heifer Barn (left) toward the Dry Cow Barn (in distance). Location: Northwest corner of the Heifer Barn. Camera Direction: South Date/Time: September 14, 2022 9:41 AM Page 4 Richter Dairy Farm September 14, 2022 8: P9140099 Description: Looking west toward the fence along St. Rose Road from the Northwest corner of the Heifer Barn. Location: Northwest corner of the Heifer Barn. Camera Direction: West Date/Time: September 14, 2022 9:41 AM 9: P9140100 Description: Looking west toward the fence along St. Rose Road from the Northwest corner of the Heifer Barn. Location: Northwest corner of the Heifer Barn. Camera Direction: West Date/Time: September 14, 2022 9:42 AM Page 5 Richter Dairy Farm September 14, 2022 10: P9140101 Description: Looking northwest toward the fence along St. Rose Road from the Northwest corner of the Heifer Barn. Location: Northwest corner of the Heifer Barn. Camera Direction: Northwest Date/Time: September 14, 2022 9:42 AM 11: P9140102 Description: Looking north from the north end of the Heifer Barn toward plastic wrapped feed. Location: North of the Heifer Barn. Camera Direction: North Date/Time: September 14, 2022 9:42 AM Page 6 Richter Dairy Farm September 14, 2022 12: P9140103 Description: Looking southeast from the north end of the facility. Note the flow path (red line) originating at the north end of the feed bags. Location: North end of the facilty. Camera Direction: Southeast Date/Time: September 14, 2022 9:45 AM 13: P9140104 Description: Close up of the flow path noted in photo 12. Location: North end of the facility. Camera Direction: Southeast Date/Time: September 14, 2022 9:45 AM Page 7 Richter Dairy Farm September 14, 2022 14: P9140105 Description: Looking southeast from the north end of the facility. Note the flow path (red line) originating at the north end of the feed bags. Location: North end of the facilty. Camera Direction: Southeast Date/Time: September 14, 2022 9:45 AM 15: P9140106 Description: Looking upstream along Bull Branch from the west bank. Location: West bank of Bull Branch on the north side of the facility. Camera Direction: Northeast Date/Time: September 14, 2022 9:50 AM Page 8 Richter Dairy Farm September 14, 2022 16: P9140107 Description: Looking downstream along Bull Branch from the west bank. Location: West bank of Bull Branch on the north side of the facility. Camera Direction: Southeast Date/Time: September 14, 2022 9:50 AM 17: P9140108 Description: A mound of solid manure with no runoff containment located north of the Hospital Barn and east of the Heifer Barn. Location: North of the Hospital Barn and east of the Heifer Barn. Camera Direction: West Date/Time: September 14, 2022 9:52 AM Page 9 Richter Dairy Farm September 14, 2022 18: P9140109 Description: Manure solids on the west bank of Bull Branch east of the mound of solid manure. Location: East of the mound of solid manure. Camera Direction: Down Date/Time: September 14, 2022 9:52 AM 19: P9140110 Description: Manure solids on the west bank of Bull Branch east of the mound of solid manure. Location: East of the mound of solid manure. Camera Direction: Down Date/Time: September 14, 2022 9:52 AM Page 10 Richter Dairy Farm September 14, 2022 20: P9140111 Description: Error Photo Location: Camera Direction: Date/Time: September 14, 2022 21: P9140112 Description: Error Photo Location: Camera Direction: Date/Time: September 14, 2022 Page 11 Richter Dairy Farm September 14, 2022 22: P9140113 Description: Looking downstream along the Bull Branch. Location: West bank of Bull Branch, east of the Hospital Barn. Camera Direction: Southeast Date/Time: September 14, 2022 9:52 AM 23: P9140114 Description: Looking south along Bull Branch. Location: East of the Hospital Barn Camera Direction: South Date/Time: September 14, 2022 9:52 AM Page 12 Richter Dairy Farm September 14, 2022 24: P9140115 Description: Looking north along the access road paralel to Bull Branch. Location: West of Bull Branch and east of the Hospital Barn. Camera Direction: North Date/Time: September 14, 2022 9:53 AM 25: P9140116 Description: Dark colored leachate in access road between the solid manure mound and Bull Branch. Location: East of the solid manure mound and the Hospital Barn. Camera Direction: West Date/Time: September 14, 2022 9:53 AM Page 13 Richter Dairy Farm September 14, 2022 26: P9140117 Description: Solids deposited in grass along the west bank of Bull Branch. Location: West bank of Bull Branch, east of Hospital Barn. Camera Direction: East Date/Time: September 14, 2022 9:53 AM 27: P9140118 Description: Manure solids deposited on access road east of the Hospital Barn. Location: East of the Hospital Barn. Camera Direction: South Date/Time: September 14, 2022 9:54 AM Page 14 Richter Dairy Farm September 14, 2022 28: P9140119 Description: Dead vegitation and eroded flow paths along the west bank of Bull Branch and the access road. Location: East of the Hospital Barn. Camera Direction: Northeast Date/Time: September 14, 2022 9:54 AM 29: P9140120 Description: Manure solids on the ground around the exterior of the pen on the south side of the Hospital Barn. Location: Southeast corner of the Hospital Barn Camera Direction: West Date/Time: September 14, 2022 9:54 AM Page 15 Richter Dairy Farm September 14, 2022 30: P9140121 Description: Looking north along the access road between Bull Branch (right) and the Hospital Barn (left center). Location: South of the Hospital Barn. Camera Direction: North Date/Time: September 14, 2022 9:55 AM 31: P9140122 Description: Looking north along the access road between Bull Branch (right) and the Hospital Barn (left center). Location: South of the Hospital Barn. Camera Direction: North Date/Time: September 14, 2022 9:55 AM Page 16 Richter Dairy Farm September 14, 2022 32: P9140123 Description: Looking north along Bull Branch from the access road over the waterway. Location: Access road over Bull Branch. Camera Direction: North Date/Time: September 14, 2022 9:56 AM 33: P9140124 Description: Looking south along Bull Branch from the access road over the waterway. Location: Access road over Bull Branch. Camera Direction: South Date/Time: September 14, 2022 9:56 AM Page 17 Richter Dairy Farm September 14, 2022 34: P9140125 Description: Looking north on the east side of Bull Branch. Note the slatted concrete cover over the 16'x40' pit and the curbing along the top west edge of the pit. Location: East side of the facility, west of the silos. Camera Direction: North Date/Time: September 14, 2022 9:56 AM 35: P9140126 Description: Looking south toward the Hay Barn (left) and the Pit 3 (right). Location: East side of the facilty, southwest of the silos. Camera Direction: South Date/Time: September 14, 2022 9:56 AM Page 18 Richter Dairy Farm September 14, 2022 36: P9140127 Description: Looking southwest across Bull Branch from the area northwest of the silos. Location: Northwest of the silos on the east side of the facility. Camera Direction: Southwest Date/Time: September 14, 2022 9:58 AM 37: P9140128 Description: Looking southwest across Bull Branch from the area northwest of the silos. Location: Northwest of the silos on the east side of the facility. Camera Direction: Southwest Date/Time: September 14, 2022 9:58 AM Page 19 Richter Dairy Farm September 14, 2022 38: P9140129 Description: Looking west across Bull Branch toward the Hospital Barn. western bank are visible (red arrows). Location: Northwest of the silos on the east side of the facility. Camera Direction: West Date/Time: September 14, 2022 9:58 AM The solids deposited along the 39: P9140130 Description: Looking west from the area northwest of the silos. Note the solid manure stacked (right) and the runoff flowpaths (blue arrow). Location: Northwest of the silos on the east side of the facility. Camera Direction: West Date/Time: September 14, 2022 9:58 AM Page 20 Richter Dairy Farm September 14, 2022 40: P9140131 Description: Looking southwest along the runoff pathways (blue arrows) from the solid manure stacked northwest of the silos to Pit 2. Location: Northwest of the silos on the east side of the facility. Camera Direction: Southwest Date/Time: September 14, 2022 9:59 AM 41: P9140132 Description: Solid manure stacked northwest of the silos. Location: Northwest of the silos on the east side of the facility. Camera Direction: North Date/Time: September 14, 2022 9:59 AM Page 21 Richter Dairy Farm September 14, 2022 42: P9140133 Description: Looking south along the feed bag on the east side of the silos. Location: Northeast of the silos on the east side of the facility. Camera Direction: South Date/Time: September 14, 2022 10:00 AM 43: P9140134 Description: Looking at the north end of the feed bag east of the silos (right), the north commodity barn (left) and a mound of organic solids. Location: North of the silos on the east side of the facility. Camera Direction: North Date/Time: September 14, 2022 10:00 AM Page 22 Richter Dairy Farm September 14, 2022 44: P9140135 Description: Looking northwest at the northwest corner of the bunker north of the silos on the east side of the facility. Location: North of the silos on the on east side of the facility. Camera Direction: Northwest Date/Time: September 14, 2022 10:01 AM 45: P9140136 Description: Looking north at the Commodity Barn north of the silos. Location: North of the silos on the east side of the facility. Camera Direction: North Date/Time: September 14, 2022 10:01 AM Page 23 Richter Dairy Farm September 14, 2022 46: P9140137 Description: Looking north at the Commodity Barn north of the silos. Location: North of the silos on the east side of the facility. Camera Direction: North Date/Time: September 14, 2022 10:01 AM 47: P9140138 Description: Looking northwest at the northwest corner of the bunker north of the silos on the east side of the facility. Location: North of the silos on the on east side of the facility. Camera Direction: Northwest Date/Time: September 14, 2022 10:01 AM Page 24 Richter Dairy Farm September 14, 2022 48: P9140139 Description: Feed loading area south of the silos. Location: South of the silos Camera Direction: Northwest Date/Time: September 14, 2022 10:01 AM 49: P9140140 Description: North side of the Hay Barn (left) and the adjacent Pit 3 (right). Location: North of the Hay Barn. Camera Direction: West Date/Time: September 14, 2022 10:03 AM Page 25 Richter Dairy Farm September 14, 2022 50: P9140141 Description: North side of the Hay Barn (left) and the adjacent Pit 3 (right). Location: North of the Hay Barn. Camera Direction: West Date/Time: September 14, 2022 10:03 AM 51: P9140142 Description: North side of the Hay Barn (left) and the adjacent Pit 3. (right). Location: North of the Hay Barn. Camera Direction: West Date/Time: September 14, 2022 10:03 AM Page 26 Richter Dairy Farm September 14, 2022 52: P9140143 Description: Looking south along the west side of Pit 3. Note the black hose connected to a pump at the south end (red arrow). Location: Northwest corner of Pit 3. Camera Direction: South Date/Time: September 14, 2022 10:03 AM 53: P9140144 Description: Potential flow path on the east bank of Bull Branch west of Pit 3. Location: East bank of Bull Branch, west of Pit 3. Camera Direction: Southwest Date/Time: September 14, 2022 10:04 AM Page 27 Richter Dairy Farm September 14, 2022 54: P9140145 Description: Area southwest of Pit 3. Note the black hose (red arrow). One end of the black hose is connected to a pump and other end is toward Bull Branch. Location: Southwest corner of Pit 3. Camera Direction: Southwest Date/Time: September 14, 2022 10:04 AM 55: P9140146 Description: Potential flow paths on the east bank of Bull Branch west of the the black hose attached to the pump. Location: Southwest corner of Pit 3. Camera Direction: Southwest Date/Time: September 14, 2022 10:04 AM Page 28 Richter Dairy Farm September 14, 2022 56: P9140147 Description: Potential flow paths on the east bank of Bull Branch west of the the black hose attached to the pump. Location: Southwest corner of Pit 3. Camera Direction: Southwest Date/Time: September 14, 2022 10:04 AM 57: P9140148 Description: Looking south along the west side of Pit 3. Note the black hose was picked up and moved over onto Pit 3 (red arrow). Location: Northwest corner of Pit 3. Camera Direction: South Date/Time: September 14, 2022 10:05 AM Page 29 Richter Dairy Farm September 14, 2022 58: P9140149 Description: Organic solids deposited on the road, culvert, and banks of Bull Branch. Location: East side of the box culvert over Bull Branch. Camera Direction: Southwest Date/Time: September 14, 2022 10:05 AM 59: P9140150 Description: Looking south along the west side of the Milking Parlor (left) toward the outdoor lot on the west side of the West Milk Cow Barn. Location: Northwest of the Milking Parlor. Camera Direction: South Date/Time: September 14, 2022 10:11 AM Page 30 Richter Dairy Farm September 14, 2022 60: P9140151 Description: Looking south along the outdoor lot on the west side of the West Milk Cow Barn. Location: North end of the outdoor lot on the west side of the West Milk Cow Barn. Camera Direction: South Date/Time: September 14, 2022 10:11 AM 61: P9140152 Description: White pipe protruding from the east side of the roadside ditch adjacent to the entrance to the facility. Location: South side of entrance on west side of the facility. Camera Direction: Down Date/Time: September 14, 2022 10:11 AM Page 31 Richter Dairy Farm September 14, 2022 62: P9140153 Description: Potential flow path from outdoor lot on the west side of the West Milk Cow Barn to the roadside ditch. Location: West side of the facility, west of the West Milk Cow Barn. Camera Direction: South Date/Time: September 14, 2022 10:12 AM 63: P9140154 Description: Potential flow path from outdoor lot on the west side of the West Milk Cow Barn to the roadside ditch. Location: West side of the facility, west of the West Milk Cow Barn. Camera Direction: South Date/Time: September 14, 2022 10:12 AM Page 32 Richter Dairy Farm September 14, 2022 64: P9140155 Description: Potential flow path from outdoor lot on the west side of the West Milk Cow Barn to the roadside ditch. Location: West side of the facility, west of the West Milk Cow Barn. Camera Direction: South Date/Time: September 14, 2022 10:12 AM 65: P9140156 Description: Blue pipe protruding from the east side of the roadside ditch. Location: West side of the facility, west of the West Milk Cow Barn. Camera Direction: Date/Time: September 14, 2022 Page 33 Richter Dairy Farm September 14, 2022 66: P9140157 Description: Looking east toward the West Milk Cow Barn across the denuded outdoor lot. Note the blue pipe receiving roof gutter water (blue arrow). Location: West side of the facility, west of the West Milk Cow Barn. Camera Direction: East Date/Time: September 14, 2022 10:13 AM 67: P9140158 Description: Looking north along the roadside ditch from the south entrance. Location: South entrance on west side of the facility. Camera Direction: North Date/Time: September 14, 2022 10:14 AM Page 34 Richter Dairy Farm September 14, 2022 68: P9140159 Description: Looking north across the outdoor lot on the west side of the West Milk Cow Barn. Location: South entrance on the west side of the facility. Camera Direction: North Date/Time: September 14, 2022 10:14 AM 69: P9140160 Description: Looking northeast across the outdoor lot on the west side of the West Milk Cow Barn. Location: South entrance on the west side of the facility. Camera Direction: Northeast Date/Time: September 14, 2022 10:14 AM Page 35 Richter Dairy Farm September 14, 2022 70: P9140161 Description: Burnt vegetation and organic solids on ground in path on west side of fence west of Pit 4 ramp. Location: West side of the facility approximately 220 feet south of the south entrance. Camera Direction: Southeast Date/Time: September 14, 2022 10:15 AM 71: P9140162 Description: Burnt vegetation and organic solids on ground in path on west side of fence west of Pit 4 ramp. Location: West side of the facility approximately 220 feet south of the south entrance. Camera Direction: South Date/Time: September 14, 2022 10:15 AM Page 36 Richter Dairy Farm September 14, 2022 72: P9140163 Description: Roadside ditch along St. Rose Road. Location: West side of the facility approximately 220 feet south of the south entrance. Camera Direction: Southwest Date/Time: September 14, 2022 10:15 AM 73: P9140164 Description: Burnt vegetation and organic solids on ground in path on west side of fence west of Pit 4 ramp. Location: West side of the facility approximately 220 feet south of the south entrance. Camera Direction: East Date/Time: September 14, 2022 10:16 AM Page 37 Richter Dairy Farm September 14, 2022 74: P9140165 Description: Looking on the east side of the fence from photos 70 and 73 toward the ramp to Pit 4. Location: Southwest of the ramp to Pit 4. Camera Direction: Northeast Date/Time: September 14, 2022 10:16 AM 75: P9140166 Description: Looking on the east side of the fence from photos 70 and 73 toward the ramp to Pit 4. Location: Southwest of the ramp to Pit 4. Camera Direction: Northeast Date/Time: September 14, 2022 10:16 AM Page 38 Richter Dairy Farm September 14, 2022 76: P9140167 Description: Organic solids and pathway seen in photos 70 - 73. Location: Location: West side of the facility approximately 220 feet south of the south entrance. Camera Direction: Northwest Date/Time: September 14, 2022 10:16 AM 77: P9140168 Description: Looking north along fence line. Location: West side of the facility approximately 220 feet south of the south entrance. Camera Direction: North Date/Time: September 14, 2022 10:16 AM Page 39 Richter Dairy Farm September 14, 2022 78: P9140169 Description: Concrete within the Bull Branch channel. Location: Bull Branch approximately 100 feet northeast from the intersection of St. Rose Road and Holy Cross Lane. Camera Direction: Southeast Date/Time: September 14, 2022 10:19 AM 79: P9140170 Description: Organic solids and burnt vegetation along a path down to Bull Branch. Location: Approximately 100 feet southwest of the ramp to Pit 4. Camera Direction: Northwest Date/Time: September 14, 2022 10:19 AM Page 40 Richter Dairy Farm September 14, 2022 80: P9140171 Description: Potential flow path from photo 79 continuing southeast toward Bull Branch. Location: Approximately 100 feet southwest of the ramp to Pit 4. Camera Direction: Southeast Date/Time: September 14, 2022 10:19 AM 81: P9140172 Description: Potential flow path from photo 79 continuing southeast toward Bull Branch. Location: Approximately 100 feet southwest of the ramp to Pit 4. Camera Direction: Southeast Date/Time: September 14, 2022 10:19 AM Page 41 Richter Dairy Farm September 14, 2022 82: P9140173 Description: Potential flow path from photo 79 continuing southeast toward Bull Branch. Location: Approximately 100 feet southwest of the ramp to Pit 4. Camera Direction: Southeast Date/Time: September 14, 2022 10:19 AM 83: P9140174 Description: Looking north into Pit 4 along the ramp. Location: South of Pit 4. Camera Direction: North Date/Time: September 14, 2022 10:20 AM Page 42 Richter Dairy Farm September 14, 2022 84: P9140175 Description: Looking south toward the upslope portion of the path seen in photos 79-81. Note the organic solids on the ground (red arrow). Location: South of Pit 4. Camera Direction: Southwest Date/Time: September 14, 2022 10:20 AM 85: P9140176 Description: Looking south toward the upslope portion of the path seen in photos 79-81. Note the organic solids on the ground (red arrow). Location: South of Pit 4. Camera Direction: South Date/Time: September 14, 2022 10:20 AM Page 43 Richter Dairy Farm September 14, 2022 86: P9140177 Description: Looking north into Pit 4 along the ramp. Location: South of Pit 4. Camera Direction: North Date/Time: September 14, 2022 10:20 AM 87: P9140178 Description: Looking southwest from the southeast corner of the ramp to Pit 4. Location: Southeast corner of the ramp to Pit 4. Camera Direction: Southwest Date/Time: September 14, 2022 10:21 AM Page 44 Richter Dairy Farm September 14, 2022 88: P9140179 Description: Organic solids deposited on the fence on the east side of the ramp to Pit 4. Location: East side of the ramp to Pit 4. Camera Direction: Northwest Date/Time: September 14, 2022 10:21 AM 89: P9140180 Description: Organic solids deposited on the fence on the east side of the ramp to Pit 4. Location: East side of the ramp to Pit 4. Camera Direction: North Date/Time: September 14, 2022 10:22 AM Page 45 Richter Dairy Farm September 14, 2022 90: P9140181 Description: Potential flow path down the bank Bull Branch from the area on the east side of the ramp to Pit 4. Location: East of the ramp to Pit 4 west of Bull Branch. Camera Direction: East Date/Time: September 14, 2022 10:22 AM 91: P9140182 Description: Potential flow path down the bank Bull Branch from the area on the east side of the ramp to Pit 4. Location: East of the ramp to Pit 4 west of Bull Branch. Camera Direction: East Date/Time: September 14, 2022 10:22 AM Page 46 Richter Dairy Farm September 14, 2022 92: P9140183 Description: Potential flow path down the bank Bull Branch from the area on the east side of the ramp to Pit 4. Note the foam on the surface of the water. Location: East of the ramp to Pit 4 west of Bull Branch. Camera Direction: East Date/Time: September 14, 2022 10:22 AM 93: P9140184 Description: Upstream on Bull Branch. Note the foam on the surface of the water. Location: West side of Bull Branch east of the ramp to Pit 4. Camera Direction: Northeast Date/Time: September 14, 2022 10:22 AM Page 47 Richter Dairy Farm September 14, 2022 94: P9140185 Description: Downstream on Bull Branch. Note the foam on the surface of the water. Location: West side of Bull Branch east of the ramp to Pit 4. Camera Direction: Southeast Date/Time: September 14, 2022 10:22 AM 95: P9140186 Description: Downstream on Bull Branch. Note the foam on the surface of the water. Location: West side of Bull Branch east of the ramp to Pit 4. Camera Direction: Southeast Date/Time: September 14, 2022 10:22 AM Page 48 Richter Dairy Farm September 14, 2022 96: P9140187 Description: Looking east into Bull Branch. Note the foam on the surface on the water. Location: West bank of Bull Branch, East of Pit 4. Camera Direction: East Date/Time: September 14, 2022 10:23 AM 97: P9140188 Description: Looking east into Bull Branch. Note the foam on the surface on the water. Location: West bank of Bull Branch, East of Pit 4. Camera Direction: East Date/Time: September 14, 2022 10:23 AM Page 49 Richter Dairy Farm September 14, 2022 98: P9140189 Description: Looking at Pit 4 from the northeast corner. Location: Northeast corner of Pit 4 Camera Direction: West Date/Time: September 14, 2022 10:23 AM 99: P9140190 Description: Looking north from the northeast corner of Pit 4. Location: Northeast corner of Pit 4. Camera Direction: North Date/Time: September 14, 2022 10:24 AM Page 50 Richter Dairy Farm September 14, 2022 100: P9140191 Description: Looking northwest across the solids settling area north of Pit 4. of the concrete wall (red arrows). Location: Northeast of the northeast corner of Pit 4. Camera Direction: Northwest Date/Time: September 14, 2022 10:24 AM Note the manure solids on the top 101: P9140192 Description: Looking northwest across the solids settling area north of Pit 4. of the concrete wall (red arrows). Location: Northeast of the northeast corner of Pit 4. Camera Direction: Northwest Date/Time: September 14, 2022 10:24 AM Page 51 Note the manure solids on the top Richter Dairy Farm September 14, 2022 102: P9140193 Description: Manure flowing from the solids settling area into Pit 4. Location: Northeast corner of Pit 4. Camera Direction: Down Date/Time: September 14, 2022 10:24 AM 103: P9140194 Description: Looking Southwest across Pit 4 from the northeast corner of Pit 4. Location: Northeast corner of Pit 4. Camera Direction: Southwest Date/Time: September 14, 2022 10:24 AM Page 52 Richter Dairy Farm September 14, 2022 104: P9140195 Description: Looking Northwest across the north end of Pit 4. Location: Northeast corner of Pit 4. Camera Direction: Northwest Date/Time: September 14, 2022 10:24 AM 105: P9140196 Description: Looking Southwest across Pit 4 from the northeast corner of Pit 4. Location: Northeast corner of Pit 4. Camera Direction: Southwest Date/Time: September 14, 2022 10:24 AM Page 53 Richter Dairy Farm September 14, 2022 106: P9140197 Description: Looking northwest across the solids settling area north of Pit 4. Location: Northeast of the northeast corner of Pit 4. Camera Direction: Northwest Date/Time: September 14, 2022 10:24 AM 107: P9140198 Description: Looking north across the solids settling area north of Pit 4. Location: Northeast corner of Pit 4. Camera Direction: North Date/Time: September 14, 2022 10:24 AM Page 54 Richter Dairy Farm September 14, 2022 108: P9140199 Description: Looking northeast across the solids settling area north of Pit 4. Location: Northeast corner of Pit 4. Camera Direction: North Date/Time: September 14, 2022 10:24 AM 109: P9140200 Description: Looking east into Bull Branch. Note organic solids deposited in the channel ( red arrow). Location: Southeast of the East Milk Cow Barn. Camera Direction: East Date/Time: September 14, 2022 10:27 AM Page 55 Richter Dairy Farm September 14, 2022 110: P9140201 Description: Looking southeast into Bull Branch. Note organic solids deposited in the channel ( red arrow). Location: Southeast of the East Milk Cow Barn. Camera Direction: Southeast Date/Time: September 14, 2022 10:28 AM 111: P9140202 Description: Looking north along the east side of the outdoor concrete lot east of the East Milk Cow Barn. Note the manure solids on the top of and on the east side of the concrete wall (red arrows). Location: East of the East Milk Cow Barn. Camera Direction: North Date/Time: September 14, 2022 10:28 AM Page 56 Richter Dairy Farm September 14, 2022 112: P9140203 Description: Looking west at the east side of the outdoor concrete lot east of the East Milk Cow Barn. Note the manure solids on the top of and on the east side of the concrete wall (red arrows). Location: East of the East Milk Cow Barn. Camera Direction: West Date/Time: September 14, 2022 10:28 AM 113: P9140204 Description: Looking southwest toward the outdoor concrete lot east of the East Milk Cow Barn. Location: East of the East Milk Cow Barn. Camera Direction: Southwest Date/Time: September 14, 2022 10:29 AM Page 57 Richter Dairy Farm September 14, 2022 114: P9140205 Description: A blue pipe protruding from the west bank of Bull Branch. There was a small flow of clear water coming from the pipe. Location: East of the southeast corner of the East Milk Cow Barn Camera Direction: Down Date/Time: September 14, 2022 10:30 AM 115: P9140206 Description: A blue pipe protruding from the west bank of Bull Branch. There was a small flow of clear water coming from the pipe. Location: East of the southeast corner of the East Milk Cow Barn Camera Direction: Down Date/Time: September 14, 2022 10:30 AM Page 58 Richter Dairy Farm September 14, 2022 116: P9140207 Description: Looking west from the location of the blue pipe protruding from west bank of Bull Branch. Note the two blue pipes collecting roof gutter water. Location: East of East Milk Cow Barn. Camera Direction: West Date/Time: September 14, 2022 10:31 AM 117: P9140208 Description: Cracked concrete wall allowing manure to flow into channelized path to Bull Branch. Location: East side of the outdoor lot east of the East Milk Cow Barn. Camera Direction: West Date/Time: September 14, 2022 10:33 AM Page 59 Richter Dairy Farm September 14, 2022 118: P9140209 Description: Channelized flow path conveying liquid manure to Bull Branch. Location: East side of the outdoor lot east of the East Milk Cow Barn. Camera Direction: North Date/Time: September 14, 2022 10:33 AM 119: P9140210 Description: Cracked concrete wall allowing manure to flow into channelized path to Bull Branch. Location: East side of the outdoor lot east of the East Milk Cow Barn. Camera Direction: West Date/Time: September 14, 2022 10:33 AM Page 60 Richter Dairy Farm September 14, 2022 120: P9140211 Description: Channelized flow path conveying liquid manure to Bull Branch. Location: East side of the outdoor lot east of the East Milk Cow Barn. Camera Direction: North Date/Time: September 14, 2022 10:33 AM Page 61 Richter Dairy Farm September 14, 2022 121: P9140212 Description: Manure flowing in the channelized flow path to Bull Branch. Location: West bank of Bull Branch east of the East Milk Cow Barn. Camera Direction: South Date/Time: September 14, 2022 10:34 AM Page 62 Richter Dairy Farm September 14, 2022 122: P9140213 Description: Confluence of the channelized flow path conveying manure to Bull Branch. Location: Location: West bank of Bull Branch east of the East Milk Cow Barn. Camera Direction: Southeast Date/Time: September 14, 2022 10:34 AM Page 63 Richter Dairy Farm September 14, 2022 123: P9140214 Description: Confluence of the channelized flow path conveying manure to Bull Branch. Location: Location: West bank of Bull Branch east of the East Milk Cow Barn. Camera Direction: Southeast Date/Time: September 14, 2022 10:34 AM Page 64 Richter Dairy Farm September 14, 2022 124: P9140215 Description: Upstream along Bull Branch from the confluence of the channelized flow path. Location: West bank of Bull Branch east of the East Milk Cow Barn. Camera Direction: North Date/Time: September 14, 2022 10:34 AM Page 65 Richter Dairy Farm September 14, 2022 125: P9140216 Description: Downstream along Bull Branch from the confluence of the channelized flow path. Location: West bank of Bull Branch east of the East Milk Cow Barn. Camera Direction: South Date/Time: September 14, 2022 10:34 AM Page 66 Richter Dairy Farm September 14, 2022 126: P9140217 Description: Error photo Date/Time: September 14, 2022 127: P9140218 Description: Closeup of manure flowing into Bull Branch from the channelized flow path. Location: The confluence of the channelized flow path and Bull Branch. Camera Direction: Down Date/Time: September 14, 2022 10:37 AM Page 67 Richter Dairy Farm September 14, 2022 128: P9140219 Description: Closeup of manure flowing into Bull Branch from the channelized flow path. Location: The confluence of the channelized flow path and Bull Branch. Camera Direction: Down Date/Time: September 14, 2022 10:37 AM 129: P9140220 Description: Closeup of manure flowing into Bull Branch from the channelized flow path. Location: The confluence of the channelized flow path and Bull Branch. Camera Direction: Down Date/Time: September 14, 2022 10:37 AM Page 68 Richter Dairy Farm September 14, 2022 130: P9140221 Description: Closeup of manure flowing into Bull Branch from the channelized flow path. Location: The confluence of the channelized flow path and Bull Branch. Camera Direction: Down Date/Time: September 14, 2022 10:37 AM 131: P9140222 Description: Closeup of manure flowing into Bull Branch from the channelized flow path. Location: The confluence of the channelized flow path and Bull Branch. Camera Direction: Down Date/Time: September 14, 2022 10:37 AM Page 69 Richter Dairy Farm September 14, 2022 132: P9140223 Description: Looking east across the culvert for the access road on the north side of the facility. Location: West side of the access road culvert over Bull Branch. Camera Direction: East Date/Time: September 14, 2022 10:41 AM 133: P9140224 Description: Looking west across Bull Branch toward the channelized flow path. Location: East bank of Bull Branch, east of the East Milk Cow Barn. Camera Direction: West Date/Time: September 14, 2022 10:53 AM Page 70 Richter Dairy Farm September 14, 2022 134: P9140225 Description: Bones and decomposing animal carcasses on east side of Bull Branch. Location: West of Pit 5, east of Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:01 AM 135: P9140226 Description: Bones and decomposing animal carcasses on east side of Bull Branch. Location: West of Pit 5, east of Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:01 AM Page 71 Richter Dairy Farm September 14, 2022 136: P9140227 Description: Bones and decomposing animal carcasses on east side of Bull Branch. Location: West of Pit 5, east of Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:01 AM 137: P9140228 Description: Bones and decomposing animal carcasses on east side of Bull Branch. Location: West of Pit 5, east of Bull Branch. Camera Direction: Northwest Date/Time: September 14, 2022 11:01 AM Page 72 Richter Dairy Farm September 14, 2022 138: P9140229 Description: Bones and decomposing animal carcasses on east side of Bull Branch. Location: West of Pit 5, east of Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:01 AM 139: P9140230 Description: Looking west toward Bull Branch west of the area with bones and decomposing animal carcasses on east side Bull Branch. Location: West of Pit 5, east of Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:01 AM Page 73 Richter Dairy Farm September 14, 2022 140: P9140231 Description: Looking downstream along Bull Branch. Note the foam on the surface of the water. Location: East bank of Bull Branch, west of Pit 5. Camera Direction: South Date/Time: September 14, 2022 11:02 AM 141: P9140232 Description: Looking downstream along Bull Branch. Note the foam on the surface of the water. Location: East bank of Bull Branch, west of Pit 5. Camera Direction: South Date/Time: September 14, 2022 11:03 AM Page 74 Richter Dairy Farm September 14, 2022 142: P9140233 Description: Looking west across Bull Branch to the west bank. Location: East bank of Bull Branch, west of Pit 5. Camera Direction: South Date/Time: September 14, 2022 11:04 AM 143: P9140234 Description: Looking downstream along Bull Branch. Note the foam on the surface of the water. Location: East bank of Bull Branch, west of Pit 5. Camera Direction: South Date/Time: September 14, 2022 11:05 AM Page 75 Richter Dairy Farm September 14, 2022 144: P9140235 Description: Looking northeast across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: Northeast Date/Time: September 14, 2022 11:06 AM 145: P9140236 Description: Looking east across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: East Date/Time: September 14, 2022 11:06 AM Page 76 Richter Dairy Farm September 14, 2022 146: P9140237 Description: Looking east across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: East Date/Time: September 14, 2022 11:06 AM 147: P9140238 Description: Looking east across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: East Date/Time: September 14, 2022 11:06 AM Page 77 Richter Dairy Farm September 14, 2022 148: P9140239 Description: Looking southeast across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: Southeast Date/Time: September 14, 2022 11:06 AM 149: P9140240 Description: Looking east across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: East Date/Time: September 14, 2022 11:06 AM Page 78 Richter Dairy Farm September 14, 2022 150: P9140241 Description: Looking northeast across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: Northeast Date/Time: September 14, 2022 11:07 AM 151: P9140242 Description: Looking northeast across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: Northeast Date/Time: September 14, 2022 11:08 AM Page 79 Richter Dairy Farm September 14, 2022 152: P9140243 Description: Hose used to transfer manure from Pit 4 to Pit 5. Location: Southwest corner of Pit 5. Camera Direction: Northeast Date/Time: September 14, 2022 11:08 AM 153: P9140244 Description: Looking northeast across Pit 5 from the southwest side. Location: Southwest corner of Pit 5. Camera Direction: Northeast Date/Time: September 14, 2022 11:08 AM Page 80 Richter Dairy Farm September 14, 2022 154: P9140245 Description: Hose used to transfer manure from Pit 4 to Pit 5. Location: Southwest corner of Pit 5. Camera Direction: Down Date/Time: September 14, 2022 11:08 AM 155: P9140246 Description: Hose used to transfer manure from Pit 4 to Pit 5. Location: Southwest corner of Pit 5. Camera Direction: Down Date/Time: September 14, 2022 11:08 AM Page 81 Richter Dairy Farm September 14, 2022 156: P9140247 Description: Hose used to transfer manure from Pit 4 to Pit 5. Location: Southwest corner of Pit 5. Camera Direction: Down Date/Time: September 14, 2022 11:09 AM 157: P9140248 Description: Hose used to transfer manure from Pit 4 to Pit 5. Location: Southwest corner of Pit 5. Camera Direction: Down Date/Time: September 14, 2022 11:09 AM Page 82 Richter Dairy Farm September 14, 2022 158: P9140249 Description: Hose used to transfer manure from Pit 4 to Pit 5. Location: Southwest corner of Pit 5. Camera Direction: Down Date/Time: September 14, 2022 11:09 AM 159: P9140250 Description: Looking north across Pit 5 from the west end of the south side. Location: West end of the south side of Pit 5. Camera Direction: North Date/Time: September 14, 2022 11:09 AM Page 83 Richter Dairy Farm September 14, 2022 160: P9140251 Description: Looking northwest across Pit 5 from the west end of the south side. Location: West end of the south side of Pit 5. Camera Direction: Northwest Date/Time: September 14, 2022 11:09 AM 161: P9140252 Description: Looking northwest across Pit 5 from the west end of the south side. Location: West end of the south side of Pit 5. Camera Direction: Northwest Date/Time: September 14, 2022 11:09 AM Page 84 Richter Dairy Farm September 14, 2022 162: P9140253 Description: Looking north into the ramp to Pit 5 on the east side of Pit 5. Location: East end of the south side of Pit 5. Camera Direction: North Date/Time: September 14, 2022 11:10 AM 163: P9140254 Description: Looking north into the ramp to Pit 5 on the east side of Pit 5. Location: East end of the south side of Pit 5. Camera Direction: North Date/Time: September 14, 2022 11:10 AM Page 85 Richter Dairy Farm September 14, 2022 164: P9140255 Description: Looking west across the south end of Pit 5. Location: South end of the east side of Pit 5. Camera Direction: West Date/Time: September 14, 2022 11:11 AM 165: P9140256 Description: Looking west across the south end of Pit 5. Location: South end of the east side of Pit 5. Camera Direction: West Date/Time: September 14, 2022 11:11 AM Page 86 Richter Dairy Farm September 14, 2022 166: P9140257 Description: Looking west across the south end of Pit 5. Location: South end of the east side of Pit 5. Camera Direction: West Date/Time: September 14, 2022 11:11 AM 167: P9140258 Description: Manure application gun sitting east of Pit 5. Location: East side of Pit 5. Camera Direction: Northeast Date/Time: September 14, 2022 11:12 AM Page 87 Richter Dairy Farm September 14, 2022 168: P9140259 Description: Looking North along the east side of the facility from the northeast corner of Pit 5. Location: Northeast corner of Pit 5. Camera Direction: North Date/Time: September 14, 2022 11:12 AM 169: P9140260 Description: Looking east at the feed storage area from the culvert over Bull Branch. Location: Access road culvert over Bull Branch. Camera Direction: East Date/Time: September 14, 2022 11:17 AM Page 88 Richter Dairy Farm September 14, 2022 170: P9140261 Description: Sample S01 taken at the north end of the facility Location: Bull Branch at the north end of the facility. Camera Direction: Down Date/Time: September 14, 2022 11:45 AM 171: P9140262 Description: Sample S01 taken at the north end of the facility Location: Bull Branch at the north end of the facility. Camera Direction: Down Date/Time: September 14, 2022 11:45 AM Page 89 Richter Dairy Farm September 14, 2022 172: P9140263 Description: Water flowing south into the access road culvert over Bull Branch. Location: North side of the access road culvert over Bull Branch. Camera Direction: East Date/Time: September 14, 2022 11:49 AM 173: P9140264 Description: Water flowing out of the acces road culvert over Bull Branch. Location: South side of the access road culver over Bull Branch. Camera Direction: Southeast Date/Time: September 14, 2022 11:49 AM Page 90 Richter Dairy Farm September 14, 2022 174: P9140265 Description: Water flowing out of the acces road culvert over Bull Branch. Note the water snake in the waterway. Location: South side of the access road culver over Bull Branch. Camera Direction: Southeast Date/Time: September 14, 2022 11:49 AM 175: P9140266 Description: Solids near Bull Branch near the outlet of the the acces road culvert over Bull Branch. Location: South side of the access road culver over Bull Branch. Camera Direction: Down Date/Time: September 14, 2022 11:49 AM Page 91 Richter Dairy Farm September 14, 2022 176: P9140267 Description: Water flowing out of the acces road culvert over Bull Branch. Note the water snake in the waterway. Location: South side of the access road culver over Bull Branch. Camera Direction: Southeast Date/Time: September 14, 2022 11:50 AM 177: P9140268 Description: Sampling point S02. The concluence of the channelized manure flow path and Bull Branch. Location: The concluence of the channelized manure flow path and Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:54 AM Page 92 Richter Dairy Farm September 14, 2022 178: P9140269 Description: Sampling point S02. The concluence of the channelized manure flow path and Bull Branch. Location: The concluence of the channelized manure flow path and Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:54 AM 179: P9140270 Description: Sample S02. Location: The concluence of the channelized manure flow path and Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:58 AM Page 93 Richter Dairy Farm September 14, 2022 180: P9140271 Description: Sample S02. Location: The concluence of the channelized manure flow path and Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:58 AM 181: P9140272 Description: Sample S02. Location: The concluence of the channelized manure flow path and Bull Branch. Camera Direction: West Date/Time: September 14, 2022 11:58 AM Page 94 Richter Dairy Farm September 14, 2022 182: P9140273 Description: Fill placed by the operator to prevent further discharges of manure. Location: Cracked concrete wall east of the East Milk Cow Barn. Camera Direction: West Date/Time: September 14, 2022 11:59 AM 183: P9140274 Description: Fill placed by the operator to prevent further discharges of manure. Note the channelized flow path to the left. Location: Cracked concrete wall east of the East Milk Cow Barn. Camera Direction: Down Date/Time: September 14, 2022 11:59 AM Page 95 Richter Dairy Farm September 14, 2022 APPENDIX C UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 9/27/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Christina Rice, Chemist Rice.Christina@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: Ammonia N DA, Distilled Report Name: 2209004 Ammonia N DA, Distilled FINAL Sep 27 22 1214 Page 1 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Reported: Sep-27-22 12:14 Method: Analysis: Analyte SM 4500-H+ B in Water Ammonia N DA, Distilled Ammonia as N Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 Ammonia N DA, Distilled FINAL Sep 27 22 1214 Page 2 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 12:14 ANALYSIS CASE NARRATIVE GENERAL INFORMATION: Results are reported for the following samples. LabNumber 2209004-01 2209004-02 2209004-03 SampleName S01 S02 B01 LogMatrix Water Water Water Received 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM Analysis Ammonia N DA, Distilled Ammonia N DA, Distilled Ammonia N DA, Distilled Sample Login Incident Reports (IRs) and Client Communications: (CCs): 2209004 Client Contact ID# 30516: Client notified of field blank result. Analyst: Christina Rice, Rice.Christina@epa.gov Holding Times: All holding times were met except for any listed below. Sample Analysis The samples were analyzed using the following SOP(s). Analysis Ammonia N DA, Distilled Code AIG029B v9 SpecificMethod SM 4500-H+ B QUALITY CONTROL: All quality control audits were within ASB limits or did not result in qualification of the data except for any listed below. Refer to Flag/Qualifiers column in sample results section and the Notes and Definitions section at the end of this report for any flagging information. Also, refer to the Analyst Notes section for any additional information or notes. Report Name: 2209004 Ammonia N DA, Distilled FINAL Sep 27 22 1214 Page 3 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett B22I022-DUP1 Source: 2209004-01 %RPD for Ammonia as N (32%) was outside acceptance limits (14%) for Ammonia N DA, Distilled. ANALYST NOTES: Additional Analysis Information: B22I022-MS1 had a stick removed prior to distillation. B22I022-DUP1 met absolute difference criteria. Reported: Sep-27-22 12:14 Report Name: 2209004 Ammonia N DA, Distilled FINAL Sep 27 22 1214 Page 4 of 8 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l vPawxgyez5{zo|f}z8~ Page 6 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 12:14 S01 (2209004-01) Analyte Ammonia as N S02 (2209004-02) Analyte Ammonia as N B01 (2209004-03) Analyte Ammonia as N Ammonia Nitrogen, SM4500B & H (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Result Flags / Qualifiers MDL Reporting Limit 0.41 [D] 0.16 0.20 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I022 Matrix: Water Sampled: Sep-14-22 11:58 Result Flags / Qualifiers MDL Reporting Limit 46.6 3.20 4.00 Received: Sep-15-22 10:33 Units mg/L Dilution 20 Batch B22I022 Matrix: Water Sampled: Sep-14-22 12:04 Result Flags / Qualifiers MDL Reporting Limit U 0.16 0.20 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I022 Prepared Sep-20-22 Analyzed Sep-20-22 Prepared Sep-20-22 Analyzed Sep-20-22 Prepared Sep-20-22 Analyzed Sep-20-22 Report Name: 2209004 Ammonia N DA, Distilled FINAL Sep 27 22 1214 Page 7 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Ammonia N DA, Distilled Result calculations based on MDL Notes and Definitions: [D] The absolute difference between the duplicate and source sample is less than the detection limit. The duplicate criteria is acceptable, even though the Relative Percent Difference (RPD) is not within the acceptance limits. U Not Detected NR Not Reported Q QC limit Exceeded Reported: Sep-27-22 12:14 Report Name: 2209004 Ammonia N DA, Distilled FINAL Sep 27 22 1214 Page 8 of 8 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 9/29/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Colin Breslin, Chemist breslin.colin@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: BOD Report Name: 2209004 BOD FINAL Sep 29 22 0716 Page 1 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Reported: Sep-29-22 07:16 Method: Analysis: Analyte SM 5210 B in Water BOD Biochemical Oxygen Demand Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 BOD FINAL Sep 29 22 0716 Page 2 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 07:16 ANALYSIS CASE NARRATIVE GENERAL INFORMATION: Results are reported for the following samples. LabNumber 2209004-01 2209004-02 2209004-03 SampleName S01 S02 B01 LogMatrix Water Water Water Received 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM Analysis BOD BOD BOD Sample Login Incident Reports (IRs) and Client Communications: (CCs): 2209004 Client Contact ID# 30516: Client notified of field blank result. Analyst: Colin Breslin, breslin.colin@epa.gov Holding Times: All holding times were met except for any listed below. Sample Analysis The samples were analyzed using the following SOP(s). Analysis BOD Code AIG006A V7 SpecificMethod SM 5210 B QUALITY CONTROL: All quality control audits were within ASB limits or did not result in qualification of the data except for any listed below. Refer to Flag/Qualifiers column in sample results section and the Notes and Definitions section at the end of this report for any flagging information. Also, refer to the Analyst Notes section for any additional information or notes. Report Name: 2209004 BOD FINAL Sep 29 22 0716 Page 3 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 07:16 B22I012-BS4 Recovery for Biochemical Oxygen Demand (62.4%) was outside acceptance limits (84.6-115.4%) for BOD. ANALYST NOTES: Additional Analysis Information: The low recovery of the GGA check solution (identified as QC code B22I012-BS4) was likely due to a weak seed solution. All sample results were flagged with a potential low bias. Report Name: 2209004 BOD FINAL Sep 29 22 0716 Page 4 of 8 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l vPawxgyez5{zo|f}z8~ Page 6 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 07:16 S01 (2209004-01) Analyte Biochemical Oxygen Demand S02 (2209004-02) Analyte Biochemical Oxygen Demand B01 (2209004-03) Analyte Biochemical Oxygen Demand BOD, 5 day, SM 5210 B (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Result Flags / Qualifiers MDL Reporting Limit 3 (BOD4), 2 (LCS), L Matrix: Water Sampled: Sep-14-22 11:58 Result Flags / Qualifiers MDL Reporting Limit 640 (LCS), L 2 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I012 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I012 Matrix: Water Sampled: Sep-14-22 12:04 Result Flags / Qualifiers MDL Reporting Limit 6 (LCS), L 2 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I012 Prepared Sep-15-22 Analyzed Sep-15-22 Prepared Sep-15-22 Analyzed Sep-15-22 Prepared Sep-15-22 Analyzed Sep-15-22 Report Name: 2209004 BOD FINAL Sep 29 22 0716 Page 7 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 07:16 Notes and Definitions: L (LCS) The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greater than the reported value. Blank spike recovery criteria not met for this analyte (BOD4) (BOD1) The samples did not have valid depletions of at least 2 mg/L dissolved oxygen (DO) from the initial day to the final day across the dilution series. BS4: Average GGA result of BS1, BS2, and BS3 used for final evaluation of QC limit. U Not Detected NR Not Reported Q QC limit Exceeded Report Name: 2209004 BOD FINAL Sep 29 22 0716 Page 8 of 8 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 9/29/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Colin Breslin, Chemist breslin.colin@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: Nitrate-Nitrite N DA, Enzymatic reduction Report Name: 2209004 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Sep 29 22 1359 Page 1 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Reported: Sep-29-22 13:59 Method: Analysis: Analyte NECi Method NO7-0003 in Water Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Sep 29 22 1359 Page 2 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 13:59 ANALYSIS CASE NARRATIVE GENERAL INFORMATION: Results are reported for the following samples. LabNumber 2209004-01 2209004-02 2209004-03 SampleName S01 S02 B01 LogMatrix Water Water Water Received 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM Analysis Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Sample Login Incident Reports (IRs) and Client Communications: (CCs): 2209004 Client Contact ID# 30516: Client notified of field blank result. Analyst: Colin Breslin, breslin.colin@epa.gov Holding Times: All holding times were met except for any listed below. Sample Analysis The samples were analyzed using the following SOP(s). Analysis Nitrate-Nitrite N DA, Enzymatic reduction Code AIG031B v6 SpecificMethod NECi Method NO7-0003 QUALITY CONTROL: All quality control audits were within ASB limits or did not result in qualification of the data except for any listed below. Refer to Flag/Qualifiers column in sample results section and the Notes and Definitions section at the end of this report for any flagging information. Also, refer to the Analyst Notes section for any additional information or notes. Report Name: 2209004 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Sep 29 22 1359 Page 3 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 13:59 Report Name: 2209004 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Sep 29 22 1359 Page 4 of 8 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l vPawxgyez5{zo|f}z8~ Page 6 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-29-22 13:59 S01 (2209004-01) Analyte Nitrate-Nitrite N S02 (2209004-02) Analyte Nitrate-Nitrite N B01 (2209004-03) Analyte Nitrate-Nitrite N Nitrate-Nitrite Nitrogen, Nitrate Reductase, NECi Method N07-0003 (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Result Flags / Qualifiers MDL Reporting Limit U 0.07 0.10 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I026 Prepared Sep-22-22 Analyzed Sep-22-22 Matrix: Water Sampled: Sep-14-22 11:58 Result Flags / Qualifiers MDL Reporting Limit U 0.07 0.10 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I026 Prepared Sep-22-22 Analyzed Sep-22-22 Matrix: Water Sampled: Sep-14-22 12:04 Result Flags / Qualifiers MDL Reporting Limit U 0.07 0.10 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I026 Prepared Sep-22-22 Analyzed Sep-22-22 Report Name: 2209004 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Sep 29 22 1359 Page 7 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Results Reported to MDL: Nitrate-Nitrite N DA, Enzymatic reduction Result calculations based on MDL Notes and Definitions: U Not Detected NR Not Reported Q QC limit Exceeded Reported: Sep-29-22 13:59 Report Name: 2209004 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Sep 29 22 1359 Page 8 of 8 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 9/27/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Edgar Santiago, Analyst santiago.edgar@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: TKN DA Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 1 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Reported: Sep-27-22 14:20 Method: Analysis: Analyte EPA 351.2 in Water TKN DA Total Kjeldahl Nitrogen Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 2 of 9 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l vPawxgyez3{zo|f}z9~ Page 4 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:20 S01 (2209004-01) Analyte Total Kjeldahl Nitrogen S02 (2209004-02) Analyte Total Kjeldahl Nitrogen B01 (2209004-03) Analyte Total Kjeldahl Nitrogen Total Kjeldahl Nitrogen, EPA 351.2 (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Result Flags / Qualifiers MDL Reporting Limit 1.31 0.30 0.50 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I019 Matrix: Water Sampled: Sep-14-22 11:58 Result Flags / Qualifiers MDL Reporting Limit 69.5 3.00 5.00 Received: Sep-15-22 10:33 Units mg/L Dilution 10 Batch B22I019 Matrix: Water Sampled: Sep-14-22 12:04 Result Flags / Qualifiers MDL Reporting Limit U 0.30 0.50 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I019 Prepared Sep-19-22 Analyzed Sep-19-22 Prepared Sep-19-22 Analyzed Sep-19-22 Prepared Sep-19-22 Analyzed Sep-19-22 Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 5 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:20 Batch 22I1902 - B22I019 Cal Standard (22I1902-CAL1) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL2) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL3) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL4) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL5) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL6) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL7) Analyte Total Kjeldahl Nitrogen Cal Standard (22I1902-CAL8) Analyte Total Kjeldahl Nitrogen, EPA 351.2 (modified) - Quality Control US EPA Region 5 LSASD Analytical Services Branch Result 0.0040 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result 0.31 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 0.2500 %REC 123% %REC Limits RPD RPD Limit Result 0.50 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 0.5000 %REC 100% %REC Limits RPD RPD Limit Result 0.95 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 1.000 %REC 95% %REC Limits RPD RPD Limit Result 1.96 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 2.000 %REC 98% %REC Limits RPD RPD Limit Result 2.51 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 2.500 %REC 100% %REC Limits RPD RPD Limit Result 5.03 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 5.000 %REC 101% %REC Limits RPD RPD Limit Result Flags / Qualifiers MDL Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result %REC %REC Limits RPD RPD Limit Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 6 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:20 Total Kjeldahl Nitrogen, EPA 351.2 (modified) - Quality Control US EPA Region 5 LSASD Analytical Services Branch Batch 22I1902 - B22I019 Cal Standard (22I1902-CAL8) Analyte Total Kjeldahl Nitrogen Calibration Blank (22I1902-CCB1) Analyte Total Kjeldahl Nitrogen Calibration Blank (22I1902-CCB2) Analyte Total Kjeldahl Nitrogen Calibration Check (22I1902-CCV1) Analyte Total Kjeldahl Nitrogen Calibration Check (22I1902-CCV2) Analyte Total Kjeldahl Nitrogen Initial Cal Blank (22I1902-ICB1) Analyte Total Kjeldahl Nitrogen Initial Cal Check (22I1902-ICV1) Analyte Total Kjeldahl Nitrogen Batch B22I019 - EPA 365.4 (TP) Result 9.99 Flags / Qualifiers Q MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 10.00 %REC 100% %REC Limits RPD RPD Limit Result -0.03 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result -0.0090 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result 5.11 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 5.000 %REC 102% %REC Limits 90-110 RPD RPD Limit Result 5.20 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 5.000 %REC 104% %REC Limits 90-110 RPD RPD Limit Result -0.05 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result 5.02 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 5.000 %REC 100% %REC Limits 90-110 RPD RPD Limit Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 7 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:20 Total Kjeldahl Nitrogen, EPA 351.2 (modified) - Quality Control US EPA Region 5 LSASD Analytical Services Branch Batch B22I019 - EPA 365.4 (TP) Blank (B22I019-BLK1) Analyte Total Kjeldahl Nitrogen LCS (B22I019-BS1) Analyte Total Kjeldahl Nitrogen Duplicate (B22I019-DUP1) Analyte Total Kjeldahl Nitrogen MRL Check (B22I019-MRL1) Analyte Total Kjeldahl Nitrogen Matrix Spike (B22I019-MS1) Analyte Total Kjeldahl Nitrogen Result U Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L %REC %REC Limits RPD RPD Limit Result 1.95 Flags / Qualifiers MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 2.000 %REC 97% %REC Limits 90-110 RPD RPD Limit Source: 2209004-01 Result Flags / Qualifiers 1.31 MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 1.31 %REC %REC Limits RPD 0.09 RPD Limit 17 Result 0.40 Flags / Qualifiers MDL Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result mg/L 0.5000 %REC 79% %REC Limits 73-140 RPD RPD Limit Source: 2209004-01 Result Flags / Qualifiers 3.52 MDL 0.30 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.50 mg/L 2.000 1.31 %REC 110% %REC Limits 90-110 RPD RPD Limit Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 8 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 U Not Detected NR Not Reported Q QC limit Exceeded Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Notes and Definitions Reported: Sep-27-22 14:20 Report Name: 2209004 TKN DA FINAL Sep 27 22 1420 Page 9 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 9/27/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Edgar Santiago, Analyst santiago.edgar@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: Total Phosphorus DA Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 1 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Reported: Sep-27-22 14:14 Method: Analysis: Analyte EPA 365.4 in Water Total Phosphorus DA Total Phosphorus Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 2 of 9 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l vPawxgyez3{zo|f}z9~ Page 4 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:14 S01 (2209004-01) Analyte Total Phosphorus S02 (2209004-02) Analyte Total Phosphorus B01 (2209004-03) Analyte Total Phosphorus Phosphorus, Colorimetric, EPA 365.4 (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Result Flags / Qualifiers MDL Reporting Limit 2.09 0.06 0.15 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I018 Matrix: Water Sampled: Sep-14-22 11:58 Result Flags / Qualifiers MDL Reporting Limit 21.5 0.60 1.50 Received: Sep-15-22 10:33 Units mg/L Dilution 10 Batch B22I018 Matrix: Water Sampled: Sep-14-22 12:04 Result Flags / Qualifiers MDL Reporting Limit U 0.06 0.15 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I018 Prepared Sep-19-22 Analyzed Sep-19-22 Prepared Sep-19-22 Analyzed Sep-19-22 Prepared Sep-19-22 Analyzed Sep-19-22 Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 5 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:14 Phosphorus, Colorimetric, EPA 365.4 (modified) - Quality Control US EPA Region 5 LSASD Analytical Services Branch Batch 22I1901 - B22I018 Cal Standard (22I1901-CAL1) Analyte Total Phosphorus Cal Standard (22I1901-CAL2) Analyte Total Phosphorus Cal Standard (22I1901-CAL3) Analyte Total Phosphorus Cal Standard (22I1901-CAL4) Analyte Total Phosphorus Cal Standard (22I1901-CAL5) Analyte Total Phosphorus Cal Standard (22I1901-CAL6) Analyte Total Phosphorus Cal Standard (22I1901-CAL7) Analyte Total Phosphorus Calibration Blank (22I1901-CCB1) Analyte Result 0.03 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result 0.16 Flags / Qualifiers Q MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.1500 %REC 109% %REC Limits RPD RPD Limit Result 0.30 Flags / Qualifiers Q MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.3000 %REC 101% %REC Limits RPD RPD Limit Result 0.72 Flags / Qualifiers Q MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.7500 %REC 97% %REC Limits RPD RPD Limit Result 0.98 Flags / Qualifiers Q MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 1.000 %REC 98% %REC Limits RPD RPD Limit Result 1.47 Flags / Qualifiers Q MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 1.500 %REC 98% %REC Limits RPD RPD Limit Result 3.03 Flags / Qualifiers Q MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 3.000 %REC 101% %REC Limits RPD RPD Limit Result Flags / Qualifiers MDL Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result %REC %REC Limits RPD RPD Limit Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 6 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:14 Phosphorus, Colorimetric, EPA 365.4 (modified) - Quality Control US EPA Region 5 LSASD Analytical Services Branch Batch 22I1901 - B22I018 Calibration Blank (22I1901-CCB1) Analyte Total Phosphorus Calibration Blank (22I1901-CCB2) Analyte Total Phosphorus Calibration Check (22I1901-CCV1) Analyte Total Phosphorus Calibration Check (22I1901-CCV2) Analyte Total Phosphorus Initial Cal Blank (22I1901-ICB1) Analyte Total Phosphorus Initial Cal Check (22I1901-ICV1) Analyte Total Phosphorus Batch B22I018 - EPA 365.4 (TP) Blank (B22I018-BLK1) Analyte Total Phosphorus Result -0.0050 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result -0.0050 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result 1.98 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 2.000 %REC 99% %REC Limits 92-112 RPD RPD Limit Result 2.01 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 2.000 %REC 100% %REC Limits 92-112 RPD RPD Limit Result -0.0050 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 0.000 %REC % %REC Limits RPD RPD Limit Result 1.99 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 2.000 %REC 100% %REC Limits 92-112 RPD RPD Limit Result U Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L %REC %REC Limits RPD RPD Limit Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 7 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Sep-27-22 14:14 Phosphorus, Colorimetric, EPA 365.4 (modified) - Quality Control US EPA Region 5 LSASD Analytical Services Branch Batch B22I018 - EPA 365.4 (TP) LCS (B22I018-BS1) Analyte Total Phosphorus Duplicate (B22I018-DUP1) Analyte Total Phosphorus MRL Check (B22I018-MRL1) Analyte Total Phosphorus Matrix Spike (B22I018-MS1) Analyte Total Phosphorus Result 0.96 Flags / Qualifiers MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 1.000 %REC 96% %REC Limits 88-114 RPD RPD Limit Source: 2209004-01 Result Flags / Qualifiers 2.09 MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 2.09 %REC %REC Limits RPD 0.09 RPD Limit 15 Result 0.14 Flags / Qualifiers MDL Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result mg/L 0.1500 %REC 92% %REC Limits 75-140 RPD RPD Limit Source: 2209004-01 Result Flags / Qualifiers 3.00 MDL 0.06 Prepared & Analyzed: Sep-19-22 Reporting Spike Source Limit Units Level Result 0.15 mg/L 1.000 2.09 %REC 91% %REC Limits 79-122 RPD RPD Limit Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 8 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 U Not Detected NR Not Reported Q QC limit Exceeded Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Notes and Definitions Reported: Sep-27-22 14:14 Report Name: 2209004 Total Phosphorus DA FINAL Sep 27 22 1414 Page 9 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 10/14/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Jocelyn Escobar, Chemist Escobar.Jocelyn@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: Solids, TDS Report Name: 2209004 Solids, TDS FINAL Oct 14 22 0853 Page 1 of 6 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Reported: Oct-14-22 08:53 Method: Analysis: Analyte SM 2540 C in Water Solids, TDS Total Dissolved Solids Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 Solids, TDS FINAL Oct 14 22 0853 Page 2 of 6 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l vPawxgyez3{zo|f}z6~ Page 4 of 6 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Reported: Oct-14-22 08:53 S01 (2209004-01) Analyte Total Dissolved Solids S02 (2209004-02) Analyte Total Dissolved Solids B01 (2209004-03) Analyte Total Dissolved Solids Dissolved Solids, SM 2540C (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Result Flags / Qualifiers MDL Reporting Limit 154 (DUP), J 20 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I016 Matrix: Water Sampled: Sep-14-22 11:58 Result Flags / Qualifiers MDL Reporting Limit 1580 20 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I016 Matrix: Water Sampled: Sep-14-22 12:04 Result Flags / Qualifiers MDL Reporting Limit U 20 Received: Sep-15-22 10:33 Units mg/L Dilution 1 Batch B22I016 Prepared Sep-19-22 Analyzed Sep-19-22 Prepared Sep-19-22 Analyzed Sep-19-22 Prepared Sep-19-22 Analyzed Sep-19-22 Report Name: 2209004 Solids, TDS FINAL Oct 14 22 0853 Page 5 of 6 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett J (DUP) U NR Q Notes and Definitions The identification of the analyte is acceptable; the reported value is an estimate. Duplicate precision criteria not met for this analyte Not Detected Not Reported QC limit Exceeded Reported: Oct-14-22 08:53 Report Name: 2209004 Solids, TDS FINAL Oct 14 22 0853 Page 6 of 6 Table of Contents UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY 536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605 ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID: Digital Signature of Primary Analyst: 2209004 Jocelyn Escobar Solids, TSS October 11, 2022 30688 Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature. Page 1 of 44 Client Project Name: Work Order Number: Richter Breese Project Number: [none] 2209004 1 Cover Page 2 Level I Report 3 QC Summary 4 Client Communications (CCs, IRs) 5 Checklist 6 Sample Prep and Supporting Data (Solids, TSS) 6.1 Bench Sheets (B22I021) 6.2 Batch Reagents (B22I021) 6.3 Standards (22F1322) 7 Data not Used Table of Contents Table of Contents 1 3 11 12 17 21 22 28 36 39 US EPA Region 5 LSASD Analytical Services Branch, 536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 Page 2 of 44 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Table of Contents Date: 10/11/2022 Title: To: From: ASB Data Report for Richter Breese Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Jocelyn Escobar, Chemist Escobar.Jocelyn@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Richter Breese Analyses included in this report: Solids, TSS Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 3 of 44 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Accredited Analyses included in this Report Table of Contents Reported: Oct-11-22 08:30 Method: Analysis: Analyte SM 2540 D in Water Solids, TSS Total Suspended Solids Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 4 of 44 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Table of Contents Reported: Oct-11-22 08:30 ANALYSIS CASE NARRATIVE GENERAL INFORMATION: Results are reported for the following samples. LabNumber 2209004-01RE1 2209004-02RE1 2209004-03RE1 SampleName S01 S02 B01 LogMatrix Water Water Water Received 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM 9/15/2022 10:33:00AM Analysis Solids, TSS Solids, TSS Solids, TSS Sample Login Incident Reports (IRs) and Client Communications: (CCs): 2209004 Client Contact ID# 30516: Client notified of field blank result. Analyst: Jocelyn Escobar, Escobar.Jocelyn@epa.gov Holding Times: All holding times were met except for any listed below. Sample Analysis The samples were analyzed using the following SOP(s). Analysis Solids, TSS Code AIG018 Version #7 SpecificMethod SM 2540 D QUALITY CONTROL: All quality control audits were within ASB limits or did not result in qualification of the data except for any listed below. Refer to Flag/Qualifiers column in sample results section and the Notes and Definitions section at the end of this report for any flagging information. Also, refer to the Analyst Notes section for any additional information or notes. Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 5 of 44 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett B22I021-DUP1 Source: 2209004-01RE1 %RPD for Total Suspended Solids (30.3%) was outside acceptance limits (10%) for Solids, TSS. Table of Contents Reported: Oct-11-22 08:30 Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 6 of 44 30192345156718974355871839517195743591854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 Table of Contents ?@A@<0 BBCDCCE :;07351;;<19839;74237=>491 43187MJDNONBCBBOCJPJEDQ 3718J ?9874<323=351F:;07351 45I78J3874>477=7 45I78Q91974J 179@ R49==9<923= 45I78KL674J G1517H 7S548T5J %#]!^#_% U"%#V'W'X'.&YZ-[\%)'. V"%V%/ \%(%'W%_^]/ +))%_*.^]/ b(4164221/,,02_"]c[c3 \e%#.]_%# \e%#.]_%# 66U%X`"($X.^!%W"#_ '(")&*+,,a V"%\%(%'W%_/ %d414221,/ V"%+))%_*./ %d414221,/a -.%/012342,,a 7"8/01235542,,1 f7= ?54R@4M74566718=J f7= dgd"d%#X_'. h21i,111&22Z221 f7= f7= !%#0X3'.j#k"'./ V%j"! !%#41l1, ;96S7m<J BBCDCCEnCO ;96S7MJ ;7SnOEnBBOOJE ;96S7K967J ;CO ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 25 ^bV 2 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 !'_X&cV 6 !'_X&c 6 cisV[ 25 c"!-Xd#XV[ 25 Q9843oJ ?9874 ;96S7598351N566718=J :S=84796 0oS347= b(4124222/9 %d4142211/a b(4124222/9 %d4214222/9 %d4214222/9 b(4124222/9 b(4124222/9 566718= dgh1l dgh6 dgh1l dgh6 dgh6 dgh1l dgh1l ;96S7m<J BBCDCCEnCB ;96S7MJ ;7SnOEnBBOOJP Q9843oJ ?9874 ;96S7K967J ;CB ;96S7598351N566718=J 51uL717 ;96S7566718=J 19 =3= [kk.'"sV[&V'X'!!%_ p5M8367qM9=r 0oS347= 566718= 25 b(4124222/9 dgh1l ^bV 2 %d4142211/5 dgh6 s'#"%4s'#'%sV[&Z.t]k"'(#%_('. 25 b(4124222/9 dgh1l Pvawgxey7z{oz|f}4z~4 Table of Contents Page 8 of 44 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 S01 (2209004-01RE1) Analyte Total Suspended Solids S02 (2209004-02RE1) Analyte Total Suspended Solids B01 (2209004-03RE1) Analyte Total Suspended Solids Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Table of Contents Reported: Oct-11-22 08:30 Total Suspended Solids, SM 2540 D (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Sep-14-22 11:45 Received: Sep-15-22 10:33 Result Flags / Qualifiers MDL Reporting Limit Units Dilution Batch 19 (DUP), J 5 mg/L 1 B22I021 Prepared Sep-20-22 Analyzed Sep-20-22 Matrix: Water Sampled: Sep-14-22 11:58 Received: Sep-15-22 10:33 Result Flags / Qualifiers MDL Reporting Limit Units Dilution Batch 550 5 mg/L 1 B22I021 Prepared Sep-20-22 Analyzed Sep-20-22 Matrix: Water Result Flags / Qualifiers U Sampled: Sep-14-22 12:04 MDL Reporting Limit Units 5 mg/L Received: Sep-15-22 10:33 Dilution 1 Batch B22I021 Prepared Sep-20-22 Analyzed Sep-20-22 Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 9 of 44 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Richter Breese Project Number: [none] Project Manager: Cheryl Burdett Notes and Definitions: J The identification of the analyte is acceptable; the reported value is an estimate. (DUP) Duplicate precision criteria not met for this analyte U Not Detected NR Not Reported Q QC limit Exceeded Table of Contents Reported: Oct-11-22 08:30 Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 10 of 44 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Date: Project: 10/11/2022 Richter Breese Quality Control Summary Analyst: Jocelyn Escobar Analyte: Total Suspended Solids Analysis: Solids, TSS QC Sample Name B22I021-BLK1 Result 0.00 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 3 5 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits B22I021-DUP1 Source: 2209004-01RE1 B22I021-SRM1 14.00 24.00 mg/L mg/L Q 3 5 19 30.3 10 23.90 100% 82-107 J (DUP) U NR Q Notes and Definitions The identification of the analyte is acceptable; the reported value is an estimate. Duplicate precision criteria not met for this analyte Not Detected Not Reported QC limit Exceeded B22I021-DUP1 Solids, TSS Total Suspended Solids Q Jocelyn Escobar Report Name: 2209004 Solids, TSS FINAL Oct 11 22 0830 Page 11 of 44 012212235265789  8 Table of Contents -5.670718293:4<:8=>?@ABCD --99>>::>>EE::88F5GO>H89I:J5@PBA9KL:EMQN:DCGAHKLIJ@BAKLMNDCAKLBLRSTTST1TT3TU12UV0WX ]<E8699FQY^P87FZ_P:P>Y7>`QYEO:P>aP9b[D5cOBPN?d8e5KCPf9B:CEKgQK:BLGHhieIJU@0B1A2KL3M\jNDBCLAKLRSBTLTRSTST1TTSTT31TTUT330TU2U330WUXV\WX k8QP7F.>?=P?>:>P9]E69Q^8F[5OP?85P9:EQ:GHlBNmnABopcgKBLqrDcsgBNBLRSTTST1TT3TU30U23WX 555OPt?u8H=8 v@DAKADDcLggw{AABgxgwKngKcwwfgfKAByzLS@BLCDLg <@@^PwL7d:SBuN>:{O@8bCxBNggKgAD M|e}KDAdMAwLmbDCsAg 5in5LBtw5cgPKB9L:KECQND:<sD6C~gDd~Egy7fHD{Spz 5P9:EQ:.E:8 5O>89Y:Y>ZO>EE~:>P89E9F 7_PP87Q`:E97FF87P7 .85?PQ97>:=E:Q>:P9 Q:>P9k868?: RST3ST1TT M@DxLDNpygAmMKLsCNdBDLggSqWp bKcxgDNMNDDCD f{BBggDKnLKDgdKwA@MAK|DLegBn @nNADKDCLxgoowKgAADfNKcmDsnBfND b2 cgxBDLgnwKDAdKLwAgwKBLLmzKLvDD LvDDrDgDKLCwfKDAzcgKBLz DwKAz 50152t35P@9@:JEMQ|:eJ:D:EQw^KA~zf8d9n: 5vD5ADtcgwAYAY8NQBs:8fFD87D?NPC9gx9w8gOwffAyz TzpvMXwLwDNh413j VzpvMvwfAD@BBNdKLwgBNh2R\j pffNBDNSbDKDoDNpi@BAKLMh33V0j pffNBDNSbDKDoDNpiS@XvqdwNh33VRj 5|{5qtb|Q:>WPX9q<X6Mq~b~|{E7IHU@BfADgDgxDwffNBfNKwgDnKDAdCDABowLdCDADcgvpq@p{qvz|LcDgxDcAKDLgxwCwccDfgDdgxD wwccggKKBBLLBKCNNNDDssDDCCggDDddBwncwgKLBBLgxBDnNwLBNBgxsDfNzinNBLsBfwdcdxKBgKBBCLDwAgxwDcgwKBfLfNKCBfNDNKwsgDDCNgBDsdgDgzy@fxDB{BCSpDzpeeii|{pp}}q@qeWqbv|{{qBLAyKnwL Q:>P9.E:8 Q:>P9.8?Q7>=:>P9 FF>:>P9EOQ:>P9k868?: 55tQ:>P9::EQ^~89: 5|{5Iti}FwFcg>KB:>LPC9wENDONDYYs8DCQg:D8dFBnw8LB7?gxPD9N9N8BOsfCDADcgwAANBsfDDNCgxwgwffAyz 5|{5qtb|FFW>:X>Pq9XMEqOb|Q{:>PIU9@<B6f~AD~gDEgx7DHwffNBfNKwgDnKDAdCDABowLdCDADcgvpq@p{qvz|LcDgxDcAKDLgxwCwccDfgDdgxD 611!"!#$1 18"%##&'(7)*#&+,5) Page 12 of 45412 012212235265789  8 Table of Contents --.2/071I23..J057121/6.712/5/-7.8/B9:;<8:=>?8>@1A/7BCD-2-./01206@7EA76/7F1D-21/57@G@1AH3.5116789:;<8:=>?8>@1A/7-2F020/0-/7 KLLMNMOPQRKTNMOPUQNV KLLMNMOPQRKTNMOPUVWTXMYNMOP ZZ[KLLMNMOPQRKTNMOPKNNQT\]VPN ZZ[^QMN_OXUMWYOWMNMOPUQNV 611!"!#$1 18"%##&'(7)*#&+,5) Page 13 of 42412 Table of Contents Breslin, Colin From: Sent: To: Cc: Subject: Atkinson, Benjamin Wednesday, September 21, 2022 10:27 AM Breslin, Colin Burdett, Cheryl RE: CAFO Inspection September 27 I appreciate it! I think Cheryl is getting some new water. From: Breslin, Colin <breslin.colin@epa.gov> Sent: Wednesday, September 21, 2022 10:26 AM To: Atkinson, Benjamin <atkinson.ben@epa.gov> Cc: Burdett, Cheryl <burdett.cheryl@epa.gov> Subject: RE: CAFO Inspection September 27 The preliminary report will be transmitted via our regular transmittal procedures. Let me know if you have any questions. I'm working on getting the report peer reviewed and the final approved report sent. All other blank checks in the lab were acceptable. It was peculiar, so I wanted to let you know before your next inspection next week. From: Atkinson, Benjamin <atkinson.ben@epa.gov> Sent: Wednesday, September 21, 2022 10:12 AM To: Breslin, Colin <breslin.colin@epa.gov> Cc: Burdett, Cheryl <burdett.cheryl@epa.gov> Subject: RE: CAFO Inspection September 27 Wow. From: Breslin, Colin <breslin.colin@epa.gov> Sent: Wednesday, September 21, 2022 10:10 AM To: Burdett, Cheryl <burdett.cheryl@epa.gov>; Wroble, Amanda <wroble.amanda@epa.gov> Cc: Atkinson, Benjamin <atkinson.ben@epa.gov>; Snyder, Robert <snyder.robert@epa.gov>; Awanya, Francis <awanya.francis@epa.gov> Subject: RE: CAFO Inspection September 27 Cheryl and Ben, I am going to send you a preliminary report for BOD. The sample identified as BO1 (presumably the field blank) had BOD above the reporting limit. You may wish to pickrup fresh water before your next inspection. From: Burdett, Cheryl <burdett.cheryl@epa.gov> Sent: Tuesday, September 20, 2022 12:52 PM To: Wroble, Amanda <wroble.amanda@epa.gov> Cc: Atkinson, Benjamin <atkinson.ben@epa.gov>; Snyder, Robert <snyder.robert@epa.gov>; Breslin, Colin <breslin.colin@epa.gov>; Awanya, Francis <awanya.francis@epa.gov> Subject: RE: CAFO Inspection September 27 I will thank you. Cheryl Burdett 1 Page 14 of 44 Table of Contents From: Wroble, Amanda <wroble.amanda@epa.gov> Sent: Tuesday, September 20, 2022 12:52 PM To: Burdett, Cheryl <burdett.cheryl@epa.gov> Cc: Atkinson, Benjamin <atkinson.ben@epa.gov>; Snyder, Robert <snyder.robert@epa.gov>; Breslin, Colin <breslin.colin@epa.gov>; Awanya, Francis <awanya.francis@epa.gov> Subject: RE: CAFO Inspection September 27 Hi Cheryl, Rob will be around to receive the samples on the 28th. Regarding BOD, taking the samples as late as you can on the 27th will be helpful in meeting the 48 hour holding time. If you need anything else, please let me know. Thanks, Amanda Amanda Wroble, Ph.D. Trace Metals Chemist & Group Leader and Sample Coordinator USEPA Region 5 LSASD Analytical Services Branch 536 S. Clark St. LABr10C, 10th Floor Chicago, IL 60605 (312) 353r0375 From: Wroble, Amanda Sent: Tuesday, September 20, 2022 10:16 AM To: Burdett, Cheryl <burdett.cheryl@epa.gov> Cc: Atkinson, Benjamin <atkinson.ben@epa.gov>; Snyder, Robert <snyder.robert@epa.gov>; Breslin, Colin <breslin.colin@epa.gov>; Awanya, Francis <awanya.francis@epa.gov> Subject: RE: CAFO Inspection September 27 Hi Cheryl, Let me check in with Rob and the analysts. Thanks, Amanda Amanda Wroble, Ph.D. Trace Metals Chemist & Group Leader and Sample Coordinator USEPA Region 5 LSASD Analytical Services Branch 536 S. Clark St. LABr10C, 10th Floor Chicago, IL 60605 (312) 353r0375 From: Burdett, Cheryl <burdett.cheryl@epa.gov> Sent: Tuesday, September 20, 2022 10:10 AM To: Wroble, Amanda <wroble.amanda@epa.gov>; Snyder, Robert <snyder.robert@epa.gov>; Breslin, Colin <breslin.colin@epa.gov>; Awanya, Francis <awanya.francis@epa.gov> Cc: Atkinson, Benjamin <atkinson.ben@epa.gov> Subject: CAFO Inspection September 27 2 Page 15 of 44 Table of Contents Hello Amanda: I am planning on conducting an inspection at a poultry operation on September 27 in Wisconsin. I may take samples would anyone be available on Wednesday, September 28 to receive the samples if I drop them off? Parameters include: BOD 5rday TDS TSS Nutrients: NitraterNitrite TKN Total Phosphorus AmmoniarNitrogen Sincerely, Cheryl Burdett 3 Page 16 of 44 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Work: 2209004 Data Verification Checklist Project: Richter Breese Analysis: Solids, TSS CRL SOP Used: AIG018 Version #7 Batch ID: General Information B22I021 Question # 1 Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt? 2 Was customer contact communication included? 3 Are all field sample ID numbers cross-referenced to the laboratory ID numbers? 4 Were all samples prepared and analyzed within holding times? Question # 5 6 7 8 9 10 11 12 13 Sample Results Were calculations checked? Question Were all analyte results checked? Were all results for soil and sediment samples reported on a dry weight basis? Were % moisture (or solids) reported for all soil and sediment samples? Other than those results < RL, were all other raw values bracketed by calibration standards? Are the RLs for each method analyte included in the laboratory data package? Are MDLs/RLs adjusted for dilutions? Were the raw data (for example, chromatograms, spectral data) reviewed? Were data associated with manual integrations flagged on the raw data? Question # 14 15 Question # Standards Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable? Batch Quality Control Question Print Date: 9/23/2022 Table of Contents Analyst Response (YES/ NO/ NA) YES <(6 YES YES Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES NA YES NA Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) PPagagee171 of 44 Work: 2209004 Project: Richter Breese Question # 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 Batch Quality Control Were appropriate type(s) of blanks analyzed? Question Were blanks analyzed at the appropriate frequency? Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures? Were blank concentrations <= MDL or RL, as applicable in the analytical SOP? Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps? Were LCSs/SRMs analyzed at the required frequency? Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria? Were the project/method specified analytes included in the MS? Were MS analyzed at the appropriate frequency? Were MS %Rs within the laboratory QC limits? Were appropriate analytical duplicates analyzed for each matrix? Were analytical duplicates analyzed at the appropriate frequency? Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria? Notes/Comments: The RPD of B22I021-DUP1 and the source sample 2209004-01RE1 was above QC limits. As a result, sample 2209004-01RE1 was flagged "J" as estimated. Were RLs analyzed at the appropriate frequency? Were RL recoveries within the laboratory QC limits? Question # 31 32 33 34 Calibration Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used? Question # 35 36 37 Calibration Verification Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte? Has the calibration curve been verified using an appropriate second source standard? Print Date: 9/23/2022 Table of Contents Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES NA NA NA YES YES NO NA NA Analyst Response (YES/ NO/ NA) YES NA NA YES Analyst Response (YES/ NO/ NA) NA NA NA PPagagee182 of 44 Work: 2209004 Project: Richter Breese Question # 38 39 Calibration Verification Question Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits? Question # 40 41 42 Quality Control QC limits in LIMS checked against the SOP? Question Were percent differences, recoveries, and the linearity within the QC limits specified in the method? Notes/Comments: See item # 28 Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit? Question # 43 44 Supporting Data Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used? Question # 45 46 47 48 49 50 Question # 51 Document Verification Question Is the MDL or RL study up-to-date for each reported analyte? Is documentation of the analyst's capability up-to-date and on file? Notes/Comments: DOC 29093 Are the procedures for compound/analyte identification documented? Are laboratory SOPs current and on file for the method performed? Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)? Notes/Comments: \\204.46.201.26\Root Share\R5CRL\Vol1\Projects (New File Structure)\Richter Breese\1. A&I\JEscobar\2209004\Balance #17\Solids, TSS Accreditation ANAB logo used appropriately? Question Analyst's Signature and Date*: Jocelyn Escobar Digitally signed by Jocelyn Escobar Date: 2022.10.03 15:15:57 -05'00' Print Date: 9/23/2022 Table of Contents Analyst Response (YES/ NO/ NA) NA NA Analyst Response (YES/ NO/ NA) YES NO YES Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES YES NA Analyst Response (YES/ NO/ NA) YES PPagagee193 of 44 Work: 2209004 Project: Richter Breese Table of Contents Reviewer's Signature and Date*: FRANCIS AWANYA Digitally signed by FRANCIS AWANYA Date: 2022.10.07 11:50:11 -05'00' *Reviewer Concurs with Analyst Responses Additional Notes/Comments (if applicable): Print Date: 9/23/2022 PPagagee204 of 44 Table of Contents Solids, TSS Page 21 of 44 BATCH B22I021 [TOC_1]Benchsheets[TTOabCl]e of Contents Page 22 of 44 Prepared Date: Analyst (initials): Sep-20-22 JE US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 9/20/2022 RESIDUE, NON-FILTERABLE (TSS) Batch Number: B22I021 Analyses Included On This Benchsheet Solids, TSS Filter ID Sample Number gU96I 2209004-01RE1 gU8PT 2209004-02RE1 gU96J 2209004-03RE1 gU96F B22I021-BLK1 gU96H B22I021-DUP1 gU96G B22I021-SRM1 Balance ID Number: #17 Oven ID Number: #10 Sample Volume (mL) 100 10 100 100 100 100 Spike ID Clean Filter Weight (g) Initial Weight of Dried Filter + Sample (g) 2 (if app) Final Source Sample Comments 0.1186 0.1204 0.1205 0.1196 0.1255 0.1251 0.1192 0.1192 0.1191 0.1190 0.1192 0.1190 - 0.1191 0.1209 0.1205 2209004-01RE1 22F1322 0.1195 0.1220 0.1219 - Dry Cycle #1 Date/Time IN - OUT: Dry Cycle #2 Date/Time IN - OUT: Dry Cycle #3 Date/Time IN - OUT: 09/20/22 10:44 AM - 09/20/22 11:47 AM 09/20/22 1:07 PM - 09/20/22 2:11 PM NA pH = 7 pH = 7 pH = 5 PREPARATION REAGENTS/STANDARDS/PIPETTES: 22F1322: TSS- SRM (Hardness) Prepared: Jun-13-22 21L0204: Filters - ProWeigh Prepared: Dec-02-21 Expires: Sep-03-24 Expires: Dec-02-26 Table of Contents Page 23 of 44 Batch Comments: Samples re-analyzed due to failing QC Page 1 of 1 %DODQFH &KHFN Table of Contents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age 24 of 44 Table of Contents By Jocelyn Escobar at 12:59 pm, Sep 21, 2022 Page 25 of 44 Table of Contents Page 26 of 44 ^ v}OE E u W D OE s o &OE}uW d}W hv]sW d]u }v W }vsW s l d]u s o X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW Table of Contents r K v X^ X WW X^ X WW hd r W ^s s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s Dry Cycle #1 By Jocelyn Escobar at 12:38 pm, Sep 23, 2022 Dry Cycle #2 The oven reached the set temperature at 13:07 By Jocelyn Escobar at 12:38 pm, Sep 23, 2022 Page 27 of 44 BATCH REAGENTS 21L0204 Table of Contents Page 28 of 44 Table of Contents Page 29 of 44 Table of Contents Page 30 of 44 Table of Contents Page 31 of 44 Table of Contents Page 32 of 44 Table of Contents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age 33 of 44 Table of Contents Page 34 of 44 Table of Contents Page 35 of 44 Table of Contents Page 36 of 44 Table of Contents Page 37 of 44 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 22F1322 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TSS- SRM (Hardness) Reference Material NA 500 5 ERA P316-507 ERA Catalog No. 507, WatR Pollution Hardness. C of A attached. Expires: Prepared: Prepared By: Department: Last Edit: Sep-03-24 Jun-13-22 ** Vendor ** A&I Jun-13-22 14:59 by CR Table of Contents Analyte Suspended Sediment Solids Total Suspended Solids CAS Number NA NA Concentration (ppm) 23.9 23.9 SRM Control Limits 82-107 82-107 PPagagee381 of 414  Data Not Used. By Jocelyn Escobar at 9:57 am, Sep 26, 2022 Table of Contents Page 39of44 Prepared Date: Analyst (initials): Sep-19-22 JE US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 9/19/2022 RESIDUE, NON-FILTERABLE (TSS) Batch Number: B22I017 Analyses Included On This Benchsheet Solids, TSS Filter ID Sample Number gU95Y 2209004-01 gU965 2209004-02 gU963 2209004-03 gU95Z B22I017-BLK1 gU961 B22I017-DUP1 gU960 B22I017-SRM1 Balance ID Number: #17 Oven ID Number: #10 Sample Volume (mL) 100 10 100 100 100 100 Spike ID Clean Filter Weight (g) Initial Weight of Dried Filter + Sample (g) 2 (if app) Final Source Sample 0.1187 0.1206 0.1206 0.1182 0.1240 0.1236 0.1179 0.1183 0.1181 0.1193 0.1194 0.1193 - 0.1185 0.1213 0.1210 2209004-01 22F1322 0.1200 0.1221 0.1218 - Dry Cycle #1 Date/Time IN - OUT: Dry Cycle #2 Date/Time IN - OUT: Dry Cycle #3 Date/Time IN - OUT: 09/19/22 10:35 AM - 09/19/22 11:35 AM 09/19/22 1:24 AM - 09/19/22 2:25 AM NA Comments pH = 7 pH = 7 pH = 5 PREPARATION REAGENTS/STANDARDS/PIPETTES: 22F1322: TSS- SRM (Hardness) Prepared: Jun-13-22 21L0204: Filters - ProWeigh Prepared: Dec-02-21 Expires: Sep-03-24 Expires: Dec-02-26 Table of Contents Page 40 of 44 Batch Comments: Data not used due to failed QC. By Jocelyn Escobar at 1:47 pm, Sep 23, 2022 Page 1 of 1 %DODQFH &KHFN Data not used By Jocelyn Escobar at 1:54 pm, Sep 23, 2022 Table of Contents %$/$1&( ,' '$7( $1$/<67 -RFHO\Q (VFREDU :(,*+7 6(7 ,' 752(01(5 6 1 :*7 6(7 &21),50(' <(6 :(,*+7 6(7 ,' :*7 6(7 &21),50(' 127( 6DYH DV H[FHO ILOH DQG SULQW WR SGI 6WRUH ERWK ILOHV LQ EDODQFH FKHFN IROGHUV RQ - ? 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By Jocelyn Escobar at 3:03 pm, Sep 23, 2022 Table of Contents ^ v}OE E u W D OE s o &OE}uW d}W hv]sW d]u }v W }vsW s l d]u s o X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW X^ X WW r K v X^ X WW X^ X WW hd r W ^s s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s X s] s Dry cycle #1 By Jocelyn Escobar at 3:03 pm, Sep 23, 2022 Dry cycle #2 By Jocelyn Escobar at 3:03 pm, Sep 23, 2022 Page 44 of 44 Pace Analytical Services, LLC 2231 W. Altorfer Drive Peoria, IL 61615 (800)752-6651 September 16, 2022 Sara Bossenbroek Eastern Research Group 14555 Avion Parkway Ste 200 Chantilly, VA 20151 Dear Sara Bossenbroek: Please find enclosed the analytical results for the 2 sample(s) the laboratory received on 9/14/22 1:35 pm and logged in under work order FI02787. All testing is performed according to our current TNI accreditations unless otherwise noted. This report cannot be reproduced, except in full, without the written permission of Pace Analytical Services, LLC. If you have any questions regarding your report, please contact your project manager. Quality and timely data is of the utmost importance to us. Pace Analytical Services appreciates the opportunity to provide you with analytical expertise . We are always trying to improve our customer service and we welcome you to contact the Director of Client Services, Lisa Grant, with any feedback you have about your experience with our laboratory at 309-683-1764 or lisa.grant@pacelabs.com. Sincerely, Chenise Lambert-Sykes Project Manager (314)432-0550 Chenise.Lambert-Sykes@pacelabs.com Customer #: 72-100934 www.pacelabs.com PaPgaege11ooff65 Pace Analytical Services, LLC 2231 W. Altorfer Drive Peoria, IL 61615 (800)752-6651 SAMPLE RECEIPT CHECK LIST Items not applicable will be marked as in compliance Work Order FI02787 YES YES YES YES YES NO YES YES YES YES YES YES YES YES NO YES YES NO NO Samples received within temperature compliance when applicable COC present upon sample receipt COC completed & legible Sampler name & signature present Unique sample IDs assigned Sample collection location recorded Date & time collected recorded on COC Relinquished by client signature on COC COC & labels match Sample labels are legible Appropriate bottle(s) received Sufficient sample volume received Sample containers received undamaged Zero headspace, <6 mm present in VOA vials Trip blank(s) received All non-field analyses received within holding times Short hold time analysis Current PDC COC submitted Case narrative provided Customer #: 72-100934 www.pacelabs.com PaPgaege22ooff65 Pace Analytical Services, LLC 2231 W. Altorfer Drive Peoria, IL 61615 (800)752-6651 Sample: FI02787-01 Name: Upstream Matrix: Waste Water - Grab ANALYTICAL RESULTS Sampled: 09/14/22 11:45 Received: 09/14/22 13:35 PO #: 0352.02.002/26 Parameter Result Unit Qualifier Prepared Dilution MRL Analyzed Analyst Microbiology - STL Fecal coliform bacteria 712 MPN/100 mL Sample: FI02787-02 Name: Downstream Matrix: Waste Water - Grab 09/14/22 16:43 1 10.0 09/14/22 16:43 NDM Sampled: 09/14/22 11:58 Received: 09/14/22 13:35 PO #: 0352.02.002/26 Parameter Result Unit Qualifier Prepared Dilution MRL Analyzed Analyst Microbiology - STL Fecal coliform bacteria >242,000 MPN/100 mL 09/14/22 16:43 1 100 09/14/22 16:43 NDM Method SM 9223B Method SM 9223B Customer #: 72-100934 www.pacelabs.com PaPgaege33ooff65 Pace Analytical Services, LLC 2231 W. Altorfer Drive Peoria, IL 61615 (800)752-6651 NOTES Specifications regarding method revisions, method modifications, and calculations used for analysis are available upon request. Please contact your project manager. * Not a TNI accredited analyte Memos 242,000 is the highest the lab can go for Fecal Coliform. Certifications CHI - McHenry, IL - 4314-A W. Crystal Lake Road, McHenry, IL 60050 TNI Accreditation for Drinking Water and Wastewater Fields of Testing through IL EPA Accreditation No. 100279 Illinois Department of Public Health Bacterial Analysis in Drinking Water Approved Laboratory Registry No. 17556 PIA - Peoria, IL - 2231 W. Altorfer Drive, Peoria, IL 61615 TNI Accreditation for Drinking Water, Wastewater, Solid and Hazardous Material Fields of Testing through IL EPA Accreditation No. 100230 Illinois Department of Public Health Bacterial Analysis in Drinking Water Approved Laboratory Registry No. 17553 Drinking Water Certifications/Accreditations: Iowa (240); Kansas (E-10338); Missouri (870) Wastewater Certifications/Accreditations: Arkansas (88-0677); Iowa (240); Kansas (E-10338) Solid and Hazardous Material Certifications/Accreditations: Arkansas (88-0677); Iowa (240); Kansas (E-10338) SPMO - Springfield, MO - 1805 W Sunset Street, Springfield, MO 65807 USEPA DMR-QA Program STL - Hazelwood, MO - 944 Anglum Rd, Hazelwood, MO 63042 TNI Accreditation for Wastewater, Solid and Hazardous Material Fields of Testing through KS KDHE Certification No. E-10389 TNI Accreditation for Wastewater, Solid and Hazardous Material Fields of Testing through IL EPA Accreditation No. - 200080 Illinois Department of Public Health Bacterial Analysis in Drinking Water Approved Laboratory, Registry No. 171050 Missouri Department of Natural Resources - Certificate of Approval for Microbiological Laboratory Service - No. 1050 Certified by: Chenise Lambert-Sykes, Project Manager Customer #: 72-100934 www.pacelabs.com PaPgaege44ooff65 Page 5 of 6 Page 6 of 6