Document 2REKz8YmZar6ZrM8yxDZVL48a

Element 3: Exposure Control (continued) This section contains the following documents: 1. Written Personal Protective Equipment Program 2. Training Documentation Tab 5 March 96 00 A 0407P4 CONFTDFNTTAi I j DO A 0407DS f.ONFTDFNTTAl Solvents/EDC1 1996 Chemical Resistant Personal Protective Equipment Written Program I. Introduction The primary objective of an Industrial Hygiene Program is to control health hazards. The control of health hazards can be accomplished through education and training, engineering technology, administrative measures and/or though the use of personal protective equipment (PPE). Selection of proper PPE requires consideration of intended use, toxicology database, chemical compatibility and service life, (i.e., how often the glove, suit or boot should be discarded). The PPE is first approved by the Division PPE Committee and then by plant/department supervision and the I.H. or Safety Contact before it is used in the block. The Safety section of job procedures and/or reference on the Safe Work Permit indicate the required PPE for the job task. These requirements apply to Dow employees and any contractors working in the area. Decontamination procedures, in-use storage conditions and disposal frequency are documented in this written program. II. List of Chemical Resistant Protective Equipment A. Gloves Manufacturer's Name & Description Mode] Number Material Of Construction Chemicals handled with gloves Pioneer StanSolv* Safety 4* Vallen Leather Driver Cotton Vinyl Impregnated LabCraft AK-22 4H TGD-258-L Nitrile Rubber Laminate Leather Cotton Vinyl/Cotton PVC All All (liner for EDC liquid) Petroleum Based Oils and Dirt Petroleum Based Oils and Dirt Petroleum Based Oils and Dirt All (lab gloves, incidental contact, not for immersion) The Edmont 4H glove is used as a liner in the Stansolv glove when prolonged exposure (>15 minutes) to liquid EDC is expected. Page 1 B. Boots Manufacturer's Name & Description Servus 12" Tingley Overshoe Tingley Model Number 22148 1302 98245 Material Of Construction Neoprene Neoprene Nitrile Blend Boots used to protect against these chemicals All All All C. General Service Weight Suits [i.e., rainsuits, disposables (such Tyvek, Saranex)] Manufacturer's Model Material Of Suits used to protect Name & Description Number Construction against these chemicals Neese 2 Piece Rainsuit Type 45 PVC/Nylon/PVC All / Splash Protection WorkRite Coveralls Nomex III None Kappler Disposable Coveralls 1681040 Tyvek Paper None - Clean Body Covering Kappler Saranex 23P Coveralls 77417 Saranex-Tyvek All / Splash Protection D. Heavy-Duty Suits [i.e., Acid Suits, Level A Suits] Manufacturer's M Name & Description LifeGuard Responder (Level A) LifeGuard Responder (Level B) StaSafe Gralite Accordion Suit Material Of Number Construction M-104-DYM Multi-Film Multi-Film LJ-105 PVC Suits used to protect against these chemicals All All HCL, AHCL III. Decontamination or Laundering Procedures A. Gloves Gloves are not decontaminated or laundered. B. Boots Boots are decontaminated by water washing or scrubbing with water and detergent. C. General Service Weight Suits PPE issued for splash protection must be decontaminated immediately after contamination occurs. Items issued for splash protection do not afford the necessary permeation resistance for prolonged contact with chemicals. Other equipment intended for re-use must be decontaminated before removal. Decontamination is accomplished by water washing or water and detergent washing. In some instances, a scrub brush will be needed to clean heavily soiled areas. Some of the equipment is used on a one time basis and is discarded after use. Nomex clothing must be laundered at the end of every work day. Nomex clothing that is too contaminated for laundering will be discarded. Page 2 A 0407.?7 CONFIDENT TAl D. Heavy-Duty Suits Decontamination is accomplished by water washing or water and detergent washing. In some instances, a scrub brush will be needed to clean heavily soiled areas. IV. In-Use Storage Practices A. Gloves Issued for personal use. As soon as heavy soiling (contamination) is evident during the course of the workday the gloves are discarded. Normally discarded at the end of the work day or sooner and not placed into storage. B. Boots Issued for personal use. As soon as heavy soiling (contamination) is evident during the course of the workday the boots may be discarded if they cannot be decontaminated. At the end of the workday, the boots are placed on the boot rack in the locker room where they are purged with plant air until the next time they are worn. Normal lifespan is 6 months to one year. C. General Service Weight Suits Issued for personal use. Rainsuits and Nomex are removed for laundering as soon as heavy soiling (contamination) is evident during the course of the workday. The Nomex suits (each employee is issued at least two pair) are stored in personal lockers. The Rainsuits or Nomex may be discarded if they cannot be decontaminated. Other one-time-use PPE (Tyvek or SaranexTyvek) is discarded at the end of the work day or sooner. These items are used on a per-day basis and in-use storage is normally not required. D. Heavy-Duty Suits Storage and re-use of these items is evaluated on an individual (per job) basis. Heavy-Duty suits may require frequent cleanings during the course of the job, and will be cleaned as per manufacturers instructions before storage. These suits are normally discarded dependent on contamination and/or wear. V. Disposal Frequency A. Gloves As needed dependent on contamination, usually at least once a shift or at the end of the shift. B. Boots As needed dependent on contamination, usually at least once every 6 months to a year. Page 3 on A 0407?ft CONF TDFNT T At. C. General Service Weight Suits As needed dependent on contamination and wear, usually at least once every 6 months to a year. Some suits are intended for disposal immediately after use. D. Heavy-Duty Suits As needed dependent on contamination and wear (disposal is evaluated on an individual (per job) basis). VI. Attachments The performance data for the chemical resistant equipment listed is attached. Industrial Hygiene Contact Date: // Plant Superintendent Next Review : 3/97 Chemical Resistant Personal Protective Equipment Written Program Permeation Resistance Data Chemical Protective Gloves Nitrile Gloves: The Edmont Solvex 37-175 Nitrile Glove (13" length, 15 mils thickness, with flock lining, cost ~$ 1/pair) is the primary chemical resistant glove used in the Louisiana Division. The Pioneer Stansolv AK-22 Nitrile Glove (12" length, ~ 15 mil thickness, with knit lining, cost ~$4/pair) is also used in those plants where gloves are worn for extended periods. Under these situations the knit lining is more comfortable because it absorbs hand perspiration and that is the reason for the higher cost. The nitrile gloves generally range in thickness from 11 mils to 22 mils. The thicker the glove the better the chemical resistance and physical strength, but finger dexterity decreases as the thickness increases. The 22 mil glove has 4 times the breakthrough time and 1/2 the permeation rate as the 11 mil. The 15 mil glove provides a good balance between chemical resistance and finger dexterity. Flat Film Gloves: Additional chemical protection is achievable with the use of the Edmont 4H or Silver Shield Glove. These ambidextrous gloves have superior chemical resistance to a wide variety of chemicals, and are very thin and light weight. Constructed using "Flat Film" technology (a film layer construction of polyethylene (PE)/Ethylene vinyl alcohol,/PE, cost $l/pair), they may serve as a liner for other gloves, or, can be used alone. Neoprene: The Edmont Scorpio 8-354 Neoprene Glove (14" length, heavy weight, knit lined, cost $3/pair) is designed for heavier duty work, provides some thermal protection, has a knit liner to absorb hand perspiration and is easy on and off, but has less finger dexterity than the Edmont Solvex 37-175 gloves. The chemical resistance performance is similar to the nitrile, but should not be used with certain chlorinated solvents (i.e.; carbon tetrachloride, chloroform, 1, 1, 1- trichloroethane, and perchloroethylene). Polyvinyl Chloride: The Best Hustler 725R PVC Glove (12" length, heavy weight, flock lined, cost $3/pair) is designed for heavier work duty, provides some thermal protection, and is easy on and off but again has less finger dexterity than the Edmont Solvex 37-175 glove. This glove has acceptable chemical resistance performance for 50% caustic and 10% hydrochloric or sulfuric acid (but not for high concentrated acids). It is generally not good for chlorinated solvents because it will remove the plasticizer from the glove and accelerates degradation. The Caustic Plant uses this glove to catch hot caustic samples because of the thermal protection. Permeation Data: The PPE Glove Permeation Table (attached) provides the approval status of the above gloves based upon information supplied by the manufacturer's of the gloves and the approval of the Page 5 DO A 04-0730 OONFTOFNT TAL LAD Industrial Hygiene Department. This information is based on immersion of the glove into the chemical or heavy contact to the chemical and work experience. Chemicals for which the gloves are un-acceptable for use or for which data is not available may present a problem in determining the appropriate glove for the task. In most cases, the problem can be resolved by examining: 1) the potential type of contact during the task (brief, splash, immersion, etc.), 2) the characteristics of the chemical itself (corrosive to the skin, absorbed through the skin in toxic amounts), 3) the historical experience with the glove usage in the plant. Many times, gloves are wom for jobs only as a precaution, or to protect against the possibility of incidental contact for a short duration. In these cases, the gloves selected should provide protection similar to their normal capabilities (if more than incidental contact occurs, the gloves would be removed immediately and decontaminated or replaced). The Safety Section of the Operating Procedures should specifically state the type of gloves needed for the job. Chemical Protective Clothing-General Service Suits Kappler Disposable Tyvek: The Kappler Disposable Tyvek coveralls are made of non-woven polyolefin filaments. They are primarily used in the Louisiana division when handling or working with various types of dusts, powders, dirt, oils and greases and other non corrosive, viscous liquids which will not penetrate the garment. Because of the economics ($2.44 ea.), these coveralls shall be disposed at the end of the work day. These coveralls do not have a protective barrier to liquids or gases. Kappler Polyethylene Coated Tyvek: The Kappler Polyethylene Coated Tyvek coveralls are made of a 1.25 mil polyethylene coating (yellow) applied to a Tyvek substrate. The protective barrier is good for inorganic acids and bases (i.e., chlorine gas, sodium hydroxide, sulfuric and hydrochloric acid), and heavy contact with oils and greases. It is not to be used with most organic chemicals although it would provide some splash protection. The garment has sewn seams that allow liquid penetration. Again because of economics ($4.44 ea.), these coveralls shall be disposed at the end of the work day. Kappler Saranex 23-P Laminated Tyvek: The Kappler Saranex 23-P Laminated Tyvek coveralls are made of a multi-layered barrier film (made by Dow Chemical) which is laminated to the Tyvek substrate. The barrier film is 2.0 mil thick and is composed of low density polyethylene (outer layer), ethylene vinyl acetate (glue layer), Saran (resin-based polymer barrier film) and finally glued with EVA to the substrate. It offers very good barrier protection to several chemicals typically used in the Louisiana Division (see attached list). The garment has a strapped overlay seam which is strong and prevents any liquid penetration. A storm flap over the zipper also prevents liquid penetration. In addition there is high tensile and tear strength and good puncture and abrasion resistance. It provides good splash protection and liquid holdout for those chemicals for which it is approved. Because of the cost of the overalls (~$20/ea.), it is used for selected jobs and then disposed of. It is considered "limited-use" clothing and not to be laundered for re-use. Neese Rainsuits: Page 6 HO A 040731 fONFTOFNTTAI / The Neese Rainsuits (2 piece suit or raincoat) are made of PVC/nylon/PVC layered construction V which is 12 mils thick. The material does provide some chemical resistance but is not intended to be a protective barrier. The garment has water proof seams and the jacket/coat has a storm flap. They are available with or without a hood. The primary use of this item is rain protection and would provide some protection for dirt, grime, oil, greases and incidental contact with chemicals. The suits can be laundered for reuse. Chemical Protection-Heavy Duty Suits The chemical performance data base for the following suits is available from the Division PPE Committee or the Industrial Hygiene Department. Sta-Safe Gralite 20 and Hi-Glo Acid Suits: The Sta-Safe Gralite 20 (gray) and Hi-Glo (yellow) Suits are made of a special polyvinyl chloride compound that gives protection to severe corrosive and abrasive conditions. The Gralite 20 fabric is 30 mils thick and the Hi-Glo is 20 mils thick and consequently somewhat lighter in weight. The 2 piece suit consists of a jacket and bib overall (with polypropylene webbing shoulder straps). The seams are reinforced and the flexibility of the material permits general ease of movement. The jacket sleeve is designed to provide a liquid-tight seal when properly used with the rigid plastic inset placed inside a glove gauntlet. An accessory is a chemical hood made of the Gralite 20 material with hard hat insert and a large permanent inner window and replaceable cover window. A full face air-line respirator can be used inside the hood. There is limited chemical resistant data on the Gralite 20 (see attached list) and no data on the Hi-Glo. The protective barrier is good for inorganic acids and bases i.e., chlorine gas, sulfuric acid (98%) and sodium hydroxide (50%) and should not be used with chlorinated solvents although it would provide some splash protection. These suits can be laundered and reused. The price of the Gralite 20 jacket/bib overalls is $118/$66, Hi-Glo jacket/bib overalls is $91/$48 and the Gralite 20 chemical hood is $180 respectively. Since there is limited chemical performance data, another very important factor is the plant's historical experience with the acid suit usage in that there have been no problems with suit deterioration or skin burns, etc.. Wheeler Aluminized PBI/Kevlar Suit: The Wheeler Aluminized PBI/Kevlar 2-piece suit is made of an aluminized film laminated to a PBI/Kevlar knit fabric. The 2-piece suit consists of a jacket and pants. The use of this suit is restricted for handling alkyl catalysts in the polyethylene plants because of the pyrophoric nature of the catalyst. The suit was recommended by Ethyl Corporation who is the supplier of the alkyl materials. The price of the 2 piece suit is $175. Page 7 04073/ DO A CONFT OfNT T Al In-house laboratory screening tests were performed by direct contact of the suit material with heptane and isopentane for 15 minutes. There was no visual evidence of deterioration or liquid penetration through the material. Responder Life Guard Level A Suit: The Responder Life Guard Level A totally encapsulated suit is made of a multi-film construction which provides excellent chemical resistance to a broad range of chemicals. This material exhibits no permeation breakthrough after 8 hours of exposure to the ASTM FI001 chemical test battery using the ASTM F739 permeation test protocol. An additional 100 chemicals have been tested with successful results other key features include light weight, ease of mobility, durable seams, double over-lapping storm flaps and excellent physical strength. The 40 mil PVC window comes with a 5 mil FEP Teflon overlay. The suit comes with a replaceable butyl gloves and silver shield glove liners. The price of the suit is $450 and is classified as a "limited use" apparel to be discarded when it becomes contaminated or shows signs of wear. Chemron Chemrel Max: The Chemron Chemrel Max Level A suit or coveralls are made of multi-film construction which provides excellent chemical resistance to a broad range of chemicals (similar as described in the Responder section and are also "limited use" apparel). The Chemrel Max 102 Level A suit is approved for the materials which are used in the Vinyl II plant. The Chemrel Max 203 coveralls are approved for the materials which are used in the Vector SBC plant. MSA Blue Max Level A Suit: The MSA Blue Max Level A totally encapsulated suit is made of a multi-film construction which provides excellent chemical resistance to a broad range of chemicals (similar as described in the Responder section and are also "limited use" apparel). The MSA Blue Max Level A Suit is approved for the materials which are used in the Glycol II plant with emphasis on ethylene oxide. The suit window has a 5 mil FEP Teflon overly to the 40 mil PVC underlens which provide protection against liquid EO. Page 8 DO A 040777 CONF T DFMT T AI f Kappler Saranex 23-P/Tyvek V Typical chemicals handled in LAD for which suit is approved A Chemicals not approved A methyl chloride * + carbon tetrachloride * + epichlorohydrin * + chloroform + mineral spirits perchloroethylene + styrene * + ethylene oxide + butadiene + toluene * methanol * methylene chloride + ethylene glycol ammonia anhydrous * --chlorine gas hydrogen chloride gas * hydrochloric acid (37%) * nitric acid (70%) * phosphoric acid (85%) * sulfur acid cone. * ammonium hydroxide (28%) * sodium hydroxide (50%) * ethylene glycol monobutyl ether - (Dowanol EB) 1,1,2,2 tetrachloroethane * + Vendor Data not available A ethylene dichloride + 1,1,1 trichloroethane 1,2 propylene oxide + cyclohexane benzene + xylene propylene dichloride + propylene chlorodydrin * vinyl chloride + misc. oil and grease * Corrosive to skin and/or toxic by absorption + Known or suspect carcinogen A Based on Chemical Resistance Performance Data from the Vendor Page 9 D 0 A (''40734 CONFTDFNTTAl ( Sta-Safe Gralite 20 Acid Suit Typical chemicals handled in LAD for which suit is approved A Chemicals not approved A Vendor Data not available A chlorine gas sodium hydroxide (50%) * cell effluent * sulfuric acid (98%) * methylene chloride + perchloroethylene + toluene * isopentane sec-Butyl Lithium * phosphoric acid * silicon tetrachloride * propylene oxide + propylene dichloride + hydrochloric acid * propylene chlorohydrin * formic acid * * Corrosive to skin and/or toxic by absorption + Known or suspect carcinogen A Based on Chemical Resistance Performance Data from the Vendor Page 10 DO A 040735 CONF TDFNTTAl INDUSTRIAL HYGIENE OPERATING DISCIPLINE GULF COAST INDUSTRIAL HYGIENE CENTER Louisiana Division AN OPERATING UNIT OF THE DOW CHEMICAL COMPANY Title Introduction Location Personal Protective Equipment Implementation Process The following is the Industrial Hygiene Operating Discipline implementation process for the Personal Protective Equipment Program. Lant51\ IH_Com\ oper_dis\3exp_cnt\3ppe2.doc Roles and Responsibilities See Appendix A. Technical Owner Bruce Heinze (xl8l7) Changes to theIH- 1) Industrial Hygiene contacts update IH-9 checklist 9 Checklist Supporting Documents (Location) 1) OSHA 29 CFR 1910.132 - .137 regulations (Industrial Hygiene) r Restrictedfor Use Within The Dow Chemical Company 00 A 0407.lt. r'0NjFrr)FNTTA| Technical Expert Appendix A: Roles and Responsibilities 3* ~l o >r1 us>j \f ODIT -Operating Discipline Implementation Team PIH - Plant Industrial Hygienist SIP - Standard Implementation Procedure Page 2 Technical Expert Appendix A: Roles and Responsibilities ODIT r PIH Plant Contact Plant File electronically at the Plant and Industrial Hygiene Ensure that all parties are notified of responsibilities. Adjust Compliance Checklist to reflect program requirements and review Comply with program elements. \ ODIT - Operating Discipline Implementation Team PIH - Plant Industrial Hygienist / Do any changes need to be made to the template? If no, complete \ Yes Submit written comments to the ODIT Team Page 3 I>0 A 0 4 0 7 3 8 C O N F ID E N T TA1 Technical Expert ODIT Coordinate comments to Tech. Expert A ppendix A . Roles and Responsibilities Review comments for technical correctness. Return comments t6 the ODIT Team Initiate MOC if necessary. PIH Plant Contact n Oo o^ n-i o M o Plant ODIT - Operating Discipline Implementation Team PIH - Plant Industrial Hygienist MOC - Management of Change Page 4 Operating Discipline 12 Industrial Hygiene (Place Plant Name Here) 12.3.3 Personal Protective Equipment Program 12.3 Exposure Control Introduction Information in this program reflects OSHA Standard 29 CFR 1910.132 through 1910.138 (April 6, 1994). Personal protective equipment (PPE) includes all clothing and other work accessories designed to create a barrier against workplace hazards. Workplace Hazard Assessment All personal protective equipment for this facility is selected based on the workplace hazard assessment in accordance with OSHA Standard 29 CFR 1910.132, Section (d)(2) (April 6, 1994). Selection Specific selections were based upon the potential health and safety hazards associated with job tasks within this facility and have been reviewed by the facility's Industrial Hygienist and Safety Professionals. PPE selections are task specific and are written in the facility's operating procedures or prestartup inspections. (Note: In a situation where operating procedures or prestartup inspections do not include a required workplace hazard assessment, a tool has been provided in PPE Appendix B.) Options for selection have been made available from the site's List of Acceptable PPE. All PPE used in this facility is listed in PPE Program Appendix A, which may be referenced when ordering PPE for this facility. . Training In accordance with OSHA 29 CFR 1910.132, PPE training will be conducted for all employees upon initial assignment and periodically thereafter. Topics will include: User responsibilities PPE inspection Use Donning/Doffmg Decontamination Limitations Location of the department PPE program Training will be the responsibility of the person named on this facility's Compliance Checklist. A copy of the training documentation will be forwarded to Industrial Hygiene Services for retention in the plant's file. Visitors will be informed of and provided the minimum PPE required Inspection All PPE items must be inspected visually before, during and after use for signs of deterioration, defect, damage, etc. Some equipment requires minimum inspection at specific intervals according to requiredprotocol. Included among these are; Hard Hats Respirators Damaged equipment will be discarded or repaired. Maintenance If PPE is found to be defective or damaged. (Select one) If PPE is disposable PPE is repairable, and user is authorized/certified to do repairs1 PPE is repairable and requires factory certified repairs Then Dispose of properly Repair item equal to or superior to the original manufacturer's specifications Return PPE to authorized repair agent l SCBA respirators, hard hats, and fall protection have specific certification restrictions for repairs Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-1 DO A 0407 4 0 CONFIDENT T A1 Operating Discipline 12 Industrial Hygiene Control (Place Plant Name Here) 12.3.3 Personal Protective Equipment, continued 12.3 Exposure Decontamination and Disposal In accordance with this facility and Industrial Hygiene policy, chemically-contaminated PPE must be decontaminated at a designated station prior to entering any control room, office, or eating area. At present, the designated decontamination stations in this facility are (Fill in designated areas, i.e.: safety shower/eyewash tailhoses). If an item cannot be sufficiently decontaminated, it must be disposed of as chemical waste in accordance with applicable environmental standards. After each use where PPE has been contaminated by hazardous substances, users of the contaminated PPE shall clean their PPE rinsing with copious quantities of water. Contaminated PPE which cannot be properly decontaminated must be disposed of as chemical waste in accordance with applicable environmental standards. Laundering This facility uses the following methods to clean contaminated and/or used PPE Select Yes/no Yes/no Yes/no Yes/no Options No laundering available Central Laundry Facility (in-plant) Laundry Contracted Laundry Comments Dispose of appropriately Communicate hazards appropriately Communicate hazards appropriately Material Safety Data Sheets will be sent if chemical contamination is suspected Storage When PPE is not in use, it is properly stored in a location free from contamination. Continued on next page f Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-2 nn A 040741 OONFTDFNTTAl Operating Discipline 12 Industrial Hygiene (Place Plant Name Here> 12.3 Exposure Control 12.3.3 Personal Protective Equipment, Continued Appendix A Approved Protective Equipment The following lists only PPE currently approved for use at this facility. Written, blockspecific job procedures indicate when and which PPE item must be wom (See imbedded example below). Hand Protection MSMS (Write in name and description ofhandprotection) Write MSMS # here Example: 1. Scooba #JPS 10B Cotton gloves 2. Edmont 29-875 (black) neoprene gloves, 19 mils size 8 size 10 size 11 3. Best 7005 "N-Dex", laboratory (blue) glove, 4.5 mils Small Med Large 2895810 147984 147988 147989 827 829 833 Foot and Leg Protection (Write in name and description offoot and leg protection) Example: 1. Servus #21629 steel toe, natural rubber boot black w/yellow toe size 6 size 7 (If this boot not appropriate for certain size 8 individuals, contact your Industrial size 9 Hygienist for assistance). size 10 size 11 size 12 2. Servus Neoprene III 422114 boot size 6 size 7 size 8 size 9 size 10 size 11 size 12 size 13 MSMS (Write MSMS# herefor each size) 74453 270630 74457 74458 74459 74463 74465 74467 61085 61086 61087 61088 61089 61091 61092 Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-3 On A 04074' 0NF7f)FNTTAl' Operating Discipline 12 Industrial Hygiene Control (Place Plant Same Here) 12.3.3 Personal Protective Equipment, Table 1,Continu d 123 Exposure Hearing Protection {Type in description ofeach type ofhearing protection in your department) Example: 1. Ear Plugs - E.A.R. Foam (yellow) 2. Ear Plugs - Howard Leight MAX Foam (orange) 3. QB2 band, foam plugs MSMS (type in MSMS numberfor each , type here) 4884 144284 128334 Eye, Face & Head Protection (Type in description ofeach type ofeye, face, and head protection in your department) Example: 1. American Optical Aerosite Safety glasses with Side Shields, clear lens, polycarbonate 54 mm 58 mm 2. American Allsafe #G21l-lOR monogoggle (green), tinted body, clear lens 3, American Allsafe #G211-13R Foggard monogogglefogged lens and body 4. American Allsafe monogoggle VPC (fits well over prescription glasses) 5. Encon #160 Series chemical splash goggle, gray body, clear lens (specify anti-fog) 6. Jackson JP-50 welding & burning goggles 7. Bullard hard hat - #302 8. Bullard #840M Visor (faceshield), clear acetate 9. Bullard #100G aluminum bracketforfaceshield 10. Ratchetfaceshield 11. Bullard #100G aluminum bracketforfaceshield MSMS (type in MSMS numberfor each type here) 60168 56256 2895880 49701 121040 122642 65385 4863 17340 23460 61287 23460 Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-4 DO A 040740 CONFTDFNTTAl Operating Discipline 12 Industrial Hygiene {Place Plant Name Here) 12.3.3 Personal Protective Equipment, Table 1,Continu d 12.3 Exposure Control Respiratory Protection Equipment (Type in description ofeach type ofrespirators and accessory protection in your department) MSMS (type in MSMS numberfor each type here) Example: respirators and accessories 1. Scott Air Pak 2.2 SCBA, pressure-demand 2. Scott-o-Vista #801548-04, Full-face Pressure-DemandAirline respiratorfacepiece 3. Scott-o- Vista SKA-pak #90005552, fullface pressuredemand w/S min. escape cylinder 96536 64082 74764 4. 3M 6000 series half-face respirator 6100 small 6200med 6300 Ig HEPA filters (2) Pre-filter Adapterfor 3M 6000 Filter adapter Organic Vapor Cartridges Acid Gas Cartridges 148337 148338 148339 132192 148333 148332 123456 1234567 Fall Protection {Type in name and description allfallprotection used in this department) Example: 1. RTCSafety harness #7430-PQ1 2. Rose #501437-6 Dyna Brake Lanyard MSMS {Type in MSMS numberfor equipment 74679 145163 Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-5 no A 040744 C-ONF tdfntt ai Operating Discipline 12 Industrial Hygiene Control (Place Plant Name Here) 12.3 Exposure ^ 12.3.3 Personal Protective Equipment, Table 1, Continued Body Protection (Type in name and description ofall body protection, including chemical and rain suits used in this department) Example: 1. Neese 45jacket (neoprene on nylon), w/hood 2. Neese 45 bib overalls, w/elastic suspenders 3. Kappler Frontline #80428 I pc. coverall w/zipperfront, elastic wrists, attached hood elastic ankles 4. Kappter Frontline #80434 1 pc. coverall w/zipperfront, elastic wrists, attached hood attached boots Sm Med Lg XL Sm Med Lg XL Med Lg XL Med Lg XL MSMS (Type in MSMS numberfor equipment) 268540 268510 268460 268420 134895 134896 134897 134898 144548 108504 108505 148440 148441 148442 Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-6 DO A 040745 CONFTDFNTTAi, Operating Discipline 12 Industrial Hygiene (Place Plant Name Here) 12.3.3 Personal Protective Equipment, Continued Appendix B Certification of Hazard Assessment 12.3 Exposure Control Introduction OSHA's standard on personal protective equipment, 29 CFR 1910.132 (October 1994), requires written certification of a "workplace hazard assessment" by the facility's management. The following table may be used to fulfill this requirement when properly completed and signed. In the blocks below, indicate the type of personal protective equipment required to perform each task. List material of construction and thickness of chemical protection. When completed, this information is to be transferred to the department's safe operating procedure or prestartup- inspection lists. (See example below) Workplace evaluated: Task Designation Chemical, biological or physical concern Hands Feet & Legs Body Eyes and Face Respirator & Cartridges Signature of person certifying evaluation:______ Date of Original Workplace Hazard Assessment: Revisions to this Workplace Hazard Assessment were made on the following dates: Signature of person certifying evaluation: Date of Hazard Assessment Revision: Signature of person certifying evaluation: Date of Hazard Assessment Revision: Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-7 ^>0 A 04 o 74(S OONFTDFNTTAi Operating Discipline 12 Industrial Hygiene Control (Place Plant Name Here) 12.3 Exposure Task Designation Drumming Certification of Hazard Assessment Appendix B Example Chemical, biological, or physical concern Ethyl Acetate Hands North Butyl .41 mm Feet & Legs Body Butyl rubber 4H apron boots Eyes and Respirator & Face Cartridges face shield & goggles half-face and OVAG Remember to included appropriate signatures r Published: (Date) Revised: (Date) Restrictedfor use within the Dow Chemical Company 12.3.3-8 DO A 040747 rONFTDFNTTAI,