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Technical Report for
MONSANTO COMPANY 600 N.LINDBERGH BLVD.
R3B ST.LOUIS, MO 63167
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HONS 220986
HONS 220987
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Appendix A Mass Spectral Data
lor Quantitated Compounds
0 a loiai ion chromatogram tpr aach sample anaiyieo py a GC/MS ins ir ume nt
2) a Quart report used by the analyst to oeiermme Qualitative ana Quantitative rasu'ts of the compounas present
3) a mass spectrum and a reference spectrum for each priority pollutant compound detecteo m the sample
HONS 220968
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HONS 220909
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HONS 220990
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Technical Report for
MONSANTO COMPANY 600 N.LINDBERGH BLVD.
R3B ST.LOUIS, MO 63167
LTt r?c
CAoffl of Cuolooy Dtl* RtQuiria Ior (TC On* M*n*em*t tummtry A*p*rt*
, HOHSANTO COMPANY
HQNCORPEH0 1 *7
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HONS 220991
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TABLE OF CONTENTS
introduction Tabta 1 Raauila and Quality Aaauranea Data Ttb'a 2 Mathod Partormanca Data Malhodolopy QA Protocol Raport Appandicaa
Appandlx A - Maaa Spactral Data tor Quantltatad Compound! Appandlx Cl - OC/MS SuPildiary Data - Blank Chromatopnma Appandlx E * Chain of Cuatody Forma
L HONS 220992
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Introduction
This report contains the analytical results on your son sample S' S6/0S/14 it is designed to mciude comprehensive daia trom ihe entire analytical process m order to satisfy the needs ot vj'ious levels of review The resu'ts obtained from your sample are presented in tabular formal immediately following this introduction Quality assurance data <s tabulated atong wiih the appropriate samp.e results tor verification Depending on the eneiyse* ordered, the quality assurance data may include results from Dtank spiked blank, spiked sample 0 e matrix spike) and replicate samp.e as wen as results trom surrogate compound analyses Quality assurance date (or verification o' proper instrument pertormance is also included where appropriate The report appendices mciude the chain of custody record tor your sample and. where appropriate, the gas chromatograms and mass spectra The procedures used in the analysis of the sample are described m this report s methodology section ah analytical procedures witmn our laboratory are performed within a strictly enforced Quality Assurance Protocol a description ot this Protocol is included m the report
Results
Sample results and associated quaniy assurance data, are always tabulated m one or more ot tins reports Quantitative Results Tables The tormat of each table varies with the ciass oi analysis
Priority Polluttntt
The priority pollutant compounds and elements are listed with their NPDES (National Pollution Discharge Elimination System) numbers, and the Method Detection Limit (MOD published in the Federal Register When a compound or aiement is present below its published mdl it is reported as Bmql (Below Meihod Detection Limit) when e compound or element is not present et any detectable concentrations it is reported as ND (Not Detected) mDl s tor pon-aqueous matrices are based on USEPA published MDL's but are adjusted as per sample weight Matrix spike end replicate analyses, where included, were performed on samples randomly chosen within each quality assurance batch and are therefore not necessarily sP'hes end replicates ot this report's sample Surrogate compound recovery data ano instrument calibration data are included in the Method Performance Deta Tables
mons 220993
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TABLE 1: QUANTITATtVE RESULTS and QUALITY ASSURANCE DATA
AM | 1916 Q44T4 t
Acid Compound* - OC/MS Analytli Data (OR02)
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HONS 22099*
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TABLE 1: QUANTITATIVE RESULTS and QUALITY ASSURANCE DATA BASE/NEUTRAL COMPOUNDS - QC/MS ANALYSIS DATA (ORD3)
APB 4 1916
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166 6vty) b*myl phth)ii* 166 ?'CM*r*ft*phlh1tnt
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MOWS 220995
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TABLE 1: QUANTITATIVE RESULTS *nd QUALITY ASSURANCE DATA
APR 4 1916
BASE/NEUTRAL COMPOUNDS - QC/MS ANALYSIS DATA (QR03)
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MONS 220996
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TABLE 1: OUANTI1ATIVE RESULTS and QUALITY ASSURANCE DATA Priority Pollutant Matalt - Analytic Data (QR05)
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RONS 220997
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TABLE 2: METHOD PERFORMANCE DATA Surrogata Recovery Soil - GC/MS Data (OR20)
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HONS 220998
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49.32 .95
52.22 .23
47.25 0.00
100.00 6.94
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2.33 9.10 55.89 10.99
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HONS 220999
TABLE 2l METHOD PERFORMANCE DATA IQR23)
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91 68 69 70 127 197 196 199
275 3*9 441 442 443
30-60* of maaa 196 La** thin 2*1 of mat* 69 (rlflrmci only) Loot than 2* of me** 69 40-60* of maa* 196 Lea* than 1* of maa* 196 8*6* puk, 100k ri lit i viabundant* 9-9* of mat* 198
10-30* of maa* 196 Greater than 1* of mta* 196 0-100* of **** 443 Graataf than 40* of maa* 198
17-23* of maa* 442
50.74 0.00
52.21 >26
46.40 0<00
100.00 7.32
22.40 2.43
10.56 74.07 13,75
50-74 0 . 00
52.21 .50
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100.00 7 32
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76.75 74.07
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Ini*c11on Data*
Injaetton Timet Run No)
Spactrun Not
04/01/06
00)41 >F6374 400
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Procaaaor QC Batch Sample* 1 mOiS-mlM?, L9194 i9l<55 Ltsll1 itrt>l2
HONS 221000
PTA eHVIfiOHUtNTAl I ^ lesrtNQ tnp CifiTIftCATfON
Methodology for
GC/MS Analysis of Priority Pollutant Compounds
Tr>e methods employed in the GC/m$ analysis tor priority pollutants are established Eda metnoos Piflid compliance with the instrument parameters and performance criteria o the published methods was achieved in some eases, the precise emounts of sample used ana the sample handling procedures vary with the complexity of the sample matrrx Ouai'tative identification of the priority pollutants was performed using the reiftrv# retention trmes the relative abundance of three characteristic <ons and the abundance ratios The entire mass spectrum was raviewed to confirm sach identification Quantitative analysis of detected compounds was performed by using a response factor operated by a major characteristic ion of the specific compound and an internal standard Compounds m addition to those on the priority pollutant list, were identified through a computer-aided search of the nB$-pa spectra library Aftar ravi#w th# identifications are induced in separate tabulation and labelled 'tentatively identified'
Ada ln/N*utr>l $na Pottlda* Priority Pollurvu Compound*
For the analysis of the Ac>d. Base/Neutrat end Pesticide pnonty pollutants m a soil matrix, a modificat'on of Epa Method 635 was used The method can oe summarized as follows a 30 gm semi-wet soil sample is soxhiet extracted with a 11 mixture of acetone and hexane The acetone is mermauy stripped The remaining hexane extract is diluted to 300 mi wth methylene chloride and twice extracted with an aoueous NaOn solution followed by an extraction with deionized water The methylene chionoe extract is onea end concentrated to a t mt tmai volume This concentrete is injected into e GC/MS instrument configured for the enatys>s of Bese/Neut'e* priority poitutant compounds The rememrng aqueous extracts ere combined end the pH adjusted to value less than 3 The aoueous phase is serially extracted with 3 aliquots of methylene ehionae The methylene ehionde extracts era onea, concentrated to e t mi fmei volume The concentrete is injected into e GC/MS instrument configured for the analysis of acid extractable priority pollutant compounds
HONS 221001
tNVIfiONMCNT AL CfV TesrtNG $na CifiTtHCATfON
Methodology for
Analysis of Metals
AOUJOUS The determination of meia's m aqueous samples is performed according to the memoas PuD'SheO by EpA in 'MethoOS for Chemical Analysis of wafer end Wastes* Epa-600/4-?9-0?0 March 1963 end the Federal Register. Octooer 26, 1963 Arsenic seienium ana thallium ere determined Oy furnace aa, silver, aluminum barium, beryllium ooron cadmium, calcium chromium, copper, coOd't. iron, magnesium, manganese molybdenum mc^ei lead sodium, antimony tm. titanium vanadium, end fine ere determined by icp emission spectrometry except where lower levels of detection ere required in these cases <e 9 lead 111 groundwater monitoring samples) furnace AA i* used All furnace AA parameters are run tty method of standard additions Tha determination of mercury is performed Dy coid vapor aa sp rox/c'Tr The determination o< metats in aouaous EP Toxicity leachates is performed according to me methods pupiishea Dy EPa m 'Test Methods for Evaluating Sod waste* EPa $w-046. revised Apni, tg64 and the Federal Regisiar, Oct 26 f$63 ig79 S'lver. arsenic, oarium. cadmium chromium, lead and seianium are determined by ICP amission spectrometry Mercury is determined usmg co>d vapor aa For leachates that ere organic in nature, the analyses are performed according to the methods described under o/t/ScubQf below SQlL/$eO'UtNT The determination of silver, beryllium, cadmium, chromium, copper, mcket, antimony, lead ana zme m sediment samples is performed according to methods published by EPa in 'interim Methods for the Sampling end Analysis ol Priority Pollutants *n Sediments and Fish Tissue* EPa S00/4*6t-0$S. October igso Mercury 1$ determined according to the sediment method published by EPa in 'Method for Chemical Analysis o< water and wastes* P* 600/4-79-020, March t963 Arsemc, selenium and thallium ara determined by furnace aa usmg nitric acid in a closed decomposition vessel for sample digestion OIL/tUJOQt The determination of silver, aluminum boron, barium, beryllium, ce'dum, cadmium copoer, chromium, cobalt, iron, magnesium, manganese, molybdenum, sodium, nickel, lead, antimony, tm, titanium, vanadium, end 2>nc in siudge/petroteum-based samples is performed oy (CP amission spectrometry usmg a magnesium nitrate dry ashing digestion techmoua Arsenic seieniym ana thallium ara determined by furnace aa using mine acd <n e closed decomposition vessel <or sample digestion Mercury is oetermmed Oy cold vapor AA usmg the seme digestion technique
MONS 221002
PTA iNVIRONUtNl AL I Ks TtSTINQ tna ce*TlflC*TIQN
Summary of Quality Assurance/Quality Control Procedures (QA/OC)
ETC Das<rs its Qualify assurance protocols on the following government guidelines
Handbook tor AnaiyHcai Quality Control m Water and wastewater Laboratories'. Epa-P00/4-79-0i9, March 1979,
National Enforcement investigation Center Polices, and Procedures manual. EPA-330r,9/79/00t-n. October 1979.
ti.e recommended guioeimes tor EPa Methods 624 and 625 (Federal Register December 3 1979 updated on October 26, 1964),
`Manual of Analytical Methods for the Analysis of Pesticides in Humans ana Environmental Samples." Pa 600/6-60*036. June I960
`Determination ot 23 7 6-TCDD m Soil and Sediment" EPa, Region vii Kansas City September 1963,
Organic Analysis Multi-media, Muid Concentration-iFB WA84-A267 ana
D'oxm Analysis Soit/Sediment Matrix, Multi-Concentration, Selected ion Monitoring with Jar Extration Procedure-IFB WA64-AOO?
However, we have modified our protocols to provioe a higher level ot Oa/QC than the gu'deiines require For example, we analyze a higher than required number ot quality control samples ana we pay especially careful attention to the certification ot the 'reference standard' compounds we use <n analysis Beiow are listed the key OA/OC elements tor the methods we used
Analysis of Volatile Organic Compounds by Gas Chromatography/Mass Spectrometry
- Each batch of 13 samples consists ot 9 customer samples (at a maximun) one oiank sample, one spiked blank, one spiked sample and onerepiicate sample This amounts to a 30% quality control (actor
- Three surrogate compounds are added to each sample m the batch of t3
- a biinq quality control sample is introduced to the laboratory tor analysis on a weekly oasis
- Each GC/MS <s checked end retuneo. if necessary, at the beginning of eacn day to ensure that ita performance on bromoftuorobenzene (8FB) meets the EPa criteria
- A calibration curve for Quantitation i$ prepared using a mixture of volatile Organs Priority Pollutant "standards at a minimum of 3 aiderent concentrations ana using a mixture of 3 internal standards at a constant concentration
- The calibration curve 'S verified witn a mi*tui-e of priority pollutant stanqaras every nay it the response factors vary greaier man 25%, the instrument must be recalibrated
Analysis ot Organic Compounds Extracted in Acid or Base/Neutrai Solutions by Gas Sivggt tlpar iphyZMm JU4sir9nfi.su
- Eaci- oaten o' C samples consists of 16 Customer samples (at a maximum) one D'am sampie one son ec oiam- 'ioi wate' matrices' cn samo'e soixeo witn the onor t> ponutani stanoaro m.xtufe ano a ouP'.cate c,,siomer sample Tims amounts to a 20% ouai'ti COndO1 f 3C'0`
MONS 221003
ETC f/VVtAOWWf WT *L TIS7INQ tnO Ce*T/*ICATlOH
- thrse surrogate compounds are aaued 10 each sample m me oaten (or Base 'Neo'rai
analyses
,
- Tnree surrogate compounds are aaaeo to each sample m the Oaten (or Apia ana- ,S'S
- a Dima quality control samp's ts introduced to the laOoratory (or analyses on a wee- ? oa$i$
- E ach GC/ms is checked ana retunea i( necessary, at the bey...n>ng of each day ro
ensure that its per iprmance on decaf luorotnpnanyiphosphme (OF Tppj meets me EPa criteria
- a calibration curve tor quantitation is prepared using e mixture o( standards composed
o< either the Organic Ac-d or Base^entrai Extractepie Comoounds at a minimum o' 3 concentrations ana using i.va internal standards (or quantitation
Analysis ot Metals
All Santpiat
- New standards are prepared (qr each patch ot samples
- Normal calibration is performed us ng a oiank sample ana four standards that have been through the sample preparation procedure a regression analysis is used to construct the calibration curve
- ah P Toxicity samples and an samples determined by furnace atomic absorpiion are calculated by ma 'method of additions'
- For each sempie analysis that requires ihe use ot the 'method o( additions' tech"iaue a three point calibration is performed uaing u s EPa 'Methods (or Chemical Analysis c water and wastes. t979' Results are obtained using linear regression analysis Any regression wiih a coefficient of correlation below o 990 it consideraa suspect, necessitating review of calibration data or sample re*enaiysi$
- in constructing the normal calibration curves the lowesi concentration leve's we use are values greater than or equal to 5 times the instrument) Detection Limit odd
- aii calibration standards are analyzed m duplicate at a minimum
- independent reference atanaards are used to check the accuracy of calibration standards
A check standard is analyzed every ten samples to veiidata the normal calibration Curve
- One Customer sample out ot every ten is analyzed in triplicate
Homoatntous Stmpm (**e*Ai tar Utieury tnHytn)
Samples are analyzed m oatenes ot 30 or less For patches in which the sample marnces are homogeneous, the QC program >s a minimum of 25% and consists of analyzing 3 sets of triplicate analyses. - 2 Replicate spikes, - f independent reference standard - a Cat'Oraiion standards (processes using me sample preparation method) - 4 Calibration standards (without sample preparation) ana
- i Reagem Bianu
MONS 221004
tNVIfiOHMCHTAt El\S TfST/WO C(KT IF 1C AT IOH
Wtfarojontout Stntplti (incopf tor ui/eury tntlytitl
Samples are analyzed in batches o* 30 or (ess for batches m which the sample matrices are heterogeneous the OC program is a minimum pi 3S% ana consists oi ane'yzmg - 3 sets ot triplicate analyses, - 2 Replicate spikes. - t Replicate independent reference standards. A Calibration standards (processed using the sample preparation method), - i Procedural Blank, A Calibration standards (without sample preparation), and - 1 Reagent Blank
Antlym ot Mercury
T-o analyze samples for mercury we group them by matrix mpatches of 30 or less Our QC program is a minimum of 309b and eonsisis of analyzing - each of ihe 30 customer samples in dupiicaie. - 3 sets of triplicate anayises. - ? Replicate spikes, - 2 Repncete independent reference standards, - 10 Calibration standards (processed using the sample preparation method) and - 2 Procedural Blanks
Antiyeis ot Pesticides, Herbicides and PCS a by Gas Chromatography
Pesticde. nerbicide ana PC6 samples sr* grouped m patches ot tfc customer samples or less according to the type of analysis to be performed The OC program for aech of these three types of analyses is a minimum of 20% and consists of analyzing
* t procedural blank sampie(a reagent piank i$ analyzed in the case of r>on~water matrices).
- t spiked blank samoie (the spiked blank i$ eliminated in the case of non-water matrices),
- t replicate sample, ~ t replicate spiked sample, and
- i known refernece OC sample for at least each ioo samples analyzed The instrument -s caiiorateo eacn run with three stanoaros and cneckeo every to samces
Analysis ot Cyanides Phenols Piuonde Chloride Nitrate and Nitrite
a parameter are analyzed us mg a lecn:;r Auto analyzer n G' - : ca `zra'-cn s'a-aarcs are ara'yrto a- > e oe: nnmg ancenoof eacn ta'ci-
MONS 221005
CT/n envmoNutuTAt
CI
TtSTlNO tna CtfiTIflCATlON
- Each &atch (ud to 60 samples) consists of analyzing on* blank, one sckea oiank or-e duplicate and spiked sample every 20 samples, and an EPA known reference sa^ p e
Analysis of Total Organic Carbon (TOC)
TOC sampies are analyzed on a daily Basis with ihe number of samples analyzed per oay oeoenoent on the request for Oupuceie or auadruoiicate analyses The quality conuo> program ,s designed to maintain the appropriate amount of QC and consists of the following e'emenis
- Daily mstrumant calibration
- One blank - Standard recaiibration every to samples
* Spiked samples at a low and high level
* Every sample is run in duplicate at a minimum
Analyst* of Total Organic Halide (TOX)
- Blank reagent water for absolute carbon beckrounei must contain less than S ugn of hehae (as chloride)
* Using a tnchiorophenoi standard, the mean adsorption efficiency must be within + /15% o< the standard value
- Calibration standards are run every 10 samples
- Every temple la run m duplicate at a minimum
Ana I ye la of 2,3,7,8-TCDD <Djox_fn)_byJJC/MS {SIM)
* Each sample is dosed with a known quantity of ,3Cj-2.3,7.e-TCDD as internal standard and 37Qd~TCDD as surogata standard The action limits for surrogate standard results * + /- *0% of The true value Semples showing surrogate standard results outBide of these limits are reextracted and reanalyzed
-Two laboratory 'method blanks* are run along wlln each set of 24 or iawer samples The method blank is also dosed with the internal standard end surrogate standard
- At least one per sat of 2d samples is run in duplicate to determine mtraiaboratory precision
- Qualitative Reoukamenta The following are met m order to confirm the presence o< native 2.3.7.8-TCDD
e, isomer specificity must be demonstrated initially and verified once per 8-hour work shift. The verification consisis of meeting a mixture containing TCOO isomers which eiute dost to 2 3 7 e-TCDO The 2 3 7 8-TCOD must be separated from interfering isomers, with no more than 25% veiiay relative to the 2,3,7.6-TCOO peak
b The 320/322 ratio >s within the range of 0 67 to 087
c ions 320. 322, and 257 are an present and maximize together the S'gnai to mea' noise ratio must be 2 5 to ' or better for an 3 ions
d The retention time is eouat (within 3 seconds) the retention time for the isoiopicaiiy labeled 2.3,7,8-TCDO
e a t ieasi one of the pos>lives can be confirmed by obtaining par iiai scan spec i'a irom mass tSO to mass 350 Tne partial scan guidelines are as fonows
* MOWS 221006
CTA tNVI*0NMH7H C/w TMTfWO tr>4 Ct*1iflCAltQN
the 320/324 ratio shov'd be i $8 */- 0 16
the 257/259 ratio should be t03 + /* 0 tO
the 19^/196 ratio shova be 1 54 +/- 0 15
- One sample is spiked witn native 2 3 7,8-TCOD at a level of to PP0 (tor eoi> for eacn set of 24 or fewer samples
- tn cases where no native 2.37 6`TCOO is detected me actua' detection nmit -s
estimated and reported based on a signal to noisa ratio of 25 to t at ions 320 ana 322
' For each sample, the internal standard is present with at least a >0 to 1 signal to noise
ratio for both mass 332 ana mass 334 Also, the internal standard 332/334 ratio
:
be within the range of 0 67 to 0 87
Subcontractor QA/QC
Each suocontractoer is required to maintain an appropriate level of Quality control To insure this, each subcontractor <$ reduced to submit to ETC the ouanty control data for an analyses it pe'forms Ths data ts kept on tne et Etc m genera' the amount o* Quality control reouireo is one duplicate sample with one spiked sample tor every ten analyses
Chefn-of-Custody
The chdin`of-cu$iody procedure is pert of our Quality assurance protocol we oeneve our Chd<n*of-cusiody record fully complies with the legal requirements ot federal, state ana local government agencies ana of tne courts of <ew The record covers
* labeling of sample potties, packing the Sample Shuttle eno transferring tne Shuttle unoer see' to the custody of a shipper.
* Outgoing shipping manifests. - the chem-of-custody form completed by the persons) breaking the Shuttle sea<
taking the sample, reseeling the Shuttle and transfarnng custody to a shipper - incoming shipping memfests, - breaking the Shuttle s reseal.
- storing each labeled sample bottle <n a secured area. * disposition of each sample to an analyst or technician, and
- me use df the sample n each oottie m a testing procedure appropriate to the intenoea purpose of the sample
The recoros show for each imk in this process
- the person with custody, eno
* me time and date each person accepteo or reimQuisned custoay
HONS 221007
ETC INVMONMC HTAl
'tSUHQ
Cl*Ti*ICAtlON
Appendix A
Mass Spectral Data for
Quantitated Compounds
1) a total ion chromatogram for each sample analyzed oy a GC/MS instrument
2) A Quant report used by the analyst to determine qualitative and Quantitative results ol the compounds present
3) a mass spectrum and a reference spectrum for each priority pollutant compound detected m the sempie
MQNS 221008
Date File' >17664:iU?
Name: 060771 ACID
I
M i sc : L?195N ,QAo?4?,S, 7 1.99,1
Id FiJei EACIDiiUS Title: PP/-ACID 1DFILE Lett Calibration: 860771 14:52
Operator ID: OH210O Quant Time: 860771 17:75 Injected ett 860771 17:02
BfLt 9
HONS 221009
QUANT REPORT
Optritor 1UI Output F i 1* : 0* t Ftl*l
N*m* 860331 lliicl L7195A
JH2160
a13664iiAQ
M3664IIU7
ACID
I
,QA474?iS,31.99,l
Qu*nt
R*v:
5 Gu*nt Tim*: lnj*et*d *ti
Dilution F*ctOM
06U3J1 060331
BTL9 9
17:>5 17102
1. 00
ID Fil*i 1 AC 101tUS (it 1*1 PP/-MCIU IUI-lLfc Lat Calibration! 060331 14i52
Compound
R.T. Sc*nt
1) d4-l,4-0ich)orob*n**n*
- < >3) 2-F l uo r opn*noI
(SURR)
--fr-F-itfo rophano 1 ------------------- DURR
0 ) PhenoI-05
tSURR)
11 > dB-N*phth*1*n*
17) dlO-Ac*n*phth*l*n*
24) dlO-Ph*n*nthr*n*
25 ) 2,4,6-Tribromop(i*no1
C SURR)
26 ) dl2-Chry**n*
6.18 4. 17 4.3? 5.63 9.25 14.46 10.91 16.09
27.03
175
62
- ?>
144
340 641 092 770
1349
iCompound it tSTD
Ar*
36470 54499 ------- 4^0 66909 77959 32493 55542 17427 25131
Cone
Unit*
40.00 UG^t-tL 00.15 UG-'ML - - ie i UG-'MU 03.11 UG^riL 40.00 UG.'ML 40.00 UG-'ML 40.00 UGrTIL 113.12 UG-'ML 40. 00 UG-'ML
ecs Hit tot*
q
9' Cl r
6> y< y 9" 9` y* 10i
MOHS 221010
Dot * Pilot > F 6 J 9 0 : >U2 Name: 860JJ1 tF B'-N&PEST
M i c : L?195B,QB4?4?,S,n.99,l
Id File: FBNP:iUS Title; B^N*PEST ID FILE .... FOR F Latt Calibration: 060401 1V:U>
Operator 1C': R^Ol?? Due n t Timet 660401 20:26 S nje c t od at: 660401 19i>8
850J26
BiLtr*
HONS 221011
QUANT REPORT
]pernjr JO* RA015?
Output Filt: ~F6 39 0t AQ
)tt| F i 1 a :
>F639Q;i U2
Jama: 060331 *P' B'NtPEST
Inc; L7195B,Qe474?,S,31.99,l
Quant Rev! 5
Quant Tima;
In jactad a t:
Dl Jut ton Fac t or J
060401 ;o :t
060401 19:39
1 . 00
BTL924
ID F i la t FBNPiiU5
Title: B'N * PEST ID FILE -------
FOR F
.eat Calibration: $60401 12 > 03
050326
Compound
R.T, Scan# Araa
Cone
Unit a
1) d4-l,4-DichIorobaniana
6.50 249
10099
40.00 UG'-r-V
12 > Ni t robaniena-05
(SURR) 7.92 329
25391
39.1? UG ML
10 J *dB-Nepht ha 1 ana
9.76 433
73275
40.00 UG'-ML
19 1 2-Fluorobiphanyl
(SURR) 13.11 622
61804
35.03 UG-'ML
13 ) dlO-Aeanaphthalana
15.00 733
46407
40- 00 UG/'Ml
30 ) 2-ChloronaphthaIana
1-2-.99 ----- 649 ---------- 1905
- -4,-47 -UG^L
41 ) 2 ,6-Dtn11 rot oluana
1*7-09 --73? ---------5675 -- -+0.??-UerML
34 ) dlO-Phanan thrana
19.64 990
99920
40.00 UG'-ML
30 ) Phanan t h rana
l*t69 -- 99> -------2016
* 1t?3 -US'-ML
39 ) ftnlhracana
l-9r69 -- 999~------- 2010 - - -*t20 -WG'-ML
31 > F luoran t hana
24,29-124-4------ 11641-2-- 93,6-1 UG-'NL
13 > Pyrana
24,99 -4294 ------146410 101.00 UC-l
?2 3 d!2-Chryaana
27.04 1451
170U
40.00 UG-'HL
>5 > Endoauifan I
24.30 1252- -11521 156.02 UC ml
343 Tarphany I -D14
(SURR 3 24.90 1206
25927
23.90 UG'ML
36 1 Butyl benzyl phthalata
25-r-99 -3r?43 ------ 1691 - 5.21 UC ml
>0 ) b ta<2-EthylhaxyI)ph tha 1 a t a
29.29 --1474- -- 49? 1 -
4.02 UGrP-L
>01 bta<2-E'hylhaxyI3phthalata
29,-41--4403 -- 7751 - -20.40 UC Ml
Q
96 eo 93 97
95 tb
06 9& 02 00 P2 02 100 61 9M T9 92 4
* Compound ta IS1D
HONS 221012
CTA INVmOUMlNTAL C (V rtsrijvo*nocfT/^/c>(r'ON
Appendix Cl QC/MS Subsidiary Data
HONS 221013
Data Fi |#t >13663)iU?
Nam#i 860331 ACID
1
fl!#ct QC4747A ,QA4?47,S,1,1
t d F i 1 i I AC ID MUS T i t I *i PP/ACID IDF1LE L##t C*libr#tieni 8#0331 14(52
Oparatcr ID JH2180 Quant Tim*t 860331 16t52 InjaCtad ti 860331 16119
01L# u
HONS 221014
QUANT REPORT
Operator ID: JH210O
Output Filai ~ 1 366 3 I lAQ
Data F : I a >
>I 3663iiU7
Namai 060331 ACID
1
Miac: QC4747A ,QA4747,S,1.1
ID FiJai lACIDt tUS T: t la : PP/wClD IDFIlE Laat Calibration) 060331 14152
Quant Ravi 9
Quant Timai
Injactad at:
Dilution Factor l
6 6 DJ JI 16;^ 2 860331 16 119
1. CM}
BTL4 8
Compound
1) d4-1,4-Dtchi orobantana 11) *d9-Naphtha lane 17) dlO-Acan#phthal*na 24) d 1 O-Phanan thr#n# 20) dl2-Chryaana
R.T. Sean#
6.17 9.26 14.46 10.92
27.02
17$ 349
642 893
1349
Area
39403 9 0499 34993 60069 1891$
Cone
Un 11
40.00 UG/Ml 40.00 UG^Mt 40.00 UG/HL 40.00 UG/NL
40.00 UGr'ML
* Compound la 1STD
HONS 221015
total tOH CH*ONATOCan
Data Ft I: >F6384J:U2 Namat 960331 IF B'NiPEST Hite! QC4747B ,QB474?,S,3 0,1
Id Ft U> FBNPt tUS
TttUi B-'N*PEST ID FILE ____
FOR F
Latt Calt b r a tton I 860401 02i06
Operator IDt KUQ786 Quant Tima* 660401 09:56 Injactad at` 860401 O9i08
050326
btl*i8
MONS 221016
QUhNT report
Operator IDf KU07B6
Output File; 'R639*S! !AQ
Data Pi let
>F63B4! :U2
Name t 660331 *F B^NiPEST
fltec ! QC4747B,QB4747,S,30,1
Quant Rau; 6
Quant Time;
Injected at:
Dilution Fee t or:
Bo040 1 09; 5c06O*tOl 09;08
1 . 00
BTl*1B
ID FiM F BNP i i US
Title! B'NrPEST ID FILE ____
FOR F
Last Calibration; 860401 02:06
650326
Compound
1) 2) 16) 33 ) 39 ) 54) 60) 72 )
90 >
04-1,4-DlChlorobenzene N-Nttroaodimethylemme
dB-Nephthelane dlO-Acanaphthalena
Dimethyl p'lthelete dlO-Phenanthrena
Di-n-butyl phthelete dl2-Chrysene
bt*(2-EthyIhexyI)phthelete
MO nundl. Compound ta JSTD
R. T. Scan# Area
Cone
Units
6. S3 249
24624
40.00 uG'Hl
J"r*9~------- 14----------44*4 ----1-0,46 UG-HL
9.77 432
89791
40.00 UG/'ML
IS. 06 732
41534
4 0,00 UG-'ML
l^c-ee------PM------- H4+?--------6t3 0 UG.'WL
19.56 966 119392
40.00 UG-'ML
21.89 1116
9574
3.24 UG/-ML
27.62 1451
96321
40.00 UGr'ML
28.41 1484
53616
25.56 UGr-ML
4
9 10
9 9 6 9 9 10 9
MOMS 221017
r--ETC ENVIRONMENTAL TESTING tnO CERTIFICATION
Appendix E Chaln-of Custody Forms
t) A field Chem-of-Custody form (CCl) It included for til samples
shipped by El c shuttle
2) An In-houte sample Cheln-ot Custody form ts Included for ii samples not shipped by ETC shuttle.
3) Any additional Chein-of-Custody materiel provided by e client or by client's tempting agent is also included
S) A subcontractor's Chsln-ol-Custody form is Included for any analytical work not performed within ETC's laboratory
5) Analysis and Extraction Custody forms art included for the period the sample was m ETC's possession
HONS 221018
ETC TtSTIMQ to* CtfiTifrCATiO*
CHAIN Of CUSTODY
Company
> --________ Job Mo.
Addraaa_____________ ____________________
At tantIont__________ Sampla Daacrlptlom CUSTOMER ID
> a-r*p U & s' ~
DESCRIPTION
____ l_____
ETC t
LitQi iirts
tMpli(i) ftilinquiihtd by>_ (ld/^%
l&sneT}lOHii f
**___ l_: LL________ Ptar_ Sampla(a) Racalvad byi ^
____ _____ _______________ _
Tima i j " l 1________ Datai ?/* < /(rt
V
tH ***ITAH CIHTf* HtKWAt *01*0*. HJ ttUt
IW) *)
HONS 221019
CHAIN or CUSTODY RECORD
MAC JOB NUMBER _
. ._
CUSTOMER RE ARE SENT AT I YE _
,f 0 CONTRACT NUMBER
MW CONTRACT MANAGER
U
PLANT NAME OR COOE _
C TEAM LEADER _ <f|j C,/
(SptdEk InforMtloA on iMptct I* *v*ll*b)* M *ttehtd *Spl< IdcnttfItitlon Log*)
SI|Mtwr
Tew Lndr Ytrlfleeltoft /p> ,, i jrv-,_j * of C*1t*ct*d S*npt*i:
Reltnqulthid Nr'^fSU.TWiK *Kftd by:
Rl lfM)uUbtd By. ^
Rec*W*d by:
Ufpod-in-by:
Re*lv*d for AftllylU by:
Method *f SMp*flt: A,r fy^a
Dit* Tloe Vz-y/fV '*>d 2/1 Olot
Reairti
n ^ 1 r* b Ac Crc
Nuntwr *f Conti In*re: /
ip*e||T Inttrj&ttoni {StRpT* priiffvftlon, Rfcorjty, **"y*ry to, etc.)
_ 5niTy/e
Cwi *Jrif/v} _ .
MOHS 221020
CTr |*paM*|Ni(i
* IV
m *nKir<(
LABORATORY CHRONICLE: Sample Preparation Deparir
lmpt Numprr
"iVteieT tofl ftampla -Vol.Jml) Link Walghl (gm)
T
LHM um
+ /.Wv?
ary
LUK L6lLi
_ --/.'/. .
TunwMAd
a/
Uill Uni
Data_____ . Extraction Method:
ap Funnal __ ____
Contlnuout .___. Soxhitl___ __ v<
-ft 'k
Ottor_______
____
COMMENTS
bmt/iLs ^
<JLC V "fl-O - s+*tf
r*ht k kit! /h/yr^Ljp,
<
l*i M3 ? f/erj/>
ThtsC
f<-> i
* y?9
KHiMt.
Xfi_ 1.0
u-4 1-0 IP.
to"1 auhl.
i_
#^<>3/^663? i, <_fc3',
hwd lo*d i`w TW flccou^y
be. tff.
MIAC1JOK
-ML.
Jki
uyctf-t
*M<J/3.
~I7o
7TO
M
h b<$~
SFtKI.
Conei/kT^ t*l
TJ&&Ti^z
lit______ X^SWCs
f*9
T-rzr .
T*<
JLSlStk-,
tar<W"a*^
~I.Sk
Stt-up: #N Cone
n c f.c.*......
^_
p-li:^Veld Cone.:
*<Mtb
UFWSupsnrlsor. SpIkMSun. Vfridsd:
/>%/
_C2TW CtJuJ'i,.KJ 3/2?A
HONS 221021
ETCKT^iw.r*.
LABORATORY CHRONICLE: GC MS Dprtmnf
DATE ^.3/vJti - SHIFT-
FRACTION_ _ _ _ At.J - ----------
INSTRUMENT___- -
tune file.___ SEOUENCE FILE_ _ ?' xfr* T.<
methodfile__ -
ID FILE ____FK A .
ANALYST(S)
j
SUPERVISOR
_
BATCH r*.___ QKojO
STANOAAO
pr rfr
. _A* i c-'j;a _t - _d C--ff '
. co-v - tA fiT_ `j. - jT . . .A- & _
_&//*<_! i. TEF .
CONC
ffm
LOT NO
/&> ^ Jto -
"
,, >^0
1 * "i I Iftv
<*|A9I WVT>AU
CUFFtHT CWI ITATUI
tTANDAADS UFOATiD
_AC0 mt
-04*
.... AAT| j/j> r
.. .
LOT voi
l>t #QAu NU
HONS 221022
BTC
LABORATORY CHRONICLE: GC-MS Department
DATE^^M/#/. SHIFT-.
FRACT ION___ -A/*C
instrument __
F.
TUNE FILE,,
. PITS 6S~
SE0UENCEFILE__ KV2/.
METHOD FILE____H * ?.F /*Xl2'_
id file
ANALYST(S) ....
SUPERVISOR,^**
BATCH re
- Y ~1V4
y?Pi
Plt*l IMflUkU
current
CMI STATUS
STANDARDS UADATED
standard
CONC ARM
v>, !*_ _
JTO
ZClZ>.
_____ -llQ _
. _4<L _
_________
. ____________________ -
. ---------- -
-J>/riZXP___ _______ :
. _ __________________ -_WLt?4...
A[ </ * * W J
^*r|
IT - -
NAME
DATA FILE
<*. als MJ
Dtt.
TARE*
. ..
SAECIALS (WRITE A TYRE)
>fnti
/
7--
& foopp-' >Ei>J,r_
i
ALUS TIN
>FiTo
>Ek>AL
lEiZZL kJ4UL!fL^rjS&r >rCH>
pft?? -?mw
-X2fL&_ . >E-Usl
_____ \>Jz6*2L
-- Jr ^11A
L i SM 3
? Ei>2L >Fi37t
- & _ L ft/lj.
>Jzkm
\ECKt!
_ l r/foj,
_j)cj
>FASA}
C v?v ?z > F
_L
. ... >*yfc
_ l `tjirfSz
hr' ?*:
L ?/?*. <J 1 Litfri
tk > *s*7
;> f3 ,r > few __ b>i*f p
V r
.-JL. ? ,r 1
.1
/i _73. . Jtt...
!C ll
f? a It _ iv u l\ 7!>
1
... .
......
.
< fS< . .. . Gl72i him.
$>/V4 -V/AA
1
j
|
1 ..J ..
v_.
_ .
A
V
rI S3
l
AF'Uo
-
1
i
HONS 221023
Civ UtlMlft M {MWiC^W
LABORATORY CHRONICLE; QC-MS Department
DATE _ ^ ^ ^
fraction^
instrument _
tune file_
SEQUENCE FILE _
METHOD FILE _
ID FILE _ _
,
ANALYST(S) ____
SHIFT_
STANOARD * --
CONC PPM
LOT NO
--____ __ __ _ _ __ _ ^ _
_
$ l'f ?<7 \
IPIU1I iwruu
CURHENT CSM STATUS
stanoaros
UPDATED
*co WIP
ATI
- * ------------------------------
-------- ---- -
.......................
----------
-
------_
__
NAME
OPAiTllA INuJl A1lt ml TAPE f
if 24*2 __ _
L (%/fj __ L cjJjj
_L
>A*1L ---. >A}JL, >F(i? 3
>JLilTr _ >A1K __ . . -
--uC-- U. 2? Jtf i*
. s
-- -------------- - -- -- --
__ ^____ _
* v -- ~-- -
-------
------------
--
*-
SPECIALS (WHITE A-TYPE}
-- - ---- -- -- -- ------ --
----- .,
- f --*
___
----------- ---------------- ------ --- -- --
-- . ---------- . -- -- -- -
i-- - - ----- -- - ---------- -- - -- -
-- _-
-- --
LOT vOL
PLUS
TIN
- --------- -- _.. -
HONS 221024
fNWRONMfNTJl
Civ testing *< certification
U_ 1*4 teu
LABORATORY CHRONICLE: Mata Is Dapartmanl Sampl*_L.nj<JdL/ LJU93
0l
_______
t'C roM *\*\
MOHS 221025
S7C NWJONMfwrjIl TfSTi^G tnc (,g*TtfiCATtON Technical Report for MONSANTO COMPANY 800 N.LINDBERGH BLVD.
HONS 221026
HONS 221027
ETC--
JSSVNQ n<3 CAL*TiFiCA7iON
f
Appendix A
Mass Spectral Data for
Quantitated Compounds
1) a totsf ion chrometogrem for tech sample analyzed by a CC/MS instrument.
2) A Quant report used by the analyst to oatermme Qualitative ano Quantitative results of the compounds present.
3) a mass spectrum and a reference spectrum for each priority pollutant compound delactad m the sample
MOMS 221028
1 I
I f!
$i
i
i f
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