Document 2G1ZgRNvz2G74yeRG6yB2e4g

Monsanto 11563 COPYl MONSANTO COMPANY / DAYTON LABORATORY / DAYTON, OHIO 45407 ESC - DAYTON IDeparteent/Section) analytical (Type of Report) REPORT NO.: KDA - 441 JO#/PROJECT NO.i 4(4.1000 DATE: 13 January 1M4 PERIOD COVERED: TITLE: ANALYSIS or LIQUID AND SOIL SAMPLES AUTHORS: S. M. Huqhes T IT L E i ANALYSIS OP L IQ U IO ANO S O IL SAMPLES ARSTRACT: A liquid and a soil aanpla wore recaivad Iron the Decatur Plant for analysis for possible PCS contaaination and a GC/KS videscan screening analysis. The results of these analytes are shown in this report. Technical Approval _ 3. DO I P Approved y= Robert r. Ivory 0;;?Y Fnvironnental Sciences Center Service Project Manager ^ r'.3:i FIlE Date: COMPANY CONFIDENTIAL This deewaat is tbs property ef Nsnssnta Csnpsay sad the reclpieat la raopoaalbla far its ssfekaepiaq and dlapeeltiaa: it realties trapisewTisi nroananoN stack asst an he refrodarad. revealed ta isutherised pereeas or seat eettlde Neaeeate reapany without proper authorisation. HONS 022764 ;1' S T r i e; ijt i o \ COPY NUMBER 1 D. Hepburn 2 It. E. Ivory 1 B. M. Hughes 4 Central Pilaa s Technical Reports Lbry 1260 1250 12S0 1250 R2C ABSTRACT ONt-Y H. A. Holternann 1250 NOTE: Distribution of this roport is restricted. Requests for sdditionsl copies should be msde through the Frincipsl contsct st the Monsanto locution involved or the Msnsger, Environrentsl Sciences Center, Dayton Laboratory, Dayton, Ohio. ACKXOWLEDGEXEXT Contributions of the following Daytor. Laboratory personnel to this project are gratefully acknowledged: Analyses: B. M. Hughes C. Trang COM PAW CONFIDENTIAL When no longer needed, or upon request, return this rsport to Control Files. Dayton. HONS 022 765 ANALYSIS REPORT 11563 COPYl LOO NUHKRt I-84-01 >04-01 DATEi Jtnuirv II* 1984 PROJECT NO* 484.90018 TO* Ivorv/Docotur Flont Attn) Davi d HoPbur* 81*628*2884 PROHt Cr.vtrAMntl Scionc** Cor.tor HohftAAto Co*OAAr/D4>ton Loborotor. ISIS Nsc*<>t9 Rood DottdA* Ohio 454ID Phono Noi <3I3> 268- 1*4 11 Titlo* Aftihm of tiouid tolid mmI* StoAdord Sttplinv nothod Not*)* N/A StAAdord CKtnction fWthod NotoM PCEiOl ttn4*r tailxit rwt>.4 Nt<>! ECAMOI. Hi-ZHi-2 TimI RopoM Pill Not*:* A300IS f" ! ? PL ,'1' Oh* mmU <ontoinir.o liquid ood Al*d Mf rocoivoO *ot i*i KIA AAd PCi Tho I|hi4 Ml -)ot*riAod to bo ot*r. bo*tJ * Itft ftOlwbllitv rroportio* Mhtrt oi>o4 with wotrttlono chlorido* b*r*sA. WOthAAOl* ACOtOOO AAd WAtOf. Th# *Olld Ml dotrfWiAod |* br ; f.oroor.lv. No to It* iMOlvtllltv IA tho obovo ftOlvoAt*. DuPliCOt* Iwc-r.'. ! |AU*t( of tho wotor iimIo woro *rb#d with 2 uo oor.tocMorobvASom Mch oil ^i. I Aft A ftwrrooAto orikiAO coarouod. Two ftlft doioAisod wotor wo* tr4tcd idOAtiCOllY oa4 ftorvod Aft tho oothod blAAk. Coch # tho 2-*l soiled u*t*i IMfttOft wa oxtrACtod with 2 Burdick And Jac(coa diftti I lod-iA-olo** bOAtOAO* Rocovorioft for oohtAChloroboASooo w>t o4*jrod to b* ^ 4*d 1092 for tho two durticoto wotor mopUi And 107X for tho oothvd M*l. No PCSft (with lovolft of dotoctioh of 1 */*) woro dotoctod in on. **f ti** AAOlOft. No OXtrACtAblO OrOAAIC COATOUA4I with VOlAtllitiOft l0> thOA tolooao woro dotoctod. This tottor aaoIvoIs was condwctod with o lev#I of dotoctioo of SO uo/o. ANALVtTlSH B. rteftOQ ANALYST APPROVALi1 . Trent HONS 022766 Th# Antl>ii dottowir.o %* tfotcnfct $tr.4r4 E<tfctin fWtM vMd dor this rrojoct. notho.j ont Stonttrtf HONS 022767 ESC Standard Extraction flatbed ISCH 1'dfLfi in Virlm Htrlc n*TJt!(X>fCS> Stilt tottMi* *ail. Itf fat. lilt itruti ifhtlt ilk* Ntf fact* ESC Standard Extraction flatbad Nat PCEXOl TYPICAL SAMPLE SUE (a) typical extract VOLUME (at) 0.5 - 5.0 1 - 10 TYPICAL ANALYTES* Araclar* 1232. I24S* 1294. 1240. 1262. tnchlarrfctrMnvl t*ar tnrawan tirhvnvt taaaara ESC Standard AnalrtU flatt.ad N*s CCANOI. ECAN02. tt3AN03 iNICNIHNCISi An* alactra* cantor>n* aaaciaa m tba rataMxn tir taaion af tricKlaraSiahan.l aaaaara tbreaat. actacMaraSirt.anrI noatn far ECWJ and CCANCC. Anr aaaciaa in th+ vhicN 9va tha rataliv. Mil rtIMl i..i P'!E iiiairi Tar UMNO}. typical 'jr.T.oc-aTE' rifitm recoverit: iihu<hl(t(>lin:*rii i :ltUriMr.r .i 5(* - 11*.* v> - i;:> APPAAATUS M> MATERIALSi Ivr.Kk Ml JIClrlM IIKMti t.nj.n* l>4 Mlll.IlM <hlri4 lor IM.ll MllKllM. CancantraltA tuliuric Mil Ear IM'I# 4fa*.tin or im'^i cIii.-. Silica l cilgMi ivritMl.l wit.- >itmi urMMiMlv. i.Hi'k i-n Ml aatasaiu* hr4r-<i4.. ActivataA banc alMina. Dn.a.abta iIiiimm. LIMITATIONS! NathaS iMlIai *1r ta aatncaa which 4a n.t c.nlaln a-h.4r*litabla alactaaa caatwrtaa aaaciai m tba IricMoi*n*hn> I thr.uata cblarabiafcanvl liaaar ratantian tiw. r.aion fi EC 4t.ctin ailMli. IM1TY PRECAUTIONS' Saa PCS han4lin vratacala in lab.raturr iil.tf mmu:- MTES OP ICTHOO OVATION AND UPDATES! 10/23/83 MONS 022768 CSC Standard SMlfill flathod (SMI) TITLE. Oraanlc Ctaraunda in Salvanta CSC Standard Anal rata Mathad Na; I1SMJ02 ANALYTICAL INSTRUMENT ANO HOOC OF OPERATION! HP-39830 Capillary CC/HS-Scanni! with Rtviaian-G Hulti-driv* Tvrictl Tvplctl TyoIcoI Tvrtcol Tvnictl Run Ttno* HultiHaor Throthold* n$s Ron*** Scon Roto* 3-40 *in. 1800 - 2400 #V 100 counts 10 - 500 ku 2/t*cond TYPICAL ANALYTE typical INSTRUMENT LEVEL OP DETECTION <L00> (U9/1> TYPICAL Pf-CCISION t 10X LCD <XI T\riCAL accuracy 4 K'X L'O x Of mc Cowntf tlwtlM Ittwtri ttluth# M n-C34-*n# 1 30 30 INTERFERENCES ANO LIMITATIONS* Antirto ut chfo*tttrtohic11. rotolvod frM Othf N9IAIC CHROMATOOAAPMIC COLUFMs 30-*#tor fgod >tlic JIU D8-5 (0.25 wN> wit*. vio btrt 10. 32 m) COLUMN TEMPERATIRE PROGRAMS 50(41/6/300 1UJCCTI0N TYPE* CAL I ORATION ANO STANDARDIZATION! Ouontitttivo* Utt lAttrrtil t%ndrd amMiUTua tf(l>f .vi IM Cllllrtt* iAitru*At r#M9Ai* fro* mtorntl tt%ndrd. OwthUttvf* Nil! o( unknown conrovr.tf* or* CMtirtt It ftANr4 ou rctr ir. th NDA/EPA PUs* S**#<t"4t Litr: . vMct <AAtirn ov#r J 0. 000 c<n*ognJ*. Potitiv* d*nt i f i cf <. : rn.ii <' oftor triiMf M> M<tr9c*rit Ai vivll . toopi*j thv vnln>wi. COAPOvnd MM INCtrg* with lh*M idontlfiod u*t rroboblo ft*r, ,i.;i ImH woon tMir Motet. Factor. CALCULATIONS* Anftlvt* concontr 4ti*n * (AmM* %r %>/Unt*r nt St*n4*r4 RRT> vh*r#< Anftlvto trtt It tb tetll ion ro of tho oiaoltto. RAT It tho roUtivo rotnonto ftctor for th# intorrv*! not#* Thit ctlcvIhlloA It m(i vhon unknown coanowndt * rrtmt vhon no thfAti tAfrf ro milMft. SAFETY PRECAUTIONS! Soo PCD handling protocolt in laboratory %ftv mayaK DATES OF METHOO CREATION AND tCTHOD UPDATES! 10/31/83 HONS 022 769 CSC Standard Analvtit Hathad (SAM) TITLE' Kil in Salvanta ESC Standard Analvtla t1tt.d Nil ECANOI ANALYTICAL INSTRUMENT AND MODE OF OPERATION! HP-5880 Camllarv CC/CC ir.Uftacad ta an HP-33S6-LA? Laboratory Data Svataa TYPICAL analyte TYPICAL INSTRUMENT LEVEL OF DETECTION <LOO> <U/*I ) Tr i<ht*rMpfcrw 1 UOAtn throuth 0.01 TYPICAL PRECISION 10X LOO <X> so TYPICAL ACCURACY e KX LOl* *x INTERFERENCES AND LIMITATIONS* An. alactren cantvrina taaciat in tn ratantian t ina raaian at iricSUraMrMnl tbreja). acticMir ebinher. * I itenari ara netantial intar ra* ancai. let ratantivn limat at natt liiel. PCD itvnart can ta attained Iran ll.a anal .'tit at Aractvi 124S. Arvelar ICS4 ar Aivdvr ICtO ftrmglatlent. CHROMATOORAFNIC COLUMN! 30-a-rtar fgted Hi let JtU W-? CO. 35 vMI will, wlda bara <0.33 an) COLUMN TEtrCRATURE PROGRAHi 130(11/4/300 INXCTION TVPCi Calitlaii CALIBRATION AND STANDARDIZATION! Uaa ir.tarnal atar.dard awantitatian tacl.niaua and calibrate mttrumant ratoanta tactara Iraa authantic PCD itamai ttandaidt. CALCULATIONS! PCD Itaaar cancantratian Iitamer araal/litemar RRF) fiarai RRF it tha ralativa retnenta factar ter ll. trarviiiatv PCS itaaar. SAFETY PRECAUTIONS! Saa PCS Nandiina aratacoIt in labaratarv aafat. mangaI. DATES OF METHOO CREATION AND METHOD UPDATES! 10/35/83 HONS 022770