Document 15yjogj6R20emr0MnnOdw5vOZ
Report Prepared by: Report Approved by:
NPDES Compliance Sampling Inspection Report
Palo Seco Power Plant Levittown, Puerto Rico PR0001031 September 12-13, 2022
ROBERT
Digitally signed by ROBERT MORRELL
_M_O__R_R_E__L_L___D1_3a:t_0e7:_:2002_2-2_0.41_'10.0_0'3_____________
Robert Morrell, Geologist
Monitoring Operations Section
Date: ________________
________________________________ PHILIP
COCUZZA
Digitally signed by PHILIP COCUZZA Date: 2022.11.01 14:09:42 -04'00'
Phil Cocuzza, Chief
Monitoring Operations Section
Date: ________________
Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
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Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
1.0 OBJECTIVE
On September 12-13, 2022, at the request of the Caribbean Environmental Protection Division, a National Pollutant Discharge Elimination System (NPDES) Compliance Sampling Inspection (CSI) was conducted at the Palo Seco Power Plant in Levittown, Puerto Rico. The objective of the CSI was to gather information necessary to determine compliance with the requirements and limitations of NPDES Permit No. PR0001031, specifically Outfalls 001C and 001-C1.
2.0 KEY PARTICIPANTS
Listed below are key inspection participants and contact information, grouped by organization.
U.S. Environmental Protection Agency Robert Morrell, Geologist, Lead Inspector Morrell.robert@epa.gov, 848-229-5054 Jaime Lopez, Senior Enforcement Officer / Physical Scientist Lopez.jaime@epa.gov, 787-390-3403 Jose Rivera, Team Leader, Clean Water Act Team Rivera.jose@epa.gov, 787-402-0987
Puerto Rico Electric Power Authority Indira Mohip Colon, Environmental Protection and QA Division Head Indira.mohip@prepa.com, 939-227-5574 Yvonne Roman Sandor, Program Officer, Environmental Protection Division Yvonne.roman@prepa.com Abraham Rivera, Mechanical Supervisor and NPDES Compliance Officer Abraham.rivera@prepa.com Luis E. Carrillo, Senior Chemical Supervisor Luis.carrillo@prepa.com, 787-521-7029
3.0 FACILITY DESCRIPTION
3.1 General Information
The Palo Seco Power Plant is located at km. 3.8 on State Road No. 165 in Levittown, Puerto Rico. The facility, which is owned and operated by the Puerto Rico Electric Power Authority (PREPA), began operations in 1960. The facility is engaged in the generation, transmission, and distribution of electricity and is categorized as Standard Industrial Classification (SIC) 4911. The Palo Seco Power Plant employs 120 personnel and operates 24 hours per day, 7 days per week.
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Palo Seco Power Plant PR0001031
3.2 Process Information
Inspection Date: September 12-13, 2022
The Palo Seco Power Plant consists of four oil-fired units and six gas turbines. Units 1 and 2 each have a capacity of 100 megawatts (MW). Units 3 and 4 each have a capacity of 200 MW. Each gas turbine has a capacity of 22 MW.
Process water and potable water are provided by a municipal water supply and an on-site desalinization plant. A seawater intake provides non-contact cooling water.
Industrial wastewater is conveyed to the wastewater treatment plant. Industrial wastewater consists of boiler wash water, ion exchange wastes, and air preheater cleanings. The wastewater flows into a collection basin and is pumped to Equalization Tank No. 2, where the pH is adjusted. The sludge from Equalization Tank No. 2 is pumped to the South Pond. The wastewater then flows into Equalization Tank No. 1. The wastewater is directed to one of two Nautilus units, where a polymer is added. Sediment from the Nautilus units is pumped to the South Pond. The wastewater then flows into a collection sump, where the pH is adjusted again. The wastewater is pumped through the gravel filters and is conveyed to a post treatment tank. The treated wastewater is then batch-discharged through internal Outfall 001-C1. The treated wastewater from Outfall 001-C1 combines with storm water runoff, equipment drains, and boiler blowdown. The combined flow is discharged through Outfall 001C to the old Bayamon River Bed.
3.3 Facility Self-Monitoring Information
Samples are collected and analyzed by Environmental Quality Laboratories in San Juan, Puerto Rico. Flow is measured continuously with a V-notch weir and ultrasonic meter.
4.0 EPA SAMPLING/INSPECTION ACTIVITIES
4.1 Sampling Activities
On the first day of the sampling inspection, September 12, 2022, there was no discharge at internal Outfall 001-C1, as the post treatment tank was not full. The batch discharge was scheduled for the following day, September 13, 2022. There was also no stormwater runoff observed at Outfall 002. As a result, there were no samples collected on September 12, 2022.
On September 13, 2022, an automatic composite sampler was set up at the discharge location for Outfall 001C. The sampler was programmed to collect an aliquot of the effluent wastewater every 15 minutes for 6 hours. The composite sample container was packed in ice. After 6 hours, the batch discharge from the wastewater treatment plant was completed and the automatic sampler was shut off. The composite sample was collected for the analyses of total suspended solids (TSS) and 5-day biochemical oxygen demand (BOD5).
A grab sample was collected at Outfall 001C using a rod and clamp. This grab sample was analyzed for metals (arsenic, cadmium, copper, mercury, nickel, silver, and thallium), color, free cyanide, oil and grease, pentachlorophenol, PCB's, sulfates, sulfide, turbidity, nitrate +
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Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
nitrite, and ammonia. Dissolved oxygen, pH, settleable solids, temperature, and total residual chlorine were analyzed in the field and recorded in the field notebook. Flow measurement data were provided by facility personnel.
A manual composite sample was collected at Outfall 001-C1. Four aliquots were collected from a tap on the discharge line during the batch discharge. This composite sample was analyzed for TSS and metals (copper and iron).
A grab sample was collected at Outfall 001-C1 by directly filling the sample containers from a tap on the discharge pipe. This grab sample was analyzed for oil and grease, and metals (chromium and zinc). The pH was analyzed in the field and recorded in the field notebook. The flow measurement was provided by facility personnel.
All sample containers, preservation techniques and holding times were in accordance with US EPA requirements specified in 40 CFR Part 136.
Split samples were collected and given to the facility representative.
4.2 Inspection Activities
A walk-through inspection of Outfall 001C, Outfall 001-C1, and Outfall 002 was conducted on September 12, 2022. There was no flow at Outfall 001C and Outfall 002. There was minimal flow at Outfall 001C. On September 13, 2022, the batch discharge of the wastewater treatment plant effluent was started and samples were collected at Outfall 001C and Outfall 001-C1.
4.3 Deviations and/or Environmental Conditions
Samples were not collected at Outfall 002 because there was no stormwater runoff.
5.0 ANALYTICAL RESULTS
Palo Seco Power Plant Outfall 001-C1
Parameter Flow TSS TSS Iron Iron Copper Copper Chromium Zinc Oil and Grease pH
Units MGD mg/l kg/day mg/l kg/day mg/l kg/day mg/l mg/l mg/l su
Permit Limit 0.74 -170.4 -1.7 -1.7 0.2 1.0 34.1 6.0 - 9.0
Page 5 of 13
EPA Result 0.155931 Not detected Not detected 0.0652 0.038 Not detected Not detected Not detected Not detected Not detected 7.89
Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
Palo Seco Power Plant Outfall 001C
Parameter TSS BOD5 Arsenic Cadmium Copper Mercury Nickel Silver Thallium Color Free Cyanide Oil and Grease Pentachlorophenol PCB's Sulfates Sulfide Turbidity Nitrate + Nitrite Ammonia Dissolved Oxygen pH Settleable Solids Temperature Total Residual Chlorine
Units mg/l mg/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Pt-Co units ug/l mg/l ug/l ug/l mg/l ug/l NTU mg/l mg/l mg/l su ml/l oC mg/l
Permit Limit -30.0 36.0 Monitor only 3.73 0.051 8.28 2.24 0.47 Shall not be altered 1.0 20 Monitor only Monitor only 2800 2 10 Monitor only Monitor only 4.0 minimum 7.3 - 8.5 Shall not cause deposition 32.2 --
L = the reported value may be biased low.
EPA Result Not detected 6.47 Not detected Not detected Not detected Not detected Not detected Not detected Not detected 5.00 Not detected Not detected Not detected Not detected 3570 22.6 L 0.773 1.18 L 0.115 6.7 8.11 0.0 31.0 0.02
6.0 FINDINGS 6.1 Sampling Result Findings The EPA analytical results obtained during this inspection show the following parameter(s) as being outside of the acceptable limits: Sulfates (Outfall 001C) Sulfide (Outfall 001C)
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Palo Seco Power Plant PR0001031
6.2 Inspection Findings
Inspection Date: September 12-13, 2022
In addition to the sampling, an inspection of the facility outfalls was conducted as discussed in Section 4.2 above. The following observation was noted at Outfall 001C:
The primary flow measuring device was off-center and not located immediately upstream of the weir crest.
7.0 ATTACHMENTS
Photographs (#1 - #4) Chain of Custody / Field Data Forms Laboratory Data Report
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Palo Seco Power Plant PR0001031
Photo #1: Outfall 001-C1.
Inspection Date: September 12-13, 2022
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Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
Photo #2: View of sample tap for Outfall 001-C1.
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Palo Seco Power Plant PR0001031
Photo #3: Outfall 001C.
Inspection Date: September 12-13, 2022
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Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
Photo #4: View of Outfall 001C where samples were collected.
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Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
Page 12 of 13
Palo Seco Power Plant PR0001031
Inspection Date: September 12-13, 2022
Page 13 of 13
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
2890 Woodbridge Avenue Edison , New Jersey 08837
732-906-6886 Phone 732-906-6165 Fax
October 03, 2022
Philip Cocuzza Monitoring & Assessment Branch LSASD/MAB Edison, NJ 08837
RE: PREPA Palo Seco Power Plant - 2209014 Enclosed are the results of analyses for samples received by the laboratory on 09/14/2022. The signature below reflects the laboratory's approval of the reported results. If you have any questions concerning this report, please refer to Project Number 2209014 and contact the laboratory. Sincerely,
John R. Bourbon Chief, LSASD/LB
Project Narrative:
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
The National Environmental Laboratory Accreditation Conference Institute (TNI) is a voluntary environmental laboratory accreditation association of State and Federal agencies. TNI established and promoted a National Environmental Laboratory Accreditation Program (NELAP) that provides a uniform set of standards for the generation of environmental data that are of known and defensible quality. The EPA Region 2 Laboratory is NELAP accredited. The Laboratory tests that are accredited have met all the requirements established under the TNI Standards.
Condition Comments
None
Comment(s):
The "Sample Analysis Date and Time" is included in the results section for any analyte with a prescribed holding time of 72 hours or less.
The results for Color are reported as "Apparent Color". The pH of the sample was confrimed between 4 and 8, therfore no pH adjustments necessary prior to Color measurement.
Note: For this project, only MS was extracted and analyzed because, the MSD sample bottle was broken during shipment and no extra sample was available to replace.
Data Qualifier(s):
U- The analyte was not detected at or above the Reporting Limit. J- The identification of the analyte is acceptable; the reported value is an estimate. K- The identification of the analyte is acceptable; the reported value may be biased high. L- The identification of the analyte is acceptable; the reported value may be biased low. NJ- There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. The reported value is an estimate.
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 1 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
Reporting Limit(s):
The Laboratory was able to achieve the standard laboratory reporting limits, where applicable, for each analyte requested except for the following analyte(s):
NVOA GCMS
The reporting level of 5.00 ug/L was raised to 30 ug/L for the following analyte(s): 4,6-Dinitro-2-Methylphenol, Pentachlorophenol for the following samples: 2209014-01 The reporting level of 5.00 ug/L was raised to 50 ug/L for the following analyte(s): 2,4-Dinitrophenol for the following samples: 2209014-01
SUMMARY REPORT FOR SAMPLES
Field ID Outfall 001C-Grab Outfall 001-C1-Composite Outfall 001-C1-Grab Outfall 001C-Composite
Laboratory ID 2209014-01 2209014-02 2209014-03 2209014-04
Matrix Aqueous Aqueous Aqueous Aqueous
Date Sampled 09/13/2022 12:35 09/13/2022 14:10 09/13/2022 10:46 09/13/2022 14:30
Date Received 09/14/2022 10:50 09/14/2022 10:50 09/14/2022 10:50 09/14/2022 10:50
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 2 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
Analysis 608.3 PCB Aroclors NPDES 625.1 SVOA NPDES Ammonia [As N] Biochemical Oxygen Demand Color Weak Acid Dissociable [Free] Cyanide Mercury Metals ICP TAL NPDES/DW Nitrate + Nitrite [As N] Oil & Grease Sulfate Sulfide Residue, Non-Filterable Turbidity
SUMMARY REPORT FOR METHODS
Method
EPA 608.3 SOP C-91 Rev 4.3 EPA 625.1 SOP C-90 Rev 3.8 EPA 350.1 SOP C-80 Rev 2.7 SM 5210B SOP C-21 Rev 2.7 SM 2120 SOP C-47 Rev 3.6 EPA 335.4 SOP C-28 Rev 2.7 EPA 245.1 SOP C-110 Rev 2.7 EPA 200.7 SOP C-109 Rev 3.6 EPA 353.2 SOP C-79 Rev 3.6 EPA 1664A SOP C-126 Rev 1.6 EPA 300.0 SOP C-94 Rev 2.7 SM 4500 S2 D SOP C-115 Rev 2.7 SM 2540D SOP C-33 Rev 3.7 EPA 180.1 SOP C-81 Rev 2.7
Certification NELAP NELAP NELAP NELAP NELAP
NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP
Matrix
Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 3 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
Analyte
Field ID: Outfall 001C-Grab NVOA GCMS Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2209014-01
Date and Time of Analysis*
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
51.0
ug/L B209096
---
U
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
30.6
ug/L B209096
---
U
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 4 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
Analyte
Field ID: Outfall 001C-Grab NVOA GCMS 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2209014-01
Date and Time of Analysis*
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U J
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U J
5.10
ug/L B209096
---
U L
5.10
ug/L B209096
---
U
5.10
ug/L B209096
---
U
30.6
ug/L B209096
---
U L
5.10
ug/L B209096
---
U
5.10
ug/L B209096
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 5 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
Analyte
Result
Qualifier
Reporting Limit
Units
Batch
Date and Time of Analysis*
Field ID: Outfall 001C-Grab PCB Aroclors GC Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 GC - Sanitary Oil & Grease Metals ICP Arsenic Cadmium Copper Nickel Silver Thallium Mercury CVAA Mercury Sanitary Ammonia [As N] Color
Weak Acid Dissociable [Free] Cyanide Nitrate + Nitrite [As N] Sulfate Sulfide Turbidity
Field ID: Outfall 001-C1-Composite Metals ICP Copper
Sample ID: 2209014-01
---
U
0.031
ug/L B209085
---
U
0.062
ug/L B209085
---
U
0.031
ug/L B209085
---
U
0.031
ug/L B209085
---
U
0.031
ug/L B209085
---
U
0.031
ug/L B209085
---
U
0.031
ug/L B209085
---
U
6.50
mg/L B209121
---
U
8.00
ug/L B209117
---
U
3.00
ug/L B209117
---
U
10.0
ug/L B209117
---
U
20.0
ug/L B209117
---
U
5.00
ug/L B209117
---
U J
20.0
ug/L B209117
---
U
0.050
ug/L B209111
0.115
0.100
mg/L B209079
5.00
5.00
Color B209078 09/14/2022 11:55
Units
---
U
10.0
ug/L B209088
1.18
L
0.0500
mg/L B209114
3570
100
mg/L B209109
0.0226
L
0.0100
mg/L B209089
0.773
0.100
NTU B209081 09/14/2022 13:50
Sample ID: 2209014-02
---
U
10.0
ug/L B209117
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 6 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
Analyte
Field ID: Outfall 001-C1-Composite Metals ICP Iron Sanitary Total Suspended Solids
Field ID: Outfall 001-C1-Grab GC - Sanitary Oil & Grease Metals ICP Chromium Zinc
Field ID: Outfall 001C-Composite Sanitary
Biochemical Oxygen Demand Total Suspended Solids
Result
Qualifier
Reporting Limit
Units Batch
Sample ID: 2209014-02
Date and Time of Analysis*
65.2
50.0
ug/L B209117
---
U
10.0
mg/L B209083
Sample ID: 2209014-03
---
U
6.00
mg/L B209121
---
U
5.00
ug/L B209117
---
U
20.0
ug/L B209117
Sample ID: 2209014-04
6.47
2.00
mg/L B209080 09/20/2022 08:10
---
U
10.0
mg/L B209083
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 7 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014
NVOA GCMS - Quality Control
Analyte
Batch B209096
Blank (B209096-BLK1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 8 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Batch B209096
Blank (B209096-BLK1) Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
LCS (B209096-BS1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
--- U
5.00 ug/L
41.6
ug/L
50.00
ND
ug/L
50.00
37.7
ug/L
50.00
37.0
ug/L
50.00
37.6
ug/L
50.00
61.9
ug/L
50.00
44.4
ug/L
50.00
37.7
5.00 ug/L
50.00
37.4
5.00 ug/L
50.00
43.9
5.00 ug/L
50.00
38.8
5.00 ug/L
50.00
48.2
5.00 ug/L
50.00
51.2
5.00 ug/L
50.00
47.8
5.00 ug/L
50.00
83.2
60-140
34.9
60-140
75.4
60-140
74.1
60-140
75.2
60-140
124
60-140
88.7
60-140
75.5
47-145
74.9
33-145
87.9
27-133
77.5
33-143
96.4
17-163
102
24-159
95.5
35-219
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 9 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Batch B209096
LCS (B209096-BS1) Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene
48.0
5.00 ug/L
50.00
39.2
5.00 ug/L
50.00
49.0
5.00 ug/L
50.00
48.0
5.00 ug/L
50.00
42.3
5.00 ug/L
50.00
52.2
5.00 ug/L
50.00
35.9
5.00 ug/L
50.00
44.1
5.00 ug/L
50.00
32.3
5.00 ug/L
50.00
41.1
5.00 ug/L
50.00
41.7
5.00 ug/L
50.00
44.7
5.00 ug/L
50.00
48.0
5.00 ug/L
50.00
42.7
5.00 ug/L
50.00
46.5
5.00 ug/L
50.00
35.4
5.00 ug/L
50.00
42.4
5.00 ug/L
50.00
43.8
5.00 ug/L
50.00
48.3
5.00 ug/L
50.00
57.6
5.00 ug/L
50.00
42.8
5.00 ug/L
50.00
40.8
5.00 ug/L
50.00
41.3
5.00 ug/L
50.00
21.4
5.00 ug/L
50.00
39.0
5.00 ug/L
50.00
41.9
5.00 ug/L
50.00
36.0
5.00 ug/L
50.00
46.1
5.00 ug/L
50.00
41.2
5.00 ug/L
50.00
42.0
5.00 ug/L
50.00
27.8
5.00 ug/L
50.00
9.04
5.00 ug/L
50.00
41.1
5.00 ug/L
50.00
49.4
5.00 ug/L
50.00
43.2
5.00 ug/L
50.00
95.9
11-162
78.4
17-168
98.0
33-227
96.0
26-137
84.6
59-121
104
39-171
71.8
21-133
88.2
54-120
64.7
44-142
82.3
37-144
83.4
39-135
89.4
32-120
95.9
39-139
85.4
50-158
93.0
21-191
70.7
60-120
84.8
23-134
87.6
29-182
96.5
38-262
115
17-181
85.6
53-127
81.7
22-147
82.6
25-158
42.8
9-132
77.9
33-184
83.8
12-158
72.1
36-166
92.2
8-158
82.3
38-152
84.0
60-115
55.5
31-114
18.1
28-120
82.1
1-120
98.8
4-146
86.4
35-152
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
RPD Limit
Page 10 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Batch B209096
LCS (B209096-BS1) Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
LCS Dup (B209096-BSD1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
29.5
5.00 ug/L
50.00
29.0
5.00 ug/L
50.00
30.8
5.00 ug/L
50.00
42.0
5.00 ug/L
50.00
42.7
5.00 ug/L
50.00
28.9
5.00 ug/L
50.00
39.2
5.00 ug/L
50.00
49.1
5.00 ug/L
50.00
45.1
5.00 ug/L
50.00
19.2
5.00 ug/L
50.00
49.1
5.00 ug/L
50.00
43.6
ug/L
50.00
17.9
ug/L
50.00
34.3
ug/L
50.00
31.5
ug/L
50.00
38.6
ug/L
50.00
56.4
ug/L
50.00
36.3
ug/L
50.00
40.3
5.00 ug/L
50.00
39.6
5.00 ug/L
50.00
47.4
5.00 ug/L
50.00
42.7
5.00 ug/L
50.00
53.0
5.00 ug/L
50.00
56.1
5.00 ug/L
50.00
53.6
5.00 ug/L
50.00
53.3
5.00 ug/L
50.00
42.8
5.00 ug/L
50.00
54.9
5.00 ug/L
50.00
53.1
5.00 ug/L
50.00
44.4
5.00 ug/L
50.00
57.9
5.00 ug/L
50.00
36.9
5.00 ug/L
50.00
48.4
5.00 ug/L
50.00
58.9
24-120
58.0
15-76
61.6
40-120
84.0
21-196
85.4
35-180
57.7
17-127
78.4
43-230
98.2
79-139
90.3
14-176
38.4
5-120
98.1
52-120
87.2
60-140
35.8
60-140
68.7
60-140
62.9
60-140
77.2
60-140
113
60-140
72.6
60-140
80.5
47-145
6.46
30
79.2
33-145
5.68
30
94.9
27-133
7.66
30
85.3
33-143
9.58
30
106
17-163
9.53
30
112
24-159
9.06
30
107
35-219
11.6
30
107
11-162
10.5
30
85.7
17-168
8.80
30
110
33-227
11.4
30
106
26-137
10.0
30
88.8
59-121
4.94
30
116
39-171
10.3
30
73.8
21-133
2.77
30
96.8
54-120
9.30
30
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 11 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike Level
Source Result
%REC
%REC Limits
Batch B209096
LCS Dup (B209096-BSD1) 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine
33.3
5.00 ug/L
50.00
43.8
5.00 ug/L
50.00
43.1
5.00 ug/L
50.00
40.9
5.00 ug/L
50.00
53.6
5.00 ug/L
50.00
47.4
5.00 ug/L
50.00
53.3
5.00 ug/L
50.00
37.3
5.00 ug/L
50.00
42.1
5.00 ug/L
50.00
44.8
5.00 ug/L
50.00
52.0
5.00 ug/L
50.00
65.9
5.00 ug/L
50.00
46.5
5.00 ug/L
50.00
43.4
5.00 ug/L
50.00
44.3
5.00 ug/L
50.00
23.9
5.00 ug/L
50.00
39.8
5.00 ug/L
50.00
41.6
5.00 ug/L
50.00
35.2
5.00 ug/L
50.00
51.6
5.00 ug/L
50.00
49.4
5.00 ug/L
50.00
44.5
5.00 ug/L
50.00
30.6
5.00 ug/L
50.00
10.8
5.00 ug/L
50.00
46.1
5.00 ug/L
50.00
55.2
5.00 ug/L
50.00
47.9
5.00 ug/L
50.00
29.8
5.00 ug/L
50.00
30.3
5.00 ug/L
50.00
31.4
5.00 ug/L
50.00
44.1
5.00 ug/L
50.00
43.7
5.00 ug/L
50.00
28.1
5.00 ug/L
50.00
40.4
5.00 ug/L
50.00
52.6
5.00 ug/L
50.00
66.6
44-142
87.5
37-144
86.3
39-135
81.7
32-120
107
39-139
94.8
50-158
107
21-191
74.7
60-120
84.2
23-134
89.5
29-182
104
38-262
132
17-181
93.1
53-127
86.9
22-147
88.6
25-158
47.8
9-132
79.7
33-184
83.1
12-158
70.4
36-166
103
8-158
98.8
38-152
89.0
60-115
61.2
31-114
21.6
28-120
92.2
1-120
110
4-146
95.7
35-152
59.7
24-120
60.6
15-76
62.7
40-120
88.2
21-196
87.4
35-180
56.3
17-127
80.8
43-230
105
79-139
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
RPD
2.90 6.19 3.35 8.93 11.2 10.4 13.7 5.48 0.615 2.21 7.38 13.3 8.33 6.12 6.92 11.0 2.18 0.815 2.39 11.4 18.2 5.78 9.70 17.7 11.6 11.1 10.2 1.21 4.38 1.90 4.81 2.31 2.53 3.12 6.90
RPD Limit
30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30
Page 12 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Batch B209096
LCS Dup (B209096-BSD1) Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
Matrix Spike (B209096-MS1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
51.4
5.00 ug/L
50.00
19.1
5.00 ug/L
50.00
54.3
5.00 ug/L
50.00
43.2
ug/L
50.00
17.4
ug/L
50.00
35.4
ug/L
50.00
33.3
ug/L
50.00
40.7
ug/L
50.00
61.5
ug/L
50.00
39.1
ug/L
50.00
103
14-176
13.0
30
38.2
5-120
0.574
30
109
52-120
10.2
30
86.5
60-140
34.9
60-140
70.8
60-140
66.6
60-140
81.3
60-140
123
60-140
78.3
60-140
Source: 2209014-01
41.5
5.00 ug/L
42.8
5.00 ug/L
47.4
5.00 ug/L
40.7
5.00 ug/L
53.2
5.00 ug/L
52.7
5.00 ug/L
51.1
5.00 ug/L
50.0
5.00 ug/L
41.2
5.00 ug/L
53.7
5.00 ug/L
49.1
5.00 ug/L
50.8
5.00 ug/L
56.7
5.00 ug/L
39.2
5.00 ug/L
49.4
5.00 ug/L
38.4
5.00 ug/L
46.2
5.00 ug/L
44.2
5.00 ug/L
43.6
5.00 ug/L
55.9
5.00 ug/L
46.0
5.00 ug/L
58.5
5.00 ug/L
40.8
5.00 ug/L
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
83.0
47-145
85.5
33-145
94.9
27-133
81.5
33-143
106
17-163
105
24-159
102
35-219
100
11-162
82.4
17-168
107
33-227
98.2
26-137
102
59-121
113
39-171
78.4
21-133
98.9
54-120
76.9
44-142
92.4
37-144
88.4
39-135
87.2
32-120
112
39-139
92.0
50-158
117
21-191
81.6
60-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 13 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Batch B209096
Matrix Spike (B209096-MS1) 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol
Source: 2209014-01
38.8
5.00 ug/L
45.8
5.00 ug/L
42.3
5.00 ug/L
64.2
5.00 ug/L
52.7
5.00 ug/L
44.0
5.00 ug/L
52.5
5.00 ug/L
22.0
5.00 ug/L
41.8
5.00 ug/L
40.1
5.00 ug/L
38.8
5.00 ug/L
50.1
5.00 ug/L
49.5
5.00 ug/L
51.0
5.00 ug/L
40.4
5.00 ug/L
19.2
5.00 ug/L
48.3
5.00 ug/L
54.2
5.00 ug/L
52.4
5.00 ug/L
36.0
5.00 ug/L
28.6
5.00 ug/L
34.9
5.00 ug/L
41.5
5.00 ug/L
43.9
5.00 ug/L
21.4
5.00 ug/L
44.0
5.00 ug/L
48.4
5.00 ug/L
52.8
5.00 ug/L
18.7
5.00 ug/L
49.2
5.00 ug/L
40.8
ug/L
17.9
ug/L
40.1
ug/L
38.0
ug/L
44.1
ug/L
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00 50.00 50.00 50.00 50.00
77.6
23-134
91.6
29-182
84.5
38-262
128
17-181
105
53-127
88.0
22-147
105
25-158
44.0
9-132
83.5
33-184
80.2
12-158
77.7
36-166
100
8-158
99.0
38-152
102
61-106
80.9
31-114
38.3
28-120
96.6
1-120
108
4-146
105
35-152
72.1
24-120
57.1
15-76
69.8
40-120
83.1
21-196
87.8
35-180
42.8
17-127
87.9
43-230
96.7
79-139
106
14-176
37.3
5-120
98.5
52-120
81.5
60-140
35.9
60-140
80.1
60-140
76.0
60-140
88.2
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
RPD Limit
Page 14 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Batch B209096
Matrix Spike (B209096-MS1) Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
Matrix Spike (B209096-MS2) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
Source: 2209014-01
65.8
ug/L
38.5
ug/L
Source: 2209015-02
39.0
5.00 ug/L
39.4
5.00 ug/L
43.9
5.00 ug/L
40.0
5.00 ug/L
54.2
5.00 ug/L
52.0
5.00 ug/L
50.6
5.00 ug/L
49.8
5.00 ug/L
40.8
5.00 ug/L
52.9
5.00 ug/L
49.1
5.00 ug/L
43.6
5.00 ug/L
55.8
5.00 ug/L
37.8
5.00 ug/L
45.2
5.00 ug/L
39.8
5.00 ug/L
42.8
5.00 ug/L
42.5
5.00 ug/L
37.1
5.00 ug/L
49.2
5.00 ug/L
43.0
5.00 ug/L
66.1
5.00 ug/L
38.8
5.00 ug/L
39.0
5.00 ug/L
44.4
5.00 ug/L
44.4
5.00 ug/L
62.1
5.00 ug/L
45.1
5.00 ug/L
41.8
5.00 ug/L
44.8
5.00 ug/L
24.6
5.00 ug/L
50.00 50.00
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
132
60-140
76.9
60-140
78.0
47-145
78.8
33-145
87.7
27-133
80.0
33-143
108
17-163
104
24-159
101
35-219
99.7
11-162
81.5
17-168
106
33-227
98.2
26-137
87.1
59-121
112
39-171
75.5
21-133
90.5
54-120
79.6
44-142
85.6
37-144
84.9
39-135
74.2
32-120
98.5
39-139
86.0
50-158
132
21-191
77.7
60-120
78.0
23-134
88.8
29-182
88.8
38-262
124
17-181
90.2
53-127
83.5
22-147
89.6
25-158
49.2
9-132
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
RPD Limit
Page 15 of 32
Analyte
Batch B209096
Matrix Spike (B209096-MS2) Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2209015-02
38.0
5.00 ug/L
38.2
5.00 ug/L
36.4
5.00 ug/L
51.4
5.00 ug/L
66.1
5.00 ug/L
43.8
5.00 ug/L
43.9
5.00 ug/L
38.4
5.00 ug/L
49.2
5.00 ug/L
55.8
5.00 ug/L
45.0
5.00 ug/L
40.7
5.00 ug/L
40.4
5.00 ug/L
40.6
5.00 ug/L
38.1
5.00 ug/L
41.3
5.00 ug/L
24.6
5.00 ug/L
39.8
5.00 ug/L
42.5
5.00 ug/L
48.3
5.00 ug/L
18.8
5.00 ug/L
50.0
5.00 ug/L
37.6
ug/L
18.0
ug/L
38.9
ug/L
38.8
ug/L
41.3
ug/L
59.9
ug/L
38.2
ug/L
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00 50.00 50.00 50.00 50.00 50.00 50.00
75.9
33-184
76.4
12-158
72.9
36-166
103
8-158
132
38-152
87.7
61-106
87.8
31-114
76.9
28-120
98.3
1-120
112
4-146
90.0
35-152
81.3
24-120
80.9
15-76
81.3
40-120
76.1
21-196
82.5
35-180
49.2
17-127
79.7
43-230
85.1
79-139
96.6
14-176
37.7
5-120
99.9
52-120
75.3
60-140
35.9
60-140
77.7
60-140
77.5
60-140
82.6
60-140
120
60-140
76.5
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 16 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike Level
Source Result
%REC
%REC Limits
Batch B209096
Matrix Spike Dup (B209096-MSD1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate
Source: 2209014-01
37.8
5.00 ug/L
38.7
5.00 ug/L
44.0
5.00 ug/L
38.9
5.00 ug/L
51.8
5.00 ug/L
51.2
5.00 ug/L
50.0
5.00 ug/L
48.1
5.00 ug/L
39.4
5.00 ug/L
52.2
5.00 ug/L
48.8
5.00 ug/L
44.9
5.00 ug/L
55.1
5.00 ug/L
37.2
5.00 ug/L
45.6
5.00 ug/L
36.7
5.00 ug/L
41.8
5.00 ug/L
41.3
5.00 ug/L
41.6
5.00 ug/L
50.8
5.00 ug/L
42.0
5.00 ug/L
63.9
5.00 ug/L
37.1
5.00 ug/L
39.2
5.00 ug/L
43.6
5.00 ug/L
41.1
5.00 ug/L
60.7
5.00 ug/L
45.5
5.00 ug/L
40.4
5.00 ug/L
44.8
5.00 ug/L
23.0
5.00 ug/L
37.7
5.00 ug/L
39.0
5.00 ug/L
36.1
5.00 ug/L
48.0
5.00 ug/L
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
50.00
ND
75.5
47-145
77.3
33-145
88.1
27-133
77.9
33-143
104
17-163
102
24-159
100
35-219
96.2
11-162
78.9
17-168
104
33-227
97.6
26-137
89.8
59-121
110
39-171
74.4
21-133
91.2
54-120
73.4
44-142
83.6
37-144
82.6
39-135
83.3
32-120
102
39-139
84.0
50-158
128
21-191
74.2
60-120
78.5
23-134
87.2
29-182
82.2
38-262
121
17-181
91.1
53-127
80.7
22-147
89.7
25-158
46.1
9-132
75.4
33-184
78.0
12-158
72.2
36-166
96.0
8-158
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
RPD
9.46 10.0 7.41 4.52 2.66 2.85 2.00 3.81 4.37 2.83 0.695 12.4 2.79 5.23 8.12 4.71 10.0 6.71 4.67 9.73 9.16 8.81 9.55 1.18 4.95 2.86 5.59 14.7 8.68 15.8 4.66 10.2 2.73 7.34 4.24
RPD Limit
24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24
Page 17 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Batch B209096
Matrix Spike Dup (B209096-MSD1) Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
Matrix Spike Dup (B209096-MSD2) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2209014-01
45.8
5.00 ug/L
50.00
ND
91.6
38-152
7.77
24
44.7
5.00 ug/L
50.00
ND
89.4
61-106
13.2
24
33.6
5.00 ug/L
50.00
ND
67.2
31-114
18.4
24
15.2
5.00 ug/L
50.00
ND
30.5
28-120
22.8
24
43.1
5.00 ug/L
50.00
ND
86.2
1-120
11.4
24
52.6
5.00 ug/L
50.00
ND
105
4-146
3.05
24
46.0
5.00 ug/L
50.00
ND
91.9
35-152
13.0
24
35.7
5.00 ug/L
50.00
ND
71.4
24-120
1.03
24
26.1
5.00 ug/L
50.00
ND
52.2
15-76
8.92
24
36.0
5.00 ug/L
50.00
ND
72.1
40-120
3.19
24
37.2
5.00 ug/L
50.00
ND
74.5
21-196
10.9
24
41.7
5.00 ug/L
50.00
ND
83.4
35-180
5.16
24
27.6
5.00 ug/L
50.00
ND
55.3
17-127
25.5
24
39.5
5.00 ug/L
50.00
ND
79.0
43-230
10.8
24
43.1
5.00 ug/L
50.00
ND
86.3
79-139
11.4
24
49.6
5.00 ug/L
50.00
ND
99.2
14-176
6.23
24
19.5
5.00 ug/L
50.00
ND
39.0
5-120
4.45
24
49.7
5.00 ug/L
50.00
ND
99.5
52-120
1.03
24
41.1
ug/L
50.00
82.2
60-140
18.9
ug/L
50.00
37.8
60-140
36.5
ug/L
50.00
73.0
60-140
34.0
ug/L
50.00
68.0
60-140
39.4
ug/L
50.00
78.9
60-140
60.1
ug/L
50.00
120
60-140
36.9
ug/L
50.00
73.7
60-140
Source: 2209015-02
39.8
5.05 ug/L
50.51
ND
78.8
47-145
2.03
24
40.2
5.05 ug/L
50.51
ND
79.5
33-145
1.97
24
44.7
5.05 ug/L
50.51
ND
88.5
27-133
1.85
24
40.3
5.05 ug/L
50.51
ND
79.9
33-143
0.880
24
54.0
5.05 ug/L
50.51
ND
107
17-163
0.332
24
52.7
5.05 ug/L
50.51
ND
104
24-159
1.35
24
51.1
5.05 ug/L
50.51
ND
101
35-219
0.827
24
49.6
5.05 ug/L
50.51
ND
98.2
11-162
0.532
24
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 18 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Result
Reporting Limit
Units
Spike Level
Source Result
%REC
%REC Limits
Batch B209096
Matrix Spike Dup (B209096-MSD2) Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene
Source: 2209015-02
41.2
5.05 ug/L
53.6
5.05 ug/L
50.8
5.05 ug/L
44.5
5.05 ug/L
56.5
5.05 ug/L
38.2
5.05 ug/L
46.4
5.05 ug/L
39.9
5.05 ug/L
43.7
5.05 ug/L
41.9
5.05 ug/L
29.2
5.05 ug/L
51.2
5.05 ug/L
44.6
5.05 ug/L
70.9
5.05 ug/L
39.6
5.05 ug/L
39.0
5.05 ug/L
45.2
5.05 ug/L
43.2
5.05 ug/L
63.6
5.05 ug/L
46.6
5.05 ug/L
42.0
5.05 ug/L
45.9
5.05 ug/L
23.1
5.05 ug/L
38.0
5.05 ug/L
38.8
5.05 ug/L
36.0
5.05 ug/L
50.1
5.05 ug/L
65.9
5.05 ug/L
44.4
5.05 ug/L
44.8
5.05 ug/L
38.8
5.05 ug/L
50.0
5.05 ug/L
54.2
5.05 ug/L
46.8
5.05 ug/L
40.8
5.05 ug/L
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
50.51
ND
81.6
17-168
106
33-227
101
26-137
88.1
59-121
112
39-171
75.6
21-133
91.8
54-120
79.0
44-142
86.6
37-144
83.0
39-135
57.9
32-120
101
39-139
88.2
50-158
140
21-191
78.3
60-120
77.2
23-134
89.4
29-182
85.4
38-262
126
17-181
92.2
53-127
83.2
22-147
90.8
25-158
45.7
9-132
75.2
33-184
76.9
12-158
71.4
36-166
99.2
8-158
130
38-152
88.0
61-106
88.8
31-114
76.9
28-120
98.9
1-120
107
4-146
92.7
35-152
80.7
24-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
RPD
1.10 1.44 3.38 2.06 1.17 1.14 2.50 0.274 2.14 1.33 23.7 3.99 3.55 7.04 1.83 0.0518 1.66 2.90 2.49 3.18 0.669 2.31 6.42 0.0253 1.55 1.10 2.62 0.289 1.32 2.14 1.01 1.61 2.85 3.94 0.289
RPD Limit
24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24
Page 19 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 NVOA GCMS - Quality Control
Analyte
Batch B209096
Matrix Spike Dup (B209096-MSD2) Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene
Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2209015-02
38.6
5.05 ug/L
50.51
ND
76.5
15-76
4.59
24
41.2
5.05 ug/L
50.51
ND
81.7
40-120
1.50
24
38.4
5.05 ug/L
50.51
ND
76.0
21-196
0.900
24
41.6
5.05 ug/L
50.51
ND
82.4
35-180
0.835
24
26.9
5.05 ug/L
50.51
ND
53.2
17-127
8.77
24
40.2
5.05 ug/L
50.51
ND
79.6
43-230
0.854
24
43.5
5.05 ug/L
50.51
ND
86.0
79-139
2.15
24
48.4
5.05 ug/L
50.51
ND
95.8
14-176
0.194
24
17.9
5.05 ug/L
50.51
ND
35.5
5-120
5.01
24
51.2
5.05 ug/L
50.51
ND
101
52-120
2.55
24
39.7
ug/L
50.51
78.6
60-140
17.2
ug/L
50.51
34.1
60-140
39.4
ug/L
50.51
78.0
60-140
39.1
ug/L
50.51
77.4
60-140
42.1
ug/L
50.51
83.4
60-140
61.8
ug/L
50.51
122
60-140
38.8
ug/L
50.51
76.8
60-140
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 20 of 32
Analyte
Batch B209085
Blank (B209085-BLK1) Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260
Surrogate: TCMX Surrogate: TCMX [2C] Surrogate: DCB Surrogate: DCB [2C]
LCS (B209085-BS1) Aroclor 1016 Aroclor 1016 [2C] Aroclor 1260 Aroclor 1260 [2C]
Surrogate: TCMX Surrogate: TCMX [2C] Surrogate: DCB Surrogate: DCB [2C]
LCS Dup (B209085-BSD1) Aroclor 1016 Aroclor 1016 [2C] Aroclor 1260 Aroclor 1260 [2C]
Surrogate: TCMX Surrogate: TCMX [2C] Surrogate: DCB Surrogate: DCB [2C]
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 PCB Aroclors GC - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U --- U --- U --- U --- U --- U --- U
ND ND ND ND
0.251 0.276 0.232 0.217 0.0437 0.0433 0.0280 0.0266
0.259 0.281 0.226 0.219 0.0431 0.0439 0.0324 0.0300
0.031 ug/L 0.062 ug/L 0.031 ug/L 0.031 ug/L 0.031 ug/L 0.031 ug/L 0.031 ug/L
ug/L ug/L ug/L ug/L
0.06000 0.06000 0.06000 0.06000
0.031 ug/L 0.031 ug/L 0.031 ug/L 0.031 ug/L
ug/L ug/L ug/L ug/L
0.2500 0.2500 0.2500 0.2500
0.06000 0.06000 0.06000 0.06000
0.031 ug/L 0.031 ug/L 0.031 ug/L 0.031 ug/L
ug/L ug/L ug/L ug/L
0.2500 0.2500 0.2500 0.2500
0.06000 0.06000 0.06000 0.06000
54.8
23-101
54.4
23-101
46.6
25-107
43.8
25-107
100
50-140
110
50-140
92.8
8-140
86.8
8-140
72.8
23-101
72.1
23-101
46.6
25-107
44.4
25-107
104
50-140
3.19
36
112
50-140
1.84
36
90.2
8-140
2.77
38
87.6
8-140
0.932
38
71.9
23-101
73.1
23-101
54.0
25-107
50.0
25-107
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 21 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 PCB Aroclors GC - Quality Control
Analyte
Batch B209085
Matrix Spike (B209085-MS1) Aroclor 1016 Aroclor 1016 [2C] Aroclor 1260 Aroclor 1260 [2C] Surrogate: TCMX Surrogate: TCMX [2C] Surrogate: DCB Surrogate: DCB [2C]
Matrix Spike (B209085-MS2) Aroclor 1016 Aroclor 1016 [2C] Aroclor 1260 Aroclor 1260 [2C] Surrogate: TCMX Surrogate: TCMX [2C] Surrogate: DCB Surrogate: DCB [2C]
Matrix Spike Dup (B209085-MSD1) Aroclor 1016 Aroclor 1016 [2C] Aroclor 1260 Aroclor 1260 [2C] Surrogate: TCMX Surrogate: TCMX [2C] Surrogate: DCB Surrogate: DCB [2C]
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2209016-06
0.204
0.031 ug/L
0.224
0.031 ug/L
0.264
0.031 ug/L
0.171
0.031 ug/L
0.0361
ug/L
0.0402
ug/L
0.0446
ug/L
0.0437
ug/L
0.2451
ND
0.2451
ND
0.2451
ND
0.2451
ND
0.05882 0.05882 0.05882 0.05882
83.1
50-140
91.6
50-140
108
8-140
69.8
8-140
61.4
23-101
68.3
23-101
75.8
25-107
74.2
25-107
Source: 2209014-01
0.274
0.031 ug/L
0.262
0.031 ug/L
0.250
0.031 ug/L
0.160
0.031 ug/L
0.0324
ug/L
0.0315
ug/L
0.0481
ug/L
0.0387
ug/L
0.2463
ND
0.2463
ND
0.2463
ND
0.2463
ND
0.05911 0.05911 0.05911 0.05911
111
50-140
106
50-140
102
8-140
64.9
8-140
54.8
23-101
53.3
23-101
81.4
25-107
65.5
25-107
Source: 2209016-06
0.271
0.031 ug/L
0.2463
ND
110
50-140
28.4
36
0.254
0.031 ug/L
0.2463
ND
103
50-140
12.2
36
0.218
0.031 ug/L
0.2463
ND
88.6
8-140
18.9
38
0.162
0.031 ug/L
0.2463
ND
65.7
8-140
5.67
38
0.0354 0.0357 0.0438 0.0393
ug/L
0.05911
ug/L
0.05911
ug/L
0.05911
ug/L
0.05911
59.9
23-101
60.4
23-101
74.2
25-107
66.4
25-107
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 22 of 32
Analyte
Batch B209121 Blank (B209121-BLK1)
Oil & Grease
LCS (B209121-BS1) Oil & Grease
LCS Dup (B209121-BSD1) Oil & Grease
Matrix Spike (B209121-MS1) Oil & Grease
Matrix Spike (B209121-MS2) Oil & Grease
Matrix Spike (B209121-MS3) Oil & Grease
Matrix Spike (B209121-MS4) Oil & Grease
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 GC - Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
5.00 mg/L
34.4
5.00 mg/L
40.00
86
78-114
37.3
5.00 mg/L
40.00
93
78-114
8
20
Source: 2209013-02
41.8
5.00 mg/L
51.28
ND
82
78-114
Source: 2209014-01
42.2
5.00 mg/L
51.28
ND
82
78-114
Source: 2209015-04
39.1
5.00 mg/L
45.98
ND
85
78-114
Source: 2209016-02
42.2
5.00 mg/L
48.78
ND
87
78-114
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 23 of 32
Analyte
Batch B209117
Blank (B209117-BLK1) Antimony Arsenic Beryllium Cadmium Chromium Copper Iron Lead Nickel Selenium Silver Thallium Zinc
LCS (B209117-BS1) Antimony Arsenic Beryllium Cadmium Chromium Copper Iron Lead Nickel Selenium Silver Thallium Zinc
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Metals ICP - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U
188 185 190 190 192 190 4770 191 191 183 191 187 188
20.0 ug/L 8.00 ug/L 3.00 ug/L 3.00 ug/L 5.00 ug/L 10.0 ug/L 50.0 ug/L 8.00 ug/L 20.0 ug/L 20.0 ug/L 5.00 ug/L 20.0 ug/L 20.0 ug/L
20.0 ug/L 8.00 ug/L 3.00 ug/L 3.00 ug/L 5.00 ug/L 10.0 ug/L 50.0 ug/L 8.00 ug/L 20.0 ug/L 20.0 ug/L 5.00 ug/L 20.0 ug/L 20.0 ug/L
200.0 200.0 200.0 200.0 200.0 200.0 5000 200.0 200.0 200.0 200.0 200.0 200.0
94.2
85-115
92.7
85-115
95.1
85-115
95.0
85-115
95.9
85-115
94.9
85-115
95.5
85-115
95.6
85-115
95.5
85-115
91.4
85-115
95.4
85-115
93.6
85-115
94.2
85-115
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 24 of 32
Analyte
Batch B209117
LCS Dup (B209117-BSD1) Antimony Arsenic Beryllium Cadmium Chromium Copper Iron Lead Nickel Selenium Silver Thallium Zinc
Matrix Spike (B209117-MS1) Cadmium Lead Nickel Thallium
Matrix Spike (B209117-MS2) Arsenic Cadmium Copper Nickel Silver Thallium
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Metals ICP - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
191 186 196 192 194 192 4920 194 192 188 192 190 190
20.0 ug/L 8.00 ug/L 3.00 ug/L 3.00 ug/L 5.00 ug/L 10.0 ug/L 50.0 ug/L 8.00 ug/L 20.0 ug/L 20.0 ug/L 5.00 ug/L 20.0 ug/L 20.0 ug/L
200.0 200.0 200.0 200.0 200.0 200.0 5000 200.0 200.0 200.0 200.0 200.0 200.0
95.3
85-115
1.17
20
93.2
85-115
0.527
20
98.1
85-115
3.12
20
95.8
85-115
0.755
20
96.8
85-115
0.944
20
95.9
85-115
1.05
20
98.5
85-115
3.12
20
96.9
85-115
1.29
20
96.1
85-115
0.668
20
94.1
85-115
2.90
20
96.1
85-115
0.783
20
94.8
85-115
1.37
20
95.0
85-115
0.830
20
Source: 2209013-02
166
3.00 ug/L
175
8.00 ug/L
193
20.0 ug/L
169
20.0 ug/L
200.0
ND
200.0
2.40
200.0
19.0
200.0
7.03
82.8
80-120
86.4
80-120
87.2
80-120
81.1
80-120
Source: 2209014-01
196
8.00 ug/L
178
3.00 ug/L
213
10.0 ug/L
188
20.0 ug/L
201
5.00 ug/L
170
20.0 ug/L
200.0
3.57
200.0
ND
200.0
3.06
200.0
8.85
200.0
ND
200.0
7.07
96.0
80-120
88.8
80-120
105
80-120
89.6
80-120
101
80-120
81.4
80-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 25 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Metals ICP - Quality Control
Analyte
Batch B209117 Matrix Spike (B209117-MS3)
Copper Zinc
Matrix Spike (B209117-MS4) Zinc
Matrix Spike Dup (B209117-MSD1) Cadmium Lead Nickel Thallium
Matrix Spike Dup (B209117-MSD2) Arsenic Cadmium Copper Nickel Silver Thallium
Matrix Spike Dup (B209117-MSD3) Copper Zinc
Matrix Spike Dup (B209117-MSD4) Zinc
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2209015-01
289
10.0 ug/L
146
20.0 ug/L
200.0
ND
200.0
ND
145
80-120
72.9
80-120
Source: 2209016-01
137
20.0 ug/L
200.0
1.99
67.5
80-120
Source: 2209013-02
184
15.0 ug/L
200.0
ND
91.9
80-120
10.4
10
194
40.0 ug/L
200.0
ND
97.1
80-120
10.3
10
216
100 ug/L
200.0
19.0
98.8
80-120
11.3
10
200
100 ug/L
200.0
ND
99.8
80-120
16.5
10
Source: 2209014-01
187
40.0 ug/L
200.0
ND
93.4
80-120
4.55
10
183
15.0 ug/L
200.0
ND
91.4
80-120
2.84
10
204
50.0 ug/L
200.0
ND
102
80-120
4.63
10
190
100 ug/L
200.0
ND
95.0
80-120
1.08
10
187
25.0 ug/L
200.0
ND
93.4
80-120
7.48
10
198
100 ug/L
200.0
ND
98.8
80-120
15.1
10
Source: 2209015-01
248
50.0 ug/L
200.0
ND
124
80-120
15.4
10
190
100 ug/L
200.0
ND
94.8
80-120
26.2
10
Source: 2209016-01
182
100 ug/L
200.0
ND
91.0
80-120
28.3
10
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 26 of 32
Analyte
Batch B209111 Blank (B209111-BLK1)
Mercury
LCS (B209111-BS1) Mercury
LCS Dup (B209111-BSD1) Mercury
Matrix Spike (B209111-MS2) Mercury
Matrix Spike (B209111-MS3) Mercury
Matrix Spike (B209111-MS4) Mercury
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Mercury CVAA - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
0.050 ug/L
0.971
0.050 ug/L
1.000
97.1
85-115
0.931
0.050 ug/L
1.000
93.1
85-115
4.21
20
Source: 2209013-04
0.928
0.050 ug/L
1.000
ND
92.8
80-120
Source: 2209014-01
0.902
0.050 ug/L
1.000
ND
90.2
80-120
Source: 2209016-02
0.990
0.050 ug/L
1.000
0.068
92.2
80-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 27 of 32
Analyte
Batch B209078 Blank (B209078-BLK1)
Color
LCS (B209078-BS1) Color
LCS Dup (B209078-BSD1) Color
Duplicate (B209078-DUP1) Color
Batch B209079 Blank (B209079-BLK1)
Ammonia [As N]
LCS (B209079-BS1) Ammonia [As N]
LCS Dup (B209079-BSD1) Ammonia [As N]
Matrix Spike (B209079-MS1) Ammonia [As N]
Batch B209080 Blank (B209080-BLK1)
Biochemical Oxygen Demand
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
<5
5.00 Color Units
40.0
10.0 Color Units 40.00
100
85-115
40.0
10.0 Color Units 40.00
100
85-115
0.00
20
Source: 2209016-01
5.00
5.00 Color Units
5.00
0.00
20
--- U
0.100 mg/L
15.5
0.200 mg/L
14.90
104
90-110
15.6
0.200 mg/L
14.90
105
90-110
0.9
20
Source: 2209014-01
4.96
0.100 mg/L
5.000
0.115
97
90-110
--- U
2.00 mg/L
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 28 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Sanitary - Quality Control
Analyte
Batch B209080 LCS (B209080-BS1)
Biochemical Oxygen Demand
LCS (B209080-BS2) Biochemical Oxygen Demand
LCS (B209080-BS3) Biochemical Oxygen Demand
Duplicate (B209080-DUP1) Biochemical Oxygen Demand
Matrix Spike (B209080-MS1) Biochemical Oxygen Demand
Matrix Spike Dup (B209080-MSD1) Biochemical Oxygen Demand
Batch B209081 LCS (B209081-BS1)
Turbidity
LCS Dup (B209081-BSD1) Turbidity
Duplicate (B209081-DUP1) Turbidity
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
215
mg/L
198.0
108 84.6-115.4
201
mg/L
198.0
101 84.6-115.4
200
mg/L
198.0
101 84.6-115.4
Source: 2209014-04
5.94
2.00 mg/L
6.47
8.46
25
Source: 2209014-04
38.4
2.00 mg/L
31.68
6.47
101
75-125
Source: 2209014-04
31.6
2.00 mg/L
23.76
6.47
106
75-125
19.3
200
19.3
0.100 NTU
19.90
97.0
90-110
19.3
0.100 NTU
19.90
97.0
90-110
0.00
20
Source: 2209014-01
0.735
0.100 NTU
0.773
5.04
20
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 29 of 32
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Sanitary - Quality Control
Analyte
Batch B209083 Blank (B209083-BLK1)
Residue, Non-Filterable
LCS (B209083-BS1) Residue, Non-Filterable
LCS Dup (B209083-BSD1) Residue, Non-Filterable
Duplicate (B209083-DUP1) Residue, Non-Filterable
Batch B209088 Blank (B209088-BLK1)
Weak Acid Dissociable [Free] Cyanide
Blank (B209088-BLK2) Weak Acid Dissociable [Free] Cyanide
LCS (B209088-BS1) Cyanide, Total
LCS Dup (B209088-BSD1) Cyanide, Total
Matrix Spike (B209088-MS1) Cyanide, Total
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
--- U
10.0 mg/L
55.0
10.0 mg/L
55.10
99.8
85-115
55.0
10.0 mg/L
55.10
99.8
85-115
0.00
20
Source: 2209014-04
4.00
10.0 mg/L
7.00
54.5
20
--- U
10.0 ug/L
--- U
10.0 ug/L
477
10.0 ug/L
440.0
108
85-115
474
10.0 ug/L
440.0
108
85-115
0.6
20
Source: 2209014-01
484
10.0 ug/L
500.0
0.747
97
80-120
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 30 of 32
Analyte
Batch B209088 Matrix Spike (B209088-MS2)
Cyanide, Total
Batch B209089 LCS (B209089-BS1)
Sulfide
LCS Dup (B209089-BSD1) Sulfide
Matrix Spike (B209089-MS1) Sulfide
Batch B209109 LCS (B209109-BS1)
Sulfate
LCS Dup (B209109-BSD1) Sulfate
Matrix Spike (B209109-MS1) Sulfate
Matrix Spike (B209109-MS2) Sulfate
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
Source: 2209016-02
482
10.0 ug/L
500.0
0.304
96
80-120
0.580
0.0100 mg/L
0.5720
101
85-115
0.609
0.0100 mg/L
0.5720
107
85-115
5
20
Source: 2209014-01
0.0926
0.0100 mg/L
0.2000 0.0226
35
80-120
12.4
2.00 mg/L
12.50
99
90-110
12.5
2.00 mg/L
12.50
100
90-110
0.8
20
Source: 2209021-07
44.9
1.00 mg/L
20.00
24.6
102
90-110
Source: 2209014-01
3420
100 mg/L
20.00
3570
NR
90-110
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 31 of 32
Analyte
Batch B209114 LCS (B209114-BS1)
Nitrate + Nitrite [As N]
LCS Dup (B209114-BSD1) Nitrate + Nitrite [As N]
Matrix Spike (B209114-MS1) Nitrate + Nitrite [As N]
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory
Final Report Project: PREPA Palo Seco Power Plant - 2209014
Project Number: 2209014 Sanitary - Quality Control
Result
Reporting Limit
Units
Spike
Source
%REC
Level
Result %REC Limits
RPD
RPD Limit
16.7
0.500 mg/L
16.50
101
90-110
16.9
0.500 mg/L
16.50
102
90-110
1.19
200
Source: 2209014-01
1.35
0.0500 mg/L
0.2000
1.18
85.0
90-110
U.S.E.P.A Region 2 Laboratory
NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 10/3/2022
Page 32 of 32
