Document 159EkEzZoqMw0Qb91299nNKpo
NEW ADDITIONS TO THE
3M #3500 COMPOUND GUIDE
Butyl Acrylate Butyl Glycidyl Ether (BGE) Carbon Disulfide O-Chlorostyrene o-Chlorotoluene Chloroprene
(2-Chloro-l,3-butadiene) 1,l-Dichloroethane 1,2,-Dichloroethylene Dichloroethyl Ether Dipropylene Glycol Methyl Ether Ethyl Alcohol Ethyl Butyl Ketone
(3-Heptanone) Ethyl Formate Ethylene Chlorohydrin
(2-Chloroethanol) Furfuryl Alcohol Hexachloroethane s-Hexyl Acetate Methylal
(Dime thyoxymethane) Methyl Amyl Ketone
(2-Heptanone) Methyl Bromide Methyl Cyclohexane Methyl Cyclohexanol Methyl Formate 5-Methyl-3-heptanone
(Ethyl Amyl Ketone) Methyl Iodide Methyl Isobutyl Carbinol
(Methyl Amyl Alcohol) Methyl Isoamyl Ketone Methyl Methacrylate Alpha Methyl Styrene Methylene Chloride
(Dichloromethane) Naphtha (VM&P) Nonane Phenyl Glycidyl Ether Propylene Glycol Monomethyl Ether n-Propyl Nitrate Tetrahydrofuran 1,2,3-Trichloropropane Vinyl Acetate Vinyl Bromide Vinylidene Chloride Vinyl Toluene
3M 005334
3H 005335
Ij
((Jce^ewe*1 AcetentTrl 1 e AcrylaittrUn Ullyl Alcohol Ally! :morld* w-4*'.^ Acetate n-A'".y) Acetate h-Ayl Alcohol* t-Anyl Alcohol* |^t-Arayl Alcohol Benzene* Benzyl Chloride Bronof orm Bu tedlene A-putyl Acetate 3-B'>tyl Acetate t-Butyl Acetate * >tyl J^rylate *fc* fcutyl Alcohol!* s-Butyl Alcohol jUtyl Alcohol 1 Butyl Cellosolve * | (2-3utoxyethnol)
JAhl ,-ii.u
OiLu l
UillA A tandn i t
I-------------------------------------------- UhCOl'lfwill&J
dAhhl.iWC i r\;' J. Ob
rUA-J'Ai.
(hr)
.`liiuti r l'l5h t.
( ) AC^llH 1'l.V
C-C e 11 In i
nA iii ___ All < ?Qa
microsran 1 " * 5 .5 -3
Ah > .1-.5 '
70,. .5-3
( 1 *) 31'ai.
1,1 r. I (' min)
OVh
(lit.) (cc/i'il n ' (ijnn-hr m. i'bt. rtiL 1*41 (m.) UsHye
1000 AO 2
40.1 AN .2 irj.B
5.71 A.85 5.70
1 5 1 .5
n2
61
82
61
1250 iff,') AO Yes
--
2 1 100 125 (100)
40. 4 35.1 26.0
5.75 6.63 7.36
27.2
8.68
51.4
6.78
88 88 88 83 88
86 86 84 84 84
2 No 2 No 150 Yes ---
100 (100)
10 1
5 1000
150 200
32.3 32.3
6.98 6.98
35.5 27.2
6.78 8.48
29.3 18.19
42.8 31.6
5.67 9.00
28.6
8.14
88 88
84 8A
88 88 88 .4 NR 37 85
86 86 86 .4 Nil 63 63
125 Yea -25 Yes --
1250 Yes 200 Yes 250 Yes,
200
29.4
8.37
(10)
100 (50)
150
28.7
9.01
34.3 34.8
5.55 6.32
100
35.2
6.39
50
28.2
8.15
84
6
88 8
3 6
88
8A
86
63
87
63
8 8( 8 6
250 Yes --- -150 Yes 150 Yes
i 3M 005336
1 6>ut.yi ciytteyl thei (BcF) "Kr
OMI-.A tondu i'ii
iWa-j oi, ( jACviltl
n.v
CAm'i.lMC HATS
H &C OhincH DSL) CAhl'lilNu Tciu IDb
(Hra)
nli 470/
hh>7 0*
t; -i;i!Uli (J-i'h)
T (co/nln
il erne, re in Pijm-Kr
.1-.5 nil.
.5-3 1'iiL
.i i'EL
.5-3 i`ta.
j|. v.,1 f 1511 u'jUht 1 lr J I'
( 15 iMn)
..ret.
OVh
(11 k) Usage
50
27.0
8.61
88
06
i t -Buty1 toluene*
CnfW*r
Carbon Disulfide
Carbol "flptrachlorldo*
tel 1 eaolve* (2-(fthoxyethanol)
C*noolve Acetate* f2-tboxyethyl Acetate)
Chlorobenzene*
o-Chl oroe tyrene ^o-Chlomtoluene
Chiorobromomethane*
Chloroform
1 -Chioro-1-nltropropana
10
2
20
10
200 (100)
100
75
(50)
(50) 200
50 (10)
20.
20.7 21.4
7-51 7.11
42.8
7.88
30.2 11.41
32.4
7.14
26.6
8.60
290
8.12
26.0
8.87
270
8.51
34.4 10.89
33.5 30.4
9.78 9.25
88
86
88
86
82
61
88
86
85 88
83 84
'8
8
85
88
86
88
86
8 1.5 6 1.5
84
63
8 8 , 8 .6
20 yes 3 No
-- 20 res 150 Yes 150 les -75 lea 75 Yes 250 Yes 50 Yes --
Chloroprene (2-Chloro-l,3-butadiene)
Cumene*
Cyclohexane* Cycl ohexanol* Cyolohexanon/ Cyclohexene* Diacetone Aloohol? ^-Dlchlorobenzene *
p-Dlchlorobenzene *
25 (10)
50
32.2 24.5
7.03 8.82
300
32.4
6.6?
50 29.5 7.24
50
28.9
6.94
300
320
6.49
50
28.2
7.15
50 27.8 10.03
75 2?,8 10.03
88 88 a3 88 88 83 88 88 88
64 86 62 86 86 62 86 86 86
-75 Yes
375 Yes ---75 Yes
j110 Yes
3M 005337
ii
1,1 'D) (>> I 'icoijM 'inn I ,2-IMchloioathylane* l, i-Dlehloro-l-nl treethane
f.JA-iVX
(jAt;.; ui n.v
LiiU.t'l, Li. J L i-t
-`-Cell 1 n
lie v'vrni.i (iJi'M) (cc/tnln) l>|jm-h>`
{j: Oi-u'i
SAHrLIiKi I'Chl'.'J (Hi)
nil < 70i
hH>70,o
.1-.5 5-3 1-.5 .5-3 i'&l. Mil. 1 hi. t cL
1 t\,,ii ,
.W. i iJ'illl'a!. l. . .1
0 5 i ll ri )
> l'ii.
UV H
( 1 i'K) IIHHui:
100 (200)
200
10
33.2
3.0?
35-2
U. 33
28.5 10.0?
y 1.5 4 1.5
1 .2 1 .2
88
a6
2 30 tV'< 250 fen
10 yes
Dlchloroothyl lifcher )(" JM isobut.y 1 Ketone*
15 (5)
50
]ii)"icthyl /nr'imintcie
10
y^)\ ')x*ino *B>1 propylene tilyool Methyl tither
100 (50)
100
^nfliirnne (2-chloro-l,1,2 trlfluoro-
, ethyl dlfluoromethyl a the] i ilitohlorohydrln
(l-Chloro-2,3-epoxy-propan
thyl Acetate*
(2)
5 (2)
'*00
gthyl Acrylate thyl Alcohol
*
25 1000
Ethyl Benzene
100
fcthyl Bronlde*
fithyl Butyl Ketone (3-Heptan<m)t
200 50
26.1 24.6 32.4 34.5
9.16 8.56 5.8 7.45
25.3 - 9.19
28.3 12.81
29.6
6.76
34.5
7.45
32.2
7.90
51.2
5.78
27.3 36.4 28.0
7.10 9.74 7.83
88
a6
88
86
a 8. 8 6
8 `8
8 8
84 84
88 88 71 88
86 86 41 64
4 .5
4 .5
88
84
1 .2 1 .2
88
86
10 ys
--
20 yes
150 yes
5 iio -- --125 yes 250 yes 75 yes
thyl
thyl foriKte
thylene chlorohydrln {2-C hioroethenol) ^
nylene Dlbromlde* (1,2-Dlbromoraethane)
t.thylene Bichloride* (1,2-Dlohloroethane)
400 100
36.8 38.8
6.68 7.04
5
.20
50 (10).
33-9
6.66
29.6 13.66
33.2
8.07
NR 3 .5 88
3 NR 3 .5 86
88
86
88
64
500 yes 150 yea -"*
15 yes
3M 005338
i-' I'u i 1'iJ JU IL- U
3H 005339
(
NVethyl Amyl Katone ^6* (2-Heptanone)
A^ethyl Bromide
Methyl Butyl Kotone* (2-Hexanone)
Methyl Isobufcyl Ketone* (Hexanone)
Methyl cellosolve* (2-Hethoxyethanol)
Methyl Cellosolve Acetate* (Ethylene Glyool Methyl
. Etjjer Aoatate) Methyl Chloroform
J,' * W tt.Uyo tfO*
Methyl Cyclohexane* *"
Methyl Cyclohexanol ^
Methyl hthyl Ketone* (2-Butanone)
Methyl Formate *t*
3-Methyl-3-heptanone ^ (Ethyl Amyl Ketone) "
Methyl iodide Hr
Methyl Isotntyl Carttee$^;3fel<; (Methyl Amyl
Methyl ieoanyl ietM J#|i"
Methyl Me theorylate J
Alpha Methyl styrene*
Met,tt/ieno Chloride* ^ (Dlohloroaethane)
Naphtha (VHfcP)*
XT
Naphthalene
i
Nonane
/
Octane*
SAMPLING GUlUc 5
03HA
Standard TUA-PEL
() ACGIH
SAMPLING RATS
recommended
SAMPLING PERIOD (Hrs)
TLV -Celling
RH<,7Q*
RH ^ 70%
(PPM)
tlcroKram 1-.5 .5-3 .l-.f .5-3
(oo/mln ppm-kr PEL
PEL PEL PEL
SHORT TERM
EXPOSURE LIMIT (15 min)
STSL (PPM)
QVM
Usage
100
2 7.9
7.81
88
84
150 Yes
20 (15)
100
46.5 10.84
29.7
7.29
100
30.0
7.35
25
36.3
6.76
25
29.0
8.38
350 30.9 10.09
500
28.9
6.94
100 (50)
200
28.8 36.3
8.06 6.41
100
45.0
6.33
25
26.4
7.39
5 36.7 12.79
25
29.2
6.51
100 100
28.0
7.83
31.8
7.80
100
25.0
7.24
4 .5 3 .5
88
84
88
84
88
86
88
86
61
41
8 2.5 6 2
88
84
83
62
.7 na 7 NR
88
86
61 88
41 86
88
84
88 88
.8 4 84
-50 Yea 125 Yes 35 Yes 35 Yes 450 Yes 500 Yes 75 Yes 300 Yes 150 Yes
--
10 Yes 40 Yes 150 Yes 125 yes
vOo\(oMO
300 10
(200) 500
37.9 33.2
7.91 8.15
24.6
6.88
24.6
7.71
26.6
7.43
1 .2 1 .2
82
62
250 Yes 400 Yes
88
86
15 Yes
85
63
250 Yes
83
6 2 --2ZL. laa-..
3H 005340
1
V'entnne* 2-Pentenone* (liethyl propyl Ketone) 'jWchloroethylone
GA.-U'LING guide 6
03HA
Standard TWA-PEL
SAMPLING HATE
( ) ACGI1 TLV
<
^CEILINC (PPM)
l co/nin j'
lcroaram ppm-hr
RECOMMENDED
SAMPLING PERIOD (Hra)
RH<70*
RH > 70a
.1-.5 5-3 1-.5 5-3
PEL PEL
PEL PEL
SHORT TEH!. SXiOSUnE LIMIT
(15 min)
SCEl. 0VM (PPM) Usage
1000 (600)
200
350 33.0
5.56 6.95
2. 5 .4 2.5 .4
85
63
750 250 lea
100 280 11.53
87
63
150 Yea
Phenyl Ether
1
Phenyl Glyoldyl Ether
10
n-Propyl Acetate*
200
n-Propyl Alcohol
200
Propylene Dlohlorlde* ^ (1,2-Dlohloropropane) Vropylen Glycol Monoaethyl Bthe:
n-propyl Mitrefee Afc
75
--
(100) 25
Stoddnrri Solvent Styrene*
500 (100)
100.
1,1.22 -Tetrachioroethane
111.1,2-Tetrnchloro-2,2-dlfluoro ethane
1,1,2,2-Tetraohloro-l,2-dlfluoro ethane
Ifelrahydrofuren
5 .500 5 00 200
Toluene*
200
1,1,2-Trlohloroethane*
10
Trie hioroe thylene*
^1.2-rrlchloro-l,2,2-trlfluoroT othana
ji.2,3-,rrlchloropr pan* ^
10 (100) 1000
50
24.1 10.05
20.8 30.1
7*71 7.53
39.7 30.6 32.4
5.21 8.49 6.09
330 240
7.27 8.59
26.8
6.83
28.4 11*71
29.7 14,87
28.2 14.12
37.2 31.4
6.57 7.08
29.7
9.69
31.1 10.00 31.4 14.41
27.4
9.88
88
88
88 84
86 83
`8
8
64
88 88 88
64 84 84
c*.
a
84 88 88 5 5 .75
63 8 4 86 4 75 4 , 75
82 86 88
42 63 66
88
86
5 NR 88
5 NR 86
2 No 15 Yes 250 Yes 250 Yes 110 Yes 150 Yes 40 Yes 125 Yes 125 Yes 10 Yes 625 Yes 625 Yea 250 Yes 150 Yea 20 Yes 150 Yes 1250 Yea 75 Yea
jAKi
>jUloc. 7
j------------------------------------------------------------------
) I
03HA STANDARD
TWA-PEL
() ACGIH
SAMPLING RATE
TLV
r;<?RTr.TN(
(PPM)
alcroftran (oc/mln) ppm-hr
HECQMKENDED SAMPLING PERIOD
.(Hrs)
RH <.70*
1-.5 .5-3 PEL PEL-.
RH??0>
1- * 9.5-3 PEL PEL
short TEAM iXPOSUn- LIMIT
(15 min)
stel
(PPM)
OVM
i i
Vinyl Acetate Vinyl 3roald# Vinyl Chloride* vinylldene Chloride ^ vinyl Toluene ^ Xylene*
(10) (5)
1 (5)
(10) 100
100
35.9
7-56
41.0 10.77
40.9
6.22
38.6 26.8
9.19 7.75
27.3
7.09
88 22 22 22 88 88
64 22 2 1.5 22 64 64
20 Xes --
20 Yes 150 Yes 150 Yes
3M 005341
