Document 0qgo1wLXwDMgD4orM44gYExVb

CHEMICAL Era MLB KFL TIL > HYGIENE, TOXICOLOGY, FIRE, EXPLOSION AND DISASTER HAZARD STUDY ON ORGANIC AREA CHEMICALS M3 OO *e cj i4 O +J o >U h 4J in < w 0 If W O *W M < G! a m Z -P i WC e U, in css n Ch H fci z o -Ou_ -'O^Oz o3 S'1 0! XI .Q *v 3 ~t W 3 sera ABSORPTION EIE SWALLOWING (Ingestion) BREATHING (inliallation) FIRE, EXP LOG TON,DISASTER HAZARD AND DANGEROUS REACTIONS Remove contaminated Flush with water for clothing. Hash vith at least 15 minutes. voter, then, soap and voter. , CoII a specialist. Report to First Aid. Report to First Aid. Remove contaminated clothing. Hash vith water. Flush with copious amounts of water. Report to First Aid. Report to First Aid. Remove contaminated clothing. Hash with voter, then, soap and water. Flush with copious quantities of water. Report to First Aid. Report to First Aid. Induce vomiting by stick ing finger down throat or by giving soapy or strong salty water to drink. Re peat until vomit Is clear. Report to First Aid. nduce vomiting. Report to First Aid. Report to First Aid. Remove patient to fresh air If not breathing, give artificial respiration, preferably mouth-to-mouth Flammable. Explosive limit and flash point unknown. g(fi.vberconxlyhgineqn,is difficult, dtepovt to First Aid, threshold limit is 20 ppm. Penetrating, ammonla- cal odor. FJ nrxinble. Do not expose to open flame. Volatile. Report to First Aid. Flash posit is 72F. May form explosive vapor-oir mixtures. Threshold limit is 200 ppm. Flash point is 87F. FhrmvpnH.', Alcohol-like odor. No liangdrous fire, < ' ' 1 ' [ -r- cumulative effect. ter hazard!) when exposed to heat or Remove patient from flame; can react vigorously with contaminated area. oxidising materials!. Lower explosive Give artificial res limit is 2.6% and upper explosive piration. Give oxygen limit la 15-yf> in air. To fight if necessary. fire: carbon dioxide, dry chemical or carbon tetrachloride. NPL con Report to First Aid. form explosive varior-nir mixtures. Remove contaminated clothing, finish off chemical Immediately. Hash with waler, then soap and water. Flush continuously with water for IS minutes; then use soap and water Not severe enough to cause death. Not severe enough to Moderately dangerous disaster hazard. cause death. Remove When heated it emits toxic fumes. patient from contami nated area. Give arti Avoid oxidizing agents. ficial respiration. Give oxygen, if neces sary. Report to First Aid, Report to First Aid. Report to First Aid. Report to First Aid. SL 020786 &tn -I ' % SL 020787 CHEMICAL n % O. **i ye ><j Vr1f^ *t-o. tf-i -* *s*o d> yj t-1 7*. ^c S-O f' t qTS O 01 X . HYGIENE, TOXICOLOGY, FIRE, EXPLOSION AND DISASTER HAZARD STUDY ON ORGANIC AREA CHEMICALS --------- H----------------------------SfftH ABSORPTION EYE swALLO'.mia (ingestion) , BREATlttNa t (Inhallatlon) FIRE, EXPLOSION,DISASTER HAZARD AND DANGEROUS REACTIONS Copper Chloride Remove contaminated clothins. Hash with water. Report to First Aid. Potasalum chloride Remove contaminated clothing. Wash with water. Report to Flret Aid. GDI, Remove contaminated clothing. .Hash with water. Report to First Aid. ADY Remove contaminated clothing. Rash with water, then, with soap and water. EMH 1 Report to First Aid. Renfcve contaminated clothing. Rash with water or alcohol. Flush with copious quantities of water. Report to First Aid, Flush with copious quantities of water. Report to First Aid. Flush with copious quantities of water. Report to First Aid. Report to First Aid, Slightly toxic. Induce vomiting. Report to First Aid. Report to First Aid. Flush with water for at least IS minutes. Emetic is indicated. Give patient salt water or soapy water and induce vomiting. Report to First Aid. Call a Specialist. Flush with copious quantities of water. Report to First Aid. * 1 01 ,,* A 1 4 n ..... . 1 rs ti*f 1 All Report to FirGt Aid, Chlorides in general are a dangerous disaster hazard. When heated to de composition or on contact with acids they evolve highly toxic chloride fumes. 1 Report to First Aid* Chlorides In general ore a dangerous disaster hazard. When heated to de composition or on contact with acids they evolve highly toxic chloride fumes. Threshold limit 50 ppm Fla/onable and very reactive. Not unusual odor. Remove patient from 1. . (1.. it , <. *' ' / ' ' 1, contaminated area. Give artificial res u : 1 , > 1 ` ' piration if necessary. Report to First Aid. Threshold limit 200 Dangerous fire hazard when exposed ppm. Penetrating to heat or flame; can react vigor fruity odor. Remove ously with oxidizing materials. patient from contami Severe explosive hazard when exposed nated area. Give to flor.e. ADY has a low boiling artificial respiration point, Is very volatile, and has a Give oxygen treatment very low flash point. To fight fire; if necessary. carbon dioxide, dry chemical or Report to First Aid. carbon tetrachloride. Threshold limit 0,5 Dangerous fire hazard when exposed to ppm. Fishy or amine- heat 01 fbv.e. highly dangerous dis like o.lor. R-.-i ovc pa aster ,,vl, wk'-n heated to do*.c"po tient from contami sit ion, it emits highly toxic furs a nated area. Give arti of nitrogen cc.-.pour.ds ~'\n react, ficial respiration. vigorously with oxidi- kunderlulu . Give o::ygen fventincnt To rl dil. Tire: foam, Finn dioxile, .................... t...... ... r .! 1.......... . -1 r 1 d.l < HYGIENE, TOXICOLOGY, FIRE, EXPLOSION AND DISASTER HAZARD STUDY ON ORGANIC AREA CHEMICALS CHEMICAL SKIN ABSORPTION / BLM Remove contaminated ` * ' clothing. Wash with' toap and water. DPE A 'W MC . rt v_i- Xf 0 n ft : C -O Zo ;j0p.(o+Oa""j vo o n H cs fcj-J !- 0f-t- tg*Jj t-* O 0 HI 1-hC H " v/t ft i-- tr* < * H- fO .0 .. . r*- O t-t o Or o ro c^ .H > - , - .** Report to First Aid. v Remove contaminated clothing. Wosh with water*. Slightly soluble In water. EYE Flush with water for at least 15 minutes . 0 v - Report to First Aid. Flush with copious quantities of water for at least 15 min. Use 2 or 3 drops of 0,5% Pontocaino solution or a topical anesthetic. No oils or ally ointments should be. instilled. I Cal la specialist. SWALLOWING f Inncstionl Induce vomiting by tickling back of tongue or giving an emetic such as salt water. * ,. BREATHING (Infra Hatton) Threshold limit 400 ppm . Sweetish, disagreeable odor. Caution: Highly toxic concentration of vapor are obtained ah room temperature. Remove patient From confaminaled area. Keep warm. Give artificial respiration, if necessary. FIRE, EXPLOSION, DISASTER HAZARDS AND DANGEROUS REACTIONS Flash point less than 0F. Burns violently Extremely flammable. BLM is capable of polymerizing exothermically and reacting vigorously with compounds having a labile hydrogen, including water, alcohols, polyols, phenols, thiols, ammonia, amines and acids. Forms explosive vapor-air mixtures. Burns violently. To fight Fire: carbon dioxide, dry chemical or carbon tetrachloride. Report to First Aid. Report to First Aid, If patient is conscious. encourage the drinking of large quantities of water followed bydilutc vinegar, lemon juice, cider pr other weak acid juices, such as orange or lime. Administer a demulcent such as raw egg, milk or cream, barley water or olive oil, if the patient does not vomit sponlaneously, stimulate vomiting by having him tickle the back of the throat. Keep patient *"<rm and quiet, Admtnis jxygen or artificial resnirntinn if Threshold limit 10 ppm. Ammonia like odor. Remove patient from contaminated area. Give artificial respiration. if necessary. Give oxygen. Keep patient warm but not hot. Dangerous fire and dla'.lei ha~tnd when exposed to heat or flame; can react vigorously with oxidizing materials. DPE should not be allowed to come in contact with metallic mercury as a violent explosion moy occur. To fight fire: foam, carbon dioxide, dry chemical or carbon tetrachloride. 4 to c< o to- ' o. -j 4 HYGIENE, TOXICOLOGY, FIRE, EXPLOSION AND DISASTER HAZARD STUDY ON ORGANIC AREA CHEMICALS CHEMICAL Stent ABSORPTION EIE SWALLOWING (ingestIon) BREATHING (inhallation) FIRE, EXPLOSION-,DISASTER H '.ARD AND DANGEROUS REACTION l/ Dcrvtherm A Remove contaminated Soluble in alcohol, ethe clothing. Wash with end benzene. alcohol. Insoluble In water. wi m +> tr rttj. o Cl ft eQ Bfttf 2 c eX _______1--2____*2.______ Report to First Aid. Report to First Aid. Report to First Aid. Geraniinn-like odor. Highly flam.able because tesq Remove patient from con use are above the flash poll taminnted area. Give therm A can react with oxidi artificial respiration, terials. To fight firej < if necessary. Control dioxide, dry chemical or coi vapor concentration to tetrachloride. 1 ppm to avoid com plaints and possible nausea. Odor Is irri tating to intolerable below safe toxic limit. Because of low vapor pressure and low order of toxicity, this does not present a hygiene hazard and there is no need further discussion iturrs of Dov- ig ma-bon i Report to First Aid. LPDrEoNtTe.:.cMt iv. :e O rd e r ia l D is tric t C ourt i9 1 - 1 1 4 5 - / Remove contaminated Flilsh eyes with copious Induce vomiting by Tlireshold limit 5 .ppm. t todcrate fire hazard when ex 'ed to clothing. Wash with quantities of water. mechanical incltntion Chloroform like odor. heat or flame. Dangerous dl ster soap and water. Any to promote gagging* Remove patient from hazard. When heated to dccc leition blistering from pro EracticB are not always contaminated area and It emits highly toxic fu-res phos- longed contact should reliable, Give uni keep quiet. Give oxyget gene; can react vlth oxidizi IM- be treated as a burn. versal antidote of 2 if necessary. Cumulativr tcrialo. To fight fire: vet , fozrr, parts activiated char effect from repeated carbon dioxide, dry chemical r carbon coal, 1 part magnesium doaee. tetrachloride. EPN and Its dci i fives oxide and 1 part tannic which contain the epoxide gioup e generol )----------------- Report to First Aid. Report t First Aid. acid. Oral adminis unstable in the presence of ocidi M basic tration of oil after substances. EPN, aiycidol, am) I /c'doi poiconing appears un- ethers have been observed to rom V inoiou sl ad1visable. to explosively with strong sulfuric acid end Re-* to First Aid. Report to First Aid. anhydrous metal hai idcferric chlorides, even s slowly added to the epoxide at room temperatures; giycidol was ais l<ucb os stannic an kthese reagents -iTund to eact alnir explosively with itrong aqueous caustic soda under these conditions. %% koH , i CO ^ n o to o * 1 W- * . as 10 o 'i->1 Z^*0> cwA.* * . w* rwt \L ^v-*i *-* * Vr '& *. iji1 tfl ' **a H*** *(25 ao o* HYGIENE, TOXICOLOGY, FIRE, EXPLOSION AND DISASTER HAZARD STUDY od ORGANIC AREA CHEMICALS CHEMICAL --r-....... - SCUT ABSORPTION ETC 6WAIL0WIH0 (ingestion) breathing (inhollation) FIRE, EXPLOSION,DISASTER HAZARD AND DANGEROUS REACTIONS ADH ` Chloroglycerine Sodium Methylate Caustic & Cell Liquor Remove contaminated clothing. Remove patient from contaminated area. Give artificial re spiration. Give oxygen, if necessary. Flammable i t 1 . Report to First Aid. Report to First Aid. Report to First Aid. Report to First Aid. 1 Remove contaminated clothing. Remove patient from contaminated area. Give artificial re spiration. Give oxygen, if necessary. Flammable Report to First Aid. Report to First Aid. Report to First Aid. Report to First Aid. Remove contaminated clothing. Remove patient from contaminated area. Give artificial re spiration. Give oxygen, if necessary. Flammable Report to First Aid. Report to First Aid. Report to First Aid. Report to First Aid. Wash with water 1 to Flush with water for at 2 hourB. Remove con least 15 minutes. Use taminated clothing. O.556 pantocaine solu Use 5$ ammonium chlo tion or aqueous topical ride solution available ir anesthetic. plastic bottles at each shower In caustic area. t1 Give dilute vinegar or Threshold limit 2 mill Will not aupport combustion an ' will a 556 solution of ammo igrams per cubic meter not burn. KaOH will react wit: water nium chloride, If avail of air. Remove patient or steam to produce heat and will able. If not available, from contaminated area. attack organic tissue. encourage patient to Give artificial re drink large quantities spiration, if necessary or water without delay. Bid) administer whites of eggs or mineral oil. Report to First Aid. Report to First Aid. Call a Specialist. Report to F1rat Aid. Report to First Aid.