Document 0JJzBvpBMZw9aoKno61qkj6yM

* PPrroodduucctt TTooxxiicciittyy SSuummmmaarryy SShheeeet Form 15594 - G - PWO pPaaggee 11 ooff 55 SM Product Name [Issue Date Sores im FLUORAD Brand Fluorochemical Surfactant F0-951 June 5~ 1992 ty in to teh ett Ces estes8 on arr Below is a summary of the study data giving an indication of the relative toxicity of the product. (Definitions of test procedures are found on the reverse side of this sheet.) This summary is the data for the precautionary use information provided with the product. fret at fp AN ac roSAA ic Relative toxicity of a material is only one factor that is important in determining the degree of hazard in handling a chemical or product Other considerations to include are physical properties of the chemical, extent and frequency of use or exposu re, intended use, and possible misuse of the product. For additional 1223410 Suporacdes October 2, 1991 information regarding safe handling of the product, please reference the Material or Product Safety Data Sheet. 12234-I0 Supersedes October 2, 1991 AAuCpCoUUnTT~E aOOcRRuAAtLLe TToOOrIXaIIlCCIITTaYYd::miniMMsOOtDDrEEaRRtAiAToT~nE!.L~YY TTIOOnXXIICCt..he FPsCCt--u99d35y wwFaaCss-95ffoouuwnnadds ttaoodebbieenimmsootddeeerrrsaadtteeillnyy attooxs2ii0sc% uLaaepccvooeenttloo.nnasec//uE8Ft00oe%%uroccrdooaorrlsnne aooldiiemllvienssliuusssstppvreeeannrtsseiiiooonunn.sedtt:ooIn1i0100t0hrr,eaatt2ses1t5u,((dffyii4vv6ee4F,Cmm-aa9all5need w1aaan0nsdd00affdmiimavvi/eenkigffseotommefaarllebeedo))dyippneewrreaigddhoo2tss0.%ee AAalttcetvei3ilv00.i00t00y,Faaonnudddrec44rd66eo44assee5mdlg/e/kvLkgeigmlbsaALltw)loenraaeenniiaummsnaaedlldss:ateddxiiiiee0add0..., 2A1TTt5hh,ee241ss6ii4,ggmnngss/akngdbbeeff3Ioo/01r0r00ee mdddgeee/aaatktthghhsoiifwnnoccrblleouudddyreeeddpwoerihhtgyyehppdto..oAAaCttcotrin13ve00ia00tly,%moggp//dakkecggcirtennyaoosaeddndeedaalttiihhmssgbhwwteeoSrrnaeeercaooinbbadssgeeerra.vvteaexddi..Tahoe AAcdAdodtdmiibtt2iii1noo5enndaamllg/mkappglhheaa3rr/mma1asn0ccdoodttfeooeaxnmtiiahcclsesswiierggrannetssereiiLpnnDoccSrllOtuuedddeei.dds c22S59co11urtnemmegag/l/okrkaggolp(a(b59ca55is%%tiysCC...aI1n..dt: h11i99g99h~-3311c88arrmnigga//gkxegg.)).. TFFhCOe--99c55omiibssincceoodnnssmiiaddleeerreeddandmmooddfeeerrmaaattleeellyyratttoosxxiiccLD5oo0nn aainns atcruateceosraRl beassinsd.Daecshc Cor:Noy17: 152038) (IntemationalResearchandD~elopmentCo~.; ~ay19~;137~38) AArCCeUUcTTeEEiveDDdEERRaMMAAdLLosTTeOOXXoIIfCCIIFTTCYY-::95 ePPqRRuAAiCCvTTaIIlCCeAAnLLtLLYYtoNNOOSNN0~T0OO0IXIImCCg../kg.TTaennThmmeaallteeestaannddmattteaernniaffleemmwaaallsee dorrsaaebbdbbiittasss wrareuacsspeuppiseevpnedednsswiiiaootnnhdosiiaennn vwoiaafmttpeeFersCr-v9aai5nnodduesqaaupppipplvllaaiisleeteddinctttoosthAo4e00e%%5t0i0Oon0ffg tmtghfh/aoekrgtt.ooattaapllTohrhebioooddtdyyesotaafrreem2asa4..tehroiTTuahhrlees wrraaaafsbbtbbeiidrttossswehwdwieecrrahese wVhtreiilnmaaeeppettfdhhoeerwS3is0hhteehsdeattayiinann.ggimwwpaaHessyrpvrreieeronmuaooscvvieevpddliataasynntddiwcattshhesehneoFPetCCte--id90n55ginwwaafsso5hrheeoddfa oo1pff0effrmiattolhhdeeesossfkokini2nn4..dahyoTTuhGhr.ees aaaAnnfLiitLmmeaarllassniwmwhwaeielrrcseeh @)| Grrhaeeeiclcndoosvveefrrwoeereddre28bbyyOdbaGdsyuaesyyr.ve77dHaaynnfpddoerrrraeeacmmitaaiiiivnnrieeatddbybiaawtssasyys.mmppnttoootNmmeoaadttviiiiccnsitt5bhhlrroeoofuugg1ihh00oo8uu1mt0ta0l8ttehhsweeeorssnettuudddnayyoytepp6dee.rriiAootAddl..lecraWWnoeeipiimeggayhhl.Cts TTnghhoaeienntsoaaxcciwuuoettreedeerddomeebarrslamelsaryllv.edDLDS5fO0or (arlalbbirta)bbiitss. (rabbit) is greNaotevrisitbhlaen greater than 9/kg. lesions 5 g/kg. F-95 ia practically were noted at necropsy. FC-95 is practically nionrtoSxeiycrdaetrimoanlLlayv.oro; oc. Mah 1, 5: 07RARORS) (~ker~luation ~bomto~,lnc.; ~arch13,198]; ~70AB~32) E~tYYhE~e eIIyRReRRsIITToAAfTTIIOOaNNl::binoMWIIrLLaDDbLLbYYitsIIRRhRRIIeTTnAATTIItNNeGGs.,ted PFaCCc--c99o55rdwwieanssg tffooouunnsddtanttdooarbBdee FmmHiiSllAddllgyyuiiidrrerrliiittnaeastt.iinngg Thtteoo otoTchcrueurlliaateraryetsiiiorrnorrfiiuttaaaalsttbiiioonnnnooterwvdaaabssabtitllsiitmmhwiiehtteee1ndd, tt2feo4osteattdnhhdeeac4cCc5ooornndhjjiouununngrcctttiipovvoaasscett-ainiindnntairttldhhleoaFtHiSssAoiinxxgurittedeeaessdlttiinngeaasnn.iiimmnaaellTsssh...e TTrIhhereaerdiimmtnaaagxtx.iiiommnuummBywiia7rrs3rriinhttooaatutteriidaoonnpatossscctoot-rrhieeenswwitaa,sisll929s4..c33iao((nnhhdiiagg4lhh8leessttrheoauppdrooissnsspgiiosbbslltwee-eirssneccsootzrrieeelrlo1ia.1it00i..o00n)) at the reading at the 22t44imhheoosuu.rr reHaARdEinng.iBnyc7N2ovheomubresr 1p97o,stW-AiREnNstoi4l1l3a0t1i)on all readings were zero. ('WARFInstitute, lnc.; Novcmber7,19~; WARFNo. 410~71) PtPhRReIIMAAsRRkYYinSSKKoIIfNN aIIlKRbRRiIInTToAATTrIIaOObNNb::itsN~OOwNNhIIeRRnRRIItZTeAAsTTtIIeNNdGO..undeFFCrC--99c55onwwvaaessntiffooonuuannldd tDtooraibbseee nmpoornnoiicrrerrdiiuttraaettsii.nngg Nttooo dtssuhiiregginunsesgkioonffthdodefeerrsmmataalullbdiyniiorrprreiirrttaiaabottbdiii.ootnns wwwTheeherrenee potorbebisssmteeaerrrdvvyeeddunsdiikennirnaacnnioyyrnrvooiefftnattttihhioeeonnaltteesssDcttroaraaiennziiewmmaaapslirssoc0.eaa0dtt.uraa(ennhsyyi.gthtieimsmNteeo PpdCoouAssrRssiEiinbgnnliieetehsseccooocrrs.eetNud88oy..00)ep).esri7,o%d,.WARETNhoe.42p5r7i)mary skin irritation score was 0.0 (highest (WARFInstitute, lnc.; Novcmber7,19~; WARFNo. 410~71) AApCacUfrToeErneDINdAHAToLInATOISNOpN:r:agus-AADavssieeerryiieessratoosff. oonnTeeh--ehhoouunrromiiinnnehhlaallaaettxiipooonnsureeexxppcooossnuucrreeensstrtatootioFFnCCs~-99525 .0wwaa,ss pp77.er.00ro55fd,,ourcme66ed.d4499a,,ton44t..hS08ep88,r,ango22us.0ei68-n66Da,~alwl11e.e.8x8y99porsaaaunntrddse.00..c00onTcmmheiienlltllnriioaggmtrriiaanommanssl ppoefeerrxp2oll4sii.utt0ree9err.. mciolnTTlocoitetgaanrlltarsammstooirropttneaasrlliitt2lyy4i.t0eww9raa,.ss @ pPrParaerorottdiiuaac(lle5d0mm)oo,arrttt4aa.tll6hii8ettyy(n2wwo0aam0ssi)nappalrrnoodsdeuix2cc.pee8odd6suaar(t:e101nnc)ooommnimicnnieaadnllitirgeearxxtappimooosssnuuprreoeerf ccloo2inn4tcc.ee0er9nn.ttrrmaaittliilooinngssraoomffs 77p..e00r55 l((i8Bt00e%Vr)),., 6.49 (80%), 4.88 (20%) and 2.86 (10%) milligrams per liter. TeLtEon to oe ores rL n lee otLateaae oe re Tondo See This information is intended to be used by a person qualified to evaluate toxicological data. Inquiries are to be referred to Toxicology Services, Medical Oepartment!3M, Building 220-2E, 3M Center, St. Paul, M N 55144-1000, (612) 733-2882. The above information is based upon studies conducted by 3M and/or by recognized profosslonal testing laboratories. It is believed to be correct, and it is supplied to others upon the condition that the person receiving it shall make theil own determieation of its suitabilily fol Iheir purposes. 11337744..00000011 1374 State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 on) 3M MN02252650 sm Tost Descriptions Test Descriptions EO ----_--_-- Below are described the toxicity studies commonly used in testing 3M products. The tests are normally oo Ean ner Bote conducted according to standard OECD (Organization for Economic Cooperation and Development) or Be aa ov eam oF re eroens FHSA (USA Federal Hazardous Substances Act) test guidelines or modifications of these protocols. LD thdos thal 150% of the exposed animal, Dosages expressed grams, milgrams LDs0 -the dose lethal to 50% of the exposed animals. Dosage is expressed in grams, milligrams a oan amt oy wg or milliliters per kilogram of animal body weight. Lu tho ihoconcenvaton th1 50a8 oflthe xpased animals. Dosages exoresoed in -the airborne concentration lethal to 50% of the exposed animals. Dosage is expressed in on emissions omen parts per million (ppm) by volume or milligrams per liter (mg/I) of chamber concentration Er par for a stated period of time. 1. Acute ra. eer 0. tot of ange dose of aproct a seciied eight or volume pr iogram 1. Acute Ora~ - refers to a test of a single dose of a product; a specified weight or volume per kilogram no cea os chm Thr ay cosa of body weight is administered orally to albino rabbits. There is a 14-day observation period laos oye, following dosing. The product is classified for oral toxicity according to the system of Hedge eo Fe eseins and Sterner (classified on basis of oral LDs0 in mg/kg): Extremely toxic: 1 mg or less; Highly tons S050 500 ma Shanyis 08 tows Poy toxic: 1 to 50 mg; Moderately toxic: 50 to 500 rag; Slightly toxic: 500 mg to 5 gms; Practically oe Bh ata rosters STS non-toxic: 5 to 15 gms; Relatively harmless: >15 gins. BS rec aa 2. Acute Derma~ - refers to a test of a single dose of a product; a specified weight or volume per kilogram amos oom oso son of body weight is administered by continuous contact for 24 hours with the bare skin of albino La Li ls sins rabbits. There is a 14-day post-administration observation period. A descriptive rating of the EB paola vo ont dermal toxicological properties (i.e., American National Standards Institute, USA Federal Eros EomCommit oy Hazardous Substances Act, Hedge-Sterner or European Economic Community toxicity as anos aston classification) is assigned to the product. 5 ActInhalation. tefrs o atest of asing continuous inhalation exposure of speci concentration 3. Acute ~nha~ation - refers to a test of a single continuous inhalation exposure of a specific concentration rs vos poe tie a oe eo of a product for a given period of time. A descriptive rating of the inhalation toxicological pprrooppeerrttiieess ((ii..ee..,, AAmmeerriiccaann NNaattiioonnaall SSttaannddaarrddss IInnssttiittuuttee,, UUSSAA FFeeddeerraall HHaazzaarrddoouuss SSuubbssttaanncceess AAcctt,, He A en ess sens Hodge-Sterner or European Economic Community toxicity classification) is assigned to the Hodges product. 4. Pimary Sin noon. eters toa ot of singe dermal aplicationof gramor Smilifrofa 4. Prin~ary Skin ~rritation o refers to a test of single dermal application of 0.5 gram or 0.5 milliliter of a Te Ei nr Eon soda crop an product to albino rabbits. Either the OECD or the FHSA test guideline is employed. In the Lr i OECD test method the sample is applied to intact skin test sites of three or more animals, isos ae aso re Tor oil semiooccluded, and held in contact for 4 hours. Observations are made at 4, 24, 48 and 72 or and sts sp ho myn hours post-application. In the FHSA test method the sample is applied to both intact and on Sooo nd oe cone ot4 ws. ona abraded skin test sites of six animals, occluded, and held in contact for24 hours. Observaeee orasana mos tn oars tions are made at 24 and 72 hours. Scoring for dermal irritation in both test methods is tre i according to the procedure of Draize. no of tho tllowing cescrptivoratingis ssignod to Woproduct: noniating, minimally One of the following descriptive ratings is assigned to the product: non-irritating, minimally me ten ial Arto Wg Severe ego irritating, slightly irritating, mildly irritating, moderately irritating, severely irritating or ici bl dy extremely irritating. 5. Epo ton. rors to104 ofa ingle application of 0 ram 1 mila of a product nfo tho Bye irritation - refers to a test of a single application of 0.1 gram or 0.1 milliliter of a product into the em Tats conjunctival sac of the eye of the test animals (usually albino rabbits). Either the OECD or aE OE or FHSA test guideline is employed. In the OECD test method three animals are normally used EA mate ere os with the eyes observed at 1,24, 48 and 72 hours. In the FHSA procedure six animals are used eto Concutroon with observations at 24 and 72 hours post-application. Additional observations or evaluation re mesesios times may be added. Scoring for eye irritation in both protocols is according to the procedure men of Draize. Oneof tn following deserptiverating is aeignd to Woprocust: nonitating, praca One of the following descriptive ratings is assigned to the product: non-irritating, practically i acolo st. aoe rand non-irritating, minimally irritating, mildly irritating, moderately irritating, severely irritating or rr -- extremely irritating. Othrtosts nloing dormat sonia suo un ig), human patch toss, Invi Other tests including dermal sensitization studies (guinea pigs), human patch tests, in vitro my So es tho mutagenicity tests and sub-acute or chronic toxicity tests may be conducted and summarized on the oe sa ea Product Toxicity Summary Sheet. 7 11337744..00000022 swmozzszsst 3M MN02252651  PPrroodduucctt TTooxxiicciittyy SSuummmmaarryy SShheeeett Fo~m 15594 - G - PWO 2Psaggee 22 ooff 5s aM Product Narqe TT EE se omarse t FFLLUUOORRA~D BBrraanndd FFlluuoorroocchheemmiccaall SSuurrffaaccttaanntt FFCC--9955 June 5, 1992 Below is a summary of the study data giving ar~ indication of the relative toxicity of the product. (Definitions of test procedures are found on the reverse side of this sheet.) This summary is the data for the precautionary use information provided with the product, i se Shr apes ofBcc omwe nc hs ep. FShSed is SHAS 5 oho or ens Relative toxicity of a material is only 3no factor that is important in determining the degree of hazard in handling a chemical or product. Other considerations to include are physical properties of 1he chemical, extent and frequency of use or exposure, intended use, and possible misuse of the product. For additional information regarding safe handling of the product, please reference the Material or Product Safety Data Sheet. serio 12234=10 supersedes cctoser 2, 1991 pPPSPlFueaearerrrcaee,iriddiioooomGmdammassiiartnntiaaiioatwtoneeecen,rheppshhmmyyuussilccmiiaaoaoccnbcsiaoaoeadrllrceeinaddaaanstbbdnnbbooorrrerrneeomsmdadaatttllhhhiimnieittaanniisagfgeaeka,,lsshcicaoGdfrlhbiieasevsdseecstuerhhecuvvaeaenecersd.odgdees,ddasauurecrirynJtiieiionncglvrggiliomvtoeatetywchr,haeesssteoeerSaaxxxuiomppacpnmooeeeinssasrnsuussgirreieneedvoeeefsaaennmtddOsShrcaeeltlppioiooTvbvsasaeatnttrto--iiei-eeoog2xxr,nneppnooeiss1ent9usana9rsnta1lede LLr Effiuurrrnnee,ggquuedaendiinsrsta.iccen oodaarlbboornmrreooaadrttrmiiamaooamlnntSewvrnnoaaieerssacolrraSoolkpposesenoayr mSseebresvveadtiionnas:Mwieamne soohnbahnenSst the facial area, and general observations were of lung observed in a high number of heouartiSnonaairteionm.oslTehreetmioosnt, poor condition. The most and liver discoloration. control rats and thus may eeTTSnxxhhoOpeeptoossobnnuuemoorrimmeetdiirnneettaaaoonllttllm6FsyyeC-n-5tT9dd-i55eerntteiwaeeltarrassmmtiieodenndfeeeostdde4er.r3mmmmiieeBnnddireeiiisdaoinnottoeo.olleempbttseehhaap55llo.r22 ccMmmooiiinnvrlccatleeniinngottarrrraeaammsttseiiooennppeerro((L1lSC0io5m3t0a0e))rraiwffiiootrrnnh Saaa.peTpprooeEonnmExeeai=-Rimhhoaooutuuserr prices To 95% confidence limits of 4.4 milligrams per liter and 6.4 milligrams per liter. T9a5a(Bonn00irda-o-eD/d0A33~YY0n0am 00i00FiP~tEE,IEEpLpnDDacop.rIInm; eNNDsGGt+eco6eaeSmt~mCcbJDhheeDraar3vyrr1:~e,li1nee9~ss;dFFoPCRR-sr-i~ie09evvp5c5eeetNrrowwL.aa~cCo-ssDhv71e~rfrcf5eeea)cddteesn.diinnfFoorthrh'oeS33 haddmoioianeneitttmhhseaaa.sttnlleePFTvveieevehllesssemmoaoofftlee 3300oa,,nnda1100500,,fpeem3300al00l;~,e r11Ia000t000s000 @ IAtSwcteeeorrcrmeaucdiiioonmiansaaniaittisgoiitsenooisnna,leteevoovdeff"eiala1nststtuhhteaooe.eaffdchsv33te"00duaF00oddo,,seyyta..igI1re00e00,0l0OOevvv"aeeveeennrlrsda.st and in the 3m3"0s0bs0i9aig00aennisdppaaplmmoo,,ef control group. (aatsolioltixxmiirrcamaitttoeseyho"dwmiiianmenecedsltuDrpdpeerreldiie:oorrmtootS,soosemctasshccceihhdaeeetuddiiuulollenened,ds rmneSrcaaeoiietvdnneeuvrnrrcueeiileisaasdstilnomsnToos(a(et,uavaiononasreeocp-oag:gslSaoetecnneLttiriioitevvaadiihllttsyyprrodmweesooeggtsvriiuaeoeorg.nene.),)se,,vSiierdvd"eieeIdnnsenctcrrwmeeisaaepsetsreneeidtrdo.iwrhaelssteeosnmose(miimreittoioigisinhctvmtaiitttdJyyeeeeasymttestihaoosgn..aemnedxso/toeTpemrrrinnmanaenlmlosoufEtL senhti)cid,mmeuatlt"L yihela1wlar0aonsa8dw directly related to the dosage level with the earliest deaths seen in the 3000 ppm AAEFrtteoerLlxeaaatttttthhheemeeeadent33Tcc00ahhtaagannrppgogpoueeammptss.ddtiSoohnnssaaasagg3ppee0ppoepsallpsreemaavvnneedllcce,,eesaoonnsrreeeiibbttTeehhenheevaarrevvsiioommwrnaah.slleeer Mmnneeeoomawrrpnniffrbbeoeoomzdsdasyyllveeaowrerirrsggaantthissteswsswrehheoorewwreeeddes1sltaainngoyyhntlcceyoommpplcoooeuuwnenordd AACcSftCaooonmrreppttsaathhrrheoeee(dda1IrC00etati00toossktpphiahpoatemonutcctddhoooosenssmytaa3regg0oeetslhpssopllnmeeffivvooFdeerriollcsmmaasaanigttlteseyes33lesvaahmmenneooldtnnnttwhffhhcsooe,rr,onnftfbbceoeooommnddmahtyyploaenrswwese.esedilgstthFSohhtpoeoootdmmnheeeeoaacemnnoemssonomsnamutwwnmreeEmporrtleeiisioooonllnoeiwvmTeeeTrreaeenarddsm ba wwweehhvereonrenme lower (statistically significant) when compared to the controls for males and CtCifEoooneommmvvappoeslooliaeuuvvcsnniie.nddnig--gtrxieaotthllnheaa.e.tteessddttosomingianerciooshiusossraannddccchhhalLaaniinnsvsggeeeeersrss wvweeessrrruueeecchhos`bbasviaaoeossercvveepeedntmseasawrccmaiieoaanenttgdgiiootnnmL,r,reesasitaaniecrendeeasSrussaotsnsooefftphoaaattddtiiissodccsiooieillsdooodrrrsaaptttrpriiiiioooocrnnne Secritloea to sacrifice. sacrificed at commimation of seats eon the Similar changes were also termination of study from the ena 300 por ern observed in the liver 30 and i00 ppm groups. of a few rats Er rr Ts This information is intended to be used by a persor~ qualified to evaluate toxicological data. Inquiries are to be referred to Toxico'logy Services, Et re es Medical Department/3M, Building 220.2E, 3M Center, St. Paul, MN 55144-1000, (612) 733-2882. q'he above information is based upon studies conducted BEby 3M and/or by recognized professional testing laboratories. It is believed to be correct, and it is supplied to others upon the condition that the person receiving it shall make their own determinalion of its mdlability for their purpeses. awwozzszese 3M MN02252652 11337744..00000033 Test Descriptions ; Below are described the toxicity studies commonly used i testin3Mg products. Th tstsaro normaly @) Below are described the toxicity studies commonly used in testing 3M products. The tests are normally `conducted according to standard OECD (Organization for Economic Cooperation and Developmen) or conducted according to standard OECD (Organization for Economic Cooperation and Development) or FHSA (USA Federal Hazardous Substances Act) test guidelines or modifications of thes protocols. FHSA (USA Federal Hazardous Substances Act) test guidelines or modifications of these protocols. LD. LDs0 --`ttohhreemiddloolssieetollerestthhpaalelrttok0i.5l05o%0g%raoomff tothfheeaneeixxmppaoolsseebddodaaynniwimmeaialglssh.t. .DDoossaaggee is is expressed expressed in in grams, grams, milligrams. milligrams or milliliters per kilogram of animal body weight. LG. LC~0 --ptthaheretaasiirprbebororrmnnieellcciooonnncc(ee5nnptrtmra)attbiioyonnvollelettuhhmaaell totoor 55m0i0l%%lioogffratthmhese epeexxrppooissteeerdd(aamngni/immlaalosfls.c. hDDaoomssbaaeggree oiisns ceeexxnppirrereassstseiedodniinn pfoarrtasspteartemdilplieornio(dppofm)tibmye.volume or milligrams per liter (mg/I) of chamber concentration for a stated period of time. 11. . AAccuuttee OOorrfaa~lboo drreyeffewerressigttohotaaittseeasstdtmooiffnaaissstiinonrggalleed ddorooassleelyoo0ff aa8pp1rbroionddouuccrat;;bbaaitssspp.eecTcihiffoiieredod 5ww.ee4iigg1hh4tt-dooraryvvooobllusumemreevappteeirroKkniilploaogrgriraoamdm faofoonflldlbolooSwdwtiiynongrwgeeddroiogs(shilitnnagsgis.a.iaTTfdhhimeeodippnorrionsotddebuuraccetitdssisoocrcfallaoallsysrssatiioffLiieaDed,ldb.iffinoonorr moorraraaakbllabtt)ioot:sxxi.iccETiixhtttyyerraaoeccmccaisoolryarddt1iion4nvg-gidoatt:ooy tto1hhbemesgsseyyrovssratteateimsomsn:oofpfHeHHirgooiohddldggyee ttnaoonoxxdmiiccoS::xtie11cr1nt:o0e5r5500(1c0mrlaag1gs;6;sMM igfoimeodsdde;reoaRrnatelatbealatlyyisvtitsoeolxxoiyifcch::oarr0a5m0lieLttoDsoss55:000>i00n1mrma5ggg;;g/kmSSgsll)i.i:gghhEttllxyytrtteoomxxiiecc:l:y 500mg toxic: 500 mg 1 (05mg to 5 gm; Practically or less; Highly gins; Practically non-toxic: 5 to 15 gms; Relatively harmless: >15 gms. 2. AAccuuttee DD`oeefrrbmmoaadl~y--wrreoeffieogrrsshotoisaaatdteemsistnt ioosfftaaersseiinndggblleye cddooonssteoioonffuoaauppsrroocddouunccttt;a; caa fssoppreec2ci4iffiiheeoddurwwsoeiwiggihththt ootrhrovvoobllaurumemeesppoekrrokkfiiilalo1ogbgnriranamom dorraaefbbrbbbmiotaidtsls.y.twTTohhxeoieigcrroeohltioissigsaiacaa11dl44m--pddirnaaoiyysptppeeororstestitd--saab.ddy6mm .,ciinoAninmissteittnrraauittoiicouoannsnoocbNbosasnetetirarovvcnaatattlifioooSnrnt2ppa4eenrhrdiioooauddr.r.tsAAwIddnisetehtssictctrhuriteippet,tbiivaUvereSeAarsatkFtiiiennndggeorooffafalttlhbheeino cdHHleaaarzszmasairarlddliootcouuatxssiicSoSrouu)lbbosisgsttiaaacsnnascclieepgssrnoAAepcdctet,{,rtoiHHetooshdde(ggi.peeer-.-o,SSdAtutecemtrmn.eeerrircooarrn European National European Economic Standards Economic Gommunity toxicity Institute, USA Federal Community toxicity classification) is assigned to the product. 3. 3. Acute Acute Iionnhhfaaallpaarttiiooodnnuc-rtreefffeeorrarss 0tgoiavatenteespstetrooiffoaad sosifinnigglmleeec.coonAtnditeinnsucuorouiuspstiiivnnehhaarlalaaltitiniogonnofeexxhppeoossiuunrrheealooafftiaaossnppteeoccxiififciicoclccooognincccaeelnnttrraattiioonn Hpoporfrodoapgppeeorr-ortSidettuseecs(mti.eeif.ro..,.roAAarmmgEeeiurvrrieicocnapanepnaeNNnraioatEdticioooonnnfaaotllim mSSitetcaa.nnACddoadamrerdmdssuscnrIIiinnpststiiytvtiteuuotxterea,i,tciUnUigSySAAoclfFFateeshsddeioefirrinacahlaatHHilaaaozntzia)oarnriddootaouusxsssiicSSgouunlbobesgdstitcataoannlccteehess AAcctt,, (@) product Hodge-Sterner product. or European Economic Community toxicity classification) is assigned to the 4. PPrriinm~aarryyprSSokkdiinunc~Itnrirtitotaaattilioobnnino orreerfafeebbrrsistttso,o aEaittehessottrootffhsseiinnOggElleeCDddeeorrrmmatahlloaaFpppIplSliicAcaatttiioooann goouffi00d.a5liggnrroaamims ooorrmp00l.55oym meidill.lilliIteerrthooeff a a OsOperEEomCCdiDDu-octtcteeltssouttdammelebdeti,tnhhaooonddrdattbhhhbeeolitssdsaa.immnEppciltloheonetiirsaotchaatpeppfpOlliiEeo4doCdhDlotoourorinrsnt.tthaaceOcttbFsssHkkeSiinrnAvotetasesttststisigotiateunersissdeoeofmlfiantthedhrreeiaoseoteoom4fr,2pmm4looo,ryrce4e8daa.annniIinm mdat7ahl2less,, ashhbeoorumuarrFdssoeppdcoocsssltukt--idaanepppdtple,ilsiactcnaastdtiiiloohennes..ldoIIfnninsttihhcxeeoanFFntHiHamSScatAAlsfott,eersso4tct ehm mloeeuutdtrhhosood. d,dOattbhnhseodessrhvaaammtpiepiollnneescliiosasnraateppdapmcpltlaiiedefddeorttaoo2t4bb4o,hoot2thuh4r,siin4.n8ttaaOaccbtntsdaaennr7dd2va ataticiobocrnnaossrddeaairrdeongsmmkatianoddteeteheasatttp22sr44iotecaaesnndddoufr77se22ixohhfooauuDnrrrsisam,i. azSSelcsc.o,ororiicnncggluffoodrreddde, rrammnadal imitation in both test held in contact for 24 irritation in both test methodiss hours. Observa- methods is according to the procedure of Draize. OOirnnrioetoaotfifnttgh,heoslffoioglllholtowwyiiningrgetddaeetsiscncrgri,ippmttiiivlvedolryraaittiriningtgasstiiinssga,assmssoiidggennreoaddtettoloyttihhreoitppartrooidndguu,cctst:e: vennoronenil-ryirirtiitaratrtiiitnnaggt,i,ngmmioinnriim maallllyy extremely iritating. irritating, slightly irritating, mildly irritating, moderately irritating, severely irritating or extremely irritating. 55.. EEyyoe I~irrt`iatcatotinioojnunn-ct-rerievffeaolrrsssttaooc. aoftteetsshtteooaffyaaossoiifnnggtlhleee aatpoppaptlliiaccnaaittmiiooannlsoof(f u00s..11uagglrryaaamlmbooirrn00o..11rammiblbillilitillsiit)teeErrtoohffeaar ptprrhooedduuOccEttCiiDnnttooortthhee. wFcFioHHtnSShjuAAtnht(eceotsscivttyagoglusuisioddabaeclsliioennrfeovtheiisesdoeeammiype1pl,looo2fyy4ete,hdd4e..3taIIennnsttdthhaee7n2OOimhEEoaCCulrDDss(.ttueeIsssntut tammhlaleeyttFhhaHoolbSddinAttohhprrrreoaoeebcabaenindtisium)mr.aeaEllsssiithxaaerraeerntinnhmooerarmm lOasEalaClllryyDeuuuosssreeeddd www{iiiittmthhhastoohbbmessaeeeyrryvvebaasottiioaoodbnndssssedaar.vtte22Sd44coaaartnni1ddn,g277422f,ohh4oo8ouuyrarossndrppioo7ts2sattt-h-laaooppunlprisilcin.cabtaIniotiototnhhn.e.pFAArdHoddStdioAtiticiooponnrlioaaslcl eooadbcbuscseroeerrrvdvsaiaitxntiigoaonnntossimtooahrrelseepvvaararloeluucaaeutdtsiiueoordnne toifmDersaimzea. y be added. Scoring for eye irritation in both protocols is according to the procedure of Draize. OOnonnnoerooifftttahhteoinffgoo,lllolmoiwwniiinnmggalddleeyssecirrriipaptltiiivvneogr,raamttiiinlngdgslsyiisstaaasstssiiinggngne,oddmottoodotthhreeaapprlrooyddurucicttt:a:tinnnoognn,i-rSiriertvitaeatrteiilnnyggr,,apptrraaiccnttiigccaallollyry xtreme iritaling. non-irritating, minimally irritating, mildly irritating, moderately irritating, severely irritating or extremely irritating. mutaOOgtethhneiercrittteeysstttssesiintnscllauunddidinnsgguddbeearrcmmuaatllesoseernnscsihtirtiiozznaaittciiootnnoxssittcuuiddtiiyeeesss((tggsuumiinnaeeyaabppioiggssc)),o, nhhduuummcaatnnedppaaatntccdhhsttueemssmttssa,,riiinnzvveiidttrrooon the PmruodtaugcetnTiocxitiycitetystSsuamnmdasruybS-aheceutt.e or chronic toxicity tests may be conducted and summarized on the Product Toxicity Summary Sheet. 11337744..00000044 33MM_MMNN0022225522665533 + PPrroodduucctt TTooxxiicciittyy SSuummmmaarryy SShheeeett ~~ PPeagsee 33 ooff 55 Form 15594 - G - PWO 3M . Product NamFeLUOMD Brand Fluorochemical Surfactant 76-5 FLUORAD Brand Fluorochemical Surfactant FC-95 dune 5, 1992 Issue Date June 5, 1992 Soof Pe ato ere roms Bln eoeeforbuvs Below is a summary of the study data giving an indication of the relative toxicity of the product. (Definitions of test procedures are found on the reverse side Em Ro el of this sheet.) This summary is the data for the precautionary use information provided with the product. nin otofa mtn nti at ge detwinhcgne atl rl chic, Ohconden Relative toxicity of a material is only one factor that is important in determining the degree of hazard in handling a chemical or product. Other considerations era aso ot to include are physical properties of the chemical, extent and frequency of use or exposure, intended use, and possible misuse of the product, For additional pC aE Ce TC, information regarding safe handling sf the product, please reference the Material or Product Safety Data Sheet. 1230-30 12234-10 Supersedes october 2, 1951 Supersedes October 2, 1991 MMMiioccrrrpoohssoccloooppgiiicccaaalllllyy,,chascnoogmmeppsoouunnddc--orcneeslliaasttteeiddng lleeOssfiioonnsscewwneertreerilooobblssaeerrrvveeddtoaammoomnniggdsoaanllelll tteeessytttogpgrlrooauusppmssi..c MeeTonnvrllepaarhrroggleeGommegeeininltctsal((hhwyyappcseehrrattanirlgoooepposhhyy))prcaooovnffeswishhs.eetppiaasnttgooowccyystotfeesshevwsceeserr.neetrrcoiehblvasoeeeb.rruvvleeaddrThiinentottihhneemciillddiizevvoneencrraessl.. endNNc.eeycctrrrooopesslliiaesssvmiivoocffe lSievveerritcyelolfs thweasaboavlesoLepsrieosnesntweraemomnogretvheiseensratasn.on mTahtee iensctidernacvee. and relative severity of the above lesions were more evident among male test rats. tIIhnnataadddddiiiettdiioonnp,,rioeerssppteeocciisaaallcllryyifaaimmcooenn,gg crrhaaattnssgesffrrooimnnvottlhhveein33g00,,theI10000p00rimaaannrddy 33(00t00h00ymppappsma, ddbooossnaaeggeewarllieeovvwee)ll tiaahnnntadaetstdssiieeneccedoosnn,ddparairrmoyyursctl((oesspplslaeeaneecdnnr,,isfkiicmmneee,,sseewcnnehttraeenerrgiiecccsbiisllniyyvvmmoeppldhhviannnngdooddteewhssee))raprLliAyymiemalpprhnycoooii(nddtshiydmooeurrrsggesaadnnssb,,ao8ne scstomtoamomrmparaooccuwhhn),,d rotates. intestines, related. muscle and skins were observed and were all considered as compound m95o00nkDDeRAyYYs RRaAHtEESSdUUoSSsaMWgOoeNwKKlEEeYYveFFlEEsEEDDoIIfNNGG0 SSTT(UU8DDiYYs::tillFFeCCd--99w55stuwemarss oaanddimm)ii,nniiss0tt.ee5rr,eedd1.bb5yy aggnaadvvaa4gg.ee5 ttmooa/rrkhhaeeassauuyss amFfnooodnrrke9a9y00lssoddaaayytissn..dotshTaTeegweoocommlnaaetllvreeeollsaanngddorfottuwup0oo, alnodvedalsioedin otrhewecroentsraoclrigfriocuepd. (ffideeniTTmashhassteellixeeltmmlrmmooeeoonndnnnkkikekewseyeyasyystssbeettrtwwrrweeeeoerraaneeettlneeyddii)nnV,iieaattott0iki.ssa5tttt,hheeee5dd1.44aaa5..ntt55d aeenmmaa7dogccr/hhokk4fag.ddj/5ootedsshsaaamayygggee/kddstgoollu/sseedadavvyggaee.leeyl TeTlnhheoeovnsesilees,mmdooinnbekkldeeayycosskr oesxxwthheoiirobbeliictaseenadddcrssidiifegingncynsedrooefftiinttooonxxe)iixcctfiirrtteoyymmisiitnnhbettehhteefwiegrgesaantssttwrroeooreiiknnsstteeecsso5ttniidannnaaddllaytt7rroaaofccftestt((uhaadennyoo.rrseetxxuiidAaayL;,L tSTehhmoeeev.soirhhseii,ggrhhib--glddiaoodcssikeetysmm;tooonnoCkkloeemyyuassnldshhiaaodddenhsdyd,edecrcargrteeeinaaoessnree)addliAfasrCceottdmiivvbiitotthdyyey fAaLinnrrddesstbbbieaoiffrnoogrr:saeecPddoreenoaadvttihhdraasysthhioooowwfneeddsatnmmuddaayrrb.kkoeewdd Altotlfoo bbtsooeuddvdyyeyrewweeii0rggihhg2tti..d7i0tyiTk,hhgeecammoCeneavawunnelesbkbiooodd5nyysO,ewfeiiggtgenhhnetterSaddtleeuiccdzrryeee.daasseebAddotdyff1zrootmmmroenm33tb..hl44i44nogfkK,ggStpaaurttdoysttthhreeaailtbbieeomggnoiinnnknnaeiniyndnsgg laoootfsfs ttthhhoefee 3a4s.7it55kuedlymmiggnt//eokkggp2//h.ddo7aas0yyphkagddtooassasataeggeewaecetLlkieevvv5ieetllyof.hhaatddhe dsetcurdeys.sedAt se1rummontchhoolfesstteurdoyl decreased serum cholesterol values and all monkeys values and soras at the serum alkaline phosphatase activity. ARAoLlnlLikmmoooynnskkeeeyyxsshiaabttitetthdhee GrrIeeImmGaahiitnnliiynnggdeddcoorsseaaaggseeedlleevvaeeclltssivisstuuyrrvviifvvreeoddm tttoohetthheefLreaenntdd oowffeoktthheeOfsstttuuhtdeyy... stTuThhdeey "mwShohtinioockclhehsy,sooccccaeaaixssahiiriooebnhniaeatalle,lldyy msbbulaeciccogaauhnmsteelyimmnoodddeeetcrrhraaeettaeesstettodooolmmaaacarrtnkkideevddi,.btlyooTTfdhhryeeomsaatnntoiihommelaa.llsfsirooTscchtcceaassw1iie.ooe5nnkaamlloollf/yykgthhhaaeddmonbbskllteauaycdcsykk esxthooilbsi,teddidaarmryhaesaa,timouncoours geinnertahle bsotdoyoltraenmdblibnlgooadty tshteooaln.d ofThsetu1doy5. mg/kg monkeys exhibited dehydration or general body trembling at the end of study. MNTooolaggrrreoodssssworooerr GommoiinccrrioonssccooSppLii0ccBUSppaattGhhHooRllEooEggiiScchaaallm tllheeessiiMooAnnrssOTwAwLhhEii,cchhPAwvneeCrrFee3c.cc.oonnassniidddeerbreeeddidccioopmmeppooluuennrdd rsSTeoaavllleaiilvtvsaeardryyweggrlleaannsddessenooffinmmaatllieessuaaennsdd female thous other than the female rhesus moreys at tne 4.5 adrenals, pancreas, monkeys at the 4.5 ma/kalasy dosage and submandibular mg/kg/day dosage level. NWoococussrttraaettdiissbtteiitccwaaellellnyy thsseiiggCnnoiinfftiirccoaalnnttanvdvaaerrxiipaaettriiioonnnessnteiilnn Gssreeoxxupsgg.rroouwp mmeeamn wweeiigghhttss ooff oorrggaannss Uncrate Reach ndDepCor t7) occurred between the control and (I.temationalResearchandDevelopmentCo~.;1978) experimental groups. ee re ero rr This information is intended to be used by a person qualified to evaluate toxicological dais. Inquiries are to be referred to Toxicology Sen4ces, Medical Department/3M, Building 220-2E, 3M Center, St. Paul, MN 55144o1000, (612) 733-2882. The above information is based upon studies conducted by 3M and/or by recognized professional testing laboratories. It is believed to be correct, and it is supplied to others upon] the condition that the persoo r~ceiving it shall ~rrake their own determination of its suitability for their purposes. 3uN0z252654 3M MN02252654 11337744..00000055 Test Descriptions condBBueeclltooewwdaaarrceecdoderesdscicrnrigibbeteoddsttthhaeenttdooaxxriidcciiOttyyEssCttDuudd(iiOeerssgcacnooimmzmamtoiononlnlyyfuousrseEedcdoiinnnottmeeisstctiinnCggoo33pMMorpparrtooiddouuncctatssn..dTThDheeetvtoeassittsosaparmroeonnnotoorr)rmmaallllyy (@) FHSA (USA Fodoral Hazardous Substancos Act) (ost Quidaiines or modificatioonsf thoso protocols. conducted according to standard OECD (Organization for Economic Cooperation and Development) FHSA (USA Federal Hazardous Substances Act) test guidelines or modifications of these protocols. or LLDD~,o,-`-ttohhreemiddloolssleetollreestthphaaellrttooK55i00%%loooffogttfhhaeerneeiaxxmppamoolssbeeodddaaynnwiiemmiagalhlsst...DDoossaaggee is is expreisngsraemsd, expressed in grams, milligrams milligrams or milliliters per kilogram of animal body weight. LG. --tpthaheretaasiirprbebororrmnnieellcciooonnncc(eepnnptmtrr)aattbiioyonnvollelettuhhmaaellottroom55i00l%%lioogfrf atthmhese epeexxrppoolissteeerdd(aamnaniiimm)aoalflss..chDDaoomssbaaeggree ciisosenexcxpeprnrreeasstssieeoddn in in for a stated period of time. parts per million (ppm) by volume for a stated period of time. or milligrams per liter (mg/I) of chamber concentration 11.. AAccuuttee OOorfraabllo-drreyeffweeerrssigtfoohtaitesesastdtomoiffnaaisssitinnogrgleleed ddorooassleelyoofofaaapplrbrooidnduouccrtt;a;baabssipp.eecTcihiffeiiereded wwiseeaiigg1hh4tt-odoraryvvoooblulsmuormevpploeirronkkiilploeogrgriraoamdm ofafoofnlldlbolooSwwdtiiyonnrgwgmeeddroiogs(shicinltngagi.ss.saiTTfdhhim eoedpipnorrionsoddtbeuuaracesttidsiissoorccfallaaollrsysassltiioffLiieaDedld,bffinoionror moorgrra/aablklbgtt)ioot:sxxi.EiccTxiithttyyreeraaemcceccislooyrarddt1iino4nxgogidctta:ooy t1tohhbmeesgsseoyyrvrssatteteem isomsn:oofpfHeHHirgoeihoddldggyee tatnooonxxndiitccoS::xtie11cr:1nto0e5r5500(1c0mmlagg1s;5;sgMM ifomieodsdde;eroRarnaetltebealatlyyisvtitseoolxxoyiifcch::oarra55m00liLctfoDoss5s5~:00i00n>m1mmg5gg;;g/kSmSglsl)i.i:gghhEttllxyytrtteoomxxiicec:l:y 500mg toxic: 500 mg 1 (05mg to5 gms, Practically or less; Highly gms; Practically non4oxic: 5 to 15 gms; Relatively harmless: >15 gins. 22.. AAccuuttee DDoeferrbmmoadalyl- wrreeefifeegrrhssttoos aaadteemssittnioosfftaaersseiinndggblleye ddcooonssteeioonffuoaauppsrroocdodunuctctat;;ctaa sfsoppreec2ci4iffiiheeoddurwwseewiiigglhhhtt ooirhrevvobolalurumemeeskppieenrrokkfiilalologbgriranamom doraaebf brbbibmotaitdslsy,. tTwTohhxeieeigcrroehltioissigsiaacaa11dl44mo-pddirnaaoyiypsetpperootrsesitetd--saab(ddy.mm.ci,inoniAnissmtittenrarautitoiicoouannsnoocNbboassntoetinarovvcnaataltlifiooSonrtna2pp4naedrhraoioodrud.dr.sAdAIwnedssittechisrtctuihtrpeiopl,tibivvaUereSeArrasalktFiiinenndggeoroofaffalhtlhboeino HacdHzelarazmaraasdrdlosotuouisxslicSSiouublcibosssgatatiaatscnnasiccil eeogpssnrnoeAA)pdccett,t,rotiHHetoehsded(pggi.reeeo-.-,dSSAuttecm ertrne.eerrircooafrnEENuurarootippoeenaaannl Economic Standards Economic Community toxicity Institute, USA Federal Community toxicity classification) is assigned to the product. 3.o AAccuutteeo~Ifnnhhapaalr~aaottdiioounnc-trreefffoeerrrsas 0tgoiavaenotespstetrooiffodaa sosfiinniggmlleoe.ccoAodnnettsiincnruuioopuutssiiivnnehhaarlalaattitiinoognnofeexxthppeioonsshuuarreleoaoftfiaaosnsppetecoixcfiificicoclccooognincocaeelnntrtraattiioonn opHpfrorodaopgppeeerrSotritdeteusirce(nti.seefo..,roAAarmmgEeeiurvrrieicocnapanpeneaNNnraioaiEdtlicoooonnnfaaotllimmSSiettcaa. nnCAddoadamrermddsusscnrnIiinptastiytvtiteutuotre,xa,iticnUUigSSyAAoclfFFateeshsddeioefirrinaachlaatHHilaaaoztnzia)oarnriddsootaouusxsssiicSSguounblobsegstdaticananclcatehses AAcctt,, (@) product HodgeoSterner product. or European Economic Community toxicity classification) is assigned to the 4. PPrriimmaarryyprSSokkdiinuncI~tirrt0iatatatiileobnni-noorreerffaeebrrbssitt1o0.. aEttteehssottrootfhsseiinOnggElleoGDddeeorrrmmatahlloaaFppppSlliiAccaatttiiooaon!nogouffi00d.e5lgigrnraoammisooarrmp00l.55omymiedlil.llilieIterrthoofef aa `sOpOerEEomCCidD-Duotccottesstlso!ut dmamealbdeti,tnhhooaodndrdattbhhhbeeelitssdsaa.immnEppciltlohoenetairsaatchapteppfplOlioiEe4erdCdDhtLooouoirirnnsttt.haaecOctbtFsskHekirSinnvAatttetoeisoostntsssigitteuaerisdeoeofmlfianttdhehreeeiseeaoteomf4r,pmm2lo4oo,ryre4eea0dan.aniIninmmdatahl7sle2s,, ahshobeourmurarissd-oeppcdoocssslutkt-diaanepppdtplo,ilsiacctanatsdtiiiotohnene.s.ldoIIfnninithhxcoeoanFFntHHiamSScaAtAlfsott,eoross4tct chmmlooueutdtrhhesood. ,ddOattbhnhseodessrhvaaammtpiepoillnnoecsliiosasnraaetppdapmpcllaiieedfddeorttaoo2t4bb4o,ohto2thuh4r,snin4.t8taaOcacbtntsdeaarnn7vdd2a- tiaaticoobcnrnaossrdadearirdeengsmmktaianoddtoetehaosatttp22sr44iotecaaosnndddoufr77so22ixohhfooauuDnrrrsisma..iazSSlocsco,ororiicnncggluffodorreddde,erram mnaadll hiiremrliidttaaittniioocnnoniinntbabocottthhfottree2ss4tt methods is hours. Observa- methods is according to the procedure of Draize. eOiOirxnrnntiatoertaoitooimnfnfgegtt,lhh,yeelsiiflfirogogihllthltolatlotwlywyiiningitnr.ggraittddaieetsnisncgcgr,ri,ippmmttiiivilvleddellyrryaaiittriiirntnitgagaststiiniinssgg,aa, ssm mssoiiodggdonnereearddattatteololyytthhtieroarippttarriootnidndguugc,c,tt:ss: eevvnnoeoorrmnoeil-liiyyrtrtiiartatraiitttiannitgginn,,ggmmiooinnrriim maallllyy extremely irritating. 5. 5. Eyo Eye I~mrirt`iatcatoitoinonjnun- crrioevffeaerlrsssttaooc:aotfteetsshtteoofefyaaesisonifnggtlhleeeaapteppalptilciacanatitimiooannlsoof(f u00s..1u1 aglrlraaymmaolborirn00o.11mramibbliillttislie)t.erEriootfhfeaarptprrhooedduuOccEttCiinnDttooo rtthhee icFFoHHhnSSjuAAtnhttceeetaseivttyaegglusuisioddabeeclsliioennrfeevtheiisesdeeaemm type1pl,oloo2yfy4et,edhd4.e. tIIeannnstttdhhaee7n2OOimhEEoaCGulrDDss(.ttueeIsssntut tammlheleyttFhhaHoolbSddinAttohhprrrereaoeebcabaenindtisiumm)r.aeaEllsssiitahxareraeerntinnhmooearrlmm OsaEalrClllyyeDuuuosssreeeddd t`wwwiiiimttthhehsotohbbmessaeeeyryrvvbeaaesttiioaoodbnndssseedaar.vtte22Sd44coaaartnnid1dn,7g27f242o,rhh4oo8euuyraressndippmooi7st2stat-th-aaiopoppunlprisilicn.caaIbtniotiotothnhn.e.prFAAodHdtdSdoicAtitoiiolopnsnraoailclseooadbcbsucseroeerrrvdvsaiaitxntiigoaonnntsosimtooahrrelseepvvaararloeluucaeautdtsiiueoordnne otifmbersazme.ay be added. Scoring for eye irritation in both protocols is according to the procedure of Draize. OneOnoxnonntone-ro-reiofrimfrteitttalahhtyoetiinniffgrgooi,,lltlaolmmtoiwiwinnniiignin.mmggaladdlleelyyssectirrriariipptttatiiitvnvineogg,rr,aamtm tiiinilnlgddgslslyyiissitararasisttsasiitiniggngnngee,,ddmmottoododettrehhaereatppteerlrlooyydduriurcircttitt:a:attiinnnnooggnn,,i-ssitreeravivtteaeirrteinenllggyy,,iirpprrritrtaaaactcttiitininccggaalloollyryr extremely irritating. PY mutaOOgtethhneiercrtitetesystttssesiintnscollauundddiinnsgguddbeearrcmmuaatlleosseernnscsihtitriiozznaaitticiootnnoxssittcuuiddtiiyeotsses((gtgsuuiimnneaeaayppbiiaggssc)),o, nhhduuummoaatnnodppaaatntccdhhsttueemsstmtssa,,riiinnzvveiidttrrooon the: Product Todeity Summary Sheol. mutagenicity tests and sub-acute Product Toxicity Summary Sheet. or chronic toxicity tests may be conducted and summarized on the 11337744..00000066 33MM_MMNNo022225522665555 + PPrroo4duucctt TTooxxiicciittyy SSuummmmaary, SShheeeett Form 15594 - G - PWO rPaaggee 44 ooff 55 SM ioRwaA hoy ota gGiengtcrto etary fAh se ed Oelons fet oceasIs tdnrevr 890 Product Name lssue Deto FLUORAD Brand Fluorochemical Surfactant FC-95 June 5~ 1992 Below is a summary of the study data giving an indication of the relative toxicity of the product. (Definitions of test procedures are found on the reverse side of lhis sheet.) This summary is the data for the precautionary use information provided with the product. Relative toxicity of a material is only one factor that is important in determining the degree of hazard in handling a chemical or product. Other considerations to include are physical properties of the chemical, extenl and frequency of use or exposure, intended use, and possible misuse of the product. For additional information regarding safe handling of the product, please reference the Material or Product Safety Data Sheet. 12122233-4-1100 sSuuppeerrsseeddeess oOccttoobbeerr 22,, 11999911 TCTEoEnRRcAaeTonOctGmrEuaNItXCiCIoXTnTsYY i((nRRtAaeTmn))d::ed tNNoOoTrdeTTlEiEKvMAeOTrGOEG1EN,NTTII5CC.oor 1F0FCC--m99g55,/,kg/ssduuassyppeenn(ddGeerddoupiisnn 2cc,oorr3nn, ooaiinlld a3a,tc rCrceoeossunppceeerccnattttiirsvvaeetlloiyyno))n,,sprwwieaanssptueeaanddddmmeiidgnneiistsstottaeetrrdieeeoddlnibbvdyyearyoosrriaa,ll6-51ii5nn.ttouurbbaaiAtt0iioofnnmogu/ttrkootgh/mmdaagattryeeoddup(ffGeer(mmoGaaurllpoeeswpSS2pp,rr1)aagg3,uuoeef--abDnmaadavwtileeedyy rCffDaeotmneaallrpeeaosstrsssdeeoorrnvsveeeddplreaaevssseulttm.hheeed ccgooennstttrraootllioggnrrooduuappysaanndd6-1rr5ee.cceeiivvAeedd fttohhueertvvheehhgiirccollueep only.(Group only. TThhiee)rresofwweerrmeeate225d5 rats per dose level. T"vwaoondGGrroo&uupp i44ncffleeummdaaelldeessthddiiineendde..ss,TTrrehesuatntcmmheeenndtt--rrseepllpaaettseerddanccclleiisn,niiccraaollugoohbbsseehrravviaarttciioooanntsss,nnooattleeoddpeiicnniaGG,rroouuappnssd 3aCanononoartrnreedoxxliiaa4..biontchFFloouoodddduerdccioontnnghasiuuntmmnreeeeddsast,bbmyyenhtGGurrnoocauuhnppedssd 33tahpraaponneuddagrha44onuctaaennsii,gmmeaasllrtssoautgwwihaaossnh.assiiirggcnnCoiioaffrtiipscca,aarnnettdalllyyoSpoelLceeisscasso,ntttrhhaoaanlnnd ac((noGGdnrrtooru4uopplfoI1n))ablobbetooshdd'yytdwwhueerrioiigugnhghgthtoutggtraaeiianngtssem,,setnassttiiiggonaaniin.ffdiiccaaAtnnchtttrluloyayulghlloeleusostssssbbgoooefdtsyytbawowtedeiiyioggnhhw.tteigwwahaCstsomoggpacaaicirnnueeerdddredbbtyyoiGnGrrcooGouurnppotssurpols33 g3a3r"nadaavnni4dddf44eumtaaaenlnrieiimsmnaaelltsshrwoooeunnigccgheehotutttrrweagaasesttsomtaeaanntlttieocnhh.aaddsiAgbbcneetieeufnnailciiannnliitottlsiiysaattoeefddde..cbroedayTTseeerrwdmmeiiinngiaahnllt obObcoorcddouyyurprswweeedii3ggihhnttaGnmmrdioinunupu4:sss TGgTarrrascevtoairttdommieennnutttte--esrrrteeiillnnaaeattleeddwteriggagrrchoottssssefwfappesaacttthhsaoo.lllsoooggyy in Grow significantly in Group 4 aadnneiicmmraaellasssediinnccillnuuddeeGddrouiipnnscciidd3eennccaeensds oo4ff gastrointestinal tract effects. aSStttaatttriiissbttuiitccaaabllle aannpaarlliyymssaiirssilyrreevv0eeaalleeandd aaincpprooessaiistteiidvvee itntrcrieedaaettnmmceeenntt--orrfeelllaaattteeadd ttrrreeesnnoddrbiiinnny fffeeettraavlleellsoossssi,,n loaliiitttgtttrneeiirrbfssuitcaaffbnrrltooelmmy pdrGGeirrcmoorauuerppaisle44yd dtdiaoanmmssfa..antuisneMMcseeraaeGnnarsoeummdpaaslleei3ncaaainnnddddenc4ffeeelomiaaotllfteeerlsaff.taeettaallSriegsbbnoooirddfbyyiicnagwwneetiifggehihttntsucs.sreesawwseeerriseen iisinnnicglneeuixxdftteieedcrrannnaastllulbycaaunndtddeacnrvveeiioassusccseeedrraaeldilenmaaaf,nneootmmuacasllleiieseefsstGrooopuccapcclsuuarrtrr3eee,ddanadiinnnd4 fflceeirtttyuutpsseteerosssc.hffirrsSoonimn.gnGGirrfooiAuucnppaonmt44aliiddneaacsmmrsseawseaaernnedsd omoiabbntssceeelrrrunvvdaeeelddd pptsorruxiibimmccaauirtrtaiiynll,eyyousiiinn.c.e,fdfeeemttaudu,sseeecssrcelaeffsfrretoodnm pfGGaorrloooadtuuepp,cod4nsanudddmaapmmtssciroyneopxxthhoaiirnbbcdiihttiiswinmen.gigghsstiiAggnnnlossomsasolo.ffiesssePewveveteearrrleee mttfaoooxtxtieiucrrceinintat,yly dmtmeaoacxnnriiiacffaieestsseyttd,eeddfeiraoaassel.,iibnnodccderryecearawsseeeeaiddsgehdtnnsuu,mmfbboaeeonrrddss cdoooefflnisyullsmaaptttieeinonsrrkeeessaloonerrdtbbaiilnwngegisgyffhseetttteuumssleeoossssss.iaafnniddcaFtedditeeoasanldd ofcetcuusrerse,d idneclrietatseerds fdeetrailvebdodfyrowmeitghhatts,Graonudp daeslawyesll.in skeletal system ossification occurred in litters derived from that group as well. TT9hh5eetosspppeercceiigffniiaccniitttyyxaaantndad dffurrreeiqqnuugeennccDyyayeooff6t-th1h5eesseeofrrgeesseuuslltttasstioiinnnddiiactcaatt&eedttohhvaaett ofaaddmm1ii0nnmiigss/ttkrraagttiiFooOnnBNLooEffEFFCCi--n mmV95aaittseectrreonnraaaplllreagttnnooaoxxnniitacciiiirtteayyst,,sandfdfueerttsiooknttegoolxxeDiitaccayiilsttyyv6a-r1aai5nnaddnotfs.aagnnestiianntccirroaensassaeetdd a iidnnoccsiieddeeonnfcceei0 oomffg/keegxxtteerrrennsauallltsaanniddn visceral anomalies and skeletal variants. FFFOCC---995555 i1inss nnnooot ttteeerrraaatttooogggeeennniiiccc aiitnn drroaastteses aabtteloddwoossmeeatlleeervvneealllssly lletessossx ictthhlaaennv eoorrrs. aqual equal to to 5 5 ma/ks. mg/kg, ton FC-95 iLsorntootn tAemrearto,gneen:iDc eatedros15e,0s5 b15e4l1o6)w maternally toxic levels. (H~elton ~bomto~Amefica, lnc.;Decemberl9, l~3;l~-l~) E Fe eeE oot ae te ee aT SoSee This information is intended to be used by a person qualified to evaluate loxicological data. Inquiries are to be referred to Tcxicology Services, Medical Departmentt3M, Building 220-2E, 3M Center, St. Paul, MN 55144o1000, (612) 733-2882. ]'he above information is based upon studies conducted by 3M and!or by recognized professional testing laboratories. It is believed to be correct, and it is supplied to others upon the condition that the person receiving it shall make their own determination of Its suitability for their purposes. W_MN02252656 3M MN02252656 11337744..00000077 TTeesstt DDeessccrriippttiioonnss condBBueeclltooewwdaaarrceecdoderesdscicrnriigbbeteoddsttthhaeenttdooaxxriidcciiOttyyEssCttDuudd(iiOeerssgaccnooimmzmamtoiononlnlyyfouurssEeedcoiInnottmeeisstctiinnCggoo33pMMarpparrtooiddouuncctatssn..dTThDheeevtteelssottspsmaaarreen)nnooorrrmmaallllyy @) cFoHnSdAuc(tUeSdAaFcocdoorrdailngHatozasrtdaonudsarSdubOsEtCaDnc(eOsrgAcatn)iztaetsiotngufiodrolEicnoonsoomr imcoCdiofoipceatraiotinosnoafntdheDseevperlootpomceolnst) or FHSA (USA Federal Hazardous Substances Act) test guidelines or modifications of these protocols. LD, LDs0 -t`tohhreemddioloslseeltllreestthhpaaollr1toK0i55l00o%g%raoomff tothfheeaneeixxmppaoolsseebddodaaynniiwmmeaialglhsst... Dosage Dosage is is expressed expressed in in grams, grams, milligrams. milligrams or milliliters per kilogram of animal body weight. LG. LCso t-`tpfhhpoaaeerrrttaaasspiisrptetbbearoortmrrem nindleeillplcciieoooornnnincoc((edpepnponptfmrmtra)ta)titbbiimoyyoevn.nvoollleleuutthmhmaaeell ttooorm55i00l%%ligoorffatthmhsee or milligrams epeexxrppootsseeerdd(maagnn/iilmm)aaolflss.c. hDDaoomssbaaeggree per liter (rag/I) of chamber ciisosenexcxeppnrrieeissassteeiddoniinn concentration for a stated period of time. 1. 1. Acute Acute OOorrfaal~boo drreyeffewererssigt0ohata ittseeasstdtmooiffnaaissstiinenrggelleed ddorooassleelyooflfoaappbrrioonddouuccrtat;;babaitssspp,eecTcihiffeiiereded wiwseeaiigg1hh4tt-dooarryvvooobllusumemreevapptoeirrokkniilploeogrgriraoamdm oaffoonflldlbolooSwdwtiiyonnrgwgmeeddroiogs(shicinltngagi.ss.saiTTfdhhim oeedippnorrinosotddebuuarccesttdiaiissocorclfaalaolslryssasiltifofLiieaDedyldb;ofinoirnor morraraalalbklbgttlioot:sxxi.iccETiixhtttyyerraaeeccmcceisoolrayrddt1iino4nxg-gidc1at:o0y tt1ohhbmeosgsseyyrovssratteetem isomsn:oofpfHeHHirgoeiohddldggyoe attnooonxxtdiioccS:x: ite1c1 r:1tno0e555r0(01c0mmlag1gs;5;siM Mgfoimeodsdde;eroarRnaetltebealatlyyisvtitseoolxxoyiifcch::oarra55m00llLet1oDs0.s~55:00i0n0>m1mmg5gg;;g/kSmSglsl)ii.:gghhEttllxyytrtteoomxxiicec:l:y 500mg toxic: 500 mg 1 {05mg to 5 gms; Practically or tess; Highly gins; Practically non-toxic: 5 to 15 gms; Relatively harmless: >15 gins. 22.. AAccuuttee DD`oeferrbmmoaadllyr- wereefifeegrrhsstttoio.saadtteemssittnioosfftaaersseiinndggblleye dcdooonssteeioonffuoaauppsrroocdodunuctctat;;cta fssoppreec2ci4iffhiieeoddurwwsoeiwiggihththt ootrhrevvoobllaurumemeeskppieenrrokkfiilalologbgirranoam.m dorraaefbbrbbmbioaittdlssy..twTTohxheeieicgrroeehltoiissigsiaacaa11dl44m-opddirnaaoyiysptppeeoorrsestltdi--eaabdsdymm(ic.n.i,oninAsismititrenraarutitoiiocuoannsnoocNbboassnteetirarovvcnaatattlifiooSonrtna2pp4needhrraiooirudodr.dssAA.wInddisetethsisctctruhrtieiopp,ttbiivaUvereSerArasatktFiiiennndggeoroofaffalhtlhbee.ino cdHHleaaarzszmasairarlddliooctouuatxssiicoSSnouu)lbboissgsttiaacasnanscclieepgssrnoAAepcdcett,{,rtoiHHetoeshdde(ggi.peeer.-o,SSdtAuteecmrtrnn.eeerrircooarrn European National European Economic Standards Economic Gommunity toxicity Institute, USA Federal Community toxicity classification) is assigned to the product. 33.. AAccuutteeoI~nfnhhaaalplaarttoiiodonnucotrreofffoeorrrassg0tiovaaentteespstetrooiffoada sosfiinnigglleo ccmAoonndtteiine snucurooiuup. sstiiivnnehhaarlalaatittiniogonnofeexxipphoeossiuunrrheealooafftiaaossnpptoeocxciififciicoclccoogoinncccaeelnnttrraattiioonn HpoprforooadppgpoeerrroSttitdeieuesrcf(nti.eeefo..,orAArammgEeeiurvrrieicocnapanepnaeNNnraioatEdticioooonnnfaaoltlim mSSitetcaa. nnCAddoadamrermddsusscnrIiinnpststtiytviiteuuetxtreeia,,ctiiUUntgSSyAAoclfFFatesehdsdeeierfirianaclhlaatIlilteaaozntzia)oarnriddootaouusxsssiciSSoguunlbobesgsdtitca0aannlccteheess AAcctt,, (@) product HodgeoSterner product. or European Economic Community toxicity classification) is assigned to the 4. PPrriirm~aarryyprSSokkdiinuncIItrrritittoaatatiiloobnninoorreerffaeebrrbssitttoos aEittetehssettrootffhsseiinOnggElleCe DddeeorrrmmatahlleaaFpppHplSliiccAaatttiioosontn goouffi00d.e5liggnrreaamims ooerrmp00.l55oym meiidlll.illiIteenrrthooeff a a OsOproEEoCmCdDiDucotttecotsscottlam mulebedtitnhhoaooodnddr,dattbhhhbeoitsssoiaa.m mnEpcpilltolheenetiirdsaotchaatpeppfpOollriiEeo4CddhDttooouoriirnsntt.thaaeOcctbtFsssHakkrSiinvnAatttetoeisssotttnsssgiitluaeorisdsceoomlffianttdhehrereisoeaetoom,fr pmm2l4ooo,ryr4eee6daa.annnIiinmmdatahl7les2s,, ashhbeoorumurarFssdoappcdoocsssltukt-idaaneppdptplo,siliatccnasatidtliiooohsnne..ldoIIfnnsinihthxcoeoanFFntiHHamSScatAAlsfotL,earsso4tct shm mloeueutdtrhhosood. ,ddOattbhnhseedessrhvaalammdtpipolilneensciisasornaaetppapmpclltaiiedefddeorttaoo2t4bb4o,ohio2thuh4r,isin4n.8ttaaOaccbtntsdaacnnr7ddv2a aatticiobocrnnaossrddaeairrdeengsmmkatianoddetteehesaatttp22sr44iotecaasenndddoufr77se22ixohhofoauuDrnrsrism a.i. azSSelcs.co,orroiincncggluffoodrredddee,rrammnaadll ritation in both test held in contact for 24 irritation in both test methods is hours. Observa- methods is according to the procedure of Draize. OOinnnioteaotoiffntgth,heoslffioogllhloltolwwyiinrngigtddaotesiscncrgr,iippmttiiivlvedolrryaaittiriningtgasstiiinssga,assmssoiidggennreeaddtattoloytthhieeitpparrtooiddnuguc,ct:ts:evnneoornneil-riyrirtiitarartitiitnnaggti,,ngmmioinrniim maallllyy extremely iritating. irritating, slightly irritating, extremely irritating. mildly irritating, moderately irritating, severely irritating or 55.. EEyyoe IIrirti`taaotntiijoounnn-cirrieovffeaolrrsssttaoocoaatfteetsshttooooffyaaossoiifnnggtlhleee aa(poppaptlliiaccnaaittmiioaonnlooof(f u00s..1u1aggllrrayamamolobrir0n0.o.11rammbibliillltiil)itt.eerrEootfhfaearpprtrohoedduuOccEttCinDnttooortthhee. wcFFioHHtnSShjuAAhnettceotas0ivttya0gql3usuiodabecisloiondrfevtiheoissedeloeammtypiep1l,looon2yfy4ot,eghd4d.e8. taIIennnsttdthhaee7n2OOimhEEoaCCulrDDss.(ttueoIsssn!uttammhleleeyttFhahHolobSddinAttohhprrrercaeoebcbaaeinndtsiium)rm.eaaElsssitihxaaerraeerntinnhmooearrmlmOasEalaClllryyDeuuuosssreeeddd wwwtiiiitttmhhhestoohbbmessaeeeyryrvvebaasottiioaoodbnndsssoedaar.vtte22Sd4coaaartnni1ddn, g772224f,ohhr4oo80uuyrarossndtppaoo7sts2ttiohaoaopnpuplprsiilnic.cabaItnoititotohnhn.e.pFArAdoHddtSdiotAitciioooplnnraoailclseooadbcbsucseroeerrrvvdsaiaitxntiigoaonnntossimiooahrrelesepvvaararloleuucaeautdtsiiuoeordnne toifmDersaimzea.y be added. Scoring for eye irritation in both protocols is according to the procedure of Draize. OOnonnnoeirooifftttahhteoinffgoo,llllomowiwniininmggadldolesysccririiiptptatitivivenogrr,aamttiiinlngdgslsyiissiraatssasstiiiggnnnge,eddmootodotthrhaeotpperrlooydduiucrctt:ta: tinnnoognn,i-siiretrviateatriteinnlggy,,ipprrtraaacctttiicicaanlollglyry extremely iritating. non-irritating, minimally extremely irritating. irritating, mildly irritating, moderately irritating, severely irritating or mutaOOgtethhneiercrittteeysstttssesiintnsccllauundddiinnsgguddbeearrcmmuaatllessoeernnscsihitrtiiozznaaittciiootnnoxssittcuuiddtiiyeetsses((gtgsuuiinmneaeaaybppioiggcss)o),,nhhduuumcmtaaennpdpaaatntccdhhsttueomssimtssa,,riiinnzvveiidttrrooon the m PruotdaugcetnTiocxitiycitetystSsuamnmdasruyb-Sahceeutt.e or chronic toxicity tests may be conducted and summarized on the Product Toxicity Summary Sheet. 11337744..00000088 I3MM_MMNN0022225522665577 + PaPrriooddsuucct7t0TT0ooxxiicciittyy SSuummmmaarryy SShheeeett Form15594-G-PWO Product Name page 5 of 5 Page 5 of 5 SM Issue Date tlt cs test Ht Crs oe rine _ ~.~ Below is a summary of the study data giving an indication of the relative toxicity of the product. (Definitions of test procedures are found on the reverse side of this sheet.) This summary is the data for the precautionary use information provided with the product. oc ota tras nrc nt poe tra degra ein chicas cde OP rcs Relative toxicily of a material is only one factor that is important in determining the degree of hazard in handling a chemical or product. Other considerations to include are physical properties of :he chemical, extent and frequency of use or exposure, intended use, and possible misuse of the product. For additional again Brin i te Pe Sy Ss Je IHD 0 Fr bor information regarding safe handling of the product, please reference the Material or Product Safety Data Sheet. 12122233-4-3100 Superaades october 2, 1991 Supersedes October 2~ 1991 IINN VVIITTRHOO NMUUTTAAGGEENNIICCIITTYY TTEESSTTSS:: NNOOTT MMUUTTAAGGEENNIICC.. FFCC--9955 was was tteesstteedd for for ite its mmuuttaaggeenniicc pTpTEaAooai1ttcs5eeh33nns8tts,,iitaarllaTTiAAwwn9iSi8ttvhhasasnnffddiitvveeeTTsAAtILAAe00mmd0OeesswaaiSSnncaaddhllmmwawooininntdteehhlllulaiattthhhtteeo_yyop_yythpeeihaami8ssmutturmrieiSuStuammaaccvccbbohhaalaaccirrttceoeemmrrayviiccacateeissssvttarrctcaaeieiiorrnnneessvv~,iissstTTiieAAaap11e.eS533S5Ss,,ttArriaalTTiiAAnn11t55e33s0D774t4,to.s wEWCeaehrcroehen Bnnseeteggraaacttiiin,ovvcee:wFaiisennddtbiieccs9aa7ttt5e,iidnnLggIwPiFFtCCh~r-955Naoen.i1d3s8cw)nniootnmhmomuutttaaggeaenniimceetaiibnnolttihhcee assays. activation assays. step. All tests (~ttonBioneti~,Inc.;~b~a~19~; LBlP~ectNo. 208~) (105-pcss) (105-FC95) 3M Industrial Chemical Products Division 3M Industrial Chemical Products Division This information is intended to be used by a person qualified to evaluate toxicological data. Inquiries are to be referred to Toxicology Services, Medical Departlqentf3M, Building 220-2E, 3M Center, St. Patti, MN 55144-1000, (612) 733-2882. The above information is based upon studies conducted by 3M andfor by recognized professional testing laboratories. It Is believed to be correct, and it is supplied to others npon the condition that person receiving it shall make their own determir~ation of its suitability for their purposes. 33M uMN0Nz02225522665558 11337744..00000099 TToesstt DDeessccrriippttiioonnss . condBBuecltoeawdaaarrlceecdoderesodscicrnriigwbvee10ddsttthhaeendttoaoxxrcidciiOltyysCsttDuudd(iiOeerssgcaconoimmsmamotinoolnnlyyfuursEedcsioinntoetemesistctdiinnCggoo33pMMerpparrtooidduoucnctasts.n.dTTDhheeevtteoelssottspsmaaerrenetnn)ooorrrmmaallllyy @) cFoHnSdAuc(tUeSdAaFcecdoerrdailngHatozasrtdaonudsarSdubOsEtCaDnc(eOsrgAcatn)iztaestitongufiodreElicnoensoomr imcoCdoiofpiecraattiioononfasntdheDseevperloofpomcoelns.t) or FHSA (USA Federal Hazardous Substances Act) test guidelines or modifications of these protocols. LD,LDs0 -tothhrm ee ddoosi see lleetl tphhaarll t1kt o0il55o00g%e %roaomffor ttfhheaeneeis xxmppaoolsseebddodaaynnwiimemaialgslsh... Dosage Dosage is is expressed expressed in in grams, grams, milligrams. milligrams or milliliters per kilogram of animal body weight. LGLC~0 -ttphhaeertaaaiirpfboborormnmieellcciooonnncc(eenntortraatbtpiiyoovnnomllleoutt)hmhaaello1tro0m55i00l%l%igoofrfatthmhese eopoxxtppoossoerodd(aanniimmmaoalflss.g.chDDaoomss)baaoggreeciisosnaecxxeppnrrteorssassteoiddoniinn fora stated poriod of time. parts per million (ppm) by volume for a stated period of time. or milligrams per liter (mg/I) of chamber concentration 1. 1. Acute Acute OO`Tororoffaal~lbbloooo ddwr-eiyyonffewwegrraesdsioiggttcohohitntaagii.stosesaasTtddthmm ooaifnfipanairissssottiidenonurrggecallededsddoooorrcassalleiaelsyoyosf1tifo0faaiiapepbldrbriooionnddroouurccrraatat;blb;ababittissotspsxp.ie.eccTTciihhtiffayeiiereradeodcciwwisoseeralaidgg11ihh44ntt--gddooararyyvvtoooohblbluesusmesemryerevvsapaptteeteiirormonKknoiilfppolaoeHgrgrroiiraodoamddgmo ntatfaoooonnxxlnddlioitccSoSw:t:xet1iienm1c1rmg:nto0oerd5r55o(00(sccmlirnlaaga11gsgs:5s.;sigTMiM ff6mihioeoesedddd;peooerRrnnoaerdltbbeaauatlcytiastvtiteseoiossolxloxyfcificihyola::oar5srasra5lsm00liifLoLitteoDosdss550D:00foi>00nr1mrmmoa5garggla:;g/klkSmSgtgislol)g.:i:gxhihtcEEtlixlxtyytytrrtteaooomcmxxiociecclo:l:yyrd55ttioon00xx0gi0iccmm:t:ogg1t1ht1mo0me.g5g5soyggorsmmrtlesl;oem;gsePPs;ro;raHfaHciHctgitigeihcchdlaalglyyllleyy non-toxic: 5 to 15 gins; Relatively harmless: >15 gms. 2. 2. Acuto Acute DIoDeferrbmmoaadl~y- wreoriofefgrohsstttooi.s aatdteemssittnooiffsaatsrsieinndgglbleey ddcooonssteeioonffuoaauppsrroocddouunccttt;a; caa sfsoppreec2ci4iffiiheeoddurwwseewiiiggthhhtt ootrhrevvooblalurumameesipponerrokKfiilaollogbgriarnamom oTorafarbbbbmobidta.sy.twTTohhxeeieigrcrecohltiiosaigsiaacaa11dl44m--pddirnaaoiyypsetpperootrsesitetd-saabd.dymom .i,cnioAninsmistteitrnrraauittoiicouoannsnoocNbboassnteetirarovvcnaatattlifioooSnrnt2app4enerhdriiaooodrud.dr.ssAAwIddnioteohssuctclrhrioeipp,tbtivvaUeorSeArrsaaktFtiiinenngdgoroofaffalttlhbheeino dHcHleaaazrszmasairarfddliootcouuaxtssiicSSonouu)blboissgsttiaaacsnnascclieepgssrnoAAepcdctet,{,rt0iHHetoeshdde(ggi.peeer.S-o,StdAuatecmrtrnn.eoerrircooarrnEENuuarrootippoeenaaannl Economic Standards Economic Commuiy toxicity Institute, USA Federal Community toxicity classification) is assigned to the product. 3. 3. Acute Acute iIfnnhhaaalplaarttoiiodonun-o-torefffooerrrssa ttgoiavaetonteosrsttioooffdaa ssofiinnm gglleo ccAooo nndttsiinsncuurooi. uupsstiiivnnohhaaaltlaaittniiogonnofeexxtppheoossiuunrhreeaiooafftiaaossnppetecoixcfiifciicaclccooognincccaeelnnttrraattiioonn oppFirfrooaodppgpeoerrotriSdeitusoecrs(tmi.ceefo,r.,roAAarmmgEeeiurvrrieicocnapanpeneaNNrnaioatEdtiicoooonnnfaaoltlim mSSitetcaa.nnCAddoadamrermddsusscnrIIiinpntssttiytviitetutuottrexoai,,tciUnUitgSSyAAoclfFFatoeshdsdeeierfirianaclhlaatHHilaaaoztnzia)oarnrsddootaouusxssisScSiuoublgobongstitacaonanclctoehses AAcctt,, (@) product Hedge-Sterner product. or European Economic Community toxicity classification) is assigned to the 4. PPrriimmaarryy`pprSSrookkdgiinO unutoc~Itotnrsr0ttE oittaatamatiilaloobbC tnniinhn-ooorrdeerrDfafateebbhrrbbsseiitt1stso0..:aEatethietshmostetrr5oophtffhasospeilpinnOOlggioElEleoeCCdDDdd1oeoeorrrnm rmtattahahllceotaaFFppspHHpklSSiliincAcAaaattttesiiootsossnntioggtofueufsii00ddo.5ee5glfliigrnntreaaoommiisaos ooerermrm00p.pm.l5mlooom ryiyoeeildll.ai.lnitIItinenmratetohlhoefsofr,aa ShOseoeErummCriisD--ooptcceoccsslltutu.ddmaeopeddp,lt,hiaaocnnadtddithohhneoe.llsddIaniimnntphcceoloennFtitsHaacScattApfpfoaloirsert&4d hhmtoooeuutrirnhsst.o.adOOcbttbshsseekersinrvavaamttetiisootnnsssiitasaerrsaeepopmmflaaitdhedrdeee0eaaltob44ro,,mt22h4,o,rn84et8aacaantnnimddaan77ld22s, taihaboboinruaasrdsdaeeprddoosssmkkta-iianndtpetepeslasitlctsa2sit4ititoeeanssno.dofInf7ss2thixxheoaauFnrnHisimm.SaaAlSlscst,o,erosoictcnccmglluuefddothreeodddd,e, raathmnnaeddlshhiaeermlltddaptiilnenioccinsoonnainttpbaapoclctitehffdootrrtoo42s4tbohhmotoehuutrrshisn.o.tdaOOscbbtsiseasernrvdvaa:- aticocnosrdairengmtaodteheatp2r4ocaenddur7e2 of Draize. hours. Scoring for dermal irritation in both test methods is according to the procedure of Draize. iOOnnnieetaootfifnttghheeslffoioglllholtolwwyiiningagtddieesnscgcr,riippmttiiivlvedelyrraatttiianntggissniisgs ,aassmssoiigdgennreeaddtettoloytthhieenapptrroiodnduguc,ct:ts:ovnneoorinail-iytrranittiaittainntggi,,ngmmioinnriimmaallllyy extremely imitating irritating, slightly irritating, extremely irritating. mildly irritating, moderately irritating, severely irritating or 5. EoEye I~rFrcicitHoaontSntijejuAunnanc-tcioortitsefivvtfeaeariglrlusdst$soota2ool0c.inaoonoftfoe-sthshtitoesooofe0fm7yaape0slsooioifnnfyggttohlldehee aatlIeopnsspptttlhiaacopnnaOiitmlmiEoaaCnlilDoseofc((ftuu0o0s.ss.a1u1tugaamgltrllarlayaytimmahaololobobrdiirn0nn0too..h11rrraaom mbbabibinltliiiitsls)imt).ea.lrlEEosotifthfthaaoaerrporprettrnhoohoededrurumOOcacEtEltCClinnyDDttuoooosrrttohhdeo wwwFiiHittthhSh Aothhbetesenseevtyyaeegtssuiioodobbensslsieenrarevtveei2sddeaaatmtn11pd,,lo7224y24,e,hd48o.8uaIrannsntddhpoe77s22tO-hhEaoopCupurDlrsis.ct.eaIItsnnitottmhnh.eoetFFAhdHHodSSditAAtpihoprrneroaoeclceaeodndbuiusmrereeravlsssaixtxairaaoennninsimmooararlmlsesavralalryloeuuauustsseieedoddn tofimDersaimza.y bo added. with observations at times may be added. Scoring for oyo 24 and 72 hours Scoring for eye tation in both protocols is post-application. Additional irritation in both protocols is according lo observations according to the procedure or evaluation the procedure of Draize. eOnOnxonontionerro-eioifrmtfreiatttlahthyieteinnrffggoao,,lltlolmmioiwnwinnigiinin.m mggaalddlloelyyssecrirrrariiipttpatititvinineogg,rr,aamm ttiiinilnlgddgslslyyiisstiraaraiststassitiinignggnng,ee,ddmmttooooddattehhrreeaatptperlrlooyydduitucrarcti:ttt:aitninnnogogn,n,r-isoirtevriavotateritreiennllgygy,,iitrpprrairtaataccitiitinniccggaalloollfyyr extremely irritating. mutaOOgtethhneiercrtitetesysttesssiitnnsccllauundddiinnsgguddbeearrcmmuaatllessoeennscsihlirtiiozznaaitticioo{nnoxssittcuuiddtiiyeeesss((tggsuuiimnneaeaay ppbiieggssc)),o, nmhduuamctanendppaaalntccdhhsttueemsstmtssa,,riiinnzvveiitdtrrooon the PmruotdaugcetnTiocxitiycitteystSsuamnmdasruyb-Sahecoult.e or chronic toxicity tests may be conducted and summarized on the Product Toxicity Summary Sheet. 11337744..00001100 3M_MN02252559 3M MN02252659